DE10021412A1 - Fungicidal active ingredient combinations - Google Patents

Fungicidal active ingredient combinations

Info

Publication number
DE10021412A1
DE10021412A1 DE10021412A DE10021412A DE10021412A1 DE 10021412 A1 DE10021412 A1 DE 10021412A1 DE 10021412 A DE10021412 A DE 10021412A DE 10021412 A DE10021412 A DE 10021412A DE 10021412 A1 DE10021412 A1 DE 10021412A1
Authority
DE
Germany
Prior art keywords
formula
active ingredient
group
compound
derivative
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
DE10021412A
Other languages
German (de)
Inventor
Ulrike Wachendorff-Neumann
Herbert Gayer
Ulrich Heinemann
Thomas Seitz
Bernd-Wieland Krueger
Wolfgang Kraemer
Lutz Asmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer AG
Original Assignee
Bayer AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer AG filed Critical Bayer AG
Priority to DE10021412A priority Critical patent/DE10021412A1/en
Priority to EP00985119A priority patent/EP1239733B1/en
Priority to DE50002776T priority patent/DE50002776D1/en
Priority to CNA2004100446979A priority patent/CN1547911A/en
Priority to ES00985119T priority patent/ES2197124T3/en
Priority to PCT/EP2000/011989 priority patent/WO2001044215A2/en
Priority to CZ20022079A priority patent/CZ301233B6/en
Priority to AT00985119T priority patent/ATE243933T1/en
Priority to CA002393988A priority patent/CA2393988A1/en
Priority to US10/149,353 priority patent/US6624183B2/en
Priority to PL355756A priority patent/PL200668B1/en
Priority to RU2002119003/04A priority patent/RU2002119003A/en
Priority to MXPA02005835A priority patent/MXPA02005835A/en
Priority to AU21641/01A priority patent/AU2164101A/en
Priority to JP2001544705A priority patent/JP2003516979A/en
Priority to NZ519460A priority patent/NZ519460A/en
Priority to BR0016336-8A priority patent/BR0016336A/en
Priority to PT00985119T priority patent/PT1239733E/en
Priority to HU0203563A priority patent/HUP0203563A3/en
Priority to DK00985119T priority patent/DK1239733T3/en
Priority to KR1020027006458A priority patent/KR100613238B1/en
Priority to IL14955400A priority patent/IL149554A0/en
Priority to TR2002/01544T priority patent/TR200201544T2/en
Priority to CN00817110.6A priority patent/CN1212768C/en
Priority to CO00094463A priority patent/CO5221089A1/en
Priority to TW089126400A priority patent/TW590741B/en
Priority to ARP000106607A priority patent/AR026938A1/en
Publication of DE10021412A1 publication Critical patent/DE10021412A1/en
Priority to ZA200203650A priority patent/ZA200203650B/en
Priority to IL149554A priority patent/IL149554A/en
Priority to US10/619,730 priority patent/US7115593B2/en
Priority to US11/336,501 priority patent/US7208510B2/en
Priority to US11/714,497 priority patent/US7956009B2/en
Pending legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring

Abstract

The invention relates to novel combinations of active substances. Said combinations consist of a fluor-benzothiazol derivative of formula (I) and the groups of active substances (1 to 51), whereby said groups are mentioned in the description. The inventive combinations are provided with very good fungicidal characteristics.

Description

Die vorliegende Erfindung betrifft neue Wirkstoffkombinationen, die aus einem be­ kannten Fluor-benzothiazol-Derivat einerseits und weiteren bekannten Wirkstoffen andererseits bestehen und sehr gut zur Bekämpfung von phytopathogenen Pilzen ge­ eignet sind.The present invention relates to new combinations of active ingredients that consist of a be knew fluorobenzothiazole derivative on the one hand and other known active ingredients on the other hand exist and very good for combating phytopathogenic fungi are suitable.

Es ist bereits bekannt, dass Isopropyl 1-({[1-(6-fluor-1,3-benzothiazol-2-yl)ethyl]- amino}carbonyl)-2-methylpropylcarbamat fungizide Eigenschaften besitzt (vgl. EP- A1-775 696). Die Wirksamkeit dieses Stoffes ist gut, lässt aber bei niedrigen Auf­ wandmengen in manchen Fällen zu wünschen übrig.It is already known that isopropyl 1 - ({[1- (6-fluoro-1,3-benzothiazol-2-yl) ethyl] - amino} carbonyl) -2-methylpropyl carbamate has fungicidal properties (cf. EP- A1-775 696). The effectiveness of this substance is good, but leaves at low levels Wall quantities left something to be desired in some cases.

Ferner ist schon bekannt, dass zahlreiche Triazol-Derivate, Anilin-Derivate, Dicarb­ oximide und andere Heterocyclen zur Bekämpfung von Pilzen eingesetzt werden können (vgl. EP-A 0 040 345, DE-A 22 01 063, DE-A 23 24 010, Pesticide Manual, 9th. Edition (1991), Seiten 249 und 827, EP-A 0 382 375 und EP-A 0 515 901). Auch die Wirkung dieser Stoffe ist aber bei niedrigen Aufwandmengen nicht immer ausreichend.Furthermore, it is already known that numerous triazole derivatives, aniline derivatives, dicarb oximides and other heterocycles can be used to combat fungi can (cf. EP-A 0 040 345, DE-A 22 01 063, DE-A 23 24 010, Pesticide Manual, 9th. Edition (1991), pages 249 and 827, EP-A 0 382 375 and EP-A 0 515 901). However, the effect of these substances is not always the case at low application rates sufficient.

Schließlich ist auch bekannt, dass 1-[(6-Chlor-3-pyridinyl)-methyl]-N-nitro-2-imid­ azolidinimin zur Bekämpfung tierischer Schädlinge, wie Insekten, verwendbar ist (vgl. Pesticide Manual, 9th. Edition (1991), Seite 491). Fungizide Eigenschaften die­ ses Stoffes wurden aber bisher noch nicht beschrieben.Finally, it is also known that 1 - [(6-chloro-3-pyridinyl) methyl] -N-nitro-2-imide azolidinimine can be used to control animal pests, such as insects (see Pesticide Manual, 9th Edition (1991), page 491). Fungicidal properties However, this substance has not yet been described.

Ferner ist bereits bekannt, dass 1-(3,5-Dimethyl-isoxazol-4-sulfonyl)-2-chlor-6,6- difluor-[1,3]-dioxolo-[4,5f]-benzimidazol fungizide Eigenschaften besitzt (vgl. WO 97/06171).Furthermore, it is already known that 1- (3,5-dimethyl-isoxazole-4-sulfonyl) -2-chloro-6,6- difluoro- [1,3] -dioxolo- [4,5f] -benzimidazole has fungicidal properties (cf. WO 97/06171).

Ferner ist bereits bekannt, dass substituierte Azadioxacycloalkene eine fungizide Wirkung zeigen (vgl. EP-B-712 396). Furthermore, it is already known that substituted azadioxacycloalkenes are fungicidal Show effect (cf. EP-B-712 396).  

Schließlich ist auch bekannt, dass substituierte Halogenpyrimidine fungizide Eigen­ schaften besitzen (vgl. DE-A1-196 46 407, EP-B-712 396).Finally, it is also known that substituted halopyrimidines are fungicidal possess shafts (cf. DE-A1-196 46 407, EP-B-712 396).

Es wurde nun gefunden, dass die neuen Wirkstoffkombinationen aus einem Fluor­ benzothiazol-Derivat der Formel
It has now been found that the new drug combinations of a fluorobenzothiazole derivative of the formula

