TW200800861A - Active compound combinations having insecticidal and acaricidal properties - Google Patents

Active compound combinations having insecticidal and acaricidal properties Download PDF

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Publication number
TW200800861A
TW200800861A TW96107420A TW96107420A TW200800861A TW 200800861 A TW200800861 A TW 200800861A TW 96107420 A TW96107420 A TW 96107420A TW 96107420 A TW96107420 A TW 96107420A TW 200800861 A TW200800861 A TW 200800861A
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spp
cypermethrin
active compound
genus
composition according
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TW96107420A
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Chinese (zh)
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Ruediger Fischer
Christian Funke
Heike Hungenberg
Wolfgang Thielert
Anton Kraus
Hiroshi Kodama
Shingo Tamura
Fumiaki Hakuno
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Bayer Cropscience Ag
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    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
    • A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
    • A01N41/10—Sulfones; Sulfoxides

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
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  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

The novel mixtures comprising at least one active compound of the formula (I) where Hal represents chlorine, bromine or iodine, and denotes a carbon atom in the R- or S-configuration, preferably in the S-configuration, and at least one of the active compounds 1 to 24 from the class of the pyrethroids listed in the description have very good insecticidal and acaricidal properties.

Description

200800861 九、發明說明： 【發明所屬之技術領域】 本發明係有關一種新穎之活性化合物組合，其首先包 含至少一種已知式(I)化合物，及其次包含至少另一種選自 5 擬除蟲菊酯類之已知活性化合物，該組合極適合控制動物 害蟲，如：昆蟲及不要之蟎類。 | 【先前技術】 已知式(I)化合物200800861 IX. INSTRUCTIONS OF THE INVENTION: FIELD OF THE INVENTION The present invention relates to a novel active compound combination which first comprises at least one compound of the formula (I), and secondarily comprises at least one other selected from the group 5 pyrethrum A known active compound of an ester which is highly suitable for controlling animal pests such as insects and unwanted mites. [Prior Art] Compounds of formula (I) are known

> μ …、> μ ...,

Hal 代表氯、溴或蛾，及 * 代表呈R-或S-組態之碳原子，較佳為S-組態， 具有殺昆蟲活性。此點適用於該化合物之消旋型（EP-A 1 2〇 006 107)，甚至適用於（S)-組態之對映異構物(已公開之曰本 專利申請案JP 2006-089469)。可明確述及化合物(la)、（lb) 與(Ic)。 (la): (S)-3-碘《^-{2-甲基·4-[ 1，2,2,2-四氟小(三氟甲基）乙 基]苯基}_N -(1 -甲基-2-曱基績酿基乙基)駄酿胺 200800861Hal represents chlorine, bromine or moth, and * represents a carbon atom in the R- or S-configuration, preferably in an S-configuration, with insecticidal activity. This applies to the racemic form of the compound (EP-A 1 2〇006 107) and even to the enantiomer of the (S)-configuration (disclosed in this patent application JP 2006-089469) . Compounds (la), (lb) and (Ic) can be clearly stated. (la): (S)-3-iodine "^-{2-methyl·4-[ 1,2,2,2-tetrafluoros(trifluoromethyl)ethyl]phenyl}_N -(1 -Methyl-2-indenyl base ethyl) anthraquinone 200800861

55

四氟一 Η三氟甲基）乙基] 苯基卜Ν2-(1·曱基I甲基磺醯基乙基)醜醯胺Tetrafluoro-trifluoromethyl)ethyl]phenylphenyl 2-(1·indolylmethylsulfonylethyl) ugly amine

h3c 10 (^) : (S^IN1·^-甲基冰[1，2,2,2-四氟小(三氟甲基）乙基] 苯基}-Ν2-(1-甲基-2-甲基磺醯基乙基)酞醯胺H3c 10 (^) : (S^IN1·^-methyl ice [1,2,2,2-tetrafluoro-(trifluoromethyl)ethyl]phenyl}-Ν2-(1-methyl-2 -methylsulfonylethyl) decylamine

此外’已知某些來自擬除蟲菊酯類之活性化合物具有 殺昆蟲與殺蟎作用。 【發明内容】 現已發現一種混合物，其包含至少一種式(I)化合物 20 200800861 與至少一種選自下列各物所組成群中之化合物： 1.自 EP-A-048 186 中已知之阿納寧（acrinathrin)Furthermore, it is known that certain active compounds derived from pyrethroids have insecticidal and acaricidal effects. SUMMARY OF THE INVENTION A mixture has now been found which comprises at least one compound of the formula (I) 20 200800861 and at least one compound selected from the group consisting of: 1. Ananine known from EP-A-048 186 (acrinathrin)

及/或And/or

10 2.自 EP-A-067 461 中已知之亞滅寧（alpha-cypermethrin)10 2. Alpha-cypermethrin known from EP-A-067 461

15 及/或 k 3•自 EP-A-206149 中已知之 β-賽扶寧(beta_cyfluthrin)15 and / or k 3 • β-cyfluthrin known from EP-A-206149

4. 自 DE-A-2 802 962 中已知之 7 賽赫寧(gamma-cyhalothriii) 200800861 54. Known from DE-A-2 802 962 7 gamma-cyhalothriii 200800861 5

10 1510 15

5.自 DE-A-2 326 077 中已知之賽滅寧（cypermethrin) ci5. Cypermethrin ci known from DE-A-2 326 077

6.自 DE-A-2 326 077 中已知之第滅寧（deltamethrin)6. Detamethrin known from DE-A-2 326 077

7.自 DE-A-2 737 297 中已知之益化利（esfenvalerate)7. Esfenvalerate known from DE-A-2 737 297

8· 自 DE-A-3 117 510 中已知之依芬寧（ethofenprox) 20 2008008618· etfinenprox 20 known from DE-A-3 117 510 2008 20080861

5 9.自 DE-A-2 231 312 中已知之芬普寧（fenpropathrin)5 9. Fenpropathin known from DE-A-2 231 312

1010

10.自 DE-A-2 335 347 中已知之芬化利（fbnvalerate) 1510. Fbnvalerate 15 known from DE-A-2 335 347

11.自 DE-A-2 757 066 中已知之護賽寧（flucythrinate)11. Flucythrinate known from DE-A-2 757 066

12.自 EP-A-106 469 中已知之又-賽赫寧(lambda-cyhalothrin) 20 20080086112. Known from EP-A-106 469 - lambda-cyhalothrin 20 200800861

13.自 DE-A-2 326 077 中已知之百滅寧(permethrin)13. Permethrin known from DE-A-2 326 077

CICI

1010

OV 14.自 EP-A-038 617 中已知之特福化利（taufluvalinate) 15OV 14. Taufluvalinate known from EP-A-038 617 15

15.自 DE-A-2 742 546 中已知之泰滅寧(tralomethrin)15. Tralomethrin known from DE-A-2 742 546

HXHX

〇 CN EP-A-026 542 中已知之（_賽滅寧(zeta-cypermethrin) -11 - 16. 20已知 CN EP-A-026 542 (Zeta-cypermethrin -11 - 16. 20

200800861 V 5 17. 10 18.200800861 V 5 17. 10 18.

DE-A-27 09 264 中已知之賽扶寧（cyfhitlirin)Cyfhitlirin known in DE-A-27 09 264

EP-A-049 977 中已知之畢芬寧(bifenthrin) 15 19.Bifenthrin 15 is known from EP-A-049 977.

自DE-A-2653189中已知之乙氰菊酯（cycloprothrin)Phloprofen (cycloprothrin) known from DE-A-2653189

-12· 20 200800861 Λ、 20·自 DE-A-36 04 781 中已知之抑伏辛（eflusilanate)-12· 20 200800861 Λ, 20· effusilanate known from DE-A-36 04 781

21 ·自 DE-A-37 08 231 中已知之伏本斯（fubfenprox)21 · Fubfenprox known from DE-A-37 08 231

22.自“農藥手冊(The Pesticide Manual)” 1997,第 11 版， ρ· 1 056中已知之除蟲菊酯❻}^^!^!!) 1522. From the Pesticide Manual 1997, 11th edition, pyrethrins known in ρ·1 056}^^!^!!) 15

CH0 Η 〇 R = -CH3 或·€02€Η3 R! = -CH=CH2 或-CH3 或-ch2ch3 23.自 GB-A-1 168 797 中已知之利滅寧(resmethrin) -13- 20 200800861CH0 Η 〇 R = -CH3 or · €02€Η3 R! = -CH=CH2 or -CH3 or -ch2ch3 23. Resmethrin -13- 20 200800861 known from GB-A-1 168 797

10 1510 15

2020

與24·自 EP-A131 199 中已知之汰福寧（tefJuthrin)And TefJuthrin (24) known from EP-A131 199

具有增效活性且適合控制動物害蟲。根據本發明活性化合 物組合之殺昆蟲與殺瞒活性驚人地大幅優於個別活性化合 物之活性總合。其展現無法預期之真正增效效力，且不僅 加成活性而已。 除了至少一種呈對映異構性純型或呈兩種對映異構物 依任何比例形成之混合物之式⑴活性化合物外，根據本發 明活性化合物組合尚包含至少一種如上述擬除蟲菊酯^至 24 〇 較佳者，根據本發明活性化合物組合包含一種活性化 a物(la)、(lb)或(Ic)與一種如上述擬除蟲菊酯卜234、 5、6、12、16、17、18 或 24。 特別佳為表1所示之混合物。 -14- 混合物包含 la 與 1 (阿納寧（acrinathrin)) la 與 2(亞滅寧（alpha-cypermethrin)) la 與 3(β-賽扶寧（beta-cyfluthrin)) la 與 4(γ·賽赫寧(gamma_cyhalotlirin)) la 與 5(賽滅寧(cypermethrin)) la 與 6(第滅寧(deltamethrin)) la 與 12(λ-賽赫寧（lambda-cyhalothrin)) la 與 16(ζ-賽滅寧(zeta-cypermethrin)) la 與 17(賽扶寧（cyfluthrin)) la 與 18(畢芬寧(bifenthrin)) la 與 24(汰福寧（tefluthrin)) lb 與 1 (阿納寧（acrinathrin)) lb 與 2(亞滅寧(alpha-cypermethrin)) lb 與 3(β-賽扶寧（beta-cyfluthrin)) lb 與 4(γ-賽赫寧(gamma-cyhalothrin)) lb 與 5 (賽滅寧(cypermethrin)) lb 與 6(第滅寧(deltamethrin)) lb 與 12(λ·賽赫寧(lambda-cyhalothrin)) lb 與 16(ζ-賽滅寧(zeta-cypermethrin)) lb 與 17 (賽扶寧（cyfluthrin)) lb 與 18(畢芬寧(bifenthrin)) lb 與 24(汰福寧（tefluthrin)) 200800861It has synergistic activity and is suitable for controlling animal pests. The insecticidal and acaricidal activity of the combination of active compounds according to the present invention is surprisingly significantly superior to the activity of individual active compounds. It exhibits unpredictable true synergistic effects and is not only additive activity. In addition to at least one active compound of the formula (1) which is enantiomerically pure or in a mixture of the two enantiomers in any proportion, the active compound combination according to the invention still comprises at least one pyrethroid as described above Preferably, the active compound combination according to the invention comprises an activator a (la), (lb) or (Ic) and a pyrethroid as described above 234, 5, 6, 12, 16 , 17, 18 or 24. Particularly preferred are the mixtures shown in Table 1. -14- The mixture contains la and 1 (acrinathrin) la and 2 (alpha-cypermethrin) la and 3 (beta-cyfluthrin) la and 4 (γ·赛宁 (gamma_cyhalotlirin) la and 5 (cypermethrin) la and 6 (deltamethrin) la and 12 (lambda-cyhalothrin) la and 16 (ζ-赛Zeta-cypermethrin) la and 17 (cyfluthrin) la and 18 (bifenthrin) la and 24 (tefluthrin) lb and 1 (acrinathrin) lb And 2 (alpha-cypermethrin) lb and 3 (beta-cyfluthrin) lb and 4 (gamma-cyhalothrin) lb and 5 (said ning ( Cypermethrin)) lb and 6 (deltamethrin) lb and 12 (lambda-cyhalothrin) lb and 16 (zeta-cypermethrin) lb and 17 (said Ning (cyfluthrin) lb and 18 (bifenthrin) lb and 24 (tefluthrin) 200800861

