201003147 六、發明說明： 【發明所屬之技術領域】 本發明係有關著色感光性樹脂組成物。 【先前技術】 彩色液晶顯示器、彩色攝影機等所使用之濾色器 (color filter)，一般係藉由在玻璃等透明基板或石夕等不 透明基板上形成紅（R)、綠（G)及藍（B)等3色之透明著色微 細圖案而製造。透明著色微細圖案係由著色感光性樹脂組 成物所構成，係依據著色感光性樹脂組成物所含之顏料之 種類或含量而調色。 例如在專利文獻1中揭示一種著色感光性樹脂組成 物，其含有C. I.顏料紅177及C. I.顏料紅242，並且全顏 料中之C. I.顏料紅242之含量為65至90重量％。 [專利文獻1]日本專利第3924872號 【發明内容】 ^ 期望獲得可製造高對比（contrast)之紅色像素（pixel) 及濾色器的著色感光性樹脂組成物。 本發明係提供一種著色感光性樹脂組成物，其含有顏 料（A )、黏結劑樹脂（B)、光聚合性化合物（C)、光聚合起始 劑（D)及溶劑（E)，其中，顏料（A)為含有C. I.顏料紅177、 C. I.顏料紅242及C. I.顏料紅254之顏料，並且全顏料中 之C. I.顏料紅242之含量為60重量％以下。 又，本發明係提供如上述之著色感光性樹脂組成物， 其中，C. I.顏料紅242之含量為50重量％以下。 3 321228 201003147 又，本發明係提供如上述之著色感光性樹脂組成物， 其中，C. I.顏料紅242之含量為35重量％以下。 又，本發明係提供如上述之著色感光性樹脂組成物， 其中，C.I·顏料紅254之含量為8〇重量％以下。 又，本發明係提供如上述之著色感光性樹脂組成物， 其中，C.I.顏料紅254之含量為5〇重量％以下。 、又，本發明係提供制上述著色感纽樹脂組成物而 形成之像素。 本發明係提供含有上述像素之遽色器 【實施方式】 本發明之著色感光性樹月旨組成物含有顏料⑴、黏結劑 树月曰⑻仏合性化合物（c)、光聚合起始劑⑼及溶劑 (E)其中’顏料⑴為含有c. !•顏料紅⑺、c.工.顏料紅 242及C. I.顏料紅254之顏料，並且全顏料中之c.工.顏料 紅242之含量為6〇重量％以下。 、王顏料中之c. I.顏料紅242之含量較佳為5〇重量％ 、下更4土為35重量％以下。此外，較佳為5重量％以上， 更佳為15重量％以上dC i.顏料紅242之含量只要在上述 範圍内，即可形成亮度與色純度高之紅色像素。 全顏料中之C.I.顏料紅m之含量較佳為5重量％以 二為1〇重量％以上。此外，較佳為95重量％以下， 重量％以下。c. !.顏料紅m之含量只要在上述 乾圍即可形成亮度與色純度高之紅色像素。 全顏料中之C·1.顏料紅254之含量較佳為8〇重量％ 321228 4 201003147 以下Y更佳為50重量％以下，特佳為40重量％以下。此 :’較佳為5重量％以上，更佳為2。重量％以上。其含量 ,、要在上返乾圍内’即可使熱析出物導致之異物產生變少。 又’顏料（Α)亦可含有任意顏料作為調色顏料。 、、工色顏料可列舉如C· I.顏料紅9、97、105、122、123、 144 149 、 166 、 168 、 176 、 180 、 192 、 209 、 215 、 216 、 224 255、264、265 #。此等紅色顏料可分別單獨使用或 組合2種以上使用。 >藍色顏料可列舉如C.I.顏料藍15:3、15:4、76等， 較佳可列舉如c·丨.顏料藍15: 3、15: 4及76，更佳可列 舉如C. I.顏料監15: 3。此等藍色顏料可分別單獨使用或 組合2種以上使用。 黃色顏料可列舉如G.I.顏料2、1G、13、2G、24、31、 53、55、83、86、93、94、1〇9、11〇、117、125i37i38、 ；^Η7Μ48^50^5^153.154Μ66Μ73.1δ〇^ 4 ’較佳可列舉如c. L顏料黃δ3、139、15〇。此等普 色顏料可分別單獨使用或組合2種以上使用。 ，、 再者，在此等顏料中亦可再添加c. J.顏料綠36或 顏料綠7作為調色用。 · 、，以著色感紐樹餘成物巾之全_份量為基 料（A)之含量通常為1G重量％以上6G重量心下 ^ 10重量％以上55重量％以下，更佳為15重量％以上 。重科以下。當顏料⑷之含量在上述_内時，製成_ h之色4充足，且可使組成物中含有必需量之黏㈣ 321228 5 201003147 聚合物’故有可形成機械強度充足之圖案的傾向。 黏結劑樹脂（B)係以具有鹼溶解性為佳。此外，黏結劑 樹脂（B)具有作為顏料（a)之分散煤的作用。前述黏結劑樹 脂（B)較佳為由衍生自不飽和羧酸之構成單元所構成的共 聚物。 八 前述衍生自不飽和羧酸之構成單元，具體上可列舉如 衍生自丙烯酸之構成單元、以及衍生自甲基丙烯酸之構成 單元。丙烯酸及甲基丙烯酸可分別單獨使用或組合兩者使 用此外，除了此·#丙烯酸和甲基丙稀·酸以外，亦可併用 選自巴丑酸、伊康酸、馬來酸、富馬酸等其他不飽和羧酸 及不飽和羧酸酐所成群組中之至少一種羧酸。又，亦可併 用α (羥基曱基）丙烯酸等在同一分子中含有羥基及羧基 之單體。 前^黏結劑樹脂（Β)較佳為由上述衍生自不飽和羧酸 =構成單元及可與則述衍生自不飽和敌酸之構成單元共聚 =之構成單元所構成的共聚物。可與前述衍生自不餘和幾 酉文之構成單元共聚合之構成單元，較佳可列舉如衍生自（甲 基）丙烯酸酯之構成單元。 (甲基）丙烯酸酯可列舉如丙烯酸酯化合物，具體上可 列舉如：（甲基）丙嫦酸甲_、（甲基）丙稀酸乙醋、（甲基） 丙_丁醋、（甲基）丙烯酸苯曱醋、（甲基）丙烯酸2-經基 乙醋及（甲基）丙_胺基乙g旨等不飽和㈣之無取代或取 代淀*基酉旨； (甲基）丙稀酸被戊g旨、（甲基）丙稀酸環己醋、（甲基）丙婦 321228 6 201003147 酸甲基環己醋、（甲基）丙烯酸環庚§旨、（甲基）丙婦酸環辛 酯、（甲基）丙烯酸蓋酯（menthyi (meth)acrylate)、基） 丙烯酸環戊烯酯、（甲基）丙烯酸環己烯酯、（曱基）丙烯酸 環庚烯酯、（甲基）丙烯酸環辛烯酯、（甲基）丙烯酸蓋二烯 酯（menthadienyl (meth)acrylate)、（甲基）丙烯酸異莰 酯、（甲基）丙烯酸蒎酯、（甲基）丙烯酸三環癸酯、（甲基） 丙烯酸三環癸氧基乙酯、（曱基）丙烯酸金剛烷酯、（甲基） 丙烯酸降莰烯酯（n〇rb〇rneny i)、（甲基）丙烯酸蒎烯酯、（甲 基）丙烯酸二環戊烯酯及（·甲基）丙烯酸二環戊烯氧基乙酯 等不飽和羧酸之含脂環式基之酯； (曱基）丙蝉酸縮水甘油酯等不餘和叛酸縮水甘油醋； (甲基）丙烯酸氧雜環丁酯等不飽和羧酸氧雜環丁酯； 寡聚乙二醇單烷基（曱基）丙烯酸酯等甘醇類之單飽和羧酸 酯等； 較佳可列舉如（甲基）丙烯酸甲酯、（曱基）丙烯酸苯曱酯。 在此’（曱基）丙烯酸酯表示丙烯酸酯或甲基丙烯酸酯。 黏結劑樹脂（B)亦可再含有可與不飽和羧酸及丙烯酸 酯共聚合之其他構成單元。該可與不飽和羧酸及丙烯酸酯 共聚合之其他構成單元，可列舉如衍生自下述者之構成單 疋.苯乙烯、甲基苯乙烯及乙烯基甲苯等芳香族乙烯基 化合物；乙酸乙烯酯及丙酸乙烯酯等羧酸乙烯酯；（曱基） 丙烯腈及α-氣丙烯腈等氰化乙烯化合物；Ν_苯基馬來醯亞 胺等馬來醯亞胺化合物。 上述之此等化合物可分別單獨使用，亦可組合2種以 7 321228 201003147 上使用。 可與衍生自不飽和羧酸之構成單元共聚合之構成單 兀，係以衍生自（甲基）丙烯酸酯之構成單元今佳，尤其以 從（甲基）丙婦酸之無取代或取代院基醋、或（甲基)月烯酸 之含脂％式烴基之酯所衍生的構成單元為更佳。 在黏結劑樹脂（B)中，於前述共聚物之全構成單元中， 以質量分率計，衍生自不飽和羧酸之構成單元通常為1〇至 50質量％ ’較佳為以15至4〇質量％存在。當衍生自不飽 和羧酸之構成單元在前述基準下為1〇至5〇質量％時，由 於對顯像液之溶解性充分，故在未曝光部之基板上不會產 生殘渣，此外，在顯像時不會發生曝光部之像素部份之膜 減少，像素整體有不會剝離之傾向，而較佳。 、 共聚合一般係使用聚合起始劑，並在溶媒中進行。聚 合起始劑可列舉如2, 2，-偶氮雙異丁腈或2, 2，-偶氮雙⑶ Z基丙酸甲醋）等化合物、過氧化苯甲酿或過氧化第三丁基 等過氧化物等。此外，溶媒只要是會溶解各單體者即可， T列，如乙二醇單甲趟乙酸醋、乙二醇單乙鍵乙酸酉旨、丙 :醇早曱醚乙酸酯、丙二醇單乙醚乙酸酯等二醇醚酯類 等反應溫度只要考慮聚合起始劑之分解溫度或溶劑及單 體之彿點等而決定即可。又，亦可將如此獲得之共聚物之 :鏈以具有感紐基之化合物進行改質而製絲紐之黏 、、’°劑樹脂⑻。此時，亦可添加用以使感紐基導入樹脂中 =觸媒。該觸媒可列舉如三（二曱基胺基甲基）紛。另外， 亦可添加用以防止副反應之添加劑。該添加劑可列舉如氫 321228 8 201003147 酉昆。 黏結劑樹脂（B)換算成聚苯乙烯之重量平均分子量較 佳為5, 000至100, 000，更佳為7, 000至50, 000。當黏結 劑樹脂（B)換算成聚苯乙烯之重量平均分子量為5, 000至 100,000時，由於在顯像時不易發生膜減少，且在顯像時 非像素部分之脫離性有良好之傾向，故較佳。 相對於著色感光性樹脂組成物中之全固形份量，黏結 劑樹脂（B)通常為5至90質量％，較佳為含有10至70質 量％。當前述黏結劑樹脂（B)之含量在前述基準下為5至 90質量％時，由於對顯像液之溶解性充分，在非像素部分 之基板上不易產生顯像殘渣，並且在顯像時不易發生曝光 部之像素部份之膜減少，非像素部分之脫離性有良&好之傾 向，而為較佳。 本發明之著色感光性樹脂組成物所含有之光聚合性化 合物（C)係因光及光聚合起始劑（D)之作用而進行聚合之化 合物、’例如具有碳-碳不飽合鍵之化合物為適當者。前述光 聚合性化合物（C)可列舉如單官能單體、二官能單體、其他 多官能單體。 單官能單體之具體例可列舉如壬基苯基卡必醇丙烯酸 酯、丙烯酸2-羥基-3-苯氧基丙酯、2-乙基己基卡必醇丙 烯酸酯、丙烯酸2-羥基乙酯、N-乙烯基吡咯啶酮等。 又，二官能單體之具體例可列舉如1，6-己二醇二（甲 基）丙烯酸酯、乙二醇二（曱基）丙烯酸酯、新戊二醇二（甲 基）丙烯酸酯、三乙二醇二（曱基）丙烯酸酯、雙酚A之雙（丙 9 321228 201003147 環 稀醯氧基乙基）醚、3~甲基戊二醇二（甲基）丙烯酸醋、 癸院一甲醇二（尹基）丙稀酸醋等。 其他多官能單體之具體例可列舉如三經曱基丙烧三 (甲基）丙稀酸醋、季戊四醇三（甲基）丙烯酸醋、季戊四醇 四（甲基）丙烯酸酉旨、二季戊四醇五（甲基）丙烤酸醋、二季 戊四醇六（甲基）丙稀酸醋、異三聚氣酸三（甲基丙婦醒氧基 乙基）酯等。 前述光聚合性化合物(c)尤其是以具有丙烯醯基⑽ = CHC0-)且化合物每單位重量之丙_基數多者為佳，換 言之’是鱗-當量丙_基之化合物之克數所示之丙稀 醯基當量小者為佳，其巾㈣烯轉#量為⑽以下之化 合物為更佳。若丙_基當量變大，财曝光或顯像時， 由於感度不充足，故有時會導致濾色器之生產性降低。汚 稀醯基當量為1GG以下之單體可列舉如乙二醇二丙稀把 酯、3至甲基丙烧三丙稀酸酉旨、季戊四醇三丙稀酸酉旨、季欠 戊四醇四丙稀酸醋、二季戊四醇六丙騎g旨等，較佳可 舉如三㈣基城三丙稀_旨、季細醇四丙_醋或二 季戊四醇六_酸轉。又，光聚合性化合物⑹係以 能單體、其他多官能單體為佳。 ，相對於著色感光性樹脂組成物中之黏結劑樹脂⑻及 先聚合性化合物（C)之合計⑽f量份，技合性化合物 之含量通常為i至60質量份，較佳為5至5〇質量份。去) 光聚合性化合物（C)之含量在前述範圍内時，像素部二 度、圖案形狀和平滑性有變良好之傾向，故為較佳。/ 321228 10 201003147 光聚合起始劑（D)可列舉如因光照射而產生活性自由 基之活性自由基產生劑、產生酸之酸產生劑等。活性自由 基產生劑可列舉如苯乙酮系光聚合起始劑、苯偶姻系光聚 ，合起始劑、三哄系光聚合起始劑、二苯甲酮系光聚合起始 •劑及两系光聚合起始劑等。 苯乙酮系光聚合起始劑可列舉如2-甲基_2_(N-嗎啉基） -1-(4-甲硫基苯基）丙烷酮、二乙氧基苯乙酮、2_羥基 -2-甲基-1-苯基丙烷—i一酮、苯甲基二甲基縮酮、2_羥基_2_ 甲基1 [4-(2-起基乙氧基）苯基]丙烧_ι —酮、經基環己 基苯基酮、2-苯甲基-2-二甲基胺基一i-(4-(N—嗎啉基）苯基） 丁烷-1-酮、2-羥基-2-甲基-1 一 [4-(1-曱基乙烯基）笨基] 丙烷-1-酮之寡聚物等。 苯偶姻系光聚合起始劑可列舉如苯偶姻、苯偶姻.甲基 醚、苯偶姻乙基醚、苯偶姻異丙基醚、苯偶姻異丁基醚等。 三畊系光聚合起始劑可列舉如2, 4-雙（三氯甲基）-6_ X (4一曱氧基苯基卜1，3,5—三畊、2, 4-雙（三氯甲基）-6-(4-: 甲氧基萘基）-1，3, 5-三畊、2, 4-雙（三氯甲基）-6-向曰葵基 一1，3, 5—三畊、2, 4-雙（三氯甲基）-6-(4-甲氧基苯乙烯基） -1’3’5-三哄、2,4-雙（三氣曱基）_6_[2-(5-曱基呋喃—2- 基）乙烯基]-1，3,5-三啡、2,4-雙（三氯甲基）-6-[2-(呋喃 -2-基）乙烯基]3, 5_三畊、2, 4_雙（三氯甲基）一6_[2一（4_ 二乙基胺基-2-甲基苯基）乙烯基卜丨，3, 5—三哄、2, 4—雙（三 氯曱基）-6-[2-(3, 4-二甲氧基苯基）乙烯基]_ι，3, 5_三哄 等。 321228 11 201003147 一苯甲綱系光聚合起始劑可列舉如二笨曱酮、鄰笨甲 醯基笨甲酸甲酯、4_苯基二苯曱酮、4_苯甲醯基_4,—甲基 一苯基硫化物、3, 3’，4, 4,-四（過氧化第三丁基羰基）二笨 甲酮、2,4, 6-三甲基二苯甲酮等。 肟系光聚合起始劑可列舉如〇_醯基肟系化合物，其具 體例可列舉如1-(4-苯硫基-苯基）-丁烷-1，2-二酮2-肟 -〇-苯曱酸酯、1-(4_苯硫基-苯基）_辛烷_丨，2_二酮2_肟 -0-苯曱酸酯、1-[9—乙基—6_(2_乙基苯甲醯基）_9H—咔唑 -3-基]乙酮1-〇_乙酸酯、卜[9_乙基_6_(2_曱基_4_(3,3— 二甲基-2, 4-二氧雜環戊基曱基氧基）苯曱醯基）_卯一咔唑 -3-基]乙酮1-0-乙酸酯等。 前述例示以外之活性自由基產生劑，可列舉如2,4,6-二甲基苯甲醯基二苯基膦氧化物、2, 2’-雙（鄰氯苯基） -4, 4，5, 5 -四笨基—1，2,-聯咪唑、；[〇_丁基_2_氯吖啶酮、 2-乙基恩醌、二苯乙二酮（benzi丨）、9,丨〇_菲醌、樟腦醌、 苯基乙醛酸曱酯、二茂鈦化合物等。 酸產生劑可列舉如對曱苯磺酸4-羥基苯基二甲基銃、 六氟銻酸4 -羥基苯基二曱基銃、對甲苯磺酸4 —乙醯氧基苯 基二甲基銃、六氟銻酸4-乙醯氧基苯基•曱基•苯曱基錡、 對甲苯磺酸三苯基銃、六氟銻酸三苯基鏟、對甲苯磺酸二 苯基錤、六氟銻酸二苯基錤等鑌鹽類或硝基苯甲基甲苯磺 酸酯類、苯偶姻曱苯石黃酸醋類等。 又，在上述化合物中，就活性自由基產生劑而言，亦 有同產生活性自由基與酸之化合物，例如三啡系光聚合 321228 12 201003147 起始劑等活性自由基產生劑即亦可作為酸產生劑使用。 此等光聚合起始劑（D)可分別單獨使用亦可2種以上 組合使用。 光聚合起始劑（D )亦可組合光聚合起始助劑而使用。前 述光聚合起始助劑係以胺化合物、含有硫醇基之化合物及 羧酸化合物為佳，又，胺化合物係以芳香族胺化合物為更 佳。 胺化合物可列舉如：三乙醇胺、甲基二乙醇胺、三異 丙醇胺等脂肪族胺化合物；4-二甲基胺基苯甲酸曱酯、4-二甲基胺基苯甲酸乙酯、4-二曱基胺基苯甲酸異戊酯、4-二曱基胺基苯甲酸2-乙基己酯、苯甲酸2-二甲基胺基乙 酯、N，N-二甲基對曱苯胺、4, 4’-雙（二曱基胺基）二苯曱酮 (通稱米其勒酮）、4, 4’ -雙（二乙基胺基）二苯曱酮等芳香族 胺化合物。 含有硫醇基之化合物為在分子中具有硫醇基之化合 物，具有1個硫醇基之硫醇化合物可列舉如2-巯基苯并。塞. 