TW201028089A - Method for preventing odor-spread of creeping pest repelling compound - Google Patents

Method for preventing odor-spread of creeping pest repelling compound Download PDF

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TW201028089A
TW201028089A TW98120456A TW98120456A TW201028089A TW 201028089 A TW201028089 A TW 201028089A TW 98120456 A TW98120456 A TW 98120456A TW 98120456 A TW98120456 A TW 98120456A TW 201028089 A TW201028089 A TW 201028089A
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Taiwan
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pest
diol
escaping
pests
odor
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TW98120456A
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Chinese (zh)
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TWI444138B (en
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Tomoyuki Hikitsuchi
Yukiko Miki
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Dainippon Jochugiku Kk
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Priority claimed from JP2009099452A external-priority patent/JP5234650B2/en
Priority claimed from JP2009113469A external-priority patent/JP5288199B2/en
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Publication of TW201028089A publication Critical patent/TW201028089A/en
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Abstract

The present invention provides a method for preventing odor-spread of creeping pest repelling compound, which is characterized in applying a creeping pest repelling agent containing a creeping pest repelling compound with properties of preventing odor-spread in places or surroundings where creeping pests move around or there are concerns of creeping pests move around, or near articles or surroundings thereof where creeping pests might approach or there are concerns of creeping pests approaching, when there are needs of preventing creeping pests from approaching or lingering in places where creeping pests move around or there are concerns of creeping pests move around, or near articles which creeping pests might approach or there are concerns of creeping pests approaching.

