201121608 六、發明說明： 【發明所屬之技術領域】 本發明係有關一種處理技術’特別是關於一種無機有害廢棄物的 處理方法及其處理裝置。 【先前技術】 電弧爐煉鋼業所產生的集塵灰因含有大量重金屬，粉塵微粒徑 小，溶出毒性高，任意拋棄容易影響空氣品質，且進入土壤及地下水 4，造成食物鏈的累積污染。故環保署明定煉鋼業電弧爐集塵灰為有 害事業廢棄物》 ~ ^ 國内煉鋼業除中鋼為高爐之外，其餘的大部分均為電弧爐煉鋼。 以環保署統計資料顯示，國内有二十餘家電弧爐煉鋼業，其中每年所 產生的集塵灰高達二十四萬噸。除自行清理及回爐之外，國内目前所 核可之處理業有限，且以固化掩埋以及回收其中所含的鋅為主，未能 妥善處理的錢躺讀内暫存為主H於整體魏技術尚未有 突破的發展。 在國外的專利技術中，美國專利證號5582573A1、4911757A1、 5542977A1、5582573A1、5683344A1對於重金屬的有害廢棄物，通 常以水泥、石灰固化的方式固化後直接進入掩埋場掩埋，並未做資源 再利用。所以更沒有資源再彻的_製程。台灣專利公告編號 00397868-不銹鋼集塵灰之固定化方法，以及公告編號2〇〇512299•一 種自電弧爐集塵灰中充份回收金屬氧化物以減少集塵灰產出量的方 法’並未有直接將集塵灰做資源再利用的方法。 在目前處理賴歧_外大致上扣下紐處理技術： -·回收金屬成分.回收的方法有直接回爐法、Te_cs電聚法及 熱碳還原法，這些方法都是回收集塵灰巾的辞金屬。 -·集塵灰直接糊.集塵灰直接作為玻璃喊的原料，用以產生 彩色陶瓷及彩色玻璃。 201121608 二.濕式法萃取：以酸液萃取回收集塵灰的金屬。但是此製程產生 大量的酸廢液，將造成環境的另一種污染及需要處理的成本。 所以目前國内的焚化爐飛灰均採用固化法或是穩定化加上固化 ，，然後運至垃圾掩埋場分區掩埋。並未走再利用的方式。集塵灰的 部份，只有場内回爐、或是回收辞金屬、固化處理及厫内暫存等方式。 因此本發明係在針對上述之困擾，提出一種無機有害廢棄物的 處理方，及其處理錢，使減有害廢棄物之重金屬穩定，達到低溶 解性，高密度，低自由水量，低滲透係數，高抗壓強度和強耐候性等 特性，並可以通過毒性溶出試驗(TCLP)，確保廢棄物之無毒化、無害 化、穩定化，並直接使用於土木、建材等骨材上，達到資源化的目^。 【發明内容】 本發明之主要目的，在於提供一種無機有害廢棄物的處理方法及 其處理裝置，使無機有害廢棄物之重金屬穩定，達到低溶解性，高密 度，低自由水量，低滲透係數，高抗壓強度和強耐候性等特性，並可 以通過毒性溶出試驗(TCLP)，確保廢棄物之無害化，直接使用於土木、 建材等骨材上，達到資源化的目的。 本發明之另一目的，在於提供一種無機有害廢棄物的處理方法及 其處理裝置，使整個處理過程可兼顧安全性、穩定性、時效性，且極 具經濟效益。 為達上述目的，本發明提供一種無機有害廢棄物的處理裝置，包 含第一容置槽，用來存有穩定化藥劑，穩定化藥劑係選自熱塑性物質、 熱固性物質或彈性物質，還有第二容置槽，用來存有含重金屬之無機 有害廢棄物’該二容置槽係連接一組反應設備，反應設備從二容置槽 中接收穩定化藥劑與無機有害廢棄物，將其進行連續式或半連續式製 程之均勻混合’並予以高溫加熱，使其反應為熔融狀液體之資源化產 物’最後再利用一模具組’將資源化產物模型化，使其成為一資源化 產品。 4 201121608 本發明祕供-種錢有害純_處理找 酿含重金狀無财害廢聽-起進行連續式解連續式^之^ 勻混合’並予以高溫加熱，使其反應聽融狀液體之資源化產物，其 中穩定化藥劑係選自熱塑性物質、熱固性物質或彈性物質，最後將資 源化產物模型化，使其成為一資源化產品。 兹為使貴審查委員對本發明之結構特徵及所達成之功效更有進 -步之瞭解與賴’謹似較佳之實施_及配合詳細之說明，說明 如後： 【實施方式】 第1圖，本發明包含第一、第二容置槽1〇、12，並分別存 有穩定化藥_及含重金屬之減有害廢棄物，敎化咖係選自熱 塑性物質、熱固性物質、彈性物質或以上三種物f之群組組合彈性 物質可為ϋ青或娜，錢有害廢棄物可岐單_廢棄物或多種混合 的廢棄物，混合廢棄物的混合比例在彳〇/〇〜99%，無機有害廢棄物如一 般垃圾焚化歧、-般城焚化総、事業廢棄物之焚化爐飛灰、事 業廢棄物之焚化爐底渣、煉鋼業電弧爐集塵灰（EAF dust)、不鑛鋼廢 料、金屬冶煉業的集塵灰及廢料、含汞廢料、含汞污泥、含重金屬之 污尼、含重金屬污染之土壤、含氣化合物、低放射性核廢料之樹脂、 焚化爐飛灰、底渣或經過破碎之低放射性核廢料。重金屬可為鉛、鎘、 砷、m、鋇、銅、銀、鈦、鎳、鋅、鈣、鎂、鈹、銻或釩， 穩疋化藥劑可為硫續'硫化物、填化物、聚乙稀、聚苯乙烯、環氧樹 脂或聚合物之單體。第―、第二容置槽彳0、12連接一組反應設備，且 此組反應設備包含至少一反應設備，在此例十，反應設備的數量以一 為例’即反應設備18。 第一秤量槽14連接第二容置槽12與反應設備18,可量測從第二 容置槽12流入反應設備18之無機有害廢棄物的流量，第二秤量槽16 連接第一容置槽10與反應設備18，可量測從第一容置槽1〇流入反應 201121608 設備18之穩定化藥劑的流量。反應設備18可為一使固體與固體、固 體與液體或固體與熔融物質攪拌均句之混合機械，如螺旋攪拌混合 器、旋轉混合器、錐形攪拌混合器、單螺桿攪拌混合器、雙螺桿攪拌 混合器，捏合機或乳化均勻機，反應設備18設置一加熱器，並附有熱 傳導物質，加熱器可為失套或盤管，而其加熱傳導物質可為電、蒸汽 或熱媒油；穩定化藥劑與無機有害廢棄物在反應設備18中一起進行均 勻混合，且其混合比例為5%〜95%，當進行混合時，利用加熱器可同 時予以高溫加熱，使其反應為熔融狀液體之資源化產物。 模具組20連接反應設備18,可對由反應設備18所輸出的資源化 產物依序進行成型、冷卻、脫模之程序模型化，並以連續造粒、成型 的方式產生資源化產品，該資源化產品之形式為粉狀之固體，產生之 後先由一儲槽22接收，再由一輸送帶24將資源化產品傳送出去。 以下說明本發明之處理方法，其為批式製程之均勻混合，本實施 例之有害無機廢棄物為垃圾焚化爐飛灰，反應設備18為雙螺桿混合機 或雙腕式捏合機，加熱方式是熱媒油夾層方式加熱，一開始將含有重 金屬之有害無機廢棄物垃圾焚化爐飛灰以及穩定化藥劑分別放置於兩 個容置槽10、12中，之後先將穩定化藥劑輸送到第一秤量槽14中， 再從秤量槽14中將定量的穩定化藥劑放入反應設備18中加熱到熔 融，再將定量的焚化爐飛灰打入第二秤量槽16中，再以一定的速度同 時加入反應設備18中並與穩定化藥劑混合反應，同時溫度用 5(TC〜300eC加熱’最適當的溫度為190。〇，使垃圾焚化爐飛灰以及穩 定化藥劑加熱成為熔融狀液體，穩定化物質與焚化爐飛灰混合比例為 10〜90% ’最佳比例為80:20。反應設備18的轉速為10〜200RPM， 最佳速度為60RPM。經過混合反應的資源化產物，應用反應設備18 本身的推力，一定的速度，直接輸送到模具組中成型或是連續造 粒，冷卻、脫膜，經過TCLP測試合格，即可得到資源化產品。資源 化產〇口產生之後先由一儲槽22接收，再由一輸送帶24將資源化產品 傳送出去，此連續式均勻混合使整個處理過程可兼顧安全性、穩定性、 201121608 時效性，且極具經濟效益β 以上皆可參閱第1圖，另外亦附上第2圖之平面圖以供對照用。 第3圖提供本發明之第二實施例的結構圖，此為另一批式製程之 均句混合’第3圖與第1圖的處理方式差異在於使用螺旋反應釜36, 將無機有害廢棄物與穩定化藥劑完全混合並形成資源化產物後，再批 次送至模具組38中，最後將資源化產物模型化，形成資源化產品。 以下請繼續同時參閱第三實施例之第4圖與第5圖。同樣地，第 二實施例包含第一、第二容置槽44、46，並分別存有含重金屬之無機 有害廢棄物以及穩定化藥劑，其成分皆與第一實施例相同。第一、第 φ 二容置槽44、46連接一組反應設備，其係包含一組第一、第二、第三 子反應設備，此組第一、第二、第三子反應設備分別皆包含至少一反 應設備’在此例中，第一子反應設備包含的反應設備之數量以一為例， 即第一反應設備54;第二子反應設備包含的反應設備之數量以一為 例’即第二反應設備56 ;第三子反應設備包含的反應設備之數量以一 為例，即第三反應設備58» 第一秤量槽48連接第二容置槽46與第一反應設備54，可量測從 第二容置槽46流入第一反應設備54之穩定化藥劑的流量；第二秤量 槽50連接第一容置槽44與第一、第二反應設備54、56,可量測從第 鲁-容置槽44流人第-、第二反應設備54、56之無機有害廢棄物的流 量，第二秤量槽52連接第一容置槽44與第三反應設備58，可量測從 第一容置槽44流入第三反應設備58之無機有害廢棄物的流量。 另外第一反應設備54連接第二反應設備56’第二反應設備56連 接第三反應設備58，第一、第二、第三反應設備54、56、58皆為一 使固體與固體、固體與液體或固體與熔融物質攪拌均勻之混合機械， 如螺旋攪拌混合器、旋轉混合器、錐形攪拌混合器、單螺桿攪拌混合 器、雙螺桿授拌混合器，捏合機或乳化均勻機，第一、第二、第三反 應設備54、56、58皆有設置一加熱器，並附有熱傳導物質，加^器 可為爽套或盤管’而其加熱傳導物質可為電、蒸汽或熱媒油，穩定化 201121608 藥劑與無機有害廢棄物在第一、第二、第三反應設備54、56、58 — 起進行均勻混合反應，且其混合比例為5%~95%，當進行混合時，利 用加熱器可同時予以高溫加熱，使其反應為熔融狀液體之資源化產 物’第二反應設備56與第二秤量槽50之間的管路上有設置一閘門開 關55 ’以調節有害廢棄物進料速度；第三秤量槽52與第三反應設備 58之間的管路上有設置一閘門開關57，以調節有害廢棄物進料速度。 