200846502 九、發明說明 【發明所屬之技術領域】 本發明係關於臭氧水產生裝置。 【先前技術】 現在，在產業用普及的臭氧水的製法，係大致區分 爲：讓藉由放電而產生的臭氧氣體溶解的氣體溶解法、使 藉由電解而產生的臭氧氣體溶解於水的電解氣體溶解法、 使原料水直接接觸於電解面而使臭氧水產生的直接電解法 之3方式而被實用。直接電解法，係比起氣體溶解法或電 解氣體溶解法，可知爲以更簡單的方法而可產生高濃度的 臭氧水。 如此的直接電解法，例如如專利文獻1所示地，在由 陽極側蓋板和陰極側蓋板所構成的框體內，收容：固形電 解質膜、和設置於該兩面的陽極電極板及陰極電極板，藉 由在陽極電極板與陰極電極板之間供給了直流電流的狀 態，從通到陽極電極的流入口使原水供給，從通到陰極電 極的流入口使電解液供給，而電性分解原水而產生臭氧 水。在此，通到陽極電極的流入口，係以從陽極側蓋板的 表面連通於陽極電極的方式形成流路而成，通到陰極電極 的流入口，係以從陰極側蓋板的表面連通於陰極電極的方 式形成流路，將挾持了陽離子交換膜的陽極電極側與陰極 電極側，成爲各別流通原水及電解水。 [專利文獻1]日本特開2002-292 370號公報 200846502 【發明內容】 然而，上述先前的臭氧水產生裝置，係2個流入口爲 各別被設置於互相相對配置的陽極側蓋板與陰極側蓋板， 因此有裝置本身爲大型化的問題。另外，如上述般地將二 個流入口各別設置蓋板內之情事，係流路變得複雜，在藉 * 由簡單的樹脂成形而形成的情況係難以形成複雜的流路。 φ 本發明係鑑於上述事情而爲之物，其目的爲提供：不 形成用以供給原料水之複雜的流路而爲單純的構造、可謀 求小型化之臭氧水產生裝置。 爲了解決上述課題，申請專利範圍第1項的發明，係 例如第5圖〜第8圖所示地，係在陽極電極22與陰極電 極2 3之間挾持陽離子交換膜2 1而成之觸媒電極2，藉由 在供給水的同時，在前述陽極電極與前述陰極電極之間施 加直流電壓而產生臭氧水之臭氧水產生裝置100， Φ 以：於收容前述觸媒電極的外殻本體1，設置對前述陽極 電極及前述陰極電極供給水的原料水供給路1 3， " 在面臨前述陽離子交換膜的前述原料水供給路之部 — 分，設置互相連通前述陽極電極與前述陰極電極的連通穴 211， 從前述原料水供給路流出的水，係在供給於前述陽極 電極及前述陰極電極之中的一方的電極的同時，經由前述 連通穴而被供給於另一方的電極， 作爲其特徵之臭氧水產生裝置。 -5- 200846502 如藉由申請專利範圍第1項的發明，則在 交換膜的原料水供給路的部分，設置陽極電極 爲相互連通的連通穴’從原料水供給路流出的 供給於一方的電極的同時，經由連通穴而供給 電極，所以不將原料水供給路，在陽極電極側 側各別地形成而作爲複雜的供給路，而是以只 而共有一個原料水供給路，可將水各別容易地 電極側與陰極電極側。因而，構造亦變單純， 的小型化。’ 申請專利範圍第2項的發明，係例如如第 圖所示地，在申請專利範圍第1項所記載的臭 置，以： 於前述外殼本體，各別設置：連通於前述 排出在前述陽極電極產生的臭氧水的臭氧水排; 連通於前述陰極電極，排出在前述陰極電極產 的陰極水排出路1 5， 前述臭氧水排出路及前述陰極水排出路 (臭氧水排出口 1 43、陰極水排出口 1 5 3 )係 外殼本體的同一面而設置， 前述臭氧水排出路之連通於前述陽極電極 前述陰極水排出路之連通於前述陰極電極的部 已被挾持於前述陽極電極與前述陰極電極之間 子交換膜而被隔開， 作爲其特徵。 面臨陽離子 與陰極電極 水係因爲在 於另一方的 與陰極電極 形成連通穴 供給於陽極 可謀求裝置 5圖〜第8 氧水產生裝 陽極電極， ϋ路1 4、和 生的陰極水 的各排出口 相鄰於前述 的部分、和 分，爲藉由 的前述陽離 -6 - 200846502 如申請專利範圍第2項的發明，則臭氧水排出路之連 通於陽極電極的部分、與陰極水排出路之連通於陰極電極 的部分，係因爲藉由被挾持於兩電極間的陽離子交換膜而 被隔開，所以在陽極電極側產生的臭氧水、和在陰極電極 側產生的陰極水爲不混合，可通過各個臭氧水排出路及陰 極水排出路內而使之確實地排出。 另外，臭氧水排出路及陰極水排出路的各排出口係因 爲鄰接於外殼本體的同一面而設置，所以可謀求裝置的薄 型化。 申請專利範圍第3項的發明，係例如如第1圖、第2 圖、第9圖所示地，在記載於申請專利範圍第2項的臭氧 水產生裝置， 具備在支持前述外殼本體的同時、自由裝卸的安裝台 3， 於前述安裝台，設置：連接於被設置在前述外殻本體 的前述臭氧水排出路之其他的前述臭氧水排出路32，在已 設置於前述安裝台的前述臭氧水排出路，設置檢測臭氧水 的臭氧濃度的濃度檢測手段（例如：濃度檢測感測器 4 )。 如藉由申請專利範圍第3項的發明，則設置在支持外 殼本體的同時，自由裝卸的安裝台，於安裝台設置其他的 臭氧水排出路’因爲在安裝台側的臭氧水排出路設置著濃 度檢測手段’所以可產生藉由濃度檢測手段而設定之特定 濃度的臭氧水。另外，濃度檢測手段，係因爲被設置在自 200846502 由裝卸於外殼本體的安裝台，所以在外殼本體的維護或交 換的情況，沒有將濃度檢測手段進行不必要的交換之必 要，可降低成本。 申請專利範圍第4項的發明，係例如：如第2圖、第 5圖所示地，在申請專利範圍第3項所記載的臭氧水產生 裝置，以： 前述陽極電極（例如：棒狀電極部2 5 )，係突出於前 述外殼本體的外部而設置， 藉由前述安裝台被安裝於前述外殼本體，而按壓突出 的前述陽極電極而按壓前述陽離子交換膜， 作爲其特徵。 如藉由申請專利範圍第4項的發明，則陽極電極係突 出於外殼本體的外部而設置，安裝台爲藉由被安裝於外殼 本體，因爲突出的陽極電極被按壓而陽離子交換膜被按 壓，所以藉由因安裝台的按壓力而可容易地調整朝向陽離 子交換膜的壓接力。 申請專利範圍第5項的發明，係例如：如第1 0圖所 示地，在申請專利範圍第3項或第4項所記載的臭氧水產 生裝置100A，以： 前述外殼本體1A的至少一部分係由磁性材料17A所 構成，於前述安裝台3A設置磁鐵37A，作爲其特徵。 如藉由申請專利範圍第5項的發明，則外殼本體的至 少一部分爲由磁性材料所構成，因爲於安裝台被設置磁 鐵，所以外殼本體與安裝台爲由磁力而吸附，可將外殼本 -8- 200846502 體與安裝台作爲容易自由裝卸的構造。 申請專利範圍第6項的發明，係在申請專利範圍第5 項所記載的臭氧水產生裝置，以前述磁鐵爲電磁鐵作爲其 特徵。 如錯由申請專利範圍第6項的發明，則藉由使用電磁 鐵’則藉由電磁鐵的開關而在可將外殼本體與安裝台，比 起在磁鐵的情況作爲更容易自由裝卸的構造的同時，可電 性地控制朝向外殼本體的安裝台的按壓力，可電性地容易 調整陽極電極被按壓而朝向陽離子交換膜的按壓力。 【實施方式】 以下，關於本發明的實施形態一邊參照圖面一邊說 明。 第1圖爲臭氧水產生裝置100的外觀立體圖、第2圖 爲臭氧水產生裝置1〇〇的分解立體圖。 • 有關本發明的臭氧水產生裝置1 00，係在被供給原料 水（例如：自來水）的外殼本體1內配置觸媒電極2 (參 • 照後述的第5圖）而構成之物’藉由對觸媒電極2施加直 . 流電壓而使細微的臭氧氣泡產生’藉由使即將產生的細微 臭氧氣泡溶解於水而可產生臭氧水的裝置。 第3圖爲構成臭氧水產生裝置100的外殼本體（第一 外殼1及第二外殼12) 1的立體圖、第4圖爲在嵌合第一 外殼11及第二外殼1 2的狀態’從第一外殼11側所見時 的透視平面圖、第5圖爲在第一外殼11安裝了安裝台3 -9- 200846502 的狀態，沿著在第4圖的切斷線V-V而切斷時之所見剖 面圖。 如第1圖〜第3圖所示地，臭氧水產生裝置100，係 具備：由可相互地嵌合的第一外殼11及第二外殻12所構 成的外殼本體1、和自由裝卸地被安裝於第一外殼11的一 方的面（與第二外殻12相反側的面）lib而支持外殼本體 1的安裝台3。外殼本體1及安裝台3係藉由射出成形成 被成形。 如第3圖所示地，第一外殼1 1，係爲矩形板狀，在與 第二外殼12的嵌合面11a形成後述的第二外殼12的凸部 121可嵌入之第一凹部111，於此第一凹部111，係在後述 的觸媒電極2的陽極電極22之中，更形成配置了板狀電 極部24的第二凹部112。另外，在嵌合面11a，係以包圍 第一凹部111的周圍的方式形成略矩形框狀的溝部113, 在此溝部1 1 3內被嵌入〇型環1 1 4 (參照第5圖）。藉 由Ο型環114而於第一外殼11的嵌合面11a，在設置了 後述的第二外殼1 2的情況，在第一外殼1 1的嵌合面1 i a 與第二外殼12的嵌合面l2a之間係被密封，成爲耐壓性 及水密性優良之物。 於第一外殼1 1，係形成用以對配置於第二凹部1 1 2內 的觸媒電極2之陽極電極22及陰極電極23供給原料水的 原料水供給路1 3。原料水供給路丨3，係具備從與嵌合面 Ha相反側的面lib朝向第一外殼n的厚度方向，貫通第 一凹部111而形成的貫通穴131、與從貫通穴131朝向第 -10- 200846502 二凹部1 1 2而延伸的溝部1 3 2。另外，在爲貫通穴1 3 1的 入口之原料水供給口 1 3 3，成爲安裝被設置於後述的安裝 台3的原料水供給管3 4 (參照第2圖）。 另外，於第一外殼1 1，係用以排出藉由觸媒電極2的 陽極電極22而產生的臭氧水之臭氧水排出路14，係連通 於陽極電極22而形成。臭氧水排出路14，係具備：從與 嵌合面11a相反側的面lib朝向第一外殼11的厚度方 向，貫通第一凹部111而形成的貫通穴141、與從貫通穴 141朝向第二凹部1 12而延伸的溝部142。另外，在爲貫 通穴141的出口之臭氧水排出口_ 1 43，成爲安裝被設置於 後述的安裝台3的臭氧水排出管351 (參照第2圖）。 另外，於第一外殼1 1，係用以排出在觸媒電極2的陰 極電極23與臭氧水同時產生的陰極水之陰極水排出路 1 5，係連通於陰極電極2 3而形成。陰極水排出路1 5，係 具備：從與嵌合面1 1 a相反側的面i〗b朝向第一外殼i j 的厚度方向，貫通第一凹部111而形成的貫通穴151、與 從貫通穴151朝向形成於第一凹部ill的壁面iiia而延 伸，切去該壁面111a的一部分而形成的溝部152。另外， 在爲貫通穴151的出口之陰極水排出口 153，係成爲安裝 被設置於後述的安裝台3的陰極水排出管3 6 1 (參照第2 圖）。另外，臭氧水排出口 143與陰極水排出口 153，係 被形成於爲外殼本體1 (第一外殻1 1 )的同一面之前述相 反側的面1 1 b，臭氧水排出管3 5 1與陰極水排出管3 6丨係 因爲從前述相反側的面1 1 b突出，所以成爲可謀求裝置全 -11 - 200846502 體的薄型化。 上述原料水供給口 1 3 3，係被設置於第一外殼1 1的長 邊方向一端部側（第4圖中，下端部側），臭氧水排出口 1 43及陰極水排出口 1 5 3，係被設置於第一外殻1 1的長邊 方向另一端部側（第4圖中，上端部側）。 另外，如第2圖所示地，在與第一外殼11的嵌合面 1 1 a相反側的面1 1 b，係形成延伸於短邊方向的第四凹部 16’在此第四凹部16內，配置著向第一外殼11的外部突 出之，後述的陽極電極22的棒狀電極部25。如第3圖所 示地’第二外殼12，係爲略矩形板狀，比起第一外殼11 而厚度變得更薄。在第二外殼12之與第一外殼11的嵌合 面12a，係形成被嵌入第一外殻的第一凹部ill內的凸 部 121。 凸部1 2 1，係具備：沿著第一凹部1 1 1的內壁面；i丨j a 而抵接的框狀部122、與被框狀部122 —體成形，在嵌合 第二外殼1 2時覆蓋臭氧水排出路〗4的蓋部1 23、與以相 對於陰極水排出路1 5的溝部1 5 2和第二凹部1 1 2的方式 被直線狀地形成的溝部1 24、與被一體地形成於框狀部 122的一部分而在嵌合第二外殼12時，覆蓋原料水供給路 13的溝部132之延出部126。如此地進行而形成的凸部 121的內側，係成爲在觸媒電極2的陰極電極23之內，被 配置板狀電極部27的第三凹部125。也就是，在藉由第一 外殼1 1的第二凹部1 1 2與第二外殻1 2的第三凹部1 25而 形成的收容部1 1 0 (參照第5圖）收容觸媒電極2。 -12 -200846502 IX. Description of the Invention [Technical Field of the Invention] The present invention relates to an ozone water generating device. [Prior Art] At present, the method for producing ozone water which is widely used in the industry is roughly classified into a gas dissolution method in which ozone gas generated by discharge is dissolved, and an ozone gas generated by electrolysis is dissolved in water. The gas dissolution method and the direct electrolysis method in which the raw material water is directly contacted with the electrolytic surface to generate ozone water are practical. The direct electrolysis method is known to produce a high concentration of ozone water in a simpler manner than the gas dissolution method or the electrolytic gas dissolution method. In such a direct electrolysis method, for example, as shown in Patent Document 1, a solid electrolyte membrane and an anode electrode plate and a cathode electrode provided on the both surfaces are housed in a casing composed of an anode side cover and a cathode side cover. The plate is supplied with a direct current between the anode electrode plate and the cathode electrode plate, and the raw water is supplied from the inlet to the anode electrode, and the electrolyte is supplied from the inlet to the cathode electrode, and the electrolyte is electrically decomposed. Ozone water is produced from raw water. Here, the inflow port leading to the anode electrode is formed by forming a flow path from the surface of the anode side cover plate to the anode electrode, and the flow port leading to the cathode electrode is connected from the surface of the cathode side cover plate. A flow path is formed in the form of a cathode electrode, and the anode electrode side and the cathode electrode side of the cation exchange membrane are held, and the raw water and the electrolyzed water are separately distributed. [Patent Document 1] Japanese Laid-Open Patent Publication No. 2002-292370 No. 200846502 SUMMARY OF THE INVENTION However, in the above-described conventional ozone water generating apparatus, two inlets are provided on the anode side cover and the cathode which are disposed to face each other. The side cover, therefore, has the problem that the device itself is large. Further, as described above, when the two inlets are provided in the respective cover plates, the flow path is complicated, and it is difficult to form a complicated flow path when formed by simple resin molding. φ The present invention has been made in view of the above-mentioned circumstances, and an object of the invention is to provide an ozone water generating device which can be reduced in size without forming a complicated flow path for supplying raw material water. In order to