CN107873728A - The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pyraclonil - Google Patents
The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pyraclonil Download PDFInfo
- Publication number
- CN107873728A CN107873728A CN201711272635.7A CN201711272635A CN107873728A CN 107873728 A CN107873728 A CN 107873728A CN 201711272635 A CN201711272635 A CN 201711272635A CN 107873728 A CN107873728 A CN 107873728A
- Authority
- CN
- China
- Prior art keywords
- glufosinate
- ammonium
- pyraclonil
- herbicidal combinations
- herbicidal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses the Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pyraclonil, for the Herbicidal combinations using glufosinate-ammonium and pyraclonil as principle active component, the mass ratio of glufosinate-ammonium and pyraclonil is 1：60~60：1.Herbicidal combinations of the present invention can be used for bare place, orchard and agent for removing grass in paddy field, and being particularly used to prevent and kill off grass family and broad leaved weed in bare place, orchard and rice terrace has remarkable result.Herbicidal combinations of the present invention on the premise of drug effect is improved, delay Weed Resistance relative to single dose, and herbicidal spectrum is wide, lasting period length, and all have security to rice, fruit tree and succession crop.
Description
Technical field
The invention belongs to technical field of pesticide, especially herbicide field, and in particular to a kind of Glufosinate-ammoniumpesticideng and polybenzobisoxazole grass
The binary built Herbicidal combinations of nitrile, the Herbicidal combinations can be applied to bare place, orchard and agent for removing grass in paddy field.
Background technology
Glufosinate-ammonium (Glufosinate-ammonium).Chemical name：4- [hydroxyl (methyl) phosphono] high third ammonia of-DL-
Acid, structural formula are：
Glufosinate-ammonium also known as careless fourth phosphine, it is a kind of organophosphorus herbicide of non-selective foliage-spray, 1979 by federal moral
State's Hoechst (Hoechst) chemical company synthesizes exploitation first.The herbicide effect mechanism of glufosinate-ammonium is tool after being absorbed by blade
Have part systemic action, can from blade base to end-transfer, shifted to other positions of plant it is less, to not unearthed young shoot and
Seed is harmless.Ammonium metabolism sinks into disorder in a short time after administration in plant, and strong cytotoxic agent ammonium ion is in plant
Interior accumulation；Make dunsiekte and dead.Photosynthesis is also heavily suppressed simultaneously, is in yellow-white after aggrieved plant chlorosis, and 2~5
Start withered and yellow die after it.Lost activity after contact soil, only preferably make the spraying of after seedling cauline leaf.
Glufosinate-ammonium is mainly used in orchard, vineyard, potato fields, nursery, forest, pasture, ornamental shrub and no-tillage gone out
Nature herbiciding, annual and perennial grassy weed is prevented and kill off, such as amur foxtail, wild oat, lady's-grass, barnyard grass, green bristlegrass, precocity
Standing grain, quackgrass, Bermuda grass, bent grass, reed, fescue grass etc..Also lamb's-quarters, amaranth, knotweed, shepherd's purse, black nightshade, chickweed, purslane, pig can be prevented and kill off
The broad leaved weeds such as calamity, sonchus oleraceus, creeping thistle, field bindweed, dandelion are brought disaster to, also have certain effect to nutgrass flatsedge and pteridophyte.
Pyraclonil (pyraclonil), chemical name：1- (the chloro- 4,5,6,7- tetrahydro-pyrazoles of 3- simultaneously [1,5-a] pyridine-
2- yls) -5- [methyl (Propargyl) amino] pyrazoles -4- nitriles.Pyraclonil belongs to new double pyrazole class herbicide for paddy field,
The mechanism of action is the inhibitor of proporphyrinogen oxidase, is a kind of contact killing type herbicide, can effectively prevent and kill off all kinds of weeds, including barnyard grass
Grass, difformed galingale herb, pasture and water, arrowhead, Monochoria korsakowii, dichotomous fimbristylis herb, wild water chestnut, Monochoria vaginalis etc. and resistant to sulfonylurea herbicide
Weeds.
Bare place, orchard and herbicide for paddy field are limited by crop safety at present, and herbicide controlling spectrum is also limited, are used alone one
Kind herbicide single dose can not completely effectively control the generation of weeds of wheat, furthermore some herbicides are due to water-soluble big or field
Between the lasting period is oversize, dosage is excessive or the uneven residual hazard all easily caused to this season crop or succession crop of dispenser.Hair
A person of good sense it has been investigated that, the synergistic complex of herbicide is the effective measures for expanding weed control spectrum and improving preventive effect, so far
It is not yet found that close the Herbicidal combinations of glufosinate-ammonium and pyraclonil compounding.
The content of the invention
It is an object of the invention to provide a kind of Glufosinate-ammoniumpesticideng and the Herbicidal combinations of pyraclonil.
It is a further object of the present invention to provide application of the Herbicidal combinations in bare place, orchard and agent for removing grass in paddy field.
The purpose of the present invention is achieved through the following technical solutions：
The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and pyraclonil, the Herbicidal combinations are based on glufosinate-ammonium and pyraclonil
Want active ingredient, the mass ratio of glufosinate-ammonium and pyraclonil is 1：60~60：1.It is preferred that the mass ratio of glufosinate-ammonium and pyraclonil
For 1：20~40：1, most preferably 1：30~40：1.In some preferable technical schemes：Glufosinate-ammonium and pyraclonil can be with
34：1、29：1、59：1、12：1、60：1、50：1、40：1、20：1、10：1、5：1、1：1、1：5、1：10、1：20、1：30、1：
50、1：Selected in 60 these ratios.
This compound weeding composition can comprise only active component glufosinate-ammonium and pyraclonil, also can in use or preparation to
Other components are added in active component, the effective ingredient in the Pesticidal combination can be present in composition with enhancing effective amount
In.
In Herbicidal combinations, glufosinate-ammonium is 1% with weight/mass percentage composition of both pyraclonils in Herbicidal combinations
~80%, preferred mass percentage composition is 10%~65%.
In the glufosinate-ammonium of the present invention and the binary built composition of pyraclonil, except glufosinate-ammonium and pyraclonil etc. are effective
Outside composition, the auxiliary agents such as the conventional surfactants allowed on pesticidal preparations, thickener, solvent or solid packing can also be added and matched somebody with somebody
Any one formulation allowed on agricultural chemicals is made.It is preferred that be processed into missible oil, suspending agent, aqueous emulsion, microemulsion, water dispersible granules,
Wettable powder etc..
Herbicidal combinations of the present invention can be applied in bare place, orchard and agent for removing grass in paddy field, particularly prevent and kill off
Using having remarkable result in grass family and broad leaved weed in bare place, orchard and rice terrace.
Present invention selection can herbicide controlling spectrum it is different, the complementary two kinds of herbicides of glufosinate-ammonium and pyraclonil of advantage and disadvantage are suitably reduced
After be made into mixture use, so both expand herbicide controlling spectrum, hence it is evident that improve herbicidal effect, it also avoid to this season crop produce medicine
Evil and the possibility that residual hazard is produced to succession crop.
The Herbicidal combinations of the present invention have advantages below：
1st, activity of weeding is high.The Herbicidal combinations of the present invention can kill weeds by two kinds of different mechanism so that weeds
Resistance produces speed and reduced, and is greatly enhanced the removing activity of herbicide.
2nd, herbicidal spectrum is wide, lasting period length.After both mixing, it is possible to increase a variety of grassy weeds and broad leaved weed are prevented
Control.
3rd, Weed Resistance is delayed.Herbicidal combinations of the present invention reduce resistance of the weeds to medicament, and carry by binary built
The preventive effect of high antagonism weeds, so as to extend the service life of medicament.
4th, it is safe.Because its dosage is under control, making medicament, it is to small on the premise of drug effect is improved
The security of wheat and succession crop is also improved.
The Herbicidal combinations of the present invention, applied to bare place, orchard and agent for removing grass in paddy field, it can prevent and kill off bare place, fruit
Various grass family and broad leaved weed in garden and rice terrace, on the premise of drug effect is improved, to bare place, orchard and rice terrace with
And succession crop all has security.
Therefore, Herbicidal combinations of the present invention can be being prepared for bare place, orchard and rice terrace postemergence weed control
Applied in herbicide, be particularly used for the weeding for preventing and kill off grass family and broad leaved weed in bare place, orchard and rice terrace preparing
Applied in agent.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that specific embodiment described herein is not used to limit only to explain the present invention
The fixed present invention, it is all that the protection model of the present invention is belonged to the simple modifications of preparation method of the present invention under the concept thereof of the present invention
Within enclosing.
Percentage is mass percent in all formulas of following examples.The processing work of the various preparations of the present composition
Skill is prior art, can be varied from according to different situations.
First, formulation prepares embodiment
Embodiment 1：35% glufosinate-ammonium pyraclonil missible oil (34：1)
Glufosinate-ammonium 34%, pyraclonil 1%, APES 4%, phenethyl phenol polyethenoxy ether 15%, two
Toluene complements to 100%, and the missible oil that weight/mass percentage composition is 35% is configured to according to the formulation method of routine.
Embodiment 2：30% glufosinate-ammonium pyraclonil suspending agent (29：1)
Glufosinate-ammonium 29%, pyraclonil 1%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%,
Aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus are water, are matched somebody with somebody according to the formulation method of routine
The suspending agent that weight/mass percentage composition is 30% is made.
Embodiment 3：60% glufosinate-ammonium pyraclonil water dispersible granules (59：1)
Glufosinate-ammonium 59%, pyraclonil 1%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, kaolin complements to 100%, and the water dispersible granules that weight/mass percentage composition is 60% are configured to according to the formulation method of routine
(WDG)。
Embodiment 4：65% glufosinate-ammonium pyraclonil wettable powder (12：1)
Glufosinate-ammonium 60%, pyraclonil 5%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4%, kaolinite
Soil complements to 100%, and the wettable powder (WP) that weight/mass percentage composition is 65% is configured to according to the formulation method of routine.
Embodiment 5：61% glufosinate-ammonium pyraclonil missible oil (60：1)
Glufosinate-ammonium 60%, pyraclonil 1%, APES 4%, phenethyl phenol polyethenoxy ether 15%, two
Toluene complements to 100%, and the missible oil that weight/mass percentage composition is 61% is configured to according to the formulation method of routine.
Embodiment 6：61% glufosinate-ammonium pyraclonil missible oil (1：60)
Glufosinate-ammonium 1%, pyraclonil 60%, APES 4%, phenethyl phenol polyethenoxy ether 15%, two
Toluene complements to 100%, and the missible oil that weight/mass percentage composition is 61% is configured to according to the formulation method of routine.
Embodiment 7：51% glufosinate-ammonium pyraclonil suspending agent (50：1)
Glufosinate-ammonium 50%, pyraclonil 1%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%,
Aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus are water, are matched somebody with somebody according to the formulation method of routine
The suspending agent that weight/mass percentage composition is 51% is made.
Embodiment 8：51% glufosinate-ammonium pyraclonil suspending agent (1：50)
Glufosinate-ammonium 1%, pyraclonil 50%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%,
Aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus are water, are matched somebody with somebody according to the formulation method of routine
The suspending agent that weight/mass percentage composition is 51% is made.
Embodiment 9：31% glufosinate-ammonium pyraclonil water dispersible granules (1：30)
Glufosinate-ammonium 1%, pyraclonil 30%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, kaolin complements to 100%, and the water dispersible granules that weight/mass percentage composition is 31% are configured to according to the formulation method of routine.
Embodiment 10：41% glufosinate-ammonium pyraclonil water dispersible granules (40：1)
Glufosinate-ammonium 40%, pyraclonil 1%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, kaolin complements to 100%, and the water dispersible granules that weight/mass percentage composition is 41% are configured to according to the formulation method of routine.
Embodiment 11：42% glufosinate-ammonium pyraclonil wettable powder (20：1)
Glufosinate-ammonium 40%, pyraclonil 2%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4%, kaolinite
Soil complements to 100%, and the wettable powder that weight/mass percentage composition is 42% is configured to according to the formulation method of routine.
Embodiment 12：21% glufosinate-ammonium pyraclonil wettable powder (1：20)
Glufosinate-ammonium 1%, pyraclonil 20%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4%, kaolinite
Soil complements to 100%, and the wettable powder that weight/mass percentage composition is 21% is configured to according to the formulation method of routine.
Embodiment 13：33% glufosinate-ammonium pyraclonil aqueous emulsion (1：10)
Glufosinate-ammonium 3%, pyraclonil 30%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%,
Aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, 200# solvent naphthas 20%, water complements to 100%, according to routine
Formulation method is configured to the aqueous emulsion that weight/mass percentage composition is 33%.
Embodiment 14：33% glufosinate-ammonium pyraclonil aqueous emulsion (10：1)
Glufosinate-ammonium 30%, pyraclonil 3%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%,
Aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, 200# solvent naphthas 20%, water complements to 100%, according to routine
Formulation method is configured to the aqueous emulsion that weight/mass percentage composition is 33%.
Embodiment 15：30% glufosinate-ammonium pyraclonil microemulsion (5：1)
Glufosinate-ammonium 25%, pyraclonil 5%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE 3%,
Aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, water complements to 100%, is configured to according to the formulation method of routine
Weight/mass percentage composition is 30% microemulsion.
Embodiment 16：60% glufosinate-ammonium pyraclonil wettable powder (1：5)
Glufosinate-ammonium 10%, pyraclonil 50%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4%, kaolinite
Soil complements to 100%, and the wettable powder that weight/mass percentage composition is 60% is configured to according to the formulation method of routine.
Embodiment 17：10% glufosinate-ammonium pyraclonil wettable powder (1：1)
Glufosinate-ammonium 5%, pyraclonil 5%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4%, kaolin
100% is complemented to, the wettable powder that weight/mass percentage composition is 10% is configured to according to the formulation method of routine.
2nd, drug effect checking test
1), toxicity determination test
According to active ingredient glufosinate-ammonium：Pyraclonil quality proportioning is：34：1、29：1、59：1、12：1、60：1、50：1、
40：1、20：1、10：1、5：1、1：1、1：5、1：10、1：20、1：30、1：50、1：60 are tested, and determine it to bare place, fruit
Garden and the co-toxicity coefficient of rice terrace common weed acalypha copperleaf.
Test method：The seed of quantitative acalypha copperleaf is seeded in 9cm Disposable paper cup respectively, 10 are sowed in every glass
~15 seeds, are cultivated in illumination box, when the acalypha copperleaf 1-3 leaf phases, are sprayed on crawler type crops sprayer
Processing.Continue to cultivate in greenhouse after processing, routine observation respectively handles the preventive effect to weeds, after weighing each processing after 30d
Weeds fresh weight, calculate its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient is more than 100, shows that two kinds of active principles have and increases
Effect acts on, and co-toxicity coefficient is more than 120, shows that two kinds of active principles have notable synergistic effect, co-toxicity coefficient is less than 100, shown
Two kinds of active principles have antagonism.Measurement result is as shown in table 1.
The toxicity measurement result of table 1
The herbicidal effect of acalypha copperleaf is significantly improved as it can be seen from table 1 glufosinate-ammonium compounds with pyraclonil, illustrates the two
Compounding has significant synergies to preventing and kill off acalypha copperleaf.Especially the proportioning of glufosinate-ammonium and pyraclonil is 1：30~40：1 it
Between, the co-toxicity coefficient after two kinds of active principle compoundings is optimal, illustrates that the present invention has obvious synergistic effect.
2), field control effectiveness test.
Reagent agent：
Glufosinate-ammonium prepared by embodiment 1~17 and the re-compounded binary herbicide of pyraclonil different ratio.
Comparison medicament：
30% glufosinate-ammonium AS (commercially available), 3.6% pyraclonil suspending agent (commercially available).
For studying thing：Rice.
Rice seedlings grow fine, robust plant, without other pest and disease damages.
Control object：
Barnyard grass, lady's-grass, Monochoria vaginalis, pasture and water, arrowhead, acalypha copperleaf, shepherd's purse.
Test method：
According to the area of experimental plot, good various medicaments of precise, and after being watered dilution, using knapsack sprayer,
Carry out even spraying, the special Fan spray head of sprinkler selection herbicide.During spraying, it should be noted that it is small that decoction is uniformly sprayed application to experiment
Qu Zhong, the phenomenon for accomplish no drain spray, spraying more.
20d, 40d observe weeds death condition, and the activity of weeding of more various medicaments after medicine respectively after experiment.This
Outside, the condition of production (dosage is the dosage of every mu of ground active ingredient) of crop is also observed in 1~15d after medicine, to investigate
Whether medicament has poisoning to crop.
Embodiments of the invention preparation Herbicidal Testing Trials effect see the table below 2 (20d after medicine) and table 3 (40d after medicine)
The field control effectiveness test result of table 2 (20d after medicine)
The field control effectiveness test result of table 3 (40d after medicine)
From table 2 and table 3 as can be seen that glufosinate-ammonium with expansion herbicidal spectrum and improves activity of weeding with pyraclonil compounding
Effect, and extend the lasting period of medicament.Broad leaved weed and grassy weed can be effectively prevented and kill off, its preventive effect is better than single dose
Preventive effect, illustrate that the two compounding has significantly to broad leaved weed in bare place, orchard and rice terrace and the preventive effect of grassy weed
Synergistic effect.
Security survey result of the medicament of table 4 to crop
The rice is doing well in each processing cell, has no any medicine spot, illustrates various medicaments to rice safety.
Claims (9)
1. the Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and pyraclonil, it is characterised in that the Herbicidal combinations are with glufosinate-ammonium and polybenzobisoxazole
Oxalic acid dinitrile is principle active component, wherein, the mass ratio of glufosinate-ammonium and pyraclonil is 1：60~60：1.
2. Herbicidal combinations according to claim 1, it is characterised in that glufosinate-ammonium and pyraclonil in the Herbicidal combinations
Mass ratio be 1：20~40：1.
3. Herbicidal combinations according to claim 2, it is characterised in that glufosinate-ammonium and pyraclonil in the Herbicidal combinations
Mass ratio be 1：30~40：1.
4. according to the Herbicidal combinations described in claim 1,2 or 3, it is characterised in that glufosinate-ammonium is with both pyraclonils in weeding
Weight/mass percentage composition in composition is 1%~80%.
5. Herbicidal combinations according to claim 4, it is characterised in that glufosinate-ammonium is with both pyraclonils in Herbicidal combination
Weight/mass percentage composition in thing is 10%~65%.
6. Herbicidal combinations according to claim 1, it is characterised in that the Herbicidal combinations are with glufosinate-ammonium and pyraclonil
Auxiliary agent to allow on principle active component and agricultural chemicals is configured to any one formulation.
7. Herbicidal combinations according to claim 6, it is characterised in that described formulation be missible oil, suspending agent, aqueous emulsion,
Microemulsion, water dispersible granules or wettable powder.
8. application of the Herbicidal combinations in preparing for bare place, orchard and agent for removing grass in paddy field described in claim 1.
9. application according to claim 1, it is characterised in that described Herbicidal combinations are preventing and kill off bare place, orchard and water
Application in rice field in grass family and broad leaved weed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711272635.7A CN107873728A (en) | 2017-12-06 | 2017-12-06 | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pyraclonil |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711272635.7A CN107873728A (en) | 2017-12-06 | 2017-12-06 | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pyraclonil |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107873728A true CN107873728A (en) | 2018-04-06 |
Family
ID=61772888
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711272635.7A Withdrawn CN107873728A (en) | 2017-12-06 | 2017-12-06 | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pyraclonil |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107873728A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021151753A1 (en) | 2020-01-31 | 2021-08-05 | Basf Se | Herbicide combinations comprising glufosinate and selected ppo inhibitors |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102027988A (en) * | 2009-09-28 | 2011-04-27 | 南京华洲药业有限公司 | Synergistic herbicide composition comprising triclopyr and glufosinate and application thereof |
| CN103283778A (en) * | 2013-06-08 | 2013-09-11 | 肇庆市真格生物科技有限公司 | Weeding composition comprising glufosinate and saflufenacil |
| CN106070312A (en) * | 2016-06-22 | 2016-11-09 | 南京华洲药业有限公司 | The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and monosulfmeturon and application thereof |
| CN106070313A (en) * | 2016-06-22 | 2016-11-09 | 南京华洲药业有限公司 | The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and triaziflam and application thereof |
| CN106689191A (en) * | 2015-07-14 | 2017-05-24 | 江苏扬农化工股份有限公司 | Compound weeding composition containing glufosinate-ammonium and application thereof |
-
2017
- 2017-12-06 CN CN201711272635.7A patent/CN107873728A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102027988A (en) * | 2009-09-28 | 2011-04-27 | 南京华洲药业有限公司 | Synergistic herbicide composition comprising triclopyr and glufosinate and application thereof |
| CN103283778A (en) * | 2013-06-08 | 2013-09-11 | 肇庆市真格生物科技有限公司 | Weeding composition comprising glufosinate and saflufenacil |
| CN106689191A (en) * | 2015-07-14 | 2017-05-24 | 江苏扬农化工股份有限公司 | Compound weeding composition containing glufosinate-ammonium and application thereof |
| CN106070312A (en) * | 2016-06-22 | 2016-11-09 | 南京华洲药业有限公司 | The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and monosulfmeturon and application thereof |
| CN106070313A (en) * | 2016-06-22 | 2016-11-09 | 南京华洲药业有限公司 | The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and triaziflam and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2021151753A1 (en) | 2020-01-31 | 2021-08-05 | Basf Se | Herbicide combinations comprising glufosinate and selected ppo inhibitors |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108029699A (en) | The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and bispyribac-sodium and its application | |
| CN108174865A (en) | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and mesotrione | |
| CN107873728A (en) | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pyraclonil | |
| CN106070313A (en) | The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and triaziflam and application thereof | |
| CN106070312A (en) | The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and monosulfmeturon and application thereof | |
| CN105941469B (en) | A kind of Herbicidal combinations and its application of Glufosinate-ammoniumpesticideng and ethoxyfen-ethyl | |
| CN107873727A (en) | The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and oxadiargyl and its application | |
| CN108174866A (en) | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and propyzamide | |
| CN108041070A (en) | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pethoxamid | |
| CN108077302A (en) | A kind of grand Herbicidal combinations and its application with propisochlor of sulphur of ketone containing thiophene | |
| CN107047592A (en) | A kind of Herbicidal combinations and its application containing pyraclonil and bensulfuron-methyl | |
| CN107156130A (en) | A kind of Herbicidal combinations and its application containing the bicyclic ketone of benzo and Diflufenican | |
| CN108077294A (en) | A kind of Herbicidal combinations and its application containing primisulfuronmethyl and isopropyl methoxalamine | |
| CN107156124A (en) | A kind of Herbicidal combinations and its application containing the bicyclic ketone of benzo and butachlor | |
| CN107136110A (en) | A kind of Herbicidal combinations and its application containing the bicyclic ketone of benzo and ethoxysulfuron | |
| CN106973929A (en) | The Herbicidal combinations of a kind of Sulfometuron Methyl containing promazine and benthiocarb and its application | |
| CN107996604A (en) | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and flucetosulfuron | |
| CN108094440A (en) | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and fentrazamide | |
| CN108174863A (en) | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and mefenacet | |
| CN108174864A (en) | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and cloransulammethyl | |
| CN107853314A (en) | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of prometryn and its application | |
| CN107810972A (en) | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of sulfentrazone and its application | |
| CN107950558A (en) | A kind of sulphur of ketone containing thiophene is grand with the Herbicidal combinations of bentazone and its application | |
| CN107372539A (en) | A kind of Herbicidal combinations and its application containing the bicyclic ketone of benzo and bentazone | |
| CN107853312A (en) | A kind of Herbicidal combinations and its application containing primisulfuronmethyl and isoxaben |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180406 |
|
| WW01 | Invention patent application withdrawn after publication |