TW201004567A - A method for enhancing the rainfastness of glyphosate - Google Patents

Abstract

A method to enhance the rainfastness of glyphosate by applying a composition com- prising (a) glyphosate or at least one agriculturally acceptable salt, derivative or mix- tures thereof, and (b) at least one rainfastness enhancing herbicidal component B, or at least one agriculturally acceptable salt, derivative or mixtures thereof, to unwanted vegetation, crops, crop seed or other crop propagating organ.

Description

201004567 VI. Description of the invention: [Technical field to which the invention pertains] The present invention relates to a method for enhancing a kiln or a salt thereof or a conjugate thereof. [Sexuality] [Prior Art] Jiabosai and its salt in agriculture, industry and recuperation The area is widely used as a herbicide. It is usually applied as a formulated product to be applied to protect or control the foliage of the plant. However, the reliability of such combinations is highly dependent on weather conditions. Carbophosphorus and especially its salts are highly water soluble and can slowly penetrate into the surface of waxy leaves. Therefore, the Jia Phoser plug is easily washed away from the surface of the blade by rain or sprinkling. Since Jiaphos plug has virtually no herbicidal activity in the soil, its effectiveness can be significantly reduced by this flushing. A common problem in the use of gamma phosphate is therefore that its effectiveness is reduced if it is rained shortly after application. Therefore, the method of overcoming this problem should enhance the "rain resistance" of Jialinsai. Methods for enhancing the rainfastness of galaxies by using specific adjuvants or formulation auxiliaries have been disclosed in the literature (see, for example, WO 95/16351, WO 97/00010). However, it is known that the rainfastness of the Jia Phoser formulation is not satisfactory because it requires at least six hours of rain-free period after application to achieve optimal control potential. If rain occurs within two hours of application, it may be necessary to apply a galvanic plug. Surprisingly, it has now been found that the application of a composition comprising a carboplatin and at least one herbicidal component B which enhances the rainfastness is effective to enhance the rainfastness of the carboplatin. SUMMARY OF THE INVENTION 141151.doc 201004567 The present invention therefore relates to a method for enhancing the rainfastness of a galaxin by applying a composition to an undesirable plant, crop, crop seed or other crop reproductive organ, the composition comprising: a) Jiadisan or at least one agriculturally acceptable salt, derivative or mixture thereof, and b) at least one herbicidal component b which enhances rainfastness, or at least one agriculturally acceptable salt, derivative or mixture thereof . The invention further relates to a herbicidal composition comprising: carboprene or at least one agriculturally acceptable salt, derivative or mixture thereof, and saflufenacil or at least one agriculturally acceptable salt thereof Or a mixture in a ratio of 1:50 to 50:1. [Embodiment] Cascade [common name N-(phosphonium fluorenyl) glycine] is a well-known non-selective systemic herbicide, which is described, for example, in US Pat. No. 3,799,758 and US Pat. No. 4,4505,531. . Jiake is sold under the trade names RoundupTM and T〇uch (jownTM from (for example) Monsanto. Jiaphos can also be obtained and sold in the form of its agriculturally acceptable salt, such as Jiasei-Two Money [69254-40] -6], Jiabosai-isopropyl record [38641-94-0], Jia stuffed-single money [4〇4 65-66-5], Jia Bowle-_[70901-20-1], Jiadisu Sesame-semi-sodium [70393-85-0], Jialinsai-trimethylpyrene [81591-81-3]. Preferably, the use of Jiagansai in the form of monoammonium, diammonium, isopropanol or trimethylsulfonium salt The term "herbicidal component B for enhancing rainfastness" means herbicidal active ingredient B (herbicide B), preferably in combination with galaxin or one or more agriculturally acceptable salts, derivatives or mixtures thereof ( For example, when applied simultaneously or sequentially, 141151.doc 201004567 can enhance the financial rainability of the galaxin or one or more agriculturally acceptable salts, derivatives or mixtures thereof. The examples are preferably as individual or combined examples. The herbicidal component B which enhances the rain resistance is preferably selected from the group consisting of: B.1 Porphyrinogen-IX oxidase inhibitor (PPO inhibitor) B.2 Photosystem I inhibitor (PS I inhibitor) B.3 Inhibitor of photosystem II (PS II inhibitor)

Preferably, the herbicidal component B is a herbicidal compound B.1 which is selected from the group consisting of a porphyrinogen-IX oxidase inhibitor (PPO inhibitor). The mode of action of the PPO inhibitor system is based on the key steps of inhibiting chlorophyll biosynthesis in plants and belongs to the E class in the HRAC classification system (see HRAC, Classification of Herbicides According to Mode of Action > http://www.plantprotection.org /hrac/MOA.html) 4 conjugates. According to the present invention, the PPO inhibitor is preferably selected from the group consisting of: B.1.1 phenyl uracil herbicide; B.1.2 triazolone and oxadiazolone herbicide; B.1.3 dicarboxymethyl carbamide imide herbicide And B.1.4 nitrophenyl ether, B.1.5 selected from the following group of mixed PPO: ethoxyfen, fluazolate, 11 pyraflufen, pyrazine Fluthiacet, thidiazimin, pentoxazone, pyraclonil, profluazol, fluoroquinone 141151.doc 201004567 ( Flufenpyr) & ° is better than nigracilin (〇nyraci〇fen). The inhibitor is selected from the group consisting of Bli, β.12, β.1.3 and Β.1.4. Phenyluracil herbicides (category B.l.i) include benzfendizone and compounds of formula I and salts thereof,

R is selected from the group consisting of: propargyloxy, allyloxy, isopropoxy, c(=o)nhso2nr3r4, c(=0)N-NR3R4, C(=〇)〇-CR3R5- C(=0)-OR7 > C(=〇)〇-R4 . C(=0)0-CHR5- c(=o)nhso2nr3r4, nhso2nr3r4, S02NHC(=0)NR3R4, CH2-CH(Cl)C 〇2-R6 and formula 0C(CH3)2-C(=0)-0R7 groups; R is hydrogen, fluorine or gas; R3 hydrogen or CVCV alkyl; R4 hydrogen or (VC4-alkyl; R system Or a C1-C4-alkyl or an agriculturally acceptable cation; and R7 is (^-(: 4-alkyl, propargyl or allyl. According to a preferred embodiment of the invention, the herbicidal compound B·1 comprises At least one compound of the formula I and a salt thereof, preferably at least one agriculturally acceptable salt. Examples of compounds of the formula I include -fluofopyrazine (butafenacil KRkcpCOO-CCCH^-CpO) - 141151.doc 201004567 OCH2CH=CH2,r2 =h), -flupupacil (flupropacilMRLcpCOO-CEKCHA, R2=H), and -pyrimidin (Ι^=(:(=0)ΝΗ802Ν((:Η3)((:Η((:Η3)) 2), R2 = F). According to a particularly preferred embodiment of the invention, preferred are compounds of formula I in which the variables R! to R7, independently or in combination, have the following meanings R1 is selected from the group consisting of C(=〇)NHS02NR3R4, C(=0)〇-CR3R5-C(=〇)-〇r7; c(=o)nhso2nr3r4 is preferred; c(=o)〇 -cr3r5-c(=〇)_OR7 is also preferred; R2 is hydrogen, fluorine or gas; hydrogen or fluorine is preferred; fluorine is preferred; R3 is hydrogen or Ci-CV alkyl;

Ci-C4-alkyl is preferred; fluorenyl is preferred; R4 is ketone-based; isopropyl is preferred; R5 is hydrogen or cvcv alkyl; C1-C4-fluorenyl is preferred; and r7 is C1- C4-alkyl, propargyl or allyl; dipropyl is preferred. Preferred herbicides B11 are fluproxil and pyrimidin. In a particularly preferred embodiment of the invention, the herbicide B comprises or specifically is a fluoropropane spray. 141151.doc 201004567 In another particularly preferred embodiment of the invention, herbicide B comprises or specifically pyrimidin. Phenyluracil herbicides (B.1 · 1) can be found, for example, in G. Theodoridis "Protopor-phyrinogen-IX-oxidase Inhibitors", "Modern Crop Protection Compounds", Vol. 1, Wiley-VHC 2007, page 153 -186 pages; CDS Tomlin, "The Pesticide Manual", 13th edition, BCPC (2003), and The Compendium of Pesticide Common Names http://www.alanwood.net/pesticides/. Pyrimidine oxalate having the following formula [common name 2-gas-5-[3,6-dihydro-3-methyl-2,6-dioxo-4-(trifluoromethyl)-1-(2Η) )-pyrimidinyl]-4-fluoro-N-[[methyl(1-methylethyl)amino]sulfonyl]clumamine]

See, for example, W0 0 1/83459 and The Compendium of Pesticide Common Names http://www.alanwood.net/pesticides/. Triazolone and oxadiazolone herbicides (B. 1.2) include compounds of formula II and salts thereof,

141151.doc 201004567 wherein X is 0 or NR11, and R8 is selected from the group consisting of propargyloxy, allyloxy, isopropoxy, CH2-CH(Cl)C〇2-R12 groups and a group of nh-so2-ch3; R9 is fluorine or gas; R1G is CH3, a third butyl group; R" is CHF2, or forms a 1,4-butane group with R10; R12 is hydrogen, alkyl or Agriculturally acceptable cations. Examples of compounds of formula II include azafenidin, carfentrazone, sulfentrazone, oxadiazon, and propiyl oxadiargyl. Also included are the salts of humulone, including in particular the sodium, potassium, ammonium or substituted ammonium salts thereof as defined above, in particular mono-, di- and tri-Ci-Cg-alkylated salts 'e.g. isopropyl sulphate; and an ester of oxazolone, in particular an alkyl ester such as a decyl ester, an ethyl ester, an isopropyl ester. A suitable example of such an ester is oxazolidin-ethyl. Triazolone and oxadiazolone herbicides (B_1.2) can be found, for example, in G. Theo-doridis "Protoporphyrinogen-IX-oxidase Inhibitors", "Modern Crop Protection Compounds j Vol. 1, Wiley-VHC 2007, 153-186; CDS Tomlin, "The Pesticide Manual" 13th Edition, BCPC (2003), and The Compendium of Pesticide Common Names http://www. alanwood.net/pesticides/ ° Dicarboxyximide Weeding Agent (Class B.1.3) includes a compound of formula III, I41151.doc -9- (111) 13 (111) 13201004567

Wherein R13 is hydrogen, fluorine or chlorine; R14 is selected from the group consisting of: propargyloxy, allyloxy, 1-methyl-2-propynyloxy, o-ch2co2-r16, CH=C (C1 C02-R16 and isopropoxy; R15 is fluorine or gas; or R14 and R15 together form part of 0-CH2-C(=0)-NR17, wherein R17 is propargyl and wherein the oxygen atom is relative to R13 The position is meta; R16 is hydrogen, alkyl or an agriculturally acceptable cation. Examples of compounds of formula III include cinidon, flumioxazin, flumiclorac, and flumipropyn. Also included are salts of <*" and flumethacic acid, specifically including the sodium, potassium, ammonium or substituted ammonium salts thereof as defined above, specifically mono-, di- and tri- CrCs-alkylammonium salts, such as isopropylammonium salts; and esters of anthrone and flumethacic acid, in particular C^-Cs-alkyl esters thereof, such as methyl esters, ethyl esters, isopropyl groups ester. Suitable examples of such esters are anthrone-ethyl and fluoroethene-pentyl. Dicarboxymethylimine herbicides (Class B. 1.3) can be found, for example, in G. Theodoridis "Protopor-phyrinogen-IX-oxidase Inhibitors", "Modern Crop Protection Compounds", Vol. 1, Wiley-VHC 2007, page 153 -186 pages; CDS Tomlin, "The 141151.doc -10- 201004567

Pesticide Manual, 13th edition, BCPC (2003), and The Compendium of Pesticide Common Names http://www. alanwood.net/pesticides/ o Shishuangji phenyl herbicide (Bl. 4) includes arsenic Furyloxyphen and a compound of formula IV,

Wherein R18 is chloro or trifluoromethyl; R19 is selected from the group consisting of hydrogen, CVC4-alkoxy, C02-R21, C(=0)0-CH2C02-R21 'C(=0)0-CH( CH3)C02-R21, C(=0)NH-S02-R22, preferably selected from the group consisting of hydrogen, CVC4-alkoxy, co2-r21, c(=o)o-ch2co2-r21, C (=0)0-CH(CH3)C02-R21, C(=0)NH-S〇2-R22 'Cj-Φ C4-alkoxy-C(=0)NH-R22; R20 is hydrogen, fluorine Or gas; * R21 is hydrogen, (^46-alkyl or an agriculturally acceptable cation; and R22 is (^-(:4 alkyl). Examples of compounds of formula IV include nitrofen, bifenfen (bifenox), oxyfluorfen, acifluorfen, fluoroglycofen, fluorodifen, fomesafen, flufenacil (lactofen), selefen 141151.doc 11 201004567 (halosafen), chlornitrofen, fluoro herbicide, methoxy herbicide, nitrofluorfen and ethipj^mi^ Its salts and esters, herbicide ether, bifenfen, phlorin, axifen, acesulfame, triflurane, sulfonamide Ether, fluoxetine, halosafen, total chlorfenapyr, fluoroherbic ether, methoxy herbicide, trioxazole, preferably include acesulfame and acesulfame. a salt, a sodium salt, a potassium salt, an ammonium salt or a substituted ammonium salt as defined above, in particular a mono-, di- and tri-Ci-Cg-alkyl salt, such as an isopropanol salt; And esters of acesulfame and acesulfame, in particular, G-C8.alkyl esters, such as decyl esters, ethyl esters, isopropyl esters. A suitable example of such salts is Yaxifen - Sodium. Suitable examples of such esters are acesulfame-mercapto and acesulfame-ethyl. For nitrophenyl ether herbicides, see, for example, G. Theodoridis "Pro-toporphyrinogen-IX-oxidase Inhibitors" , "Modern Crop Protection Compounds", Vol. 1, Wiley, VHC 2007, pp. 153-186; CDS Tomlin, "The Pesticide Manual", 13th edition, BCPC (2003), and The Compendium of Pesticide Common Names http: //www.alanwood.net/pesticides/. According to a second preferred embodiment of the present invention, the herbicidal composition of the present invention comprises at least one other herbicide B.2 which can affect the photosynthesis (PSI inhibitor) of the plant by diverting electrons in the photosystem I. PSI inhibitors belong to class D of the above HRAC classification system. PSI herbicide B.2 includes cyperquat and difenzoquat, as well as chlorpyrifos herbicides, including Daishakui I41151.doc 12 201004567 (diethamquat), diquat, Morfamquat and paraquat, including its salts, specifically its hydrochloride, hydrobromide, hydroiodide, sulfate, nitrate, carbonate, alkanoate ( For example, formate and acetate), alkyl sulfates (such as methyl sulfate (methyl sulfate), and the like. Suitable examples of such salts are diethamquat dihydrochloride, diquat fast dihydrogen Bromate, succulent dihydrochloride, chlorpyrifos dihydrochloride, and diquat sulphate. Preferred PSI herbicides include bipyridylium herbicides for grass fast and diquat (including the above) Salt), especially for grasses (including the above salts). PSI herbicides can be found, for example, in CDS Tomlin, "The Pesticide Manual", 13th edition, BCPC (2003), and The Compendium of Pesticide Common Names , http://www.alanwood.net/pesticides/0 according to the third comparison of the present invention In an embodiment, the herbicidal composition of the present invention comprises at least one other herbicide B.3, which is an inhibitor of electron transfer in plant photosynthesis. The mode of action of the compounds comprises inhibiting electron transfer in plant photosynthesis photosystem II (PSII) Inhibitors. They belong to the C1 to C3 classes in the above HRAC classification system. Suitable PSII inhibitors are selected from the group consisting of: B.3.1 aryl urea herbicides; B.3.2 triazine (di) ketone herbicides; B .3.3 chlorotriazine herbicide; B.3.4 pyridazinone herbicide; B.3.5 phenylamino phthalate herbicide; B.3.6 nitrile herbicide; 141151.doc -13- 201004567 B.3.7 bentazon (bentazone) and its salts, such as sodium bentazone; B.3.8 nonoxytriazine and sulfonium triazine herbicide; and B.3.9 selected from the following group of mixed herbicides: buthiuron (buthiuron), Etidiuron, thiazafluron, amicarbazone, bromofenoxim, flumezin, methazole, enemies Propanil), pentanochlor, paridate and Lori Pyrifalol. Suitable PSII inhibitors are preferably selected from the above categories B.3.1 to B.3.8. Aryl-based herbicides (B.3.1) include, for example, anisuron, buturon, chlorbromuron, chlorotoluron, chloroxuron, ethoxylate Chloreturon, difenoxuron, . Dimefuron, diuron, fenuron, fluometuron, fluothiuron, isoproturon, isouron , linuron, methabenzthiazuron, methuron, metobenzuron, metobromuron, metoxuron, monoxolon (monoisouron), monolinuron, monuron, neburon, parafluron, phenobenzuron, siduron, tetrafluorol ( Tetrafluron), tebuthiuron and thidiazuron. Preferred aryl urea herbicides (B.3.1) include chloromeron, diuron, ligulon, isoproturon, and butazolam. Triazine (di) ketone herbicides (B.3.2) include, for example, amantadine 141151.doc -14-201004567 (ametridione), amipuzin, hexazinone, butyrazine Isomethiozin, metamitron and metribuzin. Preferably, the triterpenoid (2) herbicide (B.3.2) comprises hexagram, oxazinone and oxazinone. Triterpenoid herbicides (B.3.3) include, for example, atrazine, chlorazine, cyanazine, cyprazine, eglinazine, and grass Ipazine, mesoprazine, procyazine, proglinazine, propazine, sebuthylazine, simazine, chlorpyrifos (terbuthylazine) and trietazine. Preferred is chlorine three. Qin herbicide (B.3.3) includes atrazine, oxazin and cimaazine. Bacterial herbicides (B.3.4) include (for example) brompyrazon, chloridazon, dimidazon, metflurazon, norflurazon ), oxapyrazon and pydanon. Preferably, the ketone herbicide is oxalic. The phenylcarbamate herbicide (B.3.5) includes, for example, desmedipham, phenisopham, phenmedipham, and beetin-ethyl. Nitrile herbicides (B.3.6) include, for example, bromobonil, bromoxynil, chloroxynil, dichlobenil, iodobonil and iodine. Ioxynil and its salts and esters, specifically bromoxynil, hydroxybenzonitrile and iodobenzonitrile. A preferred nitrile herbicide is bromoxynil. The benzothiadiazinone herbicide (B.3.7) includes bentazon and its salts, specifically 141151.doc -15- 201004567 an alkali metal salt thereof, such as a bastasis-sodium. The decyloxytriazine and sulfonium triazine herbicides (B.3.8) include, for example, atraton, dipropetryn, metometon, prometon, Secbumeton, simeton, terbumeton, ametryne, aziprotryne, cyanatryn, desmetryne , dimethametryn, methoprotryne, prometryn, simetryn, and terbutryn. Preferred are methylthiotriazine herbicides such as chlorpyrifos, azide, cyanide, diquat, isoprene, geranazine, chlorpyrifos, chlorhexidine and de-grass. Preferably, the thiotriazine herbicide is herbicide. Especially preferred are PSII inhibitors of various herbicides. • B.3.1, specifically, chloromeron, diuron, ligulon, isoproturon and/or butyl beta, - Β.3.2, specifically hexazinone, oxazinone and/or Azinone, - Β. 3.3, specifically atrazine and / or oxazin, and - Β. 3.8, specifically, chlorpyrifos, and mixtures thereof. Particularly preferred is the composition of the present embodiment, wherein the PSII inhibitor is selected from the group consisting of: butazosone, atrazine, cyanazine, simazine, chlorpyrifos, chlorpyrifos, hexazinone, Azinone, diuron, isoproturon, bromoxynil and agriculturally acceptable salts thereof and mixtures thereof. More preferably, the composition of the preferred embodiment wherein the PSII inhibitor is selected from the group consisting of atrazine, chlorpyrifos, chlorpyrifos, hexazinone, oxazin 141151.doc -16 - 201004567 ketone , diuron, isoproturon and its agriculturally acceptable salts and mixtures thereof. In a particularly preferred composition of this embodiment, herbicide B comprises or specifically is hexaploquinone. In other particularly preferred compositions of this embodiment, herbicide B comprises or specifically is oxazinone. In other particularly preferred compositions of this embodiment, herbicide B comprises or specifically diuron. In other winterly preferred compositions of this example, herbicide B comprises or specifically is isoproturon. In other particularly preferred compositions of this embodiment, herbicide B comprises or specifically is atrazine. In other particularly preferred compositions of this embodiment, the herbicide B comprises or specifically is herbicide. In other particularly preferred compositions of this embodiment, herbicide B comprises or specifically is oxalicin. In other particularly preferred compositions of this embodiment, herbicide B comprises or specifically is a mixture of atrazine and herbicide. In other particularly preferred compositions of this embodiment, herbicide B comprises or specifically is a mixture of atrazine and oxazinone. PSII inhibitors can be found, for example, in K.-W. Miinks and K.-H. Mtiller, "Photosynthesis Inhibitors", "Modern Crop Protection Compounds", Vol. 1, Wiley-VHC 2007, pages 359-400; CDS Tomlin, "The Pesticide Manual", 13th edition, BCPC (2003), and The Compendium of Pesticide Common 141151.doc 201004567

Names, http://www.alanwood.net/pesticides/ ° The compositions of the present invention may also comprise one or more safeners C as component c). Safeners are also known as herbicide safener organic compounds which, in some cases, result in better crop plant compatibility when applied in combination with a specific herbicide. Some safeners themselves have herbicidal activity. In such cases, the safener acts as an antidote or antagonist to the crop plant and thereby reduces or even prevents damage to the crop plant. However, in the compositions of the present invention, safeners are generally not required. Accordingly, a preferred embodiment of the invention relates to a composition which does not contain a safener C or which is substantially free of a safener (i.e., less than 1% by weight based on the total amount of galaxin and herbicide B). Suitable safeners c for use in the compositions of the present invention are known in the art, for example, see The Compendium of Pesticide Common Names (http://www.alanwood.net/pesticides/); Farm Chemicals Handbook 2000 Vol. 86, Meister Publishing Company, 2000; B. Hock, C. Fedtke, RR Schmidt, Herbizide, Georg Thieme Verlag, Stuttgart 1995; WH Ahrens, Herbicide Handbook, 7th Edition, Weed Science Society of America, 1994; and KK Hatzios, Herbicide Handbook ' Supplement to the 7th edition, Weed Science Society of America, 1998. Safener C includes benoxacor, cloquintocet, cyometrinil, cyprosulfamide, dichlormid, dicyclonon, double ten Dietholate, fenchlorazole, fenclorim, flurazole, fluxofenim, solution 1411Sl.doc -18 - 201004567 furilazole, diphenyl Isoxadifen, mefenpyr, mephenate, naphthalic anhydride, 2,2,5-trimethyl-3-(dichloroethenyl)-1, 3-oxazolidine, 4-(dichloroethenyl)_ι_oxa-4_azaspiro[4.5]pyrazine and oxalyl nitrile (〇xabetrinil), and agriculturally acceptable salts thereof (if Has a slow base) its agriculturally acceptable derivatives.

2,2,5-Dimethyl_3_(dioxaethyl)_ι,3-oxazolidine [cas number 52836-31-4] is also known as R-29394. 4-(diqiethylene) _ι·Oxa_4_Azaspiro[4.5] brothel [CAS No. 71526_〇7_〇3] Also known as ad_67 and M〇n 4660 〇 The composition of the present invention preferably comprises at least one group selected from the group consisting of The compound acts as a safener C: oxaloin, detoxification quinone, sulforaphane, di- propylene amide, oxazolidine, oxadiazepine, valerian, oxazolidine, dibenzoxazole, hydrazinolysis Grass _, naphthalene dicarboxylic acid needle, 2, 2, 5 _ tridecyl _3 _ (two gas ethyl aryl) _ 1, 3 stagnation, and 4 _ (two gas acetyl oxa _ 4 _ snail [(5] decane and oxalic acid, and agriculturally acceptable salts thereof and (where the compound has a (7) (10) group) an agriculturally acceptable derivative as defined below. Preferred Embodiments of the Invention A composition for applying no safener c or substantially no safener (i.e., less than i% by weight based on the total amount of at least herbicide B). In other words, in the preferred embodiment , the combination of the invention: 匕3 Jia scale plug and at least a species of herbicide group with enhanced rain resistance Part B, better: seed increase _ rainy weeding group sage as a _ difficult component. In this article, the active ingredient" means insecticide and safener. The conjugate may also contain one or more with Jiayusai And herbicide B does not weed _ as component d). These other herbicides can broaden the range of activity of the composition of the present invention 141151.doc • 19· 201004567. However, other herbicides D are generally not required. Preferred embodiments of the invention are compositions which are free of other herbicides D or which are substantially free of other herbicides D (i.e., less than i% by weight based on the total amount of gamma phosphate and herbicide B). In a preferred embodiment, the composition of the present invention comprises a carboplatin and at least one herbicidal component B which enhances the rainfastness, preferably a herbicidal component B which enhances the rainfastness as the sole herbicidal active component, preferably as the only component. - Insecticidal active component. In particular, the composition of the invention consists of a carboplatin and at least one herbicidal component B which enhances the rainfastness, i.e. it does not contain a safener C and does not contain another herbicide D. The organic moiety mentioned in the definition of substituents R1 to R22 - with the term halogen A collective name for each member of a group listed separately. All hydrocarbon chains (i.e., all alkyl groups) may be straight or branched, and the prefix Cn_cm in each case indicates the number of possible carbon atoms in the group. Examples of such meanings are: -CVC4.alkyl and Ci-CV alkoxy-Ci-C4-alkyl and hydroxy-CVC4-alkoxy-CrCU-alkyl alkyl moiety: CH3, C2H5, n-propyl Base, ch(ch3)2, n-butyl, CH(CH3)-C2H5, ch2-ch(ch3)2&c(ch3)3;

Ci_C6_alkyl group·the above c丨-C4-alkyl group, and (for example) n-decyl group, 1-methylbutyl group, 2-methylbutyl group, 3-methylbutyl group, 2,2-dimethyl group Propyl, 1-ethylpropyl, n-hexyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl, 1-methylpentyl, 2-methylpentyl, 3- Methylpentyl, 4-methylpentane I41151.doc -20· 201004567 base, ι,ι-dimercaptobutyl, 12•didecylbutyl, i 3 dimercaptobutyl, 2,2-di Methyl butyl, 2,3-dimethylbutyl, 3,3-dimethylbutyl 1-ethylbutyl, 2-ethyl-butyl, trimethylpropyl, 1,2,2· Trimethylpropyl, rethylberhydrylpropyl or 1-ethyl-2-methylpropyl, preferably methyl, ethyl, n-propyl, lf-ethyl, n-; , 1-dimethylethyl, n-pentyl or n-hexyl; CVCV hydroxyalkyl: for example, hydroxymethyl, hydrazine-hydroxyethyl, 2-hydroxyethyl-buyl, 1-propan-1-yl, 2- Propyl, 3-propanyl κ, 1 • propyl 2 — 2, propyl 2 —, 1 — butyl butyl, 2 — butyl group, % butyl group, 4-hydroxybutan-1-yl 1-hydroxybuty-1-hydroxybutan-2-yl, 2-hydroxybutan-2-yl

