JP7433244B2 - Mixtures containing benzpyrimoxane and oxazosulfil and methods of use and application thereof - Google Patents

Description

The present invention relates to pesticidal mixtures of benzpyrimoxane and oxazosulfil, and methods of applying such mixtures.

There is a need for effective and safe pesticides and pesticide mixtures, particularly in agriculture and particularly against invertebrate pests of rice. It has been found that these objectives can be achieved by a pesticide mixture containing the pesticides benzpyrimoxane and oxazosulfil.

In a first aspect, the invention relates to a pesticide mixture (mixture according to the invention) comprising benzpyrimoxane and the pesticide oxazosulfur.

Benzpyrimoxane and oxazosulfyl are also referred to as compounds I and/or compounds II of the mixture according to the invention and also as compounds of the invention. It is not important whether the compound is called Compound I or Compound II, since the order of the mixing partners in the name of the mixture is not important.

Benzpyrimoxane and some of its mixtures are described in WO2016104516.

Oxazosulfyl is described, for example, in WO2017104592, and some of its mixtures are described in WO2016002595.

One typical problem that arises in the field of pest control is to reduce the dose rate of active ingredients in order to reduce or avoid undesirable environmental or toxicological effects, while still maintaining effective pest control. There is a need to still be able to control pests. Another problem encountered relates to the need to have available pest control agents that are effective against a wide range of pests.

There also exists a need for pest control agents that have both knockdown activity and sustained control (ie, immediate action and sustained action).

Another difficulty with the use of pesticides is that the repeated and exclusive application of individual pesticide compounds often destroys pests that have developed natural or adaptive resistance to the active compound. It is to bring about rapid selection. Therefore, there is a need for pest control agents that help prevent or overcome resistance.

Furthermore, there is a need for pesticidal compounds or combinations of compounds that, when applied, can improve plants and result in "plant health", "vitality of plant propagation material" or "increased plant yield".

Therefore, the purpose of the present invention is to solve the problems discussed below:
- reduction in dose rate;
- Enhancement of activity spectrum;
- Combines knockdown activity and sustained control;
- Improved resistance management;
- Improving plant health;
- Improving the vigor of plant propagation material (also called seed vigor);
- To provide a combination of pesticides that solve one or more of the problems of increasing plant yield.

The aim of the present invention was therefore to provide a pesticidal mixture that solves at least one of the problems discussed above.

It has been found that this object is partly or wholly achieved by the combination of active compounds defined herein.

Furthermore, the present invention provides:
- a composition comprising a pesticidal mixture as defined herein and at least one inert liquid and/or solid acceptable carrier;
- a pesticide composition comprising a pesticidal mixture as defined herein and at least one inert liquid and/or solid acceptable carrier;
- A method for controlling or exterminating an invertebrate pest, comprising: said pest or its food supply, habitat, breeding ground; and a pesticidal effective amount of a pesticidal mixture as defined herein; a method comprising contacting with;
- A method of protecting plants from attack or infestation by invertebrate pests, comprising: a plant, plant propagation material, or the soil or water in which the plant is grown; and a pesticidal effective amount of the plant; a method comprising contacting with a pesticidal mixture as defined in;
- plant propagation material comprising a pesticidal mixture as defined herein in an amount of 0.1 g to 10 kg per 100 kg of seeds;
- a method for protecting plant propagation material, comprising contacting the plant propagation material with a pesticidal mixture as defined herein in an amount of 0.1 g to 10 kg per 100 kg of plant propagation material; Method;
- the use of a pesticidal mixture as defined herein for the protection of growing plants or plant propagation material from attack or damage by invertebrate pests;
- A method for controlling phytopathogenic harmful fungi, in which the fungi, their habitat, or the plants, soil or seeds to be protected from fungal attack contain a compound I and at least one specific compound B a method, wherein the method is treated with an effective amount of a pesticidal mixture comprising;
- A method for the protection of plants from phytopathogenic harmful fungi, in which the fungi, their habitat, or the plants, soil or seeds to be protected from fungal attack contain a compound I and at least one specific a method, wherein the method is treated with an effective amount of a pesticidal mixture comprising compound B;
- a method for protecting an animal from infestation or infection by a parasite, comprising administering to the animal a parasitically effective amount of a pesticidal mixture as defined herein;
- A method for treating an animal infested with or infected with a parasite, the method comprising applying a parasiticide-effective amount of a pesticidal mixture as defined herein to the animal in need of treatment. a method comprising administering; and
- Concerning the use of a pesticidal mixture as defined herein for combating parasites in and on animals.

In a particular embodiment, the invention relates to the use of a mixture according to the invention for killing or controlling rice pest invertebrates, respectively by applying such a mixture. Concerning methods of pest control.

Rice (Oryza species, especially Oryza sativa) is an important basic food in the world. It is a staple food in Asia and an important part of many cultures. Therefore, rice is an important crop and is cultivated in a wide area, especially in Asia.

Invertebrate pests, particularly insects, arthropods and nematodes, cause significant damage to growing and harvested rice crops, thereby causing significant economic losses to food supplies and property. Although a large number of pesticides are known, target pests can develop resistance to the drugs, so new drugs are needed to control invertebrate pests such as insects, arachnids and nematodes. continues to be needed. Rice cultivation also requires special pesticides that are suitable for use in farming methods used for rice, such as nursery boxes, rice paddies, aquatic environments, etc. Pesticides suitable for use on rice must also be well tolerated by the rice plant. The pesticide must also be well tolerated by the environment of the rice plant, for example from an ecotoxicological point of view, ie the pesticide must not harm beneficial organisms. Additionally, the pesticide must withstand the conditions to which it is applied to ensure effectiveness. This is a particular challenge in aquatic environments and the hot climatic conditions in which rice typically grows. On the other hand, pesticides must degrade within a reasonable period of time so as not to have a negative impact on the environment. Pesticides must not affect the health of farmers and consumers. Pesticides must not subsequently be present in rice products (low or no residue) to ensure the safety of humans consuming the rice. Furthermore, many pests have developed resistance to pesticides commonly used in rice. Therefore, pesticides suitable for use on rice should be effective against pests that have acquired resistance to other pesticides. Not all pesticides meet the requirements for use in these conditions.

It is therefore an object of the present invention to have good pesticidal activity and to be effective against a large number of different invertebrate pests occurring on rice, in particular insects, arachnids and nematodes which are difficult to control. The object is to provide compounds that exhibit a spectrum of activity and at the same time also a good regulatory profile.

In a further embodiment of the invention, the invention relates to mixtures according to the invention, in which benzpyrimoxane and oxazosulfyl are the only active ingredients (binary mixture). However, they may contain further ingredients such as carriers, adjuvants, auxiliaries and other formulation ingredients.

As mentioned above, the mixture according to the invention is particularly suitable for rice.

In one embodiment of the invention, the invention relates to a particular method and use of the mixture according to the invention in rice:
- a mixture according to the invention for use in the control of rice pests (in particular rice pest invertebrates) in rice;
- a composition comprising a mixture according to the invention for use in the control of rice pests (in particular rice pest invertebrates) in rice;
- A method for combating rice pest invertebrates, infestation or infection by rice pest invertebrates, the method comprising: applying a pesticidal effective amount of the above to said pest or its food source, habitat or breeding site; A method as described above, comprising contacting a mixture according to the invention or a composition thereof as defined in
- A method for controlling rice pest invertebrates, infestation or infection by invertebrate pests, the present invention comprising applying a pesticidal effective amount to said pests or their food sources, habitats or breeding grounds. or a composition comprising a mixture according to the invention;
- a method for preventing or protecting against invertebrate pests of rice, wherein the invertebrates or their food source, habitat or breeding site are treated with a mixture according to the invention as defined above; or a composition comprising a mixture according to the invention as defined above, or a composition comprising a mixture according to the invention;
- A method for protecting rice, rice plants, rice plant propagation material and/or growing rice plants from attack or damage by rice harmful invertebrates, the method comprising: A growing rice plant, or the soil, material, surface, space, area or water in which rice, rice plants, rice plant propagation material is stored or in which rice plants are grown, is treated with a pesticidal effective amount of A method as defined above, comprising contacting with or treating with a mixture according to the invention or a composition comprising a mixture according to the invention as defined above;
- a method for increasing the health of rice plants, especially in rice fields, comprising treatment with a mixture according to the invention;
- A method for increasing the yield of rice plants, comprising treatment with a mixture according to the invention.
- rice seeds containing the mixture according to the invention as defined above in an amount of 0.1 g to 10 kg per 100 kg of seeds;
- Use of the mixture according to the invention as defined above for the protection of growing rice plants or rice plant propagation material from attack or damage by rice pest invertebrates.

All of the compounds of the mixtures of the invention (including, where applicable, their stereoisomers, their tautomers, their salts or their N-oxides), as well as their compositions, are harmful to invertebrates. It is particularly useful for controlling organisms, especially arthropods and nematodes, especially insects. The present invention therefore relates to the use of the compounds disclosed in the present invention for combating or controlling invertebrate pests, in particular of the group of insects, arachnids or nematodes.

The term "composition(s) according to the invention" or "composition(s) according to the invention" refers to composition(s) comprising a mixture according to the invention as defined above. and thus also stereoisomers, agriculturally or veterinarily acceptable salts, tautomers or N-oxides of each compound.

Furthermore, the simultaneous, joint or separate application of benzpyrimoxane and oxazosulfil, or the sequential application of benzpyrimoxane and oxazosulfil, compared to the control rates possible with the individual compounds. , has also been found to allow enhanced control of pests.

The mixture of the present invention may be a physical mixture of benzpyrimoxane and oxazosulfur. Accordingly, the present invention also provides a mixture benzpyrimoxane and oxazosulfur. However, the composition may be any combination of benzpyrimoxane and oxazosulfil, and there is no need for benzpyrimoxane and oxazosulfil to be present together in the same formulation.

An example of a composition according to the invention or a composition used according to the invention in which benzpyrimoxane and oxazosulfil are not present together in the same formulation is a combipack. In a combi-pack, two or more components of the combi-pack are packaged separately, i.e. not pre-blended together. Thus, a combipack comprises one or more separate containers, such as vials, cans, bottles, pouches, bags or canisters, each container containing separate ingredients for the agrochemical composition. An example is a two-component combination pack. The invention therefore also provides a first component comprising in order a compound I, a liquid or solid carrier and, if appropriate, at least one surfactant and/or at least one customary auxiliary; It relates to a two-component combination pack comprising a compound II, a liquid or solid carrier and, if appropriate, a second component which in turn comprises at least one surfactant and/or at least one customary auxiliary. For example, further details regarding suitable liquid and solid carriers, surfactants and customary auxiliaries are described below.

The "combination" use of benzpyrimoxane "in combination" with oxazosulfil can on the one hand be understood as using a physical mixture of benzpyrimoxane and oxazosulfil. . On the other hand, a combination use may also consist of using benzpyrimoxane and oxazosulfil separately but within a sufficiently short time of each other so that the desired effect can occur. A more detailed description of the combination use can be found herein below.

As used herein, the term "invertebrate pest" (also referred to as animal pest) refers to insects, arachnids, and nematodes that attack plants and thereby cause substantial damage to the attacked plants. ectoparasites that infect animal populations, as well as animals, especially warm-blooded animals such as mammals or birds, or other higher animals such as reptiles, amphibians or fish, thereby causing substantial damage to the parasitized animals. include.

Pests The mixtures of the invention are particularly suitable for efficiently combating animal pests, such as arthropods, gastropods, and nematodes, such as, but not limited to:

Insects from the order of Lepidoptera, such as Achroia grisella, Acleris spp., such as A. fimbriana, A. globellana (A. gloverana), A. variana; Acrolepiopsis assectella, Acronicta major, Adoxophyes spp., e.g. A. cyrtosema, A. orana; Aedia leucomelas, Agrotis spp., e.g. A. exclamationis, A. fucosa (A. fucosa), A. ipsilon, A. orthogoma, A. segetum, A. subterranea; Alabama argillacea, Aleurodicus dispersus,Alsophila pometaria,Ampelophaga rubiginosa,Amyelois transitella,Anacampsis sarcitella,Anagasta kuehniella,Anarsia Anarsia lineatella, Anisota senatoria, Antheraea pernyi, Anticarsia (=Thermesia) spp., e.g. A. gemmatalis ); Apamea spp., Aproaerema modicella, Archips spp., such as A. argyrospila, A. fuscocopleanus. fuscocupreanus), A. rosana, A. xyloseanus; Argyresthia conjugella, Argyroploce spp., Argyrotaenia spp. , for example, A. velutinana; Athetis mindara, Austroasca viridigrisea, Autographa gamma, Autographa nigrisigna, Balasula brassicae. (Barathra brassicae), Bedellia spp., Bonagota salubricola, Borbo cinnara, Bucculatrix thurberiella, Bupalus piniarius,

Busseola spp., Cacoecia spp., such as C. murinana, C. podana; Cactoblastis cactorum, Cadra spp. Cadra cautella, Calingo braziliensis, Caloptilis theivora, Capua reticulana, Carposina spp., e.g. C. niponensis (C. niponensis), C. sasakii; Cephus spp., Chaetocnema aridula, Cheimatobia brumata, Chilo spp., e.g. C. Indicus, C. suppressalis, C. partellus; Choreutis pariana, Choristoneura spp., e.g. C. conflictana, C. fumiferana, C. longicellana, C. murinana, C. occidentalis, C. rosaceana rosaceana); species of the genus Chrysodeixis (=Pseudoplusia) spp., such as C. eriosoma, C. includens; Cirphis unipuncta , Clysia ambiguella, Cnaphalocerus spp., Cnaphalocrocis medinalis, Cnephasia spp., Cochylis hospes, Coleophora spp. species (Coleophora spp.), Colias eurytheme, Conopomorpha spp., Conotrachelus spp., Copitarsia spp., Corsilla cephalonica ( Corcyra cephalonica), Crambus caliginosellus, Crambus teterrellus, Crocidosema (=Epinotia) aporema, Cydalima (=Diaphania) ) perspectalis), species of the genus Cydia (=Carpocapsa) spp., such as C. pomonella, C. latiferreana; Dalaca noctuides, Datana integerrima, Dasychira pinicola, Dendrolimus spp., such as D. pini, D. spectabilis, D. sibilix (D. sibiricus); Desmia funeralis, Diaphania spp., such as D. nitidalis, D. hyalinata; Diatraea grandiosella ( Diatraea grandiosella), Diatraea saccharalis, Diphthera festiva, Earias spp., such as E. insulana, E. vittella; Ecdytolopha aurantianu, Egira (=Xylomyges) curialis, Elasmopalpus lignosellus, Eldana saccharina, Endopiza viteana, Ennomos Ennomos subsignaria, Eoreuma loftini, Ephestia spp., such as E. cautella, E. elutella, E. queniella. kuehniella); Epinotia aporema, Epiphyas postvittana, Erannis tiliaria, Erionota thrax, Etiella spp.

Eulia spp., Eupoecilia ambiguella, Euproctis chrysorrhoea, Euxoa spp., Evetria bouliana, Faronta albilinea ( Faronta albilinea), Feltia spp., e.g. F. subterranean; Galleria mellonella, Gracillaria spp., Grapholita spp. spp.), such as G. funebrana, G. molesta, G. inopinata; Halysidota spp., Harrisina americana ), Hedylepta spp., Helicoverpa spp., such as H. armigera (= Heliothis armigera), H. zea )(=Heliothis zea); Species of the genus Heliothis (Heliothis spp.), such as H. assulta, H. subflexa, H. virescens Species of the genus Hellula (Hellula spp.), such as H. undalis, H. rogatalis; Helocoverpa gelotopoeon, Hemileuca oliviae, Herpetogranma・Herpetogramma licarsisalis, Hibernia defoliaria, Hofmannophila pseudospretella, Homoeosoma electellum, Homona magnanima, Hypena scabra, American white flycatcher ( Hyphantria cunea), Hyponomeuta padella, Hyponomeuta marinellus, Kakivoria flavofasciata, Keiferia lycopersicella, Lambdina fiscellaria fiscellaria , Lambdina Fiscellaria Lugubrosa, Lamprosema Indicata, Laspeyresia Molesta, Legeminibora (Legminiborella) Eguminivora glycinivorella), Lerodea eufala, Leucinodes Orbonalis ), Leucoma salicis, Leucoptera spp.

For example, L. coffeella, L. scitella; Leuminivora lycinivorella, Lithocolletis blancardella, Lithophane antennata, Llattia octo)(=Amyna axis), Lobesia botrana, Lophocampa spp., Loxagrotis albicosta, Loxostege spp., e.g. , L. sticticalis, L. cereralis; Lymantria spp., such as L. dispar, L. monacha; (Lyonetia clerkella), Lyonetia prunifoliella, Malacosoma spp., such as M. americanum, M. californicum, M. constrictum ( M. constrictum), M. neustria; Mamestra spp., such as M. brassicae, M. configurata; Mamstra brassica brassicae), Manduca spp., such as M. quinquemaculata, M. sexta; Marasmia spp., Marmara spp. ), Maruca testulalis, Megalopyge lanata, Melanchra picta, Melanitis leda, Mocis spp., e.g. M. lapites (M. lapites), M. repanda; Mocis latipes, Monochroa fragariae, Mythimna separata, Nemapogon cloacella, Neoleusinodes elegans Neoleucinodes elegantalis, Nepytia spp., Nymphula spp., Oiketicus spp., Omiodes indicata, Omphisa anastomosalis ), Operophtera brumata, Orgyia pseudotsugata, Oria spp., Orthaga thyrisalis, Ostrinia spp., e.g. O. nubilalis; Oulema oryzae, Paleacrita vernata, Panolis flammea, Parnara spp., Papaipema nebris, papilio - Papilio cresphontes, Paramyelois transitella, Paranthrene regalis, Paysandisia archon, Pectinophora spp., such as P. gossipiella. gossypiella); Peridroma saucia, Perileucoptera spp., such as P. coffeella; Phalera bucephala, Phryganidia californica, Fusolymaea spp. (Phthorimaea spp.), such as P. operculella; Phyllocnistis citrella, Phyllonorycter spp.,

For example, P. blancardella, P. crataegella, P. issikii, P. ringoniella; Pieris spp., e.g. , P. brassicae, P. rapae, P. napi; Pilocrocis tripunctata, Plathypena scabra, Platynota species spp.), such as P. flavedana, P. idaeusalis, P. stultana; Platyptilia carduidactyla, Plebejus argus ), Plodia interpunctella, Plusia spp, Plutella maculipennis, Plutella xylostella, Pontia protodica, Plusia spp. Prays spp.), Prodenia spp., Proxenus lepigone, Pseudaletia spp., such as P. sequax, P. unipuncta ( P. unipuncta); Pyrausta nubilalis, Rachiplusia nu, Richia albicosta, Rhizobius ventralis, Rhyacionia frustrana, Sabrodes aegrotata ( Sabulodes aegrotata), Schizura concinna, Schoenobius spp., Schreckensteinia festaliella, Scirpophaga spp., e.g. S. inselturus (S. incertulas), S. innotata; Scotia segetum, Sesamia spp., such as S. inferens, Seudyra subflava), Sitotroga cerealella, Sparganothis pilleriana, Spilonota lechriaspis, S. ocellana, Spodoptera (=Lamphygma) spp. , for example, S. cosmoides, S. eridania, S. exigua, S. frugiperda, S. latisfascia, S. S. littoralis, S. litura, S. omithogalli; Stigmella spp., Stomopteryx subsecivella, Strymon bazochii ), Sylepta derogata, Synanthedon spp., such as S. exitiosa, Tecia solanivora, Telehin licus, Thaumatopoa pithiocampa (Thaumatopoea pityocampa), Thaumatotibia (=Cryptophlebia) leucotreta, Thaumetopoea pityocampa, Thecla spp., Theresimima ampelophaga, Chirinteina Thyrinteina spp., Tildenia inconspicuella, Tinea spp., such as T. cloacella, T. pellionella; Tineola bisselliella, Tortrix spp., e.g. T. viridana; Trichophaga tapetzella, Trichoplusia spp., e.g. T. T. ni; Tuta (=Scrobipalpula) absoluta, species of the genus Udea (Udea spp.), such as U. rubigalis, U. rubigalis (U. . rubigalis); Virachola spp., Yponomeuta padella, and Zeiraphera canadensis;