solve the above problems, the invention of claim 1 is a catalyst obtained by sandwiching a cation exchange membrane 2 1 between an anode electrode 22 and a cathode electrode 23 as shown in Figs. 5 to 8 . The electrode 2 generates an ozone water generating apparatus 100 for generating ozone water by applying a DC voltage between the anode electrode and the cathode electrode while supplying water, and Φ is for housing the body 1 of the catalyst electrode. a raw material water supply path 13 for supplying water to the anode electrode and the cathode electrode, and a portion connecting the anode electrode and the cathode electrode in a portion facing the raw material water supply path of the cation exchange membrane In the hole 211, the water that has flowed out of the raw material water supply path is supplied to one of the anode electrode and the cathode electrode, and is supplied to the other electrode via the communication hole, and is characterized by Ozone water generating device. In the invention of the first aspect of the invention, in the portion of the raw material water supply path of the exchange membrane, the anode electrode is provided as a communication hole that communicates with each other and flows from the raw material water supply path to one of the electrodes. At the same time, since the electrode is supplied through the communication hole, the raw material water is not supplied to the anode, and the anode electrode side is separately formed as a complicated supply path, and only one raw material water supply path is shared, and each water can be supplied. Do not easily electrode side and cathode electrode side. Therefore, the structure is also simple and miniaturized. In the invention of claim 2, for example, as shown in the figure, the odor described in the first aspect of the patent application is as follows: the casing body is separately provided to communicate with the discharge at the anode The ozone water discharged from the ozone water generated by the electrode is connected to the cathode electrode, and the cathode water discharge path 15 produced by the cathode electrode is discharged, the ozone water discharge path and the cathode water discharge path (ozone water discharge port 143, cathode) The water discharge port 1 5 3 ) is provided on the same surface of the casing body, and the portion of the ozone water discharge path that communicates with the anode electrode and communicates with the cathode electrode in the cathode water discharge path is held by the anode electrode and the cathode The electrodes are separated by a sub-exchange membrane as a feature. The cation and cathode electrode water system is supplied to the anode by the other cathode and the cathode electrode, and the anode electrode of the device 5 to the eighth oxygen water generating device, the circuit 14 and the discharge port of the raw cathode water are obtained. The portion and the portion adjacent to the foregoing are the inventions of the above-mentioned cations -6 - 200846502, as in the second aspect of the patent application, the portion of the ozone water discharge path that communicates with the anode electrode, and the cathode water discharge path. The portion connected to the cathode electrode is separated by the cation exchange membrane held between the electrodes, so the ozone water generated on the anode electrode side and the cathode water generated on the cathode electrode side are not mixed. Each of the ozone water discharge passage and the cathode water discharge passage are reliably discharged. Further, since each of the discharge ports of the ozone water discharge passage and the cathode water discharge passage is provided adjacent to the same surface of the casing main body, it is possible to reduce the thickness of the apparatus. In the invention of claim 3, for example, as shown in FIG. 1, FIG. 2, and FIG. 9, the ozone water generating apparatus of the second aspect of the patent application is provided to support the casing body. The mounting base 3 that is detachably attached to the mounting base is provided with the ozone water discharge passage 32 connected to the ozone water discharge passage provided in the outer casing main body, and the ozone provided on the mounting base The water discharge path is provided with a concentration detecting means for detecting the ozone concentration of the ozone water (for example, the concentration detecting sensor 4). According to the invention of claim 3, the mounting base that is detachably mounted while supporting the main body of the casing is provided with another ozone water discharge path at the mounting table because the ozone water discharge path on the mounting table side is provided. The concentration detecting means' can generate ozone water of a specific concentration set by the concentration detecting means. Further, since the concentration detecting means is provided in the mounting table attached to and detached from the casing body since 200846502, in the case of maintenance or exchange of the casing body, it is not necessary to exchange the concentration detecting means unnecessarily, and the cost can be reduced. In the ozone water generating device according to the third aspect of the invention, the anode electrode (for example, a rod electrode) is described in the second aspect of the invention. The portion 2 5 ) is provided to protrude from the outside of the casing body, and is attached to the casing body by the mounting base, and the protruding anode electrode is pressed to press the cation exchange film. According to the invention of claim 4, the anode electrode is provided to protrude from the outside of the casing body, and the mounting table is mounted on the casing body, and the cation exchange film is pressed because the protruding anode electrode is pressed. Therefore, the crimping force toward the cation exchange membrane can be easily adjusted by the pressing force of the mounting table. The invention of claim 5, wherein the ozone water generating apparatus 100A according to the third or fourth aspect of the patent application, as shown in Fig. 10, is characterized in that: at least a part of the outer casing body 1A It is composed of a magnetic material 17A, and a magnet 37A is provided on the mounting table 3A as a feature. According to the invention of claim 5, at least a part of the outer casing body is made of a magnetic material, because the magnet is attached to the mounting base, so that the outer casing body and the mounting table are magnetically attracted, and the outer casing can be 8- 200846502 The body and the mounting table are constructed as easy to handle. The invention of claim 6 is the ozone water generating apparatus according to the fifth aspect of the invention, wherein the magnet is an electromagnet. According to the invention of claim 6 of the patent application, by using the electromagnet, the outer casing main body and the mounting base can be more easily attached and detached than the magnet by the opening and closing of the electromagnet. At the same time, the pressing force of the mounting table toward the casing body can be electrically controlled, and the pressing force of the anode electrode pressed against the cation exchange membrane can be easily adjusted electrically. [Embodiment] Hereinafter, embodiments of the present invention will be described with reference to the drawings. Fig. 1 is an external perspective view of the ozone water generating device 100, and Fig. 2 is an exploded perspective view of the ozone water generating device 1A. In the ozone water generating device 100 of the present invention, the catalyst electrode 2 is disposed in the casing main body 1 to which the raw material water (for example, tap water) is supplied (see Fig. 5, which will be described later). Applying a direct current voltage to the catalyst electrode 2 causes fine ozone bubbles to generate a device that generates ozone water by dissolving the immediately generated fine ozone bubbles in water. 