200524721 玖、發明說明： 【發明所屬之技術領域】 本《明係關於由木質粉末材料組成的複合木質粉末及 其製造方法。具體地說，係關於在塑膠薄片、塑膠薄膜、 各種塑膠成形品以及塗料蓉中 科專中作為賦予各種特性的填充材 料和者色材料等使用時，把主要 要由木私組成的木質粉末材 =作為被載粉體，把硬f載體粒子固定在上述被載粉體的 、面的複合木質粉末及其製造方法；還係關於作為塗料中 的填充材㈣例如詩電磁波料㈣、電波吸收材料、 防靜電材料等的各種導電性用途的複合木質粉末及其製造 方法。 【先前技術】 妙、太=為了得到具有天然木材特性’特別是得到類似天 材表面特性的各種塑膠成形品、塑膠薄片以及塑膠薄 =^_„製品）等’以及對用塗料形成的各種家 〃 、σ曰用品類等的表面塗層或保護膜賦予同樣特性，嘗 3細粉末狀的木粉等木質粉末材料（以下簡稱木粉）I =形成塑膠製品的塑膠材料中、以及家具類和日用品類 寻表面塗層或保護膜的塗料中等。 賦予這種類似天然木材表面特性的原因是，為了有兮 出這些木材的韻味，通過添加規定量的木粉和規二 里的顏料’獲得模仿天然木材的色調。 :在作為塑膠成形用的填充材料使用破碎成細粉末狀 ^ ’但是要求上述木粉使用時不凝集㈣ 200524721 料等中具有良好的分散性，以及用塑膠成形裝置成形時可 抑制木酸氣體等產生。 對上述头點改進後的現有典型的木粉例如有用尿素類 树月曰硬化處理的層壓板的表面研磨粉。使用上述層壓板的 表面研磨粉的主要原因是，上述層壓板的表面研磨粉是微 細的，而且是纖維毛部分比較少的“顆粒，，狀。也就是因 為利用對層壓板的表面研磨方法，可以容易得到微細而且 光滑的細粉末狀研磨粉，特別是對塑膠製品的成形樹脂材 料具有良好分散性的細粉末狀研磨粉。 但另一方面，因為層壓板本身材料特性不具有材質均 勻的平均的木質特性，所以存在有這類層壓板的表面研 ㈣不會帶來材質均句的、平均的木材特性的問題。另外 逛存在有伴隨上述尿素類樹脂的硬化處理的硬化部分缺乏 普通木粉特有的吸濕性、防潮性等，而且缺乏木粉具有的 柔軟觸感等問題。 因此’現在嘗試把木材原料用 β刀具碾磨機等進行機械 切斷，同時用衝擊、剪切、麻 嫉… 轉^ "碎的破碎機，例如葉輪碾磨 柃寺進一步破碎成細粉末狀， ^ , 乂便用保留下來的此木材原 身具有的吸濕性能、防潮性能等的木粉的方法。 下面說明塑膠製品以及樹脂塗芦 的顏料。 曰土層荨的者色方法中所用 為了塑膠成形，通 ’還要求在成形樹 另一方面，用於塗 此顏料例如用於塑膠製品著色時， 常除了需要耐熱性和不溶於溶劑等之外 脂材料等中具有有效的良好的分散性。 200524721 料的顏料要求混合在塗敷液中的顏料本身不凝聚，在塗敷 液中的分散性良好，而且在塗敷液中不容易沈澱。另外， 用於粉體塗裝的顏料例如為了能與環氧樹脂粉體等有效混 合，需要具有良好的流動性。 此外使塗料具有導電性的填充材料例如電磁波遮罩材 料、電波吸收材料、防靜電材料等的導電性材料使用時， 對形成的塗層賦予這些各種電磁波遮罩、防靜電等特性的 導電性填充材料使用了 Ag，Cu，Ni等金屬細粉末、㈣，200524721 发明 Description of the invention: [Technical field to which the invention belongs] This "Ming system" is about composite wood powder composed of wood powder material and its manufacturing method. Specifically, it relates to the use of wood powder, which is mainly composed of wood, when it is used as a filling material and coloring material that imparts various characteristics to plastic sheets, plastic films, various plastic molded products, and paints. = As a supported powder, a composite wood powder having a hard f carrier particle fixed to the supported powder and its surface, and a method for manufacturing the same; it also relates to fillers used in coatings, such as poetic electromagnetic wave materials, and radio wave absorbing materials. Composite wood powder for various conductive uses such as antistatic materials and its manufacturing method. [Prior technology] Miao, Tai = In order to obtain the characteristics of natural wood 'especially to obtain a variety of plastic moldings, plastic sheet and plastic thin similar to the surface characteristics of natural materials = ^ _ „products, etc.' 