TW201127484A - Method for preventing plugging of a continuous-reaction channel-system and micro-reactor for carrying out the method - Google Patents
Method for preventing plugging of a continuous-reaction channel-system and micro-reactor for carrying out the method Download PDFInfo
- Publication number
- TW201127484A TW201127484A TW099128895A TW99128895A TW201127484A TW 201127484 A TW201127484 A TW 201127484A TW 099128895 A TW099128895 A TW 099128895A TW 99128895 A TW99128895 A TW 99128895A TW 201127484 A TW201127484 A TW 201127484A
- Authority
- TW
- Taiwan
- Prior art keywords
- channel system
- microreactor
- ultrasonic wave
- ultrasonic
- continuous reaction
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims abstract description 52
- 238000006243 chemical reaction Methods 0.000 title claims abstract description 30
- 239000012530 fluid Substances 0.000 claims abstract description 36
- 230000008878 coupling Effects 0.000 claims abstract description 8
- 238000010168 coupling process Methods 0.000 claims abstract description 8
- 238000005859 coupling reaction Methods 0.000 claims abstract description 8
- 239000006227 byproduct Substances 0.000 claims abstract description 5
- 239000000376 reactant Substances 0.000 claims description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000047 product Substances 0.000 claims description 9
- 239000000126 substance Substances 0.000 claims description 8
- 229910052751 metal Inorganic materials 0.000 claims description 7
- 239000002184 metal Substances 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 5
- 150000001875 compounds Chemical class 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 4
- 239000012465 retentate Substances 0.000 claims description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 229910052783 alkali metal Inorganic materials 0.000 claims 1
- 150000001340 alkali metals Chemical class 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 9
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000001465 metallisation Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 125000003261 o-tolyl group Chemical group [H]C1=C([H])C(*)=C(C([H])=C1[H])C([H])([H])[H] 0.000 description 2
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 2
- CPRMKOQKXYSDML-UHFFFAOYSA-M rubidium hydroxide Chemical compound [OH-].[Rb+] CPRMKOQKXYSDML-UHFFFAOYSA-M 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- DIIIISSCIXVANO-UHFFFAOYSA-N 1,2-Dimethylhydrazine Chemical compound CNNC DIIIISSCIXVANO-UHFFFAOYSA-N 0.000 description 1
- 125000001140 1,4-phenylene group Chemical group [H]C1=C([H])C([*:2])=C([H])C([H])=C1[*:1] 0.000 description 1
- XTEGARKTQYYJKE-UHFFFAOYSA-M Chlorate Chemical class [O-]Cl(=O)=O XTEGARKTQYYJKE-UHFFFAOYSA-M 0.000 description 1
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 150000001540 azides Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- PPCXFTKZPBHXIW-UHFFFAOYSA-N ethyl ethanesulfonate Chemical compound CCOS(=O)(=O)CC PPCXFTKZPBHXIW-UHFFFAOYSA-N 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000000684 flow cytometry Methods 0.000 description 1
- 125000003983 fluorenyl group Chemical group C1(=CC=CC=2C3=CC=CC=C3CC12)* 0.000 description 1
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052744 lithium Inorganic materials 0.000 description 1
- DLEDOFVPSDKWEF-UHFFFAOYSA-N lithium butane Chemical compound [Li+].CCC[CH2-] DLEDOFVPSDKWEF-UHFFFAOYSA-N 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000013307 optical fiber Substances 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 230000010349 pulsation Effects 0.000 description 1
- 239000000523 sample Substances 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- -1 sec-hexyl Chemical group 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- KSMWLICLECSXMI-UHFFFAOYSA-N sodium;benzene Chemical compound [Na+].C1=CC=[C-]C=C1 KSMWLICLECSXMI-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 125000004213 tert-butoxy group Chemical group [H]C([H])([H])C(O*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J19/0093—Microreactors, e.g. miniaturised or microfabricated reactors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F25/00—Flow mixers; Mixers for falling materials, e.g. solid particles
- B01F25/40—Static mixers
- B01F25/42—Static mixers in which the mixing is affected by moving the components jointly in changing directions, e.g. in tubes provided with baffles or obstructions
- B01F25/43—Mixing tubes, e.g. wherein the material is moved in a radial or partly reversed direction
- B01F25/433—Mixing tubes wherein the shape of the tube influences the mixing, e.g. mixing tubes with varying cross-section or provided with inwardly extending profiles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F33/00—Other mixers; Mixing plants; Combinations of mixers
- B01F33/30—Micromixers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
- B01F35/00—Accessories for mixers; Auxiliary operations or auxiliary devices; Parts or details of general application
- B01F35/10—Maintenance of mixers
- B01F35/145—Washing or cleaning mixers not provided for in other groups in this subclass; Inhibiting build-up of material on machine parts using other means
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B17/00—Methods preventing fouling
- B08B17/02—Preventing deposition of fouling or of dust
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B9/00—Cleaning hollow articles by methods or apparatus specially adapted thereto
- B08B9/02—Cleaning pipes or tubes or systems of pipes or tubes
- B08B9/027—Cleaning the internal surfaces; Removal of blockages
- B08B9/032—Cleaning the internal surfaces; Removal of blockages by the mechanical action of a moving fluid, e.g. by flushing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00783—Laminate assemblies, i.e. the reactor comprising a stack of plates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00889—Mixing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00891—Feeding or evacuation
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00891—Feeding or evacuation
- B01J2219/00894—More than two inlets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/00925—Irradiation
- B01J2219/00932—Sonic or ultrasonic vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00781—Aspects relating to microreactors
- B01J2219/0099—Cleaning
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B08—CLEANING
- B08B—CLEANING IN GENERAL; PREVENTION OF FOULING IN GENERAL
- B08B2209/00—Details of machines or methods for cleaning hollow articles
- B08B2209/005—Use of ultrasonics or cavitation, e.g. as primary or secondary action
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Dispersion Chemistry (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/EP2009/061143 WO2011023236A1 (en) | 2009-08-28 | 2009-08-28 | Method for preventing plugging of a continuous-reaction channel-system and micro-reactor for carrying out the method |
| EP09011726 | 2009-09-14 | ||
| EP10157285 | 2010-03-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW201127484A true TW201127484A (en) | 2011-08-16 |
Family
ID=42829408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW099128895A TW201127484A (en) | 2009-08-28 | 2010-08-27 | Method for preventing plugging of a continuous-reaction channel-system and micro-reactor for carrying out the method |
Country Status (13)
| Country | Link |
|---|---|
| US (1) | US10058840B2 (enExample) |
| EP (1) | EP2470296A1 (enExample) |
| JP (1) | JP5718335B2 (enExample) |
| CN (2) | CN107744786A (enExample) |
| BR (1) | BR112012004437A2 (enExample) |
| CA (1) | CA2757436C (enExample) |
| EA (1) | EA026338B1 (enExample) |
| IL (1) | IL215568A0 (enExample) |
| IN (1) | IN2012DN01781A (enExample) |
| MX (1) | MX2012001571A (enExample) |
| SG (1) | SG178233A1 (enExample) |
| TW (1) | TW201127484A (enExample) |
| WO (1) | WO2011023761A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104162395B (zh) * | 2014-03-21 | 2017-01-25 | 中国科学院大连化学物理研究所 | 一种强化微反应器内气液过程的方法 |
| EP3031518B1 (en) * | 2014-12-08 | 2021-01-20 | Lonza Ltd | Fluid mixing structure, continuous reaction unit, continuous reaction reactor and method of using the same |
| FR3050943B1 (fr) * | 2016-05-03 | 2019-12-20 | L'air Liquide, Societe Anonyme Pour L'etude Et L'exploitation Des Procedes Georges Claude | Procede de nettoyage d'un canal millimetrique d'un echangeur-reacteur |
| CN106824909B (zh) * | 2017-02-21 | 2022-11-08 | 华中农业大学 | 管道式超声波清洗机 |
| CN108568264A (zh) * | 2017-03-13 | 2018-09-25 | 许昌义 | 超声波s形管混合器 |
| US10527843B2 (en) * | 2017-05-12 | 2020-01-07 | International Business Machines Corporation | Ultra-sonic self-cleaning system |
| CN109020811A (zh) * | 2018-09-19 | 2018-12-18 | 张家港瀚康化工有限公司 | 利用微型反应器制备丙酸酯的方法 |
