200825243 九、發明說明： 【發明所屬之技術領域】 本發明係關於-種低發煙_橡膠布，其係特棚於—種 機難燃劑製成低發煙耐燃橡膠布之方法。 … 【先前技術】200825243 IX. Description of the Invention: [Technical Field] The present invention relates to a low-smoke-rubber cloth which is a method for making a low-smoke flame-resistant rubber cloth. ... [prior art]
常見之防火布料係將基布與難_丨加卫，1讀成之防火布料。難 燃劑主要分為反應型及添加型兩種，而以添加型的用量最多，其又可 分為有機難輔和無機難關兩類。—般高分子賴燒原理，從巨觀 而言，是經受熱、分解、燃燒、傳播.··...等步驟週而復始的連鎖反應. 從微硯現象而言’主要是受氫自由基（H ·)及氮氧自由基（〇η 所引發的-連串連鎖反應，此要使高分子_程度提升，則 材料文熱或阻絕氧氣或防止其傳播，亦即隔絕烬燒三 面也可從捕域自由基及氫氧自域，破壞其_反_手， 多具阻燃效·耐難品所使狀方紐機構，便是基於上述的原埋。 .1白素a)系難燃劑為例’其主要在於捕捉可燃性的自由 基’系脑:酬是形成料g㈣保護層以_氧氣，並促進高 分子炭化’減少可雜氣體產生，為固相的保護作用；如㈣素（阶同 CI)系難燃劑作成之防火布料，由於㈣（Br、c丨）系難燃劑 麵劑因其驗生大量煙霧或毒性氣體等對人體有害之物料缺失。 為此，本發明提供一種低發煙耐燃橡膠布之加工方法，、其係 無機難燃槪為低發煙耐輯膠布，藉以改善上述缺失。’、 【發明内容】 ^ 月之主要目的在提供一種低發煙耐燃橡膠布之加工方法，其 係可製造-種有高耐磨、良好日光堅牢度及耐曲折性、具備低發煙量、、 防火耐燃聽之雜之低魏_轉布。 /本卷月之另一目的在提供一種低發煙耐燃橡膠布之加工方法，其 係可使本發日續造之低發煙_橡膠在發生火災時，具有較高的安ς 5 200825243 性。Common fire-retardant fabrics are made of base fabric and hard 丨 丨, 1 read into fire-resistant fabric. The flame retardant is mainly divided into two types: reactive type and additive type, and the most used type is added, which can be divided into organic difficult and inorganic difficult. The principle of polymer-based calcination is a chain reaction that undergoes cycles of heat, decomposition, combustion, and propagation, etc. from the perspective of microscopic phenomena. From the microscopic phenomenon, it is mainly caused by hydrogen radicals ( H ·) and nitroxyl radicals (the series of chain reactions initiated by 〇η, which is to increase the degree of polymer _, the material heat or block oxygen or prevent its propagation, that is, it can also be isolated from the three sides of the simmering The capture of free radicals and hydrogen and oxygen from the domain, destroying its _ anti-hands, many flame retardant and difficult materials are based on the above-mentioned original buried. .1 white a) is flame retardant For example, the agent 'mainly lies in the capture of flammable free radicals' is the brain: the formation of the material g (four) protective layer with _ oxygen, and promotes the carbonization of the polymer 'reducing the generation of miscellaneous gases, for the protection of the solid phase; such as (four) (The same order as CI) is a fireproof fabric made of a flame retardant. Because (4) (Br, c丨) is a flame retardant agent, it is missing due to its large amount of smoke or toxic gas. To this end, the present invention provides a method for processing a low-smoke flame-resistant rubber cloth, which is an inorganic flame-retardant crepe which is a low-smoke resistant tape, thereby improving the above-mentioned deficiency. ', 【Contents of the Invention】 ^ The main purpose of the month is to provide a processing method for low-smoke and flame-resistant rubber cloth, which can be manufactured with high wear resistance, good daylight fastness and tortuosity, low smoke generation, , fire and flame resistance to listen to the low Wei _ transfer cloth. / Another purpose of this month is to provide a method for processing low-smoke and flame-resistant rubber cloth, which can make the low-smoke _ rubber produced in this day have a high ampereness in the event of fire 5 200825243 .
