201105360 六、發明說明： 【發明所屬之技術領域】 本發明係關於一種包含無四級胺化合物之調理凝膠之毛 髮調理組合物。 【先前技術】 含有基於四級銨之調理成分之陽離子性調理劑在具有陰 離子性蛋白質部份時不安定。因此，仍需要一種專用且有 效的調理組合物，其在具有此等成分時係安定。 【發明内容】 因此，本發明係關於一種包括陰離子性蛋白質部份及具 有16至22個碳原子之烷基之陰離子性界面活性劑、具有16 至22個碳原子之脂肪物質及水之毛髮護理組合物，其中該 組合物包括少於1重量％的具有8至14個碳原子的烷基之陰 離子性界面活性劑及少於0.5重量％的陽離子性界面活性 劑。 較佳地，該組合物不含具有8至14個碳原子之烷基之陰 離子性界面活性劑。 較佳地，該組合物包含少於〇·2重量％之陽離子性界面活 性劑，更佳少於0.1重量％之陽離子性界面活性冑，最佳不 含陽離子性界面活性劑。 該脂肪物質較佳係脂肪醇。以鯨蠟硬脂醇特別佳。 較佳地’該凝膠網狀結構中之該陰離子性界面活性劑及 該脂肪物質之碳數係4個以内，較佳各含2個碳，且最=具 有相同的奴數。更佳地，該界面活性劑/脂肪物質包括糊 149057.doc 201105360 石厌以内’更佳2個碳以内，1最佳係具有相同長度之單一 烷基。此有助於保持該凝膠網狀結構之安定性。 /遠組合物包括陰離子性蛋白f部份，該蛋白質部份較佳 係以角蛋白為主’較佳的角蛋白部份係經s•磺化，以其中 。玄、’主S碩化之角蛋白部份係完整者更佳。「完整」係指尚 未顯者水解之蛋白質。尤其與本發明相關者係由Gillespie 在 Gdlespie^och—stry and physi〇1〇gy 〇f 加—，第工卷別 Goldsmith 〇xford University press，倫敦，i983，第 4乃至 η。 頁）中所述之「完整」蛋白質。此等相當於呈其天然形式 (不含經由角質化過程所形成的二硫化物交聯鍵）之角蛋 白。 角蛋白伤」係純化形式的角蛋白，其主要（儘管並 非全部）含有一種獨特的蛋白基。 ’’IS s化之角蛋白具有主要呈$_續基半胱胺酸形式（通常 稱為邦特（Bunte)鹽）存在之半胱胺酸/胱胺酸。 較佳的角蛋白部份係含有s_磺化角蛋白高硫蛋白（SHSp) 之S-磺化角蛋白部份。此等蛋白質較佳具有1〇至3〇 kD範 圍内之刀子;g，及南於10%的半胱胺酸含量（經由胺基酸分 析測得）。此物質可藉由多種方法製備，包括彼等描述於 W0 2003011894 A1 中者。 較佳的s-磺化蛋白質部份係Keratec HSP(來自Croda公 司）。 角蛋白部份在該組合物中之濃度為該組合物（組舍物1的 至少0.2重量％，較佳高於0 5重量％，更佳高於i 5重量％， 149057.doc 201105360 最佳為1至7重里％。如果角蛋白部份之濃度低於5重量％， 則發現该產品具有較佳的安定性。 較佳地’該組合物包括植物油。較佳的植物油包括荷荷 巴油、大丑油、莫花杆油、米糠油m杏仁油、撖 欖油、芝麻油、蓖麻油、椰子油、貂油。 較佳地《亥組合#包括陰離子性聚合物n m n 物之實例包括烧基乙稀基__馬來酸共聚物（商標名： G續ez S95)、黃原膠(商標名：κ-〇ι rd)及去氫黃原膠 (商標名：Amaze XT)。 較佳地，該組合物之pH為2 5至8。 在第- I、樣中，本發明提供_種根據先前技術方案中任 一項之組合物用於調理毛髮之用途。 根據本發明組合物可含有常見於調理組合物中之任何種 類的成分，例如聚石夕氧、脂肪醇、脂肪酸、脂肪醯胺、著 色劑 '染料、顏料、珍珠光澤劑、增㈣、結構化劑 光劑等。 聚石夕氧係本發明毛髮處理組合物中一種特別佳的成分。 具體而言’本發明調理劑較佳亦將包含乳化的聚石夕氧顆 ^ ’以用於增強調理性能。㈣氧不溶於該組合物之水性 :質，且因此呈乳化形式存在’聚石夕氧則以分散顆粒存 合適的聚⑦氧包括聚雙有財氧炫，特定言之係CTFA 名稱為二甲聚碎氧烧（dimethie_)之聚二甲基 適用於本發明組合物（尤其係洗髮精及調理劑）者為^有末 i49057.doc 201105360 端經基之聚二甲基石夕氧烧，其CTFA名稱為二甲聚石夕氧烧 醇(dimethic〇n〇1)。亦適用於本發明組合物者為具有低交聯 度的聚㈣膠’如WO 96/31188中所述。該等材料可賦予 毛髮質地、蓬鬆及可塑性，及良好的乾濕調理性。 乳化聚石夕氧自身（非乳液或最終的毛髮調理組合物）之黏 度通常係至少1〇，_ 一般，吾人發現調理效果隨黏 度的增加而增強。因此，聚矽氧自身之黏度較佳係至少 60，_ cst ’最佳係至少5⑽，_⑶，理想係至少1，嶋嶋 cst。為方便調配，該黏度較佳不超過1〇9 。 用於本發明毛髮洗髮精及調理劑的乳化聚矽氧通常在組 合物中具有小於30微米，較佳小於2〇微米，更佳小於⑺微 米之平均聚石夕氧粒度。吾人已發現，減小粒度通常改善調 理性能。組合物中該乳化聚矽氧之平均聚矽氧粒度最佳為 小於2微米，其理想為（^(^至丨微米之間。具有α 15微米之 平均聚石夕氧粒度的聚矽氧乳液通常稱為微乳液。 粒度可藉由雷射散射技術，使用購自Malvern㈤加咖⑽ 之2600D粒度分析儀測量。 用於本發明之合適的聚矽氧乳液亦可呈預乳化形式購 得。 合適的預形成乳液實例包括乳液DC2-1766、DC2-1784 及微乳液DC2-1865及DC2-1870,其等均購自Dow Corning。 該等均係二曱聚矽氧烷醇之乳液/微乳液。交聯之聚矽氧 膠亦可呈預乳化形式購得，其有利於方便調製。較佳實例 係購自Dow Corning的DC X2-1787材料，其係交聯二曱聚 149057.doc 201105360 石夕氧烧醇膠之乳液。另—較佳實例係購自D_ ㈣的 之DC X2-1391材料’其係交聯二甲聚矽氧烷醇膠之微乳 液。 本發明之洗髮精及調理劑中另一較佳聚矽氧種類係胺基 官能性聚矽氧。「胺基官能性聚矽氧」意指包含至少—個 一級胺基，二級胺基或三級胺基，或四級胺基的聚矽氧。 