und
and

  • 1. einem Triazol-Derivat der Formel
    in welcher
    X für Chlor oder Phenyl steht, und
    Y für
    steht
    und/oder     1. a triazole derivative of the formula
    in which
    X represents chlorine or phenyl, and
    Y for
    stands
    and or
  • 2. dem Triazol-Derivat der Formel
    und/oder    2. the triazole derivative of the formula
    and or
  • 3. einem Anilin-Derivat der Formel
    in welcher
    R1 für Wasserstoff oder Methyl steht,
    und/oder    3. an aniline derivative of the formula
    in which
    R 1 represents hydrogen or methyl,
    and or
  • 4. N-[1-(4-Chlor-phenyl)-ethyl]-2,2-dichlor-1-ethyl-3-methyl-cyclopropan-car­ bonsäureamid der Formel
    und/oder     4. N- [1- (4-chlorophenyl) ethyl] -2,2-dichloro-1-ethyl-3-methylcyclopropanecarboxamide of the formula
    and or
  • 5. dem Zink-propylen-1,2-bis-(dithiocarbamidat) der Formel
    und/oder    5. the zinc propylene-1,2-bis (dithiocarbamidate) of the formula
    and or
  • 6. mindestens einem Thiocarbamat der Formel
    Me = Zn oder Mn oder Gemisch aus Zn und Mn
    und/oder    6. at least one thiocarbamate of the formula
    Me = Zn or Mn or mixture of Zn and Mn
    and or
  • 7. dem Anilin-Derivat der Formel
    und/oder    7. the aniline derivative of the formula
    and or
  • 8. der Verbindung der Formel
    und/oder    8. the compound of formula
    and or
  • 9. dem Benzothiadiazol-Derivat der Formel
    und/oder    9. the benzothiadiazole derivative of the formula
    and or
  • 10. dem 8-t-Butyl-2-(N-ethyl-N-n-propyl-amino)-methyl-1,4-dioxaspiro[5,4]- decan der Formel
    und/oder    10. the 8-t-butyl-2- (N-ethyl-Nn-propylamino) methyl-1,4-dioxaspiro [5,4] decane of the formula
    and or
  • 11. der Verbindung der Formel
    und/oder    11. The compound of the formula
    and or
  • 12. der Verbindung der Formel
    und/oder    12. The compound of the formula
    and or
  • 13. der Verbindung der Formel
    und/oder    13. the compound of formula
    and or
  • 14. dem Cyanoxim-Derivat der Formel
    und/oder     14. the cyanoxime derivative of the formula
    and or
  • 15. einem Pyrimidin-Derivat der Formel
    in welcher
    R2 für Methyl oder Cyclopropyl steht,
    und/oder    15. a pyrimidine derivative of the formula
    in which
    R 2 represents methyl or cyclopropyl,
    and or
  • 16. einem Anilin-Derivat der Formel
    und/oder    16. an aniline derivative of the formula
    and or
  • 17. dem Morpholin-Derivat der Formel
    und/oder     17. the morpholine derivative of the formula
    and or
  • 18. dem Phthalimid-Derivat der Formel
    und/oder    18. The phthalimide derivative of the formula
    and or
  • 19. der Phosphor-Verbindung der Formel
    und/oder    19. The phosphorus compound of the formula
    and or
  • 20. dem Hydroxyethyl-triazol-Derivat der Formel
    und/oder    20. the hydroxyethyl triazole derivative of the formula
    and or
  • 21. dem 1-[(6-Chlor-3-pyridinyl)]-methyl-N-nitro-2-imidazolidinimin der Formel
    und/oder    21. The 1 - [(6-chloro-3-pyridinyl)] methyl-N-nitro-2-imidazolidinimine of the formula
    and or
  • 22. dem Oxazolidindion der Formel
    und/oder    22. the oxazolidinedione of the formula
    and or
  • 23. dem Benzamid-Derivat der Formel
    und/oder    23. the benzamide derivative of the formula
    and or
  • 24. einem Guanidin-Derivat der Formel
    in welcher
    m für ganze Zahlen von 0 bis 5 steht und
    R3 für Wasserstoff (17 bis 23%) oder den Rest der Formel
    steht,
    und/oder    24. a guanidine derivative of the formula
    in which
    m stands for integers from 0 to 5 and
    R 3 represents hydrogen (17 to 23%) or the rest of the formula
    stands,
    and or
  • 25. dem Triazol-Derivat der Formel
    und/oder    25. the triazole derivative of the formula
    and or
  • 26. dem Halogen-benzimidazol der Formel
    und/oder     26. The halogen benzimidazole of the formula
    and or
  • 27. dem Halogenpyrimidin der Formel
    und/oder    27. The halopyrimidine of the formula
    and or
  • 28. dem Tetrachlor-isophthalo-dinitril der Formel
    und/oder    28. The tetrachloroisophthalodinitrile of the formula
    and or
  • 29. der Verbindung der Formel
    und/oder     29. the compound of formula
    and or
  • 30. dem Pyridinamin der Formel
    und/oder    30. the pyridinamine of the formula
    and or
  • 31. dem Thiazolcarboxamid der Formel
    und/oder    31. the thiazole carboxamide of the formula
    and or
  • 32. dem Sulfonamid der Formel
    und/oder    32. the sulfonamide of the formula
    and or
  • 33. der Verbindung der Formel
    und/oder    33. the compound of formula
    and or
  • 34. der Verbindung der Formel
    und/oder    34. the compound of formula
    and or
  • 35. der Verbindung der Formel
    und/oder     35. the compound of formula
    and or
  • 36. dem Diamid der Formel
    und/oder    36. the diamide of the formula
    and or
  • 37. dem Methoxyacrylat-Derivat der Formel
    und/oder    37. the methoxyacrylate derivative of the formula
    and or
  • 38. dem Chinolin-Derivat der Formel
    und/oder     38. the quinoline derivative of the formula
    and or
  • 39. dem Phenylamid-Derivat der Formel
    und/oder    39. the phenylamide derivative of the formula
    and or
  • 40. dem Phenylamid-Derivat der Formel
    und/oder    40. the phenylamide derivative of the formula
    and or
  • 41. das Dicarboxim-Derivat der Formel
    und/oder    41. the dicarboxime derivative of the formula
    and or
  • 42. der Phosphonsäure der Formel
    und/oder    42. the phosphonic acid of the formula
    and or
  • 43. dem Pyrrol-Derivat der Formel
    und/oder    43. the pyrrole derivative of the formula
    and or
  • 44. dem Phenylcarbonat der Formel
    und/oder    44. the phenyl carbonate of the formula
    and or
  • 45. den Kupferverbindungen
    • a) Kupferoxychlorid (XXXXVIa)
    • b) Kupferhydroxid (XXXXVIb)
      und/oder
    45. the copper compounds
    • a) Copper oxychloride (XXXXVIa)
    • b) copper hydroxide (XXXXVIb)
      and or
  • 46. dem Imidazol-Derivat der Formel
    und/oder    46. the imidazole derivative of the formula
    and or
  • 47. einem Triazolderivat der Formel
    und/oder
    und/oder
    und/oder
    und/oder
    und/oder
    und/oder
    und/oder
    und/oder    47. a triazole derivative of the formula
    and or
    and or
    and or
    and or
    and or
    and or
    and or
    and or
  • 48. einer Verbindung der allgemeinen Formel
    in welcher
    R1 für unsubstituiertes oder durch Fluor, Chlor, Brom, Methyl oder Ethyl substituiertes Phenyl, 2-Naphthyl, 1,2,3,4-Tetrahydronaphthyl oder Indanyl steht,
    und/oder    48. a compound of the general formula
    in which
    R 1 represents phenyl which is unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl,
    and or
  • 49. N-Methyl-2-(methoxyimino)-2-[2-([1-(3-tri-fluoro-methyl­ phenyl)ethoxy]iminomethyl)phenyl]acetamid der Formel
    und/oder    49. N-Methyl-2- (methoxyimino) -2- [2 - ([1- (3-tri-fluoro-methyl phenyl) ethoxy] iminomethyl) phenyl] acetamide of the formula
    and or
  • 50. 2,4-Dihydro-5-methoxy-2-methyl-4-[2-([([1-(3-tri-fluoro­ methylphenyl)ethylidene]amino)oxy]methyl)phenyl]-3H-1,2,4-triazol-3-one der Formel
    und/oder    50. 2,4-Dihydro-5-methoxy-2-methyl-4- [2 - ([([1- (3-tri-fluoro methylphenyl) ethylidene] amino) oxy] methyl) phenyl] -3H-1, 2,4-triazol-3-one of the formula
    and or
  • 51. der Verbindung der Formel
    und/oder    51. the compound of formula
    and or
  • 52. der Verbindung der Formel
    sehr gute fungizide Eigenschaften besitzen.    52. the compound of the formula
    have very good fungicidal properties.

Überraschenderweise ist die fungizide Wirkung der erfindungsgemäßen Wirkstoff­ kombinationen wesentlich höher als die Summe der Wirkungen der einzelnen Wirk­ stoffe. Es liegt also ein nicht vorhersehbarer, echter synergistischer Effekt vor und nicht nur eine Wirkungsergänzung.Surprisingly, the fungicidal activity of the active ingredient according to the invention combinations significantly higher than the sum of the effects of the individual effects fabrics. So there is an unforeseeable, real synergistic effect and not just a supplement.

Aus der Strukturformel für den Wirkstoff der Formel (I) ist ersichtlich, dass die Ver­ bindung zwei asymmetrisch substituierte Kohlenstoffatome aufweist. Das Produkt kann daher als Gemisch von verschiedenen Isomeren oder auch in Form eines einzi­ gen Isomeren vorliegen.From the structural formula for the active ingredient of the formula (I) it can be seen that the ver bond has two asymmetrically substituted carbon atoms. The product can therefore as a mixture of different isomers or in the form of a single gene isomers present.

Bevorzugte Verbindungen der Formel (I) sind Verbindungen, in denen der Amino­ säureteil aus i-Propyloxycarbonyl-L-valin gebildet wird und der Fluor-benzothiazol­ ethylaminteil racemisch ist, insbesondere aber die (R)-Konfiguration aufweist.Preferred compounds of formula (I) are compounds in which the amino acid part is formed from i-propyloxycarbonyl-L-valine and the fluorobenzothiazole ethylamine part is racemic, but in particular has the (R) configuration.

Die Formel (II) umfasst die VerbindungenFormula (II) includes the compounds

1-(4-Chlor-phenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-butan-2-on der Formel
1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) butan-2-one of the formula

1-(4-Chlor-phenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-butan-2-ol der Formel
1- (4-chlorophenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) butan-2-ol of the formula

und
1-(4-Phenyl-phenoxy)-3,3-dimethyl-1-(1,2,4-triazol-1-yl)-butan-2-ol der Formel
and
1- (4-phenylphenoxy) -3,3-dimethyl-1- (1,2,4-triazol-1-yl) butan-2-ol of the formula

Die Formel (IV) umfasst die Anilin-Derivate der Formeln
Formula (IV) comprises the aniline derivatives of the formulas

und
and

Aus der Strukturformel für den Wirkstoff der Formel (V) ist ersichtlich, dass die Ver­ bindung drei asymmetrisch substituierte Kohlenstoffatome aufweist. Das Produkt kann daher als Gemisch von verschiedenen Isomeren oder auch in Form einer einzi­ gen Komponente vorliegen. Besonders bevorzugt sind die VerbindungenFrom the structural formula for the active ingredient of the formula (V) it can be seen that the ver bond has three asymmetrically substituted carbon atoms. The product can therefore as a mixture of different isomers or in the form of a single gene component. The compounds are particularly preferred

N-(R)-[1-(4-Chlor-phenyl)-ethyl]-(1S)-2,2-dichlor-1-ethyl-3t-methyl-1R-cyclopro­ pancarbonsäureamid der Formel
N- (R) - [1- (4-chlorophenyl) ethyl] - (1S) -2,2-dichloro-1-ethyl-3t-methyl-1R-cyclopro-pancarboxamide of the formula

und
N-(R)-[1-(4-Chlor-phenyl)-ethyl]-(1R)-2,2-dichlor-1-ethyl-3t-methyl-1R-cyclopro­ pancarbonsäureamid der Formel
and
N- (R) - [1- (4-chlorophenyl) ethyl] - (1R) -2,2-dichloro-1-ethyl-3t-methyl-1R-cyclopro-pancarboxamide of the formula

Die Formel (VII) umfasst die Verbindungen
Formula (VII) includes the compounds

  • 1. Me = Zn (Zineb),1. Me = Zn (Zineb),
  • 2. Me = Mn (Maneb) und2. Me = Mn (Maneb) and
  • 3. Mischung aus (VIIa) und (VIIb) (Mancozeb).3. Mixture of (VIIa) and (VIIb) (Mancozeb).

Die Formel (XVI) umfasst die Verbindungen
Formula (XVI) includes the compounds

  • 1. R2 = CH3 (Pyrimethanil) und1. R 2 = CH 3 (pyrimethanil) and
  • 2. R2 = (Cyprodinyl)2. R 2 = (cyprodinyl)

Die Verbindung der Formel (XVII) kann als Methyl N-(2,6-dimethylphenyl)-N- (methoxyacetyl)-DL-alaninat (Metalaxyl, XVIIa) oder als Methyl N-(2,6- dimethylphenyl)-N-(methoxyacetyl)-D-alaninat (Metalaxyl-M, XVIIb) vorliegen.The compound of formula (XVII) can be methyl N- (2,6-dimethylphenyl) -N- (methoxyacetyl) -DL-alaninate (metalaxyl, XVIIa) or as methyl N- (2,6- dimethylphenyl) -N- (methoxyacetyl) -D-alaninate (Metalaxyl-M, XVIIb) are present.

Das Hydroxyethyl-triazol-Derivat der Formel (XXI) kann in der "Thiono"-Form der Formel
The hydroxyethyl-triazole derivative of the formula (XXI) can be in the "thiono" form of the formula

oder in der tautomeren "Mercapto"-Form der Formel
or in the tautomeric "mercapto" form of the formula

vorliegen. Der Einfachheit halber wird jeweils nur die "Thiono"-Form aufgeführt.available. For the sake of simplicity, only the "Thiono" form is listed.