Insects from the order Coleoptera, such as Acalymma vittatum, Acanthoscehdes obtectus, Adoretus spp., Agelastica alni, Agrillus Species of the genus Agrilus spp., e.g. A. anxius, A. planipennis, A. sinuatus; Species of the genus Agriotes, e.g. A. fuscicollis, A. lineatus, A. obscurus; Alphitobius diaperinus, Amphimalus solstitialis, Anisandrus. Anisandrus dispar, Anisoplia austriaca, Anobium punctatum, Anomala corpulenta, Anomala rufocuprea, Anoplophora spp., e.g. A. glabripennis; species of the genus Anthonomus, such as A. eugenii, A. grandis, A. pomorum; species (Anthrenus spp.), Aphthona euphoridae, Apion spp., Apogonia spp., Athous haemorrhoidalis, Atomaria spp. .), for example A. linearis; Attagenus spp., Aulacophora femoralis, Blastophagus piniperda, Blitophaga undata, Burchidius obectus. (Bruchidius obtectus), species of the genus Bruchus (Bruchus spp.), such as B. lentis, B. pisorum, B. rufimanus; Byctiscus betulae ), Callidiellum rufipenne, Callopistria floridensis, Callosobruchus chinensis, Cameraria ohridella, Cassida nebulosa, Cerotoma trifurcata, Setonia Cetonia aurata, Ceuthorhynchus spp., e.g. C. assimilis, C. napi; Chaetocnema tibialis, Cleonus mendicus ), Conoderus spp., such as C. vespertinus; Conotrachelus nenuphar, Cosmopolites spp., Costelytra zealandica, Cryoselis - Asparagi (Crioceris asparagi), Cryptolestes ferrugineus, Cryptorhynchus lapathi, Ctenicera spp., such as C. destructor; Curculio spp. species (Curculio spp.), Cylindrocopturus spp., Cyclocephala spp., Dactylispa balyi, Dectes texanus, Dermestes spp. species (Dermestes spp.), species of the genus Diabrotica (Diabrotica spp.), such as D. undecimpunctata, D. speciosa, D. longicornis, D. D. semipunctata, D. virgifera; Diaprepes abbreviates, Dichocrocis spp., Dicladispa armigera, Diloboderus abderus), Diocalandra frumenti (Diocalandra stigmaticollis), Enaphalodes rufulus, Epilachna spp., e.g. E. varivestis , E. vigintioctomaculata; Epitrix spp., such as E. hirtipennis, E. similaris; Eutheola humilis ), Eutinobothrus brasiliensis, Faustinus cubae, Gibbium psylloides, Gnathocerus cornutus, Hellula undalis, Heteronychus arator ), Hylamorpha elegans,

Hylobius abietis, Hylotrupes bajulus, Hypera spp., such as H. brunneipennis, H. postica; Hypomeces・Hypomeces squamosus, Hypothenemus spp., Ips typographus, Lachnosterna consanguinea, Lasioderma serricorne, Latheticus oryzae, Lathridius spp., Lema spp., such as L. bilineata, L. melanopus; Leptinotarsa spp., For example, L. decemlineata; Leptispa pygmaea, Limonius californicus, Lissorhoptrus oryzophilus, Lixus spp., Luperodes spp. Luperodes spp.), Lyctus spp., e.g. L. bruneus; Liogenys fuscus, Macrodactylus spp., e.g. M. M. subspinosus; Maladera matrida, Megaplatypus mutates, Megascelis spp., Melanotus communis, Meligethes spp. , such as M. aeneus; Melolontha spp., such as M. hippocastani, M. melolontha; Metamasius hemipterus, Microtheca spp., Migdolus spp., e.g. M. fryanus, Monochamus spp., e.g. M. alternatus ); Naupactus xanthographus, Niptus hololeucus, Oberia brevis, Oemona hirta, Oryctes rhinoceros, Oryzaephilus surinamensis ), Oryzaphagus oryzae, Otiorrhynchus sulcatus, Otiorrhynchus ovatus, Otiorrhynchus sulcatus, Oulema melanopus, Oulema oryzae , Oxycetonia jucunda, Phaedon spp., such as P. brassicae, P. cochleariae; Phoracantha recurva, Phyllobius piri ( Phyllobius pyri), Phyllopertha horticola, Phyllophaga spp., e.g. P. helleri; Phyllotreta spp., e.g. P. chrysocephala (P chrysocephala), P. nemorum, P. striolata, P. vittula; Phyllopertha horticola, Popillia japonica, Premnotrypes spp. Species (Premnotrypes spp.), Psacothea hilaris, Psylliodes chrysocephala, Prostephanus truncates, Psylliodes spp., Ptinus spp. ), Pulga saltona, Rhizopertha dominica, Rhynchophorus spp., such as R. billineatus, R. ferrugineus, R. R. palmarum, R. phoenicis, R. vulneratus; Saperda candida, Scolytus schevyrewi, Scyphophorus acupunctatus, R. vulneratus Sitona lineatus, Sitophilus spp., such as S. granaria, S. oryzae, S. zeamais; Sphenophorus spp. Species of Sphenophorus spp., e.g. S. levis; Stegobium paniceum, Sternechus spp., e.g. S. subsignatus; Strohomorphus spp. Strophomorphus ctenotus, Symphyletes spp., Tanymecus spp., Tenebrio molitor, Tenebrioides mauretanicus, Tribolium spp. ), e.g. T. castaneum; Trogoderma spp., Tychius spp., Xylotrechus spp., e.g. pyrrhoderus); and Zabrus spp., such as Z. tenebrioides;

Insects from the order of Diptera, such as Aedes spp., such as A. aegypti, A. albopictus, A. vexans (A. vexans); Mexican fruit fly (Anastrepha ludens), species of the genus Anopheles (Anopheles spp.), such as A. albimanus, A. crucians, A. freeborni ), A. gambiae, A. leucosphyrus, A. maculipennis, A. minimus, A. quadrimaculatus , A. sinensis; Bactrocera invadens, Bibio hortulanus, Calliphora erythrocephala, Calliphora vicina, Ceratitis Chrysomyia spp., such as C. bezziana, C. hominivorax, C. macellaria; Chrysops atlanticus, Chrysops discalis, Chrysops silacea, Cochliomyia spp., e.g. C. hominivorax; Contarinia spp., e.g. C. sorghicola; Cordylobia anthropophaga, Culex spp., such as C. nigripalpus, C. pipiens, C. kink C. quinquefasciatus, C. tarsalis, C. tritaeniorhynchus; Culicoides furens, Culiseta inornata, Culiseta melanura ), Cuterebra spp., Dacus cucurbitae, Dacus oleae, Dasineura brassicae, Dasineura oxycoccana, Delia spp. , for example, D. antique, D. coarctata, D. platura, D. radicum; Dermatobia hominis, Drosophila spp. Species (Drosophila spp.), e.g. D. suzukii, Fannia spp., e.g. F. canicularis; Gastraphilus spp. , e.g. G. intestinalis; Geomyza tipunctata, Glossina spp., e.g. G. fuscipes, G. morsitans ), G. palpalis, G. tachinoides; Haematobia irritans, Haplodiplosis equestris, Hippelates spp., Hilemia spp. Hylemyia spp.), such as H. platura; Hypoderma spp., such as H. lineata; Hyppobosca spp.,

Hydrellia philippina, Leptoconops torrens, Liriomyza spp., such as L. sativae, L. trifolii; Lucilia spp. species (Lucilia spp.), such as L. caprina, L. cuprina, L. sericata; Lycoria pectoralis, Mansonia titillannus titillanus), Mayetiola spp., e.g. M. destructor; Musca spp., e.g. M. autumnalis, M. domestica (M. Muscina stabulans, Oestrus spp., e.g. O. ovis; Opomyza florum, Oscinella spp., e.g. , O. frit; Orseolia oryzae, Pegomya hysocyami, Phlebotomus argentipes, Phorbia spp., e.g. P. antiqua (P. antiqua), P. brassicae, P. coarctata; Phytomyza gymnostoma, Prosimulium mixtum, Psila rosae, Psolophora Psorophora columbiae, Psorophora discolor, Rhagoletis spp., such as R. cerasi, R. cingulate, R. indife R. indifferens, R. mendax, R. pomonella; Rivellia quadrifasciata, Sarcophaga spp., e.g. S. haemoroidalis (S. haemorrhoidalis); Simulium vittatum, Sitodiplosis mosellana, Stomoxys spp., such as S. calcitrans; Tabanus spp. spp.), such as T. atratus, T. bovinus, T. lineola, T. similis; Tannia spp. ), Thecodiplosis japonensis, Tipula oleracea, Tipula paludosa, and Wohlfahrtia spp;

Insects from the order of Thysanoptera, such as Baliothrips biformis, Dichromothrips corbetti, Dichromothrips ssp., Echinothrips americanus , Enneothrips flavens, Frankliniella spp., such as F. fusca, F. occidentalis, F. tritici; Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Microcephalothrips abdominalis, Neohydathrips samayunculi ( Neohydatothrips samayunkur), Pezothrips kellyanus, Rhipiphorothrips cruentatus, Scirtothrips spp., such as S. citri, S. dorsalis (S. dorsalis), S. perseae; Stenchaetothrips spp, Taeniothrips cardamoni, Taeniothrips inconsequens, Thrips spp. spp.), for example T. imagines, T. hawaiiensis, T. oryzae, T. palmi, T. parvispinus ), T. tabaci;

Insects from the order of Hemiptera, such as Acizzia jamatonica, Acrosternum spp., such as A. hilare; Acyrthosipon spp., e.g. A. onobrychis, A. pisum; Adelges laicis, Adelges tsugae, Adelphocoris spp. spp.), such as A. rapidus, A. superbus; Aeneolamia spp., Agonoscena spp., Aulacorthum solani ), Aleurocanthus woglumi, Aleurodes spp., Aleurodicus disperses, Aleurolobus barodensis, Aleurothrixus spp., Amlaska spp. Amrasca spp., Anasa tristis, Antestiopsis spp., Anuraphis cardui, Aonidiella spp., Aphanostigma spp. Aphanostigma piri, Aphidula nasturtii, Aphis spp., such as A. craccivora, A. fabae, A. holbesii. forbesi), A. gossypii, A. grossulariae, A. maidiradicis, A. pomi, A. sambuci, A. A. schneideri, A. spiraecola; Arboridia apicalis, Arilus critatus, Aspidiella spp., Aspidiotus spp. Aspidiotus spp.), Atanus spp., Aulacaspis yasumatsui, Aulacorthum solani, Bactericera cockerelli (Paratrioza cockerelli), Bemisia spp. Species of Blissus spp., e.g. B. argentifolii, B. tabaci (Aleurodes tabaci); Blissus spp., e.g. B. leucopterus; Brachycaudus spp., such as B. cardui, B. helichrysi, B. persicae, B. prunicola (B. prunicola); Brachycolus spp., Brachycorynella asparagi, Brevicoryne brassicae, Cacopsylla spp., e.g. C. fulguralis (C. fulguralis), C. pyricola (Psylla piri);

Calligypona marginata, Calocoris spp., Campylomma livida, Capitophorus horni, Carneocephala fulgida, Cavellerius spp. ), Ceraplastes spp., Ceratovacuna lanigera, Ceroplastes ceriferus, Cerosipha gossypii, Chaetosiphon fragaefolii, Chionaspis tegalen sis ), Chlorita onukii, Chromaphis juglandicola, Chrysomphalus ficus, Cicadulina mbila, Cimex spp., e.g. C. hemipterus, C. lectularius; Coccomytilus halli, Coccus spp., e.g. C. hesperidum, C. C. pseudomagnoliarum; Corythucha arcuata, Creontiades dilutus, Cryptomyzus ribis, Chrysomphalus aonidum, Cryptomyzus ribis ), Ctenarytaina spatulata, Cyrtopeltis notatus, Dalbulus spp., Dasynus piperis, Dialeurodes spp., such as D. D. citrifolii; Dalbulus maidis, Diaphorina spp., e.g. D. citri; Diaspis spp., e.g. D. bromeliae; Dichelops furcatus, Diconocoris hewetti, Doralis spp., Dreyfusia nordmannianae, Dreyfusia piceae , Drosicha spp., Dysaphis spp., such as D. plantaginea, D. pyri, D. radicola Dysaulacorthum pseudosolani, Dysdercus spp., such as D. cingulatus, D. intermedius; Dysmicoccus spp. ), Edessa spp., Geocoris spp., Empoasca spp., such as E. fabae, E. solana. solana); Epidiaspis leperii, Eriosoma spp., such as E. lanigerum, E. pyricola; Erythroneura spp. ), Eurygaster spp., e.g. E. integriceps; Euscelis bilobatus, Euschistus spp., e.g. E. heros ), E. impictiventris, E. servus; Fiorinia theae, Geococcus coffeae, Glycaspis brimblecombei, Haliomorpha species of the genus Halyomorpha spp., e.g. H. halys; species of the genus Heliopeltis spp., Homalodisca vitripennis (=H. coagulata) ), Horcias nobilellus, Hyalopterus pruni, Hyperomyzus lactucae, Icerya spp., such as I. purchase; Species (Idiocerus spp.), Idioscopus spp., Laodelphax striatellus, Lecanium spp., Lecanoideus floccissimus, Lepidosafes spp. (Lepidosaphes spp.), such as L. ulmi; Leptocorisa spp., Leptoglossus phyllopus,

Lipaphis erysimi, species of the genus Lygus, such as L. hesperus, L. lineolaris, L. pratensis; Maconellicox - Maconellicoccus hirsutus, Marchalina hellenica, Macropes excavatus, Macrosiphum spp., such as M. rosae, M. avena. avenae), M. euphorbiae; Macrosteles quadrilineatus, Mahanarva fimbriolata, Megacopta cribraria, Megoura viciae, Melanaphis pilarius (Melanaphis pyrarius), Melanaphis sacchari, Melanocallis (=Tinocallis) caryaefoliae, Metcafiella spp., Metopolophium dirhodum, Moneria costalis (Monellia costalis), Monelliopsis pecanis, Myzocallis coryli, Murgantia spp., Myzus spp., such as M. ascalonicus (M. ascalonicus), M. cerasi, M. nicotianae, M. persicae, M. varians; Nasonovia ribis-nigri, Neotoxoptera・Neotoxoptera formosana, Neomegalotomus spp., Nephotettix spp., such as N. malayanus, N. nigropictus, N. N. parvus, N. virescens; Nezara spp., such as N. viridula; Nilaparvata lugens, Nysius huttoni), Oebalus spp., such as O. pugnax; Oncometopia spp., Orthezia praelonga, Oxycaraenus hyalinipennis, Parabemisia myricae, Parlatoria spp., Parthenolecanium spp., such as P. corni, P. persicae; Species of the genus Pemphigus (Pemphigus spp.), such as P. bursarius, P. populivenae; Peregrinus maidis, Perkinsiella saccharicida, Phenacoccus spp. species (Phenacoccus spp.), such as P. aceris, P. gossypii; Phloeomyzus passerinii, Phorodon humuli, Phylloxera spp. ), such as P. devastatrix, Piesma quadrata, Piezodorus spp., such as P. guildinii;

Pinnaspis aspidistrae, Planococcus spp., such as P. citri, P. ficus; Prosapia bicincta, Proto Protopulvinaria pyriformis, Psallus seriatus, Pseudacysta persea, Pseudaulacaspis pentagona, Pseudococcus spp., e.g. , P. comstocki; Psylla spp., such as P. mali; Pteromalus spp., Pulvinaria amygdali, Psylla spp. Pyrilla spp., Quadraspidiotus spp., e.g. Q. perniciosus; Quesada gigas, Rastrococcus spp. , Reduvius senilis, Rhizoecus americanus, Rhodnius spp., Rhoparomyzus ascalonicus, Rhopalosiphum spp., e.g. R. pseudobrassicas, R. insertum, R. maidis, R. padi; Sagatodes spp., Saarbergera Sahlbergella singularis, Saissetia spp., Sappaphis mala, Sappaphis mali, Scaptocoris spp., Scaphoides titanus, Schizaphis graminum, Schizoneura lanuginosa, Scotinophora spp., Selenaspidus articulatus, Sitobion avenae, Sogata spp. spp.), Sogatella furcifera, Solubea insularis, Spissistilus festinus(=Stictocephala festina), Stephanitis nashi , Stephanitis pyrioides, Stephanitis takeyai, Tenalaphara malayensis, Tetraleurodes perseae, Therioaphis maculate, species of the genus Chianta (Thyanta spp.), such as T. accerra, T. perditor; Tibraca spp., Tomaspis spp., Toxoptera spp. (Toxoptera spp.), e.g. T. aurantii; Species of the genus Trialeurodes (Trialeurodes spp.), e.g. T. abutilonea, T. ricini, T. vaporariorum (T. vaporariorum); Triatoma spp., Trioza spp., Typhlocyba spp., Unaspis spp., e.g. U. U. citri, U. yanonensis; and Viteus vitifolii,

Insects from the order of the Hymenoptera, such as Acanthomyops interjectus, Athalia rosae, Atta spp., such as A A. capiguara, A. cephalotes, A. cephalotes, A. laevigata, A. robusta, A. sequidens. sexdens), A. texana, Bombus spp., Brachymyrmex spp., Camponotus spp., e.g., C. floridianus (C. floridanus), C. pennsylvanicus, C. modoc; Cardiocondyla nuda, Chalibion sp., Crematogaster sp. (Crematogaster spp.), Dasymutilla occidentalis, Diprion spp., Dolichovespula maculata, Dorymyrmex spp., Dryocosmus kuriphilus , Formica spp., Hoplocampa spp., such as H. minuta, H. testudinea; Iridomyrmex humilis, Lasius Lasius spp., such as L. niger, Linepithema humile, Liometopum spp., Leptocybe invasa, Monomorium spp. Monomorium spp.), such as M. pharaonis, Monomorium, Nylandria fulva, Pachycondyla chinensis, Paratrechina longicornis, Paravespula sp. (Paravespula spp.), e.g. P. germanica, P. pennsylvanica, P. vulgaris; Pheidole spp., e.g. P. P. megacephala; Pogonomyrmex spp., such as P. barbatus, P. californicus, Polistes rubiginosa, Plenolepis impilus ( Prenolepis impairs), Pseudomyrmex gracilis, Schelipron spp., Sirex cyaneus, Solenopsis spp., e.g. S. geminata ( S. geminata), S. invicta, S. molesta, S. richteri, S. xyloni, Sphecius speciosus, Sphecis Sphex spp., Tapinoma spp., e.g. T. melanocephalum, T. sessile; Tetramorium spp., e.g. , T. caespitum, T. bicarinatum, Vespa spp., such as V. crabro; Vespula spp., For example, V. squamosal; Wasmannia auropunctata, Xylocopa sp;

Insects from the order of Orthoptera, such as Acheta domesticus, Calliptamus italicus, Chortoicetes terminifera, Ceuthophilus spp. ), Diastrammena asynamora, Dociostaurus maroccanus, Gryllotalpa spp., such as G. africana, G. gryllotalpa; Gryllus spp., Hieroglyphus daganensis, Kraussaria angulifera, Locusta spp., such as L. migratoria, L. L. pardalina; Melanoplus spp., such as M. bivittatus, M. femurrubrum, M. mexicanus, M. sanguinipes (M. sanguinipes), M. spretus; Nomadacris septemfasciata, Oedaleus senegalensis, Scapteriscus spp., Schistocerca spp. , such as S. americana, S. gregaria, Stemopelmatus spp., Tachycines asynamorus, and Zonozerus variegatus;