3 is a perspective view of the casing body (the first casing 1 and the second casing 12) 1 constituting the ozone water generating device 100, and FIG. 4 is a state in which the first casing 11 and the second casing 12 are fitted. A perspective plan view when seen on the side of a casing 11 and a fifth view showing a state in which the mounting table 3 -9-200846502 is attached to the first casing 11 and is cut along the cutting line VV of Fig. 4 . As shown in FIG. 1 to FIG. 3, the ozone water generating device 100 includes a casing body 1 composed of a first casing 11 and a second casing 12 that can be fitted to each other, and is detachably attached. The mounting surface 3 of the casing body 1 is supported by being attached to one surface (surface opposite to the second casing 12) lib of the first casing 11. The casing body 1 and the mounting table 3 are formed by injection molding. As shown in FIG. 3, the first outer casing 1 is formed in a rectangular plate shape, and the convex portion 121 of the second outer casing 12, which will be described later, can be fitted into the first concave portion 111, which is formed in the fitting surface 11a of the second outer casing 12, In the first recessed portion 111, a second recessed portion 112 in which the plate-like electrode portion 24 is disposed is formed in the anode electrode 22 of the catalyst electrode 2 to be described later. Further, the fitting surface 11a is formed with a substantially rectangular frame-shaped groove portion 113 so as to surround the periphery of the first concave portion 111, and the 〇-shaped ring 1 1 4 is fitted into the groove portion 1 1 3 (see Fig. 5). In the case where the second outer casing 12 to be described later is provided on the fitting surface 11a of the first casing 11 by the Ο-shaped ring 114, the fitting surface 1 ia of the first outer casing 1 and the second outer casing 12 are embedded. The joint surface l2a is sealed and is excellent in pressure resistance and watertightness. The raw material water supply path 13 for supplying the raw material water to the anode electrode 22 and the cathode electrode 23 of the catalyst electrode 2 disposed in the second recess 1 1 2 is formed in the first outer casing 11. The raw material water supply path 3 is provided with a through hole 131 formed by penetrating the first concave portion 111 from the surface lib opposite to the fitting surface Ha toward the thickness direction of the first outer casing n, and from the through hole 131 toward the tenth - 200846502 The groove portion 1 3 2 extending from the two recesses 1 1 2 . In addition, the raw material water supply port 1 3 3 which is the inlet of the through hole 1 3 1 is attached to the raw material water supply pipe 3 4 (see Fig. 2) which is attached to the mounting base 3 which will be described later. Further, the first outer casing 1 1 is formed by discharging the ozone water discharge path 14 of ozone water generated by the anode electrode 22 of the catalyst electrode 2, and is connected to the anode electrode 22. The ozone water discharge passage 14 includes a through hole 141 formed to penetrate the first recess 111 from the surface lib opposite to the fitting surface 11a in the thickness direction of the first casing 11, and a second recess from the through hole 141 The groove portion 142 extends 1 12 . In the ozone water discharge port _ 1 43, which is the outlet of the through hole 141, the ozone water discharge pipe 351 (see Fig. 2) to be mounted on the mounting table 3 to be described later is attached. Further, the first casing 11 is formed by discharging the cathode water discharge path 15 of the cathode water generated simultaneously with the ozone electrode 23 of the catalyst electrode 2 and the cathode electrode 23. The cathode water discharge path 15 includes a through hole 151 formed through the first concave portion 111 from a surface i of the opposite side of the fitting surface 1 1 a toward the thickness direction of the first outer casing ij, and a through hole The 151 extends toward the wall surface iiia of the first recess ill, and the groove portion 152 formed by cutting a part of the wall surface 111a is cut away. In addition, the cathode water discharge port 153 which is the outlet of the through hole 151 is attached to the cathode water discharge pipe 361 (see Fig. 2) provided in a mounting table 3 which will be described later. Further, the ozone water discharge port 143 and the cathode water discharge port 153 are formed on the opposite side surface 1 1 b of the same surface of the casing body 1 (first casing 1 1 ), and the ozone water discharge pipe 3 5 1 Since the cathode water discharge pipe 36 is protruded from the surface 1 1 b on the opposite side, it is possible to reduce the thickness of the device -11 - 200846502. The raw material water supply port 133 is provided on one end side of the first outer casing 1 1 in the longitudinal direction (the lower end side in Fig. 4), the ozone water discharge port 143 and the cathode water discharge port 1 5 3 The other end side of the first outer casing 11 is disposed in the longitudinal direction (the upper end side in Fig. 4). Further, as shown in Fig. 2, a fourth recess 16' extending in the short-side direction is formed on the surface 1 1 b on the side opposite to the fitting surface 11 a of the first casing 11 in the fourth recess 16 The rod electrode portion 25 of the anode electrode 22 which will be described later, which protrudes to the outside of the first casing 11, is disposed. As shown in Fig. 3, the second outer casing 12 has a substantially rectangular plate shape and becomes thinner than the first outer casing 11. On the fitting surface 12a of the second outer casing 12 with the first outer casing 11, a convex portion 121 which is fitted into the first concave portion ill of the first outer casing is formed. The convex portion 1 1 1 includes a frame-shaped portion 122 that is in contact with the inner wall surface of the first concave portion 1 1 1 and is formed integrally with the frame-shaped portion 122, and is fitted to the second outer casing 1 At 2 o'clock, the cover portion 1 23 covering the ozone water discharge path 4 and the groove portion 1 24 formed linearly with respect to the groove portion 155 and the second recess portion 1 1 2 of the cathode water discharge path 15 are provided. When the second outer casing 12 is fitted to a part of the frame-shaped portion 122, the extension portion 126 of the groove portion 132 of the raw material water supply path 13 is covered. The inside of the convex portion 121 formed in this manner is the third concave portion 125 in which the plate-shaped electrode portion 27 is disposed in the cathode electrode 23 of the catalyst electrode 2. That is, the accommodating portion 1 1 0 (refer to FIG. 5) formed by the second concave portion 1 1 2 of the first outer casing 1 and the third concave portion 152 of the second outer casing 1 2 accommodates the catalyst electrode 2 . -12 -