Ic 與 1 (阿納寧（acrinathdn)) Ic 與 2(亞滅寧(alpha-cypermethrin)) Ic 與 3(β·賽扶寧（beta-cyfluthrin)) Ic 與 4(γ-赛赫寧(gamma-cyhalothrin)) Ic 與 5 (賽滅寧(cypermethrin)) Ic 與 6(第滅寧(deltamethrin)) Ic 與 12(λ-赛赫寧(lambda-cyhalothrin)) Ic 與 16(ζ-賽滅寧(zeta-cypermethrin)) Ic 與 17(賽扶寧(cyfluthrin)) Ic 與 18(畢芬寧(biftnthrin)) Ic 與 24(汰福寧（tefluthrin)) 極特別佳混合物示於表2。 表2 混合物包含 lb 與 1 (阿納寧（acrinathrin)) lb 與 2(亞滅寧（alpha-cypermethrin)) lb 與 3 (β-赛扶寧(beta-cy fluthdn)) lb 與 4(γ-赛赫寧(gamma-cyhalothrin)) lb 與 5(賽滅寧(cypermethrin)) lb 與 6(第滅寧(deltamethrin)) lb 與 12(λ-賽赫寧(lambda-cyhalothrin)) lb 與 16(ζ-賽滅寧(zeta-cypermethrin)) -16- 200800861 lb 與 17(賽扶寧(cy fluthrin)) lb 與 18(畢芬寧(bifenthrin)) lb 與 —--------_______ 24(汰福寧（tefluthrin)) 極特別適合處理種子之混合物包含(lb)與24(汰福寧 (tefluthdn))或 3(β_赛扶寧(beta_cyfluthrin))。 若根據本發明活性化合物以某重量比例組合時，其增 效性效力特別顯著。然而，活性化合物組合中活性化合物 重里比可在相當大範圍内變化。通常，根據本發明組合包 含一種式(I)活性化合物與一種擬除蟲菊酯1至24，其混合 比例為下列所示之較佳及特別佳比例： 較佳混合比例 125 : 1至1 : 125 特別佳混合比例 25 : 1至1 : 25 混合比例係以重量比例計。咸了解，該比例係指式（I) 活性化合物：擬除蟲菊酯。 本發明活性化合物組合具有良好之植物耐受性、對忸 溫動物具有有利之毒性及良好之環境相容性，適合保護植 物與植物器官，提高收成產量，改善收成材料之品質及控 制動物害蟲’尤指出現在農業、園#、動物飼養、森林、 化園與休閒設施、保護庫存產品與原料，及在衛生等方面 之動物害蟲，尤指昆蟲、科類、蹲蟲、線蟲與軟體動物。 其較適用為植物保護劑。其可活性對抗—紐感性與抗性 品種，及對抗所有或某些發展階段。上述害蟲包括： 兹目（Phthimptera)，例如：DamaHnia屬、豬蝨屬 200800861 (Haematopinus spp·)、犬蝨屬（Linognathus spp·)、人蝨屬 (Pediculus spp.)、獸鳥兹屬（Trichodectes spp·)。 虫知蛛綱（Arachnida) ’ 例如：粗腳粉蜗(Acarus siro)、Aceria sheldoni、刺皮癭蜗屬（Aculops spp·)、刺癭蟎屬（Aculus 5 SPP·)、花蜱屬(Amblyomma spp·)、銳緣蜱屬(Argas spp.)、 牛蜱屬（Boophilus spp·)、紅鬚蜗屬（Brevipalpus spp·)、苜蓿 苔蜗(Bryobia praetiosa)、恙蜗屬（Chorioptes spp.)、雞皮刺 I 蟎（Dermanyssus gallinae)、Eotetranychus 屬、梨上癭蟎 (Epitrimerus pyri)、真葉蹣屬（Eutetranychus spp.)、癭蟎屬 ίο (Eriophyes spp·)、半跗線蟎屬（Hemitarsonemus spp·)、璃眼 蜱屬（Hyalomma spp·)、硬蜱屬（Ixodes spp·)、黑寡婦球腹蛛 (Latrodectus mactans)、後紅葉蜗屬（Metatetranychus spp·)、 小爪蜗屬（Oligonychus spp·)、鈍緣蜱屬（Ornithodoros spp·)、 紅虫知蛛屬（Panonychus spp·)、橘銹蜗（Phyllocoptruta 15 oleivora)、雜食線瞒屬（Polyphagotarsonemus latus)、癢蜗屬 , (Psoroptes spp.)、扇頭蜱屬（Rhipicephalus spp.)、根蜗屬 (Rhizoglyphus spp·)、人济蜗屬（Sarcoptes spp·)、蛾(Scorpio maurus)、狹附線瞒屬（Stenotarsonemus spp.)、細蜗屬 (Tarsonemus spp·)、紅葉蜗屬（Tetranychus spp·)、Vasates 2〇 lycopersici o 雙殼綱(Bivalva)，例如··飾貝屬（Dreissena spp·)。 唇足目（Chilopoda)，例如：地娱忪屬（Geophilus spp·)與蚰蜓 屬（Scutigera spp·) 〇 鞘翅目（Coleoptera)，例如：大豆象（Acanthoscelides -18 - 200800861 obtectus)、麗金龜屬（八(1〇代扣53师.）、赤揚紫跳曱（八名61&3价这 alni)、叩頭蟲屬（Agriotes spp·)、六月金龜子(Amphimallon solstitialis)、食骸蟲（Anobium punctatum)、天牛屬 (Anoplophora spp·)、棉鈴象鼻蟲(Anthonomus spp·)、蠢屬 5 (Anthrenus spp·)、Apogonia 屬、隱食曱屬（Atomaria spp·)、 小鰹節蟲屬（Attagenus spp·)、豆象(Bruchidius obtectus)、豆 象曱屬（Bruchus spp·)、象鼻蟲屬（Ceuthorrhynchus spp·)、牛 I 蒡象甲（Cleonus mendicus)、金針蟲屬（Conoderus spp·)、球 莖象鼻蟲屬（Cosmopolites spp·)、Costelytra zealandica、象 i〇 曱屬（Curculio spp·)、柳小隱喙象甲（Cryptorhynchus lapathi)、皮蠹屬（Dermestes spp·)、葉曱屬（Diabrotica spp.)、 瓢蟲屬(Epilachna spp·)、Faustinus cubae、麥蛛曱（Gibbium psylloides)、白蜻螬（Heteronychus arator)、Hylamorpha elegans、象天牛(Hylotrupes bajulus)、苜蓿象鼻蟲(Hypera 15 postica)、小蠹屬（Hypothenemus spp.)、 總角金龜 I (Lachnosterna consanguinea)、馬鈴薯曱蟲（Leptinotarsa decemlineata)、稻象曱（Lissorhoptrus oryzophilus)、黃象曱 屬（Lixus spp·)、粉蠹屬（Lyctus spp·)、花粉曱（Meligethes 36如115)、吹粉金龜（]^^1〇1〇111：1^!1^1〇1〇111；1^)、]^£(1〇1113屬、 20 天牛屬（Monochamus spp.)、Naupactus xanthographus、 金黃 蛛曱（Niptus hololeucus)、Oryctes rhinoceros、鑛胸粉扁蟲 (Oryzaephilus surinamensis)、深溝象曱（Otiorrhynchus sulcatus)、銀點花金龜（Oxycetonia jucunda)、猿葉蟲（Phaedon cochleariae)、食葉蟲屬（Phyllophaga spp·)、曰本麗金龜 -19 - 200800861 (Popillia japonica)、Premnotrypes 屬、油菜蘭跳甲（Psylliodes chrysocephala)、蛛甲屬（Ptinus spp·)、黑根瓢蟲(Rhizobius ventralis)、粉長蠹蟲（Rhizopertha dominica)、米象屬 (Sitophilus spp·)、谷象屬（Sphenophoms spp·)、莖象屬 5 (Sternechus spp·)、爲肩象屬（Symphyletes spp.)、粉甲 (Tenebrio molitor)、擬穀盜屬（Tribolium spp.)、鰹節蟲屬 (Trogoderma spp·)、象曱屬（Tychius spp·)、虎天牛屬 I (Xylotrechus spp·)、步曱屬（Zabrus spp·) 〇 彈尾目（Collembola)，例如：棘跳蟲（Onychiurus armatus)。 i〇 革翅目（Dermapterans)，例如：歐洲球螋（Forficula auriculana) ° 重足目（Diplopoda)，例如：Blaniulus guttulatus 〇 雙翅目（Diptera)，例如：伊蚊屬（Aedes spp.)、按蚊屬 (Anopheles spp·)、毛蚊(Bibio hortulanus)、麗繩（Calliphora 15 erythrocephala)、地中海果實繩(〇6了31;出8〇&0池1&)、金繩屬 I (Chrysomyia spp·)、刺蚊屬（Cochliomyia spp·)、糞蠅 (Cordylobia anthropophaga)、庫蚊屬（Culex spp·)、疽绳屬 (Cuterebra spp.)、果繩（Dacus oleae)、人膚繩（Dermatobia hominis)、猩獲蠅(Drosophila spp·)、廄蠅屬（Fannia spp·)、 20 胃繩屬（Gastrophilus spp·)、種绳屬（Hylemyia spp·)、Ic and 1 (acrinathdn) Ic and 2 (alpha-cypermethrin) Ic and 3 (beta-cyfluthrin) Ic and 4 (gamma-cynin) Cyhalothrin)) Ic and 5 (cypermethrin) Ic and 6 (deltamethrin) Ic and 12 (lambda-cyhalothrin) Ic and 16 (ζ-赛宁宁( Zeta-cypermethrin)) Ic and 17 (cyfluthrin) Ic and 18 (biftnthrin) Ic and 24 (tefluthrin) very excellent mixtures are shown in Table 2. Table 2 Mixtures containing lb and 1 (acrinathrin) lb and 2 (alpha-cypermethrin) lb and 3 (beta-cy fluthdn) lb and 4 (gamma-race Gamma-cyhalothrin) lb and 5 (cypermethrin) lb and 6 (deltamethrin) lb and 12 (lambda-cyhalothrin) lb and 16 (ζ -zeta-cypermethrin) -16- 200800861 lb and 17 (cy fluthrin) lb and 18 (bifenthrin) lb and ---------_______ 24 Tefluthrin is a very suitable mixture for the treatment of seeds containing (lb) and 24 (tefluthdn) or 3 (beta_cyfluthrin). If the active compounds according to the invention are combined in a certain proportion by weight, their potency is particularly pronounced. However, the active compound weight ratio in the active compound combination can vary over a considerable range. In general, the combination according to the invention comprises a compound of the formula (I) and a pyrethroid of from 1 to 24 in a preferred ratio and a particularly preferred ratio shown below: a preferred mixing ratio of 125:1 to 1: 125 Specially good mixing ratio 25 : 1 to 1: 25 The mixing ratio is based on the weight ratio. It is understood that this ratio refers to the active compound of formula (I): pyrethroid. The active compound combination of the invention has good plant tolerance, has favorable toxicity to temperate animals and good environmental compatibility, is suitable for protecting plants and plant organs, improves harvest yield, improves the quality of harvested materials and controls animal pests' In particular, it now points to agriculture, gardens, animal husbandry, forests, chemical gardens and leisure facilities, protection of stock products and raw materials, and animal pests in terms of hygiene, especially insects, families, mites, nematodes and mollusks. It is more suitable as a plant protection agent. It is active against the sensational and resistant varieties and against all or some stages of development. The above pests include: Phthimptera, for example: DamaHnia genus, Polyporus 200800861 (Haematopinus spp.), Canine genus (Linognathus spp.), Pelican spp., Trichodectes spp ·). Arachnida ' For example: Acarus siro, Aceria sheldoni, Aculops spp., Aculus 5 SPP·, Amblyomma spp ·), Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., chicken skin Dermanyssus gallinae, Eotetranychus genus, Epipirerus pyri, Eutetranychus spp., Eriophyes spp., Hemitarsonemus spp. , Hyalomama spp., Ixodes spp., Latrodectus mactans, Metatetranychus spp., Oligonychus spp. Ornithodoros spp., Panonychus spp., Phyllocoptruta 15 oleivora, Polyphagotarsonemus latus, Psoroptes spp., fan Rhipicephalus spp., Rhizoglyphus spp· ), Sarcoptes spp., Scorpio maurus, Stenotarsonemus spp., Tarsonemus spp., Tetranychus spp., Vasates 2〇 Lycopersici o Bivalva, for example, Dreissena spp. From the order of the genus Chilopoda, for example, Geophilus spp. and Scutigera spp., Coleoptera, for example: soy elephant (Acanthoscelides -18 - 200800861 obtectus), Lijin tortoise (eight (1 〇 buckle 53 division.), red Yang purple flea (eight 61 & 3 price this alni), Agios spp (Agriotes spp), June chafer (Amphimallon solstitialis), food mites (Anobium Punctatum), Anoplophora spp., Anthonomus spp., Anthrenus spp., Apogonia, Atomaria spp., Attagenus Spp·), bean (Bruchidius obtectus), genus Bruchus spp., genus Ceuthorrhynchus spp., Cleonus mendicus, Conoderus spp. Cosmopolites spp., Costelytra zealandica, Curculio spp., Cryptorhynchus lapathi, Dermestes spp., Diabrotica spp. ), Ladybug (Epilachna spp.), Faustinu s cubae, Gibbium psylloides, Heteronychus arator, Hylamorpha elegans, Hylotrupes bajulus, Hypera 15 postica, Hypothenemus spp., total Lachnosterna consanguinea, Leptinotarsa decemlineata, Lissorhoptrus oryzophilus, Lixus spp., Lyctus spp., Pollen Me (Meligethes 36, 115), Blowing the golden tortoise (]^^1〇1〇111:1^!1^1〇1〇111;1^),]^£(1〇1113 genus, 20 genus Monochamus spp., Naupactus xanthographus, Golden Spider (Niptus hololeucus), Oryctes rhinoceros, Oryzaephilus surinamensis, Otiorrhynchus sulcatus, Oxycetonia jucunda, Phaedon cochleariae, Leafhopper (Phyllophaga spp·), 曰本丽金龟-19 - 200800861 (Popillia japonica), Premnotrypes genus, Psylliodes chrysocephala, Ptinus spp., Rhizobius ventra Lis), Rhizopertha dominica, Sitophilus spp., Sphenophoms spp., Sternechus spp., Symphyletes spp., powder Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus Spp·) Collembola, for example: Onychiurus armatus. i. Dermapterans, for example: Forficula auriculana ° Diplopoda, for example: Blaniulus guttulatus DDiptera, eg Aedes spp. Anopheles spp·, Bibio hortulanus, Calliphora 15 erythrocephala, Mediterranean fruit rope (〇6 31; 8〇&0 pool 1&), Golden rope I (Chrysomyia spp) ·), Cochliomyia spp., Cordylobia anthropophaga, Culex spp., Cuterebra spp., Dacus oleae, Dermatobia hominis ), Drosophila spp., Fannia spp., 20 Gastrophilus spp., Hylemyia spp.

Hyppobosca 屬、皮蠅屬（Hypoderma spp·)、潛繩屬（Lidomyza spp·)、綠蠅屬（Lucilia spp·)、家繩屬（Musca spp.)、綠蝽屬 (Nezara spp·)、狂蠅屬（Oestrus spp·)、瑞典蠅（Oscindla frit)、 菠菜潛葉蛾(Pegomyia hyoscyami)、蚤繩屬（Phorbia spp·)、 -20- 200800861 螫蠅屬（Stomoxys spp·)、it 屬（Tabanus spp.)、Tannia 屬、大 蚊(Tipula paludosa)、肉蠅屬（Wohlfahrtia spp·)。 腹足綱（Gastropoda)，例如:虫舌蝓屬（Arion spp.)、Biomphalaria 屬、泡螺屬（Bulinus spp·)、灰姑蝓屬（Deroceras spp·)、土蜗 螺屬（Galba spp·)、椎實螺屬（Lymnaea spp.)、釘螺屬 (Oncomelania spp·)、琥拍螺屬（Succinea spp·)。 10 15Hyppobosca genus, Hypoderma spp., Lidomyza spp., Lucilia spp., Musca spp., Nezara spp., flies Oestrus spp., Oscindla frit, Pegomyia hyoscyami, Phorbia spp., -20- 200800861 Stomoxys spp., it genus (Tabanus spp) .), Tannia genus, Tipula paludosa, Wohlfahrtia spp. Gastropoda, for example: Arion spp., Biomphalaria, Bulinus spp., Deroceras spp., Galba spp. , Lymnaea spp., Oncomelania spp., Succinea spp. 10 15

螺蟲類，例如：十二指腸鉤蟲(Ancylostomaduodenale)、鉤 蟲（Ancylostoma ceylanicum)、|苗鉤蟲（AcylostOma braziliensis)、鉤蟲屬（Ancylostoma spp·)、人虫回蟲（Ascaris lubricoides)、虫回蟲屬（Ascaris spp·)、布魯線蟲（Brugia malayi、Brugia timori)、仰口 線蟲屬（Bunostomum spp·)、 Chabertia 屬、支澤吸蟲屬（Clonorchis spp·)、Cooperia 屬、 雙腔吸蟲屬（Dicrocoelium spp·)、網尾線蟲（Dictyocaulus filariar)、闊節二葉槽蟲(〇1卩11)41〇1)〇1;1111111111&1；11111)、地中海龍 線蟲（Dracunculus medinensis)、棘球縧蟲（Echinococcus granulosus)、球縧蟲（Echinococcus multilocularis)、蟯蟲 (Enterobius vermicularis)、Faciola 屬、血矛線蟲屬 (Haemonchus spp·)、異刺線蟲屬（Heterakis spp·)、微小膜殼 縧蟲(Hymenolepis nana)、下圓線蟲屬（11)^〇31；1'〇叩111113 301}·)、 羅阿血絲蟲(Loa Loa)、細頸線蟲屬（Nematodirus spp.)、結 線蟲屬（Oesophagostomum spp·)、後睪吸蟲屬（Opisthorchis spp·)、盤尾線蟲(Onchocerca volvulus)、Ostertagia 屬、并殖 吸蟲屬（Paragonimus spp·)、裂吸蟲屬（Schistosomen spp·)、 糞類圓線蟲（Strongyloides fuelleborni、Strongyloides -21 - 20 200800861 5Spirozoans, for example: Ancylostomaduodenale, Ancylostoma ceylanicum, AcylostOma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp ·), Brugia malayi, Brugia timori, Bunostomum spp., Chabertia, Clonorchis spp., Cooperia, Dicrocoelium spp· ), Dictyocaulus filariar, Phyllostachys pubescens (〇1卩11) 41〇1)〇1;1111111111&1;11111), Dracunculus medinensis, Echinococcus granulosus , Echinococcus multilocularis, Enterobius vermicularis, Faciola genus, Haemonchus spp., Heterakis spp., Hymenolepis nana, Lower nematode Genus (11)^〇31;1'〇叩111113 301}·), Loa Loa, Nematodirus spp., Neissophagostomum s Pp·), genus Opisthorchis spp., Onchocerca volvulus, Ostertagia, Paragonimus spp., Schistosomen spp., fecal round Nematodes (Strongyloides fuelleborni, Strongyloides -21 - 20 200800861 5