Pests from the Classes of the Arachnida, e.g. Acari, e.g. the following families: Argasidae, Ixodidae and Sarcoptidae , for example, Amblyomma spp. (e.g. A. americanum, A. variegatum, A. maculatum), Argas spp. spp.), e.g. A. persicu), Boophilus spp., e.g. B. annulatus, B. decoloratus, B. micropulus ( B. microplus), Dermacentor spp., such as D. silvarum, D. andersoni, D. variabilis, Dermacentor spp. Hyalomma spp.), e.g. H. truncatum, Ixodes spp., e.g. I. ricinus, I. rubicundus, I. scapularis ( I. scapularis), I. holocyclus, I. pacificus, Rhipicephalus sanguineus, Ornithodorus spp., e.g. moubata), O. hermsi, O. turicata, Ornithonyssus bacoti, Otobius megnini, Dermanyssus gallinae, Psoroptes spp. ), e.g. P. ovis, Rhipicephalus spp., e.g. R. sanguineus, R. appendiculatus, Rhipicephalus spp. (Rhipicephalus evertsi), Rhizoglyphus spp., Sarcoptes spp., e.g. S. Scabiei; and Family Eriophyidae, e.g. Aceria Species of the genus Aceria spp., e.g. A. sheldoni, A. anthocoptes, Acallitus spp., Aculops spp., e.g. , A. lycopersici, A. pelecassi; Aculus spp., such as A. schlechtendali; Colomerus vitis, Epitrimelus spp. Epitrimerus pyri, Phyllocoptruta oleivora; Eriophytes ribis and species of the genus Eriophyes, such as Eriophyes sheldoni; Family Tarsonemidae ), such as Hemitarsonemus spp., Phytonemus pallidus and Polyphagotarsonemus latus, Stenotarsonemus spp., Stenotarsonemus spinki (Steneotarsonemus spinki); Family Tenuipalpidae, e.g. Brevipalpus spp., e.g. B. phoenicis; Family Tetranychidae, e.g. Eotetranychus spp., Eutetranychus spp., Oligonychus spp., Petrobia latens, Tetranychus spp. ), for example, T. cinnabarinus, T. evansi, T. kanzawai, T. pacificus, T. phaseulus, T. telarius and T. urticae; Bryobia praetiosa; Panonychus spp., such as P. ulmi, P. citri (P. citri); species of the genus Metatetranychus (Metatetranychus spp.) and species of the genus Oligonychus (Oligonychus spp.), such as O. pratensis, O. perseae, Vasates・Vasates lycopersici; Raoiella indica, Family Carpoglyphidae, e.g. Carpoglyphus spp.; Penthaleidae spp., e.g. Halotideus・Halotydeus destructor; Family: Demodicidae and its species, such as Demodex spp.; Family: Trombicidea, such as Trombicula spp. Family: Macronyssidae, e.g., Ornothonyssus spp.; Family: Pyemotidae, e.g., Pyemotes tritici; Tyrophagus putrescentiae); Family Acaridae, e.g. Acarus siro; Family Araneida, e.g. Latrodectus mactans, Tegenaria agrestis, Chiracanthium sp, Lycosa sp, Achaearanea tepidariorum and Loxosceles reclusa;

Pests from the Phylum of the Nematoda, such as plant parasitic nematodes, such as root-knot nematodes, Meloidogyne spp., such as M. hapla), M. incognita, M. javanica; cyst-forming nematodes, Globodera spp., e.g. G. rostochiensis (G. rostochiensis); Heterodera spp., such as H. avenae, H. glycines, H. schachtii, H. trifolii trifolii); Seed gall nematodes, Anguina spp.; Stem and foliar nematodes, Aphelenchoides spp., such as A. A. besseyi; Sting nematodes, Belonolaimus spp., e.g. B. longicaudatus; Pine nematodes, Bursapherenchus spp. species (Bursaphelenchus spp.), such as B. lignicolus, B. xylophilus; Ring nematodes, Criconema spp., Criconema spp. Species of Criconemella spp., such as C. xenoplax and C. ornata; and species of the genus Criconemoides, such as Criconemoides informis; Species of the genus (Mesocriconema spp.); Stem and bulb nematodes, species of the genus Ditylenchus (Ditylenchus spp.), such as D. destructor, D. dipsaci; All Awl nematodes, Dolichodorus spp.; Spiral nematodes, Heliocotylenchus multicinctus; Sheath and sheathoid nematodes, Hemicycliophora spp. and Hemicriconemoides spp.; Hirshmanniella spp.; Lance nematodes, Hoploaimus spp. False rootknot nematodes, Nacobbus spp.; Needle nematodes, Longidorus spp., e.g. L. elongatus Lesion nematodes, Pratylenchus spp., such as P. brachyurus, P. neglectus, P. penetrans, P. P. curvitatus, P. goodeyi; Burrowing nematodes, Radopholus spp., e.g. R. similis; Rhadopholus spp.); Rhodopholus spp.; Reniform nematodes, Rotylenchus spp., such as R. robustus, R. reniformis (R. reniformis); Scutellonema spp.; Stubby-root nematode, Trichodorus spp., such as T. obtusus, T. primitivus ); Paratrichodorus spp., e.g. P. minor; Stunt nematodes, Tylenchorhynchus spp., e.g. T. claytoni), T. dubius; Citrus nematodes, Tylenchulus spp., such as T. semipenetrans; Dagger nematodes ), Xiphinema spp.; and other plant parasitic nematode species;

Insects from the order of the suborder Blattodea, such as Macrotermes spp., such as M. natalensis; Cornitermes cumulans, Procornitermes Procornitermes spp., Globitermes sulfureus, Neocapritermes spp., such as N. opacus, N. parvus; Odontotermes spp., Nasutitermes spp., e.g. N. corniger; Coptotermes spp., e.g. C. formosanus (C formosanus), C. gestroi, C. acinaciformis; Reticulitermes spp., such as R. hesperus, R. tibialis (R. tibialis), R. speratus, R. flavipes, R. grassei, R. lucifugus, R. virginicus; hetero Heterotermes spp., such as H. aureus, H. longiceps, H. tenuis; Cryptotermes spp. For example, C. brevis, C. cavifrons; Incisitermes spp.), such as I. minor, I. snider. Snyder)i; Marginitermes hubbardi, Kalotermes flavicollis, Neotermes spp., such as N. castaneus, Zootermopsis spp. , e.g. Z. an-gusticollis, Z. nevadensis, Mastotermes spp., e.g. M. darwiniensis; Blatta Species of the genus Blattella (BlAtta spp.), e.g. B. orientalis, B. lateralis; species of the genus Blattella (BlAtta spp.), e.g. B. asahinae, B. germani-ca; Rhyparobia maderae, Panchlora nivea, Periplaneta spp., such as P. americana, P. P. australasiae, P. brunnea, P. fuliginosa, P. japonica; Supella longipalpa, Parcoblatta pennsylvanica ), Eurycotis floridana, Pycnoscelus surinamensis,

Insects from the order of the Siphonoptera, such as Cediopsylla simples, Ceratophyllus spp., Ctenocephalides spp., e.g. C. felis, C. canis, Xenopsylla cheopis, Pulex irritans, Trichodectes canis, Tunga penetrans, and European rat flea (Nosopsyllus fasciatus),

Insects from the order of Thysanura, such as Lepisma saccharina, Ctenolepisma urbana, and Thermobia domestica,

pests from the Class Chilopoda, such as Geophilus spp., Scutigera spp., such as Scutigera coleoptrata;

Pests from the Class Diplopoda, such as Blaniulus guttulatus, Julus spp., Narceus spp.

Pests from the Class Symphyla, such as Scutigerella immaculata,

Insects from the order of Dermaptera, such as Forficula auricularia,

Insects from the order Collembola, such as species of the genus Onychiurus, such as Onychiurus armatus,

Pests from the order of the Isopoda, such as Armadillidium vulgare, Oniscus asellus, Porcellio scaber,

Insects from the order Phthiraptera, e.g. Damalinia spp., Pediculus spp., e.g. Pediculus humanus capitis, Pediculus humanus corporis ), Pediculus humanus humanus; Pthirus pubis, Haematopinus spp., e.g. cow lice (Haematopinus eurysternus), pig lice (Haematopinus suis); Linognathus spp. .), for example the cow louse (Linognathus vituli); the cow louse (Bovicola bovis), the chicken louse (Menopon gallinae), the chicken leopard louse (Menacanthus stramineus) and the woolly cow louse (Solenopotes capillatus), Trichodectes spp.,

Examples of further pest species that may be controlled by compounds of formula (I) include: from the Phylum Mollusca, Class Bivalvia, e.g. , Dreissena spp.; Class Gastropoda, e.g. Arion spp., Biomphalaria spp., Bulinus spp. (Bulinus spp.), Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Pomacea canaliculata ( Pomacea canaliclata), Succinea spp.; From the class of helminths, for example, Ancylostoma duodenale, Ancylostoma ceylanicum, Ancylostoma・Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori (Brugia timori), Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp. species (Dicrocoelium spp.), Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus mulch Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., such as Haemonchus contortus; Heterachis spp. (Heterakis spp.), Hymenolepis nana, Hyostrongulus spp., Loa Loa, Nematodirus spp., Esophagostomum spp. Oesophagostomum spp., Opisthorchis spp., Onchocerca volvulus, Ostertagia spp., Paragonimus spp., Schistostomen spp. Schistosomen spp.), Strongyloides fuelleborni, Strongyloides stercora lis, Stronyloides spp., Taenia saginata, Taenia solium ), Trichinella spiralis, Trichinella nativa, Trichinella britovi, Trichinella nelsoni, Trichinella pseudopsiralis, Trichostrongulus species (Trichostrongulus spp.), Trichuris trichuria, Wuchereria bancrofti.

Rice pests:
In the context of the present invention, rice pest invertebrates are animal pests that occur on rice. Invertebrates harmful to rice include insects, mites, nematodes, and the like, preferably insects. Well-known rice pest invertebrates in rice include, but are not limited to, the following species:

Hemiptera:
Brown planthopper (brown planthopper) - Nilaparvata lugens
Small Brown Planthopper - Laodelphax striatellus
White-backed planthopper - Sogatella furcifera
White Leafhopper - Cofana spectra
Green leafhopper - Nephotettix virescens, N. nigriceps, N. cincticeps, N. malayanus
Lightning leafhopper (zig zag leafhopper) - Recilia dorsalis
Leafhopper (maize orange leafhopper) - Cicadulina bipunctata
Leafhopper (aster leafhopper) - Macrosteles fascifrons
Formosan stink bug (rice earhead bug), Leptocorisa oratorius, L. acuta
Rice stink bugs - Nezara viridula, Pygomenida varipennis, Eysarcoris, Tibraca limbatriventris, Eysarcoris ventralis
small stink bug - Oebalus poecilus, O. pugnax
Coreid bug - Eysarcoris sp.
Chinch bug - Blissus leucopterus, leucopterus
Rice mealybug, Brevennia rehi, Pseudococcus saccharicola
Rice aphids, Rhopalosiphum rufiabdominalis, Macrosiphum avenae, Hysteroneura setariae, Tetraneuro nigriabdominalis
bean root aphid - Smynthurodes betae

Lepidoptera:
Rice skipper - Parnara guttata, Melanitis Ieda ismene
Japanese borer moth (rice stem borer/striped stem borer) - Chilo suppressalis, Chilo polychrusus, Chilo partellus, Chilo preja Chilo plejadellus
Rice stalk borer - Chilotraea polychrysa
Rice armyworm (pink rice borer) - Sesamia inferens
Yellow rice borer - Tryporyza(=Scirpophaga) incertulas
White Rice Borer - Tryporyza innotata
Knot borer (rice leafroller/rice leaf folder) - Cnaphalocrocis medinalis, Marasmia patnalis, M. exigua
Armyworm (rice ear-cutting caterpillar/armyworm) - Pseudaletia separata
Green caterpillar - Xanthodes transversa
Green rice caterpillar - Narnaga aenescens
green horned caterpillars - Melanitis Ieda ismene, Mycalesis sp.
Fall army worm - Spodoptera frugiperda
Cutworm - Mythimna separata
Rice case worm (rice case worm) - Nymphula depunctalis
black hairy caterpillar, Amata sp.
Hairy caterpillar - Mocis frugalis
Obiga (yellow caterpillar), Psalis pennatula
Rice semi-brown looper, Mocis frugalis
Rice semi-looper, Chrysodeixis chalcites
Grass webworm - Herpetogramma licarsisalis
Sugarcane borer - Diatraea saccharalis
Corn stalk borer - Elasmopalpus lignosellus
Striped grass looper - Mocis latipes
European corn borer - Ostrinia nubilalis
Mexican rice borer - Eoreuma loftini

Coleoptera:
Water weevil - Lissorhopterus oryzophilus
Rice weevil (rice plant weevil) - Echinocnemus squamous
Rice weevil (rice weevil) - Oryzophagus oryzae
Rice hispa - Diclodispa armigera Rice leaf beetle - Oulema oryzae
Rice blackbug - Scotinophora vermidulate, S. vermidulate, S. lurida, S. latiuscula
Rice flea beetle - Chaetocnima basalis
Grubs - Leucopholis irrorata, Leucopholis irrorata, Phyllophaga sp, Heteronychus sp.
Scarab beetle (bicho torito) - Diloboderus abderus
Billbugs - Sphenophorus spp.
grape colaspis - Colaspis brunnea, C. louisianae
Rice pollen beetle, Chilolaba acuta

Diptera:
Stem maggot - Chlorops oryzae
Leafminer - Agromyza oryzae
Rice whorl maggot/rice stem maggot - Hydrellia sasakii
Rice whorl maggot/small rice leafminer - Hydrellia griseola
Rice gall midge - Orseolia (=Pachydiplosis) oryzae
Rice shoot fly - Atherigona oryzae
Rice seed midge - Chironomus cavazzai, Chironomus spp, Cricotopus spp.

Thysanoptera:
Rice thrips - Chloethrips oryzae, Stenochaetothrips biformis, Perrisothrips sp., Hoplothrips sp.,

Orthoptera:
rice grasshoppers, Hieroglyphus banian, Hieroglyphus nigrorepletus, Catantops pinguis, Attractomorpha burri, A. crenulata ( A. crenulate), A. psittacina, A. Bedeli, Oxya adenttata, Oxya ebneri, Oxya hyla intricata, Acrida turricata
Locusts - Locusta migratoria manilensis
mole cricket, Grylotalpa africana
Field crickets: Gryllus bimaculatus, Teleogryllus occipitalis, Euscyrtus concinus
Katydid - Conocephalus longipennis

Isoptera:
termites - Macrotermes gilvus, Syntermes molestans

Hymenoptera:
ants - red fire ant (Solenopsis geminata)
Rice white tip nematode (rice white tip nematode) - Aphelenchoides besseyi

Acari:
rice panicle mite - Steotarsonemus pinki

Crustacea:
tadpole shrimp - American tadpole shrimp (Triops longicaudatus), European tadpole shrimp (T. cancriformis)
rice crayfish - American crayfish (Procambarus clarkii), Orconectes virilis.

In addition, rice plants include Leptocorisa chinensis, Lagynotomus elongates, Nerzara viridula, Eysacoris parvus, Leptocorisa oratorius, and Oebalus pugnax. pugnax, Cletus trigonus, and a wide range of insects, including various mites, caterpillars, beetles, rootworms, and maggots.

In one embodiment, the rice pest invertebrate is a biting/chewing insect.

In one embodiment, the rice pest invertebrate is a piercing/sucking insect.

In one embodiment, the rice pest invertebrate is a rasping insect.

In one embodiment, the rice pest invertebrate is a siphoning insect.

In one embodiment, the rice pest invertebrate is a sponging insect.

In one embodiment, the rice harmful invertebrates include the brown plant hopper (Nilaparvata lugens), the small brown planthopper (Lao delphax Laodelphax striatellus), white-backed planthopper (Sogatella furcifera), rice stem borer (rice stem borer), rice striped stem borer (rice stem borer) striped stem borer) (Chilo suppressalis), Yellow rice borer (Tryporyza(=Scirpophaga) incertulas), Yellow rice borer (Tryporyza(=Scirpophaga) incertulas) (rice leafroller)/rice leaf folder) (Cnaphalocrocis medinalis), rice weevil (water weevil) (Lissorhopterus oryzophilus) .

In one embodiment, the rice pest invertebrate is selected from the order Hemiptera or the order Lepidoptera.

In one embodiment, the rice pest invertebrate is selected from the order Hemiptera. In a further embodiment, the rice harmful invertebrate is a leafhopper, preferably the brown plant hopper (Nilaparvata lugens), the small brown plant hopper (Nilaparvata lugens), the small brown plant hopper brown planthopper) (Laodelphax striatellus), white-backed planthopper (Sogatella furcifera), green leafhopper (green leafhopper) )) (Nephotettix virescens). In a further embodiment, the rice harmful invertebrates include the brown plant hopper (Nilaparvata lugens) and the green leafhopper (Nephotettix virescens). virescens)), preferably the brown plant hopper (Nilaparvata lugens).

In one embodiment, the rice pest invertebrate is the brown plant hopper (Nilaparvata lugens).

In one embodiment, the rice pest invertebrate is the green leafhopper (Nephotettix virescens).

In a further embodiment, the rice pest invertebrate is a stink bug, preferably rice stink bugs (Nezara viridula), Pygomenida varipennis, Eysarcoris. , Tibraca limbatriventris, Eysarcoris ventralis), or small stink bug ( Oebalus poecilus), O. pugnax ) is selected.

In one embodiment, the rice pest invertebrate is selected from the order Lepidoptera. In a further embodiment, the rice pest invertebrate is a borer, preferably a stem borer, preferably a rice borer (rice stem borer (Chilo suppressalis)), Or yellow rice borer (Tryporyza(=Scirpophaga) incertulas).

In a further embodiment, the rice harmful invertebrate is the rice leaf roller/rice leaf folder (Cnaphalocrocis medinalis), Marasmia patnalis. ), M. exigua).

In one embodiment, the rice pest invertebrate is selected from the order Coleoptera. In a further embodiment, the rice pest invertebrate is the rice water weevil (Lissorhopterus oryzophilus). In a further embodiment, the rice pest invertebrate is the rice weevil (Oryzophagus oryzae).

In one embodiment, the rice pest invertebrate is selected from the family of the order Temites (Isoptera).

Mixtures of two or more components The mixtures according to the invention may be combined with other active ingredients, such as other pesticides, in particular insecticides, nematicides, fungicides, herbicides, safeners, etc. It can be applied in agriculture as a mixture with fertilizers (eg ammonium nitrate, urea, potash, and superphosphates), phytotoxicants, and plant growth regulators.

These mixtures are also encompassed by the term "mixture(s) of the invention" or "mixture(s) according to the invention".

These additional components may be used sequentially or in combination with the mixture according to the invention and, if appropriate, added immediately before use (tank mixing). For example, the plant(s) may be sprayed with the mixture of the invention either before or after being treated with the other active ingredients.

In one embodiment, the invention relates to a mixture of the invention that is a binary mixture of compounds I and II, ie, these active ingredients are the only active ingredients. Preferred weight ratios for such binary mixtures are from 5000:1 to 1:5000, preferably from 1000:1 to 1:1000, more preferably from 100:1 to 1:100, particularly preferably from 10:1 to 1: It is 10. In such binary mixtures, compounds I and II may be used in equal amounts, or an excess of component I or an excess of component II may be used.

In one embodiment, the preferred weight ratios of benzpyrimoxane and oxazosulfyl are 100:1 to 1:1, 50:1 to 1:1, 40:1 to 1:1, 20:1 to 1: 1, 16:1 to 1:1 or 10:1 to 1:1. In another embodiment, preferred weight ratios are 100:1 to 1:3, 50:1 to 1:3, 40:1 to 1:3, 20:1 to 1:3, 16:1 to 1:3. Or 10:1 to 1:3. In another embodiment, preferred weight ratios are 100:1-3:1, 50:1-3:1, 40:1-3:1, 20:1-3:1, 16:1-3:1 Or 10:1 to 3:1.

The same preferred mixture ratios also apply to compounds I and II if the mixture is not a binary mixture, ie it contains more active compound.

The invention also relates to a process according to the invention, in which a mixture of mixtures according to the invention is applied together with at least one further mixing partner as defined herein below, provided that the additional mixing partner is compound I and II). Mixtures of these are also considered mixtures of the present invention.

