JP6739493B2 - Candelilla wax dispersion composition - Google Patents
Candelilla wax dispersion composition Download PDFInfo
- Publication number
- JP6739493B2 JP6739493B2 JP2018186936A JP2018186936A JP6739493B2 JP 6739493 B2 JP6739493 B2 JP 6739493B2 JP 2018186936 A JP2018186936 A JP 2018186936A JP 2018186936 A JP2018186936 A JP 2018186936A JP 6739493 B2 JP6739493 B2 JP 6739493B2
- Authority
- JP
- Japan
- Prior art keywords
- candelilla wax
- mass
- cetyl ether
- hair
- less
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 239000004204 candelilla wax Substances 0.000 title claims description 78
- 235000013868 candelilla wax Nutrition 0.000 title claims description 78
- 229940073532 candelilla wax Drugs 0.000 title claims description 78
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 title claims description 78
- 239000000203 mixture Substances 0.000 title claims description 69
- 239000006185 dispersion Substances 0.000 title claims description 30
- 239000003795 chemical substances by application Substances 0.000 claims description 53
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 claims description 41
- 238000011282 treatment Methods 0.000 claims description 39
- 239000002736 nonionic surfactant Substances 0.000 claims description 27
- -1 polyoxyethylene cetyl ether Polymers 0.000 claims description 27
- 239000002245 particle Substances 0.000 claims description 19
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 14
- 239000000194 fatty acid Substances 0.000 claims description 14
- 229930195729 fatty acid Natural products 0.000 claims description 14
- 150000004665 fatty acids Chemical class 0.000 claims description 13
- 238000013329 compounding Methods 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003945 anionic surfactant Substances 0.000 claims description 10
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 8
- 239000002280 amphoteric surfactant Substances 0.000 claims description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 7
- 150000005846 sugar alcohols Polymers 0.000 claims description 7
- 239000001993 wax Substances 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 238000010348 incorporation Methods 0.000 claims 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 19
- 239000002994 raw material Substances 0.000 description 12
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 9
- 239000003093 cationic surfactant Substances 0.000 description 9
- 238000002156 mixing Methods 0.000 description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 7
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 239000003755 preservative agent Substances 0.000 description 6
- 239000004094 surface-active agent Substances 0.000 description 6
- 150000001298 alcohols Chemical class 0.000 description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 5
- 230000002335 preservative effect Effects 0.000 description 5
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 4
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 4
- 239000007844 bleaching agent Substances 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 229940057995 liquid paraffin Drugs 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 239000002453 shampoo Substances 0.000 description 4
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 235000013871 bee wax Nutrition 0.000 description 3
- 239000012166 beeswax Substances 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- 229960000541 cetyl alcohol Drugs 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000004615 ingredient Substances 0.000 description 3
- 238000007561 laser diffraction method Methods 0.000 description 3
- 235000013336 milk Nutrition 0.000 description 3
- 210000004080 milk Anatomy 0.000 description 3
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 3
- 239000002304 perfume Substances 0.000 description 3
- 239000012071 phase Substances 0.000 description 3
- 238000002203 pretreatment Methods 0.000 description 3
- 238000000790 scattering method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- SZEMGTQCPRNXEG-UHFFFAOYSA-M trimethyl(octadecyl)azanium;bromide Chemical compound [Br-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C SZEMGTQCPRNXEG-UHFFFAOYSA-M 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- JPPRXACMNPYJNK-UHFFFAOYSA-N 1-docosoxydocosane Chemical compound CCCCCCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCCCCCC JPPRXACMNPYJNK-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- 229940058020 2-amino-2-methyl-1-propanol Drugs 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 2
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 2
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 2
- 241001553290 Euphorbia antisyphilitica Species 0.000 description 2
- 125000000217 alkyl group Chemical group 0.000 description 2
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 2
- 235000019270 ammonium chloride Nutrition 0.000 description 2
- 238000004364 calculation method Methods 0.000 description 2
- 125000004432 carbon atom Chemical group C* 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000003638 chemical reducing agent Substances 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 238000004945 emulsification Methods 0.000 description 2
- 239000010696 ester oil Substances 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000000118 hair dye Substances 0.000 description 2
- 230000007794 irritation Effects 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 239000004200 microcrystalline wax Substances 0.000 description 2
- 235000019808 microcrystalline wax Nutrition 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- HLERILKGMXJNBU-UHFFFAOYSA-N norvaline betaine Chemical compound CCCC(C([O-])=O)[N+](C)(C)C HLERILKGMXJNBU-UHFFFAOYSA-N 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 235000013772 propylene glycol Nutrition 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 239000000600 sorbitol Substances 0.000 description 2
- 235000010356 sorbitol Nutrition 0.000 description 2
- 229920001059 synthetic polymer Chemical class 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- AZUYLZMQTIKGSC-UHFFFAOYSA-N 1-[6-[4-(5-chloro-6-methyl-1H-indazol-4-yl)-5-methyl-3-(1-methylindazol-5-yl)pyrazol-1-yl]-2-azaspiro[3.3]heptan-2-yl]prop-2-en-1-one Chemical compound ClC=1C(=C2C=NNC2=CC=1C)C=1C(=NN(C=1C)C1CC2(CN(C2)C(C=C)=O)C1)C=1C=C2C=NN(C2=CC=1)C AZUYLZMQTIKGSC-UHFFFAOYSA-N 0.000 description 1
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 1
- KZVIUXKOLXVBPC-UHFFFAOYSA-N 16-methylheptadecanamide Chemical compound CC(C)CCCCCCCCCCCCCCC(N)=O KZVIUXKOLXVBPC-UHFFFAOYSA-N 0.000 description 1
- KIHBGTRZFAVZRV-UHFFFAOYSA-N 2-Hydroxyoctadecanoic acid Natural products CCCCCCCCCCCCCCCCC(O)C(O)=O KIHBGTRZFAVZRV-UHFFFAOYSA-N 0.000 description 1
- UOFCAQWHTQFNHS-UHFFFAOYSA-N 2-[2-[2-[2-[2-(2-hexadecoxyethoxy)ethoxy]ethoxy]ethoxy]ethoxy]ethanol Chemical compound CCCCCCCCCCCCCCCCOCCOCCOCCOCCOCCOCCO UOFCAQWHTQFNHS-UHFFFAOYSA-N 0.000 description 1
- TWJNQYPJQDRXPH-UHFFFAOYSA-N 2-cyanobenzohydrazide Chemical compound NNC(=O)C1=CC=CC=C1C#N TWJNQYPJQDRXPH-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 1
- BIVBRWYINDPWKA-VLQRKCJKSA-L Glycyrrhizinate dipotassium Chemical compound [K+].[K+].O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@H]1CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@](C)(CC[C@@]5(CC[C@@]4(C)[C@]3(C)CC[C@H]2C1(C)C)C)C(O)=O)C([O-])=O)[C@@H]1O[C@H](C([O-])=O)[C@@H](O)[C@H](O)[C@H]1O BIVBRWYINDPWKA-VLQRKCJKSA-L 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 235000018330 Macadamia integrifolia Nutrition 0.000 description 1
