CN106070313A - The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and triaziflam and application thereof - Google Patents
The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and triaziflam and application thereof Download PDFInfo
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- CN106070313A CN106070313A CN201610459630.4A CN201610459630A CN106070313A CN 106070313 A CN106070313 A CN 106070313A CN 201610459630 A CN201610459630 A CN 201610459630A CN 106070313 A CN106070313 A CN 106070313A
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- glufosinate
- ammonium
- herbicidal combinations
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
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- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
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Abstract
The invention discloses Herbicidal combinations and the application thereof of a kind of Glufosinate-ammoniumpesticideng and triaziflam, this Herbicidal combinations with glufosinate-ammonium with triaziflam as principle active component, glufosinate-ammonium is 1:60～60:1 with the mass ratio of triaziflam.Herbicidal combinations of the present invention can be used for corn field postemergence weed control, has remarkable result especially for preventing and kill off grass family and broad leaved weed in corn field.Herbicidal combinations of the present invention on the premise of improve drug effect, delays Weed Resistance relative to single dose, and herbicidal spectrum is wide, and the lasting period is long, and Semen Maydis and succession crop are all had safety.
Description
Technical field
The invention belongs to technical field of pesticide, especially herbicide field, be specifically related to a kind of Glufosinate-ammoniumpesticideng and triazine fluorine
The binary built Herbicidal combinations of grass amine, this Herbicidal combinations can be applicable to corn field postemergence weed control.
Background technology
Glufosinate-ammonium (Glufosinate-ammonium).Chemical name: 4-[hydroxyl (methyl) phosphono] high third ammonia of-DL-
Acid.
Glufosinate-ammonium has another name called grass fourth phosphine, is the organophosphorus herbicide of a kind of non-selective foliage-spray, and 1979 by federal moral
First state's Hoechst (Hoechst) chemical company synthesizes exploitation.The herbicide effect mechanism of glufosinate-ammonium be absorbed by blade after, tool
Have part systemic action, can be by blade base to end-transfer, to other positions of plant, transfer is less, to the plumelet not being unearthed and
Seed is harmless.In plant, disorder is the most i.e. sunk in ammonium metabolism, and strong cytotoxic agent ammonium ion is at plant
Interior accumulation；Make dunsiekte and dead.Photosynthesis is the most heavily suppressed simultaneously, in yellow-white after plant chlorosis of being injured, and 2～5
Withered and yellow dying is started after it.Lose activity after contact soil, only preferably make stem and leaf spraying after Seedling.
Glufosinate-ammonium is mainly used in orchard, vineyard, potato fields, nursery, forest, pasture, ornamental shrub and no-tillage goes out
Nature herbiciding, prevents and kill off annual and perennial grassy weed, such as amur foxtail, wild oat, Herba Digitariae, barnyard grass, Herba Setariae Viridis, precocity
Standing grain, quackgrass, Bermuda grass, bent grass, phragmites communis, fescue grass etc..Also Herba chenopodii, Herba Amaranthi tricoloris, knotweed, shepherd's purse, Herba Solani Nigri, Herba stellariae mediae, Herba Portulacae, pig can be prevented and kill off
The broad leaved weeds such as calamity calamity, Herba Sonchi Oleracei, creeping thistle, Herba seu Flos Convolvuli arvensis, Herba Taraxaci, also have certain effect to dried tuber and pteridophyta.
Triaziflam (prosulfuron), chemical name: 1-(4-methoxyl group-6-methyl isophthalic acid, 3,5-triazine-2-bases)-
3-(2, (3,3,3-trifluoro propyl) phenyl sulfonyl) urea.Triaziflam is the inhibitor of acetolactate synthestase (ALS).Logical
Crossing weeds root and leaf absorbs, conduct in plant, weeds i.e. stop growing, leaf color chlorisis, the most withered.It is mainly used in preventing and kill off wealthy
The weeds such as abutilon, Amaranthus, Chenopodium, Stellaria are had the preventive effect of excellence by leaf weeds.Suitable for crop such as Semen Maydis, Sorghum vulgare Pers., cereal
Class crop, lawn and pasture.Because its half-life in soil is 8-40d, the half-life in milpa is 1-2.5h, bright
Show and be shorter than other commercialization sulfonylurea herbicides metabolism time in corn plants.