The following pesticides, grouped and numbered according to the Insecticide Resistance Control Committee (IRAC) classification scheme, which can be used with the mixtures of the invention and with which synergistic effects may occur: List M is intended to illustrate possible combinations and does not impose any restrictions:

M.1 Acetylcholinesterase (AChE) inhibitors: M.1A carbamates, such as aldicarb, alanycarb, bendiocarb, benfuracarb, butocarboxim, butoxy Carboxim, carbaryl, carbofuran, carbosulfan, ethiofencarb, fenobucarb, formetate, furathiocarb, isoprocarb, methiocarb methiocarb, methomyl, metolcarb, oxamyl, pirimicarb, propoxur, thiodicarb, thiofanox, trimethacarb, XMC, xylylcarb ) and triazamate; or M.1B organophosphates, such as acephate, azamethiphos, azinphos-ethyl, azinphosmethyl, cadusafos, chlorethoxyphos ( chlorethoxyfos, chlorfenvinphos, chlormephos, chlorpyrifos, chlorpyrifos-methyl, coumaphos, cyanophos, demeton-S-methyl methyl), diazinon, dichlorvos/DDVP, dicrotophos, dimethoate, dimethylvinphos, disulfoton, EPN, ethion, ethoprophos, famfur (famphur), fenamiphos, fenitrothion, fenthion, fosthiazate, heptenophos, imicyafos, isofenphos, isopropyl O-(methoxyaminothio-phosphoryl) salicylate (isopropyl O-(methoxyaminothio-phosphoryl)salicylate), isoxathion, malathion, mecarbam, methamidophos, methidathion, mevinphos, monocrotophos, naled( naled), omethoate, oxydemeton-methyl, parathion, parathion-methyl, phenthoate, phorate, phosalone, phosmet , phosphamidon, phoxim, pirimiphos-methyl, profenofos, propetamphos, prothiofos, pyraclofos, pyridaphenthion, quinalphos ), sulfotep, tebupirimfos, temephos, terbufos, tetrachlorvinphos, thiometon, triazophos, trichlorfon and vamidothion;

M.2. GABAergic chloride channel antagonists: M.2A cyclodiene organochlorine compounds, such as endosulfan or chlordane; or M.2B fiproles (phenylpyrazoles) ), such as ethiprole, fipronil, flufiprole, pyrafluprole and pyriprole;

M.3 Sodium channel modulators: M.3A From the class of pyrethroids, e.g. acrinathrin, allethrin, d-cis-trans allethrin, d-trans d-trans allethrin, bifenthrin, kappa-bifenthrin, bioallethrin, bioallethrin S-cylclopentenyl, bioresmethrin, cycloprothrin ( cycloprothrin), cyfluthrin, beta-cyfluthrin, cyhalothrin, lambda-cyhalothrin, gamma-cyhalothrin, cypermethrin, alpha-cypermethrin (alpha-cypermethrin), beta-cypermethrin, theta-cypermethrin, zeta-cypermethrin, cyphenothrin, deltamethrin, empenthrin ), esfenvalerate, etofenprox, fenpropathrin, fenvalerate, flucythrinate, flumethrin, tau-fluvalinate , halfenprox, heptafluthrin, imiprothrin, meperfluthrin, metofluthrin, momfluorothrin, epsilon-momfluorothrin, permethrin ( permethrin, phenothrin, prallethrin, profluthrin, pyrethrin (pyrethrum), resmethrin, silafluofen, tefluthrin, kappa-tefluthrin or M.3B sodium channel modulators, such as DDT or methoxychlor;

M.4 Nicotinic acetylcholine receptor agonists (nAChR): M.4A neonicotinoids, such as acetamiprid, clothianidin, cycloxaprid, dinotefuran, imidacloprid , nitenpyram, thiacloprid and thiamethoxam; or compound M.4A.1 4,5-dihydro-N-nitro-1-(2-oxiranylmethyl)-1H-imidazole-2- Amine, M.4A.2: (2E-)-1-[(6-chloropyridin-3-yl)methyl]-N'-nitro-2-pentylidenehydrazinecarboximidamide; or M4.A.3: 1-[(6-chloropyridin-3-yl)methyl]-7-methyl-8-nitro-5-propoxy-1,2,3,5,6,7-hexahydroimidazo[1,2-a] Pyridine; or M.4B nicotine; M.4C sulfoxaflor; M.4D flupyradifurone; M.4E triflumezopyrim; M.4E.1a) (3R)-3-( 2-chlorothiazol-5-yl)-8-methyl-5-oxo-6-phenyl-2,3-dihydrothiazolo[3,2-a]pyrimidin-8-ium-7-oleate, M.4E. 1b) (3S)-3-(6-chloro-3-pyridyl)-8-methyl-5-oxo-6-phenyl-2,3-dihydrothiazolo[3,2-a]pyrimidin-8-ium- 7-Olate, M.4E.1c) (3S)-8-Methyl-5-oxo-6-phenyl-3-pyrimidin-5-yl-2,3-dihydrothiazolo[3,2-a]pyrimidine- 8-ium-7-oleate, M.4E.1d) (3R)-3-(2-chlorothiazol-5-yl)-8-methyl-5-oxo-6-[3-(trifluoromethyl)phenyl ]-2,3-dihydrothiazolo[3,2-a]pyrimidin-8-ium-7-oleate; M.4E.1e) (3R)-3-(2-chlorothiazol-5-yl)-6 -(3,5-dichlorophenyl)-8-methyl-5-oxo-2,3-dihydrothiazolo[3,2-a]pyrimidin-8-ium-7-oleate, M.4E.1f) (3R) -3-(2-chlorothiazol-5-yl)-8-ethyl-5-oxo-6-phenyl-2,3-dihydrothiazolo[3,2-a]pyrimidin-8-ium-7-oleate;

M.5 Nicotinic acetylcholine receptor allosteric activators: spinosyns, such as spinosad or spinetoram;

M.6 Chloride channel activators, from the classes of avermectins and milbemycins, for example abamectin, emamectin benzoate, ivermectin, lepimectin or Milbemectin;

M.7 Juvenile hormone mimics, such as M.7A juvenile hormone analogues hydroprene, kinoprene and methoprene; or M.7B phenoxy Fenoxycarb or M.7C pyriproxyfen;

M.8 Miscellaneous non-specific (multisite) inhibitors, such as M.8A alkyl halides (e.g. methyl bromide) and other alkyl halides, M.8B chloropicrin, M.8C sulfuryl fluoride. (sulfuryl fluoride), M.8D borax, or M.8E tartar emetic;

M.9 chordotonal organ TRPV channel modulators, such as M.9B pymetrozine; pyrifluquinazon;

M.10 Mite growth inhibitors, such as M.10A clofentezine, hexythiazox and diflovidazin, or M.10B etoxazole;

M.11 Insect midgut lining disrupting agents derived from microorganisms, such as Bacillus thuringiensis or Bacillus sphaericus and the insecticidal proteins they produce, such as Bacillus thuringiensis subsp. bacillus thuringiensis subsp. israelensis), bacillus sphaericus, bacillus thuringiensis subsp. aizawai, bacillus thuringiensis subsp. Bacillus thuringiensis subsp. tenebrionis or Bt crop proteins: Cry1Ab, Cry1Ac, Cry1Fa, Cry2Ab, mCry3A, Cry3Ab, Cry3Bb, and Cry34/35Ab1;

M.12 Mitochondrial ATP synthase inhibitors, such as M.12A diafenthiuron, or M.12B Organotin acaricides, such as azocyclotin, cyhexatin, or fenbutatin oxide ( fenbutatin oxide), M.12C propargite, or M.12D tetradifon;

M.13 Uncoupling agents of oxidative phosphorylation by perturbation of the proton gradient, such as chlorfenapyr, DNOC or sulfluramid;

M.14 Nicotinic acetylcholine receptor (nAChR) channel blockers, such as nereistoxin analogues, bensultap, cartap hydrochloride, thiocyclam, or thiosultap sodium (thiosultap sodium);

M.15 Chitin biosynthesis inhibitor type 0, such as benzoylureas, such as bistrifluron, chlorfluazuron, diflubenzuron, flucycloxuron, flufenoxuron, hexaflumuron, lufenuron, novaluron, noviflumuron, teflubenzuron, or triflumuron;

M.16 Chitin biosynthesis inhibitor type 1, e.g. buprofezin;

M.17 Molting disruptors, Dipteran, e.g. cyromazine;

M.18 Ecdysone receptor agonists, such as diacylhydrazines, such as methoxyfenozide, tebufenozide, halofenozide, fufenozide, or chromafenozide;

M.19 Octopamine receptor agonists, such as amitraz;

M.20 Mitochondrial complex III electron transport inhibitors, such as M.20A hydramethylnon, or M.20B acequinocyl, or M.20C fluacrypyrim; or M.20D bifenazate. ;

M.21 Mitochondrial complex I electron transport inhibitors, e.g. M.21A METI acaricides and insecticides, e.g. fenazaquin, fenpyroximate, pyrimidifen, pyridaben, tebufenpyrad ) or tolfenpyrad, or M.21B rotenone;

M.22 Voltage-gated sodium channel blockers, such as M.22A indoxacarb, or M.22B metaflumizone, or M.22B.1: 2-[2-(4-cyanophenyl) -1-[3-(trifluoromethyl)phenyl]ethylidene]-N-[4-(difluoromethoxy)phenyl]-hydrazinecarboxamide or M.22B.2: N-(3-chloro-2-methylphenyl)- 2-[(4-chlorophenyl)[4-[methyl(methylsulfonyl)amino]phenyl]methylene]-hydrazinecarboxamide;

M.23 Inhibitors of acetyl-CoA carboxylase, such as tetronic acid and tetramic acid derivatives, such as spirodiclofen, spiromesifen, or spirotetramat; M.23.1 spiropidion

M.24 Mitochondrial complex IV electron transport inhibitors, e.g. M.24A phosphine, e.g. aluminum phosphide, calcium phosphide, phosphine, or zinc phosphide phosphide), or M.24B cyanide;

M.25 Mitochondrial complex II electron transport inhibitors, such as beta-ketonitrile derivatives, such as cyenopyrafen or cyflumetofen;

M.28 Ryanodine receptor modulators, from the class of diamides, such as flubendiamide, chlorantraniliprole, cyantraniliprole, tetraniliprole, M.28.1: (R)-3-chloro-N1-{2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl}-N2-(1- Methyl-2-methylsulfonylethyl)phthalamide, M.28.2: (S)-3-chloro-N1-{2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl) ethyl]phenyl}-N2-(1-methyl-2-methylsulfonylethyl)phthalamide, M.28.3: cyclaniliprole, or M.28.4: methyl-2-[3,5-dibromo-2-({[ 3-Bromo-1-(3-chloropyridin-2-yl)-1H-pyrazol-5-yl]carbonyl}amino)benzoyl]-1,2-dimethylhydrazinecarboxylate; M.28.5i) N-[2 -(5-amino-1,3,4-thiadiazol-2-yl)-4-chloro-6-methylphenyl]-3-bromo-1-(3-chloro-2-pyridinyl)-1H-pyrazole-5 -Carboxamide; M.28.5j) 3-chloro-1-(3-chloro-2-pyridinyl)-N-[2,4-dichloro-6-[[(1-cyano-1-methylethyl)amino]carbonyl ]phenyl]-1H-pyrazole-5-carboxamide; M.28.5k)tetrachlorantraniliprole; M.28.5L) N-[4-chloro-2-[[(1,1-dimethylethyl)amino] carbonyl]-6-methylphenyl]-1-(3-chloro-2-pyridinyl)-3-(fluoromethoxy)-1H-pyrazole-5-carboxamide; or

M.28.6: cyhalodiamide; or

M.29: chordotonal organ modulator - undefined target site, e.g. flonicamid;

M.UN. Insecticidal active compounds with unknown or unclear mechanism of action, such as afidopyropen, afoxolaner, azadirachtin, amidoflumet, benzoximate, brofuranilide (broflanilide), bromopropylate, chinomethionat, cryolite, dicloromezotiaz, dicofol, flufenerim, flometoquin, fluensulfone , fluhexafon, fluopyram, fluralaner, metaldehyde, metoxadiazone, piperonyl butoxide, pyflubumide, pyridalyl, tioxazafen,

M.UN.3: 11-(4-chloro-2,6-dimethylphenyl)-12-hydroxy-1,4-dioxa-9-azaspiro[4.2.4.2]-tetradec-11-en-10-one,

M.UN.4: 3-(4’-fluoro-2,4-dimethylbiphenyl-3-yl)-4-hydroxy-8-oxa-1-azaspiro[4.5]dec-3-en-2-one,

M.UN.5: 1-[2-fluoro-4-methyl-5-[(2,2,2-trifluoroethyl)sulfinyl]phenyl]-3-(trifluoromethyl)-1H-1,2, 4-triazol-5-amine, or an activator based on Bacillus firmus (Votivo, I-1582);

M.UN.6: Flupyrimin;

M.UN.8: fluazaindolizine; M.UN.9.a): 4-[5-(3,5-dichlorophenyl)-5-(trifluoromethyl)-4H-isoxazole-3 M.UN.10: 5-[3-[2,6 -dichloro-4-(3,3-dichloroallyloxy)phenoxy]propoxy]-1H-pyrazole;

M.UN.11.i) 4-cyano-N-[2-cyano-5-[[2,6-dibromo-4-[1,2,2,3,3,3-hexafluoro-1-( M.UN.11.j) 4-cyano-3-[(4-cyano-2-methyl-benzoyl)amino]-N- [2,6-dichloro-4-[1,2,2,3,3,3-hexafluoro-1-(trifluoromethyl)propyl]phenyl]-2-fluoro-benzamide; M.UN.11.k ) N-[5-[[2-chloro-6-cyano-4-[1,2,2,3,3,3-hexafluoro-1-(trifluoromethyl)propyl]phenyl]carbamoyl]-2- cyano-phenyl]-4-cyano-2-methyl-benzamide; M.UN.11.l) N-[5-[[2-bromo-6-chloro-4-[2,2,2-trifluoro- 1-Hydroxy-1-(trifluoromethyl)ethyl]phenyl]carbamoyl]-2-cyano-phenyl]-4-cyano-2-methyl-benzamide; M.UN.11.m) N-[5-[[ 2-bromo-6-chloro-4-[1,2,2,3,3,3-hexafluoro-1-(trifluoromethyl)propyl]phenyl]carbamoyl]-2-cyano-phenyl]-4-cyano -2-Methyl-benzamide; M.UN.11.n) 4-cyano-N-[2-cyano-5-[[2,6-dichloro-4-[1,2,2,3,3,3 -hexafluoro-1-(trifluoromethyl)propyl]phenyl]carbamoyl]phenyl]-2-methyl-benzamide; M.UN.11.o) 4-cyano-N-[2-cyano-5-[[2 ,6-dichloro-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]carbamoyl]phenyl]-2-methyl-benzamide; M.UN.11.p) N -[5-[[2-bromo-6-chloro-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]carbamoyl]-2-cyano-phenyl]-4 -cyano-2-methyl-benzamide; or

M.UN.12.a) 2-(1,3-dioxan-2-yl)-6-[2-(3-pyridinyl)-5-thiazolyl]-pyridine; M.UN.12.b) 2- [6-[2-(5-fluoro-3-pyridinyl)-5-thiazolyl]-2-pyridinyl]-pyrimidine; M.UN.12.c) 2-[6-[2-(3-pyridinyl)- 5-thiazolyl]-2-pyridinyl]-pyrimidine; M.UN.12.d) N-methylsulfonyl-6-[2-(3-pyridyl)thiazol-5-yl]pyridine-2-carboxamide; M.UN .12.e) N-methylsulfonyl-6-[2-(3-pyridyl)thiazol-5-yl]pyridine-2-carboxamide;

M.UN.14a) 1-[(6-chloro-3-pyridinyl)methyl]-1,2,3,5,6,7-hexahydro-5-methoxy-7-methyl-8-nitro-imidazo[1 ,2-a]pyridine; or M.UN.14b) 1-[(6-chloropyridin-3-yl)methyl]-7-methyl-8-nitro-1,2,3,5,6,7- hexahydroimidazo[1,2-a]pyridin-5-ol;

M.UN.16a) 1-isopropyl-N,5-dimethyl-N-pyridazin-4-yl-pyrazole-4-carboxamide; or M.UN.16b) 1-(1,2-dimethylpropyl)-N- Ethyl-5-methyl-N-pyridazin-4-yl-pyrazole-4-carboxamide; M.UN.16c) N,5-dimethyl-N-pyridazin-4-yl-1-(2,2,2-tri- Fluoro-1-methyl-ethyl)pyrazole-4-carboxamide; M.UN.16d) 1-[1-(1-cyanocyclopropyl)ethyl]-N-ethyl-5-methyl-N-pyridazin-4-yl -pyrazole-4-carboxamide; M.UN.16e) N-ethyl-1-(2-fluoro-1-methyl-propyl)-5-methyl-N-pyridazin-4-yl-pyrazole-4-carboxamide; M .UN.16f) 1-(1,2-dimethylpropyl)-N,5-dimethyl-N-pyridazin-4-yl-pyrazole-4-carboxamide; M.UN.16g) 1-[1-(1- M.UN.16h) N-methyl-1-(2-fluoro-1-methyl-propyl) -5-Methyl-N-pyridazin-4-yl-pyrazole-4-carboxamide; M.UN.16i) 1-(4,4-difluorocyclohexyl)-N-ethyl-5-methyl-N-pyridazine-4- or M.UN.16j) 1-(4,4-difluorocyclohexyl)-N,5-dimethyl-N-pyridazin-4-yl-pyrazole-4-carboxamide;

M.UN.17a) N-(1-methylethyl)-2-(3-pyridinyl)-2H-indazole-4-carboxamide; M.UN.17b) N-cyclopropyl-2-(3-pyridinyl)- 2H-indazole-4-carboxamide; M.UN.17c) N-cyclohexyl-2-(3-pyridinyl)-2H-indazole-4-carboxamide; M.UN.17d) 2-(3-pyridinyl)-N- (2,2,2-trifluoroethyl)-2H-indazole-4-carboxamide; M.UN.17e) 2-(3-pyridinyl)-N-[(tetrahydro-2-furanyl)methyl]-2H-indazole -5-carboxamide; M.UN.17f) Methyl 2-[[2-(3-pyridinyl)-2H-indazol-5-yl]carbonyl]hydrazinecarboxylate; M.UN.17g) N-[(2, M.UN.17h) N-(2,2-difluoropropyl)-2-(3-pyridinyl)- 2H-indazole-5-carboxamide; M.UN.17i) 2-(3-pyridinyl)-N-(2-pyrimidinylmethyl)-2H-indazole-5-carboxamide; M.UN.17j) N-[(5 -methyl-2-pyrazinyl)methyl]-2-(3-pyridinyl)-2H-indazole-5-carboxamide,

M.UN.18. tyclopyrazoflor;

M.UN.19 sarolaner, M.UN.20 lotilaner;

M.UN.21 N-[4-chloro-3-[[(phenylmethyl)amino]carbonyl]phenyl]-1-methyl-3-(1,1,2,2,2-pentafluoroethyl)-4 -(Trifluoromethyl)-1H-pyrazole-5-carboxamide; M.UN.22a 2-(3-ethylsulfonyl-2-pyridyl)-3-methyl-6-(trifluoromethyl)imidazo[4,5- b]Pyridine, or M.UN.22b 2-[3-ethylsulfonyl-5-(trifluoromethyl)-2-pyridyl]-3-methyl-6-(trifluoromethyl)imidazo[4,5-b] Pyridine;

M.UN.23 Isocycloseram;

M.UN.24a) N-[4-chloro-3-(cyclopropylcarbamoyl)phenyl]-2-methyl-5-(1,1,2,2,2-pentafluoroethyl)-4-(trifluoro methyl)pyrazole-3-carboxamide or M.UN.24b) N-[4-chloro-3-[(1-cyanocyclopropyl)carbamoyl]phenyl]-2-methyl-5-(1,1,2,2 ,2-Pentafluoroethyl)-4-(trifluoromethyl)pyrazole-3-carboxamide; M.UN.25 acynonapyr; M.UN.26 benzpyrimoxan; M.UN.27 Tigolaner (tigolaner); M.29.28 oxazosulfyl;