〃, σ, and other surface coatings or protective films provide similar characteristics. Try fine wood powder materials such as wood powder (hereinafter referred to as wood powder). I = plastic materials forming plastic products, furniture and furniture. The surface coating or protective film coating of daily necessities is medium. The reason for giving the surface characteristics similar to natural wood is to imitate the flavor of these woods by adding a prescribed amount of wood flour and the pigment of Ruji The hue of natural wood.: When used as a filling material for plastic molding, it is broken into fine powder. ^ 'However, it is required that the above wood powder does not agglomerate when used. 200524721 Good dispersibility in materials, etc. Suppresses the production of xylic acid gas, etc. The existing typical wood flours, which have been improved on the above mentioned points, are for example, urea-based hardening treatment Laminate surface grinding dust mainly due to the above-described surface polishing powder is laminate, the laminate surface abrasive powder described above is a micro-fine, but a relatively small portion of the hair fibers "particle form ,,. That is, by using a surface grinding method for a laminate, it is easy to obtain a fine and smooth fine powdery grinding powder, particularly a fine powdery grinding powder having good dispersibility for a molded resin material of a plastic product. On the other hand, because the material properties of the laminate itself do not have the average wood characteristics of uniform materials, there is a problem that the surface study of such laminates does not bring about uniform and average wood characteristics of the materials. In addition, there is a problem that the hardened portion accompanying the hardening treatment of the urea-based resin lacks the moisture absorption and moisture resistance characteristic of ordinary wood flour, and lacks the soft touch of wood flour. Therefore 'now try to mechanically cut the wood raw materials with a β-knife mill, etc., while using impact, shearing, jealousy ... Turn ^ " A crushing crusher, such as an impeller mill to grind the temple to further crush it into a