TW201003942A - Laminate for solar cell back sheet and back sheet having said laminate - Google Patents

Abstract

This invention provides a laminate for solar cell back sheet by laminating a vinylidene chloride resin layer and a silicon-modified acrylic resin layer, which is excellent in weather resistance and humidity resistance where an extraordinary vapor barrier feature can be found and upheld even under a harsh natural ambience in a long time.

Description

[Technical Field] The present invention relates to a laminate for a solar cell back sheet which can withstand a long period of time in a severe natural environment, and has a laminate for the solar cell back sheet. The solar battery back plate and the solar battery module having the solar battery back plate. [Prior Art] In recent years, concerns about global warming have been increasing in various fields at home and abroad, and various efforts are continuing to suppress carbon dioxide emissions. Increasing consumption of fossil fuels will increase the amount of carbon dioxide in the atmosphere and increase the temperature of the earth due to its greenhouse effect, thus having a major impact on the global environment. As an alternative energy source for fossil fuels, various studies have been carried out. The expectation for solar power generation of 哀 保 能源 energy is rising. The solar cell constitutes the heart of the solar power generation system that directly converts the energy of sunlight into electrical energy, and is made by a semiconductor. The structure does not directly use the solar cell element alone in its original state, and generally several to several tens of solar cell elements are wired in series and in parallel, and are protected for a long time (about 20 years). Various packages are unitized. The component enclosed in the package is called a solar cell module, and the surface of the solar cell module that is exposed to sunlight is generally covered by glass. Further, a gap is formed by a filler composed of a thermoplastic plastic (generally ethylene-vinyl acetate copolymer resin) to form a structure in which the inner surface is protected by a sheet of heat-resistant or weather-resistant plastic material. In order to use it outside the house, the solar cell module is required to have sufficient resistance to its composition and material, 3321209 201003942.曰^ (7) face protection board) has weather resistance and water vapor transmission rate ==== and peeling or discoloration, resulting in line rot, scorpion sputum, and the output power itself is affected. In the past, most of the solar cell backsheets have been made of a highly weatherable resin film such as poly, (gas film), which has a gas barrier property (generally 1) or an inorganic oxide vaporized film. (- Generally speaking, acid? Divine vinegar (ΡΕΤ) film) is made of a central layer or a layered structure: plus: back plate. However, this film has a weak mechanical strength and 'has a solar cell component when manufacturing a solar cell module=the total weight of the material will penetrate and contact the inner protective plate, etc., too% battery components and (4) When a short circuit occurs and the battery performance is adversely affected, the complexity of the components composed of several layers is difficult to be known from the productive Yang, and the solar cell is hindered from being popularized. "For the sake of!", "Knowledge: Disadvantages and Obstacles", we are studying, for example, polyacrylic acid: ruthenium film, vinyl film, polyester film, polycarbonate, bismuth, polyethylene film, etc. The solar cell back sheet is described in Patent Document 1 which will be described later, and a solar cell i-shaped moon plate in which a vapor (four) film composed of a polycarbonate film and an organic oxide is laminated. The towel has a pair of (four) vapor-deposited layers which are laminated on the both sides of the film of the poly-ply-ethylene film by a back layer, and the field is made of an amine ester-based adhesive. In the case of the above-mentioned patent document 3, there is described a thermoplastic resin sheet for a solar cell, which has a thermoplastic resin layer such as polyethylene terephthalate containing titanium dioxide. Document 4 discloses a solar cell sheet member which is formed of a plurality of layers of a resin film layer and which is disposed on a side farther from the solar cell module and which comprises a polyethylene terephthalate film. Patent Document 5 described later discloses a thin film solar cell module in which a butyl rubber is coated on an inner peripheral end surface of a protective surface of a thin film solar cell module, and an aluminum foil is used as a moisture proof layer, and The base material layer and the moisture-proof layer composed of the PET film are followed by an amine ester resin-based adhesive. Patent Document 6 described later describes an inner surface protective sheet for a solar cell, which is provided with at least one layer. A laminated sheet of a sheet made of a polyethylene resin is disposed on at least one side of the polypropylene resin sheet. The patent document 7 described later describes an inner surface protection sheet for a solar cell module. And a solar cell module using the inner surface protective sheet, which is composed of a three-layer laminated resin film obtained by laminating a heat-resistant polypropylene resin film containing a UV absorber and a light stabilizer. [Patent Document 1] Japanese Laid-Open Patent Publication No. 2005-322687 [Patent Document 3] Japanese Laid-Open Patent Publication No. 2006-270025 [Patent Document] [Patent Document 5] Japanese Patent Laid-Open Publication No. 2004-31 0680 (Patent Document 6) Japanese Laid-Open Patent Publication No. 2004-223925 No. 5 321209 201003942 [Patent Document 7] JP-A-2003- [Patent Document 8] International Publication No. 2008/043848 [Draft of the Invention] (Problems to be Solved by the Invention) However, the solar cell back sheet layer system of the patent reading 丨 丨 无法 无法 无法 无法 无法 无法 无法 , , It has various functions such as heat, weather resistance and care. It is difficult to say that it is ideal for the long-term (fourth) silky self-sufficiency of the _ _ _ _ _ _ _ _ _ _ _ _ _ _ The gas barrier layered body, the ship's full gas barrier performance, the gas barrier layer must be at least 0 士1 and in the content of the 7^, it is difficult to provide as a solar cell. Be the ideal. In order to solve the problem, the problem to be solved by the present invention is to provide an excellent water vapor resistance even in a long-term environment, and a sun having excellent weatherability and moisture resistance. A laminated body for the battery backboard. Product Tai = Question: To provide a battery module with the aforementioned solar battery back plate. 1 plate, and the sun with the solar cell back plate (the means to solve the problem) After the research is carried out by the above-mentioned problem, the poly-acrylic acid tree of the solar cell can be made. An effective means to solve the aforementioned problems. 321209 6 201003942 ::On: Bencher's provides the following solar cell back: Second =: Solar cell for solar cell backplane with laminated body: Solar cell module with battery back panel. And [1] a laminated body for a solar battery back sheet of the present invention, comprising: a dichloro-di- fluorinated resin layer laminated on the vinylidene chloride-based resin layer. [2] The laminated body for a solar cell back sheet according to [:], wherein the meta-ruthenium resin layer and the polyfluorene-modified acrylic resin layer are directly in contact with each other to be laminated. [3] In the case of the solar panel for a material [1] or [2], the vinyl chloride resin layer is a vinylidene chloride resin obtained by using a vinylidene resin in (4) a solvent. Made of lacquer Gacquer, or a vinylidene chloride emulsion. i [4] The laminate for a solar cell backsheet according to [3], wherein the vinylidene chloride resin powder and the partial ethylene ethylene latex in the vinylidene chloride paint are contained in the whole monomer. 50% by mass or more of the monomer of the partial olefin is obtained by emulsion polymerization. [5] The laminated body for a solar cell backsheet according to any one of [1], wherein the poly-stone-modified acrylic resin layer is modified by poly-stone-oxygen-modified acrylic acid. Made by latex. [6] The laminate for a solar cell backsheet according to the above [5], wherein the polyoxo-modified propylene (tetra) latex contains a polyoxyl resin and an acrylic resin. [7] The laminated body for a solar battery back sheet according to the above [6], wherein the poly-modified propylene (10) and the chylo-based acryl-based resin are subjected to the emulsification of the acrylic resin. At the same time, the emulsified double-into Detian "just added, after the emulsion polymerization, the addition of the poly-stone modified oxygen sword. [8] As in the previous [5] to [7], and +, take the pool back plate with a layered polyoxygen modified acrylic latex in the right (four) line suction _ and / or light stabilizer. / Zhong fine has (9) as claimed in the scope of [5] to [1〇] In any one of the solar panel laminates, wherein the above-mentioned polyelectrolytic, the month is used as a paint mixed with the pigment to make the propylene system [1〇]: [1] to [9] A solar battery back sheet 1 B::=Rare resin layer is a second-air ethylene paint or partial: a coating layer of the knee, a poly-stone modified acrylic resin layer, a poly-milk modified acrylic system Latex coating layer. m [11] = 2 (4) Battery laminate: wherein the thickness of the above-mentioned partial dichloride coating layer is 5 to 5 mm, and the thickness of the coating layer of the acid resin coating is i0 m.夕 L12j is a solar cell backsheet, which has a substrate, and a laminate for a solar cell backsheet according to [1] to [11], wherein the solar cell backsheet is laminated on the substrate. . , the solar cell backsheet of 12, wherein the substrate is a plastic substrate.太阳13] The solar backsheet, wherein the layer of the second gas, the bismuth A and the base material are laminated with a binder. [15]:: [14] The solar battery back sheet, wherein the plastic substrate is made of χκ-ethylene phthalate resin. 321209 8 201003942 [1 6] such as [15] solar power, and also _ lipid hydrolysis resistance 'pre-acidic acid ethylene glycol ester [17] = domain battery charm, storage mi2 positive battery back plate. L Jr Shibeizhitai (the effect of the invention) Under = Ben I Ming' can provide a long-term water vapor barrier performance in a harsh self-tanning environment. In addition, a solar battery module having the battery back plate and the battery back plate of the above-mentioned mouth basket can be provided. [Embodiment] The best mode of the present invention (hereinafter, the present invention is not limited to the following embodiments (the sun is changed variously - the vinyl resin layer and the system) In the present embodiment, in the present embodiment, the vinylidene chloride is required for the solar cell backsheet to be maintained in order to maintain the composition of the polycrystalline silicon dioxide-based resin layer. In addition, the gas barrier property of the solar cell is a solar cell backsheet layer in order to maintain the eve of the um heart fork for a long time in the harsh white 妒 position, especially in order to maintain the weather resistance performance is necessary Weather resistance and moisture resistance are maximized. Polyhard = 321209 9 201003942 C = The layer of the tree is directly layered on the vinylidene chloride resin layer. The structure is such that even if the gas barrier layer is a reed, the gas barrier property required for the solar cell backsheet can be exerted. It can be filled in the perishal manner, in the vinylidene chloride resin layer and the polybe acrylic resin layer. Other layers can also be inserted between them, in which case it will appear The water vapor barrier required for the solar battery backsheet: properties such as properties, moisture resistance, heat resistance, etc. In addition, in the present embodiment, the polyacrylonitrile is directly coated by the second embodiment. Acid-based latex, and in plastic: Meilian::_ and other two layers (that is, the second-gas layer B: the two-milk modified acrylic resin layer directly connected and laminated) is better. Electricity: back layer with laminate body, heat resistance, sputum, disordered limbs (four), electrical insulation, physical strength, etc. on the plastic substrate layered with vinylidene chloride tree - with oxygen modified propylene Acid resin:::Connected to (preferably one vinyl ruthenium resin layer) The partial vinylidene chloride film and the second ethylene sapphire tree in the present application form are not caused by partial dichloroethylene. It is specially limited to be made by the partial & 虱 卸 卸 卸 所 由 由 由 由 由 由 由 由 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 虱 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛 洛Look, from =, clothing is better, from easy control, in addition to the simplification of the component structure, the addition of two is more ambiguous. See, the vinylidene chloride resin layer to coating two =Productivity is better than vinyl lacquer. One-gas ethylene latex or partial dichloride 321209 10 201003942 Here, the second layer of ethylene resin, the composition of the fat composition. :, _ 曰 树 指 指 指 指 指 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树 树When the heterogeneous resin in the copolymer of the other monomer is a copolymer, the polymerization ratio of the partial vinylidene chloride is from 5 G f to 94% by mass, preferably 4, by mass. % more preferably ' 〇 to 93 贝 "better, rib to 92. In addition, the preferred partial dichloroethylene resin, refers to the composition or consists of a vinylidene chloride-based resin, and a dry powder. Do not suspicion: and the so-called vinylidene chloride film refers to a resin composition composed of a partial or a vinylidene chloride-containing resin. The vinylidene chloride latex is mainly composed of vinylidene chloride.

There is no particular limitation on the latex of the resin composition produced. It can be a latex made of J or a compound made of vinylidene chloride. The vinylidene chloride emulsion is preferably obtained by emulsifying and polymerizing a monomer containing a monomer: a monomer: a monomer. In the early body, the content of the vinylidene chloride is preferably 94% by mass, more preferably 93% by mass, and particularly preferably 88% to 92% by mass. The ratio of the vinylidene chloride is 50% by mass or more, and (the gas barrier property such as barrier property. In addition, the ratio of the vinylidene chloride = 321209 11 201003942 94% by mass or less, and the dichloroethylene resin layer The film-forming property of the upper coating film is preferably such that the powder of the vinylidene chloride-based resin (for example, in the organic solvent, the compound is dried and powdered) is dissolved in the solution. The organic solvent is not particularly limited. The organic solvent may be soluble or the like: ?-butyl ester, methyl-hydrogen = mixed and = species, or two or more of these may be in any ratio. Examples of the dilute copolymerized monomer include, for example, gas butyl vinegar, acrylic acid 2-B A "t: methyl θ, propyl (tetra) ethyl ester, propylene ester; methyl methacrylate methyl vinegar and formic acid △ Acrylic vinegar such as ethyl vinegar; acrylonitrile 1 propyl propyl vinegar and other methyl methicic acid and cis-butane diacid, etc.: dipropyl, methyl propyl, i. , can be selected as one type or more than two types. In addition, 'in the case of partial dichloroethylene milk Riga to prevent thin Up ' can also add organic ... 糸 lubricant (example矽 矽 矽 ) ) ) 矽 矽 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 用以 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽 矽, . . . 2 to 2 〇; v 2 please be good, organic lubricants * 2; to 6 mass % is better. 〃 should be evenly dissolved or dispersed in the second 321209 12 201003942 vinyl chloride latex and partial In the vinyl chloride paint - for example, the amine vinegar is cut, the epoxy is cut, etc. For either, the method may be applied by applying a vinylidene chloride latex and a method of coating the substrate to a thickness of two mm (4). Preferably, the method is carried out. At this time, the heart is sub-dried to form a vinylidene chloride film. The concentration of the % coating liquid is preferably i-drying to be carried out between 2G and 15 Gt. The pseudo- _ can be used to make the thickness of the bismuth layer after coating (4) to 9 (TC is better for coating. Also, · · 曰 degree is better, therefore, month i)偏一氯乙乙妇乳,偏:气乙#漆&#; by gravure coating method 'dip_nip coating method, soil testing method can be widely used) coating method , air knife coating method # various square 'bar (; the performance of the two-wave dichloroethane-based resin layer and more uniform scoop cloth ^ in order to fully apply the bar coating method, air knife coating method More cloth ^ coating, between the materials: in, in the 'in order to increase the vinylidene chloride resin layer disc base pre-corrosion of the substrate is strictly controlled ^ for a wind B% paint before the dichloroethylene Resin layer. <Adhesive layer can be laminated and laminated: agent = can be used on the substrate and vinylidene chloride, for example, .% fat transfer agent, amine ester tree spray, adhesive 1 Resin-based splicing agent, poly-glycolized acrylic resin-based resin connection == 系 接着 # ] ] ] 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。. In the above-mentioned search, it is preferable to use an amine (10) fat-based adhesive or an acrylic resin-based adhesive 321209 13 201003942 = an oxygen-modified acrylic acid-based resin-based adhesive, and B. Ethyl acetate-ester-based adhesive for the use of the adhesive. The method of using the vinylidene chloride varnish is a Japanese-made product, and / is a vinyl-based resin layer. The addition amount is preferably used in the presence of two lacquers. . At this time, the right is better. 4, the emulsion of the fine resin is 1 to 6 mass%. When the product is manufactured by Zuo Sheng, the pre-:: '仏 layer is coated with an adhesive with a vinylidene chloride cloth, and then coated on it. In the present embodiment, the second _ is preferably 5 to 3 Π έ wheel " the thickness of the 曰 layer is preferably 5 to 50 to '30 / / ηη, such as coating a vinylidene chloride on a plastic substrate or the like. Milk 30 heart is better. The thick resin of the resin layer obtained by the partial ethylene gas, the bismuth, the bismuth or the partial-mouse lacquer, and the ^ ^ ^ 如 偏 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如 如High gas, and 'When in order to increase the coating of the dichloroethylene-based resin layer, a large amount of vinylidene chloride latex or vinylidene chloride paint is used: in the process sometimes occurs in the film production The problem of cracks or twists in 4 produces such a poor appearance of the film, which not only damages the work. The second is also unable to achieve the desired gas barrier properties. If you want to increase the coating thickness of the second, outer = tree: layer, you can use the method of coating the resin layer: =: several times to install vinylidene chloride latex or vinylidene chloride paint: Shixi oxygen modified acrylic resin layer) 323209 14 201003942 The polyfluorene-modified acrylic resin layer in the present embodiment is a polyacrylic acid-modified acrylic resin, a polyfluorene-modified acrylic resin, or a poly The oxime-modified, acrylic latex or the like is not particularly limited, and it is preferably produced from a polyoxygen-modified acrylic emulsion from the viewpoint of easy control of the film thickness. v In addition, from the viewpoint of the simplification of the component composition and the productivity of the processability, it is preferable to use a polyacrylic acid modified copolymer to coat the Wei modified acrylic latex. According to the bamboo, the oxygen-modified acrylic resin layer is composed of polysulfide-modified acrylic resin or composed of resin containing polysulfate (tetra) acid resin. The layer of matter. In addition, the = oxygen modified acrylic acid (four) month, refers to the coexistence of money burning bonds and propylene ^ resin resin or resin composition 'for example: can be poly-modified hunger oxime oxygen complex a copolymer with an ethylenically unsaturated monomer, or a pot

Read the knot with sand oxide (4) called acid resin, or a mixture of poly dream resin and acrylic resin. ''" ^ = 'The so-called acid-based resin, which refers to a polymer containing at least a kind of monounsaturated monomer as a monomer component, which can be at least a vinyl residue and a monomer. The polymer may also be at least i kinds of ethyl ether having a carboxyl group. 1 Early body and other single slaves/ices which can be copolymerized with the same. When it is a copolymer, at least 丨^ The polymerization ratio of the monomer to the monomer is -94% by mass, and may be 80 to =^ or more, or 50% by weight. The ethylenic monomer may be exemplified by two degrees = 88 to 92. A methacrylic acid monomer, propylene 321209 15 201003942 an enoic acid monomer, a methacrylic acid ester monomer, an acrylate monomer, etc. The term "polylithium oxy-oxygen resin" refers to a polymer compound having a cerium oxide bond. ^亚和, the so-called poly-oxygen-modified acrylic film and poly-n-oxygen modified yoghurt yttrium resin" refers to a single poly-oxygen modified acrylic resin, consisting of poly-wei modified (tetra) acid A film or a dry powder composed of a resin composition of Xuzhi. In addition, a polyfluorene-modified acrylic resin.....I...into a small column such as /100仏3 It is obtained by coating coatings of Siqi oxygen (4) (4) latex and pigment. = Asia has no special restrictions, for example: white pigment can use zinc oxide, white carbon _, zinc bismuth (1) th0 qing e, zinc sulphide Organic pigments such as titanium emulsified titanium, deposited barium sulfate and barite (baHte) powder mixed with sulfuric acid lock; ', and organic pigments such as polyethylene copolymer particles

Pigments can use carbon black, etc., red pigments. Bu ~, E main name red 丨 丨 Ι 丹 丹 、, iron oxide red, etc. (6) trT;, 'can use road yellow, yellow, etc., blue pigment can use group ^ tramarlne Mue ), Prussian blue (ferrous iron nitride; ^ Yang battery module light reflection and improve the efficiency of conversion into electrical energy # H is better than white, especially zinc oxide, calcium carbonate is better. Titanium, in the case of pigments and polyfluorene-modified acrylics, a dispersant, a pH adjuster, a coating agent (organic solvent), etc. can be used as needed. You can use =, tackifier, pigment and polyfluorene modified acrylic acid system. In the coating film after coating and drying, / the ratio of blending, converted to %, polyfluorene modified C; It is better to use a pigment of 20 to 60 masses of yoghurt to change the shellfish. The color of the tree is 4 to 8 〇 mass%, the 321209 16 201003942 pigment is 30 to 50 mass%, and the polyoxygen modified acrylic resin is 50. It is preferably 70% by mass. If the mass ratio of the pigment is 20% by mass or more, the opacity of the coating film can be improved. In the case of a white pigment, the light incident from the surface of the solar power generation unit can be efficiently reflected. On the other hand, when the ratio is 60% by mass or less, the film formation property of the coating film and the weather resistance in the natural environment change. From the viewpoint of weather resistance, the polyfluorene-modified acrylic emulsion in the present embodiment is a polyfluorene-modified agent and at least one ethylenically unsaturated monomer having a carboxyl group (hereinafter, sometimes Only one type of "ethylenically unsaturated monomer A") and at least one type of ethylenically unsaturated monomer different from the above-mentioned ethylenically unsaturated monomer having a carboxyl group (hereinafter, simply described as "ethylenically unsaturated monomer" Preferably, the polymer B") and the emulsifier are polymerized to obtain a polymer emulsion containing polyoxymethylene. From the viewpoint of light resistance, the poly-oxygen-modified acrylic emulsion is formulated with an ultraviolet absorber and/or light. It is preferable that the stabilizer is obtained by copolymerizing an ultraviolet absorber and/or a photosensitizer with a polyfluorene-modified acrylic latex. The polyfluorene-modified acrylic acid of the present embodiment is produced by polymerization. system The method of the gel is, for example, a polymerization method such as emulsion polymerization, suspension polymerization, bulk polymerization, or microemulsification polymerization, and the like, and is not particularly limited. A method of stably producing a latex having a good dispersion stability of an average particle diameter of about 10 nm to 1 μηη. In the present embodiment, the emulsion polymerization is carried out by simultaneously carrying out an ethylenically unsaturated monomer 属于 which is a radical polymerizable monomer in an aqueous medium, and B 17321209 201003942 Emulsification polymerization of the free silk (4) line of the body B, and emulsion polymerization by the hydrolysis/condensation reaction of the polyfluorene modifier: 佳' can obtain the acrylic resin containing the acrylic resin The above-mentioned aqueous medium mainly uses water, but a medium in which a lower alcohol of 1 i 3 or a solvent which is equally soluble in water is added to water may be used. The amount of the solvent other than the water to be added at this time is added as a good port so that 1 is 20% by mass or less in the pre-emulsion before the start of the polymerization. Since the amount of the solvent other than water is 20% by mass or less, the emulsion polymerization can be carried out stably without damaging the emulsified state of the pre-emulsion = liquid. It is more preferable to carry out emulsion polymerization using only water as a solvent. In the present embodiment, the pH of the pre-emulsion composed of the ethylidene unsaturated monomer A, at least the ethylenically unsaturated monomer β, and the emulsifier before the emulsion polymerization is not particularly limited. It is better to take Qiu 4 〇 below. By carrying out the emulsion polymerization at pH 4.0 or lower, the condensation reaction of the polyoxime modifier can be rapidly formed, and the condensation reaction can be inhibited by the emulsion polymerization. From the viewpoint of storage stability of the product, the pH of the reaction W is preferably 4.0 or less, and more preferably ρΗ1·5 or more. In the case of the present invention, there is no particular limitation on the method of introducing the free radical initiator in the polymerization. It can be pre-directed to the reaction system as a free radical initiator = salt. In addition, it may also be a method in which at least one type of ethylenically unsaturated monomer A, at least one kind of ethylenically unsaturated monomer B, the agent, and the (four) starting Lai group Ub (four) are added to the reaction system. . In addition, it can be separated from the pre-emulsion 321209 18 201003942 liquid system and the like are sequentially introduced into the reaction system. As described above, in the radical polymerization, the addition of the polyoxo-modified agent can be carried out before the emulsion polymerization, at the time of the emulsion polymerization, or after the emulsion polymerization. It is preferred to carry out the emulsion polymerization. Further, in the emulsion polymerization, the emulsion polymerization by the hydrolysis/condensation reaction of the polyoxo-modified agent is free from the ethylenically unsaturated monomer A or the ethylenically unsaturated monomer B. Emulsification polymerization by polymerization of the base is also particularly preferred at the same time. Further, the polyoxymethylene resin obtained by the hydrolysis/condensation reaction of the polyoxo-modified agent may be blended with an acrylic latex containing an acrylic resin. The polyoxo-modified agent used in the present embodiment may contain the hard-burning compound (1), the dream-burning compound (2), and decane shown in the following (1), (2), and (3), respectively. At least one selected from the group consisting of the compound (3) and the cyclic decane compound, and a combination of two or more kinds thereof may be used. In order to maintain the weather resistance required for the solar battery back sheet, a combination of the above decane compound (2) and the aforementioned decane compound (3) is preferred.

RfmSiRVno (1) (wherein R1 is a phenyl group or a cyclohexyl group; R2 is a hydrogen atom, an aliphatic hydrocarbon group having 1 to 16 carbon atoms, an aryl group having 6 to 10 carbon atoms, a cycloalkyl group having 5 to 6 carbon atoms, a propylene group having a carbon number of 1 to 10 or a methyl acrylate having a carbon number of 1 to 10; R3 is an alkoxy group independently having a carbon number of 1 to 8, an ethoxy group or Selected from the hydroxyl group; 19 321209 (2) 201003942 m is 0 or 1). CH3Si(R4)3 (wherein the acetoxy group or the group consisting of a group of Si&s or a radical R is independently selected from alkoxy groups having a carbon number of j to 8). (CH3)2Si(R5)2 (3) (wherein R3 is independently selected from the group consisting of Wei's to 8 alkoxy groups).