M.UN.29a) [(2S,3R,4R,5S,6S)-3,5-dimethoxy-6-methyl-4-propoxy-tetrahydropyran-2-yl] N-[4-[1-[4 -(trifluoromethoxy)phenyl]-1,2,4-triazol-3-yl]phenyl]carbamate; M.UN.29b) [(2S,3R,4R,5S,6S)-3,4,5- Trimethoxy-6-methyl-tetrahydropyran-2-yl] N-[4-[1-[4-(trifluoromethoxy)phenyl]-1,2,4-triazol-3-yl]phenyl]carbamate; M. UN.29c) [(2S,3R,4R,5S,6S)-3,5-dimethoxy-6-methyl-4-propoxy-tetrahydropyran-2-yl] N-[4-[1-[4-( M.UN.29d) [(2S,3R,4R,5S,6S )-3,4,5-trimethoxy-6-methyl-tetrahydropyran-2-yl] N-[4-[1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl]- 1,2,4-triazol-3-yl]phenyl]carbamate; M.UN.29.e) (2Z)-3-(2-isopropylphenyl)-2-[(E)-[4-[1- [4-(trifluoromethoxy)phenyl]-1,2,4-triazol-3-yl]phenyl]methylenehydrazono]thiazolidin-4-one or M.UN.29f) (2Z)-3-(2- isopropylphenyl)-2-[(E)-[4-[1-[4-(1,1,2,2,2-pentafluoroethoxy)phenyl]-1,2,4-triazol-3-yl] phenyl]methylenehydrazono]thiazolidin-4-one;

M.UN.30a) 2-(6-chloro-3-ethylsulfonyl-imidazo[1,2-a]pyridin-2-yl)-3-methyl-6-(trifluoromethyl)imidazo[4,5- b]Pyridine, M.UN.30b) 2-(6-bromo-3-ethylsulfonyl-imidazo[1,2-a]pyridin-2-yl)-3-methyl-6-(trifluoromethyl)imidazo[ 4,5-b]pyridine, M.UN.30c) 2-(3-ethylsulfonyl-6-iodo-imidazo[1,2-a]pyridin-2-yl)-3-methyl-6-(trifluoro methyl)imidazo[4,5-b]pyridine, M.UN.30d) 2-[3-ethylsulfonyl-6-(trifluoromethyl)imidazo[1,2-a]pyridin-2-yl]-3- Methyl-6-(trifluoromethyl)imidazo[4,5-b]pyridine, M.UN.30e) 2-(7-chloro-3-ethylsulfonyl-imidazo[1,2-a]pyridin-2-yl )-3-Methyl-6-(trifluoromethyl)imidazo[4,5-b]pyridine, M.UN.30f) 2-(3-ethylsulfonyl-7-iodo-imidazo[1,2-a]pyridine -2-yl)-3-methyl-6-(trifluoromethyl)imidazo[4,5-b]pyridine, M.UN.30g) 3-ethylsulfonyl-6-iodo-2-[3-methyl-6 -(trifluoromethyl)imidazo[4,5-b]pyridin-2-yl]imidazo[1,2-a]pyridine-8-carbonitrile, M.UN.30h) 2-[3-ethylsulfonyl-8 -Fluoro-6-(trifluoromethyl)imidazo[1,2-a]pyridin-2-yl]-3-methyl-6-(trifluoromethyl)imidazo[4,5-b]pyridine, M.UN. 30i) 2-[3-ethylsulfonyl-7-(trifluoromethyl)imidazo[1,2-a]pyridin-2-yl]-3-methyl-6-(trifluoromethylsulfinyl)imidazo[4,5- b]Pyridine, M.UN.30j) 2-[3-ethylsulfonyl-7-(trifluoromethyl)imidazo[1,2-a]pyridin-2-yl]-3-methyl-6-(trifluoromethyl ) imidazo[4,5-c]pyridine, M.UN.30k) 2-(6-bromo-3-ethylsulfonyl-imidazo[1,2-a]pyridin-2-yl)-6-(trifluoromethyl ) pyrazolo[4,3-c]pyridine.

Commercially available compounds of group M listed above can be found in The Pesticide Manual, 17th Edition, C. MacBean, British Crop Protection Council (2015), among other publications. The online Pesticide Manual is updated regularly and can be accessed through http://bcpcdata.com/pesticide-manual.html.

M.4 Cycloxapride is known from WO 2010/069266 and WO 2011/069456. M.4A.1 is known from CN 103814937; CN105367557, CN 105481839. M.4A.2, guadipyr, is known from WO 2013/003977 and M.4A.3 (licensed in China as paichongding) is known from WO 2007/101369. M.4E.1a) to M.4E.1f) are known from WO2018177970. M.22B.1 is described in CN10171577. M.22B.2 is described in CN102126994. Spiropidione M.23.1 is known from WO 2014/191271. M.28.1 and M.28.2 are known from WO2007/101540. M.28.3 is described in WO2005/077934. M.28.4 is described in WO2007/043677. M.28.5a) to M.28.5d) and M.28.5h) are described in WO 2007/006670, WO2013/024009 and WO 2013/024010, and M.28.5i) is described in WO2011/085575. M.28.5j) is described in WO2008/134969, M.28.5k) in US2011/046186, and M.28.5L) in WO2012/034403. M.28.6 can be found in WO2012/034472. M.UN.3 is known from WO2006/089633 and M.UN.4 is known from WO2008/067911. M.UN.5 is described in WO2006/043635 and biological control agents based on Bacillus firmus are described in WO2009/124707. Flupyrimin is described in WO2012/029672. M.UN.8 is known from WO2013/055584. M.UN.9.a) is described in WO2013/050317. M.UN.9.b) is described in WO2014/126208. M.UN.10 is known from WO2010/060379. Broflanilide and M.UN.11.b) to M.UN.11.h) are described in WO2010/018714, and M.UN.11.i) to M.UN.11.p) are , WO 2010/127926. M.UN.12.a) to M.UN.12.c) are known from WO2010/006713, and M.UN.12.d) and M.UN.12.e) are known from WO2012/000896. be. M.UN.14a) and M.UN.14b) are known from WO2007/101369. M.UN.16.a) to M.UN.16h) are described in WO2010/034737, WO2012/084670, and WO2012/143317, respectively, and M.UN.16i) and M.UN.16j) are , described in WO2015/055497. M.UN.17a) to M.UN.17.j) are described in WO2015/038503. M.UN.18 tyclopyrazoflor is described in US2014/0213448. M.UN.19 is described in WO2014/036056. M.UN.20 is known from WO2014/090918. M.UN.21 is known from EP2910126. M.UN.22a and M.UN.22b are known from WO2015/059039 and WO2015/190316. M.UN.23a and M.UN.23b are known from WO2013/050302. M.UN.24a and M.UN.24b are known from WO2012/126766. Acynonapyr M.UN.25 is known from WO 2011/105506. Benzpyrimoxan M.UN.26 is known from WO2016/104516. M.UN.27 is known from WO2016174049. M.UN.28 Oxazosulfyl is known from WO2017/104592. M.UN.29a) to M.UN.29f) are known from WO2009/102736 or WO2013116053. M.UN.30 is known from WO2013/050302. M.UN.30a) to M.UN.30k) are known from WO2018/052136.

The following list of fungicides that can be used with the mixture according to the invention is intended to illustrate the combination possibilities in the method according to the invention and does not impose any restrictions:

A) respiratory inhibitors
- Complex III inhibitors at the Qo site: azoxystrobin (A.1.1), coumethoxystrobin (A.1.2), coumoxystrobin (A.1.3), zymo dimoxystrobin (A.1.4), enestroburin (A.1.5), phenaminstrobin (A.1.6), fenoxystrobin/flufenoxystrobin (A.1.7), fluoxastrobin (A.1.8), kresoxim-methyl (A.1.9), mandestrobin (A.1.10), metominostrobin ) (A.1.11), orysastrobin (A.1.12), picoxystrobin (A.1.13), pyraclostrobin (A.1.14), pyrametostrobin (A. .1.15), pyraoxystrobin (A.1.16), trifloxystrobin (A.1.17), 2 (2-(3-(2,6-dichlorophenyl)-1-methyl-ali Lydenaminooxymethyl)-phenyl)-2-methoxyimino-N-methyl-acetamide (A.1.18), pyribencarb (A.1.19), triclopyricarb/chlorodincarb (A. .1.20), famoxadone (A.1.21), fenamidone (A.1.21), methyl-N-[2-[(1,4-dimethyl-5-phenyl-pyrazol-3-yl)oxyl methyl]phenyl]-N-methoxy-carbamate (A.1.22), methyltetrapole (A.1.25), (Z,2E)-5-[1-(2,4-dichlorophenyl)pyrazole-3- yl]-oxy-2-methoxyimino-N,3-dimethyl-pent-3-enamide (A.1.34), (Z,2E)-5-[1(4-chlorophenyl)pyrazol-3-yl]oxy- 2-methoxyimino-N,3-dimethyl-pent-3-enamide (A.1.35), pyriminostrobin (A.1.36), bifujunzhi (A.1.37), 2-(ortho- ((2,5-dimethylphenyl-oxymethylene)phenyl)-3-methoxy-acrylic acid methyl ester (A.1.38);

Complex III inhibitors at the -Qi site: cyazofamid (A.2.1), amisulbrom (A.2.2), [(6S,7R,8R)-8-benzyl-3-[(3-hydroxy -4-Methoxy-pyridine-2-carbonyl)amino]-6-methyl-4,9-dioxo-1,5-dioxonan-7-yl]-2-methylpropanoate (A.2.3), Fempicoxa fenpicoxamid (A.2.4), florylpicoxamid (A.2.5);

- Complex II inhibitors: benodanil (A.3.1), benzovindiflupyr (A.3.2), bixafen (A.3.3), boscalid (A.3.4), carboxin (A.3.5), fenfuram (A.3.6), fluopyram (A.3.7), flutolanil (A.3.8), fluxapyroxad (A. .3.9), furametpyr (A.3.10), isofetamid (A.3.11), isopyrazam (A.3.12), mepronil (A.3.13), oxycarboxin (A.3.14), penflufen (A.3.15), penthiopyrad (A.3.16), pydiflumetofen (A.3.17), pyraziflumid (A.3.18), sedaxane (sedaxane) (A.3.19), tecloftalam (A.3.20), thifluzamide (A.3.21), inpyrfluxam (A.3.22), pyrapropoyne (A.3.23) ), fluindapyr (A.3.28), N-[2-[2-chloro-4-(trifluoromethyl)phenoxy]phenyl]-3-(difluoromethyl)-5-fluoro-1-methyl-pyrazole -4-carboxamide (A.3.29), methyl (E)-2-[2-[(5-cyano-2-methyl-phenoxy)methyl]phenyl]-3-methoxy-prop-2-enoate (A.3.30 ), isoflucipram (A.3.31), 2-(difluoromethyl)-N-(1,1,3-trimethyl-indan-4-yl)pyridine-3-carboxamide (A.3.32), 2 -(difluoromethyl)-N-[(3R)-1,1,3-trimethylindan-4-yl]pyridine-3-carboxamide (A.3.33), 2-(difluoromethyl)-N-(3-ethyl -1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide (A.3.34), 2-(difluoromethyl)-N-[(3R)-3-ethyl-1,1-dimethyl-indan- 4-yl]pyridine-3-carboxamide (A.3.35), 2-(difluoromethyl)-N-(1,1-dimethyl-3-propyl-indan-4-yl)pyridine-3-carboxamide (A.3.36 ), 2-(difluoromethyl)-N-[(3R)-1,1-dimethyl-3-propyl-indan-4-yl]pyridine-3-carboxamide (A.3.37), 2-(difluoromethyl)- N-(3-isobutyl-1,1-dimethyl-indan-4-yl)pyridine-3-carboxamide (A.3.38), 2-(difluoromethyl)-N-[(3R)-3-isobutyl-1, 1-dimethyl-indan-4-yl]pyridine-3-carboxamide (A.3.39);

-Other respiratory inhibitors: diflumetorim (A.4.1); nitrophenyl derivatives: binapacryl (A.4.2), dinobuton (A.4.3), dinocap (A.4.4) , fluazinam (A.4.5), meptyldinocap (A.4.6), ferimzone (A.4.7); organometallic compounds: fentin salts, e.g. fentin-acetate ( fentin-acetate (A.4.8), fentin chloride (A.4.9) or fentin hydroxide (A.4.10); ametoctradin (A.4.11); silthiofam )(A.4.12);

B) Sterol biosynthesis inhibitor (SBI fungicide)
- C14 demethylase inhibitors: triazoles: azaconazole (B.1.1), bitertanol (B.1.2), bromuconazole (B.1.3), cyproconazole (B.1.4), difenoconazole (B.1.5), diniconazole (B.1.6), diniconazole-M (B.1.7), epoxiconazole (B.1.8) ), fenbuconazole (B.1.9), fluquinconazole (B.1.10), flusilazole (B.1.11), flutriafol (B.1.12), hexaco hexaconazole (B.1.13), imibenconazole (B.1.14), ipconazole (B.1.15), metconazole (B.1.17), myclobutanil (B.1.18) ), oxpoconazole (B.1.19), paclobutrazole (B.1.20), penconazole (B.1.21), propiconazole (B.1.22), prothioconazole (B.1.23), simeconazole (B.1.24), tebuconazole (B.1.25), tetraconazole (B.1.26), triadimefon (B. .1.27), triadimenol (B.1.28), triticonazole (B.1.29), uniconazole (B.1.30), 2-(2,4-difluorophenyl)-1 ,1-difluoro-3-(tetrazol-1-yl)-1-[5-[4-(2,2,2-trifluoroethoxy)phenyl]-2-pyridyl]propan-2-ol (B.1.31 ), 2-(2,4-difluorophenyl)-1,1-difluoro-3-(tetrazol-1-yl)-1-[5-[4-(trifluoromethoxy)phenyl]-2-pyridyl]propane -2-ol (B.1.32), 4-[[6-[2-(2,4-difluorophenyl)-1,1-difluoro-2-hydroxy-3-(5-sulfanyl-1,2,4 -triazol-1-yl)propyl]-3-pyridyl]oxy]benzonitrile (B.1.33), ipfentrifluconazole (B.1.37), mefentrifluconazole (B.1.38), 2-( (chloromethyl)-2-methyl-5-(p-tolylmethyl)-1-(1,2,4-triazol-1-ylmethyl)cyclopentanol (B.1.43); imidazoles: imazalil (B.1.44), pefurazoate (B.1.45), prochloraz (B.1.46), triflumizol (B.1.47); pyrimidines, pyridines, Piperazines: fenarimol (B.1.49), pyrifenox (B.1.50), triforine (B.1.51), [3-(4-chloro-2-fluoro- phenyl)-5-(2,4-difluorophenyl)isoxazol-4-yl]-(3-pyridyl)methanol (B.1.52);

-Delta 14-reductase inhibitors: aldimorph (B.2.1), dodemorph (B.2.2), dodemorph-acetate (B.2.3), fenpropimorph (B. 2.4), tridemorph (B.2.5), fenpropidin (B.2.6), piperalin (B.2.7), spiroxamine (B.2.8);

-3-Ketoreductase inhibitor: fenhexamid (B.3.1);

-Other sterol biosynthesis inhibitors: chlorphenomizole (B.4.1);

C) Nucleic acid synthesis inhibitor
-Phenylamides or acyl amino acid fungicides: benalaxyl (C.1.1), benalaxyl-M (C.1.2), kiralaxyl (C. 1.3), metalaxyl (C.1.4), metalaxyl-M (C.1.5), ofurace (C.1.6), oxadixyl (C.1.7);

-Other nucleic acid synthesis inhibitors: hymexazole (C.2.1), octhilinone (C.2.2), oxolinic acid (C.2.3), bupirimate (C.2.4), 5-fluorocytosine (C.2.5), 5-fluoro-2-(p-tolylmethoxy)pyrimidin-4-amine (C.2.6), 5-fluoro-2-(4-fluorophenylmethoxy) ) pyrimidin-4-amine (C.2.7), 5-fluoro-2-(4-chlorophenylmethoxy)pyrimidin-4-amine (C.2.8);

D) Cell division and cytoskeletal inhibitors
- Tubulin inhibitors: benomyl (D.1.1), carbendazim (D.1.2), fuberidazole (D.1.3), thiabendazole (D.1.4), thiophanate-methyl (thiophanate-methyl)(D.1.5), pyridachlomethyl(D.1.6), 3-chloro-6-methyl-5-phenyl-4-(2,4,6-trifluorophenyl)pyridazine( D.1.7), N-ethyl-2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]butanamide (D.1.8), N-ethyl-2-[(3-ethynyl-8-methyl- 6-quinolyl)oxy]-2-methylsulfanyl-acetamide (D.1.9), 2-[(3-ethynyl-8-methyl-6-quinol-yl)oxy]-N-(2-fluoroethyl)butanamide ( D.1.10), 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-N-(2-fluoroethyl)-2-methoxy-acetamide (D.1.11), 2-[(3- Ethynyl-8-methyl-6-quinolyl)oxy]-N-propyl-butanamide (D.1.12), 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-2-methoxy-N-propyl -acetamide (D.1.13), 2-[(3-ethynyl-8-methyl-6-quinolyl)oxy]-2-methylsulfanyl-N-propyl-acetamide (D.1.14), 2-[(3-ethynyl) -8-methyl-6-quinolyl)oxy]-N-(2-fluoroethyl)-2-methylsulfanyl-acetamide (D.1.15), 4-(2-bromo-4-fluoro-phenyl)-N-( 2-chloro-6-fluoro-phenyl)-2,5-dimethyl-pyrazole-3 amine (D.1.16);

-Other cell division inhibitors: diethofencarb (D.2.1), ethaboxam (D.2.2), pencycuron (D.2.3), fluopicolide (D.2.4), zoxamide ( zoxamide (D.2.5), metrafenone (D.2.6), pyriofenone (D.2.7), phenamacryl (D.2.8);

E) Amino acid and protein synthesis inhibitors
-Methionine synthesis inhibitors: cyprodinil (E.1.1), mepanipyrim (E.1.2), pyrimethanil (E.1.3);

-Protein synthesis inhibitors: blasticidin-S (E.2.1), kasugamycin (E.2.2), kasugamycin hydrochloride-hydrate (E.2.3), Mil Mildiomycin (E.2.4), streptomycin (E.2.5), oxytetracyclin (E.2.6);

F) Signal transduction inhibitors
-MAP/histidine kinase inhibitors: fluoroimid (F.1.1), iprodione (F.1.2), procymidone (F.1.3), vinclozolin (F.1.4), fludioxonil (fludioxonil)(F.1.5);
-G protein inhibitor: quinoxyfen (F.2.1);

G) Lipid and membrane synthesis inhibitors
-Phospholipid biosynthesis inhibitors: edifenphos (G.1.1), iprobenfos (G.1.2), pyrazophos (G.1.3), isoprothiolane (G.1.4);

-Lipid peroxidation: dicloran (G.2.1), quintozene (G.2.2), tecnazene (G.2.3), tolclofos-methyl (G. .2.4), biphenyl (G.2.5), chloroneb (G.2.6), etridiazole (G.2.7), zinc thiazole (G.2.8);

-Phospholipid biosynthesis and cell wall deposition: dimethomorph (G.3.1), flumorph (G.3.2), mandipropamid (G.3.3), pyrimorph (G.3.4), bench Benthiavalicarb (G.3.5), iprovalicarb (G.3.6), valifenalate (G.3.7);

- Compounds that affect cell membrane permeability and fatty acids: propamocarb (G.4.1);

- Inhibitors of oxysterol-binding proteins: oxathiapiprolin (G.5.1), fluoxapiprolin (G.5.3), 4-[1-[2-[3-(difluoromethyl)] -5-Methyl-pyrazol-1-yl]acetyl]-4-piperidyl]-N-tetralin-1-yl-pyridine-2-carboxamide (G.5.4), 4-[1-[2-[3,5 -bis(difluoromethyl)pyrazol-1-yl]acetyl]-4-piperidyl]-N-tetralin-1-yl-pyridine-2-carboxamide (G.5.5), 4-[1-[2-[3- (difluoromethyl)-5-(trifluoromethyl)pyrazol-1-yl]acetyl]-4-piperidyl]-N-tetralin-1-yl-pyridine-2-carboxamide (G.5.6), 4-[1- [2-[5-cyclopropyl-3-(difluoromethyl)pyrazol-1-yl]acetyl]-4-piperidyl]-N-tetralin-1-yl-pyridine-2-carboxamide (G.5.7), 4- [1-[2-[5-methyl-3-(trifluoromethyl)pyrazol-1-yl]acetyl]-4-piperidyl]-N-tetralin-1-yl-pyridine-2-carboxamide (G.5.8) , 4-[1-[2-[5-(difluoromethyl)-3-(trifluoromethyl)pyrazol-1-yl]acetyl]-4-piperidyl]-N-tetralin-1-yl-pyridin-2- Carboxamide (G.5.9), 4-[1-[2-[3,5-bis(trifluoromethyl)pyrazol-1-yl]acetyl]-4-piperidyl]-N-tetralin-1-yl-pyridin- 2-Carboxamide (G.5.10), (4-[1-[2-[5-cyclopropyl-3-(trifluoromethyl)pyrazol-1-yl]acetyl]-4-piperidyl]-N-tetralin-1 -yl-pyridine-2-carboxamide (G.5.11);