- 240000000912 Macadamia tetraphylla Species 0.000 description 1
- 235000003800 Macadamia tetraphylla Nutrition 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000004183 alkoxy alkyl group Chemical group 0.000 description 1
- 125000005211 alkyl trimethyl ammonium group Chemical group 0.000 description 1
- 229940024606 amino acid Drugs 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000008346 aqueous phase Substances 0.000 description 1
- BTFJIXJJCSYFAL-UHFFFAOYSA-N arachidyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCO BTFJIXJJCSYFAL-UHFFFAOYSA-N 0.000 description 1
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 1
- WMNULTDOANGXRT-UHFFFAOYSA-N bis(2-ethylhexyl) butanedioate Chemical compound CCCCC(CC)COC(=O)CCC(=O)OCC(CC)CCCC WMNULTDOANGXRT-UHFFFAOYSA-N 0.000 description 1
- SHZIWNPUGXLXDT-UHFFFAOYSA-N caproic acid ethyl ester Natural products CCCCCC(=O)OCC SHZIWNPUGXLXDT-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 229940082500 cetostearyl alcohol Drugs 0.000 description 1
- 238000012790 confirmation Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- ZCPCLAPUXMZUCD-UHFFFAOYSA-M dihexadecyl(dimethyl)azanium;chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCC ZCPCLAPUXMZUCD-UHFFFAOYSA-M 0.000 description 1
- REZZEXDLIUJMMS-UHFFFAOYSA-M dimethyldioctadecylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)CCCCCCCCCCCCCCCCCC REZZEXDLIUJMMS-UHFFFAOYSA-M 0.000 description 1
- 229940101029 dipotassium glycyrrhizinate Drugs 0.000 description 1
- 239000000982 direct dye Substances 0.000 description 1
- 239000004664 distearyldimethylammonium chloride (DHTDMAC) Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- QIVLQXGSQSFTIF-UHFFFAOYSA-M docosyl(trimethyl)azanium;methyl sulfate Chemical compound COS([O-])(=O)=O.CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C QIVLQXGSQSFTIF-UHFFFAOYSA-M 0.000 description 1
- 239000002552 dosage form Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000000499 gel Substances 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 230000037308 hair color Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- SFFVATKALSIZGN-UHFFFAOYSA-N hexadecan-7-ol Chemical compound CCCCCCCCCC(O)CCCCCC SFFVATKALSIZGN-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Chemical class 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 150000002484 inorganic compounds Chemical class 0.000 description 1
- 229910010272 inorganic material Inorganic materials 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- DVEKCXOJTLDBFE-UHFFFAOYSA-N n-dodecyl-n,n-dimethylglycinate Chemical compound CCCCCCCCCCCC[N+](C)(C)CC([O-])=O DVEKCXOJTLDBFE-UHFFFAOYSA-N 0.000 description 1
- 229920005615 natural polymer Chemical class 0.000 description 1
- 239000010466 nut oil Substances 0.000 description 1
- 239000007764 o/w emulsion Substances 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920001296 polysiloxane Chemical class 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000003380 propellant Substances 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 210000004761 scalp Anatomy 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229940073490 sodium glutamate Drugs 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000001587 sorbitan monostearate Substances 0.000 description 1
- 235000011076 sorbitan monostearate Nutrition 0.000 description 1
- 229940035048 sorbitan monostearate Drugs 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000011550 stock solution Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
-
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Description
本発明は、毛髪用処理剤の原料などとして用いられるキャンデリラロウ分散組成物に関するものである。 The present invention relates to a candelilla wax dispersion composition used as a raw material for a hair treatment agent.
キャンデリラロウは、整髪剤などの毛髪用処理剤の原料として使用されている。整髪剤においては、整髪成分としてキャンデリラロウが配合され、キャンデリラロウを分散させる界面活性剤としてノニオン界面活性剤と共に高級脂肪酸系アニオン界面活性剤を使用することが汎用的である(例えば、特許文献1の段落0014参照)。整髪性を高めるためにキャンデリラロウの配合量を増加させるときには、高級脂肪酸系アニオン界面活性剤の使用頻度が高まる。また、特許文献2には、POE(20)ベヘニルエーテル単独よりも、POE(20)ベヘニルエーテル及びラウリルジメチルアミノ酢酸ベタインの併用が、キャンデリラロウを分散させる界面活性剤として優れるとされている(段落0017)。 Candelilla wax is used as a raw material for hair treatment agents such as hair styling agents. In a hair styling agent, candelilla wax is blended as a hair styling ingredient, and it is general to use a higher fatty acid anionic surfactant together with a nonionic surfactant as a surfactant for dispersing the candelilla wax (for example, patents See paragraph 1 of document 1). When the amount of candelilla wax is increased to improve the hair styling property, the frequency of use of the higher fatty acid anionic surfactant increases. Further, in Patent Document 2, it is said that the combined use of POE(20) behenyl ether and betaine lauryl dimethylaminoacetate is superior as a surfactant for dispersing candelilla wax, rather than POE(20) behenyl ether alone ( Paragraph 0017).
キャンデリラロウを分散させる際に適した界面活性剤の提案があるのは、上記の通りである。界面活性剤の種類は、キャンデリラロウを配合した組成物の用途に応じても選定されるから、特定の界面活性剤の配合を制限した上で、ノニオン界面活性剤を使用してキャンデリラロウを分散させる提案も、望まれる場合がある。 It is as described above that there is a proposal of a surfactant suitable for dispersing candelilla wax. The type of surfactant is also selected depending on the application of the composition containing candelilla wax. Therefore, after limiting the compounding of a specific surfactant, the candelilla wax is used with a nonionic surfactant. Proposals to disperse may also be desirable.
本発明は、上記事情に鑑み、高級脂肪酸系アニオン界面活性剤を配合せず、アミドベタイン型両性界面活性剤を所定量以下にした上で、キャンデリラロウの分散性をノニオン界面活性剤を用いて高めた組成物の提供を目的とする。 In view of the above circumstances, the present invention does not blend a higher fatty acid-based anionic surfactant, sets the amidobetaine-type amphoteric surfactant to a predetermined amount or less, and uses the nonionic surfactant for the dispersibility of candelilla wax. The purpose of the present invention is to provide a composition having an improved composition.
本発明者等が鋭意検討を行った結果、所定のポリオキシエチレンセチルエーテル又はポリオキシエチレンポリオキシプロピレンセチルエーテルを使用すれば、キャンデリラロウの分散性が良い知見を得た。また、その分散性を高めるには、キャンデリラロウの配合量を調整して粘度を抑えるのが良い知見を得た。これらの知見に基づき、本発明を完成するに至った。 As a result of earnest studies by the present inventors, it was found that the dispersibility of candelilla wax was good when a predetermined polyoxyethylene cetyl ether or polyoxyethylene polyoxypropylene cetyl ether was used. Further, in order to improve the dispersibility, it was found that it is good to control the viscosity by adjusting the compounding amount of candelilla wax. The present invention has been completed based on these findings.
すなわち、本発明に係るキャンデリラロウ分散組成物は、キャンデリラロウ、ポリオキシエチレンセチルエーテル及びポリオキシエチレンポリオキシプロピレンセチルエーテルから選ばれた一種又は二種以上のセチルエーテル系ノニオン界面活性剤、並びに水が配合され、前記セチルエーテル系ノニオン界面活性剤のHLB値が11.0以上16.0以下であり、高級脂肪酸系アニオン界面活性剤が配合されず、アミドベタイン型両性界面活性剤が1.5質量%未満の配合量又は配合されず、粘度が20000mPa・sであることを特徴とする。 That is, the candelilla wax dispersion composition according to the present invention, candelilla wax, one or more cetyl ether nonionic surfactants selected from polyoxyethylene cetyl ether and polyoxyethylene polyoxypropylene cetyl ether, In addition, water is blended, the HLB value of the cetyl ether nonionic surfactant is 11.0 or more and 16.0 or less, the higher fatty acid anionic surfactant is not blended, and the amidobetaine type amphoteric surfactant is 1 The compounding amount is less than 0.5 mass% or is not compounded, and the viscosity is 20000 mPa·s.
前記キャンデリラロウの配合量(A)に対する前記セチルエーテル系ノニオン界面活性剤の配合量(B)の比(B)/(A)は、0.2以上が良い。この比率であると、キャンデリラロウの分散性に特に好適である。 The ratio (B)/(A) of the compounding amount (B) of the cetyl ether type nonionic surfactant to the compounding amount (A) of the candelilla wax is preferably 0.2 or more. This ratio is particularly suitable for the dispersibility of candelilla wax.