10 1510 15

stercoralis)、糞類圓線蟲屬（Strongyloides spp·)、帶縧蟲 (Taenia saginata、Taenia solium)、旋毛線蟲（Trichinella spiralis、Trichinella nativa、Trichinella britovi、Trichinella nelsoni、Trichinella pseudopsiralis)、毛圓線嘉屬 (Trichostrongulus spp.)、鞭蟲（Trichuris trichuria)、吳策線蟲 (Wuchereria bancrofti) 〇 亦可控制其他原蟲，如：艾美球蟲(Eimeria)。 異翅目（Heteroptera)，例如：南瓜緣蝽(Anasa tristis)、芒果 蝽屬（Antestiopsis spp·)、麥長蜂屬（Blissus spp·)、盲蝽屬 (Calocoris spp·)、盲墙（Campylomma livida)、二尾财屬 (Cavelerius spp·)、蟲屬（Cimex spp·)、盲蝽（Creontiades dilutus)、胡椒緣蝽(Dasynus piperis)、二葉嗓培(Dichelops furcatus)、Diconocoris hewetti、蝽象屬（Dysdercus spp·)、臭 蝽屬（Euschistus spp·)、刺蝽屬（Eurygaster spp·)、夜蛾屬 (Heliopeltis spp·)、Horcias nobilellus、豬緣蝽屬（Leptocorisa spp·)、葉足緣蝽（Leptoglossus phyllopus)、盲蝽屬（Lygus spp·)、嚴黑長培(Macropes excavatus)、盲蝽(1^11(!&6)、綠蝽 屬（Nezara spp·)、盾蝽屬（Oebalus spp·)、Pentomidae、擬配 軍蟲（Piesma quadrata)、壁蝽屬（Piezodorus spp·)、紅盲蝽 (Psallus seriatus)、Pseudacysta persea、紅腹獵蝽屬（Rhodnius spp·)、可可褐盲蝽（Sahlbergella singularis)、稻黑蝽屬 (Scotinophora spp·)、梨花網蝽（Stephanitis nashi)、Tibraca 屬、椎蝽屬（Triatoma spp·)。 同翅目（Homoptera)，例如：無網長管财屬（Acyrthosipon -22- 20 200800861 10 15Stercoralis), Strongyloides spp., Taenia saginata, Taenia solium, Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus Spp.), Trichuris trichuria, Wuchereria bancrofti can also control other protozoa, such as Eimeria. Heteroptera, for example: Anasa tristis, Antestiopsis spp., Blissus spp., Calocoris spp., blind wall (Campylomma livida) ), Cavelerius spp., Cimex spp., Creontiades dilutus, Dasynus piperis, Dielops furcatus, Diconocoris hewetti, genus Dysdercus spp·), Euschistus spp., Eurygaster spp., Heliopeltis spp., Horcias nobilellus, Leptocorisa spp., leaf foot margin Leptoglossus phyllopus), Lygus spp., Macropes excavatus, blind scorpion (1^11 (!&6), genus Nezara spp., Oebalus spp ·), Pentomidae, Piesma quadrata, Piezodorus spp., Psallus seriatus, Pseudacysta persea, Rhodnius spp., Cocoa brown cockroach ( Sahlbergella singularis), Scotinophora spp·, pear flower Bug (Stephanitis nashi), Tibraca genus, genus vertebral bug (Triatoma spp ·) Homoptera (Homoptera), for example: no net long tube Choi genus (Acyrthosipon -22- 20 200800861 10 15

spp·)、Aeneolamia 屬、Agonoscena 屬、粉風屬（Aleurodes spp·)、甘嚴粉虱（Aleurolobus barodensis)、粉氮屬 (Aleurothrixus spp.)、Amrasca 屬、圓尾財（Anuraphis cardui)、圓虫介屬（Aonidiella spp·)、蘇聯黃粉财（Aphanostigma piri)、财蟲屬（Aphis spp·)、Arboridia apicalis、Aspidiella 屬、 圓虫介屬（Aspidiotus spp·)、Atanus屬、蘇溝無網财 (Aulacorthum solani)、粉虱屬（Bemisia spp·)、桃短尾财 (Brachycaudus helichrysii)、微管财屬（Brachycolus spp·)、甘 藍财（Brevicoryne brassicae)、葉曱（Calligypona marginata)、 Carneocephala fulgida、甘蔬棉財（Ceratovacuna lanigera)、 沫蟬科(Cercopidae)、躐价屬（Ceroplastes spp·)、草莓毛管虫牙 (Chaetosiphon fragaefolii)、蔗黃雪盾虫介（Chionaspis tegalensis)、葉蟬（Chloritaonukii)、核桃黑斑财（Chromaphis juglandicola)、茶褐圓虫介（Chrysomphalus ficus)、葉蟬 (Cicadulina mbila)、Coccomytilus halli、軟虫介屬（Coccus SPP·)、茶蔗隱瘤額財(Cryptomyzus ribis)、Dalbulus 屬、粉 風屬（Dialeurodes spp·)、Diaphorina 屬、盾虫介屬（Diaspis spp.)、Doralis 屬、棉紛屬（Drosicha spp·)、圓尾蚜屬（Dysaphis spp·)、粉虫介屬（Dysmicoccus spp·)、微葉蟬屬（£!^〇公3〇3 spp·)、棉蚜屬（Eriosoma spp·)、斑葉蟬屬（Erythroneura spp·)、二葉缚（Euscelis bilobatus)、叻口 啡根虫介（Geococcus coffeae)、Homalodisca coagulata、桃吹粉財（Hyalopterus arundinis)、綿紛屬（Icerya spp·)、葉蟬屬（Idiocerus spp·)、葉 蟬屬（Idioscopus spp·)、稻灰飛虱(Laodelphax striatellus)、躐 -23- 20 200800861 5Spp·), Aeneolamia genus, Agonoscena genus, Aleurodes spp., Aleurolobus barodensis, Aleurothrixus spp., Amrasca genus, Anuraphis cardui, worm Genus (Aonidiella spp.), Aphanostigma piri, Aphis spp., Arboridia apicalis, Aspidiella, Aspidiotus spp., Atanus, and a ditch (Aulacorthum solani) ), Bemisia spp., Brachycaudus helichrysii, Brachycolus spp., Brevicoryne brassicae, Calligypona marginata, Carneocephala fulgida, sweet and vegetable cotton Ceratovacuna lanigera, Cercopidae, Ceroplastes spp., Chaetosiphon fragaefolii, Chionaspis tegalensis, Chloritaonukii, Walnut black spot Chromaphis juglandicola), Chrysomphalus ficus, Cicadulina mbila, Coccomytilus halli, Coccus SPP·), Cryptomyzus ribis, Dalbulus, Dialeurodes spp., Diaphorina, Diaspis spp., Doralis, Drosicha spp· ), Dysaphis spp., Dysmicoccus spp., Drosophila (£!^〇3〇3 spp·), Aristolochia (Eriosoma spp.), variegata Genus (Erythroneura spp.), Euscelis bilobatus, Geococcus coffeae, Homalodisca coagulata, Hyalopterus arundinis, Icerya spp., Aphis Idiocerus spp·), Idyuscopus spp., Laodelphax striatellus, 躐-23-20 200800861 5

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虫介屬（Lecanium spp·)、螺紛屬（Lepidosaphes spp·)、菜溢管对 (Lipaphis erysimi)、長鬚虫牙屬（Macrosiphum spp·)、Mahanarva fimbriolata、暗圓紛(Melanaphis sacchari)、Metcalfiella 屬、 薔薇麥财（Metopolophium dirhodum)、黑緣平翅斑虫牙 (Monellia costalis)、Monelliopsis pecanis、桃虫牙屬（Myzus SPP·)、茼蒿財（Nasonovia ribisnigri)、介殼蟲（Nephotettix spp·)、褐飛乳(Nilaparvata lugens)、Oncometopia 屬、牲价 (Orthezia praelonga) ^ #^p^IL(Parabemisia myricae) ^ >jv|^ 屬（Paratrioza spp·)、盾虫介屬（Parlatoria spp.)、癭棉财屬 (Pemphigus spp.)、Peregrinus maidis、粉風屬(Phenacoccus spp·)、揚平翅棉财（Phloeomyzus passerinii)、瘤財（Phorodon humuli)、桃根财屬（Phylloxera spp·)、橘長盾紛(Pinnaspis aspidistrae)、粉矫屬（Planococcus spp·)、梨形原棉蛉 (Protopulvinaria pyriformis)、桑白虫介（Pseudaulacaspis pentagona)、粉介殼蟲(Pseudococcus spp·)、木風蟲(Psylla spp·)、金小蜂屬（Pteromalus spp·)、飛乱屬（Pyrilla spp·)、圓 虫介屬（Quadraspidiotus spp·)、Quesada gigas、Rastrococcus 屬、頸狀财屬（Rhopalosiphum spp·)、扁介毅蟲屬（Saissetia spp·)、螻蛄（Scaphoides titanus)、麥二叉财（Schizaphis graminum)、Selenaspidus articulatus、飛風屬（Sogata spp·)、 白背飛5l(Sogatella furcifera)、飛虱屬（Sogatodes spp.)、沐 蟬（Stictocephala festina)、Tenalaphara malayensis、核桃黑 財（Tinocallis caryaefoliae)、沫蟬屬（Tomaspis spp·)、二叉虫牙 屬（Toxoptera spp·)、桑粉兹（Trialeurodes vaporariorum)、木 -24- 20 200800861 風屬（Trioza spp·)、小葉蟬屬（Typhi〇Cyba spp·)、盾虫介屬 (Unaspis spp·)、葡萄根瘤騎(viteus vitifolii) 〇 膜翅目（Hymenoptera)，例如··松葉蜂屬（Diprion spp·)、葉 蜂屬（Hoplocampa spp.)、蟻屬（Lasius spp·)、廚蟻 (Monomorium pharaonis)、胡蜂屬（Vespa spp·)。 等足目（Isopoda) ’ 例如：鼠婦(Armadillidium vulgare)、海 蛆（Oniscus asellus)、球鼠婦(porceiii〇 scaber)。Lecanium spp., Lepidosaphes spp., Lipaphis erysimi, Macrosiphum spp., Mahanarva fimbriolata, Melanaphis sacchari, Metcalfiella , Metopolophium dirhodum, Monellia costalis, Monelliopsis pecanis, Myzus SPP·, Nasonovia ribisnigri, Nephotettix spp·, brown milk (Nilaparvata lugens), Oncometopia genus, Orthezia praelonga ^ #^p^IL(Parabemisia myricae) ^ >jv|^ genus (Paratrioza spp.), Shield worm (Parlatoria spp.), 瘿棉财Genus (Pemphigus spp.), Peregrinus maidis, Phenacoccus spp., Phloeomyzus passerinii, Phorodon humuli, Phyloxera spp., Orange long shield ( Pinnaspis aspidistrae), Planococcus spp., Protopulvinaria pyriformis, Pseudaulacaspis pentagona, Pseudococcus spp., Psy Lla spp·), Pteromalus spp., Pyrilla spp., Quadraspidiotus spp., Quesada gigas, Rastrococcus, Rhopalosiphum spp. Saissetia spp., Scaphoides titanus, Schizaphis graminum, Selenaspidus articulatus, Sogata spp., Sogatella furcifera, locust (Sogatodes spp.), Stictocephala festina, Tenalaphara malayensis, Tinocallis caryaefoliae, Tomaspis spp., Toxoptera spp., Trialeurodes vaporariorum ,木-24- 20 200800861 Wind genus (Trioza spp.), genus Typhi 〇Cyba spp., Unaspis spp·, viteus vitifolii, Hymenoptera For example, Diprion spp., Hoplocampa spp., Lasius spp., Monomorium pharaonis, Vespa spp. Isopoda ‘ for example: Armadillidium vulgare, Oniscus asellus, porceiii〇 scaber.

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等翅目（Isoptera) ’ 例如：白蟻屬（Reticulitermes spp·)、土白 蟻屬（Odontotermes spp·)。 鱗翅目（Lepidoptera)，例如：梁劍紋夜蛾(Acronicta major)、 電紋夜蛾(Aedia leucomelas)、地老虎屬（Agrotis spp·)、棉葉 波紋夜蛾(Alabama argillacea)、夜蛾屬（Anticarsia spp·)、甘 藍夜蛾（Barathra brassicae)、棉葉穿孔潛蛾（Bucculatrix thurberiella)、松尺蠖(Bupalus piniarius)、捲葉蛾（Cacoecia podana)、煙捲葉蛾(Capua reticulana)、蘋果蠹蛾(Carpocapsa pomonella)、冬尺蛾（Cheimatobia brumata)、煩屬（Chilo SPP·)、雲杉捲葉蛾(Choristoneura fumiferana)、葡萄果橐蛾 (Clysia ambiguella)、捲堪屬（Cnaphalocerus spp·)、埃及金剛 鑽（Earias insulana)、粉螺（Ephestia kuehniella)、毒蛾 (Euproctis chrysorrhoea)、切根蟲屬（Euxoa spp·)、褐夜蛾屬 (Feltia spp·)、大躐模（Galleria mellonella)、夜蛾屬 (Helicoverpa spp·)、棉鈴蟲屬（Heliothis spp·)、褐織夜蛾 (Hofmannophila pseudospretella)、捲葉蛾（Homona magnanima)、櫻桃巢蛾（Hyponomeuta padella)、黏蟲屬 -25- 20 200800861 (Laphygma spp·)、細蛾(Lithocolletis blancardella)、綠果夜 蛾（Lithophane antennata)、豆白緣切根蟲（Loxagrotis albicosta)、毒蛾屬（Lymantria spp·)、金龜（Malacosoma neustria)、甘藍夜蛾(Mamestra brassicae)、Mods repanda、 5 東方黏蟲(Mythimna separate)、夜蛾屬（Oria spp.)、稻負泥 蟲（Oulema oryzae)、小眼夜蛾(Panolis flammea)、紅鈴蟲 (Pectinophora gossypiella)、橘葉潛蛾（Phyllocnistis I citrella)、粉蝶屬（Pieris spp·)、小菜蛾(Plutella xylostella)、 黏蟲屬（Prodenia spp·)、黏蟲屬（Pseudaletia spp.)、大豆夜蛾 i〇 (Pseudoplusia includens)、野模（Pyrausta nubilalis)、黏蟲屬 (Spodoptera spp·)、Thermesia gemmatalis、網衣蛾（Tinea pellionella)、袋衣蛾(Tineola bisselliella)、櫟綠捲葉蛾(Tortrix viridana)、S^^KTrichoplusiaspp·)。 直翅目（〇11；11€^6^)，例如：家蟻蟀(八(；1^&(1〇111631；1(；113)、東 15 方蜚蠊(Blatta orientalis)、德國蜚蠊(丑1&批11公86〇11311化3)、 ，螻蛄(Gryllotalpa spp·)、馬得拉蜚蠊(Leucophaea maderae)、 飛虫皇屬（Locusta spp·)、負虫皇屬（Melanoplus spp·)、美洲大蠊 蚤目（81口11〇1^卩16叫，例如：|苗蚤屬（〇6如〇卩11}^11115 50卩.)、印 2〇 度鼠蚤(Xenopsylla cheopis) 〇 結合目（Symphyla) ’ 例如：Scutigerella immaculata。 缨翅目（Thysanoptera)，例如：稻薊馬（Bali〇thrips biformis)、 Enneothrips flavens、薊馬屬（Frankliniella spp·)、薊馬屬 (Heliothrips spp·)、桃薊馬（Hercinothrips femoralis)、 -26 - 200800861 1(^：0也1^3屬、大花薊馬(^1]^丨卩1101^111^3(；0^1^1113)、黃薊 馬屬（Scktothrips spp·)、薊馬（Taeniothrips cardamoni)、薊馬 屬(Thrips spp·) 〇 總尾目（Thysanura)，例如：西洋衣魚（Lepisma saccharina) 〇 5 植物寄生性線蟲包括，例如：Anguina屬、葉芽線蟲 屬（Aphelenchoides spp.)、刺螫線蟲屬（Belonoaimus spp·)、 黏液囊線蟲屬（Bursaphelenchus spp·)、包囊線蟲(Ditylenchus | dipsaci)、Globodera 屬、Heliocotylenchus 屬、異皮線蟲屬 (Heteroderaspp.)、長針線蟲屬（Longidorus spp·)、根瘤線蟲 ίο 屬（Meloidogyne spp.)、根腐線蟲屬（pratyienchus spp.)、穿 孔線蟲（Radopholus similis)、輪轉線蟲屬（R〇tylenchus spp·)、鬃根線蟲屬（Trichodorus spp·)、矮化線蟲屬 (Tylenchorhynchus spp.)、墊刃線蟲屬（Tylenchulus spp )、墊 刃線蟲（Tylenchulus semipenetrans)、劍線蟲屬（xiphinema 15 Spp·)。 | 若適當時，根據本發明活性化合物組合亦可在某些濃 度或施用率下，作為除草劑、安全劑、生長調節劑或改善 植物性貝之製劑或作為殺微生物劑使用，例如：殺真菌劑、 抗黴菌劑、殺細菌劑、殺病毒劑（包括對抗類病毒）或作為對 20 抗MLO(似黴漿菌生物體)與RL0(似立克次體生物體)之製 劑。若適當％，亦可作為合成其他活性化合物之中間物或 前體使用。 根據本發明，所有植物與植株部份均可接受處理。此 時，咸了解植物係指所有植物及植物族群，如：需要及不 -27· 200800861Isoptera ′ For example: Reticulitermes spp., Odontotermes spp. Lepidoptera, for example: Acronicta major, Aedia leucomelas, Agrotis spp., Alabama argillacea, Noctuidae Anticarsia spp·), Barathra brassicae, Bucculatrix thurberiella, Bupalus piniarius, Cacoecia podana, Capua reticulana, Carpocapsa pomonella , Cheimatobia brumata, Chilo SPP·, Choristoneura fumiferana, Clysia ambiguella, Cnaphalocerus spp., Earias insulana, Ephestia kuehniella, Euproctis chrysorrhoea, Euxoa spp., Feltia spp., Galleria mellonella, Helicoverpa spp. Heliothis spp., Hofmannophila pseudospretella, Homona magnanima, Hyponomeuta padella, Mythimx-2 5- 20 200800861 (Laphygma spp.), Lithocolletis blancardella, Lithhophane antennata, Loxaltis albicosta, Lymantria spp., Malacosoma neustria , Maamestra brassicae, Mods repanda, 5 Mythimna separate, Oria spp., Oulema oryzae, Panolis flammea, red bell Pectinophora gossypiella, Phyllocnistis I citrella, Pieris spp., Plutella xylostella, Prodenia spp., Pseudaletia spp., soybean Pseudoplusia includens, Pyrausta nubilalis, Spodoptera spp., Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix viridana ), S^^KTrichoplusiaspp·). Orthoptera (〇11;11€^6^), for example: home ant 蟀 (eight (; 1^ &(1〇111631; 1 (; 113), East 15 square 蜚蠊 (Blatta orientalis), German 蜚蠊 (Ugly 1 & batch 11 gong 86 〇 11311 3 3), 蝼蛄 (Gryllotalpa spp·), eu 蜚蠊 L (Leucophaea maderae), 飞 皇 (Locusta spp.), 负虫皇 (Melanoplus spp ·), the American lynx (81 mouth 11 〇 1 ^ 卩 16 called, for example: | nursery genus (〇 6 如〇卩 11} ^ 11115 50 卩.), India 2 〇 蚤 蚤 (Xenopsylla cheopis) "Symphyla" ' For example: Scutigerella immaculata. Thysanoptera, for example: Bali〇thrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp· ), cin 蓟 (Hercinothrips femoralis), -26 - 200800861 1 (^: 0 also 1^3 genus, large flower 蓟 horse (^1] ^ 丨卩 1101 ^ 111 ^ 3 (; 0 ^ 1 ^ 1113), Scktothrips spp., Taeniothrips cardamoni, Thrips spp. Thysanura, for example: Lepisma saccharina 〇5 Plant parasitism Nematodes include, for example, Anguina genus, Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus | dipsaci, Globodera genus, Heliocotylenchus Genus, Heteroderaspp., Longidorus spp., Meloidogyne spp., pratyienchus spp., Radopholus similis, Rotary nematode (R〇tylenchus spp.), Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp, Tylenchulus semipenetrans, xiphinema 15 Spp·). If appropriate, the active compound combinations according to the invention can also be used as herbicides, safeners, growth regulators or formulations for improving phytoplankton or as microbicides at certain concentrations or application rates, for example: fungicidal Agent, antifungal agent, bactericide, virucide (including antiviral) or as a preparation against 20 MLO (mycoplasma-like organism) and RL0 (like rickettsia organism). If appropriate, it can also be used as an intermediate or precursor for the synthesis of other active compounds. According to the invention, all plants and plant parts are acceptable for treatment. At this time, the salty understanding of the plant refers to all plants and plant groups, such as: need and not -27· 200800861

