TW200911383A - Nozzle used in cold sprayer and cold sprayer device - Google Patents

Nozzle used in cold sprayer and cold sprayer device Download PDF

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Publication number
TW200911383A
TW200911383A TW97111775A TW97111775A TW200911383A TW 200911383 A TW200911383 A TW 200911383A TW 97111775 A TW97111775 A TW 97111775A TW 97111775 A TW97111775 A TW 97111775A TW 200911383 A TW200911383 A TW 200911383A
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Taiwan
Prior art keywords
nozzle
cold
raw material
sprayer
cold sprayer
Prior art date
Application number
TW97111775A
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Chinese (zh)
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TWI417143B (en
Inventor
Hirotaka Fukanuma
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Plasma Giken Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C24/00Coating starting from inorganic powder
    • C23C24/02Coating starting from inorganic powder by application of pressure only
    • C23C24/04Impact or kinetic deposition of particles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/14Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas designed for spraying particulate materials
    • B05B7/1404Arrangements for supplying particulate material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/14Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas designed for spraying particulate materials
    • B05B7/1481Spray pistols or apparatus for discharging particulate material
    • B05B7/1486Spray pistols or apparatus for discharging particulate material for spraying particulate material in dry state
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05BSPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
    • B05B7/00Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas
    • B05B7/16Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed
    • B05B7/1606Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air
    • B05B7/1613Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air comprising means for heating the atomising fluid before mixing with the material to be sprayed
    • B05B7/162Spraying apparatus for discharge of liquids or other fluent materials from two or more sources, e.g. of liquid and air, of powder and gas incorporating means for heating or cooling the material to be sprayed the spraying of the material involving the use of an atomising fluid, e.g. air comprising means for heating the atomising fluid before mixing with the material to be sprayed and heat being transferred from the atomising fluid to the material to be sprayed

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Nozzles (AREA)
  • Other Surface Treatments For Metallic Materials (AREA)

Abstract

The present invention provides a nozzle for cold sprayer and a cold sprayer device, which can great reduce the stock power adhering on inner wall of the nozzle and clogging the nozzle. To attain the above purposes, the nozzle for cold sprayer is characterized by comprising a cone-shape pressing part having a narrow tip end and a cone-shape extension part having a wide tip end, which is communicated with the pressing part, and using an action gas at a temperature not more than the melting point of the stock powder to allow the stock powder flowing into the inlet of the pressing part and ejecting from the output of the extension part as an ultrasonic flow, wherein at least the inner wall of the extension part is made from any ceramics material selected from silicon nitride ceramics, zircornia ceramics, and silicon carbide.

Description

200911383 九、發明說明: 【發明所屬之技術領域】 本發明係有關爲了大幅減少操作中起因於原 ΐϊϋ噴嘴之附著而發生之冷噴霧器用噴嘴阻塞^冷嗔霧 ,用噴嘴,以及使用該噴嘴之冷噴霧器裝之 【先前技術】 已往,在製鐵製程中的鑄型或乳製、气車車 ==的各種金屬,上,爲使===機 銅、1、鉻或其件上形成錄、 電鑛有==:題_金屬 射,包懕iSif方式形成皮膜的方法。作為該溶 射(HVOF)以及大氣電漿炼射等。^^ 2落 有因熔射中的氧化作用,在&有皮膜 作為代替該方法的皮膜 態之原料粉末形成皮膜的「冷喷;備為D以固相狀 喷霧器係使低於斤料於古沾卜、^」傷又業界注目。此種冷 音速噴流錄化關作耻體成爲超 予以投入,再=嘴將被搬送的原料粉末 材而形成皮臈i就是ΐ二金相2就此衝撞基 陶竞等原料粉末以超音速嗔流炫射於金化合物、 態衝撞而形成爲皮膜者。嘗‘射於基材表面,使其以固相狀 進而詳細說明冷喷霧器技術如 — 空氣等之1 縮氣體筒之氣體供自有氮乳、乳氣、 送氣體二管路。其口分岐爲作用氣體及輪 熱至原料粉末之炫點訂^的作用風體,以加熱器予以加 禾之魅U下的邮後,供給至冷無器噴检之腔200911383 IX. OBJECTS OF THE INVENTION: TECHNICAL FIELD The present invention relates to nozzles for cold sprayers that are used to greatly reduce the adhesion of nozzles caused by the nozzles in the operation, nozzles, and nozzles. Cold sprayer [Prior Art] In the past, in the mold making process of the iron making process or the various metals of the dairy and air-cars ==, in order to make === machine copper, 1, chrome or its parts , electric mine has ==: question _ metal shot, including the iSif method to form a film. This is the HVOF, atmospheric plasma refining, and the like. ^^ 2 falls due to the oxidation in the spray, and the film has a film as a substitute for the film of the film to form a film of "cold spray; prepared as a solid phase sprayer for D. It is expected that the ancient dip, ^" injury and the industry's attention. This kind of cold-sonic jet recording is turned into a savvy body to be super-inputted, and then the raw material powder material that will be conveyed by the mouth will form a skin 臈i, which is the 金二金相2, which will collide with the base material such as 陶陶竞 and supersonic turbulence. A smear of a gold compound and a collision of the state to form a film. Try to shoot on the surface of the substrate so that it is solid-phase and then detail the cold sprayer technology, such as air, such as air, which is supplied with nitrogen, milk, and gas. The mouth is divided into a functioning body for the gas and the heat of the wheel to the raw material powder, and is supplied to the cavity of the cold-free device by the postage of the heater under the charm U.

