TW201032832A - Surface-treated powder and cosmetic incorporated with the same - Google Patents

Abstract

This invention provides a surfacetreating powder having excellent utility and adhesion property to skin. The powder is coated by a surface treating agent including a fluorine-containing copolymer of (a) a fluorine-containing monomer represented by formula (I) and (b) a monomer containing alkoxy group represented by formula (II). The powder is used in various cosmetics. [Formula 1] CH2=C(-X)-C(=O)-Y-[-(CH2)m-Z-]p-(CH2)n-Rf (I) [Formula 2] CH2=C(X1)-C(=O)-O-(RO)q-X2 (II)

Description

201032832 ^103/pu VI. Description of the Invention: [Technical Field] The present invention relates to a surface-treated powder, and more particularly to a powder particle comprising at least a fluorinated copolymer comprising at least a fluorene-containing fluorene copolymer The surface-treated powder coated with the compound, and the cosmetic containing the surface-treated powder. The surface-treated powder of the present invention is excellent in usability, adhesion to skin, and excellent in affinity with other components to be blended in a cosmetic preparation. The cosmetic material to be blended with such a surface-treated powder is excellent in the feeling of use, the effect of makeup, and the persistence of makeup, and is excellent in quality stability and safety against living organisms and the environment. Further, the surface-treated powder of the present invention is preferably used as a surface-treated powder for cosmetics, but it can be applied not only to cosmetics but also to ink, paint, resin master batch (resin master batch). Paper powder (10) e shouts ((10) ❿ material], magnetic materials, rare earth (rare earth), optical materials, conductive materials, and other fields. [Prior Art] Previously, a fluorine-containing compound-treated powder used in cosmetics disclosed a surface-treated powder using perfluoroalkyl phosphate and perfluoroalkyl decane. Patent Publication No. 62-250074 and Japanese Patent Bulletin No. 2-218603). Although these powders have water-repellent oil and have resistance to sweat and sebum secreted from the skin, they have a poor affinity with the raw material for the raw material, and there is considerable enthalpy in formulation. Pile 201032832

mJ Λ. V/«/ I is not sufficient in terms of feeling of use or adhesion to the skin. In addition, in a system in which air and sebum which are oily sebum can be repelled (in an environment where sweat is easy to sweat in summer), the oil repellency (peeling resistance) of the treated powders is weakened, and the makeup continues. There are problems with sex. The surface-treated powder which solves this problem reveals: _acid perfluoroalkyl group s surface treatment with fluorinated copolymer of polyaluminum methacrylate and polyalkylene glycol acrylate Powder (Japanese Patent Laid-Open Publication No. 2_8_5〇62〇). However, if the leader of the molecule is gathered into a Wei chain, the disadvantages of reduced oiliness are reduced. Further, in the publication of Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. An oil-based alkyl group having a carbon number of 6 or less and a methyl group of 10% (hydfC) xyethyl methawylate (mMA) B are shown in the oil-repellent property of 2000-290640. In recent years, the industry believes that a compound containing a fluoroalkyl group having a carbon number of 8 or more has a burden on the environment by using a chemical decomposition product of the decomposition domain, which is a product of the fluorinated iirfuorooctanoie acid (PFOA). obvious. In view of this, the fluoroalkylation compound 2 used for the powder treatment is such that the number of hours is a compound of a small group of 6 lysines instead of a gas-containing compound containing a charcoal 1 and a ratio of 8 to 8. For example, a gas-containing copolymer having a fluorine-containing group having a carbon content of 6 and having excellent water-repellency and oil-repellent properties is disclosed (Japanese Laid-Open Patent Publication No. 2007-238690). For the purpose of water and oil repellency, there are disclosed: a graft copolymer having a gas bond in the molecule 201032832 MOJ/pu segment and a hydrophilic segment. In addition, it is also known that it has solubility in water and is excellent in water resistance, flexibility, and film strength (WO 95 Α _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ However, the fluorine-treated powder which has been shown to have water repellency and oil repellency has a problem that the solubility, emulsifying property, and dispersibility of the raw material for other cosmetic materials are inferior, and the variation in formulation is small. In addition, the conventional fluorine-containing compound-treated powder has excellent water-repellent property and good usability, and has excellent adhesion to the skin, and is excellent in usability when used for cosmetics, and has both a makeup finish effect and a makeup durability. In addition, it is not sufficient, and a fluorine-containing compound-treated powder having a fluoroalkyl group having a carbon number of 6 or less which is safe for living organisms and the environment has not been considered. Further, there is no fluorine-containing compound-treated powder having a fluorine-containing group having a carbon number of 6 or less which is excellent in affinity with other components to be blended in the cosmetic preparation. Therefore, the industry is striving for an excellent affinity with other components to be blended in a cosmetic preparation, and is excellent in oil repellency and useability in a cosmetic, and has both a makeup finish effect and a makeup continuity. And environmentally safe surface treatment powder. SUMMARY OF THE INVENTION An object of the present invention is to provide a fluorochemical-treated powder excellent in usability and adhesion to skin, and to provide a cosmetic compound to be combined with the surface-treated powder of the present invention, the use of the cosmetic Sense, make-up finish, make-up persistence, quality stability, and excellent safety to living organisms and the environment. 201032832 In order to solve the above problems, I have made painstaking research, and I have a compound containing a specific fluorinated copolymer = miscellaneous: =. The above specific fluorine-containing total == a) the fluorine-containing monomer represented by the following formula (1) and (8) lower =. (1) Silk (4) The silk-containing single substance is copolymerized to obtain (1) that is, the present invention can provide a surface-treated powder, and the surface of the powder particle to be surface-treated, The above-mentioned surface treatment agent is a gas-containing copolymer obtained by copolymerizing a monomer which must contain u) a monomer having the following general formula (1), a cadaver, and (8) an alkoxy group-containing monomer represented by the following formula (5); Substance: '[1], CH2=C(.X)-C(=〇)-Y-[-(CH2)mZ-]p.(CH2)n-Rf (I) [wherein X is hydrogen An atom, a methyl group, a fluorine atom, a chlorine atom, a bromine atom, a dish atom, a CFX1X2 group (wherein 'XI and a hydrogen atom, a fluorine atom or a chlorine atom), a cyano group, a linear chain having a carbon number of 1 to 20 or Branched fluoroalkyl, substituted or unsubstituted indolyl, substituted or unsubstituted phenyl; Y is -〇- or -NH-; Z is a direct bond, -S- or -so2- ;

Rf is a fluoroalkyl group having a carbon number of 1 to 6; m is 1 to 10, η is 〇~1〇, p is 〇 or η [Chemical 2] CH2==C(X1)-C(=0)-〇 ~(R〇)q-X2 (II) [wherein X1 is a hydrogen atom or a methyl group; 201032832 31637pif χ2 is a hydrogen atom or an unsaturated or saturated hydrocarbon group having a carbon number of 1 to 22; R is a part of a hydrogen atom or All of the alkyl groups having a carbon number of 2 to 4 which may be substituted by a radical; q is an integer of 1 to 50]. Preferred examples of the surface-treated powder of the present invention include the following. (2) The surface-treated powder according to (1), wherein, in the above formula (work), X2 is a hydrogen atom. (3) The surface-treated powder according to (1) or (2), wherein the surface-treated powder has water repellency. (4) The surface-treated powder according to (1) or (2), wherein the surface-treated powder has hydrophilic water repellency. (5) The surface-treated powder according to any one of (1) to (4), wherein the fluorinated copolymer comprises a crosslinkable single product represented by the following formula (guar) Coating of the fluorinated copolymer of the body: [Chemical 3] CH2=C(X3)-C(=〇)-〇-(R1 〇)qC(=0)-C(X3)=CH2 (III) Each of χ3 is a hydrogen atom or a fluorenyl group; R1 is a group in which a part or all of a hydrogen atom may be substituted with a carbon number of 2 to 1 (); q is an integer of i to 50]. (6) The surface-treated powder according to any one of (1) to (5) wherein the fluorocopolymer has a weight average molecular weight of from about 诵1 to about 1,000,000. (7) The surface-treated powder according to any one of (1) to (6) wherein, in the fluorinated copolymer, the fluorine-containing monomer (a) is a part by weight, and 201032832 J /pu contains an alkoxy group. The monomer (b) is from 10 parts by weight to 400 parts by weight. (8) The surface-treated powder according to any one of (1) to (7), wherein the coating amount of the II-containing copolymer is 〇 with respect to 1 part by weight of the powder to be surface-treated. 〇 1 part by weight to 4 parts by weight. (9) The surface-treated powder according to any one of claims 1 to 8, wherein the surface treatment agent further comprises one or more compounds selected from the group consisting of the following compound groups,

The above compound group: other fluorine-containing compounds other than the above-mentioned fluorine-containing copolymer, organic polyoxane, alkyl decane, polyether modified decane, organic bismuth citrate, olefinic acid, hydrogenated lecithin (containing hydrogenated egg cans in salt form), aromatized amino acids (thiolated amino acids in the form of salts or compositions), acidic ester oils, fatty acids (including fatty acids in the form of salts), And dextrin fatty acid vinegar. The surface-treated powder according to the item (9), wherein the fluorine-containing compound is a perfluoroalkyl phosphate having a carbon number of 6 or less, a perfluoroalkyl decane, a perfluoropolyether phosphate, and a perfluoro group. At least one of polyether decane. The surface-treated powder according to any one of (1) to (1), which is a part by weight of the powder to be surface-treated, and is 0.01 parts by weight to 39. 99 parts by weight of the above gas-containing copolymer and 39.99 parts by weight to 1 part by weight of one or more compounds selected from the group of the above compounds are coated. The surface-treated powder according to any one of (1) to (11), wherein the powder to be surface-treated is powder which can be used for cosmetics 9 201032832 3103/pit (13) as in (12) The surface-treated powder described above, the powder of the cosmetic material is an inorganic powder which can be secreted (4). (14) The surface-treated powder according to (13), 苴中=mica (1), mica-), kaolin: medium (=) machine 'moonstone\talC), silica, Any one or two or more of barium sulfate, boron nitride, oxygen =, zinc oxide, iron oxide, and pearl material. (15) The surface-treated powder according to (12), wherein the powder which can be used for the above-mentioned cosmetic is an organic powder which can be used for a cosmetic. According to another aspect of the present invention, a cosmetic material can be provided, = a surface-treated powder at the upper surface of the silk surface, and a surface treatment powder (the fourth embodiment). In addition to the body, at least one of the component, the aqueous component 'and the interface activity _, the cosmetic of the present invention is preferably skin care = material, hair cosmetic, makeup (make_upk_, and anti-purple line cosmetic) Any cosmetic material. The product form is preferably liquid, emulsion, cream, solid shape, paste, gelatinous, powdery, multi-layered, mousse ( [Embedded effect of the invention] [Effect of the invention] The present invention provides a usable property, excellent adhesion to skin, and other components blended in a cosmetic preparation. A powder having excellent affinity, in particular, a surface-treated powder for cosmetics. 201032832 A /

The surface-treated powder can be made into a surface-treated powder having water repellency or hydrophilic oil repellency. Here, the water repellency and oil repellency means that the surface structure powder exhibits water repellency and oil repellency by changing the structural structure of the polymer molecules according to the coating method and the coating amount of the specific fluoropolymer. A surface treatment agent which is water-repellent or hydrophilic and oil-repellent can be produced depending on the purpose and use. The above-mentioned hydrophilic oil repellency means that the steric structure of the polymer molecules is changed according to the coating method and the coating amount of the specific fluorinated copolymer described above, whereby the surface-treated powder exhibits hydrophilicity and oil repellency. The amount of water repellency or hydrophilicity varies depending on the type of the powder to be coated and the conditions of the treatment. The hydrophilic oil-repellent powder of the present invention can be used not only with the aqueous component of the cosmetic material but also as an emulsification aid, and the flexibility of formulation is greatly expanded. Further, by blending with the surface-treated powder of the present invention, it is possible to easily and easily produce a cosmetic having a feeling of use, a makeup finish effect, and a good makeup durability. In addition, the cosmetic material to be blended with the surface-treated powder is excellent in sebum resistance and transfer resistance, and exhibits a powder aggregation preventing effect, a catalyst activity suppressing effect, and a mutual interaction with an organic ultraviolet absorber or the like. An effect of preventing odor or coloration caused by an action, an effect of preventing crystallization, and an effect of preventing the effect of preventing water from increasing (4). In addition, the stability and safety of the product (four) is greatly improved. Therefore, the present invention is particularly useful in industry and extremely useful in industry. The above features and advantages of the present invention will become more apparent from the following detailed description. The following is a description of the following: In the following, the most === for implementing the present invention is limited to the above embodiments with the surface treatment of the present invention as the center. Further, in the present invention, the surface-treated powder contains any form of powder and particles. (The surface-treated powder of the present invention) The surface-treated powder of the present invention is a surface-treated powder, preferably a surface-treated powder for a cosmetic, and a surface of a powder particle to be surface-treated.

At least part of it is covered by a surface treating agent containing at least a compound of a specific fluorine-containing copolymer. The surface treatment agent used in the present invention is a specific fluorine-containing copolymer. The fluorinated copolymer is a monomer which must contain (a) a fluorine-containing monomer represented by the following formula (the fluorinated monomer represented by the phantom and (b) an alkoxy group-containing monomer represented by the following formula (Π) Fluoromonomer (a): [Chemical 4]

CH2=C(-X)-C(=0)-Y-[.(CH2)mZ-]p-(CH2)n-Rf (I) [wherein X is a hydrogen atom, a fluorenyl group, and the carbon number is a linear or branched alkyl group of 1 to 21, a fluorine atom, a chlorine atom, a bromine atom, an iodine atom or a CFX1X2 group (wherein 'XI and X2 are a hydrogen atom, a fluorine atom', a gas atom, a bromine atom or an iodine atom) a cyano group, a linear or branched fluoroalkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted benzyl group, a substituted or unsubstituted phenyl group; Y is -〇- or -NH -; Z is a direct bond, -S- or -so2·; 12 201032832 i\JJ /ρχι

Rf is a fluoroalkyl group having a carbon number of i~6; 1]. The alkoxy group-containing single m is 1 to 10, n is o 10, p is 0 or the body (b) is represented by the formula (II): [Chemical 5] ~VA; -Le〇)-〇_( R1〇)q_X2 [, wherein X1 is a chlorine atom or a fluorenyl group; 1 is a hydrogen atom or an unsaturated or saturated hydrocarbon group having a number of from 1 to 22;

= is an alkyl group of a carbon atom which is a part or all of a hydrogen atom which may be woven by substitution; the gate q is an integer of 1 to 5 Å]. A preferred example of the above formula (1)+, wherein P is 〇°X, is a hydrogen atom. The fluorine-containing monomer (a) generally has a perfluorofilament and/or a partially fluorinated fluoroalkyl group. More preferred is perfluorofilament. The carbon number of the Rf group is 1 to 6. The carbon number of the Rf group is preferably 4, 5 or 6, and particularly preferably 6. Examples of Rf bases are: -cf3 ' -cf2cf3 ^ -cf2cf2cf3 ^ -CF(CF3)2 > -cf2cf2cf2cf3 > -CF2CF(CF3)2 , -C(CF3)3 ^ -(CF2)4CF3 > -( CF2) 2CF(CF3)2 ^ -CF2C(CF3)3, -(cf2)5cf3, and the like. The fluorine-containing monomer (a) may of course be used singly or in combination of two or more. The fluorine-containing monomer (a) is, for example, as follows. CH2=C(-X)-C(=0)-〇.(CH2)mS-(CH2)n-Rf CH2=C(-X)-C(=0)-〇-(CH2)m-S02- (CH2)n-Rf CH2=C(-X)-C(=0)-〇.(CH2)n-Rf 13 201032832 /pu CH2=C(-X)-C(=〇)-NH-(CH2 n-Rf [In the above formula, X is a hydrogen atom, a fluorenyl group, a fluorine atom, a gas atom, a bromine atom, an iodine atom, a CFX12 group (wherein, χΐ and X2 are a hydrogen atom, a gas atom or a chlorine atom), and a cyano group; a linear or branched sucrose group having a carbon number of 1 to 20, a substituted or unsubstituted benzyl group, a substituted or unsubstituted w group;

Rf is a fluoroalkyl group of 1 to 6; m is 1 to 1 Torr, and η is 0 to 10] Specific examples of the fluorine-containing monomer (a) are as follows, but are also set forth in these examples. Limit CH2=C(-H)-C(=0)-0-(CH2)2-S-Rf CH2=C(-H)-C(=0)-〇-(CH2)2-S-(CH2 )2-Rf CH2=C(-H)-C(=0)-〇-(CH2)3-S02-Rf CH2=C(-H)-C(=0)-〇-(CH2)2-S02 -(CH2)2-Rf CH2=C(-H)-C(=0)-〇-(CH2)2-Rf CH2=C(-H)-C(=0)-NH-(CH2)2- Rf

CH2==C(-H)-C(=0)-〇CH2CH2N(C2H5)S02-Rf CH2=C(-H)-C(=0)-〇CH2CH2N(CH3)S02-Rf CH2=C(- H)-C(=0)-0CH2CH(0C0CH3)CH2-Rf CH2=C(-CH3)-C(=〇)-〇-(CH2)2-S-Rf CH2=C(-CH3)-C( =〇)-〇-(CH2)2-S-(CH2)2-Rf CH2=C(-CH3)-C(=0)-0-(CH2)3-S02-Rf CH2=C(-CH3) -C(=〇)-〇-(CH2)2-S02-(CH2)2-Rf CH2=C(-CH3)-C(=〇)-〇-(CH2)2-Rf 201032832 J /pil CH2= C(-CH3)-C(=0)-NH-(CH2)2-Rf CH2=C(-CH3)-C(=0)-0CH2CH2N(C2H5)S02-Rf CH2=C(-CH3)-C (=0)-0CH2CH2N(CH3)S02-Rf CH2=C(-CH3)-C(=0)-OCH2CH(OCOCH3)CH2-Rf CH2=C(-F)-C(=0)-0-( CH2)2-S-Rf CH2=C(-F)-C(=0)-0-(CH2)2-S-(CH2)2-Rf CH2=C(-F)-C(=0)- 0-(CH2)2-S02-Rf CH2=C(-F)-C(=0)-0-(CH2)2-S02-(CH2)2-Rf CH2=C(-F)-C(= 0)-0-(CH2)2-Rf CH2=C(-F)-C(=0)-NH-(CH2)2-Rf CH2=C(-Cl)-C(=0)-0-( CH2)2-S-Rf CH2=C(-Cl)-C(=0)-0-(CH2)2-S-(CH2)2-Rf CH2=C(-Cl)-C(=0)- 0-(CH2)2-S02-Rf CH2=C(-Cl)-C(=0)-0-(CH2)2-S02-(CH2)2-Rf CH2=C(-Cl)-C(= 0)-0-(CH2)2-Rf CH2=C(-Cl)-C(=0)-NH-(CH2)2-Rf CH2=C(-CF3)-C(=0)-0-( CH2)2-S-Rf CH2=C(-CF3)-C(=0)-0-(CH2)2-S-(CH2)2-Rf CH2=C(-CF3)-C(=0)- 0-(CH2)2-S02-Rf CH2=C(-CF3)-C(=0)-0-(CH2)2-S 02-(CH2)2-Rf CH2=C(-CF3)-C(=0)-0-(CH2)2-Rf CH2=C(-CF3)-C(=0)-NH-(CH2)2 -Rf CH2=C(-CF2H)-C(=0)-0-(CH2)2-S-Rf CH2=C(-CF2H)-C(=0)-0-(CH2)2-S-( CH2)2-Rf 15 201032832 J1637pit CH2=C(-CF2H)-C(=0)-0-(CH2)2-S02-Rf CH2=C(-CF2H)-C(=0)-0-(CH2 )2-S02-(CH2)2-Rf CH2=C(-CF2H)-C(=0)-0-(CH2)2-Rf CH2=C(-CF2H)-C(=0)-NH-( CH2)2-Rf CH2=C(-CN)-C(=0)-0-(CH2)2-S-Rf CH2=C(-CN)-C(=0)-0-(CH2)2- S-(CH2)2-Rf CH2=C(-CN)-C(=0)-0-(CH2)2-S02-Rf CH2=C(-CN)-C(=0)-0-(CH2 )2-S02-(CH2)2-Rf

A CH2=C(-CN)-C(=0)-0-(CH2)2-Rf CH2=C(-CN)-C(=0)-NH-(CH2)2-Rf CH2=C(- CF2CF3)-C(=0)-0-(CH2)2-S-Rf CH2=C(-CF2CF3)-C(=0)-0-(CH2)2-S-(CH2)2-Rf CH2= C(-CF2CF3)-C(=0)-0-(CH2)2-S02-Rf CH2=C(-CF2CF3)-C(=0)-0-(CH2)2-S02-(CH2)2- Rf CH2=C(-CF2CF3)-C(=0)-0-(CH2)2-Rf CH2=C(-CF2CF3)-C(=0)-NH-(CH2)2-Rf CH2=C(- F)-C(=0)-0-(CH2)3-S-Rf 〇CH2=C(-F)-C(=0)-0-(CH2)3-S-(CH2)2-Rf CH2 =C(-F)-C(=0)-0-(CH2)3-S02-Rf CH2=C(-F)-C(=0)-0-(CH2)3-S02-(CH2)2 -Rf CH2=C(-F)-C(=0)-0-(CH2)3-Rf CH2=C(-F)-C(=0)-NH-(CH2)3-Rf CH2=C( -Cl)-C(=0)-0-(CH2)3-S-Rf CH2=C(-Cl)-C(=0)-0-(CH2)3-S-(CH2)2-Rf 201032832 X \J^J / CH2=C(-Cl)-C(=0)-0-(CH2)3-S02-Rf CH2=C(-Cl)-C(=0)-0-(CH2)3 -S02-(CH2)2-Rf CH2=C(-CF3)-C(=0)-0-(CH2)3-S-Rf CH2=C(-CF3)-C(=0)-0-( CH2)3-S-(CH2)2-Rf CH2=C(-CF3)-C(=0)-0-(CH2)3-S02-Rf CH2=C(-CF3)-C(=0)- 0-(CH2)3-S02-(CH2)2-Rf CH2=C(-CF2H)-C(=0)-0-(CH2)3-S-Rf CH2=C(-CF2H)-C(= 0)-0-(CH2)3-S-(CH2)2-Rf CH2=C(-CF2H)-C(=0)-0-(CH2)3-S02-Rf CH2=C(-CF2H)- C(=0)-0-(CH2)3-S02-(CH2)2-Rf CH2=C(-CN)-C(=0)-0-(CH2)3-S-Rf CH2=C(- CN)-C(=0)-0-(CH2)3-S -(CH2)2-Rf CH2=C(-CN)-C(=0)-0-(CH2)3-S02-Rf CH2=C(-CN)-C(=0)-0-(CH2) 3-S02-(CH2)2-Rf CH2=C(-CF2CF3)-C(=0)-0-(CH2)3-S-Rf CH2=C(-CF2CF3)-C(=0)-0- (CH2)3-S-(CH2)2-Rf CH2=C(-CF2CF3)-C(=0)-0-(CH2)3-S02-Rf CH2=C(-CF2CF3)-C(=0) -0-(CH2)2-S02-(CH2)2-Rf [In the above formula, Rf is a fluoroalkyl group of 1 to 6] The alkoxy group-containing monomer (b) is a non-fluorine monomer, and is the following A compound represented by the formula (II) (alkanediol (mercapto) acrylate). CH2=C(X1)-C(=0)-0-(R0)q-X2 (II) [wherein X1 is a ruthenium atom or a ruthenium group, X2 is a ruthenium atom or the carbon number is 1 17 201032832 3163 / pit ~ 22 of unsaturated _ and a hydrocarbon group, R is a hydrogen atom - part or all of the carboxyl group substituted by a carboxyl group of 2 to 4; q is i ~ 5 〇 integral with alkoxy In the monomer (b), q is preferably 2 to 10, particularly preferably 2 to 5. In the formula (II), R is preferably an ethyl group or a propyl group, and particularly preferably an ethyl group. R in the formula (11) may also be a combination of two or more kinds of stretching groups. At this time, it is preferred that at least one of R is an exoethyl group. The combination of R may be a combination of an exoethyl/extended propyl group and a combination of an exoethyl/terpenyl group. The alkoxy group-containing monomer (b) may also be a mixture of two or more kinds. Specific examples of the monomer (b) containing an alkoxy group include, but are not limited to, these examples.

CH2=CHC00-(CH2CH20)9-H

CH2=C(CH3)C00-(CH2CH20)9-H

CH2=C(CH3)C00-(CH2CH20)23-H

CH2=C(CH3)COO-(CH2CH2O)50-H

CH2=C(CH3)C00-(CH2CH(CH3)0)9-H CH2=CHC00-(CH2CH(CH3)0)9-H ❹

CH2=C(CH3)C00-(CH2CH(CH3)0)9-H

CH2=C(CH3)C00-(CH2CH20)5-(CH2CH(CH3)0)2-H

CH2=C(CH3)C00-(CH2CH20)8-(CH2CH(CH3)0)6-H CH2=CXl-(CH2CH20)n-CH3 CH2=CXlC00-(CH2CH(CH3)0)n-CH3 CH2=CX1C00 The -(CH2CH20)5-(CH2CH(CH3)0)3-CH3 fluorinated copolymer may also contain a crosslinkable monomer. The crosslinkable monomer may be a compound having 18 201032832 J 1UJ / pil having at least two reactive groups and/or carbon-carbon double bonds and no fluorine. The crosslinkable monomer may be a compound having at least two carbon-carbon double bonds, or a compound having at least one carbon-carbon double bond and at least one reactive group. Examples of the reactive group are a hydroxyl group, an epoxy group, a gas methyl group, a blocked isocyanate group, a buffer group, and the like. In the present invention, a monomer having an amine group is not used. The crosslinkable monomer is preferably a non-fluorine crosslinkable monomer, more preferably a di(indenyl)propionate. Particularly preferred for the parent-linked monomer is a compound represented by the following formula (ΠΙ) (calcinol di(methyl)-propyl acetoacetate): [Chemical 7] • CH2=C(X3).C(= 〇).〇.(Ri〇)q_c(=〇).C(X3)=:CH2 (m) • [In the middle of each χ3 is a hydrogen atom or a sulfhydryl group; R is a part or all of a hydrogen atom which may be hydroxyl group The substituted carbon number is a stretching base of 2 to 10; q is an integer of 1 to 50]. Further, the carbon number of R1 is 2 to 1 Å, for example, preferably 2 to 6, and particularly preferably 2 to 4. Ri is preferably an ethyl group. By controlling the molecular weight or mole of each monomer constituting the fluorinated copolymer, the coating property of the fluorinated copolymer on the powder particles or the formation of the film can be imparted: the dispersibility of the powder particles, moisture absorption and Moisturizing ability, etc. The weight average molecular weight of the plate-containing copolymer of the present invention can be set to 1000 to 1,000,000, and the right enthalpy is preferably set to about 5,000 to 500,000. If the above weight average is less than 1_', the skin forming ability is weak and it is not suitable for the surface treatment having the effect of the present invention; if the above weight average molecular weight is greater than 1000000, 201032832 31637ριί not only the solubility of the polymer is deteriorated, but also the surface-treated powder Dispersibility will deteriorate. Further, the weight average molecular weight is a value obtained by polystyrene conversion by gel permeation chromatography. When the fluorinated copolymer is, for example, 1 part by weight of the fluorine-containing monomer (a), the amount of the alkoxy group-containing monomer (b) may be 100 parts by weight based on the fluorine-containing monomer (a). It is preferably 1 part by weight to 4 parts by weight, preferably parts by weight to 150 parts by weight, more preferably 43 parts by weight to 1 part by weight. If the amount of the alkoxy group-containing monomer (b) is less than 1 part by weight, the hydrophilicity cannot be obtained; if the amount of the alkoxy group-containing monomer (b) is more than 4 〇〇' parts by weight, The oil repellency will be reduced. When the fluorinated copolymer contains a crosslinkable monomer, the amount of the crosslinkable monomer can be set to 3 parts by weight or less, and can be set to 0.1 part by weight to 20 parts by weight, particularly It is set to 5 parts by weight to 10 parts by weight. If the amount of the crosslinkable monomer is more than 3 parts by weight, - it becomes a hard film and the feeling of use is deteriorated. Further, the fluorinated copolymer used in the present invention can be synthesized, for example, by the method disclosed in Japanese Laid-Open Patent Publication No. 2000-290640, but is not limited to the method. For example, the polymerization of the fluorinated copolymer is not particularly limited, and various polymerization methods such as bulk polymerization, solution polymerization, emulsion polymerization, and radiation polymerization are optional. For example, it is generally selected from a solution polymerization using an organic solvent, or an emulsion polymerization using water or an organic solvent and water. The treatment liquid is usually prepared by diluting with water after polymerization or by adding an emulsifier to emulsify in water. The surface treating agent used in the present invention is preferably in the form of a solution, an emulsion 20 201032832 /μιι (emulsi〇n) or an aerosol (coffee 8〇1). The surface treatment agent is, for example, a mixture of a fluorinated copolymer and a medium (e.g., an organic solvent and a liquid such as water). The concentration of the surface-treated fluorinated copolymer can be, for example, 0.01% by weight (wt%) to 5% by weight. The coating amount of the powder to be surface-treated is different depending on the chemical composition of the powder to be subjected to the surface, the particle diameter, the presence or absence of porosity, the oil absorption amount, the water absorption amount, and the specific surface area. The amount of the above-mentioned specific fluorine-containing copolymer to be coated is preferably from 0.1 part by weight to 40 parts by weight, based on the surface by weight of the powder. More preferably, it is 5 parts by weight to 35 parts by weight. + If the coating amount is less than the above range, a sufficient effect cannot be obtained, and if the coating amount is larger than the above range, not only the aggregation of the powder particles due to the polymer occurs, but also the function of the surface-treated powder is lowered. The effect in the cosmetic material is insufficient, and there is also a tendency to be uneconomical. In the present invention, 'the feeling of use of the surface-treated powder coated with the specific fluorinated copolymer or the adhesion to the skin is improved, and the affinity with other components in the cosmetic preparation is improved, and From the viewpoints of the feeling of use of the surface-treated powder-compounded cosmetic, the finish of makeup, and the persistence of makeup, in order to obtain performance more effectively, it is effective to utilize the above-mentioned characteristic fluorinated copolymer and the above specific The other compound other than the fluorinated copolymer is subjected to surface treatment in combination, that is, the surface treatment agent further contains other compounds than the above specific fluorinated copolymer. Other compounds other than the above specific fluorine-containing copolymer are, for example, fluorine-containing compounds selected from the group consisting of perfluoroalkyl phosphates, perfluoropolyether phosphates, perfluoropolyether decanes, and all of 201032832 31637pit fluoranthene sulphate, organic polymerization Shixi oxygen burning, burning base stone, organic titanate 'polyolefin, hydrogenated lecithin (including its salt), N_mercapto amino acid (including its salt or composition), acidic ester oil, fatty acid (including a salt thereof, and one or more compounds of the dextrin fatty acid vinegar. In the present invention, other fluorine-containing compounds other than the specific fluorine-containing copolymer which is surface-treated in combination with a specific fluorine-containing copolymer may, for example, be a perfluoroalkyl phosphate, a perfluoropolyether sulphate or a whole. Fluoropolyphthalocene, perfluoroalkyl decane, perfluoropolyether modified polyamine phthalate, perfluoropolyether modified acrylate, perfluoroalkyl modified polyoxyl, perfluoropolyether聚聚矽 oxygen and so on. As the perfluoroalkyl phosphate, a known compound of the following formula (1) can be used, and a preferred compound is a compound having a carbon number of Rf of 6 or less in the compound represented by the following formula (1). [RfCnH2n〇]yP〇[〇M]3.y (1) , (wherein Rf represents a perfluoroalkyl group or a perfluoroalkyl group having a carbon number of 1 to 6, which is linear Or branched, may be a single chain length or a composite chain length. η represents an integer of 1 to 12, y represents an integer of 1 to 3. Μ represents hydrogen, test metal, ammonium or substituted ammonium) perfluoro As the polyether phosphate, a known compound can be used, and a preferred compound is a compound represented by the following formula (2). [?9] l?(CF2)3〇[CF(CF3)CF20]mCF(CF3)aH2nO]wP(0)(0^( 2 ) (where m represents an integer of 0 to 50, and η represents 1 to 16 The integer, w is 1 or 2) The phosphoric acid moiety may be an alkali metal salt or an amine salt such as Na or hydrazine, or a salt of ammonium 22 201032832. In addition, it may be a shaped bear which is modified by using citric acid to change both ends ( Fomblin HC/P2-1000: Solvay Solexis Co., Ltd.) A well-known compound described in WO 97/07155 and JP-A-2008-214229, etc. can be used for the whole mouse. A known compound of the following formula (3) can be used, and a preferred compound is a compound having a carbon number of Rf of 6 or less in the compound represented by the following formula (3).

