201132495 六、發明說明： 【發明所屬之技術領域】 本發明係有關-餘水麟之製造驗，制是指_種用於大型 巴士或是火車車廂間連結伸縮縫、耐燃性複合材料之製造方法。 【先前技術】 近代路上交通工具發展迅速，全球許多開發中或已開發國家大量 應用大眾運輸交通玉具，而各種大科輸交通卫具多有㈣節以上車 厢連結方式來增加載客量；諸如火車、電聯車、捷運、大型兩段連結 鲁巧士 (台灣目前無這種巴士’但歐美與大陸相當常見）、高速磁浮式列 車等等，最早僅用掛勾方式連結各車厢，而現今為了讓乘客方便在車 廂與車厢間移動’車厢與車厢間設計成通道，因此需使用橡膠皮料所 製成之連結伸縮縫(Gangways and bellows)來避免金屬製成的車厢相 互碰撞》 ▲此外，由於現今社會發祕速，對大眾運輸交通卫具的要求也更 除原來訴求的便利性、速度、高效率外，在安全性的要求更是不 谷忽視，各國皆有大眾運輸工具在消P方相關的安全法規。 -般應用之橡軸織物之複合材料在物性上強度不足、耐燃性亦 _ 不夠，且成品需要三次加工，包括先製作織物之第一種複合材料再 製作第二種複合材料，接著將兩種複合材料貼附組合，在貼合過程所 需之人工成本高昂，也因此需要較長的工作時間，工作效率低落，且 加硫後的橡勝做大面積接著時容易產生接著不良之情形。 因此，本發_提出—種顧於連結伸縮縫之耐雖複合材料之 U方法了產生手感柔軟、易於加工、強度更強，耐燃性更佳且更 对久之五層式結構之橡膠皮料，以有效克服上述之該等問題具體架 構及其實施方式將詳述於下。 【發明内容】 本發明之主要目的在提供—種細於連結伸綱之耐雕複合材 201132495 ΓΓΓ ’絲料财及妓找可生產μ度更好、_性更 佳、加工性更好且更耐久之五層結構之複合材料。 2明之另-目的在提供—種朗於連結伸縮縫之_性複合材 之.方法’其係錄邦海魏與娜填_、耐燃鮮配合材料 經過屋延的技術製作出的橡膠㈣合在㈣纖維之基布上，並以麼 延、熱壓合及硫化步驟形成膠料_基布-膠料_基布_膠料之五層結構，使 材料具更強的物性。 ，本發明之再—目的在提供—種細於連結伸賴之咖性複合材 料之製造方法’其係、提升橡膠複合材料之加卫性可有效降低加工難 度、增加加：L的效率，進轉低成本，提升辭優勢與降低不良率。 本發明之又-目的在提供-種應驗連結侧縫之·性複合材 料之製造方法’其做科献生產，與傳顏壓以狀*連續製程 相比，連續式生產無接頭，故可大幅增加每捲之長度。 為達上述之目的，本發明提供一種聚氯乙烯抗靜電膠皮之製造方 法，包括下列步驟：將一橡膠混合物以一萬馬力機混煉成一膠料，冷 部後將勝料進行第二次混煉，並再次冷卻後靜置；接輕膠料塗佈於 基布上，愿延形成一膠布，並將膠布分別以膠面朝外及布面朝外兩 種方式捲取出第—膠布及第二膠布，膠料並1延出-橡膠薄片；將第 一膠布及第二膠布分別貼合於橡膠薄片之上下，且第一膠布及第二膠 布皆為布面朝内，壓合成一複合材料；最後將複合材料進行連續加硫 處理即形成本發明之耐燃性複合材料。 底下藉由具體實施例詳加說明，當更容易瞭解本發明之目的、技 術内容、特點及其所達成之功效。 【實施方式】 本發明提供一種應用於連結伸縮縫之耐燃性複合材料之製造方 法，其主要製造一種手感柔軟容易加工、強度更好、耐燃性更佳更耐 久之多層橡膠皮料，可廣泛應用在火車、電聯車、捷運、大型兩段連 201132495 結式巴士、高速磁浮式列車等車廂間之連結伸縮縫(Gangways and bellows) 〇 第一圖所示為本發明之方塊圖，第二圖為本發明之流程圖，請同 時參考第一圖及第二圖。 在步驟S10中’將橡膠混合物之配方以一萬馬力機1〇混煉成一 膠料，此橡膠混合物之配方包括100重量份之杜邦海波龍（Hupaion)、 25〜65重量份之填充劑、60〜110重量份之難燃劑及5〜20重量份之 之可塑劑，其中，難燃劑可包括20〜40重量份之氫氧化鋁、20〜40 重量份之梦質難燃劑（如梦酸納）及20〜30重量份之有機耐燃劑（如 鲁 對二苯酸鉀）’而填充劑可包括20〜40重量份之輕質碳酸妈及5〜15 重量份之白燕華CC粉。步驟S10之投料順序為杜邦海波龍、填充劑、 可塑劑、難燃劑；在溫度14〇〜15〇〇C之間混煉五分鐘後冷卻至室溫存 放。 做為主膠之杜邦海波龍’其成分可區分為以天然橡膠（Nr)、苯 乙稀丁二基橡膠（SBR)、氯磺化橡膠（CSM)、氣丁基橡膠（CR)、 丁基橡膠（IIR)或耐油膠（NBR)等以不同成分配合之膠種。 接著步驟S12中，再將上述混煉後之膠料中加入一功能性細粉以 萬馬力機10進行第二次混煉，此功能性細粉包括彳〜3重量份之老防 劑（如丁羥曱苯，Butylated Hydroxytoluene，BHT)、2〜5 重量份之硬 脂酸、7重量份之橡膠軟化劑（如鄰笨二甲酸二（乙基己基)醋，（Dj (2-ethylhexyl)phthalate，DEHP)、2〜6重量份之架橋劑（如硫績）以 及〇·5〜0.8重量份之加硫助劑（如二甲基二硫代胺基曱酸锌，pz)，第 二次混煉係於溫度100〜120Ό之間進行兩分半鐘，完成後冷卻至室溫 存放’並靜置至少十二小時。 步驟S14中，將經過二次混煉之膠料塗佈於一基布上，並以一連 續式橡膠壓延機12壓延成一膠布，再將膠料單獨壓延成一 〇1〜5公 f (mm)之膠料薄片，依據成品厚度需求調整橡膠薄片之厚度。基布 可為聚酯布、尼龍布、棉布、聚酯尼龍混紡紗布及其他不同組成纖維 201132495 之混紡梭織布、平織布、橫紋、格子布、斜紋布、緹花布、N/Τ交織 布、色紗交織布、塔夫塔、牛津布或緞紋布等。膠布並收捲後備使用， 收捲方式採取布面向外及膠面向外兩種，且兩種方法捲取的數量相 同。此外，由於橡膠薄片具有黏性極易沾黏，因此將橡膠薄片貼附於 一經過撥水處理之布料上，此布料可視需求選擇聚酯纖維布、棉布、 聚酯尼龍混紡紗布及其他不同組成纖維之混紡紗梭織布，或是平織 布、橫紋、格子布、斜紋布、緹花布、Ν/τ交織布、色紗交織布、塔 夫塔、牛津布、緞紋布等各種布種。 接著步驟S16，取出步驟S14中所準備之膠布兩捲及橡膠薄片一 捲’將其分別定為Α捲、Β捲及C捲，按照Α捲、C捲、Β捲之順序 置於-連續^熱壓貼合機14之捲人架上1注意的是，當膠布a捲 拉開時，橡膠面必_上’ _物面朝下，而日捲賴咖為纺織物 面朝上’橡膠面朝下。當進行捲入貼合時，使A捲、c捲、B捲由上 而下重叠並同時進行減貼合，其侧方式自上而下即為獅基布_ 橡膠薄片-基布-膠料。連續式熱壓貼合機14奴溫度為6〇〜齡 壓貼合壓力蚊為每平方公分2請公斤，熱壓貼合後便形成五層結 構之複合材料。·五層結構之複合材料·於 互相沾黏，㈣祕。 料上避免橡膠 取俊 仍㈣㈣將五盾結構之複合材料置入-鼓式連續加硫木 16中’於溫度140〜1WC、產速為每分鐘2〜8賴力每平方公/ 40:90公斤下進行加硫處理’同時將避免沾黏之布料剝除，當加硫: 成後即為本發明之耐燃性複合材料之成品。 瓜71 ，三_耐雛複合㈣之成品示意圖賴巾所示，包 薄片20及分別設於橡膠薄片2〇兩側之膝布级 ^ 出4 = 22a及22b之方向相反，膠布细之膠料從二I中^ 224面朝下，而膠布22b則是基布欲面朝上 基布 綜上所述，本發騎提叙應胁賴伸_^^^下。 之製造方法係產生一種以橡膠薄片與膠料、織物層疊之五層 201132495 料’其係為連續式生產且可收捲備用，由於連續式生產無接頭，故每 捲長度可高於250碼，與模壓式片狀不連續製程大不相同，且依據本 發明所製造之複合材料更可提升耐燃性及物性，使用壽命長，適 大眾運輸工具對於安全之訴求。 