IP080245/0PGK000U.QP 200911383 料粉末供給機構, 粉末,藉由作用氣體經過送氣體搬送的原料 膜相密成 化或熱變質亦少、且其密著性優異。及導熱率亦高、氧 於該粉末附粉末附著於喷嘴或起因 鋼、超硬合金等製造,但藉由m嘴係使用不鎮鋼、工具 合金作爲原料之冷噴霧器二n、銘、不錄鋼或該等之 係於擴_容易附著原太皮、f之^形時,在喷嘴各部、尤 於操作時,原料粉末與喷嘴^°此乃起因 的温度上升,而使娜之間發生摩擦,致使喷嘴内面 其成細物·因而, 種起因於原料粉末附著於嗔^呆作。此 發生在___數分鐘itnm塞^時 上造成極大障礙。 叩於令嗔霧器技術的實用化 中揭喷==特__63號公報) 屬粉末附著顧料上錢射由射嘴糾減少金 報)ί揭利=特開2005·95886號公 狀前端細尖部、介由喉部連接=f接於喷嘴人σ的圓錐 張部、及連接於太戚接士義細尖部之短圓錐狀末端擴 設置部 於專利文獻2中’由特定上述喷嘴的設計,即可使用廉價規格IP080245/0PGK000U.QP 200911383 Material powder supply mechanism, powder, the raw material film that is transported by the gas through the gas is densely formed or thermally degraded, and the adhesion is excellent. And the thermal conductivity is also high, oxygen is attached to the nozzle powder or the cause of steel, super-hard alloy, etc., but the m-nozzle uses the non-town steel, tool alloy as the raw material of the cold sprayer, n, Ming, not recorded When the steel or the like is attached to the original smear and the shape of the f, the temperature of the raw material powder and the nozzle is increased at each part of the nozzle, especially during the operation, and the friction between the nucleus occurs. This causes the inner surface of the nozzle to be fine. Therefore, the seed is caused by the adhesion of the raw material powder to the sputum. This occurs when ___ minutes of itnm plug ^ cause a great obstacle.叩 嗔 嗔 嗔 嗔 = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = = 粉末 粉末 粉末 粉末 粉末 粉末 粉末 粉末 粉末 粉末 粉末 粉末 粉末a fine tip portion, a conical portion connected to the nozzle person σ via a throat connection, and a short conical end extension portion connected to the tip end portion of the tarp joint, in Patent Document 2, Design, you can use cheap specifications

