TW200942166A - Microencapsulation - Google Patents
Microencapsulation Download PDFInfo
- Publication number
- TW200942166A TW200942166A TW098108095A TW98108095A TW200942166A TW 200942166 A TW200942166 A TW 200942166A TW 098108095 A TW098108095 A TW 098108095A TW 98108095 A TW98108095 A TW 98108095A TW 200942166 A TW200942166 A TW 200942166A
- Authority
- TW
- Taiwan
- Prior art keywords
- inorganic material
- particulate inorganic
- modified
- microcapsule
- dispersion
- Prior art date
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- 239000003094 microcapsule Substances 0.000 claims abstract description 57
- 238000000034 method Methods 0.000 claims abstract description 50
- 229910010272 inorganic material Inorganic materials 0.000 claims abstract description 41
- 239000011147 inorganic material Substances 0.000 claims abstract description 41
- 239000007788 liquid Substances 0.000 claims abstract description 20
- 239000002002 slurry Substances 0.000 claims abstract description 14
- 239000012736 aqueous medium Substances 0.000 claims abstract description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 48
- 239000002245 particle Substances 0.000 claims description 38
- 239000004927 clay Substances 0.000 claims description 31
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 27
- 239000003431 cross linking reagent Substances 0.000 claims description 19
- 239000000463 material Substances 0.000 claims description 18
- 239000004480 active ingredient Substances 0.000 claims description 13
- 239000005995 Aluminium silicate Substances 0.000 claims description 12
- 235000012211 aluminium silicate Nutrition 0.000 claims description 12
- 239000003905 agrochemical Substances 0.000 claims description 11
- -1 oxidized Substances 0.000 claims description 9
- 238000004132 cross linking Methods 0.000 claims description 8
- 239000002917 insecticide Substances 0.000 claims description 8
- 239000005056 polyisocyanate Substances 0.000 claims description 8
- 229920001228 polyisocyanate Polymers 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 7
- 229910052625 palygorskite Inorganic materials 0.000 claims description 6
- 239000004113 Sepiolite Substances 0.000 claims description 5
- 125000003277 amino group Chemical group 0.000 claims description 5
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 claims description 5
- ZLNQQNXFFQJAID-UHFFFAOYSA-L magnesium carbonate Chemical compound [Mg+2].[O-]C([O-])=O ZLNQQNXFFQJAID-UHFFFAOYSA-L 0.000 claims description 5
- 239000001095 magnesium carbonate Substances 0.000 claims description 5
- 229910000021 magnesium carbonate Inorganic materials 0.000 claims description 5
- 235000014380 magnesium carbonate Nutrition 0.000 claims description 5
- 229910052901 montmorillonite Inorganic materials 0.000 claims description 5
- 229910052624 sepiolite Inorganic materials 0.000 claims description 5
- 235000019355 sepiolite Nutrition 0.000 claims description 5
- 229910052684 Cerium Inorganic materials 0.000 claims description 4
- 239000010440 gypsum Substances 0.000 claims description 4
- 229910052602 gypsum Inorganic materials 0.000 claims description 4
- 229910052622 kaolinite Inorganic materials 0.000 claims description 4
- 239000002728 pyrethroid Substances 0.000 claims description 4
- 235000019738 Limestone Nutrition 0.000 claims description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 3
- 239000011149 active material Substances 0.000 claims description 3
- 125000000217 alkyl group Chemical group 0.000 claims description 3
- 229910052782 aluminium Inorganic materials 0.000 claims description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 3
- 229960000892 attapulgite Drugs 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 229910001593 boehmite Inorganic materials 0.000 claims description 3