10 20 需要之野生植物或作物（包括天然作物）。作物可為得自依傳 統植物育種法與最適化方法或利用生物技術或遺傳工程法 或此等方法之組合所取得者，包括基因轉殖植物，包括受 植物育種者權益保護及未受保護之植物栽培品種。亦咸了 解，植株部份意指植物之所有地上及地下部份與器官，如· 芽、葉、花與根，其實例可述及：闊葉、針葉、軸、莖、 花、果實體、果實、種子、根、球莖與根莖。植株部&亦 包括收穫之材料，與營養性及繁殖性材料，例如··杆插、' 球莖、根莖、槩枝與種子。 根據本發明使用活性化合物組合處理植物與植株部份 之方法為依傳統處理法，直接進行處理，或使化合物作用 在^ % i兄、樓息地或庫存空間，例如：浸泡、喷灑、蒸發 喷務、撒播、塗刷、注射，及處理繁殖材斜時，特定言之 處理種子時，亦可包覆一層或多層包衣。 。 、洛性化合物組合可轉換成慣用調配物，如：溶液、乳 ^、可濕化粉劑、水性與油性懸浮液、粉劑、細粉劑、糊 =可溶性粉劑、可紐_、撒制粒劑、懸浮-乳液濃 浸泡過活性化合物之天錢質與浸泡騎性化合物 、肥料及含在聚合材料中之微膠囊化物。 物與配物係依已知方式製備，例如：混合活性化合 界面、、諸=丨料液體溶劑及/或11)11載劑，視需要可使用 ㈣法亦即乳化劑及/或勾散劑，及/或發泡劑。調配 物1係在施用前或施用期間於合適設備中進行。 °為輔d之物質為彼等適合對組合物本身及/或其所 -28- 200800861 何生之製劑（例如：噴灑液、種子包衣)賦與特殊性質，如· 某些機械性質及/或特殊生物性質之物質。典型之 為：補充劑、溶劑與載劑。 釗 510 20 Wild plants or crops (including natural crops) needed. Crops may be obtained from traditional plant breeding methods and optimization methods or using biotechnology or genetic engineering methods or combinations of such methods, including genetically modified plants, including protected by plant breeders and unprotected. Plant cultivars. It is also known that plant parts mean all above-ground and underground parts and organs of plants, such as buds, leaves, flowers and roots. Examples can be described as: broadleaf, needles, shafts, stems, flowers, fruit bodies. , fruit, seeds, roots, bulbs and rhizomes. The Plant Department & also includes harvested materials, and nutritive and reproductive materials such as rods, 'bulbs, rhizomes, lychees and seeds. The method of treating plants and plant parts using the active compound combination according to the invention is carried out according to a conventional treatment method, or the compound is applied to the brothers, the land or the stock space, for example: soaking, spraying, evaporating When spraying, spreading, painting, injecting, and treating the propagation material, it may be coated with one or more layers when the seed is treated specifically. . The combination of the compound of Luo can be converted into a conventional formulation, such as: solution, milk, wettable powder, aqueous and oily suspension, powder, fine powder, paste = soluble powder, can be used, granulated, suspended - The emulsion is concentrated in the soaking of the active compound and the soaking compound, the fertilizer and the microencapsulated compound contained in the polymeric material. The preparation and the preparation are prepared in a known manner, for example, by mixing an active compound interface, a liquid solvent, and/or 11) a carrier, and if necessary, an emulsifier and/or a emulsifier, And / or foaming agent. Formulation 1 is carried out in a suitable apparatus prior to or during application. The substances which are auxiliary d are suitable for the composition itself and/or its preparations (for example: spray liquid, seed coating), such as · certain mechanical properties and / Or a substance of a special biological nature. Typically: supplements, solvents and carriers.钊 5

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20 a適之補充劑為例如：水、極性與非極性有機化學 體例如·芳香系與非芳香系烴類(如：鏈烧烴、烧基笨、 烧基奈、氯苯）、醇類與多元醇(若適當時，亦可經取代 化及/或醋化）、酮類(如：丙_、環己酮）、_(包括脂肪類 與油類）與（聚）喊類、未取代與經取代之胺類、醯胺類、內 醯胺類(如：N-烧基吼略咬酮)與内醋類、石風類與亞石風類(如： -T亞石思‘、〇 兔越當^用水作為補充劑時，亦可使用例如：有機溶劑作 ί;甲類、氯化芳香烴與心 例如m稀或—乳甲燒，脂族煙類如：環己烧或石壤， 门如·石油分鶴物、礦物油與植物油，醇類如. $其醚類與醋類，酮類如：丙義 丁基，，嗣’強極性溶劑如:二甲亞二_ 合適之固態載劑為： =石ί鹽及天然礦物磨粉如：高嶺土、黏土、滑石、白 磨t、如國活性白土、蒙脫土或残土，及合成物質 礬土與矽酸鹽；適用為粒劑之固能 =::r與分碎天然礦石，如:方解石、大理:: 及有機物’及無機與有機磨粉之合成顆粒， 及有機物質顆粒如：紙、㈣、椰子殼、玉米穗軸與煙草 -29- 20080086120 a suitable supplements are, for example, water, polar and non-polar organic chemicals such as aromatic and non-aromatic hydrocarbons (eg, chain hydrocarbons, burnt base, burntylene, chlorobenzene), alcohols and Polyol (may be substituted and/or acetated if appropriate), ketones (eg, C-, cyclohexanone), _ (including fats and oils) and (poly) shouts, unsubstituted And substituted amines, guanamines, indoleamines (such as N-alkyl ketone) and internal vinegars, stone winds and sub-stones (such as: -T Ya Shisi), When the rabbit is used as a supplement, it can also be used, for example, as an organic solvent; a class A, a chlorinated aromatic hydrocarbon with a heart such as m or a milk, and an aliphatic cigarette such as a ring or a stone Soil, such as oil, crane oil, mineral oil and vegetable oil, alcohols such as. $ ether and vinegar, ketones such as: propyl butyl, 嗣 'strong polar solvent such as: dimethyl s The solid carrier is: = stone salt and natural mineral mill such as: kaolin, clay, talc, white mill t, such as national activated clay, montmorillonite or residual soil, and synthetic bauxite and citrate; Solids of the agent =::r and crushed natural ores, such as: calcite, Dali:: and organic matter' and synthetic particles of inorganic and organic grinding, and organic matter particles such as: paper, (four), coconut shell, corn cob With tobacco -29- 200800861

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桿；適用之乳化劑及/或發泡劑為例如：非離子性與陰離子 性乳化劑如：聚氧乙烯脂肪酸酯、聚氧乙烯脂肪醇醚，例 如：烷芳基聚二醇醚類、磺酸烷基酯、硫酸烷基酯、績酸 芳基酯、與蛋白質水解產物；合適勻散劑為非離子性及/或 離子性物質，例如：來自醇-POE及/或-POP醚類、酸及/ 或POPPOE酯類、烷基-芳基及/或poppoe醚類、脂肪及 /或POPPOE加合物、P0E-及/或pop-多元醇衍生物、p〇E_ 及/或POP-山梨糖醇酐或-糖加合物、烷基或芳基硫酸酯、 烷基或芳基磺酸酯與烷基或芳基磷酸酯或相應之P0_醚加 合物。此外，亦可使用合適之寡聚物或聚合物，例如：彼 等衍生自乙烯基單體之寡聚物或聚合物、衍生自丙烯酸之 寡聚物或聚合物、由EO及/或P0單獨或組合例如：（聚) 醇類或（聚）胺類衍生成之寡聚物或聚合物。此外亦可使用木 質素與其雜衍生物、未修飾與經修飾之纖維素、芳香系 及/或月曰糸石k S文類及其與甲齡之加合物。 调配物中可使用增稠劑如：叛甲基纖維素，及呈粉末、 顆粒或料之^與合絲合物，如：阿拉伯膠、聚乙稀 醇與聚醋酸乙烯i旨，及天_脂如：麟脂與_脂及合 •無機色素(例如：氧化鐵，氧化 ，如：茜素染料，偶氮染料與金 養"素如·鐵、猛、、銅、在古、 亦可使用染色劑，如 鈦與普魯士藍)及有機染料 屬酜花青染料，及微量營 鉬與鋅之鹽類。 可視需要修飾之礦物油或植 其他可能添加物為香料 -30- 20 200800861 物油、_與營養素(亦包括微量營養素），如：鐵、猛 銅、鈷、鉬與鋅之鹽類。 亦可包括安低溫安定劑、防腐劑、抗氧化 劑、光安定劑或-他文。化學/物i里安定性之製劑。 該調配物中通常包含〇.〇1至98重量％活性化合物，以 0.5至90重量％之間較佳。Rods; suitable emulsifiers and/or foaming agents are, for example, nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, for example: alkaryl polyglycol ethers, An alkyl sulfonate, an alkyl sulfate, an aryl acid ester, and a protein hydrolysate; suitable dispersing agents are nonionic and/or ionic materials, for example, from alcohol-POE and/or -POP ethers, Acid and/or PPOOE esters, alkyl-aryl and/or poppoe ethers, fat and/or PPOOE adducts, P0E- and/or pop-polyol derivatives, p〇E_ and/or POP-sorbent A sugar anhydride or a sugar adduct, an alkyl or aryl sulfate, an alkyl or aryl sulfonate and an alkyl or aryl phosphate or a corresponding P0_ether adduct. In addition, suitable oligomers or polymers may also be used, for example: oligomers or polymers derived from vinyl monomers, oligomers or polymers derived from acrylic acid, alone by EO and/or P0. Or a combination of, for example, an (oligo) alcohol or a (poly)amine derived oligomer or polymer. In addition, lignin and its hetero-derivatives, unmodified and modified cellulose, aromatic and/or moonstone k S and their age-related adducts can also be used. Thickeners such as: methyl cellulose, and powders, granules or materials, such as gum arabic, polyethylene glycol and polyvinyl acetate, and days _ can be used in the formulation. Lipids such as: linseed and _fat and combined with inorganic pigments (for example: iron oxide, oxidation, such as: alizarin dyes, azo dyes and gold raises), such as iron, fierce, copper, in ancient times, Use dyes such as titanium and Prussian blue) and organic dyes are phthalocyanine dyes, and trace salts of molybdenum and zinc. Mineral oils or plants that may be modified as needed. Other additives are spices. -30- 20 200800861 Oils, _ and nutrients (including micronutrients) such as iron, copper, cobalt, molybdenum and zinc. It may also include a low temperature stabilizer, a preservative, an antioxidant, a light stabilizer or -. Chemical/material i stable preparation. The formulation generally comprises from 1 to 98% by weight of active compound, preferably from 0.5 to 90% by weight.