合適的胺基聚矽氧實例包括： ⑴聚矽氧烧，其CTFA名稱為「胺基二曱聚矽氧烧 (amodimethicone)」且具有以下通式：201105360 VI. INSTRUCTIONS OF THE INVENTION: TECHNICAL FIELD OF THE INVENTION The present invention relates to a hair conditioning composition comprising a conditioning gel without a quaternary amine compound. [Prior Art] A cationic conditioning agent containing a quaternary ammonium-based conditioning component is unstable when it has an anionic protein moiety. Thus, there remains a need for a proprietary and effective conditioning composition that is stable when present in such compositions. SUMMARY OF THE INVENTION Accordingly, the present invention is directed to an anionic surfactant comprising an anionic protein moiety and an alkyl group having 16 to 22 carbon atoms, a fatty material having 16 to 22 carbon atoms, and a hair care for water. A composition wherein the composition comprises less than 1% by weight of an anionic surfactant having an alkyl group of 8 to 14 carbon atoms and less than 0.5% by weight of a cationic surfactant. Preferably, the composition is free of anionic surfactants having an alkyl group of from 8 to 14 carbon atoms. Preferably, the composition comprises less than 0.2% by weight of a cationic surfactant, more preferably less than 0.1% by weight of a cationic interfacial surfactant, and most preferably no cationic surfactant. The fatty substance is preferably a fatty alcohol. It is especially good with cetearyl alcohol. Preferably, the anionic surfactant and the fatty substance in the gel network have a carbon number of 4 or less, preferably 2 carbons each, and most have the same slave number. More preferably, the surfactant/fat substance comprises a paste of 149057.doc 201105360, preferably within 2 carbons, and 1 of a single alkyl group of the same length. This helps to maintain the stability of the gel network. The far/distortion composition includes an anionic protein f moiety, and the protein moiety is preferably keratin-based. The preferred keratin moiety is sulphonated to sulphonate. It is better to have the keratin fraction of the main S master. "Complete" means a protein that has not been hydrolyzed. In particular, the person associated with the present invention is Gillespie at Gdlespie^och-stry and physi〇1〇gy 〇f plus, the work volume Goldsmith 〇xford University press, London, i983, 4th to η. The "complete" protein described in the page). These are equivalent to keratin in its natural form (without the disulfide crosslinks formed by the keratinization process). Keratin injury is a purified form of keratin that contains, although not exclusively, a unique protein group. The 's sinized keratin has a cysteine/cystamic acid which is predominantly in the form of the $-contiguous cysteic acid (commonly known as the Bunte salt). A preferred keratin moiety is the S-sulfonated keratin fraction comprising s_sulfonated keratin high sulfur protein (SHSp). These proteins preferably have a knife in the range of 1 〇 to 3 〇 kD; g, and a cysteine content of 10% (measured by amino acid analysis). This material can be prepared by a variety of methods, including those described in WO 2003011894 A1. A preferred s-sulfonated protein fraction is Keratec