Description

201028089 六、發明說明 【發明所屬之技術領域】 本發明係關於抑制走爬性害蟲徘徊或靠近，防止趨避 走爬性害蟲成分之臭味轉移的方法，詳細而言，係關於將 含有難以轉移臭味的趨避走爬性害蟲成分之趨避走爬性害 蟲用劑，適用於走爬性害蟲會徘徊或有徘徊之虞的場所或 其附近、或走爬性害蟲會靠近或有靠近之虞的物品或其附 _ 近的方法。 另外，本發明亦關於米缸用防蟲劑。 【先前技術】 傳統上，作爲蚊、蚋、搖蚊等之飛翔性害蟲之趨避 劑，已知許多選自以 N，N-二乙基間苯胺（N，N-Diethyl Meta ToluamideH後續亦記載爲DEET。）爲首，香茅醛、 葱品醇、薄荷醇、檸檬烯、香葉醇、香茅醇、樟腦烯 φ (camphene)等之組成物等（例如參考專利文獻1)。 另一方面，作爲趨避走爬性害蟲成分，揭示有檸檬 嫌、蔽品稀4醇（Terpinen-4_ol)、紫蘇醛、辛醒、茶樹 油、柚子油等（例如參考專利文獻2)，另外，揭示使用草 酸二乙酯、丙二酸二甲酯、琥珀酸二甲酯等之二羧酸酯之 趨避走爬性害蟲的方法（例如參考專利文獻3)。然而，此 等趨避成分的趨避效果並不一定充足，或具有安全性上的 問題，很難說實用性優異。 因此，盛行檢討自安全性優異之來自天然物之肉桂、 -5- 201028089 樟腦、檸檬草、酢漿草、百里香、天竺葵、佛手柑、月桂 樹、松、紅桃、銀薄荷、桉樹及印度楝樹等所萃取之精 油、萃取液等作爲趨避成分使用。 如上述之來自天然之趨避成分大多爲臭味（香味）強 者，即使此等絕非不愉快臭味，於走爬性害蟲會徘徊或有 徘徊之虞之廚房等處理許多食品·飲料等之場所使用時， 此等趨避成分之臭味直接轉移於食品·飲料等、或此等趨 避成分之臭味轉移於食器等，藉由該食器等間接轉移此等 趨避成分之臭味於食品·飲料等，因此損害此等食品·飲料 ¥ 等之風味、香味、味道等。 因此’除了安全性優異，趨避走爬性害蟲成分的臭 味’走爬性害蟲會徘徊或有徘徊之虞之例如廚房場所或走 爬性害蟲會靠近或有靠近之虞之例如食品·飲料等或食器 等之物品，關於抑制走爬性害蟲徘徊或靠近，存在對防止 趨避走爬性害蟲成分之臭味轉移的方法強烈要求。 另外，傳統以來，提出各種米缸用途或貯藏榖物類之 _ 主要害蟲之玉米象對策。例如特開平6-38678號公報所示 之已知以蒜素（allicin)、辣椒素（capsaicin)等爲成分之以 米之抗菌、防黴、防蟲爲目的之品質保存劑，特許第 3409176號公報中揭示含浸以紫蘇醛爲主要成分的藥劑之 液體含浸材料而成之米缸防蟲具，另一方面，特開平11_ 222409號公報中記載’含有作爲有效成分之來自天然物 之茶樹油及/或松油之玉米象趨避劑。 另外’最近，使用山葵、芥末、辣椒、蒜頭等之玉米 -6- 201028089 象趨避劑係市售米缸用多。此等係因爲使用的藥劑爲食 品，所以無須擔心藥害，但因趨避效果弱，爲確保效果， 必須大量使用。另外，因爲臭味強，不能避免轉移臭味於 米’而且亦有對人產生刺激之問題。 [專利文獻] [專利文獻1]特開2003_2〇12〇3號公報 [專利文獻2]特開平1 1-60421號公報 ❿ [專利文獻3]特開2007-230894號公報 [專利文獻4]特開平6-38678號公報 . [專利文獻5]特許第34091 76號公報 [專利文獻6]特開平1 1-222409號公報 【發明內容】 發明之揭示 發明所欲解決之課題 φ 本發明係以提供安全性優異，抑制走爬性害蟲徘徊或 靠近，防止趨避走爬性害蟲成分之臭味轉移的方法爲課 題。 另外，本發明亦提供對玉米象所代表之食品害蟲之趨 避效果及防蟲效果以及對人畜之安全性優異，容易使用之 實用性高之米缸用防蟲劑爲目的。 課題之解決手段 化合物之臭味係來自該揮發性，雖因化合物具有臭 201028089 味，具有某程度的揮發性者，但另一方面，並非揮發性愈 高該臭味變強，另外，揮發性若低時，並不表示該臭味幾 乎沒有。 另外，化合物的臭味是否容易轉移於其他物品不一定 與該化合物臭味的強度相關。 本發明等係就上述觀點，調查檢討關於對走爬性害蟲 具有趨避效果之化合物的臭味，依據安全性高，不接觸而 使揮發於空間，發現可抑制走爬性害蟲徘徊或靠近，而且 不易轉移臭味之特定化合物。‘ 亦即，害蟲的嗅覺與人類的嗅覺上有某種差異，但此 等化合物尤其對害蟲嗅覺的敏感度高，對人類嗅覺的敏感 度低係本發明之技術思想。 接著，將含有此等化合物作爲趨避走爬性害蟲成分之 走爬性害蟲趨避劑，若適用於走爬性害蟲會徘徊或有徘徊 之虞的場所或其附近、或走爬性害蟲會靠近或有靠近之虞 的物品或其附近，抑制走爬性害蟲徘徊或靠近時，發現可 防止趨避走爬性害蟲成分之臭味轉移，完成本發明。 另外，本發明者等係努力檢討可達成上述目的之米缸 用防蟲劑的結果，發現對孟烷-3,8-二醇係萜烯系化合物中 達成特別優異的趨避效果及防蟲效果，另外，發現因爲含 該化合物之米缸用防蟲劑對人畜的安全性高，臭味亦弱， 所以於本用途極爲有效。 亦即，本發明係採用以下組成者。 (1)於走爬性害蟲會徘徊的場所或有徘徊之虞的場 201028089 所、或走爬性害蟲會靠近的物品或有靠近之虞的物品’抑 制走爬性害蟲徘徊或靠近時’ 將含有難以轉移臭味的趨避走爬性害蟲成分之走爬性 害蟲趨避劑，適用於走爬性害蟲會徘徊或有徘徊之虞的場 所或其附近、或走爬性害蟲會靠近或有靠近之虞的物品或 其附近爲特徵之防止趨避走爬性害蟲成分之臭味轉移於所 適用之場所或物品的方法。 φ (2)於走爬性害蟲會徘徊的場所或有徘徊之虞的場 所、或走爬性害蟲會靠近的物品或有靠近之虞的物品，抑 ' 制走爬性害蟲徘徊或靠近時， ' 將含有難以轉移臭味的趨避走爬性害蟲成分之走爬性 害蟲趨避製品，設置於走爬性害蟲會徘徊或有徘徊之虞的 場所或其附近、或走爬性害蟲會靠近或有靠近之虞的物品 或其附近爲特徵之防止趨避走爬性害蟲成分之臭味轉移於 所設置之場所或物品的方法。 Ο (3)趨避走爬性害蟲製品係具備同時載持難以轉移臭 #的趨避走爬性害蟲成分及該溶解液或分散液於纖維質載 體者而成之前述（2)記載之防止趨避走爬性害蟲成分之臭 味轉移的方法。 (4)上述難以轉移臭味的趨避走爬性害蟲成分係對害 蟲嗅覺的敏感度高，對人類嗅覺的敏感度低之化合物之前 述（1)至（3)中任—項記載之防止趨避走爬性害蟲成分之臭 . 味轉移的方法。 (5M乍爲上述難以轉移臭味的趨避走爬性害蟲成分係 -9 - 201028089 使用對孟院-3,8-二醇、對孟院_1，8-二醇、3-(]^-乙醯基-1^-丁基）胺基丙酸乙酯、picaridin(l-哌陡殘酸2-(2-經乙基）-1-甲基丙酯）、2-乙基- l，3-己二醇、草酸二乙酯、丙二酸 二甲酯、丙二酸二乙酯、琥珀酸二甲酯、琥珀酸二乙酯、 琥珀酸二丙酯、琥珀酸二丁酯、戊二酸二甲酯、己二酸二 乙酯、己二酸二丙酯、己二酸二丁酯、癸二酸二乙酯、癸 二酸二丙酯、癸二酸二丁酯、苯二甲酸二甲酯、苯二甲酸 二丁酯、苯二甲酸二戊酯、馬來酸二丁酯、富馬酸二丁酯 參 或此等之混合物之前述（1)至（4)中任一項記載之方法。 (6) 作爲上述難以轉移臭味的趨避走爬性害蟲成分係 使用對孟烷-3,8-二醇、對孟院-i，8-二醇、3-(N-乙醯基-N-丁基）胺基丙酸乙醋、picaridin(l -峨陡殘酸2-(2 -羥乙基）_ 1-甲基丙酯）、2 -乙基-1,3 -己二醇或此等之混合物之前述 (5)記載之方法。 (7) 作爲上述難以轉移臭味的趨避走爬性害蟲成分係 使用對孟院-3,8-二醇、對孟院-i，8-二醇、3-(N-乙醯基-N- Q 丁基）胺基丙酸乙酯、picaridin(l-哌啶羧酸2-(2-羥乙基）-1-甲基丙酯）或此等之混合物之前述（6)記載之方法。 (8) 作爲上述難以轉移臭味的趨避走爬性害蟲成分係 使用對孟烷-3,8-二醇、對孟烷-〗，8_二醇或此等之混合物 之前述（7)記載之方法。 (9) 將含對孟烷-3，8-二醇爲難以轉移臭味的趨避走爬 性害蟲成分之趨避走爬性害蟲製品，設置於走爬性害蟲會 徘徊或有徘徊之虞的物品之米缸內爲特徵之前述（2)記載 -10- 201028089 之方法。 (10)上述對孟烷-3,8-二醇之使用量係相對於米缸容量 爲0.02〜1.0g/10L爲特徵之前述（9)記載之方法。 (1 1)前述（9)或（10)記載之方法所使用之趨避走爬性害 蟲製品。 (12) 同時含前述對孟烷-3,8-二醇及來自植物之除臭成 分爲特徵之前述（11)記載之趨避走爬性害蟲製品。 (13) 收納載持〇.1〜1〇〇111§/(；1112之前述對孟院-3,8-二 醇之纖維質載體於通氣性容器中而成，此通氣性容器係具 備固定於米缸的機構爲特徵之前述（11)或（12)記載之趨避 走爬性害蟲製品。 (14) 含有對孟烷-3,8-二醇爲防蟲成分，並設置於米缸 內爲特徵之米缸用防蟲劑。 (15) 同時含前述對孟烷-3,8-二醇及來自植物之除臭成 分爲特徵之前述（14)記載之米缸用防蟲劑。 (1 6)前述對孟烷-3，8 -二醇之含量係相對於米缸容量爲 0.02〜1.0g/10L爲特徵之前述（14)或（15)記載之米缸用防 蟲劑。 (17)收納載持0.1〜lOOmg/cm2之前述對孟烷-3,8-二 醇之纖維質載體於通氣性容器中而成’此通氣性容器係具 備固定於米缸的機構爲特徵之前述（14)至（16)中任一項記 載之米缸用防蟲劑。 發明之功效 -11 - 201028089 依據本發明’提供安全性優異，抑制趨避走爬性害蟲 之徘徊或靠近’防止趨避走爬性害蟲成分之臭味轉移的方 法。 藉此’趨避走爬性害蟲成分之臭味轉移成爲問題，抑 制走爬性害蟲徘徊或靠近食品·飲料等時，可防止趨避走 爬性害蟲成分之臭味轉移於該食品.飲料等。 另外，趨避走爬性害蟲成分之臭味轉移於食器等時， 使用此等附著臭味之食器前，爲消除臭味，必須進行洗淨 等’若使用本發明之防止臭味轉移的方法，可省略如此之 洗淨作業。 另外，不局限於廚房，亦可安心地使用至今因趨避成 分的臭味轉移而避免使用趨避劑之場所。 另外，因爲本發明之米缸用防蟲劑對玉米象所代表之 食品害蟲之趨避效果及防蟲效果及對人畜之安全性優異， 不轉移臭味於米，容易使用，所以該實用性極高。 用以實施發明之最佳型態 本發明之抑制走爬性害蟲徘徊或靠近，防止趨避走爬 性害蟲成分之臭味轉移的方法係將含有難以轉移臭味的趨 避走爬性害蟲成分之趨避走爬性害蟲用劑，適用於走爬性 害蟲會徘徊或有徘徊之虞的場所或其附近、或走爬性害蟲 會靠近或有靠近之虞的物品或其附近爲特徵。 可使用於本發明之難以轉移臭味的趨避走爬性害蟲成 分係對害蟲嗅覺的敏感度高，對人類嗅覺的敏感度低之化 -12- 201028089 合物，作爲如此化合物’可列舉對孟烷-3，8-二醇、對孟 烷-1，8 -二醇、3-(N-乙醯基-N-丁基）胺基丙酸乙酯、 picaridin(l-哌啶羧酸2-(2-羥乙基）-1-甲基丙酯）、2-乙基-1，3-己二醇、草酸二乙酯、丙二酸二甲酯、丙二酸二乙 酯、琥珀酸二甲酯、琥珀酸二乙酯、琥珀酸二丙酯、琥珀 酸二丁酯、戊二酸二甲酯、己二酸二乙酯、己二酸二丙 酯、己二酸二丁酯、癸二酸二乙酯、癸二酸二丙酯、癸二 φ 酸二丁酯、苯二甲酸二甲酯、苯二甲酸二丁酯、苯二甲酸 二戊酯、馬來酸二丁酯、富馬酸二丁酯或此等之混合物。 作爲適合難以轉移臭味的趨避走爬性害蟲成分係列舉 對孟烷-3,8-二醇、對孟烷-l，8-二醇、3-(N-乙醯基-N-丁基） 胺基丙酸乙酯、picaridin(l-哌啶羧酸2-(2-羥乙基）-卜甲 基丙酯）、2-乙基-1,3-己二醇或此等之混合物。 作爲較適合難以轉移臭味的趨避走爬性害蟲成分係列 舉對孟烷-3,8-二醇、對孟烷-1，8-二醇、3-(N-乙醯基-N-丁 ^ 基）胺基丙酸乙酯、picaridin(l-哌淀翔酸2-(2-徑乙基）-1-甲基丙酯）或此等之混合物。 作爲更適合難以轉移臭味的趨避走爬性害蟲成分係列 舉對孟烷-3,8-二醇、對孟烷-1，8-二醇或此等之混合物。 另外，以對孟烷-3,8-二醇尤佳。 上述化合物係任一種可爲合成品，亦可爲來自天然成 分。 另外，上述化合物中，對孟烷-3，8-二醇及對孟烷· 1，8-二醇雖存在基於立體結構之反式體及順式體，但於本 -13- 201028089 發明係可使用兩者異構物之任意比率之混合物。 對孟烷-3,8-二醇及/或對孟烷-1，8-二醇係檸檬桉精油 所含物質，已知作爲蚊子等之飛翔害蟲用趨避劑之趨避成 分，但關於對趨避走爬性害蟲效果，至今仍未有檢討報 告。 另一方面’關於對孟烷-1,8-二醇，雖稱對蚊子具有若 干趨避效果，但傳統上從未受到注目。 作爲可使用於本發明之走爬性害蟲趨避劑，雖亦可胃 以上述趨避走爬性害蟲成分組成，但通常加入各種成分， 調製成各種型態。 趨避走爬性害蟲成分之含量或對趨避劑整體量之比率 係依趨避劑之型態而改變。 例如使用如液劑之液狀時，設定成〇. 2〜2 0質量％程 度爲宜。若未滿0.2質量％時，趨避效果不足，另一方 面，超過20質量％時，出現發黏感等，並不實用。 另外，載持於載體使用之型態時，載持 〇.〇1〜 0 100mg/cm2的同時，調整該趨避走爬性害蟲成分之每24 小時的揮發量範圍於0.2〜200mg爲適當。 使用如液劑之液狀之走爬性害蟲趨避劑係除了難以轉 移臭味的趨避走爬性害蟲成分，另外，配合沸點中央値爲 1 60 °C以上之溶劑作爲效力增強劑爲宜。作爲如此溶劑， 可列舉甘醇、甘醇醚、脂肪族烴系溶劑等，以甘醇、甘醇 醚、燈油尤佳。 具體上，雖可舉例如丙二醇、1,3-丁二醇、；!，2_己二 -14- 201028089 醇、二乙二醇單丁醚、丙二醇單丁醚、二丙二醇單甲醚、 卜甲氧基-1,2-丙二醇等，但不局限於此等。 使用對孟烷-3，8-二醇及/或對孟烷-1，8-二醇作爲趨避 走爬性害蟲成分時，若配合甘醇或甘醇醚，雖認爲該趨避 效果之效力增強，但其與於除蟲菊（pyrethroid)系殺蟲成 分中配合甘醇或甘醇醚時，該殺蟲效果降低之已知現象成 對照結果。推測此乃因趨避走爬性害蟲成分時，該揮發性 φ 係以與殺蟲成分時不同型態，大大地參與趨避作用，組合 對孟烷-3,8-二醇及/或對孟烷-1,8-二醇，及沸點中央値爲 16(TC以上，尤其甘醇、甘醇醚系溶劑或燈油於趨避效果 表現上特別有效。另外，效力增強劑之配合量係趨避走爬 性害蟲成分的〇.5倍以上，以2.0〜50倍量爲適當。 另外，可使用於本發明之走爬性害蟲趨避劑中，可加 入如綠茶萃取物或柿萃取物之來自植物的除臭成分。另 外，依據使用用途，爲調整香氣亦可配合其他芳香成分， φ 亦可添加例如被稱爲「綠的香味」的綠葉醇或綠葉醛等， 賦予舒壓效果。 可使用於本發明之走爬性害蟲趨避劑係可配合使用情 況需要，採用液狀、凝膠狀、固體狀、薄片狀等之各種型 態。 調製液劑時，除了水以外，亦可適當使用如乙醇、異 丙醇之低級醇、酯系或醚系溶劑、或界面活性劑、可溶化 劑、分散劑。另外，除此之外，亦可再適當配合安定化 劑、pH調整劑、著色劑等。 -15- 201028089 另外，調製凝膠狀體所使用之膠化劑，可列舉鹿角菜 膠、三仙膠、結蘭膠、明膠、辛酸鋁、12-羥基硬脂酸 等。 關於液狀型態之走爬性害蟲趨避劑，詳述如下。 作爲處方，含有0.2〜20質量％之趨避走爬性害蟲成 分、0.2〜40質量％之沸點中央値爲160°C以上之溶劑、低 級醇及水，必要時再配合界面活性劑而成之水性液劑爲 宜，此趨避劑係適合使用於直接分散方式、藉由吸液芯引 ^ ◎ 導於蒸發部，分散趨避走爬性害蟲成分於空間之方式。 作爲低級醇，乙醇或異丙醇係代表，於性能上以乙醇 爲宜。另外，低級醇之配合量若超過10質量％時，對火 氣的危險性增大，產生不符合消防法上非危險物。 就趨避走爬性害蟲成分之安定性及分散性，界面活性 劑係以倂用高級烷基氧化胺系界面活性劑及非離子系界面 活性劑爲宜。 作爲高級烷基氧化胺系界面活性劑，可舉例如月桂基 Φ 氧化胺、硬脂醯氧化胺、月桂酸醯胺丙基二甲基氧化胺 等，另一方面，作爲非離子系界面活性劑，可列舉聚氧乙 烯硬化箆麻油、聚氧乙烯高級烷基醚（聚氧乙烯月桂基 醚、聚氧乙烯油基醚）、聚氧乙烯高級脂肪酸酯、聚氧乙 烯聚氧丙烯烷基醚等。 如此所得之走爬性害蟲趨避劑係例如放入該液劑於各 種容器中’作爲趨避走爬性害蟲製品，設置於需要抑制走 爬性害蟲徘徊或靠近之場所，可適用直接分散該液劑之方 •16- 201028089 式。 另外，上述所得之走爬性害蟲趨避劑係適用於例如填 充於具有吸液芯之容器本體中，作爲走爬性害蟲趨避製 品，設置於需要抑制走爬性害蟲之徘徊或靠近之場所，藉 由吸液芯分散趨避走爬性害蟲成分於空間之方式。 必要時，亦可通電以加熱於設置於吸液芯上方附近之 後述之蒸發部，促進分散。 Φ 吸液芯係對趨避劑安定且以毛細管現象吸取水溶液 者，作爲具體的材質，可舉例如尼龍、聚酯等之塑膠纖 維、天然纖維、木材等。其中塑膠纖維或天然纖維製毛氈 吸液芯容易使用，形成外徑爲3〜10mm程度之棒狀或撚 芯狀，供予使用。 通常，分散所吸取的趨避劑之蒸發部設置於吸液芯之 上方。自然分散時，蒸發部之結構係吸液素材爲毛氈或薄 片狀，另外，作爲該材質係與吸液芯時同樣地可使用例如 φ 尼龍、聚酯等之塑膠纖維、天然纖維、木材等。其中以塑 膠纖維或天然纖維之毛氈或薄片狀者爲宜，厚度爲2〜 15mm，成型成表面積爲10〜60cm2之略圓形，若將此配 設於接觸吸液芯的頂面，所吸取的趨避劑自吸液芯移往蒸 發部，自此緩緩分散於空中。通常調整成趨避劑每1天之 空中蒸發量爲1〜8mL，有效持續時間爲1〜2個月。 另一方面，適用於加熱成50〜130 °C之系統時，於蒸 發部附設適當的加熱器。 作爲走爬性害蟲會徘徊或有徘徊之虞的場所，可列舉 -17- 201028089 走爬性害蟲例如蜚蠊類（德國姬蠊（Blattella germanica)、 黑胸大蠊（Periplaneta fuliginosa)、美洲蛮蠊（Periplaneta americana)、日本大蠊（Periplaneta japonica)、棕色蛮蠊 (Periplaneta brunnea)、京都亞蠊（Asiablatta kyotensis) 等）、蟻類（含黑蟻、紅蟻、雙針犠等）、嚙蟲 (Psocoptera)、標本蟲（Anobiidae)、玉米象（Sitophilus zeamais)、經節蟲（Dermestidae)、瞒類等之走爬性害蟲係 當然、蚊類、蚋'搖蚊類、蠅類、蛾蚋類、衣蛾類等之會 0 徘徊或有徘徊之虞的場所，具體上可列舉蔚房（水槽周 圍、水槽下方的收納櫃中、米缸周圍、貯蔵食品（乾物、 砂糖、調味料等）之抽屜或櫃中等）、冰箱下方、食器櫃中 及周圍、置物櫃、廁所、洗臉處之水槽周圍或洗臉台之抽 屜中、玄關等之屋內、倉庫、飲食店等。 作爲走爬性害蟲會靠近或有靠近之虞的物品，可列舉 各種食品（例如生鮮食品（蔬菜、魚、肉）、加工食品、調 味料、乾物等）、飲料、食器等。 參 上述之嚙蟲係吃食品微細片或黴，於屋內一般可見之 體長爲1.5mm以下之微細蟲，玉米象係對米粒、穀粉等 造成食害，米、麥、玉蜀黍之重要害蟲，體長約2〜4mm 之甲蟲，鰹節蟲係以柴魚、魚干、穀類等食品爲首，亦加 害纖維製品之體長約3〜5mm之甲蟲，標本蟲係對麵線等 之乾燥食品或榻榻米、木材造成食害之體長約3 mm之甲 蟲’螞蟻係收集砂糖等之糖分、點心、魚干等之食品，以 及多數個體侵入屋內，造成不愉快感的蟲，蛾係發生於點 -18- 201028089 心、麵粉、米粒、豆類等之乾燥食品、穀類的蟲，但此等 各種害蟲係於一般家庭，例如廚房存在許多米、麵粉、點 心、魚千、砂糖、乾物等，並且容易發生於有濕氣之容易 長黴的場所。 本發明之方法中，將含浸或保持上述趨避走爬性害蟲 成分於各種固體載體之型態之走爬性害蟲趨避劑，適用於 走爬性害蟲會徘徊或有徘徊之虞的場所或其附近、或走爬 φ 性害蟲會靠近或有靠近之虞的物品或其附近，亦可自固體 載體自然蒸散趨避走爬性害蟲成分，利用對象空間內空氣 移動或對流將蒸散之有效成分，遍布於對象空間整體。 含浸或保持於固體載體之型態之走爬性害蟲趨避劑係 放入例如具有可蒸散趨避走爬性害蟲成分之開口部之容器 中，例如放入塑膠製容器中，作爲趨避走爬性害蟲製品， 設置於需要抑制走爬性害蟲會徘徊或靠近的場所，可適用 於直接分散該趨避走爬性害蟲成分之方式。 〇 作爲固體載體，可列舉紙漿、線頭、嫘縈等之纖維素 製載體、尼龍、聚乙烯醇、聚乙烯、聚苯乙烯、聚丙烯製 載體、矽酸鹽、二氧化矽、沸石等之無機多孔性載體、三 噁烷、金剛烷等之昇華性載體等，同時載持趨避走爬性害 蟲成分及因應需要之溶劑等於此等，可調製固體狀、薄片 狀、粒狀等之走爬性害蟲趨避劑。 另外，本發明之載體槪念亦包含藉由膠化劑所形成之 凝膠、或藉由固化材料所形成之固形物。 作爲上述凝膠，可列舉使用鹿角菜膠、三仙膠、結蘭 -19- 201028089 膠、明膠、辛酸鋁、12-羥基硬脂酸等之膠化劑，使趨避 走爬性害蟲成分及其他成分膠化者，作爲上述固形物，可 列舉使用皂、蠟、石膏、骨膠、香、塑膠等之固化材料， 將趨避走爬性害蟲成分及其他成分，形成含趨避走爬性害 蟲成分及其他成分之固形物者等。 載體中，尤其容易使用紙漿、線頭、嫘縈等之纖維素 製載體或尼龍、聚乙烯醇、聚乙烯、聚苯乙烯、聚丙烯製 載體，若於此載持0.01〜100mg/cm2之該趨避走爬性害蟲 _ 成分，同時使趨避成分之每24小時之揮發量爲0.2〜 2〇〇mg，達成對走爬性害蟲優異的趨避效果，而且因爲不 轉移趨避成分的臭味，所以提供尤其適合使用於廚房、冰 箱下方或食器櫃周圍等之防止趨避走爬性害蟲成分之臭味 轉移的方法。 另外，於空氣移動、對流不足的條件下，使用風扇或 冷氣機等之送風機構，使發生人工空氣的移動或對流，有 效率地達成趨避走爬性害蟲成分蒸散。 @ 作爲上述具體例，可舉例如所謂的旋轉型防蟲裝置 等。 另外，於可實施本發明之範圍，亦可利用超音波霧化 系統、壓式霧化系統、燻煙·燻蒸系統等，另外，當然亦 可適用各種防蟲具或防蟲裝置。 如此所得趨避走爬性害蟲製品係藉由設置於廚房（水 槽周圍、水槽下方的收納櫃中、米缸周圍、貯蔵食品（乾 物、砂糖、調味料等）之抽屜或櫃中等）、冰箱下方、食器 -20- 201028089 櫃中及周圍、置物櫃、廁所、洗臉處之水槽周圍或洗臉台 之抽屜中、玄關等之屋內、倉庫、飲食店等’當然對蜚蠊 類（德國姬蠊、黑胸大蠊、美洲蜚蠊、日本大蠊、棕色蜚 蠊、京都亞蠊等）、蟻類（含黑蟻、紅蟻、雙針蟻等）、嚙 蟲、標本蟲、玉米象、鏗節蟲、食心蟲、大穀盜 (Tenebroides mauritani cus)(含擬穀盜（Tribolium castaneum )等）、蜈松、花蚰蜓（Thereuonema ❾ tuberculata)、鼠婦（Armadillidium vulgare)、潮蟲 Oniscidea)、馬陸、蝶蛾幼蟲、蟎類等之走爬性害蟲、及 對蚊類、蚋、搖蚊類、蠅類、蛾蚋類、衣蛾類等之各種害 蟲，達成實用的趨避效果者。接著，因爲趨避走爬性害蟲 製品係於1個月至2個月長期間達成實用的趨避效果，臭 味亦不轉移，所以可成爲實用性極高的防止趨避走爬性害 蟲成分之臭味轉移的方法。 本發明之米缸用防蟲劑，通常加入各種成分於對孟 Φ 院-3,8_二醇’調製防蟲組成物，此適用於各種型態之米缸 用防蟲劑。對孟烷-3,8-二醇相對於米缸用防蟲劑整體量係 依米缸用防蟲劑的型態而異，但以設定米缸容量每10L爲 0-02〜l.Og程度爲宜。若未滿〇.〇2g時防蟲效果不足，另 一方面’若超過l.〇g時則出現發黏感等，並不實用。 本發明之米缸用防蟲劑係以同時配合上述對孟烷·3,8_ 二醇及來自植物之除臭成分爲宜。作爲如此之植物萃取 物’適當自稻科、山茶科、銀杏科、木犀科、桑科、橘 科、黃祷花科、柿樹科中選擇一種以上使用，綠茶萃取物 21 - 201028089 或柿萃取物爲代表。另外，來自植物之除臭成分之配合量 相對於對孟烷-3,8-二醇之0.01〜0.1倍量程度係足夠的。 已知作爲植物萃取物成分，例如多酚類係已知爲除臭 成分，但於本發明之米缸用防蟲劑，作爲對孟烷-3，8-二醇 之效力增強成分作用係全新的發現。該理由係推測防蟲成 分揮發時造成某些相互作用。 本發明之米缸用防蟲劑係配合使用情況需要，可採用 液狀、凝膠狀、固體狀、薄片狀等之各種防蟲組成物、以 及型態。 於調製液狀防蟲組成物，除水之外，亦適合使用如乙 醇、異丙醇之醇系溶劑、如1，3-丁二醇、丙二醇、二丙二 醇之甘醇系溶劑、二乙二醇單丁醚、丙二醇單甲醚等之甘 醇醚系溶劑、脂肪族烴系溶劑等之各種溶劑、或界面活性 劑（可溶化劑）等。 作爲界面活性劑，可列舉聚氧乙烯硬化箆麻油、聚氧 乙烯高級烷基醚（聚氧乙烯月桂基醚、聚氧乙烯油基醚）、 聚氧乙烯高級脂肪酸酯、聚氧乙烯聚氧丙烯烷基醚等之非 離子系界面活性劑、或月桂基氧化胺、硬脂醯氧化胺、月 桂酸醯胺丙基二甲基氧化胺等之高級烷基氧化胺系界面活 性劑等。 另外，可適當配合安定化劑、pH調整劑、著色劑 等，或亦可添加例如被稱爲「綠的香味」的綠葉醇或綠葉 醛等，賦予舒壓效果。 另外，作爲調製凝膠狀體所使用之膠化劑，可列舉鹿 -22- 201028089 角菜膠、三仙膠、結蘭膠、明膠、辛酸鋁、12-羥基硬脂 酸等。 本發明之米缸用防蟲劑係將含浸或保持上述防蟲組成 物於固體載體者，設置於米缸內，自固體載體揮發防蟲成 分之方式爲宜。作爲固體載體，可列舉紙漿、線頭、嫘縈 等之纖維質載體、矽酸鹽、二氧化矽、沸石等之無機多孔 性載體、三噁烷、金剛烷等之昇華性載體等。適宜的是收 φ 納使載持0.1〜lOOmg/cm2之對孟烷-3,8-二醇之纖維質載 體於通氣性容器中，使用適當的固定機構固定此通氣性容 器於米缸上蓋的裡面、或埋設於米中、或置於表面。 通氣性容器之形狀或組成並無特別限定，可舉例如設 置墊夾持零件於可開關之米俵狀通氣性盒內，夾持含浸防 蟲組成物之紙漿製墊於此而成者、或收納含浸防蟲組成物 製墊或珠粒之扁平狀之通氣性盒中、或收納含浸防蟲組成 物之紙漿製墊於使用紙、織布、不織布、多孔薄片等之袋 〇 狀通氣性容器中而成者。 若設置如此所得之本發明之米缸用防蟲劑於米缸內， 對玉米象、鰹節蟲、嚙蟲、標本蟲、蜚蠊、蟻類等之靠近 食品之害蟲係當然，亦對蚊類、蚋、搖蚊類、蠅類、蛾蚋 類、衣蛾類等之害蟲，於1個月至2個月之長期間達成實 用的防蟲效果者。接著，本發明中作爲防蟲成分使用之對 孟烷-3,8-二醇與傳統之山葵、芥末、薑或辣椒等比較，臭 味極弱，幾乎不轉移臭味於米，所以該實用性極高。 使用圖說明可使用於本發明之趨避走爬性害蟲製品之 -23- 201028089 具體例，但本發明當然不局限於此。圖1至圖4係表示放 入含浸或保持趨避走爬性害蟲成分於固體載體之型態之走 爬性害蟲趨避劑於容器中之趨避走爬性害蟲製品之1種型 態。該趨避走爬性害蟲製品係形成於容器1自上下夾住含 浸含趨避走爬性害蟲成分之藥劑之藥劑含浸體2(走爬性 害蟲趨避劑）之組成，整體成爲薄板狀之形狀。容器1係 具有用以蒸發趨避走爬性害蟲成分之開口部。 如上所述，藉由具有薄板狀之形狀，可容易地放入抽 ❹ 屜或食器櫃之狹小空隙，另外，藉由放入藥劑含浸體2於 容器1中，可防止含趨避走爬性害蟲成分之藥劑直接附著 於手、食器、食品、設置場所等。 容器1係可藉由各種塑膠材料形成，另外，藥劑含浸 體2(走爬性害蟲趨避劑）亦可使用含浸含趨避走爬性害蟲 成分之藥劑於紙漿等載體者。 圖5至8及圖9至12係表示放入含浸或保持趨避走 爬性害蟲成分於固體載體之型態之走爬性害蟲趨避劑於容 @ 器中之趨避走爬性害蟲製品之其他型態（容器1中用以蒸 發趨避走爬性害蟲成分之開口部之形狀不同）。 【實施方式】 實施例 接著，基於具體的實施例，更詳細地說明關於本發明 之防止趨避走爬性害蟲成分之臭味轉移的方法。 -24- 201028089 實施例1至4及比較例1、2 [濾紙趨避效力試驗] 調製表1表示之各種走爬性害蟲趨避劑試料（實施例 1至4及比較例1、2)’含浸規定量於直徑爲15cm之濾紙 後風乾。於塑膠容器（40cmx60cm)中放入各30隻之玉米象 或雙針蟻，同時設置前述濾紙於容器內’被覆濾紙於具有 8個出入口（直徑爲〇.5cm)之直徑爲15cm之紙製杯子。同 φ 樣地設置與使用於試料處理相同大小之濾紙及紙製杯子爲 無處理區。 放置水及實驗動物用飼料於中央，計數8小時後潛伏 於兩紙製杯子內之蟲數，依據下式算出趨避率。重複試驗 4次，該平均値如表1表示。 趨避率（％)=[無處理區之潛伏蟲數-試料處理區之潛 伏蟲數]/[無處理區之潛伏蟲數+試料處理區之潛伏蟲數]X 100 表1濾紙趨避效力試驗之結果 趟性害蟲 mm mm (%) 麵走爬性害蟲成分 其他成分 成分名 g/m2 成分名 g/m2 玉米象 雙針蟻 實 1 對;S^-3,8-二醇 0.2 _ . 81 91 施 2 對孟烷-1,8-二醇 0.2 _ 寒 73 81 例 3 對孟院-3,8-二醇 0.2 二乙二醇單丁醚 2.0 93 98 4 對孟院-1,8-二醇 0.2 1,3-丁二醇 2.0 90 94 比 1 迷迭香油 0.2 . 37 41 敉 例 2 百里香 0.2 - - 33 36 -25- 201028089 試驗結果，本發明之走爬性害蟲趨避劑係基於作爲趨 避走爬性害蟲成分配合之對孟烷-3,8-二醇及/或對孟烷-1，8 -二醇之作用，顯示對玉米象或雙針蟻之趨避效果遠遠 勝於比較例之迷迭香油或百里香。另外，該趨避效果係藉 由配合沸點爲160 °C以上之溶劑，尤其甘醇系、甘醇醚系 溶劑而更增強。 對照上’如比較例1及比較例2所示，迷迭香油或百 里香之趨避效果低。 實施例5至19及比較例3至7 [濾紙趨避效力試驗] 調製表2表示之各種走爬性害蟲趨避劑試料（實施例 5至19及比較例3至7)，含浸規定量於直徑爲15 cm之濾 紙後風乾。於塑膠容器（4〇cmx6〇cm)中放入15隻（雄成 蟲、雌成蟲、幼蟲各5隻）之黑胸大蠊’設置前述濾紙於 容器內’同時被覆濾紙於具有4個出入口（寬爲2cm，高 φ 爲2cm)之直徑爲15cm之紙製杯子。同樣地設置與使用於 試料處理相同大小之濾紙及紙製杯子爲無處理區。 放置水及實驗動物用飼料於中央，計數8小時後潛伏 於兩紙製杯子內之蜚蠊數’依據下式算出趨避率。重複試 驗8次，該平均値如表2表示。 趨避率（％)=[無處理區之潛伏蟲數-試料處理區之潛 伏蟲數]/[無處理區之潛伏蟲數+試料處理區之潛伏蟲數]x 100 -26- 201028089 表2濾紙趨避效力試驗之結果 走爬性害蟲趨避劑 趨避率 (%) 趨避走爬性害蟲成分 其他成分 成分名 g/m2 成分名 g/m2 實 5 對孟烷-3,8-二醇 0.1 _ 53 施 6 對孟烷-3,8-二醇 0.2 68 例 7 對孟烷-1,8-二醇 0.1 一 _ 51 8 對孟烷-1，8-二醇 0.2 - _ 65 9 對孟烷-3,8-二醇 0.2 二乙二醇單丁醚 2.0 94 10 對孟烷-1，8-二醇 0.2 1,3-丁二醇 2.5 92 11 對孟烷-3,8-二醇 0.15 二丙二醇單甲醚 3.0 97 對孟烷-1，8-二醇 0.05 12 對孟烷-3,8-二醇 0.1 1-甲氧基-1，2-丙二醇 3.0 93 紫羅蘭酮 0.1 13 對孟烷-1,8-二醇突厥酮 0.1 - - 80 (damascone) 0.1 14 對孟烷-1，8-二醇薄荷醇 0.1 - - 59 0.1 15 對孟院-3,8-一醇 0.2 燈油(沸點；170°C ) 2.0 84 16 對孟院-1，8-一醇 0.15 二乙二醇單丙醚 1.5 94 烯丙紫羅蘭酮 0.05 17 3-(N-乙醯基-N-丁基） 0.2 二乙二醇單丁醚 1.0 81 胺基丙酸乙酯 18 picaridin 0.2 _ • 57 19 琥珀酸二丁酯 0.2 59 比 3 薄荷醇 0.2 一 _ 27 較 4 萜品烯-4-醇 0.2 一 _ 31 例 5 百里香 0.2 _ 26 6 日本薄荷油 _ _ 一 32 7 - - 二乙二醇單丁醚 2.0 8 -27- 201028089 試驗結果，本發明之走爬性害蟲趨避劑係基於配合作 爲趨避走爬性害蟲成分之對孟烷-3,8-二醇及/或對孟烷_ 1，8-二醇、3-(N-乙醯基-N- 丁基）胺基丙酸乙酯、 picaridin、琥珀酸二丁酯之作用，顯示對蜚蠊之趨避效果 遠遠勝於比較例之薄荷醇、萜品烯-4-醇（揭示於特開平 11-60 421號公報）、百里香或日本薄荷油。另外，該趨避 效果係如實施例15所示，藉由配合沸點爲160 °C以上之 溶劑，尤其甘醇系、甘醇醚系溶劑而大幅地增強。另外， 由實施例1 3及實施例1 4之對比判斷與金剛烷倂用係有效 的，此趨勢係紫蘿蘭酮或烯丙紫羅蘭酮亦相同。 對照上，如比較例3至比較例7所示，薄荷醇、萜品 烯-4-醇、百里香或日本薄荷油之趨避效果低，作爲效力 增強劑使用之甘醇醚系溶劑於單獨時亦幾乎完全未顯示趨 避效果。 實施例20、21及比較例8至10 [實地趨避效力試驗] 將含浸各種趨避走爬性害蟲成分之紙漿製墊（5χ 10cm) ’收納於具有規定揮發孔（表裡總面積爲35cm2，相 對於容器之表裡總表面積爲 28 %)之塑膠容器（5.8χ 10_8 cm)’調製表3所示之各種走爬性害蟲趨避劑試料。 此等之每24小時之趨避成分揮發量係如表3所示。 放置60隻之德國蜚蠊於2 m2之場地，使馴化可自由 攝取水及固體飼料。放入趨避劑試料及適量的固體飼料於 201028089 塑膠製容器，以設有間隙（lcm)之狀態加蓋’設置於場地 內。另外，設置相同尺寸的容器作爲無處理區。經時地計 數潛伏於容器內之蜚蠊’依據下式算出趨避率。合併結果 如表3表示。 趨避率（％) =[無處理區之潛伏蟲數-試料處理區之潛 伏蟲數]/[無處理區之潛伏蟲數+試料處理區之潛伏蟲數]x 100 表3實地趨避效力試驗之結果 走爬件害蟲趨避齊!I 揮發量 (mg/24hr) 趨避率(％) 趨避趙性害蟲成分 含浸量 fmg/cm2) Id後 4d後 l〇d後 實施例 20 對孟烷3,8-二醇 8 3 84 71 70 21 對孟烷1,8-二醇 8 4 86 80 70 比較例 8 檜木油 50 44 53 43 40 9 萊姆油 50 62 63 47 43 10 迷迭香油 40 13 37 33 31 試驗結果，含浸對孟烷-3,8-二醇或對孟烷-1，8-二醇 之本發明之走爬性害蟲趨避劑（實施例20、21)與含其他香 草成分之比較相比較，因爲即使含浸量及揮發量少，仍顯 示高趨避率，而且幾乎不感到臭味，所以極爲實用。 相對於此’含檜木油、百里香油或迷迭香油之比較例 之走爬性害蟲趨避劑，即使揮發量高，趨避效果仍低，並 且臭味過強，判斷尤其不適用於廚房。 實施例22、23及比較例11 -29- 201028089 [合成板趨避效力試驗]201028089 VI. Description of the Invention [Technical Fields of the Invention] The present invention relates to a method for suppressing the migration of pests or stalks and preventing the odor transfer of the escaping pest components, and in detail, it is difficult to transfer odor A smattering agent that avoids the escaping pests and is suitable for escaping pests, and is suitable for use in places where squatting pests may or may not be smashed, or where escaping pests are close to or close to each other. Or its attached _ near method. Further, the present invention relates to an insect repellent for a rice cylinder. [Prior Art] Traditionally, as a evasive agent for flying insects such as mosquitoes, cockroaches, and chironomids, many kinds of N,N-diethyl metaaniline (N,N-Diethyl Meta ToluamideH) have been known as DEET.), a composition of citronellal, onion alcohol, menthol, limonene, geraniol, citronellol, camphorene, etc. (for example, refer to Patent Document 1). On the other hand, as a component of the escaping pest, a lemon smear, a squid, a saponin, a perilla, a scent, a tea tree oil, a grapefruit oil, and the like are disclosed (for example, refer to Patent Document 2). A method of avoiding escaping pests using a dicarboxylic acid ester such as diethyl oxalate, dimethyl malonate or dimethyl succinate (for example, refer to Patent Document 3). However, the avoidance effect of such avoiding components is not necessarily sufficient, or has a safety problem, and it is difficult to say that the practicality is excellent. Therefore, it is preliminarily reviewed from the natural safety of cinnamon, -5- 201028089 camphor, lemongrass, sorrel, thyme, geranium, bergamot, laurel, pine, red peach, silver mint, eucalyptus and neem The extracted essential oil, extract, etc. are used as a avoidance component. For example, most of the natural evasive ingredients are strong in odor (fragrance), and even if they are not unpleasant odors, they are used in places where many foods, beverages, etc. are handled in kitchens where squatting pests are paralyzed or smashed. In this case, the odor of the escaping component is directly transferred to the food, drink, or the like, or the odor of the escaping component is transferred to the food or the like, and the odor of the evasive component is indirectly transferred to the food, drink, or the like by the food container or the like. Therefore, the flavor, flavor, taste, and the like of such foods and beverages are impaired. Therefore, in addition to excellent safety, it avoids the odor of the creeping pest components. 'Climbing pests may be paralyzed or smashed. For example, kitchen places or climbing pests may be close to or close to, such as food and beverages. In the case of an article such as a food eater, there is a strong demand for a method for preventing the odor transfer of the escaping pest component. In addition, conventionally, various corn tanks have been proposed for use in various rice cylinders or storage of mites. For example, it is known as a quality preservative for the purpose of antibacterial, anti-mildew, and insect-prevention of rice, which is composed of allicin, capsaicin, etc., as disclosed in Japanese Patent Publication No. Hei 6-38678. Japanese Patent Publication No. 11-222409 discloses a tea tree oil containing natural substances as an active ingredient, and a rice-tank insect-proofing material which is impregnated with a liquid impregnating material containing a perillantaldehyde as a main component. / or corn oil as a repellent. In addition, recently, corn using wasabi, mustard, pepper, garlic, etc. -6- 201028089 Like a repellent, it is used in commercial rice cylinders. Since these medicines are used as foods, there is no need to worry about phytotoxicity. However, since the avoidance effect is weak, it is necessary to use them in large quantities to ensure the effect. In addition, because of the strong odor, it is impossible to avoid the transfer of odor to the rice, and there is also a problem of irritation to people. [Patent Document 1] JP-A-2007-230894 [Patent Document 4] JP-A-2007-230894 (Patent Document 4) Kaiping No. 6-38678.  [Patent Document 5] Japanese Laid-Open Patent Publication No. Hei No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. The method of preventing the odor transfer of the stalking insect pest component is a problem. Further, the present invention also provides an insect repellent for rice cylinders which is easy to use and which is easy to use and which is easy to use and has an anti-insect effect and an insect-repellent effect on food pests represented by corn elephants. Solution to the problem The odor of the compound comes from this volatility. Although the compound has a odor of 201028089 and has a certain degree of volatility, on the other hand, the higher the volatility, the higher the odor and the more volatile. If it is low, it does not mean that the odor is almost absent. Further, whether or not the odor of the compound is easily transferred to other articles is not necessarily related to the strength of the odor of the compound. According to the above-mentioned viewpoint, the present invention investigates and evaluates the odor of a compound having a evading effect on migrating pests, and is volatilized in space according to high safety and non-contact, and is found to suppress stagnation pests or close, and A specific compound that does not easily transfer odor. ‘that is, there is some difference between the insect's sense of smell and the human sense of smell, but these compounds are particularly sensitive to the insect's sense of smell, and the sensitivity to human sense of smell is low. Next, the use of these compounds as a migrating pest repellent for avoiding escaping pests, if applied to a place where the migrating pests may or may not be squatted, or the migrating pests may approach or The article near the top of the article or in the vicinity thereof is found to prevent the odor transfer of the escaping pest component from being inhibited when the cockroach pest is caught or approached, and the present invention has been completed. In addition, the inventors of the present invention have made an effort to review the results of the insect repellent for rice cylinders which achieve the above-mentioned object, and have found that a particularly excellent anti-aspiration effect and an insect-repellent effect are achieved in the montan-3,8-diol terpene-based compound. In addition, it has been found that the insecticide for rice cylinders containing the compound has high safety to humans and animals and has a low odor, so it is extremely effective for the purpose. That is, the present invention employs the following constituents. (1) In the place where the climbing pests will be paralyzed or in the field of 2010-0889, or the items that the climbing pests will approach or the items that are close to the 'suppressing the crawling pests or close to them' A migrating pest repellent that contains a component that is difficult to transfer odor and avoids escaping pests, and is suitable for use in or near a place where escaping pests may be paralyzed or smashed, or where escaping pests are close to or close to each other. A method of preventing the odor of the escaping pest component from being transferred to a suitable place or article in the vicinity of the sputum article. Φ (2) in places where walking pests are paralyzed or in places where there are squats, or items in which stalking pests are close or articles that are close to the cockroach, or when walking or crawling pests are close, ' A migrating pest-avoiding product containing a stalking scent that is difficult to transfer odors, placed in or near a place where escaping pests may be paralyzed or smashed, or stalking pests may approach or have A method of preventing the odor of the escaping pest component from being transferred to the place or article to be placed in the vicinity of the article or the vicinity thereof. Ο (3) The escaping pest-resistant product system is provided with the escaping pest component which is difficult to transfer odor # and the lysate or dispersion in the fibrous carrier, and the prevention and avoidance described in (2) A method of transferring the odor of a crawling pest component. (4) The above-mentioned difficult-to-transfer odor-avoiding stalking pest component is highly sensitive to pest olfaction, and the compound having low sensitivity to human olfaction is prevented from escaping as described in any of (1) to (3) above. Stinky insect pests.  The method of taste transfer. (5M乍 is the above-mentioned difficult-to-transfer odor-avoiding stalking pest component -9 - 201028089 Using Mengyuan-3,8-diol, to Mengyuan_1,8-diol, 3-(]^- Ethylidene-1^-butyl)aminopropionic acid ethyl ester, picaridin (1-pipered residual acid 2-(2-ethyl)-1-methylpropyl), 2-ethyl-l, 3-hexanediol, diethyl oxalate, dimethyl malonate, diethyl malonate, dimethyl succinate, diethyl succinate, dipropyl succinate, dibutyl succinate, pentane Dimethyl dicarboxylate, diethyl adipate, dipropyl adipate, dibutyl adipate, diethyl sebacate, dipropyl sebacate, dibutyl sebacate, benzene Any of the aforementioned (1) to (4) of dimethyl formate, dibutyl phthalate, diamyl phthalate, dibutyl maleate, dibutyl fumarate or a mixture thereof. (6) As the above-mentioned difficult-to-transfer odor-avoiding stalking pest component, it is used for montan-3,8-diol, paraben-i,8-diol, 3-(N- Acetyl-N-butyl)aminopropionic acid ethyl acetate, picaridin (1-anthracene 2-(2-hydroxyethyl)-1-methylpropyl), 2 - The method described in the above (5) of the ketone-1,3-hexanediol or a mixture of the above. (7) As the above-mentioned difficult-to-transfer odor, the escaping pest component is used for the Mengyuan-3,8-two Alcohol, Essence-i, 8-diol, 3-(N-ethylindolyl-N-Q butyl)aminopropionic acid ethyl ester, picaridin (l-piperidinecarboxylic acid 2-(2-hydroxyethyl) The method described in the above (6) of the above-mentioned mixture of the above-mentioned (6). (8) As the above-mentioned difficult-to-transfer odor, the escaping pest component is used for the montane-3,8- a method described in the above (7) for a diol, a paraben-, a diol or a mixture of the above. (9) A refractory odor containing a paraben--3,8-diol The above-mentioned (2) method of the above-mentioned (2) is described in the above-mentioned (2) description of the method of -10- 201028089, which is characterized by the escaping pests and the escaping pests. The amount of montan-3,8-diol used is 0. 02~1. 0g/10L is a method described in the above (9). (1) A method for avoiding escaping pests used in the method described in the above (9) or (10). (12) The anti-crawling pest product described in the above (11) which is characterized by the above-mentioned deodorizing component derived from the plant. (13) Storage load 〇. 1~1〇〇111§/(;1112 The above-mentioned fibrous carrier of Mengyuan-3,8-diol is formed in an air permeable container, and the ventilated container is characterized by a mechanism fixed to the rice cylinder. The anti-crawling pest product described in the above (11) or (12). (14) The insect-repellent insect rice containing the paraffin-3,8-diol as an insect-repellent component and disposed in the rice cylinder (15) The insecticide for rice cylinder described in the above (14) characterized by the above-mentioned deodorant component derived from the plant, and the deodorant component derived from the plant (16) The content of 3,8-diol is 0. 02~1. 0g/10L is an insect repellent for a rice cylinder described in the above (14) or (15). (17) Storage and carrying 0. 1 to 100 mg/cm 2 of the above-mentioned cellulosic carrier of montan-3,8-diol in an air permeable container. The vented container is characterized by the mechanism (14) to (the mechanism fixed to the rice cylinder) 16) An insect repellent for a rice cylinder according to any one of the items. EFFECTS OF THE INVENTION -11 - 201028089 According to the present invention, it is excellent in safety, and it is possible to suppress the escaping of or avoiding the escaping of the escaping pests. Therefore, it is a problem to avoid the odor transfer of the stalking pest component, and it is possible to prevent the odor of the escaping pest component from being transferred to the food when the stalking insect pest or the food/drink is approached. Drinks, etc. In addition, when the odor of the stalking pest component is transferred to a food container or the like, it is necessary to perform washing, etc., in order to eliminate the odor before using the odor-affected food eater. Such a washing operation can be omitted. Further, it is not limited to the kitchen, and it is also possible to use the place where the avoidance agent is avoided by avoiding the odor transfer of the component. In addition, the pest control agent for the rice cylinder of the present invention is excellent in the avoidance effect and pest control effect of the food pest represented by the corn elephant and the safety to the human and animal, and does not transfer the odor to the rice, and is easy to use, so the practicality is extremely high. high. BEST MODE FOR CARRYING OUT THE INVENTION The method for inhibiting the escaping pests or the proximity of the stalking pests of the present invention to prevent the odor transfer of the escaping pest components is to avoid the escape of the escaping pest components which are difficult to transfer odors. A walking insecticide agent is suitable for use in or near a place where a crawling pest is paralyzed or has a cockroach, or an article in which the migrating pest is close to or near. The anti-migration pest component used in the present invention which is difficult to transfer odor is highly sensitive to insect olfaction, and has low sensitivity to human olfaction. -12- 201028089 compound, as such a compound Alkane-3,8-diol, p-mentane-1,8-diol, ethyl 3-(N-ethinyl-N-butyl)aminopropionate, picaridin (l-piperidinecarboxylic acid 2 -(2-hydroxyethyl)-1-methylpropyl), 2-ethyl-1,3-hexanediol, diethyl oxalate, dimethyl malonate, diethyl malonate, amber Dimethyl methacrylate, diethyl succinate, dipropyl succinate, dibutyl succinate, dimethyl glutarate, diethyl adipate, dipropyl adipate, dibutyl adipate , diethyl sebacate, dipropyl sebacate, dibutyl phthalate, dimethyl phthalate, dibutyl phthalate, diamyl phthalate, dibutyl maleate , dibutyl fumarate or a mixture of these. As a series of avoidable escaping pests suitable for difficult to transfer odor, it is a series of montane-3,8-diol, p-mentane-1,8-diol, 3-(N-ethinyl-N-butyl Ethyl propyl acrylate, picaridin (2-(2-hydroxyethyl)- propyl propyl propyl), 2-ethyl-1,3-hexane diol or a mixture of these. As a series of escaping pests that are more suitable for difficult to transfer odor, it is a series of montane-3,8-diol, p-mentane-1,8-diol, 3-(N-ethinyl-N-butyl ^) Aminopropyl propionate, picaridin (2-(2-diaethyl)-1-methylpropyl)- or a mixture of these. As a series of escaping pests that are more suitable for difficult to transfer odors, it is a mixture of montan-3,8-diol, p-mentane-1,8-diol or the like. Further, it is especially preferred for the cyclohexane-3,8-diol. Any of the above compounds may be a synthetic product or a natural component. Further, among the above compounds, there are a trans-form and a cis-form based on a stereo structure for montan-3,8-diol and p-mentane·1,8-diol, but the present invention is in the present invention. Mixtures of any ratio of the two isomers can be used. The substance contained in the mendelane-3,8-diol and/or the paraben-1,8-diol-based lemon tart essential oil is known as a repellent component of a repellent for flying insects such as mosquitoes, but There is still no review report on the effect of climbing pests. On the other hand, regarding the cyclohexane-1,8-diol, although it has an effect of avoiding mosquitoes, it has never been noticed. As the escaping pest repellent which can be used in the present invention, the stomach can be composed of the above-mentioned escaping pest component, but various components are usually added to prepare various forms. The ratio of the content of the anti-crawling pest component or the total amount of the anti-avoiding agent varies depending on the type of the anti-avoiding agent. For example, when using a liquid such as a liquid, set it to 〇.  2 to 20% by mass is preferred. If it is less than 0. When the amount is 2% by mass, the effect of avoiding is insufficient. On the other hand, when it exceeds 20% by mass, stickiness or the like occurs, which is not practical. In addition, when carried in the type of carrier used, it carries 〇. 