TW200844127A - Curable composition, cured film and laminate thereof - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide a curable composition affording a cured film having excellent antistatic properties and further anti-staining properties and wet heat resistance. ; SOLUTION: The curable composition comprises (A) a polymer containing a polymerizable unsaturated group and repeating units represented by formulas (1a) and (1b), (B) a compound represented by formula: LiC<SB>n'</SB>F<SB>2n'+1</SB>X or formula: Li(C<SB>n'</SB>F<SB>2n'+1</SB>Y)<SB>2</SB>N, (C) a compound having >=2 polymerizable unsaturated groups in the molecule other than the component (A) and (D) a photopolymerization initiator.

Description

200844127 IX. OBJECTS OF THE INVENTION [Technical Field] The present invention relates to a hardenable composition, and in detail, the present invention relates to a curable composition capable of obtaining a cured film having a pen (anti-contamination property) , am body 0 [Prior Art] In recent years, prevent plastic (polycarbonate, polyester, polystyrene, polyester, polyolefin, epoxy resin, cellulose triacetate resin, ABS resin, AS resin, etc.), metal Wood, paper, glass, stone surface damage (scratch) or anti-pollution is used as a hardenable composition for protecting a coating material for a coating film, and is required to form a surface for various substrates, regardless of hardness wearability. The surface of each of the hard various substrates excellent in surface smoothness, low curling property, adhesive property, and appearance of the coating film surface is provided with antifouling property, so that the film has antistatic property. A lithium compound is blended in the composition imparting antistatic properties to the cured film. For example, Patent Document 1 discloses a polyethylene terephthalate, a polymerizable compound having no polyethylene glycol mono(meth)acryloxy group in the molecule, lithium bisimide, and a photoinitiator. A photocurable resin film and a laminate formed. More excellent antistatic properties, such as cured film and laminated various surface cloth materials such as methyl methacrylic acid, cyanuric resin, norbornene, etc., and excellent anti-reflection properties and scratch resistance. Resistance, transparency, and drug-resistant film. In general, the hardening method 1 is in the polydi(methyl)propyl group and has at least 2 perfluoroalkane sulfonium compounds. -6- 200844127 In this patent, there is no use of a perfluorohomogeneous oligomer of polyether-containing polydimethylether ether. In addition, the hardness may be low due to the use of a larger amount. Patent Document 2 discloses an optical element containing a lithium salt selected from the group consisting of an ionizing radiation resin composition and a perfluoroalkylsulfonic acid lithium, a diperfluoroalkyl group, and a lithium perchlorate. Polyether-containing polydimethyl siloxane or polyether-containing oligomer is not used. Further, the photocurable single system is monofunctional or divalent, and has a low hardness as a hard coat layer. In Patent Document 3, A), an ethylenically unsaturated compound (B), and a specific curable composition obtained by subjecting a hydrolyzate of a phthalic acid microparticle compound to a condensation reaction are disclosed. Although cerium oxide particles modified with a decane coupling agent are used, a decane coupling agent containing a methacryl oxime group is used, and in view of the above, sufficient hardness or scratch resistance may not be obtained. In the case of using a hard reflective film for a recording disc such as a DVD, it is required to have fingerprint wiping property, etc., for example, when used for recording of an electronic device for vehicle mounting, it is hardened during use. The membrane component flows out, or the light barrier, and may cause fire, it must be resistant to heat and humidity. [Patent Document 1] Japanese Laid-Open Patent Publication No. 2004-331909, a peroxane-based monomer composed of a resin containing a polydiacrylate ray-curable bismuthimide hydride, and an organic decane dioxide (lithium compound) In the case of the embodiment, the coating or the antifouling property is prevented. The reading of a disc such as a disc is 200844127 [Patent Document 2] JP-A-2005-3 1 282 [Patent Document 3] Special Opening 2005 [Problem to be Solved by the Invention] The present invention has an object of providing a curable composition capable of obtaining a cured film having excellent antistatic properties, antifouling properties, and moist heat resistance. Means for Solving the Problem The present inventors have found that a polymerizable unsaturated group having a polymerizable unsaturated group and a compound having a polyether chain and a polydimethylphosphonyl group, and a specific The curable composition of the lithium compound can solve the above problems, and the present invention can be completed. According to the present invention, the following curable composition, cured film, and laminate can be provided. 1 · A curable composition, The following components (A) to (D) are contained: (A) a polymer having a polymerizable unsaturated group, a repeating unit represented by the following formula (ia), and a repeating unit represented by the following formula (1b) (B) a compound represented by the following formula (3a) or (3b), (C) a compound having two or more polymerizable unsaturated groups in a molecule other than the component (A), -8- 200844127 (D) Photopolymerization initiator; [Chemical 1] (1a) (1b) *-|-CpH2p〇-J-* 'ch3 · *--SiO--*

I L CH3" [In the formulas (la) and (lb), p is 1 to 10. ]

LiCn, F2n' + iX (3 a)

Li (Cn, F2n, + 1Y) 2N (3b) [In the formulae (3a) and (3b), X represents CO 2 or S03, Y represents CO or S 〇 2, and n' represents an integer of 1 to 9. 2. The curable composition according to the above item 1, wherein the component (A) has a polymerizable unsaturated group (meth) acrylonitrile group. 3. The curable composition according to the above item 1 or 2, wherein the component (A) further contains a urethane group. 4. The curable composition according to any one of the above items 1 to 3, further comprising the following component (E): (E) having a polymerizable unsaturated group and selected from the group consisting of ruthenium, aluminum, chromium, A particle containing at least one element of a group of titanium, zinc, bismuth, indium, tin, antimony, and bismuth as a main component. 5. The curable composition according to the above item 4, wherein the polymerizable unsaturated group of the component (E) contains a group having a structure of -9-200844127 represented by the following formula (4); [Chemical 2] Η “, —U—C—Ν—(4)

II

V

In the formula (4), U represents hydrazine, hydrazine (oxygen atom) or s (sulfur atom), and V represents hydrazine or S. And a cured film obtained by curing the curable composition according to any one of items 1 to 5 above. A laminate comprising a cured film as in item 6 above, on a substrate. [Effect of the Invention] According to the present invention, it is possible to provide a curable composition capable of obtaining a cured film having excellent antistatic properties, fingerprint wiping property, and moist heat resistance. [Best Mode for Carrying Out the Invention] 1. Curable Composition The curable composition of the present invention is characterized by containing the following components (A) to (D). By combining the components (A) and (B), the antistatic property can be exhibited even if the amount of the component (B) is small. It is inferred that when the composition is hardened, the component (B) is biased toward the air side of the coating film or near the interface of the substrate side, or the component (B) is caused by the polyether chain of the component (A). 10- 200844127 Also tends to move around the interface. The curable composition of the present invention preferably contains the following component (E). (E) particles having a polymerizable unsaturated group and having an oxide of at least one element selected from the group consisting of ruthenium, aluminum, pin, chin, zinc, ruthenium, indium, tin, a chain, and ruthenium as a main component (below Known as reactive particles). By combining such reactive particles, the scratch resistance of the cured film can be further improved. Hereinafter, each component will be described. Component (A): a polymer containing a polymerizable unsaturated group, a repeating unit represented by the formula (1), and a repeating unit represented by the formula (1b), which is used in the component (A) of the present invention, and contains a polymerizable property. A saturated group, a polyether chain of a repeating unit represented by the following formula (la), and a polymer of a poly-methylsulfate bond which is not repeated by the following formula (lb). [化3] *—CpH2pO--* (1a) Γ ch3 ί

I *一一Si〇--* (1b)

I L CH3" [In the formula (la), p is 1 to l〇. The component (A) is used in combination with the component (B) described below, and even if the amount of the component (B) added is small, excellent antistatic properties can be imparted. Further, since the component (A) has a polymerizable unsaturated group and is polymerized to bond with other components -11 - 200844127, condensed powder does not occur even under moist heat conditions. The polyether chain (sub-hydrocarbyloxy structure) of the repeating unit represented by the above formula (1 a ) may be linear or branched. The polymerizable unsaturated group may have one or more, but more preferably two or more. The polymerizable unsaturated group may, for example, be a (meth)acryl fluorenyl group or a vinyl group, and among them, a (meth) acrylonitrile group is preferred. Further, in addition to the polymerizable unsaturated group, a urethane may also be present. The component (A) is preferably a compound having a structure represented by the following formulas (5) to (8). The component (A) used in the present invention can be produced by introducing a polymerizable unsaturated group into a compound having a structure represented by the following formulas (5) to (8). -12- 200844127 [化4] —0~(-CkH2k0-)^· ch3 Si〇4— I 7 m CH3

(5)

(6) ch3 ICH3-{|i〇^ ch3 ch3 SiO-)- q CH3 I (si〇-)-Si(CH3)3 ' 1 m ch3 (7) R-(

CkH2k〇- n ch3 fsiO^-Si(CH3)3 \ q (8)

CH3 I 3 CH3-(si〇-)^ ch3 [In the formulas (5) to (8), p is 1 to 10; R represents a divalent value of 1 to 20 carbon atoms which may contain a sub, a sulfur atom or a hetero atom. The organic group; η is independently 5 to 1,000; q is 1 to 100. A compound having a structure represented by the formula (5), which is commercially available as SF8427, BY16-201, SF8428, SZ-2162, SH3773M (manufactured by Corning Toray), KF-8010, KF-1002, X-22- 4952 22-4272, X-22-6266 (Shin-Etsu Silkic), etc. The polymer of the component (A) can be, for example, a polymer having any of the structures shown in the above (5) to (8), 2,4-toluene-13-oxogen m, and Dow, X- the above-mentioned diiso 200844127 isocyanate such as cyanate ester or isophorone diisocyanate, and mixed in the presence of tin dibutyl laurate, for example, after reacting at room temperature to 40 ° C for several hours, A hydroxyl group-containing (meth) acrylate such as pentaerythritol triacrylate or hydroxyethyl acrylate is added, and the mixture is produced, for example, at 60 ° C to 7 (TC is allowed to react for several hours. The composition in the composition of the present invention (A) When the total amount of the composition of the (F) organic solvent is removed by 1% by mass, the amount thereof is preferably 0.01 to 40% by mass, more preferably 0.1 to 25% by mass, and more preferably 0.5 to 15% by mass. If the amount of the component (A) is less than 〇. 质量1% by mass, sufficient antistatic properties may not be obtained. If it exceeds 40% by mass, the hardness may be insufficient as a cured product. Component (B): Formula (3a) Or a compound represented by (3b) is used in the component (B) of the composition of the present invention by the following formula (3a) Or a lithium-containing compound represented by (3b).

LiCn, F2n+1X (3a)

Li(Cn, F2n, + 1 Y)2N (3b) [In the formulae (3a) and (3b), X represents CO 2 or S03, Y represents CO or S 〇 2, and n' represents an integer of 1 to 9. Specific examples of the component (Β) include lithium perfluoroacetate, lithium perfluoropropionate, lithium perfluorobutyrate, lithium perfluoropentanoate, lithium perfluorohexanoate, lithium perfluoropentanoate, lithium perfluorooctanoate, and Lithium fluoroantimonate, lithium perfluoroantimonate, lithium trifluoromethanesulfonate, lithium perfluoroethanesulfonate, lithium perfluoropropane sulfonate, lithium perfluorobutanesulfonate, lithium perfluoropentanesulfonate, perfluorohexane Lithium acid, lithium perfluoroheptanoate, lithium perfluorooctanoate, perfluoroindole-14- 200844127 lithium acid, lithium bistrifluoromethyl sulfoximine, lithium bis-perfluoromethyl sulfinimide perfluoro ethionimide, lithium double Fluoropropyl sulfoximine, lithium bis-perfluoroimine, lithium bis-perfluoropentasulfonimide, lithium bis-perfluorohexyl sulfinimide, perfluoroheptanthine, lithium bis-perfluorooctyl sulfinimide, lithium bis-perfluoro Imine, lithium bis-trifluoromethaneimide, lithium bis-perfluoroacetate yttrium imine fluoroindolide, lithium bis-perfluorobutyric acid ylide, lithium bis-perfluoroimine, lithium bis-perfluorohexanoate Lithium bis-perfluoroheptanoate ylide imine perfluorooctanoate, lithium bis-perfluorodecanoate yttrium, lithium bis-perfluoroimine and the like. Further, a mixture of the component (B) and a polymerizable unsaturated group is commercially available, and examples thereof include Sankonol A600-3 0R, A600 PETA-30R, PETA-20R, and A4 00-20R (Sanko Chemical Industry Co., Ltd.). When the component (B) in the composition of the present invention is removed (the total amount of the composition of the F solvent is 100% by mass, the amount thereof is preferably 0. mass%, more preferably 0.05 to 15 mass%, and 0.1 to 1% is more preferable. If the amount of the component (B) is less than 0.01% by mass, sufficient electrostatic attenuation cannot be obtained, and if it exceeds 20% by mass, the hardness as a cured product is insufficient. The method reaches the lower portion (internal). (C) A compound having two hydrophilic unsaturated groups in a molecule other than the above component (A) (polyfunctional polymerizable organic compound) The polyfunctional polymerizable organic compound (C) used in the present invention It is used to improve the film-forming property of the composition. When hardened, the composition (A), lithium dibutyl sulfonium, lithium bismuth sulfonium sulfonium, lithium bismuth valerate, lithium bismuth bismuth ruthenate -20R, (share) ) Organic 01 ~ 20 〇 quality, I am afraid that it will harden without aggregation.) Suitable for polymerization 15-200844127 Unsaturated groups also react together to form a polymer. The polyfunctional polymerizable organic compound (C) is not particularly limited as long as it contains two or more polymerizable unsaturated groups in the molecule, and examples thereof include (meth)acrylates and vinyl compounds. Among these, (meth) acrylates are preferred. Examples of the (meth) acrylate include trimethylolpropane tri(meth)acrylate, ditrimethylolpropane tetra(meth)acrylate, pentaerythritol tri(meth)acrylate, and pentaerythritol tetra(a). Acrylate, dipentaerythritol penta (meth) acrylate, dipentaerythritol hexa (meth) acrylate, glycerol tri (meth) acrylate, ginseng (2-hydroxyethyl) isocyanurate (Meth) acrylate, ethylene glycol di(meth) acrylate, 13-butanediol di(meth) acrylate, 1,4-butanediol di(meth) acrylate, 1,6- Hexanediol di(meth)acrylate, neopentyl glycol di(meth)acrylate, diethylene glycol di(meth)acrylate, triethylene glycol di(meth)acrylate, dipropylene glycol II A hydroxyl group such as (meth) acrylate or bis(2-hydroxyethyl)isocyanurate di(meth)acrylate contains a (meth) acrylate, and ethylene oxide or propylene oxide with respect to such a hydroxyl group Poly(meth)acrylates of the product, having two or more molecules in the molecule (methyl Acryl oxime oligoester (meth) acrylates, oligoether (meth) acrylates, oligomeric urethane (meth) acrylates, and oligomeric epoxides (methyl) Acrylates, compounds represented by the following formulas (4) and (5), and the like. Among these, dipentaerythritol hexa(meth) acrylate, dipentaerythritol penta (meth) acrylate, pentaerythritol tetra (meth) acrylate, ditrimethylol propyl tetra (meth) acrylate, The compounds represented by the following formulas (9) and (10) are preferably -16-200844127. [Chemical 5]

In the formulae (9) and (10), "Acryl" represents an acrylonitrile group. The vinyl compound may, for example, be divinylbenzene, ethylene glycol divinyl ether, diethylene glycol divinyl ether or triethylene glycol divinyl ether. As a commercial product of such a polymerizable organic compound (C), for example, East Asian Synthetic Co., Ltd. is made up of eight feet 0&gt; 11 and ] ^-400, ]^-404, ]^-408, %-450, M-. 305, M-309, M-310, M-315, M-320, M-350, M_3 60, M-208, M-210, M-215, M-220, M-225, M-233, M -240, M-245, M-260, M-270, M-1100, M-1 200, M-1210, M-1310, M-1 600, M-221, M-203, TO-924, TO -1270, TO-1231, TO-595, TO-756, TO-1343, TO-902, TO-904, TO-905, TO-1330, Nippon Chemical Co., Ltd. KAYARAD D-310, D-3 30, DPHA, DPCA-20, DPCA-30, DPCA-60, DPCA-120, DN-0075, DN-2475, SR-295, SR-355, SR-399E, SR-494, SR-9041, SR -368, SR-415, SR-444, SR-454, SR-492, SR-499, SR-502, SR-9020 -17- 200844127, SR-9035, SR-111, SR-212 &gt; SR- 213, SR-230, SR-259, SR-268, SR-272, SR-344, SR-349, SR-601, SR-602, SR-610, SR-9003, PET-30, T- 1 420 , GPO-3 03, TC-120S, HDDA, NPGDA, TPGDA, PEG400DA, MANDA, HX-220, HX-620, R-551, R-712, R-167, R -526, R-551, R-712, R-604, R-684, TMPTA, THE-3 3 0, TP A-3 20, TPA-3 3 0, KS-HDDA, KS-TPGDA, KS-TMPTA , glory AC Chemicals (shares) LIGHT-ACRYLATE PE-4A, DPE-6A, DTMP-4A and so on. In the component (C) in the composition of the present invention, when the total amount of the composition of the (F) organic solvent is removed, the amount of the component is 5 to 8% by mass. It is preferably 10 to 80% by mass, more preferably 15 to 80% by mass. When it is less than 5% by mass or more than 80% by mass, it is feared that a high hardness may not be obtained as a cured product. Further, when it is a laminate, the adhesion between the cured film and the substrate may be lowered. Further, in the case of a composition containing the component (E) described later, the component (C) does not contain the component (E). (D) Photopolymerization initiator The polymerization initiator (D) is a compound (radiation (light) polymerization initiator) which generates an active radical species by irradiation with radiation (light). The radiation (light) polymerization initiator is not particularly limited as long as it is decomposed by light irradiation to generate a radical, and is, for example, acetophenone-18-200844127, acetophenone benzyl ketal, 1 Monohydroxycyclohexyl phenyl ketone, 2,2-dimethoxy-1,2-diphenylethyl-1-one, xanthone 'fluorenone, benzaldehyde, hydrazine, hydrazine, triphenylamine , carbazole, 3-methylacetophenone, 4-chlorobenzophenone, 4,4'-dimethoxybenzophenone, 4,4,-diaminobenzophenone, benzoin Propyl ether, benzoin ethyl ether, benzyl dimethyl ketal, 1-(4-isopropylphenyl)-2-hydroxy- 2~methylpropan-1-one, 2-hydroxy-2 -methyl-1-phenylpropan-1-one, thioxanthone, diethylthioxanthone, 2-isopropylthioxanthone, 2-chlorothioxanthene Wake up, 2_methyl-1,[4-mono(methylthio)phenyl]-2-isomorpholino-propen-1-one, 2-n-phenyl-2-phenylamino-indole (4-morpholinophenyl)-butanone-1,4-(2-carbylethoxy)phenyl-(2-hydroxy- 2 - Propyl)ketone, 2,4,6-trimethylphenylphosphonium diphenylphosphine oxide, bis(2,6-dimethoxybenzoquinone)-2,4,4-trimethylpentylphosphine oxide Oligomer (2-hydroxy-2-methyl-l-(4-(1-methylvinyl)phenyl)acetone) and the like. Commercial products of the radiation (photo) polymerization initiator may, for example, be IRUGACUR 184, 369, 651, 500, 819, 907, 784, 295 9 , CGI 1 700, CGI 1 75 0 manufactured by Ciba Specialty Chemicals Co., Ltd. CGI 1 8 5 0, CG24-61, DAROCUR 1116, 1173, LUCIRIN BA, 8 893 manufactured by BASF, UBECRYL P36 manufactured by UCB, EZ ACUR - KIP 1 500 from LANBELTY CORPORATION, KIP65LT, KIP100F, KT 3 7, KT 5 5, KT 0 4 6 , ΚΙ P 7 5 / B, etc. o The amount of the polymerization initiator (D), when the total amount of the composition of (F) organic solvent -19-200844127 is 100% by mass, It is preferable to use 〇·〇丨~20% by mass, 〇·1 to 10% by mass, and 0.5 to 10% by mass. If it is less than 质量·〇1% by mass, the hardness as a cured product may be insufficient, and if it exceeds 20% by mass, it may not be able to reach the inside (lower layer) as a cured product. Further, in the present invention, it may be necessary The photopolymerization initiator is used in combination with a thermal polymerization initiator. The preferred thermal polymerization initiator may, for example, be a peroxide or an azo compound, and specific examples thereof include benzoquinone peroxide, t-butyl-peroxybenzoate, azobisisobutyronitrile, and the like. (E) particles having a polymerizable unsaturated group and having an oxide of at least one element selected from the group consisting of ruthenium, aluminum, zirconium, titanium, zinc, bismuth, indium, tin, antimony and bismuth as a main component of the present invention The component (E) (hereinafter also referred to as "reactive particle") which is compatible with it is formed by selecting bismuth, aluminum, bismuth, titanium, zinc, bismuth, indium, tin, antimony and bismuth. The particles (Ea) which are oxides of at least one element of the group are reacted with an organic compound (Eb) having a polymerizable unsaturated group and a hydrolyzable formyl group in the molecule. When the component (E) is blended, it can react with the polymerizable unsaturated groups of the components (A) and (C), and by polymerization, the hardness of the obtained cured film can be further improved, and since the hardening shrinkage can be reduced (bending) ) and better. (1) Particles containing oxide as a main component (Ea) Oxide particles (Ea) for producing reactive particles (E) 'The colorlessness of the cured film of the curable composition obtained from -20-200844127 It is a particle mainly composed of an oxide of one element from bismuth, aluminum, zirconium, titanium, zinc, bismuth, indium, tin, antimony and bismuth. Examples of the oxide particles (Ea) include particles of cerium oxide, chromium oxide, titanium oxide, zinc oxide, cerium oxide, indium oxide, indium tin oxide (ITO), cerium oxide, and cerium oxide. From the viewpoint of high hardness, particles of cerium oxide, aluminum oxide, and cerium oxide are preferred. These may be used singly or in combination of two or more kinds, and the oxide particles (Ea) are preferably used in the form of a powder or a solvent. When it is used as a solvent-dispersed sol, the dispersion medium is preferably an organic solvent from the viewpoint of compatibility with other components. Such a solvent may, for example, be methanol, ethanol, isopropanol, butanol, octanol or the like; acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone or the like ethyl acetate, butyl acetate, lactate B Esters such as ester, r-butyrolactone, propyl methyl ether acetate, propylene glycol monoethyl ether acetate; ethers such as monomethyl ether, diethylene glycol monobutyl ether; benzene, toluene An aromatic hydrocarbon such as benzene; a guanamine such as dimethylformamide or dimethylacetamide methylpyrrolidone. Among them, methanol, isopropanol, methyl ethyl ketone, methyl isobutyl ketone, ethyl acetate, butyl benzene or xylene is preferred. The number average particle diameter ' of the oxide particles (Ea) is preferably from o.ool //m, more preferably 〇.〇〇3//m 〜l/zm, and 0.005/zm^ // m is particularly preferred. If the number average particle diameter exceeds 2 // m, the transparency as hard will be lowered, and the surface state as a cured film may be selected from the group consisting of tin oxide, in which pin and oxygen are used. Disperse-dissolved and dispersed organic alcohol ketones; diol monoethylene glycol, dimethyl:, N-, butanol ester, and a μ m~2 -0.5 compound-timed -21 - 200844127. Further, in order to improve the dispersibility of the particles, various surfactants or amines may be added. The number average particle diameter of the oxide particles was measured by dynamic dispersion. The commercially available product of the cerium oxide particles (for example, cerium oxide particles) may, for example, be a ceric acid gel, and may be a methanol dioxide cerium oxide sol, IPA-ST, MEK-ST or NBA-ST manufactured by Nissan Chemical Industries Co., Ltd. , XBA-ST, DMAC-ST, ST-UP, ST-OUP, ST-20, ST-40, ST-C, ST-N, ST-0, ST-50, ST-OL, etc. Further, examples of the powdered cerium oxide include AER0SIL 130, AER0SIL 3 00, AER0SIL 380, AEROSIL TT600, AER0SIL 0X50, and Asahi Glass (shared) SILDEX H31, H32, H51, H52, H121 manufactured by AER0SIL Co., Ltd., Japan. , H122, E220A, E220 manufactured by Sakamoto Sebacide Industry Co., Ltd., SYLYSIA470 made by Fuji Fuji Silysia Co., Ltd., SG sheet made of Nippon Sheet Glass Co., Ltd., etc. Further, the aqueous dispersion of alumina may be exemplified by Nissan Chemical Industry Co., Ltd. alumina sol-1 〇〇, -200, - 5 2 0; the isopropyl alcohol dispersion of alumina may be Sumitomo Osaka CEMENT (stock) AS-150I; Alumina toluene dispersions can be found in Sumitomo Osaka CEMENT (stock) AS-150T: chrome oxide toluene dispersions can be found in Sumitomo Osaka CEMENT (shares) HXU- 1 10JC; The water-dispersible zinc citrate powder may be CELNAX manufactured by Nissan Chemical Industries Co., Ltd.; powders and solvent dispersions of alumina, titania, tin oxide, indium oxide, zinc oxide, etc. may be cited as CI ·Chemical (share) system TEK; water-dispersed sol of antimony-doped tin oxide can be SN-100D manufactured by Ishihara Industry Co., Ltd.; ΙΤΟ powder can be exemplified by Mitsubishi-22- 200844127

Products made of Materials; the water dispersion of cerium oxide can be exemplified by NEEDRAL. The oxide particles (Ea) have a spherical shape, a hollow shape, a porous shape, a rod shape, a plate shape, a fibrous shape, or an unfixed shape, and are preferably spherical. The specific surface area of the oxide particles (Ea) (the BET specific surface area measurement method using nitrogen gas) is preferably 10 to 1 m 2 /g, more preferably 1 to 5 00 m 2 /g. The use form of these oxide particles (Ea) can be used in a state in which a powder in a dry state or water or an organic solvent is dispersed. For example, as the solvent-dispersing sol of the above oxide, a dispersion of fine particle-like oxide particles as known in the art can be used as it is. In particular, in applications where excellent transparency is required on a cured product, it is preferred to use an organic solvent-dispersing sol of an oxide. (2) Organic compound (Eb) The organic compound (Eb) used in the present invention has polymerization. The compound of the unsaturated group is preferably an organic compound containing a group represented by the following formula (4). [6] (4) Η

—U-C-N— II

V

[In the formula (4), U represents ΝΗ, 0 (oxygen atom) or S (sulfur atom), and V represents 0 or S. Wherein, it contains [-0-C(=0)-NH-], and further contains -23-200844127 [-0-0(= 3),11-] and [-3-(:( It is preferable that at least one of the groups of the group of the formulas of the group of the compounds of the formula (eb) is preferably a compound having a hydrazine hydroxyl group in the molecule or a compound having a hydrazine hydroxy group by hydrolysis. (i) The polymerizable unsaturated group contained in the polymerizable unsaturated organic compound (Eb) is not particularly limited, and examples thereof include an acryl fluorenyl group, a methacryl fluorenyl group, a vinyl group, a propylene group, and a butadienyl group. The styrene group, the ethynyl group, the cinnamyl group, the maleate group, and the acrylamide group are preferred examples. The polymerizable unsaturated group is a constituent unit of addition polymerization by living radical species. (ii) The group [-UC(=V)-NH-] represented by the above formula (4) contained in the base organic compound represented by the above formula (4) specifically has [-0-C ( = 0)-NH_], [_0-C( = S)-NH-] , [-SC( = 0)-NH-], [-NH-C( = 0)-NH-] &gt; [-NH 6 types of -C(=S)-NH-] and [-SC(=S)-NH-]. These bases may be used alone or in combination of two or more. Among them, thermal stability From the point of view, with [-0-C(=0)-NH-], [-0-C(=S)-NH-], and [-SC(=0)-NH-] At least one of them is preferably used. When the group [-UC(=V)-NH-] represented by the above formula (4) is a hardened substance due to a moderate cohesive force caused by hydrogen bonding between molecules It imparts excellent mechanical strength, adhesion to a neighboring layer such as a substrate or a high refractive index layer, and heat resistance, etc. -24- 200844127 (iii) Formation of sand hydrogen by sand hydroxyl or hydrolysis The oxy group-based organic compound (Eb) is preferably a compound having a hydrazine hydroxyl group in the molecule or a compound which is hydrolyzed to form a hydrazine hydroxy group. The compound which forms a hydrazine hydroxy group can be exemplified by a ruthenium atom. a compound having an alkoxy group, an aryloxy group, an ethoxylated group, an amine group, a halogen atom or the like, wherein a compound having an alkoxy group or an aryloxy group bonded to a fluorene atom is preferred, that is, an alkoxy group-containing group a compound of a decyl group or a compound containing an aryloxycarbyl group. A hydrazine hydroxyl-forming site of a hydrazine-hydroxyl group or a hydrazine-hydroxyl group-forming compound is condensed by a condensation reaction or hydrolysis. The constituent unit of the oxide particle (Ea) is bonded. (iv) A preferred embodiment of the preferred organic compound (Eb) is, for example, a compound represented by the following formula (1 1 ). ] (〇R6)i I |_| |_| R73-j SiH-R8—S—C—N—R9—N—C—O—R10—II II v ;koo (1 1 ), R6, R7 is a hydrogen atom or an alkyl group or an aryl group having 1 to 8 carbon atoms which may be the same or different, and examples thereof include a methyl group, an ethyl group, a propyl group, a butyl group, a sheep group, a phenyl group, and a xylyl group. Here, j is an integer of 1 to 3. The group represented by [(R60)jR73_jSi-] may, for example, be a trimethoxymethyl decyl group, a diethoxymethyl sulfonyl group, a diphenoxymethyl sulfonium group, or a methyl dimethyloxy-25-200844127. Methyl decyl, dimethyl methoxy carboxyalkyl, and the like. Among these groups, a trimethoxycarbenyl group or a triethoxycarbenyl group is preferred. R8 is an aliphatic group having 1 to 12 carbon atoms or a divalent organic group having an aromatic structure, and may have a chain, a branched or a cyclic structure. Specific examples thereof include methyl, ethylene, propylene, butyl, hexamethylene, cyclohexene, phenylene, benzodimethyl, and dodecyl. R9 is a divalent organic group, usually having a molecular weight of from 14 to 10,000; preferably selected from a divalent organic group having a molecular weight of from 76 to 500. Specific examples thereof include a chain polyalkylene group such as hexamethylene, octamethylidene, and dodecylylene; an alicyclic or polycyclic divalent organic group such as cyclohexene or bornereyl; and benzene; a divalent aromatic group such as a phthalocyanine, a bisphenylene or a polyphenylene; and an alkyl substituent or an aryl substituent. Further, these divalent organic groups may have an atomic group containing an element other than carbon and a hydrogen atom, and may also contain a polyether bond, a polyester bond, a polyamine bond, or a polycarbonate bond. R1G is an organic group of (k + 1 ) valence, and is preferably selected from a chain hydrocarbon, a branched or cyclic saturated hydrocarbon group, and an unsaturated hydrocarbon group. Z represents a monovalent organic group having a polymerizable unsaturated group which undergoes an intermolecular crosslinking reaction in the molecule in the presence of a living radical species. Further, k is preferably an integer of 1 to 20, more preferably an integer of 1 to 1 Å, and particularly preferably an integer of 1 to 5. Specific examples of the compound represented by the formula (1 1 ) include compounds represented by the following formulas (1 2 ) and (13). -26- 200844127 [化8]

γ'.Si(OCH3)3 (12), Si(OCH3)3 (13) [In the formulas (12) and (13), "Acryl" means an acryl fluorenyl group. The synthesis of the organic compound (Eb) used in the present invention is, for example, the method described in JP-A-9-0101. Preferably, the pentaerythritol triacrylate is added by mixing the thiopropylpropyltrimethoxydecane with the isophorone diisocyanate in the presence of the base tin dilaurate and reacting it at 60 to 70 ° C. The ester was produced by further reacting it for 60 hours. (3) Preparation of Reactive Particles (E) A base compound (Eb) having a hydrazine hydroxyl group or a hydrazine hydroxyl group formed by hydrolysis is mixed with metal oxide particles (Ea) to cause both Bonding. The ratio of the hydrolyzate and the condensate of the hydrolyzable decane to the organic poly component in the obtained reactive particle (E), usually, the constant mass % of the mass of the dry powder when it is completely burned in the air, by, for example, air Thermal mass from room temperature to usually 800 °C

It can be obtained by using a hydrolyzate with a small number of 70 °C to analyze the dry system -27-200844127. The amount of bonding of the organic compound (Eb) bonded to the oxide particles (Ea) is 100% by mass when the reactive particles (E) (total of the metal oxide particles (E a ) and the organic compound (Eb )) are 100% by mass, It is preferably 1% by mass or more, and more preferably 0.1% by mass or more, and particularly preferably 1% by mass or more. When the amount of bonding of the organic compound (Eb) bonded to the metal oxide particles (Ea) is less than 0.01% by mass, the dispersibility of the reactive particles (E) in the composition is insufficient, and the transparency of the obtained cured product is Scratch resistance will become insufficient. Further, in the production of the reactive particles (E), the ratio of the metal oxide particles (Ea) in the raw material is preferably from 5 to 99% by mass, more preferably from 10 to 98% by mass. The content of the oxide particles (Ea) constituting the reactive particles (E) is preferably 65 to 95% by mass based on the reactive particles (E). The content of the reactive particles (E) in the curable composition is preferably from 5 to 85% by mass based on the total amount of the organic solvent to be removed (F). More preferably, it is 10 to 80% by mass, and 10 to 75% by mass is particularly preferable. When the amount is less than 5% by mass, a cured product having a high hardness cannot be obtained as a cured product, and when it is more than 85 mass%, the film formability is insufficient. Further, the content of the reactive particles (E) means a solid component, and when the reactive particles (E) are used in the form of a solvent-dispersed sol, the content thereof does not include the amount of the solvent. In the curable composition of the present invention, (F) an organic solvent may be added as needed. The organic solvent may, for example, be an alcohol such as methanol, ethanol, isopropanol, butanol or octanol-28-200844127; a ketone such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone; Ethyl acetate, butyl acetate, ethyl lactate, r-butyrolactone, propylene glycol monomethyl ether acetate, propylene glycol monoethyl ether acetate, etc.; ethylene glycol monomethyl ether, diethyl An ether such as diol monobutyl ether; an aromatic hydrocarbon such as benzene, toluene or xylene; or a guanamine such as dimethylformamide, dimethylacetamide or n-methylpyrrolidone. (F) Organic solvent In the curable resin composition of the present invention, it is preferred to further add an organic solvent. By adding such an organic solvent, a cured film can be uniformly formed. Examples of such an organic solvent include ketones such as acetone, methyl isobutyl ketone, methyl ethyl ketone, cyclohexanone, and methyl amyl ketone, ethyl acetate, butyl acetate, and propylene glycol monomethyl ether. Esters such as acetates, propylene glycol monomethyl ether, methanol, ethanol, S e C-butanol, t-butanol, 2-propanol, isopropanol, alcohols, benzene, toluene, chlorobenzene, etc. The aromatics, aliphatic groups such as hexane and cyclohexane may be used alone or in combination of two or more. Among these, ketones such as acetone, methyl isobutyl ketone, methyl ethyl ketone, cyclohexanone, methyl amyl ketone, ethyl acetate, butyl acetate, propylene glycol monomethyl ether acetate An ester such as an ester, propylene glycol monomethyl ether, methanol, ethanol, sec-butanol, t-butanol, 2-propanol, isopropanol or the like is preferred, and more preferably methanol or propylene glycol monomethyl The ether, methyl ethyl ketone, and methyl isobutyl ketone may be used alone or in combination of two or more. The amount of the (F) organic solvent to be added is not particularly limited, and is preferably 1 〇〇-29 to 200844127 〜1 相对, based on the total amount of the organic solvent-removing composition. Share. The reason is that if the amount of addition is less than 100 parts, the viscosity of the curable composition is difficult to adjust, and if the amount exceeds 1 〇〇 and the amount of 〇〇〇 is part by mass, the storage of the curable composition is lowered. Or there is a situation where the viscosity is too low and it is difficult to operate. (G) Fluorine-based additive The fluorine-based additive is added to the curable composition of the present invention to impart antifouling properties and fingerprint wiping properties. The commercial products of the component (G) are 305 SF, F-4 70, and F477 Otsuka Ink Chemical Industry Co., Ltd. The amount of the fluorine-based additive (G) is preferably 0.01 to 10 by mass, 0.05 to 5% by mass, more preferably 0.1 to 3 mass%, more preferably when the total amount of the organic solvent composition is 100% by mass. . If it is 0. 01% by mass, a sufficient effect cannot be obtained. If it exceeds the mass, sufficient hardness cannot be obtained as a cured product, or hardening cannot be achieved (lower layer). (Η) Other Additives In the curable composition of the present invention, it is necessary to appropriately mix the photosensitizer, the polymerization inhibiting agent, and the polymerization in accordance with the effect of the present invention. I 'leveling agent, wettability improvement Agent, surfactant, plasticizer, wire absorbent, antioxidant, antistatic agent, inorganic chelating agent, emollient and the like. 2. The cured film and the quality of the laminate are qualitatively added, and the % of the MCF-based agent is less than %, and the inside is under the ultraviolet, dyeing -30-200844127. The cured film or laminate system of the present invention is made by the present invention. The curable composition is obtained by hardening on a substrate. The substrate may, for example, be a plastic (polycarbonate, polymethacrylate, polystyrene, polyester, polyolefin, epoxy, cyanuric acid, cellulose triacetate, ABS, AS, norborne film storage resin temple). ), metal, wood, paper, glass, slate, etc. The shape of these substrates may be a plate shape, a film shape or a ternary molded body. Further, a meso layer may be formed between the substrate and the cured film as needed. The coating method of the composition may be a general coating method such as dipping coating, inkjet coating, flow coating, drip coating, roll coating, spin coating, brush coating, or the like. The thickness of the coating film in such coating is usually from 0.1 to 400 / zm, preferably from 1 to 200 / / m after drying and hardening. In order to adjust the thickness of the coating film, the composition of the present invention can be used after being diluted with the above organic solvent (F). For example, when used as an antireflection film or a covering material, the viscosity is usually 0.1 to 50,000 mPa·s / 25 ° C, preferably 〇.5 〜 l 〇, 〇〇〇 mPa · sec / 25 ° C. After the application, the volatile component is preferably dried at 0 to 200 ° C and then cured by heat and/or radiation to obtain a laminate. When the heat is hardened, the preferable curing conditions are carried out in the range of 20 to 150 ° C for 10 seconds to 24 hours. In the case of hardening by radiation, it is preferred to use ultraviolet rays or electron beams. In this case, the amount of ultraviolet light to be irradiated is preferably 1 to 10 j/cm 2 , preferably 0.1 to 2 J/cm 2 . Further, preferred electron beam irradiation conditions are an acceleration voltage of 10 to 30 OkV, an electron density of 0.02 to 30.30 mA/cm2, and an electron beam irradiation amount of 1 to 1 OMrad. -31 - 200844127 The heat source during hardening can be, for example, an electric heater, an infrared lamp, a hot air, or the like. A line source of light or an electron wire is not particularly limited as long as the composition can be hardened in a short time after coating. For example, the source of the infrared light may be an illumination lamp, a resistance heating plate, or a laser. The line source of visible light may be sunlight, an illumination lamp, a fluorescent lamp, or a laser. The source of the ultraviolet light may be mercury. Lights, halogen lights, lasers, etc. Further, the line source of the electron beam may be a commercially available method using a hot electron generated by a tungsten filament, or a cold cathode method in which a high voltage pulse is generated on a metal, and a gaseous molecule by ionization. The second-order electronic method of the second electron generated by the collision with the metal electrode. Further, the line source of the α-ray, the x-ray, and the r-ray may be, for example, a nuclear fission material such as c〇6(), and the r-ray may be a vacuum tube or the like which accelerates the collision of electrons with the anode. These radiation systems may be irradiated by one type or two or more types at the same time or at intervals. When the laminate of the present invention is used as an antireflection film, the cured film obtained by curing the composition of the present invention can generally function as a layer of an antistatic hard coat layer. When it is an antireflection film, a high refractive index layer, a medium refractive index layer, a low refractive index layer, etc. are formed as needed. [Embodiment] [Embodiment] Hereinafter, the present invention will be more specifically described by way of examples, but the present invention is not limited to the embodiments. In addition, the "parts" and "%" described below indicate the parts by mass and mass% unless otherwise specified. -32- 200844127 Production Example 1: Production of Organic Compound (Eb) Having Polymerizable Unsaturated Group In dry air, 22 parts of thiopropylpropyltrimethoxydecane and 1 part of dibutyltin dilaurate were formed. The solution was dropped with 222 parts of isophorone diisocyanate at 50 ° C for 1 hour, and the mixture was stirred under heating at 70 ° C for 3 hours. In the above solution, NK ester A-TMM-3LM-N (manufactured by Xinzhongcun Chemical Co., Ltd., 60% by mass of pentaerythritol triacrylate and 40% by mass of pentaerythritol tetraacrylate) was used for one hour at 30 °C. The reaction was carried out only with 5 49 parts of pentaerythritol triacrylate having a hydroxyl group, and the mixture was heated and stirred at 60 ° C for 10 hours to obtain an organic compound (Ab ) containing a polymerizable unsaturated group. When the amount of residual isocyanate in the FT-IR analysis product was 0.1% or less, the reaction was almost quantitatively terminated. The infrared absorption spectrum of the product is an absorption peak of 25 5 cm·1 on the hydrogen-sulfur group in the raw material and 226 (the absorption peak of the ^1^1 disappeared on the isocyanate compound of the raw material, and the newly observed aminocarboxylic acid is observed. The ester bond and the S (C = 0) NH- group are characterized by a peak of 1 660 CHT1 and a characteristic of 1 720 (: 1 ^ 1 ) on the acryloxy group, which is formed as a polymerizable unsaturated group and simultaneously a oxydecane having a propylene oxime group and a -S(C=0)NH-, urethane-bonded propylene oxime-modified oxime. In addition to the above, 773 parts of the above formula (12) or (13) In addition to the compound (Eb) shown, 220 parts of pentaerythritol tetraacrylate which is not related to the reaction are mixed therein. -33- 200844127 Production Example 2: Preparation of Reactive Particle Dispersion The composition produced in Production Example 1 9.35 parts (containing 7.28 parts of organic compound (Eb) having a polymerizable unsaturated group) and a cerium oxide particle dispersion (Ea) (ceria concentration: 32%, average particle diameter: 10 nm, manufactured by Nissan Chemical Industries Co., Ltd.) 89.90 parts of methanol cerium oxide sol), 0.12 parts of ion-exchanged water, and p-hydroxyphenyl group A mixture of 0.01 parts of methyl ether was stirred at 60 ° C for 4 hours, and then 1.36 parts of methyl orthoformate was added, and the mixture was heated and stirred at the same temperature for 1 hour to obtain a dispersion of reactive particles. After weighing 2 g of the weighing pan, it was dried on a hot plate at 1 75 °C for 1 hour, and the solid content was determined to be 37.8%. Further, after the dispersion was weighed 2 g in a magnetic boiler, the heating plate at 80 °C The resultant was dried for 30 minutes, and after firing in a muffle furnace at 75 ° C for 1 hour, the inorganic content in the solid component was determined to be 75.5% from the inorganic residue. Production Example 3: Compound of the component (A) A solution of 5 parts of toluene diisocyanate and 1 part of dibutyltin dilaurate was prepared, and a polyether-containing polydimethyl methoxy hydride (SF 427 manufactured by DOWCORNING TORAY Co., Ltd.) was dropped over several hours. 3 60 parts, stirred at room temperature for 3 hours. In the above solution, Xinzhongcun Chemical NK ester A-TMM-3LM-N (60% by weight of pentaerythritol triacrylate and pentaerythritol tetraacrylic acid) was added in 1 hour at 25 t. The ester is composed of 40% by mass. Among them, only the quarter with hydroxyl group is involved in the reaction. Tetrahydrin triacrylate) After dropping 173 parts, the objective polymerizable unsaturated group-containing organic compound (A) was obtained by heating and stirring at 60 ° C for 10 hours. The product was analyzed by FT-IR-34-200844127. When the amount of the residual isocyanate is 0.1% or less, the reaction is almost quantitatively terminated. The infrared absorption spectrum of the product is such that the absorption peak of the 2260 CHT1 characteristic of the raw material isocyanate compound disappears, and the urethane bond is newly observed. The peak of the 1 660CIXT1 and the peak of the 1 720CIXT1 characteristic of the acryloxy group on the C = ONH-based group, which means the formation of a propylene methoxy group as a polymerizable unsaturated group and -C = ONH- a urethane-bonded polyether-containing polydimethyloxane. According to the above, in addition to 5 22 parts of polyether-containing polydimethyl siloxane having a polymerizable unsaturated group imparting the component (A), 69 parts of the reaction-free pentaerythritol tetraacrylate were mixed therein. Example 1 (1) The curable composition was prepared by dissolving ultraviolet rays in a container equipped with a stirrer, and the components were added in the proportions shown in Table 1, and stirred at room temperature for 1 hour to obtain a uniform composition 0 (2) Production of Laminated Body The composition obtained in the above (1) was applied by spin coating on the polycarbonate of the substrate. Thereafter, it was dried at room temperature for 1 minute to form a coating film. Next, a high-pressure mercury irradiation lamp was used in the atmosphere, and the coating film was cured by ultraviolet light under a light irradiation condition of 500 mJ/cm2 to prepare a cured film having a film thickness of 10/m, thereby obtaining a laminate. -35- 200844127 Examples 2 to 3, Reference Examples 1 to 2, and Comparative Examples 1 to 4 The collocations described in the other Table 1 were carried out in the same manner as in Example 1 to prepare a composition, and a laminate was obtained. Evaluation Example The following properties were evaluated for the laminates obtained in the above examples, reference examples and comparative examples, and the results are shown in Table 1. (1) Electrostatic decay rate half-life (minutes) The laminates prepared in the above examples, reference examples, and comparative examples were subjected to a voltage of 3 kV using a Static Honest Meter and an Honest Meter Analyzer (manufactured by SHISHIDO Electrostatic Gas Co., Ltd.). The time when the applied voltage becomes half of 1.5 kV (static decay rate half-life (minutes)). (2) Water and oleic acid contact angle (°) The contact angle of water and oleic acid is an automatic contact angle contact angle meter using a solid-liquid interface analysis device DROP MASTER5 00 (Kyowa Interface Science Co., Ltd.) After the surface of the laminate was formed into droplets, the angle between the water and the laminate, and the interface between the oleic acid and the laminate was measured for 5 seconds. The contact angle of water and oleic acid is closely related to the fingerprint wiping property. The water and oleic acid contact angles are recovered, and the fingerprint wiping property is better. (3) Fingerprint wiping off -36- 200844127 Actually, the fingerprint was attached to the laminate, and the fingerprint was traced after being wiped off with a soft cloth. There are no traces of defects, some traces are Δ, and they cannot be wiped out as X. (4) The presence or absence of precipitates under the damp heat test The laminate was placed under constant temperature and humidity of 80 ° C and 80 % RH. After 100 hours, visual inspection was performed to confirm the presence or absence of oily precipitates. -37- 200844127 Reference Example 3 1 should be 1 0.30 26.06 0.69 0.94 0.56 70.95 0.50 100.00 10.00 90.00 CN Ό 60 minutes or more ο Reference example 2 5.95 1 1 1 18.85 piece 0.96 0.57 73.16 0.51 100.00 10.00 90.00 (N VO 60 minutes or more 〇\ 00 〇壊Comparative example 1 1 1 1 1 21.67 1 1.01 0.60 76.72 1 100.00 10.00 90.00 (N VO 60 minutes or more s, &lt;1 壊Reference example 2 1 1 8.77 1 18.28 1 0.94 0.56 70.95 0.50 100.00 10.00 90.00 (N VO 60 minutes or more (N 00 f - Η Ό 〇 Reference Example 1 1 8.69 1 0.30 18.10 0.69 0.93 0.55 70.25 0.49 100.00 10.00 90.00 (N Ό m 00 〇 Example 4 5.83 1 1 0.23 20.24 0.52 0.95 0.56 71.67 1 100.00 10.00 90.00 CN m ON CN 〇壊Example 3 5.80 1 1 0.30 19.89 0.70 0.94 0.56 71.31 0.50 100.00 10.00 90.00 (N rH 〇〇壊Example 2 5.80 1 1 0.23 20.14 0.52 0.94 0.56 71.31 0.50 100.00 10.00 90.00 CN Ό 〇§ 〇裢Example 1 1.00 1 1 0.23 24.94 0.52 0.94 0.56 71.31 0.50 100.00 10.00 90.00 CN VO (N 〇〇 soil composition (mass part) SF8427-TP (acrylate modified product of SF8427) ADDID130 SF8427 PET compound in PETA-30R DPHA PETA-30 (C) component gb § Reactive particles (YSX-91S) MCF-350SF Solid component total methanol propylene glycol monomethyl ether solid component concentration (% by mass) Electrostatic decay Rate half-life (minutes) Water contact angle 0 Oleic acid contact angle 0 Fingerprint wipeability I 2 33 a 2 Μ Disk 00 Μ c\ M ?s Composition 1 gg α g 龌^鲣g you-38- 200844127 In addition, Table 1 The components described in the above are as follows. SF8427: polydimethyl siloxane containing a polyether chain, SF8427-TP manufactured by DOWCORNING TORAY: a polymer modified by the above-mentioned SF8427 (manufacturing example 3). (Product or Production Example 3) ADDID130: polydimethyl siloxane containing a polyether chain, PETA-3 OR (a mixture of pentaerythritol triacrylate and lithium bistrifluoromethaneimine) manufactured by Wacker C hemie. The lithium bistrifluoromethaneimine contained in the PETA-30R* is composed of the component (B) and pentaerythritol triacrylate as the component (C). DPHA: a hexafunctional acrylate monomer, manufactured by Nippon Kayaku Co., Ltd. Irg. 184. Photopolymerization initiator, manufactured by Ciba Specialty Chemicals

Irg. 907, a photopolymerization initiator, and a reactive particle manufactured by Ciba Specialty Chemicals Co., Ltd., were produced in Production Example 2, and the amount of the compound was expressed as a solid component. MCF-3 5 0SF: an oligomer containing a perfluoroalkyl group, a hydrophilic group, and a lipophilic group, manufactured by Dainippon Ink and Chemicals Co., Ltd. [Industrial Applicability] The curable composition of the present invention is suitable for use as a plastic Protective coating materials for preventing damage (scratching) or anti-contamination of various substrate surfaces, and coating materials for reflective films. The cured film or laminate of the present invention has high hardness and resistance to i, and at the same time, it can form a coating film excellent in surface smoothness (as a feature of the ®, particularly suitable for: CD, DVD, MO, high density DVD density- DVD; HD-DVD), Blu-ray disc, recording disc for second-generation DVD, plastic optical parts, touch-sensitive film type liquid crystal elements, plastic containers, floor wood wall materials for building interior materials, artificial Anti-damage (scratch) or anti-fouling protective material for marble, etc.; or anti-reflection film for thin film type liquid crystal elements, touch panel, driving school parts, etc. Injury) high, etc. version, material, used glue -40-

Claims (1)

200844127 X. Patent Application No. 1 A curable composition containing the following components (A) to (D): (A) a repeating unit having a polymerizable unsaturated group represented by the following formula (1a) And a polymer having a repeating unit represented by the following formula (1 b ), (B) a compound represented by the following formula (3 a ) or (3 b ), and (C) having a molecule other than the above component (A); Two or more polymerizable unsaturated group compounds, (D) photopolymerization initiator; [Chemical Formula 1] *--CpH2pO-一* (1a) "?H3 1 L CH3" [Formula (la) and (lb In the case, P is 1 to 10. LiCn, F2n, + 1X (3a) Li(Cn, F2n, + 1 Y)2N (3b) [In the formulas (3a) and (3b), X represents CO 2 or S03, and Y represents CO or S02, n, indicating An integer from 1 to 9]. 2. The curable composition according to the first aspect of the invention, wherein the component (A) has a polymerizable unsaturated group (meth) propylene group. 3. The curable composition according to claim 1 or 2, wherein the component (A) further contains a urethane group. The curable composition according to any one of items 1 to 3, further comprising the following component (E): (E) having a polymerizable unsaturated group and selected from the group consisting of An oxide containing at least one element of a group of strontium, aluminum, chromium, titanium, zinc, bismuth, indium, tin, antimony, and bismuth as a main component. 5. The sclerosing composition of the fourth aspect of the invention, wherein the polymerizable unsaturated group of the component (E) has a group having a structure represented by the following formula (4); [Chem. 2] - U —C—N— (4) II V [In the formula (4), U represents ΝΗ, 0 (oxygen atom) or s (sulfur atom), and V represents Ο or S]. A cured film obtained by curing a curable composition according to any one of claims 1 to 5 of the patent application. A laminate comprising a cured film as claimed in claim 6 on a substrate. -42- 200844127 VII. Designated representative map: (1) The representative representative of the case is: No (2), the representative symbol of the representative figure is a simple description: No. 8. If there is a chemical formula in this case, please reveal the best display invention. Chemical formula of the feature: none