TW200731410A - Manufacturing method of semiconductor apparatus and surface processing method of SiN and SiO2 film - Google Patents

Manufacturing method of semiconductor apparatus and surface processing method of SiN and SiO2 film

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Publication number
TW200731410A
TW200731410A TW095134967A TW95134967A TW200731410A TW 200731410 A TW200731410 A TW 200731410A TW 095134967 A TW095134967 A TW 095134967A TW 95134967 A TW95134967 A TW 95134967A TW 200731410 A TW200731410 A TW 200731410A
Authority
TW
Taiwan
Prior art keywords
etching
sin
sio2
film
manufacturing
Prior art date
Application number
TW095134967A
Other languages
Chinese (zh)
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TWI369736B (en
Inventor
Yasushi Akasaka
Genji Nakamura
Original Assignee
Tokyo Electron Ltd
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Publication date
Application filed by Tokyo Electron Ltd filed Critical Tokyo Electron Ltd
Publication of TW200731410A publication Critical patent/TW200731410A/en
Application granted granted Critical
Publication of TWI369736B publication Critical patent/TWI369736B/zh

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/02104Forming layers
    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02109Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates
    • H01L21/02112Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer
    • H01L21/02123Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
    • H01L21/02164Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material being a silicon oxide, e.g. SiO2
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    • H01L21/02107Forming insulating materials on a substrate
    • H01L21/02296Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer
    • H01L21/02318Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment
    • H01L21/02321Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment introduction of substances into an already existing insulating layer
    • H01L21/02329Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment introduction of substances into an already existing insulating layer introduction of nitrogen
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    • H01L21/02057Cleaning during device manufacture
    • H01L21/0206Cleaning during device manufacture during, before or after processing of insulating layers
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    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
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    • H01L21/02107Forming insulating materials on a substrate
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    • H01L21/02123Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon
    • H01L21/02126Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing Si, O, and at least one of H, N, C, F, or other non-metal elements, e.g. SiOC, SiOC:H or SiONC
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    • H01L21/02337Forming insulating materials on a substrate characterised by the treatment performed before or after the formation of the layer post-treatment treatment by exposure to a gas or vapour
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    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
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    • H01L21/3143Inorganic layers composed of alternated layers or of mixtures of nitrides and oxides or of oxinitrides, e.g. formation of oxinitride by oxidation of nitride layers
    • H01L21/3144Inorganic layers composed of alternated layers or of mixtures of nitrides and oxides or of oxinitrides, e.g. formation of oxinitride by oxidation of nitride layers on silicon
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    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
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    • H01L21/318Inorganic layers composed of nitrides
    • H01L21/3185Inorganic layers composed of nitrides of siliconnitrides
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    • H01L21/3205Deposition of non-insulating-, e.g. conductive- or resistive-, layers on insulating layers; After-treatment of these layers
    • H01L21/321After treatment
    • H01L21/3213Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer
    • H01L21/32139Physical or chemical etching of the layers, e.g. to produce a patterned layer from a pre-deposited extensive layer using masks
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    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/70Manufacture or treatment of devices consisting of a plurality of solid state components formed in or on a common substrate or of parts thereof; Manufacture of integrated circuit devices or of parts thereof
    • H01L21/77Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate
    • H01L21/78Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices
    • H01L21/82Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components
    • H01L21/822Manufacture or treatment of devices consisting of a plurality of solid state components or integrated circuits formed in, or on, a common substrate with subsequent division of the substrate into plural individual devices to produce devices, e.g. integrated circuits, each consisting of a plurality of components the substrate being a semiconductor, using silicon technology
    • H01L21/8232Field-effect technology
    • H01L21/8234MIS technology, i.e. integration processes of field effect transistors of the conductor-insulator-semiconductor type
    • H01L21/8238Complementary field-effect transistors, e.g. CMOS
    • H01L21/823828Complementary field-effect transistors, e.g. CMOS with a particular manufacturing method of the gate conductors, e.g. particular materials, shapes
    • H01L21/823842Complementary field-effect transistors, e.g. CMOS with a particular manufacturing method of the gate conductors, e.g. particular materials, shapes gate conductors with different gate conductor materials or different gate conductor implants, e.g. dual gate structures
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    • H01L21/02142Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing silicon and at least one metal element, e.g. metal silicate based insulators or metal silicon oxynitrides
    • H01L21/02148Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing silicon the material containing silicon and at least one metal element, e.g. metal silicate based insulators or metal silicon oxynitrides the material containing hafnium, e.g. HfSiOx or HfSiON
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    • H01L21/02172Forming insulating materials on a substrate characterised by the type of layer, e.g. type of material, porous/non-porous, pre-cursors, mixtures or laminates characterised by the material of the layer the material containing at least one metal element, e.g. metal oxides, metal nitrides, metal oxynitrides or metal carbides
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    • H01L21/31Treatment of semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/26 to form insulating layers thereon, e.g. for masking or by using photolithographic techniques; After treatment of these layers; Selection of materials for these layers
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    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
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    • H01L29/66409Unipolar field-effect transistors
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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Plasma & Fusion (AREA)
  • Metal-Oxide And Bipolar Metal-Oxide Semiconductor Integrated Circuits (AREA)
  • Insulated Gate Type Field-Effect Transistor (AREA)
  • Cleaning By Liquid Or Steam (AREA)
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  • Weting (AREA)