Bei dem Guanidin-Derivat der Formel (XXV) handelt es sich um ein Substanzge­ misch mit dem Commonname Guazatine.The guanidine derivative of the formula (XXV) is a substance mix with the common name Guazatine.

Aus der Strukturformel für die Wirkstoffe der Formel (XXXXIX) ist ersichtlich, dass die Verbindungen als E- oder Z-Isomere vorliegen können. Das Produkt kann daher als Gemisch von verschiedenen Isomeren oder auch in Form eines einzigen Isomeren vorliegen. Bevorzugt sind Verbindungen der Formel (XXXXIX), in denen die Verbindungen der Formel (XXXXIX) als E-Isomer vorliegen. Besonders bevorzugt sind die Verbindungen der Formeln
From the structural formula for the active compounds of the formula (XXXXIX) it can be seen that the compounds can be present as E or Z isomers. The product can therefore be present as a mixture of different isomers or in the form of a single isomer. Compounds of the formula (XXXXIX) in which the compounds of the formula (XXXXIX) are present as E isomers are preferred. The compounds of the formulas are particularly preferred

und deren Isomere.and their isomers.

Als Mischungspartner der Verbindungen der Formel (I) sind die folgenden Wirkstoffe besonders bevorzugt:
The following active ingredients are particularly preferred as mixing partners of the compounds of the formula (I):

  • 1. Tolylfluanid (IVb),1. tolylfluanid (IVb),
  • 2. Propineb (VI),2. Propineb (VI),
  • 3. Mancozeb (VIIc),3. Mancozeb (VIIc),
  • 4. Fenhexamid (VIII),4. fenhexamide (VIII),
  • 5. Iprovalicarb (VIII),5. Iprovalicarb (VIII),
  • 6. Azoxystrobin (XII),6. azoxystrobin (XII),
  • 7. Trifloxystrobin (XIII),7. trifloxystrobin (XIII),
  • 8. Verbindung der Formel (XIV),8. compound of the formula (XIV),
  • 9. Folpet (XIX),9. Folpet (XIX),
  • 10. Verbindung der Formel (XXI),10. compound of formula (XXI),
  • 11. Verbindung der Formel (XXVII),11. Compound of the formula (XXVII),
  • 12. Verbindung der Formel (XXVIII), 12. Compound of the formula (XXVIII),  
  • 13. Chlorothalonil (XXIX),13. chlorothalonil (XXIX),
  • 14. Fluazinam (XXXI), und14. fluazinam (XXXI), and
  • 15. Kupferverbindungen
    • a) Kupferoxychlorid (XXXXVIa)
    • b) Kupferhydroxid (XXXXVIb).
    15. Copper connections
    • a) Copper oxychloride (XXXXVIa)
    • b) Copper hydroxide (XXXXVIb).

Die in den erfindungsgemäßen Wirkstoffkombinationen neben einem Halogen-benz­ imidazol der Formel (XXVII) vorhandenen Komponenten sind ebenfalls bekannt.In addition to a halogen benz in the active ingredient combinations according to the invention Components present in the imidazole of the formula (XXVII) are also known.

Im einzelnen werden die Wirkstoffe in den folgenden Publikationen beschrieben:
The active substances are described in detail in the following publications:

  • 1. Verbindungen der Formel (II)
    DE-A 22 01 063
    DE-A 23 24 010    1. Compounds of formula (II)
    DE-A 22 01 063
    DE-A 23 24 010
  • 2. Verbindung der Formel (III)
    EP-A 0 040 345    2. Compound of the formula (III)
    EP-A 0 040 345
  • 3. Verbindungen der Formel (IV)
    Pesticide Manual, 9th. Ed. (1991), Seiten 249 und 827    3. Compounds of formula (IV)
    Pesticide Manual, 9th. Ed. (1991), pages 249 and 827
  • 4. Verbindung der Formel (V) und deren einzelne Derivate
    EP-A 0 341 475    4. Compound of formula (V) and its individual derivatives
    EP-A 0 341 475
  • 5. Verbindung der Formel (VI)
    Pesticide Manual, 9th. Ed. (1991), Seite 726    5. Compound of formula (VI)
    Pesticide Manual, 9th. Ed. (1991), page 726
  • 6. Verbindungen der Formel (VII)
    Pesticide Manual, 9th. Ed. (1991), Seiten 529, 531 und 866    6. Compounds of formula (VII)
    Pesticide Manual, 9th. Ed. (1991), pages 529, 531 and 866
  • 7. Verbindung der Formel (VIII)
    EP-A 0 339 418    7. Compound of formula (VIII)
    EP-A 0 339 418
  • 8. Verbindung der Formel (IX)
    EP-A 0 472 996    8. Compound of Formula (IX)
    EP-A 0 472 996
  • 9. Verbindung der Formel (X)
    EP-A 0 313 512    9. Compound of formula (X)
    EP-A 0 313 512
  • 10. Verbindung der Formel (XI)
    EP-A 0 281 842    10. Compound of formula (XI)
    EP-A 0 281 842
  • 11. Verbindung der Formel (XII)
    EP-A 0 382 375    11. Compound of formula (XII)
    EP-A 0 382 375
  • 12. Verbindung der Formel (XIII)
    EP-A-460 575    12. Compound of formula (XIII)
    EP-A-460 575
  • 13. Verbindung der Formel (XIV)
    DE-A 196 02 095    13. Compound of formula (XIV)
    DE-A 196 02 095
  • 14. Verbindung der Formel (XV)
    Pesticide Manual, 9th. Ed. (1991), Seite 206    14. Compound of formula (XV)
    Pesticide Manual, 9th. Ed. (1991), page 206
  • 15. Verbindungen der Formel (XVI)
    EP-A 0 270 111
    EP-A 0 310 550    15. Compounds of the formula (XVI)
    EP-A 0 270 111
    EP-A 0 310 550
  • 16. Verbindung der Formel (XVII)
    Pesticide Manual, 9th. Ed. (1991), Seite 554    16. Compound of formula (XVII)
    Pesticide Manual, 9th. Ed. (1991), page 554
  • 17. Verbindung der Formel (XVIII)
    EP-A 0 219 756    17. Compound of formula (XVIII)
    EP-A 0 219 756
  • 18. Verbindung der Formel (XIX)
    Pesticide Manual, 9th. Ed. (1991), Seite 431    18. Compound of formula (XIX)
    Pesticide Manual, 9th. Ed. (1991), page 431
  • 19. Verbindung der Formel (XX)
    Pesticide Manual, 9th. Ed. (1991), Seite 443    19. Compound of formula (XX)
    Pesticide Manual, 9th. Ed. (1991), page 443
  • 20. Verbindung der Formel (XXI)
    WO 96-16048    20. Compound of formula (XXI)
    WO 96-16048
  • 21. Verbindung der Formel (XXII)
    Pesticide Manual, 9th. Ed. (1991), Seite 491    21. Compound of formula (XXII)
    Pesticide Manual, 9th. Ed. (1991), page 491
  • 22. Verbindung der Formel (XXIII)
    EP-A 0 393 911    22. Compound of formula (XXIII)
    EP-A 0 393 911
  • 23. Verbindung der Formel (XXIV)
    EP-A 0 600 629    23. Compound of formula (XXIV)
    EP-A 0 600 629
  • 24. Substanz der Formel (XXV)
    Pesticide Manual, 9th. Ed. (1991), Seite 461    24. Substance of the formula (XXV)
    Pesticide Manual, 9th. Ed. (1991), page 461
  • 25. Verbindung der Formel (XXVI)
    Pesticide Manual, 9th. Ed. (1991), Seite 654    25. Compound of formula (XXVI)
    Pesticide Manual, 9th. Ed. (1991), page 654
  • 26. Verbindung der Formel (XXVII)
    WO 97-06171    26. Compound of formula (XXVII)
    WO 97-06171
  • 27. Verbindung der Formel (XXVIII)
    DE-A1-196 46 407, EP-B-0 712 396     27. Compound of formula (XXVIII)
    DE-A1-196 46 407, EP-B-0 712 396
  • 28. Verbindung der Formel (XXIX)
    US 3 290 353    28. Compound of formula (XXIX)
    US 3,290,353
  • 29. Verbindung der Formel (XXX)
    DE-A-156 7169    29. Compound of formula (XXX)
    DE-A-156 7169
  • 30. Verbindung der Formel (XXXI)
    EP-A-0 031 257    30. Compound of formula (XXXI)
    EP-A-0 031 257
  • 31. Verbindung der Formel (XXXII)
    EP-A-0 639 547    31. Compound of formula (XXXII)
    EP-A-0 639 547
  • 32. Verbindung der Formel (XXXIII)
    EP-A-0 298 196    32. Compound of Formula (XXXIII)
    EP-A-0 298 196
  • 33. Verbindung der Formel (XXXIV)
    EP-A-0 629 616    33. Compound of the formula (XXXIV)
    EP-A-0 629 616
  • 34. Verbindung der Formel (XXXV)
    DE-A-2 149 923    34. compound of the formula (XXXV)
    DE-A-2 149 923
  • 35. Verbindung der Formel (XXXVI)
    DE-A-2 012 656    35. compound of the formula (XXXVI)
    DE-A-2 012 656
  • 36. Verbindung der Formel (XXXVII)
    US 1 972 961    36. Compound of the formula (XXXVII)
    US 1 972 961
  • 37. Verbindung der Formel (XXXVIII)
    EP-A-326 330    37. Compound of the formula (XXXVIII)
    EP-A-326 330
  • 38. Verbindung der Formel (XXXIX)
    EP-A 278 595    38. Compound of the formula (XXXIX)
    EP-A 278 595
  • 39. Verbindung der Formel (XXXX)
    DE-A-3 030 026    39. compound of formula (XXXX)
    DE-A-3 030 026
  • 40. Verbindung der Formel (XXXXI)
    DE-A-29 03 612    40. compound of formula (XXXXI)
    DE-A-29 03 612
  • 41. Verbindung der Formel (XXXXII)
    US-2 553 770    41. Compound of the formula (XXXXII)
    U.S. 2,553,770
  • 42. Verbindung der Formel (XXXXIII)
    bekannt und käuflich erwerbbar    42. Compound of Formula (XXXXIII)
    known and available for purchase
  • 43. Verbindung der Formel (XXXXIV)
    EP-A-206 999    43. Compound of Formula (XXXXIV)
    EP-A-206 999
  • 44. Verbindung der Formel (XXXXV)
    EP-A-78 663    44. Compound of the formula (XXXXV)
    EP-A-78 663
  • 45. 
    • a) Verbindung der Formel (XXXXVIa) bekannt und käuflich erwerbbar
    • b) Verbindung der Formel (XXXXVIb) bekannt und käuflich erwerbbar
    45.
    • a) Compound of the formula (XXXXVIa) known and commercially available
    • b) Compound of the formula (XXXXVIb) known and commercially available
  • 46. Verbindung der Formel (XXXXVII)
    DE-A-24 29 523    46. Compound of the formula (XXXXVII)
    DE-A-24 29 523
  • 47. 
    • a) Verbindung der Formel (XXXXVIIIa)
      EP-A-112 284
    • b) Verbindung der Formel (XXXXVIIIb)
      DE-A-30 42 303
    • c) Verbindung der Formel (XXXXVIIIc)
      DE-A-34 06 993
    • d) Verbindung der Formel (XXXXVIIId)
      EP-A-68 813
    • e) Verbindung der Formel (XXXXVIIIe)
      DE-A-25 51 560
    • f) Verbindung der Formel (XXXXVIIIf)
      EP-A-145 294
    • g) Verbindung der Formel (XXXXVIIIg)
      DE-A-37 21 786
    • h) Verbindung der Formel (XXXXVIIIh)
      EP-A-234 242
    47.
    • a) compound of the formula (XXXXVIIIa)
      EP-A-112 284
    • b) compound of the formula (XXXXVIIIb)
      DE-A-30 42 303
    • c) compound of the formula (XXXXVIIIc)
      DE-A-34 06 993
    • d) compound of the formula (XXXXVIIId)
      EP-A-68 813
    • e) compound of the formula (XXXXVIIIe)
      DE-A-25 51 560
    • f) compound of the formula (XXXXVIIIf)
      EP-A-145 294
    • g) compound of the formula (XXXXVIIIg)
      DE-A-37 21 786
    • h) compound of the formula (XXXXVIIIh)
      EP-A-234 242
  • 48. Verbindung der Formel (XXXXIX)
    WO 96/23763    48. compound of the formula (XXXXIX)
    WO 96/23763
  • 49. Verbindung der Formel (XXXXX)
    EP-A-596 254    49. compound of formula (XXXXX)
    EP-A-596 254
  • 50. Verbindung der Formel (XXXXXI)
    WO 98/23155    50. compound of the formula (XXXXXI)
    WO 98/23155
  • 51. Verbindung der Formel (XXXXXII)
    EP-A-569 384    51. Compound of the formula (XXXXXII)
    EP-A-569 384
  • 52. Verbindung der Formel (XXXXXIII)
    EP-A-600 629.    52. Compound of the formula (XXXXXIII)
    EP-A-600 629.