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本發明活性化t物組合可呈一般商品調配物及由此調 配物與其他活性化&物混合成之施用型式，如：殺昆蟲劑、 誘餌、不孕劑、殺細菌劑、殺蟎劑、殺線蟲劑、殺真菌劑、 生長調節⑱質或除草劑。殺昆蟲劑特另,j包括例如：構酸自旨 類、胺甲酸醋類、叛酸酉旨類、氣化烴類、笨基脈類、由微 生物產生之物質。 亦可與其他已知活性化合物，如··除草劑，或與肥料 及生長調節劑形成混合物。 當作為殺昆蟲劑使用時，根據本發明活性化合物組合 可進一步與增效劑形成混合物，呈其商品調配物形式及由 此調配物製成之施用形式。增效劑意指可提高活性化合物 之活性’但其本身不一定有活性之化合物。 由调配物商品製成之施用形式中之活性化合物含量可 在很大範圍内變化。施用形式之活性化合物濃度可為 0.00000001至95重量％活性化合物之範圍内，較佳為 0.00001 至 1 重量％。 該等化合物可依適合施用形式之方法施用。 如上述’根據本發明可處理所有植物與其部份植株。 20 200800861 較佳具體實施例中係處理野生植物品種與木 循:等由傳統峰物言插汰•六締、、+ > _The active t-combination of the present invention may be in the form of a general commercial formulation and a formulation in which the formulation is mixed with other active chemicals and the like, such as an insecticide, a bait, a non-fertility agent, a bactericide, an acaricide. , nematicides, fungicides, growth regulating 18 or herbicides. In particular, the insecticides include, for example, phytic acid-specific substances, urethane carboxylic acid vinegars, retinoic acid-like substances, gasified hydrocarbons, stupid gangues, and substances produced by microorganisms. It may also be admixed with other known active compounds, such as herbicides, or with fertilizers and growth regulators. When used as an insecticide, the active compound combination according to the invention may further form a mixture with the synergist, in the form of its commercial formulation and the form of administration made therefrom. Synergist means a compound which increases the activity of the active compound but which is not necessarily active per se. The active compound content of the application forms made from the formulation commercials can vary widely. The active compound concentration in the application form may range from 0.00000001 to 95% by weight of active compound, preferably from 0.00001 to 1% by weight. These compounds can be administered in a manner suitable for the form of administration. All plants and some of their plants can be treated according to the invention as described above. 20 200800861 In a preferred embodiment, the treatment of wild plant species and wood circulation: etc. is carried out by traditional peaks and words; six associations, + > _

品種與植物栽培品種或 質融合法）取得 菔貫施例中，係處理由 、虫2由 2 丨，1/丁、处士王田 5 ^^(料料，可併㈣财法)_之難基因植物 ，植物栽培品種(基因改造生物），及其部份植株。術語「部 伤」或「植株部份」或「部份植株」已如上述說明。 肖別佳者’根據本發明係處理自商品取得或使之 > 植物栽培品種之植物。戍了解 β士#、 成了解，植物栽培品種意指經由傳 10 (「月去誘、支法或重組DNA技術得到之具有新穎性質 (特性」）之植物。其可為生物型或基因型栽培品種。 ^ ，植物品種或植物栽培品種、其位置與生長條件（土 襄氣候、營養生長期、肥料）而異，根據本發明處理法亦 ^能產生超過加成性（「增效性」）妓果。因此，可能超過預 果為例如:降低施用率及/或擴大活性範圍及/或提高 ，據本發明所使用物質與組合物之活性、改善植物生長、 > Μ高對高溫或低溫之耐受性、提高對乾旱或對水 ^ t鹽含量之耐受性、提高開花率、簡化收成、加逮成孰、 提兩收穫量、提高所收成產品之品質及/或提高營養價值、 泊更仏儲存女定性及/或提高所收成產品之可加工性。 〇 根據本發明處理之較佳轉殖基因植物或植物裁抖π種 (亦即彼等由遺傳工程取得者）包括所有於基因改造^程 中，接受賦與特別有利特性之基因材料之植物。此等特性 實例為改善植物生長、提高對高溫或低溫之耐受性、提高 乾干或對水含星或土壌鹽含量之财受性、改善開花率 -32 - 200800861 簡化收成、加速成熟、提高收穫量、提高所收成產品之品 質及/或提高營養知值、更佳儲存安定性及/或提高所收成產 品之可加工性。其他及特別強調之此等特性實例為植物對 抗動物害蟲與微生物害蟲之更佳防禦性，如··對抗昆蟲、 蟎、植物病原性真菌、細菌及/或病毒，亦提高植物對某些 除草活性化合物之耐受性。此等轉殖基因植物實例為重要 作物，如··穀類（小麥、稻）、玉米、大豆、馬鈴薯、甜菜、 番茄、豌豆及其他蔬菜品種、棉花、·菸草、油菜與果實植 物（蘋果、梨、柑橘與葡萄），特別著重於玉米、大豆、馬鈐 薯、棉花、菸草與油菜。所特別強調之特性為利用植株内 所形成毒素，特定言之由來自蘇雲金芽胞桿菌（Bacillus thuringiensis)之遺傳物質（例如：基因 cryIA(a)、CrylA⑻、Variety and plant cultivar or quality fusion method) in the case of the treatment, the treatment of the insect, insect 2 from 2 丨, 1 / D, Shishi Wang Tian 5 ^ ^ (materials, can be (four) financial law) _ difficult Genetic plants, plant cultivars (genetically modified organisms), and some of their plants. The terms "partial injury" or "plant part" or "partial plant" have been described above. According to the present invention, a plant obtained from a commercial product or a plant cultivar thereof is treated.戍Understanding β士#, 成知知, Plant cultivar means a plant that has been genetically or genotyped by passing 10 ("Most-inducing, branching or recombinant DNA technology with novel properties (characteristics)). Variety. ^ , plant variety or plant cultivar, its location and growth conditions (soil climate, vegetative growth period, fertilizer), according to the treatment method of the present invention can also produce more than additive ("potentiation") Capsules. Therefore, it may be possible to exceed the pre-fruits as, for example, reducing the application rate and/or expanding the range of activity and/or increasing the activity of the substances and compositions used according to the invention, improving plant growth, > high to high or low temperature Tolerance, increase tolerance to drought or water content, increase flowering rate, simplify harvest, increase harvest, increase harvest, improve quality of harvested products, and/or improve nutritional value, The storage of the female character and/or the improvement of the processability of the harvested product. 较佳 The preferred transgenic plants or plants that are treated according to the invention are π (that is, those obtained by genetic engineering) include all Plants that receive genetic material with particularly advantageous properties for the purpose of improving the plant growth, increasing tolerance to high or low temperatures, increasing dryness or water-containing star or earthworm salt content. Wealth and improvement of flowering rate -32 - 200800861 Simplify harvest, accelerate maturity, increase harvest, improve the quality of harvested products and / or improve nutritional value, better storage stability and / or improve the processing of harvested products Other and special emphasis on these characteristics are examples of better defense against plant pests and microbial pests, such as against insects, mites, phytopathogenic fungi, bacteria and/or viruses, and also on plants. Tolerance of herbicidal active compounds. Examples of such transgenic plants are important crops such as cereals (wheat, rice), corn, soybeans, potatoes, beets, tomatoes, peas and other vegetable varieties, cotton, tobacco, Rape and fruit plants (apples, pears, citrus and grapes) with special emphasis on corn, soybeans, horses, potatoes, cotton, tobacco and canola. The characteristic is adjusted using the toxin is formed within the plant, certain words from a Bacillus thuringiensis (Bacillus thuringiensis) of the genetic material (e.g.: genes cryIA (a), CrylA⑻,

CrylA(c)、CryllA、CrylllA、CryIIIB2、Cry9c、Cry2Ab、CrylA (c), CryllA, CrylllA, CryIIIB2, Cry9c, Cry2Ab,

Cry3Bb與CryLF及其組合)於植株内所形成之毒素（下文中 稱為「Bt植物」）提南對抗昆蟲、蜘蛛、線蟲、及螞牛與姑 蝓之防禦性。亦特別強調之特性為利用後天取得之全株抗 性(SAR)、系統素(systemin)、植物抗毒素、誘發素(dicit〇rs) 與抗性基因，及相應表現之蛋白質與毒素，提高對抗真菌、 細菌與病毒之防禦性。其他特別強調之特性為提高植物對 某些除草活性化合物，例如：咪唑啉酮類、磺醯脲類、草 甘膦（glyphosate)或膦三辛（phosphin〇tricin)之耐受性（例 如··「PAT」基因）。此等賦與所需特性之基因亦可相互組合 進入轉殖基因植物中。「Bt植物」實例可述及以下列商品名 稱出售之玉米品種、棉花品種、大豆品種與馬鈴薯品種： -33- 200800861 YIELD GARD® (例如：玉米、棉花、大豆）、Kn〇ckOut(D(例 如：玉米）、StarLink⑧（例如：玉米）、Bollgard®(棉花）、 Nucotn®(棉花)與NewLeaf®(馬鈴薯）。除草劑耐受性植物實 例可述及以下列商品名稱出售之玉米品種、棉花品種與大 5 豆品種：RounduPReady®(耐受草甘膦，例如：玉米、棉花、 大豆）、Liberty Link® (耐受膦三辛(phosphinotricin)，例如： 油菜）、IMI®(财受咪唑啉酮類)與stS(D(耐受磺醯脲類，例 _ 如：玉米）。可述及之除草劑抗性植物(依傳統育種法育種而 耐受除草劑之植物）包括以下列商品名稱出售之品種： ίο Clearfiel_(例如：玉米）。當然，此等說明亦適用於已具有 此等遺傳特性或仍待發展出此等遺傳特性，而將於未來發 展及/或上市之植物栽培品種。 上述植物可依特別有利之方式，使用根據本發明活性 化合物組合處理。上述活性化合物組合所提及之較佳範圍 15 亦適用於處理此等植物。特別強調使用本文中明確說明之 馨 活性化合物組合處理植物。 根據本發明活性化合物組合不僅可活性對抗植物害 蟲、衛生環境害蟲及庫存產品害蟲，而且可用於獸醫學， 對抗動物寄生蟲（體外寄生蟲與體内寄生蟲）如：軟蜱、硬 20 蜱、疮蜗、秋收恙蜗、螫蠅與碟绳、寄生蠅幼蟲、蟲、毛 蝨、鳥蝨及跳蚤。此等寄生蟲包括： 蝨目（Anoplurada)，例如：盲蝨屬（Haemat〇pinus spp )、長 顎妙屬（Linognathusspp·)、益瞒屬（Pediculus spp·)、陰為属 (Phtirus spp·)，管蝨屬（s〇len〇p〇tes spp )。 -34- 200800861 10 15Cry3Bb and CryLF and their combination) toxins formed in plants (hereinafter referred to as "Bt plants") promote the defense against insects, spiders, nematodes, and oxen and aunts. Special emphasis is also placed on the use of acquired plant resistance (SAR), systemin, phytoalexin, dicit〇rs and resistance genes, and corresponding proteins and toxins to enhance antifungal , the defense of bacteria and viruses. Other special emphasis is on improving the tolerance of plants to certain herbicidal active compounds such as imidazolinones, sulfonylureas, glyphosate or phosphin〇tricin (eg··· "PAT" gene). These genes, which confer the desired characteristics, can also be combined into a transgenic plant. Examples of "Bt plants" may refer to corn, cotton, soybean and potato varieties sold under the following trade names: -33- 200800861 YIELD GARD® (eg corn, cotton, soybean), Kn〇ckOut (D (eg : corn), StarLink 8 (eg corn), Bollgard® (cotton), Nucotn® (cotton) and NewLeaf® (potato). Examples of herbicide-tolerant plants can be described as corn varieties and cotton varieties sold under the following trade names And large 5 bean varieties: RounduPReady® (tolerant glyphosate, eg corn, cotton, soybean), Liberty Link® (phosphinotricin, eg, rapeseed), IMI® Class) and stS (D (tolerant sulfonylureas, eg _ such as corn). Herbicide-resistant plants (plants that are tolerant to herbicides by traditional breeding methods) may be sold under the following trade names Variety: ίο Clearfiel_ (eg corn). Of course, these instructions also apply to plant cultivation that has such genetic characteristics or is still to be developed and will be developed and/or marketed in the future. The abovementioned plants can be treated in a particularly advantageous manner using a combination of the active compounds according to the invention. The preferred range 15 mentioned in the above active compound combinations is also suitable for the treatment of such plants, with particular emphasis on the use of the singly activity specified herein. The combination of compounds treats plants. According to the invention, the active compound combination is not only active against plant pests, sanitary environment pests and stock product pests, but also veterinary, against animal parasites (external parasites and endoparasites) such as: soft palate , hard 20 蜱, sore snail, autumn harvest snail, scorpion fly and dish rope, parasitic larvae, insects, ranunculus, guanine and fleas. These parasites include: Anoplurada, for example: genus Haemat〇pinus spp), Linognathus spp., Pediculus spp., Phtirus spp., s〇len〇p〇tes spp. -34- 200800861 10 15

食毛目（Mallophagida)及鈍角亞目（Amblycerina)與細角亞目 (Ischnocerina)，例如··毛鳥蝨屬（Trimenoponspp·)、雞蝨屬 (Menopon spp·)、巨毛蟲屬（Trinoton spp·)、羽兹屬（Bovicola spp·)、Werneckiella 屬、Lepikentron 屬、食蟲it(Damalina) 屬、羽兹屬（Trichodectes spp·)、I苗羽兹屬（Felicola spp·)。 雙翅目（Diptera)及長角亞目（Nematocerina)與短角亞目 (Brachycerina)，例如：伊蚊屬（Aedes spp·)、按蚊屬 (Anopheles spp·)、庫蚊屬（Culexspp·)、蚋蚊屬（Simulium SPP·)、真蚋屬（五113111111111111130|).)、白蛉屬（？11^1)(^〇111115 spp·)、沙蠅(Lutzomyia)屬、蚊屬（Culicoides spp·)、斑it屬 (Chrysops spp.)、瘤 it 屬（Hybomitra spp.)、黃 it 屬（Atylotus spp·)、it屬（Tabanus spp.)、麻翅it屬（Haematopota spp·)、 Philipomyia 屬、蜂風(Braula)屬、家蠅屬（Musca spp·)、齒 股繩（Hydrotaea)屬、螫蠅屬（Stomoxys spp·)、血蠅屬 (Haematobia spp·)、莫繩(Morellia)屬、廄繩屬（Fannia spp·)、 舌繩屬（Glossina spp·)、麗繩屬（Calliphora spp·)、綠繩屬 (Lucilia spp·)、金繩屬（Chrysomyia spp·)、肉蠅屬（Wohlfahrtia spp·)、麻繩屬（Sarcophaga spp·)、狂繩屬（Oestrus spp·)、皮 蠅屬（Hypoderma spp·)、胃蠅屬（Gasterophilus spp·)、蝨蠅屬 (Hippobosca spp·)、Lipoptena 屬、羊兹蠅屬（Melophagus spp·) 〇 蚤目（Siphonapterida)，例如：蚤屬（Pulex spp.)、櫛頭蚤屬 (Ctenocephalides spp·)、鼠蚤屬（Xenopsylla spp·)、角葉蚤屬 (Ceratophyllus spp·) 〇 -35- 20 200800861 異翅目（Heteropterida)，例如：臭蟲屬（Cimex spp·)、錐培屬 (Triatoma spp·)、紅腹獵蝽屬（Rhodnius spp·)、金圓墙屬 (Panstrongylus spp·) 〇 虫非蠊目（6丨3加1^)，例如：東方棑蠊(813似01^1^1丨3)、美洲 5 虫非蠊（Periplaneta americana)、德國虫非蠊（Blattella germanica)、緋蠊屬（Supella spp·)。 蜱蟲亞目（Acaria)(粉蟲目（Acarida))及後氣亞目 | (Metastigmata)與中氣亞目（Mesostigmata)，例如：銳緣蜱屬 (Argas spp·)、鈍緣蜱屬（Ornithodorus spp.)、殘緣蜱屬 ίο (Otobius spp·)、硬蜱屬（Ixodes spp·)、花蜱屬（Amblyomma SPP·)、牛蜱屬（Boophilus spp·)、革蜱屬（Dermacentor spp·)、 血蜱屬（Haemophysalis spp·)、璃眼蜱屬（Hyalomma spp·)、扇 頭碑屬（Rhipicephalus spp.)、刺皮蜗屬（Dermanyssus spp·)、 耳蟎屬（Raillietia spp·)、肺刺蟎屬（Pneumonyssus spp·)、胸 15 孔瞒屬（Sternostoma spp·)、瓦蜗屬（Varroa spp·)。 I 光芒蟲亞目（Actinedida)(前氣亞目（Prostigmata))與粉蜗亞目 (Acaridida)(無氣亞目（Astigmata))，例如：蜂蜗屬（Acarapis spp·)、姬蟄蜗屬（Cheyletiella spp·)、禽螫蜗屬 (Ornithocheyletia spp·)、肉蟎屬（Myobia spp·)、綿羊疥蟎 20 (Psorergates spp·)、月旨蟎屬（Demodex spp·)、恙蟎屬 (Trombicula spp·)、螫蜗屬（Listrophorus spp·)、粉瞒屬（Acarus spp.)、食赂蟎屬（Tyrophagus spp·)、嗜木蜗屬（〇&1(^1}^011115 spp·)、Hypodectes 屬、翼衣屬（Pterolichus spp·)、癢蟎屬 (Psoroptes spp·)、皮蟎屬（Chorioptes spp·)、耳蟎屬（Otodectes -36- 200800861 spp.)、疥蟎屬（Sarcoptes spp·)、耳蟎屬（Notoedres spp·)、鳥 疥蟎屬（Knemidocoptes spp·)、雞蟎屬（Cytodites spp·)、雞雛 虫茜屬（Lamimosioptes spp·)。 根據本發明活性化合物組合亦適合控制侵害農業畜牧 動物之節肢動物，此等動物如，例如：牛、綿羊、山羊、 馬、豬、驢、駱駝、水牛、兔子、雞、火雞、鴨、鵝與宓 蜂，其他寵物動物如，例如：狗、貓、鳥籠内的鳥與水二 相内的魚’及所謂的實驗動物，如，例如：倉鼠、天兮气、 大鼠及小鼠。藉由控制此等節肢動物，應可降低其死亡； 及改善其生產力（指肉品、乳品、毛、皮、蛋、蜂蜜，等等率 因此可利用根據本發明活性化合物組合達到更經濟及承)〜 單之動物管理。 、 更簡 15 根據本發明活性化合物組合係依已知方式用於獸較々 域及動物官理中，其係呈腸内投藥形式，例如：旋劑西^ 囊、飲劑、灌藥、粒劑、糊劑、大丸藥、餵食與塞膠 經腸式投藥，如，例如：注射(肌内、皮下、靜脈内 内’等等）’鼻内投藥植入，、經皮膚投藥之形式，如模 浸或泡m麗、點藥、清洗與撒粉，及藉助於八° · 性化合物之模塑物品如：項圈、耳掛、尾掛、腳帶、&居 標識裝置，等等。 趣繩、 當用於牛、禽、寵物動物，等等時，活性化合 可呈郝物形式施_如：粉末、乳液、自由流、二 物）’其中包含！至80重量％活性化合物，可直接 ^ 釋議至1〇，_倍後使用，或可呈化學浸藥水使用。或稀 -37- 200800861 此外，發現根據本發明活性化合物組合對破壞工業原 料之昆蟲具有強力殺尾蟲作用。 可述及下列昆蟲’其供作範例且為較佳範例，但未加 以限制：Mallophagida and Amblycerina and Ischnocerina, for example, Trimenoponspp·, Menopon spp., Trinoton spp· ), Bovicola spp., Werneckiella, Lepikentron, Damalina, Trichodectes spp., Felicola spp. Diptera and Nematocerina and Brachycerina, for example: Aedes spp., Anopheles spp., Culexspp. , genus Simulium SPP·, genus genus (five 113111111111111130|).), genus (?11^1) (^〇111115 spp·), genus Lutzomyia, genus (Culicoides spp) ·), Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp., Philipomyia , Brae genus, Musca spp., genus Hydrotaea, Stomoxys spp., Haematobia spp., Morellia genus, Gennia spp., Glossina spp., Calliphora spp., Lucilia spp., Chrysomyia spp., Wohlfahrtia Spp·), Sarcophaga spp., Oestrus spp., Hypoderma spp., Gasterophilus spp., Hippobosca s Pp·), Lipoptena genus, Melophagus spp., Siphonapterida, for example: Pulex spp., Ctenocephalides spp., Xenopsylla spp· ), Ceratophyllus spp. 〇-35- 20 200800861 Heteropterida, for example: Cimex spp., Triatoma spp., Rhodonius Spp·), Panstrongylus spp. 〇 蠊 ( ( (6丨3 plus 1^), for example: Oriental 棑蠊 (813 like 01^1^1丨3), American 5 worm non-蠊 ( Periplaneta americana), Blattella germanica, Supella spp. Acaria (Acarida) and Subgenus | (Metastigmata) and Mesostigmata, for example: Argas spp., blunt Ornithodorus spp.), Otobius spp., Ixodes spp., Amblyomma SPP., Boophilus spp., Dermacentor spp. ), Haemophysalis spp., Hyalomma spp., Rhipicephalus spp., Dermanyssus spp., Raillietia spp. Pneumonyssus spp., Sternostoma spp., Varroa spp. I Actinedida (Prostigmata) and Acaridida (Astigmata), for example: Acarapis spp·, Aphis gossypii (Cheyletiella spp.), Ornithocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trimcula Spp·), Listrophorus spp., Acarus spp., Tyrophagus spp., genus 〇&1(^1}^011115 spp·) , Hypodectes, Pterolichus spp., Psoroptes spp., Chorioptes spp., Otodectes -36-200800861 spp., Sarcoptes spp ·), Notoedres spp., Knemidocoptes spp., Cytodites spp., Lamemisioptes spp. The active compound combination according to the invention is also suitable for control Arthropods that invade agricultural livestock, such as cattle, sheep, goats, horses, pigs, donkeys, Camels, buffalo, rabbits, chickens, turkeys, ducks, geese and stag bees, other pet animals such as dogs, cats, birds in bird cages and fish in the water phase, and so-called experimental animals, eg, For example: hamsters, scorpion gas, rats and mice. By controlling these arthropods, they should be able to reduce their death; and improve their productivity (referring to meat, dairy, hair, skin, eggs, honey, etc.) Therefore, it is possible to use a combination of active compounds according to the invention to achieve a more economical and simple animal management. More compact 15 According to the invention, the active compound combinations are used in known manners in mammalian and animal management systems. In the form of enteral administration, for example: sputum sputum, drink, medicated, granules, paste, granules, feeding and sputum enteral administration, such as: injection (intramuscular, subcutaneous, intravenous) Nene 'etc.' 'Intranasal administration, in the form of transdermal administration, such as dip or soaking, spotting, cleaning and dusting, and molded articles with the aid of eight-degree compounds such as: Collar, earhook, tail hang, foot strap, & identification device, Other interesting rope, when used for cattle, poultry, pet animals, and the like, the active compound may be in the form of applied Hao _ such as: powders, emulsions, free-flow, two things) 'which comprises! Up to 80% by weight of active compound can be used directly after 1 〇, _ times, or can be used as chemical immersion water. Or dilute -37- 200800861 Furthermore, it has been found that the combination of active compounds according to the invention has a strong tail killing effect on insects which destroy industrial raw materials. The following insects may be mentioned as examples and are preferred examples, but are not limited:

10 1510 15

甲蟲類如：家天牛（Hylotrupes bajulus)、多毛天牛 (Chlorophorus pilosis)、家具竊蠹（Anobium pimctatum)、 Xestobium rufovillosum、Ptilinus pecticornis、Dendrobium pertinex、Ernobius mollis、Priobium carpini、歐洲竹粉蠹 (Lyctus brunneus)、非洲粉蠹(Lyctus africanus)、平頸粉蠹 (Lyctus planicollis)、桴粉蠹（Lyctus linearis)、軟毛粉蠹 (Lyctus pubescens)、Trogoxylon aequale、Minthes rugicollis、 小蠹屬（Xyleborus spec·)、Tryptodendron 屬、咖啡黑長橐 (Apate monachus)、槲長橐（Bostrychus capucins)、歐洲竹異 長橐（Heterobostrychus brunneus)、長橐屬（SinoxyIon spec·)、竹長蠹(Dinoderus minutus) o 膜翅目（Hymenopterans)如：鋼青樹蜂(Sirex juvencus)、大樹 蜂(Urocerus gigas)、泰格大樹蜂(Urocems gigas taignus)、 Urocems augur ° 白蟻類如：木白蟻（Kalotermes flavicollis)、短白蟻 (Cryptotermes brevis)、灰點異白蟻(Heterotermes indicola)、 黃胸犀白蟻（Reticulitermes flavipes)、山道犀白蟻 (Reticulitermes santonensis)、避光犀白蟻（Reticulitermes lucifugus)、澳洲白蟻(Mastotermes darwiniensis)、内華達古 白蟻(Zootermopsis nevadensis)、家白蟻（Coptotermes -38- 20 200800861 formosanus) ° 衣魚類’如·西洋衣魚(Lepismasaccharina)。 咸了解，本文所指之工業原料為無生命材料如，較佳 為塑膠、膠黏劑、膠水、紙張及紙板、皮革、木材與加二 5 木製品及塗料。 現成可用之組合物若適當時，可包括其他殺昆蟲劑， 且若適當時，可使用一種或多種殺真菌劑。 • 可行之其他添加物為如上述殺昆蟲劑與殺真菌劑。 根據本發明活性化合物組合同樣可用於與鹽水或有鹽 10 味的水接觸之需要保護之物品，尤指：船體、隔板、編網、 建築物、繫船設備及訊號系統，防止貝殼藻類污塞。 此外，根據本發明活性化合物組合可單獨使用或與其 他活性化合物組合，作為抗污塞劑使用。 活性化合物鈕合亦適用於在居家、衛生及保護庫存產 15 品中控制動物害蟲，尤指昆蟲、綠蛛與蜗類等常出現在封 φ 閉空間之害蟲，如，例如：公寓、廠房、辦公室、車廂， 等等。其可單獨使用或與其他在家庭用殺昆蟲劑產品中控 制此等害蟲之活性化合物與辅劑組合使用。其可活性對抗 敏感性及抗性品種.，並對抗所有發展階段。此等害蟲包括： 20 蠍目（Scorpionidea)，例如··钳蠍(Buthus occitanus)。 蜱虫茜目（Acarina) ’例如：波斯銳緣蜱(Argas persicus)、翅緣 銳緣蜱(Argas reflexus)、苔蟎屬（Bryobia ssp·)、雞皮刺蟎 (Dermanyssus gallinae)、家禽甜食蟎（Glyciphagus domesticus)、非洲鈍緣蜱(Ornithodorus moubat)、血紅扇頭 -39- 200800861 蜱（Rhipicephalus sanguineus)、恙蜗(Trombicula alfteddugesi)、秋收中性恙瞒(Neutrombicula autunmalis)、歐 洲家刺皮蜗(Dermatophagoides pteronissimus)、美洲家刺皮 蜗（Dermatophagoides forinae) 〇 5 换蛛目（Araneae)，例如：鳥蛤给蛛（Aviculariidae)、圓蛛 (Araneidae) 〇 盲蛛目（Opiliones)，例如：螫擬蠍（Pseudoscorpiones | chelifer)、擬缴（Pseudoscorpiones cheiridium)、長山奇盲蛛 (Opiliones phalangium) 〇 ίο 等足目（Isopoda)，例如··海蛆（Oniseus asellus)、球鼠婦 (Porcellio scaber) 〇 重足目（Diplopoda)，例如：Blaniulus guttulatus、山螢蟲屬 (Polydesmus spp.) ° 唇足目（Chilopoda)，例如：地埃虫公屬（Geophilus spp·)。 15 總尾目（Zygentoma)，例如：衣魚屬（Ctenolepisma spp·)、西 , 洋衣魚（Lepisma saccharina)、衣魚（Lepismodes inquilinus)。 虫非蠊目（Blattaria)，例如：東方虫非蠊(Blatta orientalis)、德國 虫非蠊(Blattella germanica)、棑蠊(Blattella asahinai)、馬得拉 緋蠊(Leucophaea maderae)、古巴緋蠊屬（panchl〇ra spp·)、帕 2〇 科虫非蠊屬（Parcoblatta spp.)、澳洲虫非蠊（periplaneta australasiae)、美洲緋蠊(Periplaneta americana)、褐色緋蠊 (Periplaneta brunnea)、煙色緋蠊（peripianeta fuiiginosa)、長 鬚虫非蠊(Supella longipalpa)。 跳躍亞目（Saltatoria) ’ 例如··家螺蟀(Acheta domesticus)。 200800861 革翅目（Dermaptera)，例如：歐洲球螋(Forficula auricularia)。 等翅目（Isoptera)，例如：木白蟻屬(^^1(^〇1^3 8卩口.）、犀白 蟻屬（Reticulitermes spp·)。 庵轰目（Psocoptera)，例如：Lepinatus 屬、書兹屬（Liposcelis spp.) 〇Beetles such as Hylotrupes bajulus, Chlorophorus pilosis, Anobium pimctatum, Xestobium rufovillosum, Ptilinus pecticornis, Dendrobium pertinex, Ernobius mollis, Priobium carpini, European bamboo whitefly (Lyctus brunneus) ), African whitefly (Lyctus africanus), Lyctus planicollis, Lyctus linearis, Lyctus pubescens, Trogoxylon aequale, Minthes rugicollis, Xyleborus spec. Tryptodendron genus, Apate monachus, Bostrychus capucins, Heterobostrychus brunneus, Sinoxy Ion spec, Dinoderus minutus o Hymenoptera (Hymenopterans) such as: Sirex juvencus, Urocerus gigas, Urocems gigas taignus, Urocems augur ° Termites such as: Kalofermes flavicollis, Cryptotermes brevis , Heterotermes indicola, Reticulitermes flavipe s), Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes -38-20 200800861 formosanus Fish 'Lepismasaccharina'. It is understood that the industrial raw materials referred to herein are inanimate materials such as plastics, adhesives, glues, paper and cardboard, leather, wood and wood products and coatings. The ready-to-use compositions may include other insecticides as appropriate, and if appropriate, one or more fungicides may be employed. • Other additives that are feasible are insecticides and fungicides as described above. The combination of active compounds according to the invention can also be used for the protection of articles in contact with salt water or water having a salt of 10, in particular: hulls, partitions, nets, buildings, moorings and signalling systems, to prevent shell algae Smudged. Furthermore, the active compound combinations according to the invention may be used alone or in combination with other active compounds as anti-sick plugs. The active compound button is also suitable for controlling animal pests in household, sanitary and protective stocks, especially insects, green spiders and worms, etc., which often appear in closed spaces, such as apartments, factories, Office, carriage, and more. It can be used alone or in combination with other active compounds and adjuvants which control such pests in household insecticide products. It is active against sensitive and resistant varieties and fights all stages of development. These pests include: 20 Scorpionidea, such as Buthus occitanus. Acarina ', for example: Argas persicus, Argas reflexus, Bryobia ssp·, Dermanyssus gallinae, poultry sweets ( Glyciphagus domesticus), Ornithodorus moubat, blood red head -39- 200800861 Rhipicephalus sanguineus, Trombula alfteddugesi, Neutrombicula autunmalis, Dermatophagoides Pteronissimus), Dermatophagoides forinae 〇5 Araneae, for example: Aviculariidae, Araneidae, Opiliones, for example: Pseudoscorpiones | chelifer), Pseudoscorpiones cheiridium, Opileones phalangium 〇ίο, etc., such as Oniseus asellus, Porcellio scaber (Diplopoda), for example: Blaniulus guttulatus, Polydesmus spp. ° Chilopoda, for example: Geophage (Geoph) Ilus spp·). 15 Zygentoma, for example: Ctenolepisma spp., West, Lepisma saccharina, Lepismodes inquilinus. Blattaria, for example: Blatt orientalis, Blattella germanica, Blattella asahinai, Leucophaea maderae, Cuban genus (Leucophaea maderae) Panchl〇ra spp·), Parcoblatta spp., periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, smoky (peripianeta fuiiginosa), Supella longipalpa. Jumping (Saltatoria) ‘ For example, Acheta domesticus. 200800861 Dermaptera, for example: Forficula auricularia. Isoptera, for example: wood termite genus (^^1(^〇1^3 8卩口.), Rheiulitermes spp.) Psocoptera, for example: Lepinatus genus, book Liposcelis spp. 〇

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顆翅目（Coleoptera)，例如：圓皮橐屬（Anthrenus spp·)、毛 皮蠹屬（Attagenus spp·)、皮蠹屬（Dermestes spp·)、長頭谷盜 (Latheticus oryzae)、郭工蟲屬（Necrobia spp·)、蛛曱屬（Ptinus spp·)、谷蠹（Rhizopertha dominica)、谷象（Sitophilus granaries)、米象（Sitophilus oryzae)、玉米象（Sitophilus 雙翅目（Diptera)，例如：埃及伊蚊(Aedes aegypti)、白紋伊 虫文（Aedes albopictus)、Aedes taeniorhynchus、按虫文屬 (Anopheles spp·)、紅頭麗蠅(Calliphora erythrocephala)、雨 麻 it (Chrysozona pluvialis)、致倦庫蚊（Culex quinquefasciatus)、尖音庫蚊(Culex pipiens)、附斑庫蚊(Culex tarsalis)、果繩屬（Drosophila spp·)、黃腹廄蝇（Fannia canicularis)、家繩(Musca domestica)、白蛉屬（Phlebotomus spp·)、食肉麻繩（Sarcophaga carnaria)、蚋屬（Simulium spp·)、廄绳屬（Stomoxys calcitrans)、沼澤大蚊（Tipula paludosa) o 鱗翅目（Lepidoptera)，例如：小躐填(Achroiagrisella)、大纖 模(Galleria mellonella)、印度谷模(Plodia interputictella)、木 塞谷蛾(Tinea cloacella)、網衣蛾(Tinea pellionella)、袋衣蛾 -41 - 20 200800861 (Tineola bisselliella) 〇 5From the order of the genus Coleoptera, for example, Anthrenus spp., Attagenus spp., Dermestes spp., Latheticus oryzae, and genus (Necrobia spp.), Ptinus spp., Rhizopertha dominica, Sitophilus granaries, Sitophilus oryzae, Sitophilus diptera, eg Egypt Aedes aegypti, Aedes albopictus, Aedes taeniorhynchus, Anopheles spp., Calliphora erythrocephala, Chrysozona pluvialis, Culex pipiens (Culex quinquefasciatus), Culex pipiens, Culex tarsalis, Drosophila spp., Fannia canicularis, Musca domestica, white peony Genus (Phlebotomus spp.), Sarcophaga carnaria, Simulium spp., Stomoxys calcitrans, Tipula paludosa o Lepidoptera, for example: small sputum filling (Achro Iagrisella), Galleria mellonella, Plodia interputictella, Tinea cloacella, Tinea pellionella, Coat Moth -41 - 20 200800861 (Tineola bisselliella) 〇 5

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蚤目（Siphonaptera)，例如：狗櫛頭蚤（Ctenocephalides canis)、猶櫛頭蚤（^^11〇〇6口1^1丨(165£61丨3)、人蚤（？11^\ irritans)、穿皮潛蚤(1\11^&卩61^1;^113)、東方鼠蚤(乂611〇03乂113 cheopis) 〇 膜翅目（Hymenoptera)，例如：木工蟻（Camponotus herculeanus)、黑草蟻(Lasius fuliginosus)、普通黑蟻(Lasius niger)、Lasius umbratus、小家蟻(Monomorium pharaonis)、 Paravespula 屬、草地蟻(Tetramorium caespitum) 〇 兹目（Anoplura)，例如：頭兹（Pediculus humanus capitis)、 體兹（Pediculus humanus corporis)、癭棉芽屬（Pemphigus spp·)、Phylloera vastratrix、陰兹(Phthirus pubis) 〇 異翅目（Heteroptera)，例如：熱帶臭蟲(Cimex hemipterus)、 溫帶臭蟲（Cimex lectularius)、Rhodnius prolixus、騷擾錐蝽 (Triatoma infestans) 〇 在家庭用殺昆蟲劑之領域中，其可單獨使用或組合其 他合適活性化合物使用，如··磷酸酯類、胺曱酸酯類、擬 除蟲菊酯類、類新於鹼類、生長調節劑或來自其他已知殺 昆蟲劑類之活性化合物。 其可呈氣霧劑、無壓力喷灑產品，例如：泵壓及霧化 喷灑器、自動喷霧系統、霧化器、發泡物、凝膠、使用由 纖維素或聚合物製成之蒸發片之蒸發器產品、液體蒸發 器、凝膠及膜式蒸發器、嫘漿驅動式蒸發器、無能源或被 動式蒸發系統、防蛾紙、防蛾袋及防蛾膠，呈粒狀或細粉， .42- 20 200800861 15 用於撒播式誘飼1或用於誘I耳台等形式使用。 根據本發明活性化合物組合之良好殺昆蟲與殺蜗活性 可由下列實例可見。雖然個別活性化合物展現較弱活性， 但其組合之活性則超過其作用之簡單總和。 *活性化σ物組合之活性超過該活性化合物單獨施用 時之活性總和時’則該活性化合物具有殺昆蟲與殺蟎之增 效效應。 胃 兩種活性化合物之指定組合所期望之活性 Colby’ Weeds 11_(1967)，15, 2〇-22 計算，如下： ·Κ. 若 為當使用活性化合物Α，採用施用率&克 ppm濃度時，相對於未處理對照組之死 、或 為當使用活性化合物B，採用施用率I克/八 ppm濃度時，相對於未處理對照組之死^率I頃或 為當使用活性化合物A與B，採用施用率饥1 公頃或0L與a ppm濃度時，相對於未處理^二11-克/ 死亡率％ 對照組之Siphonaptera, for example: Ctenocephalides canis, 栉 栉 蚤 (^^11〇〇6 口1^1丨(165£61丨3), human 蚤(?11^\ irritans) , wearing a skin squat (1\11^&卩61^1;^113), oriental squid (乂611〇03乂113 cheopis), Hymenoptera, for example: carpentry ant (Camponotus herculeanus), Black ants (Lasius fuliginosus), common black ants (Lasius niger), Lasius umbratus, Monomorium pharaonis, Paravespula genus, Tetramorium caespitum, Anoplura, for example: Pediculus humanus Capitis), Pediculus humanus corporis, Pemphigus spp., Phylloera vastratrix, Phthirus pubis, Heteroptera, for example, Cimex hemipterus, temperate bed bugs Cimex lectularius), Rhodnius prolixus, Triatoma infestans 〇 In the field of household insecticides, they can be used alone or in combination with other suitable active compounds, such as phosphates, amine phthalates, Pyrethroids An active compound derived from alkalis, growth regulators or from other known insecticides. It can be aerosolized, non-pressure sprayed products such as pumping and atomizing sprayers, automatic spray systems , atomizers, foams, gels, evaporator products using evaporation sheets made of cellulose or polymers, liquid evaporators, gel and membrane evaporators, slurry driven evaporators, no energy Or passive evaporation system, moth-proof paper, anti-moth bag and moth-proof glue, in granular or fine powder, .42-20 2010010061 15 For use in spread-type feeding 1 or for use in the form of lure I. The good insecticidal and bactericidal activity of the combination of active compounds of the invention can be seen from the following examples. Although individual active compounds exhibit weaker activity, the activity of the combination exceeds the simple sum of their effects. * The activity of the activated sigma combination exceeds this activity. The sum of the activities of the compounds when administered alone' then the active compound has the synergistic effect of insecticidal and acaricidal. The desired combination of the two active compounds of the stomach is expected to be active Colby' Weeds 11_(1967), 15, 2 -22 Calculated as follows: · Κ. If the active compound Α is used, the application rate & gram ppm concentration is used, relative to the untreated control group, or when the active compound B is used, the application rate is 1 g / At 8 ppm concentration, the death rate relative to the untreated control group is 1 when the active compounds A and B are used, and the application rate is 1 hectare or 0L and a ppm concentration, compared to the untreated ^2 11-gram. / Mortality % Control group

XX

YY

E 則 Ε - Χ+Υ- Χ-Υ 100 m η 若確實之殺昆蟲或殺蟎死亡率超過計算值時， 用為超加成性，亦即具有增效作用。此時，破杳^級合之作 亡率必定超過採用上列公式計算所期望之死亡率（5判之死 -43- 25 200800861 【實施方式】E Ε - Χ + Υ - Χ - Υ 100 m η If the actual killing insecticide or killing mortality exceeds the calculated value, it is used as superadditive, that is, synergistic. At this time, the death rate of the 杳 杳 级 必 必 must exceed the expected mortality rate calculated by the above formula (5 sentence death -43-25 200800861 [Embodiment]

實例A 棉坊(Aphis gossypii)試驗 溶劑：7份重量比二曱基甲醯胺 5 乳化劑：2份重量比烧芳基聚二醇醚 製備活性化合物之合適製劑時，由1份重量比活性化 | 合物與上述量溶劑及乳化劑混合，以含乳化劑之水稀釋該 濃縮物至所需濃度。 10 取受到棉財（Aphis gossypii)嚴重感染之棉花葉部 (Gossypium herbaceum)浸入所需濃度之活性化合物製劑中 處理。 ..... 經過一段所需時間後，測定死亡率％。100%表示所有 棉蚜均死亡；0%表示沒有棉蚜死亡。將所測得死亡率代入 15 柯比公式（見前文）。 > 此試驗中，根據本申請案之下列活性化合物組合相較 於單獨施用之活性化合物，展現增效性之加強活性：（Ib)+ 畢芬寧(bifenthrin)。 -44- 200800861Example A Aphis gossypii test solvent: 7 parts by weight of dimethylformamide 5 emulsifier: 2 parts by weight of the aryl polyglycol ether to prepare a suitable preparation of the active compound, from 1 part by weight activity The compound is mixed with the above amount of solvent and emulsifier, and the concentrate is diluted with water containing an emulsifier to a desired concentration. 10 Gossypium herbaceum, which is heavily infected with Aphis gossypii, is immersed in the active compound preparation at the desired concentration. ..... After a period of time, the % mortality is determined. 100% means that all cotton aphids die; 0% means no cotton aphid death. Substituting the measured mortality into the 15 Kirby formula (see above). > In this test, the following active compound combinations according to the present application exhibited potentiating potentiating activity compared to the active compound administered alone: (Ib) + bifenthrin. -44- 200800861

表A 傷害植物之昆蟲 棉財(Aphis gossypii)試驗 5 活性化合物 濃度ppm 6天德之死亡率％ (lb) 20 0 | 畢芬寧(bifenthrin) 0.8 0 10 根據本發明 (Ib)+ 畢芬寧(bifcnthrin)(25 : 1) 20+0.8 * found 85 **calc. 0 * found=實測活性 15 * * calc.=採用柯比公式計算之活性 -45- 200800861Table A Aphis gossypii test for insecticidal plants 5 Active compound concentration ppm 6 days mortality rate (lb) 20 0 | bifenthrin 0.8 0 10 According to the invention (Ib) + bifenthrin (bifcnthrin) 25 : 1) 20+0.8 * found 85 **calc. 0 * found=measured activity 15 * * calc.=activity calculated using the Kirby formula -45- 200800861

實例B 桃赤財(Myzus persicae)試驗 溶劑·· 7份重量比二曱基曱醯胺 乳化劑： 2份重量比烷芳基聚二醇醚 5 製備活性化合物之合適製劑時，由1份重量比活性化 合物與上述量溶劑及乳化劑混合，以含乳化劑之水稀釋^r | 濃縮物至所需濃度。 取受到桃赤蚜（Myzus persicae)嚴重感染之甘藍菜 ίο (Brassica oleracea)葉部浸入所需濃度之活性化合物製劑中 處理。 經過一段所需時間後，測定死亡率％。1〇〇%表示所有 桃赤蚜均死亡；0%表示沒有桃赤蚜死亡。將所測得死亡率 代入柯比公式（見前文）。 15 此試驗中，根據本申請案之下列活性化合物組合相較 _ 於單獨施用之活性化合物，展現增效性之加強活性：（Ib)+ 汰牙田 f (tefluthrin)，（Ι1))+γ-赛赫寧（gamma-Cyhai〇thdn) -46- 200800861Example B Myzus persicae test solvent · 7 parts by weight of decyl decylamine emulsifier: 2 parts by weight of alkylaryl polyglycol ether 5 When preparing a suitable preparation of the active compound, 1 part by weight The active compound is mixed with the above amount of the solvent and the emulsifier, and the concentrate is diluted with the emulsifier-containing water to the desired concentration. The leaves of Brassica oleracea, which is heavily infected with Myzus persicae, are immersed in a preparation of the active compound at the desired concentration. After a period of time required, the % mortality was determined. 1〇〇% means that all peach red mites die; 0% means no peach red mites die. Substituting the measured mortality into the Kirby formula (see above). 15 In this test, the following combination of active compounds according to the present application exhibits potentiating activity compared to the active compound administered alone: (Ib) + tefluthrin, (Ι1)) + γ - gamma-Cyhai〇thdn -46- 200800861

表B 傷害植物之昆蟲 桃赤均^Myzus persicae)試驗 15 活性化合物 濃度ppm 1天後之死亡率％ (lb) 100 10 汰福寧(tefluthrin) 4 5 根據本發明 (Ib)+汰福寧(tefluthrin)(25 : 1) 100+4 * found 55 **calc. 14 (lb) 100 25 γ-赛赫寧(ga m ma-cy halottirin) 0.8 0 根據本發明 (Ib)+y-赛赫寧(gamma-cyhalothrin)(125 : 1) 100+0.8 * found 60 **calc. 25 * found=實測活性 ** calc.=採用柯比公式計算之活性 -47- 20 200800861 實例c 猿葉蟲(Phaedon cochleariae)幼蟲試驗 溶劑：7份重量比二曱基甲醯胺 乳化劑： 2份重量比烷芳基聚二醇醚 5 製備活性化合物之合適製劑時，由1份重量比活性化 合物與上述量溶劑及乳化劑混合，以含乳化劑之水稀釋該 > 濃縮物至所需濃度。 取甘藍菜(Brassica oleracea)葉部浸入所需濃度之活性 1〇 化合物製劑中，然後趁葉部仍濕時，接種猿葉蟲(Phaedon cochleariae)幼蟲。 經過一段所需時間後，測定死亡率％。100%表示所有 幼蟲均死亡；0%表示沒有幼蟲死亡。將所測得死亡率代入 柯比公式（見前文）。 15 此試驗中，根據本申請案之下列活性化合物組合相較 > 於單獨施用之活性化合物’展現增效性之加強活性：（Ib)+ 阿納寧(acrinathrin)，（Ib)+第滅寧(deltamethrin)，（Π))+γ-賽 赫寧（gamma-cyhalothrin) -48- 200800861 表c 傷害植物之昆蟲 猿葉蟲(Phaedon cocWeariae)幼蟲試驗 5 活性化合物 濃廑ppm -之界十銮〇入 (lb) 4 45 • 阿納寧(acrinathrin) 4 10 10 根據本發明 (Ib)+ 阿納寧(acrinathrin)(l : 1) 4+4 *found 70 **calc· 50.5 15 第滅寧(deltamethrin) 0.032 0 根據本發明 (Ib)+第滅寧(deltamethrin)(125 : 1) 4+0.032 * found 65 **calc. 45 20 Y-赛赫寧(gamma-cyhalothrin) 0.032 15 25 根據本發明 (11>)+γ·赛赫寧(gamma-cyhalothriii)(125 : 1) 4+0.032 * found 95 **calc. 53.25 found=實測活性 ** calc.=採用柯比公式計算之活性 -49- 200800861Table B Insects of Injured Plants Peach Redness ^Myzus persicae) Test 15 Active Compound Concentration ppm Death Rate after 1 Day (lb) 100 10 tefluthrin 4 5 According to the invention (Ib) + Tawnin ( Tefluthrin)(25 : 1) 100+4 * found 55 **calc. 14 (lb) 100 25 γ-赛赫宁(ga m ma-cy halottirin) 0.8 0 According to the invention (Ib)+y-cyhnin (gamma-cyhalothrin) (125 : 1) 100+0.8 * found 60 **calc. 25 * found = measured activity ** calc. = activity calculated using the Kirby formula - 47-20 2000 0086 Example c Leafhopper (Phaedon Cochleariae) larva test solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of alkylaryl polyglycol ether 5 When preparing a suitable preparation of the active compound, 1 part by weight of the active compound and the above amount of solvent The emulsifier is mixed and the > concentrate is diluted to the desired concentration with water containing an emulsifier. The leaves of Brassica oleracea were immersed in the desired concentration of the compound. The larvae of the Phaedon cochleariae were inoculated while the leaves were still wet. After a period of time required, the % mortality was determined. 100% means that all larvae die; 0% means no larvae die. Substituting the measured mortality into the Kirby formula (see above). 15 In this test, the following combinations of active compounds according to the present application show synergistic enhancing activity compared to > active compound administered alone: (Ib) + arrinathrin, (Ib) + difenin (deltamethrin), (Π)) + gamma-cyhalothrin -48- 200800861 Table c Phaedon coc Weariae larvae test for harmful plants 5 Active compound concentration - - The top ten (lb) 4 45 • arrinathrin 4 10 10 according to the invention (Ib) + aninin (acrinathrin) (l: 1) 4+4 *found 70 **calc· 50.5 15 detamethrin 0.032 0 according to the invention (Ib) + deltamethrin (125 : 1) 4 + 0.032 * found 65 ** calc. 45 20 Y- singering (gamma-cyhalothrin) 0.032 15 25 according to the invention (11 &gt ;)+γ·赛赫宁(gamma-cyhalothriii)(125 : 1) 4+0.032 * found 95 **calc. 53.25 found=measured activity** calc.=activity calculated using the Kirby formula-49- 200800861

實例D 小菜蛾(Plutella xylostella)試驗(敏感性品種) 溶劑：7份重量比二甲基甲醯胺 乳化劑：2份重量比烷芳基聚二醇醚 製備活性化合物之合適製劑時，由1份 合物與上述量溶劑及乳化劑混合，以含乳化劑 tb冷性化 濃縮物至所需濃度。 t稀释讀 取甘藍菜(Brassica oleracea)葉部浸入所需丨農 10 15Example D Plutella xylostella test (sensitive species) Solvent: 7 parts by weight of dimethylformamide emulsifier: 2 parts by weight of alkaryl polyglycol ether to prepare a suitable preparation of the active compound, by 1 The composition is mixed with the above amount of solvent and emulsifier to contain the emulsifier tb to cool the concentrate to the desired concentration. tDiluted reading Brassica oleracea leaf immersion required tenant 10 15

化合物製劑中，然後趁葉部仍濕時，接種小菜性 xylostella)幼蟲。 經過一段所需時間後’測定死亡率％。100%表示所有 幼蟲均死亡，0%表示沒有幼蟲死亡。將所測得死亡率代入 柯比公式（見前文）。 此試驗中，根據本申請案之下列活性化合物組合相較 於單獨施用之活性化合物，展現增效性之加強活性··（Ib)+ 亞滅寧（alpha-cypermethrin)。 -50 - 200800861In the compound preparation, the larvae of the xylostella) were inoculated when the loquat leaves were still wet. After a period of time required, the % mortality was determined. 100% means that all larvae die, and 0% means that no larvae die. Substituting the measured mortality into the Kirby formula (see above). In this test, the following combination of active compounds according to the present application exhibits synergistic potentiating activity (Ib) + alpha-cypermethrin compared to the active compound administered alone. -50 - 200800861

表D 傷害植物之昆蟲 小菜蛾(Plutella xylostella)試驗(敏感性品種) 5 活性化合物 (lb) 濃唐 ppm 0.00128 0Table D Insects that harm plants Plutella xylostella test (sensitive species) 5 Active compound (lb) Thick Tang ppm 0.00128 0

亞滅寧(alpha-cypermethrin) 0.0064 0 10 根據本發明 * found **calc· 35 0 (Ib)+亞滅寧(alpha-cypermethrin)(l : 5) 0.00128+0.0064 15Alpha-cypermethrin 0.0064 0 10 According to the invention * found **calc· 35 0 (Ib) + alpha-cypermethrin (l : 5) 0.00128 + 0.0064 15

* found=實測活性 ** calc.=採用柯比公式計算之活性 -51- 200800861* found=actual activity ** calc.=activity calculated using the Kirby formula -51- 200800861

實例E 小菜蛾(Plutella xylostella)試驗(抗性品種) 溶劑：7份重量比二甲基曱醯胺 乳化劑：2份重量比烷芳基聚二醇醚 5 製備活性化合物之合適製劑時，由1份重量比活性化 合物與上述量溶劑及乳化劑混合，以含乳化劑之水稀釋該 t 濃縮物至所需濃度。 取甘藍菜(Brassica oleracea)葉部浸入所需濃度之活性 ίο 化合物製劑中，然後趁葉部仍濕時，接種小菜蛾(piutella xylostella)幼蟲。 經過一段所需時間後，測定死亡率％。100%表示所有 幼蟲均死亡；0%表示沒有幼蟲死亡。將所測得死亡率代入 柯比公式（見前文）。 15 此試驗中，根據本申請案之下列活性化合物組合相較 I 於單獨施用之活性化合物，展現增效性之加強活性：（Ib)+P- 賽扶寧(beta-cyfluthrin)，（Ib)+賽滅寧(cypermethrin)。 -52- 200800861Example E Plutella xylostella test (resistance variety) Solvent: 7 parts by weight dimethyl decylamine emulsifier: 2 parts by weight of alkylaryl polyglycol ether 5 When preparing a suitable preparation of the active compound, One part by weight of the active compound is mixed with the above amount of solvent and emulsifier, and the t concentrate is diluted with the emulsifier-containing water to the desired concentration. The leaves of Brassica oleracea were inoculated into the desired concentration of the compound, and then the larvae of Piutella xylostella were inoculated when the leaves were still wet. After a period of time required, the % mortality was determined. 100% means that all larvae die; 0% means no larvae die. Substituting the measured mortality into the Kirby formula (see above). 15 In this test, the following combination of active compounds according to the present application exhibits potentiating activity compared to the active compound administered alone: (Ib) + P-beta-cyfluthrin, (Ib) + cypermethrin. -52- 200800861

表E 傷害植物之昆蟲 小菜蛾(阶她切⑽她)試翁(抗性品種） 活性化合物 濃度ppm (lb) 0.032 0.0064Table E Insects that harm plants Plutella xylostella (the order she cut (10) her) test (resistant varieties) active compound concentration ppm (lb) 0.032 0.0064

-------- 0.0064 β_ 赛扶寧(beta-cyfluthrin) 根據本發明 (Ib)+p·赛扶寧(beta-cyfluthrin)(l : 1) 0.0064+0.0064 氺 found **calc. 50 〇 15 賽滅寧(cypermethrin) 0.8 0 根據本發明 (Ib)+赛滅寧(cypermethrin)(l : 25) *found 1calc. 0.032+0.8 95 80 20 -53- 1 * 2 calc.=採用柯比公式計算之活性 2 found=實測活性 200800861-------- 0.0064 β_ 赛保宁 (beta-cyfluthrin) According to the invention (Ib) + p · 赛芙宁 (beta-cyfluthrin) (l : 1) 0.0064 + 0.0064 氺found **calc. 50 〇15 cypermethrin 0.8 0 according to the invention (Ib) + cypermethrin (l: 25) *found 1calc. 0.032+0.8 95 80 20 -53- 1 * 2 calc.= using Kirby Formula calculated activity 2 found=measured activity 200800861

實例F 草地黏蟲(Spodoptera frugiperda)試驗 溶劑：7份重量比二甲基甲酿胺 乳化劑·· 2份重量比烷芳基聚二醇醚 5 製備活性化合物之合適製劑時，由1份重量比活性化 合物與上述量溶劑及乳化劑混合，以含乳化劑之水稀釋該 | 濃縮物至所需濃度。 取甘藍菜(Brassica oleracea)葉部浸入所需濃度之活性 ίο 化合物製劑中，然後趁葉部仍濕時，接種草地黏蟲 (Spodopterafrugiperda)幼蟲。 經過一段所需時間後，測定死亡率％。100%表示所有 幼蟲均死亡，0%表不沒有幼蟲死亡。將所測得死亡率代入 柯比公式（見前文）。 15 此試驗中’根據本申請案之下列活性化合物組合相較 | 於單獨施用之活性化合物，展現增效性之加強活性··（Ib)+ 亞滅寧(alpha-cypermethrin)，（Ib)+赛滅寧(cypermethrin)， (Π))+λ_ 賽赫寧（lambda-cyhalothrin) ，（Ib)+ 汰福寧 (tefluthrin) 〇 -54- 200800861Example F Spodoptera frugiperda test solvent: 7 parts by weight of dimethyl ammine amine emulsifier · 2 parts by weight of alkylaryl polyglycol ether 5 When preparing a suitable preparation of the active compound, 1 part by weight The active compound is mixed with the above amount of solvent and emulsifier, and the concentrate is diluted to the desired concentration with water containing an emulsifier. The leaves of Brassica oleracea are immersed in the desired concentration of the compound ίο compound preparation, and then the larvae of the grass worm (Spodopterafrugiperda) are inoculated. After a period of time required, the % mortality was determined. 100% means that all larvae die, and 0% does not show larval death. Substituting the measured mortality into the Kirby formula (see above). 15 In this test, the following combinations of active compounds according to the present application show synergistic potentiating activity compared to the active compound administered alone (Ib) + alpha-cypermethrin, (Ib)+ Cypermethrin, (Π))+λ_ lambda-cyhalothrin, (Ib)+ tefluthrin 〇-54- 200800861

表F(第1頁） 傷害植物之昆蟲 草地黏蟲(Spodoptera frugiperda)試驗 5 10 15 活性化合物 ____ (lb) 濃度pgm_ 0.16 0.032 4天後 1死亡率％ 80 5 亞滅寧(alpha-cypermethrin) 0.8 20 根據本發明 (Ib)+亞滅寧(alpha-cypermethrin)(l :5) 0.16+0.8 * found 1calc. 95 84 赛滅寧(cypermethrin) 0.8 45 根據本發明 (Ib)+赛滅寧(cypermethrin)(l : 5) 0.032+0.8 * found 65 **calc. 47.75 found=實測活性 -55- 20 1 calc.=採用柯比公式計算之活性 200800861 表F(第2頁） 傷害植物之昆蟲 草地黏蟲(Spodoptera frugiperda)試驗 5 活性化合物 _濃度_£鹏_g後^死亡率％ (lb) 0.032 35 > λ-赛赫寧(lambda-cyhalothrin) 0.16 10 10 根據本發明 (11>)+λ·赛赫寧(lambda-cyhalothrin)(l •5) 0.032+0.16 * found 60 **calc· 41.5 汰福寧(tefluthrin) 15 0.8 0 > 根據本發明 (Ib)+汰福寧(tefluthrin)(l : 25) 0.032+0.8 . * found 60 **calc· 35 20 * &肋#實測活性 ** calc.=採用柯比公式計算之活性 -56-Table F (Page 1) Spodoptera frugiperda test for injury plants 5 10 15 Active compound ____ (lb) Concentration pgm_ 0.16 0.032 4 days later 1 Mortality % 80 5 Alpha-cypermethrin 0.8 20 according to the invention (Ib) + alpha-cypermethrin (l: 5) 0.16 + 0.8 * found 1calc. 95 84 cypermethrin 0.8 45 according to the invention (Ib) + 赛宁宁 ( Cypermethrin)(l : 5) 0.032+0.8 * found 65 **calc. 47.75 found=measured activity-55- 20 1 calc.=activity calculated using the Kirby formula 200800861 Table F (page 2) Insect grass that damages plants S. sylvestris (Spodoptera frugiperda) test 5 active compound _ concentration _ _ _ _ post ^ mortality % (lb) 0.032 35 > λ-赛赫宁 (lambda-cyhalothrin) 0.16 10 10 according to the invention (11 >) + λ········································································································ (l : 25) 0.032+0.8 . * found 60 **calc· 35 20 * & rib # measured activity ** calc. = activity calculated using the Kirby formula -56-

Claims (1)

200800861 申請專利範圍： 1·多種組成物，其包含至少一種式(I)活性化合物200800861 Patent application scope: 1. A plurality of compositions comprising at least one active compound of formula (I) 55 其中 Hal代表氯、溴或碘，及 * 代表呈R-或S-組態之碳原子， 與至少一種選自下列各物所組成群中之活性化合物： 阿納 I (acrinathrin)、亞滅寧（aipha-Cypermethrin)、β_ 賽扶寧（beta-cyfluthrin) 、 r _ 賽赫寧 (gamma-cyhalothrin)、賽滅寧（Cypermethrin)、第滅寧 (deltamethrin)、益化利（esfenvalerate)、依芬寧 (ethofenprox)、芬普寧（€6叩1>(^31;11411)、芬化利 (fenvalerate)、護賽寧（flucythrinate)、λ-赛赫寧 (lambda-cyhalothdn)、百滅寧（permethrin)、特福化利 (taufluvalinate)、泰滅寧（tralomethrin)、ζ-賽滅寧 (zeta-cypermethrin)、赛扶寧（cyfluthrin)、畢芬寧 (bifentlirin)、乙氰菊酯（〇^1(^1〇也1111)、抑伏辛 (eflusilanate)、伏本斯（fubfenprox)、除蟲菊酯 (pyrethrin)、利滅寧(resmethrin)與汰福寧（tefhithrin)。 根據申請專利範圍第1項之組成物，其包含 -57- 2· 200800861 阿納寧（acrinathrin)、亞滅寧（alpha-cypermethrin)、β_ 賽扶寧（beta-cyfluthrin) 、 γ-赛赫寧 (gamma-cyhalothrin)、赛滅寧（cypermethrin)、第滅寧 (deltamethrin)、λ-賽赫寧（lambda-cyhalothrin)、ζ·赛滅 寧（zeta-cypermethrin)、賽扶寧（cyfhithrin)、畢芬寧 (bifenthrin)、汰福寧（tefluthrin)。 3·根據申請專利範圍第1項之組成物，其包含式(I-b): ⑻冬氯-N1]2-曱基冬[1，2,2,2·四氟小(三氟甲基）乙基] 本基}-N -(1-曱基-2-甲基石黃酿基乙基)g太酿胺。Wherein Hal represents chlorine, bromine or iodine, and * represents a carbon atom in the R- or S-configuration, and at least one active compound selected from the group consisting of: arrinathrin, arsenin ( aipha-Cypermethrin), β_cyfluthrin, r _ gamma-cyhalothrin, Cypermethrin, deltamethrin, esfenvalerate, efenin (ethofenprox), Fenpnin (€6叩1>(^31;11411), fenvalerate, flucythrinate, lambda-cyhalothdn, permethrin , taufluvalinate, tralmethrin, zeta-cypermethrin, cyfluthrin, bifentlirin, fenpropathrin (〇^1(^1) 〇1111), eflusilanate, fubfenprox, pyrethrin, resmethrin and tefhithrin. Composition according to item 1 of the scope of application Included -57- 2· 200800861 arrinathrin, alpha-cypermethrin Β_cyfluthrin, gamma-cyhalothrin, cypermethrin, deltamethrin, lambda-cyhalothrin, ζ·赛灭(zeta-cypermethrin), cyfhithrin, bifenthrin, and tefluthrin 3. The composition according to item 1 of the patent application, which comprises formula (Ib): (8) winter chlorine- N1]2-fluorenyl winter [1,2,2,2·tetrafluorosuccinyl (trifluoromethyl)ethyl] benzyl}-N-(1-mercapto-2-methyl stellate ethyl )g too brewed amine. 15 4·根據申請專利範圍第3項之組成物，其包含選自下列 ⑩ 各物所組成群中之擬除蟲菊醋：阿納寧(acrinathrin)、 亞滅寧（alpha-cypermethrin) 、 β·赛扶寧 (beta-cyfluthrin)、γ-赛赫寧（gamma-cyhalothrin)、賽滅 寧（cypermethrin)、第滅寧（deltamethrin)、λ-賽赫寧 20 (lambda-cyhalothrin)、ζ-賽滅寧（zeta，cypermethrin)、賽 扶寧（cyfluthrin)、畢芬寧（bifenthrin)、汰福寧 (tefluthrin) 〇 5· —種以根據申請專利範圍第1至4項中任一項所定義 之混合物於控制動物害蟲上之用途。 -58- 200800861 6. 一種以根據申請專利$1圍第1至4項中-項或多項之 組成物於處理種子上之用途。 、 一種以根據申請專利範圍第1至4項中-項或多項之 組成物於處理轉殖基因植物之種子上之用途。15 4. The composition according to item 3 of the patent application, comprising pyrethrum vinegar selected from the group consisting of: acrinathrin, alpha-cypermethrin, β· Beta-cyfluthrin, gamma-cyhalothrin, cypermethrin, deltamethrin, lambda-cyhalothrin, ζ-赛灭Ze (zeta, cypermethrin), cyfluthrin, bifenthrin, tefluthrin 〇5· a species controlled by a mixture as defined in any one of claims 1 to 4 Use on animal pests. -58- 200800861 6. A use of a composition according to paragraphs 1 to 4 of the application for a patent of $1 for the treatment of seeds. A use for the treatment of a seed of a transgenic plant with a composition according to the item or items 1 to 4 of the scope of the patent application. 8. 9· 10. 一種以根據申請專利範圍第1至4項中一項或多項之 組成物於處理轉殖基因植物上之用途、。 一種以根據申請專利範圍第1至4項中一項或多項之 10 組成物處理之種子。 一種控制動物害蟲之方法，其特徵在於使根據申請專 =第1至4項中任一項所定義之混合物作用在動 物害蛾及/或其棲息地。 11. 一種製備殺昆蟲及/或殺蟎組成物之方法，其特徵在、 混合根據申請專利範圍第i至4項中任一項所^於 混合物與補充劑及/或界面活性劑。 又、之8. 9· 10. Use of a composition according to one or more of items 1 to 4 of the scope of the patent application for the treatment of a transgenic plant. A seed treated with a composition according to one or more of items 1 to 4 of the scope of the patent application. A method of controlling animal pests, characterized in that a mixture as defined in any one of claims 1 to 4 is applied to animal moths and/or their habitat. A method of preparing an insecticidal and/or acaricidal composition, characterized by mixing and mixing a mixture with a supplement and/or a surfactant according to any one of items 1-4 to 4 of the patent application. Again -59- 200800861 七、指定代表圖： (一） 本案指定代表圖為：第（無）圖。 (二) 本代表圖之元件代表符號簡單說明： 無 _ 八、本案若有化學式時，請揭示最能顯示發明特徵的化學式:-59- 200800861 VII. Designated representative map: (1) The representative representative of the case is: (No). (2) A brief description of the symbol of the symbol of the representative figure: None _ VIII. If there is a chemical formula in this case, please disclose the chemical formula that best shows the characteristics of the invention: h3cH3c
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