TW200812487A - Active compound combinations having insecticidal properties - Google Patents

Abstract

The novel mixtures comprise at least one active compound of the formula (I) where Hal represents chlorine, bromine or iodine, * denotes a carbon atom in the R- or S- configuration, and at least one of the active compounds (2-1) to (2-14) listed in the description has very good insecticidal and acaricidal properties.

Description

200812487 IX. DESCRIPTION OF THE INVENTION: FIELD OF THE INVENTION The present invention relates to a novel active compound composition which first comprises at least one compound of the formula (I), and secondarily comprises at least one other selected from benzoic acid Carboxylic acids, macrolides, dimercaptopurines, carboxylic acids or other known active compounds which are highly suitable for controlling animal pests such as insects and unwanted mites. [Prior Art] 10 Compounds of formula (I) are known

Hal represents chlorine, bromine or hydrazine, and * represents a carbon atom in the R- or S-configuration, preferably in an S-configuration, having insecticidal activity. This applies to the racemic form of the compound (EP-A 1 2〇006 107) and even to the enantiomer of the (S)-configuration (disclosed in this patent application JP 2006-089469) . Compounds (la), (lb) and (Ic) can be clearly stated. 200812487

HX s〇2ch3 (la) : (S)-3-methyl-4-( 1,2,2,2·tetrafluoro-1-(trifluoromethyl)ethyl]phenyl b N, (1_ Mercaptomethylsulfonylethyl) decylamine

(this): (8)-3ϋ]2-mercapto-4-[l,2,2,2-tetrafluorosuccinyl(trifluoromethyl)ethyl]phenyl bene N2_(1-methyl-2- Methylsulfonylethyl)guanamine (k) : (S)-3-bromoindolyl-4-[l,2,2,2-tetrafluoro-1_(trifluoromethyl)ethyl]benzene }}-N2-(1_methyl-2-methylsulfonylethyl) decylamine 15 _ It is also known that a variety of different heterocycles, organotin compounds, benzamyl ureas and pyrethroids have Insecticide and mites (see W〇93-22 297, WO 93-10 083, DE-A 2 641 343, EP-A-347 488, EP-A-210 487, US_A 3 264 177 and EP- A-234 045). However, the activity of these compounds is always unsatisfactory. SUMMARY OF THE INVENTION An active compound composition comprising a compound of the formula (1) and at least one active compound of the following class 200812487 (A) benzodicarboxylic acid derivative, preferably (2-1) volt, has been discovered. Fhibendiamid (known in EP-A 1 006 107)

And/or (B) macrolides, preferably (2-2) Spinosad (known in ΕΡ-Α0 375 316)

Preferably, it is a mixture of 85% spinosyn A (R=H) and 15% spinosyn B (R=CH3) and/or (2-3) Emetin ( Abamectin) (known in DE-A27 17 040) and/or (2-4) emamectin benzoate (known in EP-A 0 089 202) 200812487 and/or (C) Diterpenoids, preferably (2-5) methoxyfenozide (known in ΕΡ-Α0 639 559)

And / or ίο (2-6) tebufenozide (known in EP-A-339 854)

15 and / or

(2-7) Chromafenozide (ANS-118) (known in ΕΡ, Α 0 496 342)

And/or (D) carboxylic acid esters, preferably (2-8) indoxacarb (known in WO 92/11249) 200812487

CI and / or (E) other insecticidal active substances, preferably (2-9) fipronil (known from EP-A0 295 117) α f3c

Cl 10 and/or (2-10) ethiprole (known in DE-A 196 53 417) 15

And / or (2-11) flonicamid (known in EP-A 0 580 374)

-10- 200812487 and / or (2-12) chlorfenapyr (known in EP-A0 347 488)

10

Br

15

And/or (2-13) (3-bromochloro-2-indolyl-6-[(methylamino)carbonyl]phenyl}·1-(3·oxapyridin-2-yl)-1Η-pyridyl Zyrom-5-carboxyguanamine) (known from WO 03/015519) and/or (2-14)3->odor-1-(3-chloroindolepyrimidin-2-yl)-N-[ 4-oxyl-2-methyl-6-(methylamine-mercapto)phenylHH-pyrazole-5-carboxyguanamine

Br

It has synergistic activity and is suitable for controlling animal pests. 20 200812487 The insecticidal activity of the active compound compositions according to the invention is surprisingly much better than the activity sum of the individual active compounds. It exhibits unpredictable synergistic effects and is not only additive activity. In addition to at least one active compound of the formula (I) which is enantiomerically pure or in a mixture of the two enantiomers 5 in any proportion, the active compound composition according to the invention still comprises at least one active as described above Compounds (2-1) to (2-14). Preferably, the active compound composition according to the invention comprises an active compound (la), (lb) or (Ic) and an active compound (2-1) to ίο (2-14) as described above. The mixture listed in 1. Table 1 The mixture contains 15 la and 2_ 1 (fubendiamid) la and 2-2 (sinosad) W la and 2-3 (amy, abmectin) la and 2- 4 (ememectin benzoic acid) la and 2-5 (methoxyfenozide) 20 la and 2-6 (tebufenozide) la and 2-7 (ke Masai ( Chromafenozide)) la with 2-8 (indoxacarb) la with 2-9 (fipronil) la and 2-10 (e1;hiprol) -12- 200812487 la with 2-11 (fl〇nicamid) la and 2 -12 (kl〇rfenapyr) la and 2-l3 (3-indigenous chloromethyl each [(methylamino)) Carbonyl]phenyl} -1-(3·Gas ratio.Determin-2-yl)-1 Η-σ ratio salivary-5-sweet amine) 5 la and 2-14(3- >odor-1 (3. Nitrogen ratio: dimethyl-2-yl)-indole-[4-nitro-2-methyl(indenylcarbinyl)phenyl]-1 oxime-pyrazole each carboxamide) lb With 2-1 (fubeiidiamid) • lb and 2-2 (Spinosad) lb and 2-3 (Amy, abumectin) 10 lb and 2-4 (Enmei , ema (ememectin) benzoic acid vinegar) lb and 2-5 (methoxyfenozide) lb and 2-6 (tebufenozide) lb and 2-7 (chromafenozide) lb and 2-8 (indoxacarb) 15 lb and 2-9 (fipronil) • lb and 2-10 (el:hiprol) lb and 2-11 (flonicamid) lb and 2 -12 (chlorfenapyr) lb and 2_13 (3_bromo) 1{4-Chloro-methylmethyl each [(methylamino)carbonyl]benzene 20-yl}small (3-chloropyridin-2-yl)-1 -pyrazol-5-carboxamide) lb and 2-14 (3-Di-1-(3-chloropyridinyl!)-N-[4-cyano-2-methyl-6-(methylamine-methyl)phenyl]-1 吼嗤-5 - Carboxylamamine) -13- 200812487