Die erfindungsgemäßen Wirkstoffkombinationen enthalten neben einem Wirkstoff der Formel (I) mindestens einen Wirkstoff von den Verbindungen der Gruppen (1) bis (52). Sie können darüberhinaus auch weitere fungizid wirksame Zumischkom­ ponenten enthalten.The active ingredient combinations according to the invention contain an active ingredient of formula (I) at least one active ingredient from the compounds of groups (1) to (52). You can also use other fungicidal admixtures components included.

Wenn die Wirkstoffe in den erfindungsgemäßen Wirkstoffkombinationen in be­ stimmten Gewichtsverhältnissen vorhanden sind, zeigt sich der synergistische Effekt besonders deutlich. Jedoch können die Gewichtsverhältnisse der Wirkstoffe in den Wirkstoffkombinationen in einem relativ großen Bereich variiert werden. Im allge­ meinen entfallen auf 1 Gewichtsteil an Wirkstoff der Formel (I)
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (1),
0,1 bis 50 Gewichtsteile, vorzugsweise 02 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (2),
1 bis 150 Gewichtsteile, vorzugsweise 1 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (3),
0,1 bis 10 Gewichtsteile, vorzugsweise 0,2 bis 5 Gewichtsteile an Wirkstoff aus der Gruppe (4),
1 bis 150 Gewichtsteile, vorzugweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (5),
1 bis 150 Gewichtsteile, vorzugsweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (6),
0,1 bis 50 Gewichtsteile, vorzugsweise 1 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (7),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (8),
0,02 bis 50 Gewichtsteile, vorzugsweise 0,1 bis 10 Gewichtsteile an Wirkstoff aus der Gruppe (9),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (10),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (11),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (12),
0,1 bis 50 Gewichtsteile, vorzugweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (13),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (14),
0,2 bis 50 Gewichtsteile, vorzugsweise 1 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (15),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (16),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (17),
1 bis 150 Gewichtsteile, vorzugweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (18),
0,1 bis 150 Gewichtsteile, vorzugsweise 1 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (19),
0,02 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 10 Gewichtsteile an Wirkstoff aus der Gruppe (20),
0,05 bis 20 Gewichtsteile, vorzugsweise 0,1 bis 10 Gewichtsteile an Wirkstoff aus der Gruppe (21),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (22),
0,1 bis 50 Gewichtsteile, vorzugweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (23),
0,02 bis 50 Gewichtsteile, vorzugsweise 0,04 bis 10 Gewichtsteile an Wirkstoff aus der Gruppe (24),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (25),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (26),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (27),
1 bis 150 Gewichtsteile, vorzugsweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (28),
1 bis 150 Gewichtsteile, vorzugsweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (29),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (30),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (31),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (32),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (33),
0,1 bis 50 Gewichtsteile, vorzugweise 1 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (34),
0,1 bis 50 Gewichtsteile, vorzugsweise 1 bis 10 Gewichtsteile an Wirkstoff aus der Gruppe (35),
1 bis 150 Gewichtsteile, vorzugsweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (36),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (37),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (38),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (39),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (40),
1 bis 150 Gewichtsteile, vorzugsweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (41),
1 bis 150 Gewichtsteile, vorzugsweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (42),
0,1 bis 50 Gewichtsteile, vorzugsweise 1 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (43),
0,1 bis 50 Gewichtsteile, vorzugweise 1 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (44),
1 bis 150 Gewichtsteile, vorzugsweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (45a),
1 bis 150 Gewichtsteile, vorzugsweise 5 bis 100 Gewichtsteile an Wirkstoff aus der Gruppe (45b),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (46),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (47a),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (47b),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (47c),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (47d),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (47e),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (47f),
0,1 bis 50 Gewichtsteile, vorzugweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (47g),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (47h),
0,1 bis 50 Gewichtsteile, vorzugweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (48),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (49),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (50),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (51),
0,1 bis 50 Gewichtsteile, vorzugsweise 0,2 bis 20 Gewichtsteile an Wirkstoff aus der Gruppe (52).If the active ingredients are present in the active ingredient combinations according to the invention in certain weight ratios, the synergistic effect is particularly evident. However, the weight ratios of the active ingredients in the active ingredient combinations can be varied within a relatively wide range. In general, 1 part by weight of active ingredient of the formula (I)
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (1),
0.1 to 50 parts by weight, preferably 02 to 20 parts by weight, of active ingredient from group (2),
1 to 150 parts by weight, preferably 1 to 100 parts by weight, of active ingredient from group (3),
0.1 to 10 parts by weight, preferably 0.2 to 5 parts by weight of active ingredient from group (4),
1 to 150 parts by weight, preferably 5 to 100 parts by weight of active ingredient from group (5),
1 to 150 parts by weight, preferably 5 to 100 parts by weight, of active ingredient from group (6),
0.1 to 50 parts by weight, preferably 1 to 20 parts by weight, of active ingredient from group (7),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (8),
0.02 to 50 parts by weight, preferably 0.1 to 10 parts by weight, of active ingredient from group (9),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (10),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (11),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (12),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (13),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, of active ingredient from group (14),
0.2 to 50 parts by weight, preferably 1 to 20 parts by weight, of active ingredient from group (15),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (16),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, of active ingredient from group (17),
1 to 150 parts by weight, preferably 5 to 100 parts by weight of active ingredient from the group (18),
0.1 to 150 parts by weight, preferably 1 to 100 parts by weight, of active ingredient from group (19),
0.02 to 50 parts by weight, preferably 0.2 to 10 parts by weight, of active ingredient from group (20),
0.05 to 20 parts by weight, preferably 0.1 to 10 parts by weight, of active ingredient from group (21),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, of active ingredient from group (22),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (23),
0.02 to 50 parts by weight, preferably 0.04 to 10 parts by weight, of active ingredient from group (24),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (25),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, of active ingredient from group (26),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (27),
1 to 150 parts by weight, preferably 5 to 100 parts by weight, of active ingredient from group (28),
1 to 150 parts by weight, preferably 5 to 100 parts by weight, of active ingredient from group (29),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (30),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (31),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (32),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, of active ingredient from group (33),
0.1 to 50 parts by weight, preferably 1 to 20 parts by weight of active ingredient from the group (34),
0.1 to 50 parts by weight, preferably 1 to 10 parts by weight, of active ingredient from group (35),
1 to 150 parts by weight, preferably 5 to 100 parts by weight, of active ingredient from group (36),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, of active ingredient from group (37),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (38),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (39),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight, of active ingredient from group (40),
1 to 150 parts by weight, preferably 5 to 100 parts by weight, of active ingredient from group (41),
1 to 150 parts by weight, preferably 5 to 100 parts by weight, of active ingredient from group (42),
0.1 to 50 parts by weight, preferably 1 to 20 parts by weight, of active ingredient from group (43),
0.1 to 50 parts by weight, preferably 1 to 20 parts by weight of active ingredient from the group (44),
1 to 150 parts by weight, preferably 5 to 100 parts by weight, of active ingredient from the group (45a),
1 to 150 parts by weight, preferably 5 to 100 parts by weight, of active ingredient from the group (45b),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (46),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (47a),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (47b),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (47c),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (47d),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (47e),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (47f),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (47 g),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (47h),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (48),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (49),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (50),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from group (51),
0.1 to 50 parts by weight, preferably 0.2 to 20 parts by weight of active ingredient from the group (52).

Die erfindungsgemäßen Wirkstoffkombinationen besitzen sehr gute fungizide Eigen­ schaften und lassen sich zur Bekämpfung von phytopathogenen Pilzen, wie Plasmo­ diophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basi­ diomycetes, Deuteromycetes usw. einsetzen.The active compound combinations according to the invention have very good fungicidal properties and can be used to combat phytopathogenic fungi such as Plasmo diophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basi Use diomycetes, Deuteromycetes etc.

Die erfindungsgemäßen Wirkstoffkombinationen eignen sich besonders gut zur Be­ kämpfung Phytophthora infestans und Plasmopara viticola.The active compound combinations according to the invention are particularly suitable for loading fighting Phytophthora infestans and Plasmopara viticola.

Die gute Pflanzenverträglichkeit der Wirkstoffkombinationen in den zur Bekämp­ fung von Pflanzenkrankheiten notwendigen Konzentrationen erlaubt eine Behand­ lung von oberirdischen Pflanzenteilen, von Pflanz- und Saatgut, und des Bodens. Die erfindungsgemäßen Wirkstoffkombinationen können zur Blattapplikation oder auch als Beizmittel eingesetzt werden. The good plant tolerance of the active ingredient combinations in the control Treatment of the necessary concentrations of plant diseases allows treatment cultivation of parts of plants above ground, of plant and seed, and of the soil. The Active substance combinations according to the invention can be used for foliar application or can be used as a mordant.  