〇1~ 0 100mg/cm2, while adjusting the volatile component of the escaping pest component every 24 hours, the range is 0. 2 to 200 mg is appropriate. The use of a liquid migrating pest repellent such as a liquid agent is not limited to the escaping pest component which is difficult to transfer odor, and it is preferable to use a solvent having a boiling point center 値 of 1 60 ° C or more as an efficacy enhancer. Examples of such a solvent include glycol, glycol ether, and an aliphatic hydrocarbon solvent, and glycol, glycol ether, and kerosene are particularly preferable. Specific examples thereof include propylene glycol, 1,3-butylene glycol, and the like, 2, hexamethylene-14-201028089 alcohol, diethylene glycol monobutyl ether, propylene glycol monobutyl ether, dipropylene glycol monomethyl ether, and Methoxy-1,2-propanediol, etc., but is not limited thereto. When using montan-3,8-diol and/or p-mentane-1,8-diol as a component for avoiding escaping pests, if the glycol or glycol ether is blended, the effect of the avoidance effect is considered. Enhanced, but when it is combined with glycol or glycol ether in the pyrethroid insecticidal component, the known phenomenon of reduced insecticidal effect is a control result. It is speculated that this is due to the different types of insecticidal components, which are greatly involved in the avoidance effect, and the combination of montan-3,8-diol and/or paraben -1,8-diol, and the central boiling point of the boiling point is 16 (TC or more, especially glycol, glycol ether solvent or lamp oil is particularly effective in the effect of avoidance effect. In addition, the amount of the potentiating agent is evading the walk-through property. Pest of pest components. 5 times or more, to 2. 0 to 50 times the amount is appropriate. Further, a plant-derived deodorant component such as a green tea extract or a persimmon extract can be added to the escaping pest repellent of the present invention. In addition, depending on the intended use, it is also possible to adjust the aroma with other aromatic components, and φ may also add, for example, a greenish alcohol or a green aldehyde, which is called a "green scent", to impart a relaxing effect. The escaping pest repellent used in the present invention can be used in various forms such as a liquid, a gel, a solid, or a flake in accordance with the use. In the preparation of the liquid preparation, a lower alcohol such as ethanol or isopropyl alcohol, an ester or ether solvent, or a surfactant, a solubilizing agent or a dispersing agent may be suitably used in addition to water. Further, in addition to this, a stabilizer, a pH adjuster, a colorant, and the like may be appropriately blended. -15- 201028089 Further, examples of the gelling agent used for preparing the gelatin include carrageenan, sanzan gum, yam gum, gelatin, aluminum octoate, and 12-hydroxystearic acid. Regarding the liquid form of the migrating pest repellent, the details are as follows. As a prescription, it contains 0. 2 to 20% by mass to avoid the crawling pest component, 0. 2 to 40% by mass of the boiling point of the center 値 is a solvent of 160 ° C or higher, a lower alcohol and water, if necessary, an aqueous liquid agent is preferably blended with a surfactant, and the evasive agent is suitable for direct dispersion, borrowing Guided by the wick, the ◎ is guided to the evaporation section, and the method of displacing the components of the stalking pests in space is dispersed. As a lower alcohol, ethanol or isopropanol is representative, and ethanol is preferred in terms of performance. Further, when the amount of the lower alcohol is more than 10% by mass, the risk of ignition is increased, and a non-hazardous substance which does not comply with the fire protection law is generated. In order to avoid the stability and dispersibility of the components of the climbing pest, the surfactant is preferably a higher alkyl amine oxide surfactant and a nonionic surfactant. Examples of the higher alkyl amine oxide-based surfactant include a lauryl Φ amine oxide, a stearic acid amine oxide, a guanamine propyl methoxide amine oxide, and the like, and a nonionic surfactant. Examples include polyoxyethylene hardened castor oil, polyoxyethylene higher alkyl ether (polyoxyethylene lauryl ether, polyoxyethylene oleyl ether), polyoxyethylene higher fatty acid ester, polyoxyethylene polyoxypropylene alkyl ether Wait. The escaping pest repellent agent thus obtained is, for example, placed in the liquid container in various containers as a evasive migrating pest product, and is disposed in a place where it is necessary to suppress stalking pests or insects, and is suitable for directly dispersing the liquid agent. The party • 16- 201028089 style. Further, the escaping pest repellent agent obtained as described above is suitably used, for example, to be filled in a container body having a wick, and is used as a migrating pest-avoiding product, and is provided in a place where it is necessary to suppress squatting pests or close to it. The manner in which the wick is dispersed to avoid the composition of the stalking pests in space. If necessary, it may be energized to be heated to a later-described evaporation portion provided near the upper side of the wick to promote dispersion. Φ The wicking liquid is a kind of a plastic material such as nylon or polyester, natural fiber, wood, etc., as a specific material. Among them, the plastic fiber or natural fiber felt wick is easy to use, and is formed into a rod shape or a core shape having an outer diameter of about 3 to 10 mm for use. Usually, the evaporation portion of the repellent adsorbent is disposed above the wick. In the case of natural dispersion, the structure of the evaporation portion is a felt or a sheet, and as the material, a plastic fiber such as φ nylon or polyester, natural fiber, wood or the like can be used as the wick. Among them, it is suitable for the felt or flaky shape of plastic fiber or natural fiber, the thickness is 2~15mm, and the surface area is slightly rounded with a surface area of 10~60cm2. If this is disposed on the top surface of the contact wick, it is sucked. The repellent moves from the wick to the evaporation section and is slowly dispersed in the air. Usually, the amount of evaporation of the avoidant in the air per day is 1 to 8 mL, and the effective duration is 1 to 2 months. On the other hand, when it is applied to a system heated to 50 to 130 °C, an appropriate heater is attached to the evaporation portion. As a place where stalking pests may be paralyzed or smashed, -17- 201028089 walking pests such as cockroaches (Blattella germanica, Periplaneta fuliginosa, American cockroach) (Periplaneta americana), Periplaneta japonica, Periplaneta brunnea, Asiablatta kyotensis, ants (black ants, red ants, double acupuncture, etc.), rodents ( Psocoptera), Anobiidae, Sitophilus zeamais, worms (Dermestidae), cockroaches, etc., of course, mosquitoes, cockroaches, chironomids, flies, moths, For the place where the clothes moths are 0 or 徘徊, the drawers around the sink (in the storage cabinet below the sink, around the rice tank, and in the storage of food (dry matter, sugar, seasonings, etc.) can be cited. Or the cabinet is medium), under the refrigerator, in and around the food cabinet, in the locker, in the toilet, in the washbasin around the sink or in the drawer of the washstand, in the house of the porch, in the warehouse, in the restaurant, etc. As items that are close to or close to the crawling pests, various foods (such as fresh foods (vegetables, fish, meat), processed foods, seasonings, dried foods, etc.), drinks, foods, and the like can be cited. The above-mentioned rodent eats food fine pieces or mildew, and the body length generally seen in the house is 1. Fine insects of less than 5 mm, corn elephants cause damage to rice grains, flour, etc., important pests of rice, wheat, and maize, beetles with a body length of about 2 to 4 mm, and the locusts are headed by food such as firewood, dried fish, and cereals. Also, it is a beetle with a body length of about 3 to 5 mm, a dry food such as a line of the opposite line of the worm, or a beetle of about 3 mm in length caused by tatami and wood. The ant collects sugar, snacks, and fish such as sugar. Dried foods, and most individuals invade the house, causing unpleasant worms. Moths occur in dry foods and cereals such as heart, flour, rice, beans, etc. at point -18- 201028089, but these various pests are In general households, such as kitchens, there are many rice, flour, snacks, fish, sugar, dry matter, etc., and they are prone to occur in places where moisture is prone to mold. In the method of the present invention, the migrating pest repellent which impregnates or maintains the above-mentioned evasive stalking pest component in various solid carriers is suitable for use in or near a place where escaping pests may be paralyzed or smashed. Or stalking pests that are close to or near the shackles or near them, or evade naturally from the solid carrier to avoid the stalking pests, and use the airborne or convective airborne components in the object space to spread the active ingredients. The object space as a whole. A migrating pest repellent that is impregnated or retained in a solid carrier is placed, for example, in a container having an opening portion that can evade the escaping pest component, for example, placed in a plastic container as a evasive walking pest. The product, which is placed in a place where it is necessary to suppress the walking or pesting, may be applied to directly disperse the means for avoiding the stalking pest component. Examples of the solid carrier include cellulose carriers such as pulp, thread, and enamel, nylon, polyvinyl alcohol, polyethylene, polystyrene, polypropylene carrier, silicate, cerium oxide, zeolite, and the like. An inorganic porous carrier, a sublimation carrier such as trioxane or adamantane, etc., and a solvent which avoids the escaping pests and a solvent which is required to be equivalent thereto can be used to modulate solid, flake, and granular materials. Sexual pest repellent. Further, the carrier of the present invention also encompasses a gel formed by a gelling agent or a solid formed by a curing material. Examples of the gel include a gelling agent such as carrageenan, sanxian gum, ylang-19-201028089 gelatin, gelatin, aluminum octoate, and 12-hydroxystearic acid, so as to avoid the escaping pest component and others. In the case of the above-mentioned solid material, a solidified material such as soap, wax, gypsum, bone glue, scent, or plastic is used, and the stalking pest component and other components are prevented from being formed to form a composition containing the escaping pest and other components. Solids of ingredients, etc. In the carrier, it is particularly easy to use a cellulose carrier such as pulp, thread, or enamel, or a carrier made of nylon, polyvinyl alcohol, polyethylene, polystyrene or polypropylene. 01~100mg/cm2 should avoid the creeping pest _ component, and at the same time make the volatile component of the avoidance component every 0 hours. 2 to 2 〇〇mg, which achieves an excellent avoidance effect on migrating pests, and because it does not transfer the odor of the escaping component, it is particularly suitable for use in the kitchen, the refrigerator, or around the food cabinet to prevent escaping pests. A method of transferring odor of ingredients. Further, under the condition of air movement and insufficient convection, a blower mechanism such as a fan or an air conditioner is used to cause the movement or convection of the artificial air to efficiently escape the evapotranspiration of the creeping pest component. @ As a specific example, a so-called rotary insect control device or the like can be mentioned. Further, in the range in which the present invention can be carried out, an ultrasonic atomization system, a pressure atomization system, a fumigation/fumigation system, or the like can be used, and of course, various insect-proof or insect-proof devices can be applied. The anti-walking pest products thus obtained are provided in the kitchen (in the storage cabinet around the sink, under the sink, around the rice tank, in the drawer or cabinet of the food (dry matter, sugar, seasoning, etc.), under the refrigerator,食器-20- 201028089 In and around the cabinet, lockers, toilets, sinks around the washbasin or drawers in the washstand, porch and other houses, warehouses, restaurants, etc. 'Of course, 蜚蠊 ( (German 蠊, black Thoracic cockroaches, American cockroaches, Japanese cockroaches, brown cockroaches, Kyoto Aachen, etc.), ants (including black ants, red ants, double needle ants, etc.), worms, specimens, corn elephants, stag beetles , T. sinensis, Tenebroides mauritani cus (including Tribolium castaneum, etc.), 蜈松, 蚰蜓 (Thereuonema ❾ tuberculata), Rat (Armadillidium vulgare), Heliotrope Oniscidea), Ma Lu, Butterfly It is a pest-resistant pest such as moth larvae and mites, and a practical anti-aspiration effect for various pests such as mosquitoes, cockroaches, cockroaches, flies, moths, and clothes moths. Then, since the escaping pest-resistant product achieves a practical avoidance effect for a period of from 1 month to 2 months, the odor does not shift, so that it is highly practical to prevent the odor of the escaping pest component. The method of transfer. The insect repellent for the rice cylinder of the present invention is usually prepared by adding various components to the insecticidal composition of the GM-3,8-diol diol, which is suitable for various types of rice cylinder insect repellents. The overall amount of the insecticide used in the methane-3,8-diol relative to the rice cylinder varies depending on the type of the insect repellent used in the Imi cylinder, but it is 0-02~l per 10L of the set cylinder capacity. The degree of Og is appropriate. If not full. 