Ic and 2-1 (fubendiamid) Ic and 2-2 (spinosad) Ic and 2-3 (abamectin) Ic and 2-4 (ememectin) Benzene citrate) 5 Ic and 2-5 (methoxyfenozide) Ic and 2-6 (tebufenozide) Ic and 2-7 (chromafenozide) Ic and 2 -8 (indoxacarb) Ic and 2-9 (fipronil) 10 Ic and 2-10 (ethiprol) Ic and 2-11 (flonicamid)嶙Ic and 2-12 (chlorfenapyr) • Ic and 2-13 (3-bromo-N-{4-chloro-2-indolyl-6-[(decylamino)carbonyl]phenyl }-1-(3-chloropyridin-2-yl)-1Η-pyrazole-5-carboxyguanamine) 15 Ic with 2-14 (3_> odor-1-(3-gas 17 to 11 -2- Base) -1^-[4-carbyl-2-indenyl • each (methylamine-mercapto)phenyl]-1H-pyrazole-5-carboxamide) Very particularly preferred as listed in Table 2 mixture. Table 2 20 Mixture containing lb and 2-1 (fubendiamid) lb and 2-2 (spinosad) lb and 2-3 (abamectin) -14- 200812487 lb with 2-4 (emme, emamectin benzoate) lb with 2-5 (methoxyfenozide) lb and 2-6 (tebufenozide) lb with 2-7 (gram Châteaux (chromafenozide) 5 lb with 2-8 (indoxacarb) lb with 2-9 (flpronil) lb with 2-10 (ethiprol) • lb and 2 -11 (flonicamid) lb with 2-12 (chlorfenapyr) 10 lb and 243 (3-bromo-indole-{4-chloro-2-indenyl [[methylamine] Carbonyl]phenyl}-1-(3-chloropyridin-2-yl)_1Η-pyrazole-5-carboxyguanamine) lb and -6-(methylaminoindenyl)phenyl]-m- Pyrazole-5-carboxamine) 15 A particularly good mixture for treating seeds contains • (lb) with fipronil (lb) and spinosad or (lb) with abamectin. 20 When the active compound compositions according to the invention comprise certain weight ratios of the active compounds, their synergistic potency is particularly pronounced. However, the weight ratio of active compound in the active compound composition can vary over a considerable range. In general, the composition according to the invention comprises an active compound of the formula (1) and a compound 5-1-200812487 compound (2-1) to (2-M) in a ratio of the following particularly preferred ratios: preferred mixing ratio I25 : 1 to 1: 125 Excellent mixing ratio 25 : 1 to 1 · · 25 The ratio of 5 is based on the weight ratio. It is understood that the ratio refers to the active compound of the formula (I): the active compounds (2-1) to (2-14). The active compound composition of the invention has good plant tolerance, has favorable toxicity to φ Shiyan animal and good environmental compatibility, is suitable for protecting plants and plant organs, improves harvest yield, and improves the quality of harvest materials and 10 Control of animal pests, especially agriculture, horticulture, animal husbandry, forests, gardens and leisure facilities, protection of stock products and raw materials, and animal pests, especially insects, spiders, worms, nematodes and software. animal. It is more suitable as a plant protection agent. It is active against general susceptibility and resistance varieties' and against all or some stages of development. The above pests include: 15 Phthiraptera, for example: Damalinia, Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp ·). Arachnida, for example, Acarus siro, Aceria sheldoni, Aculops spp., Aculus spp., A. lycopene (Amblyomma spp·) ), Argas SPP., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp·, chicken skin Dermanyssus gallinae, Eotetranychus genus, Epipirerus pyri, Eutetranychus -16-200812487 spp., Eriophyes spp., Hemitarsonemus spp .), Hyalomama spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., 〇lig〇 nyChus spp.), blunt edge 5 genus (Ornithodoros spp.), genus Panonychus spp., Phyllocoptmta oleivora, Polyphagotarsonemus latus, Psoroptes spp. , fan head φ 蜱 genus (Rhipicephalus spp.), root genus Rhizoglyphu s spp·), Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp. , Vasates lycopersici o ... Bivalva, for example: Dreissena spp. From the order of the Chilopoda, for example, Geophilus spp. and Scutigera spp. 15 Coleoptera, for example: Acanthoscelides ^ obtectus, Adoretus spp., Agelastica alni, Agriotes spp., June chafer (Amphimallon) Solstitialis), Anobium pimctatum, Anoplophora spp., Anthonomus spp., Anthrenus spp., Apogonia, Atomaria spp .), Attagenus spp., Bean Elephant (6111 (:11) (^118〇^^.1; 113), genus Bruclius spp., and genus Couthorrhynchus spp .), Cleonus mendicus, Conoderus spp., Cosmopolites spp., Costelytra zealandica, 17 200812487 Curculio spp., Liu Xiaoyin. Cryptorhynchus lapathi), Dermestes spp., Aphis (0131>1*〇1^3 8$|>·), Epilachna spp., Faustinus cubae, Gibbium Psylloides), Heteronychus arator, Hylamorpha 5 elegans Hylotrupes bajulus, Hypera postica, Hypothenemus spp, Lachnosterna consanguinea, potato beetle (Leptinotarsa • decemlineata), rice locust (Lissorhoptrus oryzophilus) ), Lixus spp., Lyctus spp., Meligerethes 10 aeneus, Melolontha melolontha, Migdolus, Monochamus spp., Naupactus xanthographus , Golden - Niptus hololeucus, Oryctes rhinoceros, Oryzaephilus surinamensis, Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, food Phyllophaga spp., Popillia japonica, Premnotrypes, Psylliodes chrysocephala, Ptinus spp., Rhizobius ventralis, powder length Rhizopertha dominica, Sitophilus spp., Sphenophorus spp., Stem genus 2〇 (Stern Echus spp.), Symphyletes spp., Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp. Collembola, for example, the spiny worm (Onychiurus -18- 200812487 armatus), Dermapterans, for example: F〇rficuia auriculana, Diplopoda, for example: Blaniulus Guttulatus. 5 Diptera (Diptera), for example: Aedes spp., Anopheles spp., Bibio hortulanus, Calliphora erythrocephala, Ceratitis capitata, (Chrysomyia spp.), Cochliomyia spp., Cordylobia anthropophaga, Culex spp., Cutrebra spp., fruit rope (Dacus) Oleae), Dermatobia hominis, Drosophila spp., Fannia spp., Gastrophihis spp., genus (1^16111}^800·) ,