HSP (from Croda Corporation). The concentration of the keratin fraction in the composition is at least 0.2% by weight of the composition (preferably above 0.5% by weight, more preferably above 5% by weight, 149057.doc 201105360 best) It is from 1 to 7% by weight. If the concentration of the keratin fraction is less than 5% by weight, the product is found to have better stability. Preferably, the composition comprises vegetable oil. Preferred vegetable oils include jojoba oil. , ugly oil, mohua oil, rice bran oil, almond oil, eucalyptus oil, sesame oil, castor oil, coconut oil, eucalyptus oil. Preferably, "Hai combination # includes an anionic polymer nmn. Ethyl __maleic acid copolymer (trade name: G continued ez S95), xanthan gum (trade name: κ-〇ι rd) and dehydrogenated xanthan gum (trade name: Amaze XT). Preferably The pH of the composition is from 25 to 8. In the first, the invention provides the use of a composition according to any one of the preceding claims for conditioning hair. The composition according to the invention may contain Any of a variety of ingredients commonly found in conditioning compositions, such as polyoxin, fatty alcohols, fatty acids, fats Indoleamine, coloring agent 'dye, pigment, pearlescent agent, sensitizing agent (4), structuring agent, etc. Polychlorite is a particularly preferred component of the hair treatment composition of the present invention. Specifically, the present invention is a conditioning agent. Preferably, it will also comprise an emulsified polysulfide oxide for use in enhancing conditioning properties. (iv) Oxygen is insoluble in the aqueous properties of the composition: quality, and thus in the presence of an emulsified form. The poly 7 oxygen includes polyglycolic acid, in particular, the CTFA name is dimethie-di polydimethyl is suitable for the composition of the present invention (especially shampoo and conditioner) Is a polydimethyl oxazepine of the end of the i49057.doc 201105360, the CTFA name of which is dimethic 烧n〇1. Also suitable for the composition of the present invention Poly(tetra) gums with a low degree of cross-linking as described in WO 96/31188. These materials impart hair texture, fluffiness and plasticity, and good dry and wet conditioning. Emulsified polyglycol itself (non-emulsion or final) Hair conditioning composition) usually has a viscosity of at least 1〇 _ In general, we have found that the conditioning effect increases with increasing viscosity. Therefore, the viscosity of polyoxygen itself is preferably at least 60, _ cst 'best is at least 5 (10), _ (3), ideal is at least 1, 嶋嶋 cst. Preferably, the viscosity is preferably no more than 1 〇 9. The emulsified polyfluorene used in the hair shampoos and conditioners of the present invention typically has less than 30 microns, preferably less than 2 microns, more preferably less than (7) microns in the composition. The average poly-stone particle size. It has been found that reducing the particle size generally improves the conditioning performance. The average particle size of the emulsified polyfluorene oxide in the composition is preferably less than 2 microns, which is ideally (^(^ to 丨) Between microns. Polyoxyxyl emulsions having an average polyoxane particle size of from 15 microns are commonly referred to as microemulsions. Particle size can be measured by laser scattering techniques using a 2600D particle size analyzer available from Malvern (10) plus coffee (10). Suitable polyoxynized emulsions for use in the present invention are also available in pre-emulsified form. Examples of suitable preformed emulsions include emulsions DC2-1766, DC2-1784 and microemulsions DC2-1865 and DC2-1870, all of which are commercially available from Dow Corning. These are all emulsions/microemulsions of dioxins. The crosslinked polyoxyl phthalate is also commercially available in a pre-emulsified form which facilitates ease of preparation. A preferred example is DC X2-1787 material available from Dow Corning, which is a crosslinked dimeric polymer 149057.doc 201105360. Alternatively, a preferred embodiment is DC X2-1391 material from D_(iv), which is a microemulsion of crosslinked dimethylpolyoxyalkanol gum. Another preferred polyoxo class of the shampoos and conditioners of the present invention is an amine functional polyoxyx. "Amino functional polyoxyl" means polyfluorene containing at least one primary, secondary or tertiary amine group, or a quaternary amine group. Examples of suitable amine polyfluorenes include: (1) Polyoxymethane, which has the CTFA designation "aminodimethicone" and has the following general formula:
H0-[Si(CH3)2-0-]x-[Si(0H)(CH2CH2CH2-NH-CH2CH2NH2)-0-]y-H 其中’ X及y係取決於該聚合物分子量的數值，通常使 分子量在約5,000至500,000之間。 (ii)聚矽氧烷，其具有通式： R’aG3-a-Si(OSiG2)n-(OSiGbR’2-b)m-〇-SiG3_a-R'a 其中： G係選自Η、苯基、OH或C1 ·8烧基，例如甲基； a為0或1至3之間的整數，較佳為0 ; b為0或1，較佳為1 ; m與η為使（m+n)在1至2000之間，較佳50至150之間的 數值； m為1至2000之間，較佳1至1〇之間的數值； η為0至1999之間，較佳49至149之間的數值，且 R'係式-CqH2qL之單價自由基，其中q為2至8之間的數 值且L係選自下列的胺基官能基： 149057.doc 201105360 -nr"-ch2-ch2-n(r")2 -n(r’’)2 -n+(r’，)3a- -n+h(r")2a· _n+h2(r')a- -N(R")-CH2-CH2-N+H2(R")a- 其中R"係選自H、苯基、爷其u 令魯卞暴或飽和早價烴基，例如H0-[Si(CH3)2-0-]x-[Si(0H)(CH2CH2CH2-NH-CH2CH2NH2)-0-]yH where 'X and y are dependent on the molecular weight of the polymer, usually the molecular weight is Between 5,000 and 500,000. (ii) a polyoxyalkylene having the formula: R'aG3-a-Si(OSiG2)n-(OSiGbR'2-b)m-〇-SiG3_a-R'a wherein: G is selected from the group consisting of ruthenium and benzene a group, OH or C1 ·8 alkyl, such as methyl; a is 0 or an integer between 1 and 3, preferably 0; b is 0 or 1, preferably 1; m and η are such that (m+ n) a value between 1 and 2000, preferably between 50 and 150; m is a value between 1 