本發明係提供一種低發煙耐燃橡膠布之加工方法，其係可將基布 經過含浸處理後，再於該基布上塗佈橡膠糊料，再將基布烘乾。完成 後進行膠料打料製造第一混合膠料，第一混合膠料係將橡膠、填充劑 以及添加劑專膠料進行打料、捏合；再將第一混合膠料與促進劑充份 混合成一 Hypalon氯磺化橡膠之第二混合膠料；再以過光貼合機兩面 貼合Hypalon氯績化橡膠於基布上形成Hypa|〇n氯磧化橡膠膠面，最 後將基布經Rotocure硫化機或罐式加硫機加硫熟成為一低發煙耐燃 橡膠布。此種低發煙耐燃橡膠布具有高耐磨、良好日光堅牢度及耐曲 折性外’ S具備低發煙量、防火耐雜佳之特性，可使低發煙耐燃橡 膠布在發生火災時，具有較高的安全性。 底下藉由具體實酬配合騎的圖式詳加說明，#更容易瞭解本 發明之目的、技術内容、特點及其所達成之功效。 【實施方式】、 or BuS ^ I丨 圍包括電車與公权車賴連接舰縫⑽n 係；^明! rs ί料’為能詳細說明本發明，請參照第—圖；第一圖 卢、¥二 侧。首歧行步驟S12，先將—基布經過-含产 SI撕t基社塗佈—橡_料’並將基布烘乾。由於橡^身又 本此需在橡膠間加人增強拉力與撕裂的基布；在 的混纺梭織布其中之—作為基布橡: 接著，並經烘_5〇^1^掏裝置塗佈一層橡膠糊料以提升 再進行步驟S14，進 fL秒，使糊料中之有機溶劑揮發。 劑等膠料進行打料、捏合，以序;^橡^、填充劑以及添加 配方如下： $混合膠料’第—混合膠料的膠料 ⑴要避用具低發煙效果之橡膠產品，就需絲用具難燃效果之橡 6 200825243 =’若再考量職本與㈣’因此轉翻具 -Hypalon ; (2) 填充劑則選用氫氧化銘及硼酸鋅做一調配，調配的比例係氮氧 崎^ : 1，由許冰驗可魏此_T綠佳之阻燃比及 ί 特Ϊ、；氫氧她充#難_時軸需添加量«，但因價格便 ’ j Χ倾用在最終產品物性並不受高含量氫氧化銘影響的橡膠材 也常與其它難關，如三氧化二銻、硼酸鋅和氯化碳氫化合物 =使用’以發揮相乘絲，同時氫氧化㈣為—良好的發煙抑制劑 吃韻。且因其不會產生大量煙霧鱗性氣體，使用在材料表面時 ^可賴材料内部不受破壞；氫氡化較鱗會魏熱量及放出水 亂、稀釋氧氣，形成固相保護層來阻隔熱源。 (3) 再來添加橡膠配方所需的添加劑(如，老防劑、加工助劑、軟化 油…···等)則依客戶所要求予以添加。 f料打料時，先將上述膠料内容物以萬馬力捏合機充分攪拌混 。1度控制在85〜1CKTC，以成第-混合膠料。接著進行步驟⑽， 將第-混合膠料與促進劑充份混合—第二混合膠料，本實施例採用之 促，劑係加琉促進劑，其中將第一混合膠料加入促進劑後，係以一滾 售輪裝置幫助第—混合膠料與促進劑混合充分混合成為第二混合膠料混 •合時之溫度係。C70〜85°C，其中此第二混合膠料係The invention provides a method for processing a low-smoke flame-resistant rubber cloth, which is characterized in that after the base cloth is subjected to impregnation treatment, a rubber paste is coated on the base cloth, and then the base cloth is dried. After the completion, the first mixed rubber is manufactured by rubber compounding, and the first mixed rubber is used for materializing and kneading the rubber, the filler and the additive special rubber; and then mixing the first mixed rubber and the accelerator into one. The second mixed rubber of Hypalon chlorosulfonated rubber; the Hypalon Chlorinated rubber is laminated on both sides of the optical bonding machine to form Hypa|〇n chlorinated rubber rubber surface, and finally the base fabric is vulcanized by Rotocure. The machine or tank type vulcanizer is sulphurized and cooked into a low-smoke flame-resistant rubber cloth. The low-smoke flame-resistant rubber cloth has high wear resistance, good daylight fastness and resistance to tortuosity. The outer s has low smoke generation, fire resistance and good compatibility, and can make the low-smoke flame-resistant rubber cloth have a fire. Higher security. The details of the present invention, the technical content, the features and the effects achieved by the present invention are explained in more detail by means of a detailed description of the specific ride. [Embodiment], or BuS ^ I 包括 包括 电 电 电 电 电 电 电 电 电 电 电 电 电 电 ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; ; Two sides. In the first step S12, the base fabric is first coated with a rubber-coated material, and the base fabric is dried. Because of the rubber body, it is necessary to add a tensile and tearing base fabric between the rubber; in the blended woven fabric, as the base fabric rubber: and then, by baking _5〇^1^掏 device A layer of rubber paste is applied to the step S14 for further lifting, and the organic solvent in the paste is volatilized. The compound and other rubber materials are mixed and kneaded in order; the rubber, the filler and the added formula are as follows: $mixed rubber compound--mixed rubber compound (1) to avoid the rubber product with low smoke effect, Rubber 6 that requires a flame retardant effect 200825243 = 'If you consider the job and (4) 'There is a turn-over-Hypalon; (2) Filler is selected from the name of Hydroxide and Zinc Borate, the ratio of nitrogen and oxygen is adjusted. Saki ^ : 1, by Xu Bing can Wei this _T green good flame retardant ratio and Ϊ Ϊ,; hydrogen oxygen her charge # difficult _ when the axis needs to add amount «, but because of the price will be used in the final Rubber materials whose physical