In the present embodiment, if at least one of the stone-smelting compound (1) is used as the J τ oxime ox 彳 彳 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 则 共 共 共 共 共 共 共 共 共 共 共Therefore, it is better. Further, it is preferred that at least one decane compound (2) is added as a polyfluorene oxide to impart a crosslinking density to the polyvalent structure. The chemical person has at least a kind of Wei compound (3) and/or a ring-shaped stone garden mouth, and the substance is used as a concentration-setting agent, because the crosslinking density of the poly-wei polymer formed by lowering the (four) oxygen modifier is It is preferable to impart flexibility to the coating of the (IV) oxygen-modified acrylic acid emulsion. The decane compound (1) used in the present embodiment is exemplified by a methoxylated m-methoxy sulphur, a triethoxy decane, a diphenyldiethoxy decane, a phenyl group. Methyl dilacyl (tetra), cyclohexyltrioxy (tetra), dicyclohexyldimethoxyalkane hexyldiethoxy decane, dicyclohexyldiethoxy decane, and the like. One type of the compound may be used, and two or more kinds of these may also be used. 321209 20 201003942 The stilbene compound (1) is preferably phenyltrimethoxy decane. Specific examples of the decane compound (2) used in the present embodiment include, for example, a decyltrimethoxy decane, a decyltriethoxydecane, and the like. These compounds may be used alone or in combination of two or more kinds. The terpene compound (2) is preferably methyltrimethoxy decane. Specific examples of the decane compound (3) used in the present embodiment include dimethyldimethoxy decane and dimercaptodiethoxy decane. These compounds may be used alone or in combination of two or more kinds. The decane compound (3) is preferably a dimercaptodimethoxy decane. Specific examples of the cyclic decane compound used in the present embodiment include octamethylcyclotetraoxane, octaphenylcyclotetraoxane, hexamethylcyclotrioxane, and dedecyl ring. Pentaoxanes, tetradecyltetravinylcyclotetraoxane, and the like. These compounds may be used alone or in combination of two or more kinds. The polyoxoxime modifier may contain an isobutyl group in addition to the polyoxonium modifier selected from the above decane compound (1), decane compound (2), decane compound (3), and cyclic decane compound. Trimethoxy decane, vinyl triethoxy pulverization, 7"-propanyloxypropyltrimethoxy oxime, 7-acryloxypropyltriethoxy decane, r-methyl Propylene methoxypropyltrimethoxydecane, r-methacryloxypropyltriethoxydecane, T-methylpropenyloxypropylmethyldimethoxydecane, r-glycidyl Oxypropyl dimethyl dimethoxymethyl decane, r-glycidoxypropyl triethoxy decane, tetramethoxy decane, tetraethoxy decane, and the like. In addition, a polyoxonium modifier can be added, or no polyoxonium modifier can be added. 21 321209 201003942 == no = heart, ethylenically unsaturated monomer B and emulsified J clothes, then #合_(四) Oxygen polyoxyl latex is not limited to dimethyl (tetra)oxy latex, such as a stupid base, a linear alkyl group, a hydrogen system, an amine system, a bismuth oxide emulsion or a polyoxo resin latex. In the present embodiment, the poly-stone-modified acrylic resin layer in the embodiment of the present invention is weathered by the weathering. Λ11 reduced fat (10 oxygen reading), so it can be achieved extremely excellent (%. =, ^ the presence of condensate of oxygen modifier can be by % - dirty vibration spectrum) or (proton NMR spectrum) and two: Erwan Bay NMR spectroscopy) is used for the use of tetramethyl, but s (Num. NMR spectroscopy) does not use the second standard, but the determination of Shixi rubber (6) gamma _ber) and its signal = ~22Qing, or the dissolution of tetramethyl-Wei dissolved in the gas imitation, the measured value from Βσ is set to Gppm and used as an external standard. For example, the chemical shift of the m-face is shown to be 9 〇, and the condensate of the compound (1) can be identified. In addition, since the chemical shift of l is -4 G to the weight of the bee, the condensate of the compound (2) can be identified. Further, since the chemical group of 2%_臓 shows a peak at -26 ppm, the compound (3) composition can be identified. Further, since the chemical shift of the hidden phase corresponding to the structure is not peaked, the condensate of the cyclic hairpin compound can be recognized. In the present embodiment, it is used in combination with the ethylenically unsaturated monomer a and ethylene 321209 22 201003942 : the total mass of the diunsaturated monomer β. 1 to 200% by mass is / soil, |'>/>^1:1:1. 1 is more useful (J.1 to (10) 2; 2 to 120% by mass is preferred, to use: Berry < more preferably, to use 1 to 1. The mass % is even better. In the present embodiment The ethylenicity to be used may be, for example, copolymerized with the ethylenically unsaturated monomer β to a less than one type and has a = polymerizable acid-inducing monomer. Specific examples include, for example, methyl methacrylate Acid and its monoacetic acid, butyl succinic acid and its mono- vinegar, diacid and its single rotation (hereinafter, sometimes acrylic acid and decyl propyl group 5 and § have been loaded as (meth)acrylic acid). The ethylenically unsaturated monomer ruthenium also functions as a catalyst for promoting the hydrolysis reaction and the condensation reaction of the polysulfide catalyst 4, and it is preferred to include at least one selected from the group. In the total quality of ethylene and the monomeric oxime and the monomeric oxime, the ethylene residue and the monomer U are used in the total amount of ethylene and blame. It is preferable to use 15% by mass. The ethylenically unsaturated monomer β used in the present invention may be, for example, a (meth)acrylic acid acetonitrile monomer or a (meth) propylene lysate represented by (diyl) (d) acid cool. The monomer and other ethylene monomers and the like are at least one type of comonomer copolymerizable with the ethylenically unsaturated monomer A. Specific examples of the mountain (meth) acrylate monomer include, for example, an alkyl moiety. The number of (meth)acrylic acid esters having a carbon number of 1 to 18, and the number of units of the epoxy group are 1 to 1. (poly) oxygen extended ethyl mono (meth) acrylate, (poly) oxygen Propyl mono(indenyl) acrylate, a hydroxyalkyl (meth) acrylate having a carbon number of 1 to fluorene, and an ethylene oxide unit number of 1 to 1 (poly) 321209 23 201003942 Oxygen-extended ethyl bis(indenyl) acrylate, etc. Specific examples of the ί ί 曱 曱 丙 丙 丙 丙 丙 丙 可 可 可 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( Ethyl ester, n-butyl (meth)acrylate, isobutyl (meth) acrylate, butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, (methyl) ) Dodecyl acrylate, cycloalkyl (meth) acrylate, etc. Two (meth) propionate vinegar with methyl methacrylate, methyl propylene N-butyl acrylate, butyl acrylate, 2-ethylhexyl methacrylate, cyclohexyl (meth) acrylate, 2-hydroxycyclohexyl (meth) acrylate, (methyl) propyl phthalate Cyclohexyl ester, 2,3 cyclohexene oxide (meth)acrylate. Specific examples of two (poly)oxyethylidene mono(indenyl) acrylate vinegar For example, ethylene glycol (mercapto) acrylate, ethylene glycol oxime (meth) acrylate (meth) acrylate (meth) acrylate, diethylene glycol methoxy (meth) acrylate Tetraethylene glycol (mercapto) acrylate, tetraethylene glycol methoxy (meth) acrylate, etc. Specific examples of the (poly)oxypropyl propyl mono (meth) acrylate include, for example, Propylene glycol (meth) acrylate, propylene glycol decyloxy (meth) acrylate, monopropylene glycol (meth) acrylate, dipropylene glycol decyloxy (meth) propylene 酉夂 曰 tetrapropanol (A Base) acrylate, tetrapropylene glycol decyloxy (fluorenyl) acrylate, and the like. Specific examples of the hydroxyalkyl (meth) acrylate are exemplified by 2-hydroxyethyl (meth)acrylate and 2-hydroxypropyl (meth)acrylate. Specific examples of the above-mentioned (ΛΚ) oxygen-extended ethyl di(methyl) acrylate may be exemplified by 321209 24 201003942 - alcohol mono(methyl)propane acid, tetraethylene glycol di(methyl) propyl ruthenium Ethylene glycol di(yl) acrylate, vinegar, triethylene glycol di(T-) acrylate, and the like. The ethylenically unsaturated monomer β is, in addition to the above, a glycidyl acrylate, a trimethyl methacrylate, a (meth) propyl group, a (meth) enoate, and the like. / In the total mass of the unsaturated monomer oxime, the above (the content of the acrylate monomer is preferably 8 〇 to 1 〇〇 mass % by mass. Berry ^ is preferably 90 to 100 in this embodiment In the form, the (meth) _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ It is preferable to use a polysecond oxygen-modified acrylic resin layer having excellent durability. One part of the ruthenium atom of the cycloalkyl group can be substituted by an alkyl group having a carbon number of 丨6 or a hydroxyl group, and can also be used. The (meth) acrylate monomer having a cycloalkyl group may, for example, be a methyl group I cycloalkyl acrylate. The cycloalkyl (meth) acrylate may, for example, have a carbon number of 5 to A cycloalkyl group of 12. Specific examples of the (meth) acrylate monomer having a cycloalkyl group include a compound represented by the following formula (4): CH2 = C(R6)COOR7 (4) (wherein , R 6 is a hydrogen atom or a methyl group; R 7 is a cyclopentyl group, a cyclohexyl group or a cyclododecyl group, and such a cycloalkyl group may have a carbon 321209 201003942 number 1 to 6 alkane And a specific example of the compound represented by the above formula (4): cyclohexyl (meth)acrylate, 2-hydroxycyclohexyl (meth)acrylate, ( Mercapto) decyl hexanoic acid propionate, 2, 3 epoxy hexamethylene vinegar (meth) acrylate, especially cyclohexyl methacrylate. In the case of ethylenically unsaturated monomer B The (meth) acrylate monomer of the main component contains the ratio of the (meth) acrylate monomer having a cycloalkyl group, and the (meth) acrylate monomer in the ethylenically unsaturated monomer B The σ juice of the body is preferably 5% by mass or more, more preferably 5 to 卯% by mass, and more preferably 5 to 80% by mass. 9 (meth)propanol I having a ring-terminated group The monomer can be used as a ruthenium or a mixture of two or more of these. The total mass of the (meth) acetoacetate in the ethylenically unsaturated monomer 含有 has a ring The (meth)acrylic acid g of the alkyl group is more than or equal to 5% by mass of the monomer, and a polyfluorene-modified acrylic resin layer excellent in durability can be produced. Further, since it contains 99% by mass or less, it is excellent in the film-forming property of the poly-oxygen-modified malonic acid-based latex. The (meth)acrylamide monomer may, for example, be (meth)acrylamide or diacetone. (Methyl) acrylamide, N-methylol (meth) acrylamide, N-butoxy fluorenyl (fluorenyl) acrylamide, etc. Other ethylene monomers may, for example, be vinyl acetate or propylene. Ethylene vinyl ester, vinyl versatate, vinyl pyrrolidone, methyl ethyl group i. Further, other ethylene monomers may be vinyl cyanide monomers, for example: 321209 26 201003942 acrylonitrile And methacrylonitrile, etc. Further, other vinyl monomers may, for example, be an aromatic monomer such as vinyl benzene, styrene or «-decyl styrene; or a vinyl halide such as vinyl chloride or vinylidene chloride; Alkene, ethylene, etc. In the present embodiment, the ethylenically unsaturated monomer B is preferably used in an amount of from 85 to 99.9% by mass, based on the total mass of the ethylenically unsaturated monomer and the ethylenically unsaturated monomer B. In the emulsifier used in the present embodiment, an ethylenically unsaturated monomer having a sulfonic acid group (-S〇3H) or a sulfonate group (-S〇3M) and having a sulfate group (-〇) At least one of the ethylenically unsaturated monomers of S〇3H or -〇S〇3M) is preferred because it can achieve high water resistance of the polyfluorene-modified acrylic resin layer. The ethylenically unsaturated monomer having a sulfonic acid group or a sulfonate group in the present embodiment may, for example, have a radical polymerizable double bond and have a free sulfonic acid group, or an ammonium salt or an alkali metal salt thereof. A compound of the group (ammonium sulfonate or alkali metal sulfonate). Preferably, it is substituted with a group of a saddle salt, a sodium salt or a potassium salt of a continuous acid group, and has an alkyl group having from 1 to 20 carbon atoms, an alkyl ether group having from 2 to 4 carbon atoms, and a carbon number of 2 a compound having a polyalkyl ether group of 4, a aryl group having 6 or 10 carbon atoms, and a substituent selected from the group consisting of succinic acid groups; or having an ammonium salt, a sodium salt or a potassium group bonded to a sulfonic acid group A vinyl vinyl sulfonate compound based on a salt. In the present embodiment, a specific example of the succinic acid compound substituted with a salt of a salt of a synthetic acid group, a sodium salt or a salt of a salt may be mentioned, for example, allylsulfonic acid 27 321209 201003942 The compounds represented by the following formulas (5) to (8) include S〇3M r8 CH-C00-(A0)n-CH2-(!): CH, -COOR9 compound: CH, (5) R8 ?h2. Oo one (10)n-CH2 丄 CH2 (6) CH-COOR9

I so3m CH2—COO一(AO)n—ps 卜—(10)—ch2 一?h—ch “0_CH24=CH2 (7) S03M oh 〒H r8 7 〇〇〇一一一—CHr〇—CH2—cUCH2 CH2- COO-(AO)ri~Rs (8)

S03M (in the formulas (5) to (8), it is hydrogen or methyl; it is a carbon number of 1 to 2 院, a carbon number of 1 to 2 稀, a carbon number of 5 to 12, a carbon number (1) 9 aryl fluorenyl hydrocarbons or straight one = base, acid group substituted ketone or polyoxysostene keis base skeletal stone versatile number 1 to 20 and alkyl group partial oxygen alkyl alkyl group Phenyl group ((4) part 2 is 2 to 4) or the carbon number of the poly group part is 2 to 4); the inverse of the stone is 1 to (4) A is the slave number 2 to 4, or the extension Its * or New Zealand takes the form of the county; the hydrogen of the H part is 钱 321209 28 201003942 Μ is money, sodium or potassium; η is an integer from 0 to 200). The emulsifier containing the compound represented by the above formulas (5) and (6), for example, ELEMINOL JS-2, JS_5 (registered trademark, manufactured by Sanyo Chemical Industries Co., Ltd.), etc., and the above formula (7) and 8) The emulsifier may, for example, be LATEMUL S-120, S-180A, or S-180 (registered trademark, manufactured by Kao Co., Ltd.). Further, specific examples of the compound having a part of the aryl group substituted with a salt group may, for example, be an ammonium salt of p-styrenesulfonate, a sodium salt or a potassium salt. Specific examples of the compound having a part of the alkyl group substituted with a sulfonate group include, for example, an ammonium salt, a sodium salt and a potassium salt of a decyl sulfonium sulfonate, an ammonium salt of a sulfonic acid alkyl acrylate, and sodium. Salts and potassium salts, ammonium salts, sodium salts and potassium salts of sulfonic acid alkyl (meth)acrylates. The ethylenically unsaturated monomer having a sulfate group in the present embodiment means a compound having a radical polymerizable double bond and having a sulfate group or an ammonium salt or a metal salt thereof. Among these, an alkyl group having from 1 to 20 carbon atoms, an alkyl ether group having from 2 to 4 carbon atoms, and a carbon number of 2 are partially substituted with a group of an ammonium salt, a sodium salt or a potassium salt of a sulfate group. A compound selected from the group consisting of a polyalkyl ether group of 4 and an aryl group having 6 or 10 carbon atoms is preferred. Specific to a compound having a part of a carbon number of 2 to 4 or a polyalkyl ether group having 2 to 4 carbon atoms substituted with a group of an ammonium salt, a sodium salt or a potassium salt of a sulfate group in the present embodiment For example, a compound represented by the following formulas (9) to (11) can be given. 29 321209 201003942 ch=chch3

O-(A0)n-SO3M (9) (wherein R1Q is an alkyl group having 6 to 18 carbon atoms, an alkenyl group, or an aralkyl group;

Rn is an alkyl group, an alkenyl group or an aralkyl group having 6 to 18 carbon atoms; R is a nitrogen or a propyl group; A is a C 2 to 4 alkyl group; and hydrazine is an ammonium, sodium, potassium or alkanolamine residue. Base; η is an integer from 1 to 200). R13

I CH2 —〇 一 CH2一C = CH2

I ch-o-(a〇)-so3m (10)

I ch2-o-(a〇), -r14 (wherein R13 is hydrogen or sulfhydryl;

Ru is an alkyl group having 8 to 24 carbon atoms, an alkylphenyl group or a fluorenyl group; A is a C 2 to 4 alkyl group; hydrazine is an ammonium, sodium, potassium or alkanolamine residue; 1 is 0 to 50 An integer; η is an integer from 0 to 20. 30 321209 201003942 R15

I CH2 — 0 — CH2 — C = CH2

I CH-R16 (11)