、 唯以上所述者，僅為本發明之較佳實施例而已，並非用來限定本 發明實施之範圍。故即凡依本發明巾請細所狀特徵及精神所為之 均等變化或修飾，均應包括於本發明之申請專利範圍内。 … 【圖式簡單說明】 第-圖為本發明細於連結伸觸之魏性複合材料之製造方法之方 塊圖。 第二圖為本發鶴驗連師鴨之_性複合材料之製造方法之流 程圖。 第三圖為本發明顧於連結伸縮縫之耐雛複合材料之示意圖。 【主要元件符號說明】 10萬馬力機 12連續式橡膠壓延機 14連續式熱壓貼合機 16鼓式連續加硫機 20橡膠薄片 22a、22b 膠布 222基布 224膠料201132495 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to the manufacturing inspection of Yushui Lin, which refers to a manufacturing method for connecting a expansion joint or a flame-resistant composite material between a large bus or a train. . [Prior Art] Modern road vehicles have developed rapidly. Many developed or developed countries in the world have applied a large number of mass transit transportation jade tools, and various large-scale transportation traffic aids have more than four (4) knots to increase the passenger capacity; Such as trains, electric cars, MRT, large-scale two-stage connection Lu Qiaoshi (Taiwan does not currently have such a bus 'but Europe and the mainland are quite common), high-speed maglev trains, etc., the earliest only use hooks to connect the cars Nowadays, in order to make it easier for passengers to move between the carriage and the carriage, the compartment between the carriage and the carriage is designed to be a passageway. Therefore, it is necessary to use a joint of expansion joints made of rubber leather (Gangways and bellows) to avoid the car made of metal. In addition, due to the rapid development of today's society, the requirements for mass transit traffic aids are more than the convenience, speed, and efficiency of the original appeal, and the safety requirements are not neglected. There are public transport related safety regulations in the consumer side. The composite material of the general application of the rubber shaft fabric is insufficient in physical strength and flame resistance. The finished product requires three times of processing, including the first composite material of the fabric first and then the second composite material. The composite material attachment combination requires a high labor cost in the laminating process, and therefore requires a long working time, and the work efficiency is low, and the rubber after the vulcanization is large, and then it is prone to cause a bad situation. Therefore, the present invention proposes a U-method that is resistant to the composite material of the joint expansion joint, and produces a rubber material which is soft to the touch, easy to process, stronger in strength, better in flame resistance, and more durable in a five-layer structure. The specific architecture and its implementation in order to effectively overcome the above problems will be described in detail below. SUMMARY OF THE INVENTION The main object of the present invention is to provide a fine-grained composite material 201132495 which is finer than the joint extension. ΓΓΓ 'Silk material and 妓 可 can produce better μ degree, better _, better processing and more A durable five-layer composite. 