本発明に係るキャンデリラロウ分散組成物において、キャンデリラロウの体積平均粒子径は、500nm以下であると良い。その体積平均粒子径は、レーザー回折・散乱法による測定で求められる値である。 In the candelilla wax dispersion composition according to the present invention, the volume average particle diameter of the candelilla wax is preferably 500 nm or less. The volume average particle diameter is a value obtained by measurement by a laser diffraction/scattering method.
本発明に係るキャンデリラロウ分散組成物は、透明又は半透明のものであると良い。ここで、「半透明」とは、直径4cmの有底円筒状ガラス容器内のキャンデリラロウ分散組成物を正面から目視確認したときに、背景を確認可能である透明性をいう。 The candelilla wax dispersion composition according to the present invention is preferably transparent or translucent. Here, "semitransparent" refers to the transparency that allows the background to be confirmed when the candelilla wax dispersion composition in a bottomed cylindrical glass container having a diameter of 4 cm is visually confirmed from the front.
また、本発明に係るキャンデリラロウ分散組成物は、整髪剤などの毛髪用処理剤に配合する原料として用いると良い。キャンデリラロウの分散性が良い本発明に係る組成物を原料として用いることで、毛髪用処理剤におけるキャンデリラロウの分散性を良好にすることが容易となり、毛髪用処理剤に配合するキャンデリラロウの増量も容易となる。 Further, the candelilla wax dispersion composition according to the present invention is preferably used as a raw material to be blended with a hair treatment agent such as a hair styling agent. By using the composition according to the present invention having a good dispersibility of candelilla wax as a raw material, it becomes easy to improve the dispersibility of the candelilla wax in the hair treatment agent, and the candelilla compounded in the hair treatment agent is obtained. It is also easy to increase the amount of wax.
本発明に係るキャンデリラロウ分散組成物は、キャンデリラロウの配合量制限により粘度を抑え、所定のHLB値範囲のセチルエーテル系ノニオン界面活性剤によりキャンデリラロウを水中に分散させるので、高級脂肪酸系アニオン界面活性剤が配合されず、かつ、アミドベタイン型両性界面活性剤が1.5質量%未満の配合量であっても、キャンデリラロウの分散性が高いものとなる。 The candelilla wax dispersion composition according to the present invention suppresses viscosity by limiting the compounding amount of candelilla wax, and disperses candelilla wax in water with a cetyl ether-based nonionic surfactant having a predetermined HLB value range. Even if the anionic anionic surfactant is not blended and the amidobetaine-type amphoteric surfactant is blended in an amount of less than 1.5% by mass, the candelilla wax has high dispersibility.
本発明の実施形態に係るキャンデリラロウ分散組成物(以下、「本実施形態に係るキャンデリラロウ分散組成物」を「本組成物」と称することがある。)に基づき、本発明を以下に説明する。本組成物は、キャンデリラロウ、所定のセチルエーテル系ノニオン界面活性剤、及び水が配合されたものである(水の配合量は、例えば50質量%以上)。 The present invention is described below based on a candelilla wax dispersion composition according to an embodiment of the present invention (hereinafter, the “candelilla wax dispersion composition according to the present embodiment” may be referred to as the “present composition”). explain. The composition is a mixture of candelilla wax, a predetermined cetyl ether-based nonionic surfactant, and water (the content of water is, for example, 50% by mass or more).
なお、本組成物は、キャンデリラロウを分散させるために好適であると知られている高級脂肪酸系アニオン界面活性剤(高級脂肪酸塩、並びに/又は、高級脂肪酸及びこれを中和する水酸化ナトリウム、2−アミノ−2−メチル−1−プロパノールなどのアルカリによるもの)を配合せずとも同ロウを分散させるものなので、高級脂肪酸系アニオン界面活性剤を配合しないものとする。 The composition is a higher fatty acid-based anionic surfactant (higher fatty acid salt and/or higher fatty acid and sodium hydroxide that neutralizes the same) known to be suitable for dispersing candelilla wax. , 2-amino-2-methyl-1-propanol and the like) are used to disperse the same wax without adding any higher fatty acid type anionic surfactant.
(キャンデリラロウ)
本組成物には、キャンデリラロウを分散させる。キャンデリラロウの配合量は、配合するセチルエーテル系ノニオン界面活性剤の種類に応じて適宜設定すると良いが、3質量%以上30質量%以下が良く、5質量%以上25質量%以下が好ましく、10質量%以上20質量%以下がより好ましい。3質量%以上にすることで、本組成物の保管面積の拡張を防止でき、30質量%以下にすることで、キャンデリラロウの分散性及び本組成物のハンドリング性に不利な高粘度化を抑えることができる。
(Candelilla Row)
Candelilla wax is dispersed in the composition. The blending amount of candelilla wax may be appropriately set according to the type of cetyl ether type nonionic surfactant to be blended, but is preferably 3% by mass or more and 30% by mass or less, and preferably 5% by mass or more and 25% by mass or less, It is more preferably 10% by mass or more and 20% by mass or less. When the amount is 3% by mass or more, the storage area of the composition can be prevented from expanding, and when the amount is 30% by mass or less, it is possible to increase the viscosity which is disadvantageous to the dispersibility of the candelilla wax and the handling property of the composition. Can be suppressed.
本組成物におけるキャンデリラロウの体積平均粒子径は、500nm以下であると良く、300nm以下が好ましく、200nm以下がより好ましく、100nm以下が更に好ましく、50nm以下がより更に好ましい。この体積平均粒子径は、セチルエーテル系ノニオン界面活性剤の配合量を増やすことで500nm以下となり、当該粒子径範囲である共にキャンデリラロウの配合量を抑えることで、本組成物の外観を透明又は半透明にできる。なお、上記体積平均粒子径は、レーザー回折・散乱法により測定することで求められる。 The volume average particle diameter of candelilla wax in the present composition is preferably 500 nm or less, preferably 300 nm or less, more preferably 200 nm or less, still more preferably 100 nm or less, still more preferably 50 nm or less. This volume average particle diameter becomes 500 nm or less by increasing the blending amount of the cetyl ether type nonionic surfactant, and by suppressing the blending amount of candelilla wax within the particle diameter range, the appearance of the composition is transparent. Or it can be translucent. The volume average particle diameter is determined by measuring with a laser diffraction/scattering method.
(セチルエーテル系ノニオン界面活性剤)
本組成物には、キャンデリラロウを分散させるためにセチルエーテル系ノニオン界面活性剤が配合される。当該セチルエーテル系ノニオン界面活性剤は、ポリオキシエチレンセチルエーテル及びポリオキシエチレンポリオキシプロピレンセチルエーテルから選ばれた一種又は二種以上であり、所定のHLB値のものである(以下において、「ポリオキシエチレン」を「POE」と称することがあり、「ポリオキシエチレンポリオキシプロピレン」を「POE・POP」と称することがある)。
(Cetyl ether nonionic surfactant)
A cetyl ether type nonionic surfactant is added to the composition in order to disperse candelilla wax. The cetyl ether nonionic surfactant is one or more selected from polyoxyethylene cetyl ether and polyoxyethylene polyoxypropylene cetyl ether, and has a predetermined HLB value (hereinafter, referred to as "Oxyethylene" may be referred to as "POE", and "polyoxyethylene polyoxypropylene" may be referred to as "POE.POP").
本組成物に配合するPOEセチルエーテルとしては、例えば、POEセチルエーテル(6E.O.)、POEセチルエーテル(7E.O.)、POEセチルエーテル(10E.O.)、POEセチルエーテル(15E.O.)、POEセチルエーテル(20E.O.)が挙げられる(以下において、「E.O.」の前に記載した数値は、POEの平均付加モル数を表す。)。市販のPOEセチルエーテルとしては、日光ケミカル社製の「NIKKOL BC−5.5」、「NIKKOL BC−7」、「NIKKOL BC−10」、「NIKKOL BC−15」、「NIKKOL BC−20」などが挙げられる。 Examples of the POE cetyl ether blended in the present composition include POE cetyl ether (6 EO), POE cetyl ether (7 EO), POE cetyl ether (10 EO), POE cetyl ether (15 EO). O.) and POE cetyl ether (20E.O.) (in the following, the numerical value described before "EO" represents the average number of moles of POE added). Examples of commercially available POE cetyl ethers include "NIKKOL BC-5.5", "NIKKOL BC-7", "NIKKOL BC-10", "NIKKOL BC-15", and "NIKKOL BC-20" manufactured by Nikko Chemical Co., Ltd. Is mentioned.
本組成物に配合するPOE・POPセチルエーテルとしては、例えば、POE・POPセチルエーテル(10E.O.)(4P.O.)、POE・POPセチルエーテル(20E.O.)(4P.O.)、POE・POPセチルエーテル(20E.O.)(8P.O.)が挙げられる(以下において、「P.O.」の前に記載した数値は、POPの平均付加モル数を表す。)。市販のPOE・POPセチルエーテルとしては、日光ケミカル社製の「NIKKOL PBC−33」、「NIKKOL PBC−34」、「NIKKOL PBC−44」などが挙げられる。 Examples of the POE/POP cetyl ether blended in the present composition include POE/POP cetyl ether (10 EO) (4 PO), POE/POP cetyl ether (20 EO) (4 PO). ), and POE/POP cetyl ether (20EO) (8PO) (the numerical value described before "PO" below represents the average number of moles of POP added). .. Examples of commercially available POE/POP cetyl ethers include “NIKKOL PBC-33”, “NIKKOL PBC-34” and “NIKKOL PBC-44” manufactured by Nikko Chemical Co., Ltd.
本組成物に配合するセチルエーテル系ノニオン界面活性剤のHLB(Hydrophile―Lipophile Balance)値は、配合するセチルエーテル系ノニオン界面活性剤が一種である場合には、乳化試験により算出されるものである(算出方法の詳細は後記)。また、配合するセチルエーテル系ノニオン界面活性剤が二種以上である場合には、加重平均したHLB値をセチルエーテル系ノニオン界面活性剤のHLB値とする。 The HLB (Hydrophile-Lipophile Balance) value of the cetyl ether nonionic surfactant blended in the present composition is calculated by an emulsification test when the cetyl ether nonionic surfactant blended is one kind. (Details of the calculation method are given below). When two or more kinds of cetyl ether type nonionic surfactants are blended, the weighted average HLB value is taken as the HLB value of the cetyl ether type nonionic surfactant.
上記の乳化試験によるHLB値の算出は、次の通り行う。すなわち、(1)a質量部のセチルエーテル系ノニオン界面活性剤と、b質量部のソルビタンモノステアリン酸エステル(日光ケミカル社製「NIKKOLSS −10MV」、HLB値=4.7)を使用し、aとbを様々な比率とした下記組成、調製法で複数の乳化物を得る、(2)一日放置した後のこれら乳化物における油滴の粒径が最小となるaとbの比率に基づき、HLB値を「(10.5−4.7×b/4)4/a」により算出する。
乳化物の組成:
流動パラフィン(油相) 40質量%
乳化剤 a+b=4質量%
水 56質量%
乳化物の調製法:
流動パラフィンを80℃程度に加温して、攪拌しながら80℃以上の水相を加えて乳化する。その後、冷却しながら、攪拌を続けて40℃で放置する。
The calculation of the HLB value by the above emulsification test is performed as follows. That is, (1) a mass part of a cetyl ether type nonionic surfactant and b mass part of sorbitan monostearate (“NIKKOLSS-10MV” manufactured by Nikko Chemical Co., HLB value=4.7) are used, and A plurality of emulsions are obtained by the following composition and preparation method with various ratios of b and b. (2) Based on the ratio of a and b in which the particle size of oil droplets in these emulsions after being left for one day becomes the minimum , HLB value is calculated by “(10.5-4.7×b/4)4/a”.
Emulsion composition:
Liquid paraffin (oil phase) 40% by mass
Emulsifier a+b=4 mass%
Water 56 mass%
Emulsion preparation method:
Liquid paraffin is heated to about 80° C., and an aqueous phase at 80° C. or higher is added with stirring to emulsify. Then, while cooling, stirring is continued and left at 40°C.
本組成物におけるセチルエーテル系ノニオン界面活性剤の配合量は、キャンデリラロウに対する比率として設定すると良い。キャンデリラロウの配合量を(A)とし、セチルエーテル系ノニオン界面活性剤の配合量を(B)としたとき、比(B)/(A)は、0.2以上3.0以下が良く、0.4以上2.5以下が好ましく、0.6以上1.5以下がより好ましい。比(B)/(A)を0.2以上にすることで、キャンデリラロウの粒子径の小さな分散性及び低温放置した後の分散性に有利であり、3.0以下であっても、3.0を超える場合に比してキャンデリラロウの分散性が顕著に異ならない。 The compounding amount of the cetyl ether type nonionic surfactant in the present composition may be set as a ratio with respect to candelilla wax. When the blending amount of candelilla wax is (A) and the blending amount of cetyl ether type nonionic surfactant is (B), the ratio (B)/(A) is preferably 0.2 or more and 3.0 or less. , 0.4 or more and 2.5 or less are preferable, and 0.6 or more and 1.5 or less are more preferable. By setting the ratio (B)/(A) to 0.2 or more, it is advantageous for the dispersibility of the candelilla wax having a small particle size and the dispersibility after being left at low temperature, and even if it is 3.0 or less, The dispersibility of the candelilla wax is not significantly different from that when it exceeds 3.0.
(その他配合原料)
キャンデリラロウ及びセチルエーテル系ノニオン界面活性剤以外の原料を、本組成物に配合しても良い。
(Other ingredients)
Ingredients other than candelilla wax and cetyl ether-based nonionic surfactants may be added to the composition.
エチレングリコール、プロピレングリコール、グリセリン、1,3−ブチレングリコールなどの多価アルコール、又はソルビトールなどの糖アルコールを本組成物に配合すれば、低温下に置かれた後のキャンデリラロウの分散性が向上する。本組成物における多価アルコール及び糖アルコールの配合量は、例えば1質量%以上6質量%以下である。 When polyhydric alcohols such as ethylene glycol, propylene glycol, glycerin, and 1,3-butylene glycol, or sugar alcohols such as sorbitol are added to the composition, the dispersibility of candelilla wax after being placed at low temperature is improved. improves. The blending amount of the polyhydric alcohol and the sugar alcohol in the composition is, for example, 1% by mass or more and 6% by mass or less.
また、アミドベタイン型両性界面活性剤などの両性界面活性剤を配合しても良いが、配合量を1.5質量%未満又は未配合としても、キャンデリラロウの分散性を高くできる。 Further, an amphoteric surfactant such as an amidobetaine type amphoteric surfactant may be blended, but the dispersibility of candelilla wax can be increased even if the blending amount is less than 1.5% by mass or not blended.
(粘度)
本組成物の粘度は、キャンデリラロウの分散性及びハンドリング性の観点から、20000mPa・s以下が良く、10000mPa・s以下が好ましく、3000mPa・s以下がより好ましく、1000mPa・s以下が更により好ましい。ここで、本組成物の粘度は、B型粘度計において粘度に応じて選定したローターを使用して25℃で計測した60秒後の値を採用する。測定する際のローター回転速度は、12rpmであると良い。
(viscosity)
From the viewpoint of dispersibility and handling of candelilla wax, the viscosity of the present composition is preferably 20000 mPa·s or less, preferably 10,000 mPa·s or less, more preferably 3000 mPa·s or less, and even more preferably 1000 mPa·s or less. .. Here, as the viscosity of the present composition, a value after 60 seconds measured at 25° C. using a rotor selected according to the viscosity in a B-type viscometer is adopted. The rotor rotation speed at the time of measurement is preferably 12 rpm.