and 2000, preferably between 1 and 1 Torr; η is between 0 and 1999, preferably 49 to a value between 149, and R' is a monovalent radical of the formula -CqH2qL, wherein q is a number between 2 and 8 and L is selected from the group consisting of the following amine functional groups: 149057.doc 201105360 -nr"-ch2- Ch2-n(r")2 -n(r'')2 -n+(r',)3a- -n+h(r")2a· _n+h2(r')a- -N(R") -CH2-CH2-N+H2(R")a- where R" is selected from the group consisting of H, phenyl, ge, or ruthenium or saturated early-valent hydrocarbon groups, for example
Cl.20烧基，及； A為_離子’例如氣離子或溴離子。 對應於上式之適宜胺基官能性聚矽氧包括下述稱為 一甲基矽烷基胺基二甲聚矽氧烷」且其不溶於水之 程度足以適用於本發明組合物之聚石夕氧烧：Cl.20 is calcined, and; A is an ionic ion such as a gas ion or a bromide ion. Suitable amine functional polyoxyl oxygen corresponding to the above formula includes the following, which is referred to as monomethylalkylalkyl dimethylpolysiloxane, and which is insoluble in water to a degree sufficient for the composition of the present invention. Oxygen burning:
Si(CH3)3-0-[Si(CH3)2-〇-]x-[Si(CH3)(R-NH-CH2CH2NH2)-〇-]y.Si(CH3)3 其中x+y為約50至約500之間的數值，且其中R為具有2至 5個碳原子的伸烷基。χ+y較佳在約1〇〇至約3〇〇之間。 (iii)四級聚矽氧聚合物，其具有通式： {(R])(R2)2(R3)_2CH(0,2〇(Ch2)3_^ -(CH2)3-0-CH2CH(OH)CH2N+(R8)(R9)(Ri〇)} (χ·)2 其中R1及R1g可相同或不同且可分別獨立地選自Η '飽 和或不飽和的長或短鏈烧（烯）基、分支鏈烷（烯）基及 C5-C8環系統； R2至R9可相同或不同且可分別獨立地選自Η、直鏈或 分支鏈低碳數烷（烯）基、及〇5-(：8環系統； η為約60至約120之間的數值，較佳約go，且 149057.doc 201105360 χ-較佳為醋酸根，但可改用例如鹵離子、有機羧酸 根'有機磺酸根等。 在ΕΡ-Α-0 530 974中描述此類合適的四級聚石夕氧聚合物。 適用於本發明洗髮精及調理劑的胺基官能性聚矽氧的胺 g能基莫耳％通常為約〇」至約8 〇莫耳％，較佳約〇 1至約 5.0莫耳％，最佳約〇.丨至約2〇莫耳％。通常胺濃度不應超 過約8.0莫耳％，因為吾人已發現過高的胺濃度對總聚矽氧 沉積不利且因此不利於調理性能。 胺基B flb性t石夕氧之黏度非特別關鍵且可在約1 〇 〇至約 500,000 cst之間適當地變化。 適用於本發明之胺基官能性聚矽氧的具體實例係胺基聚 石夕氧油 DC2-8220、DC2-8166、DC2-8466、及 DC2-8950-114(均 ex Dow Corning)、及GE 1149_75(ex General Electric SiHc〇nes)。 具有非離子及/或陽離子界面活性劑的胺基官能性聚矽 氧油之乳液亦合適β 該等預形成之乳液在該洗髮精組合物中適宜具有小於3〇 微米，較佳小於20微米，更佳小於1 〇微米之平均胺基官能 性聚矽氧粒度。吾人已再次發現減小粒度通常能改善調理 性月b。忒組合物中的平均胺基官能性聚石夕氧粒度最佳係小 於2微米，理想係(^(^至丨微米之間。具有$〇15微米之平均 聚矽氧粒度的聚矽氧乳液通常稱為微乳液。 胺基官能性聚矽氧之預形成乳液亦可自聚矽氧油供應商 購得，例如Dow Corning及General Electric。具體實例包括 DC929陽離子乳液、DC939陽離子乳液、及非離子乳液 149057.doc 201105360 0€2-7224、0〇2-8467、002-8177及002-8154(均以0〇貿（：〇1^1^)。 用於本發明的四級聚矽氧聚合物之實例係材料K3474， ex Goldschmidt ° 併入本發明組合物中的聚矽氧總量取決於所需的調理程 度及使用的材料。較佳量係占總組合物之0.01至約10重量 °/〇，儘管該等限制並非絕對。該下限係由達到調理之最低 濃度決定，且該上限係由避免毛髮及/或皮膚出現不可接 受的油腻之最高濃度決定。 吾人已發現占該總組合物0.3至5重量％，較佳0.5至3重 量％之聚矽氧總量係合適濃度。 【實施方式】 現將參考以下非限制性實例說明該等實例。 實例1 以下係根據本發明之調理組合物： 成分 1 2 3 4 5 6 7 8 鯨蝶硬脂基硫酸鈉 1 1 1.5 1.5 1 1.5 1.5 1 鯨蠟硬脂醇 4 3 6 6 3 6 6 4 NATROSOL® 250HHR(1) - 1.5 - - 1.5 - - - POLYSURF®67(2> - - 0.03 - - 0.03 - - ESAFLOR®HM22(2) - - - 0.4 - - 0.4 琴 KeratecHSP(11.9% 活性） 33.6 33.6 33.6 33.6 33.6 33.6 33.6 33.6 聚矽氧(60%活性） - - - - 1.5 1.5 1.5 1.5 甘胺酸大豆油 2 2 2 2 - - - - DMDM乙内醯脲及3-碘-2-丙炔基丁基胺基曱酸酯 (50%活性） 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 乙二胺四乙酸二鈉 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 甲基異噻唑啉酮 