Abstract

The present invention is to provide a manufacturing method of a semiconductor apparatus for removing SiN and SiO2 residues generated by selectively etching a hard mask constructed by SiN and SiO2 films without damaging bottom layer and further etching the remaining hard mask remarkably. The method includes steps of: forming an etching object film on a semiconductor substrate; forming SiN and SiO2 films on the etching object film; guiding nitrogen into the SiN and SiO2 films; selectively etching SiN and SiO2 film to form an etching mask; removing residue of SiN and SiO2 film by wet etching; applying wet etching to the etching object film through the etching mask; and removing the etching mask.
TW095134967A 2005-09-22 2006-09-21 Manufacturing method of semiconductor apparatus and surface processing method of SiN and SiO2 film TW200731410A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2005275594A JP4854245B2 (en) 2005-09-22 2005-09-22 Manufacturing method of semiconductor device

Publications (2)

Publication Number Publication Date
TW200731410A true TW200731410A (en) 2007-08-16
TWI369736B TWI369736B (en) 2012-08-01

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JP (1) JP4854245B2 (en)
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TWI490945B (en) * 2010-04-26 2015-07-01 Applied Materials Inc Method for processing substrate
CN105448835A (en) * 2010-10-29 2016-03-30 索尼公司 Semiconductor device

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JP5547878B2 (en) * 2008-06-30 2014-07-16 株式会社日立ハイテクノロジーズ Semiconductor processing method
US8058119B2 (en) * 2008-08-27 2011-11-15 Taiwan Semiconductor Manufacturing Company, Ltd. Device scheme of HKMG gate-last process
US7927943B2 (en) * 2008-09-12 2011-04-19 Taiwan Semiconductor Manufacturing Company, Ltd. Method for tuning a work function of high-k metal gate devices
US8980706B2 (en) * 2008-09-15 2015-03-17 Taiwan Semiconductor Manufacturing Company, Ltd. Double treatment on hard mask for gate N/P patterning
US7871915B2 (en) * 2008-09-26 2011-01-18 Taiwan Semiconductor Manufacturing Company, Ltd. Method for forming metal gates in a gate last process
US8222132B2 (en) * 2008-11-14 2012-07-17 Taiwan Semiconductor Manufacturing Company, Ltd. Fabricating high-K/metal gate devices in a gate last process
US20110042728A1 (en) * 2009-08-18 2011-02-24 International Business Machines Corporation Semiconductor device with enhanced stress by gates stress liner
JPWO2011033987A1 (en) * 2009-09-17 2013-02-14 東京エレクトロン株式会社 Film formation method, semiconductor element manufacturing method, insulating film, and semiconductor element
KR20120051915A (en) * 2010-11-15 2012-05-23 삼성전자주식회사 Methods of manufacturing a semiconductor device
WO2012147680A1 (en) * 2011-04-25 2012-11-01 東京エレクトロン株式会社 Film forming method
FR2979166A1 (en) * 2011-08-16 2013-02-22 St Microelectronics Crolles 2 Method for manufacturing metal oxide semiconductor transistor in semiconductor substrate, involves removing additional upper portion of silicon oxide layer and upper portion of silicon nitride layer by etching plasma offset
US8772114B2 (en) * 2012-03-30 2014-07-08 Taiwan Semiconductor Manufacturing Company, Ltd. Metal gate semiconductor device and method of fabricating thereof
US9385044B2 (en) * 2012-12-31 2016-07-05 Texas Instruments Incorporated Replacement gate process
CN104217954A (en) * 2013-06-05 2014-12-17 中芯国际集成电路制造(上海)有限公司 Formation method of transistors
US9070785B1 (en) * 2013-12-31 2015-06-30 Texas Instruments Incorporated High-k / metal gate CMOS transistors with TiN gates

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