TW200615334A - Silica-containing silicone resin composition and its molded product - Google Patents

Silica-containing silicone resin composition and its molded product

Info

Publication number
TW200615334A
TW200615334A TW094133138A TW94133138A TW200615334A TW 200615334 A TW200615334 A TW 200615334A TW 094133138 A TW094133138 A TW 094133138A TW 94133138 A TW94133138 A TW 94133138A TW 200615334 A TW200615334 A TW 200615334A
Authority
TW
Taiwan
Prior art keywords
silicone resin
resin composition
silica
group
containing silicone
Prior art date
Application number
TW094133138A
Other languages
Chinese (zh)
Other versions
TWI388629B (en
Inventor
Takashi Saito
Masayoshi Isozaki
Hideki Andoh
Akiko Yamasaki
Original Assignee
Nippon Steel Chemical Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Steel Chemical Co filed Critical Nippon Steel Chemical Co
Publication of TW200615334A publication Critical patent/TW200615334A/en
Application granted granted Critical
Publication of TWI388629B publication Critical patent/TWI388629B/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • G—PHYSICS
    • G02—OPTICS
    • G02B—OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
    • G02B1/00—Optical elements characterised by the material of which they are made; Optical coatings for optical elements
    • G02B1/04—Optical elements characterised by the material of which they are made; Optical coatings for optical elements made of organic materials, e.g. plastics
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C08K3/36—Silica
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
    • C08L43/04—Homopolymers or copolymers of monomers containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/08—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C08L51/085—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/08—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon
    • C08F230/085—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing silicon the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Silicon Polymers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

This invention provides a silica-containing silicone resin composition which can impart high heat resistance, high transparency, and high dimensional stability and is suitable, for example, for optical applications such as lenses, optical disks, optical fibers, and flat panel display substrates, and window materials for automobiles. This silica-containing silicone resin composition is produced by incorporating 1 to 70% by weight of silica fine particles into a silicone resin composition prepared by mixing a silicone resin, which is represented by [RSiO3/2]n wherein R represents an (meth)acryloyl-containing organic functional group; and n is 8, 10 or 12, and is composed mainly of polyorganosilsesquioxane having a basket structure in its structural units, and an unsaturated compound, which contains in its molecule at least one unsaturated group represented by –R3-CR3=CH2 or –CR4=CH2 wherein R3 represents an alkylene group, an alkylidene group, or group -OCO-; and R4 represents hydrogen or an alkyl group, and is radically copolymerizable with the silicone resin at a weight ratio of 1 : 99 to 99 : 1.
TW094133138A 2004-09-27 2005-09-23 Silica-containing polysiloxane resin composition and molded body TWI388629B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2004279508 2004-09-27

Publications (2)

Publication Number Publication Date
TW200615334A true TW200615334A (en) 2006-05-16
TWI388629B TWI388629B (en) 2013-03-11

Family

ID=36118795

Family Applications (1)

Application Number Title Priority Date Filing Date
TW094133138A TWI388629B (en) 2004-09-27 2005-09-23 Silica-containing polysiloxane resin composition and molded body

Country Status (5)

Country Link
JP (1) JP5000303B2 (en)
KR (1) KR100991025B1 (en)
CN (1) CN100545184C (en)
TW (1) TWI388629B (en)
WO (1) WO2006035646A1 (en)

Families Citing this family (21)