第二反應設備56與第三反應設備58之間的管路上有設置一閘門開關 60 ’利用閘門開關60與第一、第二、第三反應設備54、56、58可使 無機有害廢棄物與穩定化藥劑進行連續或半連續式之均勻混合以及調 節進料速度。 模具組62連接第三反應設備58，可對由第三反應設備58所輸出 的資源化產物依序進行成型、冷卻、脫模之程序模型化，並以連續造 粒的方式產生資源化產品，該資源化產品之形式為粉狀之固體，產生 之後先由一儲槽64接收，再由一輸送帶66將資源化產品傳送出去。 以下說明本發明之處理方法，其一是連續式製程之均勻混合，本 實施例之有害無機廢棄物為垃圾焚化爐飛灰，第一、第二、第三反應 設備54、56、58皆為雙螺桿混合機或雙腕式捏合機，加熱方式是熱 媒油夾層方式加熱，一開始將含有重金屬之部分有害無機廢棄物，即 垃圾焚化爐飛灰以及穩定化藥劑分別放置於兩個容置槽44、46中，同 時保溫加熱’之後先將穩定化藥劑輸送到第一反應設備54中加熱到熔 融’再將定量的焚化爐飛灰以一定的速度加入第一反應設備54中並與 穩定化藥劑進行第一次混合’同時溫度用50。〇300。〇加熱，最適當的 溫度為190°C，使垃圾焚化爐飛灰以及穩定化藥劑加熱成為熔融狀液 體，閘門開關60在此時是打開的，所以穩定化物質與焚化爐飛灰可以 順利從第一反應設備54輸送到第二、第三反應設備56、58同時進行 第一次及第二次混合反應；此時開關55可以調節有害廢棄物進料速度 及數量進入第二反應設備56進行混合反應；第三秤量槽52再由開關 57調節進料速度與數贷，並再加入其餘無機有害廢棄物至第三反應設 201121608 備58中，以進行第三次混合反應，穩定化物質與焚化爐飛灰混合反應 比例為10~90%，最佳比例為80:20。反應設備54、56、58的轉速為 10~200RPM ’最佳速度為60RPM。經過混合反應的資源化產物，應 用第一、第二、第三反應設備54、56、58本身的推力，一定的速度， 連續造粒的方式直接輸送到模具組62中成型，冷卻、脫膜，經過丁c|_p 測試合格’即可得到資源化產品，資源化產品產生之後先由一儲槽64 接收，再由一輸送帶66將資源化產品傳送出去，此連續式均勻混合使 整個處理過程可兼顧安全性、穩定性、時效性，且極具經濟效益。 其二是半連續式製程之均勻混合，一開始將含有重金屬之有害無 φ 機廢棄物以及穩定化藥劑分別放置於兩個容置槽44、46中，同時保溫 加熱，其中有害無機廢棄物包含三部分，之後先將穩定化藥劑輸送到 第一反應設備54中加熱到熔融，再將定量的第一部分之有害無機廢棄 物以一定的速度同時加入第一反應設備54中並與穩定化藥劑進行第 一次混合反應，同時予以加熱，使有害無機廢棄物以及穩定化藥劑加 熱成作為第一熔融混合物之第一熔融狀液體，同時藉由第一反應設備 54本身的推力，自動輸送到第二反應設備56，再由第二秤量槽5〇經 過開關55定量加入第二部分之有害無機廢棄物，進行第二次混合，以 成為作為第一熔融混合物之第二熔融狀液體；閘門開關6〇在此時是關 鲁閉的，所赠定化物質與有害紐廢棄物僅能在第―、第二反應設備 54、56同時進行混合反應，一段時間後，閘門開關6〇再打開，使第 一、第二反應設備54、56中的穩定化物質與有害無機廢棄物全部都送 入第三反應設備58中，並透過開關57調節加料速度與數量，又加入 第二秤量槽52中第三部份之有害無機廢棄物，以進行第三次混合反 應，同時予以加熱，之後再輸出資源化產物，資源化產物可再連續送 至模具組62中成型，直到第一反應槽54的反應物全部洩完為止；再 經過冷卻、脫膜，經過TCLp測試合格，即可得到資源化產品，資源 化產品產生之後先由一儲槽64接收，再由一輸送帶66將資源化產品 201121608 此資源化產品具有低溶解性，高密度，低自由水量，低滲透係數， 高抗壓強度和強耐候性等特性。可依需求做成各種不同形狀，可用廣 泛使用於土木材料的填料、路基底層填料、瀝青混凝土粗粒料、細粒 料、波特蘭水泥混凝土中的粗粒料、細粒料，取代天然的粒料及細砂。 以達到廢棄物資源化、資源再生、資源再利用、以及節省天然資源， 降低河川砂石開採，降低環境衝擊，亦可供做道路級配、一般土建材 料、人工漁礁、防波堤、消波塊、景觀圍籬、登山步道等等用途 本資源化產品經過單軸抗壓強度的測試，其最大抗壓強度可以達 jj 7300 PS丨，其測試結要如下: 項目 測試值 樣品 直徑 (Average Diameter) 高度 (Length) 最大荷重 (Maximum Load) 抗壓強度 (Compressive Strength) 徑長比 (Length Diameter Ratio) (Specimen No.) (cm) (cm) (kgf) ~~(kgf/cm2)~~ (H/D) A ~~¢85一 7.15 9567 535 1 AT B ~c— ~~i8〇~~~ ~~478~j 7.25 ~7Λ5~~ 7835 ~~7352~ 456 486 1.51 ~Ϊ55~~ 在上述的報告中，可以看出以本發明處理垃圾焚化爐有害飛灰的 優越性。以垃圾焚化爐含重金屬的飛灰，經過本技術的處理，並做成 試體’進行毒性溶出試驗(TCLP)，所測得知結果證明均符合環保規範， 且經過土木材料的規範測試’其單軸抗壓強度達到7,000 PS丨以上。 資源化產品進行毒性溶出(TCLP)試驗，其測試結果如下： 檢測項目 原始飛灰數據 資源化後檢測數據 法規要求 檢驗方法 汞(mg/L) 0.0015 0.0004 <0.2 (N1EAR314.12QNIEAR201.13C) 船(mg/L) 1.85 0.48 <5.0 (N1EAR306.13C/NIEAR201.1X) 鎘(mg/L) 29,3 [ND(<0.007)] <1.0 (NIEAR306.13ONIEAR201.1X) 鉻(mg/L) 0.32 0.15 <5.0 (NIEAR306.13C/NIEAR201.1X) 砷(mg/L) ND (ND) <5.0 (NIEAR318.10C/NIEAR201.1X) 六價鉻 (mg/L) 0.25 (ND(<0.01)] <2.5 (NIEAR3310.15T/NIEAR201.1X) 銅(mg/L) ND (ND) <15.0 (NIEAR306.13C/NIEAR201.1X) 201121608 且以公共工程委員會對於土木材料的規範進行第一類A型及第二類型 的規範進行測試，所得到的結果不僅符合要求，且優於規格甚多。故 本資源化產品，可以用於土木的粒料、級配以及道路底層粒料用。取 代天然的級配砂石，以利環境的資源永續利用。 本發明的資源化處理方法所需穩定化藥劑（種類及劑量）的選擇 乃由許多變數的考量而決定’包括：項目地點、處理廢棄物的種類、 溫度、濕度、滲透水率、顆粒大小分布、處理過物質再使用方法以及 所需保持的pH值範圍和達到的溶出測驗標準要求等等，需具備實驗 設計（Experimenta丨Design)能力會經濟有效地篩選出較經濟且敏感 φ 的操作變數。 综上所述，本發明使無機有害廢棄物之重金屬穩定，達到低溶解 性’尚密度’低自由水量’低滲透係數，高抗壓強度和強耐候性等特 ϋ並可以通過毒性溶出試驗(TCLp)，確保廢棄物之無毒無害化， 直接使用於土木、建材等骨材上，達到資源化的目的。 以上所述者，僅為本發明一較佳實施例而已，並非用來限定本發 明實施之範圍’故舉凡依本發明申請專利範圍所述之形狀、構造、特 徵及精神所狀解變化絲飾，均應包括於本㈣之_請專利範圍 内0 【圖式簡單說明】 第1圖為本㈣之第—實施繼構立體圖。 之第一實施例結構剖視圖。 第3圖為本發明之第二實施例立體圖。 Ϊ4圖為本發明立體圖。 第5圖為本發明之第三實施例結構剖視圖。 【主要元件符號說明】 第一容置槽 12笛〜 14第一胖量槽 16 ::谷置槽 第一秤量槽 201121608 18反應設備 20模具組 22儲槽 24輸送帶 28第一容置槽 30第二容置槽 32第一秤量槽 34第二秤量槽 36螺旋反應爸 38模具組 40儲槽 42輸送帶 44第一容置槽 46第二容置槽 48第一科量槽 50第二秤量槽 52第三秤量槽 54第一反應設備 55閘門開關 56第二反應設備 57閘門開關 58第三反應設備 60閘門開關 62模具組 64儲槽 66輸送帶 12201121608 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a processing technique, particularly to a method for treating inorganic hazardous waste and a processing apparatus therefor. [Prior Art] The dust collecting ash produced by the electric arc furnace steelmaking industry contains a large amount of heavy metals. The dust has a small micro-grain size and high dissolution toxicity. Any discarding easily affects the air quality and enters the soil and groundwater 4, resulting in cumulative pollution of the food chain. Therefore, the Environmental Protection Department clearly determines that the dust collecting ash in the steelmaking industry is a hazardous business waste. ~ ^ In addition to the