TW200948906A - Pigment dispersion composition and production method thereof, colored polymerizable composition, and color filter and production method thereof - Google Patents

Abstract

A pigment dispersion composition comprises a diketopyrrolopyrrole pigment, 0.1-30 parts by mass of a phthalimidoalkylated diketopyrrolopyrrole based on 100 parts by mass of the diketopyrrolopyrrole pigment, 0.1-20 parts by mass of a phthalimidoalkylated quinacridone based on 100 parts by mass of the diketopyrrolopyrrole pigment, and at least one organic solvent.

Description

[Technical Field] The present invention relates to a pigment dispersion composition, a method for producing the pigment dispersion composition, a colored polymerizable composition containing the pigment dispersion composition, and the use of the colored polymerizable composition A color filter formed and a method of manufacturing the color filter. [Prior Art] A color filter is a coloring polymer composition comprising a pigment dispersion composition obtained by dispersing an organic pigment or an inorganic pigment, a polyfunctional monomer, a photopolymerization initiator, a base to a soluble resin, and other components. And manufactured by forming a colored pattern by a photolithographic method or the like. In recent years, color dimming sheets have a tendency to be expanded not only to monitors but also to televisions (TVs) in terms of liquid crystal display (LCD) applications, and the tendency to expand with this use has evolved into High color characteristics are required for chromaticity, contrast, and the like. In addition, the use of image sensors (solid-state imaging device ® ) has similarly evolved to require high color characteristics. For the above-mentioned requirements, it is effective to use a pigment obtained by refining the primary particle diameter. The method of miniaturizing the primary particle diameter of the pigment is, for example, a water-soluble inorganic salt such as a synthetic resin or a salt of a salt which is solid and water-insoluble at room temperature, and at least a part of the synthetic resin as described above. The water-soluble organic solvent is mechanically kneaded together by a kneader or the like (hereinafter, the operation of kneading a mixture containing a pigment, a water-soluble inorganic salt, and a water-soluble organic solvent is referred to as "salt-salt" (salt-salt) The method of removing the water-soluble inorganic salt and the water-soluble organic compound 200948906 by water washing (see, for example, Japanese Patent Laid-Open No. Hei 7-13016). In this method, since the pulverization of the primary particles of the pigment and the crystallization growth are simultaneously performed, finally, a pigment having a narrow particle size distribution, a small average particle diameter, and a small surface area can be obtained, and thus, for example, a color filter is obtained. It is a suitable method to disperse a pigment having a fine particle size into a pigment for a high concentration. However, with the pigment prepared as described above, since the drying process after desalination causes intense agglomeration, the dispersibility and dispersion stability are often not good, and therefore, when such a pigment is used, It is difficult to obtain a pigment dispersion having superior dispersibility and dispersion stability. If the dispersibility of the pigment is not sufficient, for example, a fringe (zigzag indent) or surface irregularity may be caused in the colored pattern formed of the polymerizable composition containing the pigment dispersion. Surface irregularity.) The problem that the color or size accuracy of the produced color film is lowered, or the contrast is significantly deteriorated. In addition, when the dispersion stability of the pigment is not sufficient, the constituents of the colored polymerizable composition may agglomerate over time, so that the viscosity is increased, and the pot life becomes extremely short. . Further, when a color filter is produced by using the colored polymerizable composition, the uniformity of the film thickness in the coating step is lowered, and the sensitivity in the exposure step is easily caused, and the alkali in the developing step is easily caused. Problems such as fluctuations in solubility and unevenness. In particular, in the case of forming a colored film using a colored polymerizable composition on a glass substrate for producing a large-area color filter, a slit coating (or also referred to as die coating) is applied. In the case of the above, there is a problem in that defects such as streaks are easily caused on the coated surface, the state of the coated surface is lowered, and the pixel defects of the color filter are further formed. 200948906 Therefore, a method for improving the dispersibility and dispersion stability of a pigment has been proposed as a method of adding rosin or a rosin derivative or a synthetic polymer compound during salt milling (see, for example, Japan). Japanese Laid-Open Patent Publication No. 8-179111. In addition, regarding diketopyrrolopyrrole-based pigments, there has been a proposal to add a pigment derivative by performing salt milling (pigment- Derivatives to promote micronization and to improve contrast (see, for example, Japanese Patent Laid-Open Publication No. 2001-220520 and Japanese Patent Laid-Open Publication No. 2007-3 1539--). However, according to the prior art as described above, when focusing only on the refinement of pigment particles and the comparison of the portraits, although a certain degree of improvement effect can be obtained, the micronized diketopyrrolopyrrole is obtained. For the pigment, in the step of producing a color filter, especially when the development is repeated, post-baking, or UV cleaning, there is a problem that the surface becomes rough. SUMMARY OF THE INVENTION [Technical Problem to be Solved] Therefore, the present invention has been made in view of the above-mentioned problems in order to achieve the following objects. That is, the first object of the present invention is to provide a pigment dispersion composition having superior high pigment dispersibility and stability thereof and capable of forming a color film having superior contrast and a process for producing the same. Further, a second object of the present invention is to provide a colored polymerizable composition which can form a film having superior contrast and further form a color filter having a smooth surface. 200948906 A third object of the present invention is to provide a color filter having a high contrast and a smooth surface, and a method of manufacturing the color filter. [Technical method for solving the problem] The method for solving the above problems is as follows. That is, the pigment dispersion composition of the present invention is characterized in that it contains a diketopyrrolopyrrole pigment in an amount of 0.1 to 30 parts by mass relative to 100 parts by mass of the diketopyrrolopyrrole pigment. The phthalimidoalkylated diketopyrrolopyrrole is 0.1 to 20 parts by mass relative to 100 parts by mass of the diketopyrrolopyrrole pigment. The average primary particle diameter of the phthalimidoalkylated quinacridone and the at least one organic solvent of the diketopyrrolopyrrole pigment as described above is preferably from 10 nm to 30 nm. The diketopyrrolopyrrole pigment used in the pigment dispersion of the present invention is preferably obtained by using the following steps: a diketopyrrolopyrrole pigment, a water-soluble inorganic salt, and substantially insoluble of the water-soluble inorganic substance a water-soluble salt having a step of mechanically kneading a solvent; a step of removing the water-soluble inorganic salt and the water-soluble organic solvent; and a step of drying the diketopyrrolopyrrole pigment; Before the drying step, the diketopyrrolopyrrole pigment is contacted with a resin, and the like. Here, the resin which can be used for the addition is preferably a polymer compound having an acid value of 50 to 300 mgKOH/g. The method for preparing a pigment dispersion composition of the present invention comprises the steps of: adding 200948906 to a diketopyrrolopyrrole pigment having an average primary particle diameter of 10 nm to 30 nm in an amount relative to 100 parts by mass of the diketopyrrolopyrrole pigment. 0.1 to 30 parts by mass of o-phthalimidoalkylened diketopyrrolopyrrole, and 0.1 to 20 parts by mass of ortho-benzene relative to 1 part by mass of the diketopyrrolopyrrole pigment a step of alkylating at least a portion of the quinophthalone; and the diketopyrrolopyrrole pigment is 0.1 to 30 parts by mass relative to 100 parts by mass of the diketopyrrolopyrrole pigment a xylylenediamine alkylated diketopyrrolopyrrole, and 0.1 to 20 parts by mass of the phthalic acid imidoalkylated quinolin relative to 100 parts by mass of the diketopyrrolopyrrole pigment The step of dispersing the anthrone with an organic solvent. The colored polymerizable composition of the present invention comprises the pigment dispersion composition, the photopolymerizable compound, and the photopolymerization initiator of the present invention as described above, and preferably further contains an alkali-soluble resin. The color filter of the present invention is preferably formed using the 'colored polymerizable composition of the present invention as described above, and particularly preferred mode is a colored region formed by the colored polymerizable composition of the present invention. . Further, the method of producing a color filter is characterized in that it uses the coloring polymerizable composition of the present invention as described above, preferably a film is formed on a substrate by a coating method, and the formed film is exposed. It is then developed to remove the unhardened film. The pigment dispersion composition of the present invention is a diketopyrrolopyrrole pigment, a specific amount of o-phthalimidoalkylamine diketopyrrolopyrrole, and phthalic acid imidoalkylated quinolin In the present invention, the indolinone is dispersed in an organic solvent, and the diketopyrrolopyrrole pigment is used to alkylate the diketopyrrolopyrrole and the o-phthalic acid with a phthalate. Iminoalkyl 200948906-based quinophthalone can provide a pigment dispersion composition with superior dispersion stability and contrast, a superior viscosity stability, high contrast and further superior surface smoothness. The colored polymer composition of the color filter, and a color filter having high contrast and excellent surface smoothness. By using o-phthalimidoalkylated diketopyrrolopyrrole and phthalimidoalkylamine to quench the quinophthalone, the stability of the diketopyrrolopyrrole pigment can be improved by this. Sexually exerting a large complementary phase is effective, and therefore, a composition comprising the pigment can form a colored film having superior contrast and high surface smoothness. Although the mechanism of action is not clear, it can be regarded as a diphentopyrrolopyrrole pigment by a phthalate imine alkylated pigment derivative having two different cores and a diketopoxime. Strong interactions at different parts of the surface, making the unstable diketopyrrolopyrrole surface protected, compared to the case where each is used alone, and unexpectedly due to the success of these complementary phases Excellent color stability, and by the coloring polymerizable composition containing the pigment, it is possible to form a color film in which the pigment has been uniformly and stably dispersed, and the contrast is high and the surface smoothness is excellent. [Effect of the Invention] According to the present invention, it is possible to provide a pigment dispersion composition which can form a color film having superior high pigment dispersibility and stability, and superior contrast, and a process for producing the same. Further, according to the present invention, it is possible to provide a colored polymerizable composition which can form a film having superior viscosity stability, superior contrast, and excellent surface smoothness. The colored polymerizable composition is suitable for the production of color 200948906 color filters. Further, according to the present invention, a color filter having a high contrast and a smooth surface can be provided, and a method of manufacturing the color filter can be provided. [Embodiment of the Invention] Hereinafter, the pigment dispersion composition, the method for producing a pigment dispersion composition, the coloring polymerizable composition, the color filter, and the method for producing the same according to the present invention are described in detail. Explain. ® <Pigment Dispersion Composition> The pigment dispersion composition of the present invention is characterized in that it contains (A) a diketopyrrolopyrrole pigment, and the diketopyrrolopyrrole pigment is one part by mass based on 1 part by mass. 0.1 to 30 parts by mass of (B) phthalic acid imidoalkylated diketopyrrolopyrrole, and 0.1 to 20 parts by mass based on 100 parts by mass of the diketopyrrolopyrrole pigment (C) The phthalic acid iminoalkylated quinophthalone, and (D) at least one organic solvent, and optionally other components. ® [(A) Diketopyrrolopyrrole-based pigment] The diketopyrrolopyrrole pigment (hereinafter, sometimes referred to as DPP-based pigment) in the present invention is represented by the following formula (a) The structure is red to orange pigment, and has excellent light resistance and heat resistance. 200948906

In the above formula (A), X and Y each independently represent a hydrogen atom, an alkyl group, a cyano group, an aryl group or a halogen group. Here, the alkyl group is a saturated or unsaturated alkyl group. The alkyl group or the aryl group may also be a group further having a substituent. The substituent which may be introduced into the alkyl group includes, for example, a halogen atom 'alkenyl group, an aryl group, a hydroxyl group, an alkoxy group and the like; and a substituent which may be introduced into the aryl group includes, for example, a halogen atom, an alkyl group, an alkoxy group. Base. When a specific example of the DPP pigment represented by the general formula (A) shown above is represented by a color index number, CI Pigment Red 254, 255, 2 64, and CI Pigment are exemplified. Orange 71. Among these, C.I. Pigment Red 254 is particularly suitable for use in the present invention. In order to obtain a high contrast color filter, the particle size of the DPP pigment used in the present invention is preferably small in particle size and narrow in distribution, and the average primary particle diameter is preferably from 10 nm to 30 nm. . By using particles in this range, a dispersion having superior dispersion stability can be obtained, and by using the dispersion, a high contrast colored cured film can be formed. Here, the particle size of the DPP pigment can be measured, for example, by photographing a pigment at a magnification of 100,000 times using a transmission electron microscope. Further, regarding the average particle diameter, for example, the long diameter and the minor diameter mean of the particles are measured for 500 particles, and the average 値 is regarded as the average particle diameter. The average primary particle diameter in the present invention is determined by the method. The diketopyrrolopyrrole pigment having such an average primary particle diameter can be obtained by a conventional method such as a dry pulverization method, a wet pulverization method, a recrystallization method, an acid paste method, or the like, but Fine particles having a narrow particle size distribution are obtained, and in the present invention, it is preferable to refine by a salt mill. Hereinafter, the case of the diketopyrrole © and pyrrole-based pigment which is to be refined by salt milling will be described in detail. In the present invention, the finely divided diketopyrrolopyrrole pigment is preferably obtained by a method comprising the following steps: a diketone azopyrrolidine pigment, a water-soluble inorganic salt, and substantially a step of removing the water-soluble inorganic salt and the water-soluble organic solvent after mechanically kneading (salting) of the water-soluble organic solvent in which the water-soluble inorganic salt is not dissolved; and further drying; and before drying , the step of contacting the diketopyrrolopyrrole pigment with the resin. Further, the resin to be added after the salt milling and before the drying step is preferably a polymer compound having an acid value of 50 to 300 mgKOH/g. In the salt-grinding treatment, as long as the effects of the present invention are not impaired, in addition to the above-mentioned resin, additives such as a pigment dispersing aid, a plasticizer, a surfactant, and the like may be used in combination for the purpose, and each of them will be described in detail. as follows. (DPP-based pigment) The type of the diketopyrrolopyrrole pigment used in the salt milling is as described above in 200948906. In order to obtain a preferred particle diameter as described above after salt milling, the particle diameter of the diketopyrrolopyrrole pigment before salt milling is preferably from average to secondary particle diameter of from 20 nm to 300 nm, more preferably 25 nm to 200 nm, and most preferably 3 〇 nm to 150 nm. In the present invention, the DPP pigment used in the salt milling can be synthesized by a known method or a commercially available product. Specific trade names include: IRGAPHOR RED BT-CF' IRGAPHOR RED B-CF' IRGAZIN RED 2030 ' IRGAZIN DPP RED 80, IRGAZIN DPP RED BTR, IRGAZIN DPP RED BL, CROMOPHTAL RED 2030, CROMOPHTAL DPP RED BP, etc. Ciba Specialty Chemicals Co., Ltd. (manufactured by Ciba Specialty Chemicals Co., Ltd.). In the present invention, although the DPP-based pigment is preferably subjected to salt milling alone, the DPP-based pigment may be salt-milled in combination with other organic pigments. Organic pigments which can be used in combination with DPP pigments include, for example, those listed below. That is, CI Pigment Red 1, 2, 3, 4, 5, 6, 7, 9, 10, 14, 17, 22, 23, 31' 38, 41, 48:1, 48:2, 48:3, 48:4, 49, 49:1, 49:2, 52:1, 52:2, 53:1, 57:1, 60:1, 63:1, 66, 67, 81:1, 81:2 81:3, 83, 88, 90, 105, 112, 119, 122, 123, 144, 146, 149, 150, 155, 166, 168' 169, 170 &gt; 171, 172, 175, 176, 177, 178 '179 &gt; 184, 185, 187, 188, 190, 200, 202 '206, 207, 208, 209, 210, 216, 220, 224 &gt; 226, 242 '246, 270 '272, 279; CI Pigment Yellow 1, 2, 3, 4, 5, 6, 10, 11, 12, 13, 14, 15, 16, 17, 18, 20, 24, 31, 32, 34, 35, 35:1, 36, 36: 1 200948906, 37, 37:1, 40, 42, 43, 53, 55, 60, 61, 62, 63, 65, 73, 74 '77, 81, 83, 86, 93, 94, 95 '97, 98 , 100, 101, 104, 106, 108, 109, 110, 113, 114, 115, 116, 117, 118, 119, 120 '123, 125, 126, 127, 128, 129 137, 138, 139, 147, 148, 150, 151, 152, 153, 154, 155, 156, 161, 162, 164, 166, 167, 168, 169, 170, 171, 172, 173, 174, 175, 176, 177, 179, 180, 181, 182, 185, 187, 188, 193, 194, 199, 213, 214; ❹ CI Pigment Orange 2, 5, 13, 16, 17: 1, 31, 34, 36, 38, 43, 46, 48, 49, 51, 52' 55, 59, 60' 61, 62, 64; CI Pigment Green 7, 10, 36, 37; CI Pigment Blue 1, 2, 15, 15:1 15:2, 15:3, 15:4, 15:6, 16, 22, 60, 64, 66, 79, change the Cl substituent of CI Pigment Blue 79 to OH (hydroxyl), CI Pigment Blue 80; CI Pigment Violet 1, 19, 23, 27, 32, 37, 42; CI Pigment Brown 25, 28; © CI Pigment Black 1, 7, etc. Further, in the present invention, the organic pigment which can be used in combination with the DPP pigment is preferably a pigment as described below. That is, C_I. Pigment Yellow 11, 24, 108, 109, 110, 138, 139, 150 ' 151, 154, 167, 180, 185; CI Pigment Orange 36; CI Pigment Red 122, 150, 171, 175, 177 209, 224, 242 In the present invention, when DPP-based pigments are used in combination with other organic-13-200948906 pigments as needed, the ratio of DPP-based pigments can be arbitrarily changed according to the desired hue. However, it is usually 0.1% by mass or more and less than 100% by mass based on the total of the organic pigment. (Water-soluble inorganic salt) The water-soluble inorganic salt used in the salt milling is not particularly limited as long as it is soluble in water, and sodium chloride, barium chloride, potassium chloride, sodium sulfate, etc. may be used. However, from the viewpoint of price, it is preferred to use sodium chloride or sodium sulfate. The particle size of the water-soluble inorganic salt is such that a smaller particle size is obtained, but since the small-sized inorganic salt is high in price, it is preferably 0.1/zm to 100/zm, more preferably 1 /im to 50/zm. From the viewpoints of both the treatment efficiency and the production efficiency, the amount of the water-soluble inorganic salt used in the salt milling step is preferably from 1 to 30 times by mass of all the organic pigments including the DPP-based pigment, particularly preferably 5 to 25 times the mass. The larger the ratio of the inorganic salts relative to the organic pigment, the higher the refining efficiency, but since the amount of the primary pigment treatment is relatively reduced, it is preferably set in the above range. © (Water-soluble organic solvent) A water-soluble organic solvent is used to provide a function of wetting an organic pigment or an inorganic salt as long as it is a water-soluble inorganic salt which is soluble in water (mixed) and is substantially insoluble. There are no special restrictions on the person. However, since the temperature rises during the salt milling, the solvent is easily evaporated, and from the viewpoint of safety, a boiling point solvent having a boiling point of 120 ° C or higher is preferably used. The water-soluble organic solvent includes, for example, 2-methoxyethanol, 2-butoxy-14-200948906 ethanol, 2-(isopentyloxy)ethanol, 2-(hexyloxy)ethanol, ethylene glycol, Diethylene glycol, diethylene glycol monoethyl ether, diethylene glycol monoethyl ether acetate, diethylene glycol monobutyl ether, triethylene glycol, triethylene glycol monomethyl ether, liquid polyethylene glycol, 1-methoxy-2-propanol, 1-ethoxy-2-propanol, dipropylene glycol, dipropylene glycol monomethyl ether, dipropylene glycol monoethyl ether, liquid polypropylene glycol, and the like. Further, the water-soluble organic solvent may be used singly or in combination of two or more. The amount of the water-soluble organic solvent added is preferably from 5% by mass to 80% by mass based on the water-soluble inorganic salt as described above, more preferably from 1% by mass to 60% by mass based on the water-soluble β-free salt. % is preferably from 15% by mass to 50% by mass based on the water-soluble inorganic salt. When the addition amount is in the range as described above, kneading of the uniform sentence can be achieved, the particle diameter is likely to be uniform, and since the softness of the kneaded composition is maintained in an appropriate range in the treatment, it is easy to impart a moderate degree at the time of kneading. Shear force, so I can get the refinement effect I want. The addition timing of the water-soluble organic solvent in the salt milling step may be added at the beginning of the step, or may be added separately. (Resin) In the production of the micronized diketopyrrolopyrrole pigment in the present invention, in order to prevent the finely divided diketopyrrolopyrrole pigment from being strongly aggregated during drying, it can be easily dispersed. Preferably, after kneading the pigment with a water-soluble inorganic salt or the like, and removing the water-soluble inorganic salt and the water-soluble organic solvent, the diketopyrrolopyrrole-based pigment is brought into contact with the resin before being supplied to the drying step. Here, the contact of the DPP pigment with the resin means that the resin is adhered to at least a part of the surface of the DPP pigment. The treatment of contacting the DPP pigment with the resin can be carried out in the steps of -15-200948906 before drying, for example, at the beginning or on the way of the salt milling step (kneading), after the salt milling step, after the salt milling. In the step, after the water washing step, a solid resin or a resin solution is added to carry out. The resin to be used in contact with the DPP pigment is preferably a polymer compound having an acid value of from 5 Å to 300 KOH/g. When the DPP pigment is brought into contact with a polymer compound having an acid value of 50 to 300 mgKOH/g, a soft powder pigment can be obtained to obtain a fine DPP pigment having high dispersibility and dispersion stability. The polymer compound having an acid value of 50 to 300 mgKOH/g used in the present invention is preferably water-insoluble, and a natural resin, a modified natural resin, a synthetic resin, a synthetic resin modified with a natural resin can be used. Wait. The natural resin is exemplified by rosin; the modified natural resin can be a rosin derivative, a cellulose derivative, a rubber derivative, a protein derivative, and the like. Further, the synthetic resin includes an epoxy resin, an acrylic resin, a maleic acid resin, a butyral resin, a polyester resin, a melamine resin, a phenol resin, a polyurethane resin, a polyamide resin, and the like. . The acid group present in the molecule of the polymer compound having an acid value of 50 to 300 mgKOH/g is not particularly limited, but examples thereof include a sulfonic acid group, a phosphoric acid group, a carboxylic acid group, a phenol group, and a sulfonamide group. Etc., a particularly preferred acid group carboxylic acid group. The acid value is preferably from 50 to 300 mgKOH/g, more preferably from 50 to 250 mgKOH/g, most preferably from 70 to 250 mgKOH/g. When the acid value is adjusted to be in this range, it is possible to achieve superior bismuth solubility in the fine DPP-based pigment, aggregation prevention effect during drying, storage stability, and dispersibility. 200948906 The molecular weight of the polymer compound having an acid value of 50 to 300 mgKOH/g is preferably a weight average molecular weight! 〇〇〇 or more, 50,000 or less, more preferably 3,000 or more, 30,000 or less, and most preferably 4 or more, 25,000 or less. When the molecular weight is adjusted within this range, excellent alkali solubility in the fine DPP pigment, aggregation prevention effect during drying, and dispersibility can be achieved. (Polymer compound containing a pigment absorbing group) Further, a polymer compound having an acid value of 50 to 300 mgKOH/g is preferably a polymer compound having a pigment absorbing group. Specifically, the polymer compound having a pigment absorbing group preferably contains a monomer derived from a monomer represented by the following formula (1), maleimide, and cis. A polymer of a polymerized unit of a monomer of a group consisting of enediamine derivatives (hereinafter, referred to as "Specific Polymer"). Among them, a specific polymer is particularly preferably a polymer comprising a polymerized unit derived from a monomer represented by the following formula (1) &quot; ❹ 1 R1 H2C=C Formula (1)

Y-R^-Z In the above formula (1), R1 represents a hydrogen atom or an alkyl group. R2 represents a single bond or a divalent linking group. The Y series represents -CO-, -c(=0)〇, _CONH _, _〇C(=〇)-, or phenyl. The z series represents a group having a nitrogen-containing heterocyclic group. -17- 200948906 The alkyl group represented by R1 is preferably an alkyl group having 1 to 12 carbon atoms, more preferably an alkyl group having 1 to 8 carbon atoms, particularly preferably an alkyl group having 1 to 4 carbon atoms. . When the alkyl group represented by R1 has a substituent, the substituent includes, for example, a hydroxyl group or an alkoxy group such as a methoxy group, an ethoxy group or a cyclohexyloxy group. The alkoxy group is preferably a carbon number of from 1 to 5, more preferably a carbon number of from 1 to 3. Specifically, preferred alkyl groups represented by R1 include, for example, methyl, ethyl, propyl, n-butyl, isobutyl, tert-butyl, n-hexyl, cyclohexyl. , 2-hydroxyethyl, 3-hydroxypropyl, 2-hydroxypropyl, 2-methoxyethyl. Among them, R1 is most preferably a hydrogen atom or a methyl group. In the formula (1), the divalent linking group represented by R2 is preferably an alkyl group or a divalent group having an alkylene group. The alkylene group is preferably an alkylene group having 1 to 12 carbon atoms, more preferably an alkylene group having 1 to 8 carbon atoms, still more preferably an alkylene group having 1 to 4 carbon atoms. Further, when the alkylene group has a substituent, the substituent includes, for example, a hydroxyl group or the like. ◎ In particular, preferred alkylene groups represented by R2 include, for example, methylene, ethyl, propyl, trimethylene, tetramethylene. The divalent group containing an alkylene group represented by R2 may be one or more which are bonded to each other by a hetero atom (e.g., an oxygen atom, a nitrogen atom or a sulfur atom). Further, the divalent radical containing an alkylene group represented by R2 may also be a terminal bonded to Z in the exudate group, and the bond is selected from _〇-, an S-

, a C ( = 〇 ) 〇 —, a CONH-, a C (= 0) S-, a NHCONH -18- 200948906 —, an NHC (=0) Ο-, an NHC (=0) S-, - 〇c(=〇) —, an OCONH —, and an NHCO-hetero atom or a partial structure containing a hetero atom. Specifically, the nitrogen-containing heterocyclic structure for constituting the nitrogen-containing heterocyclic group represented by z in the general formula (1) includes, for example, a pyridine ring, a pyridine ring, a pyrimidine ring, a pyrrole ring, Imidazole ring, triazole ring, tetrazole ring, anthracene ring, quinoline ring, acridine ring, morpholidine ring, morphine ring, acridone ring, anthracene ring, benzimidazole structure, benzotriazole An azole structure, a benzothiazepine structure, a cyclic guanamine structure, a guanidine cyclic urea structure, and a cyclic quinone imine structure. These nitrogen-containing heterocyclic structures may have a substituent, and the substituents include, for example, an alkyl group, an alkoxy group, a halogen atom, an aliphatic ester group, an aromatic ester group, an alkoxycarbonyl group and the like. In particular, the nitrogen-containing heterocyclic group represented by Z is more preferably a group having a nitrogen-containing heterocyclic ring structure having a carbon number of 6 or more, and particularly preferably having a nitrogen-containing heterocyclic ring structure having a carbon number of 6 or more and 12 or less. The basis. Specifically, the nitrogen-containing heterocyclic structure having a carbon number of 6 or more includes: preferably: a morpholidine ring, a morphine ring, an acridone ring, an anthracene ring, a benzimidazole structure, a benzotriazole a structure, a benzothiazole structure, a cyclic guanamine structure, a cyclic urea structure, and a cyclic quinone imine structure; and particularly preferably a structure represented by the following general formula (2), (3), or (4) ^ -19- 200948906

Formula (2) Formula (3) Formula (4) In the formula (2), X is selected from a single bond, an alkyl group (for example, methylene, ethyl, propyl, trimethylene) Any of a group consisting of a base, a tetramethylene group, etc., a 0_, a _S-, an nra-, and a c(=o). Here, the ra system represents a hydrogen atom or an alkyl group. When ra is an alkyl group, the alkyl group is preferably an alkyl group having 1 to 18 carbon atoms, more preferably an alkyl group having 1 to 6 carbon atoms, and examples thereof include, for example, a methyl group, Ethyl, n-propyl, iso-propyl, n-butyl, tert-butyl, n-hexyl, n-octyl, 2-ethylhexyl, n-octadecyl and the like. Among the above, the X system in the formula (2) is preferably a single bond, a methylene group, a 0-, or a C(=0)-, and particularly preferably a C (=0). In the general formula (4), the Y and Z systems each independently represent an N=, —NH _, _N(RB) —, —S—, or _〇—. When RB represents an alkyl group, the alkyl group is preferably an alkyl group having a carbon number of 1 to 18, more preferably an alkyl group having a carbon number of 1 to 6, and the actual system includes, for example, a methyl group, Ethyl, n-propyl, iso-propyl, n-butyl, tert-butyl, n-hexyl, n-octyl, 2-ethylhexyl, n-octadecyl and the like. Among the above, the Y and Z systems in the general formula (4) are particularly preferably -N=, one NH-, and _N(RB)-. Examples of the combination of Y and Z include 200948906 ··Y and Z are either -N=, and the other is a combination of NH- (imidazolyl group). In the general formula (2), (3), or (4), the ring a, the ring b, the ring C, and the ring D each independently represent an aromatic ring. Examples of the "aromatic ring" include, for example, a benzene ring, a naphthalene ring, an anthracene ring, an argon ring, an anthracene ring, an anthracene ring, a pyridine ring, a pyridine ring, a pyrimidine ring, a pyrrole ring, an imidazole ring, an anthracene ring, a quinoline ring, a V pyridine ring, a morpholidine ring, a morphine ring, an acridone ring, an anthracene ring, etc.; among them, a benzene ring, a naphthalene ring, an anthracene ring, a pyridine ring, a morphine ring, Acridine ring, phenothiazine ring, morphine ring, acridone ring, anthracene ring, and particularly preferred are benzene ring, naphthalene ring, pyridyl ring. Specifically, examples of the cyclic oxime and the cyclic oxime in the general formula (2) include, for example, a benzene ring, a naphthalene ring, a pyridine ring, a pyridin ring and the like. Examples of the ring C in the formula (3) include, for example, a benzene ring, a naphthalene ring, a pyridine ring, a pyridin ring and the like. Examples of the ring D in the formula (4) include, for example, a benzene ring, a naphthalene ring, a pyridine ring, a pyridinium ring and the like. In the structure represented by the general formula (2), (3), or (4), considering the dispersibility and the stability of the dispersion over time, the ring A, the ring B, the ring C, and The ring D is more preferably a benzene ring or a naphthalene ring, and more preferably a benzene ring in the formula (2) or (4), and further preferably a naphthalene ring in the formula (3). The so-called maleimide derivative in the present invention means a maleimide substituted with a substituent such as an alkyl group or an aryl group at the N position. Hereinafter, a preferred specific example of the monomer represented by the general formula (1), maleimide, and maleimide derivative (monomer-21-200948906 Μ- l to M-3 0), but the invention is not limited thereto.

-22- 200948906

Η b〇C^H Μ-16

X°r Μ-17

Co^^o ο〇2^γ^ο

OH C〇2 coC^^o

M-20 Μ-19

H O -23- 200948906 Η

Μ-22

^CONH^- Ο

Μ-25

Η3

Μ-28 Μ-29

Μ-30

The specific polymer in the present invention may contain only one kind or two or more kinds derived from a monomer selected from the group consisting of the formula (1), maleimide, and maleimide. a polymerized unit of one of the groups of derivatives. Among the monomers represented by the formula (1), maleimide, and maleimide derivatives, especially due to the mono-24- represented by the formula (1) 200948906 The body is highly absorbing, so it is preferred. In the specific polymer of the present invention, it is derived from a single group selected from the group consisting of a monomer represented by the general formula (1), a maleimide, and a maleimide derivative. The content of the polymerization unit of the bulk is preferably 5% by mass or more, and more preferably 10 to 50% by mass, based on 100% by mass of all the structural units contained in the polymer. That is, in order to effectively suppress the formation of the secondary aggregate of the primary aggregate of the pigment or to effectively attenuate the cohesive force of the secondary aggregate, the derivative is freely derived from the monomer represented by the general formula (1), The content of the polymerization unit of one of the groups of the maleimide and the maleimide derivative is preferably 5% by mass or more. In addition, from the viewpoint of developability when a color filter is produced from a photopolymerizable composition containing a pigment dispersion composition, it is derived from a monomer selected from the formula (1), maleic acid The content of the polymerization unit of one of the groups consisting of the imine and the maleimide derivative is preferably 50% by mass or less. The specific polymer in the present invention is preferably a polymerized unit derived from a monomer having an acid group. Since the specific polymer contains a polymer unit derived from a monomer having an acid group, when the pigment dispersion composition is applied to a photopolymerizable composition, it has excellent development removability of the unexposed portion. The single system having an acid group includes: unsaturated monocarboxylic acids such as acrylic acid, methacrylic acid, crotonic acid, α-chloroacrylic acid, cinnamic acid, etc.; maleic acid, maleic anhydride, fumaric acid , an unsaturated dicarboxylic acid such as itaconic acid, itaconic anhydride, citraconic acid, citraconic anhydride, mesaconic acid or the like; an unsaturated polycarboxylic acid having three or more or an anhydride thereof; Acid mono(2-propenyloxyethyl) ester, mono(2-methylpropenyloxyethyl) succinate, o-benzene-25- 200948906 dicarboxylic acid mono(2-propenyloxyethyl) One of a dibasic or higher polycarboxylic acid such as an ester or a mono(2-methylpropenyloxyethyl) phthalate [(meth) propylene decyloxyalkyl] ester; ω-carboxy- One of the two terminal carboxyl groups (meth) acrylate such as polycaprolactone monoacrylate or ω-carboxy-polycaprolactone monomethacrylate. The specific polymer in the present invention may contain only one kind or two or more kinds of polymerized units derived from a monomer having an acid group. In the specific polymer, the content of the polymerized unit derived from the monomer having an acid group is preferably such that the acid value of the specific polymer is 50 mgKOH/g or more, and particularly preferably 50 to 300 mgKOH/g. the amount. That is, from the viewpoint of suppressing the formation of precipitates in the developer, the content of the polymerized unit derived from the monomer having an acid group is preferably such that the acid value of the specific polymer is 50 mgKOH/g. The above amount. In order to effectively suppress the formation of the secondary aggregate of the primary aggregate of the pigment or to effectively weaken the cohesive force of the secondary aggregate, the content of the polymerized unit derived from the monomer having an acid group is preferably The acid value of the specific polymer is made in an amount of 50 to 300 mgKOH/g. Further, if the specific polymer in the present invention has an acid value of 50 to 300 〇 mgKOH/g, the specific polymer can be used as the acid value as described above at a high temperature of 50 to 300 mgKOH/g. Molecular compound. Further, the specific polymer in the present invention may further contain a polymerized unit derived from a vinyl monomer within a range which does not impair the efficacy thereof. Here, the vinyl single system which can be used is not particularly limited, but is preferably, for example, (meth) acrylates, crotonates, vinyl esters, maleic acid diesters. , fumaric acid diesters, itaconic acid diesters, (meth) acrylamides, vinyl ethers, vinyl alcohol esters, benzene-26- 200948906 ethylene, (methyl) Acrylonitrile and the like. Specific examples of such vinyl monomers are, for example, compounds including those described below. Further, in the present specification, when either or both of "acrylic acid and methacrylic acid" are used, it is sometimes referred to as "(meth)acrylic acid". Examples of (meth) acrylates include: methyl (meth) acrylate, ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, (methyl) ) n-butyl acrylate, isobutyl (meth)acrylate, tert-butyl (meth)acrylate, n-hexyl (meth)acrylate, cyclohexyl (meth)acrylate, (methyl) Tri-butylcyclohexyl acrylate, 2-ethylhexyl (meth)acrylate, tertiary-octyl (meth)acrylate, dodecyl (meth)acrylate, (meth)acrylic acid Octacol ester, ethoxylated ethyl (meth) acrylate, phenyl (meth) acrylate, 2-hydroxyethyl (meth) acrylate, 2-methoxyethyl (meth) acrylate, (A) 2-ethoxyethyl acrylate, 2-(2.methoxyethoxy)ethyl (meth)acrylate, 3-phenoxy-2-hydroxypropyl (meth)acrylate, (A) Base) benzyl acrylate, diethylene glycol monomethyl ether (meth)acrylate, (methyl®) diethylene glycol monoethyl ether acetate, (meth)acrylic acid Glycol monomethyl ether ester, triethylene glycol monoethyl ether (meth)acrylate, polyethylene glycol monomethyl (meth)acrylate, poly(methyl) methacrylate monoethyl ether Ester, phenoxyethoxyethyl (meth)acrylate, nonylphenoxyethylene glycol (meth)acrylate, dicyclopentenyl (meth)acrylate, bicyclo(meth)acrylate Pentenyloxyethyl ester, trifluoroethyl (meth)acrylate, octafluoropentyl (meth)acrylate, perfluorooctylethyl (meth)acrylate, dicyclopentanyl (meth)acrylate, Tribromophenyl (meth)acrylate, tribromophenoxyethyl (meth)acrylate, and the like. -27- 200948906 Examples of crotonates include: butyl crotonate, and hexyl crotonate. Examples of the vinyl esters include vinyl acetate, vinyl propionate, vinyl butyrate, methoxyvinyl acetate, and vinyl benzoate. Examples of the maleic acid diesters include: dimethyl maleate, diethyl maleate, and dibutyl maleate. Examples of the fumaric acid diesters include: dimethyl fumarate, diethyl fumarate, and dibutyl fumarate. Examples of the ikonic acid diesters include: dimethyl ikonate, diethyl orthoacetate, and dibutyl itaconate. (Meth) acrylamides include: (meth) acrylamide, N-methyl (meth) acrylamide, N-ethyl (meth) acrylamide, N-propyl (methyl ) acrylamide, N-isopropyl (meth) acrylamide, N-n-butyl (meth) acrylamide, N-tertiary-butyl (meth) acrylamide, N-ring Hexyl (meth) acrylamide, N-(2-methoxyethyl)(meth) acrylamide, N,N-dimethyl(meth) decylamine, N,N-diethyl (Meth) acrylamide, N-phenyl (meth) acrylamide, N-benzyl (meth) acrylamide, (meth) propylene hydrazino, diacetone acrylamide, etc. . Examples of the vinyl ethers include methyl vinyl ether, butyl vinyl ether, hexyl vinyl ether, and methoxyethyl vinyl ether and the like. Examples of styrenes include: styrene, methyl styrene, dimethyl styrene, trimethyl styrene, ethyl styrene, isopropyl styrene, butyl styrene, hydroxystyrene, methoxy Styrene, butoxy styrene, ethoxylated styrene, chlorostyrene, dichlorostyrene, bromostyrene, chloromethylstyrene, bases deprotected by acidic materials (eg, tertiary - Butoxy-28-200948906 hydroxy styrene (t-Boc: t-butoxycarbonyl), etc., protected by hydroxystyrene, vinyl benzoic acid methyl vinegar, and α-methyl phenyl benzene. The preferred molecular weight of the specific polymer in the present invention is preferably such that the weight average molecular weight (Mw) is in the range of 1, 〇〇〇 to 50,000, and the number average molecular weight (?η) is in the range of 400 to 30,000. Preferably, the weight average molecular weight (Mw) is in the range of 3,000 to 30,000, and the number average molecular weight (?η) is in the range of 1, 〇〇〇 to 20,000. In particular, it is preferred that the weight average molecular weight (M w ) is in the range of 4,000 to 20,000 Å, and the number average molecular weight (?η) is in the range of 1,500 to 1 5,000, that is, from the primary particle agglomeration which effectively suppresses the pigment. From the viewpoint of the formation of the secondary aggregate of the body or the viewpoint of effectively reducing the cohesive force of the secondary aggregate, the weight average molecular weight (Mw) of the specific polymer is preferably 〇〇〇 or more. Further, from the viewpoint of developability when a color filter is produced from a photopolymerizable composition containing a processed pigment, the weight average molecular weight (Mw) of the specific polymer is preferably 50,000 or less. The specific polymer is produced, for example, by using a monomer represented by the formula (1) and another radical polymerizable compound as a copolymerization component, and by a general radical polymerization method. In general, a suspension polymerization method, a solution polymerization method, or the like is used. The "solvent" used in the synthesis of such specific polymers includes, for example, ethylene dichloride, cyclohexanone, methyl ethyl ketone, acetone, methanol, ethanol, propanol, butanol, ethylene glycol. Monomethyl ether, ethylene glycol monoethyl ether, 2-methoxyethyl acetate, 1-methoxy-2-propanol, 1-methoxy-2-propyl acetate, N, N-di Methylformamide, N,N-dimethylacetamide, dimethyl sulfoxide, toluene, vinegar -29- 200948906 ethyl acetate, methyl lactate, ethyl lactate, and the like. These solvents may be used singly or in combination of two or more. Further, in the case of radical polymerization, a radical polymerization initiator may be used, and a chain transfer agent (e.g., 2-hydrothioethanol and dodecylmercaptan) may be further used. In the production step of the fine DPP pigment, the total amount of the resin used in contact with the DPP pigment in the step before drying is preferably from 1% by mass to 80% based on the total amount of the organic pigment containing the DPP pigment. quality%. The amount of addition is more preferably from 5% by mass to 60% by mass based on the total amount of the organic pigment containing the DPP pigment, and most preferably from 7 mass% to 35 mass% based on the total amount of the organic pigment containing the DPP pigment. %. When the amount added is in the range of 1% by mass to 80% by mass, a sufficient color filter for preventing agglomeration can be obtained while drying, and a color filter of a preferred hue can be obtained (pigment derivative). In the invention, in order to promote the miniaturization of the diketopyrrolopyrrole pigment, a pigment derivative can be added during salt milling. Preferred skeletons of the pigment derivative include: quinophthalone pigment, anthraquinone pigment, azo pigment, sulphonone pigment, isoporphyrin pigment, isoindolinone pigment a skeleton such as a diketopyrrolopyrrole pigment or a benzimidazolone pigment. Further, a pale yellow aromatic polycyclic compound such as a naphthalene type, an anthraquinone type, a triazotized system or a sirolimus type is also included in a preferred skeleton. Among these skeletons, from the viewpoint of hue and miniaturization to promote efficacy, it is particularly preferred to be an anthrone-based pigment, a diketopyrrolopyrrole-based pigment, and an azo-based pigment 200948906. Examples of the derivative include: Japanese Patent Application Laid-Open No. Hei No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Laid-Open Patent Publication No. 2006-265528, Japanese Patent Application Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Laid-Open Publication No. 2003-240938, Japanese Patent Laid-Open No. Hei. No. 2 001-356210, Japanese Patent Laid-Open Publication No. 2001-22〇520, and Japanese Patent Laid-Open No. 2007-186681 The person disclosed in the bulletin and the like. In the case of adding a pigment derivative at the time of salt milling, the pigment derivative is preferably used in a ratio of from 〇 to 20 parts by mass, more preferably in a ratio of 100 parts by mass of the DPP pigment. It is used in the range of 0.5 to 10 parts by mass. When the content is in the range of 0.1 to 20 parts by mass based on 100 parts by mass of the DPP pigment, superior micro-refinement efficiency can be obtained. In the present invention, in the case where a pigment derivative is added during salt milling, the DPP pigment and the pigment derivative are usually mixed as a powder before kneading, but a pigment derivative may be added in the middle of kneading. Further, the pigment derivative may be added in one portion at a time or divided into several times to be added. In the present invention, in the case where a pigment derivative is added at the time of salt milling, examples of the compound which can be used are shown below.

-31- 200948906

-32- 200948906 Ο

Ο

Gh2n&quot;:Χ&gt;ΝΗ· ο

,Ν. OH so3h -ΝΗ

(h)

I-^^-so3·S03-Ca2 (salt grinding step and subsequent steps) The salt milling step in the present invention is a diketopyrrolopyrrole pigment, a water-soluble inorganic salt, and substantially insoluble in the water. The water-soluble organic solvent of the inorganic salt, and a further resin (preferably a polymer compound having an acid value of 50 to 300 mgKOH/g) is mechanically kneaded. This step can be carried out by any means such as a kneader or a planetary mixer, a continuous micronizing device, etc., but the temperature at the time of micronization is preferably from 10 ° C to 150 ° C, more preferably. It is from 20 ° C to 120 ° C, and most preferably from 30 ° C to 90 ° C. If the atomization is carried out at a temperature higher than 150 °C, the growth rate of the particles may exceed the rate of microparticulation, so that the micronization is not easy to carry out. In addition, when the atomization is carried out at a temperature of 1 〇 ° C or less, the control of the particle size may be difficult due to the heat generation during the atomization, and the production may be unstable, which is not preferable. The salt milling treatment can be carried out at any time to obtain the desired particle diameter, but it is usually from 2 hours to 24 hours. From the viewpoint of productivity and productivity, it is preferably from 2 hours to 15 hours. The water-soluble inorganic salt in the kneaded mass and the water-soluble organic solvent are removed after the salt milling step as described above, whereby a finely processed pigment can be obtained. First, after the salt milling step, the desalting treatment is usually applied to the obtained kneaded material. The desalination treatment can be carried out by using any conventional means 'but usually by feeding the kneaded material and hot water into the dispersion tank' by a high-speed mixer or the like. The dispersed pigment is usually filtered and washed. Filtration and washing can be carried out using any conventional means. However, a filter press is usually used, and in the present invention, a filter press is preferably used. The desalted and filtered pigments are usually dried and dried. Generally, a general oven is used, but a spray drying method or a vacuum drying method may also be used. In particular, the spray drying method is well known for obtaining a pigment powder which is weakly dry and agglomerated and which is easily dispersed. The temperature at which the oven is dried in an oven is usually from 30 ° C to 150 ° C, preferably from 30 ° C to 120 ° C, most preferably from 40 ° C to 90 ° C. If it is dried at a temperature higher than 150 °C, it may cause intense dry agglomeration, which makes the dispersion difficult. Further, drying at a temperature lower than 30 ° C is not preferable from the viewpoint of productivity because it takes a long time. The amount of moisture in the dried treated pigment is usually from 0.01% by mass to 10% by mass, preferably from 0.05% by mass to 5% by mass, most preferably from 0.05% by mass to 3% by mass. -34- 200948906 The pigment dispersion composition of the present invention contains a DPP pigment, but it is preferably composed of at least one type of finely divided DPP pigment as described above. The pigment dispersion composition of the present invention can also be used in combination with other pigments or dyes as needed. Specific examples of the combination are as follows. For example, the red pigment may be at least one of a diketopyrrolopyrrole pigment (containing a micronized DPP pigment as described above), a disazo yellow pigment, an isoporphyrin yellow pigment, and a quinophthalone. A mixture of yellow pigments or lanthanide red pigments. Further, in order to obtain a preferable hue, a diketopyrrolopyrrole pigment may be used in combination with an anthraquinone pigment. Preferred pigments for the diketopyrrolopyrrole pigments include CI Pigment Red 254, CI Pigment Red 255, C_I·Pigment Red 264, etc., but from the viewpoint of hue and spectral characteristics, it is preferably CI Pigment. Red 254. Preferred examples of the fluorene-based pigment include CI Pigment Red 89, CI Pigment Red 177, etc., but from the viewpoint of hue and spectral characteristics, CI Pigment Red 177» "蒽醌-based pigment" is preferably used. The content of the diketopyrrolopyrrole pigment is preferably from 0 to 20 parts by mass, preferably from 0 to 120 parts by mass, based on 100 parts by mass of the diketopyrrolopyrrole pigment. Further, from the viewpoints of hue, spectroscopic characteristics, and contrast, in CI Pigment red 254 and CI Pigment Red 177, and a yellow pigment such as CI Pigment Yellow 150 or CI Pigment Yellow 139, CI Pigment Yellow 138 or the like are also preferred. Among them, from the point of comparison, it is particularly preferable to use C.I. Pigment Red 254 and C.I_Pigment Red 177 倂 with C.I. Pigment Yellow 150. The pigment system which can be used in combination with the pigment dispersion composition of the present invention is not particularly limited, and a conventionally known one of the diketopyrrolopyrrole pigments as described above may be used, but A preferred combination is as described above. From the viewpoint of -35- 200948906 '*, it is preferable that the pigment which can be used is finely refined to the same extent as the fine DPP pigment. There is no particular limitation on the dye system which can be used in the pigment dispersion composition of the present invention. A conventional dye which has been conventionally used as a color filter can be used. Japanese Patent Publication No. 64-90403, Japanese Patent Application Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. -11614, Japanese Patent Application No. 2,592,207, U.S. Patent No. 4,808,501, U.S. Patent No. 5,667,920, U.S. Patent No. 5,059,500, Japanese Patent Application Laid-Open No. 5_3 3 Japanese Patent Publication No. Hei 6-35183, Japanese Patent Application Laid-Open No. Hei 6-5 1115, Japanese Patent Application Laid-Open No. Hei 6- 1948828, Japanese Patent Application No. Hei No. Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Publication No. 7-286107, Japanese Patent Laid-Open No. 2001-48823, Japanese Patent Publication No. 8-15522, Japanese Patent Publication No. 8-15522 Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Laid-Open No. Hei. No. 2-1 422 No. 1, Japanese Patent Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. Japanese Laid-Open Patent Publication No. 8-302224, Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Pigment. The chemical structure may be a pyrazole azo system, an anilino azo system, a triphenyl phenyl system, a brewing system, a sulphur ratio sketone system, a benzylidene system, an oxycyanine (Oxonol) system, or a pyridyl group. Oxazole triazole azo, pyridone azo, sianning, thiophene, pyrrolopyrazole methine azo, mil oxime, phthalocyanine, benzopyran, indigo A dye such as a dye. In the pigment dispersion composition of the present invention, the dpp pigment may be used alone or in combination of two or more. ® In the pigment dispersion composition, the total content of the pigment including the DPP pigment and other pigments to be used is compared with the pigment ratio of the total solid content (mass) of the pigment dispersion composition. Preferably, it is 40 to 90% by mass 'more preferably 50 to 80% by mass. When the content of the pigment is within this range, it is effective in ensuring sufficient color density and superior color characteristics. In addition, the DPP-based pigment is preferably contained in an amount of 50% by mass or more, and more preferably 7% by mass or more, based on all the pigments in the pigment dispersion composition of the present invention. All of the pigments may be one or more types of DPP

[(B) o-xylylenediamine alkylated diketopyrrolopyrrole and (C) phthalic acid imidoalkylated quinophthalone] The pigment dispersion composition of the present invention comprises: relative 100 parts by mass of the (A) diketopyrrolopyrrole pigment as described above in an amount of 0.1 to 30 parts by mass of (B) phthalic acid imidoalkylated diketopyrrolopyrrole, and relative to 100 parts by mass The mass fraction is as described above (A) the diketopyrrolopyrrole pigment is 1.1 to 20 parts by mass of (C) phthalic acid imidoalkylated quinone. (B) phthalic acid imidoalkylated diketopyrrolopyrrole is at least one-37-200948906 phthalic acid imidoalkyl group bonded to diketopyrrolopyrrole Pyrrolopyrrole. Further, the orthophthalic imidomethyl group which is representative as the phthalimidoalkylene group has the structure shown below. 〇

〇

The phthalic acid iminomethylated diketopyrrolopyrrole is a diketopyrrolopyrrole pigment derivative having the structure represented by the following formula (B).

General formula (B) 〇 In the general formula (B) as shown above, X and Y each independently represent a hydrogen atom 'alkyl group, cyano group, aryl group or halogen group. The η system represents the substitution number of the phthalic acid iminomethyl group and represents an integer of 1 to 3. The X and oxime systems in the above formula (Β) are synonymous with X and Υ in the formula (Α) as shown before, and the preferred mode is also the same. (Β) o-xylylenediamine-alkylated diketopyrrolopyrrole according to a known method, for example, a diketopyrrolopyrrole red pigment in sulfuric acid and polymethyl-38-200948906 aldehyde (paraform ), phthalimide or hydroxymethylphthalimide is reacted, etc., whereby it can be easily produced. This synthesis method has been described in detail in Japanese Laid-Open Patent Publication No. 62-149759, and the like. The diketopyrrolopyrrole red pigment which can be used for the synthesis includes, for example, CI Pigment Red 254, 255, 264, and CI Pigment Orange 71, 73, etc., from the viewpoint of ease of synthesis and hue, particularly It is preferred to use CI Pigment Red 255. (B) o-phthalimidoalkylamined diketopyrrolopyrrole can also be used as a phthalimide with a substitution number of 1 to 3 with phthalic acid imidomethyl group. A mixture of a methylated diketopyrrolopyrrole and a diketopyrrolopyrrole red pigment which is imidized without phthalic acid. The diketopyrrolopyrrole red pigment at this time includes, for example, CI Pigment Red 254, 25 5, 264, and, for example, CI Pigment Orange 71, 73, a diketopyrrolopyrrole pigment, etc. (C) phthalic acid The quinone imidoalkylated quinacridone is at least one phthalimidoalkylene group which is a quinacridone bonded by a hydrogen atom on the quinacridone ring. Further, the ortho-phenyl quinone iminoimidomethyl group which is a typical phthalimidoalkylene group has the structure shown below.

〇 o-phthalimidomethylated quinacridone is a quinophthalone pigment derivative having a structure represented by the following formula (C). -39- 200948906

In the general formula (C) as shown above, X and Y each independently represent a hydrogen atom, a methyl group or a chlorine atom. The η system represents the substitution number of the o-phthalimidomethyl group and represents an integer of 1 to 3. The (C) phthalic acid imidoalkylated quinophthalone group of the present invention which can be used for the structure represented by the above-mentioned structure includes, for example, phthalic acid imine methylation unsubstituted Quinone, phthalimidomethylated dimethyl fluorenone, phthalimidomethylated chloroquinone, and the like. The (C) phthalic acid imidoalkylated quinophthalone contained in the pigment dispersion composition of the present invention may be used alone or in a mixture of two or more. (C) phthalic acid imidoalkylated quinophthalones, for example, quinophthalone red pigment in sulfuric acid with paraformaldehyde, phthalimide or hydroxymethylortho The reaction of dimethyl sulfimine and the like can be easily produced. This method has been described in detail in Japanese Laid-Open Patent Publication No. 55-10 84 66 and the like, and can be referred to the document (C) o-phthalimidoalkylamine-based salidone. a phthalic acid imine methyl substituted phthalic acid with 1 to 3 phthalic acid imine methyl group substituted with phthalic acid, which is imidized with phthalic acid a mixture. The quinacridone red pigment at this time includes, for example, CI Pigment Violet 19-40-200948906 unsubstituted quinophthalone pigment, CI Pigment Red 122 dimethylquinoquinone uy嗣 pigment, (:_I. Pigment Red) 202, CI Pigment Red 209 bischloroquinacridone pigment, etc. The pigment dispersion composition of the present invention must contain: relative to 1 part by mass of the above (A) diketopyrrolopyrrole pigment is 〇.丨 to 3 parts by mass of (B) phthalic acid imidoalkylated diketopyrrolopyrrole, relative to 1 part by mass of (A) diketopyrrolopyrrole pigment is 〇.丨Up to 2 parts by mass of (C) phthalic acid imidoalkylated quinophthalone; however, (B) terephthalene imidoalkylated diketopyrrolopyrrole It is 0.1 parts by mass to 25 parts by mass, preferably 0.5 parts by mass to 20 parts by mass, based on 100 parts by mass of the diketopyrrolopyrrole pigment. Further, "(C) phthalic acid imidoalkyl group A particularly preferred content of the quinacridone is from 0.1 part by mass to 15 parts by mass per 100 parts by mass of the diketopyrrolopyrrole pigment, optimum It is 0.5 parts by mass to 15 parts by mass. The ratio of addition ratio of both is preferably within the range of the respective contents as described above, and (B) phthalic acid imidoalkylated diketopyrrolopyrrole The amount added is equivalent to or more than (C) o-phthalimidoalkylamine quinophthalone. By containing the range of phthalimidoalkylene dialkyl pyrroles And pyrrole and phthalic acid imidoalkylated quinacridone can obtain high pigment dispersibility, high contrast, and superior surface smoothness of color filters. In the present invention, (B) adjacent The xylylenediamine alkylated diketopyrrolopyrrole and the (C) phthalic acid imidoalkylated quinophthalone may be used singly or in combination of two or more of the present invention. Modulation of the composition, (B) o-phthalimidoalkylated diketopyrrolopyrrole and (C) phthalic acid imidoalkylated quinophthalone can be added at any time ( A) diketopyrrolopyrrole pigment, -41- 200948906, but it is preferred that at least a part is after the miniaturization of the diketopyrrolopyrrole (preferably In particular, for the addition of the kneaded material after the completion of the salt milling, the addition of the desalting dispersion, the addition of the pigment powder after the dry pulverization, and the pre-dispersion Adding a pigment dispersion composition, adding a pigment dispersion, etc. by alkylating at least a portion of the phthalic acid imino group to the diketopyrrolopyrrole and the phthalic acid imino group. When the ketopyrrolopyrrole is added after refining, high pigment dispersibility, high contrast, and excellent surface smoothness of the color filter can be obtained. 颜料 In order to improve dispersion stability and obtain high contrast, the pigment dispersion of the present invention The composition may be used in addition to (B) phthalic acid imidoalkylated diketopyrrolopyrrole and (C) phthalic acid imidoalkylated quinophthalone as described above. Pigment derivatives are also preferred. A preferred "pigment derivative" which can be used includes a portion having an affinity with a dispersant and which can be adsorbed on the surface of a DPP pigment. By using a pigment derivative having a absorbing point which can serve as a dispersing agent and absorbing the pigment derivative on the surface of the DPP pigment, the dispersing agent can be easily adsorbed on the surface of the DPP pigment, and the DPP pigment can be made fine. The particles are dispersed in the pigment dispersion composition, and in addition, re-aggregation can be prevented. Specifically, a preferred "pigment derivative" which can be used is a compound obtained by using an organic pigment as a matrix skeleton and introducing an acidic group or a basic group in the side chain and an aromatic group as a substituent. . Specifically, the "organic pigment of the matrix skeleton" includes an anthraquinone pigment, an azo pigment, a quinophthalone pigment, an isoporphyrin pigment, an isoindolinone pigment, and a benzopyrimidine. Anthrone-based pigments and the like. Further, it has a skeleton of the material of the material of the material of the above-mentioned (B), or a skeleton of the anthrone-based pigment, and is not included in the above. A derivative of the component (C) or the like can also be used as a pigment derivative. Further, the "matrix skeleton" also includes a pale yellow aromatic polycyclic compound which is not usually referred to as a pigment, such as a naphthalene, an anthracene, a triazide or a quinoline. Among them, a preferred matrix skeleton is an azo pigment, and a matrix skeleton having a quinophthalone pigment or a diketopyrrolopyrrole pigment is also included, and has a structure different from the essential components of the present invention as described above. Pigment derivatives. The pigment derivative which is suitable for use in the present invention includes, for example, Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. Japanese Laid-Open Patent Publication No. 2005-234478, Japanese Laid-Open Patent Publication No. 2003-240938, Japanese Patent Laid-Open No. 2001-356210, and Japanese Patent Application Laid-Open No. In the present invention, in addition to (B) phthalimidoalkylene diketopyrrolopyrrole and (C) phthalic acid, it is disclosed in the publication No. 2007-1 8668. In the case of a pigment derivative other than a quinone imine alkylated sulforaphanone, the amount of the other pigment derivative to be used is, in mass conversion, 'relative to 100 parts of the pigment contained in the pigment dispersion composition ( Diketopyrrolopyrrole Material), is preferably from 0.1 parts to 30 parts' is more preferably 0.5 parts to 30 parts, optimally 1 to 25 parts. If it is in this range, -43- 200948906, good dispersion and high contrast can be obtained. When a pigment derivative other than the component (B) or the component (C) is used, the total amount of the other pigment derivative is preferably set so that the total amount of the component (B) and the component (C) is 1 〇 times the amount below. [(D) Organic Solvent] The pigment dispersion composition of the present invention contains at least one organic solvent. The (D) organic solvent which can be used to prepare the pigment dispersion composition of the present invention includes 1-methoxy-2-propyl acetate, 1-methoxy-2-propanol, ethylene glycol monomethyl ether, Diethylene glycol monomethyl ether, ethyl acetate, butyl acetate, ethyl lactate, © acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, n-propanol, 2-propanol, N-butanol, cyclohexanol, ethylene glycol, diethylene glycol, toluene, xylene (oxime) and the like. The organic solvent is selected depending on the use of the pigment dispersion composition, and only one type or two or more types may be used in the composition. In addition, the amount of the organic solvent to be added is appropriately selected depending on the use of the pigment dispersion composition, etc., but it is considered from the viewpoint of handling characteristics when used to prepare a colored polymerizable composition described later. Further, the solid content concentration including the pigment or the like may be added in an amount of 5 to 50% by mass. [Other components] - dispersant _ The pigment dispersion composition of the present invention is preferably a dispersant added from the viewpoint of improving the dispersibility of the pigment to be contained. The "dispersant" which can be used in the present invention includes: a polymeric dispersant [for example, polyamidoamine and a salt thereof, a polycarboxylic acid and a salt thereof, and a high molecular weight not-44-200948906 saturated acid vinegar, Modified polyurethane, modified polyester, modified poly(meth)acrylate, (meth)acrylic copolymer, naphthalenesulfonic acid-formaldehyde condensate, polyoxidation Ethylene alkyl phosphate, polyoxyethylene alkylamine, alkanolamine, and the like. The polymer dispersant can be further classified into a linear polymer compound, a terminal modified polymer compound, a graft polymer compound, and a block polymer compound. The polymeric dispersant provides the effect of sorption on the surface of the pigment to prevent re-aggregation. Therefore, preferred examples of the structure include a terminal modified polymer compound having a fixed portion on the surface of the pigment, a graft polymer compound, and a block polymer compound. Hereinafter, the block type polymer compound, the graft type polymer compound, and the terminal modified type high molecular compound each suitable for the polymer dispersant of the present invention will be described. (Block type polymer compound) The block type polymer compound which can be used as a polymer dispersing agent is not particularly limited, and a pigment adsorbing block and a non-pigment absorbing block can be used. "Block type polymer compound" of a non-pigment adsorbing block. The "monomer constituting the pigment absorbing block" is preferably a monomer having a pigment absorbing functional group, although not particularly limited. Specifically, it includes a monomer having an organic dye structure or a heterocyclic structure, a monomer having an acidic group, a monomer having a basic nitrogen atom, and the like. In the following, a monomer having an organic dye structure or a heterocyclic structure, a monomer having an acidic group, -45-200948906, and a monomer having a basic nitrogen atom, which are suitable as monomers constituting the pigment sorption block, are used. Explain. A single system having an organic dye structure or a heterocyclic structure includes, for example, an anthracycline system, an insoluble azo system, an azo lake system, an anthraquinone system, a quinacridone system, a dioxane system, and a diketopyrrole. Pigment structure of pyrrole, pyridine pyridine, fluorenone ketone, indanthrone, ketone, fluorenone, anthraquinone, thioindigo or the like: or, for example, thiophene, furan, 卩ill嗤, pyrrole, pyrroline, pyrrolidine, dioxane, pyrazole, pyrazoline, pyrazole, imidazole, thiazole, thiazole, oxadiazole, triazole, thiadiazole, piperidine, pyridine, piperidine , dioxane, morpholine, argon, pyrimidine, piperazine, triazine, trithiane, isoporphyrin, isoindolinone, benzimidazolone, benzothiazole, amber imine, neighbor a monomer having a heterocyclic structure of benzylidene imine, naphthyl imine, hydantoin, hydrazine, quinoline, ruthenium, acridine, acridone, anthracene or the like. More specifically, although not particularly limited, a monomer having a structure as shown below can be cited. 200948906

Examples of the monomer having an acidic group include a vinyl mono-47-200948906' body having a carboxyl group, or a vinyl monomer having a sulfonic acid group, a vinyl monomer having a phosphate group, and a vinyl group having a carboxyl group. The system includes: (meth)acrylic acid, vinyl benzoic acid, maleic acid, monoalkyl maleate, fumaric acid, itaconic acid, crotonic acid, cinnamic acid, acrylic acid dimerization Things and so on. Further, an addition reaction of a monomer having a hydroxyl group such as 2-hydroxyethyl (meth)acrylate with a cyclic anhydride such as maleic anhydride or phthalic anhydride or cyclohexanedicarboxylic anhydride may also be used. , poly(meth)acrylic acid ω-carboxy-caprolactone and the like. Further, in addition to the above, as the carboxyl group precursor, an anhydride-containing monomer such as maleic anhydride, itaconic anhydride or citraconic anhydride may be used. Further, among these, (meth)acrylic acid is particularly preferable from the viewpoints of copolymerizability, cost, solubility, and the like. Further, the vinyl single system having a sulfonic acid group includes 2-propenylamine-2-methylpropanesulfonic acid and the like. Further, the vinyl single system having a phosphoric acid group includes: mono(2-propenyloxyethyl ester) phosphate, mono(1-methyl-2-propenyloxyethyl ester), and the like.单 A single system having an inert nitrogen atom includes: wherein the single system having a heterocyclic ring includes: vinyl pyridine, vinyl imidazole, vinyl triazole, etc.; (meth) acrylate type includes: (methyl ) N,N-dimethylaminoethyl acrylate, hydrazine (meth) acrylate, hydrazine-dimethylaminopropyl propyl ester, 1-(anthracene, fluorenyl-dimethylamino) (meth) acrylate 1,1-dimethylmethyl ester, bismuth (meth)acrylate, ruthenium dimethylaminohexyl hexyl ester, bismuth (meth) acrylate, ruthenium-diethylaminoethyl ester, bismuth (meth) acrylate , Ν-diisopropylaminoethyl ester, bismuth (meth) acrylate, ruthenium-di-n-butylaminoethyl ester, bismuth (meth) acrylate, ruthenium-di-iso-butylamino -48- 200948906 Ester, morpholinyl (meth) acrylate, piperidinyl (meth) acrylate, 1-pyrrolidyl (meth) acrylate, N, N-(meth) acrylate Dimethyl-2-pyrrolidylaminoethyl ester, and N,N-dimethylphenylaminoethyl (meth)acrylate, etc.; (meth) acrylamide series include: n-(n ',n'-dimethylaminoethyl) acrylamide Ν·(Ν',N'-dimethylaminoethyl)methacrylamide, N-(N',N'-diethylaminoethyl) decylamine, N-(N', N'-Diethylaminoethyl)methacrylamide, N-(N',N'-dimethylaminopropyl) acrylamide, N-(Ν', N'-dimethyl Aminopropyl)methacrylamide, ❹ Ν (Ν', N'-diethylaminopropyl) acrylamide, N-(Ν', N'-diethylaminopropyl) Methyl acrylamide, 2-(N,N-dimethylamino)ethyl(meth) acrylamide, 2-(N,N-diethylamino)ethyl(meth) propylene oxime Amine, 3-(N,N-diethylamino)propyl(meth)acrylamide, 3-(N,N-dimethylamino)propyl(meth)acrylamide,b N,N-Dimethylamino)-1,1-dimethylmethyl(meth)acrylamide, and 6-(N,N-diethylamino)hexyl(methyl)propenamide , morpholinyl (meth) acrylamide, piperidinyl (meth) acrylamide, N-methyl-2-pyrrolidinyl (meth) propylene oxime amine, etc.; styrene system including · N,N-dimethylaminostyrene Ν, Ν- dimethyl amino methyl styrene and the like. Further, a monomer having a urea group, a urethane group, a hydrocarbon group having a coordinating oxygen atom of 4 or more, an alkoxyalkyl group, an epoxy group, an isocyanate group or a hydroxyl group can also be used. Specifically, it includes a monomer having the following structure. -49- 200948906

In addition to this, a monomer having an ionic functional group can be utilized. Examples of the ionic vinyl monomer (anionic vinyl monomer, cationic vinyl monomer) include: wherein the anionic vinyl single system comprises: a vinyl monomer having an acidic group as described above An alkali metal salt or a salt with an organic amine (for example, a tertiary amine such as triethylamine or dimethylaminoethanol). The cationic vinyl single system includes: a halogenated alkyl group (alkyl group: C1 to 18; a halogen atom: a chlorine atom 'indidate atom or an iodine atom), which is a nitrogen-containing ethylenic monomer as described above. Halogenation of benzyl chloride, benzyl bromide, etc. -50-200948906 Alkyl sulfonate of benzyl, methanesulfonic acid, etc. (alkyl: C1 to 18) 'benzenesulfonic acid, toluenesulfonic acid, etc. Alkyl aryl sulfonate (alkyl: C1 to 18) 'Dialkyl diaryl ammonium salt obtained by quaternization of a dialkyl sulfate (alkyl group: C1 to 4). The "monomer having a pigment absorbing functional group" as described above can be appropriately selected depending on the kind of the pigment to be dispersed, and these may be used singly or in combination of two or more. "The monomer constituting the non-pigment absorbing block", although there is no special limitation, includes: (meth) acrylates, crotonates, vinyl esters, butylene Acid diesters, fumaric acid diesters, itaconic acid diesters, (meth) acrylamides, styrenes, vinyl ethers, vinyl ketones, olefins, butene A monomer having a non-pigment absorbing group such as a diterpene imine or (meth)acrylonitrile. These single systems constituting the non-pigment absorbing block may be used singly or in combination of two or more. Further, in the case of a stomach condition suitable for a pigment dispersion composition requiring alkali development treatment, a monomer constituting the non-pigment sorption block as described above and a vinyl monomer having an acidic group can be used. Examples of (meth) acrylates include: methyl (meth) acrylate 'ethyl (meth) acrylate, n-propyl (meth) acrylate, isopropyl (meth) acrylate, (methyl) ) n-butyl acrylate, isobutyl (meth)acrylate, tertiary butyl (meth)acrylate, amyl (meth)acrylate, n-hexyl (meth)acrylate, (meth)acrylic acid Cyclohexyl ester, tert-butylcyclohexyl (meth)acrylate, 2-ethylhexyl (meth)acrylate, tertiary-octyl (meth)acrylate, dodecyl (meth)acrylate , (methyl) -51- 200948906 octadecyl acrylate, ethoxylated ethyl (meth) acrylate, phenyl (meth) acrylate, 4-hydroxybutyl (meth) acrylate, (methyl) 2-methoxyethyl acrylate, 2-ethoxyethyl (meth) acrylate, 2-(2-methoxyethoxy)ethyl (meth) acrylate, 2-chloro (meth) acrylate Ethyl ester, vinyl (meth)acrylate, 2-phenylvinyl (meth)acrylate, 1-propenyl (meth)acrylate, (meth)acrylic acid Propyl ester, 2-allyloxyethyl (meth)acrylate, propargyl (meth)acrylate, benzyl (meth)acrylate, diethylene glycol monomethyl ether (meth)acrylate, ( Diethylene glycol monoethyl ether acrylate, triethylene glycol monomethyl ether (meth) acrylate, triethylene glycol monoethyl ether (meth) acrylate, polyethylene (meth) acrylate Alcohol monomethyl ether ester, poly(ethylene) glycol monoethyl ether acetate, (meth)acrylic acid&gt; 5-phenoxyethoxyethyl ester, poly(meth)acrylic acid decyl phenoxy Ethylene glycol ester, dicyclopentenyl (meth)acrylate, dicyclopentenyloxyethyl (meth)acrylate, trifluoroethyl (meth)acrylate 'octafluoropentyl (meth)acrylate , perfluorooctyl (meth) acrylate, dicyclopentanyl (meth) acrylate, tribromophenyl (meth) acrylate, tribromophenoxyethyl (meth) acrylate, (methyl) Examples of the ?-butyrolactone or the like © crotonic acid esters include: butyl crotonate, hexyl crotonate, and the like. Examples of the vinyl esters include vinyl acetate, vinyl chloroacetate, vinyl propionate, vinyl butyrate, methoxyvinyl acetate, and vinyl benzoate. Examples of the maleic acid diesters include: dimethyl maleate, diethyl maleate, and dibutyl maleate. -52- 200948906 Examples of the fumaric acid diesters include: dimethyl fumarate, diethyl fumarate, and dibutyl fumarate. Examples of the ikonic acid diesters include: dimethyl ikonate, diethyl itaconate, and dibutyl itaconate. (Meth) acrylamides include: (meth) acrylamide, N-methyl (meth) acrylamide, N-ethyl (meth) acrylamide, N-propyl (methyl ) acrylamide, N-isopropyl (meth) acrylamide, N-n-butyl propylene (methyl) decylamine, N-tertiary butyl (meth) acrylamide, N- Cyclohexyl(meth)acrylamide, N-(2-methoxyethyl)(meth)acrylamide, hydrazine, hydrazine-dimethyl(meth) decylamine, N,N- Diethyl (meth) acrylamide, N-phenyl (meth) acrylamide, N-nitrophenyl acrylamide, N-ethyl-N-phenyl acrylamide, N-benzoic acid (meth) acrylamide, (meth) propylene decyl morpholine, diacetone acrylamide, N-methylol acrylamide, N-hydroxyethyl acrylamide, vinyl (meth) propylene Guanidine, N,N-diallyl (meth) acrylamide, N-allyl (meth) acrylamide, and the like. Examples of styrenes include: styrene, methyl styrene, dimethyl styrene, trimethyl styrene, ethyl styrene, isopropyl styrene, butyl styrene, hydroxystyrene, Oxystyrene, butoxystyrene, ethoxylated styrene, chlorostyrene, dichlorostyrene, bromostyrene, chloromethylstyrene, which are deprotected by acidic substances (for example, three A hydroxystyrene, a methyl benzoate, an α-methyl styrene or the like protected by a butyloxycarbonyl group (t-Boc: t-butoxycarbonyl) or the like. Examples of vinyl ethers include: methyl vinyl ether, ethyl vinyl ether, 2-chloroethyl vinyl ether, hydroxyethyl vinyl ether, propyl vinyl ether, butyl vinyl ether, hexyl Vinyl ether, octyl vinyl ether, methoxyethyl-53-200948906-based vinyl ether, phenyl vinyl ether, etc. Examples of vinyl ketones include: methyl vinyl ketone, ethyl vinyl ketone , propyl vinyl ketone, phenyl vinyl ketone, and the like. Examples of the olefins include ethylene, propylene, isobutylene, butadiene, isoprene, and the like. Examples of the maleimide group include: maleimide, butyl succinimide, cyclohexylmethyleneimine, phenyl maleimide, and the like. Examples of the (meth)acrylonitrile include: methacrylonitrile, acrylonitrile, etc. Examples of the vinyl monomer having an acidic group as described above include: a vinyl monomer having a carboxyl group, or having a sulfonate An acid group vinyl monomer, a vinyl monomer having a phosphate group. The vinyl single system having a carboxyl group includes: (meth)acrylic acid, vinylbenzoic acid, maleic acid, monoalkyl maleate, fumaric acid, itaconic acid, crotonic acid, Cinnamic acid, acrylic acid dimer, and the like. Further, it is also possible to use a monomer having a hydroxy group such as 2-hydroxyethyl (meth)acrylate and a cyclic anhydride such as maleic anhydride or phthalic anhydride or cyclohexanedicarboxylic anhydride. The reactant "poly(meth)acrylic acid ω-carboxy-caprolactone and the like. In addition to this, a monomer containing an anhydride such as maleic anhydride, itaconic anhydride or citraconic anhydride may be used as the carboxyl precursor. Further, among these, it is particularly preferable to be (meth)acrylic acid from the viewpoints of copolymerizability, cost, solubility, and the like. Further, the vinyl single system having a sulfonic acid group includes 2-propenylamine-2-54-200948906 methylpropanesulfonic acid and the like. The vinyl single system having a phosphoric acid group includes: mono(2-propenyloxyethyl ester) phosphate, mono(1-methyl-2-propenyloxyethyl phosphate), and the like. In addition, a vinyl monomer having an acidic group may also be a vinyl monomer having a phenolic hydroxyl group or a vinyl monomer containing a sulfonamide group. The method for obtaining the block type polymer compound of the present invention can be produced by a conventional method. For example, a living polymerization method (、), an inferer polymerization method, and the like are known. In addition to this, there is another method: when radically polymerizing a monomer having a pigment absorbing group or a monomer having a non-pigment absorbing group, the thiocarbamic acid or 2- a polymer obtained by polymerizing a compound containing a thioester and a thiol group in the presence of a compound containing a thioester and a thiol group, such as ethionyl thioethyl ether or 10-ethyl sulfonyl thiol thiol, is sodium hydroxide or ammonia. A method in which a base is treated as a polymer having a thiol group at a single terminal, and a monomer component of another block is subjected to radical polymerization in the presence of a polymer having a thiol group at a single terminal. Well known to everyone. Among these, an active polymerization method is preferred. The weight average molecular weight of the block type polymer compound is not particularly limited, but is preferably in the range of 3,000 to 1,000,000, more preferably in the range of 5,0 Torr to 50,000. When the weight average molecular weight is 3,000 or more, the stabilizing effect can be more effectively obtained. Further, when the weight average molecular weight is 100,000 or less, it can be more effectively absorbed and exhibits good dispersibility. Commercially available products can also be used as the block type polymer compound. Specific examples include: -55- 200948906, manufactured by BYK Chemie Corp.