Die erfindungsgemäßen Wirkstoffkombinationen eignen sich auch zur Steigerung des Ernteertrages. Sie sind außerdem mindertoxisch und weisen eine gute Pflanzenver­ träglichkeit auf.The active compound combinations according to the invention are also suitable for increasing the Crop yield. They are also less toxic and show good plant ver indolence.

Erfindungsgemäß können alle Pflanzen und Pflanzenteile behandelt werden. Unter Pflanzen werden hierbei alle Pflanzen und Pflanzenpopulationen verstanden, wie erwünschte und unerwünschte Wildpflanzen oder Kulturpflanzen (einschließlich na­ türlich vorkommender Kulturpflanzen). Kulturpflanzen können Pflanzen sein, die durch konventionelle Züchtungs- und Optimierungsmethoden oder durch biotechno­ logische und gentechnologische Methoden oder Kombinationen dieser Methoden erhalten werden können, einschließlich der transgenen Pflanzen und einschließlich der durch Sortenschutzrechte schützbaren oder nicht schützbaren Pflanzensorten. Unter Pflanzenteilen sollen alle oberirdischen und unterirdischen Teile und Organe der Pflanzen, wie Spross, Blatt, Blüte und Wurzel verstanden werden, wobei beispielhaft Blätter. Nadeln, Stengel, Stämme, Blüten, Fruchtkörper, Früchte und Samen sowie Wurzeln, Knollen und Rhizome aufgeführt werden. Zu den Pflanzenteilen gehört auch Erntegut sowie vegetatives und generatives Vermehrungsmaterial, beispielsweise Stecklinge, Knollen, Rhizome, Ableger und Samen.According to the invention, all plants and parts of plants can be treated. Under Plants are understood here as all plants and plant populations desired and unwanted wild plants or crops (including na crops occurring naturally). Cultivated plants can be plants that by conventional breeding and optimization methods or by biotechno logical and genetic engineering methods or combinations of these methods can be obtained, including the transgenic plants and inclusive plant varieties that can or cannot be protected by plant breeders' rights. Plant parts should include all above-ground and underground parts and organs of plants, such as shoot, leaf, flower and root are understood, whereby exemplary leaves. Needles, stems, stems, flowers, fruiting bodies, fruits and Seeds as well as roots, tubers and rhizomes are listed. To the Plant parts also include crops as well as vegetative and generative Propagation material, for example cuttings, tubers, rhizomes, offshoots and Seeds.

Die erfindungsgemäße Behandlung der Pflanzen und Pflanzenteile mit den Wirkstof­ fen erfolgt direkt oder durch Einwirkung auf deren Umgebung, Lebensraum oder Lagerraum nach den üblichen Behandlungsmethoden, z. B. durch Tauchen, Sprühen, Verdampfen, Vernebeln, Streuen, Aufstreichen und bei Vermehrungsmaterial, insbe­ sondere bei Samen, weiterhin durch ein- oder mehrschichtiges Umhüllen.The treatment of the plants and plant parts according to the invention with the active ingredient fen takes place directly or through influence on their environment, living space or Storage room according to the usual treatment methods, e.g. B. by diving, spraying, Evaporation, misting, scattering, spreading and in the case of propagation material, in particular especially in the case of seeds, still by wrapping them in one or more layers.

Die erfindungsgemäßen Wirkstoffkombinationen können in die üblichen Formulie­ rungen überführt werden, wie Lösungen, Emulsionen, Suspensionen, Pulver, Schäu­ me, Pasten, Granulate, Aerosole, Feinstverkapselungen in polymeren Stoffen und in Hüllmassen für Saatgut, sowie ULV-Formulierungen. The active compound combinations according to the invention can be in the usual form tion, such as solutions, emulsions, suspensions, powders, foams me, pastes, granules, aerosols, very fine encapsulations in polymeric substances and in Envelopes for seeds and ULV formulations.  

Diese Formulierungen werden in bekannter Weise hergestellt, z. B. durch Vermischen der Wirkstoffe bzw. der Wirkstoffkombinationen mit Streckmitteln, also flüssigen Lösungsmitteln, unter Druck stehenden verflüssigten Gasen und/oder festen Träger­ stoffen, gegebenenfalls unter Verwendung von oberflächenaktiven Mitteln, also Emulgiermitteln und/oder Dispergiermitteln und/oder schaumerzeugenden Mitteln. Im Falle der Benutzung von Wasser als Streckmittel können z. B. auch organische Lösungsmittel als Hilfslösungsmittel verwendet werden. Als flüssige Lösungsmittel kommen im wesentlichen in Frage: Aromaten, wie Xylol, Toluol oder Alkylnaphtha­ line, chlorierte Aromaten oder chlorierte aliphatische Kohlenwasserstoffe, wie Chlorbenzole, Chlorethylene oder Methylenchlorid, aliphatische Kohlenwasserstoffe, wie Cyclohexan oder Paraffine, z. B. Erdölfraktionen, Alkohole, wie Butanol oder Glycol sowie deren Ether und Ester, Ketone, wie Aceton, Methylethylketon, Meth­ ylisobutylketon oder Cyclohexanon, stark polare Lösungsmittel wie Dimethyl­ formamid und Dimethylsulfoxid, sowie Wasser. Mit verflüssigten gasförmigen Streckmitteln oder Trägerstoffen sind solche Flüssigkeiten gemeint, welche bei nor­ maler Temperatur und unter Normaldruck gasförmig sind, z. B. Aerosol-Treibgase, wie Butan, Propan, Stickstoff und Kohlendioxid. Als feste Trägerstoffe kommen in Frage: z. B. natürliche Gesteinsmehle, wie Kaoline, Tonerden, Talkum, Kreide, Quarz, Attapulgit, Montmorillonit oder Diatomeenerde und synthetische Gesteins­ mehle, wie hochdisperse Kieselsäure, Aluminiumoxid und Silikate. Als feste Träger­ stoffe für Granulate kommen in Frage: z. B. gebrochene und fraktionierte natürliche Gesteine wie Calcit, Marmor, Bims, Sepiolith, Dolomit sowie synthetische Granulate aus anorganischen und organischen Mehlen sowie Granulate aus organischem Mate­ rial wie Sägemehl, Kokosnussschalen, Maiskolben und Tabakstengel. Als Emulgier- und/oder schaumerzeugende Mittel kommen in Frage: z. B. nichtionogene und anio­ nische Emulgatoren, wie Polyoxyethylen-Fettsäureester, Polyoxyethylen-Fettalko­ holether, z. B. Alkylarylpolyglycol-ether, Alkylsulfonate, Alkylsulfate, Arylsulfonate sowie Eiweißhydrolysate. Als Dispergiermittel kommen in Frage: z. B. Lignin-Sulfit­ ablaugen und Methylcellulose. These formulations are prepared in a known manner, e.g. B. by mixing of the active ingredients or combinations of active ingredients with extenders, i.e. liquid Solvents, pressurized liquefied gases and / or solid carriers substances, if necessary using surfactants, ie Emulsifiers and / or dispersants and / or foaming agents. In the case of the use of water as an extender, e.g. B. also organic Solvents are used as auxiliary solvents. As a liquid solvent essentially come into question: aromatics, such as xylene, toluene or alkylnaphtha line, chlorinated aromatics or chlorinated aliphatic hydrocarbons, such as Chlorobenzenes, chlorethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, e.g. B. petroleum fractions, alcohols, such as butanol or Glycol and its ethers and esters, ketones such as acetone, methyl ethyl ketone, meth ylisobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl formamide and dimethyl sulfoxide, as well as water. With liquefied gaseous Extenders or carriers are liquids that are nor painter temperature and under normal pressure are gaseous, z. B. aerosol propellants, such as butane, propane, nitrogen and carbon dioxide. As solid carriers come in Question: e.g. B. natural rock flour, such as kaolins, clays, talc, chalk, Quartz, attapulgite, montmorillonite or diatomaceous earth and synthetic rock flours, such as finely divided silica, aluminum oxide and silicates. As a solid support substances for granules are possible: z. B. broken and fractional natural Rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules from inorganic and organic flours as well as granules from organic mate such as sawdust, coconut shells, corn cobs and tobacco stalks. As an emulsifier and / or foam-generating agents are possible: z. B. non-ionic and anio African emulsifiers, such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohols holether, e.g. B. alkylaryl polyglycol ether, alkyl sulfonates, alkyl sulfates, aryl sulfonates as well as protein hydrolyzates. Possible dispersants are: B. Lignin sulfite leach and methyl cellulose.  

Es können in den Formulierungen Haftmittel wie Carboxymethylcellulose, natürliche und synthetische pulverige, körnige oder latexförmige Polymere verwendet werden, wie Gummiarabicum, Polyvinylalkohol, Polyvinylacetat, sowie natürliche Phospho­ lipide, wie Kephaline und Lecithine, und synthetische Phospholipide. Weitere Addi­ tive können mineralische und vegetabile Öle sein.Adhesives such as carboxymethyl cellulose, natural, can be used in the formulations and synthetic powdery, granular or latex-shaped polymers are used, such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospho lipids such as cephalins and lecithins, and synthetic phospholipids. More addi mineral and vegetable oils can be used.

Es können Farbstoffe wie anorganische Pigmente, z. B. Eisenoxid, Titanoxid, Ferro­ cyanblau und organische Farbstoffe, wie Alizarin-, Azo- und Metallphthalocyanin­ farbstoffe und Spurennährstoffe, wie Salze von Eisen, Mangan, Bor, Kupfer, Kobalt, Molybdän und Zink verwendet werden.Dyes such as inorganic pigments, e.g. B. iron oxide, titanium oxide, ferro cyan and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients, such as salts of iron, manganese, boron, copper, cobalt, Molybdenum and zinc can be used.

Die Formulierungen enthalten im allgemeinen zwischen 0,1 und 95 Gew.-% Wirk­ stoffe, vorzugsweise zwischen 0,5 und 90%.The formulations generally contain between 0.1 and 95% by weight of active ingredient substances, preferably between 0.5 and 90%.

Die erfindungsgemäßen Wirkstoffkombinationen können als solche oder in ihren Formulierungen auch in Mischung mit bekannten Fungiziden, Bakteriziden, Akariziden, Nematiziden oder Insektiziden verwendet werden, um so z. B. das Wirkungsspektrum zu verbreitern oder Resistenzentwicklungen vorzubeugen. In vielen Fällen erhält man dabei synergistische Effekte, d. h. die Wirksamkeit der Mischung ist größer als die Wirksamkeit der Einzelkomponenten.The active compound combinations according to the invention can be used as such or in their Formulations also in a mixture with known fungicides, bactericides, Acaricides, nematicides or insecticides can be used, e.g. B. that To broaden the spectrum of activity or to prevent the development of resistance. In many In this case, synergistic effects are obtained, i. H. the effectiveness of the mixture is greater than the effectiveness of the individual components.

Auch eine Mischung mit anderen bekannten Wirkstoffen, wie Herbiziden oder mit Düngemitteln und Wachstumsregulatoren ist möglich.A mixture with other known active ingredients, such as herbicides or with Fertilizers and growth regulators are possible.

Die Wirkstoffkombinationen können als solche, in Form ihrer Formulierungen oder den daraus bereiteten Anwendungsformen, wie gebrauchsfertige Lösungen, emul­ gierbare Konzentrate, Emulsionen, Suspensionen, Spritzpulver, lösliche Pulver und Granulate, angewendet werden. Die Anwendung geschieht in üblicher Weise, z. B. durch Gießen, Verspritzen, Versprühen, Verstreuen, Verstreichen, Trockenbeizen, Feuchtbeizen, Nassbeizen, Schlämmbeizen oder Inkrustieren. The active substance combinations can be used as such, in the form of their formulations or the resulting forms of use, such as ready-to-use solutions, emul gable concentrates, emulsions, suspensions, wettable powders, soluble powders and Granules. The application is done in the usual way, e.g. B. by pouring, spraying, spraying, scattering, spreading, dry pickling, Wet pickling, wet pickling, slurry pickling or incrustation.  

Beim Einsatz der erfindungsgemäßen Wirkstoffkombinationen können die Aufwand­ mengen je nach Applikationsart innerhalb eines größeren Bereichs variiert werden. Bei der Behandlung von Pflanzenteilen liegen die Aufwandmengen an Wirkstoff­ kombination im allgemeinen zwischen 0,1 und 10000 g/ha, vorzugsweise zwischen 10 und 1000 g/ha. Bei der Saatgutbehandlung liegen die Aufwandmengen an Wirk­ stoffkombination im allgemeinen zwischen 0,001 und 50 g pro Kilogramm Saatgut, vorzugsweise zwischen 0,01 und 10 g pro Kilogramm Saatgut. Bei der Behandlung des Bodens liegen die Aufwandmengen an Wirkstoffkombination im allgemeinen zwischen 0,1 und 10000 g/ha, vorzugsweise zwischen 1 und 5000 g/ha.When using the active compound combinations according to the invention, the effort quantities can be varied within a wide range depending on the type of application. In the treatment of parts of plants, the active compound application rates are combination generally between 0.1 and 10000 g / ha, preferably between 10 and 1000 g / ha. In the case of seed treatment, the application rates are active combination of substances generally between 0.001 and 50 g per kilogram of seed, preferably between 0.01 and 10 g per kilogram of seed. During treatment the application rates of the active ingredient combination are in general of the soil between 0.1 and 10000 g / ha, preferably between 1 and 5000 g / ha.

Die gute fungizide Wirkung der erfindungsgemäßen Wirkstoffkombinationen geht aus den nachfolgenden Beispielen hervor. Während die einzelnen Wirkstoffe in der fungiziden Wirkung Schwächen aufweisen, zeigen die Kombinationen eine Wirkung, die über eine einfache Wirkungssummierung hinausgeht.The good fungicidal activity of the active compound combinations according to the invention is successful from the examples below. While the individual active ingredients in the fungicidal activity weaknesses, the combinations show an effect, that goes beyond a simple summation of effects.

Ein synergistischer Effekt liegt bei Fungiziden immer dann vor, wenn die fungizide Wirkung der Wirkstoffkombinationen größer ist als die Summe der Wirkungen der einzeln applizierten Wirkstoffe.Fungicides always have a synergistic effect if the fungicides Effect of the drug combinations is greater than the sum of the effects of individually applied active ingredients.

Die zu erwartende Wirkung für eine gegebene Kombination zweier Wirkstoffe kann nach S. R. Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 15 (1967), 20-22) wie folgt berechnet werden:The expected effect for a given combination of two active substances can after S. R. Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations ", Weeds 15 (1967), 20-22) can be calculated as follows:

Wenn
X den Wirkungsgrad beim Einsatz des Wirkstoffes A in einer Aufwandmenge von m g/ha bedeutet,
Y den Wirkungsgrad beim Einsatz des Wirkstoffes B in einer Aufwandmenge von n g/ha bedeutet und
E den Wirkungsgrad beim Einsatz der Wirkstoffe A und B in Aufwandmengen von m und n g/ha bedeutet,
dann ist
If
X means the efficiency when using the active ingredient A in an application rate of m g / ha,
Y means the efficiency when using the active ingredient B in an application rate of n g / ha and
E means the efficiency when using active ingredients A and B in application rates of m and n g / ha,
then

Dabei wird der Wirkungsgrad in % ermittelt. Es bedeutet 0% ein Wirkungsgrad, der demjenigen der Kontrolle entspricht, während ein Wirkungsgrad von 100% bedeu­ tet, dass kein Befall beobachtet wird.The efficiency is determined in%. It means 0% efficiency corresponds to that of the control, while an efficiency of 100% means that no infection is observed.

Ist die tatsächliche fungizide Wirkung größer als berechnet, so ist die Kombination in ihrer Wirkung überadditiv, d. h. es liegt ein synergistischer Effekt vor. In diesem Fall muss der tatsächlich beobachtete Wirkungsgrad größer sein als der aus der oben angeführten Formel errechnete Wert für den erwarteten Wirkungsgrad (E).If the actual fungicidal effect is greater than calculated, the combination is in their effect superadditive, d. H. there is a synergistic effect. In this case the actually observed efficiency must be greater than that from the above listed formula calculated value for the expected efficiency (E).

Die Erfindung wird durch die folgenden Beispiele veranschaulicht. Die Erfindung ist jedoch nicht auf die Beispiele limitiert. The invention is illustrated by the following examples. The invention is but not limited to the examples.  

Beispiel 1example 1

Phytophthora-Test (Tomate)/protektiv
Lösungsmittel: 47 Gewichtsteile Aceton
Emulgator: 3 Gewichtsteile AlkylarylpolyglykoletherPhytophthora test (tomato) / protective
Solvent: 47 parts by weight of acetone
Emulsifier: 3 parts by weight of alkylaryl polyglycol ether

Zur Herstellung einer zweckmäßigen Wirkstoffzubereitung vermischt 1 Gewichtsteil Wirkstoff oder Wirkstoffkombination mit den angegebenen Mengen Lösungsmittel und Emulgator und verdünnt das Konzentrat mit Wasser auf die gewünschte Kon­ zentration oder man verdünnt eine handelsübliche Formulierung von Wirkstoff oder Wirkstoffkombination mit Wasser auf die gewünschte Konzentration.To produce a suitable preparation of active compound, 1 part by weight is mixed Active ingredient or combination of active ingredients with the stated amounts of solvent and emulsifier and dilute the concentrate with water to the desired con concentration or one dilutes a commercial formulation of active ingredient or Active ingredient combination with water to the desired concentration.

Zur Prüfung auf protektive Wirksamkeit werden junge Pflanzen mit der Wirkstoffzu­ bereitung in der angegebenen Aufwandmenge besprüht. Nach Antrocknen des Spritz­ belages werden die Pflanzen mit einer wäßrigen Sporensuspension von Phytophthora infestans inokuliert. Die Pflanzen werden dann in einer Inkubationskabine bei ca. 20°C und 100% relativer Luftfeuchtigkeit aufgestellt.To test for protective activity, young plants are added with the active ingredient preparation sprayed in the specified application rate. After the spray has dried The plants are covered with an aqueous spore suspension of Phytophthora infestans inoculated. The plants are then grown in an incubation cabin at approx. 20 ° C and 100% relative humidity.

3 Tage nach der Inokulation erfolgt die Auswertung. Dabei bedeutet 0% ein Wir­ kungsgrad, der demjenigen der Kontrolle entspricht, während ein Wirkungsgrad von 100% bedeutet, dass kein Befall beobachtet wird.Evaluation is carried out 3 days after the inoculation. 0% means a we efficiency that corresponds to that of the control, while an efficiency of 100% means that no infection is observed.

Die gefundene Wirkung der erfindungsgemäßen Wirkstoffkombination ist größer als die berechnete, d. h. es liegt ein synergistischer Effekt vor. Die Kombination aus Verbindung der Formel (I) und dem Halogen-benzimidazol der Formel Nr. XXVII besitzt bei einem Mischungsverhältnis von 1 : 1 und einer Aufwandmenge von 0,1 g/ha einen tatsächlichen Wirkungsgrad von 73%. Der nach der Colby-Formel be­ rechnete Erwartungswert ist mit 63% bedeutend geringer.The activity found of the active compound combination according to the invention is greater than the calculated, d. H. there is a synergistic effect. The combination of Compound of formula (I) and the halobenzimidazole of formula No. XXVII has a mixing ratio of 1: 1 and an application rate of 0.1 g / ha an actual efficiency of 73%. The Colby formula be expected value is significantly lower at 63%.

Wirkstoffe, Aufwandmengen und Versuchsergebnisse gehen aus den folgenden Ta­ bellen hervor. Active ingredients, application rates and test results are shown in the following days bark out.  

Tabelle 1 Table 1

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 2 Table 2

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 3 Table 3

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 4 Table 4

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 5 Table 5

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 6 Table 6

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 7 Table 7

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 8 Table 8

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 9 Table 9

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 10 Table 10

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 11 Table 11

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 12 Table 12

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 13 Table 13

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 14 Table 14

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 15 Table 15

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 16 Table 16

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 17 Table 17

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Tabelle 18 Table 18

Phytophthora-Test (Tomate)/protektiv Phytophthora test (tomato) / protective

Erfindungsgemäße Mischung Mixture according to the invention

Claims (6)

1. Wirkstoffkombinationen, enthaltend mindestens eine Verbindung der Formel
und
  • 1. ein Triazol-Derivat der Formel
    in welcher
    X für Chlor oder Phenyl steht, und
    Y für
    steht, und/oder
  • 2. das Triazol-Derivat der Formel
    und/oder
  • 3. ein Anilin-Derivat der Formel
    in welcher
    R1 für Wasserstoff oder Methyl steht,
    und/oder
  • 4. N-[1-(4-Chlor-phenyl)-ethyl]-2,2-dichlor-1-ethyl-3-methyl­ cyclopropan-carbonsäureamid der Formel
    und/oder
  • 5. das Zink-propylen-1,2-bis-(dithiocarbamidat) der Formel
    und/oder
  • 6. mindestens ein Thiocarbamat der Formel
    Me = Zn oder Mn oder Gemisch aus Zn und Mn
    und/oder
  • 7. das Anilin-Derivat der Formel
    und/oder
  • 8. die Verbindung der Formel
    und/oder
  • 9. das Benzothiadiazol-Derivat der Formel
    und/oder
  • 10. das 8-t-Butyl-2-(N-ethyl-N-n-propyl-amino)-methyl-1,4-dioxa­ spiro[5,4]-decan der Formel
    und/oder
  • 11. die Verbindung der Formel
    und/oder
  • 12. die Verbindung der Formel
    und/oder
  • 13. die Verbindung der Formel
    und/oder
  • 14. das Cyanoxim-Derivat der Formel
    und/oder
  • 15. ein Pyrimidin-Derivat der Formel
    in welcher
    R2 für Methyl oder Cyclopropyl steht,
    und/oder
  • 16. ein Anilin-Derivat der Formel
    und/oder
  • 17. das Morpholin-Derivat der Formel
    und/oder
  • 18. das Phthalimid-Derivat der Formel
    und/oder
  • 19. die Phosphor-Verbindung der Formel
    und/oder
  • 20. das Hydroxyethyl-triazol-Derivat der Formel
    und/oder
  • 21. das 1-[(6-Chlor-3-pyridinyl)-methyl]-N-nitro-2-imidazolidinimin der Formel
    und/oder
  • 22. das Oxazolidindion der Formel
    und/oder
  • 23. das Benzamid-Derivat der Formel
    und/oder
  • 24. das Guanidin-Derivat der Formel
    in welcher m für ganze Zahlen von 0 bis 5 steht und
    R3 für Wasserstoff (17 bis 23%) oder den Rest der Formel
    steht,
    und/oder
  • 25. das Triazol-Derivat der Formel
    und/oder
  • 26. das Halogen-benzimidazol der Formel
    und/oder
  • 27. das Halogenpyrimidin der Formel
    und/oder
  • 28. das Tetrachlor-isophthalo-dinitril der Formel
    und/oder
  • 29. die Verbindung der Formel
    und/oder
  • 30. das Pyridinamin der Formel
    und/oder
  • 31. das Thiazolcarboxamid der Formel
    und/oder
  • 32. das Sulfonamid der Formel
    und/oder
  • 33. die Verbindung der Formel
    und/oder
  • 34. die Verbindung der Formel
    und/oder
  • 35. die Verbindung der Formel
    und/oder
  • 36. dem Diamid der Formel
    und/oder
  • 37. das Methoxyacrylat-Derivat der Formel
    und/oder
  • 38. das Chinolin-Derivat der Formel
    und/oder
  • 39. das Phenylamid-Derivat der Formel
    und/oder
  • 40. das Phenylamid-Derivat der Formel
    und/oder
  • 41. das Dicarboxim-Derivat der Formel
    und/oder
  • 42. die Phosphonsäure der Formel
    und/oder
  • 43. das Pyrrol-Derivat der Formel
    und/oder
  • 44. das Phenylcarbonat der Formel
    und/oder
  • 45. die Kupferverbindungen
    • a) Kupferoxychlorid (XXXXVIa)
    • b) Kupferhydroxid (XXXXVIb)
    und/oder
  • 46. das Imidazol-Derivat der Formel
    und/oder
  • 47. das Triazolderivat der Formel
    und/oder
    und/oder
    und/oder
    und/oder
    und/oder
    und/oder
    und/oder
    und/oder
  • 48. eine Verbindung der allgemeinen Formel
    in welcher
    R1 für unsubstituiertes oder durch Fluor, Chlor, Brom, Methyl oder Ethyl substituiertes Phenyl, 2-Naphthyl, 1,2,3,4-Tetrahydronaphthyl oder Indanyl steht,
    und/oder
  • 49. N-Methyl-2-(methoxyimino)-2-[2-([1-(3-tri-fluoro-methyl­ phenyl)ethoxy]iminomethyl)phenyl]acetamid der Formel
    und/oder
  • 50. 2,4-Dihydro-5-methoxy-2-methyl-4-[2-([([1-(3-tri-fluoro­ methylphenyl)ethylidene]amino)oxy]methyl)phenyl]-3H-1,2,4-triazol-3-one der Formel
    und/oder
  • 51. die Verbindung der Formel
    und/oder
  • 52. die Verbindung der Formel
1. Active ingredient combinations containing at least one compound of the formula
and
  • 1. a triazole derivative of the formula
    in which
    X represents chlorine or phenyl, and
    Y for
    stands, and / or
  • 2. the triazole derivative of the formula
    and or
  • 3. an aniline derivative of the formula
    in which
    R 1 represents hydrogen or methyl,
    and or
  • 4. N- [1- (4-chlorophenyl) ethyl] -2,2-dichloro-1-ethyl-3-methylcyclopropane-carboxamide of the formula
    and or
  • 5. the zinc propylene-1,2-bis (dithiocarbamidate) of the formula
    and or
  • 6. at least one thiocarbamate of the formula
    Me = Zn or Mn or mixture of Zn and Mn
    and or
  • 7. the aniline derivative of the formula
    and or
  • 8. the compound of formula
    and or
  • 9. the benzothiadiazole derivative of the formula
    and or
  • 10. the 8-t-butyl-2- (N-ethyl-Nn-propylamino) methyl-1,4-dioxa spiro [5,4] decane of the formula
    and or
  • 11. the compound of formula
    and or
  • 12. The compound of the formula
    and or
  • 13. the compound of formula
    and or
  • 14. the cyanoxime derivative of the formula
    and or
  • 15. a pyrimidine derivative of the formula
    in which
    R 2 represents methyl or cyclopropyl,
    and or
  • 16. an aniline derivative of the formula
    and or
  • 17. the morpholine derivative of the formula
    and or
  • 18. The phthalimide derivative of the formula
    and or
  • 19. The phosphorus compound of the formula
    and or
  • 20. the hydroxyethyl triazole derivative of the formula
    and or
  • 21. The 1 - [(6-chloro-3-pyridinyl) methyl] -N-nitro-2-imidazolidinimine of the formula
    and or
  • 22. the oxazolidinedione of the formula
    and or
  • 23. the benzamide derivative of the formula
    and or
  • 24. The guanidine derivative of the formula
    in which m stands for integers from 0 to 5 and
    R 3 represents hydrogen (17 to 23%) or the rest of the formula
    stands,
    and or
  • 25. the triazole derivative of the formula
    and or
  • 26. The halogen benzimidazole of the formula
    and or
  • 27. The halopyrimidine of the formula
    and or
  • 28. The tetrachloroisophthalodinitrile of the formula
    and or
  • 29. the compound of formula
    and or
  • 30. The pyridinamine of the formula
    and or
  • 31. the thiazole carboxamide of the formula
    and or
  • 32. the sulfonamide of the formula
    and or
  • 33. the compound of the formula
    and or
  • 34. the compound of the formula
    and or
  • 35. the compound of the formula
    and or
  • 36. the diamide of the formula
    and or
  • 37. the methoxyacrylate derivative of the formula
    and or
  • 38. the quinoline derivative of the formula
    and or
  • 39. the phenylamide derivative of the formula
    and or
  • 40. the phenylamide derivative of the formula
    and or
  • 41. the dicarboxime derivative of the formula
    and or
  • 42. the phosphonic acid of the formula
    and or
  • 43. the pyrrole derivative of the formula
    and or
  • 44. the phenyl carbonate of the formula
    and or
  • 45. the copper compounds
    • a) Copper oxychloride (XXXXVIa)
    • b) copper hydroxide (XXXXVIb)
    and or
  • 46. the imidazole derivative of the formula
    and or
  • 47. the triazole derivative of the formula
    and or
    and or
    and or
    and or
    and or
    and or
    and or
    and or
  • 48. a compound of the general formula
    in which
    R 1 represents phenyl which is unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl,
    and or
  • 49. N-Methyl-2- (methoxyimino) -2- [2 - ([1- (3-tri-fluoro-methyl phenyl) ethoxy] iminomethyl) phenyl] acetamide of the formula
    and or
  • 50. 2,4-Dihydro-5-methoxy-2-methyl-4- [2 - ([([1- (3-tri-fluoro methylphenyl) ethylidene] amino) oxy] methyl) phenyl] -3H-1, 2,4-triazol-3-one of the formula
    and or
  • 51. the compound of formula
    and or
  • 52. the compound of the formula
2. Wirkstoffkombinationen, gemäß Anspruch 1, enthaltend mindestens eine Verbindung der Formel (I) wie in Anspruch 1 definiert und
  • 1. ein Anilin-Derivat der Formel
    und/oder
  • 2. das Zink-propylen-1,2-bis-(dithiocarbamidat) der Formel
    und/oder
  • 3. mindestens ein Thiocarbamat der Formel
    Me = Gemisch aus Zn und Mn
    und/oder
  • 4. das Anilin-Derivat der Formel
    und/oder
  • 5. die Verbindung der Formel
    und/oder
  • 6. die Verbindung der Formel
    und/oder
  • 7. die Verbindung der Formel
    und/oder
  • 8. die Verbindung der Formel
    und/oder
  • 9. das Phthalimid-Derivat der Formel
    und/oder
  • 10. das Hydroxyethyl-triazol-Derivat der Formel
    und/oder
  • 11. das Halogen-benzimidazol der Formel
    und/oder
  • 12. das Halogenpyrimidin der Formel
    und/oder
  • 13. das Tetrachlor-isophthalo-dinitril der Formel
    und/oder
  • 14. das Pyridinamin der Formel
    und/oder
  • 15. die Kupferverbindungen
    • a) Kupferoxychlorid (XXXXVIa)
    • b) Kupferhydroxid (XXXXVIb).
2. Active ingredient combinations according to claim 1, comprising at least one compound of the formula (I) as defined in claim 1 and
  • 1. an aniline derivative of the formula
    and or
  • 2. the zinc propylene-1,2-bis (dithiocarbamidate) of the formula
    and or
  • 3. at least one thiocarbamate of the formula
    Me = mixture of Zn and Mn
    and or
  • 4. the aniline derivative of the formula
    and or
  • 5. the compound of formula
    and or
  • 6. the compound of the formula
    and or
  • 7. the compound of formula
    and or
  • 8. the compound of formula
    and or
  • 9. the phthalimide derivative of the formula
    and or
  • 10. the hydroxyethyl triazole derivative of the formula
    and or
  • 11. The halogen benzimidazole of the formula
    and or
  • 12. The halopyrimidine of the formula
    and or
  • 13. The tetrachloroisophthalodinitrile of the formula
    and or
  • 14. The pyridinamine of the formula
    and or
  • 15. the copper connections
    • a) Copper oxychloride (XXXXVIa)
    • b) Copper hydroxide (XXXXVIb).
3. Mittel gemäß Anspruch 1, dadurch gekennzeichnet, dass in den Wirkstoff­ kombinationen das Gewichtsverhältnis von Wirkstoff der Formel (I) zu
  • - Wirkstoff der Gruppe (1) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (2) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (3) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (4) zwischen 1 : 0,1 und 1 : 10 liegt,
  • - Wirkstoff der Gruppe (5) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (6) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (7) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (8) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (9) zwischen 1 : 0,02 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (10) zwischen 1 : 0,1 und 1 : 50 liegt.
  • - Wirkstoff der Gruppe (l 1) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (12) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (13) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (14) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (15) zwischen 1 : 0,2 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (16) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (17) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (18) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (19) zwischen 1 : 0,1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (20) zwischen 1 : 0,02 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (21) zwischen 1 : 0,05 und 1 : 20 liegt,
  • - Wirkstoff der Gruppe (22) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (23) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (24) zwischen 1 : 0,02 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (25) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (26) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (27) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (28) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (29) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (30) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (31) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (32) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (33) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (34) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (35) zwischen 1 : 1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (36) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (37) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (38) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (39) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (40) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (41) zwischen 1 : 1 und 1 : 150 liegt.
  • - Wirkstoff der Gruppe (42) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (43) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (44) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (45a) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (45b) zwischen 1 : 1 und 1 : 150 liegt,
  • - Wirkstoff der Gruppe (46) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (47a) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (47b) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (47c) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (47d) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (47e) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (47f) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (47g) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (47h) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (48) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (49) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (50) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (51) zwischen 1 : 0,1 und 1 : 50 liegt,
  • - Wirkstoff der Gruppe (52) zwischen 1 : 0,1 und 1 : 50 liegt.
3. Composition according to claim 1, characterized in that in the active ingredient combinations the weight ratio of active ingredient of formula (I)
  • Active ingredient of group (1) is between 1: 0.1 and 1:50,
  • Active ingredient of group (2) is between 1: 0.1 and 1:50,
  • Active ingredient of group (3) is between 1: 1 and 1: 150,
  • Active ingredient of group (4) is between 1: 0.1 and 1:10,
  • Active ingredient of group (5) is between 1: 1 and 1: 150,
  • Active ingredient of group (6) is between 1: 1 and 1: 150,
  • Active ingredient of group (7) is between 1: 0.1 and 1:50,
  • Active ingredient of group (8) is between 1: 0.1 and 1:50,
  • Active ingredient of group (9) is between 1: 0.02 and 1:50,
  • - Active ingredient of group (10) is between 1: 0.1 and 1:50.
  • Active ingredient of group (l 1) is between 1: 0.1 and 1:50,
  • Active ingredient of group (12) is between 1: 0.1 and 1:50,
  • Active ingredient of group (13) is between 1: 0.1 and 1:50,
  • Active ingredient of group (14) is between 1: 0.1 and 1:50,
  • Active ingredient of group (15) is between 1: 0.2 and 1: 50,
  • Active ingredient of group (16) is between 1: 0.1 and 1:50,
  • Active ingredient of group (17) is between 1: 0.1 and 1:50,
  • Active ingredient of group (18) is between 1: 1 and 1: 150,
  • Active ingredient of group (19) is between 1: 0.1 and 1: 150,
  • Active ingredient of group (20) is between 1: 0.02 and 1:50,
  • Active ingredient of group (21) is between 1: 0.05 and 1:20,
  • Active ingredient of group (22) is between 1: 0.1 and 1:50,
  • Active ingredient of group (23) is between 1: 0.1 and 1:50,
  • Active ingredient of group (24) is between 1: 0.02 and 1:50,
  • Active ingredient of group (25) is between 1: 0.1 and 1:50,
  • Active ingredient of group (26) is between 1: 0.1 and 1:50,
  • Active ingredient of group (27) is between 1: 0.1 and 1:50,
  • Active ingredient of group (28) is between 1: 1 and 1: 150,
  • Active ingredient of group (29) is between 1: 1 and 1: 150,
  • Active ingredient of group (30) is between 1: 0.1 and 1:50,
  • Active ingredient of group (31) is between 1: 0.1 and 1:50,
  • Active ingredient of group (32) is between 1: 0.1 and 1:50,
  • Active ingredient of group (33) is between 1: 0.1 and 1:50,
  • Active ingredient of group (34) is between 1: 0.1 and 1: 50,
  • Active ingredient of group (35) is between 1: 1 and 1:50,
  • Active ingredient of group (36) is between 1: 1 and 1: 150,
  • Active ingredient of group (37) is between 1: 0.1 and 1:50,
  • Active ingredient of group (38) is between 1: 0.1 and 1:50,
  • Active ingredient of group (39) is between 1: 0.1 and 1: 50,
  • Active ingredient of group (40) is between 1: 0.1 and 1: 50,
  • - Active ingredient of group (41) is between 1: 1 and 1: 150.
  • Active ingredient of group (42) is between 1: 1 and 1: 150,
  • Active ingredient of group (43) is between 1: 0.1 and 1: 50,
  • Active ingredient of group (44) is between 1: 0.1 and 1: 50,
  • Active ingredient of group (45a) is between 1: 1 and 1: 150,
  • Active ingredient of group (45b) is between 1: 1 and 1: 150,
  • Active ingredient of group (46) is between 1: 0.1 and 1: 50,
  • Active ingredient of group (47a) is between 1: 0.1 and 1:50,
  • Active ingredient of group (47b) is between 1: 0.1 and 1:50,
  • Active ingredient of group (47c) is between 1: 0.1 and 1:50,
  • Active ingredient of group (47d) is between 1: 0.1 and 1:50,
  • Active ingredient of group (47e) is between 1: 0.1 and 1: 50,
  • Active ingredient of group (47f) is between 1: 0.1 and 1:50,
  • Active ingredient of the group (47g) is between 1: 0.1 and 1:50,
  • Active ingredient of the group (47h) is between 1: 0.1 and 1:50,
  • Active ingredient of group (48) is between 1: 0.1 and 1: 50,
  • Active ingredient of group (49) is between 1: 0.1 and 1: 50,
  • Active ingredient of group (50) is between 1: 0.1 and 1:50,
  • Active ingredient of group (51) is between 1: 0.1 and 1: 50,
  • - Active ingredient of group (52) is between 1: 0.1 and 1:50.
4. Verfahren zur Bekämpfung von Pilzen, dadurch gekennzeichnet, daß man Wirkstoffkombinationen gemäß mindestens einem der Ansprüche 1 bis 3 auf die Pilze und/oder deren Lebensraum ausbringt.4. Process for combating fungi, characterized in that Active substance combinations according to at least one of claims 1 to 3 which produces mushrooms and / or their habitat. 5. Verwendung von Wirkstoffkombinationen gemäß mindestens einem der Ansprüche 1 bis 3 zur Bekämpfung von Pilzen.5. Use of active ingredient combinations according to at least one of the Claims 1 to 3 for combating fungi. 6. Verfahren zur Herstellung von fungiziden Mitteln, dadurch gekennzeichnet, daß man Wirkstoffkombinationen gemäß mindestens einem der Ansprüche 1 bis 3 mit Streckmitteln und/oder oberflächenaktiven Stoffen vermischt.6. A process for the preparation of fungicidal compositions, characterized in that that active ingredient combinations according to at least one of claims 1 to 3 mixed with extenders and / or surfactants.
DE10021412A 1999-12-13 2000-05-03 Fungicidal active ingredient combinations Pending DE10021412A1 (en)