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 claims description 3
- 239000010459 dolomite Substances 0.000 claims description 3
- 229910000514 dolomite Inorganic materials 0.000 claims description 3
- 229910001701 hydrotalcite Inorganic materials 0.000 claims description 3
- 229960001545 hydrotalcite Drugs 0.000 claims description 3
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical compound O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 3
- 229910052900 illite Inorganic materials 0.000 claims description 3
- 229940094522 laponite Drugs 0.000 claims description 3
- 239000006028 limestone Substances 0.000 claims description 3
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 claims description 3
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- VGIBGUSAECPPNB-UHFFFAOYSA-L nonaaluminum;magnesium;tripotassium;1,3-dioxido-2,4,5-trioxa-1,3-disilabicyclo[1.1.1]pentane;iron(2+);oxygen(2-);fluoride;hydroxide Chemical compound [OH-].[O-2].[O-2].[O-2].[O-2].[O-2].[F-].[Mg+2].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[Al+3].[K+].[K+].[K+].[Fe+2].O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2.O1[Si]2([O-])O[Si]1([O-])O2 VGIBGUSAECPPNB-UHFFFAOYSA-L 0.000 claims description 3
- 239000010451 perlite Substances 0.000 claims description 3
- 235000019362 perlite Nutrition 0.000 claims description 3
- 239000004575 stone Substances 0.000 claims description 3
- 229910052902 vermiculite Inorganic materials 0.000 claims description 3
- 239000010455 vermiculite Substances 0.000 claims description 3
- 235000019354 vermiculite Nutrition 0.000 claims description 3
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 2
- HPTYUNKZVDYXLP-UHFFFAOYSA-N aluminum;trihydroxy(trihydroxysilyloxy)silane;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O[Si](O)(O)O HPTYUNKZVDYXLP-UHFFFAOYSA-N 0.000 claims description 2
- 229910001570 bauxite Inorganic materials 0.000 claims description 2
- 229910052791 calcium Inorganic materials 0.000 claims description 2
- 239000011575 calcium Substances 0.000 claims description 2
- CXUJOBCFZQGUGO-UHFFFAOYSA-F calcium trimagnesium tetracarbonate Chemical compound [Mg++].[Mg++].[Mg++].[Ca++].[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O.[O-]C([O-])=O CXUJOBCFZQGUGO-UHFFFAOYSA-F 0.000 claims description 2
- ZXQYGBMAQZUVMI-UNOMPAQXSA-N cyhalothrin Chemical compound CC1(C)C(\C=C(/Cl)C(F)(F)F)C1C(=O)OC(C#N)C1=CC=CC(OC=2C=CC=CC=2)=C1 ZXQYGBMAQZUVMI-UNOMPAQXSA-N 0.000 claims description 2
- 229910001679 gibbsite Inorganic materials 0.000 claims description 2
- 229910052621 halloysite Inorganic materials 0.000 claims description 2
- 229910000271 hectorite Inorganic materials 0.000 claims description 2
- KWLMIXQRALPRBC-UHFFFAOYSA-L hectorite Chemical compound [Li+].[OH-].[OH-].[Na+].[Mg+2].O1[Si]2([O-])O[Si]1([O-])O[Si]([O-])(O1)O[Si]1([O-])O2 KWLMIXQRALPRBC-UHFFFAOYSA-L 0.000 claims description 2
- 229910000515 huntite Inorganic materials 0.000 claims description 2
- 239000004579 marble Substances 0.000 claims description 2
- 239000010445 mica Substances 0.000 claims description 2
- 229910052618 mica group Inorganic materials 0.000 claims description 2
- 239000001117 sulphuric acid Substances 0.000 claims description 2
- 235000011149 sulphuric acid Nutrition 0.000 claims description 2
- 239000000454 talc Substances 0.000 claims description 2
- 229910052623 talc Inorganic materials 0.000 claims description 2
- 229910052747 lanthanoid Inorganic materials 0.000 claims 2
- 150000002602 lanthanoids Chemical class 0.000 claims 2
- ZMIGMASIKSOYAM-UHFFFAOYSA-N cerium Chemical compound [Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce][Ce] ZMIGMASIKSOYAM-UHFFFAOYSA-N 0.000 claims 1
- 239000002738 chelating agent Substances 0.000 claims 1
- 230000009194 climbing Effects 0.000 claims 1
- 239000011859 microparticle Substances 0.000 claims 1
- 150000002923 oximes Chemical class 0.000 claims 1
- 239000011435 rock Substances 0.000 claims 1
- 239000004971 Cross linker Substances 0.000 abstract description 6
- 230000008569 process Effects 0.000 abstract description 6
- 239000002775 capsule Substances 0.000 description 66
- 239000006185 dispersion Substances 0.000 description 58
- 239000000839 emulsion Substances 0.000 description 54
- 239000000243 solution Substances 0.000 description 40
- 238000002156 mixing Methods 0.000 description 36
- 239000000203 mixture Substances 0.000 description 26
- 238000000879 optical micrograph Methods 0.000 description 22
- 239000004490 capsule suspension Substances 0.000 description 21
- 238000002360 preparation method Methods 0.000 description 21
- 239000002356 single layer Substances 0.000 description 20
- 239000004615 ingredient Substances 0.000 description 14
- NIQCNGHVCWTJSM-UHFFFAOYSA-N dimethyl benzenedicarboxylate Natural products COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 13
- 239000004094 surface-active agent Substances 0.000 description 13
- 238000001035 drying Methods 0.000 description 11
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- 150000001875 compounds Chemical class 0.000 description 8
- 238000001000 micrograph Methods 0.000 description 8
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 7
- 229960001826 dimethylphthalate Drugs 0.000 description 7
- 230000004224 protection Effects 0.000 description 7
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- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000010954 inorganic particle Substances 0.000 description 5
- 239000012071 phase Substances 0.000 description 5
- 238000012360 testing method Methods 0.000 description 5
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- 239000011248 coating agent Substances 0.000 description 4
- 238000013270 controlled release Methods 0.000 description 4
- 238000000502 dialysis Methods 0.000 description 4
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- 239000000052 vinegar Substances 0.000 description 4
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- 230000004888 barrier function Effects 0.000 description 3
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- NYPJDWWKZLNGGM-UHFFFAOYSA-N fenvalerate Chemical compound C=1C=C(Cl)C=CC=1C(C(C)C)C(=O)OC(C#N)C(C=1)=CC=CC=1OC1=CC=CC=C1 NYPJDWWKZLNGGM-UHFFFAOYSA-N 0.000 description 3
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/26—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests in coated particulate form
- A01N25/28—Microcapsules or nanocapsules
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/04—Making microcapsules or microballoons by physical processes, e.g. drying, spraying
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J13/00—Colloid chemistry, e.g. the production of colloidal materials or their solutions, not otherwise provided for; Making microcapsules or microballoons
- B01J13/02—Making microcapsules or microballoons
- B01J13/06—Making microcapsules or microballoons by phase separation
- B01J13/14—Polymerisation; cross-linking
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S977/00—Nanotechnology
- Y10S977/70—Nanostructure
- Y10S977/773—Nanoparticle, i.e. structure having three dimensions of 100 nm or less
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Toxicology (AREA)
- Manufacturing Of Micro-Capsules (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GBGB0804700.3A GB0804700D0 (en) | 2008-03-13 | 2008-03-13 | Microencapsulation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| TW200942166A true TW200942166A (en) | 2009-10-16 |
Family
ID=39328079