200846502 另外，如第1圖所示地，於第二外殼12 與相反側的面1 2b，係突出著陰極電極2 3的 28。而且，在前述相反側的面12b的周緣部， 絲釘N1以特定間隔被設置，藉由此而締結第― 第二外殼1 2。 第6A圖爲將沿著在第5圖的切斷線VI 一 斷的情況，模式的表示之所見平面圖、第6B 第6A圖的切斷線Vi—b —VI-b而切斷時之所貝 6C圖爲沿著在第6A圖的切斷線VI -c-VI -c而 見剖面圖、第7A圖爲將沿著在第5圖的切斷 而切斷的情況，模式的表示之所見平面圖、第 著在第 7A圖的切斷線VE-b-W-b而切斷時 圖、第7C圖爲沿著在第7A圖的切斷線W -c-時之所見剖面圖、第7D圖爲沿著在第7A圖 d-VD -d而切斷時之所見剖面圖、第8圖爲觸瑀 解立體圖。 觸媒電極2係具備：陽離子交換膜21、β. 子交換膜21的一方的面（第8圖中，下面） 22、和壓接於另一方的面（第8圖中，上面） 23 ;然後，在收容部110內陽極電極22係》 殼Π側的方式配置觸媒電極2。 陽極電極22，係由板狀電極部24、和與 24的陽離子交換膜21相反側的面（第8圖弓 略垂直地接合而成之棒狀電極部25所構成。 5嵌合面12a 棒狀電極部 係複數的螺 一外殼11與 a- VI -a而切 圖爲沿者在 ,剖面圖。第 ί切斷時之所 線 VH -及―VD—a 7 B圖爲沿 之所見剖面 -VE -c而切斷 的切斷線W -[電極2的分 I壓接於陽離 的陽極電極 的陰極電極 又朝向第一外 ί板狀電極部 11，下面）， 作爲陽極電 -13- 200846502 極22，係使用具有臭氧產生觸媒機能的金屬，作爲此金屬 係使用白金或白金被覆金屬者爲理想。 板狀電極部24係重疊複數片的格子狀的電極241〜 24 3而構成。具體而言，從陽離子交換膜21側依序重疊： 陽極觸媒（微格柵或織網）241、微格柵（micrograting) 或壓延微格柵242、格柵或電極243。在此，所謂織網， 係可舉出將細的線材織爲格子狀之物，所謂格柵 (grating )係可舉出如已熔接了線材般的一體格子狀之 物。另外，壓延微格柵242，係.因爲觸媒241係薄而柔 軟，所以爲了對直接熔接棒狀電極部25的電極243的凹 凸來加以保護而使用之物。另外，藉由通過格柵中而產生 渦流，可捲入在陽極電極22產生的臭氧微泡而加快溶 解。另外，在圖面的關係上，複數的格子狀的241〜243 僅表示於第8圖。 棒狀電極部25，係在位於與板狀電極部24的陽離子 交換膜21相反側的格子狀的電極243，於第8圖中，對於 電極243的下面而以成爲略垂直的方式被熔接。棒狀電極 部25，係插入從第一外殼11的第四凹部16貫通第二凹部 1 1 2內而形成的棒狀電極部用穴115(參照第5圖），一 方的端部爲在第四凹部16內藉由螺帽 η而締結。此棒狀 電極部25的一方的端部，係在後述的安裝台3被固定於 外殻本體1的情況，藉由朝向安裝台3的外殼本體1側的 面3a而成爲被按壓。 另外，棒狀電極部25，係在第二凹部1 1 2內爲了確保 -14- 200846502 與第一外殼u之間的水密性所以被密封。具體而言’於 棒狀電極部25嵌入〇型環253(參照第5圖）。藉由此 而Ο型環253抵接在形成棒狀電極部用穴115的內壁面’ 可確保棒狀電極部用穴1 1 5與棒狀電極部2 5之間的水密 性。 陰極電極23，係與陽極電極22相同，由板狀電極部 27、和與板狀電極部27的陽離子交換膜2 1相反側的面 (第8圖中，上面），略垂直地接合而成之棒狀電極部28 所構成。作爲陰極電極23，係使用白金、銀、鈦等的金屬 或在薄的銀製金屬網的表面施加了氯化銀被覆之物爲理 想。 板狀電極部27係重疊複數片的格子狀的電極271〜 243而構成。具體而言，從陽離子交換膜21側依序重疊： 陰極觸媒（微格柵或織網）271、微格柵（micro grating ) 或壓延微格柵272、格柵或電極273。另外，各格子狀的 電極27 1〜273之間成爲通過水流。另外，壓延微格柵 272，係因爲觸媒271係薄而柔軟，所以爲了對直接熔接 棒狀電極部28的電極273的凹凸來加以保護而使用之 物。另外，在圖面的關係上，複數的格子狀的2 7 1〜2 7 3 僅表示於第8圖。 棒狀電極部28，係在位於與板狀電極部27的陽離子 交換膜2 1相反側的格子狀的電極273，於第8圖中，對於 電極273的上面而以成爲略垂直的方式被熔接。棒狀電極 -15- 200846502 部28，係插入從第二外殼12的嵌合面12a相反側 12b貫通第三凹部125內而形成的棒狀電極部用穴 (參照第5圖），一方的端部爲在從前述相反側的面 突出的狀態，藉由螺帽 η而締結。 另外，棒狀電極部28，係在第三凹部125內爲了 與第二外殻1 2之間的水密性所以被密封。具體而言 棒狀電極部28嵌入Ο型環2 83 (參照第5圖）。藉 而〇型環283抵接在形成第三凹部125的內壁面，可 棒狀電極部用穴126與棒狀電極部28之間的水密性。 作爲陽離子交換膜（Nafion膜）21，係可使用先 般周知之物，可使用對產生的臭氧耐久性強之氟系陽 交換膜，例如厚度大約100〜3 00 // m爲理想。 陽離子交換膜21係爲略矩形狀，如第6B、C圖 7B〜D圖所示地，比陽極電極22及陰極電極23，在 方向長度稍稍變長。總之，陽離子交換膜2 1，係成爲 容於第一凹部111，陽離子交換膜21的長邊方向一端 係比陽極電極22及陰極電極23的長邊方向一端部長 伸至面臨原料水供給路1 3的部分。陽離子交換膜2 i 邊方向另一端部，係比陽極電極22及陰極電極23的 方向另一端部長，延伸至面臨臭氧水排出路14及陰 排出路15的部分。然後，在陽離子交換膜21的一 側，而且，在面臨原料水供給路1 3的面，係形成貫 離子交換膜21而相互地連通陽極電極22與陰極電; 之連通穴211(參照第5圖、第6B圖、第8圖）。 的面 126 12b 確保 ，於 由此 確保 刖― 離子 及第 長邊 被收 部， ，延 的長 長邊 極水 端部 通陽 m 23 -16- 200846502 然後，以陽極電極22、陽離子交換膜2 1及陰極 23依序重疊而作爲平板狀的觸媒電極2係被收容於收 11〇內’在第一外殼11與第二外殻12被嵌合的狀態 配置於第一凹部1 1 1內的陽離子交換膜2 1爲藉由凸部 而被固疋。另外，如第3圖及第5圖所示地，設置於 凹部1 1 1的原料水供給路1 3的溝部1 3 2、臭氧水排 14的貫通穴141及溝部142、陰極水排出路15的貫 151及溝部152的一部分（除了壁面Ula被切除的部 外之溝部152)，係藉由陽離子交換膜21而被覆蓋。 水供給路1 3的貫通穴1 3 1，係面蕪陽離子交換膜2 j 通穴211，藉由此而連通陽極電極22側與陰極電卷 側。 而且’原料水供給路1 3的溝部1 32，係經由陽離 換膜21而藉由延出部126覆蓋，臭氧水排出路14的 142及貫通穴141，係經由陽離子交換膜21而藉由 1 2 3而覆蓋。在陰極水排出路〗5的溝部〗5 2之內，於 1 1 1 a被切除的部分，係連接於溝部〗24的端部。 因而，如第6 B圖所示地，流通原料水供給路} 3 料水，係在流過陽極電極2 2側的同時，通過連通穴 而成爲亦流至陰極電極23側。之後，如第7B圖所示 在陽極電極22產生的臭氧水，係沿著陽極電極22的 方向而流動，從連通於陽極電極22的臭氧水排出路 溝部1 4 2 ’通過貫通穴1 4 1而向臭氧水排出口 1 4 3排Θ 一方面’如第7C圖所示地，在陰極電極23產生 電極 容部 ，係 ；121 第一 出路 通穴 分以 原料 的連 I 23 子交 溝部 蓋部 壁面 的原 2 11 地， 平面 14的 B ° 的陰 -17- 200846502 極水，係沿著陰極電極2 3的平面方向而流動，通過連通 於陰極電極23的溝部U4之後，從溝部152的被切除部 分通過溝部152，更通過貫通穴151而向陰極水排出口 153排出。 如此進行而藉由陽離子交換膜21的連通穴211，從原 料水供給路1 3流出的水係各別被供給於陽極電極22側與 陰極電極23側，除了面臨陽離子交換膜21的連通穴211 的部分以及在陰極水排出路15的溝部152之內，切除了 內壁面1 1 1 a的部分以外，被挾持於陽極電極22與陰極電 極23之間的陽離子交換膜2 1係藉由覆蓋第一凹部1 1 1與 第二外殼1 2的凸部1 2 1，而隔開陽極電極22側與陰極電 極23側。也就是，臭氧水排出路14之連通於陽極電極22 的部分、與陰極水排出路15之連通於陰極電極23的部 分，係因爲藉由陽離子交換膜2 1而被隔開，所以流經陽 極電極22側的水及已產生的臭氧水、與流經陰極電極23 側的水及產生的陰極水，係成爲不混合。 而且，從第一外殼1 1的前述相反側的面1 1 b突出的 陽極電極22的棒狀電極部25之一端部、和從第二外殼12 的前述相反側的面1 2b突出的陰極電極23的棒狀電極部 28之一端部，係各別被作爲電極終端，電性地連接於電源 裝置（不圖7K)的輸出麵’被施加直流電壓。各棒狀電極 部25、28的電極終端係經由導線（不圖示）而連接於電 源裝置，施加於陽極電極22與陰極電極23之間的直流電 壓，係例如6〜1 5伏特爲理想。 -18- 200846502 第9A圖爲從朝向安裝台3的第一外殼n側的面所見 時之透視正面圖、第9B圖爲安裝台3的透視上面圖、第 9C圖爲安裝台3的透視側面圖。 如第2圖及第9圖所示地，安裝台3係被作爲自由裝 卸於與第一外殼11的嵌合面lla相反側的面nb，藉由被 安裝於外殻本體1而支持外殼本體！。安裝台3係爲長方 體狀’於安裝台3的內部形成原料水排出路3 1、臭氧水排 出路32及陰極水排出路33，使水的通路集中於一個處 所。 原料水供給路3 1 ’係朝向外殼本體1的原料水供給口 1 3 3而直線狀地延伸而形成，於原料水供給路3丨的一方的 端部從朝向第一外殻1 1側的面（正面）3 a突出而連接原 料水供給管34。於原料水供給路3 1的另一方的端部，係 連接無圖示的原料水槽或被連結於原料水槽的幫浦等。 臭氧水排出路3 2，係在安裝台3的內部被彎曲而形 成’一方的端部係從朝向第一外殼i丨側的面3a突出而連 接臭氧水排出管3 5 1。另一方的端部，係延伸在垂直於前 述面3a的面（側面）3b’連接另外的臭氧水排出管352。 另外’在臭氧水排出路32的途中，係形成朝向前述面3b 地貫通之分歧路321，於分歧路321插入檢測臭氧水的臭 氧濃度之濃度檢測感測器（濃度檢測手段）4。 第9D圖’爲表示在第9C圖於臭氧水排出路32內配 置著濃度檢測感測器4的狀態之放大模式圖。分歧路 3 2 1 ’係以連通於臭氧水排出路3 2的徑方向下端部的方式 -19- 200846502 形成。也就是，臭氧水排出路3 2，係與分歧路3 2 1 一部分之剖面係作爲在縱方向長的橢圓形狀，其他 水排出路3 2的剖面作爲圓形狀。然後，從分歧路 濃度檢測感測器4插入，濃度檢測感測器4係被配 氧水排出路32的橢圓形狀部分322之下端部。 濃度檢測感測器4，係由檢測電極（不圖示） 電位測定的基準之比較電極（不圖示）、於這些檢 及比較電極的一方的端部接線而測定電位的電位差 圖示）等而構成。檢測電極及比較電極，係被固定 歧路3 2 1旋進的感測器安裝部41的先端，藉由此 電極及比較電極爲被配置於臭氧水排出路3 2的 (橢圓形狀部分3 22 )，成爲接觸流經臭氧水排出g 臭氧水。然後，以接觸於臭氧水，而檢測因檢測電 氧濃度變化之檢測電極與比較電極的電位差而測定; 作爲檢測電極，係例如使用由白金或金等所構 極、作爲比較電極係使用銀或氯化銀爲理想。 根據如此進行而檢測的臭氧濃度，以與臭氧水 置100內的控制部（不圖示）事先設定的臭氧濃度 致的方式，控制在電源裝置施加於陽極電極2 2及 極23之間的電力量。 如上述地，將臭氧水排出路32的一部分，先 面積形成爲於縱方向長的橢圓形狀，藉由在該橢圓 分3 22的下端部使濃度檢測感測器4配置，通常， 殼本體1排出的臭氧水係被混合氧氣氣體，所以如 連通的 的臭氧 321使 置於臭 與作爲 測電極 計（不 於從分 而檢測 下端部 & 32的 極的臭 農度。 成的電 產生裝 作爲一 陰極電 將該剖 形狀部 在從外 此的氣 -20- 200846502 泡係流通臭氧水排出路3 2內的上端部，在下端部係流 爲液體之臭氧水，但以如上述地在橢圓形狀部分3 2 2的 端部配置濃度檢測感測器4，而不被上述氣泡影響，關 流通在臭氧水排出路32的橢圓形狀部分322的下端部 臭氧水，可安定進行濃度測定。 陰極水排出路33，亦在安裝台3的內部被彎曲而 置，一方的端部係從朝向第一外殼1 1側的面3 a突出而 接陰極水排出管3 6 1。另一方的端部，係延伸在垂直於 述面3a的面（上面）3c，連接另外的陰極水排出管3 62 然後，將原料水供給管3 4插入外殼本體1的原料 供給口 1 3 3，將臭氧水排出管 3 5 1插入臭氧水排出 143’使陰極水排出管361插入陰極水排出口 153，而且 藉由將外殼本體1與安裝台3以螺絲釘N2締結而固定 殼本體1與安裝台3。 此時，以朝向安裝台3的外殼本體1側的面3 a，突 於第四凹部16內的陽極電極22的棒狀電極部25的一 部被按壓，藉由調整螺絲釘N2的締結，而可容易地調 向陽離子交換膜21的壓接力。 接著’說明關於使用了由上述的構成所成的臭氧水 生裝置100之臭氧水產生方法。 一從原料水供給路31、1 3供給水，則在水流過陽 電極22的板狀電極部24的同時，經由連通穴21 1而水 過陰極電極23的板狀電極部27，在各電極部24、27違 接觸。藉由同時使電源裝置驅動，而經由陽極電極22 通 下 於 之 配 連 前 〇 水 □ 外 出 端 整 產 極 流 續 及 -21 - 200846502 陰極電極23的各電極終端（棒狀電極25、28 )而對陽極 電極22輿陰極電極23之間施加特定的電壓。藉由此通電 而水被電性分解，於陽極電極22側係臭氧氣泡及氧氣氣 泡產生，於陰極電極23側係氫氣氣泡產生。已產生的臭 氧氣泡係溶解於水而成爲臭氧水，通過臭氧水排出路1 4、 3 2而從臭氧水排出管3 5 2向外部排出。一方面，氫氣氣泡 係溶解於水而成爲氫氣水，通過陰極水排出路1 5、3 3而 從陰極水排出管362被排出至外部。 另外，在通電中，同時藉由濃度檢測感測器4而測定 臭氧水排出路3 2內的臭氧水濃度，控制部，係藉由以成 爲事先已設定的臭氧濃度的方式進行電源裝置的輸出調 整，而控制陽極電極22及陰極電極23間的電力量。如以 上的進行而產生設定濃度的臭氧水。 以上，如藉由本發明的實施形態，則在面臨陽離子交 換膜21的原料水供給路13的部分，設置陽極電極22與 陰極電極2 3爲相互連通的連通穴2 1 1，從原料水供給路 1 3流出的水係因爲在供給於陽極電極22的同時，經由連 通穴2 1 1而供給於陰極電極23，所以不將原料水供給路 1 3，在陽極電極22側與陰極電極23側各別地形成而作爲 複雜的供給路，而是以只形成連通穴211而共有一個原料 水供給路1 3，可將水各別容易地供給於陽極電極2 2側與 陰極電極2 3側。因而，構造亦變單純，可謀求裝置的小 型化。 被收容於第二凹部1 1 2的陽極電極2 2、與被收容於第 -22- 200846502 三凹部125的陰極電極23，係在藉由比陽極電極22及陰 極電極23大的陽離子交換膜21而覆蓋的同時，因爲連通 於陽極電極22的臭氧水排出路14和連通於陰極電極23 的陰極水排出路1 5，亦藉由陽離子交換膜2 1覆蓋而各別 被隔開，所以在陽極電極2 2側產生的臭氧水、和在陰極 電極23側產生的陰極水不混合，可各別通過臭氧水排出 路1 4及陰極水排出路1 5內而使其確實地排出。 於自由裝卸於外殼本體1的安裝台3，設置臭氧水排 出路3 2，因爲在此臭氧水排出路3 2設置濃度檢測感測器 4，所以藉由濃度檢測感測器4，可產生已設定之特定的濃 度的臭氧水。另外，濃度檢測感測器4，係因爲被設置在 自由裝卸於外殼本體1的安裝台，所以在外殻本體1的維 護或交換的情況，沒有將濃度檢測感測器4進行不必要的 交換之必要，可降低成本。 陽極電極22的棒狀電極部25，係突出於外殼本體1 的外部而設置，安裝台爲3藉由被安裝於外殼本體1，因 爲突出的棒狀電極部25被按壓而陽離子交換膜21被按 壓，所以藉由因安裝台3的按壓力而可容易地調整朝向陽 離子交換膜21的壓接力。 而且，於第一外殼11及第二外殼12,係形成可相互 嵌合的第一凹部111、第二凹部112、凸部121及第三凹 部1 25，另外，形成原料水供給路1 3、臭氧水排出路1 4、 陰極水排出路15、溝部113及第四凹部16等，因爲都由 僅在外殼本體1的厚度方向的凹凸所構成，所以構造單 -23 - 200846502 純，可藉由射出成形而容易地形成，而且第一外殼11和 第二外殼12的裝配亦簡單。 第10圖爲表示變形例之臭氧水產生裝置100A之物， 與第5圖同樣地沿著第3圖的切斷線V-V而切斷時之所 見剖面圖。 與臭氧水產生裝置100 A的第一外殼 UA的嵌合面 β 1 1 aA相反側的面1 1 b A，設置磁性材料1 7 A，另外在安裝 φ 台3A的第一外殼1 1A側的面3aA之內略中央位置，係埋 設電磁鐵37A。因而，藉由在第一外殼11A配置安裝台 3A，磁性材料17A被電磁鐵37A吸引而固定第一外殼 1 1 A與安裝台3A。如此地藉由使用磁性材料17A及電磁 鐵37A，外殻本體1A與安裝台3A係藉由磁力而被吸附， 可將外殼本體1A與安裝台3A作爲容易自由裝卸的構 造。另外，如上述的臭氧水產生裝置100般地，將外殼本 體1與安裝台3藉由螺絲釘N2而締結，亦可節省工時。 • 另外，臭氧水產生裝置100A的其他的構成，係因爲 與上述的臭氧水產生裝置1 00相同，所以關於相同的構成 - 部分係於同樣的數字附上英文字母A而省略該說明。 _ 本發明係不限定於上述實施形態，在不逸脫該要旨的 範圍內可適宜變更。 例如：在上述實施形態，陽極電極22的板狀電極部 24及陰極電極23的板狀電極部27，係作爲由各別三片的 電極24 1〜243、27 1〜273所構成，但不限於三片，即使 爲一片、二片、或四片以上也沒有關係。 -24- 200846502 [產業上的可利用性] 如藉由本發明，則不爲了供給水而形成複雜的流路， 以單純的構造，而可各別容易地供給於陽極電極側與陰極 電極側，而且可謀求小型化。 • 【圖式簡單說明】 φ 第1圖爲臭氧水產生裝置100的外觀立體圖。 第2圖爲臭氧水產生裝置100的分解立體圖。 第3圖爲構成臭氧水產生裝置1〇〇的外殻本體（第一 外殼11及第二外殼12)1的立體圖。 ‘ 第4圖爲在嵌合第一外殼1 1及第二外殼1 2的狀態’ 從第一外殼1 1側所見時的透視平面圖。 第5圖爲在第一外殼1 1安裝了安裝台3的狀態’沿 著在第4圖的切斷線V-V而切斷時所見的剖面圖。 • 第6A圖爲將沿著在第5圖的切斷線VI -a - VI -a而切 斷的情況，模式的表示之所見平面圖。 • 第6B圖爲沿著在第6A圖的切斷線VI -b-VI -b而切斷 . 時之所見剖面圖。 第6C圖爲沿著在第6A圖的切斷線VI -c-VI -c而切斷 時之所見剖面圖。 第7A圖爲將沿著在第5圖的切斷線VE-a-VD-a而切 斷的情況，模式的表示之所見平面圖。 第7B圖爲沿著在第7A圖的切斷線VH -b-W -b而切斷 -25- 200846502 時之所見剖面圖。 第7C圖爲沿著在第7A圖的切斷線w-c-VI-c而切斷 時之所見剖面圖。 第7D圖爲沿著在第7A圖的切斷線W -d-W -d而切斷 時之所見剖面圖。 第8圖爲觸媒電極2的分解立體圖。 弟9 A圖爲從朝向安裝台3的第一外殼1 1側的面所見 時之透視正面圖。 第9B圖爲安裝台3的透視上面圖。 第9C圖爲安裝台3的透視側面圖。 第9D圖爲表示在第9C圖於臭氧水排出路32內配置 著濃度檢測感測器4的狀態之放大模式圖。 第1〇圖爲表示變形例之臭氧水產生裝置100A之物， 與第5圖同樣地沿著第3圖的切斷線V-V而切斷時之所 見剖面圖。 【主要元件符號說明】 η :螺帽 Ν1 :螺絲釘 Ν2 :螺絲釘 · 1 :外殻本體 . 2 :觸媒電極 3 :安裝台3 3Α :安裝台 -26- 200846502 3 a ··面 3b :面 3c :面 3 a A :面 4 :濃度檢測感測器 1 1 :第一外殻 * 1 1 b :面 H 1 1 a :嵌合面 1 1 A :第一外殼 1 1 aA :嵌合面 1 1 b A :面 1 2 :第二外殼 12a :嵌合面 1 3 :原料水供給路 1 4 :臭氧水排出路 # 1 5 :陰極水排出路 1 6 :第四凹部 _ 17A :磁性材料 . 17A :磁性材料 21 :陽離子交換膜 2 2 :陽極電極 23 :陰極電極 24 :板狀電極部 2 5.:棒狀電極部 -27- 200846502 27 :板狀電極部 28 :棒狀電極部 3 1 :原料水供給路 3 2 :臭氧水排出路 3 3 :陰極水排出路 34 :原料供給管 " 37A :磁鐵 φ 3 7A :電磁鐵 4 1 :感測器安裝部 100 :臭氧水產生裝置 100A :臭氧水產生裝置 1 1 〇 :收容部 1 1 1 :第一凹部 111a：壁面 1 1 2 :第二凹部 ⑩ 1 1 3 :溝部 1 1 4 : Ο型環 * 1 1 5 :棒狀電極部用穴 . 1 2 1 :凸部 122 :框狀部 123 :蓋部 124 :溝部 125 :第三凹部 126 :延出部 -28- 200846502 126 :棒狀電極部用穴 131 :貫通穴 132 :溝部 1 3 3 :原料水供給口 141 :貫通穴 * 142 :溝部 ^ 143 :臭氧水排出口 φ 151 :貫通穴 1 5 2 :溝部 1 5 3 :陰極水排出口 21 1 :連通穴 241 :電極 241 ：陽極觸媒 242 :電極 242 :壓延微格柵 ⑩ 2 4 3 :電極 25 3 : Ο型環 - 2 7 1 :電極 „ 271 :陰極觸媒 2 7 2 :電極 272 :壓延微格柵 273 :電極 28 3 : Ο型環 3 2 1 :分歧路 -29- 200846502 322 :橢圓形狀部分 351 :臭氧水排出管 3 5 2 :臭氧水排出管 3 6 1 :陰極水排出管 3 62 :陰極水排出管 12b ：面Further, as shown in Fig. 1, the surface of the second casing 12 and the opposite side surface 1 2b protrudes from the cathode electrode 23. Further, on the peripheral portion of the surface 12b on the opposite side, the nail N1 is provided at a specific interval, whereby the second casing 12 is joined. Fig. 6A is a plan view of the mode, and a cutting line Vi-b-VI-b of Fig. 6B, Fig. 6A, when the cutting line VI of Fig. 5 is broken. The figure 6C is a cross-sectional view taken along the cutting line VI-c-VI-c in Fig. 6A, and the seventh drawing is a case where the cutting is performed along the cutting in Fig. 5, and the mode is expressed. When the plan view and the cutting line VE-bWb in Fig. 7A are cut, the figure is shown in Fig. 7C, and the cross-sectional view taken along the cutting line W-c- in Fig. 7A is shown in Fig. 7D. A cross-sectional view taken along the line d-VD-d in Fig. 7A, and Fig. 8 is a perspective view of the touch solution. The catalyst electrode 2 includes one surface (in the eighth drawing, the lower surface) 22 of the cation exchange membrane 21 and the β. sub-exchange membrane 21, and a surface (the upper surface and the upper surface) 23 which are pressure-bonded to the other surface; Then, the catalyst electrode 2 is disposed in the accommodating portion 110 so that the anode electrode 22 is on the side of the casing. The anode electrode 22 is composed of a plate-like electrode portion 24 and a rod-shaped electrode portion 25 which is formed by a surface opposite to the cation exchange film 21 of 24 (the arrow 8 is slightly perpendicularly joined to the drawing.) 5 fitting surface 12a rod The electrode portion is a plurality of screw-shells 11 and a-VI-a, and is cut away as a cross-sectional view. The line VH- and "VD-a 7 B" at the time of the cutting are the profiles along the line. - VE -c and cut line W - [the portion of the electrode 2 is crimped to the anode electrode of the anode electrode and directed toward the first outer plate electrode portion 11 and below) as the anode electrode-13 - 200846502 Extreme 22 is a metal with ozone-generating catalytic function, and it is ideal as a metal or white gold-coated metal. The plate-like electrode portion 24 is formed by stacking a plurality of lattice-shaped electrodes 241 to 24 3 . Specifically, the cation exchange membrane 21 side is sequentially superposed: an anode catalyst (microgrid or web) 241, a micrograting or calendering microgrid 242, a grid or an electrode 243. Here, the weaving mesh is a material in which a thin wire is woven into a lattice shape, and the grating is an integral lattice-like object in which a wire material has been welded. Further, the calendering microgrid 242 is used because the catalyst 241 is thin and soft, so that it is used to protect the convexity of the electrode 243 of the rod electrode portion 25 directly. Further, by generating eddy currents through the grid, ozone microbubbles generated in the anode electrode 22 can be entrained to accelerate dissolution. Further, in the relationship of the drawings, the plural lattice-like shapes 241 to 243 are only shown in Fig. 8. The rod-shaped electrode portion 25 is a lattice-shaped electrode 243 located on the opposite side of the cation exchange film 21 of the plate-like electrode portion 24. In the eighth diagram, the lower surface of the electrode 243 is welded to be slightly perpendicular. The rod-shaped electrode portion 25 is inserted into the rod-shaped electrode portion hole 115 formed by penetrating the second concave portion 1 1 2 from the fourth concave portion 16 of the first outer casing 11 (see FIG. 5), and one end portion is at the The four recesses 16 are confined by a nut η. One end of the rod-shaped electrode portion 25 is pressed against the surface 3a of the mounting body 3 on the side of the casing main body 1 when the mounting base 3 to be described later is fixed to the casing main body 1. Further, the rod-shaped electrode portion 25 is sealed in the second recessed portion 1 1 2 in order to ensure watertightness between the -14-200846502 and the first outer casing u. Specifically, the 〇-shaped ring 253 is fitted to the rod electrode portion 25 (see Fig. 5). By this, the Ο-shaped ring 253 abuts on the inner wall surface ‘where the rod-shaped electrode portion hole 115 is formed, and the watertightness between the rod-shaped electrode portion hole 1 1 5 and the rod-shaped electrode portion 25 can be ensured. Similarly to the anode electrode 22, the cathode electrode 23 is formed by a plate electrode portion 27 and a surface (the upper surface in Fig. 8) opposite to the cation exchange film 21 of the plate electrode portion 27, which are slightly joined. The rod electrode portion 28 is formed. As the cathode electrode 23, it is preferable to use a metal such as platinum, silver or titanium or a silver chloride-coated material on the surface of a thin silver metal mesh. The plate-shaped electrode portion 27 is formed by stacking a plurality of lattice-shaped electrodes 271 to 243. Specifically, the cation exchange membrane 21 side is sequentially superposed: a cathode catalyst (microgrid or mesh) 271, a micro grating (micro grating) or a calender microgrid 272, a grid or an electrode 273. Further, each of the grid-like electrodes 27 1 to 273 is passed through a water flow. In addition, since the catalyst 271 is thin and flexible, the calendering grid 272 is used to protect the irregularities of the electrode 273 of the rod electrode portion 28 by direct welding. Further, in the relationship of the drawings, a plurality of lattice-shaped lattices 2 7 1 to 2 7 3 are only shown in Fig. 8. The rod-shaped electrode portion 28 is a lattice-shaped electrode 273 located on the side opposite to the cation exchange membrane 21 of the plate-like electrode portion 27, and in the eighth diagram, the upper surface of the electrode 273 is welded in a slightly vertical manner. . The rod-shaped electrode -15-200846502 is inserted into the rod-shaped electrode portion hole (see Fig. 5) formed by penetrating the third concave portion 125 from the opposite side 12b of the fitting surface 12a of the second outer casing 12, and one end The portion is converged by the nut η in a state of protruding from the surface on the opposite side. Further, the rod-shaped electrode portion 28 is sealed in the third recess portion 125 so as to be watertight with the second outer casing 12. Specifically, the rod electrode portion 28 is fitted into the Ο-shaped ring 2 83 (see Fig. 5). Therefore, the 〇-shaped ring 283 abuts on the inner wall surface on which the third concave portion 125 is formed, and the watertightness between the rod-shaped electrode portion hole 126 and the rod-shaped electrode portion 28 can be obtained. As the cation exchange membrane (Nafion membrane) 21, a conventionally known one can be used, and a fluorine-based cation exchange membrane having high durability against ozone generated can be used, and for example, a thickness of about 100 to 300 pm is preferable. The cation exchange membrane 21 has a substantially rectangular shape. As shown