Priority Applications (32)

Application Number Priority Date Filing Date Title
DE10021412A DE10021412A1 (en) 1999-12-13 2000-05-03 Fungicidal active ingredient combinations
NZ519460A NZ519460A (en) 1999-12-13 2000-11-30 Fungicidal combinations of novel fluoro-benzothiazole active substances with other known fungicidal agents
HU0203563A HUP0203563A3 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances and use thereof
CNA2004100446979A CN1547911A (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
PT00985119T PT1239733E (en) 1999-12-13 2000-11-30 COMBINATIONS OF ACTIVE SUBSTANCES FUNGICIDES
PCT/EP2000/011989 WO2001044215A2 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
CZ20022079A CZ301233B6 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances, method of fighting fungi and use of such combinations of the active substances and process for preparing fungicidal agents
AT00985119T ATE243933T1 (en) 1999-12-13 2000-11-30 FUNGICIDAL ACTIVE COMBINATIONS
DE50002776T DE50002776D1 (en) 1999-12-13 2000-11-30 Fungicidal drug combinations
US10/149,353 US6624183B2 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
PL355756A PL200668B1 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
RU2002119003/04A RU2002119003A (en) 1999-12-13 2000-11-30 MIXTURES OF FUNGICIDAL ACTIVE SUBSTANCES
MXPA02005835A MXPA02005835A (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances.
AU21641/01A AU2164101A (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
DK00985119T DK1239733T3 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
EP00985119A EP1239733B1 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
BR0016336-8A BR0016336A (en) 1999-12-13 2000-11-30 Combinations of fungicidal active substances
ES00985119T ES2197124T3 (en) 1999-12-13 2000-11-30 COMBINATIONS OF FUNGICIDE ACTIVE PRODUCTS.
CA002393988A CA2393988A1 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
JP2001544705A JP2003516979A (en) 1999-12-13 2000-11-30 Fungicidal / fungicidal active substance combination agent
KR1020027006458A KR100613238B1 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
IL14955400A IL149554A0 (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
TR2002/01544T TR200201544T2 (en) 1999-12-13 2000-11-30 Compound combinations with fungicidal activity.
CN00817110.6A CN1212768C (en) 1999-12-13 2000-11-30 Fungicidal combinations of active substances
CO00094463A CO5221089A1 (en) 1999-12-13 2000-12-12 COMBINATIONS OF A FLUORBENZOTIAZOL AND FOLPET DERIVATIVE WITH FUNGICIDE ACTIVITY
TW089126400A TW590741B (en) 1999-12-13 2000-12-12 Fungicidal active compound combinations
ARP000106607A AR026938A1 (en) 1999-12-13 2000-12-13 COMBINATIONS OF FUNGICIDE ACTIVE PRODUCTS.
ZA200203650A ZA200203650B (en) 2000-05-03 2002-05-08 Fungicidal combinations of active substances.
IL149554A IL149554A (en) 1999-12-13 2002-05-09 Fungicidal combinations of active substances
US10/619,730 US7115593B2 (en) 1999-12-13 2003-07-15 Fungicidal combinations of active substances
US11/336,501 US7208510B2 (en) 1999-12-13 2006-01-20 Fungicidal combinations of active substances
US11/714,497 US7956009B2 (en) 1999-12-13 2007-03-06 Fungicidal combinations of active substances

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE19959947 1999-12-13
DE10021412A DE10021412A1 (en) 1999-12-13 2000-05-03 Fungicidal active ingredient combinations

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DE50002776T Expired - Lifetime DE50002776D1 (en) 1999-12-13 2000-11-30 Fungicidal drug combinations

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WO2010142779A1 (en) 2009-06-12 2010-12-16 Basf Se Antifungal 1,2,4-triazolyl derivatives having a 5- sulfur substituent
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