IP080245/0PGK00011-OP 200911383 面亦彳ί以使平行部的更換變容易,假定於〇5nf 嘴的維護變得容易。 、⑷IV生時,亦可使喷 下,得以將原料以對為喷嘴材料之情況 法使用於5〇(TC以上;噴嘴一,進而因耐熱性低故無 故並交換變容易為目的, 所引起的阻塞。原似7末對噴嘴_著或減少該起因 著引==塞因於原料粉末附 能解決。 L》抽實用上尚有極大的問題未 粉末崎操作中原料 及使用該嘴嘴之冷喷霧^嘴的長㈣化之冷喷霧器用喷嘴 【發明内容】 t 用以檢討結果,思及以下之本發明可作為 擴張部,使岐度為顧财线絲之圓錐狀 粉末由該壓縮部之噴嘴入口流入,而使原料 ;r—竞、丄心=IP080245/0PGK00011-OP 200911383 is also used to make the replacement of the parallel parts easier, assuming that the maintenance of the 〇5nf nozzle becomes easy. (4) When IV is born, it can also be sprayed, and the raw material can be used as a nozzle material for 5 〇 (TC or more; nozzle 1 and further, because of low heat resistance, and it is easy to exchange and change, Blocking. It seems that the end of the 7 pairs of nozzles _ or reduce the cause of the introduction == plug due to the raw material powder can be solved. L" pumping practical still has great problems, the raw materials in the powder and the cold use of the mouth Spray nozzle for long (four) cold sprayer of spray nozzle [Inventive content] t For reviewing the results, the following invention can be considered as a dilating portion, so that the conical powder of the twisted wire is compressed by the conical powder The nozzle inlet of the part flows in, and the raw material is made; r-competition, 丄心=

IP080245/0PGK00011-OP 200911383 又 部全體係器用喷嘴:較好其擴 張部及壓縮 紐料卿成。是、概_曼、碳切喊之任-種陶 嘴之擴張喷嘴,較好該冷喷霧器用喷 包含構本種冷鱗制喷嘴裝置,其特徵為 與輸送氣體之氣體機構;供給作用氣體 器用噴嘴。 m更用上述之任-冷喷霧 [發明的效果] 之冷冷働用喷脅 喷霧_之長壽命達成冷 ^ . , 1 〇 口此無窝頻繁的更換冷嘖霖哭4 陶料’ βΛ明有關之冷噴霧器用喷嘴之内周壁面基本上為 霧;=酸洗處理。因此,假定若原料粉末附ί 而了谷易地去除附著原料之優點。 肀 【實施方式】 ®Μ ’兹就實施本發明之最佳形態予以詳細説明。其中, 圖1係有關本發明冷傭H时嘴之—實施形態剖面圖。、 巧1巾,冷儒H时嘴丨,係由於端部具有喷嘴入口 端細尖之圓錐狀壓縮部lb、及與其連通且端部具有 擴張之®雜舰部le所成。本發明有關之 二赁霧器用喷嘴只要至少具有上述壓縮部Ib及擴張部lc即 二而可為任意之其他形狀。例如,可在上述壓縮部1b與上 .述擴張部lc間設置狹小喉部、亦可在上述擴張部lc的噴嘴出 IP080245/0PGK00011 -〇p 8 200911383 口侧設置筒狀平行部等。 流向。 ,;圖1中,箭頭表示原料粉末的 在本發明中,至少上述 氮化矽陶瓷、氧化錯陶f二二,部1c之至少其内周壁面係以 下僅簡稱為「氮化發陶 ^化石夕陶竟之任-者陶曼材料(以 含意指擴張部之外^^。其胃至少内周 僅其内周壁部係由氮化石夕 =用金屬、耐熱控m等材質, 周部以金屬、耐熱樹脂筈作為内襯之狀態。若如此於外 誤縣、缺損等之損;4壁部之嶋不易引起 因該擴張部lc内周壁而田六#優異0 生起因於粉末畴5丨_冷著補絲,極容易發 化砍陶-¾等成形,柯嘴阻塞’若該部分以氮 料粉末附著引起的冷嘴霧t嘴H粉末的_及起因於該原 面有必要以氮=少上述擴張部k之内周壁 分亦可由以往所使用之作爲i喷部1b等之其他部 峨爾成=4====壁面亦由氮 之阻塞。 叶伤末附者所引起之冷喷霧器用喷嘴 化矽陶瓷等製作成一㉟赤y v 、霧器用喷嘴1之全體以氮 以窗外功始t體成形’由經濟性之觀點觀之為較佳。 以氮化翔轉的單—材料製 ^圭 無特別限制,較好選擇使_且 Z p le等之方法,並 結:常職結、加纖結、再燒結 接形成擴張部之形狀。因為_紐料之情況下,燒結=之^ IP080245/0PGK00011 -〇p 9 200911383 理加工有困難之故。 竟,喊為以氮化乘N4)作為主成分之陶 瓷之溶體之#^(SIAL0N) °此氮化石夕陶 处構用2程陶二械性質的平衡性優異,為信雛高的 如猎由共價鍵而為強固且安定之結晶。因此, f造在低溫相的—為三方衫、在高溫曰曰 ί^ίί:ίΐ:ϊ i400"600〇c ^ t緻密燒結體。氮化_銳然在麵 熱膨脹係數職如34.5 xlOll左右,轉導性 分散Zr〇2)粉的粒子均-如構成基質度化之陶变複合材料。例 ^(si3N4)f 〇 化锆與部分安定化氧化錯之任-ΐ定化氧 料溫狀_ 著溫=晶系; 恐,故而在室溫之高溫相(正方晶、 空 定,而可抑制因升降溫引起的膨脹收縮或準安 為破壞原因之龜裂的傳播,由於自正方晶相轉變:單::受; IPO8O245/0PGKOOO] ι.〇ρ 200911383 之相變化強應力5/起 分安定 的狀態被安定介去Λ。瓜:Λ A 4 03工々日日Μ及立方晶 情況下,安定化氧化錯遭$4?0?器70用0232料來看的 用喷嘴的製造原^來看3=好^::5®:做為冷喷霧器 本身賦予高t;性’耐濺㉟特性優減^錯可對陶兗 之’2=7霧器“氧化=^ 究。然而,舰純化物系陶 丘由於各在週期表上同樣屬於第代族元素,因此 於電荷陰性度不同故亦具有離子鍵結性,因 成ί 之Λ合物。碳切之結構為以正三角形所構 原子因此於中心立置二配角置錐有1)3=個f點為Si原子或c 所構成者。有原子或Si原仅基本正四面體 圖2係有關本發明之冷噴霧器裳置概略圖。在圖2中 氣體高壓筒2、作用氣體用管線3及輸 二3 3、麵成。其中’於作用氣體用管線3及輸送氣 6α、όΓ ο ί別具備有:屢力調整器5a、5b、流量調整閥 613、流1計7&、71)以及壓力錶如、815等,予以調整來自 上述壓縮氣體高壓筒2的作用氣體及輪送氣體的壓力與流量。 in,用5翻管線3中,配置藉*電源9加熱之加熱器 兩字作用軋體加熱至原料粉末之炫點以下之温度後,導入冷 嘴務器噴搶11的喷槍腔室12内。於上述喷搶腔室I)役置壓 力計13及温度計14,驗控麵力與g狐至12 °又置壓 另一方面,原料供給機構係由原料粉末供給機構15以及 IP080245/0PGK000ll-〇p 11 200911383 附V又ft的汁量器16及原料粉末供給管路17所構ώ' 體用管線4,被導入原料粉末置H =上述輸送氣 由輪送氣體搬送至上述嘖搶腔室ϋ金° g。、出’而以固相狀態或固液共存狀態衝撞基材i8而^成二 此處使用的冷儒制噴嘴卜係如 之圓錐狀壓縮部lb及與該壓縮部lb J擴張社,且至少該擴張社之内壁面 喷嘴霧器用 嘴的阻塞得以大Si?原她末附者引起的冷喷霧器用喷 茲以實施例予以具體説明如下: [實施例1] 本實施例1係分別使用氮化石夕陶兗、氧化錯陶£、炭化矽 =堯以-體細品獲得® 1所補冷讀器时嘴。使用該冷 藉圖2所示之冷喷霧器装置進行冷喷霧器操 作。冷噴霧器之操作條件以及使用裝置如下表丨所列: IP080245/0PGK00011-OP 12 200911383 表1 原料粉末 銅粉末 原料粉末供給量 30克/分鐘 作用氣體及壓縮氣體 n2 作用氣體加熱溫度 500〇C/600〇C 冷喷霧器用喷嘴 喉部直徑:0 2mm 出口直徑:0 6 mm 長度:200 mm 腔體内氣體壓力 3 MPa 喷霧時間 30分鐘 其結果,操作30分鐘後,未發生冷喷霧器用噴嘴内壁部 之原料粉末附著,也未發生冷喷霧器用喷嘴阻塞。結果,以與 比較例比對之方式表示於表2。 [比較例] 圖1所示的冷喷霧器用喷嘴以使用習用不銹鋼予以一體 成型。該喷嘴利用圖2所示的冷喷霧器裝置進行冷喷霧操 操作條件以及使用裝置與實施例1相同。 、’' 其結果’操作4〜5分鐘後,原料粉末開始附著 張部’ 5〜6分鐘射嘴阻塞。 W、㈣之擴 表2 喷嘴材f 實施例 Si3N4陶究 Zr02陶瓷 SiC 陶 ( 比較例 不錄鋼 $ _______ 6 實施繼 作用氣體 60〇t 50〇tIP080245/0PGK00011-OP 200911383 Another full-system nozzle: better expansion and compression. Yes, the general _man, the carbon shouting arbitrarily - the expansion nozzle of the kind of ceramic mouth, preferably the cold sprayer spray comprises a cold-scale nozzle device of the present type, which is characterized by a gas mechanism for conveying gas; The nozzle is used. m is more than the above-mentioned - cold spray [effect of the invention] cold and cold spray with spray spray _ long life to reach cold ^, 1 此 mouth this no frequent replacement of cold 啧 Lin cry 4 pottery ' The inner peripheral wall surface of the nozzle for the cold sprayer related to βΛ明 is substantially fogged; = pickling treatment. Therefore, it is assumed that if the raw material powder is attached, the advantage of removing the attached raw material is easily obtained.实施 [Embodiment] The best mode for carrying out the invention will be described in detail. 