in Figs. 6B and 7B to D, the anode electrode 22 and the cathode electrode 23 are slightly longer in the direction. In other words, the cation exchange membrane 21 is accommodated in the first concave portion 111, and one end in the longitudinal direction of the cation exchange membrane 21 is extended to the raw material water supply path 13 from the one end in the longitudinal direction of the anode electrode 22 and the cathode electrode 23. part. The other end portion of the cation exchange membrane 2 i in the side direction is extended to the portion facing the ozone water discharge passage 14 and the cathode discharge passage 15 than the other end of the anode electrode 22 and the cathode electrode 23 in the direction. Then, on one side of the cation exchange membrane 21, and on the surface facing the raw material water supply path 13, a cross-ion ion exchange membrane 21 is formed to mutually communicate with the anode electrode 22 and the cathode electricity; Figure, Figure 6B, Figure 8). The surface 126 12b ensures that the 刖-ion and the long-side receiving portion are thereby ensured, and the long-side polar water end portion of the extension is passed through the m 23 -16-200846502, then the anode electrode 22 and the cation exchange membrane 2 1 and the cathodes 23 are stacked in this order, and the catalyst electrode 2 as a flat plate is housed in the housing 11'. The first housing 11 and the second housing 12 are fitted in the first recess 11 1 1 . The cation exchange membrane 21 is solidified by the convex portion. Further, as shown in FIGS. 3 and 5, the groove portion 1 3 of the raw material water supply path 13 provided in the concave portion 1 1 2, the through hole 141 of the ozone water discharge line 14, the groove portion 142, and the cathode water discharge path 15 are provided. A part 151 and a part of the groove portion 152 (the groove portion 152 except the portion where the wall surface U1a is cut) are covered by the cation exchange film 21. The through hole 1 3 1 of the water supply path 13 is connected to the anode electrode 22 side and the cathode coil side by the channel cation exchange membrane 2 j. Further, the groove portion 1 32 of the raw material water supply path 13 is covered by the extension portion 126 via the cation exchange film 21, and the 142 and the through hole 141 of the ozone water discharge path 14 are passed through the cation exchange membrane 21 Covered by 1 2 3 . In the groove portion 5.2 of the cathode water discharge path 5, the portion cut at 11 1 a is connected to the end of the groove portion 24. Therefore, as shown in Fig. 6B, the raw material water supply path 3 flows through the anode electrode 2 2 side, and also flows to the cathode electrode 23 side through the communication hole. Thereafter, the ozone water generated in the anode electrode 22 as shown in Fig. 7B flows in the direction of the anode electrode 22, and the ozone water discharge path groove portion 1 4 2 ' communicates with the anode electrode 22 through the through hole 1 4 1 And to the ozone water discharge port 1 4 3 row Θ on the one hand, as shown in Fig. 7C, the electrode portion is generated at the cathode electrode 23, the system; 121 the first outlet hole is divided into the raw material of the I 23 sub-intersection cover The original 2 11 ground of the wall surface, the cathode 17-200846502 polar water of B ° of the plane 14 flows in the plane direction of the cathode electrode 23, passes through the groove portion U4 of the cathode electrode 23, and then passes from the groove portion 152. The cut portion passes through the groove portion 152 and is further discharged to the cathode water discharge port 153 through the through hole 151. In this way, the water flowing out of the raw material water supply path 13 by the communication hole 211 of the cation exchange membrane 21 is supplied to the anode electrode 22 side and the cathode electrode 23 side, respectively, except for the communication hole 211 facing the cation exchange membrane 21. The cation exchange membrane 2 1 held between the anode electrode 22 and the cathode electrode 23 is covered by the portion other than the portion where the inner wall surface 11 1 a is cut out in the groove portion 152 of the cathode water discharge path 15 A recess 1 1 1 and a convex portion 1 2 1 of the second outer casing 12 are spaced apart from the anode electrode 22 side and the cathode electrode 23 side. That is, the portion of the ozone water discharge path 14 that communicates with the anode electrode 22 and the portion of the cathode water discharge path 15 that communicates with the cathode electrode 23 is separated by the cation exchange membrane 21, so that it flows through the anode. The water on the electrode 22 side and the generated ozone water, the water flowing through the cathode electrode 23 side, and the generated cathode water are not mixed. Further, one end portion of the rod electrode portion 25 of the anode electrode 22 protruding from the surface 1 1 b of the opposite side of the first outer casing 1 and a cathode electrode protruding from the surface 1 2b of the opposite side of the second outer casing 12 One end of the rod-shaped electrode portion 28 of the second portion is used as an electrode terminal, and a DC voltage is applied to an output surface of the power supply device (not shown in Fig. 7K). The electrode terminals of the rod-shaped electrode portions 25 and 28 are connected to the power source device via a wire (not shown), and the DC voltage applied between the anode electrode 22 and the cathode electrode 23 is preferably 6 to 15 volts, for example. -18- 200846502 Fig. 9A is a perspective front view as seen from the side facing the first outer casing n side of the mounting table 3, Fig. 9B is a perspective top view of the mounting table 3, and Fig. 9C is a perspective side view of the mounting table 3. Figure. As shown in FIGS. 2 and 9, the mounting base 3 is detachably attached to the surface nb on the opposite side to the fitting surface 11a of the first casing 11, and is supported by the casing body 1 to support the casing body. ! . The mounting table 3 is formed in a rectangular shape. The raw material water discharge path 31, the ozone water discharge path 32, and the cathode water discharge path 33 are formed inside the mounting table 3, and the water passage is concentrated in one place. The raw material water supply path 3 1 ' is formed to extend linearly toward the raw material water supply port 1 3 3 of the outer casing main body 1 , and the one end portion of the raw material water supply path 3 从 faces the first outer casing 1 1 side. The surface (front surface) 3 a is protruded and the raw material water supply pipe 34 is connected. The other end of the raw material water supply path 31 is connected to a raw material water tank (not shown) or a pump connected to the raw material water tank. The ozone water discharge passage 32 is bent inside the mounting base 3 so that the one end portion protrudes from the surface 3a facing the first outer casing i 而 and is connected to the ozone water discharge pipe 35 1 . The other end portion is connected to a surface (side surface) 3b' perpendicular to the front surface 3a to connect another ozone water discharge pipe 352. In the middle of the ozone water discharge path 32, a branch path 321 that penetrates the surface 3b is formed, and a concentration detecting sensor (concentration detecting means) 4 that detects the ozone concentration of the ozone water is inserted into the branch path 321 . Fig. 9D is an enlarged schematic view showing a state in which the concentration detecting sensor 4 is disposed in the ozone water discharge path 32 in Fig. 9C. The branch road 3 2 1 ' is formed in a manner that is connected to the lower end portion of the ozone water discharge passage 32 in the radial direction -19-200846502. In other words, the ozone water discharge path 3 2 has a cross section which is a part of the branch road 3 2 1 as an elliptical shape elongated in the longitudinal direction, and a cross section of the other water discharge path 3 2 has a circular shape. Then, it is inserted from the branch path concentration detecting sensor 4, and the concentration detecting sensor 4 is the lower end portion of the elliptical portion 322 of the oxygen-containing water discharge path 32. The concentration detecting sensor 4 is a comparison electrode (not shown) which is a reference for measuring the potential of the detecting electrode (not shown), and a potential difference diagram for measuring the potential at the end of each of the detecting electrodes. And constitute. The detecting electrode and the comparison electrode are the tip end of the sensor mounting portion 41 that is screwed into the fixed channel 3 2 1 , and the electrode and the comparison electrode are disposed in the ozone water discharge path 3 2 (elliptical portion 3 22 ) , become contact with ozone water to discharge g ozone water. Then, it is measured by measuring the potential difference between the detection electrode and the comparison electrode due to the change in the detected oxygen concentration in contact with the ozone water. For the detection electrode, for example, a structure electrode made of platinum or gold is used, and silver is used as a comparison electrode system. Silver chloride is ideal. The electric power detected by the power supply device between the anode electrode 22 and the pole 23 is controlled by the ozone concentration previously set by the control unit (not shown) in the ozone water 100 setting. the amount. As described above, a part of the ozone water discharge path 32 is formed in an elliptical shape that is long in the longitudinal direction, and the concentration detecting sensor 4 is disposed at the lower end portion of the elliptical portion 3 22. Generally, the case body 1 is generally disposed. The discharged ozone water is mixed with the oxygen gas, so that the connected ozone 321 is placed in the odor and used as the dynamometer (the odor of the pole of the lower end & 32 is not detected.) As a cathode electric power, the cross-sectional portion is in the upper end portion of the ozone-water-exhaust water discharge passage 3 2 from the outside of the gas--20-200846502, and the ozone water is liquid at the lower end portion, but is as described above. The end portion of the elliptical portion 3 2 2 is disposed with the concentration detecting sensor 4, and is not affected by the bubble, and the ozone water flowing through the lower end portion of the elliptical portion 322 of the ozone water discharge path 32 can be stably measured for concentration. The water discharge path 33 is also bent inside the mounting base 3, and one end portion protrudes from the surface 3a toward the first outer casing 1 1 side and is connected to the cathode water discharge pipe 361. The other end portion , the system extends perpendicular to The surface (upper surface) 3c of the surface 3a is connected to another cathode water discharge pipe 3 62. Then, the raw material water supply pipe 34 is inserted into the raw material supply port 1 3 3 of the casing body 1, and the ozone water discharge pipe 35 1 is inserted into the ozone. The water discharge 143' inserts the cathode water discharge pipe 361 into the cathode water discharge port 153, and fixes the case body 1 and the mounting table 3 by joining the case body 1 and the mounting table 3 with screws N2. At this time, toward the mounting table 3 The surface 3 a on the side of the casing body 1 is pressed against a portion of the rod electrode portion 25 of the anode electrode 22 protruding in the fourth recess 16 , and the cation exchange film can be easily adjusted by adjusting the engagement of the screw N2 . Next, the method of generating ozone water using the ozone water generating apparatus 100 formed by the above-described configuration will be described. When water is supplied from the raw material water supply paths 31 and 13, the water flows through the plate of the anode electrode 22. At the same time as the electrode portion 24, the plate-shaped electrode portion 27 that has passed through the cathode electrode 23 via the communication hole 21 1 is in contact with each other in the electrode portions 24 and 27. By driving the power source device at the same time, the anode electrode 22 is passed through. Before the connection □ Outgoing end of the production process and - 21 - 200846502 cathode terminals 23 (rod electrodes 25, 28) and a specific voltage is applied between the anode electrode 22 and the cathode electrode 23. Electrolytic decomposition, ozone bubbles and oxygen bubbles are generated on the side of the anode electrode 22, and hydrogen bubbles are generated on the side of the cathode electrode 23. The generated ozone bubbles are dissolved in water to become ozone water, and are discharged through the ozone water passages 14 and 3. 2, the ozone water discharge pipe 35 is discharged to the outside. On the other hand, the hydrogen gas bubbles are dissolved in water to become hydrogen water, and are discharged from the cathode water discharge pipe 362 to the outside through the cathode water discharge paths 15 and 3. Further, during the energization, the concentration of the ozone water in the ozone water discharge path 3 2 is measured by the concentration detecting sensor 4, and the control unit performs the output of the power supply device so as to become the ozone concentration that has been set in advance. The amount of electric power between the anode electrode 22 and the cathode electrode 23 is controlled while being adjusted. The ozone water of the set concentration is generated as described above. As described above, in the embodiment of the present invention, the anode electrode 22 and the cathode electrode 23 are connected to each other in the portion facing the raw material water supply path 13 of the cation exchange membrane 21, and the communication hole 2 1 1 is connected from the raw material water supply path. Since the water flowing out of the 1-3 is supplied to the cathode electrode 23 via the communication hole 2 1 1 while being supplied to the anode electrode 22, the raw material water is not supplied to the path 13 and is on the anode electrode 22 side and the cathode electrode 23 side. In addition, as a complicated supply path, a raw material water supply path 13 is shared by forming only the communication holes 211, and water can be easily supplied to the anode electrode 2 2 side and the cathode electrode 23 side, respectively. Therefore, the structure is also simple, and the size of the device can be reduced. The anode electrode 2 2 accommodated in the second concave portion 1 1 2 and the cathode electrode 23 housed in the third recess portion 125 of the -22-200846502 are connected to the cation exchange membrane 21 larger than the anode electrode 22 and the cathode electrode 23. At the same time, since the ozone water discharge path 14 connected to the anode electrode 22 and the cathode water discharge path 15 connected to the cathode electrode 23 are also covered by the cation exchange membrane 21, they are separately separated, so that the anode electrode is provided. The ozone water generated on the 2nd side and the cathode water generated on the cathode electrode 23 side are not mixed, and can be surely discharged through the ozone water discharge path 14 and the cathode water discharge path 15 respectively. The ozone water discharge path 3 2 is provided in the mounting table 3 that is detachably attached to the casing body 1. Since the concentration detecting sensor 4 is disposed in the ozone water discharge path 32, the sensor 4 can be generated by the concentration detecting sensor 