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 香料 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 水 加至 加至 加至 加至 加至 加至 加至 加至 100 100 100 100 100 100 100 100 •10- 149057.doc 201105360 成分 9 10 11 12 13 14 15 16 鯨躐硬脂基硫酸鈉 1 1 1.5 1.5 1 1.5 1.5 1 鯨蠟硬脂醇 4 3 6 6 3 6 6 4 NATROSOL® 250HHRU, - 1.5 - - 1.5 - - - POLYSURF®67(勻 - - 0.03 - - 0.03 - - ESAFLOR®HM22w - - - 0.4 - - 0.4 - KeratecHSP(11.9% 活性） 16.8 16.8 16.8 16.8 16.8 16.8 16.8 16.8 聚矽氧(60%活性） - - - - 1.5 1.5 1.5 1.5 甘胺酸大豆油 2 2 2 2 - - - - DMDM乙内醯脲及3-碘-2-丙炔基丁基胺基曱酸酯 (50%活性） 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 乙二胺四乙酸二鈉 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 曱基異噻唑啉酮 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 香料 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 水 加至 加至 加至 加至 加至 加至 加至 加至 100 100 100 100 100 100 100 100 成分 17 18 19 20 21 22 鯨堪硬脂基硫酸鈉 1 1 1 1 1 1 鯨蠟硬脂醇 3 3 3 3 3 3 Keltrol RD 1.0 - - 1.0 - - Amaze XT - 1.0 - - 1.0 - Gantrez S 95 - - 0.5 - - 0.5 聚矽氧(60%活性） 1.5 1.5 1.5 1.5 1.5 1.5 KeratecHSP(11.9% 活性） 33.6 33.6 33.6 16.8 16.8 16.8 DMDM乙内醯脲及3-碘-2-丙炔基丁基胺基甲酸酯 (50%活性） 0.1 0.1 0.1 0.1 0.1 0.1 乙二胺四乙酸二鈉 0.1 0.1 0.1 0.1 0.1 0.1 曱基異噻唑啉酮 0.04 0.04 0.04 0.04 0.04 0.04 香料 0.5 0.5 0.5 0.5 0.5 0.5 水 加至100 加至100 加至100 加至100 加至100 加至100 該等產品在45°C下儲存12天仍係安定。 以下係製備調理組合物之方法。 將水加熱至約70°C。利用高速攪拌將聚合物（當存在 時）、脂肪醇、陰離子性界面活性劑（鯨蠟硬脂基硫酸鈉）添 加至水中。當獲得均勻分散液時，以相同的攪拌速度將此 混合物冷卻至約45°C。隨後，以中等攪拌速度將其餘組分 添加至其中。 -11 - 149057.doc 201105360Si(CH3)3-0-[Si(CH3)2-〇-]x-[Si(CH3)(R-NH-CH2CH2NH2)-〇-]y.Si(CH3)3 wherein x+y is about 50 A value between about 500, and wherein R is an alkylene group having 2 to 5 carbon atoms. χ+y is preferably between about 1 〇〇 and about 3 。. (iii) a quaternary polyoxyl polymer having the formula: {(R))(R2)2(R3)_2CH(0,2〇(Ch2)3_^ -(CH2)3-0-CH2CH(OH CH2N+(R8)(R9)(Ri〇)} (χ·)2 wherein R1 and R1g may be the same or different and may be independently selected from Η 'saturated or unsaturated long or short chain alkyl (alkenyl) groups, a branched alk(en)yl group and a C5-C8 ring system; R2 to R9 may be the same or different and may be independently selected from the group consisting of a fluorene, a straight or a branched lower alkane (alkenyl) group, and a fluorene 5-(: 8-ring system; η is a value between about 60 and about 120, preferably about go, and 149057.doc 201105360 χ - preferably acetate, but can be changed to, for example, halide, organic carboxylate 'organic sulfonate, etc. Such suitable quaternary polyoxo polymers are described in ΕΡ-Α-0 530 974. Amine-functional polyoxylamine amine g-energy moles suitable for use in the shampoos and conditioners of the present invention Usually from about 〇 to about 8 〇 mol%, preferably from about 1 to about 5.0 mol%, most preferably from about 〇.