1 is a cross-sectional view showing an embodiment of the nozzle of the present invention. The sleek 1 towel, the cold scorpion H, is made up of a conical compression portion lb having a tip end of the nozzle inlet end and a cross-section of the cross-section of the product. The nozzle for the two misters according to the present invention may have any other shape as long as it has at least the compressed portion Ib and the expanded portion lc. For example, a narrow throat may be provided between the compressed portion 1b and the above-described expansion portion lc, or a cylindrical parallel portion may be provided on the nozzle side of the expansion portion 1c, IP080245/0PGK00011 - 〇p 8 200911383. Flow direction. In Fig. 1, the arrow indicates that the raw material powder is at least the above-mentioned tantalum nitride ceramic and the oxidized ceramics, and at least the inner peripheral wall surface of the portion 1c is simply referred to as "nitrided ceramic" fossil.夕陶竟任任-者陶曼材料 (inclusive of the meaning of the expansion outside the ^ ^. Its stomach at least the inner circumference of only the inner peripheral wall is made of nitride stone = metal, heat-resistant m and other materials, the surface is made of metal The heat-resistant resin 筈 is used as the inner lining. If it is so, it is damaged by the county, the defect, etc.; 4 the wall portion is not easily caused by the inner wall of the expanded portion lc, and the field is excellent. Cold-filled silk, it is very easy to be cut into ceramics -3⁄4 and so on, and the mouth of the mouth is blocked. 'If the part is made of nitrogen powder, the cold mouth mist is caused by the powder of the nozzle, and it is necessary to use nitrogen in the original surface. The inner peripheral wall portion of the expansion portion k may be used as the other portion of the i-jet portion 1b or the like which is conventionally used. The wall surface is also blocked by nitrogen. The cold spray caused by the attachment of the leaf injury The mist is made of a nozzle bismuth ceramic, etc., and is formed into a 35-yy yv, and the entire nozzle 1 of the mist is formed by nitrogen outside the window. The economical viewpoint is better. There is no special restriction on the single-material system of nitriding, and it is better to choose the method of making _ and Z p le, etc., and to conclude: permanent knot, add fiber, Re-sintering to form the shape of the expansion portion. Because of the case of _News, the sintering = ^ IP080245 / 0PGK00011 - 〇p 9 200911383 has difficulty in processing. Actually, it is called nitriding by N4) as the main component. The solution of ceramic solution #^(SIAL0N) ° The structure of the nitrite ceramsite is excellent in the balance of the properties of the 2-way pottery, and it is the strong and stable crystal of the high-quality stalk. , f made in the low temperature phase - for the three-party shirt, at high temperature 曰曰 ί ^ ίί: ΐ ϊ i400 " 600 〇 c ^ t dense sintered body. Nitriding _ sharply in the surface thermal expansion coefficient as about 34.5 xlOll, turn The particles of the conductively dispersed Zr〇2) powder are all - such as the ceramic composite material constituting the matrix. Example ^(si3N4)f Zirconium hydride and part of the stability of the oxidation of the oxidized ΐ ΐ 化 化 氧 氧 _ Temperature = crystal system; fear, so the high temperature phase at room temperature (square crystal, empty, can inhibit expansion and contraction caused by lifting temperature or quasi-ampere The propagation of cracks for the cause of damage, due to the transition from the tetragonal phase: single:: accept; IPO8O245/0PGKOOO] ι.〇ρ 200911383 The phase change strong stress 5 / the stability of the state is settled by the stability. Λ A 4 03 々 々 Μ 立方 立方 立方 立方 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 4 Give the cold sprayer itself a high t; the nature of the 'splash-resistant 35 characteristics can be reduced or wrong. It can be used for the '2=7 fogger' oxidation of the pottery. However, the ship's purified system is due to the periodic table. It also belongs to the first generation element, so it has ionic bonding property due to the difference in charge negative degree. The structure of the carbon cut is an atom composed of an equilateral triangle, so that the center is placed at the center of the two-corner, and the cone is 1) 3 = the point f is a Si atom or a c. Atom or Si is only a substantially regular tetrahedron. Fig. 2 is a schematic view of the cold sprayer of the present invention. In Fig. 2, the gas high pressure cylinder 2, the working gas pipeline 3, and the second and third sides are formed. Here, 'the operating gas line 3 and the conveying gas 6α, ο ο ί are provided with: the relay adjusters 5a and 5b, the flow rate adjusting valve 613, the flow meter 7 & 71, and the pressure gauges such as 815, etc. The pressure and flow rate of the working gas and the carrier gas from the compressed gas high pressure cylinder 2 described above are adjusted. In, using 5 to turn the pipeline 3, the heater is heated by the heater of the power supply 9 and heated to the temperature below the dazzling point of the raw material powder, and then introduced into the spray gun chamber 12 of the cold nozzle spray 11 . In the above-mentioned spray chamber I), the pressure gauge 13 and the thermometer 14 are operated, and the surface force of the test surface is pressed against the gfox to 12 °. On the other hand, the raw material supply mechanism is supplied from the raw material powder supply mechanism 15 and IP080245/0PGK000ll- 〇p 11 200911383 The juice measuring device 16 with V and ft and the raw material powder supply line 17 are configured as the body line 4, and the raw material powder is introduced. H = the above-mentioned conveying gas is transported by the carrier gas to the above-mentioned smashing chamber. Sheet metal ° g. And the solid phase state or the solid-liquid coexistence state collides with the substrate i8, and the cold Confucian nozzle used herein is a conical compression portion lb and the expansion portion lb J, and at least The clogging of the mouth of the nozzle nozzle of the inner wall surface of the expansion company is large. The cold sprayer used by the former is specifically described as follows: [Example 1] This embodiment 1 uses nitrogen respectively. Fossil 兖 兖 兖, oxidized 陶 £ £, carbonized 矽 = 尧 - 体 体 ® ® 1 1 1 1 1 1 1 1 。 。 。 。 。 。 The cold sprayer operation was carried out using the cold sprayer apparatus shown in Fig. 2. The operating conditions and equipment of the cold sprayer are listed in the following table: IP080245/0PGK00011-OP 12 200911383 Table 1 Raw material powder Copper powder Raw material powder Supply amount 30 g / min Acting gas and compressed gas n2 Acting gas heating temperature 500 〇 C / 600 〇C Nozzle throat diameter for cold sprayer: 0 2mm Outlet diameter: 0 6 mm Length: 200 mm Gas pressure in chamber 3 MPa Spray time 30 minutes Result, after 30 minutes of operation, nozzle for cold sprayer does not occur The raw material powder of the inner wall portion adhered, and the nozzle of the cold atomizer was not blocked. The results are shown in Table 2 in comparison with the comparative examples. [Comparative Example] The nozzle for a cold sprayer shown in Fig. 1 was integrally molded using conventional stainless steel. This nozzle was subjected to the cold spray operation conditions and the use apparatus using the cold atomizer apparatus shown in Fig. 2 in the same manner as in the first embodiment. After 4 to 5 minutes of operation, the raw material powder began to adhere to the slab portion for 5 to 6 minutes. W, (4) Expansion Table 2 Nozzle material f Example Si3N4 ceramics Zr02 ceramic SiC ceramics (Comparative example No steel recording $ _______ 6 Implementation of the reaction gas 60〇t 50〇t