4. Set the specific concentration of ozone water. Further, since the density detecting sensor 4 is provided at a mounting table that is detachably attached to the casing body 1, the density detecting sensor 4 is not exchanged unnecessarily in the case of maintenance or exchange of the casing body 1. If necessary, it can reduce costs. The rod electrode portion 25 of the anode electrode 22 is provided to protrude from the outside of the casing body 1. The mounting table 3 is attached to the casing body 1, and the cation exchange film 21 is pressed because the protruding rod electrode portion 25 is pressed. Since the pressing force is applied, the pressure contact force toward the cation exchange membrane 21 can be easily adjusted by the pressing force of the mounting table 3. Further, the first outer casing 11 and the second outer casing 12 are formed with a first concave portion 111, a second concave portion 112, a convex portion 121, and a third concave portion 125 which are fitted to each other, and a raw material water supply path 13 is formed. The ozone water discharge passage 14 and the cathode water discharge passage 15, the groove portion 113, the fourth recess portion 16, and the like are all formed by the unevenness in the thickness direction of the outer casing main body 1, so that the structure -23 - 200846502 is pure, by The injection molding is easily formed, and the assembly of the first outer casing 11 and the second outer casing 12 is also simple. Fig. 10 is a cross-sectional view showing the ozone water generating apparatus 100A according to the modification, which is cut along the cutting line V-V of Fig. 3, similarly to Fig. 5. The surface 1 1 b A on the side opposite to the fitting surface β 1 1 aA of the first casing UA of the ozone water generating device 100 A is provided with a magnetic material 17 A, and on the side of the first casing 1 1A on which the φ table 3A is mounted The electromagnet 37A is embedded in a slightly central position inside the surface 3aA. Therefore, by arranging the mounting table 3A in the first casing 11A, the magnetic material 17A is attracted by the electromagnet 37A to fix the first casing 1 1 A and the mounting table 3A. By using the magnetic material 17A and the electromagnetic iron 37A, the outer casing main body 1A and the mounting base 3A are attracted by the magnetic force, and the outer casing main body 1A and the mounting base 3A can be easily attached and detached. Further, as in the ozone water generating apparatus 100 described above, the outer casing body 1 and the mounting base 3 are joined by the screw N2, and man-hours can be saved. In addition, the other configuration of the ozone water generating device 100A is the same as that of the above-described ozone water generating device 100. Therefore, the same components - the same numerals are attached to the same numerals, and the description is omitted. The present invention is not limited to the above-described embodiments, and can be appropriately modified within the scope of the gist of the invention. For example, in the above embodiment, the plate-shaped electrode portion 24 of the anode electrode 22 and the plate-shaped electrode portion 27 of the cathode electrode 23 are composed of three electrodes 24 1 to 243 and 27 1 to 273, respectively. It is limited to three pieces, even if it is one piece, two pieces, or four pieces or more. -24-200846502 [Industrial Applicability] According to the present invention, a complicated flow path is not formed for supplying water, and it can be easily supplied to the anode electrode side and the cathode electrode side with a simple structure. Moreover, it is possible to achieve miniaturization. • [Simplified description of the drawings] φ Fig. 1 is an external perspective view of the ozone water generating device 100. Fig. 2 is an exploded perspective view of the ozone water generating device 100. Fig. 3 is a perspective view of the casing body (the first casing 11 and the second casing 12) 1 constituting the ozone water generating device 1A. The 'fifth view is a perspective plan view seen from the side of the first outer casing 1 1 in a state in which the first outer casing 1 1 and the second outer casing 12 are fitted. Fig. 5 is a cross-sectional view showing the state in which the mounting table 3 is attached to the first casing 11 and is cut along the cutting line V-V of Fig. 4. • Fig. 6A is a plan view showing the mode in which the cutting line VI - a - VI - a in Fig. 5 is cut. • Fig. 6B is a cross-sectional view as seen along the cutting line VI-b-VI-b of Fig. 6A. Fig. 6C is a cross-sectional view as seen along the cutting line VI-c-VI-c of Fig. 6A. Fig. 7A is a plan view showing a mode in which the cutting line VE-a-VD-a in Fig. 5 is cut. Fig. 7B is a cross-sectional view as seen along the cutting line VH-b-W-b of Fig. 7A, when -25-200846502 is cut. Fig. 7C is a cross-sectional view as seen along the cutting line w-c-VI-c of Fig. 7A. Fig. 7D is a cross-sectional view as seen along the cutting line W - d - W - d of Fig. 7A. Fig. 8 is an exploded perspective view of the catalyst electrode 2. Fig. 9A is a perspective front view as seen from the side facing the first outer casing 1 1 side of the mounting table 3. Figure 9B is a perspective top view of the mounting table 3. Figure 9C is a perspective side view of the mounting table 3. Fig. 9D is an enlarged schematic view showing a state in which the concentration detecting sensor 4 is disposed in the ozone water discharge path 32 in Fig. 9C. Fig. 1 is a cross-sectional view showing a state in which the ozone water generating apparatus 100A according to the modification is cut along the cutting line V-V of Fig. 3, similarly to Fig. 5. [Description of main component symbols] η : Nut Ν 1 : Screw Ν 2 : Screw · 1 : Housing body 2 : Catalyst electrode 3 : Mounting table 3 3 Α : Mounting table -26 - 200846502 3 a · · Face 3b : Face 3c : face 3 a A : face 4 : concentration detecting sensor 1 1 : first outer casing * 1 1 b : surface H 1 1 a : fitting surface 1 1 A : first outer casing 1 1 aA : fitting surface 1 1 b A : surface 1 2 : second outer casing 12 a : fitting surface 1 3 : raw material water supply path 1 4 : ozone water discharge path # 1 5 : cathode water discharge path 1 6 : fourth recess _ 17A : magnetic material. 17A: magnetic material 21: cation exchange membrane 2 2 : anode electrode 23 : cathode electrode 24 : plate electrode portion 2 5.: rod electrode portion -27 - 200846502 27 : plate electrode portion 28 : rod electrode portion 3 1 Raw material water supply path 3 2 : Ozone water discharge path 3 3 : Cathodic water discharge path 34 : Raw material supply pipe & 37A: Magnet φ 3 7A : Electromagnet 4 1 : Sensor mounting unit 100 : Ozone water generating device 100A Ozone water generating device 1 1 〇: housing portion 1 1 1 : first recess portion 111a: wall surface 1 1 2 : second recess portion 10 1 1 3 : groove portion 1 1 4 : Ο type ring * 1 1 5 : rod electrode portion Use a hole. 1 2 1 : convex part 122: frame portion 123: cover portion 124: groove portion 125: third recess portion 126: extension portion -28 - 200846502 126: rod electrode portion hole 131: through hole 132: groove portion 1 3 3 : raw material water supply port 141 : through hole * 142 : groove portion ^ 143 : ozone water discharge port φ 151 : through hole 1 5 2 : groove portion 1 5 3 : cathode water discharge port 21 1 : communication hole 241 : electrode 241 : anode catalyst 242 : electrode 242 : Calendered microgrid 10 2 4 3 : Electrode 25 3 : Ο-ring - 2 7 1 : Electrode „ 271 : Cathode catalyst 2 7 2 : Electrode 272 : calendered microgrid 273 : Electrode 28 3 : Ο ring 3 2 1 : Divergence road -29- 200846502 322 : elliptical shape portion 351 : ozone water discharge pipe 3 5 2 : ozone water discharge pipe 3 6 1 : cathode water discharge pipe 3 62 : cathode water discharge pipe 12b: surface