2 Mingzhi--The purpose is to provide a kind of _-sex composite material which is suitable for the joint expansion joint. The method is as follows: the method is used to produce the rubber (4) which is made by the technology of the roofing technology. (4) The base fabric of the fiber, and the five-layer structure of the rubber material_base cloth-rubber material_base cloth_rubber material is formed by the delaying, hot pressing and vulcanization steps, so that the material has stronger physical properties. Further, the object of the present invention is to provide a method for manufacturing a coffee composite material which is finer than the joint extension. The edging property of the rubber composite material can effectively reduce the processing difficulty and increase the efficiency of adding: L. Turn to low cost, improve the advantage of the word and reduce the rate of non-performing. The invention further aims to provide a method for manufacturing a composite material which is required to be joined to the side seams, which is produced by the company, and has a continuous production without joints compared with the continuous pressure process. Increase the length of each roll. To achieve the above object, the present invention provides a method for producing a polyvinyl chloride antistatic rubber, comprising the steps of: kneading a rubber mixture into a rubber compound by a 10,000 horsepower machine, and mixing the material for a second time after the cold portion. Refining, and then cooling and then standing; the light rubber is coated on the base fabric, and it is desired to form a tape, and the tape is taken out with the rubber surface facing outward and the cloth surface facing outwards. The second adhesive tape and the rubber material are extended to the rubber sheet; the first adhesive tape and the second adhesive tape are respectively attached to the rubber sheet, and the first adhesive tape and the second adhesive tape are both facing inward and pressed into a composite material. Finally, the composite material is subjected to continuous sulfurization treatment to form the flame resistant composite material of the present invention. The purpose, technical contents, features and effects achieved by the present invention will become more apparent from the detailed description of the embodiments. [Embodiment] The present invention provides a method for producing a flame-resistant composite material for use in joining expansion joints, which mainly produces a multilayer rubber material which is soft and easy to process, has better strength, better flame resistance and durability, and can be widely applied. In the train, the electric car, the MRT, the large two-stage 201132495, the junction bus and the high-speed maglev train, the interlocking joints (Gangways and bellows) 〇 the first figure shows the block diagram of the invention, the second The figure is a flow chart of the invention, please refer to the first figure and the second figure at the same time. In step S10, the formulation of the rubber mixture is kneaded into a rubber compound by a 10,000-horsepower machine, and the rubber mixture is formulated to include 100 parts by weight of a DuPont Hypaion, 25 to 65 