| FR3146815A1 (fr) | 2023-03-21 | 2024-09-27 | Khimod | microréacteur pour la mise en œuvre de procédés de chimie continue impliquant des solides |
Family Cites Families (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4734027Y1 (enExample) * | 1970-09-03 | 1972-10-14 | ||
| US5830127A (en) * | 1996-08-05 | 1998-11-03 | Cybersonics, Inc. | Method and apparatus for cleaning endoscopes and the like |
| DE10143189A1 (de) | 2001-09-04 | 2003-03-20 | Clariant Gmbh | Verfahren und Vorrichtung zur prozeßbegleitenden Reinigung von Mikro-und Minireaktoren |
| PL379008A1 (pl) | 2003-02-21 | 2006-06-26 | Novartis Ag | Chemiczny sposób wytwarzania związków pośrednich do otrzymywania związków N-formylohydroksyloaminowych |
| US20050129580A1 (en) | 2003-02-26 | 2005-06-16 | Swinehart Philip R. | Microfluidic chemical reactor for the manufacture of chemically-produced nanoparticles |
| JP2004337649A (ja) * | 2003-05-13 | 2004-12-02 | Hitachi Ltd | 有機塩素化合物処理装置 |
| US20050016851A1 (en) * | 2003-07-24 | 2005-01-27 | Jensen Klavs F. | Microchemical method and apparatus for synthesis and coating of colloidal nanoparticles |
| JP2005060281A (ja) * | 2003-07-29 | 2005-03-10 | Idemitsu Kosan Co Ltd | ビニル化合物又はビニリデン化合物の二量化方法 |
| US7439654B2 (en) | 2004-02-24 | 2008-10-21 | Air Products And Chemicals, Inc. | Transmission of ultrasonic energy into pressurized fluids |
| JP4734027B2 (ja) | 2005-05-17 | 2011-07-27 | 株式会社ブリヂストン | 空気入りタイヤ |
| DE102005025248B4 (de) | 2005-06-02 | 2009-07-30 | Forschungszentrum Karlsruhe Gmbh | Fluidführungssystem |
| US7942568B1 (en) * | 2005-06-17 | 2011-05-17 | Sandia Corporation | Active micromixer using surface acoustic wave streaming |
| GB0514349D0 (en) | 2005-07-13 | 2005-08-17 | Smiths Group Plc | Apparatus and components |
| WO2007038976A1 (en) | 2005-09-19 | 2007-04-12 | Agilent Technologies, Inc. | Microfluidic chip cleaning |
| JP4855471B2 (ja) * | 2005-09-26 | 2012-01-18 | エルジー・ケム・リミテッド | 積層反応装置 |
| JP2007252979A (ja) | 2006-03-20 | 2007-10-04 | National Institute Of Advanced Industrial & Technology | マイクロリアクタによる化合物の製造方法、そのマイクロリアクタ、及びマイクロリアクタ用の分流器 |
| TW200738328A (en) * | 2006-03-31 | 2007-10-16 | Lonza Ag | Micro-reactor system assembly |
| JP5061632B2 (ja) * | 2007-02-09 | 2012-10-31 | 和光純薬工業株式会社 | ｏ−二置換芳香族化合物の製造方法 |
| CN101652661B (zh) * | 2007-04-03 | 2013-02-13 | 佳能株式会社 | 使用微流体设备的送液装置和送液方法 |
| CA2704861C (en) | 2007-11-05 | 2017-09-05 | Velocys Inc. | Loading or unloading of particulates into or out of microchannel reactors |
| US8187554B2 (en) * | 2008-04-23 | 2012-05-29 | Microfluidics International Corporation | Apparatus and methods for nanoparticle generation and process intensification of transport and reaction systems |
-
2010
- 2010-08-26 EA EA201270233A patent/EA026338B1/ru not_active IP Right Cessation
- 2010-08-26 SG SG2012007480A patent/SG178233A1/en unknown
- 2010-08-26 CA CA2757436A patent/CA2757436C/en not_active Expired - Fee Related
- 2010-08-26 JP JP2012526059A patent/JP5718335B2/ja active Active
- 2010-08-26 IN IN1781DEN2012 patent/IN2012DN01781A/en unknown
- 2010-08-26 CN CN201711012708.9A patent/CN107744786A/zh active Pending
- 2010-08-26 US US14/387,758 patent/US10058840B2/en active Active
- 2010-08-26 BR BR112012004437A patent/BR112012004437A2/pt not_active Application Discontinuation
- 2010-08-26 MX MX2012001571A patent/MX2012001571A/es not_active Application Discontinuation
- 2010-08-26 EP EP10745268A patent/EP2470296A1/en not_active Ceased
- 2010-08-26 WO PCT/EP2010/062476 patent/WO2011023761A1/en not_active Ceased
- 2010-08-26 CN CN2010800216839A patent/CN102427876A/zh active Pending
- 2010-08-27 TW TW099128895A patent/TW201127484A/zh unknown
-
2011
- 2011-10-05 IL IL215568A patent/IL215568A0/en unknown
Also Published As
| Publication number | Publication date |
|---|---|
| CN107744786A (zh) | 2018-03-02 |
| WO2011023761A1 (en) | 2011-03-03 |
| CN102427876A (zh) | 2012-04-25 |
| IN2012DN01781A (enExample) | 2015-06-05 |
| US10058840B2 (en) | 2018-08-28 |
| MX2012001571A (es) | 2012-04-11 |
| JP5718335B2 (ja) | 2015-05-13 |
| IL215568A0 (en) | 2011-12-29 |
| US20150158007A1 (en) | 2015-06-11 |
| EA201270233A1 (ru) | 2012-09-28 |
| BR112012004437A2 (pt) | 2016-03-22 |
| CA2757436A1 (en) | 2011-03-03 |
| SG178233A1 (en) | 2012-03-29 |
| CA2757436C (en) | 2018-01-02 |
| EP2470296A1 (en) | 2012-07-04 |
| EA026338B1 (ru) | 2017-03-31 |
| JP2013503030A (ja) | 2013-01-31 |
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