* Cited by examiner, † Cited by third party
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WO2008065862A1 (en) * 2006-12-01 2008-06-05 Konica Minolta Opto, Inc. Plastic optical device material, plastic optical device made of the same, and optical pickup device
KR101457254B1 (en) * 2007-09-28 2014-10-31 아사히 가라스 가부시키가이샤 Photocurable composition, method for producing fine patterned body, and optical device
JP5283885B2 (en) * 2007-10-23 2013-09-04 コリア エレクトロテクノロジー リサーチ インスティテュート Method for producing organic-inorganic hybrid material formed of polymer resin and hydrophobicized inorganic substance, and material produced thereby
KR101504308B1 (en) * 2007-12-27 2015-03-19 신닛테츠 수미킨 가가쿠 가부시키가이샤 Curable silicone copolymer containing cage structure and process for production thereof, and curable resin composition comprising curable silicone copolymer containing cage structure and cured product thereof
US8492496B2 (en) 2007-12-28 2013-07-23 3M Innovative Properties Company Copolymers of nanoparticles, vinyl monomers and silicone
KR101542637B1 (en) 2007-12-28 2015-08-06 쓰리엠 이노베이티브 프로퍼티즈 캄파니 Copolymers of nanoparticles, vinyl monomers and silicone
CN101981478B (en) 2008-04-08 2012-11-07 旭硝子株式会社 Manufacturing method for a wire grid polarizer
JP2011246548A (en) * 2010-05-25 2011-12-08 Showa Denko Kk Curable resin composition and transparent film
CN103068884B (en) 2010-08-13 2015-06-17 旭化成电子材料株式会社 Photosensitive silicone resin composition
WO2012133080A1 (en) * 2011-03-31 2012-10-04 新日鐵化学株式会社 Curable silicone resin composition and cured silicone resin
JP2013129766A (en) * 2011-12-22 2013-07-04 Nippon Steel & Sumikin Chemical Co Ltd Glass fiber-composited resin substrate
JP2013163789A (en) * 2012-02-13 2013-08-22 Asahi Kasei E-Materials Corp Photosensitive silicone resin composition
DE112013003864B4 (en) * 2012-08-03 2023-12-14 Mazda Motor Corporation Transparent layered structure and method for producing the same
JP6021605B2 (en) * 2012-11-19 2016-11-09 新日鉄住金化学株式会社 Cage type silsesquioxane compound, curable resin composition and resin cured product using the same
IT201600108121A1 (en) * 2016-10-26 2018-04-26 Pirelli New reinforcing materials, elastomeric compositions and tires for vehicle wheels that include them
KR102412888B1 (en) * 2017-05-12 2022-06-28 삼성디스플레이 주식회사 Hard coating composition, and window member having hard coating layer
JPWO2020162615A1 (en) * 2019-02-08 2020-08-13
CN112225534B (en) * 2020-10-25 2022-05-03 湖南长重机器股份有限公司 High-strength porous ceramsite and preparation method thereof
KR20230096008A (en) * 2020-10-29 2023-06-29 스미또모 가가꾸 가부시키가이샤 curable composition
KR102497162B1 (en) * 2020-12-03 2023-02-06 홍익대학교 산학협력단 Livestock storage tank made with fiber reinforced acryl polymer and manufacturing method of thereof
WO2023120495A1 (en) * 2021-12-22 2023-06-29 日鉄ケミカル＆マテリアル株式会社 Photocurable silicone resin composition and cured product thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4455205A (en) * 1981-06-01 1984-06-19 General Electric Company UV Curable polysiloxane from colloidal silica, methacryloyl silane, diacrylate, resorcinol monobenzoate and photoinitiator
AU6524400A (en) * 1999-08-04 2001-03-05 Hybrid Plastics Process for the formation of polyhedral oligomeric silsesquioxanes
JP3321563B2 (en) * 1999-08-06 2002-09-03 株式会社山勝 Earrings
KR100881301B1 (en) * 2001-04-09 2009-02-03 세키스이가가쿠 고교가부시키가이샤 Photoreactive composition
JP4381636B2 (en) * 2001-11-05 2009-12-09 新日鐵化学株式会社 Silicone resin composition and silicone resin molded article
JP4259148B2 (en) * 2002-03-28 2009-04-30 チッソ株式会社 Sealing material for LCD panels
JP4256756B2 (en) * 2002-09-30 2009-04-22 新日鐵化学株式会社 Method for producing cage-type silsesquioxane resin having functional group
KR100952094B1 (en) * 2003-02-27 2010-04-13 우베-니토 카세이 가부시키가이샤 Method for producing polyorganosiloxane particles and for producing silica particles
WO2004085501A1 (en) * 2003-03-27 2004-10-07 Nippon Steel Chemical Co., Ltd. Silicone resin composition and moldings thereof
JP2004314468A (en) * 2003-04-17 2004-11-11 Sumitomo Chem Co Ltd Transparent substrate with cured coat formed and curable composition for the substrate

Also Published As

Publication number Publication date
KR100991025B1 (en) 2010-10-29
CN101027330A (en) 2007-08-29
JP5000303B2 (en) 2012-08-15
TWI388629B (en) 2013-03-11
WO2006035646A1 (en) 2006-04-06
CN100545184C (en) 2009-09-30
KR20070058665A (en) 2007-06-08
JPWO2006035646A1 (en) 2008-07-31

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