parts by weight of a filler, 60 to 110 parts by weight of a flame retardant and 5 to 20 parts by weight of a plasticizer, wherein the flame retardant may comprise 20 to 40 parts by weight of aluminum hydroxide and 20 to 40 parts by weight of a dream flame retardant (eg The organic flammable agent (such as potassium bis-p-benzoate) and the filler may include 20 to 40 parts by weight of the light carbonic acid mother and 5 to 15 parts by weight of the white Yanhua CC powder. The order of feeding in step S10 is DuPont Hyperbolon, a filler, a plasticizer, and a flame retardant; the mixture is kneaded at a temperature of 14 〇 15 15 ° C for five minutes, and then cooled to room temperature for storage. DuPont Haibolong, which is the main glue, can be divided into natural rubber (Nr), styrene-butadiene rubber (SBR), chlorosulfonated rubber (CSM), gas butyl rubber (CR), and A rubber compound such as a base rubber (IIR) or an oil-resistant rubber (NBR) which is compounded with different components. Next, in step S12, a functional fine powder is added to the kneaded rubber compound to perform a second kneading with a 10,000 horsepower machine 10, and the functional fine powder comprises 彳3 parts by weight of an anti-aging agent (such as Butylated Hydroxytoluene (BHT), 2 to 5 parts by weight of stearic acid, 7 parts by weight of a rubber softener (eg, diethyl (ethylhexyl) phthalate) , DEHP), 2~6 parts by weight of bridging agent (such as sulfur) and 〇·5~0.8 parts by weight of sulfur addition aid (such as zinc dimethyldithiocarbamate, pz), second time The kneading system is carried out for two and a half minutes at a temperature of 100 to 120 Torr, and then cooled to room temperature after completion, and is allowed to stand for at least twelve hours. In step S14, the rubber compound subjected to secondary kneading is applied to a base fabric. And calendered into a tape by a continuous rubber calender 12, and then the rubber is separately calendered into a sheet of 1 to 5 mm (mm) of rubber, and the thickness of the rubber sheet is adjusted according to the thickness requirement of the finished product. It is a blend of polyester cloth, nylon cloth, cotton cloth, polyester nylon blended gauze and other different constituent fibers 201132495. Woven fabric, plain weave, horizontal weave, plaid fabric, twill fabric, crepe fabric, N/Τ interwoven fabric, yarn interlacing fabric, taffeta, oxford cloth or satin fabric, etc. The tape is ready for use after winding. The winding method adopts two types of cloth facing outward and rubber facing outward, and the two methods are wound in the same amount. In addition, since the rubber sheet is sticky and easy to stick, the rubber sheet is attached to a water-repellent treatment. On the fabric, this fabric can be selected from polyester fiber cloth, cotton cloth, polyester-nylon blended gauze and other blended yarn woven fabrics of different composition fibers, or plain weave, horizontal stripes, plaid fabric, twill fabric, crepe fabric, Ν/τ interlaced cloth, colored yarn interwoven cloth, taffeta, oxford cloth, satin cloth, etc. Next, in step S16, the two rolls of the tape prepared in step S14 and the roll of rubber sheet are taken out, respectively. For the roll, the roll and the C roll, in the order of the roll, the C roll, and the roll, the roll is placed on the roll holder of the continuous heat press laminating machine. 