properties are not affected by high levels of hydrazine are often difficult to deal with, such as antimony trioxide, zinc borate and chlorinated hydrocarbons = use 'to multiply the filaments while oxidizing (iv) is good The smoking inhibitors eat rhyme. And because it does not produce a large amount of smoke scale gas, when used on the surface of the material, it can not be destroyed inside the material; hydroquinone will be more heat than the scale and release water, dilute oxygen, form a solid phase protective layer to block the heat insulation source. . (3) Add the additives required for the rubber formulation (for example, old anti-aging agents, processing aids, softening oils, etc.), and add them as required by the customer. When f material is being used, the content of the above rubber material is first thoroughly stirred and mixed by a 10,000-mass kneader. 1 degree is controlled at 85~1 CKTC to form a first-mixed compound. Then, the step (10) is carried out, and the first mixed compound is mixed with the accelerator in a sufficient manner - the second mixed rubber is used in the embodiment, and the agent is added to the accelerator, wherein the first mixed rubber is added to the accelerator, A rolling wheel device is used to help the first mixed compound and the accelerator mix and mix thoroughly to form a temperature system when the second mixed rubber is mixed. C70~85 °C, wherein the second mixed rubber system
Hypalon氯石黃化橡 膠。 八 、曰，續進行步驟S18，讓該橡膠糊料與第二混合膠料貼合，使第二 二a膠料壓於基布上；第二混合膠料貼合方式係以—係以輸送帶將第 二混合膠料送至_過光貼合機，鱗過光貼合機之羅拉溫度係。⑺〜 90C並利用過光貼合機將第二混合膠料壓延至設定厚度，讓基布上具 有Hypalon氯石黃化橡膠膠面，郷第二混合膠料做成之讓基布上具有 Hypalon氯磺化橡膠膠面與基布貼合並捲曲。 最後進行步驟S2G，雜布進行硫化處理，進行硫化處理係藉由 7 200825243 一 ROTOCURE加硫機或罐式加硫機予以硫化熟成，ROTOCURE加 硫機或罐式加硫機的溫度係控制在。對基布進行硫化處 理後而成為一低發煙耐燃橡膠布。. 以本發明製成之低發煙耐燃橡膠布除了具有高耐磨、良好日光堅 牢度及耐曲折性外，更具備低發煙量、防火耐燃性佳之特性，可使以 本發明製成之低發煙耐燃橡膠布在發生火災時，具有較高的安全性。 唯以上所述者，僅為本發明之較佳實施例而已，Hypalon chlorite yellow rubber. 8. After step S18, the rubber paste is adhered to the second mixed rubber to press the second two rubber compound on the base fabric; the second mixed rubber compounding method is to transport the rubber compound to the base fabric. The belt is sent to the _ light-gluing machine, the roller temperature system of the scale-lighting laminating machine. (7) ~ 90C and use the optical laminating machine to calender the second mixed rubber to the set thickness, so that the base cloth has Hypalon chlorite yellow rubber rubber surface, and the second mixed rubber material is made to make the base cloth have Hypalon The chlorosulfonated rubber rubber surface is bonded to the base fabric and crimped. Finally, step S2G is performed, and the swarf is subjected to vulcanization treatment, and the vulcanization treatment is carried out by vulcanization and aging by a ROTOCURE vulcanizer or a tank vulcanizer, and the temperature of the ROTOCURE vulcanizer or the tank vulcanizer is controlled. The base fabric is vulcanized to form a low-smoke flame-resistant rubber cloth. The low-smoke flame-resistant rubber cloth made by the invention has the characteristics of low smoke resistance, good light fastness and good flame resistance, and has the characteristics of low smoke generation, good fire resistance and flame resistance, and can be made by the invention. The low-smoke flame-resistant rubber cloth has high safety in the event of a fire. Only the above is only the preferred embodiment of the present invention.
發明實施之範圍。故即凡依本發明申請範圍所述之开々 及精神所為之均等變化或修飾，均應包括於本發=大、構造、特徵 【圖式簡單說明】 X申請專利範圍内。 第一圖係本發明之加工流程圖。 【主要元件符號說明】The scope of the invention. Therefore, any change or modification of the opening and the spirit described in the scope of the application of the present invention should be included in the scope of the present invention. The first figure is a process flow diagram of the present invention. [Main component symbol description]