丨 to about 2 〇 mol%. Usually the amine concentration should not exceed about 8.0 mol% Because we have found that excessive amine concentrations are detrimental to total polyoxane deposition and are therefore disadvantageous For conditioning performance, the viscosity of the amine B flb t oxalate is not particularly critical and may suitably vary between about 1 Torr and about 500,000 cst. Specific examples of amine functional polyfluorene suitable for use in the present invention. Amino-based polyoxosulfan DC2-8220, DC2-8166, DC2-8466, and DC2-8950-114 (both ex Dow Corning), and GE 1149_75 (ex General Electric SiHc〇nes). Or an emulsion of an amine functional polyoxyxanic acid of a cationic surfactant is also suitable. The preformed emulsions suitably have less than 3 Å, preferably less than 20 microns, more preferably less than 1 in the shampoo composition. The average amino-functional polyfluorene particle size of 〇micron. We have again found that reducing the particle size generally improves the conditioning month b. The average amine functional poly-stone particle size in the bismuth composition is less than 2 microns. The ideal system (^(^ to 丨 micron.) The polyfluorene emulsion with an average particle size of 〇15 μm is usually called a microemulsion. The pre-formed emulsion of the amine-based poly-oxygen can also be self-polymerized. Oxygen oil suppliers such as Dow Corning and General Electric. Examples of the body include DC929 cationic emulsion, DC939 cationic emulsion, and nonionic emulsion 149057.doc 201105360 0€2-7224, 0〇2-8467, 002-8177 and 002-8154 (both are 0〇贸(:〇1^1) ^). An example of a quaternary polyoxynoxy polymer useful in the present invention is the material K3474, ex Goldschmidt °. The total amount of polyfluorene incorporated into the compositions of the present invention depends on the degree of conditioning desired and the materials used. Preferred amounts are from 0.01 to about 10 weight percent per gram of the total composition, although such limitations are not absolute. The lower limit is determined by the lowest concentration at which conditioning is achieved, and the upper limit is determined by the highest concentration that prevents unacceptable greasy hair and/or skin. It has been found that the total amount of polyfluorene oxide in an amount of from 0.3 to 5% by weight, preferably from 0.5 to 3% by weight, based on the total composition is a suitable concentration. [Embodiment] These examples will now be described with reference to the following non-limiting examples. Example 1 The following conditioning composition according to the invention: Ingredient 1 2 3 4 5 6 7 8 Sodium stearyl sulphate 1 1 1.5 1.5 1 1.5 1.5 1 Cetearyl alcohol 4 3 6 6 3 6 6 4 NATROSOL ® 250HHR(1) - 1.5 - - 1.5 - - - POLYSURF®67(2> - - 0.03 - - 0.03 - - ESAFLOR® HM22(2) - - - 0.4 - - 0.4 KeratecHSP (11.9% active) 33.6 33.6 33.6 33.6 33.6 33.6 33.6 33.6 Polyoxyl (60% active) - - - - 1.5 1.5 1.5 1.5 Glycine Soybean Oil 2 2 2 2 - - - - DMDM carbendazim