blast furnace in the domestic steelmaking industry, most of the rest are electric arc furnace steelmaking. According to the statistics of the Environmental Protection Agency, there are more than 20 electric arc furnace steelmaking industries in China, and the annual collection of dust ash is as high as 240,000 tons. In addition to self-cleaning and re-heating, the treatment industry currently approved in China is limited, and it is mainly based on solidified burial and recovery of zinc contained in it. The money that has not been properly disposed of is temporarily stored in the temporary storage. There has not been a breakthrough in technology development. Among the foreign patented technologies, U.S. Patent Nos. 5582573A1, 4911757A1, 5542977A1, 5582573A1, 5683344A1 are harmful to heavy metals, usually solidified by cement and lime, and then directly enter the landfill for landfill, without resource reuse. . Therefore, there is no more resources to complete the process. Taiwan Patent Bulletin No. 00397868 - Method for immobilizing stainless steel dust ash, and Bulletin No. 2〇〇512299 • A method for fully recovering metal oxide from electric arc furnace dust collection ash to reduce dust ash output There is a direct method of recycling dust ash as a resource. In the current treatment of Laiqi _ outside the general deduction of the processing technology: - · recycling of metal components. Recycling methods are direct reheating method, Te_cs electropolymerization method and hot carbon reduction method, these methods are all collected back to the dusty towel metal. -·Dust ash directly paste. Dust ash is directly used as a raw material for glass to produce colored ceramics and colored glass. 201121608 2. Wet method extraction: extract the metal from the dust collection with acid solution. However, this process produces a large amount of acid waste, which will cause another pollution of the environment and the cost of treatment. Therefore, the domestic incinerator fly ash is currently solidified or stabilized and solidified, and then transported to the landfill for landfill. Did not take the way to reuse. The dust-collecting part is only returned to the furnace, or recycled metal, solidification treatment and temporary storage. Therefore, the present invention is directed to the above-mentioned problems, and proposes a treatment method for inorganic harmful waste, and a treatment cost thereof, which stabilizes the heavy metal of the harmful waste, achieves low solubility, high density, low free water volume, low permeability coefficient, High compressive strength and strong weather resistance, and can be used to ensure the non-toxicity, harmlessness and stabilization of waste through toxic dissolution test (TCLP), and can be directly used on aggregates such as civil engineering and building materials to achieve resource utilization. Head ^. SUMMARY OF THE INVENTION The main object of the present invention is to provide a method for treating inorganic hazardous waste and a treatment device thereof, which stabilizes heavy metals of inorganic hazardous waste, achieves low solubility, high density, low free water volume, low permeability coefficient, High compressive strength and strong weather resistance, and the toxic dissolution test (TCLP) can be used to ensure the harmlessness of waste, and it can be directly used on aggregates such as civil engineering and building materials to achieve resource utilization. Another object of the present invention is to provide a method for treating inorganic hazardous waste and a treatment device thereof, which can make the entire treatment process safe, stable, and time-sensitive, and is extremely economical. In order to achieve the above object, the present invention provides an apparatus for treating inorganic harmful waste, comprising a first accommodating tank for storing a stabilizing agent, wherein the stabilizing agent is selected from the group consisting of a thermoplastic substance, a thermosetting substance or an elastic substance, and The second accommodating tank is used for storing inorganic harmful waste containing heavy metals. The two accommodating tanks are connected to a group of reaction equipment, and the reaction equipment receives the stabilizing agent and the inorganic harmful waste from the two accommodating tanks, and carries out the The continuous mixing of the continuous or semi-continuous process is heated at a high temperature to react it into a resource product of the molten liquid. Finally, the resource product is modeled using a mold set to make it a resource product. 