CN108174864A - The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and cloransulammethyl - Google Patents
The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and cloransulammethyl Download PDFInfo
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- CN108174864A CN108174864A CN201711165942.5A CN201711165942A CN108174864A CN 108174864 A CN108174864 A CN 108174864A CN 201711165942 A CN201711165942 A CN 201711165942A CN 108174864 A CN108174864 A CN 108174864A
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- glufosinate
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
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Abstract
The invention discloses the Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and cloransulammethyl, for the Herbicidal combinations using glufosinate-ammonium and cloransulammethyl as principle active component, the mass ratio of glufosinate-ammonium and cloransulammethyl is 1：60~60：1.Herbicidal combinations of the present invention can be used for Soybean Field postemergence weed control, particularly have remarkable result for preventing and kill off grass family and broad leaved weed in Soybean Field.Herbicidal combinations of the present invention under the premise of drug effect is improved, delay Weed Resistance compared to single agent, and herbicidal spectrum is wide, and the lasting period is long, and all have safety to soybean and succession crop.
Description
Technical field
The invention belongs to technical field of pesticide, especially herbicide field, and in particular to a kind of Glufosinate-ammoniumpesticideng and chlorine ester sulphur
The binary built Herbicidal combinations of careless amine, the Herbicidal combinations can be applied to Soybean Field postemergence weed control.
Background technology
Glufosinate-ammonium (Glufosinate-ammonium).Chemical name：4- [hydroxyl (methyl) phosphono] high third ammonia of-DL-
Acid, structural formula are：
Glufosinate-ammonium also known as glufosinate are a kind of organophosphorus herbicides of non-selective foliage-spray, and 1979 by federal moral
State's Hoechst (Hoechst) chemical company synthesizes exploitation first.The herbicide effect mechanism of glufosinate-ammonium is tool after being absorbed by blade
Have part systemic action, can from blade base to end-transfer, shifted to other positions of plant it is less, to not unearthed young shoot and
Seed is harmless.Ammonium metabolism sinks into disorder in a short time after administration in plant, and strong cytotoxic agent ammonium ion is in plant
Interior accumulation；Make dunsiekte and dead.Photosynthesis is also heavily suppressed simultaneously, in yellow-white after aggrieved plant chlorosis, 2~5
Start withered and yellow die after it.It loses activity after contact soil, cauline leaf is sprayed after only preferably making seedling.
Glufosinate-ammonium is mainly used for orchard, vineyard, potato fields, nursery, forest, pasture, ornamental shrub and no-tillage goes out
Nature herbiciding prevents and kill off annual and perennial grassy weed, such as amur foxtail, wild oat, lady's-grass, barnyard grass, green bristlegrass, precocity
Standing grain, quackgrass, Bermuda grass, bent grass, reed, fescue grass etc..Also lamb's-quarters, amaranth, knotweed, shepherd's purse, black nightshade, chickweed, purslane, pig can be prevented and kill off
The broad leaved weeds such as calamity, sonchus oleraceus, creeping thistle, field bindweed, dandelion are brought disaster to, also have certain effect to nutgrass flatsedge and pteridophyte.
Cloransulammethyl (cloransulam-methyl), chemical name：The chloro- 2- of 3- [(5- ethyoxyls -7- it is fluoro- [1,2,
4] triazol [5,1-c] pyrimidine -2-base) sulfonamido] methyl benzoate, structural formula：
Cloransulammethyl is the newly developed sulfonamides herbicide of The Dow Agrosciences, LLC., is mainly used for Soybean Field stem
Foliar spray mist prevents and kill off broad leaved weed.Medicament in growing point, inhibits acetolactate synthestase (ALS) through grass cutting blade, root uptake and accumulation,
The synthesis of protein is influenced, weeds is made to stop growing and dead.Field control effectiveness test shows cloransulammethyl to early soybean Tian Kuo
Leaf weeds dayflower, smartweed, artemisiifolia have preferable preventive effect, have stronger inhibiting effect to bitter dish, sowthistle.
Soybean field herbicide is limited by crop safety at present, and herbicide controlling spectrum is also limited, and a kind of herbicide single dose is used alone
Cannot completely effectively control the generation of soybean weeds, furthermore some herbicides due to the water-soluble big or field lasting period too
It grows, dosage is excessive or the uneven residual hazard all be easy to causeing to this season crop or succession crop of dispenser.Inventor is through research
It was found that the synergistic complex of herbicide be expand weed control spectrum and improve preventive effect effective measures, so far it is not yet found that
Close the Herbicidal combinations of glufosinate-ammonium and cloransulammethyl compounding.
Invention content
The object of the present invention is to provide a kind of Glufosinate-ammoniumpesticidengs and the Herbicidal combinations of cloransulammethyl.
It is a further object of the present invention to provide application of the Herbicidal combinations in Soybean Field weeding.
The purpose of the present invention is achieved through the following technical solutions：
The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and cloransulammethyl, the Herbicidal combinations are with glufosinate-ammonium and cloransulammethyl
For principle active component, the mass ratio of glufosinate-ammonium and cloransulammethyl is 1：60~60：1.It is preferred that glufosinate-ammonium and cloransulammethyl
Mass ratio be 1：20~40：1, most preferably 1：30~40：1.In some preferred technical solutions：Glufosinate-ammonium and chlorine ester
Sulphur grass amine can be 34：1、29：1、59：1、12：1、60：1、50：1、40：1、20：1、10：1、5：1、1：1、1：5、1：10、1：
20、1：30、1：50、1：It is selected in 60 these ratios.
This compound weeding composition can contain only active constituent glufosinate-ammonium and cloransulammethyl, also can be when using or preparing
Other components are added in into active constituent, the effective ingredient in the Pesticidal combination can be present in composition with enhancing effective amount
In.
In Herbicidal combinations, the mass percentage of both glufosinate-ammonium and cloransulammethyl in Herbicidal combinations is
1%~80%, preferred mass percentage composition is 10%~65%.
In the glufosinate-ammonium of the present invention and the binary built composition of cloransulammethyl, in addition to glufosinate-ammonium and cloransulammethyl etc.
Outside active ingredient, the conventional surfactants allowed on pesticidal preparations, thickener, solvent or solid packing etc. can also be added and helped
Agent is configured to any one dosage form allowed on pesticide.It is preferred that it is processed into missible oil, suspending agent, aqueous emulsion, microemulsion, water-dispersible grain
Agent, wettable powder etc..
Herbicidal combinations of the present invention can be applied in Soybean Field postemergence weed control, the standing grain particularly in Soybean Field is prevented and kill off
Being applied in undergraduate course and broad leaved weed has remarkable result.
Present invention selection can herbicide controlling spectrum it is different, two kinds of herbicides of glufosinate-ammonium and cloransulammethyl of advantage and disadvantage complementation suitably subtract
Mixture use is made into after amount, both expands herbicide controlling spectrum in this way, hence it is evident that improves herbicidal effect, also avoids generating this season crop
Poisoning and the possibility that residual hazard is generated to succession crop.
The Herbicidal combinations of the present invention have the following advantages：
1st, activity of weeding is high.The Herbicidal combinations of the present invention can kill weeds by two kinds of different mechanism so that weeds
Resistance generates speed and reduces, and greatlys improve the removing activity of herbicide.
2nd, herbicidal spectrum is wide, and the lasting period is long.After the two mixing, it can improve and a variety of grassy weeds and broad leaved weed are prevented
It controls.
3rd, delay Weed Resistance.Herbicidal combinations of the present invention reduce resistance of the weeds to medicament, and carry by binary built
The preventive effect of high antagonism weeds, so as to extend the service life of medicament.
4th, it is safe.Since its dosage is under control, make medicament under the premise of drug effect is improved, to big
The safety of beans and succession crop is also improved.
The Herbicidal combinations of the present invention, applied to Soybean Field postemergence weed control, can prevent and kill off various grass family in Soybean Field
And broad leaved weed, under the premise of drug effect is improved, all there is safety to soybean and succession crop.
Therefore, Herbicidal combinations of the present invention can be applied in the herbicide for Soybean Field postemergence weed control is prepared,
Particularly applied in the herbicide of grass family and broad leaved weed in preparation for preventing and kill off in Soybean Field.
Specific embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that specific embodiment described herein is not used to limit only to explain the present invention
The fixed present invention, all protection models that under the concept thereof of the present invention simple modifications of preparation method of the present invention are belonged to the present invention
Within enclosing.
Percentage is mass percent in all formulas of following embodiment.The processing work of the various preparations of the present composition
Skill is the prior art, can be varied from according to different situations.
First, dosage form prepares embodiment
Embodiment 1：35% glufosinate-ammonium cloransulammethyl missible oil (34：1)
Glufosinate-ammonium 34%, cloransulammethyl 1%, alkyl phenol polyoxyethylene ether 4%, phenethyl phenol polyethenoxy ether 15%,
Dimethylbenzene complements to 100%, and the missible oil that mass percentage is 35% is configured to according to conventional formulation method.
Embodiment 2：30% glufosinate-ammonium cloransulammethyl suspending agent (29：1)
Glufosinate-ammonium 29%, cloransulammethyl 1%, methyl naphthalene sulfonate formaldehyde condensate 6%, nonylphenol polyoxyethylene ether
3%th, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus are water, according to conventional preparation side
Method is configured to the suspending agent that mass percentage is 30%.
Embodiment 3：60% glufosinate-ammonium cloransulammethyl water dispersible granules (59：1)
Glufosinate-ammonium 59%, cloransulammethyl 1%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, kaolin complements to 100%, and the water dispersible granules that mass percentage is 60% are configured to according to conventional formulation method
(WDG)。
Embodiment 4：65% glufosinate-ammonium cloransulammethyl wettable powder (12：1)
Glufosinate-ammonium 60%, cloransulammethyl 5%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% are high
Ridge soil complements to 100%, and the wettable powder (WP) that mass percentage is 65% is configured to according to conventional formulation method.
Embodiment 5：61% glufosinate-ammonium cloransulammethyl missible oil (60：1)
Glufosinate-ammonium 60%, cloransulammethyl 1%, alkyl phenol polyoxyethylene ether 4%, phenethyl phenol polyethenoxy ether 15%,
Dimethylbenzene complements to 100%, and the missible oil that mass percentage is 61% is configured to according to conventional formulation method.
Embodiment 6：61% glufosinate-ammonium cloransulammethyl missible oil (1：60)
Glufosinate-ammonium 1%, cloransulammethyl 60%, alkyl phenol polyoxyethylene ether 4%, phenethyl phenol polyethenoxy ether 15%,
Dimethylbenzene complements to 100%, and the missible oil that mass percentage is 61% is configured to according to conventional formulation method.
Embodiment 7：51% glufosinate-ammonium cloransulammethyl suspending agent (50：1)
Glufosinate-ammonium 50%, cloransulammethyl 1%, methyl naphthalene sulfonate formaldehyde condensate 6%, nonylphenol polyoxyethylene ether
3%th, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus are water, according to conventional preparation side
Method is configured to the suspending agent that mass percentage is 51%.
Embodiment 8：51% glufosinate-ammonium cloransulammethyl suspending agent (1：50)
Glufosinate-ammonium 1%, cloransulammethyl 50%, methyl naphthalene sulfonate formaldehyde condensate 6%, nonylphenol polyoxyethylene ether
3%th, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus are water, according to conventional preparation side
Method is configured to the suspending agent that mass percentage is 51%.
Embodiment 9：31% glufosinate-ammonium cloransulammethyl water dispersible granules (1：30)
Glufosinate-ammonium 1%, cloransulammethyl 30%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, kaolin complements to 100%, and the water dispersible granules that mass percentage is 31% are configured to according to conventional formulation method.
Embodiment 10：41% glufosinate-ammonium cloransulammethyl water dispersible granules (40：1)
Glufosinate-ammonium 40%, cloransulammethyl 1%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, kaolin complements to 100%, and the water dispersible granules that mass percentage is 41% are configured to according to conventional formulation method.
Embodiment 11：42% glufosinate-ammonium cloransulammethyl wettable powder (20：1)
Glufosinate-ammonium 40%, cloransulammethyl 2%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% are high
Ridge soil complements to 100%, and the wettable powder that mass percentage is 42% is configured to according to conventional formulation method.
Embodiment 12：21% glufosinate-ammonium cloransulammethyl wettable powder (1：20)
Glufosinate-ammonium 1%, cloransulammethyl 20%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% are high
Ridge soil complements to 100%, and the wettable powder that mass percentage is 21% is configured to according to conventional formulation method.
Embodiment 13：33% glufosinate-ammonium cloransulammethyl aqueous emulsion (1：10)
Glufosinate-ammonium 3%, cloransulammethyl 30%, methyl naphthalene sulfonate formaldehyde condensate 6%, nonylphenol polyoxyethylene ether
3%th, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, 200# solvent naphthas 20%, water complements to 100%, according to normal
The formulation method of rule is configured to the aqueous emulsion that mass percentage is 33%.
Embodiment 14：33% glufosinate-ammonium cloransulammethyl aqueous emulsion (10：1)
Glufosinate-ammonium 30%, cloransulammethyl 3%, methyl naphthalene sulfonate formaldehyde condensate 6%, nonylphenol polyoxyethylene ether
3%th, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, 200# solvent naphthas 20%, water complements to 100%, according to normal
The formulation method of rule is configured to the aqueous emulsion that mass percentage is 33%.
Embodiment 15：30% glufosinate-ammonium cloransulammethyl microemulsion (5：1)
Glufosinate-ammonium 25%, cloransulammethyl 5%, methyl naphthalene sulfonate formaldehyde condensate 6%, nonylphenol polyoxyethylene ether
3%th, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, water complements to 100%, matches according to conventional formulation method
The microemulsion that mass percentage is 30% is made.
Embodiment 16：60% glufosinate-ammonium cloransulammethyl wettable powder (1：5)
Glufosinate-ammonium 10%, cloransulammethyl 50%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% are high
Ridge soil complements to 100%, and the wettable powder that mass percentage is 60% is configured to according to conventional formulation method.
Embodiment 17：10% glufosinate-ammonium cloransulammethyl wettable powder (1：1)
Glufosinate-ammonium 5%, cloransulammethyl 5%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4%, kaolinite
Soil complements to 100%, and the wettable powder that mass percentage is 10% is configured to according to conventional formulation method.
2nd, drug effect verification test
1), toxicity determination test
According to active ingredient glufosinate-ammonium：Cloransulammethyl quality proportioning is：34：1、29：1、59：1、12：1、60：1、50：
1、40：1、20：1、10：1、5：1、1：1、1：5、1：10、1：20、1：30、1：50、1：60 are tested, and measure it to Soybean Field
The co-toxicity coefficient of common weed dayflower.
Test method：The seed of quantitative dayflower is seeded in the disposable paper cup of 9cm respectively, 10 are sowed in every glass
~15 seeds, are cultivated in illumination box, when 3~6 leaf phase of dayflower, are sprayed on crawler type crops sprayer
Processing.Continue to cultivate in greenhouse after processing, each preventive effect handled to weeds of routine observation, respectively treated for weighing after 30d
Weeds fresh weight calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient is more than 100, shows that two kinds of active principles have and increases
Effect acts on, and co-toxicity coefficient is more than 120, shows that two kinds of active principles have notable synergistic effect, co-toxicity coefficient is less than 100, shows
Two kinds of active principles have antagonism.Measurement result is as shown in table 1.
1 toxicity measurement result of table
As it can be seen from table 1 glufosinate-ammonium significantly improves the herbicidal effect of dayflower with cloransulammethyl compounding, illustrate two
Person's compounding has significant synergies to preventing and kill off dayflower.Especially the proportioning of glufosinate-ammonium and cloransulammethyl is 1：30~
40：Between 1, the co-toxicity coefficient after two kinds of active principle compoundings is optimal, illustrates that the present invention has apparent synergistic effect.
2), field control effectiveness test.
Reagent agent：
Glufosinate-ammonium prepared by embodiment 1~17 and the re-compounded binary herbicide of cloransulammethyl different ratio.
Comparison medicament：
30% glufosinate-ammonium AS (commercially available), 84% cloransulammethyl water dispersible granules (commercially available).
For studying object：Soybean
Big bean seedlings grow fine, robust plant, without other pest and disease damages.
Control object：
Dayflower, lady's-grass, barnyard grass, Bermuda grass, purslane, smartweed, artemisiifolia etc..
Test method：
According to the area of experimental plot, good various medicaments of precise, and after being watered dilution, using knapsack sprayer,
Carry out even spraying, the dedicated Fan spray head of sprinkler selection herbicide.During spraying, it should be noted that it is small that liquid is uniformly sprayed application to experiment
Qu Zhong accomplishes no drain spray, the phenomenon that spraying more.
20d, 40d observe weeds death condition, and the activity of weeding of more various medicaments after medicine respectively after experiment.This
Outside, the condition of production (dosage is the dosage of active ingredient per acre) of crop is also observed in 1~15d after medicine, to investigate
Whether medicament has poisoning to crop.
The embodiment of the present invention preparation Herbicidal Testing Trials effect see the table below 2 (20d after medicine) and table 3 (40d after medicine)
2 field control effectiveness test result of table (20d after medicine)
3 field control effectiveness test result of table (40d after medicine)
From table 2 and table 3 as can be seen that glufosinate-ammonium has expansion herbicidal spectrum with cloransulammethyl compounding and improves activity of weeding
Effect, and extend the lasting period of medicament.Broad leaved weed and grassy weed can be effectively prevented and kill off, preventive effect is better than single dose
Preventive effect, both illustrate that compounding has significant synergistic effect to the preventive effect of broad leaved weed in Soybean Field and grassy weed.
4 medicament of table is to the security survey result of crop
Soybean in each processing cell grows fine, and has no any medicine spot, illustrates that various medicaments are safe to soybean.
Claims (9)
1. the Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and cloransulammethyl, it is characterised in that the Herbicidal combinations are with glufosinate-ammonium and chlorine
Ester sulphur grass amine is principle active component, wherein, the mass ratio of glufosinate-ammonium and cloransulammethyl is 1：60~60：1.
2. Herbicidal combinations according to claim 1, it is characterised in that glufosinate-ammonium and chlorine ester sulphur grass in the Herbicidal combinations
The mass ratio of amine is 1：20~40：1.
3. Herbicidal combinations according to claim 2, it is characterised in that glufosinate-ammonium and chlorine ester sulphur grass in the Herbicidal combinations
The mass ratio of amine is 1：30~40：1.
4. according to the Herbicidal combinations described in claim 1,2 or 3, it is characterised in that both glufosinate-ammonium and cloransulammethyl except
Mass percentage in careless composition is 1%~80%.
5. Herbicidal combinations according to claim 4, it is characterised in that both glufosinate-ammonium and cloransulammethyl are in weeding group
It is 10%~65% to close the mass percentage in object.
6. Herbicidal combinations according to claim 1, it is characterised in that the Herbicidal combinations are with glufosinate-ammonium and chlorine ester sulphur grass
Amine is configured to any one dosage form for the auxiliary agent allowed on principle active component and pesticide.
7. Herbicidal combinations according to claim 6, it is characterised in that the dosage form for missible oil, suspending agent, aqueous emulsion,
Microemulsion, water dispersible granules or wettable powder.
8. application of the Herbicidal combinations described in claim 1 in Soybean Field postemergence weed control.
9. application according to claim 1, it is characterised in that Herbicidal combinations grass family in Soybean Field is prevented and kill off
With the application in broad leaved weed.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4552583A (en) * | 1977-12-28 | 1985-11-12 | Meiji Seika Kaisha Ltd. | Herbicidal compositions |
| DE4116626A1 (en) * | 1990-05-26 | 1991-11-28 | Hoechst Ag | New herbicidal compsn. esp. for use in fruit crops - contains one or more phosphinyl-butanoic acid cpds. and 3,5-di:chloro:benzamide deriv. |
| WO1992008353A1 (en) * | 1990-11-13 | 1992-05-29 | Hoechst Aktiengesellschaft | Synergistic herbicidal agent |
| CN1315832A (en) * | 1998-08-13 | 2001-10-03 | 阿温提斯作物科学有限公司 | Herbicidal composition for tolerant or resistant rice crops |
-
2017
- 2017-11-21 CN CN201711165942.5A patent/CN108174864A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4552583A (en) * | 1977-12-28 | 1985-11-12 | Meiji Seika Kaisha Ltd. | Herbicidal compositions |
| DE4116626A1 (en) * | 1990-05-26 | 1991-11-28 | Hoechst Ag | New herbicidal compsn. esp. for use in fruit crops - contains one or more phosphinyl-butanoic acid cpds. and 3,5-di:chloro:benzamide deriv. |
| WO1992008353A1 (en) * | 1990-11-13 | 1992-05-29 | Hoechst Aktiengesellschaft | Synergistic herbicidal agent |
| CN1315832A (en) * | 1998-08-13 | 2001-10-03 | 阿温提斯作物科学有限公司 | Herbicidal composition for tolerant or resistant rice crops |
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