and 3-iodo-2-propynyl butyl Amino decanoate (50% active) 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Disodium edetate 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Methylisothiazolinone 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 Fragrance 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Water added to add to add to add to add to 100 100 100 100 100 100 100 100 •10- 149057.doc 201105360 Composition 9 10 11 12 13 14 15 16 Whale Sodium stearyl sulfate 1 1 1.5 1.5 1 1.5 1.5 1 Cetearyl alcohol 4 3 6 6 3 6 6 4 NATROSOL® 250HHRU, - 1.5 - - 1.5 - - - POLYSURF® 67 (even - - 0.03 - - 0.03 - - ESAFLOR® HM22w - - - 0.4 - - 0.4 - KeratecHSP (11.9% active) 16.8 16.8 16.8 16.8 16.8 16.8 16.8 16.8 Polyoxyl (60% active) - - - - 1.5 1.5 1.5 1.5 Glycine Soybean oil 2 2 2 2 - - - - DMDM carbendazim and 3-iodo-2-propynylbutylamino phthalate (50% active) 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 Ethylenediaminetetraacetic acid Disodium 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 decyl isothiazolinone 0.04 0.04 0.04 0.04 0.04 0.04 0.04 0.04 Fragrance 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 0.5 Add to add to add to add to add to add to 100 100 100 100 100 100 100 100 Ingredients 17 18 19 20 21 22 Whale stearyl sulphate 1 1 1 1 1 1 Cetearyl alcohol 3 3 3 3 3 3 Keltrol RD 1.0 - - 1.0 - - Amaze XT - 1.0 - - 1.0 - Gantrez S 95 - - 0.5 - - 0.5 Polyoxyl (60% active) 1.5 1.5 1.5 1.5 1.5 1.5 KeratecHSP (11.9% active) 33.6 33.6 33.6 16.8 16.8 16.8 DMDM carbendazim and 3-iodine- 2-propynylbutylcarbamate (50% active) 0.1 0.1 0.1 0.1 0.1 0.1 Disodium edetate 0.1 0.1 0.1 0.1 0.1 0.1 Isoisothiazolinone 0.04 0.04 0.04 0.04 0.04 0.04 Perfume 0.5 0.5 0.5 0.5 0.5 0.5 Water added to 100 Add to 100 Add to 100 Add to 100 Add to 100 Add to 100 These products are stored at 45 ° C for 12 days. stable. The following is a method of preparing a conditioning composition. The water is heated to about 70 °C. The polymer (when present), fatty alcohol, anionic surfactant (sodium cetearyl sulphate) was added to the water using high speed agitation. When a homogeneous dispersion was obtained, the mixture was cooled to about 45 ° C at the same stirring speed. Subsequently, the remaining components were added thereto at a moderate stirring speed. -11 - 149057.doc 201105360
Keratec及所需天然油類可在單细士為 只J隹早期加熱水時（在添加脂肪 醇之前）或在後期（在將混合物冷卻至約45〇c 後）添加。 為獲得不同脂肪兩性分子之較佳混合物，可將該等不同 的脂肪物質在與該陰離子性界面活性劑一起添加至經加熱 之水中之前一起共熔。 149057.doc 12Keratec and the desired natural oils can be added when the single warp is J隹 early heating water (before adding the fatty alcohol) or later (after cooling the mixture to about 45〇c). To obtain a preferred mixture of different fatty amphiphilic molecules, the different fatty materials can be co-melted together with the anionic surfactant prior to addition to the heated water. 149057.doc 12