4 201121608 The secret of this invention - the kind of money is harmful and pure _ treatment to find the heavy gold in the form of no nuisance waste - from the continuous solution of the continuous ^ ^ ^ evenly mixed 'and heated at high temperature to make it react to the melted liquid The resourced product, wherein the stabilizing agent is selected from the group consisting of a thermoplastic substance, a thermosetting substance or an elastic substance, and finally the resourced product is modeled to become a resource product. In order to enable your review board to have a more in-depth understanding of the structural features and efficacies of the present invention, and to implement a detailed description, and to explain in detail, as follows: [Embodiment] Figure 1 The present invention comprises first and second accommodating tanks 1 and 12, and respectively contains a stabilizing drug _ and a heavy metal-containing harmful waste, and the sputum coffee is selected from the group consisting of a thermoplastic substance, a thermosetting substance, an elastic substance or the like. The group of elastic substances of the group f may be indigo or na, the hazardous waste of money may be a single waste or a plurality of mixed wastes, and the mixing ratio of the mixed waste is 彳〇/〇~99%, inorganic harmful waste Such as general waste incineration, general city incineration, industrial waste incinerator fly ash, commercial waste incinerator bottom slag, steelmaking industry electric arc furnace dust ash (EAF dust), non-mineral steel scrap, metal Dust ash and waste in smelting industry, mercury-containing waste, mercury-containing sludge, heavy metal-containing dirt, heavy metal-contaminated soil, gas-containing compounds, low-level nuclear waste resin, incinerator fly ash, bottom slag or Broken low Of nuclear waste. The heavy metal may be lead, cadmium, arsenic, m, antimony, copper, silver, titanium, nickel, zinc, calcium, magnesium, strontium, barium or vanadium, and the stabilizing agent may be sulfur sulphide, filler, polyethyl b. A monomer of dilute, polystyrene, epoxy or polymer. The first and second accommodating tanks 、0, 12 are connected to a group of reaction devices, and the group of reaction devices comprises at least one reaction device. In this example, the number of reaction devices is taken as an example, that is, the reaction device 18. The first weighing tank 14 is connected to the second accommodating tank 12 and the reaction device 18, and can measure the flow rate of the inorganic harmful waste flowing into the reaction device 18 from the second accommodating tank 12, and the second weighing tank 16 is connected to the first accommodating tank. 10 and the reaction device 18, the flow rate of the stabilizing agent flowing into the reaction device 21721608 from the first accommodating tank 1 可 can be measured. The reaction device 18 can be a mixing machine for solid and solid, solid and liquid or solid and molten material, such as a spiral agitating mixer, a rotary mixer, a conical stirring mixer, a single screw agitating mixer, a twin screw Agitating the mixer, kneading machine or emulsification homogenizer, the reaction device 18 is provided with a heater and is provided with a heat conductive substance, the heater may be a lost sleeve or a coil, and the heating conductive substance may be electric, steam or heat medium oil; The stabilizing agent and the inorganic harmful waste are uniformly mixed together in the reaction device 18, and the mixing ratio thereof is 5% to 95%. When mixing, the heater can be simultaneously heated at a high temperature to react it into a molten liquid. The resource product. The mold set 20 is connected to the reaction