1 Note that when the roll of the tape is pulled apart, The rubber surface must be _ upper ' _ object face down, while the Japanese roll Lai is the textile face up 'oil The rubber surface is facing downward. When the entanglement is applied, the A, C, and B rolls are overlapped from top to bottom and simultaneously reduced. The side mode is lion base cloth from the top to the bottom _ rubber sheet - Base cloth-rubber. Continuous hot press laminating machine 14 slave temperature is 6 〇 ~ age pressure fit pressure mosquito is 2 kg per square centimeter, hot pressing fit to form a five-layer composite material. Composite material of layer structure · Stick to each other, (4) Secret. Avoid rubber picking on material (4) (4) Put the composite material of five shield structure into - drum continuous sulfurized wood 16 in temperature 140~1WC, the production speed is 2 to 8 liters per minute / 40:90 kg per sulphur treatment' at the same time will avoid the peeling of the sticky cloth, when the sulphur is added: it is the finished product of the flame-retardant composite of the invention. The melon 71, the three_ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ From the second side of the II 224 face down, and the tape 22b is the base cloth to face up on the base cloth, as described above, the hair ride mentions the threat to stretch _ ^ ^ ^ down. The manufacturing method is to produce a five-layer 201132495 material which is laminated with rubber sheets and rubber and fabrics. It is continuously produced and can be wound up. Since the continuous production has no joints, the length of each roll can be more than 250 yards. Compared with the molded sheet-like discontinuous process, the composite material manufactured according to the present invention can improve the flame resistance and physical properties, has a long service life, and is suitable for the safety of mass transit vehicles. The above is only the preferred embodiment of the present invention and is not intended to limit the scope of the present invention. Therefore, any changes or modifications to the characteristics and spirit of the present invention should be included in the scope of the present invention. [Simplified description of the drawings] The first figure is a block diagram of the manufacturing method of the superior composite material which is finer than the joint contact. The second picture is a flow chart of the manufacturing method of the _ sexual composite material of the crane. The third figure is a schematic view of the composite resistant material of the invention considering the joint expansion joint. [Main component symbol description] 100,000 horsepower machine 12 continuous rubber calender 14 continuous hot press laminating machine 16 drum continuous vulcanizing machine 20 rubber sheet 22a, 22b tape 222 base cloth 224 compound