(用途)
本組成物を、毛髪用処理剤の原料などとして使用すると良い。この場合、毛髪用処理剤の原料として公知のものが、毛髪用処理剤の用途、目的に応じて適宜に選定される。
(Use)
The composition may be used as a raw material for a hair treatment agent. In this case, a known raw material for the hair treatment agent is appropriately selected depending on the use and purpose of the hair treatment agent.
毛髪用処理剤は、特に限定されず、整髪剤、ヘアケア剤、パーマ剤、カラーリング剤、ブリーチ剤等である。「整髪剤」とは、髪型を一時的に保持するために用いられる毛髪用処理剤である。「ヘアケア剤」とは、毛髪の手入れ、手当て等を行うために用いられる毛髪用処理剤である。ヘアケア剤としては、例えばシャンプー、リンス、コンディショナー、トリートメント(例えば、洗い流さないトリートメント、洗い流すトリートメント、整髪兼用トリートメント、多剤式トリートメントの一構成剤、パーマの前処理のためのトリートメント、パーマの後処理のためのトリートメント、カラーリングの前処理のためのトリートメント、カラーリングの後処理のためのトリートメント、ブリーチの前処理のためのトリートメント、ブリーチの後処理のためのトリートメント)が挙げられる。「パーマ剤」とは、還元反応、酸化反応等の化学反応を利用して毛髪形状を変化させるために用いられる毛髪用処理剤である。パーマ剤としては、例えば毛髪をウェーブ状に形成するためのウェーブ剤、ウェーブ状等の毛髪を直毛に近づけるためのストレート剤が挙げられ、1剤式パーマ剤、2剤式パーマ剤の還元剤が配合された第1剤及び2剤式パーマ剤の酸化剤が配合された第2剤のいずれも毛髪用処理剤に該当する。「カラーリング剤」とは、毛髪を着色するために用いられる毛髪用処理剤である。カラーリング剤としては、例えば直接染料が配合された染毛料、毛髪の染毛時に反応が必要になる反応型染料が配合された染毛剤、毛髪への着色を一時的に施す毛髪着色料が挙げられる。「ブリーチ剤」とは、毛髪の色素を脱色させるために用いられる毛髪用処理剤である。 The treatment agent for hair is not particularly limited, and examples thereof include a hair styling agent, a hair care agent, a perm agent, a coloring agent, and a bleaching agent. The "hairdressing agent" is a hair treatment agent used for temporarily holding the hairstyle. The "hair care agent" is a hair treatment agent used for caring for and treating the hair. Examples of hair care agents include shampoo, conditioner, conditioner, treatment (for example, non-rinse treatment, rinse-off treatment, combined hair treatment, one component of multi-drug treatment, treatment for pre-treatment of perm, post-treatment of perm. Treatment for pre-treatment of coloring, treatment for post-treatment of coloring, treatment for pre-treatment of bleach, treatment for post-treatment of bleach). The “perm agent” is a treatment agent for hair that is used to change the hair shape by utilizing a chemical reaction such as a reduction reaction or an oxidation reaction. Examples of the perm agent include a wave agent for forming hair in a wavy shape and a straightening agent for bringing the hair in a wavy shape close to straight hair. One-part type perm agent and a reducing agent for two-part type perm agent. Both the first agent in which is added and the second agent in which the oxidizing agent of the two-part type permanent agent is added correspond to the treatment agent for hair. The "coloring agent" is a treatment agent for hair used for coloring hair. As the coloring agent, for example, a hair dye containing a direct dye, a hair dye containing a reactive dye that requires a reaction when dyeing hair, and a hair coloring agent for temporarily coloring hair. Can be mentioned. The "bleaching agent" is a treatment agent for hair used for decolorizing hair pigment.
毛髪用処理剤の使用時の剤型は、特に限定されず、例えば液状、ローション状、クリーム状、ワックス状、ゲル状、フォーム状(泡状)、霧状が挙げられる。 The dosage form of the treatment agent for hair is not particularly limited, and examples thereof include liquid, lotion, cream, wax, gel, foam (foam) and mist.
本組成物と共に毛髪用処理剤に配合する原料は、アニオン界面活性剤、カチオン界面活性剤、両性界面活性剤、ノニオン界面活性剤、高級アルコール、低級アルコール、多価アルコール、糖類、油脂、エステル油、脂肪酸、炭化水素、ロウ、シリコーン、合成高分子化合物、半合成高分子化合物、天然高分子化合物、蛋白、アミノ酸、動植物抽出物、微生物由来物、無機化合物、香料、防腐剤、金属イオン封鎖剤、紫外線吸収剤、色素、還元剤、酸化剤、染料、顔料などである。 Raw materials to be added to the hair treatment agent together with this composition are anionic surfactants, cationic surfactants, amphoteric surfactants, nonionic surfactants, higher alcohols, lower alcohols, polyhydric alcohols, sugars, oils and fats, ester oils. , Fatty acids, hydrocarbons, waxes, silicones, synthetic polymer compounds, semi-synthetic polymer compounds, natural polymer compounds, proteins, amino acids, animal and plant extracts, microorganism-derived substances, inorganic compounds, fragrances, preservatives, sequestering agents , Ultraviolet absorbers, dyes, reducing agents, oxidizing agents, dyes, pigments and the like.
本組成物を配合する毛髪処理剤の一例としては、高級アルコール及びカチオン界面活性剤を配合したものが挙げられる。また、本組成物を使用すれば、高級アルコール及びカチオン界面活性剤の配合量が少ない整髪剤などの毛髪用処理剤(高級脂肪酸系アニオン界面活性剤を配合しないもの)においても、キャンデリラロウの分散と増量が容易となる。 As an example of the hair treatment agent to which the present composition is added, a higher alcohol and a cationic surfactant may be added. In addition, by using the present composition, even in a hair treating agent such as a hair styling agent containing a higher amount of a higher alcohol and a cationic surfactant (one in which a higher fatty acid-based anionic surfactant is not added), candelilla wax Dispersion and volume increase are easy.
上記高級アルコールは、炭素数数16以上22以下のものを用いると良く、当該高級アルコールとしては、例えば、セチルアルコール、ステアリルアルコール、アラキルアルコール、ベヘニルアルコールなどの直鎖状飽和アルコール;オレイルアルコールなどの直鎖状不飽和アルコール;ヘキシルデカノール、オクチルドデカノール、イソセチルアルコール、イソステアリルアルコールなどの分岐状飽和アルコール;が挙げられる。毛髪用処理剤における高級アルコールの配合量は、例えば0.1質量%以上10質量%以下である。カチオン界面活性剤の配合量が少ない整髪剤などにおいては、カチオン界面活性剤に対する高級アルコールの配合量を多くし過ぎると剤の粘度が低下するので、高級アルコールの配合量は、5質量%以下が良く、1質量%以下が好ましい。 The higher alcohol preferably has 16 or more and 22 or less carbon atoms, and examples of the higher alcohol include linear saturated alcohols such as cetyl alcohol, stearyl alcohol, aralkyl alcohol and behenyl alcohol; and oleyl alcohol. Linear unsaturated alcohols; branched saturated alcohols such as hexyldecanol, octyldodecanol, isocetyl alcohol, and isostearyl alcohol; The higher alcohol content in the hair treatment agent is, for example, 0.1% by mass or more and 10% by mass or less. In hair styling agents containing a small amount of the cationic surfactant, the viscosity of the agent decreases if the amount of the higher alcohol added to the cationic surfactant is too large. Therefore, the amount of the higher alcohol used should be 5% by mass or less. It is preferably 1% by mass or less.
上記カチオン界面活性剤としては、例えば、ジステアリルジメチルアンモニウムクロリド、ジセチルジメチルアンモニウムクロリド、ジココイルジメチルアンモニウムクロリド等のジ長鎖アルキルジメチルアンモニウム塩;ベヘニルトリメチルアンモニウムクロリド、ベヘニルトリメチルアンモニウムメトサルフェート、ステアリルトリメチルアンモニウムクロリド、ステアリルトリメチルアンモニウムブロミド、セチルトリメチルアンモニウムブロミド等のモノ長鎖アルキルトリメチルアンモニウム塩;ステアロキシプロピルトメチルアンモニウムクロリド等の長鎖アルコキシアルキルトリメチルアンモニウム塩;が挙げられる。ここでの「長鎖アルキル」とは、炭素数が8以上の直鎖状又は分枝状のアルキル基を意味し、その炭素数が16以上22以下であると皮膚への刺激の抑制や毛髪に付与する感触の観点から好ましい。毛髪用処理剤におけるカチオン界面活性剤の配合量は、例えば0.1質量%以上5質量%以下である。整髪剤などにおいてカチオン界面活性剤の配合量が多いと、頭皮に刺激を与える可能性があるので、カチオン界面活性剤の配合量は、3質量%以下が良く、1質量%以下が好ましい。 Examples of the cationic surfactant include dilong-chain alkyldimethylammonium salts such as distearyldimethylammonium chloride, dicetyldimethylammonium chloride and dicocoyldimethylammonium chloride; behenyltrimethylammonium chloride, behenyltrimethylammonium methosulfate, stearyltrimethyl. And mono long-chain alkyl trimethyl ammonium salts such as ammonium chloride, stearyl trimethyl ammonium bromide and cetyl trimethyl ammonium bromide; and long chain alkoxy alkyl trimethyl ammonium salts such as stearoxypropyltomethyl ammonium chloride. The term "long-chain alkyl" as used herein means a straight-chain or branched alkyl group having 8 or more carbon atoms, and when the carbon number is 16 or more and 22 or less, suppression of irritation to the skin and hair. It is preferable from the viewpoint of the feel to be imparted to. The content of the cationic surfactant in the hair treatment agent is, for example, 0.1% by mass or more and 5% by mass or less. When a large amount of the cationic surfactant is contained in the hair styling agent or the like, it may cause irritation to the scalp. Therefore, the amount of the cationic surfactant is preferably 3% by mass or less, and preferably 1% by mass or less.
以下、実施例に基づき本発明を詳述するが、この実施例の記載に基づいて本発明が限定的に解釈されるものではない。 Hereinafter, the present invention will be described in detail based on examples, but the present invention is not limitedly interpreted based on the description of the examples.
実施例、比較例、及び参考例のキャンデリラロウなどの分散組成物を製造し、粘度、平均粒子径(一部の組成物の粘度及び平均粒子径については、測定しなかった。)、外観を確認した。平均粒子径については、組成物における体積平均粒子径を、日機装社製の測定装置「Microtrac MT3000」を用いて、レーザー回折・散乱法により測定することで求めた。 Dispersion compositions such as candelilla wax of Examples, Comparative Examples, and Reference Examples were produced, and viscosity, average particle diameter (viscosity and average particle diameter of some compositions were not measured), appearance. It was confirmed. The average particle diameter was determined by measuring the volume average particle diameter in the composition by a laser diffraction/scattering method using a measuring device “Microtrac MT3000” manufactured by Nikkiso Co., Ltd.
(キャンデリラロウ分散組成物)
キャンデリラロウ分散組成物の詳細は、次の通りである。
キャンデリラロウ、マイクロクリスタリンワックス、ポリオキシエチレンセチルエーテル(6E.O.)、ポリオキシエチレンセチルエーテル(10E.O.)、ポリオキシエチレンセチルエーテル(15E.O.)、ポリオキシエチレンセチルエーテル(20E.O.)、ポリオキシエチレンラウリルエーテル(9E.O.)、ポリオキシエチレンラウリルエーテル(4E.O.)、ポリオキシエチレンベヘニルエーテル(10E.O.)、ポリオキシエチレンベヘニルエーテル(20E.O.)、ポリオキシエチレン硬化ヒマシ油(50E.O.)、ポリオキシエチレンポリオキシプロピレンセチルエーテル(20E.O.)(4P.O.)、ポリオキシエチレンポリオキシプロピレンセチルエーテル(20E.O.)(8P.O.)、プロピレングリコール、1,3−ブチレングリコール、グリセリン、及びソルビトールから選択した原料を使用した(原料の配合濃度は、下記表1〜4の通り。)。そして、原料を混合した80℃程度の油相に、当該油相を撹拌しながら、80℃程度の水を徐々に混合した。その後、自然冷却したものを実施例、比較例、及び参考例のキャンデリラロウなどの分散組成物として得た。
(Candelilla wax dispersion composition)
The details of the candelilla wax dispersion composition are as follows.
Candelilla wax, microcrystalline wax, polyoxyethylene cetyl ether (6 EO), polyoxyethylene cetyl ether (10 EO), polyoxyethylene cetyl ether (15 EO), polyoxyethylene cetyl ether ( 20 EO), polyoxyethylene lauryl ether (9 EO), polyoxyethylene lauryl ether (4 EO), polyoxyethylene behenyl ether (10 EO), polyoxyethylene behenyl ether (20 E.O.). O.), polyoxyethylene hydrogenated castor oil (50 EO), polyoxyethylene polyoxypropylene cetyl ether (20 EO) (4 PO), polyoxyethylene polyoxypropylene cetyl ether (20 EO). .) (8 PO), propylene glycol, 1,3-butylene glycol, glycerin, and sorbitol were used as raw materials (compounding concentrations of raw materials are shown in Tables 1 to 4 below). Then, water of about 80° C. was gradually mixed into the oil phase of about 80° C. in which the raw materials were mixed, while stirring the oil phase. Then, the mixture was naturally cooled to obtain a dispersion composition such as candelilla wax of Examples, Comparative Examples and Reference Examples.
下表1〜4に、組成物の調製に使用した原料及び配合濃度と共に、粘度、平均粒子径、外観の結果を示す。ここで、粘度の結果における「100以下」とは、測定可能な粘度下限以下であることを意味し、平均粒子径の結果における「50以下」とは、測定装置で表示される体積平均粒子径の下限値以下であることを意味する。また、外観の結果は目視確認した結果であり、「×」は析出又は分離が認められ、キャンデリラロウが十分に分散していなかったことを表す。 Tables 1 to 4 below show the results of viscosity, average particle size, and appearance, as well as the raw materials used for preparing the composition and the compounding concentration. Here, "100 or less" in the result of the viscosity means that it is at or below the measurable lower limit of viscosity, and "50 or less" in the result of the average particle size means the volume average particle size displayed by the measuring device. Is less than or equal to the lower limit value of. The appearance results are the results of visual confirmation, and "x" indicates that precipitation or separation was observed and the candelilla wax was not sufficiently dispersed.
上記表1においては、(1)実施例1a〜1dと比較例1a〜1bの対比により、HLB値が11.0以上16.0以下であれば、キャンデリラロウの分散性が良い傾向があること、(2)実施例1dと比較例1cの粘度及び平均粒子径の対比により、粘度が20000mPa・s以上になるほどにキャンデリラロウの配合量を増やした比較例1cは、平均粒子径が大きく、キャンデリラロウの分散性が良くないこと、(3)HLB値が11.0以上16.0以下である実施例1a〜1dと比較例1d〜1fの外観等の対比により、セチルエーテル系ノニオン界面活性剤の配合が、キャンデリラロウの分散性が良い傾向があること、を確認できる。 In Table 1 above, by comparison between (1) Examples 1a to 1d and Comparative Examples 1a to 1b, if the HLB value is 11.0 or more and 16.0 or less, the dispersibility of the candelilla wax tends to be good. (2) By comparing the viscosity and the average particle size of Example 1d and Comparative Example 1c, Comparative Example 1c in which the compounding amount of candelilla wax was increased so that the viscosity became 20000 mPa·s or more had a large average particle size. By comparing the appearances of Examples 1a to 1d having an HLB value of 11.0 or more and 16.0 or less and Comparative Examples 1d to 1f with poor dispersibility of candelilla wax, the cetyl ether type nonion is obtained. It can be confirmed that the blending of the surfactant tends to have good dispersibility of the candelilla wax.
上記表2においては、HLB値が11.0以上16.0以下のセチルエーテル系ノニオン界面活性剤を使用した実施例2a〜2cでは、キャンデリラロウの分散性が実施例1a等と同様であったことを確認できる。 In Table 2 above, in Examples 2a to 2c using the cetyl ether-based nonionic surfactant having an HLB value of 11.0 or more and 16.0 or less, the dispersibility of candelilla wax was the same as that of Example 1a or the like. I can confirm that.
上記表3において、(B)/(A)を0.2以上にすると、粘度低下、平均粒子径の微細化、乳化状態の透明化傾向を確認できるから、キャンデリラロウの分散性が向上することが分かる。なお、実施例3dに防腐剤を適量添加したものを整髪剤として用いたところ、整髪力が良く、整髪後の髪型を長時間維持できたことが確認されている。 In Table 3 above, if (B)/(A) is 0.2 or more, the viscosity decrease, the average particle size becoming finer, and the tendency of the emulsified state to become transparent can be confirmed, so that the dispersibility of the candelilla wax is improved. I understand. In addition, it was confirmed that when the hairdressing agent prepared by adding an appropriate amount of the preservative to Example 3d was used, the hairdressing ability was good and the hairstyle after hairdressing could be maintained for a long time.
下記原料、配合量のクリーム状O/W型乳化物を整髪剤として3種類製造した。この製造においては、キャンデリラロウ分散組成物を最後に配合した。製造した整髪剤は、キャンデリラロウを2〜4質量%含むものであるが、キャンデリラロウの分散性が安定していた。
セトステアリルアルコール 3質量%
4級アンモニウム塩 1.5質量%
イソプロピルアルコール 0.2質量%
1,3−ブチレングリコール 0.1質量%
固形エステル油 2質量%
グリセリン 5質量%
デカメチルシクロペンタシロキサン 10質量%
キャンデリラロウ分散組成物 20質量%、30質量%、又は40質量%
(キャンデリラロウ分散組成物:実施例3aと同じ)
Three types of cream-like O/W emulsions having the following raw materials and blending amounts were manufactured as hair styling agents. In this manufacture, the candelilla wax dispersion composition was the last compounded. The prepared hair styling agent contained 2 to 4 mass% of candelilla wax, but the dispersibility of the candelilla wax was stable.
Cetostearyl alcohol 3 mass%
Quaternary ammonium salt 1.5% by mass
Isopropyl alcohol 0.2% by mass
1,3-butylene glycol 0.1% by mass
Solid ester oil 2% by mass
Glycerin 5% by mass
Decamethylcyclopentasiloxane 10 mass%
Candelilla wax dispersion composition 20% by mass, 30% by mass, or 40% by mass
(Candelilla wax dispersion composition: same as in Example 3a)
上記キャンデリラロウ分散組成物を配合する毛髪用処理剤の例として、シャンプー、洗い流すトリートメント、フォーム状整髪剤、整髪用ヘアワックス、整髪用ヘアミルクを以下に示す。 Examples of hair treatment agents containing the above candelilla wax dispersion composition include shampoos, washing treatments, foam-type hair styling agents, hair styling hair waxes, and hair styling hair milks.
シャンプーの配合組成例は、以下の通りである。
1.N−ヤシ油脂肪酸アシル−L−グルタミン酸ナトリウム 6質量%
2.ポリオキシエチレンラウリルエーテル酢酸ナトリウム 4質量%
3.ポリオキシエチレンラウリルエーテル硫酸ナトリウム 3質量%
4.イソステアラミドプロピルベタイン 3質量%
5.ヤシ油脂肪酸アミドプロピルベタイン液 2質量%
6.ヤシ油脂肪酸N−メチルエタノールアミド 1質量%
7.塩化O−[2−ヒドロキシ−3−(トリメチルアンモニオ)プロピル]ヒドロキシエチルセルロース 0.5質量%
8.キャンデリラロウ分散組成物 0.5質量%
9.グリチルリチン酸ジカリウム 0.01質量%
10.クエン酸 適量
11.クエン酸ナトリウム 適量
12.防腐剤 適量
13.香料 適量
14.水 全量が100質量%となる量
An example of the composition of shampoo is as follows.
1. N-Palm oil fatty acid acyl-L-sodium glutamate 6% by mass
2. Sodium polyoxyethylene lauryl ether acetate 4% by mass
3. Polyoxyethylene lauryl ether sodium sulfate 3% by mass
4. Isostearamid propyl betaine 3% by mass
5. Coconut oil fatty acid amide propyl betaine solution 2% by mass
6. Coconut oil fatty acid N-methylethanolamide 1% by mass
7. O-[2-hydroxy-3-(trimethylammonio)propyl]hydroxyethyl cellulose chloride 0.5% by mass
8. Candelilla wax dispersion composition 0.5% by mass
9. Dipotassium glycyrrhizinate 0.01% by mass
10. Citric acid proper amount 11. Sodium citrate suitable amount 12. Preservative appropriate amount 13. Perfume proper amount 14. The amount that makes the total amount of water 100% by mass
上記シャンプーを製造するには、上記1〜6及び13の一部を80℃まで加熱して溶解させたものと、14の一部及び7を80℃に加熱して溶解させたものとを混合し、30℃まで冷却した後に、8〜12を添加すると良い。 In order to produce the shampoo, a part of the above 1 to 6 and 13 is heated to 80° C. and dissolved, and a part of 14 and 7 is heated to 80° C. and dissolved. Then, after cooling to 30° C., 8 to 12 may be added.
洗い流すトリートメントの配合組成例は、以下の通りである。
1.臭化ステアリルトリメチルアンモニウム 2質量%
2.塩化ステアリルトリメチルアンモニウム 1質量%
3.セタノール 3質量%
4.ステアリルアルコール 2質量%
5.マカデミアナッツ油 3質量%
6.流動パラフィン 2質量%
7.アミノエチルアミノプロピルメチルシロキサン・ジメチルシロキサン共重合体 1質量%
8.ジメチルポリシロキサン 1質量%
9.キャンデリラロウ分散組成物 5質量%
10.フェノキシエタノール 0.3質量%
11.乳酸 適量
12.香料 適量
13.水 全量が100質量%となる量
An example of the composition of the washing treatment is as follows.
1. Stearyl trimethyl ammonium bromide 2% by mass
2. Stearyl trimethyl ammonium chloride 1 mass%
3. Cetanol 3% by mass
4. Stearyl alcohol 2 mass%
5. Macadamia nut oil 3% by mass
6. Liquid paraffin 2% by mass
7. Aminoethylaminopropylmethylsiloxane/dimethylsiloxane copolymer 1% by mass
8. Dimethyl polysiloxane 1 mass%
9. Candelilla wax dispersion composition 5% by mass
10. Phenoxyethanol 0.3 mass%
11. Lactic acid 12. Perfume proper amount 13. The amount that makes the total amount of water 100% by mass
上記洗い流すトリートメントを製造するには、上記1〜6を80℃まで加熱して溶解させたものを、80℃まで加熱した13に混合して乳化させ、30℃まで冷却した後に、7〜12を添加すると良い。 In order to produce the washing treatment to be washed out, the above 1 to 6 are heated to 80° C. and dissolved, mixed with 13 heated to 80° C. to emulsify, and cooled to 30° C., then 7 to 12 are added. Good to add.
フォーム状整髪剤の原液の配合組成例は、以下の通りである。
1.ミリスチン酸 3質量%
2.ミツロウ 2質量%
3.PEG−40(平均分子量200) 1.2質量%
4.プロピレングリコール 1質量%
5.ポリオキシエチレン硬化ヒマシ油(80E.O) 1質量%
6.ポリオキシエチレンセチルエーテル(15E.O) 1質量%
7.ミリスチルアルコール 1質量%
8.エチルヘキサン酸アルキル(C14−18) 1質量%
9.2−アミノ−2−メチル−1−プロパノール 0.8質量%
10.キャンデリラロウ分散組成物 5質量%
11.防腐剤 適量
12.香料 適量
13.水 全量が100質量%となる量
An example of the composition of the undiluted solution of the foam-type hair styling agent is as follows.
1. Myristic acid 3% by mass
2. Beeswax 2% by mass
3. PEG-40 (average molecular weight 200) 1.2 mass%
4. Propylene glycol 1 mass%
5. Polyoxyethylene hydrogenated castor oil (80EO) 1% by mass
6. Polyoxyethylene cetyl ether (15EO) 1 mass%
7. Myristyl alcohol 1% by mass
8. Alkyl ethylhexanoate (C14-18) 1% by mass
9.2-Amino-2-methyl-1-propanol 0.8% by mass
10. Candelilla wax dispersion composition 5% by mass
11. Preservative proper amount 12. Perfume proper amount 13. Water amount that makes 100 mass%
上記フォーム状整髪剤の原液を製造するには、上記1〜8を80℃まで加熱して溶解させたものを、80℃まで加熱して混合した9及び13に添加して乳化させ、35℃まで冷却した後に、10〜12を添加すると良い。フォーム状整髪剤は、原液:噴射剤(LPG)の質量比を90:10として容器に充填して製造すると良く、この場合の25℃における容器からの噴射圧は、例えば0.3MPa程度であると良い。 In order to produce a stock solution of the foam-like hair styling agent, the above-mentioned 1 to 8 are heated to 80° C. and dissolved, and the mixture is heated to 80° C. and mixed into 9 and 13 to be emulsified, and then 35° C. It is advisable to add 10 to 12 after cooling to. The foam-shaped hair styling agent may be produced by filling the container with a mass ratio of undiluted solution: propellant (LPG) of 90:10. In this case, the injection pressure from the container at 25° C. is, for example, about 0.3 MPa. And good.
整髪用ヘアワックスの配合組成例は、以下の通りである。
1.ステアリン酸 4質量%
2.ヒドロキシステアリン酸 1質量%
3.ミツロウ 2質量%
4.マイクロクリスタリンワックス 2質量%
5.流動パラフィン 8質量%
6.コハク酸ジ2−エチルヘキシル 2質量%
7.ポリオキシエチレンセチルエーテル(5.5E.O) 1質量%
8.ポリオキシエチレンセチルエーテル(10E.O) 4質量%
9.1.3−ブチレングリコール 3質量%
10.アクリル樹脂アルカノールアミン液 2質量%
11.カルボキシビニルポリマー 0.1質量%
12.キャンデリラロウ分散組成物 5質量%
13.水酸化ナトリウム 0.35質量%
14.防腐剤 適量
15.香料 適量
16.水 合計100質量%となる量
An example of the composition of the hair wax for styling is as follows.
1. Stearic acid 4% by mass
2. Hydroxystearic acid 1% by mass
3. Beeswax 2% by mass
4. Microcrystalline wax 2% by mass
5. Liquid paraffin 8% by mass
6. Di-2-ethylhexyl succinate 2% by mass
7. Polyoxyethylene cetyl ether (5.5EO) 1% by mass
8. Polyoxyethylene cetyl ether (10 EO) 4% by mass
9.1-Butylene glycol 3 mass%
10. Acrylic resin alkanolamine liquid 2% by mass
11. Carboxyvinyl polymer 0.1% by mass
12. Candelilla wax dispersion composition 5% by mass
13. Sodium hydroxide 0.35% by mass
14. Preservative appropriate amount 15. Fragrance appropriate amount 16. Water amount that makes up 100% by mass in total
上記整髪用ヘアワックスを製造するには、上記1〜8を80℃まで加熱して溶解させる。これとは別に、10及び11を16に添加してから80℃まで加熱し、13を加える。この13を加えたものに、上記1〜8を溶解させたものを添加して乳化させ、35℃まで冷却した後に、12、14及び15を添加すると良い。 In order to produce the above hair styling product, the above items 1 to 8 are heated to 80° C. and dissolved. Separately, 10 and 11 are added to 16, then heated to 80° C. and 13 is added. It is advisable to add the above 13 to the one obtained by dissolving the above 1 to 8 to emulsify, cool to 35° C., and then add 12, 14 and 15.
整髪用ヘアミルクの配合組成例は、以下の通りである。
1.デカメチルシクロペンタシロキサン 5質量%
2.ミツロウ 1質量%
3.ステアリルアルコール 1.5質量%
4.セタノール 1質量%
5.ジメチルポリシロキサン 1質量%
6.臭化ステアリルトリメチルアンモニウム 1質量%
7.キャンデリラロウ分散組成物 5質量%
8.防腐剤 適量
9.香料 適量
10.水 合計100質量%となる量
An example of the composition of the hair milk for styling is as follows.
1. Decamethylcyclopentasiloxane 5 mass%
2. Beeswax 1% by mass
3. Stearyl alcohol 1.5% by mass
4. Cetanol 1% by mass
5. Dimethylpolysiloxane 1% by mass
6. Stearyl trimethyl ammonium bromide 1% by mass
7. Candelilla wax dispersion composition 5% by mass
8. Preservative proper amount 9. Fragrance proper amount 10. Water amount which becomes 100 mass% in total
上記整髪用ヘアミルクを製造するには、上記1〜6を80℃まで加熱して溶解させたものを、80℃まで加熱した10に混合して乳化させ、35℃まで冷却した後に、7〜9を添加すると良い。
In order to produce the hair milk for hairdressing described above, what is prepared by heating and dissolving 1 to 6 above at 80° C. is mixed with 10 heated to 80° C. to be emulsified and cooled to 35° C., and then 7 to 9 Should be added.
Claims (6)
前記セチルエーテル系ノニオン界面活性剤のHLB値が11.0以上16.0以下であり、
前記セチルエーテル系ノニオン界面活性剤として、ポリオキシエチレンセチルエーテル、又は、ポリオキシエチレンセチルエーテル及びポリオキシエチレンポリオキシプロピレンセチルエーテルが配合され、
高級脂肪酸系アニオン界面活性剤が配合されず、
アミドベタイン型両性界面活性剤が1.5質量%未満の配合量又は配合されず、
粘度が20000mPa・s以下であることを特徴とする
キャンデリラロウ分散組成物。 Candelilla wax, polyoxyethylene cetyl ether and polyoxyethylene polyoxypropylene cetyl ether selected from one or two or more cetyl ether nonionic surfactants, polyhydric alcohols or sugar alcohols, and water are blended,
The HLB value of the cetyl ether type nonionic surfactant is 11.0 or more and 16.0 or less,
As the cetyl ether-based nonionic surfactant, polyoxyethylene cetyl ether, or polyoxyethylene cetyl ether and polyoxyethylene polyoxypropylene cetyl ether are blended,
No higher fatty acid-based anionic surfactant is added,
Amidobetaine-type amphoteric surfactant is blended in an amount of less than 1.5% by mass or not blended ,
A candelilla wax dispersion composition having a viscosity of 20000 mPa·s or less.
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