device 18, and the process of molding, cooling, and demoulding the resource product outputted from the reaction device 18 can be sequentially modeled, and the resourceized product is produced by continuous granulation and molding. The product is in the form of a powdery solid which is received by a storage tank 22 after it is produced, and the recycled product is conveyed by a conveyor belt 24. The treatment method of the present invention is described below, which is a uniform mixing of the batch process. The harmful inorganic waste of the present embodiment is a waste incinerator fly ash, and the reaction device 18 is a twin-screw mixer or a double-winch kneader, and the heating method is The heat medium oil is heated in a sandwich manner, and the fly ash and the stabilizing agent containing the heavy metal waste incinerator are first placed in the two accommodating tanks 10 and 12, and then the stabilizing agent is first delivered to the first weighing amount. In the tank 14, the quantitative stabilizing agent is put into the reaction device 18 from the weighing tank 14 to be heated to melt, and the quantitative incinerator fly ash is driven into the second weighing tank 16, and then simultaneously added at a certain speed. The reaction device 18 is mixed and reacted with the stabilizing agent, and the temperature is heated by 5 (TC to 300 eC), and the most suitable temperature is 190. 〇, the waste incinerator fly ash and the stabilizing agent are heated to become a molten liquid, and the stabilizing substance is stabilized. The mixing ratio with the incinerator fly ash is 10~90% 'the optimum ratio is 80:20. The reaction equipment 18 rotates at 10~200RPM, and the optimum speed is 60RPM. The mixed reaction resources The product, using the thrust of the reaction equipment 18 itself, at a certain speed, directly sent to the mold group for forming or continuous granulation, cooling, stripping, and passing the TCLP test, the resource product can be obtained. Then, it is first received by a storage tank 22, and then the resourceized product is conveyed by a conveyor belt 24. This continuous uniform mixing makes the whole process safe and stable, and the 201121608 timeliness is highly economical. Referring to Fig. 1, a plan view of Fig. 2 is also attached for comparison. Fig. 3 is a structural view showing a second embodiment of the present invention, which is a mixture of the same sentence of another batch process. The difference between the treatment mode of Fig. 1 and Fig. 1 is that the spiral reaction kettle 36 is used to completely mix the inorganic hazardous waste with the stabilizing agent to form a resourced product, and then batchly sent to the mold set 38, and finally the resource product model is finally obtained. For the following, please refer to FIG. 4 and FIG. 5 of the third embodiment. Similarly, the second embodiment includes first and second receiving grooves 44 and 46, respectively. There are inorganic hazardous wastes containing heavy metals and stabilizing chemicals, the components of which are the same as in the first embodiment. The first and second φ two accommodating tanks 44, 46 are connected to a group of reaction equipment, which includes a group of first and Second, the third sub-reaction device, the first, second, and third sub-reaction devices of the group respectively comprise at least one reaction device. In this example, the number of reaction devices included in the first sub-reaction device is taken as an example. That is, the first reaction device 54; the second sub-reaction device contains the number of reaction devices as an example of the second reaction device 56; the third sub-reaction device contains the number of reaction devices, for example, the third reaction The first weighing device 48 is connected to the second receiving tank 46 and the first reaction device 54 to measure the flow rate of the stabilizing agent flowing from the second receiving tank 46 into the first reaction device 54; the second weighing tank 50 The first accommodating tank 44 and the first and second reaction devices 54 and 56 are connected to measure the flow rate of the inorganic