IP080245/0PGK00011-OP 13 200911383 體)’衝撞之原料粒子對於冷儒器时嘴 小。因此’認為冷喷霧器用噴嘴的構成材料差異變得不明顯顯 現。 結果,自喷術且塞狀況來看,相較於比較例,明顯地,實 施例較優異。作用乱體溫度高’原料粉末A致接近目液混合狀 態,衝撞之補粒子對冷儒㈣喷嘴_部之崎變 比較例之使用不錄鋼形成之冷喷霧器用喷嘴之情況下,且 現象顯著,於3〜4分鐘阻塞’無法操作冷喷霧器。相反;也 施例所示之各以氮化矽陶瓷、氧化鍅陶瓷、碳化矽陶 形成之冷喷霧H用喷嘴之情況下,難以引起原料粒子對於 壁面之附著現象,於30分鐘連續操作冷喷霧器,完全未發生 噴嘴阻塞。 x [産業上的利用可能性] 依據本發明之冷喷霧器用喷嘴以及使用該冷喷霧器 嘴的冷喷霧器裝置’可使冷喷霧器操作時之原料粉末對噴嘴的 附著以及起因於原料粉末附著引起的喷嘴阻塞得以大幅減 少,能達成喷嘴長壽命化。因而,不需要頻繁的更換嘴嘴。曰因 此,本發明對冷喷霧器技術的實用化極爲有用。、、 又,本發明之冷喷霧器用喷嘴的内周壁面基本上為陶究材 質,因此可藉由酸洗處理。因此,假定即使原料粉末附著於冷 喷霧器用噴嘴之内壁面,可藉浸潰於酸溶液中,而容易地去^ 内周壁面上附著的原料,重複使用的便利性亦高。 【圖式簡單說明】 圖1係表示有關本發明冷喷霧器用喷嘴之一實祐 概略剖面圖。 也办匕'的 圖…2係有關本發明冷喷霧器裝置之概略圖。又,圖式中 所示之茹頭係表示原料粉末之流向。 IP080245/OPGKOOO11 -〇p 14 200911383 【主要元件符號說明】 1 冷喷霧器用喷嘴 la 喷嘴入口 lb 圓錐狀壓縮部 lc 圓錐狀擴張部IP080245/0PGK00011-OP 13 200911383 体) The raw material particles of the collision are small for the cold Confucian. Therefore, it is considered that the difference in the constituent materials of the nozzle for the cold atomizer becomes inconspicuous. As a result, from the viewpoint of the squirting and the plugging condition, the embodiment was remarkably superior to the comparative example. The effect of the chaotic body is high. The raw material powder A is close to the mixed state of the liquid, and the colloidal particles of the collision are used in the case of the nozzle of the cold sprayer formed by the non-recorded steel. Significantly, blocked in 3 to 4 minutes 'cannot operate the cold sprayer. On the other hand, in the case of the cold spray H nozzle formed by the tantalum nitride ceramic, the yttria ceramic, or the tantalum tantalum ceramic as shown in the example, it is difficult to cause the adhesion of the raw material particles to the wall surface, and the continuous operation is performed for 30 minutes. Sprayer, no nozzle blockage occurred at all. x [Industrial Applicability] According to the cold sprayer nozzle of the present invention and the cold sprayer device using the cold sprayer nozzle, the adhesion and origin of the raw material powder to the nozzle during the operation of the cold sprayer can be made. The nozzle clogging caused by the adhesion of the raw material powder is greatly reduced, and the life of the nozzle can be extended. Thus, there is no need to change the mouth frequently. Therefore, the present invention is extremely useful for the practical use of cold sprayer technology. Further, since the inner peripheral wall surface of the nozzle for a cold sprayer of the present invention is basically a ceramic material, it can be treated by pickling. Therefore, even if the raw material powder adheres to the inner wall surface of the nozzle for the cold sprayer, it can be easily immersed in the acid solution, and the raw material adhering to the inner peripheral wall surface can be easily removed, and the convenience of repeated use is high. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a schematic cross-sectional view showing a nozzle for a cold sprayer of the present invention. Also Fig. 2 is a schematic view of the cold atomizer device of the present invention. Further, the ruthenium shown in the drawing indicates the flow direction of the raw material powder. IP080245/OPGKOOO11 -〇p 14 200911383 [Explanation of main component symbols] 1 nozzle for cold sprayer la nozzle inlet lb conical compression section lc conical expansion section

Id 噴嘴出口 2 壓縮氣體高壓筒 3 動作氣體用管線 4 輸送氣體用管線 5a 壓力調整器 5b 壓力調整器 6a 流量調整閥 6b 流量調整閥 . 7a 流量計 7b 流量計 8a 壓力錶 8b 壓力錶 9 電源 10 加熱器 11 冷喷霧器噴槍 12 喷槍腔室 13 壓力錶 14 温度計 15 原料粉末供給裝置 16 計量器 17 原料粉末供給管路 18 基材 IP080245/0PGK00011-OP 15Id nozzle outlet 2 compressed gas high pressure cylinder 3 operating gas pipeline 4 conveying gas pipeline 5a pressure regulator 5b pressure regulator 6a flow regulating valve 6b flow regulating valve. 7a flowmeter 7b flowmeter 8a pressure gauge 8b pressure gauge 9 power supply 10 Heater 11 Cold sprayer spray gun 12 Gun chamber 13 Pressure gauge 14 Thermometer 15 Raw material powder supply device 16 Meter 17 Raw material powder supply line 18 Substrate IP080245/0PGK00011-OP 15

Claims (1)

200911383 十、申請專利範園: 1. 一種冷喷霧器用嗔嘴,宜在主鄉达a 、 部及與該_部猶端細尖之_狀_ 度為原料粉末之熔點以下;錐:擴張部,利用其溫 氧化鍅陶瓷 2 隻之任歎:陶究、 .壓====嘴嘴’其中該擴張部及 -者陶mm形成氧⑽喊、碳切陶甍之任 3·如申请專利範圍第2項之 器用喷嘴之擴張部及_部43=嘴’其中上述冷喷霧 4· -種冷喷霧器裝置,其特徵U成形者。 供給原料粉末的原料供給機構. 用氣體與輸送氣體之氣體 具傷有利用其溫度為原料粉末:機構;以及 料粉末作為超音速喷流予以喷嘻^下的作用氣體,將原 中 、、嘴的冷噴霧器嗔槍,其 於該噴嘴係使用如申請專利範圍 項之冷喷霧器用喷嘴。 IP080245/0PGK0001l,〇p200911383 X. Applying for a patent garden: 1. A cold sprayer with a mouth, which should be below the melting point of the raw material powder in the main village, a part, and the _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ Ministry, using its warm yttria ceramics 2 sigh: 陶,, press ==== mouth mouth, where the expansion and - the pottery mm form oxygen (10) shouting, carbon cut pottery 3) The expansion portion of the nozzle for the device of the second aspect of the patent and the portion 43 of the nozzle for the above-mentioned cold spray 4 - cold sprayer device are characterized in that they are shaped. The raw material supply mechanism for supplying the raw material powder. The gas which is used for the gas and the gas to be transported is used as a raw material powder: a mechanism; and a powder which is used as a supersonic jet to sneeze, and the original medium and the mouth are used. A cold spray gun, which uses a nozzle for a cold sprayer as claimed in the patent application. IP080245/0PGK0001l, 〇p
TW97111775A 2007-04-02 2008-03-31 Nozzle used in cold sprayer and cold sprayer device TWI417143B (en)

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JP6889862B2 (en) 2017-07-05 2021-06-18 プラズマ技研工業株式会社 Cold spray gun and cold spray device equipped with it
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