H) Multisite acting inhibitors
-Inorganic active substances: Bordeaux mixture (H.1.1), copper (H.1.2), copper acetate (H.1.3), copper hydroxide (H.1.4), copper oxychloride (H.1.5) , basic copper sulfate (H.1.6), sulfur (H.1.7);

-thio- and dithiocarbamates: ferbam (H.2.1), mancozeb (H.2.2), maneb (H.2.3), metam (H .2.4), metiram (H.2.5), propineb (H.2.6), thiram (H.2.7), zineb (H.2.8), ziram (H .2.9);

-Organic chlorine compounds: anilazine (H.3.1), chlorothalonil (H.3.2), captafol (H.3.3), captan (H.3.4), folpet (H.3.5), dichlofluanid (H.3.6), dichlorophen (H.3.7), hexachlorobenzene (H.3.8), pentachlorophenole (H.3.9) ) and its salts, phthalide (H.3.10), tolylfluanid (H.3.11);

-Guanidines and others: guanidine (H.4.1), dodine (H.4.2), dodine free base (H.4.3), guazatine (H. 4.4), guazatine-acetate (H.4.5), iminoctadine (H.4.6), iminoctadine-triacetate (H.4.7), iminoctadine-tris( albesilate (H.4.8), dithianon (H.4.9), 2,6-dimethyl-1H,5H-[1,4]dithino[2,3-c:5,6-c' ] Dipyrrole-1,3,5,7(2H,6H)-tetraone (H.4.10);

I) Cell wall synthesis inhibitor
-Glucan synthesis inhibitors: validamycin (I.1.1), polyoxin B (I.1.2);

-Melanin synthesis inhibitors: pyroquilon (I.2.1), tricyclazole (I.2.2), carpropamid (I.2.3), dicyclomet (I.2.4), fenoxanil (I.2.5);

J) Plant defense inducers
-acibenzolar-S-methyl (J.1.1), probenazole (J.1.2), isotianil (J.1.3), tiadinil (J.1.4), prohexadione-calcium (J.1.5); phosphonates: fosetyl (J.1.6), fosetyl-aluminum (J.1.7), phosphorous acid) and its salts (J.1.8), calcium phosphate (J.1.11), potassium phosphate (J.1.12), potassium or sodium bicarbonate (J.1.9), 4-cyclopropyl-N-(2,4- dimethoxyphenyl)thiadiazole-5-carboxamide (J.1.10);

K) The mechanism of action is unknown.
-bronopol (K.1.1), chinomethionat (K.1.2), cyflufenamide (K.1.3), cymoxanil (K.1.4), dazomet (K.1.5) , debacarb (K.1.6), diclocymet (K.1.7), diclomezine (K.1.8), difenzoquat (K.1.9), difenzoquat-methylsulfate ) (K.1.10), diphenylamine (K.1.11), fenitropan (K.1.12), fenpyrazamine (K.1.13), flumetover (K.1.14), flusulfamide ( flusulfamide) (K.1.15), flutianil (K.1.16), harpin (K.1.17), methasulfocarb (K.1.18), nitrapyrin (K.1.19), Nitrothal-isopropyl (K.1.20), tolprocarb (K.1.21), oxin-copper (K.1.22), proquinazid (K.1.23), tebufloquin )(K.1.24), tecloftalam (K.1.25), triazoxide (K.1.26), N'-(4-(4-chloro-3-trifluoromethyl-phenoxy)-2,5 -dimethyl-phenyl)-N-ethyl-N-methylformamidine (K.1.27), N'-(4-(4-fluoro-3-trifluoromethyl-phenoxy)-2,5-dimethyl-phenyl)- N-Ethyl-N-methylformamidine (K.1.28), N'-[4-[[3-[(4-chlorophenyl)methyl]-1,2,4-thiadiazol-5-yl]oxy]-2 ,5-dimethyl-phenyl]-N-ethyl-N-methyl-formamidine (K.1.29), N'-(5-bromo-6-indan-2-yloxy-2-methyl-3-pyridyl)-N -ethyl-N-methyl-formamidine (K.1.30), N'-[5-bromo-6-[1-(3,5-difluorophenyl)ethoxy]-2-methyl-3-pyridyl]-N- Ethyl-N-methyl-formamidine (K.1.31), N'-[5-bromo-6-(4-isopropylcyclohexoxy)-2-methyl-3-pyridyl]-N-ethyl-N-methyl-form Amidine (K.1.32), N'-[5-bromo-2-methyl-6-(1-phenyl-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine (K.1.33), N'-(2-methyl-5-trifluoromethyl-4-(3-trimethylsilanyl-propoxy)-phenyl)-N-ethyl-N-methylformamidine (K.1.34), N'-(5- Difluoromethyl-2-methyl-4-(3-trimethylsilanyl-propoxy)-phenyl)-N-ethyl-N-methylformamidine (K.1.35), 2-(4-chloro-phenyl)-N-[ 4-(3,4-dimethoxy-phenyl)-isoxazol-5-yl]-2-prop-2-ynyloxy-acetamide (K.1.36), 3-[5-(4-chloro-phenyl)-2, 3-Dimethyl-isoxazolidin-3-yl]-pyridine(pyrisoxazole) (K.1.37), 3-[5-(4-methylphenyl)-2,3-dimethyl-isoxazolidin-3-yl]-pyridine( K.1.38), 5-chloro-1(4,6-dimethoxy-pyrimidin-2-yl)-2-methyl-1H-benzimidazole (K.1.39), ethyl(Z) 3-amino-2-cyano- 3-phenyl-prop-2-enoate (K.1.40), picarbutrazox (K.1.41), pentyl-N-[6-[[(Z)-[(1-methyltetrazole-5- yl)-phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate (K.1.42), but-3-ynyl N-[6-[[(Z)-[(1-methyltetrazol-5-yl) )-Phenyl-methylene]amino]oxymethyl]-2-pyridyl]carbamate (K.1.43), ipflufenoquin (K.1.44), quinofumelin (K.1.47), benzisothiazolinone (benziothiazolinone) (K.1.48), bromothalonil (K.1.49), 2-(6-benzyl-2-pyridyl)quinazoline (K.1.50), 2-[6-(3-fluoro-4-methoxy) -phenyl)-5-methyl-2-pyridyl]quinazoline (K.1.51), dichlobentiazox (K.1.52), N'-(2,5-dimethyl-4-phenoxy-phenyl)-N -ethyl-N-methyl-formamidine (K.1.53), pyrifenamine (K.1.54), fluopimomide (K.1.55), N'-[5-bromo-2-methyl-6-( 1-Methyl-2-propoxy-ethoxy)-3-pyridyl]-N-ethyl-N-methyl-formamidine (K.1.56).

The fungicides described by their common names, their preparation and their activity against harmful fungi are known (http://www.alanwood.net/pesticides/) and these substances are commercially available. The fungicides described by IUPAC nomenclature, their preparation and their pesticidal activity are also known (Can. J. Plant Sci. 48(6), 587-94, 1968; EP-A 141 317; EP-A 152 031; EP-A 226 917; EP-A 243 970; EP-A 256 503; EP-A 428 941; EP-A 532 022; EP-A 1 028 125; EP-A 1 035 122; EP-A 1 201 648; EP-A 1 122 244, JP 2002316902; DE 19650197; DE 10021412; DE 102005009458; US 3,296,272; US 3,325,503; WO 98/46608; WO 99/14187; WO 99/24413; WO 99/ 27783; WO 00/29404; WO 00/46148; WO 00/65913; WO 01/54501; WO 01/56358; WO 02/22583; WO 02/40431; WO 03/10149; WO 03/11853; WO 03/ WO 03/16286; WO 03/53145; WO 03/61388; WO 03/66609; WO 03/74491; WO 04/49804; WO 04/83193; WO 05/120234; WO 05/123689; WO 05/ WO 05/63721; WO 05/87772; WO 05/87773; WO 06/15866; WO 06/87325; WO 06/87343; WO 07/82098; WO 07/90624, WO 10/139271, WO 11/ 028657, WO12/168188, WO07/006670, WO11/77514; WO13/047749, WO 10/069882, WO 13/047441, WO 03/16303, WO 09/90181, WO 13/007767, WO 13/010862, WO 1 3 CN 1907024, CN 1456054, CN 103387541, CN 1309897, WO 12/84812 , CN 1907024, WO 09094442, WO 14/60177, WO 13/116251, WO 08/013622, WO 15/65922, WO 94/01546, EP 2865265, WO 07/129454, WO 12/165511, WO 11/08117 4, WO 13/47441 WO 16/156241, WO 16/162265). Some compounds are identified by their CAS Registry Number, which is divided into three parts by a hyphen: the first consists of 2 to 7 digits, the second consists of 2 digits, and the third consists of 1 digit.

If the mixture according to the invention is mixed with one or more fungicides, the mixture is also suitable for combating or controlling plant diseases caused by phytopathogenic fungi. Examples of phytopathogenic fungi in rice are: Alternaria species in rice, Bipolaris (e.g. Bipolaris oryzae), and Drechslera species in rice. species), Cercospora oryzae, Cochliobolus miyabeanus, Curvularia lunata, Sarocladium oryzae, S. attenuatum, Entyloma oryzae , Fusarium spp, such as Fusarium semitectum (and/or moniliforme), Gibberella fujikuroi (bakanae), grain staining complex fungi (Grainstaining complex) (various pathogens) and/or Pythium ssp, Helminthosporium. spp, e.g. Helminthosporium oryzae , Microdochium oryzae, Pyricularia grisea (syn. Pyricularia oryzae), Rhizoctonia species, such as Rhizoctonia solani (syn. Pyricularia grisea in rice). Pellicularia sasakii), Corticium sasakii and Ustilaginoidea virens.

Formulation The invention also relates to a method in which the compounds of the mixture according to the invention are provided and applied in an agrochemical composition comprising an adjuvant and a mixture according to the invention. The compounds may be present together in one formulation (for simultaneous use and) or in two separate formulations (for mixing immediately before simultaneous application or for separate application). It's okay.

The agrochemical composition comprises a pesticidally effective amount of a compound of the invention or a mixture thereof. The term "pesticidally effective amount" is defined below.

The mixtures according to the invention can be used, for example, in solutions, emulsions, suspensions, dusts, powders, pastes, gramules, compresses. It can be converted into conventional types of agrochemical compositions, such as pressings, capsules and mixtures thereof. Examples of types of compositions are suspensions (e.g. SC, OD, FS), emulsifiable concentrates (e.g. EC), emulsions (e.g. EW, EO, ES, ME), capsules (e.g. , CS, ZC), pastes, pastilles, wettable powders or wettable dusts (e.g. WP, SP, WS, DP, DS), compaction agents (e.g. BR , TB, DT), granules (e.g. WG, SG, GR, FG, GG, MG), insecticidal articles (e.g. LN), and gels for the treatment of plant propagation materials, e.g. seeds. gel formulations (eg GF). These and further composition types are defined in the "Catalogue of pesticide formulation types and international coding system", Technical Monograph No. 2, 6th edition May 2008, CropLife International.

The compositions are prepared by known methods as described, for example, in Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001, or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005. be done.

Examples of suitable auxiliaries are solvents, liquid carriers, solid carriers or fillers, surfactants, dispersants, emulsifiers, wetters, adjuvants, solubilizers, penetration enhancers, protective colloids, binders. (adhesion agents), thickeners, humectants, repellents, attractants, feeding stimulants, compatibilizers, bactericides, antifreeze agents, antifoaming agents, colorants, adhesives and binders.

Suitable solvents and liquid carriers are water and organic solvents, for example kerosene, medium to high boiling mineral oil fractions such as diesel oil, oils of vegetable or animal origin, fats such as toluene, paraffins, tetrahydronaphthalenes, alkylated naphthalenes. group, cyclic and aromatic hydrocarbons, alcohols such as ethanol, propanol, butanol, benzyl alcohol, cyclohexanol, glycols, ketones such as DMSO, cyclohexanone, lactic acid esters, carbonic esters, fatty acid esters, gamma-butyrolactone, etc. These include esters, fatty acids, phosphonates, amines, amides such as N-methylpyrrolidone and fatty acid dimethylamide, and mixtures thereof.

Suitable solid carriers or fillers are, for example, mineral earths such as silicates, silica gel, talc, kaolin, limestone, lime, chalk, clay, dolomite, diatomaceous earth, bentonite, calcium sulfate, magnesium sulfate, magnesium oxide, cellulose, starch, etc. polysaccharide powder, fertilizers such as ammonium sulfate, ammonium phosphate, ammonium nitrate, urea, plant-derived products such as cereal flour, bark flour, wood flour, nut shell flour, and mixtures thereof.

Suitable surfactants are surface-active compounds such as anionic, cationic, nonionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. Such surfactants can be used as emulsifiers, dispersants, solubilizers, wetting agents, penetration enhancers, protective colloids or auxiliaries. Examples of surfactants are listed in McCutcheon's, Vol. 1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Ed. or North American Ed.).

Suitable anionic surfactants are alkali, alkaline earth or ammonium salts of sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulfonates are alkylaryl sulfonates, diphenyl sulfonates, alpha-olefin sulfonates, lignin sulfonates, sulfonates of fatty acids and fatty oils, sulfonates of ethoxylated alkylphenols, sulfonates of alkoxylated arylphenols, sulfonates of condensed naphthalenes, dodecyl- and tridecyl Sulfonates of benzene, sulfonates of naphthalene and alkylnaphthalenes, sulfosuccinates or sulfosuccinamates. Examples of sulfates are sulfates of fatty acids and fatty oils, sulfates of ethoxylated alkylphenols, sulfates of alcohols, sulfates of ethoxylated alcohols or sulfates of fatty acid esters. Examples of phosphates are phosphoric acid esters. Examples of carboxylates are alkyl carboxylates and carboxylated alcohols or alkylphenol ethoxylates.

Suitable nonionic surfactants are alkoxylates, N-substituted fatty acid amides, amine oxides, esters, sugar-based surfactants, polymeric surfactants, and mixtures thereof. Examples of alkoxylates are compounds such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters, alkoxylated with 1 to 50 equivalents. Ethylene oxide and/or propylene oxide, preferably ethylene oxide, can be used for the alkoxylation. Examples of N-substituted fatty acid amides are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar-based surfactants are sorbitan, ethoxylated sorbitan, sucrose and glucose esters, or alkyl polyglucosides. Examples of polymeric surfactants are homo- or copolymers of vinylpyrrolidone, vinyl alcohol or vinyl acetate.

Suitable cationic surfactants are, for example, quaternary surfactants, such as quaternary ammonium compounds having one or two hydrophobic groups, or salts of long-chain primary amines. Suitable amphoteric surfactants are alkyl betaines and imidazolines. Suitable block polymers are block polymers of the A-B or A-B-A type, comprising blocks of polyethylene oxide and polypropylene oxide, or of the A-B-C type, comprising alkanols, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are polyacrylic acids or alkali salts of polyacid comb polymers. Examples of polybases are polyvinylamine or polyethyleneamine.

Suitable adjuvants are compounds which themselves have negligible or no pesticidal activity and which improve the biological action of the mixture of the invention on the target. . Examples are surfactants, mineral or vegetable oils, and other auxiliaries. Further examples are listed in Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa UK, 2006, chapter 5.

Suitable thickeners are polysaccharides (eg xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or unmodified clays), polycarboxylates, and silicates.

Suitable bactericides are bronopol and isothiazolinone derivatives such as alkylisothiazolinones and benzisothiazolinones.

Suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerin.

Suitable antifoam agents are silicones, long chain alcohols and salts of fatty acids.

Suitable colorants (eg red, blue or green) are poorly water soluble pigments and water soluble dyes. Examples are inorganic colorants (eg iron oxide, titanium oxide, iron hexacyanoferrate) and organic colorants (eg alizarin-, azo-, and phthalocyanine colorants).

Suitable adhesives or binders are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol, polyacrylates, biological or synthetic waxes, and cellulose ethers.

Examples regarding types of compositions and their preparation are as follows.

i) water-soluble concentrate (SL, LS)
10 to 60% by weight of a compound I or II or a mixture according to the invention and 5 to 15% by weight of a wetting agent (for example an alcohol alkoxylate) are dissolved in water and/or a water-soluble solvent (for example an alcohol). Make it 100% by weight. The active substance dissolves when diluted with water.

ii) Dispersible concentrate (DC)
5 to 25% by weight of a compound I or II according to the invention or a mixture according to the invention and 1 to 10% by weight of a dispersant (for example polyvinylpyrrolidone) are dissolved in an organic solvent (for example cyclohexanone) to give 100% by weight. Make it. Dilution with water gives a dispersion.

iii) Emulsifiable concentrate (EC)
15 to 70% by weight of a compound I or II or a mixture according to the invention and 5 to 10% by weight of an emulsifier (e.g. calcium dodecylbenzenesulfonate and castor oil ethoxylate) in a water-insoluble organic solvent (e.g. an aromatic hydrocarbon) to 100% by weight. Dilution with water gives an emulsion.

iv) Emulsion (EW, EO, ES)
5 to 40% by weight of a compound I or II according to the invention or a mixture according to the invention and 1 to 10% by weight of an emulsifier (for example calcium dodecylbenzenesulfonate and castor oil ethoxylate) are combined with 20 to 40% by weight of a Dissolves in water-soluble organic solvents (eg aromatic hydrocarbons). This mixture is introduced into water through an emulsifying device to 100% by weight to form a homogeneous emulsion. Dilution with water gives an emulsion.

v) Suspension (SC, OD, FS)
In a stirred ball mill, 20 to 60% by weight of the compound I or II or the mixture according to the invention are mixed with 2 to 10% by weight of dispersants and wetting agents (for example sodium lignosulfonate and alcohol ethoxylates), 0.1 to 2 By adding % by weight of a thickener (for example xanthan gum) and 100% by weight of water and comminution, a fine suspension of the active substance is obtained. Dilution with water gives a stable suspension of the active substance. For FS type compositions up to 40% by weight of binder (eg polyvinyl alcohol) is added.

vi) water-dispersible granules and water-soluble granules (WG, SG)
From 50 to 80% by weight of the compound I or II according to the invention or the mixture is finely ground with the addition of up to 100% by weight of dispersants and wetting agents (for example sodium lignosulfonate and alcohol ethoxylates) and prepared in a dedicated apparatus ( For example, they are prepared as water-dispersible or water-soluble granules using extruders, spray towers, fluidized beds). Dilution with water gives a stable dispersion or solution of the active substance.

vii) water-dispersible powder and water-soluble powder (WP, SP, WS)
In a rotor-stator mill, 50-80% by weight of the compound I or II or mixture according to the invention, 1-5% by weight of a dispersing agent (e.g. sodium lignosulfonate), 1-3% by weight of a wetting agent (e.g. alcohol ethoxylate) and up to 100% by weight of a solid support (eg silica gel) and mill. Dilution with water gives a stable dispersion or solution of the active substance.

viii) Gel (GW, GF)
In a stirred ball mill, 5 to 25% by weight of the compound I or II or the mixture according to the invention are mixed with 3 to 10% by weight of a dispersing agent (for example sodium lignosulfonate), 1 to 5% by weight of a thickening agent ( (e.g. carboxymethylcellulose) and up to 100% by weight of water to obtain a fine suspension of the active substance. Dilution with water gives a stable suspension of the active substance.

ix) microemulsion (ME) or nanoemulsion
5 to 20% by weight of a compound I or II or a mixture according to the invention, 5 to 30% by weight of an organic solvent blend (e.g. fatty acid dimethylamide and cyclohexanone), 10 to 25% by weight of a surfactant blend (e.g. alcohol ethoxy esters and arylphenol ethoxylates) and up to 100% by weight of water. This mixture is stirred for 1 hour, spontaneously forming a thermodynamically stable microemulsion.

x) Microcapsule (CS)
5-50% by weight of the compound I or II or the mixture according to the invention, 0-40% by weight of water-insoluble organic solvents (e.g. aromatic hydrocarbons), 2-15% by weight of acrylic monomers (e.g. methyl methacrylate). , methacrylic acid, and di- or triacrylates) is dispersed in an aqueous solution of a protective colloid (eg, polyvinyl alcohol). Poly(meth)acrylate microcapsules are formed by radical polymerization initiated by a radical initiator. Alternatively, 5-50% by weight of a compound I or II or a mixture according to the invention, 0-40% by weight of a water-insoluble organic solvent (e.g. an aromatic hydrocarbon) and an isocyanate monomer (e.g. diphenylmethene-4,4 '-diisocyanate) is dispersed in an aqueous solution of a protective colloid (eg, polyvinyl alcohol). Addition of a polyamine (eg hexamethylene diamine) forms polyurea microcapsules. The monomers will total 1-10% by weight. Weight % refers to the total amount of CS composition.

xi) Dustable powder (DP, DS)
From 1 to 10% by weight of the compound I or II according to the invention or the mixture is ground and thoroughly mixed with up to 100% by weight of a solid carrier (eg finely ground kaolin).

xii) Granules (GR, FG)
From 0.5 to 30% by weight of the compound I or II according to the invention or the mixture is ground and combined with up to 100% by weight of a solid carrier (for example a silicate). Granules are obtained by extrusion, spray drying or fluidized bed.

xiii) Ultra-low volume liquid (UL)
1 to 50% by weight of the compound I or II or the mixture according to the invention is dissolved in an organic solvent (for example an aromatic hydrocarbon) to 100% by weight.

Composition types i) to xiii) include 0.1 to 1% by weight bactericide, 5 to 15% by weight antifreeze agent, 0.1 to 1% by weight antifoam agent, and 0.1 to 1% by weight colorant, etc. Further auxiliaries may optionally be included.

Agrochemical compositions generally contain from 0.01 to 95% by weight of active substance, preferably from 0.1 to 90%, most preferably from 0.5 to 75%. The active substance is used in a purity of 90% to 100%, preferably 95% to 100% (according to NMR spectroscopy).

A wide variety of oils, wetting agents, adjuvants, fertilizers or micronutrients, and other pesticides (e.g. herbicides, insecticides, fungicides, growth regulators, safeners), as premixes or If appropriate, it can be added to the active substances or compositions containing them immediately before use (tank mixing). These agents can be mixed with the composition according to the invention in a weight ratio of 1:100 to 100:1, preferably 1:10 to 10:1.

In one embodiment, SC formulations (suspoconcentration (SC)) are preferred for applications in crop protection. In one subembodiment thereof, the SC pesticide composition is 50-500 g/L (grams per liter), or 100-250 g/L, or 100 g/L or 150 g/L, or 200 g/L or 250 g/L. Contains L.

In a further embodiment, granules according to formulation type xii) are used for application in rice according to the invention.

In a further embodiment, a Dispersible concentrate (DC) according to formulation type ii) is used for application in rice according to the invention.

In a further embodiment, emulsifiable concentrates (EC) according to formulation type iii) are used for application in rice according to the invention. ix.ME).

In a further embodiment, a microemulsion (ME) according to formulation type ix) is used for application in rice according to the invention.

In a further embodiment, nanoemulsions are used for application in rice according to the invention.

The user typically applies the composition according to the invention from a pre-dosing device, backpack sprayer, spray tank, spray plane or irrigation system. Usually, agrochemical compositions are prepared to the desired application concentration using water, buffers and/or further auxiliaries, and ready-to-use spray solutions or agrochemical compositions according to the invention are thus obtained. Usually 20 to 2000 liters, preferably 50 to 400 liters of ready-to-use spray solution are applied per hectare of agricultural land.

According to one embodiment, the individual components of the composition according to the invention, for example part of a kit or part of a binary or ternary mixture, can be mixed by the user himself in a spray tank and in a suitable manner. If necessary, further auxiliaries can be added.

In a further embodiment, each component of the composition according to the invention, or some premixed components, e.g. a component comprising a compound or mixture of the invention and/or a further mixing partner as defined above, is provided by the user. The mixture may be mixed in a spray tank by a method, and further auxiliaries and additives may be added if appropriate.

In a further embodiment, each component of the composition according to the invention, or some premixed components, e.g. a component comprising a compound or mixture of the invention and/or a further mixing partner as defined above (e.g. may be applied together (after tank mixing) or sequentially.

Method of application The invention also provides that the mixture according to the invention can be applied to crops and their plant propagation materials, such as seeds, in particular rice, rice plants, rice plant propagation materials, such as seeds, or the soil in which the plants or rice plants are grown. or to a method suitable for use in protecting water from attack or damage by pests or rice pests, particularly rice pest invertebrates. The present invention therefore also provides for crops or plant propagation material, rice, rice plants, rice plant propagation material, e.g. It also relates to a method for protecting plants, comprising the step of contacting soil or water with a pesticidal effective amount of a mixture according to the invention.

The present invention also provides a method for exterminating or controlling pests, especially rice pests, especially rice pest invertebrates, comprising: controlling pests, especially rice pests, especially rice pest invertebrates, their habitat, breeding; crops and their plant propagation materials, such as seeds, especially rice, rice plants, rice plants, on which the pests or rice pests, especially rice pest invertebrates, grow or can grow; It also relates to a method comprising contacting propagation material, such as seeds, or soil or water, or an area, material or environment, with a pesticidal effective amount of a compound of the invention.

The mixture of the invention is effective both in contact and ingestion. Furthermore, the mixtures of the invention can be applied to any and all developmental stages, such as eggs, larvae, pupae and adults.

The mixtures of the invention can be applied as such or in the form of compositions containing them as defined above. Furthermore, the mixtures of the invention can be applied together with further mixing partners as defined above or in the form of compositions comprising said mixtures as defined above. The components of the mixture can be applied simultaneously, together or separately, or sequentially (which means that the mixture can be applied "in situ" at the desired location, e.g. a plant), by applying immediately one after the other. (produced), can be applied and the order in the case of separate applications generally has no effect on the result of the control measure.

The application is carried out both before and after infestation of crops and their plant propagation materials, such as seeds, in particular rice, rice plants, rice plant propagation materials, such as seeds, soil, or areas, materials or environments with pests. be able to.

Suitable application methods include soil treatment, seed treatment, in-furrow application, water inlet application and foliar application, among others. Soil treatment methods include soil irrigation, root soaking, or soil injection. Seed treatment techniques include seed dressing, seed coating, seed dusting, seed dipping, and seed pelleting. Furrow application typically includes the steps of creating a furrow in the field, seeding the furrow, applying a pesticidal compound to the furrow, and closing the furrow. Foliar application refers to the application of a pesticidally active compound to the foliage of a plant, for example by means of a spray device. For foliar applications, it may be advantageous to modify the behavior of pests by using pheromones in combination with the mixtures of the invention. Suitable pheromones for particular crops and pests are known by those skilled in the art and are publicly available from databases of pheromones and semiochemicals (eg, http://www.pherobase.com).

In the context of rice cultivation and rice crops, the following application types are particularly relevant:
- "Granular application" is the application of insecticidal granules or mixtures of insecticides/fungicides and nematicides directly to the field or nursery box (either on the soil surface or in standing water). manual or mechanical spreading or casting. The granular formulation may be mixed with fillers, carriers or fertilizers to enable uniform distribution in the field.

- "Floating packet application" refers to the application of insecticides or mixtures of insecticides/fungicides and nematicides in water-soluble sachets/packets by dumping them into standing water in rice fields. .

- "Seedling box application" refers to the manual or mechanical incorporation of insecticidal formulations (e.g. granules, liquids) in seedling boxes or nursery boxes containing rice seedlings before being transplanted into the main field. Point.

- "Seed treatment" includes soaking/mixing of rice seeds in a solution of an insecticide or an insecticide/nematode/fungicide mixture. This application is carried out either before sowing, before or after seed germination.

- "Foliar application" means an insecticide in water or oil as a spray application using various application devices (e.g. knapsacks, power sprayers, boom sprayers, etc.) Refers to the application of nematicides/selective herbicides.

- "Soil application" means the application of an insecticide or a mixture of insecticides/fungicides/nematicides/selective herbicides into the soil as a irrigation application, a water drop application or a granule application; refers to

- "Aerial application" means the application of granular or liquid formulations of insecticides or mixtures of insecticides/fungicides/nematicides/selective herbicides to fields using an airplane, helicopter or drone. refers to

- "Dust application" means an insecticide as a dust formulation or a mixture of insecticides/fungicides/nematicides/selective herbicides using a special applicator (e.g. a power duster) Direct application to the field.

- "Water inlet application" is a liquid application of an insecticide or insecticide/fungicide/nematicide/selective herbicide mixture at the point where irrigation water is released into a rice field. application of the formulation.

- "Encircling application" means that a liquid or granular formulation of an insecticide or mixture of insecticides/fungicides/nematicides/selective herbicides is applied in a clockwise or counterclockwise direction to the inner border of a rice field. This is a type of application applied to standing water in a clockwise direction.

Preferred applications are granule application, nursery box application and foliar application.

In one embodiment, the invention relates to a method of applying a pesticide by granule application.

In one embodiment, the present invention relates to a method of applying a pesticide by nursery box application.

In one embodiment, the invention relates to a method of applying a pesticide by foliar application.

As used herein, the term "contacting" refers to direct contact (applying the compound/composition directly to the animal pest or to the plant (typically to the leaves, stems or roots of the plant)), and Indirect contact (applying a compound/composition to an animal pest or plant location, i.e. a habitat, breeding ground, plant, seed, soil, area, material or environment where the pest grows or can grow) ).

In the context of the present invention, the term "animal pest" includes pests, in particular rice pests (in particular rice pest invertebrates), especially the rice pest insects mentioned above, arthropods, gastropods and nematodes. Arthropods are preferably insects and arachnids, especially insects. Insects, particularly related insects, are typically referred to as crop insect pests or rice pests.

The term "crop" refers to both growing and harvested rice.

In the context of the present invention, the term "plant" preferably means a rice plant (Oryza species, preferably Oryza sativa). Two rice species, Oryza sativa and Oryza glaberrima, are most frequently cultivated. A number of subspecies of Oryza sativa are commercially important, such as Oryza sativa subsp. indica, Oryza sativa subsp. japonica, Oryza sativa subsp. javanica, Oryza sativa subsp. glutinosa (glutinous rice), Oryza sativa Aromatica group (e.g. basmati) ), and Oryza sativa (floating rice group). The term "plant" is understood to include wild-type plants and plants that have been modified either by conventional breeding or by mutagenesis or genetic engineering, or a combination thereof.

Rice is a particularly commercially important plant that has been modified by mutagenesis or genetic engineering. In plants that have been modified by mutagenesis or genetic engineering, one or more genes have been mutagenized or integrated into the plant's genetic material. The one or more mutagenized or integrated genes are preferably pat, epsps, cry1Ab, bar, cry1Fa2, cry1Ac, cry34Ab1, cry35AB1, cry3A, cryF, cry1F, mcry3a, cry2Ab2, cry3Bb1, cry1A.105, selected from dfr, barnase, vip3Aa20, barstar, als, bxn, bp40, asn1, and ppo5. Mutagenesis or integration of one or more genes is carried out to improve certain characteristics of plants. Such properties, also known as traits, include, for example, abiotic stress tolerance, altered growth/yield, disease resistance, herbicide tolerance, insect resistance, modified product quality, and pollination control. Examples include. Of these properties, herbicide tolerance, such as imidazolinone tolerance, glyphosate tolerance, or glufosinate tolerance, is particularly important.

Surprisingly, it has been found that the pesticidal activity of the mixtures of the invention can be enhanced by the insecticidal traits of the modified plants. Furthermore, the mixture of the invention can be used to prevent insects from becoming resistant to insecticidal traits or to control pests that are already resistant to insecticidal traits in modified plants. It has been found that it is suitable for Furthermore, the mixtures of the invention are suitable for combating pests for which insecticidal traits are not effective, so that complementary insecticidal activities can be used advantageously.

The term "plant propagation material" refers to all generative parts of a plant, such as seeds, germinated seeds, seedlings and seedlings. Seedlings and young plants that are transplanted after germination or after emergence from the soil may also be included. These plant propagation materials can be treated prophylactically with plant protection compounds at or before planting or transplanting.

The term "seed" refers to seeds and all kinds of plant vegetative propagules, such as, but not limited to, true seeds, seed pieces, suckers, corms, fruits, grains, cuttings, cut shoots, etc. and in preferred embodiments refers to true seeds.

Generally, a "pesticidal effective amount" means an observable effect on growth (e.g., necrosis, killing, retardation, prevention, and removal, destruction, or reducing the occurrence and activity of a target organism). means the amount of active ingredient required to obtain A pesticidally effective amount may vary for the various compounds/compositions used in the present invention. The pesticidal effective amount of the composition will also vary depending on the prevailing conditions, such as the desired pesticidal effect and duration, weather, target species, location, mode of application, and the like.

For soil treatment, furrow application or application to pest habitats or nests, the amount of active ingredient ranges from 0.0001 to 500 g per 100 m ² , preferably from 0.001 to 20 g per 100 m ² .

For use in the treatment of rice plants (e.g. by foliar application), the application rate of the active ingredient according to the invention is from 0.0001 g to 4000 g per hectare, such as from 1 g to 2 kg per hectare, or from 1 g to 750 g per hectare. , preferably 1 g to 100 g per hectare, more preferably 10 g to 50 g per hectare, such as 10 to 20 g per hectare, 20 to 30 g per hectare, 30 to 40 g per hectare, or 40 to 50 g per hectare. It can be within the range.

The mixtures of the invention are suitable for use in the treatment of seeds for protecting seeds from insect pests, in particular from soil-dwelling insect pests, and for protecting the roots and shoots of the resulting seedlings from soil pests and foliar insects. Particularly suitable. The invention therefore also provides a method for protecting seeds from insects, in particular from soil insects, and for protecting seedling roots and shoots from insects, in particular from soil insects and foliar insects, said method comprising: The present invention also relates to the above-mentioned method, which comprises treating the seeds with a compound of the invention before sowing and/or after pre-germination treatment. Protection of roots and shoots of seedlings is preferred. More preferred is the protection of seedling shoots from piercing and sucking insects, chewing insects and nematodes.

The term "seed treatment" includes all suitable seed treatment techniques known in the art, such as seed dusting, seed coating, seed dusting, seed dipping, seed pelleting, and furrow application. include. Preferably, the seed treatment application of the active compound is carried out by spraying or dusting the seeds before sowing the plants and before the emergence of the plants.

The invention also includes seeds coated with or containing active compounds. The term "coated with and/or containing" generally means that the majority of the active ingredient is on the surface of the propagation product at the time of application, but depending on the method of application, the amount of the ingredient A greater or lesser proportion may penetrate into the breeding product. When the propagation product is (re)planted, it is able to absorb the active ingredient.

In the context of the present invention, seeds are rice seeds. The active compounds of the invention can also be used for the treatment of seeds derived from plants that have been modified by mutagenesis or genetic engineering and which are resistant to the action of, for example, herbicides or fungicides or insecticides. Such modified plants are described in detail above.

Conventional seed treatment formulations include, for example, flowable concentrates FS, solutions LS, suspoemulsions (SE), powders for dry treatment DS, and slurry treatments. Examples include water dispersible powders for slurry treatment WS, water-soluble powders SS, emulsions ES and EC, and gel formulations GF. These formulations can be applied to seeds diluted or undiluted. Application to the seeds is carried out either directly on the seeds before sowing or after pregermination of the seeds. Preferably, the formulation is applied in such a way that germination is not involved.

The active substance concentration in the ready-to-use formulation, which can be obtained after a 2- to 10-fold dilution, is preferably between 0.01 and 60% by weight, more preferably between 0.1 and 40% by weight.

In a preferred embodiment, the FS formulation is used for seed treatment. Typically, FS formulations contain 1-800g/L active ingredient, 1-200g/L surfactant, 0-200g/L antifreeze, 0-400g/L binder, 0-200g /L of pigment and up to 1 liter of solvent, preferably water.

Particularly preferred FS formulations of the mixtures of the invention for seed treatment typically contain 0.1 to 80% by weight (1 to 800 g/L) of active ingredient, 0.1 to 20% by weight (1 to 200 g/L) of at least one Surfactants, such as 0.05-5% by weight wetting agents and 0.5-15% by weight dispersing agents, up to 20% by weight (eg 5-20%) antifreezes, 0-15% by weight (eg 1-15% by weight) %) of pigments and/or dyes, 0 to 40% by weight (e.g. 1 to 40% by weight) of binders (spreading agents/adhesives), optionally up to 5% by weight (e.g. 0.1 to 5% by weight). viscosity agent, optionally 0.1-2% antifoaming agent, and optionally preservatives (e.g. biocides, antioxidants, etc.) in an amount of eg 0.01-1% by weight, and further filler/vehicle 100%. Including weight%.

In the treatment of seeds, the application rate of the compounds of the invention is generally between 0.1 g and 10 kg per 100 kg of seeds, preferably between 1 g and 5 kg per 100 kg of seeds, more preferably between 1 g and 1000 g per 100 kg of seeds, and especially per 100 kg of seeds. 1 g to 200 g, for example 1 g to 100 g per 100 kg of seeds, or 5 g to 100 g.

The present invention therefore also relates to seeds comprising a compound of the invention as defined herein, or an agriculturally useful salt thereof. The amount of the compound of the invention or an agriculturally useful salt thereof will generally vary from 0.1 g to 10 kg per 100 kg of seed, preferably from 1 g to 5 kg per 100 kg of seed, especially from 1 g to 1000 g per 100 kg of seed.

In the present invention, the mixture according to the invention can also be used to improve the health of plants. Accordingly, the present invention also provides for treating rice plants, rice plant propagation material and/or sites where rice plants are growing or intended to be grown with an effective and non-phytotoxic amount of a compound of the invention. It also relates to methods of improving the health of plants by treatment.

As used herein, an "effective and non-phytotoxic amount" means that the compound has a desired effect in the treated plant, or in plants grown from the treated vegetative propagules or the treated soil. It is meant to be used in an amount that makes it possible to obtain phytotoxicity without producing any phytotoxic symptoms.

The terms "plant" and "plant propagation material" are defined above.

"Plant health" refers to yield (e.g. increased biomass and/or increased content of useful components), quality (e.g. content or composition of specific components, or improved shelf life), plant vigor (e.g. improved plant growth and/or darker green leaves (“greening effect”)), resistance to abiotic stresses (e.g. drought) and/or biotic stresses (e.g. diseases), and production efficiency (e.g. It is defined as the condition of a plant and/or its products, which is determined by several aspects such as yield rate, processability), alone or in combination with each other.

The indicators of plant health identified above are interdependent and they can arise from each other. Each index is defined in the art and can be determined by methods known to those skilled in the art.

Examples The compounds benzpyrimoxane and oxazosulfil are described in the Pesticide Manual and are commercially available or their synthesis is known.

Biological Testing Synergy can be described as an interaction in which the combined effect of two or more compounds is greater than the sum of the individual effects of each compound (zero interaction). To quantify the degree of drug synergy, we used the Highest single agent model (HSA, or Gaddum additivity) (Berenbaum, 1989), the Loewe additivity model (Loewe, 1953), and the Bliss independence model. Several models have been proposed, including one based on (Bliss, 1939).
In the present case, the two mixed partners are mutually non-exclusively active, i.e. the Bliss independence model is considered most appropriate to describe the zero interaction effect (Greco et al., 1992), and here , yBLISS is the expected effect based on the compound's single-drug effects y1 and y2, respectively (1).

A reference model is used that is particularly useful for analyzing matrix data from plate-based high-throughput experiments (Yadav et al., 2015). This model is called zero interaction potency (ZIP), which overcomes many of the limitations of existing models and is based on independent dose-response curves for each of the two mixing partners. By combining the advantages of both the Loewe and Bliss models, the ZIP model assumes that two non-interacting drugs are expected to experience minimal change in their dose-response curves. In the ZIP model (Yadav et al., 2015, equation 16), the zero interaction situation (yZIP) is defined according to equation (2), where X1 and X2 are the doses of compounds 1 and 2, m1 and m2 are the doses of compounds The dose that produces the midpoint effect, also known as the relative EC50 or IC50 of 1 and 2, where λ1 and λ2 (λ>0) are shape parameters indicating the sigmoidal character or slope of the curves for compounds 1 and 2.

The average delta score is calculated from the expected and observed values of ZIP(δ) for each dose combination in the matrix. This allows surface plots of delta scores to visualize the interaction landscape for drug combinations, with the aim of identifying synergistic and antagonistic dose regions for further dose optimization in validation screens. do. Delta scores have units of percent inhibition and are directly comparable within and between drug combinations. Finally, the average of all dose combination delta scores in the matrix can be calculated. The average score (percentage) is referred to as the "ZIP synergy score" for the ZIP model and the "Bliss synergy score" for the Bliss model.

An R script called "syngergyfinder" based on the above model has been published by He, L. et al. (2018). Bioconductor. It can also be downloaded from:
http://bioconductor.org/packages/release/bioc/html/synergyfinder.html

The following tests demonstrate the control efficacy of the compounds, mixtures or compositions of the invention against specific pests. However, the pest control protection provided by the compound, mixture or composition is not limited to these species. In certain instances, combinations of compounds of the invention with other invertebrate pest control compounds or agents have been found to exhibit synergistic effects against certain important invertebrate pests.

The tested mixture consists of two components benzpyrimoxane and oxazosulfyl belonging to two different mechanisms of action (IRAC classification).

Test 1: Tobacco budworm (Heliothis virescens)
To evaluate control of the Tobacco budworm (Heliothis virescens), a test unit consisted of a 96-well microtiter plate containing insect bait and 15-25 H. virescens eggs. .
A solution containing 75% water and 25% DMSO was used to formulate the compound or mixture. Formulated compounds or mixtures at different concentrations were sprayed onto the insect bait in 10 μL using a custom-built microatomizer.
For the experimental mixtures in these tests, equal volumes of both mixing partners were mixed together at the respective desired concentrations. The mixture application was repeated four times on four separate microtiter plates.
After application, microtiter plates were incubated for 5 days at 28±1°C and 80±5% RH. Mortality of both eggs and larvae was then visually assessed and scored (0, 50, or 100% control effectiveness).

Test 2: Greenhouse Whitefly (Trialeurodes vaporariorum)
To evaluate control of the Greenhouse Whitefly (Trialeurodes vaporariorum), a test unit was constructed with a 96-well microtiter plate containing eggplant leaf discs containing whitefly eggs. The compound or mixture was formulated using a solution containing 75% water and 25% DMSO. Different concentrations of formulated compounds or mixtures were sprayed onto the insect bait in 2.5 μL using a custom-built microatomizer. For the experimental mixtures in these tests, equal volumes of both mixing partners were mixed together at the respective desired concentrations. The mixture application was repeated four times on four separate microtiter plates. For the experimental mixtures in these tests, equal volumes of both mixing partners were mixed together at the respective desired concentrations.

After application, microtiter plates were incubated for 6 days at 23+1°C and 65+5% RH. Thereafter, the mortality rate of the hatched first instar larvae was visually evaluated and a score (0, 50, or 100% control effect) was given.

For H. virescens, for a specific dose combination between oxazosulfil and benzpyrimoxane, there is an additive synergistic effect between 40% mortality with the Bliss model and 18% mortality with ZIP model control. (Tables 1.2b and 1.3b).

For T. vaporariorum, additive and synergistic effects between 65% mortality with Bliss model and 51% mortality with ZIP model control for specific dose combinations between oxazosulfil and benzpyrimoxane was observed (Tables 2.2b and 2.3b).

References:
Berenbaum, M., C. (1989). What is synergy. Pharmacol Rev 41: 93-141
Loewe, S. (1953). The problem of synergism and antagonism of combined
Arzneimit drugstelforschung 3: 285-290
Bliss, C., I. (1939). The toxicity of poisons applied jointly. Ann Appl Biol 26: 585-615
Yadav, B.; Wennerberg, K.; Aittokallio, T.; Tang, J. (2015). Computational Searching for drug synergy in complex dose-response landscapes using an inter-action potency model. Structural Biotechnology Journal 13: 504-513
Greco, W.; Unkelbach, H. -D.; Poech, G.; Suehnel, J.; Kundi, M.; Boedeker, W. (1992) Consensus on concepts and terminology for combined-action assessment: The Saariselkae agreement. Archives of Complex Environmental Studies. 4: 65-69
He, L.; Kulesskiy, E.; Saarela, J.; Turunen, L.; Wennerberg, K.; Aittokallio, T.; Tang, J. (2018). Methods for High-Throughput Drug Combination Screening and Synergy Scoring. In von Stechow, L. (ed.), Cancer Systems Biology: Methods and Protocols, chapter 17, 351-398. Springer New York.

The present invention includes, for example, the following aspects.
[Section 1]
Pesticide mixture containing benzpyrimoxane and oxazosulfil.
[Section 2]
A mixture according to paragraph 1, wherein benzpyrimoxane and oxazosulfil are the only active ingredients.
[Section 3]
Mixture according to item 1 or 2, wherein the ratio of the mixing partners is from 1000:1 to 1:1000; preferably from 100:1 to 1:100, from 50:1 to 1:50, from 20:1 to 1:20. .
[Section 4]
A pesticidal composition comprising a liquid or solid carrier and a mixture according to any one of paragraphs 1 to 3.
[Section 5]
A method for exterminating or controlling invertebrate pests, the method comprising: treating the pest or its food supply, habitat, or breeding site; A method comprising contacting with a pest mixture.
[Section 6]
A method for protecting a growing plant or plant propagation material from attack or damage by invertebrate pests, the method comprising: the plant, the plant propagation material, or the soil or water in which the plant is grown; and a pesticidal effective amount. A method comprising contacting a pesticidal mixture according to any one of paragraphs 1 to 3 with a pesticide mixture according to any one of paragraphs 1 to 3.
[Section 7]
Plant propagation material comprising a pesticidal mixture according to any one of paragraphs 1 to 3 in an amount of 0.1 g to 10 kg per 100 kg of seeds.
[Section 8]
A method for protecting plant propagation material, comprising contacting the plant propagation material with a pesticidal mixture according to any one of paragraphs 1 to 3 in an amount of 0.1 g to 10 kg per 100 kg of plant propagation material. including methods.
[Section 9]
A method for controlling rice harmful invertebrates in rice, the method comprising applying the pesticidal mixture according to any one of items 1 to 3 to the rice harmful invertebrates.
[Section 10]
The method according to paragraph 9, wherein the rice harmful invertebrate is selected from the following group:
Hemiptera:
Brown planthopper (brown planthopper) - Nilaparvata lugens
Small Brown Planthopper - Laodelphax striatellus
White-backed planthopper - Sogatella furcifera
White Leafhopper - Cofana spectra
Green leafhopper - Nephotettix virescens, N. nigriceps, N. cincticeps, N. malayanus
Lightning leafhopper (zig zag leafhopper) - Recilia dorsalis
Leafhopper (maize orange leafhopper) - Cicadulina bipunctata
Leafhopper (aster leafhopper) - Macrosteles fascifrons
Formosan stink bug (rice earhead bug), Leptocorisa oratorius, L. acuta
Rice stink bugs - Nezara viridula, Pygomenida varipennis, Eysarcoris, Tibraca limbatriventris, Eysarcoris ventralis
small stink bug - Oebalus poecilus, O. pugnax
Coreid bug - Eysarcoris sp.
Chinch bug - Blissus leucopterus, leucopterus
Rice mealybug, Brevennia rehi, Pseudococcus saccharicola
Rice aphids, Rhopalosiphum rufiabdominalis, Macrosiphum avenae, Hysteroneura setariae, Tetraneuro nigriabdominalis
bean root aphid - Smynthurodes betae
Lepidoptera:
Rice skipper - Parnara guttata, Melanitis Ieda ismene
Japanese borer moth (rice stem borer/striped stem borer) - Chilo suppressalis, Chilo polychrusus, Chilo partellus, Chilo preja Chilo plejadellus
Rice stalk borer - Chilotraea polychrysa
Rice armyworm (pink rice borer) - Sesamia inferens
Yellow rice borer - Tryporyza(=Scirpophaga) incertulas
White Rice Borer - Tryporyza innotata
Knot borer (rice leafroller/rice leaf folder) - Cnaphalocrocis medinalis, Marasmia patnalis, M. exigua
Armyworm (rice ear-cutting caterpillar/armyworm) - Pseudaletia separata
Green caterpillar - Xanthodes transversa
Green rice caterpillar - Narnaga aenescens
green horned caterpillars - Melanitis Ieda ismene, Mycalesis sp.
Fall army worm - Spodoptera frugiperda
Cutworm - Mythimna separata
Rice case worm (rice case worm) - Nymphula depunctalis
black hairy caterpillar, Amata sp.
Hairy caterpillar - Mocis frugalis
Obiga (yellow caterpillar), Psalis pennatula
Rice semi-brown looper, Mocis frugalis
Rice semi-looper, Chrysodeixis chalcites
Grass webworm - Herpetogramma licarsisalis
Sugarcane borer - Diatraea saccharalis
Corn stalk borer - Elasmopalpus lignosellus
Striped grass looper - Mocis latipes
European corn borer - Ostrinia nubilalis
Mexican rice borer - Eoreuma loftini
Coleoptera:
Water weevil - Lissorhopterus oryzophilus
Rice weevil (rice plant weevil) - Echinocnemus squamous
Rice weevil (rice weevil) - Oryzophagus oryzae
Rice hispa - Diclodispa armigera Rice leaf beetle - Oulema oryzae
Rice blackbug - Scotinophora vermidulate, S. vermidulate, S. lurida, S. latiuscula
Rice flea beetle - Chaetocnima basalis
Grubs - Leucopholis irrorata, Leucopholis irrorata, Phyllophaga sp, Heteronychus sp.
Scarab beetle (bicho torito) - Diloboderus abderus
Billbugs - Sphenophorus spp.
grape colaspis - Colaspis brunnea, C. louisianae
Rice pollen beetle, Chilolaba acuta Diptera:
Stem maggot - Chlorops oryzae
Leafminer - Agromyza oryzae
Rice whorl maggot/rice stem maggot - Hydrellia sasakii
Rice whorl maggot/small rice leafminer - Hydrellia griseola
Rice gall midge - Orseolia (=Pachydiplosis) oryzae
Rice shoot fly - Atherigona oryzae
Rice seed midge - Chironomus cavazzai, Chironomus spp, Cricotopus spp.
Thysanoptera:
Rice thrips - Chloethrips oryzae, Stenochaetothrips biformis, Perrisothrips sp., Hoplothrips sp.,
Orthoptera:
rice grasshoppers, Hieroglyphus banian, Hieroglyphus nigrorepletus, Catantops pinguis, Attractomorpha burri, A. crenulata ( A. crenulate), A. psittacina psittacina, A. Bedeli, Oxya adenttata, Oxya ebneri, Oxya hira intricata ( Oxya hyla intricata), Acrida turricata
Locusts - Locusta migratoria manilensis
mole cricket, Grylotalpa africana
Field crickets: Gryllus bimaculatus, Teleogryllus occipitalis, Euscyrtus concinus
Katydid - Conocephalus longipennis Order Isoptera:
termites - Macrotermes gilvus, Syntermes molestans
Hymenoptera:
ants - red fire ant (Solenopsis geminata)
Rice white tip nematode (rice white tip nematode) - Aphelenchoides besseyi
Acari:
rice panicle mite - Steotarsonemus pinki
Crustacea:
tadpole shrimp - American tadpole shrimp (Triops longicaudatus), European tadpole shrimp (T. cancriformis)
rice crayfish - American crayfish (Procambarus clarkii), Orconectes virilis.
[Section 11]
The rice harmful invertebrate is selected from the order Hemiptera, Lepidoptera or Coleoptera, preferably from the hoppers, or preferably from the brown planthopper. brown plant hopper (Nilaparvata lugens), small plant brownhopper (Laodelphax striatellus), white-backed plant hopper (white-backed planthopper) (Sogatella furcifera), green leafhopper (Nephotettix virescens), rice stink bugs (Nezara viridula), Pygomenida varipennis, Eysarcoris, Tibraca limbatriventris, Eysarcoris ventralis), small stink bug (Oebalus poecillus) Oebalus poecilus, O. pugnax), rice stem borer (Chilo suppressalis), yellow rice borer (Tripoliza) Tryporyza(=Scirpophaga incertulas)), Kubno borer (rice leafroller/rice leaf folder)(Cnaphalocrocis medinalis), Marasmia patonalis (Marasmia patnalis), M. exigua), rice weevil (water weevil) (Lissorhopterus oryzophilus), rice weevil (rice weevil) (Oryzophagus oryzae) (Oryzophagus oryzae)).
[Section 12]
The method according to any one of paragraphs 9, 10 or 11, comprising granule application, seedling box application or foliar application.
[Section 13]
A method for increasing the health of plants, especially rice plants in rice fields, comprising treatment with a mixture according to any one of paragraphs 1 to 3.
[Section 14]
A method for increasing the yield of plants, in particular rice plants, comprising treatment with a mixture according to any one of paragraphs 1 to 3.
[Section 15]
A method for protecting rice plants using the mixture according to any one of items 1 to 3.

Claims (15)

A pesticide mixture comprising benzpyrimoxane and oxazosulfyl, wherein the ratio of benzpyrimoxane to oxazosulfyl is 100:1 to 1:3 . 2. A mixture according to claim 1, wherein the ratio of benzpyrimoxane to oxazosulfil is from 20:1 to 1:3 . 3. A mixture according to claim 1 or 2 , wherein benzpyrimoxane and oxazosulfyl are the only active ingredients. Pesticide composition comprising a liquid or solid carrier and a mixture according to any one of claims 1 to 3. 4. A method for exterminating or controlling an invertebrate pest, comprising: the pest or its food supply, habitat or breeding site; and a pesticidal effective amount according to any one of claims 1 to 3. A method comprising contacting with a pesticidal mixture. A method for protecting a growing plant or plant propagation material from attack or damage by invertebrate pests, the method comprising: the plant, the plant propagation material, or the soil or water in which the plant is grown; and a pesticidal effective amount. A method comprising contacting a pesticidal mixture according to any one of claims 1 to 3 with a pesticidal mixture according to any one of claims 1 to 3. Plant propagation material comprising a pesticidal mixture according to any one of claims 1 to 3 in an amount of 0.1 g to 10 kg per 100 kg of seeds. A method for protecting plant propagation material, comprising contacting the plant propagation material with a pesticidal mixture according to any one of claims 1 to 3 in an amount of 0.1 g to 10 kg per 100 kg of plant propagation material. A method including: A method for controlling rice pest invertebrates in rice, the method comprising applying a pesticidal mixture according to any one of claims 1 to 3 to said rice pest invertebrates. The method according to claim 9, wherein the rice pest invertebrate is selected from the following group:
Hemiptera:
Brown planthopper (brown planthopper) - Nilaparvata lugens
Small Brown Planthopper - Laodelphax striatellus
White-backed planthopper - Sogatella furcifera
White Leafhopper - Cofana spectra
Green leafhopper - Nephotettix virescens, N. nigriceps, N. cincticeps, N. malayanus
Lightning leafhopper (zig zag leafhopper) - Recilia dorsalis
Leafhopper (maize orange leafhopper) - Cicadulina bipunctata
Leafhopper (aster leafhopper) - Macrosteles fascifrons
Formosan stink bug (rice earhead bug), Leptocorisa oratorius, L. acuta
Rice stink bugs - Nezara viridula, Pygomenida varipennis, Eysarcoris, Tibraca limbatriventris, Eysarcoris ventralis
small stink bug - Oebalus poecilus, O. pugnax
Coreid bug - Eysarcoris sp.
Chinch bug - Blissus leucopterus, leucopterus
Rice mealybug, Brevennia rehi, Pseudococcus saccharicola
Rice aphids, Rhopalosiphum rufiabdominalis, Macrosiphum avenae, Hysteroneura setariae, Tetraneuro nigriabdominalis
bean root aphid - Smynthurodes betae
Lepidoptera:
Rice skipper - Parnara guttata, Melanitis Ieda ismene
Japanese borer moth (rice stem borer/striped stem borer) - Chilo suppressalis, Chilo polychrusus, Chilo partellus, Chilo preja Chilo plejadellus
Rice stalk borer - Chilotraea polychrysa
Rice armyworm (pink rice borer) - Sesamia inferens
Yellow rice borer - Tryporyza(=Scirpophaga) incertulas
White Rice Borer - Tryporyza innotata
Knot borer (rice leafroller/rice leaf folder) - Cnaphalocrocis medinalis, Marasmia patnalis, M. exigua
Armyworm (rice ear-cutting caterpillar/armyworm) - Pseudaletia separata
Green caterpillar - Xanthodes transversa
Green rice caterpillar - Narnaga aenescens
green horned caterpillars - Melanitis Ieda ismene, Mycalesis sp.
Fall army worm - Spodoptera frugiperda
Cutworm - Mythimna separata
Rice case worm (rice case worm) - Nymphula depunctalis
black hairy caterpillar, Amata sp.
Hairy caterpillar - Mocis frugalis
Obiga (yellow caterpillar), Psalis pennatula
Rice semi-brown looper, Mocis frugalis
Rice semi-looper, Chrysodeixis chalcites
Grass webworm - Herpetogramma licarsisalis
Sugarcane borer - Diatraea saccharalis
Corn stalk borer - Elasmopalpus lignosellus
Striped grass looper - Mocis latipes
European corn borer - Ostrinia nubilalis
Mexican rice borer - Eoreuma loftini
Coleoptera:
Water weevil - Lissorhopterus oryzophilus
Rice weevil (rice plant weevil) - Echinocnemus squamous
Rice weevil (rice weevil) - Oryzophagus oryzae
Rice hispa - Diclodispa armigera Rice leaf beetle - Oulema oryzae
Rice blackbug - Scotinophora vermidulate, S. vermidulate, S. lurida, S. latiuscula
Rice flea beetle - Chaetocnima basalis
Grubs - Leucopholis irrorata, Leucopholis irrorata, Phyllophaga sp, Heteronychus sp.
Scarab beetle (bicho torito) - Diloboderus abderus
Billbugs - Sphenophorus spp.
grape colaspis - Colaspis brunnea, C. louisianae
Rice pollen beetle, Chilolaba acuta Diptera:
Stem maggot - Chlorops oryzae
Leafminer - Agromyza oryzae
Rice whorl maggot/rice stem maggot - Hydrellia sasakii
Rice whorl maggot/small rice leafminer - Hydrellia griseola
Rice gall midge - Orseolia (=Pachydiplosis) oryzae
Rice shoot fly - Atherigona oryzae
Rice seed midge - Chironomus cavazzai, Chironomus spp, Cricotopus spp.
Thysanoptera:
Rice thrips - Chloethrips oryzae, Stenochaetothrips biformis, Perrisothrips sp., Hoplothrips sp.,
Orthoptera:
rice grasshoppers, Hieroglyphus banian, Hieroglyphus nigrorepletus, Catantops pinguis, Attractomorpha burri, A. crenulata ( A. crenulate), A. psittacina psittacina, A. Bedeli, Oxya adenttata, Oxya ebneri, Oxya hira intricata ( Oxya hyla intricata), Acrida turricata
Locusts - Locusta migratoria manilensis
mole cricket, Grylotalpa africana
Field crickets: Gryllus bimaculatus, Teleogryllus occipitalis, Euscyrtus concinus
Katydid - Conocephalus longipennis Order Isoptera:
termites - Macrotermes gilvus, Syntermes molestans
Hymenoptera:
ants - red fire ant (Solenopsis geminata)
Rice white tip nematode (rice white tip nematode) - Aphelenchoides besseyi
Acari:
rice panicle mite - Steotarsonemus pinki
Crustacea:
tadpole shrimp - American tadpole shrimp (Triops longicaudatus), European tadpole shrimp (T. cancriformis)
rice crayfish - American crayfish (Procambarus clarkii), Orconectes virilis. 11. The method according to claim 9 or 10 , wherein the rice harmful invertebrate is selected from the orders Hemiptera, Lepidoptera or Coleoptera. 12. A method according to any one of claims 9, 10 or 11, comprising granule application, nursery box application or foliar application. A method for increasing the health of plants , comprising treatment with a mixture according to any one of claims 1 to 3. A method for increasing the yield of plants , comprising treatment with a mixture according to any one of claims 1 to 3. A method for protecting rice plants using a mixture according to any one of claims 1 to 3.