0—(AO)n — S03M (wherein R15 is hydrogen or methyl; R16 is an alkyl group having 8 to 30 carbon atoms; A is an alkylene group having 2 to 4 carbon atoms; or a hydrogen of a part of an alkyl group Substituting an alkyl group with a hydroxy or carboxylic acid group; hydrazine is an ammonium, sodium, bell or alkanolamine residue; η is an integer from 1 to 200). The compound represented by the above formula (9) may, for example, be AQUAL0NHS-10 (registered trademark, manufactured by Dai-ichi Kogyo Co., Ltd.), and the compound represented by the above formula (10) may, for example, be ADEKA REASOAP SE-1025Α. SR-10N, SR-20N (product name, manufactured by ADEKA Co., Ltd.), etc., and the compound represented by the above formula (11) may, for example, be AQUALON®-10, ΚΗ-05 (registered trademark, First Industrial Pharmaceutical Co., Ltd.) Company system) and so on. In the present embodiment, an ethylenically unsaturated monomer having a rhein base, a rhein base or a sulfate group, which is used as an emulsifier, is obtained by radical polymerization of latex particles with latex particles. The state of the copolymer is present, or is adsorbed to the latex particles in the form of an unreacted material or is present in the aqueous phase of the latex, or is a copolymer of the water-soluble monomer or an emulsifier used as an emulsifier. The state of the copolymer between the bodies is adsorbed to the latex particles or present in the aqueous phase of the latex. 31 321209 201003942 Among them, through the use of Timan to carry out free radical polymerization with the milky private _2i ^, Qiu & human k-gel particles, the ratio of the state of hydrate, can be highly resistant Wet sex. 3, the film of the waiter is used as an emulsifier for the ethylenically unsaturated monomer, and the resulting film is decomposed into a gas, and the substance is recognized by the gum. In the present embodiment, it is determined that the amount of the ethylenic non-saturated monomer B is the same as that of the ethylenic acid. From 5 mass% to bismuth, it is preferred to use from 0.1% by mass to 5% by mass. In the present embodiment, in addition to an emulsifier containing an ethylenically unsaturated monomer having a rhein group or a rhein sulfate sulfonic acid group, a surfactant may be used. In the case of the aforementioned surfactant, for example, a ruthenium salt, a silk salt, a ruthenium sulphate, a polyoxyethylene sulphate, a polyoxyalkylene aryl group Anionic craniofacial active agent such as sulfate; non-reactive non-ionic non-reactive nonionics such as polyoxyalkylene aryl aryl group, polyoxyalkylene ethyl sorbitol oxime fatty acid vinegar, oxygen extended ethyloxy propyl block copolymer Type surfactant; ADEKAREAS〇APNE—2〇, 肫_3〇, νε—4〇 (product name, made by ADEKA Co., Ltd.), etc. α _[ η (女丙氧)甲^ '2-(壬基Phenoxy)ethyl]|trans-polyoxyethylene, or _fine RN-10 'RN-20, RN_3〇, 跗_5〇 (registered trademark, First Industrial Pharmaceutical Co., Ltd.) A polyoxyethylene-based propyl phenyl bond or the like is a nonionic surfactant which is a reactive nonionic surfactant which can be copolymerized with an ethylenically unsaturated monomer. The amount of the surfactant used is preferably 〇·5% by mass or less based on the total mass of the ethylenically unsaturated 321209 201003942 monomer A and the ethylenically unsaturated monomer B. The amount of the non-reactive nonionic surfactant and the reactive nonionic surfactant is preferably 2.0% by mass or less, and more preferably 0% by mass or less. When the above surfactant is used in this range, a film having a good wettability can be formed. In the present embodiment, the polyoxymethylene-modified acrylic emulsion is preferably formulated with an ultraviolet absorber and/or a light stabilizer, and a polyoxygen-modified (tetra) acid emulsion obtained by imparting high weather resistance can be obtained. Further, the polyfluorene-modified acrylic acid emulsion may be obtained by co-polymerization of light. / / UV-absorbing (four) and / or light stabilizer in the method of poly-acid modified acid-based milk kick, can be added in the Ju Shi Xi oxygen modified acrylic emulsion, artificial film additives, etc. after adding UV absorber And/or a light stabilizer, but = light resistance and durability are exhibited for a longer period of time, and it is preferable to carry out the emulsion polymerization I = or the light stabilizer. It is preferable to use o.l i 20 mass ^ 22 mass% of the total mass of the aging heart A and (10) sex and the monomer B. Further, as the ultraviolet absorber, a radical polymerizable property having a radical polymerizable double bond can be used, and a light stabilizer can be used in a molecule having a radical polymerizable double bond. Further, when the ultraviolet absorbing agent is used in combination to form a film of the high-precision latex, it is possible to obtain a poly-alkaline-modified oleic acid-based tree wall layer. The benzophenone-based, benzo------------------------------------------------------------------------------ 321209 33 201003942 The light stabilizer used in the present embodiment is preferably a hindered amine hydrazine compound, for example. Combining a polysulfide-modified acrylic latex having excellent durability with a dibenzophenone-based, benzotriazole-based, tri-grain-based ultraviolet absorber, and/or a light stabilizer having high ultraviolet absorbing ability, Synergistic effects show excellent durability. Among them, a combination of the present two-salt ultraviolet absorber and a light stabilizer is preferred. The benzophenone-based ultraviolet absorber may specifically be, for example, 2' 4 -1 -1 -benzophenone, 2 -hydroxy-4-methoxybenzophenone, 2 -hydroxy 4 -methoxy 2 Phenylketone-5-hemeic acid, 2-carbyl-4-n-octyloxybenzophenone, 2-hydroxy-4-n-dodecyloxydibenzophenone, hydroxybenzyloxydiphenyl Methyl ketone, bis(5_adenyl _4-hydroxylmethoxyphenyl)methane 2,2'-dihydroxy-4-decyloxydoprene, 2,2,-dihydroxy-one 4,4, decyl benzophenone, 2, 2', 4, 4, - tetrahydroxy dicotone, 4 - dodecyloxy-2-hydroxydibenzophenone, 2-hydroxyl_4 Monomethoxy-2, monocarboxybenzophenone, 2-hydroxy-4-stearyloxydibenzophenone and the like. The radically polymerizable benzophenone-based ultraviolet absorber may, for example, be: 2, propyl propylene oxide benzophenone, 2 methyl methyl oxybenzophenone gli], 2- Silk-5_ propylene oxide oxydiphenyl _, 2_ carbyl group: methacryl oxime oxy 2, hydroxy 4-(2-propenyloxy) benzophenone, 2 — Meridyl + (2_ mercapto ethoxy ethoxy) dibenzone, 2-hydroxy + (methacryloxy diethoxy) dimercapone, — via base ~ 4 —(propylene decyloxytriethoxy)benzophenone or the like. The ultraviolet absorber of the benzotriazine system is specifically mentioned, for example: 321209 34 201003942 2 (2-carboxy 5-methylphenyl) benzotriazole, 2_(2,_hydroxy_5,_third-stage - Butylphenyl)benzotriazole, 2-(2,-hydroxy-3,5,2-di(tert-butyl)phenyl)benzotrisole, 2-(2, thiol-tertiary Phenyl)benzotris, 2 (2hydroxy 3,5-di(trioctyl)phenyl)benzotriazole, 2_[2, monohydroxy-3,5'-bis(α,α, -Dimethylbenzyl)phenyl]benzotriazole, methyl-3_[3'-tertiary butyl_5, __(2Η-benzotrisyl-2-yl)-4, _ Condensate of phenyl]propane 13⁄4 and polyethylene glycol (molecular weight 3〇〇) (Japan No. (product of Gei Light Co., Ltd., product name: ΤίΝυνΊΝ (registered trademark) 1130), isooctyl-3-[3' -(2U-benzotris-2-yl)-5,-tertiary butyl-4-hydroxyphenyl]propionate (made by Japan Ciba - Co., Ltd.) Product Name: TINUVIN (registered trademark ) 384), 2-(3,-dodecyl-5, monomethyl 2 _ basic base) and diisohydrazine (made by Japan ciba_Geigy Co., Ltd., product name: TI NUVIN (registered trademark) 571), 2-(2,-hydroxy-3,-di-butyl-5'-nonylphenyl)-5-chlorobenzotriazole, 2_(2, _hydroxy 3,5 One (secondary amyl)phenyl)benzotrisene, 2-(2'-transyl-4, monooctyloxy)benzotriazole, 2-[2'-hydroxy-3,-( 3,,,4",5",6,,-tetrahydroindenylmethyl)-5'-methylphenyl]benzotriazole, 2,2-indenyl bis[4 (1, 1,3,3Π-tetramethylbutyl)-6'-(2Η-benzotris-7,yl)phenol], 2-(2Η-stupidyltriazol-2,-yl)-4, 6 - bis(indenyl-fluorenyl-hydrazine-phenylethyl) test (manufactured by Ciba-Geigy Co., Ltd., Japan, product name: ΤΙΝυΠΝ (registered trademark) 900), etc. Free radically polymerizable benzotriene The ultraviolet absorber may, for example, be 2-[2'-hydroxy-5, -(2"-methacryloxyethyl)p-benzobenzotriazole (manufactured by Otsuka Chemical Co., Ltd., product name: 321209 35 201003942 RUVA-93), 2-[2,-transmethyl-5, ♦methylpropoxy-oxyethyl)_3,_tri-butylphenyl)))-2H-benzotriazine, 2-[ 2,-carbyl-5,-(3-methylpropanoloxypropyl)-3 a tertiary butyl phenyl))) + chloro _ _ benzotriazole, 3-methyl propylene sulfhydryl 2 hydroxypropyl _ 3 _ 3, - (2 _ benzotriazolyl) - 4'-hydroxy-5,-tertiary butyl]phenylpropionic acid vinegar (manufactured by Sakamoto Ciba Co., Ltd., product name: CGL._1〇4). The benzotriazole-based ultraviolet absorber is preferably TINUViN (registered trademark is preferred. The ultraviolet absorbing agent of the dimorphic system is exemplified by, for example, TINUYIN400 ^ TINUVIN405 > TINUVIN460 > TINUVIN477DW > ΤΙ_IN479 (registered trademark, Japan) c soil ba_Ge; gy Co., Ltd.), etc. The UV absorber of the second tillage system is preferably TiNUVIN4〇〇. The monthly light stabilizer is preferably low in the test, and the test coefficient (Qing) is the above. Specifically, for example, a hindered amine compound or the like may be mentioned, and examples thereof include a succinic 5 leucovorin (2, 2, 6, 6-tetramethyl-4 _ ke) g|, azelaic acid double (2, 2, 6, 6 - tetramethyl-4-nitopic), 2_(3,5-di(tertiary butyl)-(tetra)benzylidenemalonic acid bis(1, 2,2,6,6-pentamethyl_4_ 咬 )) vinegar, 1 [2 [3-(3,5-di(tri-butyl)~4_hydroxyphenyl)propenyloxy] Ethyl] 4 [3 (3, 5-mono(tris-butyl-hydroxyphenyl)propoxycarbonyl 2,2,6-tetramethyl-methyl-decyl, azelaic acid double (1,2, 2, 6, 6-pentamethyl-4-indentyl) human one-yield methyl_1,2, 2, 6, pentamethyl-4_piperidinyl ester Compound (made by Chba-Geigy Co., Ltd., Japan, product name: τι·νΐΝ (Note 321209 36 201003942) 292), bis(1-octyloxy-2, 2, 6, 6-tetramethyl-4 -piperidinyl) azelaic acid g, TINUVIN 123 (registered trademark, manufactured by Ciba-Geigy Co., Ltd., Japan), etc. The radically polymerizable light stabilizer may, for example, be methacrylic acid 1,2, 2, 6, 6-pentamethyl-4-piperidinyl ester (made by ADEKA Co., Ltd., product name: ADK STAB LA82), acrylic acid 1,2, 2, 6, 6-pentamethyl-4_ϋ底π定酉, 曱基2, 2, 6, 6-tetramethyl-4-piperidyl acrylate (made by ADEKA Co., Ltd., product name: ADK STAB LA87), 2, 2, 6, 6-tetramethyl-4-piperidine acrylate Ester, 1,2, 2, 6, 6-pentamethyl-4-iminopiperidinyl methacrylate, 2, 2, 6, 6-tetramethyl-4-iminopiperidine methacrylate Ester, methyl acetoacetate 4-cyano-2, 2, 6, 6-tetramethyl-4-σ bottom decyl ester, mercapto acrylate acid 4-aryl-1, 2, 2, 6, 6-pentamethyl-4-σ bottom bite vinegar, etc. The light stabilizer is preferably TINUVINC registered trademark) 123. The emulsion polymerization in the present embodiment can be carried out by the following By making an addition polymerization using a thermal polymerization initiator and a reducing substance or the like by radical decomposition, the ethylene unsaturated monomer. As the above polymerization initiator for carrying out the emulsion polymerization, a water-soluble or oil-soluble persulfate, a peroxide, an azobis compound or the like can be used. Specific examples thereof include persulfate such as persulfate, sodium persulfate, and persulfate; peroxides such as hydrogen peroxide, tertiary butyl hydroperoxide, and butyl peroxybenzoate; , azo, such as 2-azobisisobutyronitrile, 2,2-azobis(2-diaminopropane) hydrochloride, 2,2-azobis(2,4-dimethylvaleronitrile) Double compound. It is preferred to use potassium persulfate, sodium persulfate or persulfate as a catalyst for promoting the hydrolysis reaction of the polyoxonium modifier 37 321209 201003942 and the reaction of the condensation reaction. The amount of the polymerization initiator is usually from 0.05% by mass to 1% by mass, based on the total mass of the ethylenically unsaturated monomer A and the ethylenically unsaturated monomer. In the present embodiment, the emulsion polymerization reaction is preferably carried out at a reaction temperature of 65 to 90 ° C under normal pressure, or may be carried out under high pressure in accordance with characteristics such as a vapor pressure at a reaction temperature of a monomer or the like. In the present embodiment, the reaction time of the emulsion polymerization is adjusted in accordance with the introduction time and the cooking time after the introduction. When various raw materials are simultaneously introduced into the reaction system, the introduction time is usually several minutes, and when various raw materials are sequentially introduced into the reaction system, various raw materials are introduced into the reaction system in a range in which heat generation due to polymerization can be removed. However, even if the introduction time differs depending on the polymer concentration in the latex finally obtained, it is usually 10 minutes or more. The cooked i ng time after introduction is preferably at least 10 minutes. Since the above-mentioned ripening time is 10 minutes or longer, it becomes a time sufficient for each raw material to react. Further, it may be made a time sufficient for the condensation to proceed after the polyoxo modifier is hydrolyzed. When it is desired to accelerate the polymerization rate and carry out the polymerization at a low temperature of 70 ° C or lower, a reducing agent such as sodium hydrogen sulfite, ferrous chloride, ascorbate, rongal i te, and a radical polymerization catalyst are used. Combination use is preferred. Further, in order to adjust the molecular weight of the polymer in the obtained polyfluorene-modified acrylic latex, a chain transfer agent such as a decyl mercaptan may be optionally added. 38 321209 201003942 In the polyfluorene-modified acrylic latex of the present embodiment, after the emulsion polymerization is completed, the following compound may be added to the high-endurance latex to prepare a polyfluorene-modified acrylic acid. A curing catalyst for forming a resin layer, for example, dibutyltin dilaurate, dioctyltin dilaurate, dibutyltin diacetate, tin octoate, tin laurate, iron octoate, lead octoate, titanate a metal salt of an organic acid such as butyl ester; an amine compound such as n-hexylamine or 1,8-diazabicyclo[5,4,0]-7-unde. When such a hardening catalyst is not water-soluble, it is preferred to use a surfactant and water in advance to emulsify it when using such a curing catalyst. In the polyfluorene-modified acrylic emulsion of the present embodiment, in order to maintain the long-term stable dispersion of the latex, an amine such as ammonia, water, sodium oxynitride, potassium oxynitride or dimethylaminoethanol is used to adjust A range of pH 5 to 10 is preferred. In the present embodiment, after completion of the emulsion polymerization, concentration may be carried out in order to evaporate and remove volatile substances, water, alcohol, and the like of the unreacted monomer. The average particle size of the dispersoid of the polyfluorene-modified acrylic latex in the present embodiment is preferably from 10 to 100 nm. Further, the mass ratio of the dispersing substance (solid content) in the obtained latex to the aqueous medium as the dispersing medium is preferably 70/30 or less, and more preferably 30/70 or more and 65/35 or less. In the polyfluorene-modified acrylic emulsion of the present embodiment, a film forming aid, a tackifier, an antifoaming agent, a pigment, a dispersing agent, a dye, a preservative, and the like can be optionally formulated. Specific examples of the above-mentioned film-forming auxiliary agent include: diethylene glycol monobutyl ether, 39 321209 201003942 ethylene glycol monobutyl ether, diethylene glycol diethyl ether, diethylene glycol dibutyl ether, ethylene glycol single 2-ethylhexyl hydrazine, 2,2,4-trimethyl-hydrazine, 3-butanediol isobutyric acid vinegar, diisopropyl glutarate, propylene glycol n-butyl ether, dipropylene glycol n-butyl _, tripropylene glycol Butyl ether, dipropylene glycol methyl ether, tripropylene glycol methyl ether, and the like. These film-forming aids may be formulated separately or in any combination. The method of applying the polyfluorene-modified acrylic latex in the present embodiment may, for example, be a method in which a polysulfide-modified acrylic latex is applied and dried. The resin film can be formed by the aforementioned method to produce a polysulfide-modified acryl resin layer. at this time. Preferably, the concentration of the coating liquid is preferably dried to be carried out between 15 and GC. The chyle coating method can be coated by a concave coating method, a wire bar coating method, an air knife coating method, a die coating method, a lip coat method, or a COmma coating method. Various methods such as cloth method perform the thickness of the polysulfide-modified acrylic resin layer in the present embodiment, preferably from 〇 to 〇〇 "m, preferably from 2 〇 δ Qn i to 90 _, The thickness of the polyacrylic acid-modified acrylic resin layer of 30 to 85 / /m is 1 〇 _ The battery can be transmitted to the sun with excellent environmental resistance such as durability and weather resistance. The thickness of the crushed oxygen-modified acrylic acid resin layer is broadly obtained in the drying process, and the coating film is less likely to produce a polysulfide-modified acrylic resin layer in the bovine powder. In the dry welding, the film is formed to improve the film formation. The film forming film [the solar cell back sheet] can be used. The solar cell back sheet of the present embodiment is formed by laminating the above-mentioned 321209 40 201003942 laminated body for a solar cell back sheet on a substrate. There is no limitation, but specifically, a layer of a vinylidene chloride-based resin layer is laminated on the substrate, and a polyfluorene-modified acrylic resin is laminated thereon. In the present embodiment, the vinylidene chloride-based resin layer and the polyoxo-modified acrylic resin layer are continuously laminated on the substrate (that is, laminated on the substrate). The vinylidene chloride-based resin layer is laminated on the polyfluorene-modified acrylic resin layer in a direct contact manner to protect the vinylidene chloride resin layer, and the gas barrier property is good. In addition, from the various characteristics of solar cell backsheet weather resistance, heat, moisture resistance, gas barrier properties, electrical insulation, physical strength, etc., a layer of vinylidene chloride is laminated on a plastic substrate. In the present embodiment, the base material is not particularly limited as long as it is a laminate for supporting a solar battery back sheet. It is preferable to use, for example, a plastic substrate. The plastic substrate used in the present embodiment is preferably a thermoplastic resin film which is a polycondensate belonging to a diacid acid derivative and a diol derivative. Polyester tree A lipid film is preferred. The above thermosetting resin film may be a polyethylene terephthalate, a poly(p-propyl phthalate), a polybutylene terephthalate or a polyethylene-2,6-naphthalene dicarboxylate. A polyester resin is preferably used by using a dicarboxylic acid component as a dicarboxylic acid component, using ethylene glycol as a diol component, and polymerizing by esterification reaction. Polyethylene terephthalate of crystalline thermoplastic resin 41 321209 201003942 =lipid: These resins may be a homo-resin or a copolymer or a conjugate. The melting point of the polyester used is in heat resistance. In view of the above, it is preferable to use the above, and it is preferable to use 30 or less in terms of productivity. =, heat resistance is difficult to make it have hydrolysis resistance to the high molecular weight in the range of the side. It is preferred to form a film and a shaft extending film. In order to have hydrolysis resistance, the above-mentioned number is better than the above, but from the viewpoints of polymerizability, melt formability, and biaxial stretching, it is preferred to use a number of resins. The number average molecular weight in the form of agglomeration == in the thousands of knives can be measured by the general use of the osmosis method (GPC) or the like. =& is the viewpoint of the appropriate dynamic strength, workability, and electrical insulation of the substrate of the solar cell backsheet. (4) The range of the substrate is preferably from 100 to 350 Å to the substrate. Various surface treatments can be applied, such as electro-electric treatment or atmospheric electroplating, followed by coating, and an ester-based or acesulfame-contacting agent can be used to find an adhesive. A cross-sectional view showing an example of a solar cell backsheet for a solar cell backsheet according to an embodiment of the present invention. The solar battery back sheet of this embodiment will be described using Fig. 1 . The tampering of the first embodiment of the solar cell backsheet comprising the vinylidene chloride-based resin layer 4 and the poly-tantalum layer 5 has a structure as follows: the adhesive 3 透过Vinyl resin layer 4 and polyfluorene modified acrylic resin 321209 42 201003942 Layer 5 is on plastic substrate 2. Fig. 2 is a cross-sectional view showing an example of a solar battery module including a solar battery back plate of the embodiment. The solar cell module of this embodiment will be described using Fig. 2 . As shown in FIG. 2, an example of the solar battery module 6 including the solar battery back plate 1 may be, for example, a solar battery element 8 and a filling between the glass layer 7 that receives sunlight and the solar battery back plate 1. The structure of the material 9 is made. Here, the mounting direction of the back sheet is not particularly limited, but from the viewpoint of weather resistance and moisture resistance, it is preferable to use the polyfluorene-modified acrylic resin layer to the outside. When the plastic substrate layer is used as the outer side, it is preferable to provide a polyfluorene-modified acrylic resin layer on the non-layer of the plastic substrate. In this case, in order to increase the adhesion between the surface of the plastic substrate and the surface of the polyoxygen-modified acrylic resin, it is preferred to carry out the easy treatment of the surface of the plastic substrate by corona discharge treatment or the like. The solar battery back sheet of the present embodiment is provided with a laminate for a solar cell back sheet having a vinylidene chloride-based resin layer and a polyfluorene-modified acrylic resin layer laminated on the vinylidene chloride-based resin layer. It can withstand a long time in a harsh natural environment, especially in terms of hydrolysis resistance, weatherability, heat resistance, moisture resistance, gas barrier properties, electrical insulation properties, physical strength, etc. Moreover, the simplification of the constitution of the components and the productivity of the workability are also excellent. When the polyfluorene-modified acrylic resin layer is laminated on the vinylidene chloride-based resin layer in the form of direct contact, the above effect is particularly remarkable in the case of 43321209 201003942. Further, n can be tolerated by the solar cell having the solar cell back sheet and the 杈 group. #电池 Η + ^ "Speciality in the natural environment == Weather resistance, environmental resistance, heat resistance, moisture resistance, gas earlyness, electrical insulation, and material strength. In the following, the embodiment will be described more specifically by way of examples, and the embodiments are not limited to the embodiments. - The following "target", unless otherwise specified, means "parts by mass [reference example] 'below' means vinylidene chloride latex, vinylidene oxide varnish, polyfluorene-modified acrylic acid The manufacturing example of the latex and the manufacturing method of the acrylic emulsion for comparison are exemplified as reference examples. (Preferred vinyl chloride latex) (Reference example 1) Withstand pressure applied to glass lining In the reactor, 100 parts of ion-exchanged water, 1 part of sodium alkyl sulphate, and 9 parts of sodium persulfate were charged, and the temperature of the contents was maintained at 5 〇r after degassing. 5份后。 After the methacrylonitrile 〇. 4 parts and methacrylic acid 0. 5 parts after the methacrylic acid was added to the above-mentioned pressure-resistant reactor. The first monomer mixture was charged with 3 parts, and then the residual monomer mixture was continuously added in a period of 16 hours, and the residual monomer mixture was continuously added in 96. 1 part. At this time, 321209 44 201003942 was also continuously added with the monomer. After adding the total amount of the monomer mixture, the internal pressure immediately begins to decrease, and the reaction is straight. 1份份。 I. The portion of the ion-exchanged water was charged with 100 parts of sodium sulphate. 5份,曱 曱 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 1.4 After mixing and mixing, a monomer mixture was prepared. After adding 0.5 part of acrylonitrile and 0.6 part of acrylic acid in the pressure-resistant reactor, 3 parts of the above monomer mixture was charged, and then the residual amount was continuously added continuously for 16 hours. 9份份。 At this time, with the monomer is also continuously added 0.1 parts of sodium hydrogen sulfite. After adding the total amount of the monomer mixture, the internal pressure immediately begins to decrease, the reaction is carried out until the internal helium stops decreasing, and Partially dichloroethylene latex [B]. (Part 2 mouse B.) (Reference Example 3) 300 g of the aqueous dispersion of the vinylidene chloride latex [A] prepared in Reference Example 1 was mixed with a small amount of side by side. After being dropped into 1000 g of a 3% aqueous solution of calcium chloride heated to 60 ° C, it will be formed. The agglomerate was washed with water and dried to obtain a white powder. 50 g of the powder of the vinylidene chloride-based resin thus obtained was added to 500 g of a mixed solvent of tetrahydrofuran:nonylene=2:1, followed by stirring for 30 minutes. After the ethylene resin is completely dissolved, an amine ester-based adhesive is added (Mitsui 45 321209 201003942 匕 匕: 主 lac (registered trademark) A511 主 A50" = l〇 / 1) L5g, Stir for 5 minutes with dichloroethylene lacquer [C]. Each (Polysh Oxygen-modified Acrylic Latex) (Reference Example 4) In a reversing machine equipped with a scrambler, a reflux cooler, two dropping tanks, and a thermometer, 5 parts of water is supplied and " 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 。 After the addition of 5 minutes, the step (1) is to mix the methacrylate methacrylate 3. 378 parts, cyclohexyl methacrylate 14. 5 parts, methyl group by a homomixer (h(10) 〇mixer) for 5 minutes. N-butyl acrylate 1-5. 5 parts, 14 parts of butyl acrylate, yttrium methacrylate. 622 parts, rTINUVi N384" (registered trademark 'Japan Ciba-Geigy Co., Ltd.); [. 2 parts, "TINUVIN123" (registered trademark , Japan Ciba-Geigy Co., Ltd.) 0·6 copies, "AQUALON KH-10" 3 copies, "EMULGEN 120" (registered trademark, Kao Co., Ltd., 20% aqueous solution) 2 parts, ammonium persulfate 2 6 parts of water, 2.62 parts of water, 26.2 parts of emulsion, and r-mercapto propylene oxime 0.578 parts of propyltrimethoxy decane, methyltrimethoxy decane 2.111 parts of 'dimercaptodimethoxy decane 3 · 378 parts of a mixture of 'from each individual drop into the tank took 9 〇 Drop into the reaction vessel for a minute. Maintain the temperature of the reaction vessel at 8 (TC3 () minutes, then proceed to step 46 321209 201003942 (2) 'The system will be 5.2 parts by means of a homomixer, methacrylic acid ring = Mixing 0.4 parts of methyl methacrylate formic acid for 4 minutes, part of methyl methacrylate, 7 parts of n-butyl methacrylate, 2-methyl methacrylate: bismuth diacetate · 5 parts, bismuth acrylate · 5 parts , KH-10"〇. 6 parts, sulphuric acid, 2, acrylamide oxime, 2 parts, "AQUal 〇 N made of the emulsion from the drip tank 1 aqueous solution, water 14.6 parts and the reaction container The temperature is maintained at '^ still drip into the reaction vessel. (3), which will be mixed by a uniform machine for 30 minutes, then step 6. 822 parts, thioglycolic acid cyclohexane 3 parts, "1,9 parts, 10. The n-butyl methacrylate than 2% aqueous solution of ammonium sulfate 1 g <8 parts, and the water is 14.6 parts by the r-methyl propyl group, the methyl trimethoxy decane 1267 methyl group and the decanoic acid 0. 378 parts, "TINUVIN 384" AQUALONKH-10". A mixture of emulsified 1 & propyl propyl trimethoxy decane 0.138. 022 parts was prepared, and the dimethyl dimethoxy group was dropped into the reaction vessel. 2 Other drops into the tank take 60 minutes to maintain the reaction valley temperature at temperature. The result of measuring the hydrogen ion concentration was cooled to room temperature after Μ minutes and adjusted to pH 8.5 to obtain a polyvalent change = .3. Add 25% aqueous solution (Reference Example 5) ^ Acrylic latex [a] In the installation of a blender, seven deadness - suppression of reflux, but also two drops into the tank and thermometer heart valley mouth 0 and then into the water 59_ 5 copies and "ADEKA REASOAP SR-10N" 32 parts of 'America's aqueous solution" manufactured by UDMA Co., Ltd., and the reaction volume was maintained at 5 parts of a 2% aqueous solution of ammonium persulfate. 47 321209 201003942 After 5 minutes of addition, step (1) will be mixed with methyl methacrylate u.375 #, 5 parts of cyclohexyl methacrylate, n-butyl methacrylate by a homomixer for 5 minutes. 17. 5 parts, 1.5 parts of 2-ethylhexyl acrylate, 625 parts of yttrium acrylate, 2 parts of "ADEKA REASOAP SR-10N", 2 parts of "EMULGEN 120", 2% aqueous solution of ammonium persulfate 1. 25 An emulsion prepared by making a solution of 30.1 parts of water, and 778 parts of 7-methacryloxypropyl decyloxydecane oxime, methyl decyloxy decane 2. ill part, dimethyl 2 A mixture of 3.878 parts of methoxydecane was dropped into the reaction vessel from the individual dropping tanks for 90 minutes. The reaction vessel temperature is maintained at 8 Torr for 3 minutes, and then the step (2) is carried out. [1] styrene 1 part, methacrylate 7.8, methacrylic acid ring is mixed by a homomixer for 5 minutes. 2 parts of hexyl ester, 7 parts of n-butyl methacrylate, 2 parts of ethyl hexyl acrylate, 5 parts of decyl acrylate, 0.5 parts of acrylic acid, acrylamide oxime. 2 parts, r ADEKA REAS〇 5 parts, 2% aqueous solution of ammonium persulfate Q. 5 parts, water 19.2 The emulsion prepared was dropped into the reaction vessel for 45 minutes from the time of dropping into the tank. Once the temperature of the reaction vessel was maintained at 8 ° C for 3 minutes, then step (3) was carried out by mixing 14.7 parts of methyl methacrylate, cyclohexyl methacrylate, by a homomixer for 5 minutes. 3 parts, n-butyl methacrylate 1〇5 parts, 2-ethylhexyl acrylate 丨. 425 parts 375 parts of 'acrylic acid 、, 'τι·ι_ο ι 份, 'TINUViN123' Q. 5 parts, ADEKAms〇 Ap SR-10N"0. 6 parts, 2% aqueous solution of ammonium persulfate Q. 75 parts, water 2l8. 3 wounds made of liquefied liquid, and 7 _ methacryloxypropyl propyl 321209 48 201003942 A mixture of 138 parts of oxydecane, 1.267 parts of methyltrimethoxydecane, and 0.02 parts of dimethyldimethoxydecane, respectively, was dropped into the reaction from an individual dropping tank for 60 minutes. In the container. The temperature of the reaction vessel was maintained at 80 ° C for 90 minutes and then cooled to room temperature. 4。 The hydrogen ion concentration was measured as a pH of 2. 4. The addition of a 25% aqueous ammonia solution was adjusted to ρ Ή 8.5 to obtain a polyfluorene-modified acrylic latex [b]. (Cang test example 6) In a reaction vessel equipped with a stirrer, a reflux condenser, two dropping tanks, and a thermometer, 50. 8 parts of water and "Newcol 707SF" (made by Japan Emulsifier Co., Ltd., 30% aqueous solution) 5份。 2 parts of a 2% aqueous solution of ammonium persulfate was added. After the addition of 5 minutes, the step (1) is to mix 3.875 parts of methacrylate, 25 parts of cyclohexyl methacrylate, 2 parts of butyl acrylate, and 5 parts of butyl acrylate by a homomixer for 5 minutes. 5份。 The emulsion of 0. 6 2 5 parts, "Newcol 707SF" 2. 5 parts, "EMULGEN 120" 2 parts, 2% aqueous solution of ammonium persulfate 2. 5 parts, water 24. 5 parts And a mixture of 0.353 parts of r_methacryloxypropyltrimethoxydecane, 1.277 parts of methyltrimethoxydecane, and 038 parts of dimethyldimethoxydecane, respectively It was dropped into the reaction vessel from an individual dropping tank for 90 minutes. The reaction vessel temperature was maintained at 80 ° C for 30 minutes, and then the step (2) was carried out by mixing a mixture of 4,37 parts of decyl methacrylate and 10 parts of cyclohexyl methacrylate by a homomixer for 5 minutes. 0.1 parts, n-butyl methacrylate 2. 33 parts, methacrylic acid 0.5 parts, acrylic acid 0. 5 49 321209 201003942 parts, 2-hydroxyethyl methacrylate 2 parts, acrylamide 0.2 parts, 1 part of "Newco 170 7SF", 1 part of 2% aqueous solution of ammonium persulfate, and 14.4 parts of water were added to the reaction container for 45 minutes from the time of dropping into the tank. The reaction vessel temperature was maintained at 80 ° C for 30 minutes, and then the step (3) was carried out by mixing the decyl decyl acrylate in a uniform mixer for 5 minutes. 3.15 parts, methacrylic acid cyclohexanoic acid 15 parts, butyl acrylate I 10.86 parts, methacrylic acid 0. 375 parts, 2-hydroxyethyl methacrylate 0. 6 parts, "TINUVIN123" 0. 49 parts, "Newcol707SF" 1 part, "AQUAL0N KH-10"0. 24 parts, 2% aqueous solution of ammonium persulfate 1. 5 parts, water 15.2 parts of the emulsion, and 0.084 parts of mercapto propylene methoxy propyl trimethoxy decane A mixed liquid of 0.761 parts of mercaptotrimethoxy decane and 1.223 parts of dimercaptodimethoxydecane was dropped into the reaction vessel from an individual dropping tank for 60 minutes. The temperature of the reaction vessel was maintained at 80 ° C for 90 minutes and then cooled to room temperature. 5。 The result of the determination of the hydrogen ion concentration is pH2.3. The addition of a 25% aqueous ammonia solution was adjusted to pH 8.5 to obtain a polyfluorene-modified acrylic latex [c]. (Reference Example 7) In a reaction vessel equipped with a stirrer, a reflux condenser, two dropping tanks, and a thermometer, 59.6 parts of water and 3 parts of "ADEKA REASOAP SR-10N" were added, and the temperature of the reaction vessel was measured. 5份。 2% aqueous solution of ammonium persulfate was added to 1. 5 parts. After 5 minutes of addition, step (1) will be mixed with decyl methacrylate by a homomixer for 5 minutes, 11.381 parts, cyclohexyl methacrylate 5 50 321209 201003942 parts, n-butyl methacrylate 17 parts, 1.5 parts of 2-ethylhexyl acrylate, 619 parts of acrylic acid, 2 parts of "ADEKA REASOAP SR-10N", 2 parts of "EMULGEN 120", 2% aqueous solution of ammonium persulfate 1. π An emulsion prepared by making a solution of water and water in an amount of 30,000 parts, and a mixture of 0.4 parts of methyl trimethoxy zexiyuan and 685 parts of dimethyldimethoxy styrene, respectively, from individual Dropping into the tank takes 90 minutes to drip into the reaction and cry. The temperature of the reaction vessel was maintained at 80. 〇30 scores; ^Step (2), which will be used to separate styrene i parts, 7.8 parts of methyl methacrylate, and 2 parts of methyl propyl acrylate by 5 minutes in a homogenous mixer. 7 parts of methyl (tetra) acid n-butyl vinegar, 2 - ethyl hexanoic acid acrylate, 5 parts of methyl propyl ketone, 0.5 part of propyl (tetra), 0.2 丙 丙 汾 汾 汾 汾 汾 「 REA REA REA REA REA - - REA The emulsion was made up of 0.4 parts, 2% of ammonium persulfate, 5 parts of water, and 19.2 parts of water. The emulsion was dripped into the reaction vessel from the dropping tank (4) for 45 minutes. The reaction vessel temperature was maintained at 8crc 3〇, and then step (3) was carried out, which was carried out by a homomixer for 5 minutes, U. 7 parts of methyl methacrylate, 3 parts of cyclohexyl methacrylate, methyl 1 〇 5 parts of n-butyl lactate, 425 parts of 2-ethylhexanoic acid acrylate, 缚 ΟΙ 、, τ·TM· 』, "TINUVIN123" Q 5^, "following κΑ··ρ SR- 10N"0·6 injury, 2% aqueous solution of sulphuric acid money 〇 π parts, water 218.3 parts of liquid 'and finer than methyl trimethoxide. The mixture of bird and 2 burned U9 was dropped into the reaction vessel from the individual dropping tank for 60 minutes. The temperature of the reaction vessel was maintained at 9 〇, and then cooled to the chamber 321209 51 201003942 (Reference Example 8) In the presence of a drop machine, a reflux cooler, two dropping tanks, and a thermometer.份 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 164 9 parts of dilute acid hexane vinegar, 3 parts of methyl propylene glycol n-butyl vinegar 'H5 parts of propyl benzoate, 〇. 6 parts of methacrylate, AQUALON ΚΗ-1 〇" 8, 8 parts, "_LGEN 丨 2 〇" 3 parts, 34. 4 parts of water, an emulsion prepared, and 7-methyl-methoxypropyl trimethoxy decane 0. 583 parts of 'mercaptotrimethoxydecane 33. 52 parts, dimethyl 2曱 石 夕 夕 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 21 The temperature of the reaction vessel was maintained at 耽, and after adding 4·5 parts of a 2% aqueous solution of sulphur, the temperature of the reaction vessel was adjusted to 80 Torr over 60 minutes. The reaction temperature was maintained at 8 (TC, and then step (2) was carried out by mixing 22.5 parts of methyl methacrylate, 21 parts of f-based cyclohexyl acrylate, methyl propyl group by a homomixer for 5 minutes. 7 parts of n-butyl vinegar, 13 parts of butyl acrylate, 2 parts of methacrylate 2. 14 parts of acrylic acid, 2 parts of 2-hydroxyethyl methacrylate, 2 parts of acrylamide, 2 parts, "TINUVIN400" 1 part, "TINUVIN123" 0.5 parts, "AQUALON KH-10" 3. 2 parts, "EMULGEN 120" 2 parts, 45. 1 part of water to make an emulsion, and methacryloxylate Composition of 1,3-trimethoxydecane 〇. 133 parts, methyl dimethoxy decane 22. 346 parts, dimethyl dimethoxy decane 14. 282 parts, phenyl dimethyl methoxy smelting 3. 371 parts The mixture was dropped into the reaction vessel from a temperature of 321209 201003942 and dropped into the tank for 90 minutes. The temperature of the reaction vessel was maintained at 80 ° C for 90 minutes, and then cooled to room temperature. The result of measuring the hydrogen ion concentration was pH 2 7. After adding 25% ammonia solution to the above mixture and adjusting to pHIO, the mixture is returned to the reverse of decompression. The container was heated at 80 ° C for 3 hours. Then, after adding an appropriate amount of antifoaming agent, the inside of the container was depressurized to 40 kPa, and concentrated until the solid content became 45%. After cooling to room temperature, the hydrogen ion concentration was measured. The result was pH 7.9. Thereafter, the pH was adjusted to 8.5 by adding a 25% aqueous ammonia solution to obtain a polyfluorene-modified acrylic latex [e]. (Reference Example 9) A mixer, a reflux cooler, and 2 were installed. 1 part of the reaction vessel which was dropped into the tank and the thermometer, and water was added in an amount of 97.5 parts of "AQUALON HS-10" (registered trademark, 25% aqueous solution manufactured by Daiichi Kogyo Co., Ltd.), and the temperature of the reaction vessel was maintained. 5份, After mixing 5 minutes, the methyl methacrylate was mixed by a homomixer for 5 minutes, and the mixture was mixed for 5 minutes. 11 parts of n-butyl methacrylate, 20. 1 part of butyl acrylate, 0.6 parts of propionic acid, "TINUVIN400" 3. 5 parts, "TINUVIN123" 1 · 75 parts, "AQUALON HS-10" 6. 4 5 parts, "EMULGEN 120" 2 parts, 2% aqueous solution of persulfate, 2. 5 parts, water 76. 4 parts, emulsified And 0.537 parts of 7"-mercapto acryloxypropyltrimethoxy decane, 54.825 parts of decyltrimethoxydecane, 21.9 parts of dimethyl decyloxydecane, diphenyldioxan A mixture of 5.55 parts of decane was dropped into 53 321 209 201003942 from the individual dropping tanks to the reaction vessel for 90 minutes. The reaction vessel temperature was maintained at 8 (rc for 30 minutes, and then step (2) was carried out by mixing 7 parts of methyl methacrylate, 7 parts of methyl methacrylate, and methyl propyl by a homomixer for 5 minutes. N-butyl succinate & 9 parts, 1.5 parts of methacrylic acid, 4 parts of acrylonitrile, 1 part of 2-hydroxyethyl methacrylate, 2 parts of acrylamide, 4 parts of "AQUALON HS-10" An emulsion prepared by dissolving 1 part of a 2% aqueous solution of disulfate and 3 parts of water was dropped into the reaction vessel from the dropwise addition of L to the tank for 45 minutes. The temperature of the reaction vessel was maintained at 8 (rc 3 〇 minutes, and then the steps were carried out. (3) 'These will be mixed with 10.4 parts of methyl methacrylate, 5 parts of methyl propyl acetoacetate, and 6 parts of methyl propyl acetonate by a uniform mixer for 5 minutes. 0.5 parts of bupropion acid, 15 parts of "TIN_shed", "tin_i23" 〇·75 wound AQUALON HS-10"〇3 parts, 1.5 parts of 2% aqueous solution of persulfate, 36.4 parts of water, and the emulsion was prepared. And oxypropyltrimethoxyweitrixethane decane 18. 275 parts, dimethyldimethoxydecane 7.3 parts, diphenyldimethoxy shixi 1·85 The resulting mixture was dropped into the reaction vessel from the individual dropping tanks for 60 minutes. The temperature of the reaction vessel was maintained at 80 t for 90 minutes, and then cooled to room temperature. The result of hydrogen ion concentration was determined to be pH 2.6. Adding a 25% aqueous ammonia solution to the above mixture to adjust to pH 1 () |, and then returning the mixed solution to a pressure in the reaction vessel and heating at 80 t for 3 hours. Then, after adding an appropriate amount of antifoaming agent 'The inside of the container was reduced by 40 kPa, and concentrated until the solid W knife became 45%. After cooling to room temperature, the hydrogen ion concentration was measured to be 321209 54 201003942. The result was pH 8.0. After that, the pH was adjusted to 8 by adding a 25% ammonia solution. 5, and obtained a poly-oxygen-modified acrylic latex [f ]. (Reference Example 1) In a reaction vessel equipped with a stirrer, a reflux condenser, a dropping tank, and a thermometer, 100 parts of water and dodecane were charged. 5 parts of sodium benzenesulfonate, and the temperature of the reaction vessel was maintained at 85 ° C. Then, the "dimethyl ring" (3 condensed of cyclic dimethyl methoxy olefin oligomer) was homogenized by a homomixer. Mixture of material to 7-polymer) 85 parts, r-mercaptopropene oxime 15 parts of oxypropyltrimethoxydecane, sodium decyl benzoate, and a mixture of 7 parts of water and 300 parts of water are premixed, and then cut by a homogenizer at a pressure of 350 kg/cm2. The polyfluorene emulsified liquid was prepared, and the polyxyloxy emulsified liquid was dropped into the reaction container from the time of dropping into the tank for 3 hours. After the completion of the dropwise addition, the mixture was further heated at 85 ° C for 1 hour, and then cooled to room temperature. The mixture was neutralized with an aqueous solution of sodium hydroxide to obtain a polysulfide latex. Then, 62 parts of the polyoxyl latex, "LAMUTELS-180A" (registered trademark, manufactured by Kao Co., Ltd., 20% aqueous solution) was used. After 85 parts of water was placed in another reaction vessel and the temperature was raised to 70 ° C, 3 parts of a 2% aqueous solution of ammonium persulfate was added. After 5 minutes of addition, 32 parts of methyl methacrylate, 30 parts of n-butyl methacrylate, 23 parts of 2-ethylhexyl acrylate, and 10 parts of 2-hydroxyethyl methacrylate were added dropwise over 4 hours. 3 parts of diacetone acrylamide, 2 parts of methacrylic acid, 2 parts of τ-methacryloxypropyltrimethoxy decane, 0.5 parts of "TINUVIN400", and 0.2 parts of "TINUVIN123". The temperature was adjusted to 8.5, and the pH was adjusted to 8.5, and the pH was adjusted to 8.5, and the pH was adjusted to 8.5, and the pH was adjusted to 8.5, and the pH was adjusted to 8.5, to obtain a pH of 8.5. Polyfluorene modified acrylic latex [g]. (Reference Example 11) In a reaction vessel equipped with a stirrer, a reflux condenser, a dropping tank, and a thermometer, 70 parts of water, "ADEKAREASOAPSE-1025A" (made by Adeka Co., Ltd., 25% aqueous solution), 0.8 parts, The temperature of the reaction vessel was maintained at 80 ° C, and 15 parts of a 2% aqueous solution of ammonium persulfate was added. After 5 minutes of addition, the step (1) is to mix 25 parts of methyl methacrylate, 40 parts of cyclohexyl methacrylate, 15 parts of butyl acrylate, and propylene by a homomixer for 5 minutes. 2 parts of acid 2-ethylhexene, 2 parts of 2-hydroxyethyl thioglycolate, 3 parts of acrylic acid, 0.5 parts of "TINUVIN400", 0.2 parts of "TINUVIN123", "ADEKA REASOAP SE-1025A" The emulsion prepared by making 4 parts of water and 30 parts of water was dropped into the reaction container 3 hours from the time of dropping into the tank. Thereafter, the temperature of the reaction vessel was raised to 90 ° C for 2 hours, then cooled to room temperature, and adjusted to pH 7 by adding a 25% aqueous ammonia solution. Then proceeding to step (2), adding 1 part of r-glycidoxypropyl decyloxy fluorenyl sulphate, 7-glycidoxy propyl diethoxylate from 2 parts, strong Stir for 1 hour. Then, 6 parts of methyltriethoxydecane and 2 parts of tetraethoxydecane were added, and the mixture was heated to 70 ° C and stirred for 3 hours to carry out polycondensation. Thereafter, the mixture was cooled to room temperature to obtain a polyfluorene-modified acrylic latex [h]. (Reference Example 12) In a container equipped with a mixer, a reflux cooler, a drip tank, and a thermometer, the water is supplied in a container of 77. 7 parts and "ADEKA REASOAP SR-10N" 2. 4 parts, "EMULGEN" After 1 part of 1108S" (registered trademark, 25% aqueous solution of Kao Co., Ltd.) and 1 part of stupid ethylene, the reaction vessel was heated to 70 V. Step (1) is to mix 21.9 parts of methyl propyl methyl acrylate, 1 part by weight of cyclohexyl methacrylate, 1.5 parts of 2-ethylhexyl acrylate, acrylic acid by a homomixer for 5 minutes. 1. 1 part, "ADEKA REASOAP SR-10N" 1. 8 parts, "EMULGEN 1108S" 1. 8 parts, and 17.3 parts of water, 14.1 parts of the emulsion was put into the reaction vessel from the dropping tank. After the addition, a 5% aqueous solution of a potassium persulfate aqueous solution was added to a solution of 4.2 parts, and the temperature of the reaction vessel was raised to 80 ° C for 15 minutes, followed by a reaction at 80 ° C for 30 minutes. The remaining emulsion was then kept at 80 ° C and dropped into the reaction vessel over a period of 80 minutes from the time of dropping into the tank. It was also maintained at 8〇 after instillation.匸 minutes, and add 2 05% aqueous ammonia solution 1. 05 parts, and then maintain for 1 〇. Then, 'Step (2) will be mixed with a methyl group by a homomixer for 5 minutes (25 parts of 5% of methyl methacrylate, 1 part of methacrylic acid, 1 2 of acrylic acid) 5 parts, 0.5 parts of "ADK STAB LA82" (made by ADEKA CORPORATION), 5 parts of r-methacryloxypropyltrimethoxydecane oxime, and "ADEKA REASOAP SR-10N" 1.8 The emulsion prepared in 1.8 parts of "EMULGEN 1108S" and 17.3 parts of water was dropped into the reaction vessel at 8 minutes from the time of dropping into the tank. It was also maintained at 80 ° C for 60 minutes after the dropwise addition. Thereafter, the mixture was cooled to room temperature to obtain a polyfluorene-modified acrylic latex [i]. (Reference Example 13) 321209 57 201003942 In a reaction vessel having a blender, a reflux condenser, a dropping tank, and a thermometer, water was introduced. 59.6份, "八0丑1^1^^0八?31^1〇]^"3.2 Injury, and the reaction temperature is maintained in the other. [, adding persulfate 2% aqueous solution 1. 5 parts. After 5 minutes of addition, the step (丨) was to mix 381 parts of methyl methacrylate, 5 parts of methyl propylene hexaacetate, propylene by a homomixer for 5 minutes. 17 parts of acid n-butyl vinegar, 15.5 parts of 2-ethylhexyl acrylate, 0.619 parts of acrylic acid, 2 parts of "ADEKA REASOAP SR-10N", 2 parts of "EMULGEN120", 2% aqueous solution of persulfate The emulsion prepared by making 30.0 parts of water was dropped into the reaction vessel from the time of dropping into the tank for 9 minutes. The temperature of the reaction vessel was maintained at 8 〇t 3 〇 minutes, and then the step (2) was carried out, which was mixed by the uniform sentence. The machine was mixed with styrene for 5 minutes, 7.8# for methyl propyl m, 2 parts of cyclohexyl methacrylate, methyl propylene = butyl 7 h, 1 part of acetoacetic acid 2-ethylhexanoic acid, Methyl acetoacetate 0· 5 77 propyl hydrazine 0·5 饧, acrylic acid 〇 2 parts, “ADEKA REAS0AP SIM (10)” 0·4 parts, persulfate recorded 2% aqueous solution Q·5 parts, water 19 2 = Made into a milk cut from the drop tank (four) 45 minutes drop to the reaction capacity. (3), : The temperature of the device is maintained at 8 ° ° C 3. Minutes, then proceed to step ^: worse by a uniform mixer for 5 minutes Methyl methacrylate. 7 parts: 3 parts of methyl hexaenoic acid cyclohexyl ester, n-butyl methacrylate 1 〇 5 propylene I 2 ethyl hexyl ester h 425 parts, propylene % abdomen (10)", "TI黯iN12 3"G.5 parts, "ship kareas; ap 321209 58 201003942 SR-ION" 0. 6 parts, 2% aqueous solution of ammonium persulfate 0. 75 parts, 218 parts of water, the emulsion prepared from the time of dripping into the tank It was dropped into the reaction vessel over 60 minutes. The temperature of the reaction vessel was maintained at 80 ° C for 90 minutes and then cooled to room temperature. 4。 The hydrogen ion concentration was measured as a pH of 2. 4. The acrylic latex was obtained by adding a 25% aqueous ammonia solution to pH 8.5. In this 100 parts of the acrylic latex, 2 parts of a poly-xyloxy latex "KM-785" (manufactured by Shin-Etsu Chemical Co., Ltd.) was blended to obtain a poly-xyloxy-modified acrylic latex [j]. (Acrylic Latex) (Reference Example 14) In a reaction vessel equipped with a stirrer, a reflux condenser, two dropping tanks, and a thermometer, 50. 8 parts of water and "AQUALON KH-10" (registered trademark, first 5份。 2 parts of a 2% aqueous solution of ammonium persulfate was added to the solution. After the addition, the step (1) is to mix methyl methacrylate 3. 378 parts, cyclohexyl methacrylate 14. 5 parts, n-butyl methacrylate 17.5 by a homomixer. , butyl acrylate 14 parts, methacrylic acid 0. 622 parts '"TINUVIN384" (registered trademark, made by Ciba-Geigy Co., Ltd., Japan) 1. 2 copies, "TINUVIN123" (registered trademark, Japan Ciba-Geigy limited shares Company's system) 0.6 parts, 3 parts of "AQUAL0N KH-10", "EMULGEN 120" (registered trademark, 20% aqueous solution made by Kao Co., Ltd.), 2 parts of 2% aqueous solution of ammonium persulfate, water 22 The 6 parts of the emulsion was dropped into the 59 321209 201003942 reaction vessel from the time of dropping into the tank for 90 minutes. The temperature of the reaction vessel was maintained at 8 (rc 3 〇 minutes, and then the step (2) was carried out. The mixture was mixed with methyl methacrylate vinegar by a homogenous hook mixer for 5 minutes. Ester "minute, n-butyl methacrylate", butyl glycerin _ G. 4 parts, Q 5 parts of methacrylic acid, Q 5 parts of acrylic acid, methacrylic acid S owes 2-carbyl ethyl ester oxime. 15 parts, 2 parts of acrylamide oxime, 0.6 parts of "eight training KH-10", 6 parts of water, 2% aqueous solution of sulphuric acid, and 4 parts of water sputum, and the emulsion prepared from the dropping into the tank is 45 minutes. The mixture was dropped into the reaction vessel. The temperature of the reaction vessel was maintained at 8 CTC for 30 minutes, and then the step (3) was carried out. [The mixture was then mixed with methyl methacrylate by a homomixer for 5 minutes. 6.822 parts, methacrylic acid ring 9 parts of hexyl ester, n-butyl methacrylate 〇. 5 parts, butyl acrylate 3. 3 parts, methacrylic acid 〇. 378 parts, "TINUVIN384" 0. 8 parts, "TINUVIN123" 〇. 4 copies, " AQUALON 0-10"0. 9 parts, 15 parts of a 2% aqueous solution of ammonium persulfate and 14.6 parts of water were added to the reaction container for 60 minutes from the time of dropping into the tank. The glutenic acid latex is obtained by the addition of a 25% aqueous ammonia solution for 3 weeks to ρΗ8. 5 to obtain an acrylic acid latex. The temperature is maintained at 8 Torr. [Let's] The following is a reference example of a method for producing a coating containing a polyfluorene-modified acrylic latex and a pigment. (Pigment paste) (Reference Example 15) A stainless steel container of 1 L. In the middle of the process, a dispersant (SN-Dispersant 5027/20%, manufactured by SANN0PC0) was added. 5g, 60 321209 201003942 propylene glycol 49g, water 310.42g, ammonia water (25%) lg, using a trinity motor (THREE ONE MOTOR) Stirring, and adding 60 g of titanium oxide (Tipure R-706) while stirring, and adding 6 g of an antifoaming agent (SND*~i31〇), and stirring for 30 minutes. In a stirred slurry, lkg is put. Broken bead (spherical beads of 1 mm in diameter), and 4 pieces of dispersing discs were attached to a batch type table sand mill manufactured by Kanpe Hapio Co., Ltd., and dispersed at 1490 rpm for 2 minutes to obtain a pigment concentration of 65. % of pigment paste [A]. (Reference Example 16) In addition to oxidation The pigment paste [B] was obtained in the same manner as in Reference Example 16 except that it was changed to the zinc oxide. (Reference Example 17) The same procedure as in Reference Example 15 except that the titanium oxide was changed to calcium carbonate (BRILLIANT 15). The method produces a pigment paste [C]. (enamel paint) (Reference 18)

In the poly-stone modified acrylic latex [a] (4% solids) 54. 35g of the 'one side of the side of the mixing agent to add a filming aid (butyl quercetin / water 5g after 'scrambled for 10 minutes. After adding 5 g of a film-forming auxiliary agent (manufactured by Ryuji / CHISS0 Co., Ltd.)), the mixture was further stirred for 1 minute. Thereafter, a pigment paste [A] (pigment concentration: 65%) of 25.64 g and ADEKA N0L UH_438 (10%) of 0.6 g were added for 5 minutes, followed by a bismuth coating [i] (pwc = 40%). (Reference Example 19) 61 321209 201003942 In addition to changing the pigment paste to [B], an antimony coating [2] was obtained in the same manner as in Test Example 18. (Reference Example 20) - An anthraquinone coating [3] was obtained in the same manner as in Reference Example 18 except that the pigment paste was changed to [C]. Using the polyvinylidene chloride latex [Α], [β] and vinylidene chloride varnish [C] obtained in Reference Examples 1 to 3, and the polyfluorene modified latex [a] to [as obtained in Reference Example 4] k], the bead coatings (1) to [3] obtained in Reference Examples 18 to 2Q were fabricated as described below. In addition, the solar cell module is fabricated using the solar cell backsheet. (Example 1) Coating on the side of the hydrolysis resistance «LumirrQr (10) (registered by I., TORAY Co., Ltd., thickness: 188/m) using a concave (four) cloth machine, coating amount W (4) followed by Agent (TAKELAC (registered trademark) A5U) manufactured by Mitsui Takeda Chemical Co., Ltd.: Agent "A50" = 1〇/1). Then, the vinylidene chloride latex [A] was applied by using an air knife coater so that the thickness of the vinylidene chloride-based resin layer became 11 mA. After a aging at 40 C for 48 hours, the thickness of the poly- oxy-modified acrylic resin layer of the poly- yttrium-oxygen-modified acrylic resin layer was changed to 54 Å to obtain a ruthenium-modified acrylic latex [a]. "The solar energy of the surface is not covered by the solar energy. Then, the glass layer of the surface that is exposed to the sunlight is used on the inner surface of the solar cell, and the tree is copolymerized with ethylene-vinyl acetate; 3^12〇 9 62 201003942 "SOLAR EVA" (manufactured by Mitsui Chemicals Fabro Co., Ltd.) is used as a filler to sandwich a solar cell element, and a solar cell module using a solar cell back plate as shown in Fig. 2 is obtained. (Example 2) A solar cell backsheet and a solar cell module were produced in the same manner as in Example 1 except that the thickness of the vinylidene chloride-based resin layer was 25 em. (Example 3) A solar cell back sheet and a solar cell module were produced in the same manner as in Example 1 except that the thickness of the polyfluorene-modified acrylic resin layer was 81 km. . (Example 4) A solar cell backsheet and a solar cell module were produced in the same manner as in Example 1 except that the polyfluorene-modified acrylic latex was changed to [b]. (Example 5) A solar cell backsheet and a solar cell module were produced in the same manner as in Example 1 except that the polyfluorene-modified acrylic latex was changed to [c]. (Example 6) A solar cell back sheet was obtained in the same manner as in Example 1 except that the vinylidene chloride latex was changed to [B] and the polyfluorene-modified acrylic latex was changed to [d]. With solar battery modules. (Example 7) 63 321209 201003942 Except that the vinylidene chloride latex was changed to [B], and the polydecene s text was more than [e], the other was made with the snail The domain battery is unique. ^Method (Example 8) In addition to changing the vinylidene chloride latex to [B], and changing the poly-thick acid-based latex to "f 1 ice-divided, the syllabus and the syllabus The method of dressing is too much battery back panel and solar cell module. (Example 9) In addition to changing the vinylidene chloride latex to [B], and the polyethylenic latex is arguing ” M bucket / milk modified shell C was made too much in the same manner as in Example 1 to cover the battery back plate and the solar cell module. (Example 1 〇) In addition to changing the vinylidene ethylene latex to [β] and changing the polythanoic acid latex to [h], the solar cell t-plate and solar power were prepared in the same manner as in the second embodiment. Domain group. "^ (Example 11) except that the vinylidene chloride latex was changed to [B], and the olefinic latex was very similar to "1, and the e-propene was less than [1], The solar cell backsheet and the solar cell module were planted in the same manner as in Example 1. (Example 12) In addition to the use of the polyester film "C〇SM〇SHINEA41〇〇" (Toyo Textiles Co., Ltd. limited t system) The solar cell backsheet and the solar cell module were obtained in the same manner as in Example 1 except that the thickness of the 188_) was changed to [Phosphorus]. 64 3212〇9 201003942 (Example 13) In addition to the modification of polyoxygenation, the solar cell module of the embodiment was used. (Example 14) In addition to the modification of polysulfide, the solar cell module of the example was used. (Example 15) In addition to the modification of polysulfide, the solar cell module of the example was used. (Example 16) The acrylic emulsion was changed to the enamel coating (1). 1 The same method as in the method of loosening the solar battery back sheet and the acrylic emulsion to the 珐 [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ [ The latex was changed to the enamel coating [3] 1 The same method was used to obtain a solar cell back sheet and a hydrolysis-resistant polyester film "Lumlrrc" r (10)" (registered trademark, manufactured by KK Co., Ltd., thickness i δδ V m), using a bar coating The cloth machine was maintained at 120 after applying the vinylidene chloride varnish [C] so that the thickness of the vinylidene chloride-based resin layer became 5/zm. Dry in an oven for 6 seconds. After 4 hours of TC aging, the poly-xyloxy-modified acrylic latex [a] was applied by using a die coater so that the thickness of the polyfluorene-modified acrylic resin layer was 54/zm. A solar cell back sheet having the same structure as the solar cell back sheet of Fig. 1 is obtained except for the feature of no adhesive layer. Next, the glass layer of the surface irradiated with sunlight and the solar cell back sheet are used for The inner surface of the battery is made of ethylene-vinyl acetate copolymer resin 321209 65 201003942 "SOLAR EVA" (manufactured by Mitsui Chemicals Fabro Co., Ltd.) as a filler and a solar cell element, and the solar cell using the solar cell shown in Fig. 2 is obtained. Module. (Comparative Example 1)

Lumirror XIOS is a hydrolyzable polyester film ________ ^ _ 'a registered trademark, T0RAY Co., Ltd., thickness 188 / / m) side, using a gravure coater with a coating amount of 5g / m2 coated amine g The following agent (TAKELAC (registered trademark) A5 i ι" manufactured by Mitsui Takeda Chemical Co., Ltd. / Hard: "A50" = 1 〇 / 1). θ Then, using a gas knife coater to apply a partial ethylene oxide latex [B] in such a manner that the thickness of the vinylidene chloride-based resin layer becomes 10 mm, a battery back sheet is obtained. Then, a solar cell module was produced in the same manner as in Example 1. (Comparative Example 2) On the side of the hydrolysis-resistant polyester film rLumimr xl〇s" (registered trademark, manufactured by T0RAY Co., Ltd., thickness 1δ8_), the coating was applied with a coating amount W. Agent (TAKELAC (registered trademark) Α 5 "Α50" = 10/1), the main ingredient of Mitsui Takeda Chemical Co., Ltd. Then, a silicone coating backing plate was obtained by coating a poly-modified acrylic-based latex Lb with a die coater so that the thickness of the polysulfide-modified acrylic resin was 52. Turtle and, with the embodiment! The solar cell module is also produced. (Comparative Example 3) 321209 66 201003942 On a side of a high weathering fluororesin film (manufactured by Du Pont, registered trademark "Ted 1 ar" 'thickness 50 // m), a gravure coater was used at a coating amount of 5 g/m 2 A coating of an amine ester-based adhesive (TAKELAC (registered trademark) A511, manufactured by Mitsui Takeda Chemical Co., Ltd.) and a curing agent "A50" = 10/1), and a thickness of 20/1 was laminated through the adhesive layer. After the aluminum foil of zm, the amine ester-based adhesive is applied in the same manner to the same aluminum foil, and the high-pair fluororesin film ("Tedlar", thickness 50 // m) is laminated and laminated to obtain a fluororesin film. / The solar cell back sheet consisting of three layers of foil/fluororesin film. Then, a solar cell module was produced in the same manner as in Example 1. (Comparative Example 4) One side of the lyophilic polyester film "Lumirror X10S" (registered trademark, manufactured by T0RAY Co., Ltd., thickness: 6 〇em) was coated with a coating amount of 5 g/m 2 using a gravure coater. An amine ester-based adhesive (TAKELAC (registered trademark) A511, a main agent manufactured by Mitsui Takeda Chemical Co., Ltd.) / a curing agent "A50" = 10/1), and a thickness of 20 # m is laminated via the adhesive layer. After the aluminum-plated polyethylene terephthalate (PET) film is vapor-deposited, the amine ester-based adhesive is applied to the vapor-deposited PET film in the same manner, and the laminate is high and the fluororesin film is laminated. (Tedlar, manufactured by Du Pont, registered trademark "Tedlar", thickness 50/m), and obtained a solar cell back sheet composed of a hydrolysis resistant polyester film/a vapor-deposited PET film/fluororesin film. Then, a solar cell module was produced in the same manner as in Example 1. (Comparative Example 5) One side of the hydrolysis-resistant polyester film "Lumirror X10S" (registered trademark, 67 321209 201003942 T0RAY Co., Ltd., thickness ribs) was coated with a coating amount W using a gravure coater. An adhesive (Li LAC (registered trademark) A5u) / hardener "Α50" = 10/1), which is the main ingredient of Mitsui Takeda Chemical Co., Ltd., and laminated polychlorotrifluoroethylene through the adhesive layer. (3 fluorinated) (PCTFE) film "NE〇FL〇N" (registered trademark, manufactured by Konica Minolta Co., Ltd., thickness 25/zm), and obtained a two-layer solar cell back of a film/PCTFE film with hydrolysis resistance board. Then, a solar cell module was produced in the same manner as in Example 1. (Comparative Example 6) A solar cell back sheet and a solar cell module were produced in the same manner as in Example except that the acrylic latex [k] was used instead of the polyfluorene-modified acrylic acrylate latex [aUx]. Using the solar cell back sheets obtained in Examples 1 to 16 and Comparative Examples 1 to 6, the following evaluations were carried out. The results are shown in Tables 1 to 6. &lt;Water vapor barrier property&gt; The initial water vapor of each solar cell back sheet obtained was carried out in accordance with JIS K 7129, MG (10) method (Mc) Dern PERMATRM W3/31, batch, _RH) Barrier. Inch will not reach 0. 6g/m2· 24 hours are marked as “◎”, 〇6g/m2 · 24 hours or more and less than i.og/fu hours are marked as “〇”, 夏〇/m2· 24 hours The above does not reach L 5g / V · 24 hours, the standard is 8 g 1. 5g / m2. Those who are more than 24 hours are marked as "x". &lt;Weather resistance&gt; 321209 68 201003942 Exposure test was carried out using a sunshine weathering tester (Suga Testing Machine Co., Ltd., WEL-SUN-DC) (raining cycle · 12 minutes / hour, blackboard temperature 60 to 66 ° C ). Weatherability (1) was observed after 2000 hours of testing. Those who have no change in surface are marked as "〇", and those who have deterioration such as cracking/expansion are marked as "X". Weatherability (2) was observed in the state of yellowing after 2000 hours of testing. According to CIE1 976 (JIS Z 8729), the difference in b value (ΔΙ) after exposure test and before test was measured using Konica Minolta Sensing Co., Ltd. color difference meter "CR-200", and those who did not reach 10 were marked as " ◎", 10 or more and less than 20 are marked as "〇", and 20 or more are marked as "X". Weatherability (3) measures the water vapor barrier properties after 2000 hours of testing. The measurement method and the determination are carried out in accordance with the contents described in the section "Water vapor barrier properties". &lt;Fluidity&gt; The stability of the ruler at 150 ° C after 30 minutes was evaluated in accordance with DIN 40 634, Those who have no abnormalities are marked as "〇", and those who have abnormalities are marked as "X". &lt;For wetness&gt; Moisture resistance (2000 hours) was tested at 85 ° C / 85% RH for 2000 hours. The moisture resistance (3000 hours) was tested at 85 ° C / 85% RH for 3000 hours. The water vapor barrier properties of the samples after each test time were similarly evaluated in accordance with JIS K 7129. Those who have not reached 0. 6g/m2 · 24 hours are marked as "◎", 0. 6g/m2 · 69 321209 201003942 / ; two or more but not UWn], and the time is marked as "〇i 0 ^^, hour The above is marked as ~". <Electrical Insulation> According to fc' IEC 60(4)4-1, the partial discharge voltage is evaluated, and the combination is marked as "〇", and the non-conformity is marked as 2nd. The model site is evaluated under (4). The solar cells transmitted in the middle are shown in Tables 1 to 6. <Processability;> The factory will coat the plastic substrate with the latex (four) and the product will be labeled as “Xl.” The component processing is not 321209 70 201003942 [Table 1] Embodiment 1 Embodiment 2. Embodiment 3 Embodiment 4 Embodiment 5 constituting solar cell solar cell solar cell solar cell solar electric component side element side element side element side element side hydrolysis resistant substrate and hydrolyzable substrate hydrolysis resistant substrate Hydrolysis resistant substrate hydrolysis resistance PET film PET film PET film PET film PET film adhesive agent adhesive agent adhesive agent second-dichloroethylene fine two-ethylene ethylene partial two-ethylene ethylene partial two-ethylene ethylene partial.-- Extinguish A] iW[A] Destroy A] Latex [A] Flap [A] Polyfluorene modified polyoxo-modified poly-oxygen modified poly-oxygen modified poly-oxygen modified acrylic acid-based milky knee acrylic Latex acrylic nipple acrylic latex latex acrylic milk [a] [a] [a] [b] [c] Effect water vapor barrier ◎ ◎ ◎ ◎ ◎ [g/V_24 hours] 0.58 0.32 0.58 0.58 0.58 Weather resistance (1) (Appearance or not Deterioration) Weather resistance (2) ◎ ◎ ◎ ◎ ◎ [△b] 4.8 9.2 2.6 8.9 17.2 Weather resistance (3) 〇◎ 〇〇〇 [g/V.24 hours] 0.62 0.51 0.63 0.70 0.78 Heat resistance 〇〇〇〇〇 〇〇〇〇〇 〇〇〇〇〇 ◎ ◎ ◎ 〇〇 (2000 hours) [g / V. 24 hours] 0.58 0.36 0.58 0.64 0.94 moisture resistance 〇 ◎ 3000 (3000 hours) [g / m2 * 24 hours ] 0.60 0.40 0.61 0.67 0.99 Electrical Insulation 〇〇〇〇〇 Processability 〇〇〇〇〇 71 321209 201003942 [Table 2] Example 6 Example 7 Example 8 Example 9 Example 10 constituting a solar cell solar cell solar cell Solar cell solar cell element reversing element side element side element side element side hydrolysis resistant substrate and inch hydrolyzable substrate and insoluble hydrolyzable substrate hydrolysis resistant substrate when hydrolyzable substrate PET film PET film PET film PET film PET film adhesive agent Agent adhesive agent, adhesive agent, vinylidene chloride partial, gas, ethylene, vinylidene chloride, partial deviation, chlorine dioxide, partial deviation, gas, ethylene, milk, milk, milk, milk, milk, milk, milk, milk #[B] Polyfluorene modified polyfluorene modified polyfluorene modified polyoxyn modified polyoxyn modified polyacrylic modified acrylic latex acrylic latex acrylic latex acrylic latex acrylic latex [dl [e] [f] [g ] [h] Effect water vapor barrier 〇〇〇〇〇 [g/m, 24 hours] 0.81 0. 79 0.80 0.80 0. 79 Weather resistance (1) (with or without deterioration of appearance) 〇〇〇〇〇 Weather resistance ( 2) ◎ ◎ ◎ 〇〇 [△b] 8.8 8. 6 6.4 12.7 14.8 Weather resistance (3) 〇〇〇〇〇 [g/, 24 hours] 0.88 0.88 0.87 0.93 0.9 Thermal enthalpy to wetness 〇〇◦ 〇〇 (2000 hours) [g/n〗 2_24 hours] 0.84 0.82 0.80 0.92 0. 88 Moisture resistance 3000 (3000 hours) [g/m2.24 hours] 0.86 0.85 0.83 0. 95 0. 90 Electrical Insulation 〇〇〇〇〇 Processability 〇 Q 〇〇〇 72 321209 201003942 [Table 3] Example 11 Example 12 Example 13 Example 14 Example 15 constituting solar cell solar cell solar cell solar cell sun Battery element side element side element side element side element Side hydrolysis resistance New PET film substrate PET film substrate PET film substrate PET film substrate PET film adhesive agent adhesive agent adhesive agent biased "a mouse B fried vinylidene chloride partial" - milk Partially diethylene ethylene partial ethylene ethylene latex [B] flap [A] secret [A] fine A] lion [A] polyfluorene modified polyfluorene modified acrylic 11# acrylic #1# 珐琅 coating [a珐琅 珐琅 coating [b] 珐琅 coating [C] [Π [Π effect water vapor barrier 〇 ◎ ◎ ◎ ◎ [g/mz*24 hours] 0.80 0.58 0.58 0.56 0.57 weather resistance (1) 〇Δ 〇〇〇 ( Whether the appearance is degraded or not) (spot) Weather resistance (2) 〇 ◎ ◎ ◎ ◎ [△b] 11.8 8.7 1.5 1.6 1.5 Weather resistance (3) 〇Δ 〇◎ ◎ [g/m2'24 hours] 0.99 1.2 0.61 0_57 0.59 Inch heat 〇〇〇〇〇 湿 湿 〇 ◎ ◎ (2000 hours) [g/m2.24 hours] 0.96 1.10 0.61 0.59 0. 58 Fishing resistance 〇 Δ 〇〇〇 (3000 hours) [g/m2 .24 hours] 0.99 1.12 0.60 0.61 0, 62 Electrical Insulation 〇〇〇〇〇 Machinability 〇〇 〇〇73 321209 201003942 [Table 4] Example 16 constituting the side of the solar cell element and ί hydrolyzable substrate PET film adhesive second vinyl latex [C] polyfluorene modified acrylic latex [a] effect water vapor resistance Barrier [g/V, 24 hours] 〇0. 89 Weather resistance (1) (with or without deterioration of appearance) 〇 Weather resistance (2) [△b] ◎ 1.3 Weather resistance (3) [g/V.24 hours] 〇 0. 95 Heat resistance 〇 Moisture resistance (2000 hours) [g/m2'24 hours] 〇0. 89 Moisture resistance (3000 hours) [g/m2*24 hours] 〇0. 98 Electrical insulation 〇 Processability Ο 74 321209 201003942 [Table 5]

Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 constituting solar cell solar cell solar cell solar cell solar cell element side element side element side element side element side hydrolysis resistant substrate PET film hydrolysis resistance; PET film II film Hydrolysis resistant substrate PET film hydrolysis resistance substrate PET film adhesive agent adhesive agent adhesive agent second gas ethylene derivative IMB] Polyfluorene modified acrylic latex aluminum foil steamed aluminum PET film fluorine film [b] Next Agent adhesive fluorine-based film fluorine-based film effect water vapor barrier 〇X ◎ ◎ Δ [g/m, 24 hours] 0.80 3.0 0.10 0.50 1_ 1 Weather resistance (1) (appearance or deterioration) X 〇〇〇〇 weather resistance (2) X ◎ ◎ ◎ ◎ [△b] 38.2 1.3 0,9 3.9 2.8 Weather resistance (3) XX ◎ ◎ Δ [g/m2, 24 hours] 2.89 3.00 0.10 0.51 1.10 Heat resistance X 〇〇〇〇 Wet 〇X ◎ ◎ △ (2000 hours) [g/m'24 hours] 0.92 3.00 0.10 0.50 1.2 Moisture resistance XX ◎ ◎ Δ (3000 hours) [g/m2*24 hours] 2.25 3. 05 0.11 0.50 1. 10 Electrical Insulation 〇〇X 〇〇Processability 〇〇XXX 75 321209 201003942 [Table 6] Comparative Example constituting solar cell element side hydrolysis resistant substrate PET film adhesive Bi-ethylene latex [B] Acrylic Latex [k] Effect Water vapor barrier [g/m, 24 hours] Ο 0.80 Weather resistance (1) (Appearance or not deterioration) Weather resistance (2) [△b] ◎ 8.5 Weather resistance (3) [g/ M2, 24 hours] Δ 1.09 Heat resistance and moisture resistance (2000 hours) [g/m2, 24 hours] Δ 1. 12 Moisture resistance (3000 hours) [g/m2*24 hours] 1. 99 Electrical insulation processing 〇76 1209 201003942 ^The results of Tables 1 to 6 show that the bismuth oxy-modified bismuth acrylate has a vinylidene chloride-based resin layer and θ on the vinylidene chloride-based resin layer. The solar cell back sheets of Examples I to 16 of the resin layer were all excellent in weatherability, heat resistance, wetness, water vapor barrier property, and electrical insulation. A comparative example of p compared to a layer having only a vinylidene chloride secret layer or a polyphenol modified propylene = oxime resin layer! In the solar battery back sheet of the second embodiment, the solar battery back sheets of the first to sixth embodiments are more excellent in satisfying weather resistance, smash resistance, sufficiency, and water vapor barrier property. In particular, regarding weather resistance (water vapor barrier resistance after 2 hours of purity test) and thirst resistance (3 〇 (10) hours), performance deterioration can be observed with respect to only those of the above two layers. There are two layers and that the layers are continuously stacked and that the system is excellent and the L embodiment! In addition to the adhesiveness of the solar cell f-board of 16th, since it is not necessary to use an adhesive between the vinylidene chloride-based resin layer and the polychlorinated resin layer, the component composition can be changed. The process is excellent, and the workability of each layer is also excellent. {For the other side, 'the PET-based resin layer and the fluorine-based resin that have been steamed with money: the solar cell back sheet of the fourth example' has the characteristics of weather resistance required for the solar cell back-reflection, but Between the two resin layers = 丨, the structure of the member becomes complicated, and the manufacturing steps are also complicated: the mechanical strength is insufficient, so that it is a poor reader. And the availability of a C industry.) Yang: It can provide a kind of resistance, such as weather resistance, heat resistance, and moisture resistance, even in a harsh natural environment for a long time. The simplification and processing of the components are 321209 77 201003942 and the productivity is also excellent. The back panel of the invention is the solar cell back nk of the invention. The field of solar power generation system is suitable for use in the [simplified description of the drawing] 】 1 of the back panel of the pool · 1 2 3 [Description of the main components] ^ section 1 of the module. Solar battery back sheet Plastic substrate Connector agent Partial vinyl chloride resin layer Poly stone oxide modified acrylic resin layer Too% battery module Glass layer Solar cell component Filler 321209 78

Claims (1)

201003942 VII. Scope of application for patents: L solar cell backsheets are made of a touch-sensitive layer and a layer of the former i-layer, which has a vinylidene chloride-based acrylic resin layer. - Polyurethane on the oxy-compound resin layer 2 Scope The solar cell backsheet for the first item of the range, and the description of the vinylidene chloride, 曰 basket &quot; resin layer directly The solar cell backsheet is made of laminated dichloroethylene latex, which is modified by a layer and a gas. On behalf of one gas B (four), or partial (^^ = _ third item of solar cell back sheet with a layer of body secrets of the dichloroethylene «resin powder and partial vinylidene chloride (4) ^ get. 321209 79 1 5.:= Range 1 to 4 of the solar cell back 2 ::: Among them, _ oxygen modified acrylic fine layer is made of ♦ 虱 虱 modified acrylic latex. 3 6. The solar cell backsheet for the fifth item of the application scope, the 4 C (tetra) acid latex contains polyoxygenated resin and 5 7: Shen 2: J range 6th solar cell back In the case of a laminate for a board, the 6-stone yoghurt-modified acrylic-based latex is subjected to emulsion polymerization and is returned to the acrylic acid-based resin, and is subjected to emulsion polymerization, emulsion polymerization, and emulsification polymerization. The solar cell backsheet laminate according to any one of the items 5 to 7 of the invention, wherein the polyresin modification is _ UV absorbers or light stabilizers are formulated in the latex. 9. If you apply for the special items from item 5 to item δ The battery back sheet uses a laminate body in which the above-mentioned poly-stone-modified acrylic acid-based latex is used as a coating which is mixed with a pigment. 10. If the application of the patent is in the i-th to the ninth The laminated body for a solar battery back sheet, wherein the vinylidene chloride resin layer is a coating layer of a vinylidene chloride paint or a vinylidene chloride latex, and a polyfluorene modified acrylic resin layer The coating layer of the poly-oxygen-modified acrylic latex. η·如申=1010 The laminated body for the solar cell back sheet of the patent range, wherein the thickness of the coating layer of the pseudo-nose ethylene resin coating is 5 to 5 〇" 01, and the thickness of the poly-xylene-modified acrylic resin coating layer is from 1 to 100 &quot; m., 12.: a solar cell back sheet, having: a substrate, and the patent application number 1 The laminated body for a solar cell back sheet according to any one of the items 11, wherein the solar cell back sheet is laminated on the substrate by a lamination system. 13) The solar cell back sheet of claim 12, , the aforementioned M. as claimed in the 12th or 13th solar power of the patent scope In the back sheet, two of the vinylidene chloride-based resin layers and the substrate are laminated through the adhesive. 321209 80 201003942 15 · The solar cell, the aforementioned plastic substrate, according to claim 13 or 14 It is made of polyethylene terephthalate or a pool backing plate, which is manufactured by solar energy n (four) according to item 15 of the patent application. = Hydrolyzed resin of bismuth citrate type 1 resin. .~Solar solar cell module, which is equipped with the solar cell backplane of any of the items in the application: Patent No. 12 to 321209 81 201003942 IV. Designated representative map: (1) The representative representative of the case is: (1). (2) Brief description of the symbol of the representative figure: 1 Solar battery back plate 2 Plastic substrate 3 Next agent 4 Partial air gas fine resin layer 5 Poly stone oxide modified acrylic resin layer 5. In this case When there is a chemical formula, please reveal the chemical formula that best shows the characteristics of the invention: There is no chemical formula in this case. 321209 201003942 卜 "μ "日 $ it]. Man jg patent specification (this format, order, please do not change, please do not fill in the ※ part of the mark) A ※ application number: outside H ^ IL (2 006.01) ※ Application date: f 4 chat. Classification: ββ __ I. Invention name: (Chinese/English) Laminated body for solar battery back sheet and back sheet with the laminated body LAMINATE FOR SOLAR CELL BACK SHEET AND BACK SHEET HAVING SAID LAMINATE II. Chinese Abstract: The present invention Providing a weatherability in which an excellent water vapor barrier property can be exhibited and maintained by a laminated vinylidene chloride-based resin layer and a polyfluorene-modified acrylic acid-based resin layer 'even in a severe natural environment for a long period of time' And a laminate for a solar cell back sheet excellent in moisture resistance. The invention provides a laminate for solar cell back sheet by laminating a vinylidene chloride resin layer and a silicon-modified acrylic resin layer, which is excel lent in weather resistance and humidity resistance where an extraordinary vapor barrier feature can be 1 321209 201003942 VI. Description of the Invention: [Technical Field] The present invention relates to a solar battery backsheet that can withstand long periods of time in harsh natural environments. A back sheet is a solar battery back sheet having a laminate for a solar battery back sheet, and a solar battery module including the solar battery back sheet. [Prior Art] In recent years, concerns about the global warming issue have been raised, and various efforts are continuing to suppress carbon dioxide emissions. Increasing consumption of fossil fuels will increase the amount of carbon dioxide in the atmosphere and increase the temperature of the earth due to its greenhouse effect, thus causing a major impact on the global environment. As an alternative energy source for fossil fuels, various studies have been conducted: expectations for solar power generation for environmentally friendly energy are increasing. The solar cell constitutes a part of the heart of the solar power system that directly converts the energy of sunlight into electrical energy, and is made of a semiconductor. The structure does not directly connect the solar cell components to the number of cells, and generally uses the number (4) of the cell components (4) and (4) to perform (10) two = about 2. Year) Protect the components and package them in various packages: lza ι〇η). The solar cell module enclosed in the package is pulled, and the battery is replaced by a battery, and the surface illuminated by sunlight is covered with glass. The framing material = the glacial acetic acid ice-based copolymerization, the weather-resistant plastic material, and the like, the inner surface of which is heat-resistant, and the solar battery module is used for outdoor use, and the durability is required in terms of its structure and material 321209 3 201003942 structure. Weather resistance. In particular, the back sheet (inner side protection sheet) is required to have weather resistance and a small water vapor transmission rate. The reason is that when the filler material is peeled off or discolored due to moisture penetration, and the line is corroded, there is a possibility that the output power of the module itself is affected. In the past, most of the solar cell backsheets have been made of a metal film having a gas barrier property (generally a foil) or an inorganic oxide vapor film using a high weather resistant resin film such as a polyvinyl fluoride film (fluorine film). (In general, a solar battery back sheet in which an aluminum vapor-deposited polyethylene terephthalate (PET) film is laminated or laminated. However, the fluorine film is weak in mechanical strength and has poor workability in the member. When the solar cell module is manufactured, the protrusion of the electrode portion of the solar cell element penetrates and contacts the aluminum foil in the inner surface protection plate, and the solar cell element and the aluminum foil are generated. Short circuit and shortcomings that adversely affect battery performance. In addition, the complexity of the components composed of several layers is difficult to be considered as an ideal in terms of productivity, and hinders the spread of solar cells. In order to improve these disadvantages and obstacles, other alternative films such as polyacrylic film, vinyl chloride film, polyester film, polycarbonate film, and polyvinylidene fluoride film are being studied as solar battery back sheets. Patent Document 1 described later discloses a solar battery back sheet in which a polycarbonate film and a vapor film composed of an inorganic oxide are laminated. Patent Document 2 described later discloses a back sheet for a solar cell module, which has a pair of aluminum vapor-deposited layers laminated on both sides of a polyethylene terephthalate film via an adhesive layer, and the adhesive layer is It is formed by an adhesive for a dry laminate using a polyurethane-based adhesive. 4 321209 201003942 In Patent Document 3 to be described later, a thermoplastic resin sheet for solar cells is provided, which has a thermoplastic resin layer of polyethylene terephthalate containing titanium dioxide. Patent Document 4 which will be described later describes a solar cell comprising a plurality of layers of a resin film layer and a polyethylene terephthalate film disposed on the outer side of the solar cell module. Plate member. Patent Document 5 described later discloses a thin film solar cell module in which a butyl rubber is coated on an inner peripheral end surface of a protective surface of a thin film solar cell module, and an aluminum foil is used as a moisture proof layer, and The base material layer and the moisture-proof layer composed of the PET film are followed by an amine ester resin-based adhesive. Patent Document 6 described later discloses an inner surface protective sheet for a solar cell, which is provided with at least one layer of a polypropylene resin sheet and is provided with a polyethylene resin on at least the surface side of the polypropylene resin sheet. A laminated sheet of the constituent sheets. Patent Document 7 which will be described later describes an inner surface protection panel for a solar cell module and a solar cell module using the inner surface protection panel. (The 3⁄4 surface protection panel is made of a heat-absorbing property containing an ultraviolet absorber and a light stabilizer. Japanese Laid-Open Patent Publication No. JP-A-2006-324556. [Patent Document 5] Japanese Patent Laid-Open Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. [Patent Document No. 2003-243848] [Patent Document International Publication No. 2008/043848] [Problems to be Solved by the Invention] However, Patent Documents i to 7 The solar cell backsheet laminate system cannot fully satisfy various functions such as heat resistance and weather resistance, moisture resistance, and high water vapor barrier resistance due to prolonged exposure to harsh natural environments. f &quot; In addition, in the gas barrier layered product described in Patent Document 8, in order to exhibit sufficient gas barrier properties, the gas barrier layer must have at least 2 layers in j, and disclosed In addition, it is difficult to provide the use of solar cell components, water resistance, weather resistance, and the like in a harsh natural environment. Yu Yu, the problem to be solved by the present invention is provided. A laminate for solar cell backsheets which exhibits excellent water vapor barrier properties, excellent weatherability and moisture resistance even in a severe natural environment for a long period of time. A solar battery back sheet having a laminate for a solar battery back sheet, and a solar battery module including the solar battery back sheet. (Means for Solving the Problems) The present inventors have made efforts to solve the problems described above, and the results are It was found that the solar cell having a vinylidene-based resin layer and a silicone-modified acrylic resin layer laminated on the vinylidene chloride-based resin layer was found. In other words, the present invention provides a laminate for a solar cell back sheet, a solar battery back sheet having the laminate for the solar battery back sheet, and the like. And a solar battery module having the solar battery back sheet. [1] A laminated body for a solar battery back sheet, comprising: a vinylidene chloride-based resin layer and a layer laminated on the vinylidene chloride-based resin layer [2] The layered body for a battery back sheet of the present invention, wherein the vinylidene chloride-based resin layer and the polyfluorene-modified acrylic resin layer are Directly connected and layered. [3] The laminate for a solar cell backsheet according to [1] or [2J, wherein the partial vinyl chloride resin layer is obtained by dissolving a vinylidene chloride resin powder in an organic solvent. Manufactured from lacquer or vinylidene chloride emulsion. (4) The laminate for a solar cell back sheet according to the above [3], wherein the vinylidene chloride-based resin, the powder, and the partial olefin emulsion in the vinylidene chloride paint comprise 5% by mass of the total monomer. The monomer of chloroolefin is obtained by emulsion polymerization. ^-Chlorine 6 [5] As in the above [1] to "41 ψ &amp; ^ L θ body, the laminated battery back sheet for the second item is laminated with the 'polyoxygen modified acrylic resin layer' Oxygen-modified acrylic latex. [6] As described in [5], the laminated body for solar cell backsheets: r-enoic acid-based latex contains c:: [7] The solar cell of the above [6] Backboard (4) &quot;T, just described poly 321209 7 201003942 Shi Xi oxygen modified (4) (4) Latex recorded before the reduction of polymerization, before the production of propylene I (four) (four), through the emulsion polymerization, emulsion polymerization %, emulsion polymerization after the addition of polyoxane modified According to any of the above [5] to [7], the 顼 女 陪 % % & & τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ τ The medium is formulated with a UV absorber and/or a light stabilizer. [9] The laminated body for a solar cell back sheet according to any one of the above [5] to [8] wherein the above-mentioned polyoxygen-modified lactic acid-based latex is used as a coating which is mixed with a pigment. [10] The laminate for a solar cell back sheet according to any one of [1] to [9], wherein the f' of the dichloroethylene-based resin layer is a coating of a dichloroethylene or a vinylidene chloride latex. The cloth layer, the poly-stone-oxygen-modified propyl acid-based resin layer is a coating layer of the poly-oxygen-modified acrylic latex. [11] The laminated body for a solar cell back sheet according to [10/], wherein the thickness of the vinylidene chloride-based resin coating layer is 5 to 50 mm, and the poly-stone-oxygen-modified acrylic resin coating layer The thickness is 10 to 100 #ω. [12] A solar battery back sheet comprising: a base material; and a laminate for a solar battery back sheet according to any one of the above, wherein the solar battery back sheet is laminated on the base material. [13] The solar battery back sheet of [12], wherein the substrate is a plastic substrate. [14] The solar battery back sheet according to [12] or [13] wherein the vinylidene chloride-based resin layer and the substrate are laminated via an adhesive. [15] The solar battery back sheet according to [13] or [14] wherein the plastic substrate is made of a polyethylene terephthalate resin. 321209 8 201003942 [(8) The solar battery back sheet of [15], wherein the polystyrene acid bismuth vinegar resin is a hydrolysis resistant resin. [Π]--Sunlight series, which has the solar battery backplane from [12] to _zhong. (Effect of the Invention) According to the present invention, it is possible to provide a laminate for a battery back sheet which is excellent in water vapor barrier properties and weather resistance and moisture resistance. Further, a solar battery back sheet for a laminated body for a solar battery back sheet, and a solar battery module including the above-mentioned = battery back sheet. [Embodiment] Hereinafter, the "this embodiment" for carrying out the present invention will be described in detail. Further, in the present invention, "the following is a private, M e - the following embodiments are limited to various modifications within the scope of the day. (Polymer for solar battery back sheet) In the solar cell back sheet, a laminate of a vinyl ruthenium resin layer and a laminate of the above-mentioned vinylidene chloride resin; = an oxygen-modified acrylic resin layer. The poly layer on the W layer is in the present embodiment Vinyl chloride is a gas barrier such as water vapor barrier =: Taihu pool back plate required to withstand long-term harshness: environmental adaptability, especially in order to maintain weather resistance, it is necessary, brother to make money The weather and the wettability are maximized, and it is preferable that the acrylic resin layer is directly laminated and laminated on the vinylidene chloride-based resin layer. The barrier layer is one layer, and the gas barrier properties required for the solar cell backsheet can also be fully utilized. In the present embodiment, the resin layer and the polymethylene emulsion modified acrylic resin layer Others can also be inserted between In this case, the water vapor barrier properties, weather resistance, moisture resistance, heat resistance, etc. required for the solar battery backsheet are still exhibited. In addition, in the present embodiment, The polychlorophthalocene-modified acrylic latex is directly coated on the vinyl chloride resin layer, and the two layers are continuously laminated on the plastic substrate (that is, the vinylidene chloride-based resin layer and the polyfluorene-modified acrylic acid are laminated). It is preferable that the resin layer is directly bonded to each other and laminated. From the various properties of the laminated body for a solar cell back sheet, such as weather resistance, heat resistance, moisture resistance, gas barrier properties, electrical insulation properties, physical strength, and the like, It is preferable to laminate a vinylidene chloride-based resin layer on a plastic substrate, and to laminate a polysulfide-oxygen-modified acrylic resin layer thereon in a direct contact manner. (Polyvinylidene chloride-based resin layer) This embodiment The vinylidene chloride-based resin layer is not particularly limited as long as it is made of a vinylidene chloride-based film, a vinylidene chloride resin or a vinylidene chloride-based latex, and is made of a vinylidene chloride latex or a partial second. The vinyl chloride resin is dissolved in the solvent It is preferably produced from a vinylidene chloride varnish, and it is preferably produced from a vinylidene chloride latex from the viewpoint of easy control of the film thickness. Further, the composition is simplified, the processability, and the like are produced. From the viewpoint of the above, the vinylidene chloride-based resin layer is preferably coated with a vinylidene chloride latex or a vinylidene chloride paint. 10 321209 201003942 Here, the second ethylene-based resin layer is used. , means a layer consisting of a resin composed of a partial bismuth i-battery resin or a resin composition containing a bismuth-containing bismuth resin. In addition, the term "vinylidene chloride-based resin" means The polymer of vinyl chloride as a monomer component may be a homopolymer of vinylidene chloride or a copolymer of vinylidene chloride and other monomers copolymerizable therewith. When the vinylidene chloride resin is a copolymer The polymerization ratio of the vinylidene chloride in the vinylidene chloride resin is preferably 50% by mass or more, preferably 50 to 94% by mass, more preferably 80 to 93% by mass, and still more preferably 88 to 92% by mass. Better. Further, the vinylidene chloride resin refers to a dry powder composed of a vinylidene chloride-based resin alone or a resin composition containing a vinylidene chloride-based resin. Further, the vinylidene chloride-based film refers to a film composed of a vinylidene chloride-based resin alone or a resin composition containing a vinylidene chloride-based resin. The vinylidene chloride-based latex is not particularly limited as long as it is a latex of a resin composition produced by polymerizing vinylidene chloride as a main component. It may be a latex obtained by mixing other components, or it may be a copolymer of vinylidene chloride and other components. The vinylidene chloride emulsion is preferably obtained by emulsifying and polymerizing a monomer containing 50% by mass or more of vinylidene chloride in the whole monomer. In the all monomer, the content of the vinylidene chloride is preferably from 50 to 94% by mass, more preferably from 80 to 93% by mass, particularly preferably from 88 to 92% by mass. Since the ratio of the vinylidene chloride is 50% by mass or more, the gas barrier properties such as water vapor barrier properties can be maintained. In addition, since the ratio of the vinylidene chloride is 11 321209 201003942 94% by mass or less, it is possible to produce a practical coating film which is excellent in film formability and a dichloroethylene resin layer. The vinylidene chloride varnish is not particularly limited as long as it is obtained by dissolving a powder of a vinylidene chloride-based resin (for example, the above-mentioned (10) agglomerated, washed, and dried). b The organic solvent may be any one which can dissolve the partial-resin and volatilizes when it is dried, and examples thereof include ethyl acetate, butyl acetate, toluene, methyl ethyl ketone, tetrahydrofuran, and hydrazine. , or two or more of these, in any ratio, in the present state, a monomer which can be polymerized with a meta-dichloroethane, and examples thereof include, for example, vinyl chloride; , 乙乙二曰, its 2-ethylhexyl acrylate and propyl benzoic acid 2 '· and unsaturated carboxylic acids such as acrylic acid, methacrylic acid and maleic acid. Among these monomers, one type or two or more types may be used. In addition, in the partial dichloroethylene monomer, the dichloroethylene rotating towel is also delicious to prevent the non-organic lubricant in the thin county block, to promote the a7 particle) or promote, "deuterated crystal nucleus, adhesive Such as adding various additives to the force of the opening of the helmet is suspected, called the situation seven, 'use - decene oxime resin = 2. Gf" is better, the adhesive is preferably 1 to 6 mass%. In this case, the so-called (four), as long as it can be dissolved or dispersed in the partial - 321209 12 201003942 chlorine emulsion and vinylidene chloride paint, can be any: amine ester based adhesive, epoxy based Agents, etc. "The method listed in the second gas ethyl latex, partial dichloroethylene paint, to form a partial dichloroethylene film through the vinylidene chloride latex and dried. At this time, the concentration of the coating liquid is dry. It is better to do it in 2 illusion. The quality 4 is better, and the effect of the partial dichloroethylene-based resin layer in order to fully exert the coating:: After coating, it is hardened to promote the degree of crystallization. Preferably, coating is preferably carried out at 20 to 90 C. The above-mentioned partial dichloroethylene latex and vinylidene chloride paint are coated by a gravure coating method and a dipping (dip_nip) method. , air knife μ... cloth measurement rod (met coffee hole knife coating method and other methods of coating the performance of the wave of dichloroethylene women's resin layer and:: in order; knife hair, my family, want, earthy month It is good to apply it by hand, and it is better to coat it by means of measurement, cloth method and file coating method. In this embodiment, for the sake of the secrets 4 ^ material pick h _ ^ for ^ plus The contact force between the vinylidene-based vinyl resin layer and the substrate can be corona discharge treated on the substrate by applying a partial dichloroethylene latex or a dichloroethylene. a vinyl chloride resin layer. &amp; a contact agent and a laminate bias agent: as long as it can be used as a base material and a dichloroethylene glycol resin (6). In the case of a material substrate, I, for example, an epoxy resin-based adhesive, an amine ester (tetra)-based adhesive, a propylene-based I-rule-based adhesive, a poly- oxy-modified acrylic resin, and a vinyl acetate The following agent, the japan jointer, the bismuth, the bismuth copolymer, and the like. * &amp; ester resin-based adhesive, acrylic resin-based adhesive, 321209 13 201003942 Polyoxyn modified acrylic resin-based adhesive A vinyl acetate-based adhesive is preferred. When the vinylidene chloride-based resin layer is produced from a vinylidene chloride-based varnish, it is preferably added to the lacquer and used. The amount is preferably from about 1 to 6% by mass based on the vinylidene chloride-based resin. On the other hand, when the vinylidene chloride-based resin layer is made of a vinylidene chloride-based latex, it is previously applied to the substrate. After applying the adhesive, the vinylidene chloride emulsion is coated thereon. Preferably, the thickness of the vinylidene chloride-based resin layer in the embodiment is preferably 5 to 50 // m, more preferably 5 to 30 # m, more preferably 10 to 30 / zm. The gas barrier property of the vinylidene chloride-based resin layer obtained by coating a vinylidene chloride latex or a vinylidene chloride-based paint is generally determined by the thickness of the vinylidene chloride-based resin layer, and the thicker the coating film thickness. , the higher the gas barrier property is exerted. However, when a large amount of vinylidene chloride latex or vinylidene chloride paint is applied at a time in order to increase the coating film thickness of the vinylidene chloride-based resin layer, In the drying process, the coating film may be cracked or twisted. If the appearance of such a coating film is poor, it will not only impair the appearance of the product, but also fail to exhibit the desired gas barrier properties. If the thickness of the coating film of the vinylidene chloride-based resin layer is to be increased, it may be carried out by repeatedly coating a plurality of vinylidene chloride emulsions or a vinylidene chloride coating on the coated resin layer. 〃 (Polyoxime-modified acrylic resin layer) 14 321209 201003942 In the present embodiment, the polyfluorene-modified polyacrylic acid-modified acrylic film and the polyfluorene-amp; olefin-based resin layer are modified by hydrazine From the viewpoint of the acrylic acrylic resin, the modified acrylic resin, and the poly-controllable film thickness, it is not particularly limited, and it is preferably produced. In the case of the simplification and processing of the component structure, it is preferable to use latex as a viewpoint of productivity such as polysulfide-modified acrylic tree. (3) e1 main cloth polyoxygen modified acrylic acid, here, the so-called poly 矽 ^ alone by poly; ^ oxygen modified acrylic acrylic tree layer, is the resin composition of the finger acrylic acid resin composition Z or It is a layer which consists of this, and it consists of a poly-stone-modified oxygen-modified acrylic resin. In addition, the resin or resin composition of the poly resin, for example, a decane bond and an acrylic compound, and an ethylenic unsaturated compound may be a poly- oxy-altering agent. For the money modifier, the copolymer ' can also be a mixture of its-partic acid and W-based resin. The long-term resin can also be a poly-xenon tree. In addition, the so-called propionic acid tree t-based ethylene is not Saturated monomer is: body: refers to a copolymer containing at least one homopolymer having a slow a, ^ early body, or a copolymer having at least one kind of ethylenically unsaturated monomer and at least i. When it is a copolymer, it can be "...,";; 4 quality = ' can also be 8. to 93 mass TM 4i0. : A4 Bing Lai Zhao Zhao / 15 201003942 Acrylic acid monomer, mercapto acrylate monomer and acrylate monomer, etc. The term "polyfluorinated resin" refers to a polymer compound having a siloxane coupling.矽Oxygen-modified acrylic film and poly-xyloxy-modified acrylic resin, which are modified from poly-stone-oxygenated propionic acid resin alone a film or a dry powder composed of a resin composition containing a polyfluorene-modified acrylic resin. Further, the poly-oxygen-modified acrylic resin layer may be modified by a coating of polyfluorene-modified acrylic resin. It is obtained by mixing a latex with a pigment. The pigment is not particularly limited. For example, white pigment can be zinc oxide, white, carbonate 1 , zinc bismuth (1 ithopone, a mixture of zinc sulfide and barium sulfate), titanium dioxide. Inorganic pigments such as sedimentary barium sulfate and barite powder; and organic pigments such as polystyrene copolymer particles. In addition, carbon black may be used as the black pigment, and lead dan, iron oxide red, etc. may be used as the red pigment. For yellow pigments, chrome yellow, zinc yellow, etc. can be used. For blue pigments, ultramarine blue, Prussian blue (ferric iron hydride), etc. can be used to reflect and increase the light incident on the solar cell module into electrical energy. From the viewpoint of efficiency, it is preferred to use a white pigment, and particularly preferably titanium dioxide, zinc oxide or calcium carbonate is used. In the modification of acrylic acid from pigment and polyfluorene oxide A dispersant, a pH adjuster, an antifoaming agent, a tackifier, a film forming aid (organic solvent), etc. may be used as the coating composition of the latex, and the film forming aid may be used as described below. The blending ratio of the oxygen-modified acrylic latex is preferably 20 to 60% by mass based on the mass ratio of the coating film after coating and drying, and 40 to 80% by mass of the polyfluorene-modified acrylic resin. The pigment is preferably 30 to 5% by mass, and 70% by mass is preferred. The quality of the acrylic resin is 50 to 100. The mass ratio of the pigment is η plagiar opacity, when it is white yan The above can improve the surface of the coated solar power generation unit 2 '^ efficiently reflect from too much quality"; on the other hand, if the ratio (4) will become good. And the weather resistance in the natural environment. From the viewpoint of weather resistance, the present embodiment of the roasting acid emulsion is to use the polysulfide oxime modifier; In the case of Ding Qi Shi and Xi Xi, there are one type of w yarn precursors (hereinafter, sometimes only Α), at least one kind, and at least one kind of ethylenically unsaturated monomer having the above-mentioned silky body (hereinafter, there are When only the different monomers B") and the emulsifier are used for polymerization, it is preferred that the olefinic property and the latex are good. From the point of view of light resistance, it is better to mix UV absorbers and/or light stabilizers, and: = can be externally absorbed and / or Guangan (4) and polysulfide modified = glue Aggregated. The method of producing the polysulfide-modified acrylic nipple of the present embodiment by polymerization is, for example, a polymerization method such as emulsion polymerization, suspension polymerization or bulk polymerization microemulsion polymerization, and the like, and is not particularly limited. A method of stably producing a latex having a good average particle diameter of about 10 to about 2 is preferably an emulsion polymerization. In the present embodiment, the emulsion polymerization is fine while the aqueous medium is passed through the ethylenically unsaturated monomer which is a radical polymerizable monomer, and the free radical of the ethylenically unsaturated monomer B. The human is made up of an acrylic resin and a polymerized acrylic latex by hydrolysis and shrinkage polymerization of the polyoxic acid modifier. ... 虱 知 知 知 知 知 知 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述 前述In the pre-emulsion before the dissolution of the water to be added, the amount of the solvent is 2% by mass, and the amount of the solvent other than the polymerization start water is 2% by mass. It is better. In the emulsified state of the chemical liquid, it is more preferable to carry out emulsion polymerization without destroying the pre-milk as a solvent. ^ pH pH 使用 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 仅 pH pH pH pH pH pH pH pH pH pH pH pH There is no particular limitation, and it is preferably pH4Q^. By, M·. The emulsion polymerization is carried out as follows, whereby the condensation reaction of the poly J agent is rapidly generated, and the condensation reaction is inhibited by emulsion polymerization. From the viewpoint of the storage property of the product, the pH of the reaction system is preferably 4.0 or less, and preferably pH 1.5 or more. Further, in the present embodiment, there is no special method for introducing a radical initiator in the emulsion polymerization. Persulfate or the like as a radical initiator can be preliminarily introduced to the reaction system towel. In addition, a method of directly adding the at least one ethylenically unsaturated monomer A, at least one ethylenically unsaturated monomer B, an emulsifier, and a radical initiator to the reaction system may be directly added to the reaction system. . In addition, it can be separated from the observation solution and introduced into the reaction system in sequence with a water-soluble 321209 18 201003942 liquid system. As described above, in the radical polymerization, the addition of the polyoxoxime modifier can be carried out before the emulsification polymerization, at the time of the emulsion polymerization, or after the emulsion polymerization. It is preferred to carry out the emulsion polymerization. Further, in the emulsion polymerization, the emulsion polymerization by the hydrolysis/condensation reaction of the polyoxoxime modifier is carried out by using an ethylenically unsaturated monomer A or an ethylenically unsaturated monomer B or the like. The emulsion polymerization by radical polymerization is also particularly preferable at the same time. Further, the polyoxynoxy resin obtained by the hydrolysis/condensation reaction of the polyoxime modifier may be blended with an acrylic latex containing an acrylic resin. The polyoxo-modified agent used in the present embodiment may contain a decane compound (1), a decane compound (2), and a decane compound represented by the following (1), (2), and (3), respectively. 