(RfCnH2n)aSiX4-a (3) (wherein Rf represents a perfluorodecyl group or a perfluorooxyalkyl group having a carbon number of 1 to 6, which is linear or branched, and may be a single The chain length may also be a composite chain length. η represents an integer of 1 to 12, and a represents an integer of 1 to 3, "χ represents an alkoxy group, a hydroxyl group, an amine group, or a hydroxyl atom." Commercially available perfluoroalkyl decane may be used. List Dynasylan F8261 (Evonik Degussa company) and so on. Examples of the perfluoropolyfluorene-modified polyaminophthalate include Fomblin AN-5, Fomblin CAT_5, and the like which are commercially available from Solvay Solexis. Other fluorine-containing compounds which can be used as the surface treatment agent include carboxy-modified perfluoropolyether, alcohol-modified perfluoropolypolymer, isocyanate-modified perfluoropolyfluorene, ester-modified perfluoropolyether, and difluoroalkyl group. Dimethyltridecyldecyloxydecanoic acid, fluoropropyl methicone, and the like. The organopolyoxane may or may not have a functional group, and the organopolyoxyalkylene having a functional group may be a side chain or a linear polyorganosiloxane having a functional structure at both ends or a single terminal. The compound represented by the following formula 23 201032832 ΜΟό /pll (4). (R53SiO) (R42SiO)ffi(R42SiO)n(SiR53) (4) In the above formula (4), R4 is each independently and represents a lower alkyl group or a hydrogen atom having a carbon number of 1 to 4, respectively. A plurality of R5 are independently independent of each other, and represent any of a hydrogen atom, a hydroxyl group, and a lower alkoxy group having a carbon number of 1 to 4, and m and η represent an integer of 1 or more, and m + n is 2 An integer of ~1000. Specific examples of the organic polyoxane include commercially available ginseng KF99, KF9901, X-24-9171 or X-24-9221. Further, trimethyl decyloxydecanoic acid, a polyfluorene oxide having a dimercapto group or an alkyl group, a reactive group, an acrylic polyoxyxene, a polyoxyacrylic acid or the like can be used. Shin-Etsu Chemical Industry Co., Ltd. commercially available organic poly-stone oxygen can be used: KF-96 series, KF-9908 (triethoxydecylethylethyl polydidecyl decyloxyethyl ruthenium polyoxan ) or KF-9909 (triethoxymethyl sulfonyl ethyl polydimethyl oxalate oxyethyl hexyl fluorene polyoxan), KP-541, KP-545, ΚΡ 575, KP -561, KP-574, KF-7312F, KF-7312J, Q KF-7312K, KF-9001, etc.; commercially available organic polysulfide can be used in Dow Corning · SH1107C, BY11-018, DC593, FA-4001 CM Silicone Acrylate, FA-4002 ID Silicone Acrylate. In addition, it can also be used: tetrahydrotetramethylcyclotetraoxane and other cyclic sulfhydryl hydrogenated polyfluorene oxides, amine-based modified polyoxime, rebel-modified poly-stone oxygen, polyoxynoxy-oxygen Polymer, triethoxysulfonyl fluoride modified polyfluorene oxide, triethoxy ninthyl quinone oxime, diethyl lactyl diisopropyl gas, triethoxy butyl. Afu - 24 201032832 ui\jj i yii 矽 烷 等. The alkyl decane used in the present invention is an alkyl decane selected to have a RnSiX4_n structure as a basic skeleton. Here, 'R is a linear or branched alkyl group, and X is a hydrogen atom, an alkoxy group, an amine group, or a dentate atom. The alkyl chain may have a carbon number of from 1 to 18, and specific examples thereof include an octyltriethoxydecane or an octadecyldiethoxycarbazone. Alternatively, a polyfluorene-modified alkoxydecane having a mystery group introduced into the molecule may be used. Commercially available products include Z-6341 from D〇w Corning, Dynasylan 4140 from Degussa, KBM-641 from Shin-Etsu Chemical Co., KBE-13, and Prosil 9202 from Clariant. The organic titanate used in the present invention is an organic titanate having a structure of (CnH2n_lC〇〇)aTl(〇CraH2m - l)b as a basic skeleton. Further, in the formula, n represents an integer of i to 26, m represents an integer of 丄~丨, and a and b are integers of i to 3, respectively, and have a relationship of a + b = 4. Further, the alkyl group shown here is linear or branched, and the singular group which may be a single chain length may be a base group having a long chain length. Commercially available organic titanates include isopropyl diisostearate titanate (plenact KR_TTs, Japan Ajinomoto Co., Ltd.) and the like. The polyolefin used in the present invention is a polyolefin resin having at least one carboxyl group in the molecule, such as polyethylene or polypropylene. For example, it is described in Japanese Laid-Open Patent Publication No. SHO63-179972. A compound having a molecular weight of 500 to 20,000 and a melting point of 4 〇 C or less, a low molecular weight poly(tetra) poly fluorinated sulphurized polyethylene, butylated polyethylene, oxidized polypropylene, or the like. 25

201032832 • 31W/piI The hydrogenated printing phospholipid used in the present invention is a glycerol fluorene having a Wei group, that is, +, such a hydrogenated lecithin may be exemplified by natural extracting from egg yolk, soybean, corn seed, and the like. The imprinted fat or hemolysis is lyso^lecithin) and the hydrogenated synthetic egg squama is a hydrogenated yttrium of less than or equal to I5. The hydrogen cut used in the towel of the present invention may be in the form of a salt, and the hydrogenated sealant in the form of a salt is preferably a water-insoluble hydrogenated lecithin metal salt such as AhMg, Ca, Zn, ruthenium or osmium. Particularly preferred is a hydrogenated printing disc grease (hydrogenated phospholipid containing a salt form) having a melting point of 50 ° C or higher. For example, a known compound described in Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Hydrogenated egg butter No. 5 or hydrogenated soybean phospholipid Basis LS-60HR by Nisshin OilliO Group. Other hydrogenated lecithin having a phosphate group may, for example, be commercially available from Nippon Oil Co., Ltd. such as methacryloxyethylphosphocholine -

Lipidure series. The thiolated amino acid used in the present invention is a saturated fatty acid having a carbon number of 12 or more and 20 or less and an asparaginic acid, glutamic acid, or alanine selected from the group consisting of asparaginic acid, glutamic acid, and alanine. (alanine), lysine, glycine, sarcosine, proline, sulfhydryl groups a compound, or a whole hydrolyzate derived from a peptide or a silk peptide of a plant such as wheat or cowpea or panicum, an animal-derived peptide, or the like. Free radicals, or salts forming K, Na, Fe, Zn, Ca, Mg, 26 201032832 A, Zr, Ti, and the like. Specific examples include: Amisoft HS-21P, Amihope LL (laurel-branched acid), etc., commercially available from Kawaken Fine Chemicals, Soypon SLP, Soypon SCA, Alanon AMP, Seppic, France Sepilift DPHP, etc., such as Sarcosinate MN, which is commercially available from Nikko Chemicals Co., Ltd., Pellicer, Aminofoamer, Aminosurfact, Aminocoat, etc., which are commercially available from Asahi Kasei Corporation. The thiolated amino acids may also be in the form of a composition with a fatty acid. The composition of lipoamino acid can be exemplified by Sepifeel One, commercially available from Seppic (by palmitoyl valine, palmitoyl sarcosine, palmitoyl acid, palmitic acid a composition composed of these four components). The acidic ester oil used in the present invention preferably contains a large total carbon number.

a compound having an acid value of 16 or more and an acid value of μ or more, wherein the ester compound may have one or two or more kinds of carbons having a carbon number of from 1 to 36, and one or two or more kinds of carboxylic groups having a carbon number of from 1 to 36. The acid is obtained by carrying out a reaction. Specific examples of the known compound shown in Japanese Laid-Open Patent Publication No. 2004-51945 include: Salacos MIS (isostearyl sebacate) commercially available from Nisshin 0illio Gr〇up, and Salacos MOD (octyl 12-decyl phthalate). Ester), Salacosl A (octyldodecyl adipate), Salac〇s HD (octyl dodecyl dimerate), and the like. The fatty acid used in the present invention may, for example, be a linear or branched saturated or unsaturated fatty acid having a carbon number of 12 to 22, and examples thereof include lauric acid, myristic acid, and palm. Acid ((4) melon acid), stearic acid, oleic acid (〇1咖扣(4), linseed oil 27 201032832 31637pit acid (linolic acid), tartaric acid (paimh〇ieic acid), behenic acid (behenic acid), glycerol taric acid (Hgn〇ceric acid), 2-ethylhexanoic acid, isotridecanoic acid, isomyristate, isopalmitic acid, isostearic acid, isoamyllic acid, etc., or Fatty acids and Ca, Mg, Zn, Zr, A1

a salt of a metal such as Ti. Further, the compound which can be surface-treated in combination with the specific fluorinated copolymer used in the present invention may, for example, be an alkylphosphoric acid or a salt thereof, an alkyl decanoic acid and a salt thereof, a pyrosulfuric acid and a salt thereof, and a guanamine acid. Or a salt thereof, a burnt ether carboxylic acid or a salt thereof, a polyoxyethylene alkyl ether phosphate and a salt thereof, a polyoxyethylene alkyl oxime ether sulfuric acid and a salt thereof, a mercapto stanol/three pEG-8 coconut fatty acid glyceride, and a dextrin Fatty acid esters, etc. The above-mentioned compounds which are commercially available are Akypo RLM45NV, ECT-3NEX, etc., commercially available from NIKK® L, and Monosiliol C, which is commercially available from Exsymol Co., Ltd., but are not limited thereto. The target effect of the surface-treated powder can be treated as a combination of these compounds. The compounding ratio of the specific fluorine-containing copolymer (which is referred to as the treating agent A) and the other component (which is treated as the treating agent B) which is surface-treated in combination with it is preferably A: B is 39.0 parts to 0.1 parts: 〇 1 part to 39.0 parts, the other component is, for example, other than the above-mentioned fluorine-containing copolymer selected from the group consisting of perfluoroalkyl phosphate, perfluoropolyether phosphate, total gas poly-stone, perfluoroalkyl decane Fluorinated compound, organopolyoxyalkylene, alkyl decane, organic titanate, polyolefin 'hydrogenated lecithin (including salts thereof), N-decylamino acid (including salts or compositions thereof), acidic ester oil One or more compounds of fatty acids (including salts thereof) and dextrin fatty acid vinegar. More preferably, A:B is 34.5 28 201032832 f knife ~ 0.5 parts: 0.5 parts ~ 34 · 5 parts. The blending ratio. The type of the strip and the amount of the blending material are different. If the above ratio is exceeded, the effect in the material is lowered. The powder of the present cap (four) is a powder which can be used for each of the fields, that is, when it is selected for use as a cosmetic, it is a powder which can be used for a cosmetic. In addition, any powder of Hi, can be selected. For the selection of inorganic powders and organic powders, for example, inorganic powders include boron nitride, sericite, natural mica, calcined mica, synthetic mica, synthetic mica, oxidized soda, mica, talc, kaolin, bentonite ( Bentonite), bentonite (reward (6), carbonic acid, magnesium carbonate, phosphate mother, Wei liver, magnesium oxide, tin oxide, oxidation f, oxygen, oxidation, titanium oxide, zinc oxide, oxidation, oxidation, emulsified magnesium , chrome hydroxide, iron blue (ir〇n blue), ultramarine (ultramarine), dish acid, hydrazine, barium sulfate, magnesium sulfate, ashes, liningue, ashes, mother Bismuth, magnesium aspartate, ashes acid, ashes, carbonized stone, magnesia, magnesium tartrate, magnesium aluminate, magnesium metasilicate, hydroxyaluminum, clay Zeolite, hydrazine xyapatite, ceramic powder, spinel, mullite, cordierite (-), aluminum nitride, titanium nitride, tantalum nitride,镧, 钐, button, 铽, 铕" n-Zn ferrite (ferrite), Ni_Zn ferrite, tantalum carbide (sil Icone carbide), titanate, barium titanate, iron titanate, lithium cobaltate, acid chain, tin oxide containing tin, tin oxide containing tin, magnetite, aluminum powder, gold powder, silver powder, platinum Powder, copper powder, metal colloid (n〇blemetal colloid), iron powder, zinc powder, cobalt blue, cobalt violet, cobalt green, low-valent titanium oxide, 29 201032832

JiW/pn micro-particles titanium oxide, butterfly-like barium sulfate, petal-like zinc oxide, tetragonal zinc oxide, fine-particle zinc oxide; pearl pigments include: oxidized chin, mica, titanium oxide coated mica (miea), titanium oxide Coated synthetic mica, titanium oxide, cerium oxide, titanium oxide coated synthetic mica, titanium oxide coated π stone powder, zinc oxide coated cerium oxide, titanium oxide coated pigmented mica, iron oxide coated mica titanium, iron oxide and black iron oxide Covered with mica titanium, carmine coated mica titanium, prussian blue (pmssian biue) coated mica titanium and other pearl pigments. Specific examples include Merck's Iri〇din (registered trademark) series, Timiron (registered trademark) series, c〇lor〇na series © (registered trademark) series, Dichrona (registered trademark) series, and xirona (5 main volume trademark) Series, Ronastar (registered trademark) series, BASF's Desert Reflections series, Timica series, Fiamenco series,

Cloizonne series, Duocrome series, Gemtone series, Cellini series, Mearlmaid series, Reflecks series, chroma-Lite series,

Cosmica series 'Eckart's Prestige (registered trademark) series, Visionaire (registered trademark) series, Mirage series, M 板 硝 的 的 M M M M M M M 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 〇 CQV's Cosmetica White Pearl series, sharon Pearl series, etc. ' Taizu's Precioso White

Pearlescent Pigments series, etc. Examples thereof include: effect pigments of aluminum flakes, oxidized chips, emulsified slabs, glass flakes, iron oxide coated mica, carmine, titanium oxide coated with boronic acid (sodium/series), and titanium oxide. Covered side of the acid (dance / Shao), oxygenated silver, fish scale foil, stainless steel (stainless) powder, tourmaline powder, sapphire 30 201032832 J 1UJ /pii (sapphire) or ruby (ruby) and other gemstones crushed And the obtained powder, 'Mango Violet, glass fiber, carbon fiber, strontium carbide fiber, oxidized fiber, /9 - stone ash stone (/3 -wollastonite), hard rock eve | xonotlite, Potassium titanate fiber, aluminum borate fiber, basic magnesium sulfate fiber, tantalum nitride fiber, and the like. Examples of the organic powder include metal soap, N-single long chain mercapto basic amino acid, ruthenium sulfonate polyvalent metal salt, amber powder, carbon black (black φ black), and tar dye. a powder formed by lake, a powder obtained by lake-forming a natural pigment, a polyamide powder, a polyester powder, a polyethylene powder, a polyamino phthalate powder, a polypropylene powder, a polystyrene Powder, benzoguanamine powder, polymethylbenzoguanamine powder, polytetrafluoroethylene (PTFE) powder, cellulose powder, silk powder, polyoxygenated powder, divinyl Synthetic resin such as benzene styrene copolymer, vinyl resin, urea resin, resin, fluororesin, sapphire, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, etc. Powders of microcrystalline fibers such as powder, nylon fiber, polyester® fiber, starch powder, CI pigment yellow, CI pigment orange, etc. Tar pigments can be listed as: red 3, red 10, red 1〇6, red 201, red 202, red 204, red 205, red 220, red 226, red 227, red 228 , red 230, red 401, red 505, yellow 4, yellow 5, yellow 202, yellow 2, 3, yellow 204, yellow 401, blue 1, blue 2, blue Color 201, Blue 404, Green 3, Green 201, Green 204, Green 205, Orange 201, 31 201032832 3I637pit Orange 203 拨, dial color 204, dial color 2〇6, light color 2〇7, etc.; natural pigments include ··carmine, lacquer acid accaic acid, carthamin, brazilin, crocin ((10) also), chlorophyll (chl〇rophyll), stone_hu Powders such as natural pigments such as radish (point _car〇tin) and safflower powder. The shape of the powder may be powder or fibrous. When the cosmetic material is selected for use, the grain position is in the range of about 1 nm to 2000, and it can be blended with the cosmetic material, that is, "5J" 〇 In addition, in the present invention, the above powder (before surface treatment) The powder may be a powder obtained by combining two or more kinds of powders. For example, a solid body (Excel Mica JP-2 or Excel Pearl: Sanhao Chemical Co., Ltd.) which is a composite of aluminum hydroxide on the surface of mica or pearl pigment particles may be filled in the surface of sericite or pearl pigment. A powder obtained by combining lime and zinc oxide (P〇wder La Vie: Sanhao Chemical Co., Ltd.) 'a powder obtained by dispersing and mixing fine particle titanium oxide with fine particle zinc oxide (TZ-PowderType 1: Sanhaohuacheng), A powder obtained by dispersing and mixing talc powder with fine zinc white and fine particle titanium oxide (TZ_p〇wder Type 2 : 瘳二好化成股份有限公司), 曱 曱 曱 氧 氧 / 乙烯基 乙烯基 乙烯基 乙烯基 乙烯基A mixture of burnt and sulphur dioxide (Dow Coming 9701 Cosmetic Powder), a mixture of dioxime oxime/vinyl dimethyl oxime and titanium oxide (Dow Corning EP-9261 TI Cosmetic Powder), dimerized Mixture of decane/vinyl dimethylpolyoxane with alumina (Dow Coming EP-9293 AL Cosmetic Powder), dimethicone/vinyl dioxime polyoxane and lauryl amide Acid mixture (D Ow 32 201032832 -f λ. υ_; / ριχ

Corning ΕΡ-9289 LL Cosmetic Powder ), Coverleaf series, Concelight series, etc., which are commercially available from Japan. Further, in the powder to be surface-treated in the present invention, in order to improve the affinity or fixability with the surface treatment agent, for example, aluminum, mother, magnesium, strontium, barium, zirconium, titanium, zinc, iron may be used in advance. An oxide or an aqueous oxide of at least one of cobalt, manganese, nickel, and tin is coated. These compounds may be coated in advance by surface treatment using a surface treatment agent which has been surface-treated in the present invention, or may be coated during surface treatment. Further, the oxide or the hydrous oxide particles may be coated or precipitated on the surface of the powder particles to be surface-treated. The amount of the third substance to be coated is preferably the minimum amount necessary for the function of the fluorine-containing compound of the present invention to be expressed by the surface-treated powder. In the present invention, the method of coating the surface treatment agent, particularly the specific fluorine-containing copolymer, on the powder is not particularly limited and can be carried out by a known method. The surface treatment methods are roughly classified into a dry method and a wet method. For example, using a Henschel mixer or a ball mill, a jet mill, a knea (jer), a planetary mixer, a p0ny mixer, sand Mill (grade ^ miu), attritor, ribbon blender, disper mixer, homogenizer (h〇m〇mixer), extruder, etc. The mixer, the pulverizer, the mixer, and the dispersing machine are used to mix the surface treating agent used in the present invention with the powder for a certain period of time, thereby performing treatment. At this time, it is also possible to apply mechanochemical mechanical force, Plasma, flame, 33 201032832 31637ριί Ultraviolet, electron beam, superheated steam, laser light, electromagnetic wave, etc. The wet method is to disperse the powder and surface treatment agent into the water. Or a solvent, a supercritical fluid (water, c〇2, etc.) may be mixed and contacted, and then the solvent may be evaporated, whereby the treatment may be carried out. Further, the specific fluorine-containing copolymer used in the present invention is used. And inclusions, fluorine-containing compounds such as perfluoroalkylphosphoric acid, perfluoropolyether phosphate, perfluoropolyether decane, perfluoroalkyl decane, organic polyoxane, alkyl decane, organic titanate, poly One or a kind of an olefin, a hydrogenated lecithin (including a salt thereof), an N-decylamino acid (including a salt or a composition thereof), an acidic ester oil, a fatty acid (including a salt thereof), and a dextrin fatty acid ester When the above compound is subjected to a surface treatment in a composite manner, as in the case of surface treatment using only the above specific fluorine-containing copolymer, surface treatment can be carried out by bringing the powder into contact with a surface treatment agent further containing the above compound. Further, the properties (liquid, body, gel, etc.) and physical properties (melting point, boiling point, glass transition temperature, solubility, reactivity, etc.) of the compound selected for surface treatment in combination with the surface treatment, and It is not particularly limited by the manufacturing method to select the optimum coating method for the type of the powder to be coated. 13 When the surface is treated in a composite manner, it can be cited as: a method of coating a fluorinated copolymer after coating, and then coating a surface treatment component other than the specific fluorinated copolymer; and coating a specific fluorinated copolymer and other surface treatment component other than the specific fluorinated copolymer A method of coating a specific fluorine-containing copolymer after coating a surface treatment agent other than a specific fluorine-containing copolymer, etc. A preferred coating method is to use only the specific fluorine-containing copolymer described above. In the case of the treatment and the case where the surface treatment is performed in a composite manner, the powder suspension to be coated is pre-filled in the liquid or in the liquid, or after being dispersed under the condition of coexistence with other powders, the crucible is coated. Or the method of covering at the same time. According to the invention (4), the fluorinated copolymer has a water-repellent earthy hydrophilic group in the molecule, and if only the oil-repellent group is expressed from the powder particles, the water-repellent property is exhibited. In order to obtain the superiority or dispersibility of the oil-repellent surface-treated powder and the other components of the chemical (four) injection, it is advantageous to be hydrophilic. The specific gas-containing and polymer of the present invention can expose both the oil-repellent group and the hydrophilic group to the surface of the powder particles in accordance with the coating method or the coating amount, thereby exhibiting hydrophilic oil repellency. In the coating method for obtaining the hydrophilic oil repellency, the hydrophilic oil-repellent surface-treated powder can be obtained by subjecting it to a surface having a higher coating amount than that of the water-repellent coating. The mosquito fluorocopolymer as defined in the present invention can be easily handled by the hydrogen bonding force or the film forming force with the powder substrate due to the optimum amount of the polycondensed diol in the molecule. When the amount of coating of the powder particles is higher than that of the oil-repellent 'coating amount, the free polyglycol diol chain becomes variable == The powder particles are in contact with water due to the molecular mobility (mGbiiity). Will show hydrophilicity. In addition, depending on the type of the powder, a method of treating the pH of the powder by the surface treatment, a method of controlling the temperature, or a method of controlling the temperature during the treatment may be used. After coating the fluorine-containing compound, it is coated with the specific fluorine-containing copolymer of the present invention to obtain hydrophilic oil repellency. x 35 201032832 ilbi/pu Another method of obtaining hydrophilic oil repellency is to perform multiple coatings to obtain hydrophilic oil repellency. In other words, the surface-treated powder which is coated with a specific fluorinated copolymer and imparted with water repellency and oil repellency is coated with the same or different specific fluorinated copolymer to obtain hydrophilic oil repellency. If the fluorine chain is exposed to the outermost surface of the rapid treatment layer of the surface-treated powder particles exhibiting water repellency, the surface is coated, and the fluorine chain and the rapid treatment layer of the polymer of the second treatment layer are Fluorine chain phase oriented approach

When coated, the polyalkylene glycol chain is exposed to the outermost surface of the particles to exhibit hydrophilic oil repellency. It is also possible to control the hydrophilic oil repellency by repeating this operation. ^

The evaluation method of water repellency and hydrophilic oil repellency can be carried out by measuring the contact angle of water or squalane. According to this method, the water-repellent property of the surface-treated powder of the present invention is preferably such that the contact angle with <burning is 8 大于 or more. . The surface-treated powder of the present invention preferably has a water-repellent property of a contact angle with water of less than 2 (). And:: The contact angle of the burn is 8 大于 or more. More preferably, the contact with water is equal to 1 G and the contact angle with m is greater than or equal to. . 'j The contact angle of the surface-treated powder with the corners refers to the angle formed by the drop of _ drops and = on the molded surface of the metal enamel and applying 6 MPa. The larger the angle, the more this is rejected. Table: Into the water's less investment _, _ 36 36328328

^ X \J^ I The frequency of the secret 50 slaves, observe the floating powder on the water surface and the state of the dispersion that is scattered to the water. The surface-treated powder having hydrophilic oil repellency of the present invention has a powder-free floating water layer dispersed on the water surface. A cosmetic containing a hydrophilic oil-repellent powder coated with a compound containing at least a specific fluorine-containing copolymer of the present invention, and a cosmetic material containing a powder of the previous upper barium fluoride-treated powder, and a makeup Since the other components to be blended in the preparation have excellent affinity, they are excellent in the feeling of use, the finish of makeup, the persistence of makeup, and the stability of quality in the cosmetic. The surface-treated powder of the present invention can exhibit a hydrophilic oil-repellency property and can be incorporated into an aqueous component such as a jujube compounded in a cosmetic preparation. The dispersion was applied to the skin. The S-disc of the surface-treated powder after the evaporation of the aqueous component appeared to be mixed. This means that the surface treatment which has previously been shown to be water-repellent can be used for the case where the oily component or the aqueous component of the recorded material has poor solubility or emulsifying property, poor dispersibility, and poor adhesion to the skin. The problem of the workability of the ruthenium complexed with the powder treated with the prior compound can be solved by the present invention. As an example, it is possible to achieve a water-repellent design by blending the surface-treated powder exhibiting hydrophilic oil repellency into an aqueous component and blending the component exhibiting water repellency into the oil component. It is thus possible to achieve a formulation which is higher than the previous function or which is different from the previous one. The surface-treated powder obtained by the present invention may be blended in one or two or more kinds to the cosmetic. (Cosmetic of the present invention) The cosmetic of the present invention is a cosmetic containing the surface-treated powder 37 201032832 31bJ/pit described above. Namely, the surface-treated powder can be produced by the above-mentioned recording. In the present invention, the formulation of the cosmetic is not particularly difficult, and the target cosmetic can be obtained based on the technique previously used, particularly the technique of incorporating the surface-treated powder into the cosmetic (e.g., emulsification, etc.). In the case where the surface-treated powder of the present invention is blended into a cosmetic, the amount thereof is different depending on the type and dosage form of the cosmetic, and it is preferable that the total composition of the cosmetic is (U wt% 〜1) Further, when the surface-treated powder of the present invention can be formed into a dispersion with an aqueous component, the amount of the surface-treated powder is not particularly limited to the blend of 0 to the cosmetic of the present invention. Examples of the other components include an oil component, an aqueous component, and a surfactant. Examples of the oil component include safflower oil, soybean oil, evening primrose oil, grape seed oil, rose hip oil, and Hawaiian nuclear oil (kukui nut). 〇il), almond oil, sesame oil, wheat germ oil, corn oil, cottonseed oil, avocado oil, olive oil, oyster sauce, peach oil, sesame oil 'peanut oil, hazelnut oil ), Australian walnut oil β (macadamianutoil), white mango seed oil, cocoa butter, shea butter, wood wax, coconut oil, palm oil, palm kernel oil, tallow, horse fat, oyster sauce, Cream, egg Oils such as oil and turtle oil, waxes such as candelillawax and jojoba oil (j〇j〇ba〇il), liquid paraffin, liquid paraffin, and horn Alkane, horn agroban, petrolatum, rocky soil, ceresin, microcrystalline mi (mier〇cryStauine 38 201032832 _j i υ-7 / pn 丽), 〇:-hydrocarbon oligomers and other hydrocarbons, lauric acid , nutmeg, palmitic acid, stearic acid, behenic acid, oleic acid, linoleic acid, decenoic acid, transbasic hard, eucalyptus fat fatty acid, etc., myristyl alcohol, Resveratrol, phytosterol, stearyl alcohol, aryl alcohol, camellol, oleyl alcohol, linalool, batyl alcohol, cholesterol (), phytosterol, wool Higher alcohols such as aliphatic alcohols and isostearyl alcohols, cholesterol, sterol fs+itosterol, phytol, sterols, sterols, oleic acid, vinegar Acidic acid, malic acid diisostearyl vinegar, trioctyl glycerin vinegar and other vinegars, dimethyl polyoxan, methyl phenyl polyoxane, alkyl modified polyoxane, Polyoxymethylene pentamer, cyclic polyglycol, methyltrimethylpolyoxyalkylene, octyl sulfonium polyoxyalkylene, dimethyl fluorene oxime, dimethyl oxalate, oxyalkylene Shixi oxygen burning, fertility three-stone oxygen burning, fluorine-synthesis, dream oxygen, etc., polyfluorinated oil, perfluorocarbon, hydrofluoric _ and other fluorine-based oil, ethyl acetate, butyl acetate , organic solvents such as benzene and the like. The water-based components are: lower alcohols such as ethanol and isopropanol, hydrazine, 3-butanediol, propylene glycol, polyethylene glycol, glycerin, diglycerin, polyglycerol, trehalose, (trehal〇se), erythritol ( Polyhydric alcohols such as erythritol), mannitol (mannit〇1), xylitol, sorbitol, malt〇se, and arabic gUm and tragacanth ), galactan, car〇b gum, guar gum, karaya gum, carrageenan, pectin, agar (agar), quince seed (marmelo, stick), starch (rice, jade, bell, wheat), dextrin, dextran, haiping gum 39 201032832 31637pit (algae colloid ), Trentino gum, 〇 t t bean gum (i〇cust bean gUm) and other plant water> glutinous glutinous molecules, xanthan gum, polydextrose, amber sterol (succinoglucan), pullulan (pululan) and other microorganisms are water-soluble polymers, collagen (c〇Uagen), Starch-based water-soluble polymer such as casein, albumin, gelatin, etc., starch-based water-soluble polymer such as carboxymethyl starch 'methylhydroxypropyl starch, sulfhydryl cellulose, ethyl fiber , methyl hydroxypropyl cellulose, carboxymethyl cellulose, hydroxymethyl cellulose, hydroxypropyl cellulose, nitrocellulose, sodium cellulose sulfate, sodium carboxymethyl cellulose, crystalline cellulose, fiber A cellulose-based water-soluble polymer of a powder, a seaweed acid-based water-soluble polymer such as sodium alginate or propylene glycol alginate, a vinyl-based water-soluble polymer such as a polyvinyl phthalate or a carboxyvinyl polymer, or a polyoxygen Ethylene-based water-soluble polymer, polyoxyethylene/polyoxypropylene copolymer-based water-soluble polymer, acrylic acid-soluble polymer such as sodium polyacrylate, polyethyl acrylate or polyacrylamide, polyethyleneimine, cationic polymerization Other synthetic water-soluble polymers such as bentonite, aluminum magnesium silicate, montmorillonite, beidemte 'nontromte, sap〇nke, hectorite (hect Inorganic water-soluble polymers such as 〇rite) and Shiqi acid needle. Further, these water-soluble polymers are also a film forming agent such as polyvinyl alcohol or polyvinylpyrrolidone. The surfactant may be exemplified by an anionic surfactant, which comprises a fatty acid = or a palmitic acid triethyl _ _ soap, a sinter and a condensate salt of a fatty acid and a fatty acid, a calcined acid salt. , olefinic acid salt, strontium sulphate; acid salt, fatty acid decyl amine hydrochloride, methyl condensate system 201032832

JlXJJ/pil acid salt, sulphuric acid sulphate salt, second-grade higher alcohol sulphate sulphate, sulphate and sulphuric acid sulphate sulphate, fatty acid vinegar sulphate sulphate, fatty acid sucrose sulphate sulphate, Sulfate salts such as turkey red oil, sulphonate, sulphate, sulphate, sulphate, N-mercapto-amino acid An active agent or the like; a cationic surfactant comprising an amine salt such as an alkylamine salt, a polyamine or an amino alcohol fatty acid derivative, an alkyl quaternary ammonium salt, an aromatic quaternary ammonium salt, a pyridine rust salt, or an imidazole Rust salt; _ non-ionic surfactant, which comprises sorbitol needle fatty acid vinegar, glycerin fatty acid vinegar, polyglycerin fatty acid vinegar, propylene glycol fatty acid vinegar, polyethylene glycol fatty acid vinegar, Yan sugar fatty acid vinegar, polyoxyethylene plant Base shout, polyoxypropylene chitin, polyoxyethylene alkyl benzene fine, polyoxyethylene fatty acid vinegar, polyoxyethylene b. sorbitan fatty acid vinegar, polyoxyethylene sorbitol fatty acid vinegar, polyoxyethylene glycerin fatty acid Vinegar, polyoxyethylene propylene glycol fatty acid vinegar, polyoxyethylene, Sesame oil, polyoxymethylene hardened cannabis oil, polyoxyethylene plant solid slab, polyoxyethylene phytosterol shout, polyoxyethylene dihydrocholesterol shout, polyoxyethylene ethoxylate oxidized rare organic modified 11 Wei Polyoxyalkylene/calcining base is used to change the organic material Wei, polyglycerol to f organic poly-wei, roasting amine, sugar, glycoside, etc.; and amphoteric surfactant, which includes beet test, amine based Acid salt, miso salt derivative, etc. The cosmetic of the present invention can not detract from the effects of the present invention, that is, the feeling of use, the effect of completing the makeup, the continuity of the makeup, the excellent affinity with other components blended in the cosmetic (4), and the quality stability is not impaired. For the safety of the body, the safety of the body, the safety of the environment, etc., and other ingredients used in the cosmetics such as pigments, such as pigment dispersant, oil 201032832 31637pit, surfactant, UV Absorbents, preservatives, antioxidants, film forming agents, humectants, tackifiers, dyes, pigments, various agents (vitamins, astaxanthin, alpha-lipoic acid, Coenzyme Ql (coenzyme Qi〇), etc., spices, and the like. The dosage form of the cosmetic of the present invention is not particularly limited. The dosage form of the cosmetic can be, for example, a previously known dosage form such as an emulsion form, a cream form, a solid form, a paste form, a gel form, a powder form, a multilayer form, a mousse form, and a spray form. Specifically, cosmetic cosmetics include a makeup base, a powder foundation, a liquid® foundation, an oil foundation, a stiek foundation, a compressed powder, and a honey. Powder (facep0wder), white powder, lipstick, lipstick mask, lip gloss, concealer, leg red, eye shadow, eyebrow pencil, eyeliner, mascara (mascara), nail enamel, oily nail polish, emulsified finger oil, enamel t〇p coat, enamel base coat, etc.; skin care cosmetics can be Listed: emollient cream, cold cream, whitening cream, 乳液 lotion, lotion, meiqu liquid, facial mask, carmine lotion, facial cleanser, foam cleanser, facial cleanser, Anti-ultraviolet cosmetics or lotions such as washing cleansing, make cleansing, body gloss, anti-drying or sun-drying cream; hair cosmetics can be listed as: hair gloss, Hair cream, hair shampoo, hair rinse, hair coloring, hair brushing, etc.; antiperspirant cosmetics: creams or lotions, powders , 42 201032832 / pu. Aerosol, ball-type antiperspirant body lotion, etc.; other cosmetics can be listed: milk, liquid, soap, body wash, perfume and so on. (Applications other than the granulated material) The surface-treated powder (the surface-treated powder of the present invention) described above can be applied not only to cosmetics but also to inks, paints, resin masterbatches, papers, and the like. Powder fillers, ceramic materials, magnetic materials, rare earths, optical materials, conductive materials, voltage materials and other fields. Φ Especially when powders which can be used for cosmetics are used in other fields, the surface-treated powders described for the use of the above-mentioned cosmetic materials can be similarly used in other fields. The present invention will be described in detail by the following examples and comparative examples, but the invention is not limited to the examples. [Examples] [Production Examples 1-1 to 1-3] The production examples of the fluorinated copolymer compound used in the present invention are not listed below. • [Production Example 1-1] In a 100 ml four-necked flask equipped with a reflux cooling tube, a nitrogen gas introduction tube, a thermometer, and a stirring device, 18 6 g of a fluorine-containing monomer CH2=CHC(=0)0-CH2CH2C6F13 was charged. (hereinafter referred to as C6SFA (a)), 11.4 g of polyethylene glycol acrylate CH2=CHC(=〇)〇-(CH2CH20)nH (BlemmerAE90, manufactured by Nippon Oil Co., Ltd., the average value of η is 2 ' Hereinafter, ΑΕ90 (b)), 0.3 g of 2-mercaptoethanol, and 45 g of mercaptoethyl ketone (hereinafter referred to as MEK) were carried out, and nitrogen foaming was carried out for 30 minutes. 43 201032832 31637pif After the internal temperature was raised to the thief ~ pit under a nitrogen stream, Q4 g of Perbutyl PV (denoted as pv) was added and allowed to react for 6 hours at the temperature of the machine. Next, the obtained solution was distilled under reduced pressure and at about % ° C to remove MEK, and after obtaining a pale yellow polymer residue, 1224 g of water was added, and the internal temperature was maintained at about 8 (TC was maintained at or above 丨 hours). Thereafter, the mixture was cooled to prepare an aqueous dispersion having a solid concentration of about 20% by weight. [Production Example 1-2] AE90 (b) in Production Example 1-1 was replaced with polyethylene glycol methacrylic acid δ for CH2= C(CH3)C(=0)0-(CH2CH20)n_H (Blemmer® PE350, manufactured by Nippon Oil Co., Ltd., the average value of η is 8, hereinafter referred to as ΡΕ350 (b)), and the production example 1-1 The same polymerization was carried out to prepare an aqueous dispersion having a solid concentration of about 20% by weight. [Production Example 1-3] In a 100 ml four-necked flask equipped with a reflux cooling tube, a nitrogen introduction tube, a thermometer, and a scrambler. 'Loading 18.6 g of C6SFA (a), 5.7 g of AE90 (b), 5.7 g of polyethylene glycol acrylate CH2=CHC(=0)0-(CH2CH20)nH (BlemmerAE200, Japanese oil stocks limited The company manufactured, the average value of η was 4.5, hereinafter referred to as AE200 (b)), 0.3 g of 2-mercaptoethanol, and 45 g of MEK, and the same polymerization as in Production Example 1-1 was carried out. An aqueous dispersion having a solid concentration of about 20% by weight was prepared. [Production Example 1-4] In a 100 ml four-necked flask equipped with a reflux cooling tube, a nitrogen introduction tube, a thermometer, and a stirring device, 18.6 g was charged. C6SFA (a), 10.5 g 44 201032832 A \Jw/ / ΑΕ350 (b), 0.9 g of polyethylene glycol diacrylate vinegar • CH2=CHC(=0)0-(CH2CH20)nC(=0)CH =CH2 (Blemmer ADE300, manufactured by Nippon Oil Co., Ltd., η has an average value of 7), 33 g of dodecanethiol, and 45 g of isopropyl alcohol, and the same polymerization as in Example 1 was carried out. The reaction was carried out to prepare an aqueous dispersion having a solid concentration of about 20% by weight. [Table 1-1] Table 1-1 Compound Structure Remarks - (al) The fluorine-containing copolymer of Production Example 1-1 used in the present invention Treatment of bismuth (bl) fluorinated copolymer of Production Example 1-2 Process of Preparation of Invention 17 (cl) Preparation of fluorinated copolymer of Example 1-3 The process of treatment (dl) used in the present invention Fluoropolymer (17FA/HEMA) disclosed in Production Example 1 of JP-A-2000-290640 (Preparation) of the treatment agent (el) [cf3(cf3)7~15ch2ch 2o] 2p (o) oh The treatment agent of the previous (comparative example) [Examples 1-1 to 1-14 and Comparative Examples 1-1 to 1·14] (al) to (cl) are each used in the present invention. The fluorinated copolymer, the copolymer represented by (11) and the perfluoroalkyl phosphate represented by (el) are the compounds of the foregoing (Comparative Example). Powders subjected to surface treatment with each of the above compounds were produced, and the physical properties of the surface-treated powders were evaluated. The production examples and evaluation items and methods of the surface treatment powder are listed below. (Examples and Comparative Example 1_1) 1 μg of sericin FSE (Sanshin Miner Co., Ltd.) was placed in a high-speed mixer, and each fluorine-containing compound shown in Table 1 having a solid content of 3 g was added, and A mixed solution of IPA (isopropyl alcohol) and water (5 〇 wt%: 5 〇%) 50 g ' and kneaded for 30 minutes. The kneaded product was dried at 8 ° C for 3 hours, and further dried at 110 C for 10 hours. Then, ultrafine pulverization was carried out to obtain fluorochemical-treated sericite. 45 201032832 J IUJ / pu. (Example 1-2 and Comparative Example 1-2) The mica mica Y-2300 (Yamaguchi mica company) used in Example 1-1 and Comparative Example 1-1 was implemented. Examples and Comparative Examples, ^ Surface treatment was carried out in the same manner to obtain each fluorine-containing compound-treated mica. (Examples 1-3 and Comparative Examples 1-3)

The sericite used in the examples and the comparative examples was replaced with talc JA_46R (Asada Milling Co., Ltd.), and each of the fluorine-containing compounds represented by solid content of 5 g / 2 g, respectively, 1-1 was used. The whole gas-fired squama vinegar was used as a treating agent, and surface treatment was carried out in the same manner as in the examples m and the comparative examples, and the talc powder of the composite treatment of each fluorine-containing compound and perfluoroalkyl phosphate was called. (Example 1-4 and Comparative Example 1-4) Each of the fluorine-containing compounds having a solid content of 5 g was diluted with 1 〇 of blood, and then added to 100 g of titanium CR_5 〇 (Ishihara Sangyo Co., Ltd.). After mixing for 15 minutes with a mixer, introduce 25 Torr of superheated steam,

The mixer reaches 200. The stirring was stopped at the time of the enthalpy, and each of the fluorine-containing compound-treated powders was obtained. (Examples 1-5 to 1-7 and Comparative Examples ι_5 to ι_7) The sericites of Example 1-1 and Comparative Example Ui were replaced with yellow LL-100P (Sakamoto Titanium Industrial Co., Ltd.) and red R_516ps (Sakamoto Each of the black fluorine-100P (Nippon Titanium Industries Co., Ltd.) was subjected to surface treatment in the same manner as in Example 1-1 and Comparative Example 1-1 to obtain each fluorine-containing compound-treated powder. (Examples 1-8 and Comparative Examples 1-8) 46 201032832 IT - 100 g of fine particle titanium oxide (MT1〇〇TV: Tayca) was poured into 1500 ml of deionized water to a solid content of 5 g Each of the fluorine-containing compounds was diluted with 500 ml of IPA and then added. Dispersion was carried out by a sand mill (DYNO-Mill: 1.4 L oxidized error container & blade, 〇 5 inm (p yttrium oxide beads, filling rate: 85%) in a cycle of 15 minutes. Heat to 8 〇 < ^, drop 1 〇 % 11 (=; 1 aqueous solution and adjust the pH to 4.5. After dehydration by centrifugation, dry at 12 ° C for 16 hours, then use JET ultrafine The pulverizer was pulverized, and each of the fluorine-containing compound-treated fine particle titanium oxide was obtained. (Examples 1 to 9 and Comparative Example 1 to 9) The solid content of each of the fluorine-containing compounds of Example I-8 and Comparative Example 1-8 was obtained. • By the method shown in Example 1-1 and Comparative Example μ, only the ruthenium solution was used as a solvent to carry out surface treatment, and each of the gas-containing compound-treated fine particle titanium oxide was obtained. (Examples 1-10 and Comparison For each of the fluorine-containing compound ❿ treated powders obtained in Examples 1-8 and Comparative Examples 1-8, the solvents used in the methods of Examples and Comparative Examples were replaced with HFE, and Table W is shown. The solid content of each of the containing compounds relative to the powder was set to 1%, and was carried out in the same manner as in the examples and comparative examples M. The surface treatment was carried out to obtain a double-coated surface-treated fine particle titanium oxide of each fluorine-containing compound. (Examples 1-11 and Comparative Examples to 100 g of fine particle zinc oxide (MZ_300: Tayca Corporation), 5 g Table 1-1 Each of the fluorine-containing compounds 3 g of a direct-transporting dimethicone having a degree of polymerization of 15 at the single terminal having a triethoxy 201032832 group, adding HFE (hydrofluoroether) of g and 50 g of iPA, and kneading by a kneader 3 ,,, after adding 10 g of deionized water and mixing for 3 〇 minutes, drying at 1 〇 5 C for 16 hours, then performing jET ultrafine pulverization to obtain composite granules of each fluorochemical compound and polyfluorene oxide. Zinc oxide. (Examples 1-12 and Comparative Examples ι_ΐ2) 100 g of pearl pigment (Flamenc〇G〇ld: Engelhardt) was added to 1000 ml of deionized water, followed by 15 g of N stearin-based bran Disodium amide (Japan Ajinomoto: Amis〇ft HS_21p) ❿

To dissolve and disperse. Further, the mixture was heated to 80 ° C and 3 g of each of the fluorine-containing compounds shown in Table M was added, followed by kneading for 30 minutes using a kneader. After drying at 13 〇t:T for 8 hours, a composite treated pearl pigment obtained by treating each fluorochemical compound with a thiolated amino acid was obtained. (Examples 1-13 and Comparative Examples i_i3) To 1 μg of Amihope LL (lauryl arginine: Ajinomoto, Inc.), a mixture of IPA/HFE = 15 g/10 g was added and added. 3 g Each of the fluorine-containing treatment agents shown in Table 1-1 was subjected to surface treatment in the same manner as in the methods of Examples 1 to 12 and Comparative Example M2 to obtain 3 10 Amihope LL® at each fluorine-containing compound (Example M4 and Comparative Example M4) 1 〇〇g of Red 2〇2 (癸巳化成公司) was added to a mixed solution of IPA/HFE/deionized water^g/15 g of g, and was mixed by a spiral violet type mixer. On the one hand, using the ultrasonic homogenizer, this Slber Hegner company) is dispersed. 5 g of the sample shown in Table 14 was dropped | 48 201032832 After the fluorine treatment agent was aged with 5 g of IPA, the solvent was distilled off by vacuum heating, and dried at 100 ° C for 16 hours to obtain each fluorine-containing fluorine. The compound was treated with red 2〇2. A list of the examples Μ1 to 1-14 and the comparative examples ^4 to M4 is shown in Table 1-2. [Table 1-2] Example of a good example and a comparative example. Powder compound (al) compound to be surface-treated (bl) Compound (cl) Compound (dl) Compound (el) Sericulture FSE Example 1-1 Example 1-1 Example Μ Comparative Example 1-1 Comparative Example Μ Mica Υ-2300 Example 1-2 tributive Example 1-2 Example 1-2 Comparative Example 1-2 Comparative Example 1-2 Talc JA*46R Example 1-3 Example 1-3 Example 1-3 Comparative Example 1-3 Comparative Example 1-3 Titanium CR-50 Example 1*4 Appreciation Example 1·4 Example 1-4 Comparative Example 1*4 Comparative Example 14 Yellow LL>l〇〇P Example 1-5 Example 1-5 Example 1-5 Comparative Example 1-5 Comparative Example 1-5 Red R-516PS Example 1-6 Implementation Example 1-6 Example 1-6 Comparative Example 1-6 Comparative Example 1-6 Black BL-100P Example 1-7 Example 1-7 Example 1-7 Comparative Example 1-7 Comparative Example 1-7 Particles + Oxidation Example 1-8 Example 1-8 Example 1-8 Comparative Example 1-8 Comparative Example 1-8_Microparticle Titanium Example 1-9 ^Example 1-9 Example 1-9 Comparative Example 1 -9 Comparative Example 1-9 Microparticle Titanium Example 1-10 Example 1-10 it Example 1-10 Comparative Example 1-10 Comparative Example 1-10 Microparticle Zinc Oxide Example 1-11 Example M1 Example 1-11 Comparative Example 1-11 Comparative Example 1-11 Pearl Pigment Real Example • Example 1-12 ^Example 1-12 Example 1-12 Comparative Example 1-12 Comparative Example 1-12 Amihope LL Example 1-13 Example 1-13 Example 1-13 Comparative Example 1-13 Comparative Example 1-13 Red 202 Example 1-14 Example 1-14 Example M4 Comparative Example 1 14 Comparative Example 1-14 (Contact angle test of water and horn alkane) Attach double-sided tape to the glass slide and apply each surface-treated powder on the other side of the double-sided tape with a makeup puff. Until the tape surface loses adhesion. Using a contact angle meter (CA-D) manufactured by Concord Interface Science Co., 'Drip water or squalane on the surface of the powder coating (1 〇" 1)' to measure the droplets and powder after 20 seconds The angle (contact angle) formed by the coated surface. (The number of η is set to 5) (Useability and adhesion test) Functional inspection by 15 functional tests for surface-treated powders 49 201032832

• J / piA member's evaluation of the usability and adhesion of each surface-treated powder for the same powder. The evaluation method is carried out by rubbing with a finger pad or applying it to a fingernail or an upper arm. The evaluation was carried out by absolute evaluation by each functional inspector, and the score was as follows. ◎: Very good, Ο: good, △: normal, X. Poor. (Evaluation method of water repellency and hydrophilicity) About 50 CC of purified water was placed in a 100 CC glass beaker. On the water, the powder of about 〇g is treated, and the spatula is stirred at a frequency of about 2 times per second. The turbidity of the aqueous phase after stirring for 5 〇 a, 150 times was evaluated in five grades. Person <Evaluation Criteria> 5 4 3 2 No turbidity in the aqueous phase. (strong water repellency) The water phase is slightly cloudy. The water phase showed obvious turbidity. Most of the powder is transferred to the aqueous phase. 'Review to transfer to the water phase. (The hydrophilicity is strong) The surface-treated powder of 14 m The evaluation of Examples 1-1 to 1-14 and the comparative example is shown in Table 1-3 to Table 1-5. 50 201032832 lOO /ρχι [Table 1-3]

Table 1-3: Contact angle test results of water/squalane Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Sericite FSE 1357130° 1337133° 1407130° 1247120° 14Γ/1350 Mica Y-2300 1387130° 132713(Τ 1377133° 1267129° 1457137° talcum powder JA-46R 1347127° 130 7125° 1367130° 1267129° 1477130° Titanium CR-50 1307130° 1327133° 1357130° 1367139° 1467139° Yellow LL*l〇〇 p 1377130° 1337131° 1387132° 1367120° 1457135° Red R-516PS 1367130° 135 7123° 1357128° 1367130° 1457130° Black BL*l〇〇p 1307132° 1327134* 1337130° 1367130° 1427131° Microparticle Oxidation 1327130° 132 7133 ° 1377124° 1367131° 1457130# Microparticles titanium oxide 87130° 107132° 10°/133° 1367130° 1457140° Microparticles titanium oxide 97130° 127133° 87130° 1367138° 1437141° Microparticle zinc oxide 1307131° 1327130° 1307132° 1367130° 1457130° Pearl Pigment 1337130° 132 7133° 1397131° 1367137° 1447130° Amihope LL 107125° 137135° 107128° 1367133° 1457131° Red 202 1357130 ° 1327133° 1407133° 136713Γ 1447136° [Table 1-4] __ Table 1~4: Usability/Adhesion Test Results Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) 绢Mica FSE ◎/◎ 〇/◎ 〇/◎ χ/χ Mica Y-2300 〇/◎ 〇/◎ 〇/◎ Δ/Δ χ/χ talc JA-46R 〇/x Δ/χ Titanium CR-50 〇/ ◎ 〇/◎ 〇/◎ Δ/χ χ/χ Yellow LL-100P 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/χ Red R-5i6PS 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/ χ Black BL-100P 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/χ Microparticles TiO 2 / 〇 ◎ / ◎ 〇 / ◎ 〇 / △ χ / χ Microparticles vaporized titanium 〇 / χ Δ / χ Microparticle oxidation 〇/χ Δ/χ Microparticle oxidation “ 〇/◎ 〇/◎ 〇/◎ Δ/Δ χ/χ Pearl pigment Δ/Δ χ/χ Amihope LL Δ/Δ χ/χ Red 202〇/◎ 〇/◎ 〇/◎ Δ/Δ χ/χ 51 201032832 ilOJ/pit [Table 1-5]

Examples 1-9 and M〇 and Examples The powders have a pro-integration. Each of the surface-based powders has a high feeling of use and adhesion. [Examples 1-15 to 1-32 and Comparative Examples

Next, an embodiment of a cosmetic compound to be combined with the surface-treated powder of the present invention will be described. Various cosmetics were produced by the following methods based on the respective compositions of the following tables. In addition, the cosmetic materials obtained in the respective examples and the comparative examples were prepared for each evaluation by two professional inspectors for the use feeling, the makeup effect, and the makeup sustainability, and the cosmetics were used for one day. The evaluation was performed according to the evaluation criteria shown in Tables 1-6 to 1-8 below, and the total score of all the functional inspectors was divided by 20 to obtain a score. 52 201032832

JlUJ/pil [Table 1-6] [Table 1-7]

Table 1-7 ·····················································································

Table 1-6: Evaluation criteria for feeling of use 1 The score is very good. ◎The feeling of use is good. The feeling of use is normal. ・The feeling of use is poor. △ The feeling of use is very poor. X The item for the finish is evaluated for makeup and skin care. The uniformity of the effect, the protective force, the natural luster, the uniformity of the cosmetic film, and the evaluation of whether or not the antiperspirant cosmetic material has a sticky feeling or a greasy feeling. The hair cosmetic material is evaluated for glossiness, dryness, smoothness, and ease. Board. [Table 1-8]

Table 1-8: Evaluation of makeup persistence Μ -- Rating Feeling very effective ◎ Feeling effective~' 感觉 Feeling slightly effective · Only feeling small effect Δ ~ & No effect ~ ' X

The item of the make-up powder is set to prevent the skin from being dull, preventing secondary adhesion (color shift), and preventing oily light. In addition, it is not easy to strip off for the beauty. (Examples 1-15 and Comparative Examples 1-15) Production of Powder Cake The powder cake of the composition shown in Table 1-9 was produced by the following method. The results of (10) 53 201032832 31637pit are not shown in Tables 1-10. [Table 1-9] Table 1-9: Composition _ _ --! Parts by weight (1) Sericite (Example 14 and Comparative Example 1-1) 35 0 (2) Talc powder (Example 丨 _3 and comparison Example 1-3) Residual Scene (3) Titanium Oxide (Examples ι_4 and Comparative Examples 1-4) 8 S (4) Yellow Iron Telluride (Examples 1-5 and Comparative Examples 1-5) (5) Red Oxidation Iron (Examples 1-6 and Comparative Example J · Ο ------ 1 0 (6) Black Iron Oxide (Examples I-7 and Comparative Examples I·7) One ~~-1^. Π 0 (7) Octyl dodecyl myristate-_______U·/ 4 0 (1) horn shark 炫---- ~~ 1 C (9) methyl phenyl polyoxy siloxane ~~ --±1 1 C (1) Preservative - He (11) Fragrance ------ Appropriate amount (Preparation method) The above components (1) to (6) are mixed and pulverized by a pulverizer, and transferred to a high-speed blending machine. In the middle, the component (7) is heated and mixed uniformly, and then uniformly mixed. The mixture is passed through a pulverizer, sieved to have a uniform particle size, and then compression-molded in an aluminum vessel at a surface pressure of 1 MPa. And make a dual-purpose powder cake. [Table 1-10] ▼ Price Item Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Using 〇〇 Δ Δ " Uniformity of completion effect 〇〇 ◎ Δ Δ Makeup continuity ◎ H ◎ ◎ 〇〇 (Examples 1-16 and Comparative Example) 16 Manufacture of emulsified foundation The W/〇 type liquid foundation of the composition shown in Table 丨-U was produced by the following method. The evaluation results are shown in Table 1-12. 54 201032832

JlOJ/pu [Table Ml] Table 1-11: Ingredient parts by weight (1) Shiyan ring, Wu Shixi Oxygen Burn 20.0 (2) Vaseline 0.5 (3) Methylphenyl polyoxane 2.3 (4) Shark Alkane 4.2 (5) Isotridecyl isononanoate 4.5 (6) Dimethyl polyoxyalkylene polyoxyalkylene polymer (HLB (hydrophile-lipophile balance) = 4.5) 3.0 (7) Red iron oxide (Examples 1-6 and Comparative Examples 1-6) 1.3 (8) Yellow iron oxide (Examples 1-5 and Comparative Examples 1-5) 2.4 (9) Black iron oxide (Examples 1-7 and Comparative Example 1-7) 0.1 (10) Titanium Oxide (Examples and Comparative Examples 1*4) 8.0 (11) Talc Powder (Examples 1-3 and Comparative Examples 1-3) 2.5 (12) Ethanol 5.0 (13) 1,3-butanediol 5.0 (14) sodium vaporized 2.0 (15) purified water remaining amount (16) AmihopeLL (Examples 1-13 and Comparative Examples 1-13) 5.0 (17) Preservatives (18) Spices " - Moderate (method)

The above components (7) to (11) are mixed and pulverized in advance. To the oil phase obtained by uniformly dissolving and mixing the components (1) to (6) at 7 ° C, a mixture of the previously pulverized components (7) to (11) was added, and the mixture was uniformly homogenized by a homodisperser. Disperse. The aqueous phase obtained by uniformly mixing and dissolving the components (12) to (17) at 70 ° C is slowly added to the above oil phase, uniformly dispersed by a homogenizer, cooled, and the component (18) is added and sized. The emulsion is emulsified to produce a liquid foundation. 55 201032832 31637pit [Table 1-12] Table 1-12 Evaluation item Compound (al) Compound (M) Compound (cl) Compound (dl) Compound (el) i Sense - ◎ 〇 ◎ Δ Δ Complete effect uniformity 〇 ◎ ◎ X Δ Make-up persistence ◎ ◎ ◎ △ Δ Quality stability *1 Good good good good difference

Ice 1 quality stability is at 50. The temperature was observed in the thermostat bath for one week, and the viscosity, separation, and sedimentation were observed. Those who did not change in appearance were regarded as good. The cosmetic materials blended with the treated powders of the compounds (d) and (e) of the comparative examples occurred the next day. Separation, poor quality stability. (Example 1 - Π and Comparative Examples 1-17) Manufacture of eye shadow The eye shadow of the composition shown in the table was produced by the following method. The evaluation results were not in Tables 1 - 14. [Table 1 - 13] 1·decamethylcyclopentaoxane 2·dimethylpolyoxane (6 cs) ]. polyfluorene modified polyoxo*2 4.PEG (10) lauryl ether 5. titanium oxide (implementation Examples 1 to 4 and Comparative Examples 1 to 4) _ 1· Red Iron Oxide (Examples 1-6 and Comparative Example 1·Pearl Pigments (Examples 1-12 and Comparative Example 1-1) 5 Gasification Sodium 9. Propylene Glycol 10. Preservatives ll. Spices 12. Purified water components 1-13

*2KF6026 : Shin-Etsu Chemical Manufacturing (manufacturing method) (1) Combine the ingredients 1 to 4, add the ingredients $ scatter. 7 and mix well 56 201032832 -> OJ / pu (2) The ingredients 8~l〇 And component 12 is uniformly dissolved. And (3) the mixture obtained in (2) was slowly added to (1) the obtained mixture under stirring to carry out emulsification and the addition of the component 11 eye shadow. [Table 1-H] __ Table 1-14 _ Evaluation item Compound (al) Compound (bl) lb^ (cl) Using the feeling of © 〇 〇 〇 效果 效果 ◎ ◎ 化妆 化妆 ◎ ◎ ◎ ◎ ◎ Society,

',, Cut C|, J ^, Raw solid powder The oily bottom of the composition shown in Table 1-15 was produced by the following method. The evaluation results are shown in Table 16 [Table 1-15] Table 1·15:

(4) Polyglyceryl triisostearic acid _ (5) Volatile liquid isoparaffin (6) Ant (ceresin (7) Candidella ___ (8) Red iron oxide (Examples 1-6 and Comparative Examples) 1-6) Fly 9) Titanium telluride (Example Μ and Comparative Example Ml" Ί: 10) Talc (Example 1-3 and Comparative Example 1-3^ _(11) Preservative _ ^' (12) Perfume (manufacturing method) The above components (8) to (10) are preliminarily mixed and pulverized. In the oil phase obtained by mixing and dissolving the components (1) to (7), the method 85 <: adding the pre-comminuted component (8) ~ (11) and use a uniform dispersing machine to uniformly singularly. ^ 57 201032832 31637pif Adding a fragrance to it, filling it into a metal vessel, and cooling to produce an oily solid foundation. [Table 1-16] Table 1·] 16 Evaluation item Compound (al) Compound _ (M) Compound (cH compound (dl) Compound (el) Uniformity of effect is achieved by using 〇〇 △ X ◎ ◎ • X Make-up performance -- ◎ ◎ • δ ( Example M9 and Comparative Example 1919) Manufacture of emulsified sunscreen cream

An emulsified sunscreen having the composition shown in Table 1-17 was produced by the following method. The evaluation results are shown in Table 1-18. » M7] 1·Volatile liquid isoparaffin (isododecane) 2. Dimethyl polyoxane (6csj Table 1-17 ingredients

*3 Example 1-8 and Comparative Example fluoroether (HFE7200: Sumitomo 3M Co., Ltd.) was dispersed in a sand mill at a concentration of 3 〇: 7 〇 (parts by weight, and dispersed to form a dispersion. Co-assembled surface coated with New Zealand, its pigment dispersion ability and ^

58 201032832 High stability. 7 ^ The oil phase components of the components (1) to (9) other than the component (8) are dissolved. The aqueous phase components of the components (10) to (14) were dissolved, and the homogenized liquid was added to the oil phase component, and emulsified by a homogenizer. Finally, ingredients (8) and (15) are added and cooled to produce a sunscreen. Breaking into [Table 1-18]

Evaluation of the use of the sense of uniformity of the effect of the finished makeup SPF value * 4 : ^ compound (4)) ◎ 〇 ◎ 23 Table 1-18 Compound (bl) 〇 ◎ ◎ 25 Compound (cl) 〇 _ compound (dl △ Compound (el) ◎ ◎ 26 20

X X 15 乂古 Γ1Γ is the value of the shielding effect of the SPF (sun pr〇tecti〇n faCt〇r, sun protection factor) it line (UVB), and the better the UV shielding effect is. Attached to the 3m company's surgical knee, this company-tape) is attached to the quartz glass plate at 〇·08 g/cm2

啰f was applied to the tape surface and was removed using a US-company SPF analyzer.夭罔p and Comparative Example 1-2〇) Production of eyeliner (4) 娄-于: 1 f to produce an eyeliner of the composition shown in Table M9. The evaluation results will not be as shown in Table 1-20. 59 201032832 31637pif Component parts by weight (1) Decamethylcyclopentaoxane 25.0 (2) Dimethyl polyoxane (6cs) 4.0 (3) Jojoba oil 2.5 (4) Polyether modified polyoxyl *5 1.0 (5) Black iron oxide (Examples 1-7 and Comparative Examples I·7) 20.0 (6) Ethanol 5.0 (7) Preservatives (8) Remaining amount of purified water *5 KF6026: Shin-Etsu Chemical Co., Ltd. ( (Method) (1) Components 1 to 4 were mixed at 70 ° C, and component 5 was added and uniformly dispersed. (2) The components 6 to 8 were heated and dissolved at 70 ° C to dissolve. (3) The mixture obtained in (2) was slowly added to the obtained mixture in (1) under stirring, and emulsified to obtain an eyeliner. [Table 1-20] The evaluation item used ϋ The effect of the finished makeup continued, ιϊΓ Compound (al) Q~~33 〇 ◎ Compound (bl) 〇 ◎ ◎ ◎ (Example 1-21 and Comparative Example 1-21) Lipstick The results of the manufacture of the composition shown in Table 21 by the following method are shown in Table 1-22. Compound (cl) 〇 ◎

. Will be evaluated 201032832

JlOJ/pu [Table 1-21] Table 1-21: Ingredient parts by weight 1. Diisostearyl malate 15.0 2. Residual amount of triisooctanoic acid glyceride 3. Gluconate phytol octyldodecanol Ester 15.0 4. Carnauba wax 3.5 5. Candidella wax 5.5 6. Ground soil 5.0 7. Titanium oxide (Examples 1-4 and Comparative Examples 1-4) 8.0 8. Red 202 (Examples 1-14 and Comparative Example 1-14) 0.7 9_black iron oxide (Examples 1-7 and Comparative Examples 1-7) 0.2 10. Preservative amount

(Production Method) (1) Components 7 to 9 were added to the component 1 and mixed by a roller to be uniformly dispersed. (2) After heating and mixing other components, the above component (1) is added and uniformly dispersed by a homogenizer. (3) After degassing, it flows into the mold to obtain a stick-like lipstick. [Table 1-22] Table 1-22 Evaluation item Compound (al) Compound (b1) Compound (cl) Compound (dl) Compound (el) Using sensation • • Uniformity of effect 〇 ◎ ◎ Δ X Makeup Sustainability ◎ ◎ Δ 〇 (Example 1-22 and Comparative Example 1-22) Production of Lipstick Film A lipstick film having the composition shown in Table 1-23 was produced by the following method. The evaluation results are shown in Table 1-24. 61 201032832 31637pif [Table 1-23] Table 1-23: Component parts by weight (1) Perfluoropolyether (Fomblin HC-04) 91.5 (2) Sebolite (Aerosil R-972) *6 2.0 (3) Microparticles Titanium oxide (Examples 1-8 and Comparative Examples 1-8) 6.0 (4) Glycerol 1.0 *6 was compounded with each of the fluorine-containing compounds of 5% by the methods of Example 1-1 and Comparative Example 1-1 ( Al)~(el) is a surface treatment. (method of law)

After the component (2) and the component (3) are added to the component (1) and uniformly dispersed, the component (4) is added to prepare a lipstick film. [Table 1-24] Table 1-24 Evaluation item Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Using sensation • Uniformity of effect 〇 ◎ ◎ △ X Makeup Sustainability ◎ ◎ Δ 〇 (Examples 1-23 and Comparative Examples 1-23) Production of Emulsion-Based Liquid Foundation A 0/W type liquid foundation having the composition shown in Table 1-25 was produced by the following method. The evaluation results are shown in Table 1-26.

62 201032832

JIOJ/piI

[Table 1-25] Table 1-25

(Production Method) A: The components (1) to (6) are dissolved by heating. B. The components (7) to (13) are uniformly heated and dissolved.

C. Adding the 'thinking compound' obtained by adding b to the mixture obtained by adding A component (14) to (18) after cooling, and uniformly mixing to produce a powdery liquid 0 [Table 1-26] Table 1 26 Evaluation item Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound & Uniformity of effect by using sensation 〇 ◎ Δ % Make-up continuity ◎ ◎ ◎ △ (Example 1_24 and Comparative Example 1_24) Production of skin color lotion A skin color lotion of the composition shown in Table 1-27 was produced by the following method. The evaluation results are shown in Table 1-28. 63 201032832 31637pif [Table 1-27] Table 1.27 Component parts by weight (1 ) N-stearyl sulfhydryl-L-glutamic acid 0.5 (2) Cetyl alcohol 0.5 (3) Polyoxyethylene (10 mol) Monostearate 0.8 (4) Decaglycerol monoisostearate 1.0 (5) Sorbitol sesquioleate 0.4 (6) Methyl phenyl polyoxyalkylene 5.0 (7) Glycerol 5.0 ( 8) 1,3-butanediol 5.0 (9) Sanxianjiao 0.1 (10) Carrageenan 0.05 (11) Triethanolamine 1.0 (12) Preservative amount (13) Purified water remaining amount (14) Titanium oxide (implementation Example and Comparative Example 1*4) 2.0 (15) Yellow Iron Oxide (Examples 1-5 and Comparative Examples 1-5) 1.0 (16) Red Iron Oxide (Examples 1-6 and Comparative Examples 1-6) 0.5 (17) Black iron oxide (Examples 1-7 and Comparative Examples 1-7) 0.1 (18) Talc powder (Examples 1-3 and Comparative Examples 1-3) 3.0

(Production Method) A: The components (1) to (6) are dissolved by heating. B: The components (7) to (13) were uniformly heated and dissolved.

C: A mixture obtained by adding B to the mixture obtained from A, and after cooling, components (14) to (18) were added, and uniformly mixed to prepare a skin color emulsion. [Table 1-28] Table 1-28 Evaluation item Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Using the feeling ◎ 〇〇 Δ Δ The uniformity of the effect 〇 ◎ ◎ Δ Δ Makeup Sustainability ◎ ◎ 〇〇 实施 (Examples 1-25 and Comparative Examples 1-25) Production of a nail material The enamel composition of the composition shown in Table 1-29 was produced by the following method. The evaluation results are shown in Table 1-30. 64 201032832

JiOJ /pu

[Table 1-29] Table 1-29: Component parts by weight (1) Nitrocellulose 10.0 (2) Alkyd resin 10.0 (3) Ethyl citrate tributyl acrylate 4.0 (4) dl-camphor 1.0 (5 Organically modified hectorite 1.0 (6) ethyl acetate 20.0 (7) butyl acetate remaining amount (8) isopropanol 5.0 (9) red 202 (Examples 1-14 and Comparative Examples 1-14) 0.1 (10) titanium oxide (Example 14 and Comparative Example 1-4) 3.0 (11) Pearl pigment (Examples 1-12 and Comparative Examples 1-12) 5.0 (12) Red iron oxide (Examples 1-6 and Comparative Example 1·6) 0.5 (Production Method) The components (1) to (9) were mixed and dropped by a disperser. The ingredients (10) to (12) were added thereto, and the mixture was mixed by a disperser for 10 minutes to prepare a nail material, which was filled in a glass bottle. [Table 1-30] -------Table] •30 Evaluation item Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Using sensible δ 〇Δ Δ to complete the effect Uniformity 〇〇〇Δ Δ Makeup continuity ◎ © ◎ 〇〇

Further, the nail stock which is combined with the surface coated with the specific fluorinated copolymer of the present invention does not form a hard cake over time, and the dispersion is stable. 26) The blush is produced by the production of blush. Evaluation (Examples 1-26 and Comparative Examples) Tables 1-32 were produced by the following methods. 65 201032832 31637pif [Table 1-31] Table 1-31: Component parts by weight (1) Mica (Example 1 -2 and Comparative Example 1-2) 14.0 (2) Titanium oxide (Examples 1-4 and Comparative Examples 1-4) 10.0 (3) Yellow iron oxide (Examples 1-5 and Comparative Examples 1-5) 1.0 ( 4) Red iron oxide (Examples 1-6 and Comparative Examples 1-6) 0.5 (5) Black iron oxide (Examples 1-7 and Comparative Examples 1-7) 0.1 (6) Talc powder (Examples 1-3) And Comparative Example 1-3) Remaining amount (7) Perfluoropolyether (FomblinHC-04) 7.0 (8) Dimercaptopolyoxyalkylene (10CS) 5.0

(Production Method) The components (1) to (6) were uniformly mixed and pulverized. The components (7) and (8) were added thereto and uniformly mixed, and then pulverized to produce a blush. [Table 1-32] Table 1-32 Evaluation item Compound (al) Compound (b1) Compound (cl) Compound (dl) Compound (el) Uniformity of effect by using 〇〇〇 XX ◎ ◎ 〇Δ Δ Make-up ◎ ◎ ◎ 〇〇 (Examples 1-27 and Comparative Examples 1-27) Production of Antiperspirant Cosmetics A rod-shaped antiperspirant cosmetic having the composition shown in Tables 1-33 was produced by the following method. The evaluation results are shown in Table 1-34.

66 201032832 10J /pil [Table 1-33] Table 1-33: Ingredient parts by weight (1) Carnauba wax 1.0 (2) Ground wax 6.0 (3) Stone soil (paraffinwax) 3.0 (4) Sorbitan half Isostearate 2.5 (5) 2-ethylhexanoate cetyl ester 27.0 (6) squalane 2.0 (7) deuterated base pentane oxane remaining (8) hydroxylated aluminum 25.0 (9) Sericite (Example 1-1 and Comparative Example 1-1) 10.0 (10) Talc powder (Examples 1-3 and Comparative Examples 1-3) 8.0 (11) Microparticulate zinc oxide (Examples 1-11 and Comparative Examples) 1-11) 2.0 (12) Proper amount of antioxidant (13) Proper amount of flavor (preparation method) The components (1) to (7) are heated and uniformly dissolved. After the components (8) to (12) were added thereto and uniformly mixed, the component (13) was added and cooled to produce a rod-shaped antiperspirant cosmetic. [Table 1-34] Table] -34 Evaluation item Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Using 〇 〇 〇 XX to complete the uniformity of effect ◎ ◎ 〇 Δ △ Make-up Sex ◎ ◎ ◎ 〇〇

(Examples 1-28 and Comparative Examples 1 - 2 8 ) Hair treatment 6h A hair care composition having the composition shown in Tables 1 to 35 was produced by the following method. The evaluation results are shown in Table 1-36. 67 201032832 31637pif [Table 1-35] Table 1-35 ·· Component parts by weight (1) Ethylene glycol distearate 1.0 (2) Liquid paraffin 10.0 (3) Squalane 5.0 (4) Stearyl alcohol 1.5 (5) Dimercapto polyoxyalkylene (10cs) 3.0 (6) Stearic acid 6.0 (7) Polyoxyethylene (3) Stearyl alcohol 4.5 (8) Polyoxyethylene (150) cetyl ether 2.0 (9 Organically modified bentonite 0.2 (10) AmihopeLL (Examples 1-13 and Comparative Examples 1-13) 2.0 (11) 1,3-Butanediol 6.0 (12) Preservatives (13) Proper amount (14) Purification Water remaining amount (preparation method) A: The components (1) to (9) are heated and uniformly dissolved. The component (10) was added thereto and uniformly dispersed. B: The components (11), (12), and (14) are heated and mixed. C: The mixture obtained by mixing B was added to the mixture obtained in A, and after cooling, the component (13) was added and cooled to prepare a hair lotion. [Table 1-36] Table 1-36 Evaluation item Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Uniformity of effect was achieved using 〇, ◎ 〇 ◎ ◎ ◎ Δ Δ Makeup Sustainability ◎ ◎ Δ Δ (Examples 1-29 and Comparative Examples 1-29) Production of skin color cosmetic liquid The skin color moisturizing beauty liquid having the composition shown in Tables 1-37 was produced by the following method. The evaluation results are shown in Table 1-38. 68 201032832 J10 J /pu [Table 1-37] Composition

(1) Purified water _______ (2) Acrylic acid alkyl (c10~30) — (3) Carboxyvinyl polymer preparation ~~^ (4) Anti-corrosion plant (5) Particulate titanium oxide (Example 1- 9 and Comparative Example (6) Triethanolamine ~~ (7) Glycerin ___ (8) Oxygen (1*4 and Comparative Example 1-4) T9) Yellow "13⁄4 iron (Examples 1-5 and Comparative Examples _ (10) Red iron oxide (Examples 1 and 6 and Comparative Example 0)

(U) Iron (Examples 1-7 and Comparative Examples (12) (Examples 1-3 and Comparative Examples 1-3: (Production Method) Α: The components (1) to (4) were heated and uniformly divided (5) and uniformly dispersed. Mixing. ^Ingredient (4) is added to the crucible: the components (8) to (1) are uniformly mixed, and the ingredients are added and uniformly mixed. Knives (7) C: The mixture obtained by mixing the crucible is added to the mixture obtained from the crucible, and is produced. Skin color moisturizing lotion. β [Table 1-38] Evaluation item Compound (al) J Compound (Μ) -JO Compound (cl) Compound (dl) Compound (el) Completed with sensation XX • Uniformity of effect ◎ ◎ Δ Δ Δ plate sustainability ◎ ◎ • 〇 (Example 1-30 and Comparative Example 1-30) Production of liquid eye shadow The aqueous liquid eye shadow of the composition shown in Table 1 to 39 was produced by the following method. The evaluation results are shown in Table i-40. 69 201032832 31637pif [Table 1-39] Table 1-39: Component parts by weight (1) Remaining amount of purified water (2) Copolymerization of acrylic acid/alkyl methacrylate (C10~30) ester 0.1 (3) carboxyvinyl polymer 1.0 (4) preservatives appropriate amount (5) triethanolamine 0.7 (6) glycerol 25.0 (7) titanium oxide Example 1-4 and Comparative Example 1 > 4) 2.5 (8) Red iron oxide (Examples 1-6 and Comparative Examples 1-6) 2.0 (9) Pearl pigment (Examples 1-12 and Comparative Example M2) 8.0 (method of law)

A: After the components (1) to (4) are heated and uniformly dissolved, the component (5) is added and uniformly mixed. B: After uniformly mixing the components (7) to (9), the component (6) is added and uniformly mixed. C: A mixture obtained by mixing B was added to the mixture obtained in A to prepare a liquid aqueous eye shadow. [Table 1-40] Table 1-40 Evaluation item Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Uniformity of effect is achieved using 〇〇〇ΔΔ ◎ ◎ ◎ Δ Δ Makeup Sustainability ◎ ◎ 〇〇 实施 (Example 1-31 and Comparative Example 1-31) Production of Whitening Powder The whitening powder of the composition shown in Table 1-41 was produced by the following method. The evaluation results are shown in Table 1-42. 70 201032832 / pir [Table 1-41] Table 1-41: Component parts by weight (1) L-ascorbyl phosphate 1.0 (2) Sodium citrate 1.0 (3) 1,3- Butanediol 5.0 (4) Glycerol 5.0 (5) Remaining amount of purified water (6) Methylparaben 0.2 (7) Mica (Examples 1-2 and Comparative Examples 1-2) 5.0 (8) Talc ( Examples 1-3 and Comparative Examples 1-3) 0.1 (9) Organic Polyoxane Elastomer Powder 3.0 (10) Trifluoroalkyldimethyltrimethyl-oxacyloxycruise 3.0 (11) Partial Crosslinking Type organopolyoxane polymer *7 5.0 (12) Red iron oxide (Examples 1-6 and Comparative Examples 1-6) 0.5

*7KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd.) (Production Method) A: The components (7) to (9) are mixed and pulverized. B: After uniformly mixing the components (11) to (12), it is added to the mixture obtained in the above A. C: Components (1) to (6) were mixed and dissolved. D: The mixture obtained in the above B was mixed with the mixture obtained in C, and filled into a container to obtain a whitening powder. 71 201032832 31637pif [Table 1-42] Table 1.42 Evaluation item Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Uniformity of effect is achieved using 〇〇〇ΔΔ ◎ ◎ ◎ Δ Δ _ Make-up persistence ◎ ◎ ◎ 实施 (Examples 1-32 and Comparative Examples 1-32) Manufacture of the sunscreen cream The sunscreen cream of the composition shown in Table 1-43 was produced by the following method. The evaluation results are shown in Table 1-44.

[Table 1-43] Table 1-43: Ingredient parts by weight 丨)_Decamethylcyclopentaoxoxime 15.0 (2) Poe-modified poly-stone oxygen containing long-bonding group (AbilEM-90: Degussa) 2.0 C3) Isodecyl isodecanoate 5.0 14) Diethylhexyl succinate 5.0 (5) Avobenzone (avsol 1789: DSMNutrition Japan) 0.8 octocrylene (EusolexOCR) : Merck Company) 5.0 (7) Microparticle Zinc Oxide (Examples 1-11 and Comparative Examples 1-11) 10.0 (8) Remaining amount of purified water (9) Glycerol 3.0 U0) Acetate 5.0 Microparticles Dispersion of titanium telluride ( Examples 1-10 and Comparative Examples M0) *8 10.0 Lil2) Preservatives

*8 The composition of the fine particle titanium oxide / purified water / glycerin 2 45 / 5 / 5 of Examples 1-10 and Comparative Example 1-10 was dispersed by a sand mill to prepare an aqueous dispersion. The aqueous dispersion of the examples does not settle and separate 'steadily over time. The dispersion of the dispersion of the comparative example did not proceed, and the unsalted t formed a uniform and stable dispersion. % (Processing method) A ····················· B: After uniformly mixing the components (1) and (2) and (6), they are added to the mixture obtained in the above A. 72 201032832

^ΛΟ^/pU c : The components (8) to (12) are mixed and dissolved. D 1 The mixture obtained by adding C to the mixture obtained in the above B was emulsified to obtain an anti-sun cream. [Table 1-44]

Evaluation item Compound (al) Table: Compound (bl) -44 Compound (cl) Compound (dl) Compound (el) ◎ ◎ ◎ XX 7C Wind Shuanghe Uniformity 4 匕 Makeup Continuity ◎] ◎ ◎ ◎ △ Δ Quality Stability 氺9 ◎ ◎ ◎ ◎ ◎ △ X △ X *9 The quality stability was placed in a thermostatic bath for 1 week, and the presence or absence of crystallization of the ultraviolet absorber and separation and sedimentation were observed. A cosmetic material having no change in appearance such as crystallization was recorded as good. The cosmetic compound blended with the treated powder of the compound (dl) and (el) of the comparative example was crystallized on the next day to be separated, and the quality stability was poor. (Example 1-33 and Comparative Example ι·33) 10 g of talc powder JA-13R (Asada Milling Co., Ltd.) was placed in 5 g of water prepared in a 2 L glass beaker, and thoroughly stirred. And make it 73 1 recorded. The dissolution product of the production example M of Comparative Example M and the comparative compound (el) and 1 〇g of ΙρΑ in a solid content of 3 g was slowly added, followed by stirring for 15 minutes. The glass beaker is transferred to a hot plate and heated at a temperature of 3t:/min. After the temperature reaches the thief, the temperature is maintained. During the temperature rise, the polymer of the surface treatment agent has a compound having an oxy-ethyl group in the polymer molecular structure (al) ) to (dl) dehydration due to the phenomenon of fogging, encapsulation of the powder particles and coating treatment) After stirring for 15 minutes, dehydration, washing, and drying (1151/16 hours), and using an ultrafine pulverizer The pulverized powder was treated by pulverization to obtain each fluorochemical compound. 201032832 31637pif (Examples 1-34 and Comparative Examples 1-34)

1 g of talc powder JA-13R (Asada Milling Co., Ltd.) was placed in 500 g of water prepared in a 2 L glass beaker, and the mixture was sufficiently stirred and dispersed. The solution of the fluorinated copolymer of Production Example 1·4 and Comparative Example Compound (el) and 10 g of hydrazine in a solid content of 3 g was slowly added, followed by stirring for 15 minutes. Next, while maintaining the stirring, a solution obtained by dissolving 30 g of NaCl in water of i〇〇g was slowly added. (In the process of slow addition, the compound having an oxyethyl group in the molecular structure of the surface treatment agent (al) to (dl) is dehydrated by salting out, and the powder particles are coated and coated). After 15 minutes, dehydration and washing were carried out 'dry (ll 5 ° c / 16 hours) and pulverized by an ultrafine pulverizer to obtain each fluorochemical-treated talc powder. (Examples 1-35 and Comparative Examples 1-35)

100 g of talc JA_13R (Asada Milling Co., Ltd.) was placed in 5 g of water prepared in a glass beaker of 2 L, and sufficiently stirred to be more dispersed. The production example 丨4 of 3 § in terms of solid content and the lysate of the fluorinated copolymer of the compound (e2) and 100 g of IPA were added slowly, followed by stirring for 15 minutes. The slurry thus obtained was supplied to a spray dryer of a nozzle. The inlet hot air of the spray dryer is C's two-fluid nozzle when the attack force is set to "Gal. So the fluorochemical treatment of each fluorinated compound is obtained. (Example 1-36 and Comparative Example 1-36) 5 kg of talc powder jA·^ (Asada Milling Co., Ltd.) was mixed with 5 kg of water by a kneading machine to make a secret. The investment was determined by the solid content of 3 Lu. 74 201032832 1 case 1/4 and comparative compound The fluorinated copolymer of (el) was subjected to mechanochemical treatment using a Dendrobium grinder Supermasscolloider (MKCA 6-2: Zeng Xing Industrial Co., Ltd.), and the obtained slurry was dried by a vacuum vibration dryer. The fluorinated compound-treated talc powder was obtained. (Examples 1-37 and Comparative Example 1_37) Titanyl sulfate crystals were put into water and subjected to heat addition, and the produced hydrolyzate was filtered and washed. 350 g of the obtained aqueous titanium oxide cake (titanium oxide content: g) was added to 400 g of a 48% aqueous sodium hydroxide solution while stirring, and the mixture was heated and stirred at a temperature of 95 to 105 ° C for 2 hours. Next, filtering and cleaning the titanium dioxide A suspension of the compound was prepared by adding 500 g of water to the washed cake, and further, 140 g of 35% hydrochloric acid was added while stirring, and the mixture was heated and aged at 95 C for 2 hours. The aqueous suspension/tantalum concentration of titanium oxide was adjusted to 70 g/L. To the aqueous suspension, polygasification was added (10 wt% with respect to the fine particle titanium oxide, ai2o3), and the pH was adjusted to use caustic soda. 5.0 and aging for 30 minutes. After aging, the fluorinated copolymer of Production Example 1-4 and Comparative Example Compound (el) in an amount of 7 wt% based on the solid content of titanium oxide was put and aged for 30 minutes. The mixture was filtered, washed, dried, and pulverized by an ECK superfine pulverizer. Thus, each fluorochemical-treated fine particle titanium oxide was obtained. (Examples 1-38 and Comparative Examples 1-38) The manufacture of the sun-proof condensation was performed by The anti-sun gels of the compositions shown in Tables 1-45 were prepared by the following methods. The evaluation results are shown in Table 1-46. 75 201032832 31637pif [Table 1-45] --_ parts by weight / 1 ^ -tj- . 'i — ----------- , i J a /W __ —-- 5.0 (2) Long-chain alkyl acrylate-methacrylic acid^ --- (Pemulen TR-1: BF Goodrich) 0.3 (3) Methyl p-hydroxybenzoate - 0.2 (4) Purified water ~~~~---- to 100.0 (5) Potassium argon oxide-- -- 0.2 (6) purified water ' ----- 5.0 (7) microparticle oxidation (example and ratio one - 10.0 (8) p-dimethylaminobenzoic acid isooctyl ester ~---- - 5.0 (9) Glycerol monooleyl ether ' -~--- 1.0 (Method of preparation)

The components (1) to (4) were heated to 8 ° C and dissolved. The components (5) and (6) were heated to 80 ° C and dissolved. Neutralization was carried out by adding the components (5) and (6) which were dissolved by heating to the above components - (4). The components (7) to (9) were heated to 80 ° C and mixed and dispersed. The components (7) to (9) were slowly added to the above neutralized components, and emulsified by a homogenizer to obtain an anti-sun pigment. [表卜46] Table 1.46

Evaluation item Example Comparative use Sense of use © ~ △ Completeness of effect δ △ Make-up persistence @ △ In vitro SPF value of preparation 20 15 Stability over time * 10 〇 ~~~ X

* 10 The preparation was stored at 50 C for 1 month. The cosmetic which has no change in appearance is recorded as 〇, and the cosmetic which has changed is recorded as χ. (Examples 39 and Comparative Examples 1-39) Production of Wet-Formed Powder Cake A foundation having the composition shown in Tables 1-47 was produced by the following method. The results of the evaluation are shown in Table 1-48. ° 76 201032832

JIOJ/piI

[Table 1-47] Table M7 Component parts by weight (1) Talc JA-13R (Example 1-33 and Comparative Example 1-33) to 100.0 (2) MW treatment (hydrophilization treatment) PMMA (polymethylmethacrylate, polymethylation) Methyl methacrylate) (Sankyo Chemical Co., Ltd.) 10.0 (3) Titanium oxide (compound (al) of Example 1-4 and compound (el) of Comparative Examples 1-4) 12.0 (4) Yellow iron oxide (Example 1 -5 compound (al) and Comparative Example 1-5 compound (ei)) 2.5 (5) Red iron oxide (compound (al) of Examples 1-6 and compound (ei) of Comparative Example 1-6) 0.8 (6) Black iron oxide (compound (al) of Examples 1-7 and compound (ei) of Comparative Example 1-7) 0.3 (7) p-methoxycinnamic acid-2-ethylhexyl 5.0 (8) Polyoxyethylene (20 mol) hardened castor oil Τ

(Preparation method) A: The components (7) and (8) were heated to 75 ° C and uniformly dissolved. B: The components (1) to (6) were mixed by a mixer to be ultrapulverized. C : While stirring the above b by a mixer, A was added and uniformly dispersed. D: 1 part by weight of purified water was added to 1 part by weight of the component of c, and uniformly mixed to obtain a slurry. ' E. The above D was filled into a metal vessel, and absorbent paper was placed on the surface and pressurized, and a part of purified water was removed. F. The above F was placed in a thermostat of 3 〇〇c for 24 hours, and the purified water was completely removed to obtain a wet-formed powder cake. [Table 1-48] Example ◎ 〇Comparative Example △ "δ" ----------|__^ △--- j Example 1_4G and taste example 1, F/W emulsified emulsion| The emulsion of the composition shown in Tables 1-49 was produced by the following method. The results of 77 201032832 31637pif are shown in Table 1-50. [Table 1_49] Table 1.49 Component parts by weight (1) Perfluoropolyether (Fomblin HC/04: Solvay) 25.0 (2) Hydrofluoroether (CF-76: 3M) 10.0 (3) Talc JA- 13R (Example 1-34 and Comparative Example 1-34) 6.0 (4) Ethanol 10.0 (5) Glycerol 3.5 (6) Purified water to 100.0 (7) Preservative amount (preparation method)

A: The components (1) to (3) were uniformly mixed and heated to 50 °C. B: Components (4) to (7) were dispersed and dissolved by a homogenizer and heated to 50 °C. C : While the above B was stirred by a homogenizer, the above A was slowly added to obtain an F/W emulsified emulsion. [Table 1-50] Table 1-50

Evaluation item Example Comparative example Sense of use ◎ △ Completeness of effect 〇 △ Make-up continuity ◎ X

(Examples 1-41 and Comparative Examples 1-41) Production of W/F Emulsion Emulsion An emulsion of the composition shown in Table 1-51 was produced by the following method. The evaluation results are shown in Table 1-52. [Table 1-51] Table 1-51 Component parts by weight (1) Perfluoropolyether (Fomblin HC/04: Solvay) 45.0 (2) Hydrofluoroether (CF-76: 3M company) 15.0 (3) Talc powder (Example 1-35 and Comparative Example 1-35) 5.5 (4) Ethanol 5.0 (5) Glycerol 3.5 (6) Purified water to 100.0 (7) Preservative amount 78 201032832 ->10J /ρπ (manufacturing method) A : The ingredients (1) to (3) were uniformly mixed and heated to 5 Torr. 〇^ Heat to 50 °C. C : A W/F emulsified emulsion was obtained by adding the above B to the above A using a homogenizer. [Table 1-52] B: Dispersion, mixing, and stirring of the components (4) to (7) were carried out while stirring. Table 1-52 Comparison of the use of the evaluation items The uniformity of the effect was completed △ Make-up continuity △ X ( EXAMPLES and whistle cases W) Production of powder emulsified sunscreen The emulsion of the composition shown in the table was produced by the following method. The evaluation results are shown in Table 1-54. Table 1-53 [Table 1_53] Ingredients (1) Heteroxanthine _ (2) Isotridecyl isononanoate (1) Microparticles 氡化钦 (Implementing 1-3-77 and tfc Comparative Example 1-37) (4) Talc Powder JA-13R (real 1-3-36 and comparative example (5) dimethylmethyl-weilkylation II (Aerosil R972: (6) ethanol 'sil company) _^ parts 20.0 7.0 10.0 2.0 (7) glycerol ( 8) Purified water (9) Preservative 3.0

(Production Method) A: The components (1) to (5) were uniformly mixed by a disperser and heated to 50 °C. ‘B: Heat the ingredients (6) to (9) to 5 〇 and mix them evenly. 79 201032832 3l637pif, - Stir the above A with a homogenizer, and slowly add the above B to obtain a powder emulsified sunscreen. [Table 1-54] ~~----- Table Bu 54 «Τ1聚•^ 日 Example comparison example will use 琢@~~' △ Yuanfeng double fruit evenly pay children Song Du You.UI, △ 丨匕 付 ◎ Δ Δ [Production Examples 2-1 to 2-3] The production examples of the fluorinated copolymer compound used in the present invention are listed below. [Production Example 2-1] In a 100 ml four-necked flask equipped with a reflux cooling tube, a nitrogen gas introduction tube, a thermometer, and a stirring device, 18 6 g of a fluorine-containing monomer CH2=CHC(=〇)〇-CH2CH2C6F13 ( The following is a C6SFA (a)), li.4 g polyethylene glycol acrylate CH2=CHC(=0)0-(CH2CH20)nH (BlemmerAE90, manufactured by Nippon Oil Co., Ltd., the average value of η is 2 ' Hereinafter, ΑΕ90 (b)), 〇·3 g of dodecyl mercaptan, and 45 g of isopropyl alcohol were described and nitrogen foaming was carried out for 30 minutes. After the internal temperature was raised to 50 to 65 ° C under a nitrogen stream, 0.4 g of Perbutyl PV (hereinafter referred to as PV) was added, and the mixture was reacted at 60 ° C to 65 ° C for 10 hours. Under reduced pressure and at about 70. (: The obtained solution was distilled to remove isopropyl alcohol, and after obtaining a pale yellow polymer residue, 122.4 g of water was added, and the internal temperature was maintained at about 80 ° C for 1 hour or more, followed by cooling to prepare a solid. An aqueous dispersion having a concentration of about 20% by weight. [Production Example 2-2] In a 100 ml four-necked flask equipped with a reflux cooling tube, a nitrogen gas introduction tube, a thermometer, and a stirring device 201032832 JIOJ/pu, 18.6 g was charged. C6SFA (a), 5.7 g of AE90 (b), 5.7 g of polyethylene glycol acrylate CH2=CHC(=0)〇(CH2CH20)nH (Blemmer AE200, the average value of 'n manufactured by Nippon Oil Co., Ltd.' is 4.5' hereinafter referred to as AE200 (b)), 0.3 g of dodecanyl mercaptan, and 45 g of isopropyl alcohol, and the same polymerization reaction as in Production Example 2-1 was carried out to prepare a solid concentration of about 20 wt. [Water-dispersion of 〇/. I [Production Example 2-3] To a 100 ml four-necked flask equipped with a reflux cooling tube, a nitrogen gas introduction tube, a thermometer, and a stirring apparatus, 18.6 g of C6SFA (a), 10.5 was charged. AE350 (b) of g, 0.9 g of polyethylene glycol diacrylate vinegar CH2=CHC(=0)0-(CH2CH20)nC(=0)CH=CH2 (Blem Manufactured by mer ADE300' Nippon Oil Co., Ltd., having an average value of η of 7), 0.3 g of dodecyl mercaptan, and 45 g of isopropyl alcohol, and carrying out the same polymerization reaction as in Production Example 2-1 An aqueous dispersion having a solid content concentration of about 20% by weight. [Table 2-1] Table 2-1 Compound Structure Remarks (a2) Fluoropolymer of Production Example 1 ''' The treatment agent used in the present invention (b2) The fluorine-containing copolymer of Production Example 2 The treatment agent (c2) used in the present invention The fluorine-containing copolymer of Production Example 3 The treatment agent (d2) used in the present invention 曰 This patent is open 200〇-29064 The fluorinated copolymer (17FA/HEMA, the treatment agent (e2) of the prior (comparative example), and the manufacturing example 4 of the above-mentioned Japanese Patent Laid-Open Publication No. Hei 5-213485 The fluorinated copolymer described above (Comparative Example) treatment agent [Examples 2-1 to 2-14 and Comparative Examples 2-1 to 2-14] Tables 2-1 (a2) to (C2) are Each of the fluorinated copolymers used in the present invention, the copolymers represented by (d2) and (e2) are the compounds of the previous (Comparative Example) 81 201032832 31637pif surface treatment as FAW treatment. Making each of the surface-treated by the compounds of the valence of each of these surface-treated powder properties. The surface treatment powder examples and evaluation items and methods are listed below. Further, the evaluation method of the treated powder by the fluorinated copolymer used in the present invention shown in the above Table 2-1 is as follows. (contact angle test of water and squalane)

The powder was filled in a metal vessel, and pressure was applied by applying pressure at a pressure of 6 MPa for 10 seconds, and water or squalor was dropped on the molding surface to measure the angle between the droplet and the surface of the powder. Contact angle meter (CA-D) manufactured by Kyowa Interface Science Co., Ltd. 'Drip water or squalane on the surface of the molded powder (drop amount: 10 //1), and measure the droplets and powder coating after 20 seconds. The angle formed by the face. (The number of η is 5) The case where the droplet is absorbed by the powder and cannot be measured. The contact angle is referred to as infiltration. (Useability and Adhesion Test) 官能 The functional inspector of 15 surface-treated powders was tested for the same powder to evaluate the usability and adhesion of each surface-treated powder. The evaluation method is carried out by rubbing with a finger pad or applying it to a finger or upper arm. The evaluation was performed by absolute evaluation by each functional inspector's score as follows. ◎: Very good, 〇: good, △: normal, X: poor. (Evaluation method of water repellency and hydrophilicity) About 50 CC of purified water was placed in a 100 CC glass beaker. About 0.1 g of the treated powder was placed on the water surface and stirred by a spatula at a frequency of about 2 82 201032832 J 1 \) J / pu per second. The turbidity of the aqueous phase after stirring 5 times, 1 time, and 150 times was evaluated in five grades. Person, . <Evaluation Criteria> 5 No turbidity in the aqueous phase. (strong water repellency) 4 The water phase is slightly cloudy. 3 The water phase shows obvious turbidity. 2 Most of the powder is transferred to the aqueous phase. φ 1 All powders are transferred to the aqueous phase. (Strong hydrophilicity) (Evaluation results) The results of the contact angle test of water and squalane are shown in the examples of the respective treated powders and the comparative examples. The test knots of the usability and the adhesion are shown in Table 2-18. ° 实施 (Example 2_1 (FAW treated sericite) and Comparative Example 2_1;) The surface treatment amount of each fluorinated copolymer shown in Table 2-1 was 1 g in terms of solid content (external cut 1 wt%) 100 g of sericite FSE (Sanxin Miner) ® is processed by incrementing lg to 5 g (external cut 5 wt%). 50 g of water was added to each of the fluorinated copolymers and kneaded for 3 Torr. The kneaded product was dried at 80 ° C for 3 hours, and further dried under u〇〇c for 10 hours. Then, ultrafine pulverization was carried out to obtain fluorinated copolymer-treated mica. The results are shown in Table 2-2 and Table 2-3. 83 201032832 31637pif [Table 2-2] Table 2-2: (Results of Example 2_i and Comparative Example 2_i) _ Contact angle test of sericite and water/squalane for each gas-containing copolymer treatment 1% 2% 3% 4% Γ 5% The compound (a2) of the present invention "16 ° / infiltration 50735 ° 1407130 ° 72 / 140 ° permeation / 145. Compound (b2) of the present invention 18 ° / permeation 48737 ° 1377133 ° 647139 ° infiltration A 42 The compound of the present invention (c2) 15 ° / osmosis ^ 55738. 1367122 ° 75 7139 ° osmosis / 140. Comparative compound (d2) 17 / osmosis 53 742 ° 137 7123. 1387135 ° 1457133 ° Comparative compound (e2 20°/infiltration 83./56. 1417128° 1437140° 1407142° As shown in Table 2-2, the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example is increased in proportion to the amount of treatment. However, the powder coated with the fluorinated copolymer of the present invention has a low water repellency and oil repellency when the treatment amount is 2% or less, and exhibits the highest water repellency and oil repellency when the treatment amount is 3%. 10 The treatment amount is 5 Hydrophilic oil repellency at %. Even if the treatment amount is increased to 5% or more, oil repellency and hydrophilicity are no longer The same results were also observed in the results shown in Table 2-3 below. [Table 2-3] Table 2-3: Results of Examples 2-1 and Comparative Example 2-1 Each gas-containing copolymer Processing frequency: Compound of the present invention (a2) Mica 1% water and pro 7 2% -3 κ test and 3% capsule 4% 5% _ ~ 1 invented compound.. <Inventive compound rc2 Compound of Comparative Example (d2) Compound (e2) of Comparative Example " 1 -1 1 1 D 3 3 3 3 4 4 _ 4 - 4 4 2 2 2 5 5 1 1 1 5 5 (Example 2 2 (FAW treated titanium) and Comparative Example 2_2) The surface treatment amount of each fluorinated copolymer shown in Table 2 of the human being is 1 g (external damage, n wt%) to 5 g in terms of solid content Each time, lg is added to 100g of titanium CR_5〇 (Ishihara Industry Co., Ltd.). Each fluorine-containing compound is diluted in 1G ml of water and added. Mixing with a mixer After 5 minutes, lead 25 (rc's over-rail steam, reach 200 in the mixer. (: The moment to stop the agitation, and get 彳 ^ each contains 84 201032832

^10J/piI Fluoropolymer treats titanium. The results are shown in Tables 2-4 and 2-5. [Table 2-4] Table 2·4: Results of Example 2-2 and Comparative Example 2-2 Contact angle test of each fluorocopolymer treated titanium with water/squalane 1% 2% 3% 4% 5% The compound (a2) of the present invention 16 7 permeate 61835° 140 7133° 727141° permeation/142° The compound (b2) of the present invention 18 7 is infiltrated 64. /37. 143. / 136 〇 647140° osmosis / 143 ° Compound (c2) 15 of the present invention. /Infiltration 78738° 1417131° 757137° Permeation/142° Comparative compound (d2) 20°/permeability 89. /56. 1387135° 1477140° 1487142° Compound (e2) of Comparative Example 24 7 Permeation 80742° 1377140° 1487142° 1437143° As shown in Table 2-4, the treated powder of the fluorinated copolymer of the comparative example was used. The oiliness is increased in proportion to the amount of the treatment. However, the powder coated with the fluorinated copolymer of the present invention exhibits low water repellency and oil repellency when the treatment amount is 2% or less, and exhibits the highest water repellency when the treatment amount is 3%. Oily. It exhibits hydrophilic oil repellency when the treatment amount is 5%. Even if the amount of treatment is increased to 5% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-5 below. [Table 2-5] Table 2-5: Results of Example 2-2 and Comparative Example 2-2 Water repellency and hydrophilicity test results of each fluorocopolymer treated titanium 1% 2% 3% 4% 5% The present invention Compound (a2) 1 2 4 2 1 Compound (b2) of the present invention 1 3 5 3 1 Compound (c2) of the present invention 1 2 4 2 1 Compound of Comparative Example (d2) 1 3 5 5 5 Compound of Comparative Example (e2) 1 3 5 5 5

(Example 2-3 (FAW-treated yellow iron oxide) and Comparative Example 2_3) The surface treatment amount of each fluorinated copolymer shown in Table 2-1 was 2 g in terms of solid content (external cut 2 wt%) ) 1 g of yellow iron oxide (yellow LL_1〇〇p: Sakamoto Titanium Industries Co., Ltd.) was processed in increments of 1 g between 6 g (external cut 6 wt%). Each fluorine-containing compound was diluted in 5 ml of water to be added. After mixing for 15 minutes using a Henschel mixer, 85 201032832 31637pif was dried at 110. 0 for 10 hours and then pulverized by an ultrafine pulverizer to obtain each fluorocopolymer treated yellow iron oxide. The results are shown in Table 2-6 and Table 2-7. [Table 2-6] Table 2-6: Results of Examples 2-3 and Comparative Example 2-3 Year + y color gasification iron and water 7 squalane, tentacity test 1% 3% 4% 5% 6% The compound (a2) of the invention penetrated 61835° 1327116° 617141° permeation/142. The compound (b2) 18 of the present invention. /Infiltration 64737° 1317124° 557140° Permeation / 143° The compound (c2) of the present invention 17. /Infiltration 1 85 742° 1307126° 68°/138° 溱透/143. Comparative Example Compound (d2) 2〇°/Permeation 89756° 1397135° 1487140° 1447142° Compound (e2) 24 of Comparative Example. /Infiltration 80742° 1387128. 1477142° 145. /143°

As shown in Table 2-6, the treated powder of the fluorinated copolymer of the comparative example was subjected to a water-repellent property in proportion to the treatment, and the powder coated with the fluorinated copolymer of the present invention was treated in a treatment amount. When the amount is less than or equal to 3%, the water repellency and oil repellency are low, and when the treatment amount is 4%, the highest water repellency and oil repellency are exhibited. It exhibits hydrophilic oil repellency when the treatment amount is 6%. Even if the treatment amount is increased to 6% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-7 below. [Table 2-7] Table 2-7: Results of Examples 2-3 and Comparative Example 2-3_Water-repellent and hydrophilicity test results of yellow iron oxide treated with each gas-containing copolymer 2% 3% 4% 5% 6% The compound of the present invention (a2) 1 2 4 2 1 The compound of the present invention (b2) 1 2 5 3 1 The compound of the present invention (c2) Γ 1 2 4 2 1 The compound of the comparative example (d2) 1 3 5 5 5 Comparative compound (e2) " 1 3 Bu 5 5 5

(Example 2-4 (FAW-treated red iron oxide) and Comparative Example 2-4) The surface treatment amount of each fluorinated copolymer not shown in Table 2-1 was 2 g in terms of solid content (external cut 2 wt%) ) to 6 § (external cut 6wt%) between each increment of 1 g, for 100 g of red iron oxide (red r_5 Sat: 86 201032832

JiO Xi / pu Sakamoto Titanium Industrial Co., Ltd.). The treatment with the same method as in Example 2-3 was carried out to obtain red iron oxide treated with each of the fluorinated copolymers. The results are shown in Table 2-8 and Table 2-9. [Table 2-8] Table 2-8: Results of Example 2*4 and Comparative Example 24 Contact angle test of each fluorocopolymer treated red iron oxide with water/squalane 2% 3% 4% 5% 6 % ^ The compound (a2) 18 of the present invention. /Infiltration 66. /35. 1407133° 727141° Infiltration / 142. The compound of the present invention (b2) 14 7 permeates 75 738 ° 141713 Γ 75 7137 ° permeation / 142. The compound (C2) 25 of the present invention. /Infiltration 76742° 1417130. 747138. Permeation / 143 ° Comparative Example Compound (d2) 26 7 Penetration 80756* 1387l35e 1437140. 145 7142 ^ Compound of the comparative example (e2) 28° / permeation 82742° 1377140. 1387142° 143 7143. ’

As shown in Table 2-8, the treated powder of the fluorinated copolymer of the comparative example has a water-repellent property which is increased in proportion to the amount of treatment, and the powder coated by the fluoropolymer of the present invention is less than the treatment amount. When it is equal to 3%, the water repellency and oil repellency are low, and when the treatment volume is 4%, it shows the highest water repellency. It exhibits hydrophilic oil repellency when the treatment amount is 6%. Even if the treatment amount is increased to 6% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-9 below. [Table 2-9] Table 2-9: (Results of Example 2*4 and Comparative Examples 2 to 4) Water repellency and hydrophilicity test results of red iron oxide treated with each fluorinated copolymer 2% 3% 4% 5 % 6% The compound of the present invention (32) 1 3 4 2 1 The compound of the present invention (b2) 1 3 4 3 1 The compound of the present invention (c2) 1 2 4 2 1 The compound of the comparative example (d2) 1 3 5 5 5 Comparative Example Compound (e2) 1 3 5 5 5 (Example 2-5 (FAW treated black iron oxide) and Comparative Example 2-5) Surface treatment of each fluorinated copolymer shown in Table 2-1 100 g of black iron oxide (black BL-100P: 87 201032832) in a manner of 1 g increments between 1 g (external cut 1 wt%) and 5 g (external cut 5 wt%) in terms of solid content 31637pif 曰本钛工业)). The treatment with the same procedure as in Example 2-3 was carried out to obtain a black iron oxide treated with each of the fluorine-containing copolymers. The results are shown in Table 2-10 and Table 2-11. [Table 2_10] Table 2-10: Results of Examples 2-5 and Comparative Examples 2-5 Contact angle test of each fluorinated copolymer treated black iron oxide with water/squalane 1% 2% 3% 4% 5 % The compound (a2) 35 7 of the present invention penetrates 1347128° 687133° 12. /141. Penetration / 142. The compound of the present invention (b2) 40 ° / infiltration 1367125. 707136° 137140° Permeation / 143° The compound of the invention (c2) 45° / infiltration 1387130° 647138. 1 157137° permeation / 142. Comparative Example Compound (d2) 68 7 Infiltration 1407134° 1467145° 1457140° 1457142. The compound (e2) 57 7 of the comparative example penetrated 1427133. 1447140° 1467142° 1437143°

As shown in Table 2-10, the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example was increased in proportion to the amount of treatment, and the powder coated by the fluorinated copolymer of the present invention was less than the treatment amount. When it is equal to 1%, the water repellency and oil repellency are low. When the treatment volume is 2%, it shows the highest water repellency. It exhibits hydrophilic oil repellency when the treatment amount is 4% and 5%. Even if the treatment amount is increased to 5% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-11 below. [Table 2-11] Table 2-11: (Results of Example 2-5 and Comparative Example 2-5) Water repellency and hydrophilicity test results of each fluorinated copolymer treated black iron oxide 1% 2% 3% 4% 5% The compound of the present invention (a2) 1 3 5 2 1 The compound of the present invention (b2) 2 3 5 2 1 The compound of the present invention (C2) 1 3 5 2 1 The compound of the comparative example (d2) 2 3 5 5 5 Comparative Example Compound (e2) 2 3 5 5 5

(Example 2-6 (FAW treated fine particle titanium oxide) and Comparative Example 2_〇 loog fine particle titanium oxide (MT_5〇〇SA: Tayca company) was put into 1500 ml of deionized water (6 偏 containing 〇〇 5 g) In the sodium phosphate), each of the fluorinated copolymers having a solid content of 6 g was further diluted and added to 500 ml of 88 201032832 JIUJ/pil IPA. The DYN〇_Mill :丨4 l yttrium oxide container was used. &blade, 0.5 mmp yttrium oxide beads, fill rate of 85%) Disperse in a cycle of 15 minutes. The dispersion was heated to 80 C with stirring, and a 10% aqueous HCl solution was added to adjust the pH to 4.5. After dehydration by centrifugation, it was dried at 12 Torr for 16 hours under an arm and pulverized by a JET ultrafine pulverizer to obtain TiO2-treated fine particle titanium oxide. Further, it was also trial-produced under the above treatment conditions. The surface-treated powder obtained by treating each fluorinated copolymer amount by 6% to 10% each time by 1%. The results are shown in Table 2-12 and Table 2-13. 12] Table 2-12: Results of Examples 2-6 and Comparative Examples 2-6 Each fluorocopolymer treated microparticles Contact angle test of titanium oxide and water/horn shark burning 6% 7% 8% 9% 10% osmosis / 142° The compound of the invention (a2) 35° / osmosis 1347128. 887133° 29β/141β The compound of the invention ( B2) 40°/infiltration 1367125^ 807136° 257143° permeation/143. Compound (c2) of the invention 45./Infiltration 1387130° 947138° 257139° Permeation/142° 1457142° Comparative compound (d2) 68°/permeate 1407134° 1467145° 145V140. Compound of the comparative example (e2) 57°/infiltration 1427133° 1447140° 1467142° 1_43./143. As shown in Table 2-12, the treated powder of the fluorinated copolymer of the comparative example was used. The water repellency and the oil repellency are increased in proportion to the amount of the treatment. The powder coated with the fluorinated copolymer of the present invention has a low water repellency and oil repellency when the treatment amount is 6% or less, and the highest at the treatment amount of 7%. Water and oil repellency. It exhibits hydrophilic oil repellency when the treatment capacity is 10%. Even if the treatment amount is increased to 10% or more, the oil repellency and hydrophilicity will not change. The results shown in Table 2-13 below are shown. The same result was observed in the middle. 89 201032832 31637pif [Table 2-13] Table 2 13 : Results of Examples 2-6 and Comparative Examples 2-6 The water repellency and hydrophilicity test of each fluorinated copolymer-treated fine particle titanium oxide 杲 6% 7% 8% 9% 100/» The compound of the present invention (a2 2 5 4 2 ~~*'~~~-1 Compound (b2) 2 5 4 2 1 ~~1 Inventive compound (c2) 2 5 4 2 1 Comparative compound (d2) 3 5 5 5 --- 5 Comparative Example Compound (e2) 3 5 5 5 5 (Example 2-7 (FAW Treatment/SA Treatment of Microparticle Zinc Oxide) and Comparative Example 2-7) To 10 μg of fine particle zinc oxide ( MZ-300: Tayca Co., Ltd., each of the fluorinated copolymers shown in Table 2-1, each having a solid content of 5 g to 9 g, and 3 g of a straight bond having a degree of polymerization of 15 at a single terminal having a diethoxy group. In the sulphur-based polysand (SA treatment), 20 g of water and 50 g of water were added; [PA, and kneaded for 30 minutes using a kneader. Further, after adding 1 〇g of deionized water and kneading for 30 minutes, it was dried at i〇5〇C for 16 hours, and then subjected to ultrafine pulverization of the butyl ketone to obtain a composite treatment of each fluorinated copolymer and polyfluorene oxide. Zinc. The results are shown in Table 2-14 and Table 2-15. [Table 2-14] Table 2 - 4: Results of Example 2·7 and Comparative Example 2_7 Each gas-containing particle was mixed, and the contact angle test of the treated fine zinc oxide with water/squalane was 5% 6% 7% 8 % 9% The compound (a2) of the present invention 75. /25° 1447135° 987133° 51714Γ Infiltration of eight 42. The compound (b2) of the present invention is 85726° 1487136. 1027138° 62. /137〇 Permeation / 142 ° Compound (c2) 77727 of the present invention. 1457137° 877137° ] 47l38e permeation / 143. Comparative Example Compound (d2) 88730° h1407l40° 1467145° 1457140. 1457142. Comparative Example Compound (e2) 97738° 142°/142° 1447140° 1467142° 1437143° As shown in Table 2-14, the treated powder of the fluorinated copolymer of the comparative example was used for water repellency and handling amount. The powder coated with the fluorinated copolymer of the present invention has a low water repellency and oil repellency when the treatment amount is 5% or less, and exhibits the highest water repellency when the treatment amount is 6%. 201032832 J XUJ /pu exhibits hydrophilic oil repellency when the throughput is 9%. Even if the treatment amount is increased to 9% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-15 below. [Table 2-15] Table 2-15: Results of Examples 2-7 and Comparative Example 2·7) Treatment of each fluorinated copolymer, particle oxidization and hydrophilicity test results 5% 6% 7% 8% 9% The compound of the present invention (a2) 3 5 3 2 1 The compound of the present invention (b2) 3 5 3 2 1 The compound of the present invention (C2) 3 5 3 2 1 The compound of the comparative example (d2) 4 5 5 5 5 Comparative compound (e2) 4 5 5 5 5

(Example 2-8 (FAW treated/treated pearl) and Comparative Example 2-8) 100 g of pearl pigment (Flamenco Gold: Engelhardt) was added to 1000 ml of deionized water, and 1 〇g of N was added. - Disodium sulphate succinate (Ajinomoto, Amisoft HS-21P) (dissolved). Further, 1 g to 5 g of each of the fluoro copolymers shown in Table 2_1 was added, and the mixture was heated to 80 ° C and kneaded by a kneader for 30 minutes. Further, a 0.5 mol/L aqueous solution of Al2(S〇4)3 was added to adjust the pH of the kneaded material to 5.0. The mixture was dried at 140 ° C for 8 hours to obtain a composite treated pearl pigment of each of the fluorine-containing copolymer and the mercapto amino acid. The results are shown in Table 2-16 and Table 2-17. [Table 2-16] Table 2-16: Results of Examples 2-8 and Comparative Examples 2-8 Contact angle test of each fluorocopolymer-treated micro pearl and water/squalane 1% 2% 3% 4% 5% The compound (a2) 50715 of the present invention. 1447136° 987133° 5Γ/137" Infiltration/142. The compound (b2) of the present invention is 46710° 146. /132. 907136° 45714Γ Permeation / 143. Compound (c2) of the present invention 40716° 1487133° 1027138° 527140° Permeation/142° Compound of Comparative Example (d2) 88730° 1487145° 1497146° 145·143β 1457142° Compound of Comparative Example (e2) 97738° 1487142° 146714Γ 1467142 ° 143 7143° 91 201032832 31637pif As shown in Table 2-16, the treated powder of the fluorinated copolymer of the comparative example is improved in water-repellent property in proportion to the amount of treatment, and is coated with the fluorinated copolymer of the present invention. The powder has a low water repellency and low oil repellency when the treatment amount is less than or equal to 1%, and exhibits the highest water repellency and oil repellency when the treatment amount is 2%. It exhibits hydrophilic oil repellency when the treatment amount is 5%. Even if the throughput is increased to 5% or more, the oil repellency and pro-permanence will not change. The same results were also seen in the results shown in Table 2-17 below. [Table 2-17] Table 2-17: Results of Examples 2-8 and Comparative Examples 2-8 The water repellency and hydrophilicity test results of the respective fluorocopolymer-treated micro pearls 1% 2% 3% 4% 5% The present invention Compound (a2) 2 5 3 2 1 Compound of the present invention (b2) 2 5 3 2 1 Compound of the present invention (c2) 2 5 3 2 1 Compound of Comparative Example (d2) 3 5 5 5 5 Compound of Comparative Example (e2) 3 5 5 5 5 (Example 2-9 (FAW treatment of lauric acid amide) and Comparative Example 2-9) To 100 g of Amihope LL (lauric acid lysine: Ajinomoto) 'Add IPA/mixture of pH to 8 〇 aqueous solution = 15 g/l 〇g with NaOH' and add 1 g to 5 g of each fluorinated copolymer shown in Table 2-1' by way of example 2-8 and the method of Comparative Example 2-8 were subjected to surface treatment in the same manner to obtain each of the fluorine-containing compound-treated Amihope LL. The results are shown in Table 2-18 and Table 2-19. 201032832

OlOJ/piI

[Table 2-18] Table 2-18: Results of Examples 2-9 and Comparative Examples 2-9: Contact angle test of each fluorocopolymer-treated lauric acid-free acid and water 2% 3% 4% 5% The compound of the present invention (a2) IVny] 1447135° 987133° 5Γ/14Γ permeation/142. The compound (b2) of the present invention is 85736° 1487136° 1027138° 62 7137. Penetration / 142. Compound (c2) 77727 of the present invention. 145 7137° 877137° 547138° Infiltration / 143. Comparative Example Compound (d2) 88730° 1407140° 1467145° 1457140° 1457142° Compound (e2) 97738 of Comparative Example. 1427142° 1447140° 1467142° 1437143.

As shown in Table 2-18, the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example was increased in proportion to the amount of treatment, and the powder coated by the fluorinated copolymer of the present invention was less than the treatment amount. When it is equal to 1%, the water repellency and oil repellency are low, and when the treatment volume is 2%, it shows the highest water repellency. It exhibits hydrophilic oil repellency when the treatment amount is 5%. Even if the amount of treatment is increased to 5% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-19 below. [Table 2-19] Table 2-19: Results of Examples 2-9 and Comparative Example 2-9_ Each fluorinated copolymer treated Laurel, hydrazine-based acidity water-repellent and hydrophilicity test result 1% 2% 3% 4% 5% The compound of the present invention (a2) 4 5 3 2 1 The compound of the present invention (b2) 4 5 3 2 1 The compound of the present invention (c2) 4 5 3 2 1 The compound of the comparative example (d2) 4 5 5 5 5 Compound of Comparative Example (e2) 4 - 5 5 5 5 (Bei Shi Example 2-10 (FAW Process Red No. 202) and Comparative Example 2_1〇) Add Red No. 202 (癸巳化成公司) g to IpA/ go In the mixed solution of ionized water = 4G g/IGG g, the surface was mixed by a propeller type mixer, and the surface was expanded by an ultrasonic homogenizer (Japan version: E-mail (10)). 5 g to 9 g of each of the fluorinated copolymers shown in Table 2] and 5 g of IPA were immersed, and then the solvent was removed by vacuum heating, and under 1G5C: (4), pulverized at 1 M, shouted Each containing image copolymer 93 201032832 31637pif treatment of red No. 202. The results are shown in Tables 2-20 and 2-2 [Table 2-20] Table 2-20: Results of Examples 2-10 and Comparative Example 2·10 Each fluorocopolymer was treated with red 202 and water/ Contact angle test of squalane 5% 6% 7% 8% 9% The compound of the present invention (a2) 75725° 1447135° 987133° 517141° osmosis/142. The compound (b2) of the present invention is 85 736. 1487136° 1027138° 627137° Infiltration / 142. Compound (c2) 77727 of the present invention. 1457137° 877137° 547138° Infiltration / 143. Comparative Example Compound (d2) 88730° 1407140° 1467145° 1457140° 145 7142° Comparative Compound (e2) 97738° 1427142° 1447140° 1467142° 143 7143°

As shown in Table 2-20, the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example was increased in proportion to the amount of treatment, and the powder coated by the fluorinated copolymer of the present invention was less than the treatment amount. When it is equal to 5%, the water repellency and oil repellency are low. When the treatment volume is 6%, it shows the highest water repellency. It exhibits hydrophilic oil repellency when the treatment amount is 9%. Even if the treatment amount is increased to 9% or more, the oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-21 below. [Table 2-21] Table 2-21: Results of Examples 2-10 and Comparative Examples 2-10 Water-repellent and hydrophilicity test results of each gas-containing copolymer treated red No. 202 5% 6% 7% 8% 9 % The compound (a2) of the present invention 3 5 4 3 1 The compound of the present invention (b2) 3 5 4 3 1 The compound of the present invention (c2) 3 5 4 3 1 The compound of the comparative example (d2) 4 5 5 5 5 Compound (e2) 4 5 5 5 5 (Example 2-11 (FAW treatment/ALS treatment 曱polyoxane/vinyl dioxime polyoxane and titanium oxide mixture) and Comparative Example 2-11) a mixture of 100 g of dioxonium polyoxyalkylene/vinyl dimethylpolyoxane and titanium oxide (Dow Corning, EP-9261 TI Cosmetic

Powder) is charged into a high-speed mixer, and each fluorocopolymer shown in Table 2-1, which is 1 g to 5 g in terms of solid content, and triethoxyoctylthiophene 94 201032832 / ριι decane (Dow) Coming: Z-6341) (ALS treatment) A solution prepared by dissolving in 10 g of IPA (isopropanol) and stirring for $ minutes. While maintaining the mixing, the pressure was reduced in the facing tank, and the temperature was raised to 5 °C and disturbed for 15 minutes. The obtained powder is subjected to ultrafine pulverization, and a mixture of each of the condensed polyelectron-treated and the sulphide-based sulphur-smelting dimethyl oxime-oxygen/ethylene dimethoxy siloxane and titanium oxide is obtained. . The results are shown in Table 2_22 and Table 2-23. ', φ [Table 2-22] Table 2_22: Results of Examples 2-11 and Comparative Examples 2-11 _^Fluorinated Copolymer Treatment A Polyester I Oxygen/Ethyl Group I Dimethyl Oxide Contact angle test of titanium oxide mixture samarium / squalane -:-:~:----I Ί~ 4% "w-

As shown in Table 2-22, the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example was increased in proportion to the amount of the treatment, but the amount of the powder coated by the fluorinated copolymer of the present invention was treated. When the amount is less than or equal to 2%, the water repellency and the oil repellency are low, and when the treatment amount is 3%, the highest water repellency and oil repellency are exhibited. Hydrophobicity was exhibited when Treatment 1 was 5%. Even if the treatment amount is increased to 5% or more, the oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-23 below. 95 201032832

JlOJ/pu [Table 2-23] Table 2-23 Results of Examples 2-11 and Comparative Examples 2-11) Each fluorocopolymer treated methacrylate/vinyl dimethyl hydrazine gasification Magnetic Permanence and Hydrophilicity Test Results of Titanium Mixture 1% 2% 3% 4% 5% Compound (a2) of the present invention - 2 3 4 2 1 Compound (b2) 2 3 5 2 1 of the present invention Compound (c2) 2 3 5 2 1 Compound (d2) of Comparative Example 2 3 5 5 5 Compound (e2) of Comparative Example 2 3 5 5 5 (Example 2-12 (FAW treatment/C6F decane-treated fine particle zinc oxide) And Comparative Example 2-12) To 100 g of the fine particle zinc oxide MZ-300 (Tayca Co., Ltd.), each of the fluorocopolymers shown in Table 2-1 and 5 g of tridefluoride as a solid content of 3 g to 6 g were added. Octyltriethoxydecane (Dynasylan F-8261: Evonik Degussa) (C6F decane treatment), with 60 g of water/IPA = 1/1 solution 'mixed with a kneader for 60 minutes and dried at 13 (TC) 16 hours. Then, ultrafine pulverization was carried out to obtain a composite treated fine particle zinc oxide of each fluorinated copolymer and C6F decane. The results are shown in Table 2-24 and Table 2-25. [Table 2-24] Table 2-24: Example 2 -12 and comparison Results of treatment of 2-12 The contact angle of microparticulate zinc oxide with water/squalane 3% 4% 5% 6% 7% The compound of the invention (a2) 149°/144. 1087145. 89 7145° 417150. /141. Compound (b2) of the present invention 1507146° 1027143° 787147° 32./148° Permeation/143. Compound of the present invention (c2) 1587147° 1107142° 807140° 347140° Permeation/140. Compound of Comparative Example (d2 154. / 149 ° 1547146 ° 146 7145 ° 1447140 ° 1427142 ° Comparative Example Compound (e2) 156. / 146 ° 1577145. 1447145 ° 1467142 ° 143V143.

As shown in Table 2·24, the treated powder of the fluorinated copolymer of the comparative example did not change the water repellency even when the treatment amount was increased, and the powder coated with the fluorinated copolymer of the present invention was copolymerized with fluorine. When the treatment amount of the material is 3% or less, the water repellency and the oil repellency are high. When the amount of C6F decane treated was 5% and the amount of the fluorine-containing copolymer treated was 3%, the highest water repellency was exhibited. When the content of the fluorine copolymer is 7%, it exhibits hydrophilic oil repellency. Even if the amount of treatment is increased to 7% or more, the oil repellency and hydrophilicity will not change. The same results were also seen in the results shown in Table 2-25 below. [Table 2-25] Table 2-25: Results of Examples 2-12 and Comparative Examples 2-12 The water repellency and hydrophilicity test results of the fluorocopolymer-treated fine particle zinc oxide 3% 4% 5% 6% 7 % The compound (a2) of the present invention 5 4 3 2 1 The compound of the present invention (b2) 5 4 3 2 1 The compound of the present invention (c2) 5 4 3 2 1 The compound of the comparative example (d2) 5 5 5 5 - 5 Comparative Example Compound (e2) 5 5 5 5 5 (Example 2-13 (FAW treated sericite) and Comparative Example 2-13)

By the powder and method shown in Example 2-1, except that the pH of the mixed solution of IPA and water (50 wt%: 50 wt%) 50 g was adjusted to 8.5 by Na〇H, the treatment was carried out in the same manner. And the fluorocopolymer was treated to treat sericite. The results are shown in Table 2-26 and Table 2-27. [Table 2-26] Table 2-26: Results of Examples 2-13 and Comparative Examples 2-13 Contact angle test of each fluorocopolymer treated sericite with water/squalane 1% 2% 3% 4% 5% The compound of the invention (a2) 26 7 permeates 30745° permeation / 140° permeation / 140. Penetration / 145. The compound (b2) 28 7 of the present invention penetrates 38. /42° Infiltration / 141. Permeation / 139 ° Permeation / 142 ° Compound (c2) of the invention 25 7 infiltration 35 740 ° Permeation / 140 ° Permeation / 139. Infiltration / 140. Comparative Example Compound (d2) 28 7 Permeation 53752° 1017143° 1387145° 1457143° Comparative Example Compound (e2) 25 7 Permeation 43759° 1057l45e 143°/142° 140-/142. As shown in Table 2-26, the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example was increased in proportion to the amount of treatment, and the powder coated by the fluorinated copolymer of the present invention was less than the treatment amount. When it is equal to 2%, the water repellency and oil repellency are low, and when the treatment amount is 3% or more, it exhibits high hydrophilic oil repellency. Even if the treatment amount is increased to 5% or more, oil repellency and hydrophilicity are not changed. The same results were also seen in the results shown in Table 2-27 below. 97 201032832 J / pil [Table 2-27] Table 2-27: Results of Examples 2-13 and Comparative Examples 2-13 Each fluorocopolymer treated sericite water-repellent and hydrophilic @验Μ 1% 2% 3% 4% 5% The compound (a2) of the present invention 2 2 1 1 1 The compound (b2) of the present invention 2 2 1 1 1 The compound (c2) of the present invention 2 2 1 1 1 The compound (d2) of the comparative example 2 3 4 5 5 Comparative Example Compound (e2) 2 3 4 5 5 (Example 2-14 (FAW Treated Talc Powder) and Comparative Example 2-14)

100 g of talc JA-13R (Asada Milling Co., Ltd.) was placed in 500 g of water prepared in a 2 L glass beaker, and thoroughly stirred to disperse. The solution of each of the fluorocopolymers shown in Table 2-1 and 10 g of IPA in a solid content of 1 g to 5 g was slowly added, followed by stirring for 15 minutes. The slurry thus obtained was supplied to a spray dryer equipped with a two-fluid nozzle mist nozzle. The inlet hot air temperature of the spray dryer was set to 20 (TC, and the spray pressure of the two-fluid nozzle was set to 0.6 MPa. Thus, each fluorocopolymer-treated talc powder was obtained. The results are shown in Table 2-28 and Table. 2-29. [Table 2-28] Table 2-28: Results of Examples 2-14 and Comparative Examples 2-14 Contact angle test of each fluorocopolymer treated talc powder 角太/squalane 1% 2% 3% 4% 5% The compound of the invention (a2) 29 / permeation 48765. 55 795 ° 617100 ° permeation / 101. The compound of the invention (b2) 30 7 permeate 42. / 63. 67787 ° 727108 ° permeation / 103 ° Compound (c2) of the present invention 38./Infiltration 40./62. 58786° 647100° Permeation/103° Compound of Comparative Example (d2) 44 7 Permeation 94776° 143 797° 1447110° 1427112° Compound of Comparative Example (e2 56./Infiltration 97875° 144795. 1467112° 1437113°

As shown in Table 2-28, the treated powder of the fluorinated copolymer of the comparative example has a water repellency which is increased in proportion to the amount of the treatment, but the powder coated by the fluorinated copolymer of the present invention is treated in a dose amount. When the amount is less than or equal to 2%, the water repellency and the oil repellency are low, and when the treatment amount is 3%, the highest water repellency and oil repellency are exhibited. It exhibits hydrophilic oil repellency when the treatment amount is 5%. Even if the treatment volume is increased by 98 201032832 to 5% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-29 below. [Table 2-29] 2-29: Results of Examples 2-14 and Comparative Examples 2-14 The water repellency and hydrophilicity test results of each fluorinated copolymer-treated talc powder 1% 2% 3% 4% 5% Inventive compound (a2) 2 2 3 3 1 The compound of the present invention (b2) 2 2 3 3 1 The compound of the present invention (c2) 2 2 3 3 1 The compound of the comparative example (d2) 2 3 5 5 5 of the comparative example Compound (e2) 2 3 5 5 5 (Example 2-15 (FAW-treated fine particle titanium oxide) and Comparative Example 2-15) The oxysulfate crystal was put into water and heated, and the produced hydrolyzate was filtered and washed. To 350 g of the obtained aqueous titanium oxide cake (titanium oxide content: 100 g), 4°g of 48°/ was added to one side. The aqueous sodium hydroxide solution was heated and stirred for 2 hours in the range of 95 to 10 °C. Next, the suspension of the titanium dioxide hydrate was filtered and washed. 500 g of water was added to the washed cake to prepare a slurry, and 140 g of 35% hydrochloric acid was further added while stirring, and then 95. (: heating and aging for 2 hours. The aqueous suspension concentration of the obtained fine particle titanium oxide was adjusted to 70 g/L. Polyaluminum chloride was added to the aqueous suspension (relative to the fine particle titanium oxide, Al2〇3) It is 10 wt〇/〇)' and the pH is adjusted to 5.0 by using caustic soda and aged for 30 minutes. After aging, the amount of 6 wt% to 10 wt% based on the solid content of titanium oxide is added. Each of the fluorinated copolymers represented by -1 was aged for 30 minutes, filtered, washed, dried, and pulverized by an ECK superfine pulverizer. Thus, each fluorinated copolymer-treated fine particle titanium oxide was obtained. 2-30 and Table 2-31. 99 201032832 [Table 2-30] Table 2-30: Results of Examples 2-15 and Comparative Example 2·15 Each fluorocopolymer treated fine particle titanium oxide and water/squalane Contact angle test 6% 7% 8% 9% 10% The compound of the invention (a2) 75735° 1447135° 987133° 517141. Permeation/142. The compound of the invention (b2) 85746° 1487136° 1027138° 62./137 ° Permeation / 142. Compound (c2) of the invention 77./37. 1457137. 877137° 547138° Permeation / 143 Comparative Example Compound (d2) 88740° 1407140° 146 7145° 1457140* 1457142° Compound (e2) of Comparative Example 97 748. 1427142° 1447140° 1467142° 143 71436 As shown in Table 2-30, the fluorine containing the comparative example was used. In the treated powder of the copolymer, the water repellency and the oil repellency are increased in proportion to the amount of the treatment, and the powder coated with the fluorinated copolymer of the present invention has a low water repellency and oil repellency when the treatment amount is 6% or less. It shows the highest water and oil repellency when it is 7%. It shows hydrophilic oil repellency when the treatment amount is 10%. Even if the treatment amount is increased to 10% or more, the oil repellency and hydrophilicity will not change. The same results were also seen in the results shown in Table 2-31. [Table 2-31] Results of Example 2·15 and Comparative Example 2-15 Table 2-31 w Water repellency and hydrophilicity, ft test knot j 0% 7% 8% 9% 103⁄4 The compound of the invention (a2) 3 5 3 2 1 The compound of the invention (b2) 3 5 3 2 L 1 The compound of the invention (c2) 3 5 3 2 1 of the comparative example Compound (d2) 4 5 5 5 5 --- 5 Compound (e2) of Comparative Example 4 5 5 5 Examples 2-1 to 2-15 A list of the examples 2_丨~2_15 is shown in the table ❿ 2-32 100 201032832

Jicmpii

[Table 2-32] Table 2-32 Examples and comparison of y trees List of powder compounds to be surface-treated (a2) Compound (b2) Compound (c2) Compound (d2) Compound (e2) Sericite FSE Example 2-1 Example 2-1 Example 2-1 Comparative Example 2-1 Comparative Example 2-1 Titanium CR-50 Example 2-2 Example 2-2 ^ Example 2-2 Comparative Example 2-2 Comparative Example 2-2 Yellow HOOP Example 2-3 Example 2-3 Example 2-3 Comparative Example 2-3 Comparative Example 2-3 Red R-516PS Example 2-4 Example 2-4 1 Example 2·4 Comparative Example 24 Comparative Example 2-4 Black BL-100P Example 2-5 Example 2_5 Example 2-5 Comparative Example 2-5 Comparative Example 2-5 Microparticle Titanium Oxide Example 2-6 Example 2-6 Example 2-6 Comparative Example 2-6 Comparative Example 2-6 Microparticle Oxidation Example 2-7 Example 2-7 Example 2-7 Comparative Example 2-7 Comparative Example 2-7 Pearl Pigment Example 2-8 Example 2-8 Example 2-8 Comparative Example 2-8 Comparative Example 2-8 Amihope LL Example 2-9 Example 2-9 Example 2-9 Comparative Example 2-9 Comparative Example 2-9 Red 202 Example 2-10 Example 2-10 Example 2-10 Comparative Example 2-10 Comparative Example 2-10 Polymethyl oxirane vinyl dimethyl polyoxy siloxane and oxygen Titanium Mixture Examples 2-11 Examples 2-11 Examples Ϊ 2-11 Comparative Examples 2-11 Comparative Examples 2-11 Microparticle Zinc Oxide Examples 2-12 Examples 2-12 Examples 2-12 Comparative Example 2 -12 Comparative Example 2-12 Sericula FSE Example 2-13 Example 2-13 Example 2-13 Comparative Example 2-13 Comparative Example 2-13 Talc JA-13R Example 2-14 Example 2-Μ Example 2-14 Comparative Example 2-14 Comparative Example 2-14 Microparticle Titanium Oxide Example 2-15 Example 2-15 Example 2-15 Comparative Example 2-15 Comparative Example 2-15 Example was obtained for obtaining hydrophilic The oil-repellent minimum coated amount of the treated powder was evaluated. The comparative example was a powder which was coated by the same treatment as the treatment amount of the hydrophilic oil-repellent powder of the example. [Table 2-32] — (2-33: Powder/compound (a2) Compound Cb2) to be surface-treated by the use/adhesion test results Compound (c2) Compound (d2) Compound (e2) Sericite FSE 〇 /◎ 〇/◎ 〇/© △/△ χ/χ Titanium CR-50 〇/◎ 〇/◎ 〇/◎ Δ/Δ χ/χ Yellow LL-100P 〇/x Δ/χ Red R-516PS 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/χ Black HOOP 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/χ Microparticle titanium oxide 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/χ Microparticle oxidation 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/χ Pearl pigment 〇/◎ 〇/◎ 〇/◎ 〇/△ χ/χ Amihope LL 〇/χ Δ/χ Red 202Ο/χ Δ/χ A Mixture of polyoxyalkylene/vinyl dimethyl pump oxime and titanium oxide 〇/◎ 〇/◎ 〇/◎ Δ/Δ χ/χ Microparticle oxidation Δ/Δ χ/χ sericite FSE Δ/Δ χ/滑 Talc JA-13R 〇 / ◎ 〇 / ◎ 〇 / ◎ Δ / Δ χ / χ Microparticles 〇 〇 / ◎ 〇 / ◎ 〇 / ◎ Δ / χ χ / χ 101 201032832 31637ριί (by water dispersion inhibition effect Verification of the resulting moisture retention) Surface treatment of the present invention After the powder was applied to the skin, the following method was used to verify whether or not the effect of suppressing the loss of moisture from the skin by having a moisturizing effect was obtained. The sample was treated with the above-mentioned usability and adhesion test. Test method: A skin roughness model was prepared by blocking application of a 10% sodium lauryl sulfate solution for 30 hours on the forearm flexion of a functional inspector with healthy skin. The sample to be coated was a mixture of Vaseline (Nikk® Rica Co., Ltd.): coated powder = 1 wt%: 1 wt%. Comparative Samples The powders before coating of the respective examples were tested as non-coated powders. In addition, the control was only coated with petrolatum. The coated surface of 2 cm x 4 cm was placed on the rough portion of the skin, and the above sample was applied at 2 mg/cm2. The operation was performed once a day in the morning and evening for 5 days, and the keratinous moisture content of the skin was measured using Skicon-200 (IBS Co., Ltd.). The moisturizing effect was obtained by calculating the ratio of the low-frequency conductivity before coating and after 5 days of coating in the form of relative conductivity by calculation as described below. In addition, the skin thick chain is caused by the chaos of the cristae cutis and the suici cutis. The smoothness or roughness of the skin surface is evaluated by the inspector. The evaluation criteria are numerically calculated as follows and the total value is obtained. The results will not be as shown in Table 2-34. Relative conductivity = low frequency conductivity after coating / low frequency conductivity before coating x100 (%) 102 201032832 [Table 2-34] Powder to be surface treated

Sericite FSE

Titanium CR-50 LL-100P

Red R-516PS BL-100P microparticle titanium oxide microparticle oxidation word pearl pigment

AmihopeLL Red No. 202, Table 2-34: Water Dispersion Inhibition Effect Test Results: Relative Conductivity Compound (a2) 116% 112% 110% 116% 111% 110% 115% 113% 119% 118% Compound (b2) 120% 123 % 123% 120% 114% 116% 115% 122% 125% 119% Compound (c2) 123% 124% 124% 123% 124% 113% 113% 114% 123% Compound 02) 103% 102% 103% 100% 103% 102% 95% 100% 103% Compound 101% 103% 103% 103% 104% 103% 96% 97% 104% 甲 Methyl polyoxyalkylene/vinyl dimethyl polyoxyalkylene with oxygen >鈥 mixture ~ ^ sub-oxidation

Sericite FSE i Stone Powder JA-13R Microparticle Oxidation 118% 115% 115% 120% 120% 110% 102% 117% 117% 113% 123% 112% 117% 119% 114% 123% 114% 103% 98% 103 % 103% ~97%^ 103% 104% 97% 100% 100% 99% The relative conductivity of the control using only petrolatum was 1〇2%. As shown in Table 2-34, the powder coated with the fluorinated copolymer of the present invention exhibited an effect of suppressing water dispersion. [Examples 2-16 to 2-38 and Comparative Examples 2-16 to 2-38] The receivers were prepared for the examples of the cosmetic materials to be combined with the surface-treated powder of the present invention. Based on the composition of the lower wire, # various cosmetics. In addition, regarding each of the examples and the comparison and acquisition of the recorded materials, the makeup completion effect and the makeup squeegee are prepared 2 () for the professional-bee' 凊 使用 使用 使用 使用 , , , , , , , , , , , , , , , , , , , , , Will be full of lack of mining and smoothness. The use of the project is evaluation of easy to paint 103 201032832 31637pii ' [Table 2-35] Table 2-35: evaluation of the use of feeling .... The use of the benchmark is very good - good sense of use, ordinary use - poor sense of use - • △ Very bad feeling X ~

[Table 2-36] --Table 2-36: The evaluation of the makeup finish effect is very jade ^ --- © Feel the effect "o' It feels slightly effective - C~~~· Only feels a small flaw - -- Δ~ — feeling no effect X

For the project to complete the effect, the cosmetic and skin care cosmetics are evaluated for the uniformity of the finished effect, the protective force, the natural luster, and the uniformity of the enamel film. The antiperspirant cosmetic is used to evaluate the presence or absence of stickiness and greasy feeling.

The presence or absence of 'for hair cosmetics is to evaluate the gloss, dryness, smoothness", and easy combing. X

[Table 2-37] Table 2-37 ······································································································

The item of the make-up powder is set to prevent the skin from being dull, preventing secondary adhesion (color shift), and preventing oily light. In addition, it is not easy to peel off for the nail material. (Examples 2 to 16 and Comparative Examples 2 to 16) Production of powdery powder The powder cake shown in Table 2-38 was produced by the following method. Evaluation 104 201032832 J 1UJ /pii The results are shown in Table 2-39. [Table 2-38] Table 2-38 Component parts by weight (1) Sericite (5% treated product of Example 2-1 and Comparative Example 2-1) 35.0 (2) Talc powder (Examples 2-14 and comparison) Example 2-14 5% treated product) to 100.0 (3) Polyfluorene-treated titanium oxide 8.5 (4) Polyfluorene-treated yellow iron oxide 3.5 (5) Polyfluorene-treated red iron oxide 1.8 (6) Polyoxyl Treatment of black iron oxide 0.2 (7) Hydroxyapatite 5.0 (8) Octyl dodecyl myristate 4.0 (9) Squalane 3.5 (10) Methyl phenyl polyoxyl 1.5 (11) Preservative Appropriate amount (12) the right amount of spices

(Production Method) The above components (1) to (7) were mixed and pulverized by a pulverizer. Transfer it to a high-speed blender, add the ingredients (8) ~ (12) and mix them evenly, and mix them evenly. This was passed through a pulverizer, sieved to have a uniform particle size, and then compression-molded in an aluminum vessel at a surface pressure of 10 MPa to produce a dual-purpose powder cake. The above-mentioned press-formed foundation block is measured by the water repellency test method described in Japanese Laid-Open Patent Publication No. 2003-253077. 105 201032832 31637pif [Table 2-39] Table 2-39 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Compound (e2) Uniformity of effect is achieved using 〇〇 〇〇 Δ Δ 〇〇 ◎ • Δ Makeup performance ◎ ◎ ◎ Oil repellency in the water 66. 72. 67. 36. 20. (Examples 2-17 and Comparative Examples 2-17) Production of Emulsified Foundation A W/0 type liquid foundation having the composition shown in Table 2-40 was produced by the following method. The evaluation results are shown in Table 2-41. [Table 2-40] ❹ Table 240 Component parts by weight (1) Decamethylcyclopentaoxane 20.0 (2) Vaseline 0.5 (3) Nonylphenyl polyoxane 2.3 (4) Squalat burning 4.2 (5 ) isotridecyl isononate 4.5 (6) polyether modified polyfluorene *11 3.0 (7) polyoxo-treated red iron oxide 1.3 (8) polyfluorene-treated yellow iron oxide 2.4 (9) Oxygen treatment of black iron oxide 0.1 (10) Polyoxane treatment of titanium oxide 8.0 (11) Polyoxane treatment of talc powder 2.5 (12) Ethanol 5.0 (13) 1,3-butanediol 5.0 (14) sodium vaporization 2.0 (15) Purified water to 100.0 (16) AmihopeLL (5% treated products of Examples 2-9 and Comparative Examples 2-9) 5.0 (17) Preservatives (18)

*11 KF-6038 (manufactured by Shin-Etsu Chemical Co., Ltd.) (Method)

The above components (7) to (11) are mixed and pulverized in advance. To the oil phase obtained by uniformly dissolving and mixing the components (1) to (6) at 70 ° C 106 201032832 加入 ^ / pil, a mixture of the previously pulverized components (7) to (11) is added, and uniformly dispersed. The machine spreads it evenly. The aqueous phase obtained by uniformly mixing and dissolving the components (12) to (17) at 70 ° C is slowly added to the above oil phase, uniformly dispersed by a homogenizer, and then "cooled" is added to the component (18) and sized. The emulsion is emulsified to produce a liquid foundation. [Table 2-41] Table 2*41 Evaluation item Compound (a2) Compound (b2) Sense of use 〇 ◎ 'Completion of the effect of the compound (d2) compound 〇 ◎ ~ 〇 is not evenly distributed in the aqueous component Failed to make a preparation. Take------ Make-up persistence Quality stability ~©~~ ◎ Good Good Good ^ -----1

*12 Oral stability is 5 (TC_temperature bath placed to observe viscosity and separation, sedimentation. No change in appearance is recorded as good. j Examples 2-18 and Comparative Example 2_18) Eye shadow manufacturing results The method is to create an eye shadow of the composition shown in the form. Will be evaluated 107 201032832 31637pii [Table 2-42] Ingredients __ 1. Decamethylcyclopentaoxane Table 2-42 2· Dimercapto-polyoxyl (6cs) 3·Polyether modified polyoxoxime 13 4. PEG (10) lauryl ether 5. Titanium oxide (5% treated product of Example 2-2 and Comparative Example 2-2) 6. Red iron oxide (Examples 2 to 4 and Comparative Examples 2 to 4 of 6) % treated product 7. Pearl pigment (5% treated product of Examples 2-8 and Comparative Examples 2-8) ^Sodiumated gas 9. Propylene glycol 10. Preservative 11. Spice 12_ purified water *13KF6026 (Shin-Etsu Chemical Industry Manufacturing)

(Production Method) (1) The components 1 to 4 are mixed and dissolved. (2) The components 5 to 10 and the component 12 are mixed and uniformly dispersed. (3) The mixture obtained in (2) was slowly added to the obtained mixture in (1) under stirring to carry out emulsification' and the component 11 was added to obtain an eye shadow.

[Table 2-43] Table 2-43 Servant (a2) Compound (b2) Compound (c2) Compound (d2) Compound (e2) 〇 〇 was not uniformly dispersed in the aqueous component and was not prepared as a preparation.疋 效果 “ 〇〇 〇 〇 实施 实施 实施 (Examples 2-19 and Comparative Examples 2-19) Manufacture of oily solid foundation The oily solid foundation of the composition shown in Table 2-44 was produced by the following method. The evaluation results are shown in Table 2_45. 108 201032832 j iuj/pu [Table 2-44] it ύ^χα

(4) Polyglyceryl triisostearate (5) Volatile liquid isoparaffin (6) Earth butterfly (7) Candidella fly 8) Red iron oxide (Example 2·4 and Comparative Example 3~^~ 6% of treated products / Ο Λ 4R VL· ~~7ΤΞ~77ΓΤΤ^Γ~Γ~~~:-. . . _ _------- ❿ | (9) Oxidation Chin (Examples and Comparative Examples) 2·2 (10) Talc powder (5°/〇 treated product of Examples 2-14 and Comparative Example 2-14) (11) Preservative 02) ^ (Manufacturing method) The ingredients (1) - are broken under the above ingredients Ingredients (8) - Add a fragrant residual oily solid foundation to it. • [Table 2-45] (8) ~ (10) Premixed and pulverized. Towards Μ. (7) Mixed and dissolved oil phase Add the pre-powder (11)' and uniformly disperse it by a uniform disperser. 'And fill it into the metalware I' to cool and manufacture the evaluation item compound compound (b2) 〇 compound (c2) 〇 _ use feeling ~~一^__ © w 甘 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Ϊ 效果 效果 效果 效果 效果 XX XX XX XX XX XX XX XX XX XX XX Emulsified sunscreen consisting of the composition shown in Table 2-46. The price results are shown in Table 2-47. 109 201032832 31637pif [Table 2-46]

* ------ Appropriate amount Μ Γ 14 The solid granules of 2_6 and Comparative Example 2·6 are treated with granules of oxygen: 7 〇 (parts by weight) in a sand mill for one side _ gold mining and two pots. The surface-treated powder coated with the specific fluorinated copolymer of the present invention has high pigment dispersibility and storage stability. The external portion 15 was subjected to the composition of Example 2-7 and Comparative Example 2_7 ❺ 9% of the treated granule oxygen oxime: 65 (parts by weight) in a sand mill to form a knives and 1 to 77 impurities. The specific fluorine-containing surface-treated powder of the present invention has high pigment dispersibility and storage stability. (Production method) The oil phase component of d (~5:(7) is dissolved at 75t. The water phase component of the water component of the knives (14) is uniformly dissolved at 75 〇c. The knife is scattered, and iub 〇V i5 ) is applied to the cold part to create an anti-exposure. 110 201032832

OlOJ/pil [Table 2-47] Table 2-47 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Antimony compound (e2) The sensitization was not uniformly dispersed in the aqueous component. Can be made into a preparation. Uniformity of effect 〇 ◎ ◎ 4 makeup durability ◎ ◎ ◎ (Example 2-21 and Comparative Example 2-21) Production of eyeliner The eyeliner of the composition shown in Table 2-48 was produced by the following method. . Will comment

The price results are shown in Table 2-49. [Table 2-48] Table 2-48 Component parts by weight (1) Decamethylcyclopentaoxane 25.0 (2) Dimethyl polyoxane (6cs) 4.0 (3) Jojoba oil 2.5 (4 Polyether modified polyoxonium 16 --- 1.0 (5) Black iron oxide (5% of treated products of Examples 2-5 and Comparative Examples 2-5) 2 (ΰΓ (6) Ethanol----- - 5.0 (7) Preservative (8) Purified water _ i 100.0 *16KF6026 (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Production Method) (1) Components 1 to 4 were mixed at 70 °C. (2) The components 5 to 8 were heated to 70 ° C, mixed and dissolved, and the component (5) was added and uniformly dispersed. (3) The mixture obtained in (2) was slowly added to the obtained mixture in (1) with stirring, and emulsified to obtain an eyeliner. 111 201032832 31637pif [Table 2-49] Table 2-49 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Compound (e2) was not uniformly dispersed in aqueous components using sensation Can be made into a preparation. Uniformity of effect 〇 ◎ ◎ Make-up persistence ◎ ◎ ◎ (Example 2-22 and Comparative Example 2-22) Lipstick production Lipstick of the composition shown in Table 2-50 was produced by the following method. The evaluation results are shown in Table 2-51.

[Table 2-50] Table 2-50 Component parts by weight (1) Diisostearyl malate 15.0 (2) Triisooctanoic acid glyceride to 100.0 (3) Glutamic acid phytyl octyl dodecyl alcohol ester 15.0 (4) Brazilian brown wax 3.5 (5) Candid wax 5.5 (6) Ground wax 5.0 (7) Titanium oxide (5% treated product of Example 2-2 and Comparative Example 2-2) 8.0 (8) Red No. 202 (9% treated product of Examples 2-10 and Comparative Examples 2-10) 0.7 (9) Black iron oxide (5% treated product of Example 2-5 and Comparative Example 2-5) 0.2 (10) Preservative amount (prescription method)

(1) Components 7 to 9 were added to the component 1 and mixed by a roller to be uniformly dispersed. (2) After heating and mixing the other components, the above component (1) is added and uniformly dispersed by a homogenizer. (3) After degassing, it flows into the mold to obtain a stick-like lipstick. 112 201032832

JlOJ/piI

。 。 。 。 。 。 1 ◎ ◎ △ (Example 2_23 and Comparative Example 2_23) Production of lipstick film The lipstick of the composition shown in Table 2-52 was produced by the following method. The evaluation results are shown in Table 2-53.

[Table 2-52]

Table 2-52 Composition (1) Perfluoropoly (Fomblin HC-04) (2) Dioxide (Aerosil R-972) *17 (3) Microparticles of titanium oxide (Examples 2-15 and 10 of Comparative Examples 2-15) (4) Glycerin *17 was prepared by surface treatment of each of the fluorine-containing compounds (a2) to (e2) of 5% by the methods of Example 2-1 and Comparative Example 2-1. (Production Method) The component (2) and the component (3) are added to the component (1) and uniformly dispersed, and then the component (4) is added to prepare a lipstick film. [Table 2-53] Table 2-53 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2)_ Compound (e2) Using sensation • Uniformity of effect 〇 ◎ ◎ Δ X Make-up persistence ◎ ◎ Δ 〇 转印 转印 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 18 The status of the lipstick to the cup. The case where the pad printing has not occurred is denoted by 〇, and the case where the pad printing is slightly printed is denoted as 113 201032832 31637pif Δ' The case where the pad printing occurs is referred to as X. (Examples 2 to 24 and Comparative Examples 2 to 24) Production of Emulsion-Based Liquid Foundation A 〇/w type liquid foundation having the composition shown in Table 2-54 was produced by the following method. The evaluation results are shown in Table 2-55. [Table 2_54] Table 2-54, Ingredient parts by weight (1) Stearic acid 1.5 (2) Cetyl alcohol 1.0 Ο) Polyoxyethylene sorbitan eucalyptus oil "醢 (3EO) 1.0 (4) Sorbitol Anhydride sesquioleate 1.0 (5) Liquid stone butterfly ~---- ' 5.0 (6) 2-ethylhexanoic acid glyceride 5.0 (7) glycerol ' 5.0 (8) 1,3-butanediol 5.0 ( 9) Acrylic-methacrylic acid-based (c, n~, oxime) ester copolymer 0.05 (10) locust bean gum 0.2 (11) triethylamine 0.8 (12) preservative appropriate amount (13) purified water to 100.0 ( 14) Titanium oxide (5% treated product of Example 2-2 and Comparative Example 2-2) 5.0 (15) Yellow iron oxide (6% treated product of Example 2-3 and Comparative Example 2-3) 1.0 (16 Red iron oxide (6% treated product of Examples 2 to 4 and Comparative Example 2-4) 0.3 (Π) black iron telluride (5% treated product of Example 2-5 and Comparative Example 2-5) 0.1 ( 18) Amihope LL (5% of treated products of Examples 2-9 and Comparative Examples 2-9) 5.0 (Production method) A ··The components (1) to (6) are dissolved by heating. B: The components (7) to (() 13) After uniformly heating and dissolving, components (14) to (18) are added and uniformly mixed. C: a mixture obtained by adding b to the mixture obtained from A, After cooling, the liquid foundation is prepared. 201032832 ^i〇j/pn [Table 2-55] Table 2.55 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Disperse evenly and fail to form a preparation. _-^ Completeness of effect 〇 ◎ ◎ Make-up persistence ◎ ◎ ◎ (Example 2·25 and Comparative Example 2_25) % of skin color lotion is produced. Method to produce a skin color lactation composition as shown in Table 2-56

The evaluation results are shown in Table 2-57. [Table 2-56] __Table 2-56_ ~~ Ingredients~~ (1) N-Stearyl Stearic-L·Glutamic Acid ______ (2) Cetyl Alcohol' (3) Polyoxyethylene (1〇) Moer) Single ~~~ (4) Decaglycerol monoisostearic acid vinegar _____ (5) Sorbitol sesquivalent oleic acid employment ~~ (6) Methyl stupid polyoxyalkylene - (7) Glycerin " (8) 1,3-butanediol ' ~ (9) Sanxian gum _ (ίο) Carrageenan - (11) Triethanolamine ~~ (12) Preservatives - (13) Purified jT — (14 Titanium oxide (5% treated product of Example 2-2 and Comparative Example 2-2) (15) Yellow iron oxide (5% treated product of Example 2-3 and Comparative Example 2-3) (16) Red oxygen ^匕铁 (6% of treated products of Examples 2-4 and Comparative Example 2) (Π) Black iron oxide (5% treated product of Examples 2-5 and Comparative Examples 2-5) (18) Talc powder (5% of the treated products of Examples 2-14 and Comparative Examples 2-14 - (Production Method) A: The components (1) to (6) were dissolved by heating. B: The components (7) to (13) were uniformly heated. After the dissolution, the components (14) to (18) were added and uniformly mixed. C: The paint obtained by adding B to the mixture obtained from A was cooled to obtain a skin color emulsion. 115 20103283231637pif [Table 2-57] 2-57 Price item compound (a2) Compound (b2) Compound (c2) Use feeling 1 ◎ 均匀 Complete effect uniformity 〇 ◎ ◎ Make-up persistence y © ◎ ◎ Compound ^ (d2) The compound is not uniformly distributed in the aqueous component Fractionation and failure to prepare a preparation (Examples 2-26 and Comparative Examples 2-26) Production of Bismuth Material The composition of the composition shown in Table 2-58 was produced by the following method. Table 2-59. [Table 2-58]

Table 2-58 - Ingredient Parts by Weight (N-Nitrovicin 10.0 (2) Alkyd Tree Sputum 10.0 (3) Zen-like Acid B-Butyl Triterpenoid 4.0 (4) dl-樟庵-- 1.0 (5) Organic Modification Montmorillonite 1. 〇 (6) ethyl acetate 20.0 (7) butyl acetate to 100.0 (8) isopropyl alcohol 5.0 (9) red 202 (9% of Examples 2-10 and Comparative Examples 2-10) Treatment product) 0.1 (10) Oxidized drink (5% treated product of Example 2-2 and Comparative Example 2-2) 3.0 (11) Pearl pigment (5% of treated products of Examples 2-8 and Comparative Example 2·8) 5.0 (12) Red iron oxide (6% of treated products of Example 2_4 and Comparative Example 2*4) 0.5

(Production Method) The components (1) to (9) were mixed and stirred by a disperser. The ingredients (10) to (12) were added thereto and mixed by a disperser for 10 minutes to produce a nail material, which was refilled into a glass bottle. [Table 2-59] Table 2-59 Item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Compound (e2) 用 〇〇〇 △ △ Uniformity of effect 〇〇〇 △ △ Makeup Persistence ◎ ◎ ◎ 〇〇 additionally 'with the surface covered by the specific fluorinated copolymer of the present invention 116

201032832 ^lDJ/piI The powdered mango material does not form a hard cake over time, and the dispersion stability is good. (Examples 2-27 and Comparative Examples 2-27) Production of blush Red wax having the composition shown in Table 2-60 was produced by the following method. The evaluation results are shown in Table 2-61. [Table 2-60] Table 2-60 ___ Component parts by weight C 1) Sericite (3% treated product of Examples 2-13 and Comparative Examples 2-13) ^ 14.0 (2) Titanium oxide (Example 2-2) And 5% of the treated product of Comparative Example 2-2) 10.0 (3) Yellow iron oxide (5% treated product of Example 2-3 and Comparative Example 2-3) - 1.0 (4) Red iron oxide (Example 2-4) And 6% of the treated product of Comparative Example 2*4) ___ 0.5 (5) Black iron oxide (5% treated product of Example 2-5 and Comparative Example 2-5) _ 0.1 (6) Talc powder (Example 2 14 and 5% of the treated products of Comparative Examples 2-14) _1 - to 100.0 (7) Hxcel Mica JP-2 (Sanhaohuacheng (share)) One-one-7.0 (8) Perfluoropolyfluorene (F〇mbiinHC_ 〇4) A ______ 7.0 (9) Dimethyl condensed alkane (10CS) ____ 5.0 (Preparation method) The components (1) to (7) are uniformly mixed and pulverized. The ingredients (8) and (9) are added to the mixture and uniformly mixed, and then pulverized to produce a pulse red. [Table 2-61] Clip 2-61 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (e2) Using sensation 〇1 XX The uniformity of effect ◎ ◎ 〇Δ Δ 4匕Make-up persistence ^ @ 〇〇 (Example 2_28 and Comparative Example 2·28) Manufacture of an antiperspirant cosmetic The sweat-absorbent cosmetic composition of the composition shown in Table 2-62 was produced by the following method. The evaluation results are shown in Table 2-63. 117 201032832 3103/pit [Table 2-62] Table 2-62 Component parts by weight (1) Carnauba wax 1.0 (2) Mantle 6.0 (3) Paraffin 3.0 (4) Sorbitol sesquiisostearate 2.5 (5) 2-ethylhexanoic acid cetyl ester 27.0 (6) squalane 2.0 (7) decamethylcyclopentaoxane to 100.0 (8) hydroxy aluminized aluminum 25.0 (9) sericite (Example 2-13 and 3% of the treated products of Comparative Examples 2-13) 5.0 (10) Polyoxane-treated talc powder 8.0 (11) Powder La Vie (Sanhaohuacheng (share)) 5.0 (12) Micronized zinc oxide (Example 2 -12 and 7% of the treated products of Comparative Examples 2-12) 2.0 (13) The amount of antioxidant (14) the right amount of spices

(Production Method) The components (1) to (7) are heated and uniformly dissolved. After the components (8) to (13) are added thereto and uniformly mixed, the component (14) is added and cooled to produce a stick-shaped antiperspirant cosmetic. [Table 2-63] Table 2-63 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Compound (e2) Uniformity of effect was achieved using 〇 〇 〇 XX ◎ 〇 ΔΔ Δ Makeup continued Sex ◎ ◎ ◎ 〇〇

(Examples 2-29 and Comparative Examples 2-29) Preparation of Hair Care A hair care composition having the composition shown in Table 2-64 was produced by the following method. The evaluation results are shown in Table 2-65. 118 201032832

~J J. \J^ / AX

[Table 2-64] Table 2-64

(Preparation method) A: The components (1) to (9) are heated, and the components (10) to (13) are heated and mixed and dispersed. C: A mixture obtained by adding B to the mixture obtained from A was mixed, and after cooling, the component (14) was added and cooled to prepare a hair lotion.

[Table 2-65] Table 2-65 Compound (a2) Compound (b2) Compound (c2) 1 Sense "θ' ◎ 〇 砥 砥 砥 _ _ _ ◎ ◎ ◎ Continuability ----- ◎ ◎ Compound (infringement) 丨 compound (D was not uniformly dispersed in the aqueous component and could not be prepared. (Examples 2-30 and Comparative Examples 2-30) Production of skin color cosmetic liquid ^ By the following method The skin color moisturizing liquids shown in Table 2-66 were produced. The evaluation results are shown in Table 2-67. 119 201032832 31637pif [Table 2-66] Table 2-66 Ingredients 11) Purified water (2) Acrylic acid - formazan Propylene base (C 〇 30 ~ 30) vinegar a total of pens · (3) carboxy vinyl polymer __- " 00 preservatives (5) particulate oxidation Qin (Example 2_丨5 and Comparative Example 2 10% of treated product of 15) (6) Triethanolamine (7) Glycerin ________ (8) Titanium oxide (5% treated product of Example 2-2 and Comparative Example 2-2) (9) Yellow iron oxide (Example) 2-3 and 5% of the treated products of Comparative Example 2-3) (10) Red iron oxide (6% of treated products of Examples 2 to 4 and Comparative Examples 2 to 4)

Ϊ1) Black iron oxide (5% treated product of Example 2-5 and Comparative Example 2-5) Ϊ2) Talc powder (5% of treated products of Examples 2-14 and Comparative Examples 2-14) (Preparation method) ~~~八么(1)(4)force °heat and evenly dissolve, then add into the knife (5) and evenly disperse and mix. Adding the ingredients (4) into and mixing the compound (8) ~ (丨2) %, adding the ingredients (7) [Table 2-67]

It was not uniformly dispersed in the aqueous component and was not prepared into a preparation. Shadow. The water-based liquid eye composed of the 彳 彳 转 2 2 咖 咖 咖 咖 咖 咖 汴 汴 、 、 水性 水性 水性 水性The results are shown in Table 2-69. 201032832

JlOJ/pu

[Table 2-68] Ingredients 1) Purified water (2) Acrylic acid-alkyl methacrylate (C10~30) 81#^: (3) Carboxyvinyl polymer _ _ ' (4) Preservative (5) III Ethanolamine (6) glycerol (7) titanium oxide (Example 2-2 and Comparative Example 2-2 Table 2-68

(8) Red iron oxide (Example 2-3 and Comparative Example 3) Pearl pigment (Examples 2-8 and Comparative Example j (Production Method) A: The components (1) to (4) were heated and both were resolved and then divided (5). Evenly mixed. Bacheng B: After the ingredients (7) to (9) are combined, add and mix evenly. ^ , "C: Add the mixture obtained by (4) to the secret mixture of A and mix it to produce liquid water. [Table 2-69] ---- Table 2-69 Item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Compound 02) The sensitizer is not uniformly dispersed in the aqueous component but not Can be made into a preparation" Uniformity of Yuancheng effect ◎ ◎ ◎ Persistence ◎ ◎ ◎

(Example 2-32 and Comparative Example 2-32) Production of whitening powder A whitening powder of the composition shown in Table 2-70 was produced by the following method. The evaluation results are shown in Table 2-71. 121 201032832 31637pif [Table 2_70] Table 2-70 Component parts by weight (1) Magnesium L-ascorbate 1.0 (2) Sodium citrate 1.0 (3) 1,3-butanediol 5.0 (4) Glycerol 5.0 (5 Purified water to 100_0 (6) p-hydroxybenzoic acid methyl ester 0.2 (7) sericite (5% treated product of Example 2-1 and Comparative Example 2-1) 5.0 (8) Talc powder (Example 2-14) And 5% of the treated products of Comparative Examples 2-14) 0.1 (9) Organic polyoxyalkylene oxide elastomer powder 3.0 (10) Partially crosslinked organopolyoxyalkylene polymer *19 5.0 (11) Polyoxylized red Antimony iron 0.5 (12) trifluoroalkyl dimethyl tridecyl alkaneoxy acid 3.0

氺19KSG-16 (manufactured by Shin-Etsu Chemical Co., Ltd.) (Production Method) A: The components (1) to (8) are mixed and dispersed. B: The components (9) to (12) were uniformly mixed. C: The mixture obtained in the above A was mixed with the mixture obtained in B, and filled into a container to obtain a whitening powder. [Table 2_71] Table 2-71 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Compound (e2) The use of sensible 〇 〇 was not uniformly dispersed in the aqueous component and was not prepared as a preparation. Uniformity of effect ◎ ◎ ◎ Make-up persistence ◎ ◎ ◎ (Example 2-33 and Comparative Example 2-33) Production of sun-proof cream The anti-day composition of the composition shown in Table 2-72 was produced by the following method. Sun cream. The evaluation results are shown in Table 2-73. 122 201032832 JIO-J /pu

2.0 (4) Diethylhexyl succinate ~~-----——

[Table 2-72] _ Table 2-72 (1) Decamethylcyclopentaoxane

(Abil EM90: Evonik Degussa) (3) Isophthalic acid is brewed —

(11) Microparticle oxidation water dispersion *20 (12) Preservative _ 5.0 JOO

*10 The 10%-treated fine particles of Example 2-6 and Comparative Example 2-6, titanium oxide/purified water/glycerin = 45/50/5, were dispersed by a sand mill to prepare an aqueous dispersion. The aqueous dispersion of the examples does not settle and separate over time and is relatively stable. The dispersion of the dispersion of the comparative example was not carried out, and a uniform and stable dispersion could not be formed. (Production Method) Α. The components (3) to (6) are heated and mixed. Β : After uniformly mixing the components (1) and (2), it is added to the mixture obtained in the above A. C: The components (7) to (12) were mixed and dissolved. D: A mixture obtained by adding C to the mixture obtained in the above B was emulsified to obtain an anti-sun cream. 123 201032832 31637pit [Table 2-73] 1-r-Table 2-73 矸11 Item Compound (a2) Compound (b2) Compound (c2) Compound (d2) | Compound use feeling L© ◎ ◎ Not in aqueous component It was not made into a preparation. Uniformity of the effect ◎ ◎ ◎ 1 匕 持续 ^ ^ ◎ ◎ ◎ ◎ 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质 质The presence or absence, separation, and sedimentation were observed. The cosmetic material having no change in appearance such as crystallization was considered to be good. The cosmetic materials blended with the treated powders of the compounds (d2) and (e2) of the comparative examples were crystallized on the next day to cause separation. (Production Example 2-34 and Comparative Example 2-34) Production of Anti-sunlight Condensation The anti-sunlighting gel of the composition shown in Table 2-74 was produced by the following method. In Table 2-75. [Table 2-74]

124 201032832

_5 丄OJ/piI °C. The components were slowly added to the above neutralized components, and emulsified by a homogenizer to obtain an anti-sun gel. [Table 2-75] Table 2-75 One ______-π Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2) |Chemical content, ez) Sense of use ~W~ ◎ ◎ Treatment of powder Condensation was not obtained without being dispersed in the aqueous layer. Uniformity of the finished effect ◎ ◎ Make-up persistence 〇 ◎ 1 SPF value of the preparation 18 20 19 Stability over time 22 ◎ ◎

*22 The preparation was stored at 50 ° C for 1 month. The cosmetic material having no change in appearance was recorded as ◎. The cosmetic material to be blended with the surface-treated powder of the present invention does not have reactivity with a water-soluble polymer, so that a stable preparation is obtained. (Example 2-35 and Comparative Example 2-35) Production of Wet-Formed Powder Cake A foundation having the composition shown in Table 2-76 was produced by the following method. The evaluation results are shown in Table 2-77. [Table 2-76] Composition

------77_____ (1) Sericite (3% of treated products of Examples 2-13 and Comparative Examples 2-13) (2) MW treatment (hydrophilization treatment) ΡΜΜΑ (Sanhaohuacheng (share)) (Implementation) 5% of the treated products of Example 2-2 and Comparative Example 2-2 (4) Yellow iron oxide (5% of treated products of Examples 2-3 and Comparative Examples 2-3), g, "A, · must / ▲ —...一—..............上上〇rt (5) red tile iron (6% of treated products of Examples 2 to 4 and Comparative Examples 2 to 4) (6) Black iron oxide ( 5% of the treated products of Examples 2-5 and Comparative Examples 2-5) rn\ ^ ^ , 1. ^ ^ ----- (7) p-Walki cinnamic acid _2·ethylhexyl ester (8) polyoxygen Ethylene (20 mol) hardened castor oil (preparation method) 厶-/ v

A: The components (7) and (8) were heated to 75 ° C to be uniformly dissolved. B: The components (1) to (6) were mixed by a mixer to carry out ultrafine pulverization. 125 201032832 31637pif c : - Surface mixer - Stir the above B, and add A to the surface to uniformly disperse. D: 1 part by weight of purified water was added to 1 part by weight of the component of c, and uniformly mixed to obtain a slurry. E. Fill the above D into a metal vessel, place the absorbent paper on the surface and pressurize to remove a part of the purified water. F: The above F is 50. The mixture was placed in a thermostatic bath for 24 hours to completely remove the purified water to obtain a wet-formed powder cake. [Table 2-77] ~~--- ___ Table 2-77 Evaluation item Compound (a2) Compound (b2) Compound ( C2) Compound (d2) Compound (e2) Using sensible ◎ ◎ 未 未 未 均匀 均匀 均匀 均匀 均匀 均匀 均匀 均匀 均匀 均匀 未能 未能 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成 完成Example 2·36 and Comparative Example 2-36) Production of F/W Emulsion Emulsion An emulsion of the composition shown in Table 2-78 was produced by the following method. The evaluation results are shown in Table 2-79. 78] Ingredient Weight 伢U) All-Polymeric Bond (Fomblin HC/04: Solvay) 25.0 (2)_Hefflurane (CF-76: 3M) 10.0 C3) Polyoxygenated Talc 1.5 (4) B Leaven 8.0 (5) Glycerin "ΤΓ (6) Micronized zinc oxide (7% of treated products of Examples 2-12 and Comparative Examples 2-12) 5.0 [7) Purified water to 100.0 (8) Preservatives are suitable (manufacturing method) A: The components (1) to (3) were uniformly mixed and heated to 50 °C. B: The components (4) to (8) were dispersed and dissolved by a homogenizer to '126 201032832 J) IOJ φ ΙΓ and heated to 50 °C. C: While the above b was stirred by a homogenizer, the above A was slowly added to obtain an F/W emulsified emulsion. [Table 2-79] Table 2-79 #Price item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Compound (e2) Using sensible ◎ The treated powder was not uniformly dispersed and failed to form an emulsification. Things. Uniformity of effect 〇〇 ◎ 代 代 代 ◎ ◎ ◎ 实施 实施 (Example 2-37 and Comparative Example 2-37) Manufacture of W/F emulsified emulsion The composition shown in Table 2-80 was produced by the following method. Lotion. The evaluation results are shown in Table 2-81. [Table 2-80] Table 2-80 Component parts by weight (1) Perfluoropolymer L Fomblin HC/04 : Solvay Company) 45.0 (2) Hydrofluoroether (CF-76: 3M) 15.0 (3) Polyfluorene Oxygen-treated talc 1.5 (4) Ethanol ' ' 8.0 (5) Glycerol 3.5 (6) Micronized zinc oxide (7% of treated products of Examples 2-12 and Comparative Examples 2-12) 5.0 (7) Purified water to 100.0 ( 8) Preservatives - Moderate

(Preparation method) A: The components (1) to (3) were uniformly mixed and heated to 5 Torr. Hey. B. The components (4) to (8) are dispersed and dissolved by a homogenizer, and heated to 5 °C. C: While stirring the above A with a homogenizer, the above B was slowly added to obtain a W/F emulsified emulsion. 127 201032832 31637pif [Table 2.81] Table 2-81 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2) Compound (e2) Sense ◎ 〇〇 The powder was not uniformly dispersed, and failed. Formation of emulsion" Uniformity of effect of completion 〇〇〇 Make-up persistence ◎ ◎ (Example 2-38 and Comparative Example 2-38) Production of powder emulsified sunscreen

The emulsion of the composition shown in Table 2-82 was produced by the following method. The evaluation results are not shown in Table 2-83. [Table 2-82] Table 2-82 Component parts by weight (different sixteen: - 20.0 - oxime isophthalic acid + trialkyl cool - 7.0 I3) 曱 甲 妙 妙 二 二Aerosil R972: Japan Aerosil Co., Ltd. 3.5 - (4) Microparticle titanium telluride (10% treated product of Examples 2-15 and Comparative Examples 2-15) 5.0 (5) Microparticle zinc telluride (Example 2-12 and Comparative Example 2 12% of the treated product) 10.0 (6) Ethanol 5.0 ~ ~ "7) Glycerol 7.0 (8) Purified water - -- to 100.0 (9) Preservatives

(Production Method) A: The components (1) to (3) were uniformly mixed by a disperser and heated to 50 °C. B: The components (4) to (9) were heated to 50 ° C and uniformly mixed and dispersed. C. While stirring the above A with a homogenizer, the above B is slowly added to obtain a powder emulsified sunscreen. 128 201032832

JlD^/piI

[Table 2-83] Table 2-83 Evaluation item Compound (a2) Compound (b2) Compound (c2) Compound (d2) | Beta (e2) Powder was not uniformly dispersed using sensible treatment 'Failed An emulsion is formed. Uniformity of effect 〇〇 ◎ 化妆 化妆 ◎ ◎ ◎ ◎ ◎ ◎ ◎ [Industrial Applicability] The surface-treated powder of the present invention is preferably used as a surface-treated powder for cosmetics, but it can be applied not only to The cosmetic material can also be applied to various fields such as powder filler, ceramic material, magnetic material, rare earth, optical material, conductive material, voltage material, etc., which are blended in Lu ink, paint, resin masterbatch, paper, and the like. Although the present invention has been disclosed in the above embodiments, it is not intended to limit the invention, and any one of ordinary skill in the art can make some modifications and refinements without departing from the spirit and scope of the invention. The scope of the invention is defined by the scope of the appended claims. [Simple description of the diagram] [Key component symbol description] Benefit 129

Claims (1)

201032832 31637pif VII. Application for patents: Surface treatment: Covering with a surface treatment agent (b) The total amount of fluoromonomers and copolymerizations represented by the following formulas (1) Material: Supplemental early body [Chemical 1] ❹ CH2=C(-X)_C(=〇)-Y-[.(CH2)m-2-]p-(CH2)n-Rf (1) [In the formula X is a hydrogen atom, a methyl group, an I atom, a gas atom t, a 1X2 group (wherein a hydrogen atom H^ atom), a cyano group, a linear or branched alkyl group having a carbon number of 1 to 20,姆代 or unsubstituted base, substituted benzyl y. Y is or · ΝΗ _; Z is a direct bond, | or Weng; ^ is 1 ~ 6 of the fluoroalkyl group, is Bu 1 〇, 0 〇~ , f is [Chemical 2] ^ 1J CH2=C(X1)-C(=〇)-〇-(R〇)q.X2 [wherein x1 money atom ❹ group; χ2 is hydrogen atom or carbon number (= ~ 22 unsaturated or saturated nicotine; R money atom - part or H is replaced by a base with a carbon number of 2 to 4; q is bu = upper two = special range 2 item 1 In the surface treatment powder, in the upper formula (II), χ2 is a hydrogen atom. , A. 3. The body described in the scope of claim 2 or 2, The above-mentioned surface-treated powder has a water-repellent property. The surface-treated powder of the above-mentioned surface-treated powder has a hydrophilic oil-repellency. 5. The surface-treated powder according to any one of the above-mentioned claims, wherein the constituent component of the fluorinated copolymer comprises cross-linking represented by the following formula (guar) The fluorine-containing copolymer of the monomer is coated: [Chemical 3] CH2=C(X3)-C(=〇)-〇_(Ri〇)q_c(=〇)_C(:x3)=CH2 ( m ) [ Wherein each X3 is a hydrogen atom or a methyl group; R1 is a hydrogen atom - a part or all of an alkyl group having a carbon number of 2 to 10 which may be substituted by a hydroxyl group; q is an integer of from i to 50]. The surface-treated powder of any one of the above-mentioned items, wherein the fluorocopolymer has a weight average molecular weight of from about 1,000 to about 1,000,000. As in the first to sixth aspects of the patent application. The surface-treated powder according to any one of the above-mentioned fluorinated copolymers, wherein the gas-containing green body (4) is 100 parts by weight 'and the alkoxy group-containing monomer (b) is 1 part. The surface-treated powder of any one of the above-mentioned items of the present invention, wherein The surface-treated powder of any one of the above-mentioned surface treatment agents, wherein the surface treatment agent is further selected, the surface-treated powder of any one of the above-mentioned surface treatments. One or more compounds from the following compound groups, the above compound group: other fluorine-containing copolymers other than the above-mentioned fluorine-containing copolymers; 201032832 JIOJ/pn compound, organic polyoxane, alkyl decane, polyether modified Hydrazine, organic titanate, polyolefin, hydrogenated lecithin (hydrogenated lecithin containing salt form), thiolated amino acid (thiolated amino acid in the form of a salt or a composition), acidic ester oil , fatty acids (including fatty acids in salt form), and paste 5 fatty acid esters. 10. The surface-treated powder according to claim 9, wherein the fluorine-containing compound is a perfluoroalkyl phosphate having a carbon number of 6 or less and At least one of a fluoroalkyl decane, a perfluoropolyether phosphate, and a perfluoropolyether decane. η. The surface of any one of the above-mentioned claims, wherein the powder is 100 parts by weight of the powder to be surface-treated, and 0.01 parts by weight to 399%. The above-mentioned copolymer-containing component and 39.99 parts by weight to 0. 01 parts by weight of one or more compounds selected from the group of the above compounds are coated. The surface-treated powder according to any one of claims 1 to 11, wherein the powder of the powder cosmetic to be surface-treated is the powder. Ruler with π 13. If the surface-treated powder described in item 12 of the full-time application is applied directly, the above-mentioned cosmetic sample is an inorganic powder that can be used as a cosmetic material. 14. The surface-treated powder as described in claim 13 (4), 1 the above inorganic powder is exhausted mica, mica, kaolin, talc, bismuth hydride, nitrogen (10), titanium oxide, zinc oxide, iron oxide, : Any one or two or more of the bead pigments. / 15 · The surface-treated powder according to claim 12, wherein the powder of the above-mentioned (four) is a viscous (four) financial powder. • ^ t cosmetic, which is characterized by the combination of the surface treatment powder as described in the application of the full term. The cosmetic material according to Item 16, wherein the cosmetic component further comprises at least one of an aqueous component of the oil f-forming blade and a surfactant as a constituent component. For example, the cosmetic materials described in claim 16 or 17 of the patent application, • are any cosmetics in skin care cosmetics, hair cosmetics, cosmetic cosmetics, and anti-UV chain materials. 19. The cosmetic according to any one of claims 16 to 18 wherein the product form is liquid, emulsion, cream, solid shape, paste, gel, powder, and more Any of lamellar, mousse, and spray. 133 201032832 /pil IV. Designated representative map: (1) Designated representative figure of the case: None (2) Simple description of the symbol of the representative figure: No. 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention. : CH2=C(-X)-C(=0)-Y-[-(CH2)mZ-]p-(CH2)n-Rf (I) (Π) CH2=C(X1)-C(=0 )-0-(R0)q-X2 201032832 /pul is the 98119229 Chinese manual without line correction page Invention patent specification (Do not change the format and order of this manual, please do not fill in the ※ part) ※Application number: ※Application曰: ^PC classification: 1. Name of the invention: (Chinese/English) Surface treatment powder and Cosmetics SURFACE-TREATED POWDER AND COSMETIC INCORPORATED WITH THE SAME II. SUMMARY OF THE INVENTION The present invention provides a surface-treated powder excellent in usability and adhesion to skin, which is composed of (a) A surface treatment agent of a fluorine-containing monomer of the formula (I) and (b) a fluorine-containing copolymer of the alkoxy group-containing monomer of the formula (II) is coated. This powder is used in various cosmetics. CH2=C(-X)-C(=0)-Y-[-(CH2)mZ-]p-(CH2)n-Rf (I) [Chemical 2] CH2=C(X1)- C(=0)-0-(R〇)q-X2 (Π) 201032832 310J/pul The alkoxy group-containing monomer (b) is 10 parts by weight to 400 parts by weight. (8) The surface-treated powder according to any one of (1) to (7), wherein the coating amount of the fluorinated copolymer is 〇 with respect to 1 part by weight of the powder to be surface-treated. · 1 part by weight to 4 parts by weight. The surface-treated powder according to any one of (1) to (8), wherein the surface treatment agent further comprises one or more compounds selected from the group consisting of the following compound groups: Other fluorine-containing compounds other than fluorinated copolymers, organic polyoxonium oxide, alkyl decane, polyether modified decane, organic titanic acid vinegar, polyolefin, hydrogenated lecithin (hydrogenated (tetra) lipid containing salt form) A thiolated amino acid (containing a salt form or a group of flavonoid amino acids), an acidic (tetra), a fatty acid (a fatty acid containing a salt green), and a dextrin fatty acid ester. 〇〇 〇〇 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面 表面The at least one of the above-mentioned compounds (1) to (10), wherein the powder to be surface-treated (10) parts by weight = two parts by weight of the above-mentioned fluorine-containing copolymerized two or selected from the above compounds In the group - (12) as in (1) to 〇1) - :: the above-mentioned surface treatment powder to be surface treated, as described in (12), which can be used for makeup The powder of the material is an inorganic powder which can be used for the cosmetic material. The powder is the surface-treated powder described above. The above-mentioned inorganic tertiary body is a serifte, a mica (mka), a kaolin (10) = a powder, and a second Any one of the pigments of the oxidized stone (-a), barium sulfate, boron nitride, iron oxide, and the pigment (15), the surface-treated powder according to (12), the powder of the cosmetic The body is an organic powder 可 which can be used for a cosmetic, and in another aspect of the present invention, it can be provided that the surface treatment powder is contained Preferably, the present invention is in addition to the surface treatment powder, and at least one of water_minute' and surfactant, the chemical (4) of the present invention is preferably a skin material ( Skin·) ^ (make_up) = any cosmetic in the cosmetic. The shape of the product is preferably two L, shape, cream, solid shape, paste (ρ_ (gel), powdery 'multilayer Any form of m(msse (spray) shape. Shape and spray [Effects of the Invention] The present invention provides a component which is compatible with the adhesion of the skin to the skin. Affinity = face ^ Li powder Zhao 'especially provide - a kind of cosmetic material with surface treatment powder 201032832 / pul portion ~ 0.5 parts: 0.5 parts ~ 34.5 parts. When the ratio of the blending amount of the cosmetic material and the amount of the blending roller material is the same as the amount of the blending roller, the effect of reducing the effect in the chemical conversion (4) tends to decrease: the powder used in the present invention is variously selected. The field is succinct, that is, the love is selected by taking the material as (4): the powder used for the material. Further, it is possible to select an inorganic powder and an organic powder T. For example, 'inorganic powders can be cited: boron nitride, sericite, natural mica, calcined f, synthetic mica, synthetic sericite, oxidized mica, mica talc, kaolin, bentonite, smectite , calcium carbonate, magnesium carbonate, calcium phosphate, phthalic anhydride, magnesium oxide, tin oxide, iron oxide, oxidation, chromium oxide, oxidation, oxidation, oxidation #, oxidation, magnesium oxide, chromium hydroxide, iron blue ( Iron blue), ultramarine, calcium phosphate, aluminum hydroxide, barium sulfate, magnesium sulfate, citric acid, aluminum magnesium citrate, acid strontium, acid strontium, magnesium citrate, acid ming Crushed, magnesium fluoride, metal tungstate, magnesium aluminate, magnesium metasilicate aluminate, chlorohydroxyaluminum, clay, zeolite, hydroxyapatite, ceramic powder, tip Spine, mullite, cordierite, aluminum nitride, titanium nitride, tantalum nitride, niobium, tantalum, button, money, box, condensed, Mn-Zn ferrite ( Ferrite), Ni-Zn ferrite, silicon carbide, cobalt titanate, titanic acid , iron titanate, lithium cobalt titanate, sulphuric acid, tin oxide, tin oxide, magnetite, flour, gold powder, silver powder, platinum powder, copper powder, noble metal colloid ), iron powder, lotus powder, cobalt blue, cobalt violet, cobalt green, low-priced titanium oxide, 29 201032832 31637pifl microparticle titanium oxide, butterfly-like barium sulfate, petal-like zinc oxide, - tetragonal zinc oxide, microparticle oxidation Zinc; pearl pigments include titanium oxide coated mica, titanium oxide coated mica, titanium oxide coated synthetic mica, titanium oxide coated cerium oxide, titanium oxide coated synthetic mica, titanium oxide coated talc, and zinc oxide coated oxidized Bismuth, titanium oxide coated with mica, iron oxide coated mica titanium, iron and black iron oxide coated mica titanium, carmine coated mica titanium, prussian blue (pmssian Wue) coated mica titanium and other pearl pigments. Specific examples include Merck's Iri〇din (registered trademark) series, Timiron (registered trademark) series, c〇1〇r〇na (note: trademark) series, Dichrona (registered trademark) series, and Xir〇na (registered Trademark) series, R0nastar (registered trademark) series, BARSF's Desert Reflections series, Timica series, Flamenco series, Cloizonne series, Duocr〇me series, Gemt〇ne series, (9) series \ Mearlmaid series, Reflecks series, ❿ 丄Other series, Cosmica series 'Eckart's prestige (registered trademark) series, Visi〇naire (registered trademark) series, Mirage series, Japan's platen company's Metashine (registered trademark), Japan Optical Research's pr〇minence ❹ (registered trademark) ), CQV's C〇smetica White pead series, sharon Pearl series, etc., the company's pred〇s 〇 把 P Pearlescent Pigments series. For example, effect pigments such as aluminum flakes, oxidized hair flakes, oxidized crystal sheets, and glass flakes, iron oxide coated cloud U fat red, titanium oxide coated butterfly sulphuric acid (nano/dance), oxidation Titanium coated with sulphuric acid (word / Ming), oxygenated sulphur, squama, stainless steel (stainless) powder, tourmaline (t〇unnaline) powder will sapphire 30 201032832 31W/pill C〇ming EP-9289 LL C0smetic p〇 Wder), the Coverleaf series and the Concelight series which are commercially available from the company. Further, in order to improve the affinity or fixability with the surface treatment agent, the powder to be surface-treated in the present invention may be, for example, in advance, #5, town, 钸, dream, wrong, titanium, zinc, An oxide or an aqueous oxide of at least one of iron, inscription, bell, nickel, and tin is coated. These compounds can be surface-treated by the surface treatment agent which is surface-treated in the present invention. • The coating is previously carried out, and it may be coated at the time of surface treatment. Further, the oxide or the hydrous oxide particles may be coated or precipitated on the surface of the powder particles to be surface-treated. The amount of the third substance to be coated is preferably the minimum amount necessary for the function of the fluorine-containing compound of the present invention to be expressed by the surface-treated powder. In the present invention, the method of coating the surface treatment agent, particularly the specific fluorine-containing copolymer, on the powder is not particularly limited and can be carried out by a known method. The surface treatment methods are roughly classified into a dry method and a wet method. For example, using a Henschel mixer or a ball mill, a jet mill, a kneader, a pianetary mixer, a pony mixer, sand Sandmill, attritor, ribb〇n blender, disper mixer, homogenizer, extruder, etc. The machine or the pulverizer, the mixer, and the dispersing machine are used to carry out the treatment by mixing the surface treating agent used in the present invention with the powder for a certain period of time. At this time, it is also possible to apply mechanochemical mechanical force, plasma, flame, 33 201032832 31637pifl ultraviolet light, electron beam, superheated steam, laser light, electromagnetic wave, etc. deal with. In the wet method, the powder and the surface treatment agent are dispersed in water or a solvent, a supercritical fluid (water, c〇2, etc.) to be mixed and contacted, and then the solvent is evaporated to perform treatment. Further, the specific fluorine-containing copolymer used in the present invention contains a fluorine-containing compound selected from the group consisting of perfluoroalkyl phosphate, perfluoropolyether phosphate, perfluoropolyether decane, and perfluoroalkyl decane. Organic polyoxyalkylene, alkyl decane, organic titanate, polyolefin 'hydrogenated lecithin (including salts thereof), N-decylamino acid (including salts or compositions thereof), acidic ester oil, fatty acid (including In the case where the salt or the one or more compounds of the dextrin fatty acid ester are subjected to surface treatment in combination, the same as in the case of surface treatment using only the above specific fluorine-containing compound, The powder is surface-treated by mixing with a surface treatment agent further containing the compound. Further, the properties (liquid, solid, gel, etc.) and physical properties (melting point, boiling point, glass transition temperature, solubility, reactivity, etc.) of the compound selected for surface treatment in combination with the surface treatment are required to be coated. The surface of the powder is selected to select the optimum coating manufacturing method, and the coffee is limited by the manufacturing method. In the case of performing surface treatment in a composite manner, a method of coating a specific object and then coating another surface-treated ship of the specific fluorine-containing copolymer may be mentioned; (4) being (4) a gas-containing complex, A method of recoating a specific fluorine-containing copolymer, etc., after the paste component of the surface of the gas-containing copolymer material of the gas-coated copolymer material other than the oxygen-containing copolymer. A preferred coating method is to cure the fluorochemical agent and the 5 g of IPA after the specific fluorinated copolymer, and then remove the solvent by vacuum heating and dry at 105 ° C. And pulverized for 16 hours, and each of the fluorine-containing compound treatment red No. 202 was obtained. A list of Examples 1-1 to 1-14 and Comparative Examples is shown in Table 1-2. [Table 1-2] 1 1-2: Hydrating compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Sericite FSE Example 1-1 Example 1-1 Example 1-1 Comparative Example 1-1 fc匕 Comparative Example 1·1 MicaΥ-2300 Example 1-2 Example 1-2 Example 1-2 Comparative Example 1 -2 Comparative Example 1-2 Talc JA46R Example 1-3 Example 1-3 Example 1·3 Comparative Example 1-3 Comparative Example 1-4 Comparative Example 1-3 was carried out in ιΙ1·/Ι Titanium CR-50 Example 1·4 Example 1-4 Example Yellow LL-100P Example 1-5 Example 1-5 ~~ Example 1_5 Comparative Example 1-5 Comparative Example ι-i~ Red R-516PS Example 1-6 Example 1-6 Example 1-6 Comparative Example 1-6 Black BL-100P Example 1-7 Example 1-7 _ Appreciation Example 1-7 Comparative Example 1-7 Comparative Example 1-7~~ Microparticle Titanium oxide Example 1-8 Example 1-8 Example 1-8 Comparative Example 1-8 Comparative Example 1·8 Microparticle cerium oxide Example 1-9 Example 1-9 Example 1-9 Comparative Example 1-9 Comparison Example 1-9 Microparticle Oxidation Example 1-10 Example 1-10 Example 1·10 Comparative Example M0 Comparative Example 1-10 Example of particle oxidation 1-11 Example 1-11 Example 1-11 Comparative Example M1 Comparative Example 1-11 Pearl Pigment Examples 1-12 Example 1-12 Female Court Example 1-10" Comparative Example 1-12 Comparative Example 1-12 Amihope LL Example 1-13 Example 1-13 Example lh Comparative Example 1-13 Comparative Example 1-13 Red No. 202 Example Μ 4 Example 1-14 X Example 1-14 ——— Comparative Example 1-14 Comparative Example 1-14 (contact angle test of water and squalane) Attach a double-sided tape to a glass slide and apply a surface powder to the other side of the double-sided tape using a puff (jj^eup pUff). Body until the tape surface loses adhesion. Using a contact angle meter (CA-D) manufactured by Kyowa Interface Science Co., Ltd., water or squalane (dropping amount of 10 1 ) was dropped on the surface of the powder coated crucible, and the droplets and powder coated surfaces after 20 seconds were measured. The angle formed (contact angle). (The number of η is set to 5) (Useability and adhesion test) Functional inspection by 15 functional tests capable of surface-treating powders 49 201032832 31637pitl fn private body_Useability of each surface-treated powder. The ping price method is performed by the finger or the upper arm, and the main or upper arm is used to perform the "4" application to the fingernail i to enter the π 疋 疋 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由 由: very good, 〇: good, △: normal, (evaluation method for water repellency and hydrophilicity) Add about 50 ec of purified water to a glass beaker of ^00 cc. Treat the powder with water at 0·1 g, and use The spatula is mixed at a rate of about 2 = per second. The turbidity of the aqueous phase after mixing π times, 1 time, and 150 times is evaluated in 5 levels. <Evaluation Criteria> 4 3 2 1 No turbidity in the water phase. (Strong water repellency) The water phase is slightly turbid. The water phase shows obvious turbidity. Most of the powder is transferred to the water phase. All the powder is transferred to the water phase. (Hydrophilic (evaluation) Result) Θ Zhao: ==:1~!·14 Surface treatment powder 50 201032832 Jiw/piil [Table 1-3] Table 1-3: Contact angle test results of water/squalane Compound (al) Compound (bl) Compound (cl) Compound (dl) Compound (el) Sericite FSE 1357130" 1337133° 1407130° 1247120° 1417135° Mica Y -2300 1387130° 1327130° 137 7133° 1267129° 1457137^ Talc JA-46R 1347127° 130 7125* 1367130· 1267129° 1477130° Titanium CR-50 1307130° 1327133° 1357130° 1367139° 1467139° Yellow LL^IOOP 1377130" 133 713Γ 138 7132° 1367120° 1457135° Red R-516PS 1367130° 1357123° 1357128° 1367130° 1457130° Black BL-100P 130 7132° 1327134° 1337130° 1367130° 142713 Wide particle oxidation type 1327ΐ30ΰ 1327133° 1377124° 1367131° 1457ΐ30β Microparticle oxidation Titanium 87130° 107132° 107133° 1367130° 1457140° Microparticles titanium oxide 97130° 127133° 87130° 1367138* 1437141° Microparticle oxidation 1307131° 1327130° 1307132° 1367130° 1457130" Pearl pigment 133 7130° 1327133° 1397131° 1367137° 1447130° Amihope LL 107125° 137135° 107128° 1367133° 145713Γ Red 202 No. 13 57130° 1327133° 1407133. 136713Γ 1447136° [Table 1-4] ; good 1-4 : usability/adhesion test result compound (al) compound (bl) compound (cl) compound (dl) compound (el) sericin FSE 〇/◎ 〇 /◎ 〇/◎ Δ/Δ χ/χ Mica Y-2300 〇/◎ 〇/◎ 〇/◎ Δ/Δ χ/χ talc JA-46R 〇/x Δ/χ Titanium CR-50 〇/◎ 〇/ ◎ 〇/◎ Δ/χ χ/χ Yellow LL-100P 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/χ Red R-516PS 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/χ Black BL -100P 〇/◎ 〇/◎ 〇/◎ Δ/χ χ/χ Microparticle oxidized 鈥〇/◎ 〇/◎ 〇/◎ 〇/△ χ/χ Microparticle TiO 2/χ Δ/χ Microparticle oxidation 〇/〇 Δ/χ Microparticles Zinc Oxide 〇/◎ 〇/◎ 〇/◎ Δ/Δ χ/χ Pearl pigment Δ/Δ χ/χ Amihope LL Δ/Δ χ/χ 1_>Color 202猇〇/◎ 〇/◎ 〇/ ◎ Δ / Δ χ / χ 51 201032832 31637pifl [Table 1. 5] Table 1-5: Water repellency and hydrophilicity test results Compound (al) Compound (bl) Sericite FSE Mica Y-2300 Talc JA-46R Titanium CR -50 Yellow LL-100P Red R-516PS Black BL-100P Microparticle Oxygen Titanium dioxide fine particles of titanium oxide fine particles of zinc oxide pearl pigment AmihopeLL Red No. 20 255 Compound (Cl) The powders obtained in Examples 1-9 and 1-10 and Example M3 had hydrophilic oil repellency. The surface-treated powders obtained in the respective examples all had high feeling of use and adhesion. _ [Examples 1-15 to 1-32 and Comparative Examples U15 to 1_32] Next, a practical example of a cosmetic material to be blended with the surface-treated powder of the present invention will be described. Various cosmetics were produced by the following methods based on the respective compositions of the following tables. In addition, the cosmetic materials obtained in the respective examples and the comparative examples were prepared for each evaluation by the professional inspector for each evaluation, for the feeling of use, the makeup completion effect, and the makeup durability. The evaluation was performed according to the evaluation criteria shown in Table 18 below, and the total score of all the functional inspectors was divided by 20 to obtain a score. 52 201032832 JIGJ/pill Fluoropolymer treated titanium. The results are shown in Tables 2-4 and 2-5. [Table 2-4] Table 2*4: Results of Example 2-2 and Comparative Example 2-2 1% 2% 3% 4% 5% The compound (32) of the present invention (16) 16° / osmosis 61735. 1407133° 727141° Infiltration / 142. The compound (b2) 18 7 of the present invention penetrates 64. /37. 1437136° 647140° Infiltration / 143. The compound (c2) of the present invention 15? permeation 78738° 14Γ/13Γ 757137° permeation Λ42β The compound of the comparative example (d2) 20°/infiltration 19756. 1387135° 147 7140° 148 7142° Compound of Comparative Example (e2) 24 7 Permeation 80742° 137 7140° 148°/142β 143 7143° As shown in Table 2-4, the treated powder of the fluorinated copolymer of the comparative example was used. The water repellency of the body is increased in proportion to the amount of the treatment, but the powder coated with the fluorinated copolymer of the present invention has a low water repellency and oil repellency when the treatment amount is 2% or less. Shows the highest water and oil repellency. It exhibits hydrophilic oil repellency when the treatment amount is 5%. Even if the treatment amount is increased to 5% or more, the oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-5 below. [Table 2-5] Table 2-5: Results of Example 2-2 and Comparative Example 2-2 - Water repellency and affinity test results of titanium treated with each fluorocopolymer 1% 2% 3% 4% 5% ' | Compound (a2) of the present invention 1 2 4 2 1 ... Compound (b2) of the present invention 1 3 5 3 1 Compound (c2) of the present invention 1 2 4 2 1 .. Compound (d2) of Comparative Example 1 3 5 5 5 Compound of Comparative Example (e2) 1 3 5 5 5 - (Example 2-3 (FAW-treated yellow iron oxide) and Comparative Example 2_3) Human b was copolymerized with each fluorine shown in Table 2-1 The surface treatment amount of the object is in the form of 2 g (external cut 2 wt%) to 6 g (external cut 6 wt%) in increments of 1 g per _ person's way to 100 g of yellow iron oxide ( Yellow LL-l〇〇p: Sakamotochin Industrial Co., Ltd.). Each of the compounds containing the compound was diluted in water at 5 hours and added. After mixing for 15 minutes using a Henschel mixer, 85 201032832 31637 pifl was dried at 110 ° C for 10 hours, and then pulverized by an ultrafine pulverizer to obtain yellow iron oxide treated with each fluorocopolymer. The results are shown in Table 2-6 and Table 2-7. [Table 2-6] Table 2-6: Results of Examples 2-3 and Comparative Example 2-3 Contact angle test of yellow iron oxide and water/shrimp by each fluorocopolymer treatment 2% 3% 4% 5 % 6% The compound (a2) 16 7 of the present invention penetrates 61735. 1327116. 61V141. Permeation / 142 ^ The compound of the present invention (b2) 18 7 permeates 64737. 1317124° 557140° Permeation / 143° Compound (C2) 17 of the present invention. /Infiltration 85742° 1307126° 687138° Infiltration / 143. Comparative Example Compound (d2) 20 V Penetration 89756° 1397135° 1487140° 1447142° Comparative Example Compound (e2) 247 Permeation 80742° 1387128° 1477142. 1457143° As shown in Table 2-6, the treated powder of the fluorinated copolymer of the comparative example has a water-repellent property which is increased in proportion to the amount of treatment, and the powder coated with the fluorinated copolymer of the present invention is treated. When the amount is less than or equal to 3%, the water repellency and oil repellency are low, and when the treatment amount is 4%, the highest water repellency and oil repellency are exhibited. It exhibits hydrophilic oil repellency when the treatment amount is 6%. Even if the treatment amount is increased to 6% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-7 below. [Table 2-7] Table 2-7: Results of Example 2-3 and Comparative Example 2-3 Water-repellent and hydrophilicity test results of yellow gas oxide treated with each gas-containing copolymer 2% 3% 4% 5% 6 % The compound (a2) of the present invention 1 2 4 2 1 The compound (b2) of the present invention 1 2 5 3 1 The compound (c2) of the present invention 1 2 4 2 1 The compound of the comparative example (d2) 1 3 5 5 .5 Comparative Example Compound (e2) Bu 1 3 5 5 5 (Example 2-4 (FAW treated red iron oxide) and Comparative Example 2-4) Surface treatment of each fluorinated copolymer shown in Table 2-1 The amount is between 2 g (external cut 2 wt%) and 6 g (external cut 6 wt%) in the form of solid content by 1 g each time '100 g of red iron oxide (red R-516PS: 201032832 ^ IW/pill Japan Titanium Industries Co., Ltd.). The treatment with the same method as in Example 2-3 was carried out to obtain red iron oxide treated with each of the fluorinated copolymers. The results are shown in Table 2-8 and Table 2-9. [Table 2-8] Table 2-8: Results of Example 24 and Comparative Example 2-4 Each of the fluorinated copolymers treated red iron oxide and water/horny alkane ^Electrical tentacles test 2% 3% 4% 5% A 〇 / n The compound of the invention (a2) 18 ° / infiltration 66935 ° 1407133 * 727141 ° permeation / 142. The compound of the present invention (b2) 14° / infiltration 75 738 ° 141713 Γ 757137 ° lacquer it7142. The compound (c2) 25 of the present invention. /Infiltration 76 742° 1417130° 747138° HKD / 143° Comparative compound (d2) 26 7^ Transverse 80756° 1387135° 1437140° 1457142. Comparative Example Compound (e2) 28° / permeation 82742° 137V140. 1387142° 1437143° As shown in Table 2-8, the treated powder of the fluorinated copolymer of the comparative example was improved in water-repellent property in proportion to the amount of treatment, and the powder coated with the fluoropolymer of the present invention was used. When the treatment amount is less than or equal to 3%, the water repellency and oil repellency are low, and when the treatment amount is 4%, the highest water repellency and oil repellency are exhibited. It exhibits hydrophilic oil repellency when the treatment amount is 6%. Even if the treatment amount is increased to 6% or more, the oil repellency does not change from the hydrophilicity. The same results were also seen in the results shown in Table 2-9 below. [Table 2-9] Table 2-9: (Results of Examples 2-4 and Comparative Example 2 > 4) The results of the fluorocopolymer treatment, water-staining and hydrophilicity test of red iron oxide 2% 3% 4% 5% 6% of the compound of the present invention (a2) 1 3 4 2 1 The compound of the present invention (b2) 1 3 4 3 1 The compound of the present invention (c2) 1 2 4 2 1 The compound of the comparative example (d2) 1 3 5 5 5 Compound of Comparative Example (e2) 1 3 5 5 5 (Example 2-5 (FAW treated black iron oxide) and Comparative Example 2_5) Surface treatment amount of each fluorinated copolymer shown in Table 2-1 For the case of solid content of 1 g (external cut 1 wt%) to 5 g (external cut 5 wt%), each increment of 1 g, l〇〇g of black iron oxide (black BL-100P: 87 201032832 31637pitl Japan Industrial Co., Ltd.) for processing. The treatment with the same procedure as in Example 2-3 was carried out to obtain a black iron oxide treated with each of the fluorine-containing copolymers. The results are shown in Table 2-10 and Table 2-11. [Table 2-10] Table 2-10: Results of Example 2-5 and Comparative Example 2-5 Contact angle test of each fluorocopolymer treated black iron oxide squalane - 1% - 2% 3% 4% 5% The compound (a2) 35 7 of the present invention permeates 1347128° 687133° 12V141. Permeation / 142. Compound (b2) of the present invention 40°/infiltration 1367125° 70β/136β 137140° Permeation/143° The compound (C2) of the present invention 45 7 is permeable to 1387130° 64 7138. 157137. Penetration / 142. Comparative Example Compound (d2) 68. /Cut through 1407134° 1467145° 1457140° 1457142° The compound of the comparative example (e2) 577 penetrated 1427133° 1447140° 1467142. 143 7143° As shown in Table 2-10, the treated powder of the fluorinated copolymer of the comparative example has a water-repellent property which is increased in proportion to the amount of treatment, and the powder coated by the fluorinated copolymer of the present invention is less than the treatment amount. When it is equal to 1%, the water repellency and oil repellency are low. When the treatment volume is 2%, it shows the highest water repellency. It exhibits hydrophilic oil repellency when the treatment weight is 4% and 5%. Even if the treatment amount is increased to 5% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-丨1 below. [Table 2-11] Table 2-11: Results of Examples 2-5 and Comparative Examples 2-5 The total fluorinated copolymer, the water repellency and hydrophilicity test results of black iron oxide 1% 2% 3% 4 % 5% The compound (a2) of the present invention 1 3 5 2 1 The compound of the present invention (b2) 2 3 5 2 1 The compound of the present invention (c2) 1 3 5 2 1 The compound of the comparative example (d2) 2 3 5 5 5 Comparative Example Compound (e2) 2 3 5 5 5 (Example 2-6 (FAW-treated fine particle titanium oxide) and Comparative Example 2-6) 100 g of fine particle titanium oxide (MT_500SA: Tayca Co., Ltd.) was put into 1500 ml of deionized water (containing 5 g of sodium hexametaphosphate) Further, each of the fluorinated copolymers having a solid content of 6 g exhibited a hydrophilic oil repellency at a treatment amount of 9% at 88 201032832 jioj/pifl of 5 1111. Even if the treatment amount is increased to 9% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-15 below. [Table 2-15] ♦ 1 u Table 2-15: Results of Examples 2-7 and Comparative Example 2·7 Digitation, the water repellency of the zinc oxide and the limb (4) road should be 5% 6% 7% 8% 9% The compound (a2) of the present invention 3 5 3 2 1 The compound (b2) of the present invention 3 3 5 5 2 1 The compound of the present invention (c2) 3 5 3 2 1 The compound of the comparative example (d2) 4 5 5 5 5 Compound of Comparative Example (e2) 4 5 5 5 5 (Example 2-8 (FAW treatment/NAI treated pearl) and Comparative Example 2-8) loo g pearl pigment (Flamenco Gold: Engelhardt) was added to 1000 ml of deionized water, and 1 〇g of N was added. - Dissolve and disperse by disodium succinate-sodium glutamate (Amy 〇 之 HS-21P). Further, 丨g to 5 g of each of the agricultural-containing copolymers shown in Table 2-1 was added, and the mixture was heated to 80 ° C and kneaded by a kneader for 30 minutes. Further, a 0.5 mol/L aqueous solution of A12(S04)3 was added to adjust the pH of the kneaded material to 5.0. At 140. (: drying was carried out for 8 hours to obtain a composite treated pearl pigment of each fluorinated copolymer and thiolated amino acid. The results are shown in Table 2-16 and Table 2-17. [Table 2-16] Table 2 16: Results of Examples 2-8 and Comparative Examples 2·8 Treatment of each fluorinated copolymer: Contact angle test of loose pearls and water/charged 1% 2% 3% 4% 5% The compound of the present invention (a2 50715° 1447136° 987133° 517137° Permeation/142. Compound (b2) 46710 of the present invention. 1467132° 907136° 457141° Permeation/143. Compound of the invention (c2) 40716. 1487133. 1027138° 527140. Permeation/142 Comparative Example Compound (d2) 88730°. 1487145° 1497146° 145*143° 1457142° kComparative compound (e2) 97738. 1487142° 146714Γ 146./142〇1437143° 91 201032832 31637pitl As shown in Table 2-16 It is shown that the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example is increased in proportion to the amount of the treatment, and the powder coated with the fluorinated copolymer of the present invention is water-repellent when the amount of the treatment is 1% or less. It has low oil repellency and exhibits the highest water and oil repellency when the treatment capacity is 2%. When the treatment amount is 5%, it exhibits hydrophilic oil repellency. Even if the treatment amount is increased to 5% or more, oil repellency and hydrophilicity are not changed. The same results are also seen in the results shown in Table 2-17 below. [Table 2-17] Table 2-17: Results of Example 2·8 and Comparative Example 2-8 Each fluorocopolymer treatment, pearl, water and hydrophilicity test results 1% 2% 3% 4% 5% The compound of the present invention (a2) 2 5 3 2 1 The compound of the present invention (b2) 2 5 3 2 1 The compound of the present invention (c2) 2 5 3 2 1 The compound of the comparative example (d2) 3 5 5 5 5 Comparative Example Compound (e2) 3 5 5 5 5 (Example 2-9 (FAW Treatment Laurel Brewing Amino Acid) and Comparative Example 2-9) To 100 g of Amihope LL (Lauryl Esteric Acid: Japan In Ajinomoto, add IPA/aqueous solution adjusted to pH_8 〇 with NaOH = 15 g/l 〇g mixture and add 1 g to 5 g of fluorene copolymer shown in Table 2-1. The surface treatment was carried out in the same manner as in the methods of Example 2 and 8 and Comparative Example 2-8 to obtain each of the fluorine-containing compound-treated Amihope LL. The results are shown in Table 2-18 and Table 2-19. 92 201032832 310J/pul [Table 2-18] Table 2-18: Results of Examples 2-9 and Comparative Example 2-9: The roll contact angle test of each fluorocopolymer treated lauric acid-free acid and water/squalane 1% Γ 2% 3% 4% 5% The compound of the present invention (32) 75725° "144 7135 ° 987133 · 5 Γ / 14 渗透 permeation / 142. The compound of the present invention (b2) 85736 ° 1487136 · 1027138 ° 627137 ° permeation / 142. Compound (c2) of the present invention 77. / 27. 1457137 · 877137 ° 547138 ° Permeation / 143. Compound (d2) of Comparative Example 88 / 3 〇 1407140 ° 1467145 ° 1457140. 14571426 Compound of Comparative Example (e2 97738° 1427142° 144 7140° 1467142° 1437143° As shown in Table 2-18, the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example is increased in proportion to the amount of treatment, and is contained in the present invention. When the amount of the powder coated with the fluorocopolymer is less than or equal to 1%, the water repellency and oil repellency are low, and when the treatment amount is 2%, the highest water repellency and oil repellency are exhibited. When the treatment amount is 5%, the hydrophilicity is exhibited. Oily. Even if the treatment volume is increased to 5% or more, the oil repellency and hydrophilicity are not The same results were also observed in the results shown in Table 2-19 below. [Table 2-19] Table 2-19: Results of Examples 2-9 and Comparative Examples 2-9 Treatment of laurel-based amine guns; 期 枓铋 枓铋 1 1 2% 3% 4% 5% Compound H 32) 4 5 3 2 1 Compound of the invention (b2 4 5 3 2 1 Compound (c2) of the present invention 4 5 3 2 1 Compound of Comparative Example (d2) 4 5 5 5 5 Compound of Comparative Example (e2) 4 5 5 5 5 (Example 2-10 (FAW) Treatment of Red No. 202) and Comparative Example 2-10) Add 1〇〇g of Red No. 202 (癸巳化成公司) to a mixed solution of IpA/deionized water = 40 g/100 g, and stir using a propeller mixer. Dispersion was carried out using an ultrasonic homogenizer (Saka Hegner Co., Ltd.). 5 g to 9 g of each fluorinated copolymer shown in Table 2-1 and 5 g of IPA were added, aged, and then distilled by vacuum heating. The solvent was removed and dried at 105 ° C for 16 hours to obtain each fluorine-containing copolymer 93 201032832 JlOJ/pili treated red No. 202. The results are shown in Table 2-20 and Table 2-21. [Table 2-20] Table 2-20: Results of Examples 2-10 and Comparative Examples 2-10 5% 6% 7% 8% 9% - Compound (a2) 75 725β 1447135 of the present invention. 987133° 517141° Infiltration / 142. - Compound (b2) 85 736 ° 1487136 of the invention. 1027138° 627137° Infiltration / 142. The compound (c2) of the present invention IT/21° 1457137. 877ΐ37β 547138° Infiltration/143. A comparative example of the compound (d2) 88730° 1407140° 1467145° 1457140° 1457142. Comparative Example Compound (e2) 97 738. ^ 1427142° 144 7140° 1467142° 143 7143° As shown in Table 2-20, the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example was increased in proportion to the amount of treatment, and the powder coated by the fluorinated copolymer of the present invention was less than the treatment amount. When it is equal to 5%, the water repellency and oil repellency are low. When the treatment volume is 6%, it shows the highest water repellency. It exhibits hydrophilic oil repellency when the treatment amount is 9%. Even if the treatment amount is increased to 9% or more, oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-21 below. [Table 2-21] Table 2-21: Results of Examples 2-10 and Comparative Examples 2-10 Water repellency and hydrophilicity test results of each fluorocopolymer treated red No. 202 5% 6% 7% 8% 9 % The compound of the present invention (32) 3 5 4 3 1 _ The compound of the present invention (b2) 3 5 4 3 1 _ The compound of the present invention (c2) 3 5 4 3 1 The compound of the comparative example (d2) 4 5 5 5 5 _ Compound of Comparative Example (e2) 4 5 5 5 5 (Examples 2-11 (FAW treatment/ALS treatment of a mixture of methyl polyoxyalkylene/ethylene dioxime polyoxane and titanium oxide) and Comparative Example 2-11) 100 g of dioxonium polyoxynitride /Vinyl dimethylpolyoxane and titanium oxide mixture (Dow Coming, EP-9261 TI Cosmetic Powder) was charged into a high-speed mixer and added to Table 2-1 which will be 1 g to 5 g in terms of solid content. Each of the fluorinated copolymers shown was dissolved in 10 g of IPA with 1 g of triethoxyoctyl 94 94328328 : u〇j/pifl decane (Dow Coming: Z-6341) (ALS treatment) The solution in propanol) was stirred for 5 minutes. While maintaining agitation, decompress the inside of the tank, raise the temperature to 50 ° C and stir for 15 minutes. The obtained powder is subjected to ultrafine pulverization to obtain a composite powder of each of the fluoropolymer treatment and the calcination-based calcination treatment, and a mixture of bismuth oxide and bismuth dimethylpolysiloxane and titanium oxide body. The results are shown in Table 2-22 and Table 2-23. [Table 2-22] Table 2-22: Results of Examples 2-11 and Comparative Examples 2-11 Each of the fluorocopolymers was treated with a mixture of methacrylate/vinyl dimethylpolysiloxane and titanium oxide. Contact angle test of water/squalane 1% 2% 3% 4% 5% 'Ί Compound (32) 45 of the present invention. / Penetration 94 / 65 ° 1457133 ° 517141 ° Permeation / 140 · The compound (b2) of the present invention 417 penetrates 98. /66° 1487138° 62. /137° Permeation/ΪΪΓ~~~ The compound (c2) of the present invention is 42°/permeate 85. /57. 1457137° 54°/138° Infiltration / 138. Comparative Example Compound (d2) 58. /Infiltration 90. /70. 1467145° 144°/140. 1427142 "-Comparative Example Compound (e2) 67. / infiltration - 102. /82° 1447140° 1467142° 143. As shown in Table 2-22, the powder of the fluorinated copolymer of the comparative example is improved in proportion to the amount of water treated by the fluorocopolymer of the comparative example, but the powder coated with the fluorinated copolymer of the present invention When the treatment amount is less than or equal to 2%, the water repellency and the oil repellency are low. When the treatment amount is 3%, the highest water repellency and oil repellency are exhibited. It exhibits hydrophilic oil repellency when the treatment amount is 5%. Even if the treatment amount is increased to 5% or more, the oil repellency and hydrophilicity are no longer changed. The same results were also seen in the results shown in Table 2-23 below. 95 201032832 31637pitl [Table 2-23] Table 2-23 Results of Example 2-ll and Comparative Example 2-11 Each ±^ Record (4) Silk II Compound of the present invention (a2) Compound (b2) of the present invention 3 4% 2 5% Compound (c2) of the present invention Compound (d2) of Comparative Example Compound (e2) of Comparative Example (Example 2-12 (FAW treatment/C6F treatment of fine particle zinc oxide) and Comparative Example 2 12) To 100 g of microparticulate zinc oxide MZ-300 (Tayca), add fluorocopolymers as shown in Table 2-1 with a solid content of 3 g to 6 g, and 5 g of tridecafluorooctyltriethyl Oxygen; Escherichia (Dynasylan F-8261: Evonik Degussa) (C6F decane treatment), and 60 g of water/ipa = l/i solution 'mixed with a kneader for 60 minutes, and at 13 Torr. (: drying for 16 hours. Then, ultrafine pulverization was carried out to obtain a composite treated fine particle zinc oxide of each fluorinated copolymer and C6F decane. The results are shown in Table 2-24 and Table 2-25. [Table 2-24] Table 2-24: Results of Examples 2-12 and Comparative Examples 2-12 Each fluorocopolymer treated microparticle zinc oxide and water/squalane contact angle test 3% 4% 5% 6% 7% of the present invention Compound (32) 1497144° 1087145° 897145° 417150° Permeation/141. Compound (b2) 150 7146° 1027143° 787147° 327148 of the present invention. Infiltration it 7143° Compound (C2) of the present invention 1587147° 1107142° 807140° 34 7140 ° Permeation / 140. Compound (d2) of Comparative Example 1547149. 1547146° h1467l45° 1447140. 1427ΐ42β Compound of Comparative Example (e2) 1567146. 1577145° 1447145* 1467142° 143 7143. As shown in Table 2-24 When the treated powder of the fluorinated copolymer is increased in handling amount, the water repellency does not change, and the powder coated with the fluorinated copolymer of the present invention is used when the amount of the fluorinated copolymer is 3% or less. High water and oil repellency. Treatment with C6F decane When the treatment amount of 5% and the fluorinated copolymer is 3%, the highest water repellency is exhibited. When the treatment amount of the fluorinated copolymer containing 96 201032832 /pill is 7%, the hydrophilic oil repellency is exhibited. Increased to 7% or more, oil repellency and hydrophilicity are no longer changed. The same results are also seen in the results shown in Table 2-25 below. [Table 2-25] ° Table 2-25: Examples Results of 2-12 and Comparative Examples 2-12 Each of the fluorinated copolymers treated with granules oxidized f, and the hydrophilicity test 3% 5 4% 4 5% 3 - Ma Ming: Capsule 6% 2 7 % 1 The compound of the present invention (a2) The compound of the present invention (b2) 5 4 3 2 1 The compound of the present invention (c2) 5 4 3 2 1 The compound of the comparative example (d2) 5 5 5 5 5 The compound of the comparative example ( E2) 5 5 Γ 5 5 5 (Example 2-13 (FAW treated sericite) and Comparative Example 2_13) The powder and method shown in Example 2-1 except that IPA and water were used with Na〇H The mixed solution (5 〇 wt%: 50 wt%) was adjusted to a pH of 50 g, and treated in the same manner to obtain a fluorinated copolymer-treated sericite. The results are shown in Table 2-26 and Table 2-27. . [Table 2-26] Table 2-26: Results of Examples 2-13 and Comparative Examples 2-13 Contact angle test of each gas-containing copolymer treated sericite/squalane 1% 2% 3% 4% 5% of the compound (a2) 26 of the present invention. /Infiltration 30745° Infiltration / 140. Infiltration / 140. Penetration / 145. Compound (b2) 28 of the present invention. /Infiltration 38. /42° Infiltration / 141. Infiltration / 139. _ infiltration / 142. The compound (c2) of the present invention has a penetration of 35,740° permeation/140. Infiltration / 139. Permeation / 140 ° Comparative Example Compound (d2) 28 7 Penetration 53 V525 1017143 ° 1387145 ° 1457143 ° Comparative Example Compound (e2) 25 7 Permeate 43. /59. 1057145° 143V142. 140°/142. As shown in Table 2-26, the water-repellent property of the treated powder of the fluorinated copolymer of the comparative example was increased in proportion to the amount of treatment. The powder coated by the gas-containing copolymer of the present invention was less than the treatment amount. When the amount is equal to 2%, the water repellency and oil repellency are low. When the treatment amount is 3% or more, it exhibits high hydrophilic oil repellency. Even if the treatment amount is increased to 5% or more, oil repellency and hydrophilicity are not changed. The same results were also seen in the results shown in Table 2-27 below. 97 201032832 · 31637pifl [Table 2-27] Table 2-27: Results of Examples 2-13 and Comparative Examples 2-13 The results of water repellency and hydrophilicity test of each fluorocopolymer treated sericite 1% 2% 3% 4% ^ - 5% 1 The compound of the present invention (32) 2 2 1 1 The compound of the present invention (b2) 2 2 1 1 1 The compound of the present invention (C2) 2 2 1 1 1 The compound of the comparative example (d2) 2 3 4 5 5 Compound of Comparative Example (e2) 2 3 4 5 5 (Example 2-14 (FAW-treated talc powder) and Comparative Example 2-14) 10 g of talc powder JA-13R (Asada Milling Co., Ltd.) ) The mixture was poured into 5 〇 0 g of water prepared in a 2 L glass beaker, and sufficiently stirred and dispersed. The solution of each of the fluorinated copolymers shown in Table 2-1 and 10 g of IPA in a solid content of lg to 5 g was slowly added, followed by stirring for 15 minutes. The slurry thus obtained was supplied to a spray dryer equipped with a two-fluid spray nozzle. The inlet hot air temperature of the spray dryer was set to 200. (: The spray pressure of the two-fluid nozzle was set to 0.6 MPa. Thus, each fluorocopolymer-treated talc powder was obtained. The results are shown in Table 2-28 and Table 2-29. [Table 2-23⁄4 Table 2 ·28: Results of Examples 2-14 and Comparative Examples 2-14 Each fluorine-containing total contact angle test of talc-treated talc powder and water/squalane 1% 2% 3% 4% 5% The compound of the present invention (a2) 29°/permeation 48765° 55795° 617100° permeation/10Γ The compound of the invention (b2) 307 permeates 42763° 67787. 72β/108β permeation/103° The compound of the invention (C2) 38·/infiltration 40V62" 58786 ° 647100° osmosis / 103° Compound of the comparative example (d2) 44 7 osmosis 94 776 · 143. / 97. 1447110 ° 142 7112 Φ Compound of the comparative example (e2) 56 V penetration 97 ° / 75 ° 144795 ° 1467112. 143 7113 ° As shown in Table 2-28, the treated powder of the fluorinated copolymer of the comparative example has a water repellency which is increased in proportion to the amount of the treatment, but the powder coated by the fluorinated copolymer of the present invention is treated in a dose amount. When the ratio is less than or equal to 2%, the water repellency and the oil repellency are low. When the treatment amount is 3%, the highest water repellency and oil repellency are exhibited. When the ration is 5%, it shows hydrophilic oil repellency. Even if the treatment volume is increased 98 201032832 jioj /pirl [Table 2-83] —_ Table 2-83 Field*1 Buying Day Compound (a2) Compound (b2) Compound ( C2) Compound Cd2) I compound (eW 1 〇〇〇 The powder is not uniformly dispersed by the deception treatment, and the emulsion can be formed. The uniformity of the effect is completed [o'- Γ〇 ◎ makeup persistence <8) _ — _ _ ◎ L Zhuang workability] The surface-treated powder of the present invention is preferably used as a powder for cosmetic materials, but it can be used not only for (4) but also for ^, Mineral powder, resin masterbatch, paper, etc., powder filler, ceramics, materials, rare earths, optical materials, conductive materials, voltage - the hairline, the scales are used to define the spirit and scope of the present invention, When you can make a few 2, do not leave, the scope of protection of the Ming Dynasty is attached to the patent application scope;:: is: This [simplified description of the schema] W sector is Zhuowu [main component symbol description] No 129 201032832 /pul No Chinese version of 98119229 without line correction page Invention patent specification (Do not change the format and order of this manual, please do not fill in the ※ part) ※Application number: ※Application曰: ^PC classification: 1. Name of the invention: (Chinese/English) Surface treatment powder and Cosmetics SURFACE-TREATED POWDER AND COSMETIC INCORPORATED WITH THE SAME II. SUMMARY OF THE INVENTION The present invention provides a surface-treated powder excellent in usability and adhesion to skin, which is composed of (a) A surface treatment agent of a fluorine-containing monomer of the formula (I) and (b) a fluorine-containing copolymer of the alkoxy group-containing monomer of the formula (II) is coated. This powder is used in various cosmetics. CH2=C(-X)-C(=0)-Y-[-(CH2)mZ-]p-(CH2)n-Rf (I) [Chemical 2] CH2=C(X1)- C(=0)-0-(R〇)q-X2 (Π) 201032832 31637pifl III, English invention summary: This invention provides a surfacetreating powder having excellent utility and adhesion property to skin. The powder is coated by a surface treating agent In a fluorine-containing copolymer of (a) a fluorine-containing monomer represented by formula (I) and (b) a monomer containing alkoxy group represented by formula (II). The powder is used in various cosmetics. [Formula 1] CH2 =C(-X)-C(=0)-Y-[-(CH2)mZ-]p-(CH2)n-Rf (I) [Formula 2] CH2=C(XI)-C(=0) -0-(R0)q-X2 (II) 201032832 · 31637pitl Revision date: 98 years to month 1^臼 is the number of Chinese patents No. 98119229 No underline correction. 7. Patent application scope: Table ====== , 疋 will necessarily contain (a) a fluorine-containing copolymer obtained by copolymerizing a gas-containing monomer represented by the following formula (1) and a pure monomer-containing monomer represented by the following formula (II). : [Chemical 1] (I) [wherein, X is a hydrogen atom, a methyl group, a gas atom, a chlorine atom, a desert atom, an argon atom, a CFX1X2 group (wherein, a phantom and a hydrogen atom, an oxygen atom or a gas atom), a cyano group, and a carbon number are 丨Addition of a linear or branched fluoroalkyl group, a substituted or unsubstituted unit group, a substituted or unsubstituted stupid group; Y is -0- or -NH-; Z is a direct bond, _S_ or _S〇2_ ; Rf is a fluoroalkyl group having a carbon number of 1 to 6, m is 1 to 1 Å, η is 〇~1〇, p is 〇 or 1] [Chemical 2] ^ CH2=C(X1)-C(=〇)-〇-(R〇)q-x2 (II) [wherein X1 is a hydrogen atom or a fluorenyl group; χ2 is a hydrogen atom or a carbon number of 1 to 22 a saturated or saturated hydrocarbon group; R is a part or all of a hydrogen atom which may be substituted by a hydroxyl group and has a carbon number of 2 to 4; q is an integer of 1 to 50]. 2. The surface-treated powder according to claim 1, wherein in the above formula (II), X2 is a hydrogen atom. 3. The surface-treated powder according to claim 1 or 2, wherein the surface-treated powder has water repellency. 4. The surface treatment powder according to claim 1 or 2, wherein the surface-treated powder has hydrophilic oil repellency. 5. The surface-treated powder according to the first or second aspect of the invention, wherein the fluorinated copolymer comprises a crosslinkable monomer represented by the following formula (dish) Coating of fluorinated copolymer: [Chemical 3] CH2=C(X3)-C(=0)-0-(R1〇)qC(=〇).C(X3)=CH2 (HI) [In the formula, each X3 is a hydrogen atom or a methyl group; Ri is a part of a nitrogen atom Part or all of the carbon that can be replaced by the secret is 2~1G; q is! An integer of ~50]. 6. The surface-treated powder of claim 2 or 2 wherein the fluorocopolymer has a weight average molecular weight of from about 〇1 to about 1,000,000. 7. If you apply for a patent range! The surface-treated powder according to Item 2, wherein the fluorine-containing copolymer (4) is a temple weight part, and the alkoxy group-containing monomer (1) is 1 part by weight to 働 parts by weight. The surface-treated powder described in the first or second aspect of the invention, wherein the coating amount of the fluorinated copolymer is _parts by weight to 4 parts by weight based on 100 parts by weight of the powder to be surface-treated. . The surface-treated powder treatment agent according to Item 1 or 2, further comprising one or more compounds selected from the group consisting of the following compounds, and other groups other than the above-mentioned fluorine-containing copolymer Fluoric acid vinegar, polyene furnace stone shochu, polymymy modified Wei, organic titanium diterpene lecithin (containing salt form of deuterated lecithin), 131 201032832 31637pifl Atractive amino acid (including salt form Or a thiolated amino acid in the form of a composition, an acidic ester oil, a fatty acid (a fatty acid containing a salt form), and a dextrin fatty acid ester. 10. The surface-treated powder according to claim 9, wherein the fluorine-containing compound is a perfluoroalkyl phosphate having a carbon number of 6 or less, a perfluoroalkyl decane, a perfluoropolyether phosphate, and the whole The species in the fluoropolyether decane. 11. The above-mentioned surface treatment powder according to claim 1 or 2, wherein the crucible is 1 part by weight to 19.99 parts by weight, based on 1 part by weight of the powder to be surface-treated. The fluorinated copolymer and the compound of one or more selected from the group of the above-mentioned compound are coated in a weight of 9 parts by weight to a part by weight. body The invention relates to a surface-treated powder according to item 12 of the patentable scope, The powder of the makeup material is an inorganic powder that can be used for cosmetics. 14. The inorganic powder according to the thirteenth application patent is a difficult mother: a powder of the powder 'any of its fossils, barium sulfate, nitrogen (tetra), oxygen;:, =, f stone powder, dioxoenaline or Two; 3. Zinc Oxide, Iron Oxide, and Jane 15. The powder which can be used for the above-mentioned cosmetic material is the d-side treatment powder, which is a cosmetic material, which is characterized by, for example, a patent application: if The surface-treated powder of any one of the items of any of the above-mentioned items of the present invention. 17. The cosmetic according to claim 16, which further comprises at least one of an oily component, an aqueous component, and a surfactant as a constituent component. 18. The cosmetic according to claim 16 or 17, which is any of a skin care cosmetic, a hair cosmetic, a cosmetic cosmetic, and an anti-UV cosmetic. 19. The cosmetic material according to item 16 or item π of the patent application, wherein the product form is liquid, emulsion, cream, solid shape, paste, gel, powder, multi-layer, Any form of mousse and spray. 133