唑、2-M基苯并噚唑等，在脂肪族基具有複數個硫醇基之 脂肪族多官能硫醇化合物可列舉如：己烷二硫醇、癸烷二 硫醇、1，4-二甲基巯基苯、丁二醇雙硫丙酸酯、丁二醇雙 硫乙醇酸酯、乙二醇雙硫乙醇酸酯、三羥曱基丙烷參硫乙 醇酸酯、丁二醇雙硫丙酸酯、三羥甲基丙烷參硫丙酸酯、 三羥曱基丙烷參硫乙醇酸酯、季戊四醇肆硫丙酸酯、季戊 四醇肆硫乙醇酸酯、三羥基乙基參硫丙酸酯等。 羧酸化合物可列舉如苯基硫乙酸、甲基苯基硫乙酸、 13 321228 201003147 乙基笨基硫乙酸、曱基乙基苯基硫乙酸、二甲美苯芙辟乙 酸、甲氧基苯基硫乙酸、二曱氧基笨基硫乙酸、氯笨基硫 乙酸、二氯苯基硫乙酸、N-苯基甘胺酸、笨氧基乙酸、英 基硫乙酸、萘基甘胺酸、萘氧基乙酸。 又，此等之外，亦可列舉如多元羥基化合物之硫乙醇 酸酿或硫丙酸酯等’較佳之多元羥基化合物之硫乙醇酸酯 或硫丙酸酯可列舉如三羥曱基丙烷參硫丙酸酯、三經甲基 兩烷參硫乙醇酸酯及季戊四醇肆硫丙酸酯。 相對於黏結劑樹脂（B)及光聚合性化合物（c)之合計 100質量份，光聚合起始劑（D)之含量通常為〇.丨至4〇質 量份’較佳為1至30質量份。相對於黏結劑樹脂（β)及光 聚合性化合物（C)之合計100質量份，光聚合起始助劑之含 量通常為0. 1至50質量份’較佳為1至40質量份。 溶劑（Ε)可為此領域所使用之各種溶劑。其具體例可列 舉如： 乙二醇單曱醚、乙二醇單乙醚、乙二醇單丙醚及乙二醇單 丁醚等乙二醇單烷基醚類； 二乙二醇二甲醚、二乙二醇二乙醚、二乙二醇二丙醚及二 乙二醇二丁醚等二乙二醇二烷基醚類； 乙二醇曱 ϋ 乙酸酯（methyl cel losolve acetate)、乙二醇 乙驗乙酸酯等乙二醇烷基醚乙酸酯類； 两二醇單曱醚乙酸酯、丙二醇單.乙醚乙酸酯、丙二醇單丙 喊乙酸酯、曱氧基丁基乙酸酯及曱氧基戊基乙酸酯等烷二 醇烷基醚乙酸酯類； 321228 14 201003147 苯、甲苯、二曱苯及1，3, 5_三 烴類； 曱苯（mesitylene)等芳香族 甲基乙基酮、丙酮、甲基戊基酮、甲基異丁基酮及環 等酮類； 乙醇:丙醇、丁醇、己醇、環己醇、乙二醇及甘油等醇類； 3乙氧基丙酸乙酯及3一曱氧基丙酸曱酯等酯類； 7 - 丁内醋等環狀g旨類等。 此等溶劑（E)可分別單獨使用或混合2種以上使用。 相對於著色感光性樹脂組成物整體，以質量分率 ^劑⑻之含量通常為6〇至⑽f量％，較佳為川至奶質 =辟“心谷劑⑻之含量在前述範圍内時’因塗佈性有 3C良好之傾向而較佳。 在本發明之著色感光性樹月旨組成物中，亦可再含 =劑凝:料分散劑、密著促進劑、抗氧化劑、紫外線吸收 iJ(F;。本防止材、界面活性劑、其他高分子化合物等添加 =劑具體上可解如麵、氧切、氧她等。 、氟系，、陽離子= 二吏Γ=活性劑等’可分別單獨使用或組合2種 ^上使用。刖述界面活性劑之 _、聚氧伸乙基垸基苯基鱗類、上=氧:乙舰 醇酐脂肪酸酯類、脂肪酸改 ，一酉曰類、山梨 類、聚伸乙亞胺類等，此外尚;： 竿如商品名之ΚΡ(信越 321228 15 201003147 化學工業股份有限公司製）、Polyflow(共榮化學股份有限 公司製）、F-Top(Tohkem Products 公司製）、Megaface(大 曰本油墨化學工業股份有限公司製）、Fluorad(住友3M股 份有限公司製）、AsahiGuard、Surf 1 on(以上為旭石肖子股份 有限公司製）、Solsperse(Abysia股份有限公司製）、EFKA (EFKA CHEMICALS公司製）、PB821 (味之素股份有限公司製） 等。 密著促進劑具體上可列舉如乙烯基三甲氧基石夕统、乙 稀基二乙氧基石夕烧、乙稀基二（2-曱氧基乙氧基）石夕院、n一 (2-胺基乙基）-3-胺基丙基曱基二甲氧基矽烷tN—( =胺基 乙基）-3-胺基丙基三曱氧基矽烷、3-胺基丙基三乙氧基石夕 烧、3-縮水甘油氧基丙基三甲氧基石夕燒、^‘二甘油&基 丙基曱基二曱氧基矽烷、2-(3,4-環氧基環己基）乙基三甲 氧基矽烷、3-氯丙基曱基二曱氧基矽烷、氣"丙基二^氧 基石夕院、3-曱基丙烯酿氧基丙基三曱氧基矽燒、3_魏基丙 基三甲氧基矽烷等。 抗氧化劑具體上可列舉如2, 2’ -硫代雙（4—曱基一第 三丁基酌)、2, 6-二-第三丁基-4-曱基盼等。 紫外線吸收劑具體上可列舉如2-(3__第二丁某$ -5-曱基苯基）-5-氣苯并三嗤、烧氧基二笨甲綱^。 X，凝集防止材具體上可列舉如聚丙烯酸鈉等。 界面活性劑係以具有敦原子或石夕原子之界面活性劍為 佳。具體上可列舉如選自聚錢系界面活性H系界面 活性劑及具有氟原子之料氧系界面活性_成群組中之 321228 16 201003147 至少一種。 前述聚矽氧系界面活性劑可列舉如具有矽氧烷鍵之界 面活性劑等。具體而言，可列舉如TORAY silicone DC3PA、 TORAY silicone SH7PA > TORAY silicone DC11PA > TORAY si 1 icone SH21PA'TORAY silicone SH28PA'TORAY silicone 29SHPA、TORAY silicone SH30PA、聚醚改質矽油 SH8400(商 品名，TORAY silicone股份有限公司製）、KP32卜KP322、 KP323、KP324、KP326、KP340、KP341C信越 silicone 公司 製）、TSF400、TSF401、TSF410、TSF4300、TSF4440、TSF4445、 TSF-4446 ' TSF4452 ' TSF4460(Momentive Performance Materials日本聯合公司製）等。 前述氟系界面活性劑可列舉如具有氟碳鏈之界面活性 劑等。具體而言，可列舉如Fluorad(商品名）FC430、Fluorad FC431C住友3M股份有限公司製）、Megaface(商品名） F142D、Megaface F171、Megaface F172、Megaface F173、 Megaface F177、Megaface F183、Megaface F489、Megaface F554、Megaface R30(DIC 股份有限公司製）、F-Top(商品 名）EF301、F-Top EF303、F-Top EF351、F-ΊΓορ EF352(新 秋田化成股份有限公司製）、Surf Ion(商品名）S381、201003147 VI. Description of the Invention: [Technical Field of the Invention] The present invention relates to a coloring photosensitive resin composition. [Prior Art] A color filter used in a color liquid crystal display, a color camera, or the like is generally formed by forming red (R), green (G), and blue on a transparent substrate such as glass or an opaque substrate such as Shi Xi. (B) A three-color transparent colored fine pattern is produced. The transparent colored fine pattern is composed of a colored photosensitive resin composition, and is colored according to the kind or content of the pigment contained in the colored photosensitive resin composition. For example, Patent Document 1 discloses a colored photosensitive resin composition containing C.I. Pigment Red 177 and C.I. Pigment Red 242, and the content of C.I. Pigment Red 242 in the entire pigment is 65 to 90% by weight. [Patent Document 1] Japanese Patent No. 3924872 [Disclosure] It is desired to obtain a colored photosensitive resin composition capable of producing a high contrast red pixel and a color filter. The present invention provides a colored photosensitive resin composition comprising a pigment (A), a binder resin (B), a photopolymerizable compound (C), a photopolymerization initiator (D), and a solvent (E), wherein The pigment (A) is a pigment containing CI Pigment Red 177, CI Pigment Red 242, and CI Pigment Red 254, and the content of CI Pigment Red 242 in the entire pigment is 60% by weight or less. Furthermore, the present invention provides the colored photosensitive resin composition as described above, wherein the content of C.I. Pigment Red 242 is 50% by weight or less. Further, the present invention provides a coloring photosensitive resin composition as described above, wherein the content of C.I. Pigment Red 242 is 35% by weight or less. Furthermore, the present invention provides the coloring photosensitive resin composition as described above, wherein the content of C.I. Pigment Red 254 is 8 Å by weight or less. Furthermore, the present invention provides the colored photosensitive resin composition as described above, wherein the content of C.I. Pigment Red 254 is 5 Å by weight or less. Further, the present invention provides a pixel formed by forming the above-described colored resin composition. The present invention provides a coloring device containing the above-described pixels. [Embodiment] The coloring photosensitive tree composition of the present invention contains a pigment (1), a binder, a tree (8), a compound (c), and a photopolymerization initiator (9). And solvent (E) wherein 'pigment (1) is a pigment containing c. !•Pigment Red (7), c. work. Pigment Red 242 and CI Pigment Red 254, and the content of c. work. Pigment Red 242 in the whole pigment is 6 〇% by weight or less. In the king pigment, c. I. The content of the pigment red 242 is preferably 5% by weight, and the lower 4 soil is 35% by weight or less. Further, it is preferably 5% by weight or more, more preferably 15% by weight or more, and dC i. The content of the pigment red 242 is a red pixel having high luminance and color purity as long as it is within the above range. The content of C.I. Pigment Red m in the total pigment is preferably 5% by weight or more and 2% by weight or more. Further, it is preferably 95% by weight or less and more preferably 1% by weight or less. c. !. The content of the pigment red m can form red pixels with high brightness and color purity as long as the above-mentioned dry circumference. The content of C·1. Pigment Red 254 in the entire pigment is preferably 8% by weight. 