Hyppobosca genus, Hypoderma spp., Liriomyza spp., Lucilia spp., Musca spp., Nezam spp., mad Oestrus spp., Oscinella frit, Pegomyia hyoscyami, Phorbia φ spp., Stomoxys spp., it genus Tabanus spp. , Tannia genus, big mosquito (Tipulapaludosa), carnivorous genus (\¥〇111£3]111^8卩口·). Gastropoda, for example: Arion spp., 2〇Biomphalaria, Bulinus spp., Deroceras spp., Galba spp. ), Lymnaea spp., Oncomelania spp., Succinea spp. Worm species, for example: Ancylostoma duodenale, Ancylostoma ceylanicum, Hookworm -19- 200812487 (Acylostoma braziliensis), Ancylostoma spp., Ascaris hibricoides, Helminthosporium (Ascaris spp.), Brugia malayi, Bmgia timori, Bunostomum spp., Chabertia genus, Clonorchis spp., Cooperia 5 genus, double trematode Genus (Dicrocoelium spp.), Dictyocauhis filariar, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus - ^ ^ (Echinococcus multilocularis), 蛲Enterobius vermicularis, Faciola, jk, Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus ^ spp ·), Loa Loa, Nematodirus spp., Oesophagostomum spp., Opisthorchis spp. Nematodes (Onchocerca volvulus), Ostertagia genus, Paragonimus spp., Schistosomen spp., Strongyloides fbellebomi, Strongyloides stercoralis, A. faecalis (Strongyloides spp.), Taenia saginata, Taenia solium, and squirting (1^〇1^1^11&8 mouth 3,1^(^1^11& nativa, Trichinellabritovi, Trichinellanelsoni, Trichinella 20 Pseud〇psiralis), Trichostrongulus spp., whipworm (1^〇1111118 1:11 (;11111^), Wuce nematode (\^11(;1^代1^5&11(( ^〇{^). It can also control other protozoa, such as Eimeria. Heteroptera, for example: Anasa tristis, Antestiopsis spp., Blissus spp., 蝽-20- 200812487 genus (Calocoris spp·), blind Py (Campylomma livida), Cavelleus spp., Cimex spp., Creontiades dilutus, Dasynus piperis, Dichelops furcatus, Diconocoris Hewetti, genus Dysdercus spp., 5 Euschistus spp., Eurygaster spp., Heliopeltis spp., Horcias nobilellus, Leptocorisa spp· ), Leptoglossus phyllopus, Lygus (Sp.), Macropes excavatus, Miridae, Nezara spp, Oebalus Spp.), Pentomidae, ίίο 军 军 P (Piesma quadrata), 蝽 ( (Piezodorus spp.), Red-streaked 蝽 (Psalhis seriatus), Pseudacysta persea, Rhododius - spp·, Cocoa brown Hl 蝽 (Sahlbergella singularis), 蝽黑蝽属 (Scot Inophora spp·), Stephanitis nashi, Tibraca genus, Triatoma spp. 15 Homoptera, for example: Acyrthosipon spp., Aeneolamia, Agonoscena, Aleurodes spp., Aleurolobus barodensis, pink genus Aleurothrixus spp.), Amrasca genus, Anuraphis cardui, Aonidiella spp., Aphanostigma 20 piri, Aphis spp., Arboridia apicalis, Aspidiella Aspidiotus spp., Atanus genus, Aulacorthum solani, Bemisia spp., Brachycaudus helichrysii, Brachycolus spp. Bravecoryne brassicae, leaf beetle (Calligypona -21 - 200812487

10 15

Marateata), Carneocephala fulgida, Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, CMonaspis tegalensis, leafhopper Chlorita onukii), Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus spp., Cryptomyzus Ribis), Dalbulus genus, Dialeurodes spp., Diaphorina genus, Diaspis spp., Doralis genus, Drosicha spp., Dysaphis spp. Dysmicoccus spp., Empoasca spp., Eriosoma spp., Geococcus coffeae, Homalodisca coagulata, Hyalopterus arundinis, Icerya spp., Idiocerus spp., Idioscopus spp., Laodelphax striatellus, Lecanium spp., 砺Intermedia (Lepidosaphes spp.), vegetables, Lipaphis erysimi, Macrosiphum spp., Mahanarva fimbriolata, Melanaphis sacchari, Metcalfiella, Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus spp., Nasonovia ribisnigri, Nephotettix spp., Nilaparvata lugens, Oncometopia genus Orthezia praelonga, Parabemisia myricae, hibiscus-22-20 200812487 (Paratrioza spp.), genus Parlatoria spp., Pemphigus spp., Peregrinus Maidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp., Pinnaspis 5 aspidistrae, mealworms (Planococcus spp.), pear-shaped raw cotton price (Protopulvinaria pyriformis), mulberry (Pseudaulacaspis pentagona), powder scale insect (Pseudococcus spp.), wood Insects (Psylla spp·), Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus i, genus Rhopalosiphum spp·), Saissetia spp., Scaphoides titanus, Schizaphis-graminum, Selenaspidus articulatus, Sogata spp., Sogatlella Furcifera), Sogatodes spp., Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp. Trialeurodes vaporariorum, Trioza spp., Typhlocyba spp., Unaspis spp., Viteus vitifolii. Hymenoptera, for example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp .) o Isopoda, for example: Armadillidium vulgare, Oniscus asellus, Porcellio scacalc o Isoptera, for example: Reticulitermes spp·, -23- 200812487 Odontotermes spp. Lepidoptera, for example: Spodoptera frugiperda (E. sinensis), Aedia leucomelas, Agrotis spp. ), Alabama argillacea, Anticarsia spp., Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, leaf moth (Bupalus piniarius) Cacoeciapodana), Capuareticulana, Carpocapsa pomonella, winter moth (0^11〇^1; 〇1^& bmmata), genus (Chilo spp.), spruce leaf moth ( Choristoneura ίο fumiferana), grape fruit (Clysia ambiguella), Cnaphalocerus spp., Earias insulana, Ephestia kuehniella, Euproctis chrysorrhoea, Euxoa spp., Feltia Spp.), Galleria mellonella, Helicoverpa spp., Heliothis 15 spp., Hofmannophila pseudospretella, Homona magnanima, Loucai Hyponomeuta padella, Laphygma spp., Lithocolletis blancardella, Lithhophane antennata, Loxalactalis albicosta, Lymantria spp. , Malacosoma 2〇neustria, Mamestra brassicae, Mocis repanda, Mythimna separate, Oria spp., Oulema oryzae, Ophiopogon japonicus (Panolis flammea), red worm (Pectinophora gossypiella), Phyllocnistis citrella, Pieris spp., Plutella xylostella, -24- 200812487 5 10 15 Genus (Prodenia spp ·), sticky genus (Pseudaletia spp ·), soybean armyworm (? 8611 (1〇0111813 111.11 ^ 6118), fill the wild (? >^1^&11111^1&118), Spodoptera spp., Theraiesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix viridana, Orthoptera, such as: Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa spp, horse Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria o (Siphonaptera) ), for example: Ceratophyllus spp., Xenopsylla cheopis. Combining the term (Symphyla), for example: Scutigerella immaculata. , Thysanoptera, for example: Baliothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, iCakothrips genus, Rhipiphorothrips cmentatus, Astragalus genus (8 (^1^〇化1^8 300.), 蓟马(丁361^〇让1^3 cardamoni), 蓟马属(Thrips spp·) Thysanura, for example, Lepisma saccharina ° Plant parasitic nematodes include, for example, Anguina genus, Aphelenclioides spp., Belonoaimus spp., viscous -25- 20 200812487

10 15

20 genus Bursaphelenchus spp., Ditylenchus dipsaci, Globodera, Heliocotylenchus, Heterodera spp., Longidorus spp., Meloidogyne Spp·), genus Pratylenchus spp., Radopholus similis, genus genus (〇 〇!}^11〇11118 spp·), genus Trichodorus spp., dwarf Nematode (Tylenchorhynchus spp.), Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp. 〇 Where appropriate, the active compound composition according to the present invention may also be Use as a herbicide, safener, growth regulator or plant improving agent or as a microbicide at certain concentrations or application rates, eg: fungicides, anti-fungal agents, bactericides, viricides (including Against anti-viruses) or as a preparation against MLO (mycoplasma-like organisms) and rl〇 (like rickettsia organisms). If appropriate, it can also be used as an intermediate or precursor for the synthesis of other active compounds. According to the present invention, all plants and plant parts are acceptable for treatment. When it is known, the plant system refers to all plants and plant groups, such as taiy and = or crops (including natural crops). Crops can be obtained from a combination of plant breeding methods and (iv) methods or using biotechnology methods, including genes _ plants 1 ΐ : : species conservation and unprotected plant cultivars. Also salty: planting: Partially refers to all above-ground and underground parts of plants = teeth, leaves, flowers and roots, examples of which can be described: broadleaf, needles, shafts, -26- 200812487 stems, flowers Fruit, fruit, seeds, roots, bulbs and roots are also included in harvested materials, and nutritive and reproductive materials: plugs, bulbs, rhizomes, branches and seeds. . Plant Department For example: _

10 The method for treating plants and plants using the active compound composition according to the present invention is a general treatment, direct treatment, or use in the environment, habitat or inventory space, for example: soaking, spraying: hair When spraying, spreading, painting, injecting, and processing propagation materials, the seed can also be coated with one or more layers when it is processed. The active compound composition can be converted into a conventional formulation, such as a solution specific emulsion, a wettable powder, an aqueous and oily suspension, a powder, a fine powder, a paste, a soluble powder, a soluble granule, a granule for spreading, a suspension a concentrate, a natural substance soaked with the active compound, a synthetic substance soaked with the active compound, a fertilizer, and a microencapsulated material contained in the polymeric material. 15

Such formulations are prepared in a known manner, for example, by mixing the active compound with a supplement, that is, a liquid solvent and/or a solid carrier, if desired, a surfactant, that is, an emulsifier and/or a leveling agent, And / or foaming agent. The formulation process is carried out in a suitable apparatus prior to or during application. The substances which can be used as adjuvants are suitable for the composition itself and/or its derived preparations (for example: spray liquid, seed coating) to impart special properties such as certain mechanical properties and/or special biological properties. Substance. Typical suitable adjuvants are supplements, solvents and carriers. Suitable extenders are, for example, water, polar and non-polar organic chemical liquids. For example: aromatic and non-aromatic hydrocarbons (eg, paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (and, if appropriate, substituted, -27-20 200812487) And/or brewing), ketones (eg acetone, cyclohexane), vinegars (including fats and oils) and (poly)ethers, unsubstituted and substituted amines, guanamines, Intrinsic amines (such as · · alkyl pyrrolidone) and lactones, sulfones and steroids (such as: dimethyl hydrazine).

10 20 When the animal uses water as a supplement, it is also possible to use, for example, an organic solvent as an auxiliary agent. Substantially applicable liquid solvents are: aromatic such as: dimethyl, methyl, or ketone, vaporized aromatic hydrocarbons and chlorinated aliphatic hydrocarbons such as: II, vinyl chloride or monochlorohydrazine, fat Hydrocarbons such as cyclohexane or sarcophagus, such as: petroleum fractions, mineral oils and vegetable oils, alcohols such as: butanol or glycerol = _ with esters, _ such as: c-, f-ethyl ketone, Methyl isoprene or % ketone, a strong polar solvent such as dimethyl sulfoxide, and water. Suitable solid carriers are: white examples = ammonium salts and natural mineral mills such as: kaolin, clay, talc, quality ground powder such as central fine white f, montmorillonite or diatomaceous earth' and synthetic carrier For example, · powdery acid salt; suitable for granules of solid stone, pumice, sea-bubble natural ore, such as: calcite, Dali grain, and organic matter particles; 'and inorganic and organic milling synthetic tobacco rod; Suitable for d, mineral crumb, coconut shell, corn stalk and ionic emulsifier such as % or foaming agent for example: nonionic and negative, for example: alkane, which is taken from ethylene fatty acid ester, polyoxyethylene fatty alcohol Ether, acid aryl vinegar, di?, alkyl sulfonate, alkyl vine sulfate, continuation or ionic substances, ^7. to the appropriate sentence (four) for non-ionic first / or POP POE _ _ ttPOE and / or - Pop scaly, acid and, base-and-group and/or POP P0E ethers, bacon 200812487 and/or POP POE adducts, and/or POP-polysaccharide derivatives, POE- and/or POP-sorbent A sugar alcohol, a saccharide, a sugar adduct, an alkyl or aryl sulfate, a decyl or an aryl acid, and a burned + # I or a square phosphate or a corresponding PO - ether adduct. In addition, it is also possible to use oligo or polymers which are suitable for & π, such as: oligos + or polymers derived from ethylene monomers, oligomers derived from acrylic acid or a polymer, an oligosaccharide 4 t ^ ^ or a polymer derived from squid > Η / or Ρ〇 alone or in combination, for example, a (poly)alcohol or a (poly)amine. Also available

10 15

20 Lignin and its sulfonic acid derivative, unmodified and modified cellulose, aromatic and/or aliphatic acid and its adduct with formaldehyde. Thickeners such as carboxymethylcellulose and natural and synthetic polymers in the form of powders, granules or latexes such as arabin, polyvinyl alcohol and polyethyl vinegar, and natural fats such as : brain fat and egg fat and synthetic phospholipids. It is also possible to use dyes such as inorganic pigments (for example: iron oxide, titanium oxide and Prussian blue), organic dyes such as alizarin dyes, azo dyes and metal ouocyanine dyes, and micronutrients such as iron. Salt, copper, diamond, indium and zinc salts. Other additives may be perfumes, mineral oils or vegetable oils, waxes and nutrients (including micronutrients) which may be modified as desired, such as salts of iron, lanthanum, boron, steel, cobalt, molybdenum and zinc. Stabilizers such as low temperature stabilizers, preservatives, antioxidants, light stabilizers or other agents that improve chemical/physical stability may also be included. The formulation usually comprises from 0.01 to 98% by weight of the above active compound, preferably from 0.5 to 90% by weight. -29- 200812487 The active compound composition of the present invention can be formulated as a compound and other active person, a human-like product formulation, and a medicament for infertility; fine;; a form of use, such as a microbial agent, growth regulation Substance or herbicide. ^ · Insecticides, chlorpyrifoss, amine phthalates, carboxylic acids, and the like, including, for example, substances produced by microorganisms. And deuterated hydrocarbons, phenylureas, or mixtures with other known active compounds, and growth regulators. For example, a herbicide, or a fertilizer, when used as an insecticide, can further react with a synergist to form a compound composition of a compound, but its::::!: increase the activity of the compound at::fan r : Chenghua 15 20 to 95 heavy Dan. The concentration of the active compound of the formula /4 can be o.o_m% by weight. Within the scope of the S compound, it is preferred that the compounds be administered in a manner suitable for the form of administration. ηΛΐΐ 'All plants and some of their plants can be treated according to the invention. The car is processed by the wild plant variety and the plant cultivar or the isochropod breeding method (eg, mating method or natively = with 14 plants. In another preferred embodiment, the system is treated by heredity) Engineering (if appropriate, 'can be combined with the method') to transform the gene plants and plant residues (base 0 modified silk), and its pure strain. The term "part" or "plant part,, or" Some plants have been described above. -30- 200812487 Plant 2: ί 'The plants according to the invention are processed from the commodity obtained or used. The salt knows 'plant cultivars means to pass the law or reorganize The plant obtained by the technology has a novelty. It may be biological or genotyped poetry, depending on the weight of the plant or plant cultivar, its position and growth conditions (soil = waiting, reading growth period, fertilizer), according to the treatment method of the present invention may also be produced Exceeding the additive ("potency") effect. Therefore, it may exceed the expectations of 10 15 20, for example, to reduce the application rate and/or to expand the range and/or increase the activity, and to use the activity of the composition f and the composition, to improve plant growth, to raise the temperature to normal or low temperature. Tolerance, improve tolerance to drought or water content or soil = salt content, increase flowering rate, simplify harvest, accelerate maturity, harvest in the south, improve the quality of harvested products and / or improve nutritional value, Good storage stability and / or improve the processability of the harvested products. Preferred transgenic plants or plant cultivars (i.e., those obtained by genetic engineering) treated in accordance with the present invention include all plants which are subjected to genetic modification during the genetic modification process. Examples of such characteristics are to improve plant growth, increase the susceptibility to high or low temperatures, and improve tolerance to drought or tolerance to water content or soil salt content: accelerated ripening, improved harvesting*, improved harvesting:: 3 quality and / or the nutritional value of the South, better storage stability and / or improve the processability of the harvested products. Other examples of the characteristics of the material are better defensive properties of plants against animal candlesticks and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and/or viruses, and also on plants for certain herbicidal active compounds. Tolerance. Examples of such transgenic plants are important * 31 - 200812487 crops such as: alfalfa (wheat, rice), corn, soybeans, potatoes, beets, pujia, bowls of vegetables, varieties, cotton, materials, objects (apples) , pears, tangerines and grapes) 'specially focus on corn, beans, beans and rape. Special (4) Tune special strains ^ form toxins, the genetic material from the Suyun gold buds thurmg job ls) (for example: gene CryiA (4) Axiong),

CrylA (8), CryIIA, CryIIIA, Cry Cong 2, c la Cong,

10 15

The toxins formed in the plant (hereinafter referred to as "Bt plants"') enhance the resistance to insects, (4), nematodes, and snails. It is acquired by acquired plant resistance (SAR), systemin, phytoalexin, inducer (10) 汾 (4) and resistance genes, and corresponding proteins and toxins to enhance defense against fungi, bacteria and viruses. Other special emphasis is on improving the tolerance of plants to certain herbicidal active compounds such as imidyanones, ureas, glyphosate or phosphinotdcin (eg: "PAT" gene). These genes, which confer the desired characteristics, can also be combined into a transgenic plant. Examples of ffBt plants can be described as corn varieties, cotton varieties, soybean varieties, and horse yam varieties sold under the following trade names: YIELD GARD® (eg, corn, cotton, soybean), KnockOut8 (eg, corn), StarLink 8 (eg, : Corn), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf8 (potato). Examples of herbicide-tolerant plants can be described as corn varieties, cotton varieties and soybean varieties sold under the following trade names: Roundup Ready® ( Tolerant to glyphosate (eg, corn, cotton, soybean), Liberty Link positive (phosphinotricin, -32-20 200812487 ^ oil extraction), IMI® (tolerant imidazolinones) With STS8 (tolerant to sulfonamide, six members of the ancients, such as corn). Herbicide-resistant plants (plants that are resistant to herbicides according to traditional breeding) include those sold under the following trade names. Clearfield8 (eg, corn). Of course, these instructions also apply to plant cultivars that have such genetic traits or are still developing such genetic traits that will be developed and/or marketed in the future. The remote plants can be treated in a particularly advantageous manner using the active compound compositions according to the invention. The preferred compositions mentioned above for the active compound compositions are also suitable for the treatment of such plants. The active compound composition treats the plant. The active compound composition according to the invention is not only active against plant pests, hygienic environment pests and stock product pests, but also veterinary, against animal parasites (external parasites and endoparasites) Such as: soft cockroaches, hard cockroaches, cockroaches, autumn cockroaches, ticks and ticks, parasitic larvae, cockroaches, ranunculus, cockles and fleas. These parasites include: Anoplurada 'Example: blind Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.. Mallophagida And Amblycerina and Ischnocerina, for example: Trimenopon spp., Menopon spp., and genus Trinoto n spp·), Bovicola spp., Werneckiella, Lepikentron, Damalina, Trichodectes spp., Felicola spp. Diptera and Nematocerina and Shorthorns -33- 200812487 5

10 15

(Brachycerina). For example, Aedes spp., Anopheles spp., Culex spp., Simulium spp, Eusimulium spp., Astragalus (Phlebotomus spp.), Lutzomyia genus, Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., it genus (Tabanus spp·) ), Hematopota spp., Philipomyia, Braula, Musca spp., Hydroteaa, Stomoxys spp., Haematobia spp., Morellia , genus Fannia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., meat genus Wohlfahrtia spp.), Sarcophaga spp., Oestrus spp., Hypoderma spp., Hippotosca spp., Lipoptena, Melophagus spp. 0 phon目 (Siphonapterida), for example, Pulex spp., Ctenocephalides spp., 蚤 〇 义 611〇0 87113 300.), Ceratophyllus spp. Heteropterida, for example, Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp. Blattaria, for example: Blata orientalis, Periplaneta americana, Blattella germanica, Supella spp. -34- 20 200812487 Acaria (Acarida) and Metastigmata and Mesostigmata, for example: Argas spp·, blunt Ornithodorus spp., Otobius spp., Ixodes spp., Amblyomma 5 spp., Boophilus spp., genus (Dermacentor spp.), Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus _ spp·, genus (Raillietia spp.), Pneumonyssus spp., Sternostoma spp., Varroa spp. oi Ac Ac Actinideida (former genus) (Prostigmata)) and

Acaridida (Astigmata), for example: Acarapis * spp., Cheyletiella spp., Ornithocheyletia spp., Myobia spp ·), sheep treatment (Psorergates spp.), genus (Demodex spp.), genus 15 (Trombicula spp.), genus (1^1; 1*(^11〇1118 8 mouth) .), Acarus spp., Tyr〇phagus spp., Caloglyphus spp., Hypodectes, Pterolichus SPP·, itch (Psoroptes spp·), genus Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes Spp.), Cytodites spp., Lamemisoptes spp. The active compound composition according to the invention is also suitable for controlling arthropods that infest agricultural animals, such as, for example, cattle and sheep. , goat, horse, pig, donkey, road wheel, buffalo, rabbit, chicken, turkey, duck, goose and honey -35- .200812487 Other pet animals such as: dogs, fish in the box, and so-called experimental animals, birds and aquariums in the sentence, such as: rats and mice. By controlling these Arthropod:, rate and improve its productivity (referring to meat, dairy, hair, etc. to reduce its death, etc.), so it can be used according to the invention to activate the compound =, * honey, etc. and simpler animal management. The material is more economical. According to the date of this issue, the combination is in the field of animal contact and animal management. The system is in the intestine 2 = medical 10 15 20 capsules, drink, medicine, granules, paste, Daimaru, two _, parenteral administration 'such as, for example, injection (de-in, under: base; intra-membrane, etc.), implantable, ^ ^ evaluation of the pulse, abdomen such as: sputum, spray 2 The form of administration through the skin, such as, reading, money, medicine, cleaning and containing active compounds; ^@^ σ 'knife and hunting aid for cattle, poultry, pet animals, etc., active compound cylinder characters The inclusion of 1 to 8% by weight of the active compound can be used directly after dilution of 100 to 10,000 times. Or it can be used as chemical dipping water. Furthermore, it has been found that the active compound composition according to the invention has a strong insecticidal action against fb insects which destroy industrial raw materials. The following insects can be mentioned, which are examples and preferred examples, but are not limited: Locusts such as Hylotrupes bajuhis, Chlorophoms pil〇sjs, furniture thieves (An〇bium) Punctatum), -36- 200812487

Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Emobius mollis, Priobium carpini, Lyctus brunneus, Lyctus africanus, Lyctus planicollis, Lyctus linearis, soft hair Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec·, Tryptodendron genus, Apate monachus, Bostryclms capucins, • European bamboo scorpion Heterobostrychus brunneus), Sinoxylon spec, Dinoderus minutus 〇i〇Hymenopterans such as: Sirex juvencus, Urocerus gigas, Tiger tree bee (Urocerus . gigas taignus) ^ Urocerus augur ° Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes 15 indicola, Reticulitermes flavipes, Mountain Rhinoceros Reticulitermes santonensis, Reticulitermes lucifugus Australia termites (Mastotermes darwiniensis), Nevada ancient white sacrifice (Zootermopsis nevadensis), white home sacrifice (Coptotermes formosanus) ° 20 clothing fish 'such as: Western Silverfish (Lepisma saccharina). Salty understands that the industrial raw materials referred to herein are inanimate materials such as plastics, adhesives, glues, paper and cardboard, leather, wood and processed wood products and coatings. The ready-to-use compositions may include other insecticides, if appropriate, -37-200812487 and, if appropriate, one or more fungicidal gases. Other additives that are feasible are the above-mentioned killing insects & and the bacteriostatic agents. According to the active compound composition of the present invention, the same salt-flavored water needs to be protected, especially in the case of ή 广 广 咖 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 Signal system to prevent shell algae contamination. Further, the active compound composition according to the invention may be used alone or in combination with other active compounds as an anti-soul plug. The active compound composition is also suitable for controlling animal pests in home, sanitary and protective inventory products, especially pests such as 7 insects, spiders and galls, which are often found in enclosed spaces, such as 'apartment, factory, office, carriage, etc. Wait. It can be used alone or in combination with other active compounds and adjuvants which control such pests in household insecticide products. It is active against destructive and resistant alpha alpha species and is resistant to all stages of development. Such pests include: Scorpionidea, for example: Buthus 〇ccitanus. 15 Acadna, such as Argaspersicus, Argas reflexus, Bryobia ssp·, Dermanyssus gallinae, poultry sweets (Glyciphagus domesticus), Ornithodorus moubat, Rhipicephalus sanguineus, Trombula alfreddugesi, Neutrombicula autunmalis, Dermatophagoides pteronissimus , Dermatophagoides forinae, Araneae, for example: Aviculariidae, Araneidae 〇-38 - 20 200812487 Opiliones ' For example: Isopoda (pseu(j〇scorpiones chelifer), Pseudoscorpiones cheiridium, Opiliones phalangium, Isopoda, for example: sea otter (〇11丨%1^状611118), rat Porcellio scacalc DDiplopoda ' For example: Blaniulus guttiilatus, Polydesmus spp.) 10 Chilopoda 'eg: local entertainment Geophilus spp.. Zygentoma, for example: ctenolepisma 10 spp., Lepisma saccharina, Lepismodes inquilinus B^ Blattaria ' For example: Blatt orientalis, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora 15 spp·, Paco绯蠊属(?公1^〇1>13 pillow & 8 mouth 0.), Australian 绯蠊 (?61^1&form 1& ^ australasiae), American 绯蠊 (? 61^1&1161&311^1^&1^), brown cockroach (Periplaneta brunnea), cockroach cockroach (periplaneta fuliginosa), scorpion scorpion (Supella longipalpa). Saltatoria, for example: Acheta 2〇domesticus, Dermaptera, for example: Forficula auricularia, Isoptera, for example: Kalaltermes Spp.), Reticulitermes spp. -39- 200812487 Psocoptera, for example: Lepinatus genus, Liposcelis spp. Coleptem, for example: Anthrenus spp., Attagenus spp· ), Dermestes spp., Latheticus oryzae, Necrobia spp., Ptinus spp., RMzopertha dominica, valley elephant Sitophilus granaries), Sitophilus oryzae, Sitophilus • zeamais, Stegobium paniceum, Diptera, eg Aedes aegypti, Aedes aegypti (Aedes albopictus), Aedes taeniorhynchus, Anopheles spp., red-headed rope (€311丨0|1〇6巧1:111*〇〇6口1^1&), Yuma it (Chrysozona Pluvialis), Culex quinquefasciatus, Culex pipiens, Culex pipiens

Sr* (Culex tarsalis), Drosophila spp., Fannia 15 canicularis, Musca domestica, Phlebotomus spp., Sarcophaga carnaria, Na Genus (Smallium spp.), Stomoxys calcitrans, and Tipula paludosa o Lepidoptera, for example: Achroia grisella, 20 Galleria mellonella , Plodia inteiputictella, Tinea cloacella, Nete moth (Tinea 卩611丨〇1^1, bagged moth (1^1^〇1&1^861 to 11&) Siphonaptera, for example: Ctenocephalides canis, Ctenocephalides felis, Pulex 200812487 irritans, Tunga penetrans, Xenopsylla cheopis Hymenoptera, such as Camponotus herculeanus, Lasius fuliginosus, Lasius 5 niger, Lasius umbratus, Monomorium pharaonis,

Paravespula genus, Tetramorhim caespitum o Anoplura, for example: Pediculus humanus • capitis, Pediculus humanus corporis, Pemphigus spp., Phylloera vastratrix, Yinz (Phthirus 10 pubis) Heteroptera, for example: Cimex hemiptems, temperate bed bugs ((^1116\16(:1;111&14118), 11]1〇(1]11118, Pr〇 Lixus, Triatoma infestans. The use of household insecticides can be used alone or in combination with other 15 suitable active compounds, such as phosphates, amine phthalates, and pyrethroids. a class, a new class, a growth regulator, or an active compound from other known insecticides. It can be aerosolized, non-pressure sprayed products, such as pumping and atomizing nozzles, automatic Spray system, atomizer, foam, gel, evaporator product using evaporation sheets made of 20 cellulose or polymer, liquid evaporator, gel and membrane evaporator, screw driven evaporation , no energy or being Evaporation system, insect-trapping paper, insect-trapping bag and insect-catching glue, in the form of granules or fine powder, used in the form of de-aerable bait or in a bait table, etc. Good insecticidal and active compound composition according to the invention Acaricidal-41 - 200812487 The activity can be seen by the following examples. Although the active compound exhibits a weaker activity, the activity of the combination exceeds the simple sum of its effects. When the activity of the active compound composition exceeds that of the active compound alone, The active compound has the killing & insecticide and killing 5

10 synergistic effect of tincture. The desired activity of the specified composition of the two active compounds may be based on sr.

Colby, Weeds U (1967), 20-22 Calculated as follows: If X is the active compound A, the concentration of the a field is relative to the unsuccessful rate, or -Y is the active compound B, ,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,

Hectares or HL and appm vocal 3/wood application rate SL and IL g / death rate %, compared to the untreated control group, E-X+Y-X-YToo-20 In addition, the effect of Nie or killing mortality is super-additive, that is, when there is a leaf appreciation, the mortality observed by the combination must exceed the above-mentioned two ===. At this point, it is true (E). "Formula calculates the expected mortality rate '42^ 25 200812487 [Embodiment]

Example A Phaedou cochleariae larva test solvent: 7 parts by weight of decyl decylamine 5 emulsifier: 2 parts by weight of alkaryl polyglycol ether to prepare a suitable preparation of the active compound, from 1 part by weight The activated compound is mixed with the above amount of solvent and emulsifier, and the concentrate is diluted with water containing an emulsifier to a desired concentration. Ίο The leaves of Brassica oleracea are immersed in the active compound preparation at the desired concentration, and then the larvae of Phaedon cochleariae are inoculated when the stalks are still wet. _ After a period of time, the % mortality is determined. 100% means that all larvae die; 0% means no larvae die. The measured mortality rate is substituted into the Kirby formula (see above). In this test, the following active compound compositions according to the present application exhibited synergistic enhancing activity compared to the active compounds administered alone. -43- 200812487

Table A Insects that harm plants Phaedon eochleariae larvae test

10 15

Active compound concentration ppm mortality after 4 days % _ 4 40 flubendiamide 0.8 0 According to the invention (Ib) + flubendiamide (5:1) 4+0.8 *found **calc. 60 40 (lb) 0.8 0 emamectin benzoate 0.032 65 According to the invention (Ib) + Enmei; T (emamectiii) benzoate (25: 1) 0.8 + 0.032 氺found *氺calc 85 65 * founds measured activity ** calc. 2 activity calculated using the Kirby formula -44 - 20 200812487

Example B Plutella xylostella test (sensitive species) Solvent: 7 parts by weight of decylguanamine Emulsifier: 2 parts by weight of alkylaryl polyglycol ether

10 When preparing a suitable preparation of the active compound, one part by weight of the active compound is mixed with the above amount of solvent and emulsifier, and the concentrate is diluted with the emulsifier-containing water to the desired concentration. The leaves of Brassica oleracea (Brassica oleracea) are immersed in the active compound preparation of the desired concentration, and then the larvae of small = fpiutdla xylostella are inoculated when the leaves are still wet. % of mortality was determined after the passage of time. 1% means that all larvae die; 0% means there are no larvae k. Substituting the measured mortality into the Kirby formula (see above). 15

In this test, according to the present application, the active compound composition exhibits synergistic enhancing activity compared to the active compound administered alone. -45- 200812487

Table B Plutella xylostella test for susceptible plants (sensitive species) 5 Active compound: concentrated ppm 6 (lb) 0.0064 0 #ememectin benzoate 〇.〇〇〇256 10 0 According to the invention (Ib) + emamectin benzoate (25: 1) The found **calc. 0.0064 + 0.000256 45 0 15 * founds measured activity ** calc production using the Kirby formula -47- 200812487 Table B Plutella xylostella test for susceptible plants (sensitive species) 5 Active compound concentration PDH1 4 days 遽^1^ rate% (lb) 0.032 --- ~ 85 0.0064 35 Clementine Fipronil 0.0064 45 10 According to the invention - (Ib) + flponnii (i: 1) 氺found氺本 - 0.0064+0.0064 85 64.25 15 spinosad 0.0064 0 • according to the invention ( Ib) + Spino (Spin () sad) (5 · · 1) *found **calc. 0.032+0.0064 100 85 20 * found = measured activity ** calc. = activity calculated using the Kirby formula -46- 200812487 Example c Plutella xylostella test (resistant variety) Solvent: 7 parts by weight of decyl decylamine Chemical: 2 parts by weight of aryl aryl glycol ether 5 When preparing a suitable preparation of the active compound, 1 part by weight of the active compound is mixed with the above amount of solvent and emulsifier, and the Φ concentrate is diluted with water containing an emulsifier. To the desired concentration. The leaves of Brassica oleracea were immersed in the desired concentration of 1 〇 compound preparation t, and then the larvae of Plutella xylostella were inoculated when the stalks were still wet. “ After a period of time, the % mortality is determined. 100% means that all larvae die; 0% means no larval death. The measured mortality is substituted into the Kirby formula (see above). 15 In this test, The following active compound compositions of the present application exhibit synergistic potentiating activity compared to the active compounds administered alone. -48- 200812487 Table c Insect Plutella xylostella test (resistance variety) > 'Tongue 1 匕 4 _ _ concentration ppm _ 4 days after the name r death sheep, (lb) 0.0064 〇 诺 杀 杀 (spinosad) 0.00128 〇 according to the invention (Ib) + spinosad (5: 1) * Foimd **calc· 0.0064+0.00128 30 0 15 * found=actual activity repair calc.=activity calculated using the Kirby formula-49- 200812487

Example D Spodoptera exigua test solvent: 7 parts by weight of decylguanamine emulsifier: 2 parts by weight of alkylaryl polyglycol ether 5 When preparing a suitable preparation of the active compound, by weight ratio The active compound is mixed with the above amount of solvent and emulsifier, and the concentrate is diluted to the desired concentration with water containing an emulsifier. The leaves of Brassica oleracea are immersed in the desired concentration of the compound, and then the larvae of Spodoptera exigua are inoculated when the leaves are still wet. • Determine the % mortality after a period of time. 1 〇〇% means all larvae die; 0% means no larvae die. Substituting the measured mortality into the Kirby formula (see above). In this test, the following active compound compositions according to the present application exhibited synergistic enhancing activity compared to the active compounds administered alone. -50- 200812487

Table D Insects of the injured plant Spodoptera exigua test active compound Hanta ppm mortality after 6 days (lb) 0.16 45 Indoxacarb 0.032 0 According to the invention (Ib) + Insepo ( Indoxacar!>)(5 :1) 0.16+0.032 *found **cala 90 45

10 15 * found=measured activity • **calc.=activity calculated using the Kirby formula -51 - .200812487

Example E Spodoptera frugiperda test solvent: 7 parts by weight of dimethyl decylamine emulsifier: 2 parts by weight of aryl aryl polyglycol ether to prepare suitable preparation of active compound, by weight ratio activity Chemical

10 15

The compound is mixed with the above amount of solvent and emulsifier, and the concentrate is diluted with water containing an emulsifier to a desired concentration. The leaves of Brassica oleracea (Brassica 〇leracea) were immersed in the active compound preparation at the desired concentration, and then the larvae of Spodoptera frugiperda were inoculated when the leaves were still wet. After the passage of time, the % mortality was determined. 1〇〇% means that all deaths & 0% means no larvae died. Substituting the measured mortality into the Kirby formula (see above). In this test, according to the present application ^ m ^ ^ ^ The following activating & composition of the composition of the active compound in the early (four), the activity of the synergistic effect ·· -52-* 200812487

Table E Insects of the Insects of the Plants (Spodoptera frugiperda) Test 20 Live Compounds ^ 匕ΤΤ 匕ΤΤ 7 7b to 1 LA 〇^\yj__-__________ (lb) 0.16 -45 fipronil (fipronil) 0.16 30 Invention (Ib) + Fenpro (f|pronil) (l: 1) *found **calc. 0.16+0.16 90 61.5 (lb) 0·16 80 Indoxaearb 0.032 0 According to the invention (Ib) +英赛普(inc!oxacarb)(5 :l) *found **calc· 0· 16+0.032 100 80 * found=actual activity** cala=activity calculated using the Kirby formula-53-

Claims (1)

Cao 200812487 X. Patent Application Range 1. A composition comprising (a) at least one active compound of formula (1) CH〇 5 10 15 Where Hal represents chlorine, bromine or broken, * represents a carbon atom in the R- or S-configuration, and (b) at least one of the following active compounds flubendiamid spinosad aramectin Emme, emamectin, methoxyfenozide, tebufenozide, chromafenozide, indoxacarb, fipronil, ethiprol FLonicamid -54 - 20 200812487 chlorfenapyr 3-bromo-N-{4-chloro-2-indolyl-6-[(decylamino)carbonyl]phenyl} · 1 - ( 3 - gas 0 to sigma-2-yl) _ 1 H-ntb11 sit -5-bristamine. 2. The composition according to claim 1, which comprises (a) at least one active compound of the formula (I) and (b) the active compound 3-bromo-1-(3-chloroindol-2-yl)- N-[4-Cyano-2-methyl-6-(nonylaminoindenyl)phenyl]-1H-indole-5-propanamide. 10 15 3. The composition according to claim 2, which further comprises an active compound selected from the group consisting of flubendiamid, spinosad, abamectin ), Enmei, emmectin benzoic acid S, methoxyfenozide, tebufenozide, chromafenozide, indoxacarb, fipronil, Ethiprol, flonicamid, chlorfenapyr and 3-bromo-N-{4-chloro-2-indolyl-6-[(decylamino)indolyl]benzene -1 -(3-Azain-2-yl 1 H-吼嗤-5-竣酉& 4. A composition as defined in any one of claims 1 to 3 of the patent application Use for controlling animal pests. 5. A method for controlling unwanted animal pests, characterized by applying a composition as defined in any one of claims 1 to 3 to an unwanted animal pest and/or Habitat and/or seed. 6. A method of preparing an insecticidal and acaricidal composition, characterized by being in accordance with claims 1 to 3 of the scope of the patent application The group defined by the item -55- 20 200812487 is mixed with a supplement and/or a surfactant. 7 - A composition according to any one of claims 1 to 3 is applied to the treated seed. Uses 8. A use of a composition according to any one of claims 1 to 3 of claim 1 for the treatment of a transgenic plant. 9. A method according to claims 1 to 3 Use of a composition as defined in any one of the compositions for treating a seed of a transgenic plant. ^ 10. A seed which is treated according to the composition as defined in any one of claims 1 to 3. -56- 200812487 VII. Designation of representative representatives: (1) The representative representative of the case is: (No). (2) A brief description of the symbol of the symbol of the representative figure: Benefits 10. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: