200836780 九、發明說明： 【發明所屬之技術領域】 本發明係關於含甲殼素之超音波除菌方法及設備，尤 一種由水份（X)與甲殼素（γ)組成之除菌液體，以χ :曰 Υ = 5 0 〇 : 1組成，該除菌液體經催化頻率為2 · 4而ζ〜 3 · 6ΜΗΖ之超音波霧化器加以催化而產生約3 〇 〇nm (奈米） 〜1 5 Onm (奈米）之霧化液體，再利用該霧化液體散佈於 室内空間或任何空間中，即具備完美除菌效果之超音波除菌 方法。 【先前技術】 按習知含曱殼素之抗菌組成，乃如台灣發明專利公開第 20053846 8號：抗菌喷霧組成物及其製備方法，該 習知之抗菌喷霧組成物，包含一甲殼素或幾丁聚糖，該甲殼 素或幾丁聚糖係利用過氧化氫降解後分子量介於1〇〇〇〇 一 100,000内和一酒精，其製備方法，其包含將一甲殼素或幾 丁聚糖摻入一鹼性的水中加熱，再加入一過氧化氫，將該甲 设素或幾丁聚糖降解至分子量— 1〇〇〇〇〇内；將上述分 子量100+00 - 100000内之甲殼素或幾丁聚糖以一酸加以溶解， 濾除不溶物，再以鹼液滴定使該甲殼素或幾丁聚糖析出；所 析出之該甲殼素或幾丁聚糖粉碎成漿狀，通入一二氧化碳使 該甲殼素或幾丁聚糖溶解；再摻入一乙醇，得到該抗菌喷霧 組成物，該抗菌喷霧組成物具有良好抗菌效果（抗菌效果達 99.9%)，且喷在所在部位不會產生黏腻感。 ^亦即該種主要特徵要是要製備抗菌喷霧，以去除抗菌噴 ，之，腻感，且其係將將曱殼素或幾丁聚糖經加熱，利用過 氧化氫降解後分子量介於1〇〇〇〇 — 1〇〇, 〇〇〇内，並以一酸溶解， 滤除不溶物’再以鹼液滴定使該曱殼素或幾丁聚糖析出；所 析出，該曱殼素或幾丁聚糖粉碎成漿狀，通入一二氧化碳使 该甲忒素或幾丁聚糖溶解；再摻入一乙醇，得到該抗菌喷霧 組成物。 5 200836780 ^該習知者，製備抗菌喷霧後，再以該抗菌噴霧噴在所在 部之^法，用以抗菌。而與本發明之利用超音波霧化器直接 將除菌液體加以霧化並輸出於室内空間，藉以產生殺^ 之結構特徵與方法並不相同。 【發明内容】 本毛明之目的，乃在提供一種包含曱殼素之超音波除菌 方法及没備’主要係利用由水份（X )與曱殼素（Y )，以X · , Y= 5 0 0 : 1組成之除菌液體，經催化頻率為2· 〜· 3· 6ΜΗΖ之超音波霧化器加以催化而產生約3 〇 〇nm (奈米 ^ 〜1 5 Onm (奈米）之霧化液體，並利用該含甲殼素之霧j匕 液體散佈於室内空間或任何空間中，產生極完美除菌功能夕 超音波除菌方法與設備。 本發明之特點有： 1 本發明之含曱殼素之超音波除菌方法，其中除菌液 體係由水份（X)與甲殼素（γ)，以x ·· Υ=5 0 〇、·· ’巧 合組成最理想。 ·丄處 _2.本發明之含甲殼素之超音波除菌方法，其中除菌液 • 體係由水份（X)與甲殼素（Υ)，以Χ:Υ=5〇〇:1| 成最f想，係基於該比例之除菌液體，於霧化後已具備適/ , 之除菌甲殼素。但是，基於需要將該水份之比例調整為大二 5 0 0 ;或小於5 ο 〇。及前述甲殼素之比例則可以大於、· 或小於1亦無不可。 、1’ 3 ·本發明之含甲殼素之超音波除菌方法，其中超a 霧化器之催化頻率以2 · 4MHZ〜3 · 6MHZ最理想。 曰〆 4 ·本發明之含曱殼素之超音波除菌方法，除菌液 起曰波務化裔霧化時，將產生約3〇〇 nm (奈米）〜] (奈米）之霧化液體。 nm _ 5 ·本發明之含曱殼素之超音波除菌設備，係於設備 設儲水箱，並於除菌液體經超音波霧化器霧化時，將 3 0 〇nm (奈米）〜1 5 〇nm。 王、、勺 6 200836780 【實施方式】 貴審查員可充份了解本發明’茲依附圖式 為本發明含曱殼素之超音波除菌方法，該 如此，為使 解說如下： 如圖一所示 除菌方法，包含^ $入ί ί液Ϊ1，除菌液體1係由水份（X)與甲殼素（γ) : 迷除菌液體中之水分與曱殼素之混合比例為（水 ί (水八、3素）γ = 5 0 0: 1最理想，而述除菌液體 '+· Tv ^ '、（曱设素）Y之採用此一比例，乃是基於德 ==化；’霧化後之每-除菌液體之分子，仍ΐ 相9，价:甲忒素，且能達成殺菌目的，經實驗而得。 C大二=需求’亦可將前述除菌液體之水份X比例調 或小於5 0 〇 ;及前述甲殼素Y之比例則 了周ί為ί於1;或小於1亦無不可。 〜3超2霧，超音波霧化器2之催化頻率以2.4腿 體霧化後，ί )霧化f 3將前述除菌液 霧化除菌液體二 =:)之霧化除菌液體輸送到室内空 間或靶圍中，即可將空氣中或是存在於器物上之有宝 提供更安全與舒適之生活空間者。 〃 第發=之含甲殼素f超音波除菌設備，其實施例乃如 弟一或第二圖所示，該除菌設備，包含： 本體3，本體3設儲水箱3 0，儲水箱3 〇下方並# 位檢知元件31，利用前述檢知元件31以檢知儲 量，提省使用者隨時添加儲水，確保設備運作正=水 水箱3 Q箱下方又設置出水閥3 2，利用出水閥3 = :方，3 3之水位’並控制超音波霧化器2 ; 1，精以令除菌液體可以快速產生霧化。 甲殼素儲槽4 ’曱殼素儲槽4設於水槽3 3一側（如圖 7 200836780 二或三所示），該甲殼素儲槽4係設置於儲槽座4〇， 4 0並設適當之出口4 1，利用出口4 1保持甲殼素之 並與前述水分可以混合組成前述除菌液體1。 别 起曰波務化器2則是设置於本體3 —側，利用該超立、、古 霧化器2可以將前述除菌液體加以霧化，且如前述，該二1 波霧化器2之催化頻率以2· 4MHZ〜3· 6MHZ最理想 該=菌液體霧化產生約3 〇 〇nm (奈米）〜丄5 〇nm (奈米于) ^霧化除菌液體。並利用利用除菌設備將霧化之除菌液"體輸 送到至内空間或是設定之空間或範圍中，即可將空氣中或是 存在於為物上之有害菌去除，提供更安全與舒適之生活空間 者0 再者’上述本發明，除菌液體除經美國政府環保署（腿丁仙 STSTES ENVIRONMENTAL PROTECTION AGENCY ) EP A認證通 過含甲忒素外，另經台灣檢驗科技股份有限公司（SGSTaiwan Ltd·)及中國廣州工業微生物檢測中心（guangzh〇uindustry MICROBE TEST OT·)實驗，財發縣除目液體霧化後輸 至ί空間’測試1小時可以除去自然菌66.67% ;金黃色 葡萄球菌44· 5%，測試8小時，其除菌效果達到99· 99%，且 同時可除去空間内之有機溶劑之氨氣（ΝΗ3) 約42%，及甲醛 (CH20)約65%，由此，顯見，本發明確實具備實用效果， 為本案之組成。 【圖式簡單說明】 第一圖：本發明方法之流程圖。 圖 圖 第一圖·本叙明之除菌設備之實施例一剖視 第三圖：本發明之除S設備之實施例二剖視 【主要元件符號說明】 除囷液體1 水位檢知元件3 儲槽座4 0、出 、超音波霧化器2、本體3、儲水箱3 0、 1、出水閥3 2、水槽3 3、曱殼素儲槽4、 σ 4 1 8200836780 IX. Description of the Invention: [Technical Field] The present invention relates to a chitin-containing ultrasonic sterilization method and apparatus, and particularly to a sterilization liquid composed of moisture (X) and chitin (γ), χ :曰Υ = 5 0 〇: 1 composition, the sterilizing liquid is catalyzed by an ultrasonic atomizer with a catalytic frequency of 2 · 4 and ζ ~ 3 · 6 产生 to produce about 3 〇〇 nm (nano) ~ 1 5 Onm (nano) atomized liquid, which is then dispersed in indoor space or any space, which is a supersonic sterilization method with perfect sterilization effect. [Prior Art] The antibacterial composition containing chitin is conventionally known as Taiwan Patent Publication No. 20053846 No.: an antibacterial spray composition and a preparation method thereof, the conventional antibacterial spray composition comprising a chitin or Chitosan, the chitin or chitosan is degraded by hydrogen peroxide and has a molecular weight of between 1 and 100,000 and an alcohol, and the preparation method thereof comprises a chitin or chitosan Heating in an alkaline water, adding a hydrogen peroxide, degrading the methyl or chitosan to a molecular weight of -1 ;; and the above-mentioned chitin having a molecular weight of 100+00 - 100000 Or chitosan is dissolved by an acid, the insoluble matter is filtered off, and the chitin or chitosan is precipitated by alkali droplets; the chitin or chitosan precipitated is pulverized into a slurry, and is introduced into the slurry. a carbon dioxide dissolves the chitin or chitosan; and further incorporates ethanol to obtain the antibacterial spray composition, the antibacterial spray composition has a good antibacterial effect (antibacterial effect of 99.9%), and is sprayed at the site Does not create a sticky feeling. ^ That is, the main feature of this kind is to prepare an antibacterial spray to remove the antibacterial spray, which is greasy, and the system will heat the chitin or chitosan, and the molecular weight is 1 after decomposing with hydrogen peroxide. 〇〇〇〇-1〇〇, 〇〇〇, and dissolved with an acid, filter out insolubles' and then precipitate the chitin or chitosan by alkali droplets; precipitated, the chitin or The chitosan is pulverized into a slurry, and the carbachol or chitosan is dissolved by introducing a carbon dioxide; and then an ethanol is added to obtain the antibacterial spray composition. 5 200836780 ^ The well-known person, after preparing an antibacterial spray, sprays the antibacterial spray on the part to be used for antibacterial. In contrast, the ultrasonic atomizing device of the present invention directly atomizes the sterilization liquid and outputs it in the indoor space, so that the structural features and methods for generating the killing are not the same. SUMMARY OF THE INVENTION The purpose of the present invention is to provide a method for ultrasonic sterilization comprising chitin and to prepare 'mainly utilized by moisture (X) and chitin (Y) to X · , Y = 5 0 0 : 1 consisting of a sterilizing liquid, catalyzed by an ultrasonic atomizer with a catalytic frequency of 2·3·3·6ΜΗΖ to produce about 3 〇〇nm (nano ^ 〜1 5 Onm (nano)) Atomizing the liquid and using the chitin-containing mist to disperse the liquid in the indoor space or any space, thereby producing a perfect sterilization function and a method and device for removing ultrasonic waves. The features of the present invention are as follows: Ultrasonic wave sterilization method of chitin, wherein the bacteria removal system consists of water (X) and chitin (γ), which is ideally composed of x ··Υ=5 0 〇,·· '. 2. The chitin-containing ultrasonic wave sterilization method of the present invention, wherein the sterilization liquid system comprises water (X) and chitin (Υ), and Χ:Υ=5〇〇:1| Based on the ratio of the sterilizing liquid, after the atomization, the sterilized chitin is provided. However, the proportion of the water is adjusted to be the second 50,000 according to the need; Less than 5 ο 〇. The ratio of the aforementioned chitin may be greater than, · or less than 1 and 1' 3 · The chitin-containing ultrasonic sterilization method of the present invention, wherein the catalytic frequency of the super a atomizer It is most preferably 2 · 4MHZ~3 · 6MHZ. 曰〆4 · The method for ultrasonic sterilization of the chitin containing the present invention, when the sterilization liquid is atomized by the wave, it will generate about 3 〇〇nm ( Nano)~] (nano) atomized liquid. nm _ 5 · The chitin-containing ultrasonic sterilization device of the present invention is installed in a storage tank and is subjected to an ultrasonic atomizer in a sterilization liquid. When atomizing, it will be 30 〇nm (nano)~1 5 〇nm. Wang, and spoon 6 200836780 [Embodiment] The inspector can fully understand the present invention. The method of ultrasonic sonication, in order to make the explanation as follows: As shown in Figure 1, the sterilization method includes ^ 入 ί Ϊ liquid Ϊ 1, the sterilizing liquid 1 is composed of water (X) and chitin (γ) : The mixing ratio of water and chitin in the sterilizing liquid is (water ί (water 八, 3 prime) γ = 5 0 0: 1 ideal, and the sterilizing liquid '+ · Tv ^ ', (曱素素) Y is based on this ratio, which is based on the German ==; after the atomization of the molecule of the sterilizing liquid, still ΐ phase 9, price: 甲素素, and Can achieve the purpose of sterilization, obtained through experiments. C sophomore = demand 'may also adjust the proportion of water X of the above-mentioned sterilization liquid to less than 50 〇; and the ratio of the aforementioned chitin Y is Zhou ί is 1 ; or less than 1 or no. ~ 3 super 2 fog, the catalytic frequency of the ultrasonic atomizer 2 is 2.4 atomized after atomization, ί ) atomization f 3 will atomize the above-mentioned sterilization liquid to sterilize the liquid 2 =: The atomized and sterilizing liquid is transported into the indoor space or the target area, and the person who is in the air or on the object can provide a safer and more comfortable living space. 〃 The first chiral f-containing ultrasonic sterilization device, the embodiment of which is shown in the first or second figure, the sterilization device comprises: a body 3, the body 3 is provided with a water storage tank 30, the water storage tank 3 The lower detecting unit 31 uses the detecting element 31 to detect the reserve, and saves the user to add water at any time to ensure that the device operates positively. Valve 3 = : square, 3 3 water level 'and control ultrasonic atomizer 2; 1, fine so that the sterilization liquid can quickly produce atomization. The chitin storage tank 4 'chitin storage tank 4 is arranged on the side of the water tank 3 3 (as shown in Fig. 7 200836780 two or three), and the chitin storage tank 4 is arranged in the storage tank seat 4〇, 40 A suitable outlet 4 1 is used to maintain chitin by the outlet 41 and may be mixed with the aforementioned moisture to form the aforementioned sterilizing liquid 1. The sterilizing device 2 is disposed on the side of the body 3, and the sterilizing liquid can be atomized by the ultra-low, ancient atomizer 2, and the two-wave atomizer 2 is as described above. The catalytic frequency is preferably 2·4MHZ~3·6MHZ. The liquid is atomized to produce about 3 〇〇nm (nano)~丄5 〇nm (nano). And by using the sterilization equipment to transport the atomized sterilization liquid into the inner space or the set space or range, the harmful bacteria in the air or existing in the object can be removed and provided safer. And the comfortable living space 0. In addition to the above invention, the sterilization liquid is passed by the US Government Environmental Protection Agency (STSTES ENVIRONMENTAL PROTECTION AGENCY) EP A certification, and the Taiwan Inspection Technology Co., Ltd. (SGSTaiwan Ltd.) and Guangzhou Industrial Microbial Testing Center (guangzh〇uindustry MICROBE TEST OT·) experiment, Caifa County, after the liquid atomization, was transferred to the ί space' test for 1 hour to remove 66.67% of natural bacteria; golden yellow grapes Cocci 44·5%, tested for 8 hours, the sterilization effect reached 99. 99%, and at the same time, the ammonia gas (ΝΗ3) of the organic solvent in the space was removed by about 42%, and the formaldehyde (CH20) was about 65%. It is obvious that the present invention has practical effects and is a component of the present case. BRIEF DESCRIPTION OF THE DRAWINGS First FIG.: A flow chart of the method of the present invention. BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a cross-sectional view showing a third embodiment of the sterilization apparatus of the present invention. FIG. 2 is a cross-sectional view of the second embodiment of the present invention. [Description of main component symbols] In addition to the liquid 1 water level detecting component 3 Slot 40, out, ultrasonic atomizer 2, body 3, water storage tank 30, 1, water outlet valve 3, water tank 3 3, chitin storage tank 4, σ 4 1 8