321228 4 201003147 The following Y is more preferably 50% by weight or less, particularly preferably 40% by weight or less. Here: ' is preferably 5% by weight or more, more preferably 2. More than weight%. The content of the material, in the upper back of the dry circumference, can cause the foreign matter caused by the hot precipitate to be reduced. Further, the pigment (pigment) may contain any pigment as a coloring pigment. For example, C. I. Pigment Red 9, 97, 105, 122, 123, 144 149, 166, 168, 176, 180, 192, 209, 215, 216, 224 255, 264, 265 # . These red pigments may be used alone or in combination of two or more. The blue pigment may, for example, be CI Pigment Blue 15:3, 15:4, 76, etc., preferably, for example, c·丨. Pigment Blue 15: 3, 15: 4 and 76, more preferably, for example, CI Pigment Supervisor 15: 3. These blue pigments may be used alone or in combination of two or more. The yellow pigment may, for example, be GI Pigment 2, 1G, 13, 2G, 24, 31, 53, 55, 83, 86, 93, 94, 1〇9, 11〇, 117, 125i37i38, ;Η7Μ48^50^5^ 153.154Μ66Μ73.1δ〇^ 4 ' is preferably exemplified by c. L pigment yellow δ3, 139, 15〇. These plain pigments may be used alone or in combination of two or more. Further, c. J. Pigment Green 36 or Pigment Green 7 may be further added to these pigments for coloring. The content of the base material (A) is usually 1 G weight% or more and 6 G weight is less than 10% by weight to 55% by weight, more preferably 15% by weight. the above. Under the heavy section. When the content of the pigment (4) is in the above-mentioned _, the color 4 of the _ h is sufficient, and the composition may contain a necessary amount of the viscous (tetra) 321228 5 201003147 polymer, so that there is a tendency to form a pattern having sufficient mechanical strength. The binder resin (B) preferably has an alkali solubility. Further, the binder resin (B) has a function as a dispersed coal of the pigment (a). The above-mentioned binder resin (B) is preferably a copolymer composed of constituent units derived from an unsaturated carboxylic acid. The above-mentioned constituent unit derived from the unsaturated carboxylic acid may specifically be exemplified by a constituent unit derived from acrylic acid and a constituent unit derived from methacrylic acid. Acrylic acid and methacrylic acid may be used singly or in combination of two or more. In addition to this, #acrylic acid and methyl propylene acid may be used in combination with bar succinic acid, itaconic acid, maleic acid, and fumaric acid. And at least one carboxylic acid in the group of other unsaturated carboxylic acids and unsaturated carboxylic anhydrides. Further, a monomer having a hydroxyl group and a carboxyl group in the same molecule, such as α (hydroxyindenyl)acrylic acid, may be used in combination. The pre-adhesive resin (Β) is preferably a copolymer composed of the above-mentioned constituent unit derived from the unsaturated carboxylic acid = constituent unit and copolymerizable with the constituent unit derived from the unsaturated dicarboxylic acid. The constituent unit which can be copolymerized with the constituent units derived from the above and the above is preferably a constituent unit derived from (meth) acrylate. The (meth) acrylate may, for example, be an acrylate compound, and specific examples thereof include (meth)propionic acid methyl ketone, (methyl) acrylic acid ethyl acetonate, (methyl) propylene butyl vinegar, (a) (meth)acrylic acid benzoquinone vinegar, (meth)acrylic acid 2-ethylidene vinegar and (meth) propyl-amino ethane ethoxylate unsaturated (tetra) unsubstituted or substituted Dilute acid is glutinous, (meth)acrylic acid cyclohexan vinegar, (methyl) propylene 321228 6 201003147 acid methylcyclohexan vinegar, (meth)acrylic acid ng §, (methyl) propyl Cyclooctyl octyl ester, menthyi (meth)acrylate, hydroxycyclopentene acrylate, cyclohexenyl (meth) acrylate, cycloheptenyl (meth) acrylate, (a) Base octyl acrylate, menthadienyl (meth) acrylate, isodecyl (meth) acrylate, decyl (meth) acrylate, tricyclic fluorene (meth) acrylate Ester, tricyclodecyloxyethyl (meth)acrylate, adamantyl (mercapto)acrylate, norbornene (meth)acrylate (n Rb 〇rneny i), decyl (meth) acrylate, dicyclopentenyl (meth) acrylate and dicyclopentenyloxyethyl (meth) acrylate Ester; (indenyl) glycidyl propyl phthalate and the like and tareric glycidol; unsaturated carboxylic acid oxetane such as oxetane (meth) acrylate; oligoethylene glycol A monosaturated carboxylic acid ester of a glycol such as a monoalkyl (mercapto) acrylate or the like; preferably, for example, methyl (meth)acrylate or phenyl decyl acrylate. Here, '(mercapto) acrylate means acrylate or methacrylate. The binder resin (B) may further contain other constituent units copolymerizable with the unsaturated carboxylic acid and the acrylate. Examples of the other constituent unit copolymerizable with the unsaturated carboxylic acid and the acrylate include aromatic vinyl compounds such as styrene, methyl styrene, and vinyl toluene which are derived from the following: vinyl acetate; Vinyl carboxylate such as ester and vinyl propionate; vinyl cyanide compound such as acrylonitrile and α-gas acrylonitrile; and maleic imine compound such as Ν-phenylmaleimide. These compounds may be used singly or in combination of two types, 7321228 201003147. A constituent unit which can be copolymerized with a constituent unit derived from an unsaturated carboxylic acid, which is derived from a constituent unit derived from (meth) acrylate, particularly in the form of an unsubstituted or substituted (meth) propyl acrylate. More preferably, the constituent unit derived from the ester of the vinegar or the (%) hydrocarbyl ester of (meth) enoic acid is more preferred. In the binder resin (B), in the total constituent unit of the aforementioned copolymer, the constituent unit derived from the unsaturated carboxylic acid is usually from 1 to 50% by mass, preferably from 15 to 4, in terms of mass fraction. 〇% by mass exists. When the constituent unit derived from the unsaturated carboxylic acid is from 1 Å to 5% by mass in the above-mentioned standard, since the solubility in the developing solution is sufficient, no residue is generated on the substrate of the unexposed portion, and further, When the image is developed, the film portion of the pixel portion of the exposed portion does not decrease, and the entire pixel does not tend to be peeled off, and is preferable. The copolymerization is generally carried out using a polymerization initiator in a solvent. The polymerization initiator may, for example, be a compound such as 2, 2,-azobisisobutyronitrile or 2,2,-azobis(3)Z-propionic acid methyl vinegar, benzoyl peroxide or tributyl peroxide. Such as peroxides. In addition, as long as the solvent dissolves each monomer, T column, such as ethylene glycol monomethyl acetate, ethylene glycol monoethyl acetate, glycerol: alcohol early ether acetate, propylene glycol monoethyl ether The reaction temperature such as a glycol ether ester such as an acetate may be determined in consideration of the decomposition temperature of the polymerization initiator, the solvent, and the point of the monomer. Further, the copolymer obtained as described above may be modified with a compound having a sensitizing group to form a viscous resin, and a resin (8). At this time, it is also possible to add a sensitizing group into the resin = catalyst. The catalyst may be exemplified by tris(didecylaminomethyl). In addition, an additive for preventing side reactions may also be added. The additive may, for example, be hydrogen 321228 8 201003147 酉. The weight average molecular weight of the binder resin (B) in terms of polystyrene is preferably from 5,000 to 100,000, more preferably from 7,000 to 50,000. When the weight average molecular weight of the binder resin (B) converted to polystyrene is from 5,000 to 100,000, since the film reduction is less likely to occur at the time of development, and the detachment property of the non-pixel portion is good at the time of development, Therefore, it is better. The binder resin (B) is usually from 5 to 90% by mass, preferably from 10 to 70% by mass, based on the total solid content in the coloring photosensitive resin composition. When the content of the binder resin (B) is 5 to 90% by mass based on the above-mentioned standard, since the solubility to the developing solution is sufficient, development residue is less likely to occur on the substrate of the non-pixel portion, and at the time of development It is less likely that the film portion of the pixel portion of the exposed portion is reduced, and the non-pixel portion has a good detachment property and is preferred. The photopolymerizable compound (C) contained in the colored photosensitive resin composition of the present invention is a compound which is polymerized by the action of light and a photopolymerization initiator (D), and is, for example, a compound having a carbon-carbon unsaturated bond. As appropriate. The photopolymerizable compound (C) may, for example, be a monofunctional monomer, a difunctional monomer or another polyfunctional monomer. Specific examples of the monofunctional monomer include decyl phenyl carbitol acrylate, 2-hydroxy-3-phenoxypropyl acrylate, 2-ethylhexyl carbitol acrylate, and 2-hydroxyethyl acrylate. , N-vinyl pyrrolidone and the like. Further, specific examples of the difunctional monomer include, for example, 1,6-hexanediol di(meth)acrylate, ethylene glycol di(decyl)acrylate, neopentyl glycol di(meth)acrylate, Triethylene glycol bis(indenyl) acrylate, bisphenol A bis (propane 9 321228 201003147 cycloaliphatic oxyethyl) ether, 3~methyl pentanediol di(meth) acrylate vinegar, brothel Methanol II (Yinji) acrylic acid vinegar and the like. Specific examples of the other polyfunctional monomer include, for example, trimethylsulfonium triacetate tris(meth)acrylic acid vinegar, pentaerythritol tris(meth)acrylic acid vinegar, pentaerythritol tetrakis(meth)acrylate, and dipentaerythritol five ( Methyl) propylene vinegar, dipentaerythritol hexa(methyl) acrylate vinegar, isotrimeric acid tris(methyl propyl acetoacetate). The photopolymerizable compound (c) is preferably one having a propylene fluorenyl group (10) = CHC0-) and a compound having a maximum number of propylene groups per unit weight, in other words, a gram of a scaly-equivalent propyl group. It is preferred that the acrylonitrile equivalent is small, and the compound having a (4) olefin conversion amount of (10) or less is more preferable. When the C-base equivalent becomes large, when the exposure or development is performed, the sensitivity is insufficient, so that the productivity of the color filter may be lowered. The monomer having a sulfhydryl group equivalent of 1 GG or less may, for example, be ethylene glycol dipropylene ester, 3 to methyl propyl triacetate, pentaerythritol tripropylene acid, and quaternary pentoxide. Acetic acid vinegar, dipentaerythritol, hexapropyl hexagram, etc., preferably, may be, for example, three (four) base city tripropylene, quaternary alcohol tetrapropyl vinegar or dipentaerythritol hexahydrate. Further, the photopolymerizable compound (6) is preferably a monomer or other polyfunctional monomer. The content of the pharmaceutically acceptable compound is usually from i to 60 parts by mass, preferably from 5 to 5 parts, based on the total (10)f parts of the binder resin (8) and the polymerizable compound (C) in the colored photosensitive resin composition. Parts by mass. When the content of the photopolymerizable compound (C) is within the above range, the second portion of the pixel portion, the pattern shape, and the smoothness tend to be improved, which is preferable. / 321228 10 201003147 The photopolymerization initiator (D) may, for example, be an active radical generator which generates an active radical by light irradiation, an acid generator which generates an acid, or the like. Examples of the living radical generating agent include an acetophenone-based photopolymerization initiator, a benzoin-based photopolymerization, a combination initiator, a triterpene photopolymerization initiator, and a benzophenone photopolymerization initiator. And two-line photopolymerization initiators and the like. The acetophenone-based photopolymerization initiator may, for example, be 2-methyl-2-(N-morpholinyl)-1-(4-methylthiophenyl)propanone, diethoxyacetophenone, 2_ Hydroxy-2-methyl-1-phenylpropane-i-one, benzyl dimethyl ketal, 2-hydroxy-2-methyl 1 [4-(2-p-ethoxy)phenyl] Burning ketone, ketocyclohexyl phenyl ketone, 2-benzyl-2-dimethylamino-i-(4-(N-morpholinyl)phenyl)butan-1-one, An oligomer of 2-hydroxy-2-methyl-1-[4-(1-mercaptovinyl)phenyl]propan-1-one or the like. The benzoin-based photopolymerization initiator may, for example, be benzoin, benzoin, methyl ether, benzoin ethyl ether, benzoin isopropyl ether or benzoin isobutyl ether. The three-till photopolymerization initiator may, for example, be 2,4-bis(trichloromethyl)-6_X (4-methoxyphenyl) 1,3,5-three tillage, 2,4-bis (three Chloromethyl)-6-(4-: methoxynaphthyl)-1,3, 5-trin, 2,4-bis(trichloromethyl)-6-to geranyl-1,3, 5-three tillage, 2, 4-bis(trichloromethyl)-6-(4-methoxystyryl)-1'3'5-triterpene, 2,4-bis(tris) _6_[2-(5-decylfuran-2-yl)vinyl]-1,3,5-trimorphine, 2,4-bis(trichloromethyl)-6-[2-(furan-2- Vinyl]3, 5_three tillage, 2, 4_bis(trichloromethyl)-6-[2-(4-diethylamino-2-methylphenyl)vinyl bromide, 3, 5-tris(R), 2,4-bis(trichloroindenyl)-6-[2-(3,4-dimethoxyphenyl)vinyl]_ι, 3, 5_ triterpene, etc. 321228 11 201003147 The monobenzoic photopolymerization initiator may, for example, be a dioxin, a methyl benzoate, a 4-phenyl benzophenone, a 4-phenylidene group, a methyl group. Phenyl sulfide, 3, 3', 4, 4,-tetrakis (tert-butylcarbonyl peroxide) dimercapto ketone, 2,4,6-trimethylbenzophenone, etc. beginning For example, a fluorene-based fluorene-based compound may be mentioned, and specific examples thereof include 1-(4-phenylthio-phenyl)-butane-1,2-dione 2-indole-quinone-benzoate. 1-(4-phenylthio-phenyl)-octane-indole, 2-dione 2-indole-0-benzoate, 1-[9-ethyl-6-(2-ethylbenzamide) _9H-carbazol-3-yl]ethanone 1-indole-acetate, bu [9_ethyl_6_(2_mercapto_4_(3,3-dimethyl-2, 4-di) Oxyheterocyclopentyloxy)phenylphenyl)-indolyl-3-yl]ethanone 1-0-acetate, etc. The active radical generating agent other than the above-exemplified examples may, for example, be 2 , 4,6-dimethylbenzimidyl diphenylphosphine oxide, 2, 2'-bis(o-chlorophenyl)-4,4,5,5-tetraphenyl--1,2,-linked Imidazole, [〇_butyl-2_chloroacridone, 2-ethyl hydrazine, diphenylethylenedione (benzi丨), 9, 丨〇 phenanthrenequinone, camphorquinone, phenylglyoxylate Ester, titanocene compound, etc. The acid generator may, for example, be 4-hydroxyphenyldimethylhydrazine sulfonate, 4-hydroxyphenyldifluorenyl hexafluoroantimonate, 4-ethyl b-toluenesulfonic acid Nonyloxy phenyl dimethyl hydrazine, hexafluoroantimonic acid 4-ethenyloxy phenyl fluorenyl benzene Base, triphenylsulfonium p-toluenesulfonate, triphenylsulfonium hexafluoroantimonate, diphenylsulfonium p-toluenesulfonate, diphenylsulfonium hexafluoroantimonate, etc. or nitrobenzyltoluene An acid ester, a benzoin, a fluorene phthalic acid vinegar, etc. Further, among the above compounds, in the case of a living radical generating agent, a compound which generates an active radical and an acid, such as a trimorphic photopolymerization, is also present. 321228 12 201003147 A living radical generator such as a starter can also be used as an acid generator. These photopolymerization initiators (D) may be used alone or in combination of two or more. The photopolymerization initiator (D) can also be used in combination with a photopolymerization initiation aid. The photopolymerization initiation aid is preferably an amine compound, a thiol group-containing compound or a carboxylic acid compound, and the amine compound is preferably an aromatic amine compound. The amine compound may, for example, be an aliphatic amine compound such as triethanolamine, methyldiethanolamine or triisopropanolamine; 4-dimethylaminobenzoic acid oxime ester, 4-dimethylaminobenzoic acid ethyl ester, 4 -isoamylaminobenzoic acid isoamyl ester, 4-didecylaminobenzoic acid 2-ethylhexyl benzoate, 2-dimethylaminoethyl benzoate, N,N-dimethyl-p-anilide An aromatic amine compound such as 4,4'-bis(dimercaptoamino)benzophenone (commonly known as micbutone) or 4,4'-bis(diethylamino)benzophenone. The thiol group-containing compound is a compound having a thiol group in the molecule, and the thiol compound having one thiol group is exemplified by 2-mercaptobenzoic acid. Examples of the aliphatic polyfunctional thiol compound having a plurality of thiol groups in the aliphatic group, such as hexane dithiol or decane dithiol, are exemplified by oxazole, 2-M benzoxazole, and the like. 4-dimethylnonylbenzene, butanediol dithiopropionate, butanediol dithioglycolate, ethylene glycol dithioglycolate, trishydroxypropyl propane thioglycolate, butanediol Thiopropionate, trimethylolpropane thiopropionate, trihydrocarbyl propane thioacetate, pentaerythritol thiopropionate, pentaerythritol thioglycolate, trishydroxyethyl thiopropionate Wait. The carboxylic acid compound may, for example, be phenylthioacetic acid, methylphenylthioacetic acid, 13 321228 201003147 ethylphenylthioacetic acid, mercaptoethylphenylthioacetic acid, dimethyl phenyl acetoacetate, methoxyphenyl group. Sulfuric acid, dimethoxy phenyl thioacetic acid, chlorophenyl thioacetic acid, dichlorophenyl thioacetic acid, N-phenylglycine, stupidoxyacetic acid, thiol acetic acid, naphthylglycine, naphthyloxy Acetic acid. Further, in addition to these, a thioglycolate or a thiopropionate of a preferred polyhydric hydroxy compound such as a thioglycolic acid or a thiopropionate of a polyvalent hydroxy compound may be mentioned, for example, a trihydroxy decyl propane ginseng. Thiopropionate, tri-methyl-m-alkane thioglycolate and pentaerythritol thiopropionate. The content of the photopolymerization initiator (D) is usually from 〇.丨 to 4〇 parts by mass, preferably from 1 to 30 by mass, based on 100 parts by mass of the total of the binder resin (B) and the photopolymerizable compound (c). Share. The content of the photopolymerization initiation aid is usually from 0.1 to 50 parts by mass, preferably from 1 to 40 parts by mass, per 100 parts by mass of the total of the binder resin (?) and the photopolymerizable compound (C). Solvents (Ε) are various solvents that can be used in this field. Specific examples thereof include ethylene glycol monoalkyl ethers such as ethylene glycol monoterpene ether, ethylene glycol monoethyl ether, ethylene glycol monopropyl ether, and ethylene glycol monobutyl ether; diethylene glycol dimethyl ether; Diethylene glycol dialkyl ethers such as diethylene glycol diethyl ether, diethylene glycol dipropyl ether and diethylene glycol dibutyl ether; methyl cel losolve acetate, Glycol alkyl ether acetate such as acetonitrile acetate; diglycol monoterpene ether acetate, propylene glycol monoethyl ether acetate, propylene glycol monopropyl acetate, decyloxybutyl b Alkanediol alkyl ether acetates such as acid esters and decyloxypentyl acetate; 321228 14 201003147 benzene, toluene, diphenylbenzene and 1,3,5_trihydrocarbons; aromatics such as mesitylene Groups of methyl ethyl ketone, acetone, methyl amyl ketone, methyl isobutyl ketone and cyclic ketones; ethanol: alcohols such as propanol, butanol, hexanol, cyclohexanol, ethylene glycol and glycerol 3 esters such as ethyl ethoxypropionate and decyl methoxypropionate; 7 - cyclic g of butyl vinegar and the like. These solvents (E) may be used alone or in combination of two or more. The content of the mass fraction (8) is usually 6 〇 to (10) f% by weight based on the mass of the photosensitive resin composition as a whole, and it is preferred that the content of the glutinous rice (8) is within the aforementioned range. It is preferable that the coating property tends to be 3C. The coloring photosensitive composition of the present invention may further contain a dispersant, a adhesion promoter, an antioxidant, and an ultraviolet absorption iJ. (F;. The addition of the preventive material, surfactant, other polymer compound, etc. can be specifically solved as surface, oxygen, oxygen, etc., fluorine, cation = diterpene = active agent, etc. They are used alone or in combination with two kinds of materials. The surfactants are described as _, polyoxy-extended ethyl phenyl phenyl squama, upper = oxygen: Ethyl alcohol anhydride fatty acid esters, fatty acid changes, monoterpenes , Yamanashi, Polyethylenimine, etc., in addition to: 商品 商品 商品 ΚΡ 信 信 信 信 (Shin-Etsu 321228 15 201003147 Chemical Industry Co., Ltd.), Polyflow (made by Kyoei Chemical Co., Ltd.), F-Top ( Tohkem Products Co., Ltd., Megaface (Otsuka Ink Chemical Industry Co., Ltd. Company system), Fluorad (manufactured by Sumitomo 3M Co., Ltd.), AsahiGuard, Surf 1 on (the above is manufactured by Asahi Shiko Co., Ltd.), Solsperse (made by Abysia Co., Ltd.), EFKA (made by EFKA CHEMICALS), PB821 ( Ajinomoto Co., Ltd.), etc. The adhesion promoter may specifically be exemplified by vinyl trimethoxy sulphate, ethylene diethoxy sulphur, and ethylene di(2- methoxy ethoxy). Shi Xiyuan, n-(2-aminoethyl)-3-aminopropyl-decyldimethoxydecane tN-(=aminoethyl)-3-aminopropyltrimethoxy decane , 3-aminopropyltriethoxy zephyr, 3-glycidoxypropyltrimethoxy zeoxime, ^'diglycerol & propyl propyl decyloxydecane, 2-(3, 4-epoxycyclohexyl)ethyltrimethoxydecane, 3-chloropropylindenyl decyloxydecane, gas "propyldioxyxanthine, 3-mercaptopropeneoxypropyl Trimethoxy oxime, 3_weipropyl propyl trimethoxy decane, etc. The antioxidant may specifically be exemplified by 2, 2'-thiobis (4-mercapto-t-butyl group), 2, 6 -two-number Butyl-4-mercapto expectation. The ultraviolet absorber may specifically be exemplified by 2-(3__second butyl-$-5-nonylphenyl)-5-gas benzotriazine, alkoxy succinyl A. The agglutination preventing material may specifically be, for example, sodium polyacrylate. The surfactant is preferably an interface-active sword having a saponin or a stellite atom. The H-type surfactant and the oxygen-based interface activity having a fluorine atom are at least one of 321228 16 201003147 in the group. The polyoxo-based surfactant may, for example, be an surfactant having a decane bond. Specifically, TORAY silicone DC3PA, TORAY silicone SH7PA > TORAY silicone DC11PA > TORAY si 1 icone SH21PA'TORAY silicone SH28PA'TORAY silicone 29SHPA, TORAY silicone SH30PA, polyether modified oyster sauce SH8400 (trade name, TORAY) Silicone Co., Ltd.), KP32, KP322, KP323, KP324, KP326, KP340, KP341C, Shin-Etsu Silicone Co., Ltd.), TSF400, TSF401, TSF410, TSF4300, TSF4440, TSF4445, TSF-4446 'TSF4452' TSF4460 (Momentive Performance Materials Japan Joint company system) and so on. The fluorine-based surfactant may, for example, be a surfactant having a fluorocarbon chain. Specifically, for example, Fluorad (trade name) FC430, Fluorad FC431C Sumitomo 3M Co., Ltd., Megaface (trade name) F142D, Megaface F171, Megaface F172, Megaface F173, Megaface F177, Megaface F183, Megaface F489, Megaface F554, Megaface R30 (made by DIC Co., Ltd.), F-Top (trade name) EF301, F-Top EF303, F-Top EF351, F-ΊΓορ EF352 (made by New Akita Chemical Co., Ltd.), Surf Ion (trade name) ) S381,
Surilon S382、Surflon SC101、Surflon SC105(旭硝子股 份有限公司製）、E5844(大金精化研究所股份有限公司 製）、BM-1000 ' BM-1100(皆為商品名，BM Chemie 公司製） 等。 前述具有I原子之聚石夕氧系界面活性劑可列舉如具有 321228 17 201003147 矽氧烷鍵及氟碳鏈之界面活性劑等。具體而言，可列舉如 Megaface(註冊商標）R08、Megaface BL20、Megaface F475、 Megaface F477、Megaface F443(DIC 股份有限公司製）等。 此等界面活性劑可單獨使用或組合2種以上使用。 其他高分子化合物具體上可使用：環氧樹脂等熱硬化 性樹脂，聚S旨、聚胺醋荨熱塑性樹脂；聚乙稀醇、聚丙稀 酸、聚乙二醇單烷基醚、聚丙烯酸氟烷酯等。 本發明之者色感光性樹脂組成物係例如可藉由下述才^ 作而調製。亦即’先將顏料（A)與溶劑（E)混合，然後使用 珠磨機（beads mill)等進行分散，直到顏料之平均粒徑成 為0. 2/zm以下左右為止。此時’因應需要可使用顏料分散 劑’且有時亦調配黏結劑樹脂（B)之一部分或全部。在所^ 之分散液（研磨基料（mi 11 base))中添加黏結劑樹脂（^)之 餘量、光聚合性化合物（C)及光聚合起始劑〇))、因應+要 而使用之其他成分、以及因應需要之追加溶劑，使节等成 為預定之濃度，而獲得目的之著色感光性樹腊組成物。 如此调製之者色感光性樹脂組成物係例如可如下〜十、般 塗佈於基材上’進行光硬化及顯像’而製成著色像素。首 先’將此組成物旋轉塗佈於基板（通常為破蹲）上，藉由力 熱乾燥（預烘烤）而去除溶劑，獲得平滑之塗膜。此日^之余 膜厚度為約1至左右。對如此獲得之塗膜，隔著用ρ 形成目的圖像之負遮罩（negative mask)而照射紫外線此 時’較佳係使曝光部整體均勻地被平行光線照射，且使用 遮罩對準機（mask aligner)等裝置以使遮罩與基板成為正 321228 18 201003147 確位置。然後，使硬化完畢之塗膜接觸稀驗性水溶液而溶 解非曝光部，藉由顯像而獲得目的之像素。在顯像後，亦 可因應需要而在150至230°C實施10至60分鐘左右之後 ，硬化（後烘烤）。 圖案化曝光後之顯像所使用之顯像液通常為含有鹼性 化合物與界面活性劑之水溶液。 驗性化合物可列舉如無機及有機之驗性化合物。無機 驗性化合物之具體例可列舉如氫氧化納、氫氧化钟、填酸 氫二鈉、鱗酸二氫鈉、麟酸氫二銨、填酸二氫按、鱗酸二 氫鉀、矽酸鈉、矽酸鉀、碳酸鈉、碳酸鉀、碳酸氫鈉、碳 酸氫鉀、棚酸納、酸_、氨等。 又，有機驗性化合物之具體例可列舉如氫氧化四甲基 銨、氫氧化2-羥基乙基三曱基銨、單甲基胺、二曱基胺、 三曱基胺、單乙基胺、二乙基胺、三乙基胺、單異丙基胺、 二異丙基胺、乙醇胺等。此等無機及有機之驗性化合物可 分別單獨使用或組合2種以上使用。鹼性顯像液中之鹼性 化合物之較佳濃度為0. 01至10質量％，更佳為0. 03至5 質量％。 又，鹼性顯像液中之界面活性劑可列舉如非離子系界 面活性劑、陰離子系界面活性劑、或陽離子系界面活性劑。 非離子系界面活性劑之具體例可列舉如聚氧伸乙基烷 基醚、聚氧伸乙基芳基醚、聚氧伸乙基烷基芳基醚、其他 聚氧伸乙基衍生物、氧伸乙基/氧伸丙基嵌段共聚物、山 梨醇酐脂肪酸酯、聚氧伸乙基山梨醇酐脂肪酸酯、聚氧伸 19 321228 201003147 乙基山梨醇㈣酸8旨、甘油脂肪酸s旨、聚氧伸乙基脂肪酸 酯、聚氧伸乙基烷基胺等。 陰離子系界面活性劑之具體例可列舉如月桂醇硫酸酯 鈉或油醇硫酸醋納等高級醇硫酸醋鹽類、月桂基硫酸納或 月桂基硫酸錢等烧基硫酸鹽類、十二坑基苯石黃酸納或、十 二烷基萘磺酸鈉等烷基芳基磺酸鹽類等。 陽離子系界面活性劑之具體例可列舉如鹽酸硬脂基胺 鹽酸鹽或氣化月桂基三？基銨等胺鹽或第4級錢鹽等。 此等界面活性劑可分別單獨使用，亦可組合2種以上 使用。 驗性顯像液中之界面活性劑之較佳濃度為0.01至10 質量％，更佳為0.05至8質量％，特佳為〇1至5質量％。 。歷經著色感光性樹脂組成物之塗佈、乾燥、對所得乾 f塗膜之圖案化曝光、以及顯像等各步驟，而獲得相當於 著色感光性樹月旨組成物中之著色成分之顏色的像素，並 ί.’藉„由將此等操作重複進行濾色器所需之顏色之數而獲 得遽色器。亦即，濾色器通常可將紅、綠及藍之三原色像 素配置於基板上。 使用本發明之著色感光性樹脂組成物形成紅色像素。 該、，工色像素令，CIE色度圖之x，y之座標值較佳為〇·5〇〇 <Χ<0·690、0·280<υ< 0.340,更佳為 〇 52〇<x<〇 68〇、 0. 290< y < 〇· 340。 依本發明，即可製造高對比之紅色像素及渡色器。 3有由使用本發明之著色感光性樹脂組成物所得之像 321228 20 201003147 素的濾色器，可適用於各種顯示裝置，例如監視器或電視 等液晶顯示裝置等。 (實施例） 以下，依據實施例而更詳細說明本發明。例中之「％」 及「份」若無特別註明，即表示「重量％」及「重量份」。 <黏結劑樹脂（B1)之合成> 在備有攪拌機、溫度計、回流冷卻管、滴液漏斗及氣 體導入管之1L燒瓶中，導入丙二醇單甲醚乙酸酯133g。 然後，經由氣體導入管將氮氣導入燒瓶内，將燒瓶内氣體 環境取代為氮氣。之後，將燒瓶内之溶液升溫至100°C， 並將由曱基丙烯酸二環戊酯（FA-513M，日立化成工業股份 有限公司製）22.0g(0. 10莫耳）、曱基丙烯酸苯甲酯82.8g (0.47莫耳）、曱基丙烯酸37.0廷（0.43莫耳）、2,2’-偶氮 雙異丁腈3. 6g及丙二醇單曱醚乙酸酯164g所構成之混合 物使用滴液漏斗耗費2小時滴入燒瓶内，在滴下完畢後再 於100°C攪拌5小時。 攪拌完畢後，經由氣體導入管將空氣導入燒瓶内，使 燒瓶内氣體環境取代為空氣後，將甲基丙烯酸縮水甘油酯 21.5g(0. 15莫耳）、三（二曱基胺基甲基）酚0.9g及氫醌 0. 145g投入燒瓶内，於110°C持續反應6小時，而獲得固 形份37. 8質量％、酸價97mgKOH/g的黏結劑樹脂（B1)。 在此，酸價係以中和具有緩酸等酸基之聚合物1 g所需 的氫氧化钟的量（mg)作為測定值，通常係藉由使用濃度已 知之氫氧化鉀水溶液滴定而求得。 21 321228 201003147 以下述條件之GPC法測定所得黏結劑樹脂（B1)之換算 成聚苯乙烯之重量平均分子量為9, 000。 裝置：HLC-8120GPC(東曹股份有限公司製） 管柱：TSK-GELG2000HXL 管柱溫度：40°C 溶媒：THF 流速：1. OmL/分鐘 受檢液固形份濃度：0. 001至0. 01質量％Surilon S382, Surflon SC101, Surflon SC105 (made by Asahi Glass Co., Ltd.), E5844 (made by Daikin Seika Co., Ltd.), BM-1000 'BM-1100 (all are trade names, manufactured by BM Chemie Co., Ltd.). The polyoxo-based surfactant having the I atom may, for example, be a surfactant having a 321228 17 201003147 oxime bond and a fluorocarbon chain. Specific examples include Megaface (registered trademark) R08, Megaface BL20, Megaface F475, Megaface F477, and Megaface F443 (manufactured by DIC Corporation). These surfactants may be used singly or in combination of two or more. As the other polymer compound, a thermosetting resin such as an epoxy resin, a polystyrene phthalate thermoplastic resin, a polyethylene glycol, a polyacrylic acid, a polyethylene glycol monoalkyl ether, or a polyacrylic acid fluoride can be used. Alkyl esters and the like. The color photosensitive resin composition of the present invention can be prepared, for example, by the following. That is, the pigment (A) is mixed with the solvent (E), and then dispersed using a bead mill or the like until the average particle diameter of the pigment is about 0.2 or less. At this time, a pigment dispersant may be used as needed, and some or all of the binder resin (B) may be blended. Adding the balance of the binder resin (^), the photopolymerizable compound (C), and the photopolymerization initiator 〇)) to the dispersion (mi 11 base), and using it in accordance with The other components and the additional solvent required for the purpose, the knots and the like are brought to a predetermined concentration, and the desired colored photosensitive wax composition is obtained. The photosensitive resin composition prepared in this manner can be applied, for example, to a substrate as described below, and subjected to photocuring and development to form a colored pixel. First, the composition is spin-coated on a substrate (usually broken), and the solvent is removed by forced drying (prebaking) to obtain a smooth coating film. The film thickness of this day is about 1 to about. The coating film thus obtained is irradiated with ultraviolet rays through a negative mask which forms a target image with ρ. At this time, it is preferable to uniformly expose the entire exposed portion to parallel rays, and use a mask aligning machine. (mask aligner) and other devices to make the mask and substrate become positive 321228 18 201003147. Then, the cured coating film is exposed to a rare aqueous solution to dissolve the non-exposed portion, and the intended pixel is obtained by development. After the development, it may be subjected to hardening (post-baking) after being carried out at 150 to 230 ° C for about 10 to 60 minutes as needed. The developing solution used for development after patterning exposure is usually an aqueous solution containing a basic compound and a surfactant. The test compound may, for example, be an inorganic or organic test compound. Specific examples of the inorganic compound include, for example, sodium hydroxide, hydrogen peroxide, disodium hydrogen hydride, sodium dihydrogen hydride, diammonium hydride, dihydrogen hydride, potassium dihydrogen hydride, and citric acid. Sodium, potassium citrate, sodium carbonate, potassium carbonate, sodium hydrogencarbonate, potassium hydrogencarbonate, sodium sulphate, acid _, ammonia, and the like. Further, specific examples of the organic test compound include tetramethylammonium hydroxide, 2-hydroxyethyltriammonium hydroxide, monomethylamine, dinonylamine, tridecylamine, and monoethylamine. , diethylamine, triethylamine, monoisopropylamine, diisopropylamine, ethanolamine, and the like. These inorganic and organic test compounds may be used alone or in combination of two or more.至质量质量质量。 The preferred concentration of the alkaline compound is 0. 01 to 10% by mass, more preferably 0.03 to 5% by mass. Further, examples of the surfactant in the alkaline developing solution include a nonionic surfactant, an anionic surfactant, and a cationic surfactant. Specific examples of the nonionic surfactant include polyoxyethylene ethyl ether, polyoxyethylene ethyl aryl ether, polyoxyalkylene aryl ether, and other polyoxyethylene derivatives. Oxygen extended ethyl/oxypropyl propyl block copolymer, sorbitan fatty acid ester, polyoxyethylene ethyl sorbitan fatty acid ester, polyoxygen extension 19 321228 201003147 Ethyl sorbitol (tetra) acid 8 glycerol fatty acid s, polyoxyethylene ethyl ester, polyoxyethylene ethylamine and the like. Specific examples of the anionic surfactant include, for example, higher alcohol sulfate sulfates such as sodium lauryl sulfate or oleyl sulfate, sodium laurate or lauryl sulfate, and the like. An alkyl aryl sulfonate such as sodium benzoate or sodium dodecyl naphthalene sulfonate. Specific examples of the cationic surfactant include, for example, stearylamine hydrochloride or gasified lauryl trisole. An amine salt such as a quaternary ammonium or a fourth-grade money salt or the like. These surfactants may be used alone or in combination of two or more. The preferred concentration of the surfactant in the test imaging liquid is from 0.01 to 10% by mass, more preferably from 0.05 to 8% by mass, particularly preferably from 1 to 5% by mass. . The coating of the colored photosensitive resin composition, drying, patterning exposure of the obtained dry f coating film, and development are performed to obtain a color corresponding to the coloring component in the coloring photosensitive composition. Pixels, and ί. 'borrowing' by the number of colors required to repeat the color filter to obtain a color filter. That is, the color filter can usually arrange the three primary color pixels of red, green and blue on the substrate. The red color pixel is formed by using the colored photosensitive resin composition of the present invention. The color pixel of the CIE chromaticity diagram is preferably 〇·5〇〇<Χ<0·690 , 0·280 < υ < 0.340, more preferably 〇 52 〇 < x < 〇 68 〇, 0. 290< y < 〇 · 340. According to the invention, high contrast red pixels and color filters can be manufactured (3) A color filter having an image of 321228 20 201003147 obtained by using the colored photosensitive resin composition of the present invention can be applied to various display devices such as a liquid crystal display device such as a monitor or a television. The present invention will be described in more detail based on examples. "%" And "parts" unless otherwise indicated, that means "% by weight" and "parts by weight." <Synthesis of the binder resin (B1)> In a 1 L flask equipped with a stirrer, a thermometer, a reflux cooling tube, a dropping funnel and a gas introduction tube, 133 g of propylene glycol monomethyl ether acetate was introduced. Then, nitrogen gas was introduced into the flask through a gas introduction tube, and the gas atmosphere in the flask was replaced with nitrogen. After that, the solution in the flask was heated to 100 ° C, and 22.0 g (0.10 mol) of thioglycolic acid was prepared from dicyclopentanyl acrylate (FA-513M, manufactured by Hitachi Chemical Co., Ltd.). a mixture of 82.8 g (0.47 mol) of ester, 37.0 thiol acrylate (0.43 mol), 2,2'-azobisisobutyronitrile 3. 6 g and propylene glycol monoterpene ether acetate 164 g The funnel was dropped into the flask over 2 hours, and after the completion of the dropwise addition, the mixture was further stirred at 100 ° C for 5 hours. After the stirring was completed, the air was introduced into the flask through a gas introduction tube, and after the gas atmosphere in the flask was replaced with air, 21.5 g (0.15 mol) of methacrylic acid glycidyl ester and tris(didecylaminomethyl group) were added. Phenol 0.9 g and hydroquinone 0. 145 g was placed in a flask, and the reaction was continued at 110 ° C for 6 hours to obtain a binder resin (B1) having a solid content of 37.8% by mass and an acid value of 97 mgKOH/g. Here, the acid value is a measured value of a hydration clock (1 mg) required to neutralize 1 g of a polymer having an acid group such as a slow acid, and is usually obtained by titrating with a potassium hydroxide aqueous solution having a known concentration. Got it. 21 321228 201003147 The weight average molecular weight of the obtained binder resin (B1) converted to polystyrene was 9000 by the GPC method under the following conditions. 001至0. 01。 The device: HLC-8120GPC (made by Tosoh Co., Ltd.) Column: TSK-GELG2000HXL Column temperature: 40 ° C Solvent: THF Flow rate: 1. OmL / minute test liquid solid concentration: 0. 001 to 0. 01 quality%
注入量：5 0 // L 檢測器：RI 校正用標準物質：TSK STANDARD POLYSTYRENE F-40、 F-4、F-l、A-2500、A-500(東曹股份有限公司製） 本實施例使用之其他成分係如表1所示。 22 321228 201003147 [表1] 顏料 (A1) C. I.顏料紅177 (A2) — c. I.顏料紅242 (A3) C. I.顏料紅254 光聚合性化合物 (〇 二季戊四醇六丙烯酸酯 光聚合起始劑 (D1) OXE-OK肟系化合物，汽巴精化股份_ 限公司製） (D2) 2, 4-雙（三氯甲基）-6-向日蔡基~1，3 ^ -三畊 ’ (D3) 本甲基-2-二曱基胺基-1- ♦基）苯基）丁烧-1-酿I 溶劑 (E1) 丙二醇單甲醚乙酸酯 (E2) — 丙二醇單甲醚 (E3) 乙氧基丙酸乙酉旨 界面活性劑 (F) Megaface F475(大日本油墨化學工業股 份有限公司製） (實施例1) 混合各成分使其成為如表2所示之組成，獲得著色感 光性樹脂組成物1。使用所得之著色感光性樹脂組成物1 依下述方法進行塗膜之評估。 <評估用塗膜之製作> 將邊長2英吋之正方形玻璃基板（# 1737，康寧公司製） 依序以中性洗劑、水及乙醇洗淨後，予以乾燥。 23 321228 201003147 以旋塗法將著色感光性樹脂組成物1塗佈於此玻璃基 板上，然後於無塵烤箱（clean oven)中以100°C預烘烤3 分鐘。 冷卻後，使用曝光機（TME-150RSK ’ T0PC0N股份有限 公司製）在大氣環境下以150mJ/cm2之曝光量（365nm)進行 光照射，然後以220°C加熱20分鐘，製作評估用塗膜。 <膜之評估> 對於評估用塗膜，使用膜厚計（DEKTAK，Veeco公司製） 測定膜厚，並使用顯微分光測光裝置（OSP-SP200，OLYMPUS 公司製）測定色度（X，y)及亮度（Y)。此外，使用對比測定 機（CT-1，壺坂電機公司製）測定對比值，以10000作為空 白試驗值進行測定。結果表示於表3。 24 321228 201003147 [表2] 實施例1 組成物1 顏料 (A1) 1. 850 (A2) 3. 330 (A3) 2. 220 (A2)之含有率 45 (A3)之含有率 30 ' 黏結劑樹脂（僅固形份） (B1) 5. 948 顏料分散劑 2. 514 光聚合性化合物 (C) 3. 203 光聚合起始劑 (D1) 0. 366 (D2) 0. 549 溶劑 (E1) 68. 000 (E2) 4. 000 (E3) 8. 000 界面活性劑 (F) 0.0200 (單位：％) [表3] 膜厚（#m) X y Y 對比 實施例1 組成物1 2.40 0. 658 0. 335 20. 0 3875 (實施例2至6) 以成為表4所示組成之方式，與實施例i同樣操作而 25 321228 201003147 獲得著色感光性樹脂組成物。與實施例1同樣進行評估， 結果表不於表5。 [表4] 實施例2 實施例3 實施例4 實施例5 實施例6 組成物2 組成物3 組成物4 組成物5 組成物6 顏料 (A1) 3. 419 3. 210 0. 697 0. 947 1. 080 (A2) 2. 533 1. 998 1. 161 2. 328 4. 000 (A3) 1. 488 2. 232 5. 882 4. 485 2. 920 (A2)之含有率 34 27 15 30 50 (A3)之含有率 20 30 76 58 37 黏結劑樹脂 (僅固形份） (B1) 8. 251 8. 272 5. 218 5. 170 4. 933 顏料分散劑 2. 709 2. 674 2. 936 3. 002 3. 184 光聚合性化合物 (C) 4. 443 4. 454 2. 810 2. 784 2. 656 光聚合起始劑 (D1) 0. 508 0. 509 0. 803 0. 795 0. 759 (D2) 0. 635 0. 636 0. 482 0. 477 0. 455 溶劑 (E1) 68. 400 68. 400 80. 000 80.000 80. 000 (E2) — — — — — (E3) 7. 600 7. 600 — — — 界面活性劑 (F) 0. 014 0. 014 0. 012 0.012 0. 012 (單位：％) [表5] 膜厚（// m) X y Y 對比 實施例2 組成物2 2. 58 0. 658 0. 326 18. 3 5574 實施例3 組成物3 2. 54 0. 658 0. 326 18. 4 5027 實施例4 組成物4 2. 50 0. 658 0. 337 20. 5 ;3727 實施例5 組成物5 2. 39 0. 658 0. 337 20. 4 4293 實施例6 組成物6 2. 49 0. 658 0. 339 20. 5 4936 26 321228 201003147 (產業上之可利用性） 依據本發明，即可製造高對比之紅色像素及濾色器。 【圖式簡早說明】 無。 【主要元件符號說明】 無0 27 321228Injection amount: 5 0 // L Detector: Standard material for RI calibration: TSK STANDARD POLYSTYRENE F-40, F-4, Fl, A-2500, A-500 (made by Tosoh Corporation) This example is used. The other ingredients are shown in Table 1. 22 321228 201003147 [Table 1] Pigment (A1) CI Pigment Red 177 (A2) — c. I. Pigment Red 242 (A3) CI Pigment Red 254 Photopolymerizable Compound (Plutonium Dipentaerythritol Hexacrylate Photopolymerization Starter ( D1) OXE-OK lanthanide compound, Ciba Specialty Chemical Co., Ltd. _ limited company system) (D2) 2, 4-bis(trichloromethyl)-6-to-day Caiji~1,3^-three-plowing' D3) Benzomethyl-2-didecylamino-1-yl)phenyl)butan-1-ol I solvent (E1) Propylene glycol monomethyl ether acetate (E2) — Propylene glycol monomethyl ether (E3 Ethyl ethoxypropionate surfactant (F) Megaface F475 (manufactured by Dainippon Ink and Chemicals Co., Ltd.) (Example 1) The components were mixed to have a composition as shown in Table 2, and coloring sensitivity was obtained. Resin composition 1. Using the obtained colored photosensitive resin composition 1 Evaluation of the coating film was carried out by the following method. <Preparation of Coating Film for Evaluation> A square glass substrate (#1737, manufactured by Corning Incorporated) having a side length of 2 inches was washed with a neutral detergent, water, and ethanol, and then dried. 23 321228 201003147 The colored photosensitive resin composition 1 was applied onto the glass substrate by spin coating, and then prebaked at 100 ° C for 3 minutes in a clean oven. After cooling, it was irradiated with light at an exposure amount (365 nm) of 150 mJ/cm 2 in an atmosphere using an exposure machine (TME-150RSK 'T0PC0N Co., Ltd.), and then heated at 220 ° C for 20 minutes to prepare a coating film for evaluation. <Evaluation of the film> The film thickness of the film for evaluation was measured using a film thickness meter (DEKTAK, manufactured by Veeco Co., Ltd.), and the color chromaticity (X, measured by OSP-SP200, manufactured by OLYMPUS) was measured using a microscopic spectrophotometer (OSP-SP200, manufactured by OLYMPUS). y) and brightness (Y). Further, a comparative value was measured using a comparative measuring machine (CT-1, manufactured by Hosei Electric Co., Ltd.), and 10000 was used as a blank test value. The results are shown in Table 3. 24 321228 201003147 [Table 2] Example 1 Composition 1 Pigment (A1) 1. 850 (A2) 3. 330 (A3) 2. 220 (A2) Content 45 (A3) Content 30 ' Adhesive resin (solid content only) (B1) 5. 948 pigment dispersant 2. 514 photopolymerizable compound (C) 3. 203 photopolymerization initiator (D1) 0. 366 (D2) 0. 549 solvent (E1) 68. 000 (E2) 4. 000 (E3) 8. 000 Surfactant (F) 0.0200 (unit: %) [Table 3] Film thickness (#m) X y Y Comparative Example 1 Composition 1 2.40 0. 658 0 335 20. 0 3875 (Examples 2 to 6) A coloring photosensitive resin composition was obtained in the same manner as in Example i and in the same manner as in Example i, in the manner shown in Table 4. Evaluation was carried out in the same manner as in Example 1, and the results are shown in Table 5. [Table 4] Example 2 Example 3 Example 4 Example 5 Example 6 Composition 2 Composition 3 Composition 4 Composition 5 Composition 6 Pigment (A1) 3. 419 3. 210 0. 697 0. 947 1. 080 (A2) 2. 533 1. 998 1. 161 2. 328 4. 000 (A3) 1. 488 2. 232 5. 882 4. 485 2. 920 (A2) content rate 34 27 15 30 50 (A3) Content rate 20 30 76 58 37 Adhesive resin (solid content only) (B1) 8. 251 8. 272 5. 218 5. 170 4. 933 Pigment dispersant 2. 709 2. 674 2. 936 3 002 3. 184 Photopolymerizable compound (C) 4. 443 4. 454 2. 810 2. 784 2. 656 Photopolymerization initiator (D1) 0. 508 0. 509 0. 803 0. 795 0. 759 (D2) 0. 635 0. 636 0. 482 0. 477 0. 455 Solvent (E1) 68. 400 68. 400 80. 000 80.000 80. 000 (E2) — — — — — (E3) 7. 600 7 600 — — — Surfactant (F) 0. 014 0. 014 0. 012 0.012 0. 012 (unit: %) [Table 5] Film thickness (// m) X y Y Comparative Example 2 Composition 2 2. 58 0. 658 0. 326 18. 3 5574 Example 3 Composition 3 2. 54 0. 658 0. 326 18. 4 5027 Example 4 Composition 4 2. 50 0. 658 0. 337 20. 5 ;3727 Example 5 Group 5 5 39 。 。 。 。 。 。 。 High contrast red pixels and color filters can be fabricated. [Simple description of the map] None. [Main component symbol description] None 0 27 321228