3) and at least one selected from the group consisting of cyclic decane compounds, and may be used in combination of two or more kinds. In order to maintain the weather resistance required for the solar battery back sheet, a combination of the above-mentioned zephyr compound (2) and the aforementioned pulverized compound (3) is preferred. RtSiRVm) (1) (wherein R1 is a phenyl group or a cyclohexyl group; R2 is a hydrogen atom, an aliphatic hydrocarbon group having 1 to 16 carbon atoms, an aryl group having 6 to 10 carbon atoms, and a cycloalkyl group having 5 to 6 carbon atoms; And an alkyl acrylate group having 1 to 10 carbon atoms or an alkyl methacrylate group having 1 to 10 carbon atoms; and R 3 is independently selected from alkoxy groups, ethoxylated groups or hydroxyl groups having 1 to 8 carbon atoms; 19 321209 (2) 201003942 m is 0 or 1). CH3Si(R4)3 (wherein alkoxy group to 8 alkoxy group, ethoxy group or hydroxy group (3) to 8 alkoxy group, ethoxylated oxy group or no group R4 are independently selected from carbon numbers ). (CHs)2Si(R5)2 (wherein R5 is independently from carbon number Selected among them). In the present embodiment, when at least one of the decane compound (1) is contained as the polyoxo-alternating agent, it is preferable since the polyoxy-antimonic resin and the acrylic-based resin can be smoothly coexisted after the polymerization. Further, when at least one decane compound (2) is contained as the polyoxonium modifier, it is preferred because it can impart a crosslinking density to the polyoxo structure. Further, if at least one of the decane compound (3) and/or the cyclic decane compound is contained as a polyoxo modifier, the crosslinking density of the polyoxyl polymer formed by lowering the polyoxo modifier is lowered. Further, it is preferable to impart flexibility when the polyfluorene-modified acrylic emulsion is coated. Specific examples of the decane compound (1) used in the present embodiment include phenyl trimethoxy decane, diphenyl dimethoxy decane, phenyl diethoxy phthalate, and diphenyl. Diethoxy pulverization, phenylmethyldimethoxydecane, cyclohexyltrimethoxy decane, dicyclohexyldimethoxydecane, cyclohexyltriethoxydecane, dicyclohexyldiethoxydecane Wait. One type of these compounds may be used, and two or more kinds of these may also be used. 20 321209 201003942 The decane compound (1) is preferably phenyltrimethoxy decane. Specific examples of the decane compound (2) used in the present embodiment include methyltrimethoxy decane and methyltriethoxy decane. These compounds may be used alone or in combination of two or more kinds. The decane compound (2) is preferably methyltrimethoxy decane. Specific examples of the decane compound (3) used in the present embodiment include dimercaptodimethoxy decane and dimethyldiethoxy decane. These compounds may be used alone or in combination of two or more kinds. It is preferred that the compound (3) is dimercaptodimethoxy zephyr. Specific examples of the cyclic decane compound used in the present embodiment include octamethylcyclotetraoxane, octaphenylcyclotetraoxane, hexamethylcyclotrioxane, and decathenyl ring. Pentaoxanes, tetradecyltetravinylcyclotetraoxane, and the like. These compounds may be used alone or in combination of two or more kinds. The polyoxoxime modifier may contain an isobutyl group in addition to the polyoxonium modifier selected from the above decane compound (1), decane compound (2), decane compound (3), and cyclic decane compound. Trimethoxy decane, vinyl triethoxy decane, r-propylene methoxy propyl trimethoxy decane, r propylene methoxy propyl triethoxy decane, r-mercapto propylene decyloxy Propyltrimethoxy decane, r-methacryloxypropyltriethoxydecane, r-methylpropenyloxypropylmethyldimethoxydecane, r-glycidoxypropane Dimethoxyoxymethyl decane, r-glycidoxypropyl triethoxy decane, tetramethoxy decane, tetraethoxy decane, and the like. _ In addition, a polyoxonium modifier can be added, or no polyoxon modifier 21 321209 201003942 is added, but it is made from ethylene and monomer A, ethylenically unsaturated monomer β and emulsified d (4) The blended oxygen (10) is then blended. Then, the blended oxygen latex is blended with, in addition to the dimethyl poly 7 oxygen emulsion, for example, a phenyl group, a linear alkyl group, an anthraquinone group, an amine group, an epoxy group, or a sulfhydryl group. Latex or latex resin latex. In the poly-stone-modified oxygen-based acrylic resin layer of the present embodiment, the polyoxime modifier is hydrolyzed and condensed, and the acrylic resin (acrylic emulsion) The rubber particles have a (4) oxygen resin ($ oxygen oxide), so that excellent weather resistance can be achieved. In addition, the presence of the condensate of the polyoxo-modified agent can be confirmed by 29Si-NMR (29^ NMR spectroscopy) or 1 Η-Li R (proton NMR spectroscopy). Further, H NMR (proton NMR) Spectroscopy) uses Siji Xiushi as an internal standard, but - bribe (29S i NMR spectrum) does not use internal standard 'but instead measures 7 rubber (silicon rubber) and its signal is -22_, Or the value of the liquid sample obtained by dissolving the tetraf-propion in chloroform is 〇_ and used as an external standard. For example, since the chemical shift of (6) MR is _35 to _, the peak, the condensate of the compound (1) can be identified. In addition, since the chemical shift of S^MR is, the coffee shows the condensate of the peak. Also, due to the %, the shift = 16 to -26 ppm shows the peak, the condensate of the grapefruit 1. Further, since the peak of the displacement of the riding compound (3) is observed, it is also possible to recognize that &lt;Chemistry of Chemicals In the present embodiment, it is a condensate with respect to the compound of the ethyl ester. Hoof unsaturated monomer A and ethylene 321209 22 201003942 The combination of unsaturated monomer B is 9nn. / up to ten berries, polyoxyl modifier is preferably used in an amount of 0.1 to 200 mils, to use 〇Λ, Ω Λ from U.1 to 120% by mass, preferably by mass%, to use 1 to 10, please be even better. The ethylenically unsaturated monomer A used in the present embodiment may, for example, be at least a compound which can be conjugated with an ethylenic monomer β and has a repellent radical polymerizable lysing monomer. Specific examples thereof For example, acrylic acid, methacrylic acid, itaconic acid and its monoester, thioglycolic acid and its mono- vinegar, and cis-butyl diacid and its monoester (hereinafter, sometimes cyanuric acid) And methacrylic acid is combined and described as (meth)acrylic acid). Since the ethylenic age-free monomer enthalpy also has (iv) promotes the hydrolysis reaction of the (iv) oxygen-modifying agent and the action of the condensation reaction-media, it is preferred to contain at least one selected from the group. In the total amount of the ethylenically unsaturated monomer and the ethylenically unsaturated monomer B, the ethylene content and the monomer number are preferably from 1:1 to 15% by mass. The ethylenically unsaturated monomer B used in the present embodiment may, for example, be a (meth) acrylate monomer or a (mercapto) acrylamide monomer represented by (mercapto) acrylate and the like. An ethylene monomer or the like is used as at least one comonomer copolymerizable with the ethylenically unsaturated monomer A. Specific examples of the (meth)acrylic acid vinegar monomer include, for example, an alkyl (meth)acrylic acid ester having an alkyl group of 1 to 18 and an ethylene oxide unit number of 1 to 10 (poly). Oxy-extended ethyl mono(methyl) acrylate, (poly)oxypropyl propyl mono(indenyl)propionic acid g, the alkyl group having a carbon number of 1 to 18 (mercapto) acrylate The number of alkyl esters and ethylene oxide units is from 1 to 1 (poly) 321209 23 201003942 Oxygen extended ethyl bis(indenyl) acrylate. Specific examples of the sulphuric acid vinegar of the month IJ can be exemplified by (fluorenyl) decyl acrylate, ethyl (meth) acrylate, n-butyl acrylate (meth) acrylate, (meth) acrylate Isobutyl ester, tert-butyl (meth) acrylate, 2-ethylhexyl (meth) acrylate, dodecyl (meth) acrylate, cycloalkyl (meth) acrylate, and the like. The aforementioned alkyl (meth)acrylate is methyl methacrylate, n-butyl methacrylate, butyl acrylate, 2-ethylhexyl methacrylate, cyclohexyl (meth) acrylate, (曱) 2) hydroxycyclohexyl acrylate, methylcyclohexyl (meth) acrylate, 2, 3 cyclohexene oxide (meth) acrylate. Specific examples of the above (poly)oxyethylidene mono(meth)acrylate are exemplified by: ethylene glycol (meth) acrylate, ethylene glycol methoxy (meth) acrylate, and monoethylene glycol ( Methyl) acrylate, diethylene glycol methoxy (meth) propylene oxime, tetraethylene glycol (methyl) propyl phthalate, tetraethylene glycol methoxy (fluorenyl) propionic acid Ester and the like. Specific examples of the soil (poly)oxypropyl propyl mono (meth) acrylate can be exemplified. 1. Propyl alcohol (meth) acrylic acid vinegar, propylene glycol methoxy (methyl) acrylic acid ^, two Propylene glycol (meth) propyl vinegar, dipropylene glycol methoxy (methyl) propyl hydrazine, tetrapropyl alcohol (meth) acrylate, tetrapropylene glycol methoxy (meth) acrylate, and the like. Specific examples of the hydroxyalkyl (meth) acrylate of the earth are described as follows: (methyl 2, ethyl ketone, (meth) acrylic acid 2 _ propyl acetoacetate, etc. J (♦) Specific examples of the oxygen-extended ethyl-(meth) acrylate can be exemplified by 321209 24 201003942 monoethylene glycol di(meth)acrylic acid, tetraethylene glycol di(meth)acrylic acid such as ethylene glycol di(methyl) Acrylate, hydrazine, diethylene glycol di(meth) acrylate vinegar, etc. The ethylenically unsaturated monomer B may, for example, be exemplified by (methacrylic acid oxime, trimethyl methacrylate) The content of the (meth)acrylic acid vinegar monomer is preferably from 8 G to (10)% by mass based on the total mass of the ethylenically unsaturated monomer B. U In the present embodiment, '(meth)acrylic acid vinegar monomer which is a main component of the ethylenically unsaturated monomer oxime, if it contains a (meth)acrylic acid vinegar monomer having a ring-based group, It is preferred because it can be produced into a polysulfide-modified acrylic resin layer having excellent durability. The hydrogen atom of the above ring-burning group may be substituted with an alkyl group having a carbon number of 丨 to 6, or a hydroxyl group, and an epoxy group may also be present in the ring. The (meth) acrylate monomer having a cycloalkyl group may, for example, be a (meth)acrylic acid cycloalkyl ester. The earth (fluorenyl) acrylate cycloalkyl ester may, for example, be an ester of a cycloalkyl group having 5 to 12 carbon atoms. Specific examples of the (▼-) acrylate monomer having a cycloalkyl group include a compound represented by the following formula (4). CH2 = C(R6)C00R7 (4) (wherein R6 is a hydrogen atom or a methyl group; R is a cyclopentyl group, a cyclohexyl group or a cyclododecyl group, and such a cycloalkyl group may have a carbon 25 321209 201003942 number 1 Up to 6, the base, the base or the epoxy group as a substituent). Specific examples of the compound represented by the above formula (4) include, for example, (meth)cyclohexyl acrylate, 2-hydroxycyclohexyl (meth) acrylate, (meth) propyl &quot; dilute acid fluorenyl ring Hexyl ester, 2,3-epoxycyclohexane (meth)acrylate. Among them, mercaptopropyl hexanoic acid is preferred. In the (meth) acrylate monomer which is a main component of the ethylenically unsaturated monomer B, the proportion of the above (cyclo) acrylate monomer having a cycloalkyl group is contained in the ethylenically unsaturated single In the total mass of the (meth) acrylate monomer in the bulk B, it is preferably 5% by mass or more. It is preferably 5 to 99% by mass, more preferably 5 to 80% by mass. The (meth) acrylate monomer having a % alkyl group may be used singly or in combination of two or more kinds thereof. When the (meth)acrylic acid ester monomer having a cycloalkyl group is contained in an amount of 5 mass% or more based on the total mass of the (meth)acrylic acid vinegar monomer in the ethylenically unsaturated monomer B, durability can be produced. The excellent poly-stone-oxygen-modified acrylonitrile-based resin layer is excellent in film-forming property of the poly-stone-modified acrylic latex because it is contained in an amount of 99% by mass or less. The (meth)propanamide monomer may, for example, be (mercapto) propyl galenamine, diacetone (methyl) propylamine, N-hydroxymethyl (meth) acrylamide, n-butoxy Methyl (meth) acrylamide and the like. The other (10) monomer of the mountain may, for example, be acetic acid ethyl phase, propionic acid vinyl vinegar, tert-vinyl vinyl versatate, ethenyl pyrrolidone or methyl vinyl ketone. Further, the other ethylene monomer may be a vinyl cyanide monomer, and examples thereof include: 321209 26 201003942 Acrylonitrile, methacrylonitrile, and the like. In addition, it can be exemplified by aromatic monomers such as fluorenyl styrene, chloroacetam, vinylidene, butadiene, ethylene, and the like. a mass ratio of 85 to 99.9% by mass is preferably used in the present embodiment, in the total mass of the ethylenically unsaturated monomer A and the ethylenically unsaturated monomer B. . In the emulsifier used in the present embodiment, the ethylenically unsaturated monomer which contains the acid group (-SCUH) or the sulfonate group (10) (10) has a phthalate group (-OSOsH or -OSOW). Among the ethylenically unsaturated monomers, the amount of the ethylenically unsaturated monomer is preferably - because it can achieve a high acidity of the oxygen-reducing resin layer. . . The ethylenically unsaturated monomer having a sulfonic acid group or a sulfonate group in the present embodiment may, for example, have a radical polymerizable double bond, and have a free stone yin, an acid group, or an ammonium salt or a base thereof. A compound of a metal salt group (ammonium sulfonate or alkali metal sulfonate). Preferably, a part is substituted with a group of an ammonium salt, a sodium salt or a potassium salt of a sulfonic acid group, and has a hospital group having a carbon number of 1 to 20, an alkyl group having 2 to 4 carbon atoms, and an anisotropic number of 2 to 4 a compound of a polyalkylene group, an aryl group having 6 or 1 carbon atoms, and a substituent selected from the group; or a money salt, a sodium salt or a potassium salt having a bonded thiol group; A vinyl vinyl sulfonate compound. In the present embodiment, a specific example of the succinic acid compound substituted with a group of an ammonium salt, a sodium salt or a potassium salt of a sulfonic acid group may, for example, be an allyl acid 321209 27 201003942 succinic acid salt, for example, The compound represented by the following formulas (5) to (8) R8 so3m f CH-COO- (AO)n-CH2-C=CH2I CH2-COOR9 R8I CH2-C00- (AO)n-CH2-C=CH2 CH -COOR9I so3m CH?-C00-(A0)-R9 (5) (6) R8 CH-C00-CH2-CH-CH2-0-CH2-C=CH2 (7) so3m oh OH R8 II ch-coo-ch2 -ch-ch2-o-ch2-c=ch2 CH2-COO—(AO)n-R9 (8) I so3m (In the formulas (5) to (8), R8 is hydrogen or fluorenyl; R9 is carbon number 1 a hydrocarbon group of up to 20, an alkyl group having 1 to 20 carbon atoms, a cycloalkyl group having 5 to 12 carbon atoms, an aralkyl group having 7 to 19 carbon atoms, or a hydrocarbon group partially substituted by a hydroxyl group or a carboxylic acid group Or a polyoxyalkylene alkyl ether group (the alkyl moiety has a carbon number of 1 to 20 and the alkyl moiety has a carbon number of 2 to 4) or a polyoxyalkylene alkylphenylphenyl group (alkyl moiety) a carbon number of 1 to 20 and an alkyl group having a carbon number of 2 to 4); A is a C 2 to 4 alkyl group, or a part of the alkyl group is hydrogen or a carboxyl group. The substituted alkylene group; 28 321209 201003942 M is ammonium, sodium or potassium; [eta] is an integer of 0 to 200). The emulsifier containing the compound represented by the above formulas (5) and (8) is, for example, sputum (registered trademark, manufactured by Sanyo Chemical Industry Co., Ltd.), and the like, and contains the compound represented by the above formulas (7) and (8): For example, LATEMUL S- L20, s] 8〇A, s—18〇 (made by Huahua Wang Co., Ltd.), etc. Further, examples of the compound octagonal group having a part of the aryl group substituted with a salt acid group include, for example, p-phenylene; an acid ammonium salt, a sodium salt, and a salt-removing salt. In the summer, there are some specific examples of the silk (tetra) compound substituted by Wei Yu. For example, the salt, sodium salt and unsalted salt of propylene methacrylate, propylene b acid group, ammonium salt, Nasal and potassium salts, (meth)acrylic acid = salt, sodium salt and clock salt of the ester. Soil and element C The ethylene non-n-type body having a sulfated vinegar group in the present embodiment means a compound having a radical polymerizable double bond and having a sulfate sulfate group or a salt thereof or an alkali metal salt. In this case, the number of carbons 1 to 2, the number of bases 2 to 4, and the number of carbons 2 to 4 are replaced by the base of the sulphur core, the steel salt or the (4) base. The compound selected from the group consisting of the polyalkyl group and the aryl group of the disorder I or 1G is ^, and the yoke has a part of the ammonium salt of the sulfate group, and the salt of the salt Specific examples of the compound having a carbon number of 2 to 4 or a compound having 2 to 4 carbon atoms in the formula may be, for example, the following formulas (9) to (1): 321209 29 201003942 ch=chch3 R〇^C&quot;&quot ;&quot;\ V-0-(A0)n-S03M (9) (wherein RID is an alkyl group having 6 to 18 carbon atoms, an alkenyl group or an aralkyl group; and R11 is a carbon group having 6 to 18 carbon atoms; Alkenyl, arylalkyl; R12 is hydrogen or propenyl; A is a C 2 to 4 fluorene; hydrazine is an ammonium, sodium, _ or alkoxyl residue; η is an integer from 1 to 200). R13 I ch2-o-ch2-c=ch2 I CH-0-(A0)n-S03M (10) I CH2-0-(A0), -R14 (wherein R13 is hydrogen or methyl; R14 is carbon a number of 8 to 24 alkyl, alkylphenyl or fluorenyl; A is a carbon number of 2 to 4 alkyl; hydrazine is an ammonium, sodium, potassium or alkoxyl residue; 1 is an integer from 0 to 50; η is an integer from 0 to 20). 30 321209 201003942 R15 I CH,—0-CH,-C=CH2 I ?H—R16 (11) I 0—(A0)n-S03M (wherein R15 is hydrogen or methyl; R16 is carbon number 8 to An alkyl group of 30; A is an alkylene group having 2 to 4 carbon atoms, or a hydrogen group or a carboxylic acid group substituted by a part of the alkyl group; the hydrazine is an ammonium, sodium, cesium or alkoxylamine residue. ; η is an integer from 1 to 200). The compound represented by the above formula (9) is, for example, AQUALONHS-10 (registered trademark, manufactured by Dai-ichi Kogyo Co., Ltd.), and the like (1) Examples of the compound to be shown include ADEKA REASOAP SE-1025A, SR-10N, SR-20N (product name, manufactured by ADEKA Co., Ltd.), and the compound represented by the above formula (11): for example, aqual〇n ΚΗ_1 〇, κη—〇5 (registered trademark, manufactured by Daiichi Kogyo Co., Ltd.). In the present embodiment, a vinyl-saturated monomer having an acid-reducing group, a acid-acid salt group or a sulfur (tetra) group used as an emulsifier is a state of a copolymer obtained by radical polymerization of a plate in a latex. Exist, or = in the state of the substance adsorbed to the milk scorpion or in the latex aqueous phase (4) or co-polymer with the water monomer (4) or Si:::: copolymer - gel particles IS 321209 31 201003942 It is made by radical polymerization with latex particles to have high (four) wetness.薄膜 姆 姆 所得 所得 姆 姆 化 化 化 化 化 化 化 化 化 化 化 化 化 化 化 化 化 化 化 姆 姆 姆 姆 姆 姆 姆 姆 姆 姆 μ μ μ μ μ μ μ μ μ μ μ μ μ μ μ μ μ μ In the form, it is preferable to use 〇〇5 mass% to 10 mass% with respect to the total mass of the ethylenically unsaturated monomer A and the ethyl group 1 and the monomer B, and to use 〇.丨% by mass to 5 The mass % is preferred. 1. In this embodiment, in addition to an emulsifier containing an ethylenically unsaturated monomer having a rhein acid group, a rhein acid or a sulfate group, a surfactant can be used in combination. In the case of the aforementioned surfactant, for example, a fatty acid soap, a sulfonate, a lysine, a polyoxyalkyl sulfate, a polyoxyethylene aryl sulfone crocodile Agent, polyoxyalkylene aryl aryl group, polyoxyethylene ethyl sulphate fatty acid s, oxygen sulphate pure propyl block copolymer copolymer non-ionic surfactant; MEKA REASOAP 肫-20, NE-30, Ne~4〇, ADEKA Co., Ltd.) "Seven-[(allyloxy&amp;-2-(decylphenoxy)) Ethyl]_ω_ trans-polyoxyethylene, or RN-10, RN-20, RN-30, RN-50 (registered trademark, manufactured by First Industrial Gas Co., Ltd.) Phenylphenyl (10), etc. = covalent nonionic surfactant can be co-existed with B (tetra) non-aged monomers] vice versa non-ionic surfactants, etc. /, with respect to the use of the aforementioned surfactant, relative to Ethylene 321209 32 201003942 . The total mass of monomer A and ethylenically unsaturated monomer B, and the active agent is preferably below U, 〇25 mass% ^^ non-reactive nonionic surfactant and The reactive non-offering agent is preferably 2.0% by mass or less, more preferably 1% by mass or less, and preferably the surface of the surfactant is used to form a thin right film having a good wettability. It is preferable to use a UV absorber and/or a light stabilizer in the poly-stone-oxygen-modified acrylic latex, and a poly-oxygen-modified propionic acid-based latex which is imparted with high _ properties can be obtained. The oxy olefinic latex may also be obtained by combining the photosensitizer. The ultraviolet absorber and/or the light ampere The agent is contained in the poly-stone-oxygen modified acrylic acid latex, and the ultraviolet absorber and/or the light stabilizer can be added after mixing the film-forming auxiliary agent in the poly-stone-oxygen modified acrylic acid latex. However, in order to exhibit light resistance and durability for a longer period of time, it is preferred to use an external absorbent and/or a light stabilizer in the emulsion polymerization. The ethylenically unsaturated monomer A and the ethylenically unsaturated monomer are preferred. The total mass of the body β is used as a reference, and the ultraviolet absorber and/or the light stabilizer are preferably used in an amount of 0.1 to 2% by mass, preferably 0.1 to 10% by mass. Further, the ultraviolet absorber may be used in the f molecule. In the case of a radical polymerizable group having a radical polymerizable double bond, a photopolymerization agent can be used as a radical polymerizable group having a radical polymerizable double bond in a molecule. Further, when a UV absorber and a photosensitizer are used in combination, when a film is formed using the emulsion of the emulsion, a polyoxymethylene-modified acrylic resin layer having a more excellent weather resistance of the film can be obtained. The ultraviolet absorber used in the present embodiment is preferably at least one selected from the group consisting of a benzene-based system, a benzotriazole-based system, and a triterpenoid system, and is used in the present invention by 321209 33 201003942. The light stabilizer is preferably used, for example, as a hindered m compound. Combining (4) oxygen-modified yttrium yttrium latex with excellent durability with diphenyl fluorene (IV), benzotriene, tris(4) ultraviolet absorbing drum/ or pho(A) with high UV absorption capacity, it will show excellent performance due to synergistic effect. Durability. In particular, the benzophenone-based ultraviolet absorber and the light stabilizer are exemplified by the above-mentioned benzophenone-based ultraviolet absorber, and specific examples thereof include: 2, 4-di-based benzophenone, 2_ Base + methoxydibenzoic acid (tetra), 2-cysyl-4-methoxydibenzopyrene-5-hemeic acid, 2-mono-based 4- 4-n-octyloxybenzophenone, 2-hydroxy- 4-n-dodecyloxydiphenyl fluorenone, 2-hydroxy "monobenzyloxy-benzoyl", bis(5-benzylidene-4-yl-2-ylphenyl)methane , 2, 2'-dihydroxy-4-methoxybenzophenone, 2, 2, monodihydroxy-4,4, mono-t-oxy-m-xanthone, 2, 2, 4, 4,- Tetrakilyl benzophenone g, twelve alkoxy-2-pure diphenyl (tetra), 2_county + methoxy 2, carboxyl ketone, 2-hydroxy-4-stearyloxy A benzophenone or the like. The radically polymerizable benzophenone-based ultraviolet absorber may, for example, be a 2-hydroxy-4-propenyloxybenzophenone or a 2-hydroxy-4-methylpropenyloxy group. Benzene, 2-hydroxy-5-propenyloxybenzophenone, 2-hydroxy-5-f-propenyloxydiphenyl f-net, 2,yl_4_(2-propyleneoxyl^ Oxy)diphenyl , 2 -hydroxy-4-(2-methylpropenyloxyethoxy)benzophenone, 2-hydroxy-4-(methylpropenyloxydiethoxy)diphenyl ketone, 2 - Hydroxy-4-(propylene decyloxytriethoxy)diphenyl ketone, etc. The benzotriazole-based ultraviolet absorber is specifically exemplified by: 321209 34 201003942 2-(2'-trans-based- 5'-nonylphenyl)benzotriazine, 2-(2'-trans-kily-5,-tertiary*butylphenyl)benzotriazole, 2-(2'-hydroxy-3',5 ,-bis(tributyl)phenyl)benzotriazole, 2-(2'-hydroxy-5'-tertiary octylphenyl)benzotrisole, 2-(2'-trans-yl-3 ',5'-bis(trioctyl)phenyl)benzotrisole, 2_[2, _hydroxy-3',5'-bis(α,α'-dimethylphenylhydrazino)phenyl] Benzotriazole, methyl-3-[3'-tert-butyl-5'-(2Η-benzotriazol-2-yl)-4,-hydroxyphenyl]propionate and polyethylene glycol (Molecular weight 300) condensate (manufactured by Ciba_Geigy Co., Ltd., Japan, product name: TINUVIN (registered trademark) 1130), isooctyl-3-[3'-(2H-benzotriazol-2-yl)- 5, _ tertiary butyl 4 - via basic group Propionic acid self-purpose (made by Ciba-Geigy Co., Ltd., Japan, product name: 1'1_丫11^ (registered trademark) 384), 2-(3,-d-dodecyl-5,-methyl-2 -hydroxyphenyl)benzotriazole (manufactured by Ciba_Geigy Co., Ltd., product name: TINUVIN (registered trademark) 571), 2_(2,_hydroxy_3,_tributyl-5'-methylbenzene Base gas benzotriazole, 2_(2,_hydroxy-3,5-di(tripentyl)phenyl)benzotriazole, 2_(2,_hydroxy-4, monooctyloxyphenyl)benzene And triazole, 2-[2,-hydroxy_3,_(3&quot;,4",5",6&quot;_tetrahydrofurfurimide methyl)-5-methylphenyl]benzotriazole, &amp;;2_methylenebis[4-(1,ru-tetradecylbutyl)_6,_(2}1_benzotrisole_2&quot;_base),], 2-(2H-benzo Sanfu 2, _base)_4, 6_bis(1,-methyl),-phenylethyl) (manufactured by Ciba-Geigy Co., Ltd., Japan, product name: TIN_ (registered trademark) 900). 'The free-radical polymerizable benzo-salt UV-absorbing agent can be exemplified by the death of D &amp; base _5_(2"-mercaptopropene oxyethyl) phenyl] one-n- Otsuka Chemical Co., Ltd., product name: ugly _93), 321209 35 201003942 2-[2'-hydroxy-5'-(2-methylpropenyloxyethyl)-3,_tertiary butylbenzene Benzo]-211-benzotriazole, 2-[2,-hydroxy-5,-(3-methylpropenyloxypropyl)_3-dibutylphenyl]-5-chloro-2H-benzene And triazole, 3-p-propyl-p-mentyl-2-hydroxypropyl-3-[3,-(2"-benzotriazolyl)-4,-hydroxy-5,-3-tert-butyl]benzene Propionate (manufactured by Ciba-Geigy Co., Ltd., Japan, product name: CGL-104). The benzotriazole-based ultraviolet absorber is preferably T丨N U v〖N (registered trademark) 3 8 4 . Specific examples of the ultraviolet absorbing agent of the above-mentioned three-tillage system include TINUYIN400 &gt; TINUVIN 405 ' TINUVIN 460 ' TINUVIN 477 DW ' TINUVIN 479 (registered trademark, manufactured by Ciba-Geigy Co., Ltd., Japan). The tri-grain UV absorber is preferably TINUVIN400. The light stabilizer is preferably one having a lower basicity and preferably having a basicity coefficient (1) rib of 8 or more. Specific examples thereof include a hindered amine compound and the like, and examples thereof include bis(2,2,6,6-tetramethyl-4-piperidyl) succinate and bis(2,2,6 azelaic acid). , 6-tetradecyl-4-piperidinyl), 2-(3,5-di(tert-butyl)-4-hydroxybenzyl)-2-butylmalonic acid bis (1,2 , 2, 6, 6-pentamethyl-4-piperidinyl), 1-[2-[3-(3, 5-di(tri-butyl)-4-hydroxyphenyl)propenyloxy ]ethyl]-4-[3-(3,5-di(tributyl)-4-hydroxyphenyl)propanoxy]_2, 2,6,6-tetramethylpiperidine, hydrazine Acid bis(1,2,2,6,6-pentamethyl- 4-piperidinyl) hydrazine with hydrazine monomethyl-1,2,2,6,6-pentamethyl-4-branches Mixture of esters (manufactured by Ciba-Geigy Co., Ltd., Japan, product name: (Note 321209 36 201003942) 292), bis(1-octyloxy-2, 2, 6, 6-tetramethyl-4-nithene Mercapto) sebacate, TINUVIN 123 (registered trademark, manufactured by Ciba_Geigy Co., Ltd., Japan). The free radical ^^ 之 光 光 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 可 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基 甲基Product name: ADK STAB LA82), 1,2,2,6,6-pentamethyl-4-piperidinyl acrylate, 2, 2, 6, 6-tetradecyl-4-piperidine methacrylate Ester (made by ADeka Co., Ltd., product name: ADK STAB LA87), 2, 2, 6, 6-tetradecyl-4 piperidinyl acrylate, methacrylic acid 1,2, 2, 6, 6-penta 4-Iminopiperidinyl ester, 2, 2, 6, 6-tetradecyl-4-iminopiperidine methacrylate, 4-cyano-2, 2, 6, 6 methacrylate - tetradecyl-4-pyryl ester, 4-cyano-1,2,2,6,6-pentamethyl-4-bromo ester of methacrylic acid. The light stabilizer is preferably TINUVIN (registered trademark) 123. The emulsion polymerization in the present embodiment can be carried out by subjecting an ethylenically unsaturated monomer to addition polymerization by radical decomposition using a polymerization initiator and using a heat or a reducing substance. As the above polymerization initiator for carrying out the emulsion polymerization, a water-soluble or oil-soluble persulfate, a peroxide, an azobis compound or the like can be used. Specific examples thereof include persulfate such as potassium persulfate, sodium persulfate, and ammonium persulfate; peroxides such as hydrogen peroxide, tertiary butyl hydroperoxide, and tertiary butyl peroxybenzoate; , 2_azobisisobutyronitrile, 2,2-azobis(2-diaminopropanone) hydrochloride, 2,2-azobis(2,4-didecyl valeronitrile), etc. Nitrogen double compound. It is preferred to use potassium persulfate, sodium persulfate or ammonium persulfate as a catalyst for promoting the hydrolysis reaction of the polyoxonium modifier 37 321209 201003942 and the catalyst of the condensation reaction. The amount of the polymerization initiator is usually from 0.05% by mass to 1% by mass, based on the total mass of the ethylenically unsaturated monomer A and the ethylenically unsaturated monomer. In the present embodiment, the emulsion polymerization reaction is preferably carried out at a reaction temperature of 65 to 90 ° C under normal pressure, or may be carried out under high pressure in accordance with characteristics such as a vapor pressure at a reaction temperature of a monomer or the like. In the present embodiment, the reaction time of the emulsion polymerization is adjusted in accordance with the introduction time and the cooking time after the introduction. When various raw materials are simultaneously introduced into the reaction system, the introduction time is usually several minutes. 5 When various raw materials are successively introduced into the reaction system, various raw materials are introduced into the reaction in a range in which heat generation due to polymerization can be removed. In the system, even if the introduction time varies depending on the concentration of the polymer in the latex finally obtained, it is usually 10 minutes or longer. The cooking time after the introduction is preferably at least 10 minutes or longer. Since the above-mentioned ripening time is 10 minutes or longer, it becomes a time sufficient for each raw material to react. Further, it may be made a time sufficient for the condensation to proceed after the polyoxo modifier is hydrolyzed. When it is desired to accelerate the polymerization rate and to carry out polymerization at a low temperature of 70 ° C or lower, a reducing agent such as sodium hydrogen sulfite, ferrous chloride, ascorbate or rongalite may be used in combination with a radical polymerization catalyst. It is better. Further, in order to adjust the molecular weight of the polymer in the obtained polyfluorene-modified acrylic latex, a chain transfer agent such as a decyl mercaptan may be optionally added. 38 321209 201003942 In the polyfluorene-modified acrylic latex of the present embodiment, after the emulsion polymerization is completed, the following compound may be added to the high-endurance latex to prepare a polyfluorene-modified acrylic acid. A curing catalyst for forming a resin layer, for example, dibutyltin dilaurate, dioctyltin dilaurate, dibutyltin diacetate, tin octoate, tin laurate, iron octoate, lead octoate, titanate a metal salt of an organic acid such as butyl ester; n-hexylamine, 1,8-diazabicyclo[5,4,0] ~1-~\ dilute amine compound. When such a hardening catalyst is not water-soluble, it is preferred to use a surfactant and water in advance to emulsify it when using such a curing catalyst. In the polyfluorene-modified acrylic emulsion of the present embodiment, in order to maintain a long-term stable dispersion of the latex, an amine such as ammonia water, sodium hydroxide, potassium hydroxide or dimercaptoethanol alcohol is used to adjust the pH to 5 The range of 10 is better. In the present embodiment, after completion of the emulsion polymerization, concentration may be carried out in order to evaporate and remove volatile substances, water, alcohol, and the like of the unreacted monomer. The average particle diameter of the dispersoid of the polyfluorene-modified acrylic latex in the present embodiment is preferably from 10 to 100 nm. Further, the mass ratio of the dispersing substance (solid content) in the obtained latex to the aqueous medium as the dispersing medium is preferably 70/30 or less, and more preferably 30/70 or more and 65/35 or less. In the polyfluorene-modified acrylic emulsion of the present embodiment, a film forming aid, a tackifier, an antifoaming agent, a pigment, a dispersing agent, a dye, a preservative, and the like can be optionally formulated. Specific examples of the film-forming auxiliary agent include diethylene glycol monobutyl ether, 39 321209 201003942 ethylene glycol monobutyl ether, diethylene glycol dioxime ether, diethylene glycol dibutyl ether, and ethylene glycol single 2-ethylhexyl ether, 2, 2, 4-trimethyl-1, butanediol isobutyrate, diisopropyl glutarate, propylene glycol n-butyl ether, dipropylene glycol n-butyl ether, tripropylene-fermentation Positive Ding, dipropylene glycol, mystery, tripropylene glycol, etc. These film-forming aids may be formulated separately or in any combination. A method of applying the polyfluorene-modified acrylic emulsion of the present embodiment may, for example, be a method of applying a polysulfide-modified acrylic latex and drying it. A resin film can be formed by the above method to produce a polyfluorene-modified acrylic resin layer. In this case, the concentration of the coating liquid is preferably from 1 to 70% by mass, and drying is preferably carried out between 2 and 15 (TC). The coating method of the above latex can be applied by gravure coating or wire bar coating. Various methods such as a method, an air knife coating method, a die coating method, a lip coating method, and a comfla coating method are used to perform a poly-oxygen-modified acrylic acid. The thickness of the resin layer is preferably from 〇 to 100//m, preferably from 2 〇 to 刖 (four), and from 3 〇 to 85 #m. The thickness of the poly-oxygen-modified acrylic resin layer is A solar panel excellent in durability and environmental resistance, such as durability and purity resistance, and (4) a crack which is excellent in film formation property of the poly 11 oxygen-modified acrylic resin layer; and a process in which the coating film is not easily generated in the oxygen process In order to improve film formability, a resin layer can be used. In the drying (solar battery back sheet), the "film forming aid" is described. In the present embodiment, the battery plate is attached to the substrate to cover the above-mentioned 321209 40 201003942 The solar cell back sheet is made of a laminate. The order of the layers is not limited, but specifically the substrate. A plate in which a vinylidene chloride-based resin layer is laminated and a polyfluorene-modified acrylic resin layer is laminated thereon. In the present embodiment, the vinylidene chloride-based resin layer and the polyfluorene-modified acrylic acid are modified. The resin layer is continuously laminated on the substrate (that is, a layer of a vinylidene chloride-based resin layer is laminated on the substrate, and a polyfluorene-modified acrylic resin layer is laminated thereon in a direct contact manner) The vinylidene chloride-based resin layer can be protected to have a good gas barrier property. In addition, the solar cell back sheet is economical, heat-resistant, moisture-resistant, gas-barrier, and electrically insulating. In view of various properties such as physical strength, it is preferable to laminate a vinylidene chloride-based resin layer on a plastic substrate and to laminate a polyfluorene-modified acrylic resin layer thereon. (Substrate) In the present embodiment The substrate is not particularly limited as long as it can support a laminate for a solar cell back sheet. For example, a plastic substrate is preferably used. The plastic substrate used in the embodiment is preferably a thermoplastic resin film. The aforementioned thermoplastic The lipid film is preferably a resin film which is a polycondensate of a polycondensate of a dicarboxylic acid derivative and a diol derivative. The above thermosetting resin film may be a polyethylene terephthalate or a poly(p-citric acid). A polyester resin such as a diester, a polybutylene terephthalate or a polyethylene-2,6-naphthalene diacetate. It is preferably used by using a phthalic acid and a derivative thereof as a dicarboxylic acid. The component is a polyethylene terephthalate 41 321209 201003942 resin which is a crystalline thermoplastic resin obtained by polymerizing a glycol component as a diol component by esterification reaction. These resins may be a homopolymer. It is also possible to use a copolymer or a blend. Here, the melting point of the polyester to be used is preferably 250 ° C or higher from the viewpoint of heat resistance, and 300 ° C or less from the viewpoint of productivity. It is better. Further, the heat resistant resin is preferably a biaxially stretched film composed of a high molecular weight polymer having a number average molecular weight of from 18,500 to 40,000 in order to impart hydrolysis resistance. In order to have hydrolysis resistance, the number average molecular weight is preferably as high as possible, but from the viewpoints of polymerizability, melt moldability, and biaxial elongation, it is preferred to use a polyvalent resin having a number average molecular weight within the above range. . The number average molecular weight in the present embodiment can be measured by osmometry (GPC) or the like which is generally used. The thickness of the substrate is preferably in the range of 100 to 350 // m from the viewpoint of appropriate toughness, workability, and electrical insulation of the substrate of the solar battery back sheet. Further, the substrate may be subjected to various surface treatments such as corona discharge treatment or atmospheric plasma discharge treatment, and a known adhesive such as an ester-based or amine-based adhesive may be used. Fig. 1 is a cross-sectional view showing an example of a solar battery back sheet having a laminate for a solar battery back sheet according to the embodiment. The solar battery back sheet of this embodiment will be described using Fig. 1 . As shown in Fig. 1, the solar battery back sheet 1 having a laminate for a solar battery back sheet composed of a vinylidene chloride-based resin layer 4 and a polysulfide-modified acrylic resin layer 5 has the following The structure is described in which a layer of a vinylidene-based resin layer 4 and a polysulfide-modified acrylic resin 42 321209 201003942 are laminated on the plastic substrate 2 through the adhesive 3 . Fig. 2 is a cross-sectional view showing an example of a solar battery module including a solar battery back plate of the embodiment. The solar cell module of this embodiment will be described using Fig. 2 . As shown in FIG. 2, an example of the solar battery module 6 including the solar battery back plate 1 may be, for example, a solar battery element 8 and a filling between the glass layer 7 that receives sunlight and the solar battery back plate 1. The structure of the material 9 is made. Here, the mounting direction of the back sheet is not particularly limited, but from the viewpoint of weather resistance and moisture resistance, it is preferable to use the polyfluorene-modified acrylic resin layer to the outside. When the plastic substrate layer is used as the outer side, it is preferable to provide a polyfluorene-modified acrylic resin layer on the non-layer of the plastic substrate. In this case, in order to increase the adhesion between the surface of the plastic substrate and the surface of the polyoxygen-modified acrylic resin, it is preferred to carry out the easy treatment of the surface of the plastic substrate by corona discharge treatment or the like. The solar battery back sheet of the present embodiment is provided with a laminate for a solar cell back sheet having a vinylidene chloride-based resin layer and a polyfluorene-modified acrylic resin layer laminated on the vinylidene chloride-based resin layer. It can withstand a long time in a harsh natural environment, and is excellent in various properties such as environmental resistance, heat resistance, moisture resistance, gas barrier properties, electrical insulation properties, and physical strength such as hydrolysis and finance. Moreover, the simplification of the constitution of the components and the productivity of the workability are also excellent. When the polyfluorene-modified acrylic resin layer is laminated on the vinylidene chloride-based resin layer in the form of direct contact, the above effect is particularly remarkable in the case of 43321209 201003942. Further, by manufacturing the solar cell module including the solar cell back sheet, it is possible to withstand environmental compatibility, heat and humidity which are particularly prolonged in a severe natural environment, such as chemical hydrolysis and weather resistance. A solar cell module excellent in various properties such as properties, gas barrier properties, electrical insulation properties, and physical strength. (Embodiment) Hereinafter, the present embodiment will be described more specifically by way of examples, but the present embodiment is not limited to the embodiments. Hereinafter, the "part" means "parts by mass" unless otherwise specified. [Reference Example] Hereinafter, an example of a method for producing a vinylidene chloride latex, a vinylidene chloride paint, a polyfluorene-modified acrylic latex, and a method for producing an acrylic latex for comparison are shown as reference examples. (Pre-dichloroethylene latex) (Reference Example 1) In a pressure reactor to which glass lining was applied, 100 parts of ion-exchanged water, 0.1 part of sodium alkyl sulfate, 0.9 parts of sodium persulfate were charged. After degassing, the temperature of the contents was maintained at 50 °C. In a separate container, 91.8 parts of vinylidene chloride and 7.3 parts of mercapto acrylonitrile were weighed and mixed to prepare a monomer mixture. 5份。 After adding a portion of the above monomer mixture, 3 parts of the monomer mixture was added to the above-mentioned pressure-resistant reactor. . 1份。 At this time, 44 321209 201003942 is also continuously added with the monomer. After the total amount of the monomer mixture was added, the internal pressure immediately began to decrease, and the reaction was carried out until the internal pressure was stopped to be lowered to obtain a vinylidene chloride latex [A]. (Reference Example 2) In a pressure-resistant reactor to which a glass lining is applied, 100 parts of ion-exchanged water, 0.1 part of sodium sulphate, and 0.9 parts of sodium persulfate are charged, and the contents are removed after degassing. The temperature was maintained at 50 °C. In a separate container, 89.0 parts of dichloroethylene, acrylonitrile 8.5 parts, decyl decyl acrylate 1, 1.4 parts were weighed and mixed to prepare a monomer mixture. 5份。 After adding a residual monomer mixture of 95. 9 parts. 1份。 At this time, the monomer is also continuously added 0.1 parts of hydrogen sulfite. After the total amount of the monomer mixture was added, the internal pressure immediately began to decrease, and the reaction was carried out until the internal pressure stopped decreasing to obtain a vinylidene chloride emulsion [B]. (Pre-dichloroethylene fine lacquer) (Reference Example 3) 300 g of the aqueous dispersion of the vinylidene chloride latex [A] obtained in Reference Example 1 was intermittently dropped into a small amount to be heated to 60°. After 1000 g of a 3% aqueous solution of C was chlorinated, the resulting aggregate was washed with water and dried to obtain a white powder. 50 g of the powder of the squirrel-removing resin obtained in this manner was added to 500 g of a mixed solvent of tetrahydrofuran:toluene=2:1, followed by stirring for 30 minutes. After the partial ethylene gas-based resin was completely dissolved, an amine ester-based adhesive (Mitsui 45, 321209, 201003942) A511 _ was added to obtain the main ingredient "TAKEUC" (Note / Hardener "A50" = 10) /1) 1.5g, then stir for 5 minutes, dichloroethylene paint [C]. (Polyoxime-modified acrylic latex) (Reference Example 4) In the reaction volume 2 equipped with a scrambler, a reflux cooler, two dropping tanks, and a thermometer, 5G.8 parts of water and "Shun LQNKIMq" were injected. 5份。 2% of the aqueous solution of the 2% aqueous solution of the persulfate was added to the mixture. After the addition of 5 minutes, the step (1) is to mix methyl methacrylate &amp; 378 parts, cyclohexyl methacrylate 14. 5 parts, methacrylic acid by a homo mixer. N-butyl ester 17. 5 parts, 14 parts of butyl acrylate, cesium methacrylate. 622 parts, "TINUVIN 384" (registered trademark 'Japan Ciba-Geigy Co., Ltd.) 1.2 parts, "TINUVIN123" (registered trademark, Japanese ciba -Geiger Co., Ltd.) 0. 6 parts, "AQUALON KH-10" 3 parts, "EMULGEN 120" (registered trademark, Kao Co., Ltd., 2% aqueous solution) 2 parts, 2% aqueous solution of ammonium persulfate 2. 5 parts, water 26.2 parts of the emulsion, and T-methyl propylene methoxy propyl trimethoxy decane 〇. 578 parts, methyl trimethoxy decane 2 · 111 parts, two A mixture of methyl methoxy decane 3. 378 parts was separately dropped into the reaction vessel from an individual dropping tank for 9 minutes. The temperature of the reaction vessel was maintained at 8 ° C for 3 minutes, and then proceeded to step 46 321209 201003942 (2), which was mixed with methacrylic acid by uniformly mixing 5.25 parts of mercapto-acrylic acid ring for 5 minutes. Fork, butyl acrylate (4), 4 parts, part, butyl methacrylate 7 parts, field 4, soil acid bismuth. 5 parts 'acrylic acid 〇. 5 parts, 2-hydroxyethyl hydrazide hydrazine FTi in nc-1. 15 parts, acrylamide oxime · 2 parts, "AQUALON KH-10" 〇. 6 parts, 1 part of ammonium persulfate 4lJ aqueous solution, water; [4. 6 parts of the emulsion prepared from the drop The sample was injected into the reaction vessel for 45 minutes. Ml at 8 ° C for 30 minutes, and then proceed to step (3), which will be mixed by a uniform mixing of R 〇〇 9m ^ &quot; machine for 5 minutes mixed methyl methacrylate 6. 822 parts, methacrylic acid ring酉曰9 parts, n-butyl decyl acrylate 10.5 parts, butyl acrylate 3. 3 parts, a dung work β „. r τ violent acrylic acid 0.378 parts, “TINUVIN384” 〇·8 parts, “TINUVIN123” 〇 4 8 "" υ. 4 parts, "AQUALONO-10" 0.9 parts, 2% aqueous solution of ammonium persulfate, VIII, i. 5 wounds, water 4.6 parts and made of emulsified ^ and methyl propyl hydrazine A mixture of oxypropyltrimethoxy sulphide 0.138 ketone-methoxyl h h 267 parts and dimethyldimethoxy shixiyuan was added to the individual drip tanks for a minute and a minute. In the reaction vessel. π will, the temperature should be maintained at 8 谷. . After 9 minutes, it was cooled to room = effect ^^> agricultural degree and the result was pH 2.3. A 25% aqueous ammonia solution was added to obtain a poly-modified acrylic latex W. I Reference Example 5) In a reaction vessel equipped with a scrambler, a reflux cooler, two drip tanks and a thermometer, 庐1 slaves are difficult 59, 5 copies with "ADEKAREASOAPSR-10N 丨 (ADEKa shares limited, "H _ Du Fu t, 25% aqueous solution) 3 · 2 parts, and the reaction capacity of the fox is maintained at 8 (Γγ, adding 2% aqueous solution of ammonium persulfate 1. 5 parts. 321209 47 201003942 after 5 minutes of addition' Step (1) is to use a homogenous mixer to know the methacrylic acid by 5 knives (J. 375 parts, 5 parts of decyl hexamethacrylate, butyl methacrylate 17 5) , acrylic acid 2 ethyl hexanoacetate · 5 · 5 G, 625 parts of acrylic acid, 2 parts of "ADEU REASOAP SR-1GN", EMULGEN 120" 2 wounds, 25 parts of 2% aqueous solution of persulfate, 25 parts of water, 30 parts of water, and 7_ a mixture of methyl propionoxypropyl dimethoxy Wei G · 578 parts, methyl trimethoxy Wei 2. 111 parts, and dimethyl dimethoxy decane 3.378 parts, respectively, from individual drops The tank was added to the reaction vessel at a time of 90 minutes. The temperature of the reaction vessel was maintained at 8 〇t3 〇 minutes, and then the step (2) was carried out by mixing 1 part of styrene, 7 parts of methacrylate, and methacrylic acid ring by a uniform machine for 5 minutes. 2 parts, 7 parts of n-butyl methacrylate, 2% ethyl hexanoate, propyl methacrylate, 5 acryls, 0. 5 wounds, acetamide 0.2 parts , "ADEKA REASOAP SR-Shun" 0_4 parts, 2% aqueous solution of persulfate recorded 〇. 5 parts, water i9. 2 parts of the emulsion was dripped into the reaction vessel from the drip tank for 45 minutes. The reaction vessel temperature was maintained at 8 (rc 3 〇 minutes, and then the step (3) was carried out by mixing the methyl methacrylate methyl vinegar by a homomixer for 5 minutes. 3 parts of g, 1 part of thioglycolic acid, 1 part, 5 parts of propylene oxime, 1.425 parts of ethyl hexyl ester, 0.375 parts of acrylic acid, 1 part of "TINUVIMGG", 1 part of "T_VIN123", 5 parts, "历A REAS〇Ap SR-10N"0. 6 parts, 2% aqueous solution of ammonium persulfate 〇: 75 parts, water 218.3 parts of the emulsion, and the base propylene propylene oxypropyl three曱321209 48 201003942 oxydecane 0. 138 parts, Jiaqi Ertianyi # dimethoxy shi shochu 2 〇 22 / — 曱 基 基 夕 夕 U U 267 份 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Individual drop temperature was adjusted to PH8 R, and the product -,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, 8 parts of water, 5 parts of water, and 133 parts of "Newcol 707SF" (3〇% aqueous solution made by Nippon Dairy Co., Ltd.), and the reaction was carried out in a machine, a reflux condenser, a two-drip tank, and a thermometer. The capacity of the vessel is maintained at '5% by weight of the 2% aqueous solution of the added sulfuric acid. After 5 minutes of addition, the step (1) is to mix the methacrylic acid with a 5 hr. 875 parts, methacrylic acid ring is known, butyl acrylate 20.5 parts, bismuth methacrylate 625 parts, "Newcol707SF" 2.5 parts, "EMULGEN 12" 2 parts, ammonium persulfate 2 An aqueous solution of 2.5 parts by weight of water, 2.5% of water, and 353 parts of methacryloxypropyltrimethoxydecane, 1.277 parts of decyl-methoxydecane, dimethyl Dioxane oxirane 2. 〇38 parts of the mixture was poured into the container from the individual dropping tank for 9 minutes. 夂 The temperature of the reaction vessel should be maintained at 8〇〇c 3〇 minutes. Then, 沭(2)' is used to mix methacrylic armor = 4.37 parts, cyclohexyl methacrylate 1 part, n-butyl methacrylate by a homomixer for 5 minutes, knowing Butyl acrylate 2_33 parts, bismuth methacrylate 5 parts, propylene sulphide 1 49 321209 201003942 parts, 2-hydroxyethyl methacrylate 2 parts 2 parts, 1 part of 'Newco1707317', 1% aqueous solution of ammonium persulfate and 14.4 parts of water were added to the reaction container for 45 minutes from the time of dropping into the tank. The reaction temperature is maintained at 8 °C for 3 minutes, and then the step (3) is carried out. 'The mixture will be mixed with methyl methacrylate for 3 minutes by a homomixer. 3.165 parts, cyclohexyl methacrylate 15 parts, butyl acrylate 1 〇. 86 parts, f&quot; methacrylate 〇. 375 parts, 2-hydroxyethyl methacrylate 0.6 parts, "TINUVIN123" 0.49 parts, "Newc 〇 17 〇 7 SF" j parts , "AqUAL〇n KH-10" 0. 24 parts, 2% aqueous solution of ammonium persulfate, 5 parts, 15 parts of water, and an emulsion prepared from γ-mercaptopropenyloxypropyl A mixture of 0.084 parts of trioxane decane, 0.761 parts of decyltrimethoxydecane, and 1.223 parts of decyl methoxy decane was separately dropped into the reaction vessel from an individual dropping tank for 60 minutes. in. , Maintain the temperature of the reaction vessel at 80 Χ: 90 minutes, then cool to chamber v. 5。 The result of measuring the hydrogen ion concentration is pH2.3. A 25% aqueous ammonia solution was added and the mixture was adjusted to pH 8.5 to obtain a polysulfide-modified acrylic latex [c]. (Reference Example 7) In the ampoules with a scrambler, a reflux cooler, two dropping tanks, and a thermometer, the water was injected in 59.6 parts with "ADEKAREAS〇ApsR_1〇N" 3. 2 parts, and the reaction was carried out. The container temperature was maintained at 8 (rc, 1.5 parts of water glutamate solution added with ammonium persulfate. After 5 minutes of addition, step (1) was to mix 11381 parts of methyl methacrylate by a homomixer for 5 minutes. , methacrylic acid cyclohexan vinegar 5 50 321209 201003942 parts, n-butyl decyl acrylate 17. 5 parts, 2 - ethylhexyl acrylate 15. 5 parts, acrylic acid 0. 619 parts, "ADEKA REAS 〇 AP SR_1 〇 N 2, "EMULGEN120" 2 parts, 2% aqueous solution of ammonium persulfate 丨. 25 parts, water 30. 0 parts of the emulsion, and decyl tridecyl decane 0. 417 parts, dimethyl A mixture of dimethoxy-hybrid Q. Natal is separately dropped into the reaction vessel from an individual dropping tank for 9 minutes. The temperature of the reaction vessel is maintained at 3 minutes, and then the step (2) ), which will be mixed with styrene acetonate, 7.8 parts of methyl acetonate methyl ketone in 5 minutes by means of a uniform sentence machine, 曱 曱2 parts of propylene glycol hexanoic acid, 7 parts of methyl propylene glycol n-butyl vinegar, 1 part of 2-ethylhexyl acrylate, 0.5 parts of methacrylic acid, 5 parts of acrylic acid, 5 parts of ruthenium amine Q 2 4 parts, "King KA comfort SR-10N" 0. 4 parts, 2% aqueous solution of ammonium sulphate. 5 parts, sputum 9 · 2 parts of the emulsion was dripped into the tank for 45 minutes. In the reaction vessel, the temperature of the reaction vessel is maintained at the age of 5%, and then the step (3) is carried out, and the methacrylic acid methyl ketone is mixed by a uniform of 5 minutes. 3 parts of ester, 1 part of 5 parts of n-butyl methacrylate, 1.425 parts of 2-ethylhexyl acrylate, 375 parts of acryl, TINUVIMGG"1 part, "TINUVIN123" Q. 5 parts, "a grandfather area ρ SR-10N"0. 6 parts, 2% aqueous solution of ammonium persulfate 〇. 75 parts, water 2i8. 3 parts to prepare, emulsion, and 67 parts of methyltrimethoxy heteroglycol, ~methyl-A A mixture of oxymethanol 1 〇 9 parts was separately dropped into the reaction vessel from an individual dropping tank for 60 minutes. The temperature of the reaction vessel was maintained at 8 Torr for 9 minutes, then cold. To room 51 321209 201003942 temperature. The hydrogen ion was adjusted to pH 8.5, and the result was pH 2· 1 2 3 4. Add 25% ammonia solution (Reference Example 8) to obtain polyfluorene-modified acrylic latex [d In the installation of the stirred reaction vessel +, after the cooling, the solid drop into the tank and the thermometer at 7 (TC, step, water, 164.9 parts, and maintain the temperature of the reaction vessel, the ruthenium acrylate system is added by Mixing 3 parts of dilute acid n-butyl vinegar, 9 parts of methyl propylene hexanoic acid, and methyl propyl "AQMLON KIJ1 〇 酸 酸 酉 、 、 、 、 、 、 6 6 6 6 6 6 And the preparation of the milk Lv, "Zhu GEN12Q" 3 parts, water 34 · 4 base equipment 心. Heart = and i methacryloxy propyl methoxy methoxy oxysyl asa 21 423 2: milk based Wei 33.52 The temperature of the dimethyl and dimethyl storage containers was maintained at 5.057 parts of trimethoxy. The reverse and L' were added with persulfate as a 2% aqueous solution of 4.5. The wound was adjusted to a temperature of 0 minutes. / Maintain the reaction valley to 8 degrees.匸, then proceed to step (2), which will mix methacrylate methacrylate hydrazine portion, 21 parts of cyclohexyl methacrylate, 7 parts of n-butyl methacrylate, and acrylic acid by a uniform (10) machine for 5 minutes. 13 parts of butyl vinegar, methyl propyl citrate 2. Η, a portion of propionate, 2. 2 parts of methacrylic I 2-hydroxyethyl ester, 2 parts of enediamine oxime · 2 parts, "TINUVIN 4 〇〇" 321209 1 part, "TM_123" 0.5 parts, "A_L〇NKH-1〇" 3·2 parts, 2 "Ε祖 GEN!20" 2 parts, water 45. 而份的制成液, 3 and r-Methyl propylene methoxy propyl trimethoxy I G133 parts, methyl 4 trimethoxy hydride 22 · 346 parts, dimethyl dimethoxy Wei 14 282 parts, 5 phenyl monomethoxy "戌3.371 The mixture of chopped and cut ingredients was dropped into the reaction vessel from the dropping tank of 201003942 for 90 minutes. The temperature of the reaction vessel was maintained at 80 ° C for 90 minutes and then cooled to room temperature. 7。 The hydrogen ion concentration was measured as a pH of 2. 7. After adding a 25% aqueous ammonia solution to the mixed liquid and adjusting to pH 10, the mixed liquid was returned to a reaction vessel which can be decompressed, and heated at 80 ° C for 3 hours. Then, after adding an appropriate amount of the antifoaming agent, the inside of the vessel was depressurized to 40 kPa, and concentrated until the solid content became 45%. 5。 After cooling to room temperature, the hydrogen ion concentration was measured as a pH of 7.9. After that, the pH was adjusted to 8.5 by adding a 25% aqueous ammonia solution to obtain a polyfluorene-modified acrylic latex [e]. (Reference Example 9) In a reaction vessel equipped with a stirrer, a reflux condenser, two dropping tanks, and a thermometer, 97.5 parts of water and "AQUALON HS-10" (registered trademark, First Industrial Pharmaceutical Co., Ltd.) 5份。 2% aqueous solution of ammonium persulfate was added to the solution. After the addition of 5 minutes, the step (1) is to mix 18.1 parts of methacrylate, 11 parts of n-butyl methacrylate, and 0.11 parts of butyl acrylate by a homomixer for 5 minutes. Acetic acid 0.6 parts, "TINUVIM00" 3. 5 parts, "TINUVIN123" 1 · 75 parts, "AQUALON HS-10" 6.4 parts, "EMULGEN 120" 2 parts, 2% aqueous solution of ammonium persulfate 2 5 份份, ethoxypropyl methoxy decane, 537 parts, methyl trimethoxy oxalate, 54. 825 parts, A mixture of 21.9 parts of dimethyldimethoxy decane and 5.55 parts of diphenyldimethoxy decane was dropped into 53 321 209 201003942 from the individual dropping tanks into the reaction vessel for 90 minutes. The reaction vessel temperature was maintained at 80 ° C for 30 minutes, and then step (2) was carried out by mixing 7 parts of decyl methacrylate, 7 parts of cyclohexyl methacrylate, and methyl group by a homomixer for 5 minutes. 2 parts, "AQUALON HS-10" 4 parts, butyl acrylate, 1.5 parts, methacrylic acid, 1.5 parts, acrylic acid, 0.4 parts, 2-hydroxyethyl methacrylate, 1 part, acrylamide 0. 2 parts, "AQUALON HS-10" An emulsion prepared by dissolving 1 part of a 2% aqueous solution of ammonium persulfate and 31.8 parts of water was dropped into the reaction vessel for 45 minutes from the time of dropping into the tank. The reaction vessel temperature was maintained at 80 ° C for 30 minutes, and then step (3) was carried out by mixing 10.4 parts of decyl methacrylate, 13 parts of cyclohexyl methacrylate, and sulfhydryl group by a homomixer for 5 minutes. 6.1 parts of n-butyl acrylate, 0.5 parts of acrylic acid, 1.5 parts of "TINUVIN400", 5 parts of "TINUVIN123" 0. 75 parts, 0.3 parts of "AQUALON HS-1G", 1.5 parts of 2% aqueous solution of ammonium persulfate, 36.4 parts of water to prepare an emulsion, and T-mercapto propylene methoxy propyl trimethoxy decane 0. 179 parts, methyl trimethoxy decane 18. 275 parts, dimercapto dioxin A mixed liquid of 7.3 parts of decane and 1.85 parts of diphenyldimethoxy decane was dropped into the reaction vessel from an individual dropping tank for 60 minutes. The temperature of the reaction vessel was maintained at 80 ° C for 90 minutes and then cooled to room temperature. 6。 The hydrogen ion concentration was measured as a pH of 2. 6. After adding a 25% aqueous ammonia solution to the mixed liquid and adjusting to pH 10, the mixed liquid was returned to a reaction vessel which can be decompressed, and heated at 80 ° C for 3 hours. Then, after adding an appropriate amount of the antifoaming agent, the inside of the vessel was depressurized to 40 kPa, and concentrated until the solid content became 45%. After cooling to room temperature, the hydrogen ion concentration of 54 321209 201003942 was measured, and the '' mouth was pH 8. j, the pH was adjusted to 8.5 by adding a 25% aqueous ammonia solution, and the poly-oxygen-modified acrylic latex was known. [f]. (Cang test example 10) In the women's clothing mixer, reflux cooler, drip tank and thermometer reaction, the pirates 1 liters of human water and 12 burning base (4) 5 parts, and maintain the temperature of the reaction vessel 85t. Then, by the homogenous mixer, the "dimethyl-form" (1⁄4-form diterpene oligo-oligomer 3-mer to 7-mer oxime) 85-injured, Τ-methacryl 15% of the oxypropyltrimethoxy sulphide sinter: 12 parts of the 12-sodium sulphonate, and the mixture of water is pre-mixed, and then 35 〇kg by the homogenizer. The ink of cm2 was cut to make a poly(iv) emulsion, and the emulsion of the Juxian County was dropped into the reaction vessel from the time of dropping into the tank for 3 hours. After the completion of the dropping, the temperature was maintained for 1 hour and then cooled to room temperature. The poly-xyloxy latex was obtained by neutralization with an aqueous solution of hydrogen (IV). Further, 62 parts of the polyoxyl latex, "LATEMULS_18〇A" (a registrar (20% aqueous solution, manufactured by Kao Co., Ltd.), and 85 parts of water were placed in another reaction vessel, and the temperature was raised to 70. 3 parts of a 2% aqueous solution of ammonium persulfate was added. After 5 minutes of addition, 32 parts of methyl methacrylate, 3 parts of n-butyl methacrylate, and 2 - ethyl hexyl acrylate were added dropwise over 4 hours. 23, for example, methyl propyl benzoate 2-light ketone g, 1 part, 2 propylene propylene amine 3 parts, 2 parts methacrylic acid, r-mercapto propylene methoxy propyl trimethoxy decane 2 parts , "TINUVIN400" 0.5 parts, "TINUVIN123" 0. 25 parts mixture. ^ After the temperature of the reaction thieves was maintained at 70 ° C for 1 hour, the temperature was raised to 8 〇 321209 55 201003942 · °C and maintained for 1 hour. After cooling to room temperature, the pH was adjusted to 8.5 by adding a 25% by mass aqueous ammonia solution to obtain a polyfluorene-modified acrylic latex [g]. (Reference Example 11) A mixer, a reflux cooler, and a drop were installed. In the reaction vessel of the tank and the thermometer, 70 parts of water, "ADEKAREASOAPSE-1025A" (ADEKA shares limited company) System, 25% aqueous solution) 8 parts, and the temperature of the reaction vessel was maintained at 80 ° C, and 15 parts of a 2% aqueous solution of persulfate was added. After 5 minutes of addition, 'Step (1) is to mix 25 parts of methyl methacrylate, 40 parts of cyclohexyl methacrylate, 15 parts of butyl acrylate, 2-ethyl acrylate by a homomixer for 5 minutes. 15 parts of hexyl ester, 2 parts of 2-hydroxyethyl methacrylate, 3 parts of acrylic acid, 5 parts of rTINUVIN4〇〇. 5 parts, 0. 25 parts of "TINUVIN123", 4 parts of "ADEKA REASOAPSE-1025A", 30 wounds of water The prepared emulsion was dropped into the reaction vessel from the time of dropping into the tank for 3 hours. Thereafter, the temperature of the reaction vessel was raised to 90 t for 2 hours, then cooled to temperature, and adjusted to 25% aqueous ammonia solution. Then proceed to step (2), after adding 7-glycidoxypropyldimethoxymethyl group 1 part, glycidoxypropyl triethoxy group 2 parts, strong Lin 1 hour . Then, after adding 6 parts of methyltriethoxymethane and 2 parts of acetamidine, the mixture was heated to a temperature of 3 hours to carry out polycondensation. Thereafter, the mixture was cooled to room temperature to obtain a poly 11 oxygen-modified acrylic latex [h]. (Reference example 12) In the installation of _ machine, reflux cooling H, drip tank and thermometer anti-321209 56 201003942 in the container ^ ^ history into the water ^ and the factory Yang (10) gossip as if 邡 ^ (10)" ^ * , "EMULGEN 1108S" (registered trademark, Kao Co., Ltd., 25% aqueous solution) 2.4 parts, 1 part of styrene, the reaction vessel is warmed up to the redundancy step (1) will be by a homomixer Methyl methacrylate was mixed for 9 minutes, 9 parts, 10 parts of cyclohexyl methacrylate, 15.6 parts of 2-ethylhexyl acrylate, 1.5 parts of acrylic acid, and "ADEKA REASOAP SR~i〇N 1.8 parts" And the 5% aqueous solution of potassium persulfate aqueous solution was added to the reaction vessel. At the same time, the reaction vessel temperature was raised to 8 费 at a time of 15 minutes. After that, the reaction is repeated at 8〇〇c. After maintaining at 80 C, 55 8 parts of the remaining emulsion was dropped into the reaction vessel 80 minutes from the time of dropping into the tank. After the dropwise addition, it was also maintained at 8 〇t: 3 〇 minutes, and 5 parts of a 25% aqueous ammonia solution was added, and it was maintained for 1 {) minutes. Then, 'Step (2) is to mix 29.5 parts of methyl methacrylate by a homomixer for 5 minutes, 10 parts of cyclohexyl methacrylate, 15.5 parts of 2-ethylhexyl acrylate, "ADK STAB LA82 (part of ADEKA Co., Ltd.), 0.5 parts, r-methacryloxypropyltrimethoxy decane oxime 5 parts, "ADEKA REASOAP SR-10N" 1.8 parts, "EMULGEN 1108S" 1.8 parts, water 17. 3 parts of the emulsion was made at 8 〇.滴 Drop into the reaction vessel from the time of dropping into the tank for 10 minutes. After the dropwise addition, the temperature was maintained at 80 ° C for 60 minutes, and then cooled to room temperature to obtain a polyoxygen modified acrylic latex [丨]. (Reference Example 13) 57 321209 201003942 • Installation (4) mixing machine, reflux cooler, drip tank and thermometer in the reaction state, input water 59.6 parts, "ADEKA REAS〇Ap SR_1〇N" 3.2 parts 'And maintain the temperature of the reaction vessel at 8 (TC, 1.5 parts of a 2% aqueous solution of ammonium persulfate added. After 5 minutes of addition), step (1) will be mixed with methacrylate for 5 minutes by a homomixer. 11.381 parts, Cyclohexyl methacrylate 5 injury, 17.5 parts of n-butyl methacrylate, 155 r parts of 2-ethylhexyl acrylate, 619 〇 619 parts, 2 parts of "ADEKA REASOAP SR-10N" Two parts of "EMULGEN 120", 2% aqueous solution of ammonium persulfate, 25 parts of water, and 30.0 parts of water were added to the reaction container from the drip tank for 9 {) minutes. The temperature of the reaction vessel was maintained at 8 ° C for 3 minutes, and then step (2) was carried out. 'This was to mix 1 part of styrene, 7.8 parts of methyl propylene glycol citrate, and methyl group by a homomixer for 5 minutes. 2 parts of cyclohexyl acrylate, 7 parts of n-butyl methacrylate, 2 parts of 2-ethylhexyl acrylate, hydrazino acrylate. 5 (parts, 0.5 parts of acrylic acid, propylene oxime) 2 parts, "ADEKA REASOAP SR-IGN" 0. 4 parts, 2% aqueous solution of ammonium persulfate G. 5 parts, water 19. 2 The emulsion prepared by the injection is dripped into the tank for 45 minutes. To the reaction vessel, the temperature of the reaction vessel was maintained at 8{rc 3 〇 minutes, and then the step (3) was carried out by mixing the methacrylate methacrylate in a uniform mixer for 5 minutes. 3 parts of cyclohexyl ester, 1 part by weight of n-butyl methacrylate, 1.425 parts of 2-ethylhexyl acrylate, 375 parts of acrylonitrile, 1 part of "TINUVIN400", 0.5 parts of "TINUVIN123", "ADEKA" REASOAP 58 321209 201003942 SR-10N" 0 parts, 2 parts of ammonium persulfate 2% aqueous solution 0. 75 parts, 218 parts of water, the emulsion prepared by dropping into the tank for 60 minutes The acryl latex is obtained by adding a 25% aqueous ammonia solution to pH 8.5, and adjusting to a pH of 8.5. In this 100 parts of the acrylic latex, 2 parts of a poly-xyloxy latex "KM-785" (manufactured by Shin-Etsu Chemical Co., Ltd.) was blended to obtain a poly-xyloxy-modified acrylic latex [j]. Latex) (Reference Example 14) In a reaction vessel equipped with a stirrer, a reflux condenser, two dropping tanks and a thermometer, 50. 8 parts of water and "AQUALON KH-10" (registered trademark, First Industrial Pharmaceuticals Co., Ltd.) 1 part, 25% aqueous solution), and the temperature of the reaction vessel is maintained at 80 ° C, adding 2% aqueous solution of ammonium persulfate 1. 5 parts. After 5 minutes of addition, step (1) will be The homomixer was mixed with 3.78 parts of methacrylate, 14.5 parts of cyclohexyl methacrylate, 17.5 parts of n-butyl methacrylate, 14 parts of butyl acrylate, and methacrylic acid. 622 copies, "TINUVIN384" (registered trademark, Japan Ciba-G 2-1, "TINUVIN123" (registered trademark, manufactured by Ciba-Geigy Co., Ltd., Japan) 0.6 parts, "AQUAL0N KH-10" 3 copies, "EMULGEN 120" (registered trademark, Kao) 2 parts, 2% aqueous solution of ammonium persulfate, 2 parts, 25% aqueous solution of ammonium persulfate 2. 5 parts, water 22.6 parts of the emulsion was dropped into the tank 90 minutes from the time of dropping into the tank 59 321209 201003942 Reaction vessel in. The reaction vessel temperature was maintained at 80 ° C for 30 minutes, and then the step (2) was carried out by mixing the decyl methacrylate 5.25 parts, cyclohexyl methacrylate 6 parts by a homogenous mixer for 5 minutes. 5份, 丙烯 0 0 0 . 15 正 正 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱 曱2 parts, "AQUALON KH-10" 0.6 parts, 1 part of a 2% aqueous solution of ammonium persulfate, and 14.6 parts of water were added dropwise to the reaction container for 45 minutes from the time of dropping into the tank. The temperature of the reaction vessel was maintained at 80 ° C for 30 minutes, and then the step (3) was carried out by mixing 822 parts of methacrylate, 9 parts of cyclohexyl methacrylate, by a homomixer for 5 minutes. 5 parts of n-butyl methacrylate, 3.3 parts of butyl acrylate, 0.3 parts of methacrylic acid, 378 parts, "TINUVIN384" 0. 8 parts, "TINUVIN123" 0 · 4 parts, "AQUALONKH-10" 0 9 parts, a 2% aqueous solution of ammonium persulfate, 1.5 parts, and 14.6 parts of water were dropped into the reaction vessel 60 minutes from the time of dropping into the tank. The temperature of the reaction vessel was maintained at 80 ° C for 90 minutes and then cooled to room temperature. 5。 The result of measuring the cerium ion concentration is pH2.3. The acrylic latex [k] was obtained by adding a 25% aqueous ammonia solution to pH 8.5. Hereinafter, a description will be given of a production example of a coating method in which a polyfluorene-modified acrylic emulsion and a pigment are mixed. (pigment paste) (Reference Example 15). In a 1 L stainless steel container, a dispersant (SN-Dispersant 5027/20%, manufactured by SAN NOPCO Co., Ltd.) was added. 5 g, 60 321209 201003942 propylene glycol 49 g, After water 310.42 g and ammonia water (25%) 12, the mixture was stirred using a THREE ONE MOTOR. While stirring, 700 g of titanium oxide (Tipure R-706) was added thereto, and 6 g of an antifoaming agent (SND_131〇) was added thereto, and the mixture was shaken for 30 minutes. 1 kg of glass beads (spherical beads of 1 mm in diameter) were placed in the slurried slurry, and 4 discs of dispersing discs were installed in a batch type table sand mill manufactured by Kanpe Hapi Co., Ltd. The i490 rpm was further dispersed for 20 minutes to obtain a pigment syrup [曱] having a pigment concentration of 65%. (Reference Example 16) A pigment paste [B] was obtained in the same manner as in Reference Example 15 except that the titanium oxide was changed to zinc oxide. (Reference Example 17) A pigment paste [C] was obtained in the same manner as in Reference Example 15 except that the titanium oxide was changed to calcium carbonate (BRILLIANT 15). (enamel paint) (Reference Example 18) In a polyfluorene-modified acrylic latex [a] (40% solids) 54. 35g, one side is added with one side to add a filming aid (butyl road) After su/water = 1 / 1) 5 g, stir for 10 minutes. After 5 g of a film forming aid (CS-12 (manufactured by TEXAN0L / CHISS0 Co., Ltd.)) was added thereto, the mixture was further stirred for 10 minutes. Then add pigment paste [曱] (pigment concentration: 65%) 25. 64g, ADEKA N0L UH-438 (10%) 0. 6g and stir for 5 minutes to obtain enamel paint [1] (PWC = 40%) ° (Reference Example 19) 61 321209 201003942 Similarly to (5), the enamel paint [2] was obtained by the method of the reference example ί8. (Reference Example 20) (10) The m pigment paste was changed to (5), and the enamel paint [3] was obtained by the same method as in Reference Example 18. In order to obtain the bismuth chloride emulsion obtained in the test cases i to 3 [magic, (8) and the oxygen obtained in Reference Examples 4 to 14], and the enamel coating obtained in the tea samples 18 to 20 [ 1] to [3], manufacture solar cell backsheets as described below. In addition, the solar cell back sheet is used to manufacture a solar cell (four). (Example 1) One side of the hydrolysis-resistant polyester film "Lumirr〇r xl〇s" (registered trademark, manufactured by Sung Y Corporation, thickness 188 (10)) was coated at a coating amount of 5 g/m 2 using a gravure coater. (4) Adhesive (TAKELAC (registered trademark) A5U" manufactured by Mitsui Takeda Chemical Co., Ltd. / hardener "A50" = 10/1). Then, a vinylidene chloride latex was applied by using an air knife coater so that the thickness of the ethylene-containing ethylene resin layer became 11. After 40 hours of heat formation at 40 C, 'then, a poly-coating oxygen-modified acrylic latex was coated by using a die coater so that the thickness of the most oxidized propylene I (tetra) lipid layer became 54/zm. ] 'And get the solar cell backplane shown in Figure 1. Then, the glass layer on the surface irradiated with sunlight and the solar cell back sheet were used for the inner surface, and were filled with ethylene-vinyl acetate copolymer resin 321209 62 201003942 "SOLAR EVA" (manufactured by Mitsui Chemicals Fabro Co., Ltd.). The solar cell element is sandwiched between the materials, and the solar cell module using the solar cell back sheet shown in Fig. 2 is obtained. (Example 2) A solar cell backsheet and a solar cell module were produced in the same manner as in Example 1 except that the thickness of the vinylidene-based vinyl resin layer was 25/m. (Example 3) A solar cell back sheet and a solar cell module were produced in the same manner as in Example 1 except that the thickness of the polyfluorene-modified acrylic resin layer was 81 km. . (Example 4) A solar cell backsheet and a solar cell module were produced in the same manner as in Example 1 except that the polyfluorene-modified acrylic latex was changed to [b]. (Example 5) A solar cell backsheet and a solar cell module were produced in the same manner as in Example 1 except that the polyfluorene-modified acrylic latex was changed to [c]. (Example 6) A solar cell back sheet was obtained in the same manner as in Example 1 except that the vinylidene chloride latex was changed to [B] and the polyfluorene-modified acrylic latex was changed to [d]. With solar battery modules. (Example 7) 63 321209 201003942 The sun was obtained in the same manner as in Example 1 except that the vinylidene chloride latex was changed to [B] and the polyfluorene-modified acrylic latex was changed to [e]. Battery backplane and solar battery module. (Example 8) A solar cell back sheet was obtained in the same manner as in Example 1 except that the vinylidene chloride latex was changed to [B] and the polyfluorene-modified acrylic latex was changed to [f]. With solar battery modules. (Example 9) A solar cell back was produced in the same manner as in Example 1 except that the vinylidene chloride latex was further changed to [B] and the polyfluorene-modified acrylic latex was changed to [g]. Board and solar battery module. (Example 10) A solar cell back sheet was obtained in the same manner as in Example 1 except that the vinylidene chloride latex was changed to [B] and the polyfluorene-modified acrylic latex was changed to [h]. With solar battery modules. (Example 11) A solar cell back sheet was obtained in the same manner as in Example 1 except that the vinylidene chloride latex was changed to [B] and the polyfluorene-modified acrylic latex was changed to [i]. With solar battery modules. (Example 12) A polyester film "(3) SMOSHINEA 4100" (manufactured by Toyobo Co., Ltd., thickness: 188/zm) was used as the plastic substrate, and the polyfluorene-modified acrylic latex was changed to [j]. A solar cell backsheet and a solar cell module were obtained in the same manner as in Example 1. 64 321209 201003942 (Example 13) A solar battery back sheet and a solar battery module were produced in the same manner as in Example 1 except that the polyfluorene-modified acrylic latex was changed to the enamel coating [1]. (Example 14) A solar battery back sheet and a solar battery module were produced in the same manner as in Example 1 except that the polyfluorene-modified acrylic emulsion was changed to the enamel coating [2]. (Example 15) A solar battery back sheet and a solar cell module were produced in the same manner as in Example 1 except that the polyfluorene-modified acrylic emulsion was changed to the enamel coating [3]. (Example 16) Using a bar coater to make the thickness of the vinylidene chloride-based resin layer, "Lumirror X10S" (registered trademark, manufactured by T0RAY Co., Ltd., thickness: 188/m) After the vinylidene chloride paint [C] was applied in a manner of 5/m, it was dried in an oven maintained at 120 ° C for 60 seconds. After aging at 40 ° C for 48 hours, a polyxene-modified acrylic latex [a] was applied by using a die coater so that the thickness of the polyoxygen modified acrylic resin layer was 54 / / m. Further, a solar battery back sheet having the same structure as that of the solar battery back sheet of Fig. 1 was obtained except for the feature of no adhesive layer. Next, the glass layer on the surface irradiated with the sunlight and the solar cell back sheet were used for the inner surface, and the ethylene-vinyl acetate copolymer resin 65 321209 201003942 "SOLAR EVA" (manufactured by Mitsui Chemicals Fabro Co., Ltd.) was used as the filler. The solar cell element was sandwiched, and the solar cell module using the solar cell back sheet shown in Fig. 2 was obtained. (Comparative Example 1) An amine ester-based adhesive was applied at a coating amount of 5 g/m 2 using a gravure coater on one side of a hydrolysis-resistant polyester film "Lumirror X10S" (registered trademark, manufactured by T0RAY Co., Ltd., thickness: 188 Mm). (Mitsui Takeda Chemicals Co., Ltd. κ. Co., Ltd.'s main ingredient "TAKELAC (registered trademark) A5 丨丨" / hardener "A50" = 1 〇 /; [). Then, a vinylidene chloride emulsion [B] was applied by using an air knife coater so that the thickness of the vinylidene chloride-based resin layer became 10 / / m to obtain a solar battery back sheet. Then, a solar cell module was produced in the same manner as in Example 1. (Comparative Example 2) 'In the case of the hydrolysis-resistant polyg-based film "LumirrQr Xiqs" (registered trademark, manufactured by Konica Minolta Co., Ltd., thickness 188 (four) - side, using a gravure coating H Yangba f 5W coating amine vinegar-based adhesive (Mitsui Takeda After the chemical agent Knife "lake" main agent "face LAC (registered trademark) A511" / hardener, the thickness of the m iyf layer becomes * coated machine to make polysecond oxygen modified acrylic resin [b] The method of coating the money to modify the acrylic latex 4 友阳 battery back sheet by the method of 5^m. Then (Comparative Example 3) ^ The solar cell module 321209 66 201003942 was prepared in the same manner as in the first embodiment. Film (manufactured by Du卩(10)7 company, registered trademark Tedlar", thickness 50 // 11 _ side, coated with amine ester-based adhesive with a coating amount of 5 g/m 2 using a gravure coater (Mitsui Takeda Chemical Co., Ltd. The main ingredient "TAKELAC (registered trademark) A511" / curing agent "A5〇" = 10/1), and an aluminum foil having a thickness of 20 #m is laminated through the adhesive layer, and then the same as the same Coating the above-mentioned amine g as an adhesive, and laminating the above-mentioned high weather resistant fluororesin film ("Ted Lar", thickness 5 〇 #m), and a solar cell back sheet composed of a fluororesin film/three layers of a fluororesin film. Then, a solar cell module was produced in the same manner as in Example 1. (Comparative Example 4 On the side of the hydrolysis-resistant polyester film "Lumir·X1〇s" (registered trademark, manufactured by T0RAY Co., Ltd., thickness 6-), the coating amount of 5 g/V coating amine was applied using a gravure coater. The following agent (TAKEUC (registered trademark 「 "— 1 η /1, ~ sheet j), which is the main agent of Mitsui Takeda Chemical Co., Ltd., is laminated with a thickness of 2 == 駄 r After the cold film is applied to the vapor-resistant weathering fluorine, the adhesive is described as a thinner and the laminated layer is high: = __ company system, the registered trademark "minus ~, get hydrolysis resistant film" A solar cell back sheet composed of three layers of a film. Then, in the same manner as in Example i, solar power (Comparative Example 5) was prepared for ''hydrolysis-resistant polyester film "Lumirr〇r(10)" (registered trademark, 321209 67 201003942 T0RAY shares) Co., Ltd., thickness 188 "&quot; one side, using gravure coater to coat f; 5g/m2 Bucural vinegar-based adhesive (rTAKEUC (registered trademark) A511, manufactured by Mitsui Takeda Chemical Co., Ltd.) / hardener "A50" = 1 〇 /; 1) 'Laminating polychlorinated three via the adhesive layer Fluoroethylene (3 gasification) (PCTFE) thinner "NE〇FL〇N" (registered trademark, manufactured by MIKIN Co., Ltd., thickness 25&quot;), * is formed of two layers of hydrolyzable polyester film / PCTFE film Solar battery backplane. Then, a solar cell module was produced in the same manner as in Example 1. 1 (Comparative Example 6) A solar cell back sheet and a solar cell module were produced in the same manner as in Example 1 except that the acrylic latex [k] was used instead of the polyfluorene-modified acrylic latex [a]. Using the solar cell back sheets obtained in Examples 1 to 16 and Comparative Examples 1 to 6, the following evaluation was carried out. The results are shown in Tables 1 to 6. &lt;Water vapor barrier property&gt; i, each of the obtained solar cell back sheets was evaluated in accordance with JIS K 7129 'M0C0N method (PERMATRAN W3/31, manufactured by Modern Control Co., Ltd., 40 ° C '90% RH) Initial water vapor barrier. Those who have not reached 0. 6g/m2 · 24 hours are marked as "◎", 〇. 6g/m2 · 24 hours or more and less than 1. 〇g/m2· 24 hours are marked as "〇", 丨.〇g /m2· 24 hours or more and less than 1. 5g/m2· 24 hours are marked as “△”, 1·5g/m2 · For 24 hours or more, it is marked as “X”. · &lt;Finance&gt; 321209 68 201003942 Exposure test was carried out using the Sunshine Weathering Tester (Suga Testing Machine Co., Ltd., 'WEL-SUN-DC) (rainfall period: 12 minutes/hour, blackboard temperature 60 to 66°) C). Weatherability (1) was observed after 2000 hours of testing. Those who have no change in surface are marked as "〇", and those who have deterioration such as cracking/expansion are marked as "X". Weatherability (2) was observed in the state of yellowing after 2000 hours of testing. &lt; According to CIE 1976 (JIS Z 8729), the difference in b value (Ab) between the exposure measurement and the test before the test is measured using the color difference meter "CR-200" of Konica Minolta Sensing Co., Ltd., which will not reach 1 point. Those marked as "◎", those who are less than 20 are marked as "〇", and those marked 20 or above are "χ". Weatherability (3) was measured for water vapor barrier properties after 2000 hours of testing. The measurement method and the determination are carried out in the contents described in the section [Water vapor barrier properties]. &lt;Heat resistance&gt; According to din 40 634, the stability at 15 (TC after 30 minutes) was evaluated. The heat was marked as &lt;moisture resistance, sex&gt; moisture resistance (2000 hours) was Tested for 200P hours at 85°C/85% RH. Moisture resistance (3000 hours) is at 85°C/85% RH. According to TM, the water vapor resistance of each silly sample is evaluated in the same way. Early morning. Those who have not reached 0. 6g/m2 _ 24 hours are marked as "◎", 〇. 6g/m2 · 321209 69 201003942 24 hours or more and less than 1. Og/m2 · 24 hours are marked as "〇 1. Og r /m2 · 24 hours or more and less than 1. 5g / m2 · 24 hours are marked as "△", 1. 5g / m2 · 24 hours or more is marked as "X". &lt;Electrical insulation Sexuality> The partial discharge voltage performance was evaluated in accordance with IEC 60 664-1. The conformity was marked as "〇" and the non-conformity was marked as "X". The sun obtained in Examples 1 to 16 and Comparative Examples 1 to 6 was used. The battery module was evaluated as follows: f The results are shown in Tables 1 to 6. &lt;Processability&gt; Those who have excellent processing properties such as those coated with a plastic substrate are marked as 〇", the use of a fluorine-based film having weak mechanical strength, etc., and the component workability is not marked as "X". 70 321209 201003942 [Table 1] Example 1 Example 2 Example 3 Example 4 Example 5 Solar cell solar cell solar cell solar cell solar cell component side component side component side component side component side hydrolysis resistance grade only hydrolyzable hydrolysis resistance hydrolysis resistance Yizhi hydrolysis substrate PET film PET film PET film PET film PET film adhesive agent Agent adhesive agent adhesive second-ethylene ethylene partial ethylene ethylene partial two-gas ethylene partial two-gas ethylene partial two-gas ethylene fine A] valve [A] off A] _A] fine A] poly-oxygen modified Modified poly-oxygen modified poly-oxygen modified poly-stone modified oxygen-based acrylic emulsifiable acrylic latex latex acrylic acid latex acrylic acrylic emulsion acrylic latex [a] [a] [a] [b] [ C] Effect of water vapor barrier ◎ ◎ ◎ ◎ ◎ [g/m2*24 hours] 0.58 0.32 0.58 0.58 0.58 Weather resistance (1) (The appearance is deteriorated) 〇〇〇〇〇 Weather resistance (2) ◎ ◎ ◎ ◎ ◎ [△b] 4.8 9.2 2.6 8.9 17.2 Weather resistance (3) 〇◎ 〇〇〇[g/m2.24 hours] 0.62 0.51 0.63 0.70 0.78 Finance 〇〇〇〇〇 湿 ◎ ◎ ◎ 〇 〇 (2000 hours) [g/m2-24 hours] 0.58 0.36 0.58 0. 64 0,94 Moisture resistance 〇 ◎ 3000 (3000 hours) [g/m2*24 hours] 0.60 0.40 0.61 0.67 0.99 Electrical insulation 〇〇〇〇〇Processability 〇〇〇〇〇71 321209 201003942 [Table 2] Example 6 Example 7 Example 8 Example 9 Example 10 constituting solar cell solar cell solar cell solar cell solar cell element side element side component The side element side element side is hydrolyzed and hydrolyzed ('[4] and hydrolyzed by ϋ# and only hydrolyzable: S# hydrolysis resistant substrate PET film PET film PET film PET film PET film adhesive agent adhesive adhesive followed by Agent partial two-gas ethylene partial two-ethylene ethylene partial------------------------------------------------------------------------------------------------------------------- Poly-oxygen modification Oxygen-modified acrylic latex acrylic-based guide acrylic latex acrylic acid-based shot JI acrylic acid latex [d] [e] [f] [g] [h] effect water vapor barrier 〇〇〇〇〇 [ g/m2.24 hours] 0.81 0.79 0.80 0.80 0.79 Weather resistance (1) (with or without deterioration of appearance) Weather resistance (2) ◎ ◎ ◎ 〇〇 [△b] 8.8 8.6 6.4 12.7 14.8 Weather resistance (3 ) 〇〇〇〇〇[g/m2-24 hours] 0.88 0.88 0.87 0.93 0.9 For hot 〇〇〇〇〇 湿 2000 (2000 hours) [g/V.24 hours] 0.84 0.82 0.80 0.92 0.88 Moisture resistance 3000 (3000 hours) [g/m2.24 hours] 0.86 0.85 0.83 0.95 0.90 Electrical insulation 〇〇〇〇〇 Processability 〇〇〇〇〇 72 321209 201003942 ' [Table 3] Implementation Example 11 Example 12 Example 13 Example 14 Example 15 constituting solar cell solar cell solar cell solar cell solar cell element side element side element side element side element side hydrochloric acid hydrolysis 4# PET film substrate PET film substrate PET film Substrate P ET film substrate ΡΕΓ film adhesive agent adhesive agent adhesive agent adhesive second gas ethylene partial ethylene ethylene partial ethylene ethylene vinylidene chloride vinylidene chloride B] flap [A] fine A] _A] Lai A Poly-oxygen modified poly-oxygen modified acrylic acid emulsion Yao · acrylic acid latex green enamel coating [a] 琅 coating [b] 珐琅 coating [C] [i] [i] effect water vapor resistance障 ◎ ◎ ◎ ◎ [g/m, 24 hours] 0.80 0. 58 0.58 0.56 0.57 Weather resistance (1) 〇Δ 〇〇〇 (with or without deterioration of appearance) (spot) Financial property (2) 〇◎ ◎ ◎ ◎ [△b] 11.8 8.7 1.5 1.6 1.5 Weather resistance (3) 〇Δ 〇 ◎ ◎ [g/m2, 24 hours] 0.99 1.2 0.61 0.57 0.59 Fidelity 〇〇〇〇〇 湿 〇 〇 ◎ ◎ (2000 Hour) [g/m2-24 hours] 0.96 1.10 0.61 0.59 0.58 Wetness 〇Δ 〇〇〇 (3000 hours) [g/m2.24 hours] 0.99 1.12 0.60 0.61 0.62 Electrical insulation 〇〇〇〇〇 processability 〇〇〇〇〇73 321209 201003942_ [Table 4] K Example 16 constituting a solar cell Piece-side hydrolysis-resistant substrate PET film adhesive second-ethylene latex [C] Poly-oxo-modified acrylic latex [a] Effect Water vapor barrier [g/m2*24 hours] 〇0.89 Weather resistance (1) ( Whether the appearance is deteriorated or not) Weather resistance (2) ◎ [Ab] 1.3 Weather resistance (3) 〇 [g/m2'24 hours] 0. 95 Heat resistance 〇 Moisture resistance 2000 (2000 hours) [g/in2, 24 hours] 0.89 Moisture resistance 3000 (3000 hours) [g/m2*24 hours] 0.98 Electrical insulating 〇 processability 〇 74 321209 201003942 • [Table 5] Comparative Example 1 Comparative Example 2 Comparative Example 3 Comparative Example 4 Comparative Example 5 constituting a solar cell Solar cell solar cell solar cell solar cell component side component side component side component side component side financial hydrolysis ^# PET film hydrolysis resistance 4# PET film fluorine film and hydrolyzable PET film and inch hydrolyzable PET film adhesive Agent adhesive agent, adhesive agent, second gas ethylene fine B] polyfluorene modified acrylic acid latex aluminum foil, steamed Zhongming PET film fluorine film [b] adhesive agent, fluorine film, fluorine film effect Water vapor barrier 〇X ◎ ◎ Δ [g/m2.24 hours] 0.80 3.0 0.10 0.50 1.1 Weather resistance (1) (The appearance is deteriorated) X 〇〇〇〇 Weather resistance (2) X ◎ ◎ ◎ ◎ [△ b] 38.2 1.3 0.9 3.9 2.8 Weather resistance (3) XX ◎ ◎ Δ [g/m2, 24 hours] 2.89 3.00 0.10 0.51 1.10 Financial heat X 〇〇〇〇 Moisture resistance X ◎ ◎ Δ (2000 hours) [g /m2.24 hours] 0.92 3.00 0.10 0.50 1.2 Wetness XX ◎ ◎ Δ (3000 hours) [g/m, 24 hours] 2.25 3.05 0.11 0.50 1.10 Electrical insulation 〇〇X 〇〇Processability〇〇XXX 75 321209 201003942 [Table 6] Comparative Example 6 Composition of solar cell element side Hydrolysis resistant substrate PET film adhesive Bi-ethylene latex [B] Acrylic latex [k] Effect Water vapor barrier [g/m, 24 hours] 〇0.80 Weather resistance (1) (Whether or not the appearance is deteriorated) X Weather resistance (2) [Ab] ◎ 8.5 Weather resistance (3) [g/m, 24 hours] Δ 1.09 Heat resistance X (wetness (2000 hours) [g/m2_24 hours] Δ 1.12 Moisture resistance (3000 hours) [g/m, 24 hours] X 1.99 Electrical insulation 〇 Workability 76 321209 201003942 The results of Tables 1 to 6 show that the polyvinylidene chloride-based resin layer and the polyfluorene-modified acrylic resin layer laminated on the vinylidene chloride-based resin layer are implemented. Each of the solar battery back sheets of Examples 1 to 16 is excellent in durability, heat resistance, moisture resistance, water vapor barrier property, and electrical insulation. The solar battery back sheets of Examples 1 to 16 were simultaneously compared with the solar battery back sheets of Comparative Examples 1 and 2 having only a vinylidene chloride-based resin layer or a polyoxynoxy-modified acrylic resin layer. It is more excellent in weather resistance, heat resistance, moisture resistance, and water vapor barrier properties. In particular, regarding weather resistance (3) (water vapor barrier property after 2000 hours of weather resistance test) and moisture resistance (3000 hours), performance deterioration can be observed with respect to only one of the above two layers. It has two layers and is continuously laminated to have excellent performance. Further, in addition to the above-described characteristics, the solar battery back sheets of Examples 1 to 16 can be used without using an adhesive between the vinylidene chloride-based resin layer and the polyfluorinated modified acrylic resin layer. The constitution of the members is made simpler, and the workability of each layer is also excellent. On the other hand, the solar battery back sheet of Comparative Example 4 having the vapor-deposited PET-based resin layer and the fluorine-based resin layer has characteristics such as weather resistance required for the solar battery back sheet, but in two Since an adhesive must be used between the resin layers, the component configuration becomes complicated, the manufacturing steps are complicated, and the mechanical strength is insufficient, so that the workability is poor. (Industrial Applicability) The present invention can provide a water vapor which is excellent in hydrolyzability, weather resistance, heat resistance and moisture resistance even in a severe natural environment for a long period of time. It is a laminate for solar cell backsheets that is also excellent in productivity, such as simplification of the structure of the components, and workability, such as 77321209 201003942. The solar cell backsheet and solar cell module of the present invention are suitable for use in the field of solar power generation systems. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a cross-sectional view showing an example of a solar battery back plate. Fig. 2 is a cross-sectional view showing an example of a solar battery module. [Main component symbol description] 1 Solar battery back plate 2 Plastic substrate 3 Adhesive 4 Partially dichloroacetic acid resin layer 5 Poly stone oxide modified acrylic resin layer 6 Solar battery module 7 Glass layer 8 Sun Battery component 9 Filling material 78 321209 201003942 Bu "μ "日 $ it]. Man jg patent specification (this format, order, please do not change anything, please do not fill in the ※ part of the mark) A ※ application number: outside H ^ IL (2 006.01) ※Application date: f 4 Chat. Classification: ββ __ I. Invention name: (Chinese/English) Laminated body for solar battery back sheet and back sheet with the laminated body LAMINATE FOR SOLAR CELL BACK SHEET AND BACK SHEET HAVING SAID LAMINATE II. Chinese Abstract: The present invention Providing a weatherability in which an excellent water vapor barrier property can be exhibited and maintained by a laminated vinylidene chloride-based resin layer and a polyfluorene-modified acrylic acid-based resin layer 'even in a severe natural environment for a long period of time' And a laminate for a solar cell back sheet excellent in moisture resistance. The invention provides a laminate for solar cell back sheet by laminating a vinylidene chloride resin layer and a silicon-modified acrylic resin layer, which is excel lent in weather resistance and humidity resistance where an extraordinary vapor barrier feature can be 1 321209 201003942 VII. Patent application scope: L type solar cell back sheet laminate body, gambling layer, and laminated layer in the above-mentioned partial-氤... partial-milk vinyl hydrazine The tree-like acrylic resin layer is a layer of a solar cell backsheet for the first layer of the solar cell backsheet, and the olefinic tree is rugged with the above-mentioned poly (four) modification. The A. sinensis tree layer is directly connected to the layer. The layer for the solar cell backsheet of the first or second item or the layer of the vinylidene chloride resin of the middle one is a dichloroethylene obtained by dissolving the vinylidene chloride resin in an organic solvent. Made of Ethylene Paint or Ethylene Ethylene Latex. ' 4. t Apply for the solar cell back sheet for the third item of the patent scope, the vinylidene chloride resin powder and the one-g-alkene latex in the three-part Ethyl chloride paint are all A monomer containing 50% by mass or more of vinylidene chloride in the body is obtained by emulsion polymerization. 5 For example, in the solar range of items i to 4 of the patent scope, the solar cell back-reverse = product, body, and card, the poly-stone-modified acrylic resin layer is modified by ΛΚ石夕氧Made from acrylic latex. The laminated body for a solar battery back sheet according to the fifth aspect of the invention, wherein the poly-stone-modified acrylic latex comprises a polysulfide resin acrylic resin. /, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, Pre-, emulsification poly 321209 79 201003942 ^, at least any stage after the emulsion polymerization, adding a polyoxo-modified agent and 8. As in the scope of the patent scope 5 to 7 of the solar cell laminate , wherein 'the solar cell backsheet is formulated with the ultraviolet absorber and/or the light stabilizer in the poly-stone-modified acrylic latex of the foregoing. 9. A laminate is used, wherein the above-mentioned poly-acrylic latex is used as a coating which is mixed with a pigment. The laminated body for a solar cell back sheet according to any one of the items of the present invention, wherein the second partial ethylene sulfonate layer is a coating of a vinylidene chloride paint or a vinylidene chloride latex. The cloth layer, the polyfluorene-modified acrylic resin layer is a coating layer of polysulfide-modified propylene (IV) latex. 11. The solar cell back (four) laminate according to the first aspect of the patent scope of the first aspect of the invention, wherein the thickness of the second ethylene-based resin coating layer is 5 to 50/Z m, and the poly-xylene-modified acrylic resin The thickness of the resin coating layer is from 10 to 10 0 // m. 12. A solar cell backsheet comprising: a substrate, and a laminate for a solar cell backsheet according to any one of claims 1 to 11; On the substrate. 13. The solar cell backsheet of claim 12, wherein the substrate is a plastic substrate. The solar battery back sheet of claim 12 or 13, wherein the vinylidene chloride resin layer and the substrate are laminated via an adhesive. 80 321209 201003942 15. The solar cell substrate of the 13th or 14th patent application scope is made of polyethylene terephthalate resin. 16. The solar cell back of claim 15 Hey, where kg 1^,,. The poly-p-S too acid ethyl ester-based resin system is only hydrolyzed. , t π. — A solar cell module having a solar cell backsheet according to any one of claims 12-16. , 321209 81