hazardous waste flowing from the first and second reaction devices 54 and 56 from the second arranging tank 44. The second weighing tank 52 is connected to the first receiving groove 44 and the third reaction device 58, the inflow rate measuring apparatus 58 of the third reaction inorganic hazardous waste from the first accommodating groove 44. In addition, the first reaction device 54 is connected to the second reaction device 56'. The second reaction device 56 is connected to the third reaction device 58. The first, second, and third reaction devices 54, 56, 58 are all solid and solid, solid and a mixing machine in which a liquid or solid and a molten substance are uniformly stirred, such as a spiral agitating mixer, a rotary mixer, a conical stirring mixer, a single-screw stirring mixer, a twin-screw mixing mixer, a kneading machine or an emulsification homogenizer, first The second and third reaction devices 54, 56, 58 are each provided with a heater and a heat conductive substance, and the heater can be a cool sleeve or a coil, and the heating conductive substance can be electricity, steam or heat medium. Oil, stabilized 201121608 Pharmacy and inorganic hazardous waste are uniformly mixed in the first, second and third reaction equipment 54, 56, 58, and the mixing ratio is 5% to 95%, when mixing, The heater can be simultaneously heated at a high temperature to react it into a resourceized product of the molten liquid. A gate switch 55' is disposed on the pipeline between the second reaction device 56 and the second weighing tank 50 to regulate hazardous waste. Feed rate; a third line between the groove 52 and the third reaction weighing device 58 has a gate switch 57 is provided to adjust the feed rate of hazardous waste. A gate switch 60 is disposed on the pipeline between the second reaction device 56 and the third reaction device 58. The inorganic hazardous waste can be made by using the gate switch 60 and the first, second, and third reaction devices 54, 56, 58. The stabilizing agent is subjected to a uniform or semi-continuous homogeneous mixing and to adjust the feed rate. The mold set 62 is connected to the third reaction device 58 to model the process of molding, cooling, and demoulding the resourced product outputted by the third reaction device 58 in sequence, and to generate the resourceized product by continuous granulation. The resourced product is in the form of a powdery solid which is then received by a storage tank 64 and conveyed by a conveyor belt 66. Hereinafter, the treatment method of the present invention will be described. One of them is uniform mixing of the continuous process. The harmful inorganic waste of the present embodiment is waste incinerator fly ash, and the first, second and third reaction devices 54, 56, 58 are all The twin-screw mixer or the double-winch kneader is heated by means of a heat medium oil sandwich. At the beginning, part of the harmful inorganic waste containing heavy metals, that is, the waste incinerator fly ash and the stabilizing agent are respectively placed in two accommodations. In the tanks 44, 46, the heat-suppressing agent is simultaneously sent to the first reaction device 54 to be heated to melt, and then the quantitative incinerator fly ash is added to the first reaction device 54 at a certain speed and stabilized. The chemical is mixed for the first time' while the temperature is 50. 〇300. 〇 heating, the most appropriate temperature is 190 ° C, so that the waste incinerator fly ash and the stabilizing agent are heated into a molten liquid, the gate switch 60 is open at this time, so the stabilizing substance and the incinerator fly ash can smoothly The first reaction device 54 is sent to the second and third reaction devices 56, 58 to perform the first and second mixing reactions simultaneously; at this time, the switch 55 can adjust the feed rate and quantity of the hazardous waste into the second reaction device 56. The mixing reaction; the third weighing tank 52 further adjusts the feed rate and the number of loans by the switch 57, and then adds the remaining inorganic harmful waste to the third reaction set 201121608 to perform the third mixing reaction, stabilizing the substance and The ratio of fly ash mixed reaction in incinerator is 10~90%, and the optimal ratio is 80:20. The reaction equipment 54, 56, 58 has a rotational speed of 10 to 200 RPM and an optimum speed of 60 RPM. The resourced product of the mixed reaction is directly sent to the mold set 62 for molding, cooling, and stripping by applying the thrust of the first, second, and third reaction apparatuses 54, 56, and 58 themselves at a certain speed and continuous granulation. After the test is completed, the resource product can be obtained. After the resource product is produced, it is first received by a storage tank 64, and then the resourceized product is sent out by a conveyor belt 66. This continuous uniform mixing makes the whole process The process combines safety, stability, timeliness and economics. The second is the uniform mixing of the semi-continuous process. At the beginning, the harmful non-φ machine waste containing heavy metals and the stabilizing agent are separately placed in the two accommodating tanks 44, 46, and the heat is heated, wherein the harmful inorganic waste contains After three parts, the stabilizing agent is first transferred to the first reaction device 54 to be heated to melt, and the quantitative first portion of the harmful inorganic waste is simultaneously added to the first reaction device 54 at a certain speed and is carried out with the stabilizing agent. The first mixing reaction is simultaneously heated to heat the harmful inorganic waste and the stabilizing agent into the first molten liquid as the first molten mixture, and is automatically transported to the second by the thrust of the first reaction device 54 itself. The reaction device 56 is further quantified by the second weighing tank 5 through the switch 55 to the second portion of the harmful inorganic waste for a second mixing to become the second molten liquid as the first molten mixture; the gate switch 6〇 At this time, it is closed, and the given substances and harmful new waste can only enter at the same time in the first and second reaction devices 54, 56. After the mixing reaction, after a period of time, the gate switch 6 is opened again, so that the stabilizing substance and the harmful inorganic waste in the first and second reaction devices 54, 56 are all sent to the third reaction device 58, and the switch is transmitted through the switch. 57 adjusting the feeding speed and quantity, and adding the third part of the harmful inorganic waste in the second weighing tank 52 to carry out the third mixing reaction, heating at the same time, and then outputting the resourced product, and the resourced product can be continuously continuous. It is sent to the mold set 62 for molding until the reactants of the first reaction tank 54 are completely discharged; after cooling, stripping, and passing the TCLp test, the resourceized product can be obtained, and the resourceized product is first produced by a storage. The tank 64 receives, and the recycled product of the resourceized product 201121608 by a conveyor belt 66 has low solubility, high density, low free water volume, low permeability coefficient, high compressive strength and strong weather resistance. Can be made into various shapes according to requirements, can be widely used in civil material fillers, road base layer filler, asphalt concrete coarse aggregate, fine pellets, coarse cement in Portland cement concrete, fine pellets, instead of natural Granules and fine sand. In order to achieve waste recycling, resource recycling, resource reuse, and saving natural resources, reducing sand and gravel mining and reducing environmental impact, it can also be used for road grading, general civil materials, artificial reefs, breakwaters, wave-eliminating blocks, Landscape fences, hiking trails, etc. This resource-based product has been tested for uniaxial compressive strength. The maximum compressive strength can reach jj 7300 PS丨. The test results are as follows: Project test sample diameter (Average Diameter) Height (Length) Maximum Load (Compressive Strength) Length Diameter Ratio (Specimen No.) (cm) (cm) (kgf) ~~(kgf/cm2)~~ (H/ D) A ~~¢85_7.15 9567 535 1 AT B ~c~ ~~i8〇~~~ ~~478~j 7.25 ~7Λ5~~ 7835 ~~7352~ 456 486 1.51 ~Ϊ55~~ In the above report Among them, the superiority of treating the harmful fly ash of the garbage incinerator by the present invention can be seen. The fly ash containing heavy metals in the waste incinerator is treated by this technology and made into the test body's toxic dissolution test (TCLP). The results of the test prove that they are in compliance with environmental regulations, and have passed the normative test of civil materials. The uniaxial compressive strength is above 7,000 PS丨. The resource product is subjected to toxic dissolution (TCLP) test, and the test results are as follows: Test item original fly ash data resourceization test data regulatory requirements test method mercury (mg/L) 0.0015 0.0004 <0.2 (N1EAR314.12QNIEAR201.13C) (mg/L) 1.85 0.48 <5.0 (N1EAR306.13C/NIEAR201.1X) Cadmium (mg/L) 29,3 [ND(<0.007)] <1.0 (NIEAR306.13ONIEAR201.1X) Chromium (mg/ L) 0.32 0.15 <5.0 (NIEAR306.13C/NIEAR201.1X) Arsenic (mg/L) ND (ND) <5.0 (NIEAR318.10C/NIEAR201.1X) Hexavalent chromium (mg/L) 0.25 (ND( <0.01)] <2.5 (NIEAR3310.15T/NIEAR201.1X) Copper (mg/L) ND (ND) <15.0 (NIEAR306.13C/NIEAR201.1X) 201121608 and the Public Works Committee's specification for civil materials The first type A and the second type of specifications are tested, and the results obtained are not only in line with the requirements, but also superior to the specifications. Therefore, the resource products can be used for civil materials, grading, and road bottom particles. It is used as a material to replace the natural graded sandstone for the sustainable use of environmental resources. The resource treatment method of the present invention requires stabilization of the medicament (type and dose). The choice is determined by a number of variables' including: project location, type of waste treated, temperature, humidity, permeate rate, particle size distribution, treated material reuse method, and desired pH range and achieved The requirements of the dissolution test standard, etc., require the experimental design (Experimenta 丨 Design) ability to cost-effectively screen out the economical and sensitive φ operational variables. In summary, the present invention stabilizes the heavy metals of inorganic hazardous waste to a low level. Solubility 'still density' low free water volume 'low permeability coefficient, high compressive strength and strong weather resistance and other characteristics can pass the toxic dissolution test (TCLp) to ensure the non-toxic and harmless waste, directly used in civil engineering, building materials, etc. The above is only a preferred embodiment of the present invention, and is not intended to limit the scope of the practice of the present invention. Therefore, the shape and structure described in the patent application scope of the present invention. , the characteristics and the spirit of the changes in the silk decoration, should be included in this (four) _ the scope of the patent 0 [simple description of the map] Figure 1 The present invention is a cross-sectional view of a first embodiment of the present invention. Figure 3 is a perspective view of a second embodiment of the present invention. Figure 4 is a perspective view of the present invention. Figure 5 is a cross-sectional view showing the structure of a third embodiment of the present invention. [Main component symbol description] The first accommodating groove 12 flutes ~ 14 first fat amount groove 16 :: valley groove first weighing tank 201121608 18 reaction equipment 20 mold group 22 storage tank 24 conveyor belt 28 first accommodating tank 30 Second accommodating groove 32 first weighing tank 34 second weighing tank 36 spiral reaction dad 38 mold group 40 storage tank 42 conveyor belt 44 first accommodating groove 46 second accommodating groove 48 first branch amount 50 second weighing Tank 52 third weighing tank 54 first reaction device 55 gate switch 56 second reaction device 57 gate switch 58 third reaction device 60 gate switch 62 mold set 64 storage tank 66 conveyor belt 12