3·yl, 2-hydroxy-but-3-yl, hydroxy-2-methylpropyl-3-yl, hydrazine hydroxy-2-methylpropan-3-yl, 3-hydroxy-2-methylpropane-3 _ base and 2 hydroxymethylpropan-2-yl, 1,2-dihydroxyethyl, anthracene, 2_dihydroxy-propanyl-3-yl, 2,3 dihydroxypropyl-3-yl, 1,2-di Hydroxypropyl-2-yl, iota, 2-dihydroxybuty-4, 2,3, dihydroxybutane-4, 3,4-dihydroxybutan-4-yl, anthracene, 2-dihydroxybutanol _ base, 12 dihydroxybutanyl 3-yl, 2,3-dihydroxybut-3-yl, iota, dihydroxypropyl-3-yl, 23-dihydroxy-2-methyl-propan-3-yl ; _ cvc4-alkoxy and c丨-C4·alkoxy_Ci_C4_alkyl and hydroxy-Ci_C4·decyloxy-CrC4-alkyl alkoxy moiety: for example methoxy, ethoxy, Propyloxy, 1-methylethoxy, butoxy, bromopropoxy, 2-methylpropoxy and dimethyl ethoxy; if weeding, rain-tolerant weeding group The compounds mentioned in Part B, Herbicide d and Safener C can form geometric isomers (e.g., E/z isomers), and both the pure isomers and mixtures thereof can be used in the compositions of the present invention. 141151.doc •21 - 201004567 If the compound mentioned in the herbicidal component B, the herbicide d and the safener c, which has enhanced the rainfastness, has _ or more chiral centers, thus enantiomers or Where diastereomers are present, either the pure enantiomers or diastereomers and mixtures thereof may be employed in the compositions of the invention. If the cans S, the herbicide-preventing herbicide component B, the herbicide d and the compound mentioned in the Angular Agent C (see below) have ionizable functional groups, they may also be agriculturally acceptable salts or It is used in the form of a mixture. - "General" ’ 'The preferred ones of the cationic salts are those in which the cation has no adverse effect on the action of the active compound ("agriculturally acceptable"). Preferred cations are metal ions, preferably lithium, sodium and unloaded; alkaline earth metal ions, preferably calcium and magnesium; and transition metal ions, preferably manganese, copper, zinc and iron; and ammonium and substituted ammonium (hereinafter also referred to as organic ammonium), wherein one to four hydrogen atoms are passed through (VC4·alkyl, hydroxy·CrC4-alkyl, Ci_C4_alkoxy_Ci_C4-alkyl, hydroxy-Cl-C4-alkoxy) Substituting _Ci_C4_alkyl, phenyl or benzyl, preferably hydrazine, hydrazine, isopropyl, sulphate, triterpene, tetramethylammonium, tetraethyl hydrazine, tetrabutyl broth, 2-ethylammonium, 2-(2-hydroxyethoxy)ethylhistyl-ammonium, bis(2-hydroxyethyl-methyl)ammonium, benzyltrimethylammonium, benzyltriethylammonium; And scaly ion cerium ions, preferably tris(C^C:4-alkyl)nickel (e.g., tridecyl fluorene); and oxonium ion 'preferably tris(CrCr alkyl) oxonium. The anion of salt is mainly vaporized 'bromide, fluoride, iodide, hydrogen sulfate, sulfhydryl sulfate, sulfate, dihydrogen phosphate, hydrogen phosphate, nitrate, hydrogencarbonate, carbonate, hexafluoride. Citrate An anion of hexafluorophosphate, benzoate and Ci_C4_alkanoic acid, preferably 141151.doc -22- 201004567 formate, acetate, propionate and butyrate. In the form of agriculturally acceptable derivatives, it is also possible to use compounds having a suspending group such as a brewing amine, for example mono- or di-c Cp alkyl decylamine or aryl decylamine; esters such as allyl esters, Propargyl propyl ester, Q-Cw alkyl ester or alkoxyalkyl ester; also a thioester such as an alkyl thioester. Preferably, mono- and: _Ci_C6-alkyl guanamine is a group - and dimethyl decylamine. Preferred aryl amides are, for example, mercaptoaniline and 2_qi Φ mercaptoaniline. Preferred alkyl esters are, for example, methyl esters, ethyl esters, propyl groups异丙 'Isopropyl ester, butyl ester, isobutyl ester, pentyl ester, methyl (丨-methylhexyl) ester or isooctyl (2-ethylhexyl) ester. Preferred Ci_c4-alkoxy _c〗 C4_alkyl ester is a linear or branched Ci_C4_alkoxyethyl ester, such as methoxyethyl ester, ethoxyethyl ester or butoxyethyl ester. Examples of branched-alkylthioesters Ethyl thioesters. Preferred derivatives are decylamines and esters, and more preferably esters. In the compositions of the present invention, the relative weight of galaxin and herbicide 3 is compared: preferably between 1:50 and 50: In the range of 1, specifically in the range of 1:50 to 1:1, more preferably 1:5G to 1:2G; more preferably 1:45:1 to 1:35. Another preferred embodiment of the invention. In the examples, the relative weight of the galaxin and the herbicide B is preferably in the range of 1:6 〇 to 60.1 'specifically in the range of 1:5Q to 1:1, more preferably from $5 to 1:5. More preferably 1:45:1 to 1:35. In another preferred embodiment of the present invention, the relative weight of the Jia Phoser and the herbicide B is preferably in the range of 50:1 to 1:5〇. Specifically, it is in the range of 5 〇 to 1:10, more preferably 50:1 to 1:1. In another preferred embodiment of the present invention, the relative weight of the jia Phoser and the herbicide B is 141151.doc • 23· 201004567, and the weight is preferably in the range of 45:1 to 1:45, specifically 45:1 to In the range of 1:10, it is more preferably 45:1 to 1:1. Thus, in the method and use of the present invention, the Kaiser plug and the at least one herbicidal component B are applied in the same weight ratio. The methods and compositions of the present invention can be administered in a conventional manner by techniques well known to those skilled in the art. Suitable techniques include spraying, atomizing, spreading, spreading or watering. The type of application is determined in a well known manner for the intended purpose; in any case, such techniques should ensure that the active ingredients of the present invention are distributed as finely as possible. The methods and compositions are applied in place primarily by spraying, in particular, a thinning spray of an aqueous dilution of the active ingredients of the composition. Application can be carried out by conventional spraying techniques in which, for example, water is used as a carrier and the ratio of spray applied on the ground is from about 10 to about 500 ang/ha, preferably from about 80 to about 400 ang/ha, applied in the air. The ratio is 1〇-5〇l/ha. The herbicidal composition can be applied by a low volume and ultra low volume method, and it can be applied in the form of microparticles (application of the mixture of particles is carried out without a liquid carrier). If some crop plants are less tolerant to the active ingredient, application techniques for spraying the herbicidal composition by means of a spraying device can be used, such that the herbicidal compositions are in contact with the leaves of the susceptible crop plants (if contacted As little as possible, at the same time, the leaves or bare soil (post-directional spray, loose soil) of the undesired plants growing under the crop plants can be reached. The method of the invention is applied after the plants are not desired to be germinated, i.e., applied during and/or after germination of the plant is not desired. The components of the composition t of the present invention may be applied simultaneously or separately in the order of 141151.doc -24·201004567. Preferably, the components of the compositions of the invention are applied in combination. In a further preferred embodiment of the invention, the components of the compositions of the invention are applied separately. In the other preferred embodiment of the invention, the components of the compositions of the invention are applied simultaneously. In a further preferred embodiment of the invention, the components of the compositions of the invention are applied sequentially.

More preferably, the components of the compositions of the invention are applied simultaneously in a combined manner. In a further preferred embodiment of the invention, the components of the compositions of the invention are applied sequentially in a combined manner. Furthermore, the methods and compositions of the present invention can be applied during or after the germination of crop plants. The benefits of the compositions of the invention are especially in that they have excellent post-emergence herbicidal activity, i.e., they exhibit good herbicidal activity against germinated undesired plants. Thus, in a preferred embodiment of the invention, the composition is applied after the plant is not desired to be germinated, i.e., during and/or after germination of the plant is not desired. It is especially advantageous to apply the mixture of the invention after emergence, when the plants are not expected to grow from the beginning of the development of the leaves until the opening of the flowers. In the case of post-emergence treatment of plants, the methods and compositions of the present invention are preferably applied by application of the leaves. The rate of application of the composition of the neat active compound (i.e., carboplatin, herbicide B and, if desired, herbicide D) depends on the density of the undesired plants, the developmental stages of the plants, and the climate in which the composition is used. Conditions and application party 141151.doc • 25· 201004567 Act. In general, the application rate of the composition (the total amount of Jia Phoser, herbicide B and other optional active substances) is 15 to 1580 g/ha, preferably 380-1220 g/ha, more preferably 750-1 150 g. /ha, and especially the active ingredient (ai) of 745-1 130 g/ha. In a preferred embodiment of the invention, the application rate of the composition of the 'pure active compound (i.e., cans, herbicide B, and optionally herbicide D) provides long-term weed control when applied after targeted spraying. The application rate of Jialinsai is usually 250 g/ha-5000 g/ha or 360 g/ha- 1440 g/ha', preferably 360 g/ha-1440 g/ha, and more preferably 360 g/ha- Within the range of 1080 g/ha or 720 g/ha-1080 g/ha active substance (ai). The application rate of herbicide B (pyrimidin is preferred) is usually 5 g/ha_1〇〇〇g/ha, preferably 5 g/ha-140 g/ha 'more preferably 5 g/ha-100 g /ha is particularly preferred in the range of 20 g/ha-100 g/ha or 25 g/ha-70 g/ha active substance (ai). The application rate of the herbicidal compound B.1 (the total amount of the herbicide β·ι) is generally in the range of 5 g/ha to 1000 g/ha, preferably 10 g/ha 2〇〇g/ha and more preferably 2〇. g/ha-140 g/ha or 20 g/ha-l〇〇g/ha active substance range. The application rate of the herbicide B.1.1 (the total amount of the herbicide B11) is preferably in the range of 5 g/ha to 1000 g/ha, more preferably 10 g/ha 2 〇〇 g/ha and more preferably 2 〇 g/ Ha-140 g/ha or 20 g/ha-l〇〇g/ha active substance range. The application rate of pyrithione is generally in the range of 1 〇g/ha 2 〇〇g/ha, and preferably in the range of 20 g/ha to 140 g/ha or 20 g/ha to 100 g/ha of active substance. The application rate of pyrimidin is preferably from 5 g/ha to 140 g/ha and more preferably from 20 g/ha to 100 g/ha or from 25 g/ha to 70 g/ha of active substance (ai). 141151.doc -26 - 201004567 The application rate of herbicide Β·1.2 (the total amount of herbicide b. 1.2) is generally in the range of 10 g/ha-500 g/ha, preferably 1〇_2〇〇g/ Ha, more preferably 20-140 g/ha 'preferably 20-100 g/ha active substance (as). The application rate of the herbicide B.1.3 (the total amount of the herbicide b. 1.3) is preferably from 10 to 200 g/ha, more preferably from 20 to 140 g/ha, most preferably from 20 to 100 g/ha of the active substance ( A_s·). • The application rate of herbicide B. 1.4 (the total amount of herbicide b. 1.4) is generally in the range of 1 〇〇g/ha_l〇〇〇g/ha, preferably 10_200 g/ha, more preferably 20-140. The best g/ha ' is 20-100 g/ha active substance (as·). The application rate of the optional herbicide D (the total amount of the herbicide d) is generally in the range of 1 〇g/ha to 2500 g/ha, and preferably 40 g/ha to 1500 g/ha or 60 g/ha- Within the range of 1000 g/ha active substance. The required application rate of safener C (if applied) is generally in the range of 1 g/ha_5 〇〇〇g/ha, and preferably in the range of 2 g/ha-5000 g/ha or 5 g/ha-5000 g/ha. Within the scope of the active substance. Preferably no safener is applied or no safener is applied and φ is therefore applied at a rate of less than 5 g/ha, in particular less than 2 g/ha or less than 1 g/ha. The method according to the invention is applied at the following times And the composition: preferably before the start of rainfall. Before the early, preferably as early as six hours before the rain 'better early to four hours before the rain, especially good as early as two hours before the rain' is better early to one hour before the rain, the best As early as 30 min before the rain. The methods and compositions of the present invention are suitable for controlling a variety of harmful plants, including monocotyledonous weeds, in particular annual weeds, such as grass weeds (grass), including Echinochloa species, such as scorpions (lakes) 141151.doc •27· 201004567 Echinochloa crusgalli var. crus-galli); Digitaria species, such as Digigaria sanguinalis; Setaria species, such as blue Foxtail (Setaria viridis) and glutinous (Setaria faberii); Sorghum species, such as the Arab sorghum (Sorghum halepense Pers.); Avena species (Avena species) For example, wild oats (wild oats); Cenchrus species, such as Cenchrus echinatus; Bromus species; Lolium species; II grasses (Phalaris) Species); Eriochloa species; Panicum species; Brachiaria species; - annual bluegrass (Poa annua), black Grass (Alopecurus myosuroides), Aegilops cylindrica, Agropyron repens, Apera spica-venti, Eleusine indipa, Bermudagrass Cynodondactylon) and the like. The methods and compositions of the present invention are also suitable for controlling a variety of dicotyledonous weeds, in particular broadleaf weeds, including Polygonum species, such as the golden buckwheat (Polygonum convolvulus); the broad genus (Amaranthus) Species, such as mar (Amaranthus retroflexus); Chenopodium species, such as the common gray cabbage (Chenopodium album L.; Sida species, such as spiny yellow flower stable ( Sida spinosa L.); Ambrosia species, such as common ragweed (Ambrosia artemisiifolia); Acanthospermum species; Anthemis species; 141151.doc ·28· 201004567

Atriplex species; Cirsium species; Convolvulus species; Conyza species; Cassia species; Commelina species; Datura (Datura species); Euphorbia species; Geranium species; Galinsoga species; Morning glory (Ipomoea species); Lamium species; Malva species; Matricaria species; Sysimbrium species; Solanum species; Xanthium species; Veronica species; Amaranthus (Viola species); common scorpion (Stellaria media), ramie (Abutilon theophrasti), Hemp sesbania (Sesbania exaltata Cory), eucalyptus ( Anoda cristata), Bidens pilosa, Brassica kaber, Capsella bursa-pastoris, Centaurea cyanus, Galeopsis tetrahit, Gallium aparine Cai Hua (Heli Anthus annuus), Desmodium tortuosum, Kochia scoparia, annual Mexicana (Mercurialis annua), Myosotis arvensis, Papaver rhoeas, Raphanus raphanistrum, _ Salsola kali, sinapis arvensis, Sonchus arvensis, Thlaspi arvense, Tagetes minuta, Brazil's Richardia brasiliensis, And so on. The methods and compositions of the present invention are also suitable for controlling a variety of annual and perennial 141151.doc -29-201004567 sedge weeds, including cyperus sPecies, such as Cyperus rotundus L. Oil sorrow (Cyperus esculentus L.), geranium (Cyperus brevifolius Η·), sedge (Cyperus microiria Steud), stinky head Fragrant (Cyperus iria L.) and the like. Accordingly, the present invention is also directed to a method of combating dicotyledonous weeds, in particular broadleaf weeds, which comprises the following substances prior to and/or after germination of the crop, preferably after unwanted planting or germination: a) Jiaphosphonate or at least one agriculturally acceptable salt, derivative or mixture thereof, and b) at least one herbicidal component B which enhances the rainfastness, or at least one agriculturally acceptable salt or mixture thereof, applied to the crop plant The part. The methods and compositions of the present invention are useful for combating/controlling common harmful plants in useful plants (i.e., crops). The methods and compositions of the present invention are generally suitable for combating/controlling undesirable plants in plants: - cereal crops including, for example, cereals such as wheat (wheat aeii/vwm) and wheat-like crops such as durum wheat ( T. durum), single wheat (one wheat (7\ wowococcwm)), double wheat (two wheat (77. and cracked wheat (spe/m)), Naked wheat (Rye (Seca/ec*erea/e)), black wheat (small rye, barley (barley vw/gare)); - Yuxitai (corn; blanket rice (Zea; 141151.doc -30-) 201004567 - 粱 (eg 蜀泰(*Sorg/jw/w Z>z'co/c»Mr)); rice (rice (Ο/Τ^α ίρρ.), for example, Asian type rice·5αί/να) and African type g/a6errima); and sugar cane; • Beans (Fahceae) including, for example, soybean (Glycine max·), peanut (Rallow Peanut A>>/7〇gaea), and legume crops For example, cowpea (including cowpea (Pbww ·?αίζ·νΜΑΜ), pigeonpea and red bean), beans (including broad bean (Fzck /Μα), red bean ·5/?ρ·), and Bean π/ ? )) and lentils (/eWlS cw/iwark var.) Brassicaceae, including (for example) Brassica (Brassica oleracea (Srawzca πα/?Μ·5)), Brassica napus (Brassica napus) Brassica napus)), cabbage (5_o/eracea var·), mustard (eg mustard (5·jwwcea), wild rape (5. cawpesirz··?), stalked vegetables (5. «arznosa), black Mustard (5. m'gra) and Yankees (5· iowr «e/oriz7)); and turnip (Brassica rapa var.) other broad-leaved crops, including, for example, hollyhock, cotton, pot Hemp, linseed, sugar beet, potato and tomato; TNV crop (TNV: trees, nuts and vines), including, for example, grapes, citrus, pome fruits (such as apples and pears), coffee, pistachio and oil Coconut, stone fruit (eg peach, almond, walnut, olive, cherry, plum and apricot); - turf, pasture and pasture; onion and garlic; 141131.doc -31- 201004567 - bulbous ornamental plants, examples (4) (four) and narcissus; Conifers and deciduous trees, such as pine, eucalyptus, eucalyptus, maple, elm, hawthorn, wild apple And Rhamnus (buckthorn) *, and - ornamental (iv), for example made of mouth eight flowers, gold box flower, rose blocks and snapdragons. The present month method and composition are particularly suitable for combating and controlling undesirable plants in the following crops: wheat, barley, rye, triticale, durum wheat, rice, corn, axe, sile, *, ', 蜀黍, soybeans, bean crops (such as cowpea, and J flat ugly), metaplasia, geranium, sugar beet, potato, cotton aphid, Brassica crops (such as rapeseed, canola, fennel, cabbage and steamed Cyanine, turf, grape, pome fruit (such as apples and pears), stone fruit (such as peach, almond, walnut, eucalyptus, cherry, plum and apricot), hanging orange, coffee, pistachio garden ornamental plants (such as roses, Daffodil, calendula, gold

Grass), bulbous ornamental plants (such as camp golden incense and narcissus), foreign Hui, garlic V conifers and deciduous trees (9) such as pine, eucalyptus, occupation, maple, elm, Erye apple and buckthorn), Dried beans, bananas, pineapples, coconuts, mangoes, clocks, 2; 4ώί ❹. - Pomegranate, eucalyptus, hedgehog, rubber tree, palm tree, cocoa 'state persimmon, pasture, nut tree, cashews tree and pupunha palm. The lunar method and the compound are especially suitable for resisting/controlling undesirable plants in the following crops 'wheat, barley, rye, triticale, durum wheat, rice, corn, ganzi, alfalfa, soybean, beans Crops (eg peas, ugly), metaplasia, sunflowers, sugar beets, potatoes, cotton, Brassica crops (eg rapeseed, canola, cumin, cabbage and steamed clams), turf, grapes, Heli ~ , 1 fruit (such as apples and pears), stone fruit (such as peach, almond, 141151.doc -32- 201004567 walnut, olive, cherry, plum and apricot), citrus, coffee, pistachio, garden ornamental plants (such as roses , u-flowers, golden box flowers, snapdragons, bulbous ornamental plants (such as tulips and narcissus), onions, garlic, conifers and deciduous trees (such as pine, eucalyptus, eucalyptus, maple, elm, hawthorn Wild apples and buckthorn The methods and compositions of the present invention are preferably suitable for combating/controlling undesirable plants in the following crops: wheat, barley, rye, triticale, durum wheat, Φ rice, corn, Sugar cane, alfalfa, soybeans, legumes (eg peas, ugly and lentils), peanuts, sunflowers, sugar beets, horse yam, cotton, and genus (such as rapeseed, canola, mustard, cabbage, and turnip), Turf, grape, stone fruit (eg peach, almond, walnut, eucalyptus, cherry, plum and apricot), citrus, pistachio, onion, garlic and deciduous tree. The method and composition of the invention are preferably also suitable for resistance/control Undesired plants in crops: wheat, barley, rye, rice, corn, sweet vegetables, alfalfa, soybeans, legumes, sunflowers, potatoes, cotton, grasses, alfalfa, Portuguese _, stone fruit, citrus, a month# Seeds, kernels, dried beans, cowpeas, flowers S, coffee. Non, banana, pineapple, ram, mango, yogi, peony • right, tree, pine, hedgehog, rubber tree, palm tree, cocoa , America, persimmon, pasture, nut tree, cashew tree and pupunha palm. The method and composition of the invention are particularly suitable for application to the following crops: wheat, barley, rye, rice, corn, sweet,黍, soybean, bean crops, hollyhocks, potatoes, cotton, turf, grapes, stone fruit, hanging orange, and pistachio. 141151.doc -33- 201004567 Unless otherwise stated, in any of the varieties The compositions of the present invention are suitably suitable for application to the above crops. The compositions of the invention may also be used for genetic engineering or breeding for one or more: grassy agents, genetic engineering or breeding for one or more such as phytopathogens. In crop plants that are resistant, or (iv) red-range or breeding and resistant to insects. * For example, they are suitable for the following crop plants: preferably corn, wheat, sunflower, sorghum, cotton, rice, canola , rapeseed or soybeans' These crops are resistant to the following herbicidal PPG inhibitors: for example, 1 propylene vinegar, mouth biting, grass sulphate, oxaprofen, i oxalicone, w-amylamine, lycium, c-chew Oxalone, ketone, propofol, flufenic acid, flumethacic acid, ethinylamine, acesulfame, bifenfen, methoxy herbicide _, total herbicide, fluoridated herbicide _, flurene herb shout, sassafras Hal〇safen), lactofluridin, weeding, three air grass Test, or Fulufen; or a crop plant that has resistance to attack by certain insects by genetically modifying the gene that attracts the needle (4) toxin. Another preferred embodiment of the invention provides for control of Jia Scalee resistant weeds or crops. Carbophospha resistant crops include crops that exhibit a variety of properties other than gamma phosphate resistance, such as herbicide, antifungal or insect resistant crops, through multiple changes in the genome ("complex traits"). The present invention preferably provides for control of weeds or crops in soybean, corn, and small grain (e.g., wheat, barley, oat) crops. Another preferred embodiment of the present invention provides for the control of such weeds which are self-interfering and which are resistant or resistant to (4) plugs of conventional application rates. Examples of such weeds are ramie, amaranth, ragweed, alfalfa, 14I151.doc -34· 201004567 duck turf, white wine grass, Didiptera genus, (Eleusine), feipen (Erigeron) or ryegrass. According to another preferred aspect of the present invention, the anti-Jiaphos "self-generated" crop is controlled, preferably soybean, cotton, canola, flax, lentils, rice, sugar beet, hollyhock, tobacco, wheat or corn. crop. In a particularly preferred embodiment of the invention, the "self-generated" crop is a soybean crop. In another preferred embodiment of the invention, the "self-generated" crop is controlled to be a corn crop. In another preferred embodiment of the invention, the "self-generated" crop is a cotton crop. In another preferred embodiment of the invention, the "self-generated" crop is controlled by a canola crop. In such herbicide resistant or tolerant crops, the methods and compositions of the present invention can be used to control and control undesirable plants after crop germination. Accordingly, another particular embodiment of the invention relates to a method of controlling undesirable plants in a herbicide resistant or tolerant crop, in particular, the crop plants are resistant or tolerant to Jiaphos plug and optionally In addition, it is compounded with at least one of its herbicide resistance or tolerance, specifically at least one of the following herbicides, such as auxin, ALS inhibitors, etc., specifically, imidazolinone, A PP〇 inhibitor, preferably a PPO inhibitor. In this particular embodiment, the composition can be used to control and control undesirable plants after germination of the crop plants. In a specific embodiment, the methods and compositions of the invention are used to control undesirable plants in plants that are tolerant to herbicides, in particular, the crop plants are resistant or tolerant to Carbosee And additionally compounded with resistance or tolerance to other herbicides, in particular at least one herbicide under 141151.doc -35· 201004567: auxin such as dicamba, ALS inhibitor, specifically The imidazolinone, PPO inhibitor, preferably a PPO inhibitor. In this particular method of the invention, the method and composition of the invention are applied at least once prior to planting or germination of the herbicide resistant or tolerant crop plant to achieve effective control of the undesired plant, and also in herbicide resistance The composition is applied after the germination of the sexual or tolerant crop plants.

If the method and composition of the invention are used in a crop plant, i.e., if the method and composition of the invention are applied to the crop plant field after the crop has germinated, the method of application and rate of application for control can be applied. If some crop plants are less tolerant to the active ingredient, application techniques for spraying the herbicidal composition by means of a spray device mouth may be used, such that the herbicidal compositions are in contact with the sensitive crop plant leaves (if contacted). As little as possible, at the same time reach the leaves or bare soil of the undesired plants that grow under the crop plants (post-directional spray, loose soil). However, such methods are generally not required and the composition can be applied in a simple manner above the top (〇TT).

For example, tr, a composition comprising Carbospa or its agriculturally acceptable salt or derivative and to a herbicidal compound Bi, a preferred herbicide B11, a preferred pyrimidine, is especially useful for controlling in the field. Planting also has herbicide component B, preferably PPO inhibitor tolerant Jiadise tolerant 14 crops such as maize, canola, wheat, soybean or sunflower. Suitable composition: especially for the prevention and control in the field, which should be planted with sturdiness, ο et al., sugar cane or carcass tolerance and combined with herbicidal component B, preferably PP 视The sugarcane second-class composition with tolerance to the inhibitor can also be used to control undesired plants in crops with jia-ser-resistant resistance and pledge: 141151.doc -36 - 201004567 PPO inhibitors after crop germination . For example, a composition comprising galaxin or an agriculturally acceptable salt or derivative thereof and a PPO inhibitor herbicide is especially useful for controlling in the field of two crops: general crops such as maize, wheat, soybean , to the hollyhock and Gan Yan; and with the resistance of Jia phosphorus plug, if necessary, combined with the pp〇 inhibitor financial crop. • For example, 'a composition containing gamma phosphate or its agriculturally acceptable salt or derivative Φ and a ppo inhibitor herbicide is especially useful for controlling in the field of two crops: general crops of maize and sugar cane; And such crops with Jiaphos plug for tolerance and resistance to other herbicides as needed. These compositions can also be used to control undesirable plants in such crops after the crop has germinated. The methods and compositions of the present invention are particularly useful in so-called control procedures, and in particular, in planting control procedures, i.e., applying the compositions of the present invention to the site where the crop will be grown prior to crop planting or germination. • The present invention is therefore also directed to a method of controlling a plant in an undesired manner in a crop, which comprises applying the following to the crop prior to or prior to germination, preferably during and/or after the germination of the desired plant; The part to be planted: a) Jiaphosin or at least one agriculturally acceptable salt, derivative or mixture thereof, and b) at least one herbicidal component B which enhances rainfastness, or at least one of which is agriculturally acceptable Salt or mixture. In the control treatment of the present invention, at least one other herbicide D as described above and a herbicidal component B which enhances the rainfastness can be applied together. The term "applying together" includes simultaneous or sequential application. Similarly, the application of a group of sputum does not mean that the phosphatase, herbicide oxime, and optionally D must be applied as a single formulation or mixture of cans. In contrast, the compositions include the galangose and herbicide oxime and, if desired, a separate formulation of D, which may be administered as a single can mixture or via separate application methods. In either case, the galena plug, the herbicide oxime and one or more optional herbicides D can be applied simultaneously or sequentially. However, it is also possible to apply the herbicide D in the control treatment after sowing or even after the crop has germinated. When the method and composition of the invention are used in a control program, it may be applied prior to sowing (planting) or after sowing (or planting) of the crop plant and the germination month of the crop plant, preferably applying a combination prior to sowing of the crop plant. Things. In the control, it is generally possible to apply the composition to a certain mash of up to 6 months, preferably up to 4 months before the crop planting. The application can be carried out up to 1 day before the germination of the crop plant and preferably in the crop planting/planting Executed on a previous day, preferably at least one day before planting, preferably at least 2 days and especially at least 4 days, or 6 months to 1 day before germination, specifically 4 months before germination It is implemented in 2 days and more preferably 4 months to 4 days before germination. Of course, the control application can be repeated one or more times over this time range, such as one, two, three, four or five times. The active ingredients used in the compositions of the present invention are generally used in the form of neat materials and formulations. The formulation contains at least one organic or no 141151.doc-38-201004567 airborne material in addition to the active ingredient or composition. The formulation may also contain, if desired, one or more surfactants and (if desired or a plurality of other agents conventionally used in crop protection compositions. Active ingredients (Jiaphos, herbicidal component B and optional components) At least one of the cockroaches can be combined or separately.

❹ g g 可 可 , , , , , , , , , , , , , , , 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 At least one of the Jiaphosate and the herbicidal component B and the optional components C and D are usually combined in the form of a tank mixture prior to application. However, it is also possible to provide the herbicidal component b and optionally the group C and D to the medium; >, the seed premix and combine the premix with the Jiaphosin. . The formulation may be in the form of a single package containing the Jia Phoser and the herbicidal component B and optionally one or more herbicides D and liquid and/or solid carrier materials, and, if desired, one or more surfaces. The active agent and, if desired, one or more other adjuvants conventionally used in crop protection compositions. The formulation may be in the form of two or more (e.g., three, four or five) package formulations, one of which contains a formulation of herbicidal component B, preferably pyrimidin, and the other package contains a blend of carboplatin And, if desired, one or more other packages containing one or more other formulations comprising at least one component c, wherein all formulations contain at least one carrier material, if desired, one or more surfactants and If desired, one or more other adjuvants conventionally used in crop protection compositions. In the case of a two or more packaged formulation, the formulation containing herbicidal component B and the formulation containing the carboplatin and optionally one or more H1151.doc •39· 201004567 component c are mixed prior to application. Or a variety of formulations. Preferably, the mixing is carried out in a tank mixing mode, i.e., the formulation is mixed immediately prior to dilution with water or immediately after dilution with water. In each formulation, the active ingredient and other optional active materials are in the form of suspension, emulsification or dissolution. The formulation may be in the form of an aqueous solution, a powder, a suspension, a highly concentrated aqueous, oily or other suspension or dispersion, an aqueous emulsion, an aqueous microemulsion, an aqueous suspoemulsion, an oil dispersion, a paste, and a solution. Agent, material or granules for spreading. a terminal-viewing formulation which may comprise one or more liquid or solid carriers, (right-suitable) surfactants (eg, dispersants, protective colloids, emulsifiers, wetting agents, and tackifiers), and (if appropriate) ) Other adjuvants used to formulate crop protection products. Those skilled in the art are well versed in the formulation of such formulations. Other adjuvants include, for example, organic and inorganic thickeners, bactericides, antifreeze agents, antifoaming agents, colorants, and (in seed formulations) binders. 0 Suitable carriers include liquid and solid carriers. Liquid carriers include, for example, non-aqueous solvents such as cyclic hydrocarbons and hydrocarbons such as hydrazine, tetrahydrogen cages, deuterated naphthalenes and derivatives thereof, thiolated benzenes and derivatives thereof; alcohols such as carbamide , ethanol, propanol, butanol and cyclohexanol; nets such as cyclohexene; strong polar solvents such as amines (eg N-methylpyrrolidone) and water and pelts. Solid carrier system (for example) mineral soil, such as Shixia soil 1 glue, hair acid salt 'talc powder, kaolin, limestone, lime, white ridge, clay soil, loess, clay, dolomite, Shiyoshi, soil, sulfur _, magnesium sulfate,: crushed synthetic materials, fertilizers (such as sulfur (four), money, acid, 141151.doc 201004567 urea), and plant-derived products (such as cereal meal, bark powder, wood flour and nutshell powder) , cellulose powder) or other solid carrier. Suitable surfactants (adjuvants, wetting agents, tackifiers, dispersants and emulsifiers) are aromatic sulfonic acids (eg lignosulfonic acid (eg B〇rrespers type, Borregaard), phenolic sulfonic acid, naphthalene) Sulfonic acid (Morwet type, Akzo Nobel) and dibutylnaphthalenesulfonic acid (Nekal type, BASF AG)) and alkali metal salts, alkaline earth metal salts and ammonium salts, alkyl- and alkylaryl sulfonates of fatty acids, Alkyl sulfate, lauryl ether sulfate and fatty alcohol sulfate, and sulfated hexadecane, hepta- and octadecyl alkoxide, also fatty alcohol glycol ether, sulfonated naphthalene and its derivatives and hydrazine a condensate of an aldehyde, a condensate of naphthalene or naphthalenesulfonic acid with phenol and formaldehyde, a polyoxyethyl octyl phenol ether, an ethoxylated isooctyl-, an octyl- or nonylphenol, an alkylphenyl group or Tributyl phenyl polyglycol ether, alkyl aryl polyether alcohol, isotridecyl alcohol, fatty alcohol / ethylene oxide condensate, ethoxylated castor oil, polyoxyalkylene Shout or polyoxypropyl propyl ether, polyethylene glycol lauryl ether acetate, sorbitol ester, lignin sulfite waste liquid and protein, denatured protein, more (eg methylcellulose), hydrophobically modified starch, polyvinyl alcohol (Mowiol type, Clariant), polycarboxylate (BASF AG, Sokolan type), polyalkoxylate, polyvinylamine (BASF AG, Lupamin type), polyethylenimine (BASF AG, Lupasol type), polyethyl fluorene ratio acetophenone and its copolymer. Examples of thickeners (i.e., compounds which impart improved flow characteristics to the formulation (i.e., compounds having high viscosity at rest and low viscosity when in motion) are polysaccharides such as Huang Yuansheng (Kelzan® from Kelco), Rhodopol® 23 (Rhone Poulenc) or Veegum® (from RT·Vanderbilt); also 141151.doc •41 · 201004567 Organic and inorganic sheet materials such as Attaclay® (from Engelhardt). Examples of antifoaming agents are polyoxynizing emulsions (e.g., Silikon® SRE, Wacker or Rhodorsil® from Rh〇dia), long chain alcohols, fatty acids, fatty acid salts, organofluorine compounds, and mixtures thereof. A bactericide may be added to stabilize the aqueous herbicide formulation. Examples of bactericides are bisphenol and phenyl decyl hemiacetal (from ICI2Pr〇xel8 or Acticide® RS from Thor Chemie and from Rohm & Haas

Kathon® MK) is also a bactericidal agent based on isothiazolinone derivatives such as alkylisothiazolinone and stupid isoindole (from Actkill MBS from Thor Chemie). Alcohol, propylene glycol, urea or glycerin. Examples of coloring agents are both micro-water-soluble pigments and water-soluble dyes. Examples of dyes can be mentioned as the following dyes: Rhodamine B (Can be a b), CI pigment Red 112 and CL solvent red}, and pigment blue i5:4, pigment blue 15.3, pigment blue 15:2, pigment blue 15:1, pigment blue, pigment yellow pigment yellow π, pigment red 112, pigment red 48: 2, (4) Red 48:1, Pigment Red 57:1, Pigment Red 53:1, Pigment Orange 43, Cobalt Barium Only Trmw, Yan Yan Orange 34, Pigment Orange 5, Pigment Green 3 6, Pigment Green 7, Pigment White 6杂 γ γ 枓 枓 brown 25, test purple 10, test purple 49, acid red 51, acid red 52, acid · | · red 14, acid blue 9, acid yellow 23, test red I 〇, Authentic red 1. Examples of binders are polyvinylpyrrolidone, polyvinyl alcohol and methyl cellulose. For the preparation of emulsions, pastes or oils..v Knife liquid can be neutralized by water, or dissolved in oil or dissolved in 14H51.doc 201004567 by means of wetting agent, tackifier, dispersing agent or emulsifier (Jiaphos, weeding component B and If necessary, at least one of components C and D), or a concentrate composed of an active material, a wetting agent, a tackifier, a dispersing agent or an emulsifier and, if necessary, a solvent or an oil, and the like The concentrate is suitable for dilution with water. The powder, the spreading material and the spreading agent can be prepared by mixing or co-milling at least one of the cockroach and the herbicidal component B and the optional components C and d with the solid carrier. .

#粒 (e.g., coated particles, impregnated particles, and homogeneous particles) can be prepared by incorporating the active ingredient onto a solid carrier. The formulations of the present invention comprise an effective amount of the compositions of the invention which enhances the rainfastness. The concentration of the active ingredient in the formulation can vary over a wide range. In general, the formulation comprises i-98% by weight, preferably 1% to 6% by weight of active ingredient (Jiaphos, herbicidal component B and optionally other active ingredients). The purity of the active ingredient used is between 90% and 100%, preferably between % and 100% (according to NMR spectrum). The active ingredient and the composition of the invention may be formulated, for example, in the following form: 1. A product diluted with water: A water-soluble concentrate 1 part by weight of the active compound (or composition) is dissolved in % by weight Water or water soluble solvent. (d) Alternatives, wetting agents or other adjuvants may be added. The active compound is soluble and soluble when diluted with water. Thereby, a formulation having an active compound content of 10% by weight was formed. B dispersible concentrate U1151.doc -43- 201004567 Dissolve parts by weight of the active compound (or composition) in a weight fraction of cyclohexanone, and add 1 part by weight of a dispersant (eg polyethyl b) (4) Harbin (4) 1 water dilution to form a dispersion. The active compound content is 2% by weight. c The emulsifiable concentrate is 15 parts by weight of the active compound (or composition) dissolved in parts by weight of the organic solvent (for example, alkyl In the aromatic compound, a dodecylbenzene acid and an ethoxylated Wei oil (5 parts by weight each added) were added, and an emulsion was obtained by diluting with water, and the content of the active compound of the formulation was 丨5% by weight. D emulsion dissolves 25 parts by weight of the active compound (or composition) in 35 parts by weight of an organic/treat (for example an alkyl aromatic compound) with the addition of calcium dodecylbenzene sulfonate and ethoxylation Cannabis oil (5 parts by weight each). The mixture was introduced into 3 parts by weight of water by means of an emulsifier (Ultraturrax) and made into a homogeneous emulsion. The emulsion was obtained by dilution with water. The active compound content of the formulation was 2 5% by weight E suspension in a ball mill, pulverize 2 parts by weight of active compound (or composition)' and add 10 parts by weight of dispersant and wetting agent and 7 parts by weight of water Or an organic solvent to form a suspension of the fine active compound. A stable suspension of the active compound can be obtained by diluting with water. The active compound content in the formulation is 20% by weight. F water dispersible granules and water-soluble granules are finely ground by 50 parts by weight. Active compound (or composition), and added 141151.d〇 (201004567

The active compound content of the formulation was 50% by weight. Water dispersible powder and water soluble powder

And the addition of 25 parts by weight of the dispersant to the active compound (or group, wetting agent and silicone). Dilution with φ water to form a stable dispersion or solution of the active compound. Active compound of the formulation The content is 75% by weight. The Η gel formulation is mixed with 20 parts by weight of the active compound (or composition), 10 parts by weight of the dispersant, 1 part by weight of the gelling agent and 70 parts by weight in a ball mill. Water or organic solvent to form a fine suspension. After dilution with water, a stable suspension with an active compound content of 2% by weight is formed. 2. A product which can be applied without dilution. I Spreading agent 5 parts by weight of the active compound ( Or the composition) and thoroughly mixed with 95 parts by weight of the fine kaolin, thereby forming a powder capable of dispersing the active compound content of 5% by weight. J particles (GR, FG, GG, MG) finely ground 0.5 parts by weight The active compound (or composition) is combined and allowed to bind 99. 5 parts by weight of the carrier. The current method is extrusion, spray drying or fluidized bed, thereby forming an active compound content of 0. 5% by weight of the granules which can be applied without dilution. 141151.doc -45- 201004567 K ULV solution (ul) 10 parts by weight of the active compound (or composition) is dissolved in parts by weight of the organic solvent (for example, two Intoluene), thereby forming a product which can be applied without dilution at an active compound content of 10% by weight. Water can be prepared from an emulsion concentrate, a suspension, a paste, a wettable powder or water-dispersible granules by adding water. It is further advantageous to apply the composition of the invention alone or together with other herbicides or to apply it in admixture with other crop safeners, for example with agents for controlling pests or phytopathogenic fungi or bacteria. Also of interest is the mixing with mineral salt solutions for the treatment of nutritional deficiencies and trace element deficiencies. Other additives such as phytotoxic oils and oil concentrates may also be added. For the methods and compositions of the present invention, The boundaries in the preferred embodiments of the invention are to be understood as being preferred as examples, either alone or in combination with each other. The following examples are set forth to further illustrate The method of the present invention is disclosed, but should not be construed as limiting the present invention. The term "herbicidal component B which enhances rainfastness" represents a salt, derivative or mixture which is acceptable for agricultural use with galaxin or its genus Preferably, the herbicidal active ingredient B which enhances the rainfastness of the phosphate plug or one or more agriculturally acceptable salts, derivatives or mixtures thereof is applied. The enhancement of the rainfastness of the Jiaphos plug is via a mixture (including Jiaphos plug) And the herbicidal components b) and the single herbicidal component are determined by the herbicidal activity associated with simulating rainfall at different time intervals. The scale of the 〇·1〇〇% is used relative to the untreated plot. Inventive methods and groups 141151.doc 201004567 The evaluation of damage caused by the compound and the single herbicidal component was carried out. Here, 〇 means no damage and 100 means plants that completely destroy the weeds or crop species. The application was carried out using a fixed spray system with air pressurization and a tank spray volume of 2 liters. The spray rate of the spray device to each plant was adjusted according to the spray volume of 200 Ι/ha. The spray device is a spray can with four Teejet XR 1 1 002VS nozzles with a 50 cm spacing between nozzles. Application is carried out at the weed stage of 6 to 8 leaves. After application of the formulated herbicide, the leaves were washed with a 20 mm rainfall at the following intervals using a fixed rainfall simulation system: 15 min, 30 min, 1, 2, 3, 4 and 6 hours after treatment. Formulation of Active Ingredients: "Pyridinium A": Pyrimidine valerate has been formulated as a wettable granule (WG) containing 700 g of active ingredient per kg WG "Glyph A": Roundup Original , which contains 360 g of acid equivalent / liter of soluble concentrate (SL) "Jia Packing B": Roundup Trans orb, which contains 480 g of acid equivalent

/ L SL "Jia Phossein C": Roundup WG, which contains 720 g of acid equivalent / kg Example 1: Application rate: Mouth 唆 唆 醚 醚 A: 24.5 g / ha ° bite will be grass ether Jia Phos A : 1080 g/ha jia Phosegaphosphate plug B: 1080 g/ha jiajiasaijia phosphorus plug C: 1080 g/ha jia phosphatase 141151.doc •47- 201004567 pyrimidine oxalate A+ jiaphosphonate A: 24.5 g/ha pyrimidine saponin + 1080 g/ha filling plug mouth biting grass ether A + Jia stuffing B: 24.5 g/ha mouth biting grass ether + 1080 g/ha jiaphosphazepine valerian A + jiaphos C: 24.5 g/ha pyrimidine oxalate + 1080 g/ha Cascade has been mixed with pyrimidine oxalate A and carbamazepine A, jiaphosate B and jiaphosphonate C with 0.5% v/v Dash - From the deployment. Example 1.1: Control (no simulated rainfall after treatment) - Cassia Cassia (Cawk (CASOB) herbicidal treatment Days after application (DAA) 1 2 3 4 7 14 21 28 35 42 Pyrimidine alfalfa _ 八54 70 75 83 59 3 1 0 0 0 嘉 塞 A 0 2 6 14 44 52 59 58 55 71 嘉磷塞 B 0 2 9 19 63 76 94 97 97 76 嘉磷塞 C 0 2 6 15 60 62 74 83 93 96 Pyrimidine oxalate A+ 嘉磷塞 A 70 85 87 88 91 93 95 96 98 99 Pyrimidine 谜草谜 A+嘉磷塞 B 69 86 88 89 95 91 96 97 99 100 Pyrimidine 肟草谜八+嘉磷塞 C 69 85 90 89 94 89 94 96 97 97 141151.doc -48- 201004567 Example 1.2: Simulated rainfall 15 min after treatment - Herbicidal treatment of CASOB Treatment days after application (DAA) 1 2 3 4 7 14 21 28 35 42 Pyrimidine Grass Ether A 36 41 34 29 16 2 0 0 0 0 嘉磷塞 A 0 2 2 3 3 2 0 0 0 0 嘉磷塞 B 0 1 1 3 5 0 0 0 0 0 嘉磷塞 C 0 1 2 5 8 1 0 0 0 0 pyrimidine oxalate A + jiaphos plug A 26 40 35 39 43 41 38 28 11 3 pyrimidine oxalate A + jiaphosin B 31 44 54 69 69 68 67 63 49 30 pyrimidine oxalate A + Jia Pho Plug C 31 34 56 56 58 61 59 26 8 4

Example 1.3: simulated rainfall 30 min after treatment - herbicidal action on CASOB treatment days after application (DAA) 1 2 3 4 7 14 21 28 35 42 pyrimidine alfalfa field eight 50 65 69 60 33 1 0 0 0 0 Plug A 0 1 2 5 8 4 2 1 1 1 Jia Phossein B 0 2 1 3 11 3 2 0 0 0 Jia Phossein C 0 1 1 5 7 4 1 1 0 0 Pyrimidine Valerate A + Jia Phosphon A 41 84 83 86 86 86 88 88 91 88 pyrimidine sedge A+ jiaphosin B 54 76 84 88 90 90 93 92 95 97 pyrimidine oxalate A + gamma phosphate C 40 74 74 79 84 86 88 88 94 95 141151.doc 49- 201004567 Example 1.4: Simulated rainfall 1 hour after treatment - Herbicidal treatment of CASOB Treatment days after application (DAA) 1 2 3 4 7 14 21 28 35 42 Pyrimidine sedge key eight 53 73 74 79 53 2 0 0 0 0 嘉磷塞 A 0 1 2 6 7 4 3 2 5 5 嘉磷塞 B 0 1 1 4 10 9 7 4 7 4 嘉磷塞 C 0 1 1 6 10 7 9 3 4 5 Pyrimidine 肟草谜A+嘉磷Plug A 60 78 80 89 95 91 94 93 95 95 Pyrimidine 谜草谜 A+嘉磷塞 B 61 75 77 81 88 89 94 91 95 97 Pyrimidine oxalate A+ 嘉磷塞 C 54 79 82 86 91 90 91 93 96 95 Example 1.5: Simulated rainfall 2 hours after treatment - herbicidal treatment of CASOB Days after Hours (DAA) 1 2 3 4 7 14 21 28 35 42 Pyrimidine A 71 86 82 83 24 1 0 0 0 0 Jia Phoser A 0 1 3 8 13 26 24 25 29 31 Jia Phoser B 0 1 2 4 14 7 19 21 41 50 嘉磷塞 C 0 1 1 7 12 30 33 34 38 59 pyrimidine oxalate A+ 嘉磷塞 A 70 87 88 91 92 94 96 98 98 99 pyrimidine 谜草谜 A+嘉磷塞B 45 81 79 82 89 90 94 94 96 95 Pyrimidine oxalate A + gamma phosphate C 46 76 79 84 89 89 91 92 97 96 14115J.doc 50- 201004567 Example 1.6: Rain - Herbicidal effect on CASOB 4 hours after treatment Analog down processing

Days after application (DAA) 1 2 3 4 7 14 21 28 35 42

Jia padding A Jia Phossein B

'Bite the grass to shout A + Jia Phossein A pyrimidine oxalic acid A + Jia scale plug B tumor 肟 肟 越 A A + true magnetic red 61 81 79 88 22 2 0 1 5 12 21 29 31 36 48 43 0 2 7 13 33 26 28 46 87 87 0 2 3 6 10 9 6 4 7 8 66 84 88 90 95 92 98 100 100 100 67 84 86 93 95 95 98 99 99 99 68 84 88 80 94 95 97 98 99 98 Example 1.7 : After processing 6 hours simulated rainfall - herbicidal effect on CASOB treatment days after application (DAA) 1 2 3 4 7 14 21 28 35 42 pyrimidine sedge A 64 84 88 83 56 2 0 0 0 0 嘉磷塞 A 0 1 8 14 19 14 22 29 43 48 嘉磷塞 B 0 2 8 13 20 21 35 78 89 94 嘉磷塞 C 0 1 5 12 25 29 25 26 48 48 pyrimidine _ _ 八 + 嘉 phosphor plug A 64 86 87 90 90 88 96 97 98 100 pyrimidine alfalfa scale A + jiaphosin B 70 90 89 93 98 95 99 99 100 100 stalked grass called A + Zhenrui C 68 88 90 92 97 96 98 99 100 100 Example 2:

Application rate: pyrithione A: 24.5 g/ha pyrimidine ether Jiaphos A: 1080 g/ha Jia Phosin 141151.doc -51- 201004567 Jia Phoser B: 1080 g/ha Jiajiasaijia Pho Plug C: 1080 g/ha jiaphosphoropyrazine oxalate A+ jiaphosphonate A: 24.5 g/ha pyrimidine saponin + 1080 g/ha jiasuipyrifos A+ jiaphosphonate B: 35.0 g/ha pyrimidine Valerian Ether +1080 g/ha jiaphosphoropyrazine oxalate A+ jiaphosphonate C: 49.0 g/ha pyrimidine saponin +1080 g/ha jiaphosphorus has pyrimidine oxalate A, jiaphosate A, Mixtures of Jia Phossein B and Jia Phossein C and Jia Phossein A, Jia Phosin B and Jia Phossein C were blended with 0.25% v/v Dash. Example 2.1: Control (no simulated rainfall after treatment) - number of days after application of a small drought (5 c/z/nac/z/oa Crw^a//〇* (ECHCG) herbicidal treatment) AA) 1 2 3 4 7 pyrimidine oxalate A 22 21.25 13 7.25 2.5 jiaphosphonate A 3.25 3.25 11.25 23.75 87.5 jiaphosphorus plug B 2.5 8.75 21.25 32.5 93 jia phosphor plug C 0.75 7.5 21.25 30.25 86 pyrimidine _A_嘉+ A 80.75 79 78 80.5 91 pyrimidine alfalfa _ 八 + 嘉 phosphozein B 89.5 82.5 82.5 82.5 94.25 pyrimidine oxalic acid A + gamma phosphate C 68.25 71.25 65.5 68.75 92.5 * average results of four repetitions 141151.doc -52- 201004567 Examples 2.2 : Simulated rainfall 15 min after treatment - Herbicidal effect on ECHCG * Days after treatment (DAA) 1 2 3 4 7 Pyrimidine 谜草谜 A 4.75 6.25 4.25 4 1.75 Jia Phoser A 0 1 1.5 3.25 7.75 Jia Phoser B 0 1 0.75 1.75 8.75 Jia Phossein C 0.75 1 0.75 1.75 5 Pyrimidine oxalate A + Jia Phosphon A 17.5 20 15.5 19 19.25 Pyrimidine oxalate A + Jia Phosin B 20 27 31.25 34.25 61 Pyrimidine _ _ 八 + Jia Phosphate plug C 10 14.25 14.25 13.5 20 * Average results of four replicates Example 2.3: Simulated rainfall 30 min after treatment - for ECHC Herbicidal effect of G* Days after application (DAA) 1 2 3 4 7 Pyrimidine A. 15.5 9.25 7.5 6.5 2 Jiaphosate A 0 0.75 1.5 3.25 13 Jia Phosin B 0 0.25 3.5 4.5 20.5 Jia Phosin C 0 0.25 2 2 13.25 pyrimidine oxalate A+ jiaphosphonate A 20.25 31.5 26.25 27.25 66 pyrimidinyl A+ jiaphosphonate B 25 37.5 35.75 48 75.25 pyrimidine oxalate A+ jiaphosphonate C 12.25 16 20 26.25 26.25 *four repetitions Average results 141151.doc •53- 201004567 Example 2.4: Simulated rainfall 60 min after treatment - Herbicidal effect on ECHCG * Days after treatment (DAA) 1 2 3 4 7 Pyrimidine A A 19.25 14.5 12.25 7.5 2.25 Jia Constituent A 0.75 0.75 2.75 5.25 15.5 Jia Scalee B 0 0.5 1.5 3.5 16.25 Jia Phosin C 0 0.25 1 4.75 16.5 Pyrimidine A + Jia Phosphon A 50 43 43.25 63.75 85.5 Pyrimidine A + Jia Phosin B 55.25 50.5 52.5 70 87.75 Pyrimidine oxalate A+ jiaphosphonate C 50.5 43.25 47.5 63.25 87.5 * Average results of four replicates Example 2.5: Simulated rainfall 120 min after treatment - Herbicidal effect on ECHCG * Days after treatment (DAA) 1 2 3 4 7 pyrimidine i草 i^A 30 17 9.25 7 5.5 Jia Plug A 0 1.25 2.25 8.5 27.5 Jia Phossein B 0 1 0.25 4 19.25 Jia Phosin C 0 1.5 0.75 2.5 21 Pyrimidine A + Jia Phosphon A 70.5 53.75 70 78 87.5 Pyrimidine A + Jia Phosin B 70 46.25 66.25 79.25 84 pyrimidine scorpion mystery A + gamma phosphate C 75 76.25 74 80.25 88.75 * average of four replicates 141151.doc -54· 201004567 Example 2.6: simulated rainfall 240 min after treatment - herbicidal effect on ECHCG 1 treatment application Days after Hours (DAA) 1 2 3 4 7 35 17.75 16 11.25 8.75 Jia Phossein A 0 2.5 3 10 38.75 Jia Phossein B 0 5 3.25 11.25 66.5 Jia Phosin C 0 1.75 2 9.25 80 Pyrimidine Acetone A + Jia Phos A 76.25 79.5 82.5 87.5 95 pyrimidine oxalate A + gamma phosphate B 70 70 77 87.5 96.25 pyrimidine oxalate A + gamma phosphate C 73.75 75 82 87 97 * Average results of four replicates Example 2.7: Simulation after 360 min of treatment Rainfall - Herbicidal effect on ECHCG 1 Days after treatment (DAA) 1 2 3 4 7 Pyrimidine __ into 25 13 11.75 8.5 4.25 Jiaphosate A 0 5.25 4.5 16.25 52.25 Jia Phossein B 0 5.75 10.5 16.75 49.5 Jia Pho Plug C 0 1.75 2.5 11 70.5 Pyrimidine oxalate A + Jia Phosphon A 27.5 34.25 40.5 6 0.75 80 pyrimidine oxalic acid A+ jiaphosphonate B 32.5 31.25 38.75 66.25 81.5 pyrimidine oxalic acid A+ jiaphosphonate C 37.5 35 33.75 57.5 82 141151.doc -55- 1 average result of four replicates Example 3 : application rate: σ The bite will be the grass ether A: 24.5 g / ha bite will be the grass ether 201004567 Jia phosphorus plug C: 1080 g / ha jiajiasei pyrethroid A + Jia phosphorus plug C: 24.5 g / ha pyrethroid ether + 1080 g /ha Jiascale plug Example 3.1: Control (no simulated rainfall after treatment) - Herbicidal treatment of Mang (5 co/owwm) (ECHCO) Days after application (DAA) 1 2 3 7 14 Pyrimidine A 20 48.33 76.33 76.33 80 Jia Phosin C 0 0 10 66.33 100 Pyrimidine _ _ 八 + Jia Phossein C 40 47.33 57.66 88 100 Example 3.2 : Simulated rainfall 15 min after treatment - Herbicidal treatment of ECHCO Treatment days after application ( DAA) 1 2 3 7 14 pyrimidinol A 21 30.66 54.66 47.66 26.66 Jia Phosin C 0 0 0 21 85.66 Pyrimidine __入+嘉磷塞 C 30 51 82.33 67 88.66 Example 3.3: Simulation 30 min after treatment Rainfall - Herbicidal treatment of ECHCO Days after application (DAA) 1 2 3 7 14 Pyrimidine A 22.33 38.33 71 49.33 33.33嘉磷塞C 0 0 5.66 64.33 97.66 pyrimidine __入+嘉磷塞C 38.33 54.33 78 78.66 93.33 141151.doc -56- 201004567 Example 3.4: simulated rainfall 2 hours after treatment - herbicidal treatment of ECHCO after application Days (DAA) 1 2 3 7 14 Pyrimidine A 22.33 42.33 72 65 62.33 Jia Phosin C 0 0 4.33 72 99.33 Pyrimidine A+ Jia Phoser C 36.66 57.33 89 92.66 99.66 Example 3.5: 6 hours after treatment Simulated rainfall - Herbicidal treatment of ECHCO Days after application (DAA) 1 2 3 7 14 Feeding grass 16.33 43.33 72 65 62.33 Jia Phosin C 0 0 5.33 55 99 Pyrimidine __8+嘉磷塞 C 32.66 46.66 74 89.66 100 Example 4: Application rate: φ pyrimidine A: 24.5 g/ha pyrimidine ether Jiaphos A: 1080 g/ha jiaphosphine. Pyrimidine A+ jiaphos A : 24_5 g /ha pyrimidine oxalate +1080 g/ha scallop 141151.doc 57- 201004567 Example 4.1: Control (no simulated rainfall after treatment) - weeding of /powoea gra«山/ο/ζ·α (IPOGR) Effect Treatment Days after application (DAA) 1 2 3 7 Pyrimidine A 30.33 96 99.33 100 Jia Phos A A 0.3 1 1.3 37.5 Pyrimidine oxalate A+ jiaphosphonate A 97.8 99 99 100 Example 4.2: simulated rainfall 15 min after treatment - herbicidal action on IPOGR treatment days after application (DAA) 1 2 3 7 pyrimidine ϋΑ 23.33 41.66 53.33 56 嘉磷塞 A 0.8 1 1 6.3 Pyrimidine 谜草谜A+嘉磷塞 A 39.5 80 90.8 100 Example 4.3: Simulated rainfall at 30 min after treatment - Herbicidal treatment against IPOGR Treatment days after application (DAA) 1 2 3 7 Pyrimidinol A 23.66 39.66 63.33 86.66 Carbophosphorus A 0.3 0.8 1.3 5.8 Pyrimidine Acetone A + Jia Phosphon A 68.8 98 98 100 141151.doc -58- 201004567 Example 4.4: Simulated rainfall 2 hours after treatment - for IPOGR Herbicidal treatment days after application (DAA) 1 2 3 7 pyrimidine sorghum shouted into 24.33 63.33 86.66 99.66 jia Phosphon A 0.3 1.8 1.5 9.5 pyrimidine _ _ 八 + Jia Phossein A 90.8 98.3 98.3 100 _ Example 4.5: Simulated rainfall 6 hours after treatment - Herbicidal treatment against IPOGR Days after application (DAA) 1 2 3 7 Aquilaria A 27 87.66 97.66 100 Jia A A 0.3 1 1.8 8.8 Pyrimidine A + Jia Phos A A 97.5 99 99 100 Example 5: Application rate: pyrimidin A : 24.5 g/ha pyrimidine ether carbazide C : 1080 g/ha jiaphosphoropyrazine acesulfame A + jiaphosphonate C : 24.5 g / ha pyrethroid ether + 1080 g / ha Jia sai 141151. Doc -59- 201004567 Example 5.1: Control (no simulated rainfall after treatment) - Herbicidal treatment of erac/nirk (BRADE) After treatment (DAA) 1 2 3 7 14 Pyrimidine A 5.33 11.66 23 65 68.33 Jia Phossein C 0 0 0 59.66 100 Pyrimidine oxalic acid A + Jia Phosin C 21 27.66 55 91.33 100 Example 5.2: Simulated rainfall at 15 min after treatment - Herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 14 pyrimidine alfalfa _ eight 4.33 11 10.33 27.66 19.33 jiaphosate C 0 0 0 64.66 100 pyrimidine oxalic acid A + jiaphos plug C 10 11 19 71 100 Example 5.3: simulation 30 min after treatment Rainfall - Herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 14 Pyrimidine 趟 A 5.33 10.66 15 26.66 21.66 Jia Phoser C 0 0 0 45.66 100 Pyrimidine 喊草喊A+嘉磷塞 C 16.66 24 30.33 82.66 100 141151.doc -60- 201004567 Example 5.4: Simulating rainfall 2 hours after treatment - for BRADE Herbicidal treatment days after application (DAA) 1 2 3 7 14 pyrimidine valerian 鲢8 9 17.66 21.66 32.66 24.66 jia Phosphate C 0 0 0 67.66 100 pyrimidine _A_嘉+ Phosphorus C 15 17 32.33 67 100 Example 5.5: 6 Simulated rainfall 6 hours after treatment - Herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 14 ° Closely bite A 8.66 22.66 32 55.33 49 Jia Phoser C 0 0 0 69 100 Pyrimidine _八+嘉磷塞 C 22 31.33 43 81.66 99 Example 6 : Application rate: 嗤草酿 I : 30 g/ha11 坐草草 1 嘉磷塞 C : 1080 g/ha 嘉磷塞. oxadiazon + Jia Pho Plug C: 30 g/ha oxazolone + 1080 g/ha jiaphosate has been blended with a mixture of oxazolone and oxazolone and carbamazepine C with 0.5% v/v Dash. 141151.doc -61 - 201004567 Example 6.1: Control (no simulated rainfall after treatment) - White flower ghost needle (WIDPI) herbicidal treatment treatment days after application (DAA) 1 2 3 Juncao _ 69.66 94.33 99 Jia Pho Plug C 0 2 15.66 oxazolone + jiaphosin C 72.66 92 98.66 Example 6.2: Simulated rainfall 15 min after treatment - Herbicidal treatment of BIDPI Treatment days after application (DAA) 1 2 3 Valerone 51 54.66 53.33 Jia Pho Plug C 0 2 4 oxazolone + jiaphosin C 53 58.66 71 Example 6.3: Simulated rainfall 30 min after treatment - Herbicidal treatment of BIDPI Treatment days after application (DAA) 1 2 3 Valerone 68.66 87.66 94.66 Jia Pho Plug C 0 2.33 10 oxalofenone + jiaphos plug C 60 70 78 141151.doc -62- 201004567 Example 6.4: simulated rainfall 2 hours after treatment - herbicidal treatment of BIDPI treatment days after application (DAA) 1 2 3 ° Sitting grass _ 69.33 89 92.33 Jia Phossein C 0 2 9 oxazolone + Jia Phosin C 71.33 82 91.66 Example 6.5:

Simulated rainfall 6 hours after treatment - herbicidal effect on BIDPI treatment days after application (DAA) 1 2 3 ° sitting grass _ 56 86.66 92.33 jia Phosphon C 0 2.66 8.33 oxadiazon + Jia Phosin C 71 72 93.33 Example 7 : Application rate: Valerian _ : 30 g/hae by oxalyl phosphatidylcholine C : 1080 g / ha galaxetazin + jiaphosphonate C : 30 g / ha oxalofenone + 1080 g / ha Jia Pho The plug has been blended with a mixture of oxazolone and oxazolone and gamma phosphate C with 0.5% v/v Dash. 141151.doc 63· 201004567 Example 7.1: Control (no simulated rainfall after treatment) - Herbicidal treatment of E. coli (ECHCO) Days after application 〇MA) 1 2 3 7 ° oxalicone 14.66 54.66 76.66 76 Jia Pho Plug c 0 0 10 66.33 oxadiazon + jiaphosphonate C 16.66 44 39.66 91.33 Example 7.2: Simulated rainfall 15 min after treatment - Herbicidal treatment of ECHCO Treatment days after application (DAA) 1 2 3 7 σ oxalicone 9 33.33 36 56 Jiaphosate C 0 0 0 21 oxazolone + jiaphosate C 17.33 41.66 52.66 85.33 Example 7.3: Simulated rainfall 2 hours after treatment - Herbicidal treatment of ECHCO Treatment days after application (DAA) 1 2 3 7 ° oxalofen 14 32.22 37.66 50.33 jia Phosphon C 0 0 4.33 72 oxazolone + jiaphosin C 20 51 50.66 87.33 Example 8 : application rate: ° oxaloin: 30 g / ha ° oxalyl carbene phosphate C : 1080 g/ha jia phosphatase 141151.doc •64· 201004567 oxazolone + jiaphosphonate C: 30 g / ha oxazolone + 1080 g / ha jiaphosin has oxazolone and oxadiazon A mixture of Jiaphosin C was formulated with 0.5% v/v Dash. Example 8.1: Control (no simulated rainfall after treatment) - Herbicidal treatment of Brassica chinensis (BRADE) Treatment days after application (DAA) 1 2 3 7 β Sitting grass _ 3.66 18.33 24.33 40.33 Jia Phoser C 0 0 0 59.66 oxadiazon + jiaphosphonate C 11.33 26.66 29.33 93.66

Example 8.2: Simulated rainfall 15 min after treatment - Herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 ° Sitgrass _ 4 10.33 11.66 17.33 Carbophosphorus C 0 0 0 64.66 Zodrazone + Jiaphosate C 4.33 10.66 10.33 74.66 Example 8.3: Simulated rainfall 30 min after treatment - Herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 α oxalyl 10.66 19.66 11.66 18.66 Jia Phosin C 0 0 0 45.66 Ketone + Jia Phosin C 10 14.33 13.66 83 141151.doc -65- 201004567 Example 8.4: Simulated rainfall 2 hours after treatment - Herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 Valerian _ 15 14.33 13 16.66 Jiaphosate C 0 0 0 67.66 oxazolone + jiaphosin C 12 16 19.66 77 Example 8.5: simulated rainfall 6 hours after treatment - herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 olfactory grass _ 25 29 27.66 26 Carboplatin C 0 0 0 69 oxazolone + jiaphosphonate C 16 26 28.33 85.33 Example 9: Application rate: propiflufenamide: 60 g/ha propifluramide galvanite C : 1080 g/ha jiaphosphine cefoflucarbamide + jiaphosphonate C: 60 g / ha propiflufenic acid +1080 g / ha Jia Phosphate has been C The mixture fluroxypyr propynyl amine and amine fluoride grass and Ka of phosphorus plug C and 0.5% v / v Dash- starting formulation. 141151.doc -66 - 201004567 Example 9.1: Control (no simulated rainfall after treatment) - Herbicidal treatment of white flower ghost needle (BIDPI) Treatment days after application (DAA) 1 2 3 7 Propynefluramine 80 92 98 98.66 Jia Phossein C 0 2 15.66 96 Propyne Fluramide + Jia Phosin C 59.33 92 97.66 100

Example 9.2: simulated rainfall 15 min after treatment - herbicidal effect on BIDPI treatment days after application (DAA) 1 2 3 7 propiflufenamide 51 59.66 64 69 jiaphos plug C 0 2 4 61 propargyl flufenacetate + Jia Phossein C 60 58.66 76 81.66 Example 9.3: simulated rainfall 30 min after treatment - herbicidal effect on BIDPI treatment days after application (DAA) 1 2 3 7 propargyl flufenacetate 63.66 63 82 78.33 jiaphos plug C 0 2.33 10 76.66 Propargylamine + Carboplatin C 61.66 61.33 77.66 88 141151.doc -67- 201004567 Example 9.4: Simulated rainfall 2 hours after treatment - Herbicidal treatment of BIDPI Treatment days after application (DAA) 1 2 3 7 Propynefluramine 72.33 86.66 91.66 96.66 Carbophosphorus C 0 2 9 82.66 Propargyl fluoxetine + Jia Phosin c 68 85.33 92.33 98.33 Example 9.5: Simulated rainfall 6 hours after treatment - Herbicidal treatment of BIDPI After application Days (DAA) 1 2 3 7 Propyne-fluoxamide 66.66 84 91.33 92.66 Jia Ced C 0 2.66 8.33 83.33 Propargyl fluoxetine + Jia Phosphon C 63.33 88.33 98.66 100 Example 10 : Application rate: Propargyl fluacetamide: 60 g/ha propifluzamide plus phosphorus C: 1080 g/ha Propargylamine + Carboplatin C: 60 g / ha propiflufenic acid + 1080 g / ha Jia Phosphate has a mixture of propiflufenic acid and propargyl fluoxetine and Jia Phossein C with 0.5% v/v Dash - from the deployment. 141151.doc -68- 201004567 Example 10.1: Control (no simulated rainfall after treatment) - Herbicidal treatment of grapet/z/o/ia (IPOGR) Days after application (DAA) 1 2 3 7 14 Propyne gas Amine 19.33 93.66 98 98.66 97.66 Carboplatin C 0 0 5 17.33 93 Propargyl fluoxetine + Jia Phossein C 18.66 95.33 98 100 100 Example 10.2: 15 mi after treatment η simulated rainfall - herbicidal treatment of IPOGR after application Days (DAA) 1 2 3 7 14 Propyne flufenacetate 20.33 75 82.33 98.33 90 Jia Phosphorus C 0 0 4.66 9.33 59.33 Propyne flufenazone + Jia Phosphon C 26 79 98 100 100 Example 10.3 : After treatment 2 Hour simulated rainfall - weeding effect on IPOGR treatment days after application (DAA) 1 2 3 7 14 propofylflufenamide 24.66 80 94.33 99.66 100 jiaphos plug C 0 0 4 13.33 81.33 propargyl fluoxetine + jiaphosate C 28.66 89.33 97.66 100 100 Example 11 : Application rate: propargyl fluacetamide: 60 g/ha propiflufenic 141I51.doc -69- 201004567 jiaphosphonate C: 1080 g/ha jiaphosphine flufenamide + Jia Phossein C : 60 g / ha propiflufenic acid + 1080 g / ha Jia Phosphate has been introduced propiflufen and C A mixture of flufenacet and Jiaphosate C was formulated with 0.5% v/v Dash. Example 11.1: Control (no simulated rainfall after treatment) - Herbicidal treatment of Brassica chinensis (BRADE) Treatment days after application (DAA) 1 2 3 7 Propynefluramine 14.66 41 42.66 51 Jia Phosin c 0 0 0 59.66 Propargylamine + Carboplatin C 12.66 51.66 55.66 92 Example 11.2: Simulated rainfall 15 min after treatment - Herbicidal treatment of BRADE Treatment days after application (DAA) 1 2 3 7 Propynefluramide 28.33 64.66 80 82.33 Jia Phossein C 0 0 0 64.66 Propyfluoxetine + Jia Phossein C 12.66 52.33 72.66 93.66 141151.doc -70- 201004567 Example 11.3: Simulated rainfall 30 min after treatment - herbicidal treatment of BRADE Days after Hours (DAA) 1 2 3 7 Propionine Fluramine 22.33 53.66 76 76.66 Carbophosphorus C 0 0 0 45.66 Propyne Fluramide + Carboplatin C 12 64 90.66 98.66 Example 11.4:

Simulated rainfall 2 hours after treatment - Herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 Propionate 16.33 50.66 65 80 Carboplatin C 0 0 0 67.66 Propargylamine + Jiaphos C 18.33 50.33 90 94.33 Example 11.5: Simulated rainfall 6 hours after treatment - Herbicidal treatment of BRADE Treatment days after application (DAA) 1 2 3 7 Propionine Fluoramide 21.66 44.33 63.33 65 Jia Phosin C 0 0 0 69 Arsylfluramide + Carboplatin C 22.66 48.66 86 90.33 Example 12: Application rate: flufenacil: 180 g/ha fluoxetine phosphate plug C: 1080 g/ha jiapin 141151.doc • 7]· 201004567 Fluorine-grass + Carbophosphorus C: 180 g/ha fluoxetine +1080 g/ha Example of Phosphorus Plug 12.1: Control (no simulated rainfall after treatment) - Echco ) Herbicidal treatment days after application (DAA) 2 3 7 fluoxetine 61.66 76.66 75.33 jiaphosin C 0 10 66.33 flufenacil + jiaphosphonate C 56.55 40 63.33 Example 12_2 : after treatment 1 5 Min simulated rainfall - herbicidal effect on ECHCO treatment days after application (DAA) 2 3 7 fluoxetine 46.66 57.66 46.3 3 Jia Phossein C 0 0 21 fluoxetine + Jia Phosin C 68.33 76 76.66 Example 12.3: Simulated rainfall 30 min after treatment - Herbicidal treatment of ECHCO Treatment days after application (DAA) 2 3 7草灵53 60 46 嘉磷塞C 0 5.66 64.33 fluoxetine + jiaphosin C 70 72.66 87.66 141151.doc -72- 201004567 Example 12.4: simulated rainfall 2 hours after treatment - herbicidal treatment of ECHCO The number of days after 〇3AA) 2 3 7 fluoxetine 48.33 63.33 39.33 jia Phoser C 0 4.33 72 fluoxetine + jiaphosin C 68 82.33 89.33 Example 13 : ginseng application rate: fluoxetine: 180g/ha fluvofurin Lingjia phosphorus plug C: 1080 g/ha jia Phosphon fluoxetine + Jia Phosphorus C: 180 g/ha fluoxetine +1080 g/ha jia Phosphate example 13.1 : Control (no simulated rainfall after treatment) - days of application of the herbicide treatment of the white wp/zorMa (EUPHO) (DAA) 1 2 3 7 fluoxetine 9.66 19 37 47 jia Phoser C 1.33 6.66 49 85.33 fluoxetine + jiaphosin C 50 45 68 93.33 141151.doc -73- 201004567 Example 13.2: Simulated rainfall 15 min after treatment - for EUPH O weeding treatment Days after application (DAA) 1 2 3 7 fluoxetine 20.66 39 40 74.33 jia Phosphorus C 2.66 5.66 29.66 72.33 fluoxetine + jiaphosate C 47.66 36 60.33 89.33 Example 13.3: Simulated rainfall 2 hours after treatment - Herbicidal treatment of EUPHO Days after application (DAA) 1 2 3 7 Fluoryloxacillin 18 42 39 73.33 Jia Phossein C 3.33 5.66 38 88.66 Fluorinated herb + Jia Phossein C 45 44.66 76 99 Example 14: Application rate: fluoxetine: 1 80 g/ha flurazepam chia phosphate C: 1080 g/ha jia phosphorate fluoxacilin + jiaphosate C: 180 g/ha flurazepam +1080 g/ha Jia 141151.doc • 74· 201004567 Example 14.1: Control (no simulated rainfall after treatment) - Herbicidal treatment of Brassica chinensis (BRADE) After application Days (DAA) 1 2 3 7 fluoxetine 5 9 8.66 14 jiaphos plug c 0 0 0 59.66 fluoxetine + jiaphosin C 16 37.66 60 82.66 # Example 14.2: simulated rainfall 30 min after treatment - Herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 Fluorylcholine 5 18.33 24.66 26 Jia Phosin C 0 0 0 45.66 Ling P + Ka plug C 10.66 15 18.33 72.33 Example 14.3:

Simulated rainfall 6 hours after treatment - Herbicidal treatment of BRADE Days after application (DAA) 1 2 3 7 Fluorinated Herbs 9.66 16 22.66 25.33 Jia Phossein C 0 0 0 69 Fluorinated Herb + Jia Phosphorus C 10.66 18.33 30.66 80.33 Example 15: Application rate: Diuron: 1500 g/ha diuron 141151.doc • 75- 201004567 Jia Phoser C: 1080 g/ha Jia Phosphorus Diuron + Jia Phossein C: 1500 g/ha diuron + 1080 g/ha jia Phosphate Example 15.1 : Control (no simulated rainfall after treatment) - Herbicidal treatment of Mang (ECHCO) Days after application (DAA) 1 2 3 7 Diquat隆0 0 2.66 61 Jia Shi C 0 0 10 66.33 Diuron + Jia Phosin C 0 0 13.66 74.66 Example 15.2: Simulated rainfall 30 min after treatment - Herbicidal treatment of ECHCO Treatment days ΦΑΑ) 1 2 3 7 Diuron 0 0 6 75.33 Jia Phosin C 0 0 5.66 64.33 Diuron + Jia Phosin C 0 0 4.33 87.33 Example 15.3: Simulated rainfall 2 hours after treatment - Herbicidal treatment of ECHCO Treatment days after application) ΑΑ) 1 2 3 7 Diuron 0 0 1.66 58.33 Jia Phosin C 0 0 4.33 72 Diuron + Jia Phosin C 0 0 10 80 .33 Example 16: Application rate: Diuron: 1500 g/ha diquat 141151.doc -76- 201004567 Jia Phoser C: 1080 g/ha Jia Phosphorus Diuron + Jia Phosin C: 1500 g/ Ha diuron + 1080 g / ha Jia Phosse plug example 16.1 : Control (no simulated rainfall after treatment) - Herbicidal treatment of /pomoea (IPOGR) Days after application (DAA) 1 2 3 7 Diuron 0 0 1.33 7.33 Jia Phosin C 0 0 5 17.33 Diuron + Jia Phosin C 0 0 3.33 93.33

Example 16.2: Simulated rainfall 15 min after treatment - Herbicidal treatment against IPOGR Treatment days after application (DAA) 1 2 3 7 Diuron 0 1 3.33 21 Jia Phosin C 0 0 4.66 9.33 Diuron + Jia Phossein C 0 0 3.66 28.66 Example 16.3: Simulated rainfall 30 min after treatment - Herbicidal treatment against IPOGR Treatment days after application (DAA) 1 2 3 7 Diuron 0 0 3 16.66 Jia Phosin C 0 0 4.33 16.66 Diuron + Jia Phosin C 0 0 5 30 141151.doc -77- 201004567 Example 16.4: Simulated rainfall 2 hours after treatment - Herbicidal treatment against IPOGR Treatment days after application (DAA) 1 2 3 7 Diuron 0 0 0.33 11.66 Jia Phosphate plug c 0 0 4 13.33 Diuron + Jia Phossein C 0 0 5.66 40.66 Example 16.5: Simulated rainfall 6 hours after treatment - Herbicidal treatment against IPOGR Treatment days after application (DAA) 1 2 3 7 Diuron 0 1 2 25.55 Jia Phosin C 0 0 2.33 12.66 Diuron + Jia Phossein C 0 0 3.33 58.66 Example 17 : Application rate: Diuron: 1500 g/ha diquat galangite C: 1080 g/ha Jia Pho Sai Dun Cao Long + Jia Phossein C : 1500 g / ha diuron + 1080 g / ha Jia Phosin 141151.doc -78· 201004567 Example 17.1 : Control No simulated rainfall after treatment) - Herbicidal treatment of Brassica chinensis (BRADE) Treatment days after application (DAA) 1 2 3 7 14 Diuron 0 0 0 11 78.33 Jia Phosin C 0 0 0 59.66 100 Enemy Caolong + Jia Phosin C 0 0 0 65 100 Example 17.2: Simulated rainfall 2 hours after treatment - Herbicidal treatment of BRADE Treatment days after application (DAA) 1 2 3 7 14 Diuron 0 0 0 56 100 Jia Packing C 0 0 0 67.66 100 Diuron + Jia Phosin C 0 0 0 71.33 100 Example 17.3: Simulated rainfall 6 hours after treatment - Herbicidal treatment of BRADE Treatment days after application (DAA) 1 2 3 7 14 Diquat隆0 0 0 30 100 嘉磷塞 C 0 0 0 69 100 敌草隆+嘉磷塞 C 0 0 0 77.33 100 These results clearly indicate that the application of herbicidal component B containing jiaphos plug and at least one enhanced rainfastness The composition can effectively enhance the rain resistance of the Jiaphos plug. 141151.doc -79-

Claims (1)

201004567 VII. Scope of Application: 1. A method for enhancing the rainfastness of galaxie by applying a composition to undesirable plants, crops, crop seeds or other crop reproductive organs, the composition comprising: a) Glyphosate or at least one agriculturally acceptable salt, derivative or mixture thereof, and 'b) at least one herbicidal component b which enhances rainfastness, or at least one agriculturally acceptable salt or derivative thereof Or a mixture. The method of claim 1, wherein the herbicidal component B which enhances rain resistance is selected from the group consisting of porphyrinogen-IX oxidase inhibitors. 3. The method of claim 1 or 2, wherein the herbicidal component b which enhances rainfastness is at least one phenyluracil herbicide of the formula I or at least one agriculturally acceptable salt thereof CI • R 〇CH3 wherein R1 is selected from the group consisting of: propargyloxy, allyloxy, isopropoxy, c(=o)nhso2nr3r4, c(=o)n-nr3r4, C (=0)0-CR3R5-C(=0)-0R7 . C(=0)0-R4 ' C(=0)0-CHR5-C(=0)NHS02NR3R4 ' NHS02NR3R4 ' S02NHC(=0)NR3R4 , CH2, CH(C1)C02-R6 and OC(CH3)2_c(=〇)_〇R7 groups; R2 is hydrogen, fluorine or gas; 141151.doc 201004567 R wind or C1-C4-alkyl; R4 A C1-C4 hospital base; R5 is a hydrogen or CVCV alkyl group; R6 is a hydrogen or q-C4-alkyl or an agriculturally acceptable cation and R is a C1-C4-alkyl, propargyl or propyl group. 4. The method of claim (1), wherein the herbicidal component B, which enhances the rainfastness, is saflufenacil. 5. The method of claim (1), wherein the composition is applied to: wheat, barley, rye, triticale, durum wheat, corn, sugar cane, alfalfa, soybean, bean crop, peanut, hollyhock, : beet, potato, cotton, Brassica, turf, grape, pome fruit, stone fruit, citrus, coffee, pistachio, garden ornamental, = stem ornamental, virgin, garlic, conifer and deciduous, dry Vegetable ugly, banana, pineapple, coconut, mango, clock pear, boulder, tree, hedgehog, rubber tree, palm tree, cocoa, persimmon, pasture, nut tree, cashew tree and pupunha palm. 6. The method of claim (1), wherein the crop plant is resistant to one or more herbicides by genetic engineering or breeding, genetically engineered or breeding: resistant to one or more pathogens such as phytopathogenic fungi, Or resistant to insect attack due to genetic engineering or breeding. 7. The method of claim (1), wherein the composition is applied to a site where the crop is to be planted before or before germination to perform a control treatment on the undesired plants in the crop. 8. A herbicidal composition comprising gamma phosphate or 14115 J. doc 201004567 at a ratio of 1:5 〇 to 5 〇:1, at least one agriculturally acceptable salt, derivative or mixture thereof and pyrimidin or It is at least one agriculturally acceptable salt or mixture. 141151.doc 201004567 IV. Designation of representative drawings: (1) The representative representative of the case is: (none) (2) The symbol of the symbol of the representative figure is simple: 5. If there is a chemical formula in this case, please reveal the best indication of the characteristics of the invention. Chemical formula: (none) 141151.doc