Corn field herbicide is limited by crop safety at present, and weed control spectrum is the most limited, is used alone a kind of herbicide single dose
Can not control the generation of corn field weed completely effectively, furthermore some herbicide due to water solublity is big or the field lasting period too
Long, consumption is excessive or the uneven residual hazard all easily caused this season crop or succession crop of dispenser.Inventor is after deliberation
Finding, the synergistic complex of herbicide is to expand weed control spectrum and improve the effective measures of preventive effect, is the most not yet found to have
Close the Herbicidal combinations that glufosinate-ammonium is compounding with triaziflam.
Summary of the invention
It is an object of the invention to provide the Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and triaziflam.
It is a further object of the present invention to provide the application in cornfield weeding of this Herbicidal combinations.
The purpose of the present invention is achieved through the following technical solutions:
A kind of Glufosinate-ammoniumpesticideng and the Herbicidal combinations of triaziflam, this Herbicidal combinations is with glufosinate-ammonium and triaziflam
For principle active component, glufosinate-ammonium is 1:60～60:1 with the mass ratio of triaziflam.Preferably glufosinate-ammonium and triaziflam
Mass ratio be 1:20～40:1, most preferably 1:30～40:1.In some preferred technical schemes: glufosinate-ammonium and triazine
Benfluralin can 34:1,29:1,59:1,12:1,60:1,50:1,40:1,20:1,10:1,5:1,1:1,1:5,1:10,1:
20, these ratios of 1:30,1:50,1:60 select.
This compound weeding composition can comprise only active component glufosinate-ammonium and triaziflam, it is possible to when using or prepare
Adding other components in active component, the active ingredient in this Pesticidal combination can be present in compositions with enhancing effective amount
In.
In Herbicidal combinations, glufosinate-ammonium and both triaziflams weight/mass percentage composition in Herbicidal combinations is
1%～80%, preferred mass percentage composition is 10%～65%.
In the binary built compositions of the glufosinate-ammonium of the present invention and triaziflam, except glufosinate-ammonium and triaziflam etc.
Outside effective ingredient, it is also possible to add conventional surfactants, thickening agent, solvent or the solid packing etc. allowed on pesticidal preparations and help
Agent is configured on pesticide any one dosage form allowed.Preferably it is processed into cream, suspending agent, aqueous emulsion, microemulsion, water-dispersible grain
Agent, wettable powder etc..
Herbicidal combinations of the present invention can be applied in corn field postemergence weed control, particularly standing grain in preventing and kill off corn field
In undergraduate course and broad leaved weed, application has remarkable result.
The present invention select can weed control spectrum different, the complementary two kinds of herbicides of glufosinate-ammonium and triaziflam of pluses and minuses suitably subtract
It is made into mixture after amount to use, had the most both expanded weed control spectrum, hence it is evident that improve herbicidal effect, it also avoid and this season crop is produced
Poisoning and the probability to succession crop generation residual hazard.
The Herbicidal combinations of the present invention has the advantage that
1, activity of weeding is high.The Herbicidal combinations of the present invention can kill weeds by two kinds of different mechanism so that weeds
Resistance produces speed and reduces, and is greatly enhanced the removing activity of herbicide.
2, herbicidal spectrum is wide, and the lasting period is long.After both mixing, it is possible to increase multiple grassy weed and broad leaved weed are prevented
Control.
3, Weed Resistance is delayed.Herbicidal combinations of the present invention passes through binary built, reduces the weeds resistance to medicament, and carries
The preventive effect of high antagonism weeds, thus extend the service life of medicament.
4, safety is high.Owing to its using dosage is under control, making medicament on the premise of improve drug effect, it is to jade
The safety of rice and succession crop have also been obtained raising.
The Herbicidal combinations of the present invention, is applied to corn field postemergence weed control, and it can prevent and kill off various grass family in corn field
And broad leaved weed, on the premise of improve drug effect, Semen Maydis and succession crop are all had safety.
Therefore, Herbicidal combinations of the present invention can be applied in the herbicide of corn field postemergence weed control in preparation,
Particularly the herbicide of grass family and broad leaved weed is applied for preventing and kill off in corn field in preparation.
Detailed description of the invention
In order to make the purpose of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, to the present invention
It is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not used to limit
Determining the present invention, all simple modifications under the concept thereof of the present invention to preparation method of the present invention broadly fall into the protection model of the present invention
Within enclosing.
In all formula of following example, percentage ratio is mass percent.The processing work of the various preparation of the present composition
Skill is prior art, can be varied from according to different situations.
One, dosage form prepares embodiment
Embodiment 1:35% glufosinate-ammonium triaziflam cream (34:1)
Glufosinate-ammonium 34%, triaziflam 1%, alkylphenol polyoxyethylene 4%, phenethyl phenol polyethenoxy ether 15%,
Dimethylbenzene complements to 100%, is configured to, according to conventional formulation method, the cream that weight/mass percentage composition is 35%.
Embodiment 2:30% glufosinate-ammonium triaziflam suspending agent (29:1)
Glufosinate-ammonium 29%, triaziflam 1%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus is water, according to conventional preparation side
Method is configured to the suspending agent that weight/mass percentage composition is 30%.
Embodiment 3:60% glufosinate-ammonium triaziflam water dispersible granules (59:1)
Glufosinate-ammonium 59%, triaziflam 1%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, Kaolin complements to 100%, is configured to, according to conventional formulation method, the water dispersible granules that weight/mass percentage composition is 60%
(WDG)。
Embodiment 4:65% glufosinate-ammonium triaziflam wettable powder (12:1)
Glufosinate-ammonium 60%, triaziflam 5%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% is high
Ridge soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder (WP) that weight/mass percentage composition is 65%.
Embodiment 5:61% glufosinate-ammonium triaziflam cream (60:1)
Glufosinate-ammonium 60%, triaziflam 1%, alkylphenol polyoxyethylene 4%, phenethyl phenol polyethenoxy ether 15%,
Dimethylbenzene complements to 100%, is configured to, according to conventional formulation method, the cream that weight/mass percentage composition is 61%.
Embodiment 6:61% glufosinate-ammonium triaziflam cream (1:60)
Glufosinate-ammonium 1%, triaziflam 60%, alkylphenol polyoxyethylene 4%, phenethyl phenol polyethenoxy ether 15%,
Dimethylbenzene complements to 100%, is configured to, according to conventional formulation method, the cream that weight/mass percentage composition is 61%.
Embodiment 7:51% glufosinate-ammonium triaziflam suspending agent (50:1)
Glufosinate-ammonium 50%, triaziflam 1%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus is water, according to conventional preparation side
Method is configured to the suspending agent that weight/mass percentage composition is 51%.
Embodiment 8:51% glufosinate-ammonium triaziflam suspending agent (1:50)
Glufosinate-ammonium 1%, triaziflam 50%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, silicone oil 0.2%, surplus is water, according to conventional preparation side
Method is configured to the suspending agent that weight/mass percentage composition is 51%.
Embodiment 9:31% glufosinate-ammonium triaziflam water dispersible granules (1:30)
Glufosinate-ammonium 1%, triaziflam 30%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, Kaolin complements to 100%, is configured to, according to conventional formulation method, the water dispersible granules that weight/mass percentage composition is 31%.
Embodiment 10:41% glufosinate-ammonium triaziflam water dispersible granules (40:1)
Glufosinate-ammonium 40%, triaziflam 1%, NNO (sodium methylene bis-naphthalene sulfonate) 5%, ammonium sulfate 3%, polyvinyl alcohol
2%, Kaolin complements to 100%, is configured to, according to conventional formulation method, the water dispersible granules that weight/mass percentage composition is 41%.
Embodiment 11:42% glufosinate-ammonium triaziflam wettable powder (20:1)
Glufosinate-ammonium 40%, triaziflam 2%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% is high
Ridge soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder that weight/mass percentage composition is 42%.
Embodiment 12:21% glufosinate-ammonium triaziflam wettable powder (1:20)
Glufosinate-ammonium 1%, triaziflam 20%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% is high
Ridge soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder that weight/mass percentage composition is 21%.
Embodiment 13:33% glufosinate-ammonium triaziflam aqueous emulsion (1:10)
Glufosinate-ammonium 3%, triaziflam 30%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, solvent naphtha 20%, water complements to 100%, according to routine
Formulation method is configured to the aqueous emulsion that weight/mass percentage composition is 33%.
Embodiment 14:33% glufosinate-ammonium triaziflam aqueous emulsion (10:1)
Glufosinate-ammonium 30%, triaziflam 3%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, solvent naphtha 20%, water complements to 100%, according to routine
Formulation method is configured to the aqueous emulsion that weight/mass percentage composition is 33%.
Embodiment 15:30% glufosinate-ammonium triaziflam microemulsion (5:1)
Glufosinate-ammonium 25%, triaziflam 5%, methyl naphthalene sulfonate formaldehyde condensate 6%, NPE
3%, aluminium-magnesium silicate 0.5%, ethylene glycol 7%, tributyl phosphate 2%, water complements to 100%, joins according to conventional formulation method
Make the microemulsion that weight/mass percentage composition is 30%.
Embodiment 16:60% glufosinate-ammonium triaziflam wettable powder (1:5)
Glufosinate-ammonium 10%, triaziflam 50%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4% is high
Ridge soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder that weight/mass percentage composition is 60%.
Embodiment 17:10% glufosinate-ammonium triaziflam wettable powder (1:1)
Glufosinate-ammonium 5%, triaziflam 5%, NNO (sodium methylene bis-naphthalene sulfonate) 6%, sodium lignin sulfonate 4%, kaolinite
Soil complements to 100%, is configured to, according to conventional formulation method, the wettable powder that weight/mass percentage composition is 10%.
Two, drug effect checking test
1), toxicity determination test
According to effective ingredient glufosinate-ammonium: triaziflam quality proportioning is: 70:1,34:1,29:1,59:1,12:1,60:
1,50:1,40:1,20:1,10:1,5:1,1:1,1:5,1:10,1:20,1:30,1:50,1:60,1:70 test, and measure
Its co-toxicity coefficient to corn field common weed Herba Digitariae.
Test method: the seed of quantitative Herba Digitariae is seeded in the Disposable paper cup of 9cm respectively, in every glass sow 10～
15 seeds, cultivate in illumination box, when the 3～6 leaf phase of Herba Digitariae, carry out at spraying on crawler type crops sprayer
Reason.Continuing in greenhouse after process to cultivate, routine observation respectively processes the preventive effect to weeds, and weigh after each process after 30d is miscellaneous
Grass fresh weight, calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient is more than 100, shows that two kinds of active substance have potentiation
Effect, co-toxicity coefficient is more than 120, shows that two kinds of active substance have notable potentiation, and co-toxicity coefficient is less than 100, shows two
Plant active substance and there is antagonism.Measurement result is as shown in table 1.
Table 1 toxicity measurement result
As it can be seen from table 1 glufosinate-ammonium herbicidal effect to Herba Digitariae compounding with triaziflam significantly improves, the two is described
Compounding have significant synergies to preventing and kill off Herba Digitariae.Especially the proportioning of glufosinate-ammonium and triaziflam 1:30～40:1 it
Between, the co-toxicity coefficient after two kinds of active substance are compounding is both greater than 120, illustrates that the present invention has obvious potentiation.
2), field control effectiveness test.
Reagent agent:
The glufosinate-ammonium of embodiment 1～17 preparation and the re-compounded binary herbicide of triaziflam different ratio.
Comparison medicament:
30% glufosinate-ammonium AS (commercially available), 20% triaziflam EC (autogamy).
From fitting processing method: triaziflam 20%, add agricultural agent；Calcium dodecyl benzene sulfonate 5%, alkyl phenol gathers
Oxygen vinyl Ether 2%, blending and mixing, and in whipping process, it is continuously added 200# solvent naphtha, make mixture quality ratio reach
100%, and according to general step, form the creamy herbicide of 20% triaziflam.
For studying thing: Semen Maydis
Maize seedling grows fine, robust plant, without other pest and disease damages.
Prevent and kill off object:
Amur foxtail, Herba Digitariae, barnyard grass, Bermuda grass, Herba Acalyphae, Herba Commelinae etc..
Test method:
According to the area of experimental plot, the good various medicaments of precise, and after being watered dilution, utilize knapsack sprayer,
Carry out even spraying, the Fan spray head that sprinkler selection herbicide is special.During spraying, it should be noted that uniformly spray application to test little by medicinal liquid
Qu Zhong, accomplishes do not have drain spray, the phenomenon of many sprays.
After test, after medicine, 20d, 40d observe weeds death condition respectively, and compare the activity of weeding of various medicaments.This
Outward, after medicine, the condition of production consumption of every mu of ground effective ingredient (consumption be) of crop is also observed in 1～15d, to investigate
Whether medicament has poisoning to crop.
Embodiments of the invention preparation Herbicidal Testing Trials effect see table 2 (20d after medicine) and table 3 (40d after medicine)
Table 2 field control effectiveness test result (20d after medicine)
Table 3 field control effectiveness test result (40d after medicine)
From table 2 and table 3 it can be seen that glufosinate-ammonium is compounding with triaziflam has expansion herbicidal spectrum and raising activity of weeding
Effect, and extend the lasting period of medicament.Can effectively prevent and kill off broad leaved weed and grassy weed, its preventive effect is better than single dose
Preventive effect, illustrate that the two compounding preventive effect to broad leaved weed in corn field and grassy weed has significant potentiation.
Table 4 medicament security survey result to crop
Each Semen Maydis processed in community grows fine, and has no any medicine speckle, illustrates that various medicament is the safest to Semen Maydis.
Claims (9)
1. a Glufosinate-ammoniumpesticideng and the Herbicidal combinations of triaziflam, it is characterised in that this Herbicidal combinations is with glufosinate-ammonium and three
Piperazine benfluralin is principle active component, and wherein, glufosinate-ammonium is 1:60～60:1 with the mass ratio of triaziflam.
Herbicidal combinations the most according to claim 1, it is characterised in that glufosinate-ammonium and triazine fluorine grass in this Herbicidal combinations
The mass ratio of amine is 1:20～40:1.
Herbicidal combinations the most according to claim 1, it is characterised in that glufosinate-ammonium and triazine fluorine grass in this Herbicidal combinations
The mass ratio of amine is 1:30～40:1.
4. according to the Herbicidal combinations described in claim 1,2 or 3, it is characterised in that glufosinate-ammonium is being removed with both triaziflams
Weight/mass percentage composition in grass compositions is 1%～80%.
Herbicidal combinations the most according to claim 4, it is characterised in that glufosinate-ammonium and both triaziflams are in weeding group
Weight/mass percentage composition in compound is 10%～65%.
Herbicidal combinations the most according to claim 1, it is characterised in that this Herbicidal combinations is with glufosinate-ammonium and triazine fluorine grass
Amine is that the auxiliary agent allowed on principle active component and pesticide is configured to any one dosage form.
Herbicidal combinations the most according to claim 6, it is characterised in that described dosage form be cream, suspending agent, aqueous emulsion,
Microemulsion, water dispersible granules or wettable powder.
8. the application in corn field postemergence weed control of the Herbicidal combinations described in claim 1.
Application the most according to claim 1, it is characterised in that described Herbicidal combinations grass family in preventing and kill off corn field
With the application in broad leaved weed.
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| CN201610459630.4A CN106070313A (en) | 2016-06-22 | 2016-06-22 | The Herbicidal combinations of a kind of Glufosinate-ammoniumpesticideng and triaziflam and application thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107873728A (en) * | 2017-12-06 | 2018-04-06 | 南京红太阳股份有限公司 | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pyraclonil |
| EP3440937A1 (en) * | 2017-08-09 | 2019-02-13 | Basf Se | Herbicidal mixtures comprising l-glufosinate or its salt and a second herbicide |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0620220A2 (en) * | 1989-02-20 | 1994-10-19 | Idemitsu Kosan Company Limited | A triazine derivatives as herbicides |
| CN1312682A (en) * | 1998-08-13 | 2001-09-12 | 阿温提斯作物科学有限公司 | Herbicides for tolerant or resistant corn cultures |
| CN1599555A (en) * | 2001-12-07 | 2005-03-23 | 拜尔作物科学有限公司 | Synergistic herbicidal agents |
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2016
- 2016-06-22 CN CN201610459630.4A patent/CN106070313A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0620220A2 (en) * | 1989-02-20 | 1994-10-19 | Idemitsu Kosan Company Limited | A triazine derivatives as herbicides |
| CN1312682A (en) * | 1998-08-13 | 2001-09-12 | 阿温提斯作物科学有限公司 | Herbicides for tolerant or resistant corn cultures |
| CN1599555A (en) * | 2001-12-07 | 2005-03-23 | 拜尔作物科学有限公司 | Synergistic herbicidal agents |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP3440937A1 (en) * | 2017-08-09 | 2019-02-13 | Basf Se | Herbicidal mixtures comprising l-glufosinate or its salt and a second herbicide |
| WO2019030099A1 (en) * | 2017-08-09 | 2019-02-14 | Basf Se | Herbicidal mixtures comprising l-glufosinate or its salt and a second herbicide |
| US11122807B2 (en) | 2017-08-09 | 2021-09-21 | Basf Se | Herbicidal mixtures comprising L-glufosinate or its salt and a second herbicide |
| CN107873728A (en) * | 2017-12-06 | 2018-04-06 | 南京红太阳股份有限公司 | The Herbicidal combinations and its application of a kind of Glufosinate-ammoniumpesticideng and pyraclonil |
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