Disperbyk_2000, 2001", EFKA Additives B. V. (EFKA Additives B.V.) made "EFKA 4330, 4340" and so on. (Graft type polymer compound) The "graft type polymer compound" which can be used as a polymer dispersant is not particularly limited, and it is suitable for use in Japanese Patent Laid-Open No. 54-37082, Japanese Invention A compound obtained by reacting a polyalkyleneimine with a polyester compound as disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. Hei. No. Hei. No. 9-169821. A compound obtained by modifying an amine group of a side chain of a polyallylamine with a polyester, and a polyester polyol as disclosed in Japanese Laid-Open Patent Publication No. SHO 60-16613. In addition, it is also suitable to use the Japanese Patent Laid-Open Publication No. 9-171 25 3 or the Chemistry and Technology of Macromonomers ( A graft type ruthenium molecular compound having a polymerizable oligomer (hereinafter referred to as a macromonomer) as a copolymerization component disclosed in IPC Publications (IPC Publication), 1989, and the like. The branch part of the graft type polymer compound is preferably polystyrene, polyethylene oxide, polypropylene oxide, poly(meth)acrylate, polycaprolactone or the like. Among them, a graft type polymer compound having a structural unit represented by the following general formula (5) in the branch portion is more preferable. 200948906 R74 ^-CH2—. Present formula (5)

Q In the formula (5), R74 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms; Q represents a cyano group, an aryl group having 6 to 30 carbon atoms, or -COOR75 (here, R75 represents a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, or an aryl group having 6 to 30 carbon atoms. In the formula (5), the alkyl group represented by R74 may have a substituent, and is preferably an alkyl group having 1 to 6 carbon atoms, and particularly preferably a methyl group. The substituent which may be introduced into the alkyl group includes a halogen atom, a carboxyl group, an alkoxycarbonyl group, an alkoxy group and the like. Specific examples of such alkyl groups include methyl, ethyl, hexyl, octyl, trifluoromethyl, carboxymethyl, methoxycarbonylmethyl and the like. R74 is particularly preferably a hydrogen atom or a methyl group. In the formula (5), the aryl group represented by Q may have a substituent, and is preferably an aryl group having 6 to 20 carbon atoms, particularly preferably 6 to 12 carbon atoms. Aryl. The substituent which may be introduced into the aryl group includes a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and the like. Specific examples of such aryl groups include: phenyl, naphthyl, tolyl, fluorenyl, propylphenyl, butylphenyl, octylphenyl, dodecylphenyl, methoxyphenyl, Ethoxyphenyl, butoxyphenyl, nonyloxyphenyl, chlorophenyl, dichlorophenyl, bromophenyl, methoxycarbonylphenyl, ethoxycarbonylphenyl, butyl-57-200948906 Oxycarbonyl phenyl and the like. Among these aryl groups, preferred are unsubstituted aryl groups, or aryl groups substituted with a halogen atom, an alkyl group or an alkoxy group, particularly preferably an unsubstituted aryl group, or an alkyl group. Substituted aryl. When Q of the formula (5) is -COOR75, the alkyl group represented by R75 may have a substituent, and is preferably an alkyl group having 1 to 12 carbon atoms, particularly preferably a carbon atom. The number is from 1 to 8 alkyl groups. The substituent which may be introduced into the alkyl group includes a halogen atom, an alkenyl group, an aryl group, a hydroxyl group, an alkoxy group, an alkoxycarbonyl group, an amine group, a mercaptoamine group, an amine mercapto group or the like. Specific examples of such alkyl groups include: methyl, ethyl, propyl, butyl, heptyl, hexyl, octyl, decyl, dodecyl, thirteen, tetradecyl, hexa , octadecyl, 2-chloroethyl, 2-bromoethyl, 2-methoxycarbonylethyl, 2-methoxyethyl, 2-bromopropyl, 2-butenyl, 2-pentyl Alkenyl, 3-methyl-2-pentenyl, 2-hexenyl, 4-methyl-2-hexenyl, benzyl, phenethyl, 3-phenylpropyl, naphthylmethyl, 2-naphthylethyl, chlorobenzyl, bromobenzyl <methylbenzyl, ethylbenzyl, methoxybenzyl, dimethylbenzyl, dimethoxybenzyl , cyclohexyl, 2-cyclohexylethyl, 2-cyclopentylethyl, bicycloguanidine [3.2.1]oct-2-yl, 1-adamantyl, dimethylaminopropyl, acetylamine Ethyl ethyl, N, N-dibutylaminoamine, mercaptomethyl and the like. Among these alkyl groups, an unsubstituted alkyl group or an alkyl group substituted with a halogen atom, an aryl group or a hydroxyl group is particularly preferably an unsubstituted alkyl group. When Q of the formula (5) is -COOR75, the aryl group represented by R75 may have a substituent, and preferably an aryl group having 6 to 20 carbon atoms, particularly preferably a carbon atom. The number is 6 to 12 aryl groups. -58- 200948906 The substituent which may be introduced into the aryl group includes a halogen atom, an alkyl group, an alkenyl group, an alkoxy group, an alkoxycarbonyl group, a mercaptoamine group and the like. Specific examples of such aryl groups include: phenyl, naphthyl, tolyl, fluorenyl, propylphenyl, butylphenyl, octylphenyl, dodecylphenyl, methoxyphenyl, Ethoxyphenyl, butoxyphenyl, nonyloxyphenyl, chlorophenyl, dichlorophenyl, bromophenyl, methoxycarbonylphenyl, ethoxycarbonylphenyl, butoxycarbonylbenzene Base, acetaminophen phenyl, acrylamidophenyl, decyl decyl phenyl, and the like. Among these aryl groups, an unsubstituted aryl group or an aryl group substituted by a halogen atom, an alkyl group or an alkoxy group is preferable, and an alkyl group-substituted aryl group is particularly preferable. Among these R75, a hydrogen atom, an alkyl group having 1 to 22 carbon atoms, and particularly preferably a hydrogen atom and an alkyl group having 1 to 12 carbon atoms are preferable. Specific examples of the branching portion of the graft type polymer compound having the structural unit represented by the formula (5) in the branch portion include: poly(methyl) methacrylate, poly(methyl) Acrylic-n-butyl ester, poly(meth)acrylic acid®-iso-butyl ester, poly(methyl (meth) acrylate-co-(methyl) acrylate), poly((meth) acrylate) Ester-co-styrene), poly(methyl (meth) acrylate-co-(meth)acrylic acid), poly(methyl (meth) acrylate-co-acrylonitrile), and the like. Any of conventionally known methods for synthesizing a graft type high molecular compound having a structural unit represented by the formula (5) in the branch portion can be used. Specifically, a copolymerization of a macromonomer having a structural unit represented by the general formula (5) with an ethylenically unsaturated monomer copolymerizable with the macromonomer can be exemplified. -59- 200948906 Among the macromonomers having a structural unit represented by the general formula (5), it is preferably represented by the following general formula (6). R76 formula (6) CH2=zzc

In the general formula (6), 'R76 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms', and represents a single bond, or a linking group as shown below, or an arbitrary divalent group as shown below. The linking group constituted by the combination, and the A system represents a group having a structural unit represented by the formula (5) as described above. _CH=CH~ -Qf Z2

f O , S~~ , , N , coo^* , —S〇2^~~·

—NHCOO-, a nhcONH—

In the above-mentioned linking group, 'Zi, and Z2 each independently represent a hydrogen atom, a halogen atom, an alkyl group having 1 to 6 carbon atoms, a cyano group, or a hydroxyl group. Z3 represents a hydrogen atom, carbon. An alkyl group having 1 to 18 atoms or an aryl group having 6 to 20 carbon atoms. -60- 200948906 Specific examples of such macromonomers represented by the general formula (6) include those as shown below.

The A system in the specific structure of the macromonomer as described above is synonymous with A in the general formula (6) as shown before. These macro-systems available from commercial products include: single-end methacryl oxime-based polymethyl methacrylate oligomers (Mn = 6,000, trade name: AA-6, East Asia Synthetic Chemical Industry Limited) (manufactured by Toagosei Co., Ltd.); and a single-end methacryl oxime-based poly-n-butyl acrylate oligomer (Μη = 6,000, trade name: ΑΒ-6, manufactured by East Asia Synthetic Chemical Co., Ltd. A single-end methacryl oxime-based polystyrene oligomer (Μη = 6,000, trade name: AS-6, manufactured by Toagosei Chemical Co., Ltd.). The molecular weight of the macromonomer as described above is preferably from 1,000 to 20,000, more preferably from 2,000 to 15,000, in terms of polystyrene. If the number average molecular weight is within this range, the steric repulsion effect which the dispersant should have can be more effectively obtained. The ethylenically unsaturated mono-system which can be copolymerized with the macromonomer as described above is more than -61 to 200948906. Preferably, the "monomer constituting the pigment absorbing block" as described above is used to enhance the pigment. Dispersibility, dispersion stability. Further, the "monomer constituting the non-pigment absorbing block" as described above may be copolymerized as another copolymerization component. The weight average molecular weight of the graft type polymer compound as described above is not particularly limited, and is preferably in the range of 3,000 to 100,000, more preferably in the range of 5,000 to 50,000. When the weight average molecular weight is 3,000 or more, the stabilizing effect can be more effectively obtained, and when the weight average molecular weight is 100,000 or less, it can be more effectively absorbed and exhibits good dispersibility. © The commercially available product of the graft type polymer compound as described above includes:

"SOLSPERSE 24000, 28000, 32000, 38500, 39000, 55000" manufactured by The Lubrizol Corporation; "Disperbyk-161, 171, 174", etc., manufactured by BYK Chemie, Inc. (end-modified 髙 molecular compound) The term "terminal-modified polymer compound" as a polymer dispersing agent includes, for example, Japanese Laid-Open Patent Publication No. 9-77994, or Japanese Patent Laid-Open No. 2002-273191. A polymer compound having a functional group at the end of a polymer as disclosed in the above. The method for synthesizing the polymer compound having a functional group at the terminal of the polymer is not particularly limited, and examples thereof include the following methods, or a combination of the methods, etc.: 1. Polymerization using a polymerization initiator containing a functional group (for example, radical polymerization, anionic polymerization, cationic polymerization, etc.) synthesis; 2. A method of synthesizing by radical polymerization using a chain transfer agent containing a functional group. -62- 200948906 Here, the functional group for introduction includes: an organic dye structure selected from a heterocyclic structure, an acidic group, a group having a basic nitrogen atom, a urea group, a urethane group, and a coordination group. The carbon atom of the oxygen atom is a hydrocarbon group of 4 or more, an alkoxyalkyl group, an epoxy group, an isocyanate group, a hydroxyl group, and a site of an ionic functional group. Further, a functional group which can be derived from such a sorption site can also be used. A polymerization initiator (polymerization initiator containing a functional group) which can introduce a functional group to a polymer terminal, which is used in the synthesis method as described above, includes, for example, 2,2'-azobis (2) -Cyanpropanol), 2,2'-azobis(2-cyanopentanol), 4,4'-azobis(4-cyanovaleric acid), 4,4'-azobis(4- Cyanovalerate chloride), 2,2'-azobis[2-(5-methyl-2-imidazolin-2-yl)propane], 2,2'-azobis[2-( 2- Imidazolin-2-yl)propane], 2,2'-azobis[2·(3,4,5,6-tetrahydropyrimidin-2-yl)propane], 2,2'-azobis{ 2-[1-(2-hydroxyethyl)-2-imidazolin-2-yl]propane}, 2,2'-azobis[2-methyl-N-(2-hydroxyethyl)-propane Indoleamine, etc., and derivatives thereof. A chain transfer agent (a chain transfer agent containing a functional group) which can introduce a functional group to a polymer terminal, which is used in the synthesis method as described above, includes: Example®, for example, a thiol compound (for example, sulfur) Glycolic acid, thiomalic acid, thiosusic acid, 2-hydrothiopropionic acid, 3-hydrothiopropionic acid, 3-hydrothiobutyric acid, N-(2-hydrothiopropyl) glycine Acid, 2-hydrothionicotinic acid, 3-[N-(2-hydrothioethyl)aminemethanyl]propionic acid, 3-[N-(2-hydrothioethyl)amino] Propionic acid, N-(3-hydrothiopropyl) alanine, 2-hydrothioethane sulfonic acid, 3-hydrothiopropane sulfonic acid, 4-hydrothiobutane sulfonic acid, 2-hydrogen Thioethanol, 3-hydrothio-1,2-propanediol, 1-hydrothio-2-propanol, 3-hydrothio-2-butanol, hydrothiophenol, 2-hydrothioethyl Amine, 2-hydrothioimidazole, 2-hydrothio-3-pyridinol, benzenethiol, toluenethiol, thiothioacetophenone, naphthylthiol, naphthylmethyl mercaptan, etc.; this -63- 200948906 A disulfide compound of an oxide of a hydrosulfide compound, and a halogen compound (for example, 2-iodoethanesulfonic acid, 3-iodopropanesulfonic acid, etc.). A monomer which can be used for polymerizing a polymer compound having a functional group at the terminal of the polymer, for example, a monomer having a non-pigment absorbing block as described above can be used as the radical polymerizable single system. The molecular weight of the terminal modified polymer compound is preferably a weight average molecular weight of 1,000 to 50,000. When the weight average molecular weight is 1,000 or more, the steric repulsion effect which should be obtained as a dispersing agent can be more effectively obtained, and when it is 50,000 or less, the steric effect can be more effectively suppressed, and further shortened for The sorption time of the pigment. Commercially available products of terminal modified polymer compounds include: SOLSP ERSE 3000, 17000, 27 000, etc. manufactured by The Lubrizol Co., Ltd. In the present invention, the dispersing agent is preferably a graft type polymer compound or a terminal modified type fluorene molecular compound, and particularly preferably a copolymerized unit derived from a monomer having an organic dye structure or a heterocyclic structure. A graft-type polymer compound; a terminal modified polymer compound having an organic dye structure, a heterocyclic structure, an acidic group, a group having a basic nitrogen atom, a urea group, or a urethane group as a terminal group. Further, in the present invention, a dispersion resin may be used as needed. By using a dispersion resin, the dispersion stability and preservability of the treated pigment can be improved. A specific example of the dispersion resin which can be used in the present invention is preferably a resin having a carboxyl group, a sulfonic acid group, a phosphoric acid group, an amine group or the like. A polymer having a carboxylic acid in a side chain is disclosed, for example, in Japanese Laid-Open Patent Publication No. 59-44615, Japanese Patent No. Sho 54-34327-64-200948906, and Japanese Invention Patent No. Japanese Patent Publication No. -12577, Japanese Patent Application Laid-Open No. Hei No. 54-25957, Japanese Patent Application Laid-Open No. 59-5-3 836, and Japanese Laid-Open Patent Publication No. 59-71048 Acrylic acid copolymer, acrylic acid copolymer, itaconic acid copolymer, crotonic acid copolymer, maleic acid copolymer, partially esterified maleic acid copolymer, etc., in addition, Also in the side chain is an acidic cellulose derivative of a carboxylic acid. The polymer having a carboxylic acid in a side chain includes, for example, a carboxyl group such as (meth) acrylic acid, maleic acid (anhydride), crotonic acid, itaconic acid, or fumaric acid. Monomer; styrene, α-methylstyrene, methyl (meth)acrylate, ethyl (meth)acrylate, propyl (meth)acrylate, isopropyl (meth)acrylate, (methyl) Butyl acrylate, isobutyl (meth)acrylate, vinyl acetate, acrylonitrile, (meth) acrylamide, glycidyl (meth) acrylate, allyl glycidyl ether, glycidyl ethacrylate Ester, glycidyl ether crotonate, (meth) propylene chlorochloride, benzyl (meth) acrylate, phenyl (meth) acrylate, (meth) propylene hydroxyethyl ester, hydrazine - hydroxymethyl Acrylamide, hydrazine, hydrazine-dimethyl methacrylate, hydrazine-methacryl hydrazinomorph, hydrazine (meth) acrylate, hydrazine-dimethylaminoethyl ester, hydrazine, hydrazine-dimethyl Copolymerization of one or more kinds of aminoethyl acrylamide, maleimide, fluorene-phenyl maleimide Of the obtained polymer to be copolymerized. Among them, it is particularly preferable that the (meth)acrylic resin containing at least (meth)acrylic acid or alkyl (meth)acrylate as a structural single system contains (meth)acrylic acid and styrene (methyl) ) Acrylic resin. These acrylic acid copolymerization components are not limited to those described above. Further, these dispersed resins may also have an ethylenic double bond added to the side chain. By -65-200948906, a double bond is imparted to the side chain, whereby the photocurability is improved, and the resolution and adhesion are further improved. The method of synthesizing the ethylenic double bond is as follows, for example, the method disclosed in Japanese Laid-Open Patent Publication No. SHO-50-34443, Japanese Patent Application Laid-Open No. Hei No. 50-34444, and the like. Specifically, it is a method of reacting a compound having a glycidyl group, an epoxycyclohexyl group, and a (meth)acrylonitrile group with a carboxyl group or a hydroxyl group. For example, glycidyl (meth)acrylate, allyl glycidyl ether, glycidyl α-ethyl acrylate, crotonyl glycidyl ether, glycidyl ether (iso)crotonate, (A) (meth)acrylic acid (3,4-epoxycyclohexyl)methyl ester, (meth)acrylic acid chloride, (meth) propyl acryloyl chloride, etc. The compound is reacted with a resin having a carboxyl group or a hydroxyl group, whereby a resin having a polymer group in a side chain can be obtained. In particular, a resin obtained by reacting (3,4-epoxycyclohexyl)methyl (meth)acrylate is preferred. Specific compounds of this type include, for example, DIANAL NR series (manufactured by Mitsubishi Rayon Co., Ltd.); Photomer 6173 (polyaminoglycolic acid-based oligomers containing COOH) , manufactured by Diamond Shamrock Co. Ltd.; BISCOAT R-264, KS RESIST (KS resist) 106 (all manufactured by Osaka Organic Chemical Industry Ltd.); CYCLOMER P series, PLACCELCF200 series ( Both are manufactured by Daicel Chemical Industries, Ltd.; Ebecryl 3800 (manufactured by DAICEL-UCB Company Ltd.) and the like. 200948906 Further, a polymer obtained by copolymerization of a monomer represented by the following general formula (7) and a monomer having at least an acidic group (a copolymerizable component as described above may be mentioned) may also be used. . H2c = CRC ( = Ο ) OCR4R5C ( = r3 ) = cr2r! In the above formula (7), R represents a hydrogen atom or a methyl group, and R1 to R5 are independently represented by each other. From the hydrogen atom, a halogen atom, a cyano group, an alkyl group, and an aryl group. Specific examples of the halogen atom include: Cl, Br, I, and the like. The alkyl group may be linear, branched, or cyclic, and examples thereof include a methyl group, a n-propyl group, an iso-propyl group, a tertiary-butyl group, and the like, and preferably have a carbon number of 1 to 7. By. The aryl group includes, for example, a phenyl group, a furyl group, a naphthyl group and the like. In the above description, the dispersion resin may be selected from various monomers, and since the solubility and the acid value are controlled, a copolymer of (meth)acrylic acid and (meth) acrylate is preferred. The weight average molecular weight of these dispersion resins measured by gel permeation chromatography (GPC) preferably ranges from 1, 〇〇〇 to 80,000, more preferably from 3,000 to 50,000, and most preferably from 3,000 to 20,000. By setting the weight average molecular weight to 80,000 or less, good dispersibility and liquid fluidity can be obtained, and good developability can be obtained. These dispersion resins are not only used for dispersing the pigment when the pigment dispersion composition is prepared, but also for use in preparing a colored polymerizable composition as described later. The amount of the dispersant added is preferably from 0.5 to 100% by mass, more preferably from 3 to 100% by mass, particularly preferably from 5 to 80% by mass, based on the pigment. -67- 200948906 - If the amount of the dispersant added is within this range, sufficient pigment dispersing efficiency can be obtained, but the optimum amount of the dispersing agent should be appropriately selected depending on the combination of the pigment, solvent, etc. used. Adjust it. Further, more specifically, in the case of using a polymer dispersant, the amount thereof is preferably in the range of 5 mass% to 1 mass%, more preferably 10 mass%, based on the pigment. Up to 80% by mass. Further, in the pigment dispersion composition of the present invention, in addition to the dispersant as described above, a surfactant or the like may be used for the purpose of improving the dispersibility. By using the pigment dispersion composition of the present invention to prepare a colored polymerizable group, and applying it to the production of a color filter, a color filter having high contrast and excellent surface smoothness can be obtained. . [Preparation of Pigment Dispersion Composition] The pigment dispersion composition of the present invention can be prepared by a mixing and dispersing step of mixing and dispersing using various mixers and dispersers. Further, the mixing and dispersing step is preferably composed of a microdispersion treatment including kneading dispersion and subsequent, but kneading dispersion may be omitted. The method for producing a pigment dispersion composition of the present invention is preferably: first, when the (A ❹ ) diketopyrrolopyrrole pigment is refined, and the average primary particle diameter thereof is in the range of 10 nm to 30 nm, the addition is carried out. (B) at least a part of the specific addition amount of the phthalic acid imidoalkylated diketopyrrolopyrrole and (C) the phthalic acid imidoalkylation quinophthalone, preferably the total amount a step of then carrying out (A) a diketopyrrolopyrrole pigment, (B) a phthalimidoalkylamine diketopyrrolopyrrole and (C) a phthalimidoalkylene group The step of dispersing the salivone with an organic solvent. Although (B) phthalic acid imidyl alkylated diketopyrrole may be added before the average primary particle size of the (A) diketopyrrolopyrrole pigment reaches 10 nm to 30 nm -68 to 200948906 And a part of pyrrole and (C) phthalic acid imidoalkylated quinophthalone, but more preferably the average primary particle diameter of the (A) diketopyrrolopyrrole pigment reaches 10 nm to 30 nm. After the range is completed and the micro-finished, the total amount of the specific addition amount is added. Further, it is preferred to add (B) phthalic acid imidoalkylated diketopyrrolopyrrole and (C) phthalic acid imidoalkylated quinacridone at the beginning of dispersion. The total amount of a specific addition amount, but it is also possible to add a part of a specific addition amount when starting to disperse. In this case, for example, a residual amount can be added in the middle of the dispersion.

The method of the present invention will be specifically described as follows. For example, premixing (A) diketopyrrolopyrrole pigment with (B) phthalimidoalkylated diketopyrrolopyrrole and (C) phthalic acid iminoalkylated saliva At least a portion of the specific addition amount of the anthrone, and a dispersant further used as needed herein. In addition, the mixture previously dispersed by a homogenizer or the like is microdispersed together with an organic solvent using a medium agitating type dispersing machine such as chrome oxide beads (for example, DISPERMAT manufactured by GETZM ANN GmbH). Thereby, the pigment dispersion composition of the present invention can be prepared. The present invention is preferably subjected to a microdispersion treatment using a medium agitating type disperser, and is preferably carried out gently for a short period of time without causing damage to the dispersion. For the purpose of dispersion, a medium having an average particle diameter of 〇.〇1 mm or more and 0.2 mm or less is used. Here, the "average particle diameter" in the present invention means the circle-equivalent diameter of the medium, and is calculated from the average length 値 of the longest diameter and the shortest diameter of 100 media. Specifically, the medium can be photographed by a stereo microscope and magnified by -69-200948906, and the particle size is determined by the image thereof. In the present invention, it is preferred to carry out pre-dispersion to pre-crush the coarse particles before dispersing in a medium of 0.01 mm or more and 0.2 mm or less. Since the pre-dispersion is aimed at pulverizing coarse particles, it is preferred to use a medium having a larger size, that is, a medium having an average particle diameter of 0.3 mm or more and 1.0 mm or less, more preferably 0.4 mm or more. , medium below 1.0 mm. The dispersion time may be set according to the apparatus to be used, the amount of the pigment dispersion composition, and the like, but is usually about 1 to 24 hours. In addition, detailed details on kneading and dispersion have been described in "Paint Flow and Pigment Dispersion" by T. C. Patton Ο 斤 著作 (1964,

Published by John Wiley and Sons, Japanese Patent Laid-Open No. 2007-1 6206, and the like. Since the obtained pigment dispersion composition has superior dispersibility and dispersion stability of the diketopyrrolopyrrole pigment, it is suitably used for various uses containing a diketopyrrolopyrrole pigment as a colorant, for example, as described below. Coloring a polymerizable composition or the like. &lt;Coloring Polymerizable Composition&gt; The coloring polymerizable composition of the present invention contains the pigment dispersion composition, the photopolymerizable compound, and the photopolymerization initiator of the present invention as described above, and preferably further contains The alkali-soluble resin may contain other components as needed. Hereinafter, each component contained in the colored polymerizable composition of the present invention will be described in detail. [Pigment Dispersion Composition] The colored polymerizable composition of the present invention is composed of at least one of the pigment dispersion compositions of the present invention as described above. Detailed details regarding the pigment dispersion composition of the present invention for constituting the colored composition-70-200948906 compliant composition are as described above. The content of the pigment dispersion composition in the colored polymerizable composition of the present invention is preferably from 5 to 70% by mass based on the total solid content (by weight) of the colored polymerizable composition. The quantity is more preferably in the range of 15 to 60% by mass. When the content of the pigment dispersion composition is within this range, it is effective in securing a sufficient color density and having excellent color characteristics. [Photopolymerizable Compound] The colored polymerizable composition of the present invention contains at least one photopolymerizable compound. The photopolymerizable compound to be used in the invention may be an addition polymerizable compound having at least one ethylenically unsaturated double bond, and may be selected from at least one, preferably two or more terminal ethylenically unsaturated bonds. Compound. Such a group of compounds is well known to those skilled in the art and can be used without particular limitation in the present invention. The photopolymerizable compound has, for example, a monomer, a prepolymer, that is, a dimer, a trimer, and an oligomer, or a mixture thereof, and a chemical form of such a copolymer. Examples of the monomer and the copolymer thereof include: an unsaturated carboxylic acid (for example, acrylic acid, methacrylic acid, itaconic acid, crotonic acid, isocrotonic acid, maleic acid, etc.), or an ester thereof And guanamines, and preferably an ester of an unsaturated carboxylic acid and an aliphatic polyol compound, an amide of an unsaturated carboxylic acid and an aliphatic polyamine compound. Further, it is also suitable to use an unsaturated carboxylic acid ester or decyl amine having a nucleating substituent such as a hydroxyl group, an amine group or a thiol group, and an addition reaction product with a monofunctional or polyfunctional isocyanate or epoxy group. And a dehydration condensation reaction with monofunctional-71-200948906 or a polyfunctional carboxylic acid. Further, an addition reaction product of an unsaturated carboxylic acid ester or a guanamine having an isocyanate group or an electrophilic substituent such as an epoxy group, and a monofunctional or polyfunctional alcohol, an amine or a thiol; In addition to this, an unsaturated carboxylic acid ester or decylamine having a detachable substituent such as a halogen group or a tosyloxy group, and a monofunctional or polyfunctional alcohol, an amine or a thiol are substituted. The reactants are also suitable. Further, other examples may be substituted with an unsaturated carboxylic acid as described above and changed to a compound group obtained by unsaturated phosphonic acid, styrene, vinyl ether or the like. Specific examples of the aliphatic polyol compound and the unsaturated carboxylic acid ester monomer include: wherein the acrylate type includes: ethylene glycol diacrylate, triethylene glycol diacrylate, and diacrylate 1,3 - Butylene glycol ester, tetramethylene glycol diacrylate, propylene glycol diacrylate, neopentyl glycol diacrylate, trimethylolpropane triacrylate, trimethylolpropane tris(propylene decyloxypropane Ether, trimethylolethane triacrylate, hexanediol diacrylate, 1,4-cyclohexanediol diacrylate, tetraethylene glycol diacrylate, neopentyl glycol diacrylate, triacrylic acid Pentaerythritol ester, neopentyl glycol tetraacrylate, di pentaerythritol diacrylate, di pentaerythritol hexaacrylate, sorbitol triacrylate, sorbitol tetraacrylate, sorbitol pentoxide, Sorbyl hexaacrylate, tris(propylene oxy)ethyl isocyanate, polyester acrylate oligomer, triacrylate modified with EO of isocyanuric acid, and the like. The methacrylates include: tetramethylene glycol dimethacrylate, triethylene glycol dimethacrylate, neopentyl glycol dimethacrylate, trimethylolpropane trimethacrylate, Trimethylolethane trimethacrylate, ethylene glycol dimethacrylate, 1,3-butylene glycol dimethacrylate, hexanediol dimethacrylate, neopentyl dimethacrylate Alcohol ester, trimethyl propylene-72- 200948906 acid pentaerythritol ester, neopentyl glycol tetramethacrylate, dineopentyl glycol dimethacrylate, dipentaerythritol hexamethacrylate, Sorbyl methacrylate, sorbitan tetramethacrylate, bis[p-(3-methylpropenyloxy-2-hydroxypropoxy)phenyl]dimethylmethane, bis-[pair- (Methacryloxyethoxyethoxy)phenyl]dimethylmethane or the like. Ikonic acid esters include: ethylene glycol di-conconate, propylene glycol di-conconate, 1,3-butylene glycol di-conconate, 1,4-butanediol di-conconate, Di-methylene glycol ester of ikonic acid, neopentyl glycol di-iconconate, Pilj tetracitol acid, and pear vinegar. The crotonate system includes ethylene glycol dicrotonate, tetramethylene glycol dicrotonate, neopentyl glycol dicrotonate, sorbitol tetrabutylate, and the like. The "isocrotonate" includes ethylene glycol diisocrotonate, neopentyl glycol diisocrotonate, and sorbitan tetraisocrotonate. "Maleate" includes: ethylene glycol maleate, triethylene glycol dimaleate, neopentyl glycol maleate, tetrabutylene Sorbitan diacetate and the like. Examples of the other esters are also suitable for use: for example, the aliphatic alcohol-based esters disclosed in Japanese Patent Application Laid-Open No. 51-47334, Japanese Laid-Open Patent Publication No. Hei 57- 1962 No. An aromatic skeleton disclosed in Japanese Laid-Open Patent Publication No. 59-5240, Japanese Patent Application Laid-Open No. 59-5241, and Japanese Patent Application Laid-Open No. Hei No. 2-22 6149 The amine-containing group or the like as disclosed in Japanese Laid-Open Patent Publication No. 1-1 65 613. In addition, the ester-based single system as described above can also be used as a mixture. Further, specific examples of the "aliphatic polyamine compound and the carboxylic acid-based amide monomer" include: Bis-propyleneamine, methylene bis-methyl-73- 200948906 acrylamide, 1,6-hexamethylenebis-propenylamine, 1,6-hexamethylenebis-methylpropene oxime Amine, di-ethyltriamine propylene amide, hydrazinyl bis acrylamide, hydrazinyl bis methacrylamide, and the like. Other examples of the preferred "melamine-based monomer" include those having a cyclohexylene structure as disclosed in Japanese Laid-Open Patent Publication No. Sho 54-2 1726. Further, a urethane-based addition polymerizable compound produced by an addition reaction of an isocyanate and a hydroxyl group is also suitably used, and specific examples thereof include, for example, by Japanese Patent Publication No. 48-4 The addition of a polyisocyanate compound having two or more isocyanate groups in one molecule as disclosed in the publication No. 1 708, which is obtained by the vinyl group-containing vinyl monomer represented by the following formula (a), contains two molecules in one molecule. One or more polymerizable vinyl vinyl urethane compounds and the like. General formula (a) CH2=C (R) COOCH2CH(R,)OH (However, R and R' each represent H or CH3.) Further, for example, Japanese Patent Laid-Open No. 51-37193, Japanese Invention The urethane acrylates disclosed in Japanese Patent Application Laid-Open No. Hei No. 2-1-2676, or Japanese Patent Application Laid-Open No. Hei No. 58-49860, Japanese Invention An oxirane-based skeleton disclosed in Japanese Patent Publication No. Sho 56-1 7654, Japanese Patent Application Laid-Open No. Hei. No. 62-3 94 No. 7, Japanese Patent No. 62-3 94 No. Carbamate compounds are also suitable. In addition, it is disclosed in Japanese Laid-Open Patent Publication No. SHO-63-277653, Japanese Laid-Open Patent Publication No. SHO-63-260909, and Japanese Patent Application Laid-Open No. Hei No. 1-105-23. In the case of an addition polymerizable compound having an amine structure or a sulfide structure in the molecule, it is also possible to obtain a photopolymerizable composition having a very excellent photosensitive rate depending on the case of 200948906. Other examples include, for example, those disclosed in Japanese Laid-Open Patent Publication No. 48-64183, Japanese Patent Application Laid-Open No. 49-4 3191, Japanese Patent Application Laid-Open No. 52-30490, and the like. A polyfunctional acrylate or methacrylate such as an epoxy acrylate obtained by reacting an ester acrylate or an epoxy resin with (meth)acrylic acid. In addition, specific unsaturated compounds as disclosed in Japanese Patent Application Laid-Open No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. No. Hei. The vinyl phosphonic acid-based compound or the like as disclosed in Japanese Laid-Open Patent Publication No. 2-2549-3. Further, in some cases, a structure containing a perfluoroalkyl group as disclosed in Japanese Laid-Open Patent Publication No. 61-22048 is also suitable. Also, it can be used as photocurability in Nippon Secchaku Kyokai Shi [Journal of the Adhesion Society of Japan], Vol. 20, No. 7, pp. 00 to 308 (1984). Monomers and oligomers. The details of the structure of the addition polymerizable compound, the structure thereof, and the method of using it alone, the amount of addition, and the like can be arbitrarily set with reference to the performance design of the final colored polymerizable composition. For example, it can be selected according to the viewpoint described below. From the viewpoint of "sensitivity", it is preferred that the structure in which the content of the unsaturated group per molecule is large, and in most cases, it is preferably a difunctional or higher. In addition, in order to improve the "strength of the cured film", it is preferably a trifunctional or higher functional group, and further has a different functional number and a different polymerizable group (for example, acrylate, methacrylate, styrene) Addition polymerization of a compound, a vinyl ether compound) - 75- 200948906 Compound, whereby a method of adjusting both sensitivity and strength is also effective. In addition, the compatibility and dispersibility with other components (for example, a binder polymer such as a bismuth soluble resin, a photopolymerization initiator, and a colorant (pigment)) in the colored polymerizable composition are additive polymerization properties. The selection of the compound and the method of use are important factors. For example, by using a low-purity compound or two or more types, it is also possible to obtain an increase in compatibility. Further, it is also possible to select a specific structure for the purpose of improving adhesion to a substrate or the like. The addition polymerizable compound is preferably used in an amount of from 5 to 70% by mass, more preferably from 10 to 60% by mass, based on the nonvolatile component in the colored polymerizable composition. Further, these may be used singly or in combination of two or more thereof. The method of using the addition polymerizable compound can arbitrarily select an appropriate structure, a blending amount, and the like from the viewpoints of the degree of polymerization resistance of oxygen, the degree of resolution, the degree of fogging, the change in refractive index, the surface tackiness, and the like. The amount added. [Photopolymerization Initiator] The photopolymerization initiator constituting the coloring polymerizable composition of the present invention includes, for example, a halomethyloxadiazole as disclosed in Japanese Laid-Open Patent Publication No. 60-3626. An active halogen compound such as a halogenated methyl-s-triazine trap disclosed in Japanese Laid-Open Patent Publication No. SHO-59-1 3 3428, and the like. An aromatic carbonyl compound such as a ketal, an acetal, or a benzoin alkyl ether, as disclosed in the specification of the U.S. Patent No. 4,318,791, the European Patent Application No. EP-88050, etc.; An aromatic compound of benzophenone or the like as disclosed in the specification of U.S. Patent No. 4,199,420; (thio) hydrazone or acridine compound as disclosed in the specification of French Patent No. Fr-2456741; A compound such as a fragrant sulphate or a spheroidal dimer of the genus 200948906, which is described in Japanese Laid-Open Patent Publication No. Hei 10-62 986, and the like. Boron complexes and the like. The photopolymerization initiator in the present invention is preferably an acetophenone-based, ketal-based, benzophenone-based, benzoin-based, benzamidine-based, ketone-based, or active halogen compound (trinitrogen). Tillage, oxadiazole, coumarin, acridine, biimidazole, oxime, and the like. The acetophenone-based photopolymerization initiator as described above includes, for example, preferably 2,2-diethoxyacetophenone, p-dimethylaminoacetophenone, 2-hydroxy-2- Methyl-1-phenyl-propan-1-one, p-dimethylaminoacetophenone, 4,-isopropyl-2.hydroxy-2-methyl-propiophenone, 1-hydroxycyclohexyl -Phenyl-ketone, '2-Benzyl-2-dimethylamino-1-(4-morpholinylphenyl)-butan-1-one, 2·Tolyl-2-dimethyl Amino-1-(4-morpholinylphenyl)-butan-1-one, 2-methyl-1-[4-(methylthio)phenyl]-2-morpholinylpropane-1- Ketones, etc. The ketal-based photopolymerization initiator as described above includes, for example, benzyldimethylketal, benzylmethoxyethylacetal and the like. The benzophenone-based photopolymerization initiator as described above includes, for example, preferably benzophenone, 4,4'-(bisdimethylamino)benzophenone, 4,4'- (Diethylamino) benzophenone, 4,4'-dichlorobenzophenone. The benzoin-based or benzamidine-based photopolymerization initiator as described above includes, for example, benzoin isopropyl ether, benzoin isobutyl ether, benzoin methyl ether, Methyl o-benzimidylbenzoate, etc. The Dill ketone photopolymerization initiator as described above includes, for example, diethyl thioxanthene, diisopropyl oxysulfuron, and the like. Isopropyl oxysulfonium, chlorothiazide, and the like. The active halogen compound (triazine well, oxadiazole system, fragrant-77-200948906 coumarin) as described above includes, for example, preferably 2,4-bis(trichloromethyl)-6 - p-methoxyphenyl-s-trinitrogen, 2,4-bis(trichloromethyl)-6•p-methoxystyryl-s-triazane, 2,4-dual ( Trichloromethyl)-6_(丨-p-dimethylaminophenyl)-1,3-butadienyl-s-trinitrogen, 2,4-bis(trichloromethyl)_6_ Phenyl-s-triazine trap 2,4-bis(trichloromethyl)-6-(p-methylbiphenyl)-s-trinitrogen, p-hydroxyethoxystyryl-2 ,6-bis(trichloromethyl)-s_trinitrogen, methoxystyryl-2,6-di(trichloromethyl)-3_trinitrogen, 3,4·dimethoxy Styryl-2,6-bis(trichloromethyl)-s-triazine trap, 4-benzooxolane-2,6-di(trichloromethyl)-3-trinitrogen, 4-(o-bromo-p--:^,:^-bis(ethoxycarbonylcarbonylamino)-phenyl)-2,6-di(chloromethyl)+trinitrogen, 4_ (p. , Ν-bis(ethoxycarbonylamino)-phenyl)-2,6-di(chloromethyl)-s·triazinium, 2-trichloromethyl-5-styryl-1,3 , 4- evil Diazole, 2-trichloromethyl-5-(cyanostyryl)-1,3,4-oxadiazole, 2-trichloromethyl-5-(naphthoquinone-1-yl)-1, 3,4-oxadiazole, 2-trichloromethyl-5 ·( 4·styryl)styryl-H4-oxadiazole, 3-methyl-5-amino-((s-triazo) Till-2-yl)amino)-3-phenylcoumarin, 3-chloro-5-diethylamino-((s-diazain-2-yl)amino)-3-phenyl Coumarin, 3-butyl-5-dimethylamino-((s-triazain-2-yl)amino)-3-phenylcoumarin. The acridine photopolymerization initiator as described above includes, for example, preferably 9-phenyl acridine, 1,7-bis(9-acridinyl)heptane or the like. The bisimidazole-based photopolymerization initiator as described above includes, for example, 2-(o-chlorophenyl)-4,5-diphenylimidazolyl dimer, 2-(o-A- Oxyphenyl)-4,5-diphenylimidazolyl dimer, 2-(2,4-dimethoxyphenyl)-4,5-diphenylimidazolyl dimer, and the like. In addition to the above, it also includes: 1-phenyl_1,2·propanedione·2·(o-78-200948906 ethoxycarbonyl) fluorene, o-benzylidene-4'-(benzene And thiol)benzimidyl-hexyl-ketooxime, 2,4,6-trimethylphenylcarbonyl-diphenylphosphine oxide, hexafluorophosphonyl-trialkylphenyl squarate salt and the like. The present invention is not limited to the photopolymerization initiator as described above, and other conventional ones may be used. For example, a vicinal polyketolaldonyl compound as disclosed in the specification of U.S. Patent No. 2,367,660; the a-carbonyl compound disclosed in the specification of U.S. Patent Nos. 2,367,661 and 2,367,670; The acetoin ethers disclosed in the above-mentioned U.S. Patent No. 2,448,828; the α-hydrocarbon-substituted aromatic acetoin compound as disclosed in the specification of U.S. Patent No. 2,722,512; The polynuclear oxime compound disclosed in the specification of U.S. Patent Nos. 3,046,127 and 2,95,758; the triallyl imidazole dimer disclosed in the specification of U.S. Patent No. 3,549,357 a benzothiazole compound/trihalomethyl-s-triazine trap compound as disclosed in Japanese Laid-Open Patent Publication No. 51-485-16 In JC S. Perkin II (1979), pp. 1,653 to 1,660, J. CS Perkin 11 (1979), pp. 156-162, "Journal of Photopolymer Science and Technology j (1952), 202 To 232 pages, the invention of this invention The oxime ester compound or the like as disclosed in Japanese Laid-Open Patent Publication No. 2000-66385. Further, these photopolymerization initiators can also be used. The content of the photopolymerization initiator in the coloring polymerizable composition is relatively The total solid content of the composition is preferably from 0.1 to 10.0% by mass, more preferably from 0.5 to 5.0% by mass. If the content of the photopolymerization initiator is within this range, the polymerization reaction proceeds smoothly to form strength. [Alkali-soluble resin] -79- 200948906 The colored polymerizable composition of the present invention is preferably an age-containing soluble resin. When the alkali-soluble resin is contained in the colored polymerizable composition, the coloring polymerization is carried out. When the composition is suitable for pattern formation by photolithography, the pattern formation property can be further improved. The alkali-soluble resin is a linear organic high molecular polymer and can be used in a molecule (preferably an acrylic copolymer) And an alkali-soluble resin having at least one base which promotes alkali solubility (for example, a carboxyl group, a phosphoric acid group, a sulfonic acid group, etc.) in the styrene-based copolymer as a main chain molecule Among these, it is more preferable that it is a product which is soluble in an organic solvent and can be developed with a weakly alkaline aqueous solution. The production of a phthalic acid-soluble resin can be applied, for example, by a conventional radical polymerization method. The polymerization conditions in the case where the alkali-soluble resin is produced by the polymerization method, the polymerization conditions of the type and amount of the radical initiator, the kind of the solvent, and the like can be easily set by those skilled in the art, and the conditions can also be set according to experiments. . The linear organic polymer is preferably a polymer having a carboxylic acid in a side chain. For example, Japanese Patent Laid-Open No. 59-44615, Japanese Invention Patent No. 54-3 43 27, Japanese Invention Patent No. 5 8-1 25 77, Japanese Invention Patent No. 54 A methacrylic acid copolymer, an acrylic copolymer, and a methacrylic acid copolymer, as disclosed in Japanese Laid-Open Patent Publication No. 59-53 836, Japanese Laid-Open Patent Publication No. 59-7 No. 1048, Ikonic acid copolymer, crotonic acid copolymer, maleic acid copolymer, partially esterified maleic acid copolymer, etc.; and an acidic cellulose derivative having a carboxylic acid in a side chain, A polymer obtained by adding a hydroxyl group of a hydroxyl group, etc., and a polymer having a (meth)acryloyl group in a side chain is also exemplified as -80 to 200948906. Among these, it is particularly preferably a benzyl (meth)acrylate/(meth)acrylic acid copolymer, or a benzyl (meth)acrylate/(meth)acrylic acid/other monomer. A multicomponent copolymer composed of. Others, which are obtained by copolymerization with 2-hydroxyethyl methacrylate, etc., are also useful examples. In addition to the above, other examples include: (meth)acrylic acid 2·hydroxypropyl propyl ester/polystyrene macromonomer as disclosed in Japanese Laid-Open Patent Publication No. Hei 7- 406 54 /Methyl methacrylate / methacrylic acid copolymer, 2-hydroxy-3-phenoxypropyl acrylate / polymethyl methacrylate macro monomer / benzyl methacrylate / methacrylic acid copolymerization , 2-hydroxyethyl methacrylate/polystyrene macromonomer/methyl methacrylate/methacrylic acid copolymer, 2-hydroxyethyl methacrylate/polystyrene macromonomer/A A benzyl acrylate/methacrylic acid copolymer or the like. The alkali-soluble resin which is particularly suitable for use in the present invention is a copolymer of (meth)acrylic acid and other monomers copolymerizable therewith. Here, the term "(meth)acrylic acid" is a generic term for a combination of acrylic acid and methacrylic acid, and hereinafter is also a generic term for (meth)acrylate-based acrylate and methacrylic acid ester. Other single systems copolymerizable with (meth)acrylic acid include: alkyl (meth)acrylate, aryl (meth)acrylate, vinyl compounds, and the like. Here, the hydrogen atom of the alkyl group and the aryl group may be substituted with a substituent. Specific examples of the alkyl (meth)acrylate and the aryl (meth)acrylate as described above include: methyl (meth)acrylate, ethyl (meth)acrylate, and (meth)acrylic acid Ester, butyl (meth) acrylate, (-81 - 200948906 methyl methacrylate), amyl (meth) acrylate, (meth) propyl hexanoate, octyl (meth) acrylate, ( Phenyl methacrylate, benzyl (meth) acrylate, toluene (meth) acrylate, naphthyl (meth) acrylate, cyclohexyl (meth) acrylate, and the like. Further, the "vinyl compound" as described above includes, for example, styrene, methyl styrene, vinyl toluene, glycidyl methacrylate, acrylonitrile, vinyl acetate, oxime-vinylpyrrolidone. , tetrahydrofuran methacrylate, polystyrene macromonomer, polymethyl methacrylate macromonomer, CH2 = CRiR2, CH2 = C (R1) (COOR3) [here, R1 represents hydrogen proton or carbon The number is 1 to 5 alkyl groups, R2 represents an aromatic hydrocarbon ring having 6 to 10 carbon atoms, and R3 represents an alkyl group having 1 to 8 carbon atoms or an aralkyl group having 6 to 12 carbon atoms. 〕Wait. These other single systems which can be copolymerized may be used alone or in combination of two or more. Preferred other copolymerizable single systems are selected from at least one of (^(R1)(COOR3), phenyl (meth)acrylate, benzyl (meth)acrylate, and ethylene, and particularly preferred CH2 = CWR2, and / or CH2 = C (R1) (COOR3). The content of the bismuth soluble resin in the colored polymerizable composition is preferably from 1 to 30% by mass based on the total solid content of the composition. It is preferably from 1 to 20% by mass, particularly preferably from 2 to 15% by mass. [Solvent] In general, the colored polymerizable composition of the present invention can be used by using the components as described above together with a solvent. It can be suitably prepared. Solvents which can be used include: esters, for example, ethyl acetate, acetic acid-n-82-200948906-butyl ester, isobutyl acetate, amyl formate, isoamyl acetate, isobutyl acetate Ester, butyl propionate, isopropyl butyrate, ethyl butyrate, butyl butyrate, alkyl esters, methyl lactate, ethyl lactate, methyl oxyacetate, ethyl oxyacetate, oxy Butyl acetate, methyl methoxyacetate, ethyl methoxyacetate, butyl methoxyacetate, methyl ethoxyacetate, B 3-oxopropionic acid alkyl esters such as ethyl acetate, methyl 3-oxypropionate, ethyl 3-oxypropionate; 3. Methyl methoxypropionate, 3-methoxy Ethyl propionate, methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, methyl 2-oxypropionate, ethyl 2-oxypropionate, sodium 2-oxypropionate Ester, methyl 2-methoxypropionate, ethyl 2-methoxypropionate, propyl 2-methoxypropionate, methyl 2-ethoxypropionate, 2-ethyl 2-ethoxypropionate Ester, methyl 2-oxo-2-methylpropanoate, ethyl 2-oxy-2-methylpropanoate, methyl 2-methoxy-2-methylpropanoate, 2-ethoxyl Ethyl 2-methylpropionate, methyl pyruvate, ethyl pyruvate, propyl pyruvate, methyl acetoxyacetate, ethyl acetoxyacetate, methyl 2-oxobutanoate, 2 - Ethyl acetoacetate or the like; ethers, for example, diethylene glycol dimethyl ether, tetrahydrofuran, ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, methyl sulphate acetate, acetic acid Ethyl sirolimus, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, diethylene glycol monobutyl ether, ethyl hexyl acetate, butyl hexyl acetate, acetic acid Glycol methyl ether ester, propylene glycol ethyl ether acetate, propylene glycol propyl ether acetate, etc.; ketones such as 'methyl ethyl ketone, cyclohexanone, 2 - heptanone, 3-heptanone, etc.; aromatic hydrocarbon For example, 'toluene, xylene (oxime), etc. Among them, preferred are methyl 3-ethoxypropionate, ethyl 3-ethoxypropionate, ethyl sarbutazone acetate, Ethyl lactate, diethylene glycol dimethyl acid, n-butyl acrylate, methyl 3-methoxypropionate, 2-heptanone, cyclohexanone, ethyl hexyl acetate, butyl hydrazine acetate The alcohol ester, the propylene glycol methyl ether acetate, etc. - 83 - 200948906 The solvent may be used alone or in combination of two or more. [Other components] The colored polymerizable composition of the present invention may contain, in addition to a sensitizing dye, an epoxy resin, a fluorine-based organic compound, a thermal polymerization initiator, a thermal polymerization component, a thermal polymerization inhibitor, or a ruthenium, if necessary. Various additives such as a polymer compound other than the alkali-soluble resin described above, a surfactant, an adhesion promoter, an antioxidant, an ultraviolet absorber, and an anti-aggregation agent. [Sensitizing dye] The colored polymerizable composition of the present invention may be added with a sensitizing dye as needed. The sensitizing dye can accelerate the radical generating reaction of the photopolymerization initiator or the like by the exposure of the wavelength which the sensitizing dye can absorb, or the polymerization reaction of the photopolymerizable compound as described above. Such sensitizing pigments include: conventional sensitizing dyes or dyes, or dyes or pigments that absorb light and interact with photopolymerization initiators. (Spectral sensitizing dye or dye) The preferred spectral sensitizing dye or dyeing system which can be used as the sensitizing dye of the present invention includes: polynuclear aromatics (for example, lanthanum, cerium, and terphenyl); Classes (eg, fluorescein, blush, red algae, rose red B, rose Bengal); cynins (eg, thiaquinoline blue, oxaquinoline blue); merocyanoids (eg, anthocyanins, carbonyl phthalocyanine stilettos (eg, thiazide, methylene blue, toluidine blue); acridines (eg, acridine orange, chloroflavin, acridine flavin); Anthraquinones (eg, anthracyclines, metal phthalocyanins); porphyrins (eg, tetraphenylporphyrin, porphyrin substituted with a central metal): chlorophylls (eg, chlorophyll, chlorophyllin, trans-center) Metals are -84-200948906 instead of chlorophyll); metal complexes (for example, compounds as described below); terpenoids (for example, hydrazine): horn shark keys (for example, horn shark keys) and the like.

More preferred examples of the spectrally sensitizing dye or dye include those described below. a cationic dye as disclosed in Japanese Laid-Open Patent Publication No. 62-143044; the quinoxaline gun salt disclosed in Japanese Laid-Open Patent Publication No. 59-24147; The novel methylene blue compound disclosed in Japanese Laid-Open Patent Publication No. 64-33104; the scorpion disclosed in Japanese Laid-Open Patent Publication No. SHO-64-56767; The benzoxanthene dyes disclosed in the Japanese Patent Publication No. 1714; the acridines disclosed in Japanese Laid-Open Patent Publication No. Hei No. 2-226148 and Japanese Patent Application Laid-Open No. Hei No. 2-226149; The sulfonium salt disclosed in Japanese Laid-Open Patent Publication No. 40-28499; the sei Ning class disclosed in Japanese Laid-Open Patent Publication No. SHO 46-42363; The benzofuran dye described in Japanese Laid-Open Patent Publication No. Hei No. 2-63053, Japanese Laid-Open Patent Publication No. Hei No. 2-85858, and Japanese Laid-Open Patent Publication No. Hei No. 2-216154 Japanese Patent Publication No. 57-10605 discloses The azo acin-based derivative disclosed in Japanese Laid-Open Patent Publication No. Hei. No. Hei. No. 2-30321, which is incorporated herein by reference. The coloring matter is disclosed in Japanese Laid-Open Patent Publication No. 62-3 1844, Japanese Patent Application Laid-Open No. Hei. No. Hei. No. 62-3 1 848, and Japanese Patent Laid-Open No. 62-14 3043.卩ill π galaxies; the amino styryl ketones disclosed in Japanese Laid-Open Patent Publication No. Sho 59-283, the entire disclosure of which is hereby incorporated by reference. An anthocyanin pigment, which is disclosed in Japanese Laid-Open Patent Publication No. Hei. No. 2-24405 0, and an anthocyanin pigment disclosed in Japanese Laid-Open Patent Publication No. 59-28326; An anthocyanin pigment disclosed in Japanese Laid-Open Patent Publication No. 59-8-9303; an anthocyanin pigment disclosed in Japanese Laid-Open Patent Publication No. 8-129257; The benzopyrazine system disclosed in Japanese Laid-Open Patent Publication No. 8-3 3 4 897 pigment. Ο (Pigments with a maximum absorption wavelength from 350 nm to 450 nm) Other preferred modes of sensitizing dyes include: those belonging to the following compound groups and having a maximum absorption wavelength from 350 nm to 450 rim. For example, polynuclear aromatics (eg, lanthanum, cerium, and terphenyl); 卩 唱 (eg, fluorescent yellow, blush, red algae, rose red B, rose beng (Rose Bengal)); Nings (for example, thiaquinoline blue, oxaquinoline blue); merocyanoids (for example, procyanidins, carbonyl anthocyanins); stilettos (for example, thiazide, methylene blue, toluidine blue) ); acridines (eg, acridine-86-200948906 orange, chloroflavin, acriflavine); terpenoids (eg, sputum); horn shark guns (eg, horn shark guns). More preferred examples of sensitizing dyes include: compounds represented by the following general formulae (XIV) to (XVIII)

〔 [In the general formula (XIV), A1 represents a sulfur atom or a NR6&lt;)-, R6e represents an alkyl group or an aryl group, and L01 represents an anionic core which forms a pigment together with adjacent A1 and carbon atoms (basic) The non-metal atomic group of nucleus, R61 and R62 each independently represent a hydrogen atom or a monovalent non-metal atomic group, and R61 and R62 may be bonded to each other to form an acid nucleus of the pigment. The W system represents an oxygen atom or a sulfur atom. Preferred specific examples of the compound represented by the formula (XIV) are shown in the following [(A-1) to (A-5)]. -87- 200948906

(A-l) (A-2)

General formula (XV)

[In the general formula (XV), Ar1 and Ar2 each independently represent an aryl group, and they are linked together by a bond of 1^2-. Here, the -I/2- system represents -〇- or -S-. Further, the W system is synonymous with those shown in the general formula (XIV). -88-200948906 A preferred example of the compound represented by the formula (??) includes [(A-6) to (A-8)] shown below.

❹ 〇

The table and the adjacent A2 and carbon atoms together form a non-metal atomic group of the basic nucleus of the pigment, and R63, R64, R65, R66, R67 and R68 each independently represent a base of a monovalent non-metal atomic group, and R69 represents an alkyl group. Or aryl. Preferred examples of the compound represented by the formula (XVI) include: [(A-9) to (A-11)] as shown below. 200948906

[In the general formula (XVII), A3 and A4 each independently represent _s-, or a NR73-, R73 is a substituted or unsubstituted alkyl group, or a substituted or unsubstituted aryl group, Le4 And LQ5 each independently represents a non-metal atomic group which forms a basic nucleus of a pigment together with adjacent A3, A4 and a carbon atom, and R71 and R72 each independently represent a monovalent non-metal atomic group, and may also be bonded to each other. A ring which forms an aliphatic or aromatic ring.] Preferred examples of the compound represented by the formula (XVII) include: [(A-12) to (A-15)] shown below. -90- 200948906

(A-1 2) (A-1 2)

(A-l 4) (A-1 5) lit# ' gffeW Preferred sensitizing dyes for use in the present invention include: those represented by the following formula (XVIII). O R75

[In the formula (XVIII), A5 represents an optionally substituted aromatic ring or heterocyclic ring, and x represents an oxygen atom, a sulfur atom, or —N(R74)—, Y represents an oxygen atom, a sulfur atom, or = N(R74). R74 and R75' R76 each independently represent a hydrogen atom 'or a monovalent non-metal atomic group, and A5 and R74, R75 and r76 may each bond to each other to form an aliphatic or aromatic ring. Here, when R74, R75 and R76 represent a monovalent non-metal atomic group, it preferably represents a substituted or unsubstituted alkyl or aryl group. -91 - 200948906 Next, preferred examples of R74, R75, and R76 are specifically described below. Examples of preferred alkyl groups include linear, branched, and cyclic alkyl groups having 1 to 20 carbon atoms, and specific examples thereof include methyl group, ethyl group, and propyl group. Butyl, pentyl, hexyl, heptyl, octyl, decyl, decyl, eleven, decyl, thirteen, hexadecyl, octadecyl, decyl, isopropyl, isobutyl Base, secondary-butyl, tert-butyl, isopentyl, neopentyl, 1-methylbutyl, isohexyl, 2-ethylhexyl, 2-methylhexyl, cyclohexyl, cyclopentyl , 2-norborne base. Among these, a linear chain having a carbon number of 1 to 12, a branch having 3 to 12 carbon atoms, and a cyclic alkyl group having 5 to 10 carbon atoms are more preferable. The substituent of the substituted alkyl group is a group of a monovalent non-metal atomic group other than a hydrogen atom, and preferred examples thereof include a halogen atom (-F, -Br, -C1, -I), Alkyl, alkoxy, aryloxy, chlorothio, alkylthio, arylthio, alkyldithio, aryldithio, amine, N-alkylamino, N, N _Dialkylamino, N-arylamino, N,N-diarylamine, N-alkyl-N-arylamine, decyloxy, aminemethyloxy, N-alkyl Aminomethyl methoxy, N-arylamine methyl methoxy, N,N-dialkylamine methyl methoxy, N,N-^diarylamine methyloxy, N-alkyl-N- Arylamine methyl methoxy, alkyl sulfoxy, aryl sulfoxy, sulfonylthio, decylamino, N-alkyl decylamino, N-aryl decylamino, ureido, N-alkylureido, N,N-dialkylureido, N-arylureido, N,N-diarylureido, N-alkyl-N-arylureido, N-alkyl -N-alkylureido' N,N-dialkyl-N-alkylureido, N,N-dialkyl-N-arylureido, N-aryl-N-alkylureido, N-aryl-N-arylureido, N,N-diaryl-N-alkane Urea, N,N-diaryl-N-arylureido, N-alkyl-N-aryl-N-alkylureido, N-alkyl-N-aryl-N-arylurea Alkoxycarbonylamino group, aryloxy-92- 200948906 carbonylcarbonylamino group, N-alkyl fluorene-alkoxycarbonylamino group, N-alkyl-N-aryloxycarbonylamino group, N- Aryl-N-alkoxycarbonylamino, N-aryl-N-aryloxycarbonylamino, decyl, fluorenyl, carboxy, alkoxycarbonyl, aryloxycarbonyl, aminemethanyl, N-alkylamine, mercapto, N,N-dialkylamine, mercapto, N-arylamine, N,N-diarylamine, N-alkyl-N-aryl a sulfhydryl group, a benzyl sulfonyl group, an aryl sulfinyl group, a fluorenyl group, an aryl sulfonyl group, a sulfonic acid group (-SO3 Η), and a conjugated thiol group thereof (hereinafter , referred to as sulfonate), alkoxysulfonyl, aryloxysulfonyl, amine sulfinyl, decane-alkyl sulfinyl, hydrazine, hydrazine-dialkylamine sulfin Indenyl, fluorene-arylamine sulfinyl, anthracene, fluorene-diarylamine sulfinyl, hydrazine-alkyl hydrazine arylsulfinyl, sulfonyl, fluorenyl Aminesulfonyl, hydrazine, hydrazine-dialkylamine Anthracenyl, fluorenyl-arylamine sulfonyl, anthracene, fluorenyl-diarylamine sulfonyl, hydrazine-alkyl-hydrazine-arylsulfonyl, phosphonic acid (-Ρ〇3Η2) and Conjugated thiol group (hereinafter referred to as phosphonate group), dialkylphosphonic acid group (-Ρ〇3(alkyl) 2), diarylphosphonic acid group (-Ρ〇3 (aryl) 2 ), an alkylarylphosphonic acid group (monoindole (aryl) (aryl)), a monoalkylphosphonic acid group (-Ρ〇3Η (alkyl)) and its conjugated base (in _ Hereinafter, it is referred to as "alkylphosphonate"), an arylphosphonic acid group ("ρ〇3η (aryl)), and a conjugated test thereof (hereinafter, referred to as an arylphosphonate group) , a phosphonic acidoxy group (-〇ρ〇3Η2) and a conjugated base thereof (hereinafter, referred to as a phosphonateoxy group), a dialkylphosphonic acidoxy group (-〇Ρ〇3 ( Alkyl) 2), diarylphosphonic acidoxy (-〇Ρ〇3(aryl) 2), alkylarylphosphonic acidoxy (-indole 3 (alkyl) (aryl) a monoalkylphosphonic acidoxy group (monomethylphosphonyloxy group) and its conjugated base (hereinafter referred to as an alkylphosphonateoxy group) , an arylphosphonic acid oxy group (-0Ρ03Η(aryl)) and a conjugated fluorenyl group thereof (hereinafter referred to as arylphosphonate-93-200948906 oxy group), a cyano group, a nitro group, Among the substituents, an aryl group, a heteroaryl group, an alkenyl group, an alkynyl group, a decyl group, and a specific example of the alkyl group include the alkyl group as described above, and these groups may further have a substituent. Further, specific examples of the aryl group in the substituent of the substituted alkyl group as described above include: phenyl, biphenyl, naphthyl, tolyl, fluorenyl, lysyl, cumyl, chlorobenzene Base, bromophenyl, chloromethylphenyl, hydroxyphenyl, methoxyphenyl, ethoxyphenyl, phenoxyphenyl, ethoxylated phenyl, benzhydryloxyphenyl, A Thiopylphenyl, phenylthiophenyl, methylaminophenyl, dimethylaminophenyl, ethionylaminophenyl, carboxyphenyl, methoxycarbonylphenyl, ethoxy Phenylcarbonyl, phenoxycarbonylphenyl, N-phenylamine, mercaptophenyl, phenyl, cyanophenyl, sulfophenyl, sulfonylphenyl, phosphophenyl, phosphonic acid Base phenyl and the like. The heteroaryl group in the substituent of the substituted alkyl group as described above is a group derived from a monocyclic or polycyclic aromatic ring containing at least one of nitrogen, oxygen and sulfur atoms, particularly preferably a hetero group. Examples of the heteroaryl ring in the aryl group include, for example, thiophene, thianthrene, furan, piper, isobenzofuran, chromene, cucurbit, morphine, pyrrole, Pyrazole, isosazole, isoxazole, pyrimidine, pyrimidine, sorghum, sputum trap, isoindole, indole, carbazole, hydrazine, salivation, isoquinoline, argon, naphthalene Pyridine, quinazoline, cinnoline, dish steep, miso, morphine, phenanthrene, phlegm, pharyngeal (perimidine), morphine, guanidine, Phenosazine, furazan, etc.; and these may be further benzo ring-condensed or may have a substituent. Further, examples of the "olefin 200948906 group" in the "substituent of the substituted alkyl group" as described above include: vinyl group, i-propenyl group, i-butenyl group, cinnamyl group (cinnamyl group), 2 -Chloro-1-vinyl group or the like; further, examples of the "alkynyl group J" in the "substituent of the substituted alkyl group" as described above include: ethynyl group, 1-propynyl group, 1-butynyl group And a trimethylsilyl ethynyl group, etc. The G1 system in the fluorenyl group (Gko-) includes a hydrogen atom, and an alkyl group or an aryl group as described above. Here, the substituent of the substituted alkyl group is used. Further, more preferably: a halogen atom ("F, _Br, - Cl, - I), an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an N-alkylamino group, N, N-dialkylamino, decyloxy, N-alkyl-based amine methoxycarbonyl, N-arylamine methyl methoxy, decylamino, decyl, decyl, carboxy, alkoxy Carbonyl, aryloxycarbonyl, aminemethanyl, N-alkylamine, fluorenyl, N,N-dialkylamine, fluorenyl, N-arylamine, N-alkyl-N-aryl Base amide, sulfonate, sulfonate, sulfonate, N-alkane Amine sulfonyl, N,N-dialkylamine sulfonyl, N-arylamine sulfonyl, N-alkyl-N-arylamine sulfonyl, phosphonic acid, phosphonate, two Alkylphosphonic acid group, diarylphosphonic acid group, monoalkylphosphonic acid group, alkylphosphonic acid group, monoarylphosphonic acid group, arylphosphonic acid group, phosphonic acidoxy group, phosphonic acidoxy group , aryl, alkenyl. Specific examples of the preferred substituted alkyl group as R74, R75, or R76 obtained by combining the substituent and the alkylene group as described above include: chloromethyl, bromomethyl, 2-chloroethyl Base, trifluoromethyl, methoxymethyl, methoxyethoxyethyl, allyloxymethyl, phenoxymethyl, methylthiomethyl, tolylmethyl, ethylamine Ethyl ethyl, diethylaminopropyl, morpholinylpropyl, ethoxymethyloxy, benzhydryloxymethyl, N-cyclohexylaminemethyloxyethyl, N-phenylamine Methoxyethyl, ethyl hydrazinoethyl, N-methylbenzhydrylaminopropyl, 2· ethoxyethyl, 2-sided oxypropyl, carboxypropyl, methoxy Carbocarbonylethyl, allyloxycarbonylbutyl, chlorophenoxycarbonylmethyl, amine methyl-95- 200948906 mercaptomethyl, N-methylamine-mercaptoethyl 'N,N-dipropyl Aminomethylmethyl, N-(methoxyphenyl)amine,carboxyethyl, N-methyl-N-(sulfonylphenyl)amine,carboxymethyl, sulfonylbutyl, Sulfonic acid propyl, sulfonyl butyl, sulfonyl butyl, N-ethylamine sulfonylmethyl, hydrazine , Ν·dipropylamine sulfonylpropyl, fluorenyl-tolylamine sulfonylpropyl, hydrazine-methyl-hydrazine-(phosphonophenyl)amine sulfonyl octyl, phosphonic butyl , phosphonate hexyl, diethylphosphonic butyl, diphenylphosphonic propyl, methylphosphonic butyl, methylphosphonic butyl, tolylphosphonic hexyl, tolyl phosphine Acid radical hexyl, phosphonooxypropyl, phosphonate oxybutyl, benzyl, phenethyl, α-methyl phenylmethyl, 1-methyl-1-phenylethyl, p- -methylbenzyl, cinnamyl (cinnamate), allyl, 1-propenylmethyl, 2·butenyl, 2-methylallyl, 2-methylpropenylmethyl, 2- Propynyl, 2-butynyl, 3-butynyl and the like. Specific examples of the preferred aryl group as R74, R75, or R76 include a condensed ring formed by one to three benzene rings, and a condensed ring formed by a benzene ring and a 5-membered unsaturated ring. And specific examples thereof include: phenyl, naphthyl, anthracenyl, phenanthryl, benzyl, naphthyl (dihydrophthenyl group), fluorenyl; among these, more preferably Phenyl, naphthyl.具体 Specific examples of the preferred substituted aryl group as R74, R75, or R76 include, as a substituent, a group having a monovalent non-metal atom group (other than a hydrogen atom) on a carbon atom forming a ring. Examples of preferred substituents of the above-mentioned aryl group include: an alkyl group as described above, a substituted alkyl group, and the exemplified above with respect to the substituent of the substituted alkyl group. Preferred specific examples of such substituted aryl groups include: biphenyl, tolyl, fluorenyl, decyl, cumyl, chlorophenyl, bromophenyl, fluorophenyl, chloromethylbenzene , trifluoromethylphenyl, hydroxyphenyl, methoxyphenyl, methoxyethoxyphenyl-96- 200948906, allyloxyphenyl, phenoxyphenyl, methylthiobenzene Base, tolylphenylthio, ethylaminophenyl, diethylaminophenyl, morpholinylphenyl, ethoxylated phenyl, benzhydryloxyphenyl, N-cyclohexylamine a nonyloxyphenyl group, an N-phenylamine methyl methoxy phenyl group, an ethyl decyl phenyl phenyl group, an N-methyl benzoguanidino phenyl group, a carboxy phenyl group, a methoxycarbonyl phenyl group, Allyloxycarbonylphenyl, chlorophenoxycarbonylphenyl, amine-mercaptophenyl, N-methylamine-methylphenyl, N,N-dipropylamine-methylphenyl, N- (Methoxyphenyl)amine,nonylphenyl, N-methyl-N-(sulfonylphenyl)amine,nonylphenyl, sulfonic acid phenyl, sulfonate, β-phenyl, amine sulfonate Nonylphenyl, N-ethylaminesulfonylphenyl, n,N-dipropylaminesulfonylphenyl, N.A Amidoximeylphenyl, N.methyl-N-(phosphonophenyl)amine sulfonylphenyl, phosphonic phenyl, phosphonate phenyl, diethylphosphonic phenyl, Diphenylphosphonic phenyl, methylphosphonic phenyl, methylphosphonic phenyl, tolylphosphonic phenyl, tolylphosphonyl phenyl, allyl phenyl, 1-propene Phenylmethyl, 2-butenylphenyl, 2-methylallylphenyl, 2-methylpropenylphenyl, 2-propynylphenyl, 2-butynylphenyl, 3 - Butynylphenyl and the like. @ Further, further preferred examples of R75 and R76 are substituted or unsubstituted alkyl groups. Further, further preferred examples of R74 are substituted or unsubstituted aryl groups. Although the reason is not clear, it is presumed that due to such substituents, the interaction between the electron-excited state due to light absorption and the initiator compound is particularly enhanced, and the initiator compound is raised to generate free radicals, acids or The reason for the efficiency of 鹸. Next, A5 in the general formula (XVIII) will be described. A5 represents an aromatic ring or a heterocyclic ring which may have a substituent, and specific examples of the aromatic ring or heterocyclic ring which may have a substituent include R74-97-200948906, R75 which have been in the formula (XVIII) The same as those exemplified in the foregoing description of R76 or R76. Among them, a preferred A5 group includes an aryl group having an alkoxy group, an alkylthio group or an amine group, and a particularly preferred A5 group includes an aryl group having an amine group. Next, the Y in the general formula (XVIII) will be described. Y is directly bonded to a non-metal atom of a nitrogen-containing heterocyclic ring in the formula (XVIII) via a double bond or

A non-metal atomic group, more specifically, an oxygen atom, a sulfur atom, or =N (R74). Here, R74 represents a hydrogen atom or a monovalent non-metal atom 〇 In addition, X in the formula (XVIII) represents an oxygen atom, a sulfur atom, © or a N(R74)_. The R74 system is synonymous with the case of Y. Next, a preferred mode of the compound represented by the formula (XVIII) used in the present invention will be described by a compound represented by the formula (XVIII-1).

In the above formula (XVIII-1), A5 represents an aromatic ring or a heterocyclic ring which may have a substituent, and X represents an oxygen atom, a sulfur atom, or -N(R74)-. R74, R77 and R78 are each independently a hydrogen atom or a monovalent non-metal atomic group, and A5 and R74, R77 and R78 may each be bonded to each other to form an aliphatic or aromatic ring. The Ar system represents "an aromatic ring or a heterocyclic ring having a substituent". However, the sum of the substituents on the Ar skeleton is Hammett's -98-200948906 substituent constant, which must be greater than zero. The sum of the so-called Harman's sputum is greater than the lanthanide means that it may have one substituent and the Harmantel 该 of the substituent is greater than 〇, or has a plurality of substituents and is substituted herein. The sum of Mante's is greater than zero. In the formula (XVIII-1), A5 and R74 are synonymous with the formula (XVIII), and R77 is the same as R75 and R78 in the formula (XVIII) and R76 in the formula (XVIII). Synonymous. Further, the Ar group represents an aromatic ring or a heterocyclic ring having a substituent, and is synonymous with A5 in the formula (XVIII). However, the substituent which can be introduced into Ar in the formula (XVIII-1) must be a total of hamant, and examples of such substituents include: trifluoromethyl, carbonyl , an ester group, a halogen atom, a nitro group, a cyano group, a ruthenium group, a guanamine group, a carboxyl group, and the like. The Hammant oxime of these substituents is as follows: trifluoromethyl (a CF3, m: 0·43, ρ: 0.54), a carbonyl group (e.g., a COH 'm: 0.36, ρ: 0.43), an ester group. (a COOCH3, m: 0.37 'p: 0.45), a halogen atom (for example, Cl, m: 0.37, p: 0.23), a cyano group (-CN, m: 0.56, p: 0.66), an anthracene group (for example, a SOCH3) m: 0.52, p: 0.45), amidino group (for example, one NHCOCH3, m: 0.21, p: 0.00), a carboxyl group (one COOH, m: 0.37, ρ: 0·4 5), and the like. The parentheses indicate the introduction position of the substituent in the aryl skeleton, and the Harmant 値, for example, (m: 0·50) indicates that the substituent is introduced into the meta position. The feature is 0.50. Among them, preferred examples of Ar include a phenyl group having a substituent, and preferred substituents on the Ar skeleton include an ester group and a cyano group. The position of the substitution is particularly preferably an ortho position on the Ar skeleton. ο Hereinafter, a preferred specific example of the sensitizing dye represented by the general formula (XVIII) of the present invention -99-200948906 will be shown. [Example compound (F1) to exemplified compound (F56)], but the present invention is not limited thereto. (F1) (F2)

(F9)

〇

(F10)

-100- 200948906

(F12) (F13)

-101 200948906

-102- 200948906

(F33) (F34)

(F35) (F36)

103- 200948906 (F40) (F39)

Ph (F41) OMe

(F44)

-104- 200948906

-105- 200948906 (F49)

(F51)

106- 200948906 〔化41〕 (F54) (F53)

(F56)

In the sensitizing dye as described above, it is preferably a compound represented by the formula (XVIII) as shown in the above, from the viewpoint of deep curing property. With regard to the sensitizing dye as described above, various chemical modifications described below can be carried out for the purpose of improving the properties of the colored polymerizable composition of the present invention. For example, a sensitizing dye and an addition polymerizable compound structure (for example, an acrylonitrile group or a methacryl oxime group) are bonded by a covalent bond, an ionic bond, a hydrogen bond or the like, whereby cross-linking hardening can be obtained. The film is made to have high strength, or to enhance the unnecessary precipitation effect of the pigment from the crosslinked cured film. The content of the sensitizing dye is preferably from 〇1 to 20% by mass, more preferably from 0_01 to 10% by mass, still more preferably from 0.1 to 5% by mass, based on the total solid content of the colored polymerizable composition. If the content of the sensitizing dye is in this range, the exposure wavelength for the ultrahigh pressure mercury lamp can be obtained with high sensitivity, and the curability of lower layer portion can be obtained while developing margin (development margin) ), pattern formation is also preferred. -107-200948906 (Epoxy Resin) The colored polymerizable composition of the present invention can use an epoxy resin as a thermal polymerization component in order to increase the strength of the formed coating film. The epoxy resin is a compound having two or more epoxy rings in the molecule, such as a bisphenol A type, a cresol novolak type, a biphenyl type, or an alicyclic epoxy compound. For example, the bisphenol A type includes: EPOTOHTOYD-U5, YD-118T, YD-127, YD-128, YD-134, YD-8125, YD-7011R, ZX-1059, YDF-8 170, YDF-170, etc. (The above is Dongdu Huacheng Co., Ltd. ( Tohto Kasei Co., Ltd.): DENACOL EX-1101, EX-1102, EX-1103, etc. (The above is manufactured by Nagase ChemteX Corporation); PLACCEL GL-61, GL-62 , G101, G102 (The above is manufactured by DAICEL Chemical Industry Co., Ltd.): In addition to this, other include: bisphenol F. type and bisphenol S type similar to these. Further, an epoxy acrylate such as Ebecryl 3700, 3 70 1, 600 (the above is manufactured by DAICEL-UCB Co., Ltd.) can also be used. The cresol novolac type includes: EPOTOHTO YDPN-63 8, YDPN-701, YDPN-702, YDPN-703, YDPN-704, etc. (The above is manufactured by Dongdu Chemical Co., Ltd.); DENACOL EM-125, etc. Made by Suihua Cheng Industrial Co., Ltd.). The biphenyl type includes 3,5,3',5'-tetramethyl-4,4'-diglycidylbiphenyl and the like. The alicyclic epoxy compounds include: CELLOXIDE 2021, 208 1, 2 0 8 3, 2 0 8 5, EP OLE AD GT-3 0 1 , GT-302, GT-401, GT-403, EHPE-3150 ( The above is manufactured by DAICEL Chemical Industry Co., Ltd.); SUNTOHTO ST-3000, ST-4000, ST-5080, ST-5100, etc. (The above is manufactured by Dongdu Chemical Co., Ltd. 200948906); Epiclon 430, 673, 695, 850S, 4032 (The above is manufactured by Dainippon Ink and Chemicals, Inc.). In addition, 1,1,2,2-indole (p-glycidoxyphenyl)ethane, ginseng (p-glycidoxyphenyl)methane, triglycidyl isocyanurate can also be used. Para-hydroxyethyl ester, diglycidyl phthalate, diglycidyl terephthalate; EPOTOHTO YH-434, YH-434L of amine epoxy resin; bisphenol A epoxy A glycidyl ester modified by introducing a dimer acid into the skeleton of the resin. Among these, it is preferred that the "molecular weight/number of epoxy groups" is 1 Å or more, and more preferably 130 to 500. When the "molecular weight/number of epoxy groups" is small, the hardenability is high, and the shrinkage at the time of curing is large. When the temperature is too large, there is a concern that the curability is insufficient, the reliability is poor, and the flatness is deteriorated. Specific preferred compounds include: EPOTOHTO YD-1 15, 118T, 127, YDF-170, YDPN-63 8, YDPN-701; PLACCEL GL-61, GL-62; 3, 5, 3', 5'- Tetramethyl-4,4'-diglycidylbiphenyl; CELLOXIDE 2021, 2081, EPOLEAD GT-302, GT-403, EHPE-3 1 50, and the like. (Fluorine-based organic compound) The colored polymerizable composition of the present invention contains a fluorine-based organic compound to improve liquid properties (particularly fluidity) when it is used as a coating liquid, and to improve uniformity of coating thickness or liquid-saving property. In other words, the colored polymerizable composition containing a fluorine-based organic compound can reduce the surface tension between the surface to be coated and the coating liquid, thereby improving the wettability to the coated surface and improving the coated surface. In the case of forming a film of about Am in a small amount of liquid, it is possible to form a film having a uniform thickness having a small thickness unevenness. The fluorine content in the fluorine-based organic compound is preferably from 3 to 40% by mass, more preferably from 5 to 30% by mass, particularly preferably from 7 to 25% by mass. When the fluorine content is in this range, it is effective from the viewpoint of coating thickness uniformity or liquid-saving property, and is also excellent in solubility in the composition. "Fluorine-based organic compounds" include, for example, MEGAFAC F171, F1 72 &gt; F173, F177, F141, F142, F143, F144, R30, F437 (above is manufactured by Dainippon Ink Chemical Industry Co., Ltd.); FLUORAD FC43 0 , FC43 1, FC 1 7 1 (above is Sumitomo 3 M Limited); SURFLON S-3 82, SC-1 0 1, SC-103, SC-104, SC-105, SC1068, SC-381, SC-383, S393, KH-40 (above is manufactured by Asahi Glass Co., Ltd.). In particular, when a colored coating composition of the present invention is used to form a thin coating film, the fluorine-based organic compound can effectively prevent uneven coating or uneven thickness. Further, it is also effective to apply the colored polymerizable composition of the present invention to the slit coating which is liable to cause liquid breakage. The amount of the fluorine-based organic compound added is preferably 0.001 to 2% by mass, more preferably 0.005 to 1.0% by mass based on the total weight of the coloring polymerizable composition. 热 (Thermal polymerization initiator) The coloring polymerizable composition of the present invention The measures containing the thermal polymerization initiator are also effective. The "thermal polymerization initiator" includes, for example, various azo compounds 200948906 and a peroxide compound. The "azo compound" includes an azobis compound; the "peroxide compound" includes: a ketone peroxide, a peroxyketal, a hydrogen peroxide, a dialkyl peroxide, and a dioxane. A base peroxide, a peroxy ester, a peroxydicarbonate, and the like. (Interacting Agent) In the colored polymerizable composition of the present invention, various surfactants may be added from the viewpoint of improving coatability. The surfactant may be a non-ionic, cationic or anionic surfactant other than the fluorine-based surfactant as described above. Among them, the fluorine-based surfactant is preferably a nonionic surfactant or a nonionic surfactant having a perfluoroalkyl group as described above. Specific examples of the fluorine-based surfactant include the MEG AFACE (registered trademark) series manufactured by Dainippon Ink Chemical Industry Co., Ltd., and the FLUORAD (registered trademark) series manufactured by Sumitomo 3M Co., Ltd., and the like. Further, specific examples of the cationic surfactant include: indigo derivatives (commercially available EFKA-745 (manufactured by EFKA Additives, Inc.)); organic sand oxides (Organo) Siloxane Polymer ) KP341 (manufactured by Shin-Etsu Chemical Co., Ltd.); (meth)acrylic (co)polymer POL YFLOW No. 75, No. 90, No. 95 ( Kyoeisha Chemical Co., Ltd. manufactured by Kyoeisha Chemical Co., Ltd.; W001 (manufactured by Bodo M6ller Chemie GmbH). Specific examples of the nonionic surfactant include: polyoxyethylene lauryl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxy-111-200948906 ethylene octyl phenyl ether, poly Ethylene oxide nonylphenyl ether, polyethylene dilaurate, ethylene glycol distearate, dehydrated sorbitol fatty acid ester; PLURONIC L1 0, L3 1, manufactured by BASF Corporation L61, L62, 10R5, 17R2, 25R2, TETRONIC 304, 701, 704, 901, 904, 150R1, and the like. In addition, specific examples of the anionic surfactant include: W004, W00 5, W017 (manufactured by Yushang Co., Ltd.) and the like. (Other Additives) In addition to the above, the coloring polymerizable composition of the present invention may be added with various additives. Specific examples of the additive include: a filler of glass, alumina, etc.; an itaconic acid copolymer, a crotonic acid copolymer, a maleic acid copolymer, a partially esterified maleic acid copolymerization An alkali-soluble resin such as a substance, an acidic cellulose derivative, a polymer addition anhydride having a hydroxyl group, an alcohol-soluble nylon, a phenoxy resin formed of bisphenol A and epichlorohydrin; EFKA-46, EFKA -47, EFKA-47EA, EFKA Polymer 100, EFKA Polymer 400, EFKA Polymer 401, EFKA Polymer 450 (above is manufactured by Morishita Industrial Co., Ltd.) and other "polymer dispersants"; SOLSPERSE 3000, 5000, 9000, 12000, 1 3240 &gt; 1 3940, 17000 ' 24000 ' 26000 ' 28000 and other various SOLSPERSE dispersants (The Lubrizol Co., Ltd.); Adekapluronic L3 1, F38, L42, L44, L61, L64, F68, L72, P95, F77, P84, F87, P94, L101, P103, F108, L121, P-1 23 (manufactured by Adeka Corporation); and IONET S-20 (Sanyo Chemical Industrie) s Co., Ltd.)); 2-( 3 -tris-butyl-5-112-200948906 methyl-2-hydroxyphenyl)-5-chlorobenzotriazole, alkoxydiphenyl An ultraviolet absorber such as ketone or the like; and an anti-aggregating agent such as sodium polyacrylate. Further, when it is desired to promote the alkali solubility of the uncured portion and to further improve the developability of the coloring polymerizable composition, it is preferred to add an organic carboxylic acid to the colored polymerizable composition of the present invention. It is a low molecular weight organic carboxylic acid having a molecular weight of 1,000 or less. Specifically, for example, formic acid (formic acid), acetic acid (acetic acid), propionic acid, butyric acid (butyric acid), shikimic acid (valeric acid), trimethylacetic acid, caproic acid, di-ethyl acetate, heptanoic acid, caprylic acid Aliphatic monocarboxylic acids: oxalic acid (oxalic acid), malonic acid, succinic acid (succinic acid), glutaric acid, adipic acid, pimelic acid, suberic acid, azelaic acid, lipoic acid (sebacic acid), barium diacid (tridecanedioic acid), methylmalonic acid, ethylmalonic acid 'dimethylmalonic acid, methyl succinic acid, tetramethyl succinic acid, citraconic acid An aliphatic dicarboxylic acid; an aliphatic tricarboxylic acid such as 1,2,3-propanetricarboxylic acid, aconitic acid or oxalic acid: benzoic acid (benzoic acid), o-toluic acid, and cumin "Aromatic monocarboxylic carboxylic acid" such as acid (p-isopropylbenzoic acid), 2,3-dimethylbenzoic acid or 3,5-dimethylbenzoic acid; phthalic acid, isophthalic acid, Terephthalic acid, trimellitic acid (1,2,4-benzenetricarboxylic acid), trimesic acid (1,3,5-benzenetricarboxylic acid), pyromellitic acid (1,2,3,5- Pyromellitic acid), pyromic acid (1, 2 "Aromatic polycarboxylic acid" such as 4,5-benzenetetracarboxylic acid): phenylacetic acid, hydrogen atoic acid, hydrogen cinnamic acid, mandelic acid (phenylglycolic acid), phenylsuccinic acid, atopic acid, A carboxylic acid such as cinnamic acid, methyl cinnamate, benzyl cinnamate, cinnaminoacetic acid, coumaric acid, and valeric acid. In addition, in the colored polymerizable composition of the present invention, a thermal polymerization inhibitor-113-200948906 may be added, and a thermal polymerization inhibitor may be used, for example, hydroquinone or p-methoxyphenol. Di-tertiary-butyl-p-cresol, gallicol, tert-butylcatechol, benzoquinone, 4,4'-thiobis(3-methyl-6-tertiary-butylphenol ), 2,2'-methylenebis(4-methyl-6-tertiary-butylphenol), 2-hydrothiobenzimidazole, and the like. The colored polymerizable composition of the present invention is characterized in that a photopolymerizable compound, a photopolymerization initiator, a further alkali-soluble resin or a solvent, and a surfactant are added to the pigment dispersion composition of the present invention as described above. Etc.著 The colored polymerizable composition of the present invention contains the pigment dispersion composition of the present invention, and the pigment contained as a colorant has excellent dispersion stability. Further, by using the colored film obtained by using the colored polymerizable composition of the present invention, since the color material is uniformly and stably dispersed, the contrast is high and the surface smoothness is excellent. Therefore, the colored polymerizable composition of the present invention is preferably a colored region for forming a color filter. &lt;Color filter, and method of producing the same&gt; The color filter of the present invention is characterized in that it has a colored pattern formed on the substrate using the colored polymerizable composition of the present invention as described above. . Hereinafter, the color filter of the present invention and the method of producing the same (the method of producing the color filter of the present invention) will be described in detail. The color filter of the present invention is characterized in that it is coated on a substrate to form a film of the colored polymerizable composition of the present invention, and preferably prebaking, second exposure, and development are sequentially performed. By such a method, it is possible to manufacture a color filter which can be used for a liquid crystal display element or a solid-state image pickup element with less difficulty in the process and at a low cost with high quality and -114-200948906. Hereinafter, each step will be described in detail. [Coating] In the present invention, when a color filter is produced, a film of a colored polymerizable composition is applied by coating. As the coating method, a conventional method such as a rotary type, a slit, a rotary type, or a slit type can be used. However, from the viewpoint of productivity, slit coating is preferably used.基板 The substrate for use in the color filter of the present invention includes, for example, an alkali-free glass, a soda-lime glass, a PYREX (registered trademark) glass, a quartz glass, and the like for use in a liquid crystal display element or the like. A transparent conductive film is attached thereto or the like, or a photoelectric conversion element substrate such as a solid-state image sensor or the like, for example, a germanium substrate or a plastic substrate. On these substrates, a black matrix for isolating the respective pixels or a transparent resin layer provided to promote adhesion or the like may be formed. In addition, the plastic substrate preferably has a gas barrier layer on its surface (〇

Gas Barrier Layer) and / or solvent resistant layer. In addition, a substrate for driving a thin film transistor (TFT) in which a thin film transistor (TFT) type color liquid crystal display device is disposed (hereinafter, referred to as a "TFT substrate for liquid crystal driving") may be used. A color filter formed by using the colored polymerizable composition of the present invention is also formed on the driving substrate to produce a color filter. The "substrate of the TFT-type liquid crystal driving substrate" includes, for example, glass, polyoxymethylene, polycarbonate, polyester, aromatic polyamide, polyamidolimine, polyimine, and the like. These substrates may be preliminarily subjected to appropriate pretreatment such as chemical treatment such as decane-115-200948906 coupling agent, plasma treatment, ion plating, sputtering, gas phase reaction method, vacuum vapor deposition, etc., for example. A substrate obtained by forming a surface passivation film such as a tantalum nitride film on the surface of the TFT liquid crystal driving substrate can be used. In the present invention, the method of applying the colored polymerizable composition of the present invention to a substrate is preferably a slit coating. The conditions of the slit coating are different depending on the size of the coated substrate, but for example, when the coating is applied to the fifth generation glass substrate (1,1 mm x 1,250 mm), the slit is applied. The discharge amount of the colored polymerizable composition of the nozzle is usually 500 to 3,000 μl/sec, preferably 800 to 2000 μl/sec, and in addition, the coating speed is usually 50 to 300 mm/sec. Preferably, it is from 100 to 250 mm/second. Further, the solid content of the colored polymerizable composition which can be used in the slit coating step is usually 10 to 23%, preferably 13 to 20%. » The colored polymerizable composition using the present invention is formed on a substrate. When the film is coated, the thickness of the coating film (after prebaking treatment) is usually from 0.3 to 5.0 from m, preferably from 〇5 to 4.0 #m, most preferably from 0.5 to 3.0 #m. Further, in the case of a color filter for a solid-state image sensor, the thickness of the coating film (after the prebaking treatment) is preferably in the range of 0.5 # m to 5.0 / / m. [Prebaking] It is preferred to carry out prebaking after forming the film of the colored polymerizable composition of the present invention on the substrate by a coating method as described above. Further, a vacuum treatment may be applied before the prebaking as needed. The vacuum drying condition is usually from 0.1 to 1.0 torr (13 to 133 Pa), preferably from about 0.2 to 0.5 torr (27 to 67 Pa). -116- 200948906 In addition, when pre-baking treatment is applied as needed, hot plates, ovens, etc. may be used, in the temperature range of 50 ° C to 140 ° C, preferably about 7 (TC to 110 ° C duration) The pre-baking treatment can be carried out under the conditions of a high-frequency treatment or the like. The high-frequency treatment system can also be used alone. [Exposure] By the film system formed as described above After drying or pre-baking as needed, the coating film is exposed through a specific pattern of the mask. The radiation system used for the exposure is particularly preferably a g-line, an h-line, an i-line, or the like. Ultraviolet light such as j-® wire. In addition, when manufacturing a color filter for a liquid crystal display device, it is preferable to use a proximity light-exposure machine or a mirror projection light-mirror projection light- Exposure machine ), and mainly using h-line, i-line exposure. ' In addition, in the manufacture of color filters for solid-state imaging devices, it is better to use a stepper light-exposure machine (stepper light-exposure machine ), and mainly use i-line.

In addition, when a color filter is manufactured using a TFT liquid crystal driving substrate, the photomask that can be used is used in addition to the pattern required for forming a pixel (colored pattern), and can also be used for setting. A pattern of a through hole or a rectangular-shajied depression is formed. [Development] After the exposure as described above, development is carried out. By this development, the uncured portion of the exposed coating film is dissolved in the developing solution to leave only the hardened portion on the substrate. -117- 200948906 The development temperature is usually 20 ° C to 30 ° C, and the development time is 20 seconds to 90 seconds. The developing solution is a coating film which can be dissolved in the uncured portion of the colored polymerizable composition after the coloring polymerizable composition of the present invention is exposed and the exposed portion is polymerized and cured, but the hardened portion is not dissolved. Any one can be used. Specifically, a developer or an aqueous solution obtained by combining various organic solvents can be used. The organic solvent to be used in the developer may be a solvent as described above which can be used in the preparation of the colored polymerizable composition of the present invention. Further, the "aqueous alkaline solution" includes, for example, by using sodium hydroxide, potassium hydroxide, sodium carbonate, sodium hydrogencarbonate, sodium citrate, sodium metasilicate, aqueous ammonia, ethylamine, diethylamine. , dimethylethanolamine, tetramethylammonium hydroxide, tetraethylammonium hydroxide, choline, pyrrole, piperidine, 1,8-diazabicyclo-[5.4.0]-7-undecene The compound is dissolved in an aqueous solution obtained by a concentration of 0.001 to 10% by mass, preferably 0.01 to 1% by mass. An appropriate amount of a water-soluble organic solvent such as methanol or ethanol or a surfactant may be added to the aqueous alkaline solution. The development method may be any one of an immersion method, a shower method, a spray method, and the like, or may be combined with a shaking method, a rotation method, an ultrasonic method, or the like. The developed surface may be previously wetted with water or the like before contact with the developer to prevent uneven development. Alternatively, the substrate may be tilted for development. Further, in the production of a color filter for a solid-state image sensor, paddle development can also be used. After the development treatment, after the strip was treated and dried by the 200948906 strip for removing the remaining developer for washing, the heat treatment (post-baking) was applied in order to complete the hardening. Although the washing treatment is usually carried out in pure water, in order to save the liquid, pure water can be used in the final washing stage, and the used pure water is used in the initial stage of washing, and in addition, the substrate can be used at the inclination. The method of washing or supersonic irradiation is used. After the washing treatment, drainage, and drying, heat treatment at about 200 ° C to 250 ° C is usually carried out. The post-baking is heating after development which is made to complete the hardening, and heating (hard baking) is preferably carried out at 200 ° C to 250 ° C. The heat treatment (post-baking) is a method of using a hot plate or a convection oven (hot air circulation dryer), a high frequency heating machine or the like in a manner consistent with the above conditions, in a continuous manner. Or in batch mode. After post-baking, it is preferred to apply UV cleaning prior to performing another color coating. The UV cleaning system can be carried out by a glass substrate cleaning machine or the like (for example, LC4000, manufactured by Hitachi Electronics Engineering Co., Ltd.), and the UV irradiation amount is usually about 100 rnJ/cm 2 to 1. , 000 mJ/cm2. By applying UV cleaning, the development residue can be removed, or the pattern formation property of another color can be improved. The steps as described above are carried out in order, whereby the color filter of the present invention can be produced. Further, by repeating the above-described steps in accordance with the desired number of hue and repeating the respective colors (three colors or four colors) in order, a cured film (colored pattern) forming a colored complex color can be produced. Color filter. [Embodiment] Hereinafter, the present invention will be more specifically described by way of examples, but the invention is not limited to the following examples without departing from the spirit and scope of the invention. In addition, “parts” means “parts by mass” unless otherwise stated. First, the components used in the examples and comparative examples will be described. &lt;Synthesis of Resin B&gt; 7.5 parts of the monomer M-11 and 3 1-25 parts of methyl methacrylate exemplified as described above, 11_25 parts of methacrylic acid and 167 parts by mass of methoxypropanediol were introduced into a three-necked flask substituted with nitrogen to a stirrer (Shinto Scientific Co., Ltd.: Three-One Motor) After stirring, nitrogen gas was introduced into the flask while heating to a temperature of 78 °C. To this, 1 part of dimethyl-2,2'-azobis(2-methyl propionate) was added (trade name: V-601, Wako Pure Chemical Industries, Ltd.) ·))), heating and stirring at 78 ° C for 2 hours. After 2 hours, 0.1 part of V-601 was further added and stirred under heating for 3 hours to obtain a 30% solution of Resin B. The obtained resin B was used as a resin used before the drying step of the pigment during salt milling. &lt;Synthesis of Resin A&gt; Except that the monomer used in the synthesis of the resin B as described above and the amount of the feed thereof as shown in Table 1 were changed, the others were the same. Synthetic resin A. The obtained resin A was used as a resin used before the drying step of the pigment during salt milling. Table 1 below shows the monomers used in the synthesis of resins A and B and the amounts thereof, the weight average molecular weight of the synthesized resin A and resin B, and the acid value. Here, the weight average molecular weight is measured by GPC (gel permeation method) under the following conditions, and measured in terms of polystyrene. 200948906 Pipe string used: TSKgel Multipore HXL-M (fine pore polydisperse linear column): manufactured by TOSCH Corporation; Dissolved solution: THF; Flow rate: 1.0 ml/min; Temperature: 40° C; Detection conditions: RI; System: High-speed GPC device complete set (HLC-8220 manufactured by East Soda Co., Ltd.). Further, the acid value is determined by the following method. (Method for measuring acid value) Measured by titration with a 0.1 Ν·KOH ethanol solution. The acid value of the solution is determined according to the acid value determination method of JIS K 0070: 1992 "Test method for acid value, saponification price, ester price, iodine value, hydroxyl value and unsaponifiable matter of chemical products". The resin was dissolved in 1-methoxy-2-propyl acetate and measured by titration with a KOH/ethanol solution using phenolphthalein as an indicator. Resin composition after salt milling (% by mass) Weight average molecular weight Acid value (mgKOH/g) Resin A St/BzMA/MAA = 22.5/50/22.5 12,000 150 Resin B Monomer M-11/MMA/MAA =15/ 62.5/22.5 12,000 150 In the above Table 1, the monomer Μ-1 1 is referred to as a monomer represented by the general formula (1) as shown above, maleimide, and cis-butene. Exemplary monomers exemplified by preferred specific examples of the quinone imine derivatives. Further, in Table 1, the details of the monomer used for the synthesis of Resin A are as follows: -121- 200948906

St: Styrene

BzMA: benzyl methacrylate methacrylate MAA: methacrylic acid MMA: methyl methacrylate Next, various dispersants used in preparing the pigment dispersion composition in the examples and the comparative examples are explained below. • Resin (1): * A A-6 / monomer M-11 / styrene / methacrylic acid = 55/10/2 0 / 15 (% by mass) of the copolymer (weight average molecular weight: 20,000) (- AA-6: Single-end methacryl oxime-based polymethyl methacrylate oligomer (Μη = 600 0, manufactured by Toa Synthetic Chemical Co., Ltd.) • Resin (2): Maleimide /styrene/methacrylic acid = 2 0/6 5/15 (% by mass) of a copolymer (weight average molecular weight: 20,000) In addition, 'the pigment derivative' used in the salt milling and preparation of the pigment dispersion composition The structure is as follows: -122- 200948906

(Pigment Derivative 1)

(Pigment Derivative 3: (B Ingredient))

123- 200948906 (pigment derivative 5)

-(S03H)n n=1,2 (pigment derivative 6)

°xV° 6 c|-Q-ci

CI^CI [Example 1] (Preparation method of treated pigment using salt mill) 50 g of IRGAPHOR RED BT-CF belonging to (A) diketopyrrolopyrrole pigment in the present invention (Ciba Specialty Chemicals Co., Ltd.) The company manufactures, pigment red 254), 500 grams of sodium chloride which is a water-soluble inorganic salt (average particle size of 10; zm), and 150 grams of diethylene glycol which is a water-soluble organic solvent (Tokyo Chemical Co., Ltd. (Tokyo Chemical Co., Ltd.) Co., Ltd. (manufactured by Co., Ltd.) was fed into a 1-gallon kneader made of stainless steel (manufactured by INOUE MFG., Inc.) and kneaded at 50 ° C for 10 hours. Next, 25 g of the resin A solution (solid content: 30% by mass) obtained by the above-described synthesis was added to the mixture, and mixed, and the mixture was poured into about 3 liters of heat after -124 to 200948906. The water was heated to about 70 ° C while being stirred by a high speed mixer for about 1 hour to obtain a slurry. Thereafter, sodium chloride and a solvent were removed by filtration, washing with water, and then dried in a hot air oven at 60 ° C for about 24 hours to obtain a surface-treated (A) diketopyrrole to which at least a part of the surface was attached with Resin A. And pyrrole pigments. The particle size of the obtained treated pigment was measured by a transmission electron microscope, and the average primary particle diameter was 30 run. The measurement of the particles was carried out by measuring the average enthalpy of the average enthalpy of the long diameter and the short diameter of 500 pigments at a magnification of 100,000 times.实施 [Example 1] &lt;Preparation of pigment dispersion composition&gt; The components of the composition (1) were mixed and mixed with a homogenizer at a number of revolutions of 3,000 rprn. for 1 hour to prepare a mixed solution containing a pigment. [Composition (Ο) • Surface-treated two 86 parts of ketopyrrolopyridine pigment [(A) component] obtained by the method described above • Pigment derivative (1) (structure as described above) 10 Parts ^ Pigment Derivative (3) [Structure as described above: (B 10 parts)] [13.4 parts relative to 100 parts of (A) component] • Pigment derivative (4) [as described above Structure: (C 5 parts) Ingredients]] [6.69 parts relative to 100 parts of (A) component] • DiSperbyk-2001 (manufactured by BYK Chemie) 33 parts • Resin (1) 30% acetic acid 1-methoxy 2-propyl ester solution 50 parts liquid-125- 200948906 • Resin (2) 30% acetic acid 1-methoxy-2-propyl ester 50 parts solution • Acetic acid 1 · methoxy-2-propyl ester 767 parts Next, the mixed solution obtained as described above was used to use 0.8 ιηηηφ cerium oxide beads (manufactured by Nikkato Corporation). A bead disperser (manufactured by DISPERMAT, GETZMANN) was applied for 20 minutes of pre-dispersion. Thereafter, a bead disperser ULTRA APEX MILL (Kotobuki) using 0.10 ιηιηφ zirconia beads (manufactured by Nikkato Co., Ltd.) was used. (manufactured by Industries Co., Ltd.)) 2 hours of formal dispersion was applied to obtain a red pigment dispersion composition of Example 1. [Evaluation of Pigment Dispersion Composition] Dispersibility and dispersion stability of the obtained pigment dispersion composition For the prepared pigment dispersion composition, the viscosity of the freshly prepared viscosity was measured using an E-type viscometer 7? 1 (25 °C), and the viscosity after one week after preparation? 2 (25 ° C) Both the 7?1 and the τ?2 series were 9 cp, and therefore it was confirmed that good dispersibility and dispersion stability were exhibited. [Example 2] &lt;Preparation of colored polymerizable composition&gt; Using the examples as described above 1 obtained pigment dispersion composition to produce a colored polymerizable composition of the composition (2) as described below. Further, the red pigment dispersion composition A and the yellow pigment dispersion composition A are as The modulated manner. (A red pigment dispersion composition A)

In addition to "IRGAPHOR -126- 200948906 RED BT-CF", "Red pigment ("CROMOPHTAL Red A2B" manufactured by BASF: PR177)" is used in addition to "IRGAPHOR-126-200948906 RED BT-CF". In the same manner as in Example 1, a salt mill was applied, whereby a treated pigment having an average particle diameter of 28 nm was obtained. After that, the obtained pigment was obtained, and the red pigment dispersion composition was obtained in the same manner as in Example 1 except that the "pigment derivative (1)" was used instead of the "pigment derivative (1)". A. Further, the yellow pigment dispersion composition A is prepared by dissolving ❹ 〇 (yellow pigment dispersion composition A) as described below. In the method of treating the pigment as described above, in place of "IRGAPHOR REDBT-CF", "yellow pigment" is used. Other than the "E4GN-GT: PY150" manufactured by Lanxess Corporation, a salt mill was applied in the same manner as in Example 1, whereby a treated pigment having an average particle diameter of 30 run was obtained. After that, the obtained pigment was obtained, and the pigment dispersion (yield (6) was used instead of the r Θ pigment derivative (1)", and the yellow pigment dispersion composition was obtained in the same manner as in Example 1. A. [Composition (2)] • Red pigment dispersion composition obtained in Example 1 800 parts • Red pigment dispersion composition A 800 parts as described above • Yellow pigment dispersion composition A 400 parts as described above • Five-hexaacrylic acid Dipentaerythritol ester (photopolymerizable 80 part) • 4-[o-bromo-p-N,N-bis(ethoxycarbonyl)amine 30 parts phenyl]-2,6-di (Trichloromethyl)-3-triazaindene (light-127-200948906 polymerization initiator) • Benzyl methacrylate/methacrylic acid (=70/30 300 parts by mass) copolymer (weight Average molecular weight: 1 〇, 〇〇〇) propylene glycol monomethyl ether acetate solution (solid content 30%) (alkali soluble resin) • 1-methoxy-2-propyl acetate (solvent) 590 parts • 3- Ethyl ethoxy propionate (solvent) 400 parts

Here, the pentaerythritol penta-hexaacrylate is represented by KAY ARAD DPHA (Nippon Kayaku Co., Ltd.) 0 &lt;Color filter using a coloring polymerizable composition Manufacture &gt; The obtained colored polymerizable composition (color resist liquid) was coated on a 100 mm X 100 mm glass substrate (1737, manufactured by Corning Incorporated) so as to be an index of color concentration (index of color concentration) The x 値 was 0.650 and dried in an oven at 90 ° C for 60 seconds (prebaking). Thereafter, the entire film was exposed to 200 mJ/crn2 (illuminance of 20 mW/cm 2 ), and then an alkali developer CDK-1 (manufactured by FUJIFILM Electronic Materials Co., Ltd.) was used. The 1% aqueous solution covered the exposed film and allowed to stand for 60 seconds. After standing, the pure water was sprayed in a spray form to wash off the developer. Then, the coating film subjected to the photohardening treatment and the development treatment as described above is heat-treated in an oven at 220 ° C for 30 minutes (post-baking) to form a colored film for constituting the color filter on the glass substrate. To produce a colored filter substrate (color filter) equipped with a monochrome colored area. After the substrate was further subjected to UV cleaning (at 20 mW/cm 2 and 500 mJ/cm 2 ) by a glass substrate cleaner (-128-200948906 LC4000, manufactured by Hitachi Electronic Engineering Co., Ltd.), Pre-baking, developing, and post-baking are performed again. Thereafter, the UV cleaning, prebaking, developing, and post-baking are further carried out, whereby a color filter substrate (color filter) for evaluation can be obtained. The colored polymerizable composition (color resist liquid) prepared by the above and the colored filter substrate (color filter) for evaluation prepared from the colored polymerizable composition are as follows The method described is evaluated. The results are shown in Table 2. 1. Measurement of viscosity _ For the prepared color polymerizable composition (color photoresist), an E-type viscometer is used to measure the viscosity after the preparation of 7? 1 (25 ° C), and one week after the preparation. After the viscosity V 2 (25 ° C). 1. Comparison of Measurements • Evaluation - The comparison of the prepared colored filter substrates (color filters) was measured in the following manner. ® Place the evaluation filter substrate between two polarizing plates, and then use BM-5 manufactured by TOPCON Corporation to measure the brightness and the brightness of the polarized axis when they are parallel. The enthalpy obtained by dividing the luminance in parallel by the luminance at the time of orthogonality (= luminance in parallel/luminance in orthogonal) is used as an index for evaluating contrast (this evaluation method is referred to as "the seventh time in M90" The Seventh Colorific Optics Conference, 512-color display, 10.4-inch "Color Filter for TFT-LCD (Thin Film Transistor-Liquid Crystal Display)", Ueki, Ozeki, Fukunaga and Yamanaka, etc. -129-200948906"). - 3. Measurement of surface roughness - For the evaluation of the colored filter substrate (color filter) for evaluation, an atomic force microscope (AFM: Atomic Force Microscope) (NanoScope Ilia, Nano World (Nano World) ))) to determine the surface roughness of the surface of the pigmented film. [Example 3] In Example 1, except that 0.8 g of the pigment derivative (1) was further added at the time of salt milling, the cerium salt milling was carried out in the same manner as in Example 1, whereby Handle pigments. The treated primary pigment obtained had an average primary particle size of 26 nm. Thereafter, the obtained treated pigment was used, and a red pigment dispersion composition was obtained in the same manner as in Example 1. Further, after obtaining a red colored polymerizable composition in the same manner as in Example 2, evaluation was carried out in the same manner as in Example 2. The results are shown in Table 2. [Example 4] In Example 1, except that 0.9 g of the pigment derivative (2) was further added at the time of salt milling, the cerium salt milling was carried out in the same manner as in Example 1, whereby Handle pigments. The treated primary pigment obtained had an average primary particle size of 23 nm. Thereafter, the obtained treated pigment was used, and a red pigment dispersion composition was obtained in the same manner as in Example 1. Further, after obtaining a red colored polymerizable composition in the same manner as in Example 2, evaluation was carried out in the same manner as in Example 2. The results are shown in Table 2. [Example 5] In Example 1, except that 0.9 g of the pigment derivative (2) was further added at the time of salt milling, the -130-200948906 salt mill was carried out in the same manner as in Example 1, in addition In addition to the "resin A solution (solid content: 30% by mass)"" after the kneading, the "resin b solution (solid content: 30% by mass)" obtained in the synthesis example as described above was used, and the rest was The treated pigment was obtained in the same manner as in Example 1. The treated primary pigment obtained had an average primary particle diameter of 23 nm. Thereafter, the obtained treated pigment was used, and a red pigment dispersion composition was obtained in the same manner as in Example 1. Further, after obtaining a red colored polymerizable composition in the same manner as in Example 2, evaluation was carried out in the same manner as in Example 2. The results are shown in Table 2. [Example 6] In Example 1, except that 0.9 g of the pigment derivative (2) was further added at the time of salt milling, the remainder was carried out in the same manner as in Example ,, and further, except after kneading The treated pigment was obtained in the same manner as in Example 1 except that the "Resin A solution (solid content: 3% by mass)" was used instead of the "Resin B solution (solid content: 30% by mass)". The treated primary pigment obtained had an average primary particle size of 23 nm. Thereafter, the obtained treated pigment was used, and the same as in Example 2 except that "10 parts of the pigment derivative (1)" was used instead of "1 part of the pigment derivative (2)". The red pigment dispersion composition was obtained in a manner. Further, after obtaining a red colored polymerizable composition in the same manner as in Example 1, evaluation was carried out in the same manner as in Example 2. The results are shown in Table 2 [Example 7] In Example 1, except that in the case of salt milling, 9 g of the pigment derivative (2) was further added, the same was carried out in the same manner as in Example 1. In addition to the "resin A solution (solid content: 3% by mass)" after the kneading, the "resin b solution (solid content: 30% by mass - 131 - 200948906)" is used, and the rest is The treated pigment was obtained in the same manner as in Example 1. The average primary particle diameter of the obtained treated pigment is 23 nm», after which the obtained treated pigment is used, and "10 parts of the pigment derivative (1), 1 part of the pigment derivative (3), 5 parts are replaced. The pigment derivative (4)", and the use of "11 parts of the pigment derivative (2), 7 parts of the pigment derivative (3), and 7 parts of the pigment derivative (4)" 1 A red pigment dispersion composition was obtained in the same manner. Further, after obtaining a red colored polymerizable composition in the same manner as in Example 2, evaluation was carried out in the same manner as in Example 2. The results are shown in Table 2. [Comparative Example 1] A salt milling was carried out in the same manner as in Example 1, whereby a treated pigment was obtained. The treated primary pigment obtained had an average primary particle size of 30 urn. Thereafter, the obtained treated pigment was used, and in place of "86 parts of the treated pigment obtained by the method described above", "103 parts of the treated pigment obtained by the method described above" was used, while A red pigment dispersion composition was obtained in the same manner as in Example 1 except that the "pigment derivative (3)" and the "pigment derivative (4)" were not used. Further, a red colored polymerizable composition was obtained in the same manner as in Example 2, and then evaluated in the same manner as in Example 2. The results are shown in Table 2. [Comparative Example 2] In Example 1, except that 0.8 g of the pigment derivative (1) was further added during salt milling, salt milling was carried out in the same manner as in Example 1, whereby treatment was possible. pigment. The treated primary pigment obtained had an average primary particle size of 26 nm. Thereafter, the obtained treated pigment was used, and except for "86 parts of the treated pigment obtained by the method described above", -132-200948906 "1〇3 parts were obtained by the method as described above. The red pigment dispersion composition was obtained in the same manner as in Example 1 except that the "pigment derivative (3)" and the "pigment derivative (4)" were not used. Further, the red colored polymerizable composition was obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 2. The results are shown in Table 2. [Comparative Example 3] In Example 1, except that the salt derivative was further added with 8 g of the pigment derivative (1), the salt milling was carried out in the same manner as in Example 1 A treated pigment is obtained. The average particle size of the treated pigment obtained was 26 run. After that, the obtained treated pigment is used, and in addition to "10 parts of the pigment derivative (3), 5 parts of the pigment derivative (4)", and "15 parts of the pigment derivative (3)" is used, The remainder was obtained in the same manner as in Example 1 to obtain a red pigment dispersion composition. Further, after obtaining a red colored polymerizable composition in the same manner as in Example 2, evaluation was carried out in the same manner as in Example 2. The results are shown in Table 2. [Comparative Example 4] In Example 1, except that 0.8 g of the pigment derivative (1) was further added at the time of salt milling, the salt milling was carried out in the same manner as in Example 1, whereby treatment was possible. pigment. The treated primary pigment obtained had an average primary particle size of 26 nm. After that, the obtained treated pigment is used, and in addition to "10 parts of the pigment derivative (3), 5 parts of the pigment derivative (4)", and "15 parts of the pigment derivative (4)" is used, The remainder was obtained in the same manner as in Example 1 to obtain a red pigment dispersion composition. Further, after obtaining a red colored polymerizable composition in the same manner as in Example 2, evaluation was carried out in the same manner as in Example 2. The results are shown in Table 2. -133-200948906, [Comparative Example 5] In Example 1, except that 1 gram of the pigment derivative (4) was further added during salt milling, the salt milling was carried out in the same manner as in Example 1. This allows for the treatment of pigments. The treated primary pigment obtained had an average primary particle size of 24 nm. Thereafter, the obtained treated pigment was used, and "103 parts of the treated pigment obtained by the method described above" was used instead of "86 parts of the treated pigment obtained by the method described above", while A red pigment dispersion composition was obtained in the same manner as in Example 1 except that the "pigment derivative (3)" and the "pigment derivative (4)" were not used. Further, the red colored polymerizable composition was obtained in the same manner as in Example 2, and evaluated in the same manner as in Example 2. The results are shown in Table 2. -134- 200948906 Table 2 Initial viscosity V 1 (cp) Time-dependent viscosity? 7 2 (cp) Contrast surface coarse chick (nm) Example 2 5 5 3,000 4 Example 3 5 6 3,200 4 Example 4 5 6 3,400 5 Example 5 4 5 3,500 4 Example ό 4 4 3,700 5 Example 7 ~ Comparative Example 1 ~ 5 5 3,600 5 5 5 1,500 20 Comparative Example 2 5 5 1,000 25 Comparative Example 3 5 6 2,600 11 Comparative Example 4 15 50 2,500 9 Comparative Example 5 8 15 1,200 23 From Table 2, the colored polymerizable compositions of Examples 2 to 7 prepared by using the pigment-dispersing composition of the present invention of Example 1 were understood. No increase in viscosity after storage was observed, and it was found that the organic pigment contained therein had superior dispersion stability. At the same time, it is also known that the color filter (color filter) formed by using the colored polymerizable composition has superior contrast and can form a color film having a small surface roughness. From these results, it is presumed that the colored polymerizable composition according to the present invention can obtain a color filter which has high contrast and which has been reduced in pixel defects such as surface roughness. [Simple description of the diagram] None. [Main component symbol description] 眺0 -135-

Claims (1)

200948906 VII. Patent application scope: 1. A pigment dispersion composition comprising: a diketopyrrolopyrrole pigment, and 0.1 to 30 parts by mass of orthobenzene relative to 100 parts by mass of the diketopyrrolopyrrole pigment. Dimethyl sulfoximine alkylated diketopyrrolopyrrole, 0.1 to 20 parts by mass, based on 100 parts by mass of the diketopyrrolopyrrole pigment, of phthalimidoalkylamine quinacridone And at least one organic solvent. 2. The pigment dispersion composition according to claim 1, wherein the diketopyrrolopyrrole pigment has an average primary particle diameter of 10 nm to 30 nm ° 3. As described in claim 1 a pigment dispersion composition, wherein the diketopyrrolopyrrole pigment is obtained by a method comprising the steps of: dissolving a diketopyrrolopyrrole pigment, a water-soluble inorganic salt, and substantially not dissolving the water-soluble inorganic salt a step of mechanically kneading the water-soluble organic solvent; Φ removing the water-soluble inorganic salt and the water-soluble organic solvent; and drying the diketopyrrolopyrrole pigment, and The step of contacting the diketopyrrolopyrrole pigment with a resin before the drying step. 4. The pigment dispersion composition according to claim 3, wherein the resin is a polymer compound having an acid value of 50 to 300 mgKOH/g. 5. A method for preparing a pigment dispersion composition, comprising the steps of: a diketopyrrolopyrrole pigment having an average primary particle diameter of 10 nm to 30 nm, and adding -136 to 200948906 plus 100 parts by mass The ketopyrrolopyrrole pigment is ol to 30 parts by mass of the phthalic acid imidoalkylated diketopyrrolopyrrole and 0.1 to 20 parts by mass relative to 1 part by mass of the diketopyrrolopyrrole pigment. a step of at least a part by mass of the phthalic acid iminoalkyl quinacridone; and a diketopyrrolopyrrole pigment, relative to 100 parts by mass of the diketopyrrolopyrrole pigment 〇 1 to 30 parts by mass of o-phthalimidoalkylened diketopyrrolopyrrole and phthalic acid of 1 to 20 parts by mass relative to 100 parts by mass of the diketone The step of dispersing the dimethyl quinone iminated alkyl quinacridone together with an organic solvent. A coloring polymerizable composition comprising the pigment dispersion composition, the photopolymerizable compound, and the photopolymerization initiator according to the first aspect of the invention. 7. The colored polymerizable composition according to claim 6, further comprising an alkali-soluble resin. A color filter comprising the colored polymerizable composition as described in claim 6 of the patent application. A method of producing a color calender sheet by applying a colored polymerizable composition as described in claim 6 to a substrate to form a coating film, and exposing the formed film, followed by development. -137- 200948906 IV. Designation of Representative Representatives (1) The representative representative of the case is: None. (2) A brief description of the symbol of the representative figure: Μ 〇 j\w 5. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: