TW201008488A - Granulated agrichemical - Google Patents

Abstract

A granulated agrichemical containing an agrichemical active component, an -starch (pregelatinized starch) and bentonite, wherein the agrichemical active component has a water solubility at 20 DEG C of less than 700 mg/L, and an octanol-water distribution coefficient at 20 DEG C within a range from 1.4 to 3.5, and the amount of the bentonite is within a range from 20 to 800 parts by weight per 100 parts by weight of the pregelatinized starch is resistant to water elution of the agrichemical active component, and therefore the effect of the agrichemical active component can be maintained over a long period.

Description

201008488 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a pesticide granule. SUMMARY OF THE INVENTION The present invention provides a kind of money _, which can effectively dissolve the medicinal drug and can sustain the effect of the active ingredient of the pesticide for a long time. The composition of the invention in K is as follows: [1] A pesticide granule containing an active ingredient of a pesticide,

(pregelatinized starch), and bentonite, top paste age powder The above pesticide active ingredient at 20 ° C solubility in water is less than 7 〇〇 1 secret 2 (TC octanol / water partition coefficient is L4 ~ 3, 5 _ The bentonite content is 20 to 800 parts by weight with respect to the pre-gelatinized starch. [2] The agrochemical granule according to the above [1], wherein the gelatinized powder and the bentonite are relative to the total amount of the pesticide granule The agrochemical granule according to the above [1] or [2], which contains a nonionic surfactant, [4] as described in [1] to p] above. The agrochemical granules of any one of the above-mentioned [1] to [3], wherein the load of the pesticide granules is the load of the pesticide granules. The agrochemical granule according to any one of the above-mentioned items [1] to [5] wherein the active ingredient of the pesticide is selected from the group consisting of Ferimzone and Folabi. (Furametpyr), Trie yclazole, Futhalide, and S-allyl-5-amino-2-isopropyl 4-(2-indolyl)-3-oxyl -2,3-dihydro-1H-pyrazole-1-thiodecanoate (S-ally At least one of the group consisting of l-5-ami no-2-isopropyl-4-(2-methylphenyl)-3-oxo- 2,3-dihydro-lH-pyrazole -1-carbothioate). [7] The agrochemical granule according to any one of the items [1] to [5], wherein the active ingredient of the pesticide is Ferimzone. 201008488 [Embodiment] The water is dissolved in the _ The composition is in the 2nd ίίί machine and the octanol/water partition coefficient at 2G °c is 1 _ _ ί. Within the 100 parts by weight of the pre-gelatinized powder, the benton content is 20 values. It is usually called Log ρ ' is a physical property value of the compound. The following 'abbreviated the octanol / water partition coefficient as Log ρ. The trace coated coated pesticide particles: effect in the law' - the general use of resin r in water (four) = Therefore, this aspect of the granules is as follows: Non-tree ίίϊίί: Contains active ingredients of pesticides, pre-gelatinized temple powder, and bentonite ===== The medicine is superficial! In 20t water, ® ^J w 100^83005 〇mg^ hair mi Ϊ ί 有效 有效 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 药 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解 溶解Insecticidal compounds, Long compound, and herbicide compound.,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Cheng", and (2) at 2. The rotation degree of C to water is 2 () () ΙΙ _ above Ϊ μ ΪΪ 2 ^ L 〇 g Ρ is the active ingredient of pesticides in the range of Μ ~ 3.5. The content of the component % is usually α ΐ 25% by weight, and the compound of the woven fabric of the present invention is, for example, a compound of the town. A ί^ΐΐί , .·· Blfenarte [chemical name: 3_&lt;4-methoxybiphenyl-glycolyl) fluorenyl fi^^sa (isopropyl 3-(4-methoxybiphen.3-yl) carbazate>; 201008488 : 2.06 mg / L (20 ° C), Log P : 3.4 (25 ° C, pH 7)], common name: Diazinon (chemical name: 0-2-isopropyl-6-methyl spray -4-ylthiolinic acid 0,0-diethylacetate <〇, 〇-diethyl 0-2-isopropyl-6-methyl pyrimidin-4-yl phosphorothioate>; water solubility: 60 mg / L (20 ° C), Log P : 3.3], Common name: Bensultap [Chemical name: S, S'-2-diaminotrimethylene bis(phenylthiolate) <S, S'-2- Dimethylaminotrimethylene di (benzenethiosulfonate)>; Water solubility: 448.4481^(20.〇, Log P: 2. 28(25°C)], Common name: Fenitrothion [Chemical name: 〇~4-Nitrate --m-tolyl-thiolinic acid 0,0-diterpene <0,0_dimethyl 〇-4-nitro-w-tolyl phosp horthioate>; water solubility: 14 mg / L (35 ° C), Log P: 3.43 (20. 〇], common name: Fluvalinate [chemical name: RS-α-cyano-3-phenoxybenzyl ester --N-(2-chloro-a, a, a-trifluoro-p-phenylene)-DL-proline (RS-a-cya no-3-phenoxybenzyl N-(2-chloro-a,a , a-trifluoro-/7-tolyl)-DL-valinat e&gt;; water solubility: 30 mg/L (20 ° C), Log P: 2.9], common name: Fosthiazate [chemical name: (rs )-S-Secondary butyl hydrazine-ethyl 2-oxy-1,3-anthracenion -3-ylthiophosphonate <(Rs)-S-sec-buty 1 0-ethyl 2 -oxo-l,3-thiazolidin-3-yl phosphonothioate>; water solubility 10 degrees: 9_85g/L (20〇C), Log P: 1.68], common name: DMTP [School name: S-2,3- Dihydro-5-methoxy-2-oxy-1,3,4-thiadiazol-3-ylmethyldiindenyl dithiolate <s-2,3-dih ydro-5- Methoxy-2- ox〇-l,3,4-thiadiazol-3-ylmethyl 0,0-dimethyl p hosphorodithioate>; Water solubility: 200 mg/L (25 ° C), Log P: 2.2], Common name: Bai Kesong ( Pyraclophos) [Chemical name: (rs)-[0-1-(4-chlorophenyl)indole 峻 -4--4-yl 0-ethyl = S-propyl = thiophosphoric acid vinegar] &lt;(rs)- [〇-1-(4-chlorophenyl)pyrazol-4-yl〇-ethyl=S-propyl=ph〇Sphorothioate] &gt;; Water Solubility: 33 mg/L (20 ° C), Log P : 3.77(203⁄4)], common name: Thiodicarb [chemical name: 3,7,9,13-tetradecyl-5,11-dioxa-2,8,14-trisulph-4, 7,9,12-tetraaza-pentadecanocarbon_3,12-diene-6,1 201008488 0-dione <3,7,9,13-tetramethyl-5,ll-dioxa-2,8,14 - trithia- 4,7,9,12-te traazapentadeca -3,12-diene _6,10-dione>; water solubility: 22.2 pg/L (25 〇C), Log P: 1.62], used in the present invention The bactericidal compound may, for example, be the following compounds. Common name: Benomyl [Chemical name: 1 -(butylamine sulfhydryl)) Benzyl-2-methylamine phthalate 〈acetate <methyl 1 -(butylcarbamoyl)benzoimida zol -2-yl carbamate 〉; Water solubility: 2.9pg/L (room temperature, pH7), Log P: 1·37], Common name: Bosclid (Chemical name: 2-chloro-N-(4,-gas biphenyl- 2-based) <2-chloro-N-(4'-chlorobiphenyl-2-yl) nicotinamid e>; water solubility··4.6mg/L (20°C), Log P: 2·%] , Common name: Captan [Chemical name: N-(trichlorosulfonylthio)cyclohex-4-ylidene-1,2-dihydroiminoimine <N-(trichloromethylthio)cyclohex-4-ene -1,2-dicarboxyimide>; water solubility: 3.3 mg/L (25 ° C), Log P: 2.8 (25 ° 〇), common name · TPN [chemical name: tetrachloroisophtha lonitrile>; water Solubility: 81.81mg/L (25°C), Log P: 2.92 (25. 〇), Common name: Cyazofamid [Chemical name: 4-chloro-2-cyano-N, N-II Mercapto-5-p-tolyl imidazole-1-benzylamine <4-chloro-2-cyano-A^V-dime thyl-5_ p-tolylimidazol-1-sulfonamide〉; 7jc Solubility: 0.1 〇7ppm (20 °C, pH7), Log P: 3.2 (25°C)], Common name: Diethofencarb [Chemical name: 3,4-diethoxyanilinyl isopropyl acrylate <isopropyl 3 , 4-diethoxycarbanilate>; water solubility: 27.64mg / L (25 ° C), Log P: 3.02], common name: Nitrile sulfur (Dithianon) [chemical name: 5, l〇- dihydro-5, 1〇 Di-dimethoxynaphtho[2,3-7]-1,4-dicerene-2,3-dicarbonitrile <5,10-dihydro-5,10- diox onaphthop,3&gt;b] -l,4 -dithiin-2,3-dicarbonitrile>; Water solubility: 〇.i4mg /L (20°C 'pH7) &gt; Log P : 3.2] &gt; Common name: Fenbuconazole [Chemical name: 4_(4 _Chlorophenyl)_ 2-phenyl-2-(1Η-1,2,4-triazol-1-ylindenyl)butyronitrile <4-(4-chlorophenyl)-2-p henyl -2-( lH-l,2,4-triazol_l-ylmethyl)butyronitrile>Water Solubility·· 3.7 201008488 7mg/L (25°C), Log P: 3·23(25°〇], Common Name: Fermizone (Ferimzone) ) [Chemical name: (z)-2,-mercaptoacetophenone 4,6-dimethyl chito-2-base spell &lt;(z)-2'-methylacetophenone 4,6- dimethyl pyrimidin-2- Ylhydrazine〉; water dissolution Degree: 208 mg/L (20〇C), Log P: 2·89 (25°〇] ' Common name: Fluoroimide [Chemical name: 2,3-dichloro-indole-4-fluorophenylmaleimide <2,3-(1)111〇1*〇-]^4-£111〇1*〇?11611)4 11^ by 11^(16>; water solubility: 0.611mg/L (20°C, pH5) .4), Log Ρ : 3.04 (25. 〇], common name: Flusulfamide [chemical name: 2,,4-dichloro-α,α,α-❹ trifluoro 4'-nitro-m-phenylene sulfonate aniline <2, 4-dichl〇r〇-a, a, a-trifluoro-4,-nitro-m-toluene sulfonanilide>; water solubility: l.25mg/L (20°C, pH6.3),

Log P : 2.8] ' Common name: Flutolanil [Chemical name: α,α,α-trifluoro-3, monoisopropoxy o-toluene aniline <a, a, a-trifluoro-3 ,-isopropoxy-o- toluanilid e〉; water solubility: 8.01 mg/L (2 (TC), Log P: 3·17], common name: Furametpyr [chemical name: (rs)-5- Chloro-N-(l, 3-carbazolylisobenzo-f--4-yl)-1,3-dimethylindole than salivary-4-carbenolamine <(RS)-5-chloro -7V~(l,3-dihydro-l,l,3_trimethylisobenzoftiran- 4-yl)-l,3-dimethylpyrazole -4-carboxamide>; Water Solubility: 200mg/L (2 ❹ 〇°C), Log P : 2.36 (25 ° C)], common name: Fthalide [chemical name: 4,5,6,7-14 tetrahydrophthalic acid ester <4,5,6,7-tetrachloro phthalide>; water solubility: 2.5mg/L (25t:), Log P: 3.01], common name: IBP [Chemical name: 〇, 〇 isopropyl thiophosphoric acid s_benzyl 〈, Ο-diisopropyl phosphorothioate>; Water solubility: 54.54g / L (20 ° C), Log P: 3.37 (20 〇 C, pH 7)], common name: Iprodione [chemical name 3_(3,5-dichlorophenyl)_N-isopropyl-2,4-dioxyimidazole-丨-carbonated decylamine <3_(3 5 dichl〇r〇phenyl)_ N-isopropyl-2 , 4- dioxoimidazolidine-1-carboxamide>; Water solubility: 1 3 mg/L (20〇C) &gt; Log P : 3 (pH5)] &gt; 7 201008488 Common name: Isoprothiolane [Chemical name: ι , 3-dithiolan-2-ylmalonate diisopropyl ester <diis〇pr〇pyl 13_dithi〇lan 2_'ylidene=al〇nate>; water solubility: 48.5mg/L (20〇C), Log P : 3.3 (25. 〇), Common name: Kresoxim-methyl [Chemical name: ( played _2_methoxyimino 42-(2-(o-phenoxymethyl) benzene) ]]Acetyl acetate <me%1 (E)_2 met hoxyimmo- |&gt;(0_t〇lyi〇Xymethyl) phenyl]acetate>; Water solubility: 2 mg /L (20 ° C) ' Log p : 3.4 (25〇 C 'pH7)] ' Ordinary name: Mepanipyrim [chemical name: n_(4-mercapto_6- fast-propyl-1-ylpyrimidin-2-yl)aniline <&gt;1-(4-11 ^%1-6啊〇卩-1-丫1^1?#11^(^11_ 2-yl)aniline>; water solubility: 2.08mg/L (20°C, pH7); Log P : 3 28( 20 °C)], . Ordinary name: Destroy (M Etalaxyl) [chemical name: N-(曱ethoxyethyl)-N-(2,6-diphenylene)-DL-alanine decyl ester <11^%1 team (11 11 11 (^&amp;〇 Kiss 1)-&gt;^ (2,6-xylyl) -DL_alaninate>; water solubility: 8.4111 and 22. (:); Log P : 1 75], Common name: Metominostrobin [Chemical name: (E)_2-(nonoxyimino)-N-methyl-2-(2-phenoxyphenyl)acetamide <(E)-2-(methoxyimino)-N-methyl-2 -(2-phenoxyphenyl)acetamide>; Water solubility: 〇.128 machine (20. 〇; Log P : 2.32(20°〇] ' Common name· · Myclobutanil [Chemical name: 2-p-chlorophenyl-2-(1H-1,2,4-triazol-1-ylindenyl) hexonitrile <2> p-chlorophenyl-2_(lH- l,2,4-trizo 1-1- ylmethyl) hexanenitrile>; water solubility: I32mg/L (2(T(::), Log P: 2.94 (25. (:, pH7~8)), common name: PefUrazoate [Chemical name: N_糠基一Ν_σ米嗤_ 1-based base-DL-high alanine pentyl-4-yl ester <pent_4-enyi N_fUrfUryl~N_i midazol-l-yl carbonyl - DL-homoalaninate>; water solubility: 443 mg/L (2 5. 〇; Log P: 3), common name: Procymidone [chemical name: N-(3,5-dichlorophenyl)-1 , 2--fluorenylcyclopropane--% iodine-enamined <N-(3,5-dichloiOphenyl) _l,2-dimethyl cyclopropane-l,2-dicarboximide>; water solubility: 4.5 mg 201008488 /L(25〇C) ; Log P : 3.14(26°C)] ' , Ordinary name: Pyroquil〇n [Chemical name: ^^ tetrahydropyrrole[3,2,l- Ij] quinoline-4-one <l,2,5,6-tetrahydropyrr〇i〇[3,2,l-ij] quindin- 4-one>; water solubility: 4g/L (20°C); Log P : ι.6], common name: Tricyclazole [chemical name: 5-methyl_12 4_3. Sit and [3,4~b] benzothiazepine <5-methyl-l, 2,4-triaz〇l〇[3,4-b] benzothiazol e&gt;; Water solubility: 0596g/L (2(TC) ; Log P : 1.42], Common name: Thiophanate-methyl [Chemical name: Dimercapto 4,4'-(o-phenylene) bis(3-thioureacarboxylate) <dime%1 4,4,_(0_phenyl^ne) bis(3-thioallophanate)&gt; Log P : 1.5] &gt; Common name: Thiram [Chemical name: tetramethylthiuram disulfide]; 5-mercapto-i, 2,4-tris-[3] 4-b]benzopyrene <5-methyl-1,2,4-triazol〇p,4-b] benzothiazole〉Water solubility: 18 mg/L (room temperature); Log P: 1.73], chemical name: S-allyl 5amino-2-isopropyl-4- (2-tolyl)-3-oxy-2,3-dihydro-twist-1 pyrazole thioacetate <S-allyl-5-amino-2-isopropyl-4 (2-methylphenyl) -3 -oxo-2,3-dihydro-1 H-pyrazole-1 -carbothioat e&gt;;Water Solubility··20 mg/L (20°C); Log P: 3.2 The herbicidal compound used in the present invention may, for example, be as follows Compound. Common name: Atrazine [Chemical name: 6-chloro-N2-ethyl-N4-isopropyl-1,3,5-dioxa-2,4-diamine <6-chloro-N2-ethyl -N4-isopropyl-l,3, 5-triazine 2,4-diamine>; Solubility: 33 mg/L (water, 22. 〇, pH 7); Log P: 1.6 (25 ° C)], common name: free speed Bensulfiiron-methyl [chemical name: α-(4,6-dioxaoxypyridin-2-ylamine decylamine hydrazino) o-toluene decanoate <methyl a-(4,6 -dimethoxy pyrimidin-2-yl carbamoylsulfamoyl)-o-toluat e>; water solubility: 67 mg/L (25 ° C, pH 7); Log P: 2.18 (25 ° C, pH 5)], common name: ring performance ( Cyclosulfamuron) [Chemical name: l-[2-(cyclopropyl)aniline continuation]-3-(4,6-dimethoxy acetonyl-2-yl) gland <l-[2-(cycloprop) Ylcarbonyl) phenylsulfamoyl] -3-(4,6-dimethoxypyrimidin-2-yl)ure 201008488 a>, solubility · 6.52ppm (water, 25 C, pH 7) ; Log P : 1.41 (25 ° C, pH 7)] Common name :Flumioxazin [Chemical name: N_(7_fc_3 4_diazo-3-oxy-4-propan-2-yl-m-1,4-benzophenanthrene __6-yl) cyclohexyl-indole] , 2 - 2 carbonated decylamine <N-(7-f Luoro-3,4-dihydro-3-ox〇-4-prop-2-ynyl -2H-l,4-benzox azin-0-yl)cyclohex -l-ene-l,2-dicarboxamide>;Water Solubility: 1.79mg / L (25〇C) ; Log P : 2.55], common name: Fluometuron [chemical name · · 14 - dimercapto - 3_ (α, α, α-二亲^ tolyl) <l,l-dimethyl-3-(a,(x,a-trifluoro-m-tolyl)ure a>; solubility: 110 mg/L (water, 20 ° C); Log P : 2.38], ❹ common name :Fluthiamide [Chemical name: 4,-fluoro-N-isopropyl-2-[5-(difluoroindenyl)-1,3,4-sulfanyl-2-yloxy] acetyl anilide < 4'-fluoro-JV-isopr opyl-2-(5-trifluoromethyl-1,3,4-thiadiazol-2-yloxy) acetanilide ); water solubility: 56 mg/L (25 ° C, pH 7); Log P : 3.2 (twenty four. 〇], Common name: Isoxaflutole [Chemical name: 5-cyclopropene jj-n-oxazolyl_α, α,α_difluoromethane-2 - fluorene-p-toluene 嗣 < (5-cyclopropyl-l, 2-oxazol-4-yl)(a, a, a-trifluoro_2-mesyl~p-tolyl)ketone>; water solubility: 6.2 mg/L (20 °C, ρΗ5·5); Log P: 2.34], common Name: Mefenacet [Chemical name: 2-(1,3-benzoxanthene-^2-yl)-N-methylacetanilide <2-(l,3-benzothiazol-2 -yloxy)-N-methy 1 acetanilide>; Solubility: 4 mg/L (water, 20. 〇; Log P: 3.23), common name: Metribuzin [chemical name: 4-amino-6-three Butyl-3-methylthio-i,2,4-tris-5-(4Η)-one <4-amino-6- such as t-butyl_3-meth ylthio- l,2,4-triazin _5_( 4H)-one&gt;; water solubility·· 1.05g/L (20°C); Log P · 1.6(20〇C 'pH5.6)] '

Common name: Norflurazon [chemical name · 4-chloro-5-nonylamino-2-(α,α,α-difluorom-tolyl) talamine u3(2H)-one <4-chloro-5-methylamino -2-(a, a, a-tri fhioro-m-tolyl) pyridazin-3(2H)-one>; water solubility: 34 mg/L (25 ° C); L 〇g P : 2.45 (25 ° C, pH6.5)], common name: Propanil [chemical name: 3', 4'-di-propionyl aniline 10 201008488 <3', 4'-dichloro propionanilide>; water solubility: I30mg / L ( 20t:) ; Log P : 3.3 (20 ° C)] 'Specific examples of the active ingredients of the pesticide used in the present invention, such as S-allyl 5-amino-2-isopropyltolyl)-3-oxo Base-2,3-dihydro-111-° than 嗤-1-thioformic acid vinegar, Fthalide, Ferimzone, Furametpyr, and Tricyclazole .

Commercially available pregelatinized starch can be used in the present invention. Commercially available pregelatinized starches such as AMY COL HF, AMYCOL C, AMYCOL KF, AMYCOL HG-N, A MYCOL BJ-2, AMYCOL W, Starch MH-A, AMYCOL A, ❹ AMYCOL FW (曰殿化学), 曰Eat Arosta, 阿 阿 阿 Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η Η a. Industrial tree potato powder ατρ-2, wheat starch aW A_105 (Sanhe starch industry), AMYLOX No.l, and AMYLOX Νο.1Α(Ν ihon Cornstarch) ° The bentonite is montmorillonite The main component of clay. Commercially available bentonite can be used in the present invention. Commercially available bentonites such as KUNIGEL VI, KUNIGEL V 2, KUNIBOND (Kunimine Industries)' Bentonite Miaoyi, Bentonite Fuji,

Bentonite Asakusa, Bentonite Akane, Bentonite Anonymous (HOJUN), Shimane B entomte, Izumo Bent〇nite, Kansai Bentonite (KASANEN Industries), MIZ ❹ UKA-ACE, BENCLAY (Yaeazawa Chemical). In the granules, the ratio of the pregelatinized starch to the bentonite is 20 to 8 parts by weight, preferably 2 to 600 parts by weight, based on 100 parts by weight of the pregelatinized starch. In the granules, the total content of the pregelatinized starch and the benton is usually about 5 to 45% by weight. Further, in the granule, the active ingredient of the granules and the pregelatinized starch may be contained. The reactive, water-insoluble solid acts as a bulking agent component. Such extenders may, for example, be kaolinite, double kaolin (dickite), pearl clay (η acnte), kaolinite (hall〇ysite^kaolin type mineral, chrys〇t lie, granules). Serpentine (lizartite), leaf snake s (antig〇rite), magnesium-aluminium serpentine (la (4) 11 201008488 te), etc. serpentine phytophyllite, talc, agramatolite, muscovite, dolphic Muscovite such as phengite, serisite, illite, cristo〇balite, quartz and other meteorites, dolomite (d〇l〇mite) and other calcium carbonate minerals' Bemidite, nonironite, saponite, hectorite and other smectites, saponite, lithium bentonite, stivensi te synthetic smectite, magnesium aluminum Aqueous magnesium minerals such as attap Ulgite and sepi〇lite, 'GypSum (gypsum), gypsum and other sulfate minerals' zeolite (zeolite), zeolite, tuff (plus, permeate, pumice) Cocktails), dreamy earth (diat〇mite), and powdered citric acid, etc. in the granules, pre-paste The total content of the starch, the bentonite, and other extender components is usually 75 to 99% by weight, preferably 80 to 95% by weight. In the granule, it may contain a surfactant, a binder, and a stable Adjuvants for agents, pigments, etc.. For surfactants, such as polyoxyethylene alkyl ethers, polyoxyethylene alkylene groups, polyoxyethylene stearyl ether, polyoxyethylene lanolin, polyoxymethylene Burning formaldehyde condensate, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene glyceryl mono fatty acid ester, polyoxyethylene propylene glycol mono fatty acid ester, polyoxyethylene sorbitol single fatty acid vinegar, polyoxyethylene Castor oil derivatives, polyoxyethylene fatty acid esters, high-grade fatty acid glycerides, sorbitan fatty acid esters, sucrose fatty acid esters, polyoxyethylene polyoxypropylene block polymers, polyoxyethylene fatty acid decylamine, Alcohol amine (alky1〇1 amide;),

a nonionic surfactant such as polyoxyethylene alkylamine; G alkylamine hydrochloride such as dodecylamine hydrochloride, d〇decyltrimethyl ammonium salt, alkyl An alkyl quaternary ammonium salt, an alkyl pyridinium salt, an alkyl isoquinoline rust salt, an alkyl quaternary ammonium salt such as a dialkyl sulphate salt, phenylethyl chloroacetate, polyalkylethylene a cationic surfactant such as a pyridinium salt; a sodium salt of a fatty acid such as sodium palmitate; a sodium carboxylate such as sodium polyoxyethylene lauryl ether carboxylate; a sodium lauryl sarcosinate; a sodium N-lauric acid amylate; Higher fatty acid amino acid condensate 'higher alkane sulfonate, higher fatty acid ester sulfonate such as laurate sulfonate, dialkyl sulfosuccinate such as dioctyl sulfosuccinate, oleic acid sulfonic acid High-grade fatty acid amide sulfonate, such as salt, sodium dodecyl benzene sulfonate, diisopropyl naphthalene sulfonate, etc. 12 201008488 . Burning aryl phthalate, alkyl aryl phthalate furfural condensate , fifteen-burning sulfuric acid vinegar, etc., local grade alcoholic vinegar sulfate, dimerized oxyethylene, decyl ruthenium phosphate, etc. , A styrene-maleic acid copolymer bound anionic surfactant. In the present granules, the surfactant usually contains 0.1 to 5.5% by weight. Regarding the binder, for example, polyvinyl alcohol or a derivative thereof. When polyvinyl alcohol or a derivative thereof is used as a binder, a commercially available polyvinyl alcohol or a derivative thereof may be used, and a commercially available polyvinyl alcohol or a derivative thereof such as G-type GOSENOL, type A GOSENOL, N type may be used. G0SEN0L (Sakamoto synthetic chemistry), partially saponified POVAL, moderately enzymatic p 〇 VAL, fully saponified. In the present granules, the binder usually contains 〜1 to 5 〇% by weight. Powder, ίίΐΐϊίί method, for adding water to the active ingredients of pesticides, pre-gelatinized temples and other mixtures, kneading the resulting kneaded material, drying it, and pulverizing it as needed. Screening, tidying::, heavy pre-measurement of t-ring, bentonite and other ingredients. Weight two © As ^ method. Squeeze _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The range is good, the grain length is usually in the range of 〇·5~6.0, especially 〇.7~4.0m uta mixer), boring machine, Nota type mixer (Na granulator, drum type extrusion, etc.; ^ Extrusion granulator, such as spiral extrusion type extrusion granulator, basket machine, pellet grinding and extrusion granulator, gear type extrusion 刀 knife type extrusion granulator, vibrating extrusion Specific examples of the granulator, machine, and singular ring mode extrusion granulator, etc., such as T_D_201008488 or, Basket Granulator, peiieter Double (above Dalton Co., Ltd.), 畑 type reduction (_颂) As for the method of smashing and sizing, for example, the granules obtained by the Marumerizer (spherical granulator, d-recorded silk, and New Zealand-made kiln mill) using the above-mentioned manufacturing method, the load hardness Usually 2 is more preferably 350g or more, and more preferably 400~1000g. The load of the granule can be adjusted by the composition of the granules, kneading conditions and granulation conditions. For example, the grazing method can be carried out according to the general method of smashing. The method of squeezing and squeezing in the sizing method and using a piggyback granulator, a pipe granulator, an empty granule, a smashing machine, and a seedling box A sprinkler, a squeezing machine, etc., a sprinkler, a sprinkler, a sprinkler, a sprinkler, etc., which are used to spread the granules of the granules. The purpose is to use it in a pool, a storage area, a course, a road, a road, a shoulder, a wetland, a πίί River, a waterway, a sewer, etc. Regarding the granules, for example, the following aspects are obtained. The effect ingredient, the granulated starch, the bentonite, and the bismuth component are less than 7()() balls in the chat, and the octanol/water partition coefficient of 2〇C is in the range of 14~3 5 Parts, the content of bentonite is 2 ° ~ _ parts by weight. And non-ionic boundary butterfly 1 agent 3 has agricultural aging ingredients, surface storage powder, bent soil, relative to the pre-gelatinized starch 1 〇〇 will be 5 ^ in the farmer (4) 14 201008488 —A kind of pesticide granules containing the pesticide ϋ ϋ and octa 20C octanol/water partition coefficient in the range of u~3·5, = pre-,                                                         2 (ΤΓΪίϋΪ The degree of rotation is less than the ball, and within the range of 20C octanol/water partition coefficient is 14~3 5 , &amp; = 100 parts by weight of pregelatinized starch, the benton content is 20~_wt parts , the weight 'in the pre-gelatinized temple powder 1 〇 0 parts by weight, the active ingredient content of the pesticide is 2 ~ 500 5 weight ίί in the total amount of agricultural music granules, the total content of pre-gelatinized temple powder and benton soil is 5~4 Granules, which contain pesticides, right-handed and non-ionic surfactants, and are effective in forming knives, starches, bentonites, and it成it2〇°C. The solubility in water is less than 700, and in 20 C. The partition coefficient of octanol/water is in the range of U~3 5 , and the ratio is 1 gram by weight of pre-gelatinized starch, the content of bentonite is 2 () ~ _ parts by weight, and the weight ^ _ 1GG ® 4 parts.纽丝4 is 2~5〇〇 and non-separated; =,: bismuth contains active ingredients of pesticide, pre-gelatinization _·^ 700m8/L 1 ^ relative to 100 parts by weight of pre-gelatinized starch The content of the bentonite should be 5 parts by weight for the pre-gelatinized starch, and the total amount of the pre-gelatinized powder and the bent soil should be 5~4 201008488 and the non-separating agent 3 has the active ingredients of the pesticide. Pre-gelatinized starch, benton, _ heavy weight = amount (10) ~ _ parts by weight, parts by weight; 'heart 00 parts by weight, pesticide active ingredient content is 2~500 powder (10) parts by weight, nonionic surfactant content is 〇 .

And _== is the range of the octanol/water partition coefficient of the 20C, which is in the range of 14~3 5 , and the benton content is 2〇~8 relative to 100 parts by weight of the pre-gelatinized starch. 〇〇重量份,重量 = for faceted meal 重) heavy threat, the aging age of the agricultural product is 2~· relative to 100 parts by weight of the pre-gelatinized starch, the nonionic surfactant content is 〇. 05~0.25 parts by weight,

The total content of the pregelatinized starch and the benton is 5 to 45 wt% based on the total amount of the pesticide granules. An agricultural music granule' contains Ferimzone, pre-gelatinized starch, and bentonite, and the benton content is 20-800 parts by weight relative to 100 parts by weight of the pre-gelatinized starch, relative to the pre-gelatinized starch 100. The content of 'Frimzone' is from 2 to 500 parts by weight. A pesticide granule comprising Fermizone, pregelatinized starch, and bentonite, having a benton content of 20 to 800 parts by weight relative to 100 parts by weight of the pregelatinized starch, and 100 weight relative to the pregelatinized starch The content of Ferimzone is 2 to 500 parts by weight, 16 201008488 • The total content of pregelatinized starch and benton is 5 to 45 wt% relative to the total amount of pesticide granules. A pesticide granule comprising Fermizone, pregelatinized starch, bentonite, and nonionic surfactant, and the content of the bentonite is 20 to 800 parts by weight relative to 100 parts by weight of the pregelatinized starch, The content of the Perimzone is 100 to 500 parts by weight in the pre-gelatinized powder. A pesticide granule' contains Ferimzone, pre-gelatinized powder, bentonite, and nonionic surfactant, ❹ 1 part by weight relative to pre-gelatinized starch, and the benton content is 20-800 The parts by weight of the pre-gelatinized starch are from 2 to 500 parts by weight, based on 100 parts by weight of the pre-gelatinized starch, and the total content of the pre-gelatinized starch and the benton is 5 to 45 weights relative to the total amount of the pesticide granules. %. A pesticide granule' contains Ferimzone, pregelatinized starch, expanded soil, and nonionic surfactant. The benton content is 2〇~8〇〇 relative to 100 parts by weight of pregelatinized starch. The parts by weight of the pre-gelatinized starch are from 2 to 500 parts by weight relative to 100 parts by weight of the pre-gelatinized starch. The nonionic surfactant content is 〇〇5~ relative to 100 parts by weight of the pre-gelatinized starch. 0.25 parts by weight. .. Kindergarten granules contain Feriinzone, pregelatinized starch, bentonite, and nonionic surfactant. Cypress is 100 parts by weight of pregelatinized starch, and the content of benton is 2〇~8 〇〇 by weight, relative to 1 part by weight of the pre-gelatinized starch, the content of Fermizne (Ferimz〇ne) is 2 to 500 parts by weight, relative to 1 part by weight of the pre-gelatinized powder, nonionic interfacial activity The content of the agent is 〇05 to 0.25 parts by weight, and the total content of the pregelatinized starch and the expanded soil is 5 to 45 wt% with respect to the total amount of the pesticide granules. ° &quot; 17 201008488 2 20 (: 辛_ / / _ _ number is U ~ 3 · 5 ^ ^ ί ΓΪ ΓΪ 殿 殿 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Yu, Lai effective silk content is 1〇~5〇室置份. 1ίΐ; peony active ingredient, pre-gelatinized temple powder, and benton, 2〇.. ίί, λ into mc solubility in water is less than 700 filial And in the range of 20 C octanol/water is a ratio of 1.4 to 3.5, = pre-powder powder · parts by weight, the benton content is 2 () ~ _ parts by weight, weight g for pre-paste 100 parts by weight of starch, the active ingredient content of pesticide is 1〇~5〇= For the total amount of pesticide granules, the total content of pre-gelatinized powder and benton is 5~4 3 children's %. Containing pesticide active ingredients, pre-gelatinized starch, benton, and non-ionic surfactants, her farmer's wealth is divided into 2 () ΐ 水 ♦ 7 7__, and 20 octanol / water distribution The coefficient is in the range of 1.4 to 3. 5, and the benton content is 2 〇 8 8 parts by weight relative to 100 parts by weight of the pregelatinized starch, and 1 part by weight of the pre-gelatinized powder, the active ingredient of the pesticide Content is ι 〇~5〇篁重份. s Pesticide granules, containing pesticide active ingredients, pre-gelatinized starch, bentonite, and non-ionic surfactants, the above-mentioned f financial effect ingredients in 2 (&gt; 7 () () 111 machine, and in the range of 20 C octanol / water partition coefficient of 1.4 ~ 3.5, relative to the pre-gelatinized starch 1 〇〇 part by weight, the benton content is ~ 8 (8) parts by weight, relative to 100 parts by weight of the pre-gelatinized starch, the active ingredient content of the pesticide is 10 to 50 parts by weight, and the total content of the pre-gelatinized starch and the expanded soil is 5 to 45% by weight for the total amount of the pesticide granules.

, pregelatinized starch, bentonite, the above pesticide active ingredient is 20.辛 The octanol/water partition coefficient of water at 20 ° C is 14~3.5. Compared with 100 parts by weight of pre-gelatinized starch, the solubility of swelling is less than 700mg/L, and within the range of .5, relative to pre-gelatinized starch. 1 part by weight, part by weight, the bentonite contains 20 to 800 parts by weight, 'the active ingredient content of the pesticide is 10 to 50 parts by weight relative to 1 part by weight of the pregelatinized starch, 05 to 0.25 parts by weight.

The price is on the weight of the muscles, and the octanol/water partition coefficient of 20 C is in the range of 1.4 to 3.5, compared to 1 part by weight of the pregelatinized starch. The content of the bentonite is 2〇~8〇〇 parts by weight, and the content of the active ingredient of the pesticide is 10~50 parts by weight relative to 100 parts by weight of the pregelatinized starch, and the content of the nonionic surfactant is 100 parts by weight relative to the pregelatinized starch. 〇05~0·25 parts by weight, ...·, for the total amount of the pesticide granules, the total content of the pre-gelatinized starch and the benton is 5 to 45% by weight. Expanded soil, a kind of pesticide granules, containing Ferimzone, pre-gelatinized powder, 1 part by weight relative to pre-gelatinized starch, and the benton content is 2〇~8〇〇, relative to pre- The gelatinized powder is 1 part by weight, and the rich rice complex content is 1 to 50 parts by weight. - a kind of pesticide granules - containing Fermzone, pre-gelatinized powder, and benton, relative to 100 parts by weight of pre-gelatinized starch, the benton content is 20-800 parts by weight, relative to the pre-gelatinized starch 100 parts by weight, Ferimzone content is 10 to 50 parts by weight, 19 201008488 Relative to the total amount of pesticide granules, the total content of pregelatinized starch and benton is 5 to 5 wt% 〇 4 kinds of pesticide granules, Contains Ferimzone, pre-gelatinized lake: powder, bentonite, and nonionic surfactant, 'relative to 100 parts by weight of pre-gelatinized starch, the benton content is 2〇~8(8) by weight relative to the pre-paste The starch is 1 part by weight, and the Fermizne content is π to 50 parts by weight. Qiaochuan is a pesticide granule containing Ferimzone, pre-gelatinized powder, bentonite, and nonionic surfactant. v is 1 part by weight relative to pre-gelatinized starch. The benton content is 2 〇~8 (8) parts by weight, phase 2 in 100 parts by weight of pregelatinized starch, Ferimz〇ne content is 1〇©~50 parts by weight, relative to the total amount of pesticide granules, pregelatinized starch and bentonite The total content is 5~5% by weight 〇^ A pesticide granule containing Ferimzone, pregelatinized starch, bentonite, and nonionic surfactant, less than 100 parts by weight of pregelatinized starch. The content of the bentonite is 2 〇 8 8 parts by weight, and the content of the Fermiz 〇ne (Ferimz〇ne) is ^ 50 parts by weight relative to 1 part by weight of the pregelatinized starch, and is: 100% relative to the pre-gelatinized powder. The parts by weight of the nonionic surfactant are in the range of -0.25 parts by weight. U· A pesticide granule' contains Ferimzone, pregelatinized starch, bentonite, and nonionic surfactant, y relative to 100 parts by weight of pregelatinized starch, and the benton content is 2〇~8(8) The parts by weight, based on 100 parts by weight of the pregelatinized starch, the 'Ferimzone content is ~ '50 parts by weight, and the nonionic surfactant content is -0.25 parts by weight relative to 100 parts by weight of the pregelatinized starch, π υ. The total content of pregelatinized starch and benton is 5 to 5% by weight based on the total amount of the pesticide granules. . 〜4 20 201008488 (Embodiment) The present invention will be described in more detail by the following examples, but the invention is not limited by these examples. Example 1

Ferimzone (Feiyou Chemical, purity 97.〇%) 5〇.〇 by weight and Shengguangshan CLAY-S (made by Shengguangshan Mining) 5〇.〇 by weight mixed with juice mixer 'This mixture was pulverized by a rotary mill (R〇t〇r min, manufactured by Retsch) to obtain a pulverized material (hereinafter abbreviated as Ferimzone micropowder. The active ingredient content was 48.5 %; the laser diffraction particle size The average particle diameter of the measuring device (wet method) was 6.5 μηι.). Take 41.2 parts by weight of Ferimzone micropowder, 50.0 parts by weight of AMYLOX No.lA (Ni hon Comstarch), 200.0 parts by weight of Bentonite Fuji (H〇JTJN), SORPOL 5080 (nonionic surfactant, Toho Chemical) 〇〇 重量 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份 份1000 parts by weight of this mixed powder was mixed with 230 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Auta Mixer, manufactured by Fuji Paudal) to obtain a kneaded product. The kneaded product was extruded and granulated by a hanging basket granulator (畑铁工所) with an extrusion diameter of 0 〇.9 mm, dried with a fluidized bed dryer (manufactured by Powlex), and then a needle mill ( Free crusher, wilderness industry). This coarsely pulverized material was sieved to obtain the agrochemical granule of Example i. Example 2 ', except that Bentonite Fuji was changed to 5〇·〇 by weight, Shengguangshan CLAY_s was changed to 848.8 parts by weight, and water was changed to 22〇 parts by weight, and other operations were carried out in the same manner as in Example 2 Pesticide granules. Phase I Example 3 The pesticide of Example 3 was obtained except that Bentonite Fuji was changed to 100.0 parts by weight, Shengguangshan CLAY_S was changed to 798.8 parts by weight, and water was changed to 22 parts by weight. Granules. Example 4 Except that Bentonite Fuji was changed to 400_0 parts by weight, and Shengguangshan clay-s was changed to 21 201008488 HI='s health and real-time 1 _, Example 4 (Morning granules were obtained. Example 5 except Change AMYLOX Να1 to pulse weight, Bent〇nite Fuji 20.0 heavy injury, Shengguangshan CLAY_S to 828 8 parts by weight, and water to weight, and perform the same operation as in Example i. Granules. Example 6

In addition to changing Bentonite Fuji to 50·〇 by weight, Shengguangshan CLAY-S to 798.8 parts by weight, and water to 2〇〇 by weight, the other operations were carried out in the same manner as in Example 6, and the pesticide particles of Example 6 were obtained. Agent. Comparative Example 1 41.2 parts by weight of Ferimzone micropowder, 50.0 parts by weight of AMYLOX NalA (Ni hon Comstarch), 500.0 parts by weight of Bentonite Fuji (H〇JtJN), and 10.0 parts by weight of SORPOL 5〇80 (Toho Chemical) 398.8 parts by weight of K.K., CLAY-s (manufactured by Kyungsan Mining Industry Co., Ltd.) was mixed with a Nota mixer (manufactured by Fujipaudal Co., Ltd.) to obtain a mixed powder of 1 part by weight. One part by weight of this mixed powder was mixed with 23 mils of water, and kneaded by a Nauta mixer (manufactured by Fuji Paudai) to obtain kneading. The kneaded material was extruded and granulated by a hanging basket granulator (Nippon Iron Works) at an extrusion diameter of 00 9 mm, dried by a fluidized bed dryer (manufactured by P〇wlex), and then a needle mill ( From the smashing machine, the wilderness industry). This coarsely pulverized material was sieved to obtain a pesticide granule of Comparative Example 1. Comparative Example 2 The same procedure as in Comparative Example 1 was carried out except that Bentonite Fuji was changed to 600 parts by weight, Shengshan CLAY_S was changed to 298.8 weight damage, and water was changed to 250 parts by weight. . Comparative Example 3 Take 41.2 parts by weight of Ferimzone micropowder, 50.0 parts by weight of AMYLOX No.lA (Ni C〇mstarCh), s〇RP〇L 5〇8〇 (Dongbang Chemical) 1〇〇 weight injury, Shengguang Mountain CLAY-S (manufactured by Kwong Kwong Mining Co., Ltd.) 898 8 parts by weight was mixed with a Nota type blend 22 201008488 (manufactured by Fujil Paudal) to obtain 1000 parts by weight of the mixed powder. This mixed powder 5 g of 1000 parts by weight was mixed with 210 parts by weight of water, and then kneaded by a Nota type mixer (Fuji Pauda) to obtain a kneaded product. The kneaded product was extruded and granulated by a hanging basket granulator (畑铁工所) with a diameter of 00.9 mm, dried with a fluidized bed dryer (manufactured by P〇wlex), and then a needle mill ( The free crusher and the wilderness industry are used for rough breaking. This coarsely pulverized material was sieved to obtain a pesticide granule of Comparative Example 3. Comparative Example 4 41.2 parts by weight of Ferimzone micropowder, 30 parts by weight of GOHSENOL GL-05 s (product of Sakamoto Synthetic Chemical Industry Co., Ltd.), Bent〇nite Fujitsu OJIJN) 200.0 parts by weight, SORPOL 5〇 80 (Toho Chemical) 10.0 parts by weight, 71.88 parts by weight of Kyungsan CLAY-S (manufactured by Kyungsan Mining Co., Ltd.) were mixed with a Nauta mixer (manufactured by Fuji Pauja Co., Ltd.) to obtain a mixed powder of 1 part by weight. This mixed powder was mixed with 220 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paudal) to obtain a kneaded product. This kneading material is extruded and granulated by a hanging basket granulator (畑铁工所) with an extrusion diameter of 0 0.9 mm. After drying with a fluidized bed dryer (powh), a needle mill is used. The crusher and the wilderness industry are coarsely crushed. This coarsely pulverized material was sieved to obtain a pesticide granule of Comparative Example 4. Table 1 Example 1 2 3 4 5 6 Ferimzone (calculated as active ingredient) 2.0 2.0 2.0 2.0 2.0 2.0 AMYLOXNo.IA 5.0 5.0 5.0 5.0 10.0 10.0 Bentonite Fuji 20.0 5.0 10.0 40.0 2.0 5.0 SORPOL 5080 1.0 1.0 1.0 1.0 1.0 1.0 Shenguangshan CLAY-S bal. bal. bal. bal. bal. Total (W/W%) 100.0 100.0 100.0 100.0 100.0 100.0 Dissolution rate of active ingredient after 24 hours (〇/〇) 76.0 79.6 79.6 83.4 77.9 78.8 23 201008488 824 608 694 884 Table 2 Comparative Example _ 1 2 3 4 Ferimzone (calculated as active ingredient) 2.0 2.0 2.0 2.0 AMYLOX No. 1A 5.0 5.0 5.0 ' Bentonite Fuji 50.0 60.0 20.0 SORPOL5080 1.0 1.0 1.0 1.0 GOHSENOLGL-05S 3.0 胜光山 CLAY-S bal. bal. bal. Total (W/W%) 100.0 100.0 100.0 100.0 Dissolution rate of active ingredient after 24 hours (%) 99.0 98.0 89.2 96.5 Load hardness (g) 627 368 651 Example 7

50.0 parts by weight of Furametpyr (Sumitomo Chemical, purity 97.3%) and 50.0 parts by weight of Bentonite Fuji (HOJUN) were mixed with a juice mixer, and the mixture was pulverized by a rotary disc mill (Rotor mill). The pulverized material (hereinafter abbreviated as Furametpyr micropowder A. The active ingredient content is 48.7%; the average particle diameter is 5.8 μηι.). Take Furametpyr fine powder A 189.1 parts by weight, AMYLOX No.lA (NihonComstarch) 50.0 parts by weight, Bentonite Fuji (HOJUN) 105.4 parts by weight, SORPOL 5080 (Toho Chemical) 1 〇. 〇 by weight, Nitto carbonate NN200 (5,5 parts by weight of a product of Nitto Powder Chemical Industry Co., Ltd.) was mixed with a Nauta mixer (manufactured by Fuji Paudal Co., Ltd.) to obtain a mixed powder of 1 part by weight. 1000 parts by weight of this mixed powder was mixed with 220 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paucial Co., Ltd.) to obtain a kneaded product. This kneading material is extruded and granulated by a hanging basket type granulator (畑铁工所) with an extrusion straight 24 201008488 shuttle 0 0.9mm, and then used a needle mill (self-carrying machine, dry field production and drying) After drying (manufactured by pQwlex), it was sieved to obtain the agrochemical granule of Example 7. This coarsely disintegrated material was carried out in the same manner as in Example 8 except that Nitto Carbonate was changed to NN200, and Comparative Example 5 and Victory __ parts by weight, spleen from the mine*). The weight of the silk juice mixer is mixed with the Fl rib (metriff) micropowder B 1891 parts by weight, amyl〇x = A, _on Comstarch) 50.0 parts by weight, s〇Rp〇L 5〇8〇 (Dongbang Chemical Yang Yusheng) 750.9 parts by weight of Gwangsan Hearts S (manufactured by Kwong Kwong Mining Co., Ltd.) was mixed with a Nota type = machine (manufactured by F. Paudal) to obtain a mixed powder of 1 part by weight. The mixed powder was 1 part by weight with water. 22 parts by weight of the mixture was mixed and then kneaded by a Notal Mixer (manufactured by Pandal) to obtain a kneaded product. This kneading material is extruded by a hanging basket granulator (畑铁工所) j with a diameter of 00.9 mm, and is dried by a fluidized bed dryer. After drying, the needle mill is used. The crusher and the wilderness industry are coarsely crushed. This crude mash was sieved to obtain a pesticide granule of Comparative Example 5. Comparative Example c Take Furametpy micropowder A 189.1 parts by weight, AMYLOX No. 1A (NihonComstarch) 50.0 parts by weight, Bentonite Fuji (HOJUN) 502.9 parts by weight, SORPOL 5080 (Toho Chemical) 1 〇. 〇 by weight, win 248.0 parts by weight of Gwangsan clay-S (manufactured by Kyungsan Mining Co., Ltd.) was mixed with a Nota mixer (manufactured by Fuji Paudal Co., Ltd.) to obtain 1000 parts by weight of the mixed powder. 1000 parts by weight of this mixed powder was mixed with 22 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paudal) to obtain a kneaded product. This kneading material was extruded and granulated by a hanging basket type granulator (Nippon Iron Works) with an extrusion diameter of 0 〇 9 mm, dried with a fluidized bed dryer (manufactured by Powlex), and then a needle mill (self) 25 201008488 Pharmaceutical industry) Into the rough and broken. This coarsely disintegrated material was sieved' to compare

Furametpyr (calculated as active ingredient) AMYLOXNo.IA 9.2 9.2

Bentonite Fuji

20.0 20.0 5.0 5.0 60.0 SORPOL 5080 1.0 1.0 10.0

Shengguangshan CLAY-S 10.0 bal. bal. bal. Nitto calcium carbonate NN200 Total (W/W%) 100.0 100.0 100.0 100.0 Effective ingredient dissolution rate after 24 hours (%) Example 9 53.9 57.9 62.8 100.0 ❹ p S-allyl-5-amino-2-isopropyl-mono-tolyl-3-oxy-2,3_diindole-1Η-1-吼 thiosulfate citrate (hereinafter abbreviated as compound a)纯度 4 4 4 4 4 4 C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C C The pulverized material (hereinafter abbreviated as Compound A fine powder. The active ingredient content is 49.2%; the average particle diameter is 6.2 μιη °) ° The compound Α fine powder 40.7 parts by weight, AMYLOX No. 1A (Nihcm)

Comstarch) 50.0 parts by weight, Bentonite Fuji (HOJUN) 200.0 parts by weight, SORPOL 5080 (Toho Chemical) 1 〇. 〇 by weight, Shengguangshan CLAY-S (made by Shengguangshan Mining Co., Ltd.) 699.3 parts by weight of Nouta mixer ( Fuji Pauda@) was mixed to obtain 1000 parts by weight of the mixed powder. 1000 parts by weight of this mixed powder was mixed with 210 parts by weight of water, and then kneaded by a Nouta mixer (manufactured by Fuji pau (made by Jai) to obtain a kneaded product. This kneading 26 201008488 was used for a basket type granulator (iron iron) Extrusion granulation with an extrusion diameter of 00.9 mm. After drying with a fluidized bed dryer (manufactured by Powlex), a needle mill (free pulverizer,

The wilderness industry is carrying out rough unbroken. This coarsely pulverized material was sieved to obtain the granule of the pesticide of Example 9. Example A The same operation as in Example 9 was carried out using 40.7 parts by weight of Compound A fine powder, AMYLOX No. 1 AlOO.O parts by weight, Bentonite Fuji 20.0 parts by weight, SORPOL 5080 10.0 parts by weight, and Shengguangshan CLAY-S 829.3 parts by weight. The pesticide granule of Example A.

〇Example B The same operation as in Example 9 was carried out using 40.7 parts by weight of the compound A fine powder, AMYLOX No. 1 AlOO.O parts by weight, Bentonite Fuji 50.0 parts by weight, SORPOL 5080 10.0 parts by weight, and Shengshan CLAY-S 799.3 parts by weight. The pesticide granule of Example B was obtained. 'Comparative Example ό In addition to 40.7 parts by weight of the compound bismuth fine powder, 200.0 parts by weight of Bentonite Fuji, 30.0 parts by weight of GOHSENOL GL-05S, 10.0 parts by weight of SORPOL 5080, and 719.3 parts by weight of Shengongshan CLAY-S, the other was carried out in the same manner as in Example 9. ❾ In the same operation, the pesticide granule of Comparative Example 6 was obtained. Comparative Example a The same procedure as in Example 9 was carried out except that 40.7 parts by weight of the compound A fine powder, 50.0 parts by weight of AMYLOX No. 1A, 600.0 parts by weight of Bentonite Fuji, 10.0 parts by weight of SORPOL 5080, and 299.3 parts by weight of Shengongshan CLAY-S were used. The pesticide granule of Comparative Example a was operated. Comparative Example b 40.7 parts by weight of the compound A fine powder, 5 parts by weight of AMYLOX No.lA (Nih〇n Comstarch), 10.0 parts by weight of SORPOL 5〇80 (Toho Chemical), and Kyungsan CLAY-S (Shengguangshan Mining Institute) 89.3 parts by weight was mixed by a Nauta mixer Paudal) to obtain a mixed powder looo parts by weight. This mixed powder was mixed with 190 parts by weight of water and then mixed with a Norit mixer (manufactured by Fuji Paudal). 27 201008488 Π=2 machine ί: industry). This coarse disintegration 2 lines:

实施 Example c Mixing 50. 0 parts by weight of Tricyclazole (purity 97.8%) with 50.0 parts by weight of Shengongshan CLAY-S (manufactured by Shengguangshan Mining) with a juice blender, and then using this mixture The pulverization was carried out by a rotary mill (Rotor mill) to obtain a pulverized material (hereinafter abbreviated as Tricyclazole fine powder. The active ingredient content was 48.9%; the average particle diameter was 7.2 μιη.). Take 40.7 parts by weight of Tricyclazole micro powder, 50.0 parts by weight of AMYLOX No. lA (Nih〇nComstarch), Bentonite Fuji (H〇JUN) 200.0 28 201008488 • Parts by weight, SORPOL 5080 (Toho Chemical) 10.0 parts by weight, win 69.3 parts by weight of Gyeongsan CLAY-S (manufactured by Kwong Kwong Mining Co., Ltd.) was mixed with a Norit mixer (manufactured by Fuji Paudal) to obtain 1000 parts by weight of the mixed powder. 1000 parts by weight of this mixed powder was mixed with 2 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paudal) to obtain a kneaded product. This kneading material was subjected to extrusion granulation by a basket type granulator (畑铁工所) with an extrusion diameter of 0 〇.9 mm. After drying with a fluidized bed dryer (manufactured by Powlex), a pin mill was used ( The free crusher and the wilderness industry are used for rough breaking. This coarsely pulverized material was sieved to obtain a pesticide granule of Example C. Comparative Example d 4 40.7 parts by weight of Tricyclazole micro powder, 50.0 parts by weight of AMYLOX No.lA (Nihon Comstarch), SORPOL 5080 (Toho Chemical) 1 〇. 〇 by weight, Shengguangshan CLAY-S (Shengguangshan Mining) 89.3 parts by weight of the mixture was mixed with a Norit mixer (manufactured by Fuji Paudal) to obtain 1000 parts by weight of the mixed powder. 1000 parts by weight of this mixed powder was mixed with 200 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuy • Paudal) to obtain a kneaded product. The kneading material is used in a basket type granulator (畑铁工所), and is extruded and granulated at a diameter of .9 mm, dried by a fluidized bed dryer (manufactured by Powiex), and then a needle mill. (Free pulverizer, Takino industry) for rough smashing. This crude mash was sieved to obtain a pesticide granule of Comparative Example d. EXAMPLES Comparative Example cd Tricyclazole (calculated as active ingredient) 2.0 2.0 AMYLOXNo.IA 5.0 - . 5.0 Bentonite Fuji 20.0 1 SORPOL 5080 1.0 1.0 Shengguangshan CLAY-S Bal --- bal Total (W/W% ) 100.0 100.0 ------------- 29 201008488 Dissolution rate of active ingredient after 24 hours (0/〇) 54.8 100 Dissolution rate of active ingredient after 72 hours (〇/〇) 63.3 100

Example D 50.0 parts by weight of Futhalide (Sumitomo Chemical, purity 99.3%) and 50.0 parts by weight of Shengyinshan CLAY-S (manufactured by Shengguangshan Mining Industry Co., Ltd.) were mixed with a juice mixer. The pulverization was carried out by a rotary sacrificer (R〇t〇r miu) to obtain a pulverized material (hereinafter referred to as "Futhalide" fine powder. The active ingredient content was 49.7%; the average particle diameter was 6.8 μm.). Take 40.2 parts by weight of Futhalide powder, 50.0 parts by weight of AMYLOX No.lA (Nihon Comstarch), 200.0 parts by weight of Bentonite Fuji (HOJUN), ❹ SORPOL 5080 (Toho Chemical) 1 〇. 〇 by weight, Shengguangshan CLAY- s (manufactured by Seomyeon Mining Co., Ltd.), 699.8 parts by weight, which was prepared by a Nauta mixer Paudal, was mixed to obtain 1000 parts by weight of the mixed powder. One part by weight of this mixed powder was mixed with 2 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paudal) to obtain a kneaded product. This kneaded product was extruded and granulated by a Thai basket granulator (畑铁工所) with an extrusion diameter of 00.9 mm. After drying with a fluidized bed dryer (manufactured by Powlex), a pin mill was used (free pulverization). The machine, the wilderness industry) carried out the rough disintegration. This crude mash was sieved to obtain the granule of the pesticide of Example D. , Comparative Example e 取 Take Futhlide powder 40.2 parts by weight, AMYLOX No. 1A (Nihon Comstarch) 5 〇.0 parts by weight, s〇 RP 〇 L5 〇 80 (Toho Chemical) 1 〇. 〇 by weight, win 899.8 parts by weight of Gyeongsan CLAY-S (manufactured by Kwong Kwong Mining Co., Ltd.) was mixed with a Nauta mixer (manufactured by Fuji Paudal Co., Ltd.) to obtain a mixed powder of iodine. 1 part by weight of this mixed powder was mixed with 200 parts by weight of water, and then kneaded by a Notal Mixer (4) 丨paudal). This kneading material was dried by a hanging basket type granulator (Nippon Iron Works) with an extrusion diameter of 00.9 mm, which was dried by a fluidized bed dryer p> 〇wiex, and then a pin mill ( The free crusher and the wilderness industry are used for rough breaking. This coarsely pulverized material was sieved to obtain a pesticide granule of Comparative Example e. 30 201008488 Table 8 Comparative Example e 2.0 5.0 1.0

Bal 20.7

Example----------Futhalide (calculated as active ingredient) 2.0 AMYLOXNo.IA -—^ 5 〇Bentonite Fuji---_ 20.0 SORPOL 5080 ---^ 10 Shengguangshan CLAY —S — Bal Total (WW%) ----------------- ---__ loo.o —-— 2nd active ingredient dissolution rate (%) 0 7曰The effective ingredient dissolution rate (°/〇) 9.2 100.0 The dissolution rate of the active ingredients in the above table, one taking the capacity of 500ml beaker into the water 300m, slowly under the water temperature 25±1〇c. 4Injecting pesticide granules into it, slowly disturbing at a water temperature of 25±rC: After the set granules are put into the pesticide, the water in the beaker is taken 5 〇〇μ1 by high-speed liquid chromatography to calculate the pesticide. The concentration of the active substance. The active ingredient is dissolved in the beer by the concentration of the pesticide active material and the amount of the active substance contained in the used pesticide granule. Further, the dose of the pesticide used in the dissolution rate of the active ingredient is determined as the amount of the active ingredient of the pesticide as follows. Ferimzone: 400mg Furametpyr: 130mg Compound A: 76mg Izozosulfuron: 225mg nicotine iClothianidin): 850mg Tricyclazole: 750mg Futhalide: 13 mg 31 201008488 [Industrial Applicability] According to the present invention, a pesticide granule capable of suppressing the dissolution of an active ingredient of a pesticide in water and capable of sustaining the active ingredient of the pesticide for a long period of time can be obtained. [Simple diagram description] None [Main component symbol description] None

32

Claims (1)

201008488 VII. Patent application scope: L A pesticide granule containing pesticide active ingredient, pregelatinized starch, and bentonite, and gelatinized glutinous powder. The active ingredient of the pesticide is 20. (: the partition coefficient of octanol/water with a solubility of water of less than 20 C is in the range of 14 to 3.5, 'and the amount of bentonite is 2 〇~2 as compared with 100 parts by weight of pregelatinized starch. The pesticide granule of the first item, wherein the total amount of the weight, the total content of the pregelatinized starch and the bent soil is 5 to 45. In the agricultural granules ❹ 3·If the towel, please use the pesticide or the auxiliary of the second or the second Q-type surfactants. 3 Non-ionic drugs: Agrochemical granules according to any one of items 1 to 5, wherein the agricultural = knives are selected from Perimzone, Furametpy, and three赛azole (r^ydazole^, futhalide, and s_allyl_5_amino-2-isopropyl i group ϊί oxy-2,3—two gas—1Hm one formic acid vinegar The pesticide granules of the Yueshi 7ΐ patent application scope 1 to 5, wherein the active ingredient of the farm music is Ferimzone. 33 201008488 IV. Designated representative map: (1) Representative representative map of the case For: No (2) Simple description of the symbol of the representative figure: No. 5. If there is a chemical formula in this case, please reveal the chemical formula that best shows the characteristics of the invention: No 20100 8488 _ towel request Chinese manual and patent application scope revision (report) - γ.-λϊ- « · ..-, ^ invention patent specification; 1 ° funding Pf revision (this specification format, order 'do not arbitrarily Change, ※mark department 埴^) ※Application number: ※Application曰: (爹※1PC Classification:1^^2006.011, invention name: (Chinese/k) Pesticide granule GRANULATED AGRICHEMICAL II. Chinese abstract: 〇本The invention relates to a pesticide granule comprising an active ingredient of a pesticide, a pregelatinized starch, and a bentonite, wherein the active ingredient of the pesticide has a solubility in water of less than 700 mg/L at 20 ° C and In the range of 20. (the octanol/water partition coefficient is in the range of 1.4 to 3.5) relative to 1 part by weight of the pre-gelatinized powder, the benton content is 20 to 800 parts by weight; the pesticide granule can suppress The dissolution of the active ingredient of the pesticide in water can sustain the effect of the active ingredient of the pesticide for a long time. III. English Abstract: ❹ A granulated agrichemical containing an agrichemical active component, an -starch (prege Latinized starch) and bentonite, wherein the agrichemical active component has a water solubility at 20°C of less than 700 mg/L, and an octanol-water distribution coefficient at 20°C within a range from 1.4 to 3.5, and the amount of The bentonite is within a range from 20 to 800 parts by weight per 100 parts by weight of the pregelatinized starch is resistant to water elution of the agrichemical active component, and therefore the effect of the agrichemical active component can be « maintained over a long period 201008488 VI. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a pesticide granule. [Prior Art] A method of inhibiting the dissolution of an active ingredient of a pesticide in water by a method of coating a pesticide granule. SUMMARY OF THE INVENTION The present invention provides a pesticide granule capable of inhibiting the dissolution of agricultural mites and capable of sustaining the chemical component of the agricultural (four) effect component in water for a long period of time. The contents of the present invention are as follows: [1] Pesticide granules The agent contains the active ingredients of the pesticide, pregelatinized starch, and bentonite, and the solubility of the knife component in the water is less than that, and the octanol/water ratio at 20C is a compound. For the range of 丨4~3 5, the content of bentonite is 2〇~8〇〇 parts by weight relative to 丨(8) parts of pre-gelatinized temple powder. The agrochemical granule according to the above item [1], wherein the total content of the pregelatinized starch and the expanded soil is from 5 to 45% by weight based on the total amount of the pesticide granule. [3] The agrochemical granule according to the above [1] or [2], which contains a nonionic surfactant. The agrochemical granule of any one of the above [1] to [3], wherein the load hardness is 350 g or more. [5] The agrochemical granule according to any one of the above [1] to [3] wherein the load hardness is 350 g or more and 10 kg or less. [6] The agrochemical granule according to any one of [1] to [5], wherein the pesticide is effectively selected from the group consisting of Ferimzone, Furametpyr, and Sansaiqi ( Trie yclazole), Futhalide, and S-allyl-5-amino-2-isopropyl-4(2-tolyl)-3-oxy-2,3-dihydro- 111-pyrazole-1-thiocarboxylic acid vinegar (s_aityi_5_ami no-2-isopropyl-4-(2-methylphenyl)-3-〇x〇- 2,3-dihydro-ΙΗ-pyrazole 201008488 -l-carbothioate) In the group, the 'pesticide is effective as m as above _~[5]. Divided into Fermizone (Ferimzone). Morning Disinfectant [Embodiment] The pesticide granule of the invention (hereinafter referred to as the pre-gelatinized temple powder, and the bentonite, the agricultural material W is the active ingredient of the second chenchen, and the solubility to water is less than that of the isolated H^2 active ingredient. In the range of 2 〇 ° C 4 to 3.5, the relative / 1 octanol / water partition coefficient is 1. ~ 800 parts by weight. Reset the pre-gelatinized woman, the benton content is 20 octanol / water partition coefficient It is commonly referred to as the L value. Hereinafter, the octanol/water partition coefficient is abbreviated as a physical coating effect of the iLo/p ration, and the method of dissolving in water is generally employed as a resin effective point method. _It has the effect of inhibiting the pesticide coating. The effect of the knife on the water towel is dissolved. Therefore, the money of the invention _ does not need to be wrapped with a resin. Therefore, a form of the granule is, for example, the non-tree's system contains the active ingredient of the agricultural product. And the bentonite _., the above-mentioned agricultural financial effect ingredients in the thief dissolves in water ίi 'and in the 20 c octanol / water partition coefficient of 1,4~3.5, the meter in the pre-gelatinized starch 100 weight The content of the bentonite is 20 to 800 parts by weight. 0 The active ingredient of the pesticide used in the present invention is 2 (rc to water) The solubility is less than 70 di-τ and t is in the range of L〇g P of 2〇^, which is 1, 4 to 3.5. The insecticide can be effectively exemplified by the insecticidal compound, the bactericidal compound, and the herbicidal compound shown below. - The active ingredient of the pesticide used in the present invention may, for example, be (1) effective in the range of 2 (TC is less than 100 mg/L for water, and the range of LGg P is 4 to 3 5) Ingredients; and (2) in 2〇. (: solubility in water is 2〇〇mg/L or more, less than 700mg^L ' and pesticides in the range of 2〇t^L〇gp 4~3 5 The active ingredient of the granules is usually 0.1 to 25 parts by weight, preferably in the range of 201008488 * 0.5 to 15% by weight. The insecticidal compound used in the present invention may, for example, be as follows. Common name: Bifenazate [Chemical name: 3-(4-methoxybiphenyl-3-yl) isopropyl methacrylate <isopropyl 3-(4-methoxybiphen-3-yl) carbazate>; Water solubility: 2.06mg/L (20°C), Log P: 3.4 (25. (:, pH7)], common name: Diazinon [Chemical name: 〇2- 2-isopropyl-6-methyl bite -4- base代 二 二 二 二 dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj dj Common name: Bensultap [chemical name: s, S, 2-diamine-aminotrimethylene sulfonate) S, S'-2-dimethylaminotrimethylene di (benzenethiosulfonate) ) > Water solubility: 〇.44811^(20. 〇, Log P : 2. 28(25°〇] &gt; Common name: Fenitrothion [Chemical name: 0-4-nitro-m-tolyl-thiocaline 0,0-dioxin vinegar 〇, 〇-dimethyl O-4-nitro camp tolyl phosp horthioate>; water solubility: 14mg / L (35 ° C), Log P: 3.43 (20. 〇), common name: Fuhuali (Fluvalinate) [chemical name :RS-α-cyano-3-phenoxybenzyl-N-(2-chloro-a, a, a-trifluoro-p-tolyl)-DL-proline (RS-a-cya no-3) - phenoxybenzyl N-(2-chloro-a, a, a-trifluoro-/?-tolyl)-DL-valinat ❹ e>; water solubility: 30 mg/L (20 ° C), Log P : 2.9], common name : Fosthiazate [Chemical name: (rs)-S-di-butyl sulfonium-ethyl 2-oxy-1,3-thiazolidine-3-yl thiophosphinate <(Rs) -S-sec-buty 1 0-ethyl 2-0X0-1,3_ thiazolidin-3-yl phosphonothioate>; Water solubility: 9.85 g/L (20 ° C), Log P: 1.68], Common name: DMTP [Chemistry Name: S-2,3-dihydro-5-nonyloxy-2-oxy-1,3,4-thiadiazol-3-ylindenyl-indole, indole dimethyl dithiophosphate <s_2,3_dih ydro-5-methoxy-2- 〇xo-l,3,4-thiadiazol-3-ylmet Hyl G, O-dimethyl p hosphorodithioate > water solubility: 200 mg / L (25t:), Log P : 2.2], common name: Pyraclophos [chemical name: (rs)-[0-1-(4- Chlorophenyl)pyridinium-ylindole-ethyl=S-propyl=thiol acid vinegar]<yang)_[〇小(4_ 201008488 chlorophenyl)pyrazol-4-yl 0-ethyl=S-propyl= Ph〇sphorothioate]); Water solubility: 33mg/L (2(TC), Log P: 3.77(20.〇), Common name: Thiodicarb [Chemical name: 3,7,9,13-14 Mercapto- 5,11-dioxa-2,8,14-trithio-4,7,9,12-tetraazapentadecano-3,12-diene-6,1 0-dione 3,7,9,13-tetramethyl-5,ll-dioxa-2,8,14-trithia- 4,7,9,12-te traazapentadeca -3,12-diene -6,10-dione>; water solubility : 22.2gg/L (25. 〇, Log P: 1.62], the bactericidal compound used in the present invention may, for example, be the following compounds. Common name: Benomyl [Chemical name: 1-(butylamine-methyl sulfhydryl) Ben y 11 -2-yl-carboxylic acid 曱g for <methyl l-(butylcarbamoyl)benzoimida zol -2_yl carbamate> Water solubility: 2.9 gg / L (room temperature, pH 7), Log P: 1. 37], Common name: Bosclid (Chemical name: 2-gas-N-(4,-chlorobiphenyl-2) -based) final test guanamine <2-chl〇r〇-N-(4,-chl〇r〇biphenyl-2-yl) nicotinamid e>; water solubility: 4.6 mg / L (20 ° C), Log P : 2.96], Common name: Captan [Chemical name: N-(trichlorosulfonylthio)cyclohexyl-4-en-1,2-dicarboxyarmine imine <N-(trichlorome%lthi〇 )cyclohex-4-ene -1,2-dicarboxyimide>; water solubility: 3.3 mg/L (25t:), Log P: 2.8 (25. 〇] ', common name: TPN [chemical name: tetrachloroisoindole <tetrachl〇r〇is〇phtha lonitrile>; water solubility: 0.81mg/L (25t:), L〇gp: 2 see (7) it)], common name: Cyazofamid [chemical name: kernel chlorine - 2_Cyano-N,N-dimethyl-5-p-tolylimidazole-1-p-tolylimidazol-l-sulfonamide&gt;; : 0.107ppm (20 °C, pH7), Log P: 3.2 (25.〇), Common name: Diethofencarb [Chemical name: 3, isopropyl diethoxyanilinyl isopropyl acrylate <isopropyl 3,4- Dieth〇xyCarbanilate〉; Water Solubility: 27 64mg/L (25〇C) ' Log P : 3.02] ' Common Name: Nitrile Sulfate (DMlian〇n) [Chemical name Oxynaphthalene bH, 4-dipropene _2,3_dimethyl guess 'over 201008488 / L (20 ° C, pH 7), Log P : 3.2], common name: Fenbuconazole [chemical name: 4♦ gas phenyl) - 2-benzene Base-2-(mu,4:tris-kappamethyl)butyronitrile <br><br><〇phfnyt^ henyl Mm-U'^tnazoUylmethyDbutyronitrile>Water solubility: 3.7 7mg/L (25〇C) ' Log P : 3.23(253⁄4)] ' a pass name · although fine (Ferimzone) [chemical name: (minute _2, _ methyl acetophenone 4,6-dimercaptopyrimidine - 2-based 肼 < ( z&gt;2,-methylaeet()phen()ne 4,6_ pyrimidin-2-ylhydrazine>; water solubility: 2〇8 mg/L. L 2 89(25 °〇] ' ❹ Common name: Fluoroimide [Chemical name: 2, 3, a chlorine, a correction, fluorophenyl, maleimide, <2,3-(1,1〇1:〇-乂41_1)1^111^111); Water solubility: 0.611 mg / L (20 ° C, pH 5.4), Log P: 3.04 (25. 〇), common name: chlorosulfur (Flusulfamide) [chemical name: 2, 4_ two gas _α α α_ Three gas ~4,-nitro-m-phenylene sulfonate aniline <brown mtrom-toluene sulfonanilide> also water solubility: usmg/LpOt:, ρΗ6.3), Log P: 2.8] &gt; Common name: Flutolanil [chemical name: α,α,α_trifluoro-3,-isopropoxy oxo oxime 醯 本 本 〈 〈 <a, a, a-trifluoro-3'- Isopropoxy-c&gt;- toluanilid e>; water solubility: 8.01 mg/L (2 (rC), Log P: 3·17], common name: Furametpyr [chemical name: (rS)_5_chlorine- Ν_(ΐ, 3-dihydro-1,1,3-tridecylisobenzofuran-4-yl)_ι,3__dimethylpyrazole_4_;e carbonized guanamine <foot)-5- vomit 1〇1'〇.(1,3-(1%〇〇-1,1,3-衍11^_5(^·^^- 4-ylH,3-dimethylpyrazole -4-carboxamide>; water solubility: 200mg /L(2 〇〇C), Log P : 2·36(250〇], Common name: Fthalide [Chemical name: 4,5,6,7-tetrachlorolactone <4,5 ,6,7_tetrachloro phthalide>; Water solubility: 2.5mg/L (25°C), Log P: 3.01], Common name: IBP [Chemical name: 〇, 〇1 isopropyl thiophosphoric acid S-benzyl ester <S-benzyl 〇, 〇_diisopropyl phosphorothioate>; water solubility: 0.54g / L (2 (TC), Log P: 3.37 (20 〇 C, pH7)], 201008488 Common name: Iprodione [Chemistry] Name: 3-(3,5-Dichlorophenyl)-N-isopropyl-2,4-dioxyimidazole. 1-Hydrazine amide <3_(3,5-also 111〇]*〇卩1^1^1)-N-isopropyl-2,4-dioxoimidazolidine-1-carboxamide>; Water solubility: 1 3 mg/L (20 ° C), Log P: 3 (pH 5)], Common name: Asian So (Isoprothiolane) [chemical name · · ι, 3 dithiopenta-2-ylmalonate diisopropyl <diisopropyl l,3-dithiolan-2- ylidenemalo nate>; water solubility: 48.5mg / L (20 ° C), Log P: 3.3 (25. (::)], common name: Kresoxim-methyl [chemical name: (e)_2_methoxyimino-[2-(2-(o-phenanthryloxy)phenyl)] <methyl (E)_2_met hoxyimino-PO-tolyloxymethyl) phenyl]acetate>; water solubility: 2mg / L (20 ° C), Log P: 3.4 (25 ° C, pH 7)], common name: extinction林(Mepanipyrim) [Chemical name: n~(4-methyl-6-propargyl-1-yl"" benzophenan-2-yl) aniline <1\[-(4-1116%1-6屮屮-1 -丫1171{plus 11 version 11- 2-yl)aniline>; water solubility: 2.08mg/L (2(TC, pH7) ; Log P : 3 28(20 °〇] ' · Common name: 灭达乐( Metalaxyl) [Chemical name: N-(曱ethoxyethyl)-N-(2,6-dimethylphenyl)-DL-alanine decyl ester <1!16脚1&gt;^(11^11(^&amp;〇6墓1)-&gt;1-(2,6-xylyl)-DL-alaninate>; Water solubility: 8.4 mg/L (22〇C); Log P: 1 75], ' Ordinary name: Metominostrobin [Chemistry Name: nonoxynimido)-N-mercapto-2-(2-phenoxyphenyl)acetamido <(E)-2-(methoxyimino;)-]Sr_methyl-2 -(2-phenoxyphenyl)acetamide 〉; Water solubility: 〇.i28g/L (2(TC) ; Log P : 2.32(20°〇], normal Name: Myclobutanil [Chemical name: 2-p-chlorophenyl-2-(1H-1,2,4-tris-7-ylmethyl)hexanenitrile <2-/&gt;-chlorophenyl-2 -(lH_l,2,4-trizo 1-1- ylmethyl) hexanenitrile>; water solubility: I32mg/L (2(TC), Log P: 2.94 (25〇C, pH7~8)], common name: PefUrazoate [Chemical name: n-mercapto-N-imidazolium-1 -yl-yl-DL-high-alanyl penten-4-yl ester <pent-4-enyl N-fUrfuryl_N_i midazol-l-yl carbonyl - DL-homoalaninate> water solubility: 443 mg/L (2 201008488 Fli application Chinese manual revision page and patent pending patent revision (no /L(25 C) » Log p : 3.14(26〇C)] ' One common name: Pyroquilon [Chemical name] :1 2 5 6_·tetrahydropyrrole 7 and [3,2,1-W quinoline-4-one <l,2,5,6-tetrahydropyrr〇l〇[3,2,l-ij] quinolin- ' 4_one>; water solubility: 4g/L (2(TC); Log P: 1-6), common name: Tricyclazole [chemical name: 5-mercapto-1,2,4-trimium [3,4-b] phenylthiazolidine <5-methyl-l,2,4-triazolo[3,4-b] benzothiazol e>; water solubility: 596.596g/L (2(TC); Log P : 1· 42], Common name: Thiophanate-methyl [Chemical name: dimethyl 4,4 ~ (o-stranded) bis (3-thioadenic acid vinegar) <dimethyl 4,4'- (o-phenylene) bis bis(3-thioallophanate)〉; Log P : 1.5], Common name: Thiram [Chemical name: tetramethylthiuram disulfide]; water solubility: I8mg /L (room temperature); Lo g P: 1.73], . . , chemical name: S-propylpropyl 5-amino-2-isopropyl~4-(2-indolylphenyl)-3-oxo Base 2,3--wind-1H-1 0 sulphuric acid sulphate <S-allyl-5-amino-2-isopropyl-4, (2-methylphenyl) -3-oxo-2,3-dihydro -lH-pyrazole-l-carbothioat e>; water solubility: 20 mg/L (20 ° C); Log P: 3.2 The herbicidal compound used in the present invention may, for example, be the following compound. 'Ordinary name: grass net (Atrazine) [Chemical name: 6-gas-N2-ethyl-N4-isopropyl-1,3,5-three B well 2,4-diamine <6-chloro-N2-ethyl-N4-isopropyl- l,3, 5-triazine 2,4-diamine>; Solubility: 33 mg/L (water, 22 ° C, pH 7); Log P : 1.6 (25 ° C)], Common name: Freesulfur (BensulfUron-methyl ) [Chemical name: a-(4,6-dimethoxypyridin-2-ylamine-carbamoylsulfonyl) methyl o-toluate <methyl a-(4,6-dimethoxy pyrimidin-2- Yl carbamoylsulfamoyl)-〇-toluat e>; water solubility: 67 mg/L (25 ° C, pH 7); Log P: 2.18 (25 ° C, pH 5)], common name: Cyclosulfamuron [chemical name: 1-[2-(cyclopropyl)phenylaniline yellow-branched]-3-(4,6-dimethoxy-n-butyl-2-yl) gland <l-[2-(cyclopropylylcarbonyl)phenylsulfamoyl] - 3-(4,6-dimethoxypyri Midin-2-yl)ure a>; Solubility: 6.52 ppm (water, 25 ° C, pH 7); Log P : 1.41 (25 ° C, pH 7)] 201008488 • 5°〇; Log P : 3] &gt; Ordinary Name: Procymidone [Chemical name: n~(3,5-dichlorophenyldimethylcyclopropane-1,2-dicarbenium imine) <N-(3,5-dichloiOpheiiyl:) -l , 2-dimethyl cyclopropane -l, 2-dicarboximide>; water solubility: 4.5 mg / L (25 ° C); Log P : 3.14 (26 ° 〇] ' Also common name: Pyroquilon [Chemical name: ;[,2,5,6_tetrahydropyrrolo[3,2,1-ij]quinolin-4-one <l,2,5,6-tetrahydropyrr〇l〇[3,2,l_ij] qUin〇 Lin- 4- one&gt;; water solubility: 4g / L (2 (TC) ; Log P : 1.6], common name: Tricyclazole [chemical name: 5-mercapto_ι, 2, 4-three Salivary [3,4-b]benzothiazole <5-methyl-l,2,4-triazol〇[3,4-b] benzothiazol ® e〉; water solubility: 596.596g/L (20°C) Log P : 1.42], common name: Thiophanate-methyl [chemical name: dimercapto 4,4'-(o-phenylene) bis(3-thiourea citrate) Dimethyl 4,4,-(tKphenylene) Bis(3-thioallophanate) ) ; Log P : 1.5], Common name: Thiram [Chemical name: tetramethylthiuram disulfide]; water solubility: I8mg/L (room temperature) ;Lo g P : 1.73], Chemical name: S-allyl 5amino-2-isopropyl-4-(2-tolyl)-3-oxy-2,3-dihydro-1H-1 〇 唾 唾 唾 〈 〈 〈 唾 唾 唾 唾 唾 唾 〈 〈 〈 唾 〈 〈 〈 〈 〈 〈 唾 〈 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾 唾: 20 mg / L (; 2 ° ° c); Log P : 3.2 The herbicidal compound used in the present invention may, for example, be the following compound. Common name: Atrazine [chemical name: 6-chloro-N2-ethyl-N4-isopropyl-1,3,5-three-dimensional well 2,4-diamine <6-chloro-N2- ethyl-N4-isopropyl-l,3,5-triazine 2,4-diamine>; Solubility: 33 mg/L (water, 22. (:, pH 7); Log P: 1.6 (25. 〇), Common name: Free Bensulfuron-methyl [chemical name: α-(4,6-dioxaoxyguanidine-2-ylamine decylamine sulfonyl) o-toluene decanoate <methyl a-(4, 6-dimethoxy pyrimidin-2-yl carbamoylsulfamoyl)-〇-toluat e>; water solubility: Wmg/LpSt:, pH7); Log P: 2.18 (25t:, pH5)], 9 201008488 Common name: Flumioxazin [Chemical name: N-(7-Fluoro-3,4-dihydro-3-oxy-4-desyl-2-yl-2H-1,4-benzopyrylo-[6-yl]cyclohexan-1- N-(7-fluoro-3,4-dihydro-3-ox〇-4-prop-2-ynyl-2H-l,4-benzox azin-6-yl )cyclohex -l-ene-l,2-dicarboxamide>;water solubility: 1.79mg/L (25.〇; Log P: 2.55), common name: Fluometuron [chemical name: 1,1-two Mercapto-3-(α,α,α-trifluorom-tolyl)urea l l,di-meth Yl-3-(a, a, a-trifluoro-m-tolyl) ure a&gt;; solubility: 110 mg/L (water, 20 ° C); Log P: 2.38], common name: Fluthiamide [chemical name: 4, -Fluoro-N-isopropyl-2-[5-(trimethylsulfonyl)-1,3,4-thiodiin-2-yloxy] acetanilide <f-fluoro-iSMsopr opyl-2 -(5-trifluoromethyl-l,3,4-thiadiazol-2-yloxy] acetanilide>; Water solubility: 56 mg/L (25 ° C, pH 7); Log P: 3.2 (24. 〇), Common name: Isoxaflutole [ Chemical name: 5-cyclopropyl-1,2-B-mercapto-α, α,α-difluoro-fluorenyl-p-phenylene ketone <(5-cyclopropyl-l,2-oxazol~4- Yl) (a, a, a-trifluoro-2-mesyl-p-tolyl) ketone>; water solubility: 6.2 mg/L (20 °C 'pH 5.5); Log P: 2.34] ' Common name: fenfen Mefenacet [Chemical name: 2-(l,3-benzopyridin-2-yloxy)-N-mercaptoacetanilide <2-(l,3-benzothiazol-2-yloxy)-N -methy 1 acetanilide>; Solubility: 4 mg/L (water, 20. P; Log P : 3.23], Common name: Metribuzin [Chemical name: 4-amino-6-tertiary butyl-methylthio] 1,2,4-trimium~5-(411 )-keto <4-amino-6-such as &quot;i-butyl-3-meth ylthio- l,2,4-triazin -5-(4H)-one>; water solubility··i.〇5g/L ( 20 ° C); Log P : 1.6 (20 ° C, pH 5.6)], common name: Norflurazon [chemical name: 4_ gas -5_methylamino 2 - (α, α, α-difluoro甲哄)-3(2Η)-ketone <4-chloro-5-methylamino-2-(a, a, a-tri fhiOT(Ww-tolyl)pyridazin-3(2H)-one>; water Solubility: 34 mg / L (25 ° C); L og P : 2.45 (25 〇 C &gt; pH 6.5)] ' Ordinary name: herbicide (propanil) [chemical name: 3,, 4, _ two gas propylene Benzene <3',4'-dichloro propionanilide>; Water solubility: i3〇mg/L (20〇C); Log 201008488 Common name: Cyclosulfamuron [Chemical name: ι_[2_(cyclopropyl) Benzenesulfonyl]-3~(4,6-dioxaoxypyridyl-2-yl)urea <H^ydoprop ylcarbonyl) phenylsulfamoyl]-3-(4,6-dimethoxypyrimidin-2-yl)ure a 〉' &gt;glutination degree. 6.52ppm (water, 25 C, pH7); Log P : !.4i(25°c, pH7)] Common name: Flumioxazin [Chemical name: N—(7—gas-3,4_dichloro_3-oxy-4-propanyl-2-yl-MM- Benzopyrene ruthenium) Cyclohexyl bromide-dicarbonated decylamine <N-(7-fluoro-3,4-diliydro-3-ox〇-4-prop-2-ynyl -2H-l,4- Benzox azin-6_yl)cyclohex -l-ene-l,2_dicarboxamide>;Water solubility: i.79mg/L (25°〇; Log P : 2.55] ' Common name: Fluometuron [Chemical name: 1] L-dimercapto- 3-(a, a, a-trifluorom-phenyl)urea <l,l-dimethyl-3-(a,a,a_trifluor〇-w_toly1)ure a&gt;; solubility: 110 mg/ L (water, 20 ° C); Log P : 2.38], common name: Fluthiamide [chemical name: 4'_fluoro-N_isopropyl-2_[5_(trifluoromethyl)-1,3,4- Thiadiazol-2-yloxy]ethenolidine <4,_£111〇][〇善4〇1)1: 〇pyl-2-(5-triflu〇r〇methyl-l,3,4 -tliiadiaZ〇l_2-yl〇Xy] acetaniiide>; water solubility: 56 mg/L (25 ° C, pH 7); Log P: 3.2 (24. 〇], Common name: Isoxaflutole [Chemical name: 5-cyclopropane-i, 2-ucarbazole 4-yl-α, α,α-trifluoro-2-indolesulfonyl-p-tolylone < l) (a, a, a-trifluoro-2-mesyl-/?4〇lyl) ketone>; water solubility: 6.2 mg/L (20 °C 'pH 5.5); Log P: 2.34] &gt; common name: extinction Mefenacet [Chemical name: 2-(l,3-benzopyridin-2-yloxy)-N-mercaptoacetanilide <2-(l,3-benzothiazol_2_yloxy&gt;N-methy 1 acetanilide) 〉; Solubility: 4mg/L (water, 20. 〇; Log P: 3.23), common name: Metribuzin [chemical name: 4-amino -6_tributyl -3- thiol -1,2,4-diindole-5-(4H)-_<4-amino-6-such as t-butyl-3-meth ylthio- l,2,4-triazin -5-(4H)-one&gt; Water solubility · · 1 〇 5g / L (20 ° C); Log P : 1.6 (20 ° C, pH 5.6)], common name: Norflurazon [chemical name: 4_ gas - 5 methylamino-2 One (α,α,α-two-money 曱 曱)) 3(2Η)~ ketone <4-chloro-5-methylamino-2-(a, a, a-tri 201008488 P : 3.3 (20 ° C )], a specific example of the active ingredient of the pesticide used in the present invention, such as s-dilyl 5-amino-2-iso -4. (2-Phenylphenyl)-3-methoxy-2,3-diaza-1H-thioformic acid vinegar, Fthalide, Ferimzone, Furametpyr And Tricyclazole. Commercially available pregelatinized starch can be used in the present invention. Commercially available pregelatinized starches such as AMY COL HF, AMYCOL C, AMYCOL KF, AMYCOL HG-N, A MYCOL BJ- 2, AMYCOL W, Starch MH-A, AMYCOL A, AMYCOL FW (曰 化学 化学), foraging Arusta (transliteration), eclipse Arusta (❹ Η translation), foraging Wackhi ( Transliteration) αα (曰本食品化工),ComaY,ComaS-1, industrial tapioca starch a, industrial tapioca starch αΤΡ-2, wheat starch aW A-105 (Sanhe starch industry), AMYLOX No. And AMYLOX Νο.1Α (Ν ihon Cornstarch). The bentonite is a clay mainly composed of montmorillonite. The present invention ‘commercially available bentonite can be used. Commercially available bentonites such as KUNIGEL VI, KUNIGEL V - 2, KUNIBOND (Kunimine Industries) 'Bentonite Miaoyi, Bentonite Fuji, Bentonite Asakusa, Bentonite Chicheng, Bentonite Anonymous (HOJUN), Shimane B entonite, Izumo Bentonite, Kansai Bentonite (KASANEN Industry ), MIZ UKA-ACE, BENCLAY (Yawazawa Chemical). In the granule, the ratio of the content of the pregelatinized starch to the benton is 20 to 800 parts by weight relative to 100 parts by weight of the pre-gelatinized powder, and 20 to 600 parts by weight is preferably 0 in the granule. The total content of the pregelatinized starch and the benton is usually about 5 to 45 wt%. Further, the granules may contain a solid which is not reactive with the pesticidal active ingredient and the pregelatinized starch contained in the granules and which is insoluble in water, and is used as an extender component. Such extenders include, for example, kaolinite, dickite, n acrite, halloysite, kaolin-type minerals, serpentine (you), and serpentine. (lizartite), serpentine (antigorite), townal alkaloid (leg esi te) and other serpentine, phytophyllite, talc, Shoushan stone (agalm minus (6), 11 201008488 * ^oro-WoWpyridazin-SpHO-one 〉; water solubility: 34mg/L (25〇C); L 〇g P : 2.45 (25〇C, pH6.5)], common name: weeding (Propanil) [chemical name: 3,, 4, - two Acetophene anilide &lt;3',4'-dichloro propionanilide>; water solubility: i3〇mg/L (2(TC); Log P: 3·3 (20°〇), the pesticide used in the present invention is effective Specific examples of the component, such as S-allyl 5-amino-2-isopropyl-4-(2-methylphenyl)~3-oxy-2,3-dihydro-1H-pyrazole-1 Fthalide, Fthalide, Ferimzone, Furametpyr, and Tricyclazole. Commercially available pregelatinized starch can be used in the present invention. Commercially available pregelatinized starch such as AM O COL H F ' AMYCOL C ' AMYCOL KF ' AMYCOL HG-N &gt; A MYCOL BJ-2, AMYCOL W, Starch MH-A, AMYCOL A, AMYCOL FW (曰淀化学), Foraging Arosta (transliteration), 曰Food Aruseta, eclipse Wacky-α (Japanese food chemical), c〇maY, c〇maS -1, industrial tapioca starch a, industrial tapioca starch ατρ— 2. Wheat starch aW A-105 (Sanwa starch industry) 'AMYLOX No.l, and AMYLOX No.lA (N ihon Cornstarch). The bentonite is a clay mainly composed of montmorillonite. Commercially available bentonites such as KUNIGEL VI, KUNIGEL V ❹ 2, KUNIB〇ND (Kunimine Industries)' Bentonite Miaoyi, Bentonite Fuji, Bentonite Asakusa, Bentonite Chicheng, Bentonite Anonymous (HOJUN), Shimane B entonite, Izumo Bentonite, Kansai Bent〇nite (KASANEN Industries), MIZ UKA-ACE, BENCLAY (Hawazawa Chemical). In the granules, the ratio of the pregelatinized starch to the bentonite is 20 to 800 parts by weight, preferably 20 to 600 parts by weight, based on 100 parts by weight of the pregelatinized starch. In the granules, the total content of the pregelatinized starch and the benton is usually from about 5 to 45% by weight. • In the present granules, a solid which is not reactive with the pesticidal active ingredient and pregelatinized starch contained in the granules and which is insoluble in water may be contained as an extender component. Such increase 11 201008488 Muscovite, phengite, sericite, mite and other mica, cristobalite, quartz and other meteorites, dolomite (d〇1 〇mite) and other carbonic acid minerals such as beidelite, nontronite, saponite, hectorite, smectite, saponite, chain bentonite, Stivensi Te synthetic smectite, magnesium sulphide (attapuigite), sepiolite (sepi〇Ute) and other hydrous dream magnesium minerals 'Gypsum (gypsum), gypsum and other sulfate minerals, ze〇lite (zeolite), / Fu Stone tuff (tuff), warp, rock, diat〇mite, and powdery tannic acid. In the granules, the total content of the pregelatinized starch, the bentonite, and other extender components is usually 75 to 99% by weight, and preferably 80 to 95% by weight. In the present granules, a surfactant, a binder, a stabilizer, a pigment, etc. may be contained. Regarding surfactants, such as polyoxyethylene alkyl ether, polyoxyethylene alkyl aryl ether, polyoxyethylene stearyl phenol ether, polyoxyethylene lanolin, polyoxyethylene alkyl phenol formaldehyde condensate, polyoxyethylene sorbent Sugar anhydride fatty acid ester, polyoxyethylene glyceryl mono fatty acid ester, polyoxyethylene propylene glycol mono fatty acid ester, polyoxyethylene sorbitol mono-fat acid ester, polyoxyethylene castor oil derivative, polyoxyethylene Fatty acid ester, higher fatty acid glyceride, sorbitan fatty acid ester, sucrose fatty acid ester, polyoxyethylene polyoxy-propylene late stage polymer, polyoxyethylene fatty acid decylamine, alcohol decylamine (alkyl 〇1 pool), a nonionic surfactant such as polyoxyethylene oxime amine; an alkylamine hydrochloride such as dodecylamine hydrochloride; d〇❹ decyltrimethyl ammonium salt; Dimethylbenzylammonium salt, alkyl pyridinium salt (alkyl pyridinium _, alkyl isoquinoline rust salt, dialkyl porphyrin salt, etc. alkyl quaternary salt, phenylethylammonium chloride, polyalkylene a cationic surfactant such as acetyl sulphate or sulphate; and a fat such as sodium palmitate Sodium, sodium polyoxyethylene lauryl ether carboxylate, sodium hydroxycarboxylate, ammonium succinate, sodium N-lauroyl glutamate, amino acid condensate, higher alkane sulfonate, Higher fatty acid ester sulfonate such as laurate sulfonate, dioctyl benzoate such as dioctyl benzoate, and higher fatty acid guanamine hydrochloride such as oleic acid hydrochloride Alkaryl aryl acid salts such as sodium benzoate and diisopropyl naphthoate, "" 12 201008488 For example, kaolinite, double kaolin (dickite), pearl clay (η ~ acrite) Kaolin-type minerals such as hallowysite, chrys〇t lie: ilzartlte, serpentine (sister gamma), magnesium-aluminum serpentine (orphan (4) te), etc. Serpentine 'leaf stone she-Qing threaten', talc, Shoushan stone (four) - such as), muscovite, phegite, sericite, imte, etc., meteorite (cristobalite), quartz and other meteorites, dolomite (d〇1〇mite) and other calcium carbonate minerals 'beidelite (beidellite), nontronite (nontronite) Sapphire (sapectite), smectite, hectorite, saponite, lithium bentonite, Stivensi te synthetic smectite, magnesium stellite (attapulgite), sepiolite (sepi 〇iite), such as aqueous magnesium minerals, gypsum, gypsum and other sulfate minerals, zeolite, tuff, tuff, vermiculite, pumice, diatomite, And © powdered tannic acid, etc. In the granules, the total content of the pre-gelatinized powder, the bentonite, and other extender components is usually 75 to 99% by weight and is 80 to 95% by weight. better. In the present granules, an adjuvant for preparations such as a surfactant, a binder, a stabilizer, and a pigment may be contained. About surfactants, such as polyoxyethylene alkyl ketone, polyoxyethylene aryl ether, polyoxyethylene stearyl phenol ether, polyoxyethylene lanolin, polyoxyethylene alkyl phenol formaldehyde condensate, polyoxyethylene Sorbitol fatty acid ester, polyoxyethylene glyceryl mono fatty acid ester, polyoxyethylene propylene glycol mono fatty acid ester, polyoxyethylene sorbitan mono fatty acid vinegar, polyoxyethylene castor oil derivative, polyoxyethylene fatty acid ester , higher fatty acid glycerides, sorbitan fatty acid esters, sucrose fatty acid esters, polyoxyethylene polyoxypropylene propylene block polymers, polyoxyethylene fatty acid decylamines, alkyl hydrazines (alkyl amides), polyoxygen A nonionic surfactant such as a vinyl alkylamine, an alkylamine hydrochloride such as laurylamine hydrochloride, d〇decyltrimethyl ammonium salt, alkyl dimethyl benzyl Alkyl ammonium salt, alkyl pyridinium salt, alkyl isoquinolinium salt, alkyl quaternary ammonium salt such as dialkyl sulphate salt, phenethyl ammonium chloride, polyalkyl ethylene D pyridine Cationic surfactants such as rust salts; and sodium sulphate Amino acid such as sodium laurate, sodium sulphate, sodium sulphate, sodium sulphate, sodium aryl glutamate, etc. - 12 201008488 Alkyl aryl phthalate High-alcohol ester esters such as fifteen-burning sulfuric acid ester, dimerized ethylene oxide, twelve polyoxyethylene, sulphur-based scales, styrene-maleic acid copolymer, etc. The surfactant generally contains 〜1 to 5 〇% by weight. ^ in a binder such as polyethylenic or a derivative thereof. For the preparation of the binder, the polyethylene can be used as a binder or a derivative thereof. Commercially available polyethylene glycol or its derivatives, such as G-type G〇SEN〇L, A-type ΟN-type G〇SENOL (Sakamoto synthesis, partially polymorphic p〇p OVAL, fully saponified POVAL (K_y). P In the granules, the binder usually contains 0·1~5.0 weight 〇/0. 2 agents, the production method is to add water to the mixture of the active ingredients of the pesticide, the pre-, the bentonite and the other components (4) , the sorghum will be granulated and then the granulation will be Wei Wei, and if necessary, smash = = etc. ^ When making _, the amount of water used _, the material = agricultural ί H, = starch Mixture of bentonite and other ingredients * 1 GG parts by weight, 10 to 40 parts by weight. 1 ps, granules of pinch mash, such as squeezing &amp; silk method. Pelletizing method _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The agent has a good grain length; the range of m is better by the extrusion method; (9) drying, especially (10) to 4.0 m, the kneading machine used in the manufacture of the agent such as kneading machine, Nouta uta nuxer , Rhedig mixer, etc. . As for the extrusion 诰0 machine (10) granulator, drum type fine granulator, dish type granule _ screw = extrusion type extrusion granulator, basket type granulator, knife pellet, Ϊΐ ί Granules, gear-type extrusion granulators, and multi-hole mode extrusion t-type extrusion granulators, such as Twin D_ Gfan 11 machine. Or, Basket Granulator, Pdleter Double (to 0me 3 coffee, KM, Dalton Co., Ltd. 13 201008488 - base acid condensate, higher alkane sulfonate, laurate sulfonate, etc.) Take acid, a vinegar, 4 squid, sequel, squid, acid, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate, sulphate Alkaryl sulphonate, furfural condensate of μ 1 alkyl aryl sulfonate, higher alcohol ester sulphate such as fifteen sulphuric acid sulphate, dimer oxyethylene decyl sulphonate An anionic surfactant such as polyoxyethylene phytate, styrene-maleic acid copolymer. 1 In the granule, the surfactant usually contains 〜1~5 〇% by weight. About the adhesive, such as polyethylene Alcohol or a derivative thereof. When polyvinyl alcohol or a derivative protein is used as a binder fiber, a commercially available polyethylene or a touch thereof, a commercially available polyvinyl alcohol or a derivative thereof such as a G type can be used. GOSENOL, GOGOSENOL, N-type GOSENOL (Japanese synthetic chemistry), partially saponified p〇VAL, Sinochem p OVAL, complete soap p〇VAL (of Kuraray;). In the granules, the binder generally contains 0.1~5.0 wt%. When the π u clothing is suitable for an ancestor, the amount of water used to run the kneading is as good as ‘. As for the extrusion granulator, such as a spiral extrusion disc type "pill extrusion granulator, pellet grinding 13 201008488", and a granulator (fine iron factory). As for the method of pulverizing and granulating, for example, a method of wet granulation by extrusion granulation with a Marumerizer (ball granulator, Dal ton), and dry granulation using a pulverizer such as a pin mill method. The granules obtained by the above-described production method have a load hardness of usually 2 〇〇 g or more, and more preferably 350 g or more and preferably '400 〜 l 〇〇〇 g. The load hardness of the granules can be adjusted by appropriately setting the ingredients of the granules, kneading conditions, and granulation conditions. The application of the granules can be carried out according to the general granulation method of granules. The granulation method is as follows: a manual granulation method, and a piggyback scatterer, a pipe granulator, an air granulator, a power granulator, a seedling box granulator, a grate machine, and the like. Granulator, multi-port hose granulator, rice transplanter and other granulators for spreading, and the granules can be used for: dry soil, seedling box according to the active ingredients or use purposes of the pesticides. Non-agricultural land such as dry land, orchards, mulberry gardens, greenhouses, open-pits and other forests, forests, grasslands, golf courses, street trees, roads, shoulders, wetlands, pools, reservoirs, rivers, waterways, sewers, etc. The granules may, for example, be as follows. A pesticide granule comprising an active ingredient of a pesticide and a nonionic surfactant, a pregelatinized starch, a bentonite, a &gt; valence Ϊ pesticide active ingredient in a machine-to-water solubility of less than 70〇111, and in 2 〇c octanol/water partition coefficient is in the range of 14~3 5 , Zhe in ϊ, paste powder (10) «parts' bentonite content is 20~_ parts by weight. And the non-ionic boundary active agent I 'the active ingredient in the water solubility is less than 7 〇〇 mg / L ' and in the range of 2 〇 c = alcohol / water partition coefficient u ~ 3 5, the powder just parts by weight, The content of bentonite is 20~qq parts by weight, and the weight of 5 heavy 3 in the amount of agricultural transport is _chemical and shame. The total content is 5~4 kinds of pesticide granules, which contain pesticide active ingredients, pre-gelatinized starch, and bentonite. 201008488=Specific examples of the production of the machine, the basket type extrusion extrusion granulator, the gear type granule granulator, and the oscillating extrusion granulator, such as the Twi garment mode extrusion granulator, etc. . Or ^ Basket Granulator ρΙΓ ΓΙ ^^ Product), 畑 granulator (畑铁工所沈〇U le (above Dalton Co., Ltd. merchants ^ Mammerizer (spherical granulator, Dal broken nmtsi recorded in the record) The grinding machine or the like solves the μ G ?^7Λ0^ hardness obtained by the above-described manufacturing method. 77 The kneading conditions, the granulation conditions, and the adjustment of the load of the granules are carried out by ίί== according to the general granulation method. Granulation method Κίί and using a knapsack spreader, a pipe spreader, an aerial spreader, a power spreader, a seedling box grinder, a ΓίΓ granulator, a transplanter attached to a grain spreader, etc. Machine 'Spreading ❹ =,, forest, grassland, golf course, row m pool, reservoir, river, waterway, sewer, etc. Non-agricultural land. Road shoulder wetland, about the granules, for example, the following And non-filament side effective age, face, and bentonite '2 (ΤγΪΪΪ财Λ into ί in 2Gt: the weight is less than 7GGm, and the octanol/water in 20 C is the ratio of L4~3.5 Within the range, relative to the paste powder 1GG parts by weight, the resident content is] ~_ granules 'The system contains pesticide active ingredients, pre-gelatinized powder, bentonite, and non-ionic surfactants. The mechanical age is 2Gt, and the octanol/water partition coefficient at 20 C is 1.4. Within the range of ~3·5, 14 201008488. The above pesticide active ingredient has a solubility in water of less than 7〇〇mg/L at 2〇°c and a partition coefficient of octanol/water of 20C within the range of 14~3 5 , the bentonite content is 2〇~8〇〇 parts by weight relative to 1 part by weight of the pre-gelatinized starch, and the active ingredient content of the pesticide is 2~5〇〇1 relative to 1 part by weight of the pre-gelatinized starch. A granule containing an active ingredient of a pesticide, a pre-gelatinized temple powder, and a bentonite, wherein the composition of the sinensis is less than 7GGl, and the partition coefficient of octanol/water at 20C is 14~3. Within the range of 5, the ginseng is 1 〇〇 to 8 〇〇 by weight relative to the pre-gelatinized starch, and the active ingredient content is 2 for the pre-gelatinized starch 1 G () by weight. ~500 垔heavy, 5 heavy than the pesticide auxiliary amount, the total content of pre-paste powder and benton is 5~4 β i diif granules' Contains pesticide active ingredients, pre-gelatinized powder, benton, and non-ionic surfactants. The pesticide age is 2 (rC material is less than the emblem ball, and the octanol/water partition coefficient in C is u~ Within the range of 5 5, 100 parts by weight of the pre-gelatinized temple powder, the benton content is 20-800 parts by weight, and the weight of the pesticide is 100% by weight of the pre-gelatinized starch, and the active ingredient content of the pesticide is 2 to 5 Å and non-detached. =^=丨@ is a pesticide containing effective age, _ starch, bent soil, the solubility of water in the water is less than 7〇〇mg/L, and the octanol/water partition coefficient is in the range of L4~3 5 100 parts by weight of pre-gelatinized starch, the content of bentonite is 20-800 parts by weight, and the weight of the active ingredient of the pre-gelatinized powder is 2~500 5 weights. The total content of sorrow and shame is 5~4 - a variety of pesticides _ ' contains agricultural and financial components, chiral starch, bentonite, 15 201008488 relative to 100 parts by weight of pre-gelatinized temple powder, the content of bentonite is 2〇~800 The total content of the pregelatinized starch and the bentonite is 5 to 45 wt% based on the total amount of the pesticide granules. A pesticide granule' contains a pesticidal active ingredient, pregelatinized starch, and bentonite. The above pesticide active ingredient has a solubility in water of less than 700 mg/L at 20 ° C, and an octanol/water partition coefficient of from 1.4 to 3.5 at 20 ° C, relative to 1 part by weight of the pre-gelatinized powder. The content of the bentonite is 2 to 8 parts by weight, and the content of the active ingredient of the pesticide is 2 to 500 parts by weight based on 100 parts by weight of the pregelatinized starch. ❹ - a kind of pesticide granules, containing pesticide active ingredients, pre-gelatinized temple powder, and bent soil, 7 Λ. The above pesticide active ingredient has a solubility in water of less than 700 mg/L at 20 ° C, and a octanol/water partition coefficient of C of 1.4 to 3.5, and a benton content relative to 1 part by weight of the pregelatinized starch. It is 2〇~8〇〇 parts by weight, and the active ingredient content of the pesticide is 2~500' in the summer, relative to 100 parts by weight of the pregelatinized starch. 5 ff mesh. For the total amount of pesticide granules, the total content of pregelatinized starch and benton is 5 to 4%. ❹ ; 5 ugly touch pesticide granules ' contains pesticide active ingredients, pre-gelatinized powder and long-lasting ionic surfactant, the active ingredient of the drug at 2〇t: solubility in water is less than 7〇〇mg/L, and The alcohol/water partition coefficient is in the range of 1.4 to 3.5, and the pre-gelatinized starch is 100 parts by weight, the benton content is 20 to 800 parts by weight, and the weight g is for the pre-gelatinized powder. 2~500 and non-medicated granules' contain pesticide active ingredients, pre-gelatinized, bentonite, and external engraving surfactants. The solubility of 2〇°c financial ingredients in water at 2G °C is less than 7 ( () 111 grab, and in the range of # alcohol / water partition coefficient is ~ 3, 5, the surface of the powder to recommend the weight, the bentonite content of 2. ~ _ parts by weight, relative to the pre-gelatinized starch, the active ingredient content of the pesticide is 2~5〇〇 201008488 and nonionic surfactant, It is 05 to 0.25 parts by weight with respect to 100 parts by weight of the pregelatinized starch. Pre-gelatinized starch, bentonite, a pesticide granule containing an active ingredient of a pesticide and a non-ionic surfactant, and the solubility of the ingredient in the 2GC to water is less than 7 (8) mg/L, and at 20 ° C The octanol/water partition coefficient is in the range of 1.4 to 3.5, the parts by weight is 100 to 8 parts by weight relative to 100 parts by weight of the pre-gelatinized powder, and the active ingredient of the pesticide is 100 parts by weight relative to the pre-gelatinized starch. The content is 2 to 5 〇〇 relative to 100 parts by weight of the pregelatinized starch, and the nonionic surfactant content is 〇05 to 0.25 parts by weight, '· the total content of the pregelatinized starch and the expanded soil relative to the total amount of the pesticide granules. It is 5 to 4 5 wt%. ^ A pesticide granule' contains Ferimzone, pre-gelatinized powder, and bentonite, relative to the pre-gelatinized powder, 100 parts by weight of the 'bulk content is 2〇~8〇〇, compared to 100 parts by weight of the pregelatinized starch, and the Ferimzone content is 2 to 500 parts by weight. The invention relates to a pesticide granule comprising Fermizone, pregelatinized starch and bentonite, wherein the content of the bentonite is 20-800 parts by weight relative to 100 parts by weight of the pre-gelatinized starch, and 100 weight relative to the pre-gelatinized starch. The content of Ferimzone is 2 to 500 parts by weight, and the total content of pregelatinized starch and benton is 5 to 4 201008488 parts by weight, 5 parts by weight, relative to the total amount of pesticide granules. In the amount of pesticide particles, _ starch and its total content is 5~4 and non-mixed granules, containing pesticide active ingredients, pre-gelatinized-, bentonite, long-time nonionic surfactant, 2 (ΤγΪΪ $财丝分在耽水的杂性秘7_抓, and in the range of octanol/water partition coefficient is 1.4~3.5, ^ pre-gelatinized powder powder weight, the benton content is 2〇~ _ parts by weight, weight = for the pre-gelatinized women's touch parts by weight, the active ingredient content of the pesticide is 2~· 05~Chihualin parts by weight, and the nonionic interfacial agent content is 〇. parts by weight. Contains agricultural financial effect ingredients, pre-gelatinized lining, bentonite, Han nonionic surfactant, 2 (ΤΓίί pesticide active ingredient in water at 2 ° ° C is less than 70 〇 111 § a few, and in = octanol / water The distribution coefficient is in the range of 1 &gt; 4~3 5 , : in the pre-gelatinized powder-killing weight fraction, the benton content is 20-800 parts by weight, and the weight of the active ingredient of the pre-gelatinized powder (10) For 2~5〇〇Q 05~100 parts by weight of pregelatinized starch, the content of nonionic surfactant is 〇. parts by weight, 5 heavy granules The total amount of pre-gelatinized starch and benton is 5~4 bent soil, and the seed granules contain Ferimzone, pre-gelatinized powder, and 10 parts by weight of pre-gelatinized starch. , the content of bentonite is 20~8 (8) parts by weight, 1 part by weight of ~500 heavy gelatinized starch, the content of Ferimzone is 2 benton, and the granule of agriculture contains Ferimzone. Paste powder, and 16 201008488 5 wt%. A pesticide granule' contains Fermizne, pregelatinized starch, benton, and nonionic surfactant, relative to pregelatinized starch 100 The part by weight of the bentonite is 2 〇 8 8 parts by weight, and the amount of the rich rice complex is 2 to 500 parts by weight relative to the pre-gelatinized powder. The granule of the pesticide contains the rich rice comprehensive (Ferimzone), pregelatinized starch, bentonite, and nonionic surfactant, with a 'bulk content of 20 to 800 parts by weight relative to 100 parts by weight of pregelatinized starch, ❹ relative to pregelatinized powdered part by weight' Ferimzone content of 2 to 500 parts by weight, pregelatinized starch relative to the total amount of pesticide granules The total content of the expanded soil is 5 to 45 wt%. A pesticide granule' contains Ferimzone, pre-gelatinized powder, expanded soil, and nonionic surfactant, compared to the pre-gelatinized temple. 100 parts by weight of the powder, the benton content is 20 to 800 parts by weight, and the non-ionic interface is 2 to 500 parts by weight with respect to 100 parts by weight of the pre-gelatinized powder, and 100 parts by weight relative to the pre-gelatinized starch. The active agent content is 0 β 05 to 0.25 parts by weight. A pesticide granule' contains Ferimzone, pre-gelatinized powder, bentonite, and nonionic surfactant, and the content of the bentonite is 2 〇 to 800 parts by weight relative to 100 parts by weight of the pregelatinized starch. 05〜0.25重量份, The non-ionic surfactant content is 0. 05~0.25 parts by weight, with respect to 100 parts by weight of the pre-gelatinized starch, the non-ionic surfactant content is 0. 05~0.25 parts by weight, The total content of the pregelatinized starch and the benton is 5 to 45 wt% with respect to the total amount of the pesticide granules. 'A pesticide granule' contains a pesticidal active ingredient, pregelatinized starch, and bentonite, 17 201008488 * The benton content is 20 to 800 parts by weight relative to 100 parts by weight of the pregelatinized starch, relative to the pregelatinized starch 1 The content of the Fermizone is 2 to 500 parts by weight, and the total content of the pregelatinized starch and the benton is 5 to 45 wt% based on the total amount of the pesticide granules. A pesticide granule comprising Fermizone, pre-gelatinized powder, bentonite, and nonionic surfactant, and the content of the bentonite is 2〇~8〇 relative to 100 parts by weight of the pre-gelatinized powder. The 〇 by weight component is from 2 to 500 parts by weight based on 100 parts by weight of the pregelatinized starch.农药 A pesticide granule comprising Fermizone, pregelatinized starch, bentonite, and a nonionic surfactant, and the benton content is 20 to 800 parts by weight relative to 100 parts by weight of the pregelatinized starch. The Ferimzone content is from 2 to 500 parts by weight based on 100 parts by weight of the pregelatinized starch, and the total content of the pregelatinized starch and the expanded soil is from 5 to 4'% by weight based on the total amount of the pesticide granules. A pesticide granule containing Ferimzone, pre-gelatinized powder, bentonite, and nonionic surfactant, ❹ relative to pre-gelatinized starch, 1 〇〇 part by weight, and the benton content is 20-800 The parts by weight of the pre-gelatinized starch are from 2 to 500 parts by weight with respect to 100 parts by weight of the pre-gelatinized starch, and the content of the non-ionic surfactant is 〇. 05~0.25 by weight relative to 100 parts by weight of the pre-gelatinized starch. Share. A pesticide granule comprising Fermizone, pre-gelatinized powder, bentonite, and nonionic surfactant, and the benton content is 20-800 parts by weight relative to 100 parts by weight of the pre-gelatinized starch. The content of the Fermzone is 2 to 500 parts by weight relative to 100 parts by weight of the pre-gelatinized starch, and the content of the nonionic surfactant is 〇. 17 201008488 The content of the non-ionic surfactant is 〇. 2 (The solubility of rc in water is less than enough, and in the range of octanol/water partition coefficient of 2〇C is u~3 5 , along with 隹 pre-gelatinized powder (10) parts by weight, the benton content is 20~800 weight Parts, weight t for 44 parts of chitosan (10), the active ingredient content of pesticide is 10~50 t* Ϊ granules' contains pesticide active ingredients, pre-gelatinized powder, and benton, on. ~ two pesticide active ingredients in 2〇 °C is less than 70〇1 for water, and it has a partition coefficient of octanol/water of 20 C in the range of 1.4~3.5, j is 1 part by weight of gelatinized powder, and the content of bentonite is 2〇. ~8 (8) parts by weight, 〇^ For the flour (10) parts by weight, the active ingredient content of the pesticide is 1〇~5〇灵1份The total content of the pregelatinized starch and the bentonite is 5 to 45 wt% relative to the total amount of the pesticide granules. The "two kinds of pesticide granules" contain the active ingredients of the pesticide, the pregelatinized starch, the bentonite, and the nonionic Surfactant, the above pesticide active ingredient is 20. (: solubility in water is less than 7 〇〇 mg / L, and in the range of octanol / water partition coefficient of 20 C is 1.4 ~ 3.5, relative to pregelatinization 1 part by weight of the temple powder, the benton content is 2〇~8〇〇 parts by weight, and the active ingredient content of the pesticide is 1〇~5〇 relative to 1〇〇 part by weight of the pregelatinized starch. Parts by weight. A pesticide granule comprising an active ingredient of a pesticide, a pregelatinized starch, a bentonite, and a nonionic surfactant. The above pesticide active ingredient has a solubility in water of less than 700 mg/L at 2 ° C and an octanol/water partition coefficient of 1.4 to 3.5 at 20 ° C, and 100 parts by weight of the pregelatinized starch. The content is 20-800 parts by weight, and the content of the active ingredient of the pesticide is 1 〇 5 5 parts by weight for the pre-gelatinized starch, and the total content of the pre-gelatinized starch and the bent soil is relative to the total amount of the pesticide granules. It is 5 to 4 5 wt%. A pesticide granule' contains a pesticide active ingredient, pregelatinized starch, benton, 18 201008488 〇 5~0.25 parts by weight, and the total content of pregelatinized starch and benton is 5~4 5 relative to the total amount of pesticide granules. weight%. - Agricultural music granules' contains pesticide active ingredients, pregelatinized starch, and benton. The above pesticide active ingredients are in 2 (TC has a solubility in water of less than 7〇〇mg/L, and the octanol/water partition in C The coefficient is in the range of 1.4 to 3.5, and the benton content is 2 〇 8 8 parts by weight relative to 100 parts by weight of the pregelatinized starch, and the active ingredient content of the pesticide is 1 相对 with respect to 100 parts by weight of the pregelatinized starch. 5 〇 weigh 1 part. - farming, granules 'containing pesticide active ingredients, pre-gelatinized starch, and bentonite, the active ingredient of the pesticide on the water at 2 ° ° C is less than the redundancy 0111 ^, and in C The octanol/water partition coefficient is in the range of 1.4 to 3.5, and for 100 parts by weight of the facial granule powder, the benton content is 2 〇 to moving parts by weight, and the weight of the active ingredient of the pre-gelatinized starch is 100 parts by weight. 10~5〇5 is more important than the total amount of pesticide granules. The total content of pre-gelatinized temple powder and benton is 5~4. The non-separating agent contains pesticide active ingredients, pre-gelatinized powder, benton, and effect. The solubility of water is less than 7〇〇mg/L, and the K-knife ratio is 1.4~3 5 $铭Ifl, ^ Powder (10) parts by weight, the benton content is 2G~_parts by weight, part by weight; 100 parts by weight, the active ingredient content of the pesticide is 10~50, and the non-separating agent contains the active ingredient of the pesticide, pre-gelatinized starch, The swelling degree of the bent soil is less than 7G () mg / L, and within the range of 100 wt. 5 relative to the pre-gelatinized temple powder, the benton content is 20 to 800 weight relative to the pre-gelatinized temple powder 100 it. Ingredients, *Limited, the active ingredient content of pesticide is 10~50 18 201008488 and non-ionic surfactant. The above pesticide active ingredient has a solubility in water of less than 7〇〇mg/L at 2〇°C, and is in 20 C The octanol/water partition coefficient is in the range of 1.4 to 3.5, and the benton content is 2 〇 8 8 parts by weight relative to 100 parts by weight of the pregelatinized starch, and the pesticide active ingredient is 100 parts by weight relative to the pregelatinized starch. The content is 1〇~5〇 parts by weight, and the nonionic surfactant content is 〇05~0.25 parts by weight relative to 100 parts by weight of the pre-gelatinized powder. A pesticide granule containing the active ingredient of the pesticide, pre-gelatinized starch , bentonite, bismuth and nonionic surfactant, the above pesticides are effective The solubility to water at 20 ° C is less than 7 〇〇 mg / L, and the octanol / water partition coefficient of 2 ° ° C is in the range of 1.4 ~ 3.5, compared to the pre-gelatinized starch 100 children, part of the soil The content is 2 〇 8 8 parts by weight, and the active ingredient content of the pesticide is 1 〇 50 50 parts by weight relative to 1 (8) parts by weight of the pregelatinized starch, - 100 parts by weight of the non-ionic surfactant in the pregelatinized powder. The content is 〇05~0.25 parts by weight, &quot; relative to the total amount of pesticide granules, the total content of pregelatinized starch and benton is 5~4 ❹ 5% by weight. A pesticide granule comprising Fermizone, pre-gelatinized powder, and benton soil, and the benton content is 20-800 parts by weight relative to 100 parts by weight of the pre-gelatinized starch, relative to the pre-gelatinized starch 100 The Ferimzone content is 10 to 50 parts by weight based on parts by weight. A pesticide granule comprising Fermizone, pregelatinized starch, and swelled soil, having a benton content of 2 〇 to 800 parts by weight relative to 100 parts by weight of the pregelatinized starch, relative to the pregelatinized starch 100 parts by weight, the content of Ferimzone is 10 to 50 parts by weight, and the total content of pregelatinized starch and benton is 5 to 4 19 201008488 parts by weight relative to the total amount of pesticide granules, 5 weights of pesticide particles The total amount of the agent 'Chi Hua Dian powder and benton soil is 5~4 and the non-offering age is rich and green, and the powder is 'expanded soil, %. The agricultural and financial effect component is in the range of 2叱 to _degree less than 7_讥, and the octanol/water partition coefficient of 20C is in the range of 14~3 5 , and the benton content is 100 parts by weight relative to the pre-gelatinized powder. 2〇~foot parts by weight, ❹ ❹ Weight 2 For the pre-gelatinized powder, the active ingredient content of the pesticide is 1〇~5〇 relative to 100 parts by weight of the pre-gelatinized lining, the nonionic surfactant content is 〇. ~0.25 parts by weight. - a kind of pesticide _, containing agricultural financial effect ingredients, pregelatinized starch, bentonite, and nonionic surfactant. The above pesticide active ingredient has a solubility in water of less than 700 mg/L at 20 ° C and a range of 14 to 3 5 in an octanol/water partition coefficient of 2 〇c, and a bentonite relative to 100 parts by weight of the pregelatinized starch. The content is 2〇~8〇〇 parts by weight, and the active ingredient content of the pesticide is 1〇~5〇 parts by weight relative to 1 part by weight of the pregelatinized starch, and the nonionic surfactant is relative to the weight of the pregelatinized starch. The content is 〜. 05~0.25 parts by weight, and the total content of the pregelatinized starch and the benton is 5 to 45 wt% based on the total amount of the pesticide granules. The invention relates to a pesticide granule comprising fermizne, pre-gelatinized powder, and benton soil, wherein the content of the benton is 2〇~8〇〇, relative to 100 parts by weight of the pre-gelatinized powder, relative The content of Ferijjone is 1 〇 50 50 parts by weight of the pre-gelatinized powder. A pesticide granule' contains Ferimzone, pre-gelatinized powder, and bentonite, 201008488 5% by weight. A pesticide granule comprising Fermizone, pregelatinized starch, bentonite, and a nonionic surfactant, and the benton content is 2 〇 to 800 parts by weight relative to 100 parts by weight of the pregelatinized starch. The rich rice content is from 50 parts by weight relative to 100 parts by weight of the pre-gelatinized powder. A pesticide granule' contains Ferimzone, pre-gelatinized powder, bentonite, and nonionic surfactant, and the benton content is 2 〇 to 800 parts by weight relative to 100 parts by weight of the pre-gelatinized starch. , The content of the perimeter is 1 〇 50 50 parts by weight relative to 100 parts by weight of the pregelatinized starch, and the total content of the pregelatinized starch and the benton is 5 to 45 weights relative to the total amount of the pesticide granules. %. A pesticide granule comprising Fermizone, pre-gelatinized powder, bentonite, and nonionic surfactant, ^ relative to 100 parts by weight of pre-gelatinized starch, the benton content is 2〇~8〇 〇 by weight, relative to 100 parts by weight of the pregelatinized starch, the content of 'perimz〇ne' is ~50 parts by weight, The nonionic surfactant content is from 0.05 to 0.25 parts by weight based on 100 parts by weight of the pregelatinized starch. A pesticide granule comprising Fermizone, pregelatinized starch, teron soil, and a nonionic surfactant, - a benton content of 2 〇 to 8 相对 relative to 100 parts by weight of the pregelatinized starch The content of 〇 份 相对 100 100 100 100 100 100 100 100 100 100 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综 综0.25 parts by weight, ^ υ· The total leaf content of the pregelatinized starch and the bentonite is 55 wt/0 relative to the total amount of the pesticide granules. β 〜 4 20 201008488 Relative to 100 parts by weight of the pre-gelatinized starch, the benton content is 2 〇 8 8 parts by weight, - 2 for 100 parts by weight of the pre-gelatinized starch, the rich rice comprehensive mzo ~ 50 parts by weight, π 里π Relative to the total amount of the pesticide granules, the total content of the pregelatinized starch and the benton is ~4 &gt;% by weight. The agricultural granules contain Fermiz〇ne, pre-gelatinized powder, bentonite, and nonionic surfactant. Compared with 100 parts by weight of pre-gelatinized temple powder, the content of bentonite is 2〇. To 8 parts by weight, the Ferimzone content is 10 to 50 parts by weight based on 100 parts by weight of the pregelatinized starch. A kind of pesticide granule containing Ferimzone, pre-gelatinized powder, expanded soil, and non-ionic surfactant, and the content of bentonite is 2〇 relative to the pre-gelatinized powder. ～8〇〇 parts by weight, relative to 100 parts by weight of the pre-gelatinized starch, the content of the premi-ferimzone is 1〇~50 parts by weight, _ relative to the total amount of the pesticide granules, the total content of the pregelatinized starch and the expanded soil is 5 to 4 5 wt%. - The seed medicinal granules contain Ferimzone, pre-gelatinized powder, bentonite, and nonionic surfactant. Compared with 100 parts by weight of pre-gelatinized powder, the benton content is 2〇~ Parts by weight, ◎ relative to the pre-gelatinized powder, 1 part by weight of 'Ferrimzone' content of 10 to 50 parts by weight, relative to 1 part by weight of the pregelatinized starch, the nonionic surfactant content is 〇. 〇 5~0.25 parts by weight. a pesticide granule comprising Fermizone, pregelatinized starch, bentonite, and a nonionic surfactant, and the benton content is 20 to 800 parts by weight relative to 100 parts by weight of the pregelatinized starch, The content of the Fermzone is 10 to 50 parts by weight, and the content of the nonionic surfactant is 〇. ^ 20 201008488 (for 20 parts by weight of the pre-gelatinized powder). EXAMPLES The present invention is illustrated in more detail by the following examples, but the invention is not limited by the examples. Example 1 Ferimzone (Feiyou Chemical, purity 97.〇%) 5〇.〇 by weight, and Guangshan CLAY-S (made by Shengguangshan Mining) 5 parts by weight mixed with juice mixer 'This mixture was pulverized by a rotary mill (R〇t〇r miU, manufactured by Retsch) to obtain a pulverized material (hereinafter abbreviated as Ferimz〇ne micropowder. The active ingredient content was 48 5 %; Ray 2 diffraction The average particle diameter of the particle size analyzer (wet method) was determined to be 6 5 μm. Take 41.2 parts by weight of Fenmzone powder, 50.0 parts by weight of AMYLOX No.lA (Ni hon Comstarch), Bent〇nite Fuji (h〇jun) 200.0 weight damage SORPOL 5〇8〇 (nonionic surfactant) , Toho Chemical Co., Ltd., 69 parts by weight of Shengongshan CLAY-S (manufactured by Shengguangshan Mining Co., Ltd.) was mixed with a Nauta mixer (manufactured by Nauta Mixer'Fuji Paudal) to obtain a mixed powder of 1 〇 (8) parts by weight. . The surface part by weight of this mixed powder was mixed with 23 parts by weight of water, and then kneaded by a Nota mixer (manufactured by Nata MixeP Fuji Paudal) to obtain a kneaded product. This kneading material is used in a basket type granulator (Lai), Saki & ψα9ιηιη _ squeezing, and dried with a fluidized bed dryer (manufactured by Powlex), followed by a needle mill (free pulverizer, mold field) The crude smashed material was used for riding, and the pesticide granules of the example were obtained. /, Example 2 except that Bentonite Fuji was changed to 5 parts by weight, and Shengguangshan clay-s was changed to 848.8 parts by weight. And the water was changed to 22 G parts by weight, the other = the same operation as the pesticide granule of Example 2. The 1 phase Example 3 except that Bentonite Fuji was changed to 1 part by weight, and Shengguangshan clay_s 798.8 parts by weight 2 The water was changed to 4 22 parts by weight, and the same operation was carried out, and the pesticide granule of Example 3 was obtained. 仃 贯 _1 _1 phase Example 4 was changed to Bent 〇nite Fuji to 400.0 parts by weight, Shengguangshan CLAY_S 21 201008488 〇5~0.25 parts by weight, &lt;壬i目 For the total amount of the pesticide granules, the total content of the pregelatinized starch and the benton is 5 to 4 5 % by reset. (Example) The following examples of the examples are more The present invention will be described in detail, but the present invention is not limited to the embodiment 1 of the present invention. Body (Sumitomo Chemical, purity 97.0%) 50.0 parts by weight β Guangshan CLAY-S (made by Shengguangshan Mining Industry Co., Ltd.) 5 parts by weight mixed with a juice mixer, and the mixture is rotated by a rotary mill for 1 Bu] ^ 杉冰)) to smash, = Thai shards (hereinafter abbreviated as Fumi Township erimzQne) micro-powder. Active ingredient content milk The average particle size measured by the Thunder-type particle size analyzer (wet method) was 6._. ). Take 41.2 parts by weight of Fenmzone, 50.0 parts by weight of AMYLOX No.lA (Ni:Comstarch), Bent〇nite Fuji (H〇JUN) 2〇〇〇2^SORPOL 5〇80 (non-ionic interface) Active agent, Toho Chemical Co., Ltd. 1 () 〇 by weight, = Gwangsan CLAY-S (made by shengshiyama Mining Co., Ltd., π·wt parts by Naota mixer = AMA Mixer'Fuji Paudal), mixed powder weight Share. The powder was mixed with 23 parts by weight of water and then kneaded by a Nauta mixer (manufactured by N ® Γ J1 Paudal) to obtain a kneaded product. This kneading object uses a hanging basket (butterfly) to feed the remaining 0G.9mm cake jujube, dried with fluidized inorganic (made by Powlex), and then used a needle mill (free crusher, Louye production ^ 仃 coarsely chopped This coarsely disintegrated material was carried out (4), and the pesticide granules of the examples were obtained. 'Example 2 except that Bentonite Fuji was changed to part by weight, and Shengshan Clay_s Π?//% and ^ were changed to 22. Others performed the same as in Example 1, and the pesticide granules of Example 2 were obtained. Example 3: In addition to changing the jen touch e Fuji to the touch weight, the Shengongshan clay-s.8 heavy injury' and The water was changed to 22 G parts by weight, and the other was carried out in the same manner as in the example}. 21 201008488 ΓNong'an 'Others and fine 1 phase _, Example 4 Example 5 except that AMYLOX Νο.ΙΑ was changed to 100.0 parts by weight, Β • 20.0 parts by weight, Shengguangshan CLAY_S changed to A ent〇mte, although the county was changed to .8 parts by weight and the water was changed to 2 pesticides. The same operation as in Example 1 was carried out, and the implementation of Example 5 was obtained. Example 6 In addition to changing Bentonite Fuji to 5 parts by weight, Shengongshan clay-s, and gas and water to 2% by weight, The same procedure was carried out to obtain the pesticide granule of Example 6. /, Comparative Example 1 ', Fericone micropowder 41.2 parts by weight, fine (10) and N." omstarch) 50.0 parts by weight, Bent〇nite Fuji (h〇jun^5juven, SORPOL 5_(Dongbang Chemical) 1〇〇wt, Shengguangshan ci^y”g soil mining household: system) 398.8 parts by using Nouta mixer (Fuji system) 1000 parts by weight of the mixed powder was obtained. The mixed powder was mixed with water and smashed with water, and then mixed with a Nota-type mixer (Fuji Paudal, KK, KK, kneaded, simmered, slinged blue) The granulator (the 畑 铁工所3 uses the extrusion diameter of the state letter into the grain: the bed dryer (Ρ-made) is dried, and then the needle mill (from the wilderness industry) for coarse comminution. Screening, pesticide granules of Example 1. π lamp comparison example 2 9QS Fuji changed to 6_wt parts, Shengguangshan CLAY-S changed to π 夕, and water changed to 250 parts by weight, other comparisons and comparison examples 1 The same operation 'Compared with the pesticide granule of Comparative Example 2. Comparative Example 3 Take 41.2 parts by weight of Ferimz〇ne micropowder, AMYLOX No.lA (Ni Comstarch ) 50.0 parts by weight, s〇Rp〇L 5〇8〇 (Dongbang Chemical) 1〇〇 parts by weight, Shengguangshan CLAY-S (made by Shengguangshan Mining Industry Co., Ltd.) 898.8 parts by Nota type mixing 22 201008488 The pesticide granule of Example 3 was obtained. Example 4 A pesticide granule of Example 4 was obtained except that Bentonite Fuji was changed to 4 parts by weight and 8 parts by weight of syrup. Example 5 Except for changing AMYLOX No. 1A to 100.0 parts by weight, verifying that nite Fuji was changed to 20.2 parts by weight, Shengguangshan clay-S was changed to 828.8 parts by weight, and water was changed to 2 20 weights, other implementation and implementation The same procedure as in Example 1 gave the pesticide granule of Example 5.实施 Example 6 In addition to changing Bentonite Fuji to · parts by weight, changing the position of Shengguangshan clay-s to 798.8 parts by weight and changing the water to 2 parts by weight, the other pesticides of Example 6 were obtained. . Comparative Example 1 Take Feimzone micropowder 41·2 parts by weight, % ιΑ hon C〇mStarch) 50.0 parts by weight, Bentonite Fuji (h〇jun 〇〇: RPOL, 〇 (Dongbang Chemical) 1〇·〇 weight份份,胜光山clay"2, manufactured by the company) 398.8 parts by weight of a Nota type mixer (made by Fuji), "= 2 parts of the mixed powder, 1000 parts by weight. The mixed powder is 1 part by weight and = part by weight After mixing, the Nota mixer (manufactured by Fuji Paudal) was used to knead the kneaded material. The basket type granulator (畑铁工所) was used to extrude the diameter of the state Cong ^ = extrusion granulation, flow The chemical bed dryer (made by P〇wlex) is used for coarse disintegration. This coarsely disintegrated material is sieved = Comparative example 2 If her gold Fuji is changed to _·〇 by weight, Shengguangshan CLAY-S is changed. The residue was changed to 250 parts by weight, and the same procedure as in the comparison was carried out to obtain the agrochemical granule of Comparative Example 2. Comparative Example 3 22 201008488 Take 41.2 parts by weight of Ferimzone micropowder, AMYLOX No .lA(Ni 1^11(^〇1^; muscle 11) 50. 〇 by weight, 8〇 〇 [5〇8〇 (Dongbang Chemical) 1 〇〇 weight wins ώ CLAY-S (made by Shengguangshan Miscellaneous) )_ A .8 weight side Nota mixer (manufactured by Fuy Paudal) was mixed to obtain a mixed powder of 1 part by weight. The weight of the mixed powder and the weight of water 21G were adhered to the post. The kneading material is kneaded and kneaded. The kneading material is extruded and granulated by a hanging basket granulator (畑铁工所) with an extrusion diameter of 00.9 mm, and a fluidized bed dryer (manufactured by P〇wlex) After drying, _ was further subjected to coarse pulverization using a pin mill (free pulverizer, wilderness industry), and the coarsely pulverized material was sieved to obtain a pesticide granule of Comparative Example 3. Comparative Example 4 富 Take the rice cultivar ( Ferimzone) 41.2 parts by weight of powder, GOHSENOL GL — 05 S (commercially available from Sakamoto Chemical Industry Co., Ltd.) 3 parts by weight, Bent〇nite Fujita OJUN) 200.0 parts by weight, SORPOL 5080 (Toho Chemical) 1 〇. 〇 weight Separately, 71.78 parts by weight of CLAY-S (manufactured by Shengguangshan Mining Co., Ltd.) was mixed with a Nota mixer (made by Paudal) to obtain a mixed powder of 1 part by weight. The mixed powder was 1 〇 (8) / part by weight with water. 220 parts by weight of the mixture was kneaded by a Nouta mixer (made from Paudal) to obtain a kneaded product. This kneading material was used in a basket type granulator (a ferritic iron). The factory is subjected to extrusion granulation at an extrusion diameter of 0.9 mm and dried by a fluidized bed drying mechanism, followed by coarse pulverization using a pin mill (free pulverizer, Takino Industry). The Q sieving was carried out to obtain the pesticide granule of Comparative Example 4. Table 1 Example 1 2 3 4 5 6 Ferimzone (calculated as active ingredient) 2.0 2.0 2.0 2.0 2.0 2.0 AMYLOXNo.lA 5.0 5.0 5.0 5.0 10.0 10.0 Bentonite Fuji 20.0 5.0 10.0 40.0 2.0 5.0 SORPOL 5080 1.0 1.0 1.0 1.0 1.0 1.0 Shenguangshan CLAY-S bal. bal. bal. bal. bal. Total (W/W%) 100.0 100.0 100.0 100.0 100.0 100.0 23 201008488 Comparative Example 1 2 3 ~·. ___ 4 Fermizone (Ferimzone) ) (in terms of active ingredients) 2.0 2.0 2.0 2.0 AMYLOX No. 1A 5.0 5.0 5.0 Bentonite Fuji 50.0 60.0 —----- 20.0 SORPOL 5080 1.0 1.0 1.0 GOHSENOLGL-05S 3.0 胜光山 CLAY—S bal. bal. Bal. Total (W/W%) 100.0 100.0 100.0 100.0 *·Dissolution rate of active ingredient after 24 hours (%) 99.0 98.0 89.2 96.5 Load hardness (g) 627 368 ----- 651 1--- Example 7 50.0 parts by weight of Furametpyr (Sumitomo Chemical, purity 97.3%) and 50.0 parts by weight of Bentonite Fuji (HOJUN) were mixed with a juice mixer, and the mixture was pulverized by a rotary mill (Rotor mill). , got the crushed material (the following abbreviated as effective after 24 hours) Component dissolution rate (%) 76.0 79.6 79.6 83.4 77.9 -~~-- 78.8 Load hardness (g) 824 608 694 884 ------&gt; Table 2 Furametpyr micropowder A. The active ingredient content was 48.7%; the average particle size was 5.8 μιη. ). Take Furametpyr fine powder A 189.1 parts by weight, AMYLOX No'lA (NihonComstarch) 50.0 parts by weight, Bentonite Fuji (h〇JUN) 105.4 parts by weight, sorpol 5080 (Toho Chemical) 10_0 parts by weight, and Nitto calcium carbonate NN200 (曰 粉 粉 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 645 This mixed powder 24 201008488 is mixed with a Nota mixer (made by Paudal;) t Pinch-type granulator with a hanging basket (畑铁工所&gt; After drying with a fluidized bed dryer (manufactured by P〇wleX), the pesticide granules of Example 7 were passed through. f Example 8 , Nitto Carbon _ NN200 was changed to Shengguangshan clay-s (Shengguangshan Mining^ The same procedure as in Example 7 was carried out, and the pesticide granules of Example 8 were obtained. Comparative Example 5 _ FURAMetPyr original (Sumitomo Chemical, purity 97.3%) 50.0 parts by weight CLAY-S (winning) The _ parts by weight of the Gwangsan Mining Industry Co., Ltd. mixed with a juice mixer, and the mixture was pulverized by a pin mill to obtain a pulverized product (hereinafter abbreviated as Furametpyr Fine Powder B. The active ingredient content was 48 7%.) Furametpyr micropowder B 1891 parts by weight, ΑΜγιχ)χ No曰lA(Nih〇n C_tarCh)5〇.〇 parts by weight, s〇Rp〇L 5_(Dongbang Chemical) 1〇〇 parts by weight, Shengguangshan CLAY— 75 (9 parts by weight of Shouguangshan Mining Co., Ltd.) was mixed with a Nobel mixer (manufactured by Fuji Paudal) to obtain a mixed powder of 1 〇〇〇 The mixture of 1GGG of soil mixed powder and 220 parts by weight of water is mixed with a Norit mixer (made by Paudal) to knead the kneaded material. This kneading material uses a basket type granulator (畑铁工) Extrusion granulation was carried out at a diameter of 00.9 mm, dried by a fluidized bed dryer, and then coarsely pulverized by a pin mill (free pulverizer, Takino Industry). The coarsely pulverized material was sieved. The pesticide granule of Comparative Example 5 was obtained. Comparative Example c Furametpyr fine powder A 189.1 parts by weight, amylox No.lA (NihonComstarch) 50.0 parts by weight, Bent〇nite Fujita jun) 5〇2 9 , SORPOL 5〇80 (Dongbang Chemical) 1〇.〇重量份, Shengguangshan clay-s (made by Shengguangshan Mining) 248.0 parts by weight mixed with a Nauta mixer (made by FujiPaudal) to obtain 1000 parts by weight of mixed powder Share. 1 (8) parts by weight of this mixed powder was mixed with 22 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paudal) to obtain kneading 25 201008488. This kneading _ hanging basket granulator (} _ ^ away from the jelly, bribery bed dry (p (four) 1ex Wei _, [industry) for coarse smashing. This coarse smash into the table 3 ------ -- Example Comparative Example 7 8 5 c Furametpyr (calculated as active ingredient) 9.2 9.2 9.2 9.2 AMYLOXNo.IA 5.0 5.0 5.0 5.0 Bentonite Fuji 20.0 20.0 60.0 SORPOL 5080 1.0 1.0 10.0 10.0 Shengguangshan CLAY-S bal Bal. bal. Nitto calcium carbonate NN200 --------__ bal. Total (W/W%) 100.0 100.0 100.0 100.0 I. Effective ingredient dissolution rate after 24 hours (%) 53.9 57.9 62.8 100.0 Example 9 S-allyl-5-amino-2-isopropyl-4(2-methylphenyl)-3-oxy- 2,3-dihydropyranothioate (hereinafter abbreviated as compound a) , purity 98 4%) 5〇〇f parts and Shengguangshan CLAY - S (made by Shengguangshan Mining) 5 〇. 〇 by weight mixed with juice mixer, 'this mixture with rotary mill (R〇t 〇rmm) was pulverized to obtain a pulverized product (hereinafter abbreviated as Compound A fine powder. The active ingredient content was 49.2%; the average particle diameter was 6.2 μm.). Take 40.7 parts by weight of the compound bismuth powder, 50.0 parts by weight of AMYLOX No.lA (Nihon C〇mstarch), 200.0 parts by weight of Bentonite Fuji (HOJUN), SORPOL 5080 (Toho Chemical) 1 〇. 〇 by weight, Shengguangshan CLAY_S (Shengguangshan) 69.3 parts by weight of the product produced by the mining company was mixed by a Nauta mixer (Nippon Pauda) ^) to obtain 26 201008488 • 10 (8) parts by weight of the mixed powder. After 1000 parts by weight of this mixed powder was mixed with 210 parts by weight of water, a Norit mixer (manufactured by Fuji Paudal Co., Ltd.) was kneaded to obtain a kneaded product. This kneading material is extruded and granulated by a hanging basket granulator (Nippon Iron Works) with an extrusion diameter of 9 mm, dried by a fluidized bed dryer (manufactured by P〇wlex), and then ground with a needle. The machine (free pulverizer, the wilderness industry) is coarsely broken. This coarsely pulverized material was sieved to obtain the granule of the pesticide of Example 9. Example A The same operation as in Example 9 was carried out using 40.7 parts by weight of the compound A fine powder, 100.0 parts by weight of AMYLOX No. 1A, 20.0 parts by weight of Bentonite Fuji, 10.0 parts by weight of SORPOL 5080, and CLAY-S 829.3 parts by weight of Shengshan Mountain. It is necessary to carry out the pesticide granule of β example A. Example B The same operation as in Example 9 was carried out using 40.7 parts by weight of the compound A fine powder, AMYLOX No. 1 AlOO.O parts by weight, Bentonite Fuji 50.0 parts by weight, SORPOL 5080 10.0 parts by weight, and Shengguang-Shan CLAY-S 799.3 parts by weight. The pesticide granule of Example B was obtained. Comparative Example 6 The same procedure as in Example 9 was carried out except that 40.7 parts by weight of the compound A fine powder, 200.0 parts by weight of Bentonite Fuji, 30.0 parts by weight of GOHSENOL GL-05S, SORPOL 5080 10.0 by weight, and 71.93 parts by weight of Shengongshan CLAY-S were used. The operation of the pesticide granule of Comparative Example 6 was obtained. Comparative Example a The same procedure as in Example 9 was carried out except that 40.7 parts by weight of the compound A fine powder, 50.0 parts by weight of AMYLOX No. 1A, 600.0 parts by weight of Bentonite Fuji, 10.0 parts by weight of SORPOL 5080, and 299.3 parts by weight of Shengongshan CLAY-S were used. The agrochemical granule of Comparative Example a was obtained. Comparative Example b 40.7 parts by weight of Compound A fine powder, 50.0 parts by weight of AMYLOX No. 1A (Nihon • C〇rnstarch), 10.0 parts by weight of SORPOL 5080 (Toho Chemical), and 89.3 weight of Shengongshan CLAY-S (manufactured by Shengguangshan Mining Industry Co., Ltd.) The mixture was mixed with a Nauta mixer (manufactured by Fuji 27 201008488 Paudal) to obtain a mixed powder of 1 part by weight. The mixed powder was mixed with 190 parts by weight of water and mixed with a Norit mixer (Fujipaudal kneading kneading material. This kneading material was used in a basket type granulator (畑铁工所) to extrude straight 00.9 Mm was subjected to extrusion granulation, dried by a fluidized bed dryer (manufactured by ρ〇_χ), and then coarsely pulverized by a pin mill (free pulverizer, Takino Industry). This crude mash sieve was obtained as a comparative example. Pesticide granules of b. Table 4 Comparative examples of examples Compound A (calculated as active ingredient) AMYLOXNo.IA 5.0 10.0 10.0 5.0 5.0 Bentonite Fuji 20.0 2.0 5.0 20.0 60.0 SORPOL 5080 1.0 1.0 1.0 1.0 1.0 1.0 3.0 GOHSENOLGL-05S 胜光山 CLAY-S bal. bal. bal. bal. Bal. Total (W/Wc/c〇100.0 100.0 100.0 100.0 100.0 100.0 Dissolution rate of active ingredient after 24 hours 4% 36.7 38.9 47.1 43.6 55.8 Dissolution rate of active ingredient after 48 hours (%) Active ingredient after 72 hours Dissolution rate (%) 56.3 66.8 52.7 63.3 55.5 63.5 61.6 73.9 66.4 75.1 71.9 84.3 Example C 30.0 parts by weight of Tricyclazole (purity 97.8%) and Shengongshan CLAY-S (manufactured by Shengguangshan Mining Industry Co., Ltd.) After mixing 5 parts by weight with a juice mixer, the mixture was pulverized by a Rotor mill to obtain a pulverized material (hereinafter abbreviated as Tricyclazole micropowder. The active ingredient content was 48.9%; The average particle size is 7.2 μιη.). 28 201008488 , parts, SORPOL 5080 (Toho Chemical) ΐ〇·〇 parts by weight, Shengguangshan CLAY-s (Shengguangshan, manufactured by the company) 699.3 parts by weight Nauta mixer iv Shu Paudal Ltd.) was mixed with two parts by weight to obtain a mixed powder 1〇〇〇. 1 part by weight of this mixed powder was mixed with 2 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paudal) to obtain kneading =. This kneading material is extruded and granulated by a hanging basket type granulator (畑铁工所) with an extrusion diameter of 9 mm, dried with a fluidized bed dryer (manufactured by Powlex), and then a needle mill ( The free crusher and the wilderness industry are used for rough breaking. This coarsely pulverized material was sieved to obtain a pesticide granule of Example C. Comparative Example d 4 40.7 parts by weight of Tricyclazole micro powder, 50.0 parts by weight of AMYLOX NalA (Nihon Comstarch), SORPOL 5080 (Toho Chemical) 1 〇. 〇 by weight, Shengguangshan CLAY-S (made by Shengguangshan Mining Industry Co., Ltd.) 89.3 parts by weight were mixed by a Nauta mixer (manufactured by Fuji Paudal) to obtain a mixed powder of 0 part by weight. 1000 parts by weight of this mixed powder was mixed with 200 parts by weight of water and then kneaded by a Nauta mixer Paudal to obtain a kneaded product. This kneading material was extruded and granulated by a basket type granulator (畑铁工所) with a diameter of 0 〇.9 mm, and dried by a fluidized bed dryer (manufactured by Powlex) to re-use a pin mill ( The free crusher and the wilderness industry are used for rough breaking. This crude mash was sieved to obtain a pesticide granule of Comparative Example d. Table 5 Example Comparative Example C d Tricyclazole (calculated as active ingredient) 2.0 2.0 AMYLOX No. IA 5.0 5.0 Bentonite Fuji 20.0 SORPOL 5080 ' 1.0 1.0 Shengguangshan CLAY-S Bal bal Total (W/W%) 100.0 100.0 29 201008488 Take 40.7 parts by weight of Tricyclazole micro powder, 50.0 parts by weight of AMYLOX No.lA (NihonComstarch), 200.0 parts by weight of Bentonite Fuji (HOJUN), SORPOL 5〇80 (Toho Chemical) 1〇·〇 by weight, Shengguangshan 69.3 parts by weight of CLAY-S (manufactured by Kwong Kwong Mining Co., Ltd.) was mixed with a Nota mixer (manufactured by Fuji Paudal Co., Ltd.) in an amount of 1000 parts by weight. 1000 parts by weight of this mixed powder was mixed with 2 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paudal) to obtain a kneaded product. This kneading material is dried by a hanging basket granulator (畑铁工所) with an extrusion diameter of 9_, and dried by a fluidized bed dryer (manufactured by p〇wlex), followed by a needle mill. The machine (Free Thai Crusher, Wilderness Industry) was coarsely broken. This coarsely pulverized material was sieved to obtain a pesticide granule of Example C. Comparative Example d 40.7 parts by weight of Tricyclazole micro powder, amylox No曰lA (NihonComstarch) 5 〇. 〇 by weight, sorpol 〇 (Dongbang Chemical) 1 〇〇 by weight, Shengguangshan CLAY-S (Shengguangshan Mining) 89.3 parts by weight of the mixture was mixed with a Nobel mixer (manufactured by Fuji Paudal Co., Ltd.) to obtain a mixed powder of 1 part by weight. The mixture was mixed with 200 parts by weight of water, and then kneaded by a Nauta mixer (4) PaUdal. This kneading material is extruded and granulated by a hanging basket granulator straight through 0.9 mm, using a fluidized bed drying mechanism)) Ϊ Ϊ 丄 丄 针 针 针 针 针 针 针 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由 自由This crude material was sieved to obtain a pesticide granule of Comparative Example d. table 5 ', Tricyclazole (calculated as active ingredient) AMYLOXNo.IA Comparative Example d Bentonite Fuji 29 201008488 Dissolution rate of active ingredient after 24 hours (0/〇) 54.8 100 Dissolution rate of active ingredient after 72 hours (%) 63.3 100 Example D Futhalide (Sumitomo Chemical, purity 99.3%) 50.0 parts by weight and Shengshan CLAY-S (made by Shengguangshan Mining Industry Co., Ltd.) 5 〇. 〇 by weight mixed with a juice mixer, 'This mixture was pulverized with a rotary mill (Rotor mill) to obtain a pulverized material (hereinafter abbreviated) It is a fine powder of Futhalide. The active ingredient content is 49.7%; the average particle size is 6.8 μπι.). Take 40.2 parts by weight of Futhalide, 50.0 parts by weight of AMYLOXNo.lA (Nihon Comstarch), 200.0 parts by weight of Bentonite Fuji (HOJUN), ❿ SORP〇L5080 (Toho Chemical) 1〇.〇重量份,胜光山 CLAY 699.8 parts by weight of -S (manufactured by Kyungsan Mining Co., Ltd.) was mixed with a Nauta mixer (manufactured by Fuji Paudal Co., Ltd.) to obtain 1000 parts by weight of a mixed powder. One part by weight of this mixed powder was mixed with 2 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paudal) to obtain a kneaded product. This kneaded product was extruded by a hanging basket granulator (畑铁工所) with an extrusion diameter of 0 〇.9 mm, dried by a fluidized bed dryer (manufactured by Powlex), and then a needle mill. (Free pulverizer, Takino industry) for rough smashing. This crude mash was sieved to obtain the granule of the pesticide of Example D. Comparative Example e 40.2 parts by weight of Futhalide micropowder, 50.0 parts by weight of AMYLOX No. 1A (Nihon Comstarch), 1 part by weight of SORPOL 5080 (Toho Chemical), and 1 part by weight of Shenguangshan CLAY-S (made by Shengguangshan Mining Industry Co., Ltd.) 899.8 parts by weight was mixed with a Nauta mixer (manufactured by Fuji Paudal) to obtain a mixed powder looo parts by weight. The mixed powder woo was mixed with 200 parts by weight of water, and then kneaded by a Nauta mixer (manufactured by Fuji Paudal) to obtain a kneaded product. The kneaded material was extruded and granulated by a hanging basket granulator (畑铁工所) at an extrusion diameter of 00.9 mm, dried with a fluidized bed dryer (manufactured by P〇wlex), and then a needle mill ( The free crusher and the wilderness industry are used for rough breaking. This crude mash was sieved to obtain a pesticide killer of Comparative Example e. 30 201008488 Total (W/W%) 100.0 100.0 Dissolution rate of active ingredient after 24 hours (%) 54.8 100 Dissolution rate of active ingredient after 72 hours (%) 63.3 100 Example D Futhalide (Sumitomo Chemical) , purity: 99.3%) 50.0 parts by weight and Shengshan CLAY - S (made by Shengguangshan Mining) 5 〇 · 〇 parts by weight mixed with a juice mixer, the mixture was pulverized with a Rotor mill The pulverized material (hereinafter referred to as the Futhalide micropowder) has an active ingredient content of 49.7% and an average particle diameter of 6.8 μm. Take 40.2 parts by weight of Futhalide, 50.0 parts by weight of AMYL〇XNcUA (Nih()n Comstarch), 200.0 parts by weight of Bentonite Fuji (HOJUN), 1 part of SORP〇L5080 (Toho Chemical), 〇 by weight, win 697.8 parts of Gyeongsan CLAY-s (manufactured by Kwong Kwong Mining Co., Ltd.) was mixed with a Nouta mixer (manufactured by Fuji pau (made by Jai) to obtain 1000 parts by weight of the mixed powder. 1 part by weight and water by weight of the mixed powder After mixing, kneading was carried out by a Nota mixer (manufactured by Fuji Paudal), and the kneaded product was extruded and granulated by a basket type granulator (畑铁工所) with an extrusion diameter of 0〇9 mm. After drying with a fluidized bed dryer (manufactured by Powlex), it was coarsely pulverized by a pin mill (free pulverizer, Takino Industry). The coarsely pulverized material was sieved to obtain the pesticide granule of Example D. /' Comparative Example e Take 40.2 parts by weight of Futhalide micropowder, AMYL〇xn〇iA (Mh〇n Cornstarch)·parts by weight, SORP〇L 5〇8〇 (Dongbang Chemical) 1 part by weight, 899.8 parts by weight of CLAY-S (manufactured by Shengguangshan Mining Co., Ltd.) mixed with a Nouta mixer (Fuii = udal) to obtain a mixed powder 1 part by weight. The mixed powder 丨 _ part by weight is mixed with 2 parts by weight of water and then kneaded by a Nouta mixer (Fuji pauda). This kneading basket is used in a basket type granulator ( The 畑 工 工 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出 挤出Over 30 201008488 FuthaUde (calculated as active ingredient) AMYLOXNo.lA Bentonite Fuji Comparative Example e 2.0 SORPOL5080 胜 Shengguangshan CLAY-S Bal 5.0 1.0 bal Total (W/W%) 100.0 100.0 0 Dissolution rate of active ingredient after 2曰 (%) Dissolution rate of active ingredient after 7曰 (0/〇) 9.2 20.7 tt Take the 烧 m beaker and put it into 300ml of water, and slowly mix it at a water temperature of 25±1〇c. # Into the pesticide granules, slowly disturbed at a water temperature of 25 ± rc. After the granules to be used are put into the granules for a set period of time, the water in the beaker is taken 5 〇〇μ1 and analyzed by a high-speed liquid phase layer to calculate the concentration of the active substance of the pesticide. The dissolution rate of the active ingredient is obtained from the concentration of the pesticide active material and the amount of the active substance contained in the pesticide granule. Further, the dose of the pesticide used in the dissolution rate of the active ingredient was determined, and the amount of the pesticide active ingredient in the rabbit was determined. ~ is the following Fermzone: 400mg Furametpyr: 130mg Compound A: 76mg Izozosulfuron: 225mg Clothianidin: 850mg Tricyclazole: 750mg Futhalide : 13mg 31 201008488 sieve, the pesticide granule of comparative example e The dissolution rate of the active ingredient in each of the above tables was determined by the following method. Take a 500ml beaker and put it into water 300ml. At a water temperature of 25±Γ (: pounds into which a pesticide granule is added, slowly stir at a water temperature of 25±rC. ''After setting the pesticide granules for a set time, take the beaker The water of 500μ1 is calculated by high J, and the concentration of the active substance of the pesticide is calculated. The amount of the active substance contained in the pesticide granule is used to obtain the dissolution rate of the active ingredient, and the dissolution rate of the active ingredient is used. Nongfu New Zealand, the amount of pesticide active ingredient. q Ferimzone: 400mg Furametpyr: 130mg Compound A: 76mg Izozosulfuron: 225mg Clothianidin: 850mg 31 201008488 [ Industrial Applicability According to the present invention, a pesticide granule capable of suppressing the dissolution of an active ingredient of a pesticide in water and capable of sustaining an active ingredient of a pesticide for a long period of time can be obtained. [Simplified description of the drawing] No [Major component symbol description] None ❹ 32 201008488 Tricyclazole: 750mg Futhalide: 13mg [Industrial Applicability] and the active ingredient of the active ingredient in water. [Simple description of the diagram] No [Main component symbol description] 201008488 _ towel request Chinese manual and patent scope revision (report) - γ.-λϊ- « · .·-, ^ Invention patent specification; 1° Pf revision (in the format and order of this manual, please do not change any more, ※marking department 埴^) ※Application number: ※Application 曰: (爹※1PC Classification: 1^^2006.011, invention name: (Chinese/k) Pesticide granule GRANULATED AGRICHEMICAL II. Abstract: The present invention relates to a pesticide granule comprising an active ingredient of a pesticide, a pregelatinized starch, and a bentonite. The active ingredient of the above pesticide is The solubility of water at 20 ° C is less than 700 mg / L ' and in the range of 20. (: octanol / water partition coefficient is 1.4 ~ 3.5 'relative to 1 〇〇 part by weight of pre-gelatinized temple powder, the content of bentonite is 20 to 800 parts by weight; such a pesticide granule can inhibit the dissolution of the active ingredient of the pesticide in water, and can sustain the effect of the active ingredient of the pesticide for a long time. III. Abstract: ❹ A granulated agrichem Ian containing an agrichemical active component, an -starch (pregelatinized starch) and bentonite, wherein the agrichemical active component has a water solubility at 20°C of less than 700 mg/L, and an octanol-water distribution coefficient at 20°C within a range from 1.4 to 3.5, and the amount of the bentonite is within a range from 20 to 800 parts by weight per 100 parts by weight of the pregelatinized starch is resistant to water elution of the agrichemical active component, and therefore the effect of the Agrichemical active component can be « maintained over a long period. 201008488 VII. Patent application scope ·· 1. A pesticide granule containing pesticide ^ Sexual surfactants. 4. If the pesticide granules of the second or second application scope of the patent application have a load hardness of 350 g or more. Among them, the pesticide granules 5. The pesticide granules according to claim 1 or 2, wherein the pesticide granules have a load hardness of 350 g or more and i 〇 Kg or less. ^ ', , 6, as in patent application No. 1 or 2, pesticide granules, wherein the active ingredients of the pesticide are selected from the group consisting of Ferimzone, Furametpyr, Tricyclazole, and heat. Futhalide, and S-l-propyl-5-amino-2-isopropyl-4~{2-tolyl H3-oxy-2,3-dihydro-1H-pyrazole-1-sulfur The carbamate constitutes at least one of the group. 7. The pesticide granule according to claim 1 or 2, wherein the effective ingredient of the pesticide is Ferimzone. 33 201008488 VII. Patent application scope: L A pesticide granule containing pregelatinized starch and bentonite. Gray ash is effectively formed into v-knife and pre-gelatinized starch. The active ingredient of the pesticide is at + 4 20 ° C / moisture _ The number is 7GGmg/L ' and in ^ · Ο έρ ΙχΊ ΐλΐ, increase the lion weight. Total amount, total of face-to-face remuneration (2) 2: Pesticide granules 3. 鸢 Sexual surfactants as claimed in Article 1 or 2 of the patent application. The agricultural green agent of the item, wherein the pesticide granule containing the non-ionic consumption of the first or second item, wherein the pesticide granule has a negative hardness of 350 g or more. 5. The agrochemical granules according to claim 1 or 2 wherein the load hardness of the pesticide granules is 350 g or more and 1 〇 Kg or less. 6. A pesticide granule according to claim 1 or 2, wherein the active ingredient of the pesticide is selected from the group consisting of Ferimzone, Furametpyr, Tricyclazole, and Futhalide. And S-allyl-5-amino-2-isopropylindole phenyl)-3-oxy-2,3-dihydropyran-1-thiodecanoate constitute at least in the group 1 species. ❹ 7. For the pesticide granules of claim 1 or 2, the effective pesticide is divided into Ferimzone. 33 201008488 IV. Designation of representative drawings: (1) The representative representative of the case is: None (2) The symbol of the symbol of the representative figure is simple: None 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: None