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| TW098108095A TW200942166A (en) | 2008-03-13 | 2009-03-12 | Microencapsulation |
Country Status (21)
| Country | Link |
|---|---|
| US (3) | US9204631B2 (enExample) |
| EP (1) | EP2288257B1 (enExample) |
| JP (1) | JP5379169B2 (enExample) |
| KR (2) | KR101761544B1 (enExample) |
| CN (1) | CN102083306B (enExample) |
| AR (1) | AR075258A1 (enExample) |
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| MA34303B1 (fr) * | 2010-06-07 | 2013-06-01 | Syngenta Participations Ag | Composition chimique stabilisée |
| DE102011003829A1 (de) | 2011-02-09 | 2012-08-09 | Bayer Materialscience Aktiengesellschaft | Anorganische berflächenaktive Partikel und Verfahren zu ihrer Herstellung |
| GB201115564D0 (en) | 2011-09-08 | 2011-10-26 | Syngenta Ltd | Herbicidal composition |
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| GB201210156D0 (en) * | 2012-06-08 | 2012-07-25 | Imerys Minerals Ltd | Microcapsules |
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| BR112015002164A2 (pt) | 2012-08-01 | 2017-07-04 | Oxane Mat Inc | pluralidade de propantes cerâmicos sinterizados, método para fabricar um propante cerâmico sinterizado, propante, propante cerâmico, propante cerâmico sinterizado e método para fabricar um propante cerâmico |
| CA2950528A1 (en) * | 2012-09-20 | 2014-03-27 | The Procter & Gamble Company | Spray drying microcapsules |
| EP2919903B1 (en) | 2012-11-14 | 2020-07-22 | W.R. Grace & CO. - CONN. | Compositions containing a biologically active material and a non-ordered inorganic oxide |
| AR095420A1 (es) * | 2013-03-14 | 2015-10-14 | Syngenta Ltd | Composición herbicida que comprende micropartículas poliméricas que contienen un herbicida de tipo auxina sintética o inhibidor de als, y método para controlar malezas |
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| CN103962074B (zh) * | 2014-02-28 | 2016-02-24 | 中国科学院化学研究所 | 一种中空亚微米球、其制备方法与应用 |
| WO2016070012A1 (en) * | 2014-10-30 | 2016-05-06 | Henry Company, Llc | Phase-change materials from wax-based colloidal dispersions and their process of making |
| CN104774145B (zh) * | 2015-03-30 | 2017-03-15 | 中国农业大学 | 一种稳定脱落酸及其盐的方法 |
| CN104798774B (zh) * | 2015-03-30 | 2016-06-22 | 中国农业大学 | 一种有效改善植物生长调节剂稳定性的方法 |
| CN111518535A (zh) * | 2015-04-09 | 2020-08-11 | 沙特阿拉伯石油公司 | 用于提高烃采收的胶囊型纳米组合物及其制备方法 |
| US11059015B2 (en) | 2015-06-10 | 2021-07-13 | Council Of Scientific And Industrial Research | Microcapsules modified with nanomaterial for controlled release of active agent and process for preparation thereof |
| CN105080441B (zh) * | 2015-07-28 | 2017-10-13 | 西北工业大学 | 一种包覆液态烯微胶囊的制备方法 |
| US10272126B2 (en) | 2015-08-21 | 2019-04-30 | The University Of Massachusetts | Nanoparticle-stabilized microcapsules, dispersions comprising nanoparticle-stabilized microcapsules, and method for the treatment of bacterial biofilms |
| WO2018054719A1 (en) | 2016-09-20 | 2018-03-29 | Firmenich Sa | Hybrid microcapsules |
| CN108157361A (zh) * | 2017-12-19 | 2018-06-15 | 翟琳 | 一种病房消毒剂的制备方法 |
| WO2019229624A1 (en) * | 2018-05-27 | 2019-12-05 | The State Of Israel, Ministry Of Agriculture & Rural Development Agricultural Research Organization | Single cell encapsulation via pickering emulsion for bio-pesticides application |
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| FR3082732A1 (fr) * | 2018-06-25 | 2019-12-27 | Imertech | Emulsions de type pickering |
| CN111115854A (zh) * | 2018-10-30 | 2020-05-08 | 芜湖美的厨卫电器制造有限公司 | 包覆阻垢剂的介孔微球及其制备方法、热水器和内胆 |
| CN111790322B (zh) * | 2019-04-03 | 2022-11-29 | 苏州丝美特生物技术有限公司 | 一种利用纳米颗粒稳定和增强丝素蛋白微胶囊壳结构的方法 |
| US12403443B2 (en) | 2019-12-13 | 2025-09-02 | Firmenich Sa | Hybrid microcapsules |
| EP4081338B1 (en) * | 2019-12-25 | 2024-02-07 | Unilever IP Holdings B.V. | Microcapsules and cosmetic compositions comprising the same |
| KR102120613B1 (ko) * | 2020-03-19 | 2020-06-08 | 소대성 | 친환경 향기 마이크로캡슐과 이의 제조방법, 및 이를 포함하는 섬유 |
| CN114269813B (zh) | 2020-06-01 | 2024-01-02 | 株式会社Lg化学 | 制备聚合物微粒的方法，聚合物微粒，使用其的医用组合物、美容组合物、医用制品和美容制品 |
| CN111759804B (zh) * | 2020-07-23 | 2021-07-02 | 江南大学 | 一种粘土颗粒和醇溶谷蛋白颗粒协同稳定的皮克林乳液的制备方法 |
| CN112160163A (zh) * | 2020-08-14 | 2021-01-01 | 闽江学院 | 一种智能纤维的制备方法 |
| CN112339467B (zh) * | 2021-01-07 | 2021-03-23 | 虎丘影像（苏州）有限公司 | 一种含氟热敏染料微胶囊及其制备方法及胶片 |
| MX2023005710A (es) | 2021-02-09 | 2023-05-30 | Firmenich & Cie | Microcapsulas hibridas que comprenden particulas de lignina. |
| JP2024505778A (ja) | 2021-02-09 | 2024-02-08 | フイルメニツヒ ソシエテ アノニム | 再生バイオポリマーを含むハイブリッドマイクロカプセル |
| JP2024513056A (ja) | 2021-03-30 | 2024-03-21 | フイルメニツヒ ソシエテ アノニム | アセトアセチルポリマーをベースとするマイクロカプセル |
| CN115176802B (zh) * | 2021-04-06 | 2024-02-20 | 中国科学院化学研究所 | 木质素基液液凝聚相体系、脱落酸稳定剂、及其制备方法和应用 |
| CN113136173B (zh) * | 2021-04-09 | 2022-10-04 | 浙江理工大学 | 碗状有机硅热储能相变微胶囊及制备方法 |
| CN113735485A (zh) * | 2021-09-07 | 2021-12-03 | 青岛理工大学 | 用于混凝土的环境复响应同质膨胀型自修复微胶囊及其制备方法 |
| AR127889A1 (es) * | 2021-12-07 | 2024-03-06 | Mmag Co Ltd | Composición agroquímica y método para su producción |
| CN115337046B (zh) * | 2022-08-12 | 2025-04-25 | 苏州大学附属第二医院 | 可控肠内采样胶囊 |
| CN115486494B (zh) * | 2022-09-22 | 2023-09-19 | 中国科学院兰州化学物理研究所 | 一种以乳液为模板构筑植物精油/解离凹凸棒石复合抗菌产品的方法 |
| CN115975605A (zh) * | 2023-01-17 | 2023-04-18 | 辽宁石油化工大学 | 一种复合相变储能材料的制备方法 |
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| US5846554A (en) * | 1993-11-15 | 1998-12-08 | Zeneca Limited | Microcapsules containing suspensions of biologically active compounds and ultraviolet protectant |
| PT902724E (pt) | 1996-05-23 | 2002-03-28 | Syngenta Ltd | Composicoes microencapsuladas |
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| US6544540B2 (en) * | 1998-07-29 | 2003-04-08 | Syngenta Limited | Base-triggered release microcapsules |
| AU7421201A (en) * | 2000-06-05 | 2001-12-17 | Syngenta Limited | Novel emulsions |
| US7179480B2 (en) | 2002-04-24 | 2007-02-20 | 3M Innovative Properties Company | Sustained release microcapsules |
| US7056449B2 (en) * | 2002-08-14 | 2006-06-06 | Rohm And Haas Company | Aqueous silica dispersion |
| US6808808B2 (en) * | 2003-01-14 | 2004-10-26 | Freeman Gary M | Coating composition containing surface treated clay mixture, the surface treated clay mixture used therefor, and methods of their use |
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| GB0804700D0 (en) | 2008-03-13 | 2008-04-16 | Syngenta Ltd | Microencapsulation |
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| BRPI0909656A8 (pt) | 2016-04-26 |
| JP5379169B2 (ja) | 2013-12-25 |
| CA2717262A1 (en) | 2009-05-22 |
| EP2288257B1 (en) | 2019-01-16 |
| AU2009202113A1 (en) | 2009-05-22 |
| US20180360031A1 (en) | 2018-12-20 |
| KR101761544B1 (ko) | 2017-07-26 |
| EA201001426A1 (ru) | 2011-04-29 |
| AR075258A1 (es) | 2011-03-23 |
| US20160088838A1 (en) | 2016-03-31 |
| WO2009063257A2 (en) | 2009-05-22 |
| GB0804700D0 (en) | 2008-04-16 |
| TR201905122T4 (tr) | 2019-05-21 |
| US10015961B2 (en) | 2018-07-10 |
| KR20170001961A (ko) | 2017-01-05 |
| IL207697A0 (en) | 2010-12-30 |
| ES2720865T3 (es) | 2019-07-25 |
| NZ587501A (en) | 2012-07-27 |
| US20110200658A1 (en) | 2011-08-18 |
| WO2009063257A3 (en) | 2010-10-28 |
| JP2011514842A (ja) | 2011-05-12 |
| CN102083306A (zh) | 2011-06-01 |
| KR20100124284A (ko) | 2010-11-26 |
| EP2288257A2 (en) | 2011-03-02 |
| UA101182C2 (en) | 2013-03-11 |
| CA2717262C (en) | 2016-06-28 |
| ZA201006033B (en) | 2011-06-29 |
| MX2010009852A (es) | 2010-10-05 |
| CN102083306B (zh) | 2014-06-25 |
| PT2288257T (pt) | 2019-05-17 |
| BRPI0909656A2 (pt) | 2015-07-28 |
| US9204631B2 (en) | 2015-12-08 |
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