〇 2g when the insect control effect is insufficient, on the other hand 'if more than l. When 〇g, there is a sticky feeling, etc., which is not practical. The insect repellent for rice cylinders of the present invention is preferably formulated with the above-mentioned deodorant component of montan-3,8-diol and plant. As such a plant extract, it is appropriate to use one or more of the selected ones from the family of rice, Camellia, Ginkgo, Oleaceae, Mulberry, Orange, Yellow, and Persimmon, green tea extract 21 - 201028089 or persimmon extract Objects are representative. In addition, the amount of the deodorant component derived from the plant is relative to 0% of the mendelane-3,8-diol. 01~0. A factor of 1 is sufficient. It is known that as a plant extract component, for example, a polyphenol type is known as a deodorant component, but the insecticide for rice tank of the present invention acts as a potentiating component for the effect of molybdenum-3,8-diol. The discovery. This reason is presumed to cause some interaction when the insect-repellent component volatilizes. The insect repellent for the rice cylinder of the present invention may be used in combination with various insect-repellent compositions such as liquid, gel, solid, and flake. In the preparation of the liquid insect-repellent composition, in addition to water, an alcohol solvent such as ethanol or isopropanol, a glycol solvent such as 1,3-butanediol, propylene glycol or dipropylene glycol, or a diethylene glycol is also suitable. A glycol ether solvent such as an alcohol monobutyl ether or a propylene glycol monomethyl ether; a solvent such as an aliphatic hydrocarbon solvent; or a surfactant (a solubilizing agent). Examples of the surfactant include polyoxyethylene hardened castor oil, polyoxyethylene higher alkyl ether (polyoxyethylene lauryl ether, polyoxyethylene oleyl ether), polyoxyethylene higher fatty acid ester, and polyoxyethylene polyoxygen. A nonionic surfactant such as propylene alkyl ether or a higher alkyl amine oxide surfactant such as lauryl amine oxide, stearic acid amine oxide or guanamine propyl dimethyl amine oxide. Further, a stabilizer, a pH adjuster, a colorant or the like may be appropriately blended, or a green leaf alcohol or a green aldehyde such as a "green flavor" may be added to impart a pressure-relieving effect. Further, examples of the gelling agent used for preparing the gel-like body include deer-22-201028089 carrageenan, sanxian gum, garland gum, gelatin, aluminum octoate, and 12-hydroxystearic acid. The insect repellent for rice cylinder of the present invention is preferably one in which the insect repellent composition is impregnated or retained in a solid carrier, and is disposed in a rice cylinder, and the insecticidal component is volatilized from the solid carrier. Examples of the solid carrier include fibrous carriers such as pulp, thread, and enamel, inorganic porous carriers such as phthalate, cerium oxide, and zeolite, and sublimation carriers such as trioxane and adamantane. It is appropriate to receive φ 纳 to enable the carrier. 1~100 mg/cm2 of a cellulosic carrier of montan-3,8-diol in an air permeable container, using an appropriate fixing mechanism to fix the ventilating container inside the lid of the rice cylinder, or buried in the rice, or Place on the surface. The shape or composition of the permeable container is not particularly limited, and for example, a pad holding member may be provided in a switchable rice-shaped ventilating box, and a pulp pad impregnated with the insect-repellent composition may be sandwiched therebetween, or A bag-like ventilating container that contains a paper-impregnated box containing impregnated insect-proof composition mats or beads, or a pulp-impregnated pad containing impregnated insect-repellent composition, such as paper, woven fabric, non-woven fabric, and porous sheet. In the middle. If the insect repellent for the rice cylinder of the present invention thus obtained is provided in the rice cylinder, the pests close to the food such as corn, scorpion, worm, specimen, cockroach, ant, etc., of course, Pests such as cockroaches, cockroaches, larvae, flies, moths, and moths have achieved practical insect control effects for a period of 1 month to 2 months. Next, in the present invention, the montan-3,8-diol used as an insect-repellent component is extremely weak in odor compared with the conventional wasabi, mustard, ginger or pepper, and hardly shifts the odor to the rice, so the utility is practical. Extremely high. The use of the drawings illustrates a specific example of the -23-201028089 which can be used for the escaping pest insect products of the present invention, but the present invention is of course not limited thereto. Fig. 1 to Fig. 4 are diagrams showing a type of escaping pest-repellent product which is placed in a container by impregnating or maintaining a type of escaping pest repellent which is immersed in a solid carrier. The escaping pest-resistant insect product is formed by the composition of the drug-impregnated body 2 (walking pest repellent) containing the agent containing the escaping pest-repellent component from the upper and lower sides of the container 1, and has a thin plate shape as a whole. The container 1 has an opening for evaporating the components of the escaping pest. As described above, by having a thin plate shape, it is possible to easily insert a narrow space of the drawer or the food cabinet, and by placing the chemical impregnated body 2 in the container 1, it is possible to prevent the pests from escaping. The ingredients of the ingredients are directly attached to the hands, food, food, setting places, and the like. The container 1 can be formed of various plastic materials, and the drug-impregnated body 2 (walking pest repellent) can also be impregnated with a drug containing a component that avoids the migrating pests in a carrier such as pulp. Figures 5 to 8 and Figures 9 to 12 show other types of escaping pest insecticide products which are placed in a type of immersed pest repellent which is impregnated or kept away from the stalking pest component in a solid carrier. The state (the shape of the opening portion of the container 1 for evaporating the components of the escaping pests is different). [Embodiment] Next, a method for preventing the odor transfer of the anti-walking pest component of the present invention will be described in more detail based on a specific embodiment. -24- 201028089 Examples 1 to 4 and Comparative Examples 1 and 2 [Filter paper avoidance test] Various immigration pest repellent samples (Examples 1 to 4 and Comparative Examples 1, 2) indicated in Table 1 were impregnated. The filter paper was dried in a volume of 15 cm in diameter. Place 30 pieces of corn or double needle ants in a plastic container (40cm x 60cm), and set the filter paper in the container to cover the filter paper with 8 inlets and exits (diameter 〇. 5 cm) A paper cup of 15 cm in diameter. The filter paper and paper cups of the same size as the sample processing are set as the non-treatment area with the φ sample. The water and the experimental animal feed were placed in the center, and after counting for 8 hours, the number of insects in the two paper cups was counted, and the avoidance rate was calculated according to the following formula. The test was repeated 4 times, and the average is shown in Table 1. Repellent rate (%) = [number of latent insects in no treatment area - number of latent insects in sample processing area] / [number of latent insects in no treatment area + number of latent insects in sample processing area] X 100 Table 1 filter paper avoidance efficacy test Results 趟 pests mm mm (%) 走 性 害 害 害 害 害 其他 其他 其他 其他 其他 其他 其他 其他 其他 g g g 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 玉米 2 _ .  81 91 application 2 to montan-1,8-diol 0. 2 _ cold 73 81 cases 3 to Mengyuan-3,8-diol 0. 2 diethylene glycol monobutyl ether 2. 0 93 98 4 For Mengyuan-1,8-diol 0. 2 1,3-butanediol 2. 0 90 94 to 1 rosemary oil 0. 2 .  37 41 敉 Example 2 Thyme 0. 2 - - 33 36 -25- 201028089 As a result of the test, the migrating pest repellent of the present invention is based on the combination of montane-3,8-diol and/or para-methane-1 as a component of the evading stalking pest. The effect of 8-diol showed that the avoidance effect on corn or double-needle ants was far better than that of the comparative example of rosemary oil or thyme. Further, the avoidance effect is further enhanced by blending a solvent having a boiling point of 160 ° C or higher, particularly a glycol-based or glycol ether-based solvent. In contrast, as shown in Comparative Example 1 and Comparative Example 2, the avoidance effect of rosemary oil or thyme was low. Examples 5 to 19 and Comparative Examples 3 to 7 [Filter paper avoidance test] Various walk-through pest repellent samples (Examples 5 to 19 and Comparative Examples 3 to 7) shown in Table 2 were prepared, and the impregnation amount was 15 cm of filter paper and air dried. In a plastic container (4〇cmx6〇cm), put 15 black male cockroaches (male male, female, and larva) into the container, and set the filter paper in the container at the same time to cover the filter paper with 4 entrances and exits (wide). It is a paper cup of 2 cm in diameter and 2 cm in diameter and 15 cm in diameter. Similarly, a filter paper and a paper cup of the same size as those used for the sample processing were set as a non-treatment area. The water and the experimental animal feed were placed in the center, and the number of turns in the two paper cups after counting for 8 hours was counted. The avoidance rate was calculated according to the following formula. The test was repeated 8 times, and the average is shown in Table 2. Repellent rate (%) = [number of latent insects in no treatment area - number of latent insects in sample processing area] / [number of latent insects in no treatment area + number of latent insects in sample processing area] x 100 -26- 201028089 Table 2 Filter paper The result of the avoidance efficacy test is the evasion rate of the evasive pest repellent (%). The evasive stalking pest component other component component name g/m2 component name g/m2 实5 达 达-3,8-diol 0. 1 _ 53 Application 6 Pairs of metane-3,8-diol 0. 2 68 cases 7 pairs of montan-1,8-diol 0. 1 a _ 51 8 pairs of montan-1,8-diol 0. 2 - _ 65 9 pairs of montan-3,8-diol 0. 2 diethylene glycol monobutyl ether 2. 0 94 10 to montan-1,8-diol 0. 2 1,3-butanediol 2. 5 92 11 to metane-3,8-diol 0. 15 dipropylene glycol monomethyl ether 3. 0 97 to montan-1,8-diol 0. 05 12 to montan-3,8-diol 0. 1 1-methoxy-1,2-propanediol 3. 0 93 Ionone 0. 1 13 pairs of montan-1,8-diol thioxanthene 0. 1 - - 80 (damascone) 0. 1 14 pairs of montan-1,8-diol menthol 0. 1 - - 59 0. 1 15 pairs of Mengyuan-3,8-alcohol 0. 2 lamp oil (boiling point; 170 ° C) 2. 0 84 16 Pair of Mengyuan-1,8-one alcohol 0. 15 diethylene glycol monopropyl ether 5 94 allylantilone 0. 05 17 3-(N-Ethyl-N-butyl) 0. 2 diethylene glycol monobutyl ether 0 81 ethyl alanine propionate 18 picaridin 0. 2 _ • 57 19 Dibutyl succinate 0. 2 59 to 3 menthol 0. 2 a _ 27 is more than 4 terpinen-4-ol 0. 2 one _ 31 cases 5 thyme 0. 2 _ 26 6 Japanese peppermint oil _ _ a 32 7 - - diethylene glycol monobutyl ether 2. 0 8 -27- 201028089 As a result of the test, the migrating pest repellent of the present invention is based on the combination of montane-3,8-diol and/or p-mentane _ 1,8- as a component of the evading walking pest. The action of diol, ethyl 3-(N-ethinyl-N-butyl)lamidopropionate, picaridin and dibutyl succinate showed that the effect of avoiding cockroaches was far better than that of menthol in the comparative example. , terpinen-4-ol (disclosed in Japanese Patent Laid-Open No. Hei 11-60 421), thyme or Japanese peppermint oil. Further, this avoidance effect is greatly enhanced by blending a solvent having a boiling point of 160 °C or higher, particularly a glycolic or glycol ether solvent, as shown in Example 15. Further, it was judged from the comparison between Example 13 and Example 14 that it was effective with the adamantane oxime system, and the tendency was also the same as that of the violet lanolinone or the allylo-ionone. In contrast, as shown in Comparative Example 3 to Comparative Example 7, the evading effect of menthol, terpinen-4-ol, thyme or jasmine oil was low, and the glycol ether solvent used as the potentiator was also used alone. The avoidance effect is almost completely absent. Examples 20 and 21 and Comparative Examples 8 to 10 [Field Evacuation Test] A pulp mat (5 χ 10 cm) impregnated with various escaping pest components was housed in a predetermined volatilization hole (the total area of the surface was 35 cm 2 , a plastic container with a total surface area of 28% in the surface of the container (5. 8 χ 10_8 cm) The various migrating pest repellent samples shown in Table 3 were prepared. The amount of these components to be evaded per 24 hours is shown in Table 3. Place 60 of Germany on a 2 m2 site to allow domestication to freely ingest water and solid feed. Place the anti-aspirator sample and the appropriate amount of solid feed in the plastic container at 201028089, and cover it with a gap (lcm). In addition, containers of the same size are set as unprocessed areas. The evasion rate is calculated according to the following equation by counting 潜 in the container over time. The combined results are shown in Table 3. Repellent rate (%) = [number of latent insects in no treatment area - number of latent insects in sample treatment area] / [number of latent insects in no treatment area + number of latent insects in sample treatment area] x 100 Table 3 Field avoidance efficacy test As a result, the crawling pests are evading! I Volatilization amount (mg/24hr) Repellent rate (%) Avoiding the impregnation amount of the feminine pest component fmg/cm2) After 4 days after Id, after l〇d, Example 20 is treated with montan 3,8- Glycol 8 3 84 71 70 21 to Mentan 1,8-diol 8 4 86 80 70 Comparative Example 8 Eucalyptus oil 50 44 53 43 40 9 Lyme oil 50 62 63 47 43 10 Rosemary oil 40 13 37 33 31 As a result of the test, the immersion pest repellent of the present invention (Examples 20 and 21) impregnated with montan-3,8-diol or p-mentane-1,8-diol was compared with other vanilla-containing components. In comparison, even if the amount of impregnation and the amount of volatilization are small, the high avoidance rate is exhibited, and the odor is hardly felt, so that it is extremely practical. The escaping pest repellent of the comparative example containing eucalyptus oil, thyme oil or rosemary oil is particularly unsuitable for use in the kitchen even if the amount of volatilization is high, the avoidance effect is low, and the odor is too strong. Examples 22, 23 and Comparative Example 11 -29- 201028089 [Synthetic plate avoidance efficacy test]

放置60隻之德國姬蠊於2m2之場地，使馴化可自由 攝取水及固形飼料。調製配合各種趨避走爬性害蟲成分於 液劑’塡充於噴霧瓶，塗佈於2〇X2〇Cm之合成板，成爲 如表4表示之塗佈量（相當於趨避走爬性害蟲成分）。使此 2片合成板處理面朝內成對面，設有間隙（〇.5 cm)，設置於 場地。另外，同樣地設置相同尺寸之無藥劑處理之合成板 作爲無處理區。經時地計數潛伏於合成板內之蜚蠊，依據 下式算出趨避率。合倂結果如表4表示。 趨避率（％)=[無處理區之潛伏蟲數-試料處理區之潛 伏蟲數]/[無處理區之潛伏蟲數+試料處理區之潛伏蟲數]X 100 表4合成板趨避效力試驗之結果 越性害獅 m 塗佈量 (g/m2) mm%) 趨避走爬性害蟲成分 含浸量 (g/100mL) Id後 2d後 3d後 實施例 對孟烷3,8-二醇 5 0.4 88 88 85 對孟烷1，8-一醇 5 0.4 83 88 70 比較例 11 迷迭香油 10 0.4 55 43 40 實施例24 調製含有1.0質量％之對孟烷_3,8_二醇、3.〇質量％之 丙二醇、1.2質量％之月桂基氧化胺、3·0質量％之聚氧乙 烯油基醚、7.0質量％之乙醇、丨·0質量％之作爲除臭劑之 綠茶萃取物、0.02胃量％之檸檬酸、及83.78質量。/〇之精 -30- 201028089 製水之本發明之走爬性害蟲趨避劑（實施例24)。另外，此 水性之趨避劑係符合消防法上之非危險物。 塡充130g之本發明之走爬性害蟲趨避劑於透明聚酯 容器本體中，於該上方開口部，蓋上插通外徑爲7mm之 棒狀毛氈製吸液芯之中栓。設置蒸發部支持體，安裝厚度 爲5mm，直徑爲5.2cm之圓盤狀毛氈製蒸發部，使接觸吸 液芯頂面，製作放置型防蟲具。 φ 放置此防蟲具於廚房使用時，未感到強烈臭味，經過 約2個月，亦無蜚蠊徘徊的煩惱。 實施例2 5 加入含有2.0質量％之對孟烷-1,8-二醇、40質量％之 二乙二醇單丁醚、0.05質量％之作爲安定劑之二丁基羥甲 苯、及57.95質量％之精製水，調製液狀之本發明之走爬 性害蟲趨避劑（實施例25)。 〇 塡充此45mL於聚丙烯容器本體後，裝塡中栓、無機 物煅燒吸液芯，以加熱器溫度1 〇〇°C加熱蒸發，適用所謂 液體電蚊香型防蟲具。 此防蟲具係與實施例22、23同樣地顯示對蜚蠊或屋 內塵蟎類等走爬性害蟲優異的趨避效果。 實施例26 調製15質量％之對孟烷-1,8-二醇、25質量％之紫羅 蘭酮（ionone)、60質量％之燈油（沸點爲170°C )而成之液 -31 - 201028089 劑，含浸此l.Og於由聚酯及聚丙烯之多層結構而成之不 織布（50cmx50cm)，製作薄片狀之本發明之走爬性害蟲趨 避劑（實施例26)。使用此走爬性害蟲趨避劑作爲寵物放餌 處之下墊物時，約1個月於放餌處附近未見到蜚蠊、嚙蟲 或蟻類之徘徊，可保持舒適環境。 實施例27 調製30質量％之對孟烷-3,8 -二醇、30質量％之右旋 A 烯炔菊酯（empenthrin)、40質量％之1,3-丁二醇所成之液 劑。保持此〇.6g於具有通氣性之外徑爲4.0cm之尼龍製 載體，收納於聚碳酸酯製之保護盒（外徑爲4.5 cm，厚度爲 8 mm)中，製作本發明之走爬性害蟲趨避劑（實施例27)。 接著，適用於安裝此保護盒於旋轉驅動裝置之旋轉 軸，藉由旋轉驅動裝置（旋轉速度：1200rpm)旋轉，以離 心力揮發趨避成分之所謂的旋轉型防蟲裝置。此防蟲裝置 係與實施例22、23同樣地顯示對蜚蠊或屋內塵蟎類等走 @ 爬性害蟲優異的趨避效果。 實施例2 8 於大小爲5x10 cm，厚度爲1mm之軋毛機製墊，使含 有200mg之對孟烷-3,8-二醇及5mg之綠茶萃取物，收納 此墊於具有開口部（孔的總面積係相對於容器總表面積之 2 5%)之聚酯製容器（5.8x10.8cm)，調製本發明之走爬性害 蟲趨避劑（實施例28)。 -32- 201028089 放置此走爬性害蟲趨避劑於蔚房之食器櫃或米缸附近 使用時，約經1個月，於廚房未發現蜚蠊、蟻類、嚙蟲、 標本蟲、玉米象等。 實施例2 9 將依據實施例28調製之走爬性害蟲趨避劑，放入於 食器、放入食品（麵線）之抽屜中，以關閉抽屜之狀態，放 φ 置10天後，去除走爬性害蟲趨避劑，對於何種程度的臭 味轉移於抽屜中的食器及食品（麵線），由10人監測員進 行官能試驗。 該結果係如表5所示，食器及食品（麵線）中任一種， 臭味是否轉移或不在意程度之結果。 表5 趨避走爬性 害蟲成分 物品 官 能試驗 強烈臭味 轉移 微弱臭味 轉移 雖有些許臭味轉移， 但爲不在意之程度 臭味 未轉移 實 施 例 對二院-3,8-二醇 食器 0 0 0 10 食品 (_) 0 0 2 8 比 較 例 迷迭香油 食器 5 4 1 0 食品 9 1 0 0 實施例30:對害蟲及人類嗅覺之感應試驗 1 .試驗方法 使用圖13表示之試驗裝置進行試驗。 - 33 - 201028089 含浸稀釋試驗藥劑成一定濃度之丙酮溶液於濾紙（1.0 xl.Ocm)後風乾成爲試驗濾紙（圖13中，符號5)。於試管 (0 2 0mmx2 0cm)(圖13中，符號3)底部，放入附著德國 姬蠊糞之濾紙（0_5x0.5cm)(圖13中，符號6)及試驗濾 紙，放入10隻德國姬蠊年輕成蟲，以脫脂棉（圖13中， 符號4)加蓋。橫放試管靜置，觀察1晚後之蜚蠊分布及 有無氣味。趨避效果係算出試驗濾紙附近之蜚蠊分布比， 比較效果。 另外，以試驗減紙附近爲位置A(圖14中，符號8)， 除此以外爲位置B(圖14中’符號7)，臭味係依感應分爲 4個階段。 分布比=位置A之蜚蠊數/(位置A之蜚蛛數+位置B 之蜚蠊數） 試驗結果總括於表6。Place 60 pieces of German cockroach on the site of 2m2, so that domestication can freely take in water and solid feed. Modulation and various anti-walking pest components are applied to the spray bottle and applied to a synthetic plate of 2〇X2〇Cm to form a coating amount as shown in Table 4 (corresponding to the anti-walking pest component) . The two synthetic plates were placed face to face opposite each other with a gap (〇.5 cm) placed at the site. Further, a chemical-free composite plate of the same size was similarly provided as a non-treatment zone. The enthalpy of the latent in the composite plate was counted over time, and the avoidance rate was calculated according to the following formula. The combined results are shown in Table 4. Recession rate (%) = [number of latent insects in no treatment area - number of latent insects in sample treatment area] / [number of latent insects in no treatment area + number of latent insects in sample treatment area] X 100 Table 4 The result is the more lion m coating amount (g/m2) mm%) The leaching amount of the pest component (g/100mL) after Id 2d after 2d, the example to the dansane 3,8-diol 5 0.4 88 88 85 to Mentan 1,8-alcohol 5 0.4 83 88 70 Comparative Example 11 Rosemary oil 10 0.4 55 43 40 Example 24 Preparation of 1.0% by mass of p-mentane-3,8-diol, 3. 〇% by mass of propylene glycol, 1.2% by mass of laurylamine oxide, 3.0% by mass of polyoxyethylene oleyl ether, 7.0% by mass of ethanol, 丨·0% by mass of green tea extract as a deodorant, 0.02 The amount of stomach is citric acid, and 83.78 mass. / 〇之精 -30- 201028089 The water-resistant pest repellent of the present invention (Example 24). In addition, the water repellent is in compliance with non-hazardous materials in the fire protection law. 130 g of the climbing pest insect repellent of the present invention was placed in a transparent polyester container body, and a plug of a rod-shaped felt wick having an outer diameter of 7 mm was inserted into the upper opening. The evaporating portion support was placed, and a disc-shaped felt evaporation portion having a thickness of 5 mm and a diameter of 5.2 cm was attached to make contact with the top surface of the wick to prepare a placement type insect repellent. φ When this insect-proof device is placed in the kitchen, it does not feel strong odor. After about 2 months, there is no trouble. Example 2 5 Dibutyl hydroxytoluene containing 2.0% by mass of p-menthan-1,8-diol, 40% by mass of diethylene glycol monobutyl ether, 0.05% by mass as a stabilizer, and 57.95 mass % of purified water to prepare a liquid-like walking pest repellent of the present invention (Example 25).塡 After filling this 45mL in the polypropylene container body, the plug and the inorganic material are used to calcine the wick, and the heater is heated and evaporated at a temperature of 1 〇〇 °C. The so-called liquid electric mosquito-repellent insect-proof tool is applied. In the same manner as in Examples 22 and 23, this insect-resistant article exhibited an excellent avoidance effect against climbing pests such as cockroaches or house dust mites. Example 26 A liquid obtained by preparing 15% by mass of a pentamane-1,8-diol, 25% by mass of ionone, and 60% by mass of a lamp oil (boiling point of 170 ° C) - 31 - 201028089 The woven fabric (50 cm x 50 cm) made of a multilayer structure of polyester and polypropylene was impregnated to prepare a flank-like pest repellent of the present invention (Example 26). When this escaping pest repellent is used as a cushion under the pet bait, the cockroach, the worm or the ant is not seen near the bait for about one month, and the comfortable environment can be maintained. Example 27 A 30% by mass solution of montan-3,8-diol, 30% by mass of dextromethrin (empenthrin) and 40% by mass of 1,3-butanediol was prepared. . The crucible of the present invention was prepared by holding a nylon carrier having a ventilating outer diameter of 4.0 cm and storing it in a protective case made of polycarbonate (outer diameter: 4.5 cm, thickness: 8 mm). Pesticide repellent (Example 27). Next, it is applied to a so-called rotary insect-proof device in which the protective case is attached to the rotary shaft of the rotary drive device and rotated by a rotary drive device (rotation speed: 1200 rpm) to circulate the escape component with the centrifugal force. In the same manner as in Examples 22 and 23, the insect-repellent device showed an excellent avoidance effect against the crawling pests such as cockroaches or house dust mites. Example 2 8 A pulverized mechanical pad having a size of 5×10 cm and a thickness of 1 mm was used to contain 200 mg of montane-3,8-diol and 5 mg of green tea extract, and the pad was placed in an opening (pore) A polyester container (5.8 x 10.8 cm) having a total area of 25% by weight relative to the total surface area of the container was used to prepare the migrating pest repellent of the present invention (Example 28). -32- 201028089 When using this walking pest repellent in the vicinity of Weifang's food cabinet or rice cylinder, after about 1 month, no cockroaches, ants, worms, specimens, corn elephants, etc. were found in the kitchen. . Example 2 9 The migrating pest repellent prepared according to Example 28 was placed in a drawer of a food container and placed in a food (top line) to close the state of the drawer, and after being placed for 10 days, the crawling was removed. The sex pest repellent, for which degree of odor is transferred to the food and food (face line) in the drawer, a 10-person monitor performs a functional test. The results are shown in Table 5, and any of the food and food (top line), whether the odor is transferred or not concerned. Table 5: Avoiding the stalking pests, the components, the functional test, the strong odor transfer, the weak odor transfer, although there is a slight odor transfer, but the degree of odor is not transferred to the case of the second hospital-3,8-diol eater 0 0 0 10 Food (_) 0 0 2 8 Comparative rosemary oil 5 4 1 0 Food 9 1 0 0 Example 30: Induction test for pests and human sense of smell 1. Test method using the test device shown in Figure 13 test. - 33 - 201028089 Immersion dilution test agent A certain concentration of acetone solution was air-dried into filter paper (1.0 x l.Ocm) to become test filter paper (symbol 5 in Fig. 13). At the bottom of the test tube (0 2 0mmx2 0cm) (symbol 3 in Figure 13,), put the filter paper (0_5x0.5cm) (Fig. 13, symbol 6) attached to the German cockroach dung and the test filter paper into 10 German jiji. Young adult worms are covered with absorbent cotton (symbol 4 in Figure 13, symbol). The tube was placed horizontally and allowed to stand for observation after 1 night. The avoidance effect is to calculate the ratio of the enthalpy distribution in the vicinity of the test filter paper, and compare the effects. Further, the vicinity of the test paper is the position A (symbol 8 in Fig. 14), and the position B (symbol 7 in Fig. 14) is used, and the odor is divided into four stages according to the induction. Distribution ratio = number of turns of position A / (number of spiders at position A + number of turns of position B) The test results are summarized in Table 6.

-34- 201028089 表6-34- 201028089 Table 6

試驗藥劑 藥量(mg) [1.0x1.0cm 濾紙] 平均 分布比 效果 判定 臭味強度 對孟院-3，8-二醇 10 0 ◎ -〜+ 1 0 ◎ - 0.1 0.30 〇 - 0.01 0.70 Δ - 3-(N-乙醯-N-丁基) 10 0 ◎ -〜+ 胺基丙酸乙酯 1 0.20 〇 - 0.1 0.70 △ - 0.01 0.90 X - picaridin 10 0 ◎ -〜+ 1 0.25 〇 - 0.1 0.65 Δ - 0.01 0.85 X - 癸二酸二乙酯 10 0 ◎ 1 0.15 〇 - 0.1 0.60 Δ - 0.01 0.75 X 迷迭香 10 0 ◎ +-H- 1 0.15 〇 ++ 0.1 0.65 Δ ++ 0.01 0.80 X + 香茅油 10 0 ◎ +++ 1 0.10 〇 -H-+ 0.1 0.50 △ ++ 0.01 0.75 X + 紫蘇醛 10 0 ◎ -HH- 1 0.20 〇 -H-+ 0.1 0.75 X ++ 0.01 1.00 X + 蔽品嫌-4-醇 10 0 ◎ ++ 1 0.15 〇 ++ 0.1 0.90 X + 0.01 1.00 X - 效果之判定：◎ : 〇、〇：0.01 〜0.30、△ : 0.31 〜0.70、x : 0.71 〜1.00 臭味區分：-:無臭味、+ :些微臭味、++ :明顯的臭味、+++ :強烈臭味 -35- 201028089 試驗結果，對孟烷-3, 8-二醇揮發於空間時，以人類幾 乎未感到臭味之濃度，顯示對蜚蠊之高趨避效果。亦即， 實際證明對孟烷-3,8-二醇係對害蟲嗅覺的敏感度高，對人 類嗅覺的敏感度低之化合物。 對照上，揮發性之迷迭香油、香茅油、紫蘇醛及萜品 烯-4-醇（對照組），以認可趨避效果之濃度，對人類亦呈現 強烈臭味，並且，視爲對害蟲及人類嗅覺之敏感度差異小Test drug dose (mg) [1.0x1.0cm filter paper] Average distribution ratio effect to determine odor intensity on Mengyuan-3,8-diol 10 0 ◎ -~+ 1 0 ◎ - 0.1 0.30 〇- 0.01 0.70 Δ - 3-(N-acetonitrile-N-butyl) 10 0 ◎ -~+ Aminopropionate 1 0.20 〇- 0.1 0.70 △ - 0.01 0.90 X - picaridin 10 0 ◎ -~+ 1 0.25 〇- 0.1 0.65 Δ - 0.01 0.85 X - Diethyl sebacate 10 0 ◎ 1 0.15 〇- 0.1 0.60 Δ - 0.01 0.75 X Rosemary 10 0 ◎ +-H- 1 0.15 〇++ 0.1 0.65 Δ ++ 0.01 0.80 X + Citronella oil 10 0 ◎ +++ 1 0.10 〇-H-+ 0.1 0.50 △ ++ 0.01 0.75 X + perillaldehyde 10 0 ◎ -HH- 1 0.20 〇-H-+ 0.1 0.75 X ++ 0.01 1.00 X +嫌-4-ol 10 0 ◎ ++ 1 0.15 〇++ 0.1 0.90 X + 0.01 1.00 X - Determination of effect: ◎ : 〇, 〇: 0.01 ~ 0.30, △: 0.31 ~ 0.70, x: 0.71 ~ 1.00 stinky Taste distinction: -: no odor, +: some slight odor, ++: obvious odor, +++: strong odor -35- 201028089 test results, volatilization of montan-3, 8-diol in space When humans barely felt Ajinomoto concentration, exhibits a high aversion effect on the cockroaches. That is, a compound which is highly sensitive to the olfactory sense of pests of the montan-3,8-diol system and has low sensitivity to human sense of smell is actually proved. In contrast, volatile rosemary oil, citronella oil, perillaldehyde and terpinen-4-ol (control group), in recognition of the concentration of the avoidance effect, also showed strong odor to humans, and was regarded as pests. And the sensitivity difference of human sense of smell is small

的化合物群。 I ❹ 另外，認爲3-(N-乙醯基-N-丁基）胺基丙酸乙酯、 ?4^丨心11及癸二酸二乙酯係位於對孟烷-3,8-二醇及對照 組間，對人類嗅覺的敏感度低，另一方面，對蜚蠊之趨避 效果係略遜於對孟烷-3,8-二醇之趨勢。 另外，確認德國姬蠊以外之其他蜚蠊（黑胸大蠊、美 洲蜚蠊、日本大蠊、棕色蜚蠊、京都亞蠊等）亦具有與上 述試驗相同的敏感性。 至今，於開發空間趨避劑，雖重視揮發性因素，但本 @ 發明係基於搜尋對害蟲嗅覺之敏感度高，另一方面，對人 類嗅覺之敏感度低之化合物及開發該有效的適用方法爲技 術思想，明顯的新穎構想者。 實施例3 1 於約3g之之纖維素製珠粒，使含有210mg之 對孟烷-3,8-二醇、6mg之綠茶萃取物、及20mg之燈油（脂 肪族烴系溶劑），收納此珠粒於黏合具有通氣性之聚酯製 -36- 201028089 不織布及設有許多Φ lmm之小孔之塑膠薄膜而成的袋子（5 xlO cm)(米缸上蓋裏面附有固定用之雙面膠帶），調製本發 明之米缸用防蟲劑（實施例3 1 )。 固定此米缸用防蟲劑於米缸（容量：10L)之上蓋裏面 使用時，經過約1個月，於米缸內未發現玉米象、鰹節 蟲、嚙蟲、標本蟲、蜚蠊等。 實施例32至34及比較例12至16 :殺蟲效力試驗 依據實施例31(但是取代約3g之φ 2mm之纖維素製 珠粒，使用大小爲3x7 cm，厚度爲lmm之軋毛機製墊）， 調製表7表示之各種米缸用防蟲劑，放入容器約爲6L之 密閉容器中。放入各30隻之玉米象及標本蟲成蟲，求出 7天後之致死率如表7。 表7 念缸用防蟲劑 致死率(％) 對孟院-3,8-二醇 其他成分 玉米象 標本蟲 mg/6L mg/cm2 成分名 mg/6L mg/cm2 實 施 例 32 210 10 綠茶萃取物 6 0.3 100 55 33 210 10 柿萃取物 12 0.6 100 67 34 210 10 - 100 38 比 較 例 12 Mayol 210 10 - • 釋 30 10 13 百里香210 10 - _ • 30 20 14 山葵成分配合米缸用防蟲劑 80 25 15 辣椒成分配合米缸用防蟲劑 60 35 16 無藥劑 20 0 -37- 201028089 試驗結果，本發明之米缸用防蟲劑係基於配合作爲防 蟲成分之對孟烷-3,8 -二醇之作用，對玉米象或標本蟲之趨 避效果明顯比傳統的山葵成分或辣椒成分，顯示優異的殺 蟲效力，認爲加入對孟烷-3,8-二醇之高趨避效果時，作爲 靠近食品之害蟲的防蟲劑之實用性高。另外，藉由配合綠 茶萃取物或柿萃取物之來自植物之除臭成分，殺蟲效力明 顯提升。 進而，任一種皆對火氣之危險性低，就使用性面上亦 Λ 優異者。 對此，如比較例表示，同樣爲萜烯系化合物之 Mayol、或作爲趨避成分之一般的百里香係該殺蟲效力 低，並且臭味強，不適合作爲米缸用防蟲劑之防蟲成分。 實施例35至37及比較例17、18:臭味轉移試驗 放入米於米缸（容量：10 L)中，並且放置依據實施例 32至34調製之米缸用防蟲劑。5天後，去除米缸用防蟲 ❹ 劑’對於何種程度的臭味轉移於該周圍的米，由1〇人監 測員進行官能試驗。該結果如表8所示。 -38- 201028089 表8 米缸用防蟲劑 官能試驗 防蟲成分 其他 成分 強烈臭味 轉移 微弱臭味 轉移 雖有些許臭味轉移， 但爲不在意之程度 臭味 未轉移 實 施 例 35 對孟院·3,8-二醇 綠茶 萃取物 0 0 0 10 36 對孟垸-3,8- 二醇 柿 萃取物 0 0 0 10 37 對孟院-3,8-二醇 - 0 0 2 8 比 較 例 17 山葵成分配合米缸用 防蟲劑 7 3 0 0 18 辣椒成分配合米缸用 防蟲劑 5 4 1 0 試驗的結果，以來自天然的對孟烷-3,8-二醇作爲防蟲 成分之本發明之米缸用防蟲劑係臭味不轉移於米，而且對 人畜的毒性非常低，所以該實用性極高。 另一方面，山葵成分或辣椒成分係因爲臭味強，所以 不能避免臭味轉移於米，並且具有對人有刺激之缺點。 實施例3 8 :確認對玉米象之趨避效果試驗 1.試驗方法 使用圖14表示之試驗裝置進行試驗。 含浸稀釋試驗藥劑成一定濃度之丙酮溶液於濾紙（1.0 xl.0cm)後風乾成爲試驗濾紙（圖14中，符號5)。於試管 (Ψ 20mmx20cm)(圖14中，符號3)底部，放入10顆胚芽 米（圖14中，符號9)及試驗濾紙，放入試驗昆蟲（玉米象 -39- 201028089 成蟲10隻/區），以脫脂棉（圖14中，符號4)加蓋。橫放 試管靜置，觀察3小時後之玉米象分布及有無氣味。趨避 效果係算出試驗濾紙附近之蜚蠊分布比，比較效果。 另外，以試驗濾紙附近爲位置A(圖14中，符號8)， 除此以外爲位置B(圖14中，符號7)，臭味係依感應分爲 4個階段。 分布比=位置A之蜚蠊數/(位置A之蜚蠊數+位置B 之蜚蠊數） 試驗結果總括於表9。 表9Group of compounds. I ❹ In addition, it is considered that ethyl 3-(N-ethinyl-N-butyl)aminopropionate, ?4^丨心11 and diethyl sebacate are located in the paraben-3,8- Between the diol and the control group, the sensitivity to human olfaction is low. On the other hand, the evasive effect on cockroaches is slightly inferior to the trend of montane-3,8-diol. In addition, it is confirmed that other cockroaches other than German cockroach (Black-breasted cockroach, American cockroach, Japanese cockroach, brown cockroach, Kyoto Aachen, etc.) have the same sensitivity as the above test. So far, in the development of space avoidance agents, although the importance of volatility factors, this @ invention is based on the search for high sensitivity to pest odor, on the other hand, compounds that are less sensitive to human olfaction and the application of this effective method is Technical ideas, obvious novel ideas. Example 3 1 Into about 3 g of cellulose beads, 210 mg of p-mentane-3,8-diol, 6 mg of green tea extract, and 20 mg of kerosene (aliphatic hydrocarbon solvent) were contained therein. The beads are bonded to the air-permeable polyester-36- 201028089 non-woven fabric and a bag with a plastic film with many small holes of Φ lmm (5 x lO cm) (the double-sided tape is fixed inside the upper cover of the rice cylinder) The insect repellent for the rice cylinder of the present invention was prepared (Example 31). When the rice tank was fixed with a pest control agent on the top of the rice tank (capacity: 10L), after about one month, no corn elephant, cockroach, worm, specimen, or cockroach was found in the rice tank. Examples 32 to 34 and Comparative Examples 12 to 16: Insecticidal efficacy test According to Example 31 (but replacing about 3 g of φ 2 mm cellulose beads, using a 3 x 7 cm, 1 mm thick rolling mechanism mat) The various insect-repellent agents for the rice cylinders shown in Table 7 were placed in a closed container of about 6 L in a container. Each of the 30 corn elephants and the adult insects were placed, and the lethality after 7 days was determined as shown in Table 7. Table 7 Mortality rate of insecticides in the tank (%) To the other plants, Mengyuan-3,8-diol other components of corn elephant specimens mg/6L mg/cm2 component name mg/6L mg/cm2 Example 32 210 10 Green tea extract 6 6 100 55 33 210 10 Persimmon extract 12 0.6 100 67 34 210 10 - 100 38 Comparative Example 12 Mayol 210 10 - • Release 30 10 13 Thyme 210 10 - _ • 30 20 14 Wasabi ingredients with rice tanks for pest control Agent 80 25 15 Ingredients for peppers and insecticides for rice cylinders 60 35 16 No medicament 20 0 -37- 201028089 As a result of the test, the insect repellent for rice tanks of the present invention is based on the blending of montan-3 as an insect-repellent component. The effect of 8-diol on the avoidance of corn or specimens is significantly better than that of traditional wasabi or capsicum components. It shows excellent insecticidal efficacy and is considered to have a high avoidance effect on montan-3,8-diol. At the time, it is highly practical as an insecticide close to food pests. In addition, the insecticidal effect is markedly enhanced by the deodorant component derived from the plant in combination with the green tea extract or the persimmon extract. Furthermore, any one of them has a low risk of fire and is also excellent in the use surface. On the other hand, as shown in the comparative example, Mayol, which is also a terpene-based compound, or a general thyme which is a component of avoidance, has low insecticidal efficacy and strong odor, and is not suitable as an insect-repellent component for insecticides for rice cylinders. Examples 35 to 37 and Comparative Examples 17, 18: Odor transfer test A rice seed tank (capacity: 10 L) was placed, and an insect repellent for a rice tank prepared in accordance with Examples 32 to 34 was placed. After 5 days, the insecticide removal agent for the rice cylinder was removed. To what extent the odor was transferred to the surrounding rice, a sensory test was carried out by a monitor. The results are shown in Table 8. -38- 201028089 Table 8 Insecticides for rice cylinders Tests for insecticides Other ingredients Strong odor transfer Weak odor transfer Although there is some odor transfer, but the degree of odor is not transferred to the case of Example 35 ·3,8-diol green tea extract 0 0 0 10 36 Pair of Mengqi-3,8-diol persimmon extract 0 0 0 10 37 Pair Mengyuan-3,8-diol- 0 0 2 8 Comparative example 17 Wasabi ingredients combined with insecticides for rice tanks 7 3 0 0 18 The ingredients of peppers combined with insecticides for rice tanks 5 4 1 0, with natural paraben-3,8-diol as insect-repellent ingredient The pest control agent for the rice cylinder of the present invention does not transfer to rice, and the toxicity to humans and animals is extremely low, so the utility is extremely high. On the other hand, the wasabi component or the capsicum component is strong in odor, so that the odor is not prevented from shifting to rice, and it has the disadvantage of being irritating to humans. Example 3 8: Confirmation of the avoidance effect test on corn image 1. Test method The test apparatus shown in Fig. 14 was used for the test. The impregnation dilution test agent was dissolved in a filter paper (1.0 x 1.0 cm) to a test filter paper (symbol 5 in Fig. 14). In the bottom of the test tube (Ψ 20mm x 20cm) (symbol 3 in Figure 14,), put 10 germ rice (Figure 9, symbol 9) and test filter paper into the test insect (corn elephant -39- 201028089 adult 10 / district) ), covered with absorbent cotton (symbol 4 in Figure 14,). The test tube was placed horizontally and the corn image distribution and odorlessness were observed after 3 hours. The avoidance effect is to calculate the 蜚蠊 distribution ratio near the test filter paper and compare the effects. Further, the vicinity of the test filter paper is the position A (symbol 8 in Fig. 14), and the position B (symbol 7 in Fig. 14) is used, and the odor is divided into four stages according to the induction. Distribution ratio = number of turns of position A / (number of turns of position A + number of turns of position B) The test results are summarized in Table 9. Table 9

試驗藥劑 藥量(mg) [1.0x1.0cm 濾紙] 平均 分布比 效果 判定 臭味 強度 對孟烷-3,8-二醇 10 0.30 〇 - 0.1 0.70 △ - 實 picaridin 1 0.50 Δ - 施 0.1 0.80 X - 例 3-(N-乙醯基-N-丁基) 1 0.40 Δ 胺基丙酸乙酯 0.1 0.80 X - (IR 3535) Tabutrex 1 0.50 Δ - (琥珀酸二丁酯） 0.1 0.80 X - 萜品烯斗醇 1 0.40 △ -H- 0.1 0.80 X + 參 迷迭香油 1 0.40 △ -HH- 考 0.1 0.70 X + 例 香茅油 1 0.50 △ -HH- 0.1 0.70 X -H- 紫蘇醛 1 0.50 △ +++ 0.1 J 0.90 X 效果之判定：◎ : 〇·〇〇、〇：〇·01 〜0·30、△ : 〇·31 〜0·70、X : 〇·71 〜L00 臭味區分：-:無臭味、+ ··些微臭味、:明顯的臭味、:強烈臭味 -40 - 201028089 產業上利用性 本發明係於防治走爬性害蟲領域，應可利用。 【圖式簡單說明】 [圖1]本發明所使用之趨避走爬性害蟲製品之一種型 態之正面圖。 φ [圖2]圖1所示之趨避走爬性害蟲製品之背面圖。 [圖3]圖1所示之趨避走爬性害蟲製品之A_A’線斷面 圖。 [圖4]圖1所示之趨避走爬性害蟲製品之斜視圖。 [圖5]本發明所使用之趨避走爬性害蟲製品之其他型 態之正面圖。 [圖6]圖5所示之趨避走爬性害蟲製品之背面圖。 [圖7]圖5所示之趨避走爬性害蟲製品之A_A’線斷面 ❶ 圖。 [圖8 ]圖5所示之趨避走爬性害蟲製品之斜視圖。 [圖9]本發明所使用之趨避走爬性害蟲製品之其他型 態之正面圖。 [圖10]圖9所示之趨避走爬性害蟲製品之背面圖。 [圖11]圖9所示之趨避走爬性害蟲製品之a-A，線斷 面圖。 [圖12]圖9所示之趨避走爬性害蟲製品之斜視圖。 [圖13]表示實施例30使用之試驗裝置圖。 -41 - 201028089 [圖14]表示實施例38使用之試驗裝置圖。 【主要元件符號說明】 1 :容器 2 :藥劑含浸體 3 :試管 4 :脫脂棉 5 :試驗濾紙（1.0x1 .Ocm) 6 :糞附著濾紙（0.5x0.5cm)Test drug dose (mg) [1.0x1.0cm filter paper] Average distribution ratio effect to determine odor intensity to montan-3,8-diol 10 0.30 〇- 0.1 0.70 △ - real picaridin 1 0.50 Δ - apply 0.1 0.80 X - Example 3-(N-Ethyl-N-butyl) 1 0.40 Δ Ethyl propyl acrylate 0.1 0.80 X - (IR 3535) Tabutrex 1 0.50 Δ - (dibutyl succinate) 0.1 0.80 X - 萜Pinnadol 1 0.40 △ -H- 0.1 0.80 X + Rosemary oil 1 0.40 △ -HH- test 0.1 0.70 X + case citronella oil 1 0.50 △ -HH- 0.1 0.70 X -H- perillaldehyde 1 0.50 △ +++ 0.1 J 0.90 X Judgment of effect: ◎ : 〇·〇〇, 〇:〇·01 ～0·30, △: 〇·31 ～0·70, X: 〇·71 ～L00 Odor difference:- : No odor, + · · slightly odor, obvious odor, strong odor -40 - 201028089 Industrial Applicability The present invention is applicable to the field of controlling stalking pests and should be available. BRIEF DESCRIPTION OF THE DRAWINGS [Fig. 1] A front view of a type of anti-walking pest product used in the present invention. φ [Fig. 2] Rear view of the anti-walking pest product shown in Fig. 1. Fig. 3 is a cross-sectional view of the A_A' line of the anti-walking pest product shown in Fig. 1. Fig. 4 is a perspective view of the anti-walking pest product shown in Fig. 1. Fig. 5 is a front elevational view showing other types of escaping pest products used in the present invention. Fig. 6 is a rear view of the anti-walking pest product shown in Fig. 5. Fig. 7 is a cross-sectional view of the A_A' line of the escaping pest-resistant product shown in Fig. 5. [Fig. 8] A perspective view of the anti-walking pest product shown in Fig. 5. Fig. 9 is a front elevational view showing other types of escaping pest products used in the present invention. Fig. 10 is a rear view of the anti-walking pest product shown in Fig. 9. [Fig. 11] A-A, line cross-sectional view of the anti-walking pest product shown in Fig. 9. Fig. 12 is a perspective view of the anti-walking pest product shown in Fig. 9. Fig. 13 is a view showing a test apparatus used in Example 30. -41 - 201028089 [Fig. 14] A diagram showing a test apparatus used in Example 38. [Main component symbol description] 1 : Container 2 : Chemical impregnated body 3 : Test tube 4 : Cotton wool 5 : Test filter paper (1.0x1 .Ocm) 6 : Fecal adhesion filter paper (0.5x0.5cm)

7 :位置B 8 :位置A(濾紙附近） 9 :米10顆7 : Position B 8 : Position A (near filter paper) 9 : 10 meters

-42--42-

Claims (1)

201028089 七、申請專利範園 1. 一種防止趨避走爬性害蟲成分之臭味轉移於所適 用之場所或物品的方法，其特徵係於走爬性害蟲會徘徊的 場所或有徘徊之虞的場所、或走爬性害蟲會靠近的物品或 有靠近之虞的物品，抑制走爬性害蟲徘徊或靠近時， 將含有難以轉移臭味的趨避走爬性害蟲成分之走爬性 害蟲趨避劑，適用於走爬性害蟲會徘徊或有徘徊之虞的場 φ 所或其附近、或走爬性害蟲會靠近或有靠近之虞的物品或 其附近。 2· —種防止趨避走爬性害蟲成分之臭味轉移於所設 置之場所或物品的方法，其特徵係於走爬性害蟲會徘徊的 場所或有徘徊之虞的場所、或走爬性害蟲會靠近的物品或 有靠近之虞的物品，抑制走爬性害蟲徘徊或靠近時， 將含有難以轉移臭味的趨避走爬性害蟲成分之走爬性 害蟲趨避製品，設置於走爬性害蟲會徘徊或有徘徊之虞的 場所或其附近、或走爬性害蟲會靠近或有靠近之虞的物品 或其附近。 3. 如申請專利範圍第2項之防止趨避走爬性害蟲成 分之臭味轉移的方法，其中趨避走爬性害蟲製品係具備同 時載持難以轉移臭味的趨避走爬性害蟲成分及該溶解液或 分散液於纖維質載體者而成。 4. 如申請專利範圍第1項至第3項中任一項之防止 趨避走爬性害蟲成分之臭味轉移的方法，其中上述難以轉 移臭味的趨避走爬性害蟲成分係對害蟲嗅覺的敏感度高’ -43- 201028089 對人類嗅覺的敏感度低之化合物。 5. 如申請專利範圍第1項至第4項中任一項之方 法，其中作爲上述難以轉移臭味的趨避走爬性害蟲成分係 使用對孟烷-3,8-二醇、對孟烷-1,8-二醇、3-(N-乙醯基-N-丁基）胺基丙酸乙酯、picaridin(l-哌啶羧酸2-(2-羥乙基）· 1-甲基丙酯）、2-乙基-1,3-己二醇、草酸二乙酯、丙二酸 二甲酯、丙二酸二乙酯、琥珀酸二甲酯、琥珀酸二乙酯、 琥珀酸二丙酯、琥珀酸二丁酯、戊二酸二甲酯、己二酸二 q 乙酯、己二酸二丙酯、己二酸二丁酯、癸二酸二乙酯、癸 二酸二丙酯、癸二酸二丁酯、苯二甲酸二甲酯、苯二甲酸 二丁酯、苯二甲酸二戊酯、馬來酸二丁酯、富馬酸二丁酯 或此等之混合物。 6. 如申請專利範圍第5項之方法，其中作爲上述難 以轉移臭味的趨避走爬性害蟲成分係使用對孟烷-3,8-二 醇、對孟烷-1,8-二醇、3-(N-乙醯基-N-丁基）胺基丙酸乙 酯、picaridin(l-哌啶羧酸2-(2-羥乙基）-1-甲基丙酯）、2- q 乙基-1,3-己二醇或此等之混合物。 7. 如申請專利範圍第6項之方法，其中作爲上述難 以轉移臭味的趨避走爬性害蟲成分係使用對孟烷-3,8-二 醇、對孟烷-1，8-二醇、3-(N-乙醯基-N-丁基）胺基丙酸乙 酯、picaridin(l-哌啶羧酸2-(2-羥乙基）-1-甲基丙酯）或此 等之混合物。 8. 如申請專利範圍第7項之方法，其中作爲上述難 以轉移臭味的趨避走爬性害蟲成分係使用對孟烷-3，8-二 -44 - 201028089 醇、對孟烷-1，8-二醇或此等之混合物。 9. 如申請專利範圍第2項之方法，其中將含對孟烷-3,8-二醇爲難以轉移臭味的趨避走爬性害蟲成分之趨避走 爬性害蟲製品，設置於走爬性害蟲會徘徊或有徘徊之虞的 物品之米缸內。 10. 如申請專利範圍第9項之方法，其中上述對孟 烷-3,8-二醇之使用量係相對於米缸容量爲 0.02〜 φ 1 .Og/1 0L。 1 1. 一種趨避走爬性害蟲製品，其特徵係於申請專利 範圍第9項或第10項之方法所使用。 12. 如申請專利範圍第 Π項之趨避走爬性害蟲製 品，其同時含上述對孟烷-3，8-二醇及來自植物之除臭成 分。 13. 如申請專利範圍第11項或第12項之趨避走爬性 害蟲製品，其係收納載持0.1〜l〇〇mg/Cm2之上述對孟烷- ❹ 3,8-二醇之纖維質載體於通氣性容器中而成，此通氣性容 器係具備固定於米缸的機構。 14. 一種米缸用防蟲劑，其特徵係含有對孟烷-3,8-二 醇爲防蟲成分，並設置於米缸內。 15. 如申請專利範圍第14項之米缸用防蟲劑，其同 時含上述對孟烷-3,8-二醇及來自植物之除臭成分。 16. 如申請專利範圍第14項或第15項之米缸用防蟲 劑，其中上述對孟烷-3, 8-二醇之含量係相對於米缸容量爲 0.02 〜1 .Og/10L。 -45- 201028089 17.如申請專利範圍第14項至第16項中任一項之米 缸用防蟲劑，其係收納載持〇.1〜l〇〇mg/Cm2之上述對孟 烷-3,8-二醇之纖維質載體於通氣性容器中而成，此通氣性 容器係具備固定於米缸的機構。201028089 VII. Application for Patent Park 1. A method for preventing the odor of the escaping pest component from being transferred to the applicable place or article, characterized by a place where the crawling pests are paralyzed or a place where there is a shackle Or the items that are close to the pests or the items that are close to the cockroaches, and the stalking insect pests that are difficult to transfer odors and are resistant to escaping pests, In or near the field where the creeping pests may or may not be near, or where the climbing pests are near or near. 2. A method for preventing the odor of the escaping pest component from being transferred to a place or article to be placed, which is characterized by a place where a crawling pest is paralyzed or a place where there is a cockroach, or a climbing pest. Items that will be close to or have items close to the shackles, and when they are caught in the stalking pests or close to them, they will contain the escaping pests that are difficult to transfer the odor and avoid the escaping pests. A place where the cockroach or cockroach is located or in the vicinity, or where the migrating pests are near or near, or nearby. 3. The method for preventing the odor transfer of the escaping pest component according to the second item of the patent application, wherein the escaping pest insect product has the escaping pest component and the dissolution at the same time, which is difficult to transfer the odor. The liquid or dispersion is formed on the fibrous carrier. 4. The method for preventing the odor transfer of the escaping pest component as claimed in any one of claims 1 to 3, wherein the above-mentioned difficult-to-transfer odor-avoiding stalking pest component is harmful to the insect olfactory High sensitivity ' -43- 201028089 A compound that is less sensitive to human olfaction. 5. The method according to any one of claims 1 to 4, wherein the escaping pest component as the above-mentioned difficult-to-transfer odor is used for the cyclohexane-3,8-diol and the paraben -1,8-diol, ethyl 3-(N-ethinyl-N-butyl)aminopropionate, picaridin (2-(2-hydroxyethyl)) 1-ethyl 1-piperidinylcarboxylate Propyl propyl ester), 2-ethyl-1,3-hexanediol, diethyl oxalate, dimethyl malonate, diethyl malonate, dimethyl succinate, diethyl succinate, amber Dipropyl acrylate, dibutyl succinate, dimethyl glutarate, diqethyl adipate, dipropyl adipate, dibutyl adipate, diethyl sebacate, sebacic acid Dipropyl ester, dibutyl sebacate, dimethyl phthalate, dibutyl phthalate, diamyl phthalate, dibutyl maleate, dibutyl fumarate or mixtures of these . 6. The method of claim 5, wherein the escaping pest component is used as the above-mentioned difficult-to-transfer odor, and the paraffin-3,8-diol, p-mentane-1,8-diol, 3-(N-Ethyl-N-butyl)aminopropionic acid ethyl ester, picaridin (2-(2-hydroxyethyl)-1-methylpropyl 1-(piperidine)carboxylate), 2-q Ethyl-1,3-hexanediol or a mixture of these. 7. The method of claim 6, wherein the escaping pest component as the above-mentioned difficult-to-transfer odor is used for montan-3,8-diol, p-mentane-1,8-diol, Ethyl 3-(N-ethinyl-N-butyl)aminopropionate, picaridin (2-(2-hydroxyethyl)-1-methylpropyl)-l-piperidinecarboxylate or the like mixture. 8. The method of claim 7, wherein the escaping pest component as the above-mentioned difficult-to-transfer odor is used for the paraffin-3,8-di-44 - 201028089 alcohol, the paraben-1,8 - a diol or a mixture of these. 9. The method of claim 2, wherein the danc-3,8-diol is a evasive pest insect product that is difficult to transfer odor and avoids escaping pests, and is disposed in the stalking property. The pests will lick or lick the contents of the rice tank. 10. The method of claim 9, wherein the above-mentioned amount of the montan-3,8-diol is 0.02 to φ 1 .Og/1 0 L with respect to the cylinder capacity. 1 1. A evading stalking pest product characterized by the method of claim 9 or 10 of the patent application. 12. The escaping pest-resistant product as claimed in the scope of the patent application, which contains the above-mentioned deodorant component to the montan-3,8-diol and from the plant. 13. For the purpose of avoiding the escaping pest product according to Item 11 or Item 12 of the patent application, it is to store the above-mentioned fiber of the above-mentioned montane- ❹ 3,8-diol carrying 0.1 to 1 〇〇 mg/cm 2 . The carrier is formed in an air permeable container, and the air permeable container is provided with a mechanism fixed to the rice cylinder. 14. An insect repellent for a rice cylinder, characterized in that it contains an insecticidal component of montan-3,8-diol and is disposed in a rice cylinder. 15. For the insect repellent for rice tanks of the scope of patent application No. 14, which also contains the above-mentioned deodorant components for montan-3,8-diol and from plants. 16. For the insect repellent for rice cylinders of claim 14 or 15, wherein the content of the above-mentioned montan-3, 8-diol is 0.02 to 1. Og/10L with respect to the volume of the rice cylinder. -45-201028089 17. The insect repellent for rice cylinders according to any one of claims 14 to 16, which is to store the above-mentioned parabens of 1.1~l〇〇mg/cm2 The fibrous carrier of 3,8-diol is formed in an air permeable container, and the air permeable container is provided with a mechanism fixed to the rice cylinder. -46 --46 -
TW98120456A 2009-01-19 2009-06-18 Method for preventing odor-spread of creeping pest repelling compound TWI444138B (en)

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