fine powder , ^, 乂 will use the wood powder method retained by the original wood with moisture absorption, moisture resistance and other methods. The pigments for plastic products and resin-coated reeds are described below. The color method used in the soil layer net is used for plastic molding, and it is also required to form the tree. On the other hand, when it is used to paint this pigment, for example, it is used for coloring plastic products. In addition to heat resistance and insoluble in solvents, etc. It has effective and good dispersibility in lipid materials. 200524721 The pigment is required to be mixed in the coating liquid, and the pigment itself does not aggregate, has good dispersibility in the coating liquid, and is not easy to precipitate in the coating liquid. In addition, the pigment used for powder coating needs to have good fluidity in order to be effectively mixed with epoxy resin powder and the like. In addition, when a conductive filler material such as an electromagnetic wave masking material, an electromagnetic wave absorbing material, or an antistatic material is used to make the coating have a conductive filler, the conductive coating that imparts these various electromagnetic wave shielding and antistatic properties to the formed coating is used. The material uses fine metal powders such as Ag, Cu, Ni, rhenium,
ZnO等金屬氧化物細粉末或碳細粉末等。這些導電性填充 材料要求均勾分散在各種樹脂塗料等塗敷液中使用。、 此外作為塑膠製品的填充材料等，通過使用無機材料 的細粉末例如碳酸約粉，使此塑膠製品具有所需的尺寸穩 定性和表面硬度等。 【專利文獻1】：特公平3 —598〇4號公報 【專利文獻2】··特公平4-59804號公報 但是，上述各現有㈣中分別存在有以下問題 到的塑膠製品和塗層 接觸時有發粘感覺的 面顯出此表面研磨粉 具有木材特有的柔軟 層壓板的表面研磨粉存在有對得 不能提供充分而且均勻的吸濕性能， 缺點。另外，在塑膠製品和塗層的表 具有的熱硬化性樹脂的硬化部分，不 觸感。 其次’用葉輪礙磨機等通過衝擊、剪切、摩捧等作用 破碎的破碎餘域木㈣料破碎彳㈣切，在木粉中且 有棱角部分和突出部分以及纖維毛狀的鬚鬚部分，而且: 200524721 有很多纖維狀細長的木粉， ^ ^ ^ 卜月b頁效提n堆密度，存在有 在塗料液、塗敷液等溶劑、溶 w ，合液中的分散性極差的不利點 ’逛具有在塑膠製品的成形樹 T曰何料專或塗料中凝聚的缺 點0 此外關於用於塗料的顏料，因為不能把得到的木粉顆 粒直徑變小，所以大多數情況下顏料分散不均句，不能得 到與顏料添加量相應的塑膠製 ^衣卩口的顯色。另外，作為載體 粒子的顏料的各粉末之間玄：| $ 易產生/旋聚，凝聚的顏料損壞 J膠製品的表面特性，產生顏色不均等。 士另外，所用顏料分散不均勾而且在溶劑、溶液中經長 日^後沈殿，所以不能使塗層得到與此顏料添加量相應的 顯色。而且’作為載體粒子的顏料的各粉末之間容易產生 嘁聚，凝聚的顏料損壞塑膠製品的塗層表面特性 色不均等。 < 這些粉 此外，進行粉體塗敷時，因為顏料流動性差 體相互混合不均勻，兩者相互形成大塊狀態。 分散不 在塗料中的導電性填充材料中容易產生凝聚 均勻。 *其結果在形成的塗層表面表現出此導電性填充材料的 ，集塊等，損害表面特性，產生塗層表面的波紋、條痕、 凝集塊部分的裂口、切口等現象，形成塗層的附著強度、 耐磨損性、耐水性、耐氣候性等分別降低。 另外’含有作為載體粒子的導電性填充材料細粉末的 塗層本身的導電性，因為這些缺點對導電性細粉末相互之 200524721 間的電結合狀態產生很大影響，所以塗敷液中含有的導電 性微粉體顆粒直徑越細，越有必要提高其混合率，因此存 在有得到塗層的導電性益给4 Μ θ |奋 7f…_疋好疋壞，附著強度和彈性等 會分別相對降低的不適宜的情況。 作為塑膠製品填充劑等使用的碳_粉末，使得到的 塑勝製品的一部分具有不同性質和形狀的軟質部分，存在 有不能使製品具有所需的均勻尺寸穩定性和均勻表面硬度 的問題。 馨於上述現有示例中不妥之處，本發明的目的是提供 -種複合木質粉末及其製造方法，木粉使用典型示例中提 2木質粉末材料堆密度的高堆密度木粉，通過把上述高堆 :度木粉作為被載體’在塑膠製品的成形樹脂材料、塗料 良好的分散性’而且使在木質粉末材料表面固定 功…曰，… 材原料特有的各種特性和 功此並且相在被㈣的木質粉末㈣表_定且有各 種性能的由顏料、導電材料、無機材料、金屬材料：塑胖 材料等細粉末組成的載體，得到木材原料本身和固定在‘ =末材料表面的載體粒子本身特有的各種特性和=木 ㈣把具有各種性能的載體粒子均句且可 密度的木質粉末材料表面。 又在同堆 本發明的另外目的是描 方法，μ伟呈亡種複合木質粉末及其製造 °，’’、使”有各種性能的載體粒子被埶穩 穩定地固定在高堆密度的木粉上的狀態。 子 【發明内容】 200524721 方法達到上述目的’本發明的複合木質粉末及其製造 於，到上述目的，本發明的複合木質粉末的特徵在 A ：分級的規定顆粒直徑範圍的木質粉末材料作 通過破碎用球之間的摩擦破碎作用，乾燥: 1G重量％’破壞木材組織並細化，使外面形狀 ==角部分和突出部分的實質上稍微有點固的形 =上述木質粉末材料的堆密度更大的高堆密度木 二ΐ比::對二T被載粉體的高堆密度木質粉 ^堆也、度被載粉體顆粒直徑更小而且硬 “由顏料、導電材料或無機材料、金屬材料、塑 ,、中任忍材料組成的一種或一種以上的多個載體 述球磨機的破碎用球之間的擠塵外力的擠虔，至少 子固疋在上述高堆密度被載粉體表面的一部分上。 法二：上述目的，本發明的複合木質粉末的製造方 友的特徵在於，該方沐念紅· 匕括.把木材原料用破碎機破边 :級，得到規定顆粒直徑範圍的、含水量小於的 :質粉末材料的處理步驟；將通過上述處 里： :粉末材料，利用球磨機的破碎用球之間的摩擦破= :仃破碎’破壞纖維狀的木材組織並細化，使外面卿 成為沒有棱角部分和突出部分的實質上稍微有點狀 ^ 4度比從上述處理步驟得到的木質於古从 :更大的高堆密度木質粉末材料組成的被載粉體心理牛 對上述高堆密度被載粉體，將比上述被載粉體顆粒； 200524721 徑更小、硬度更高、由顏料、導電材料或無機材料 材料、塑膠等中任意材料組成的一種或一種以上的多個： 體拉子，通過上述球磨機的破碎用球之間的㈣外 ，至少被固定在上述高堆密度被載粉體表面的-部分二 理步驟。 ,刀的處 另外，在上述複合木質粉末的製造方法中，把 體粒子擠壓固定在上述高 固載 徵在於，把多個載體位^ 載粉體表面的方式的特 夕们戰體粒子以叹入狀態結合在上述表 或以咬入狀態結合在上述表面上的同 體粒子的全部或-部分包住的狀態下結合，二: 以插入狀態結合在相互以載體拉子 體粒子之門… 乂入狀態結合在該表面的多個載 W工、，β 狀Κ合在彡亥表面的一個以上載 體拉子以及以包住狀態結合在該表面的 之間把«粒子則#人狀㈣ 載體粒子 結合方式。 狀―4，從中選擇—種以上的 括破：發明的複合木質粉末的製造方法的特徵在於，還包 卞而且與上述破碎同時進 破碎後進行分級，μ㈣或破碎而且在上述 述處理切— 纟貝私末材料的處理步驟；將從上 直徑更小、硬度更高的多個載體:;二上述被載粉體顆粒 物利用摩擦作用進行破碎進订混合’對其混合 大上述處理步驟得到的木所於古材組織並細化，一邊增 個上述載體粒子擠壓固==料的堆密度’-邊把多 载粉體的木質粉末材枓的一 或已增大堆密度的被 刀末材枓的高堆密度的表面的處理步驟。 200524721 時，利用1 ’進㈣用上述摩擦破碎作用的處理 體和高:密2 :::Γ的球磨機，把上述被載粉 又不貝杨末材料以及作為 沿者上下方向攪拌，同時 碎：降二料粒子 ，把多個上述載體粒子咬入二在:：？洛衝擊條件下 Τ又八結合在正在增大或 度的高堆密度的被載粉體的表面。 Θ大堆费 另外，優選破碎和乾燥是在使 的溫度為90〜12(rc 风門的上迷球 於m；的破碎條件下，使上=機的球磨機内溫度為小於等 於等於2.〇重量%。 木質粉末材料的含水量為小 H說明書中’在對木材原料進行破碎的 級或破碎原料材料後分級得到的木質粉末材料，通過2 =球之間的摩擦破碎❹，破壞木材組織並細化 貝上稍微有點園的形狀，得到堆密度比上述木質粉末^ 更大的面堆密度木質粉末材料，並把它稱之為被載粉體。 作為被載粉體的木質粉末㈣，利⑽擦破 行破碎，通過破壞上述木質粉 7進 毛狀鬚鬚部分等，形成整體上猶微有點園的形狀，並：它隹 :作高堆密度木質粉末材料。然後由於把多個載體粒子固 疋在表面的被載粉體是含有由高堆 部分這些木粉等的木質粉末材料組成的被 度的木質粉末材料，所以其本身本質上保留木材的 性和功能，同時固定在被載粉體表面的多個载體粒子覆蓋 12 200524721 1矣復：其表面’對這些高堆密度的木質粉末材料等形 、面屏障，保護上述高堆密度的木質粉末材料等，確實 有效地保護上述高堆密度的木質粉末材料等的特 日士 :得到的複合木質粉末容易具有作為填充材料等的良好： 机動性和混合分散性。同時使得到的複合木質粉末確 有載體粒子的各種特性和功能。 才木用本电B月的店，對木質粉末材料利用摩擦破碎作用 進行破碎，破壞上述木f粉末材料的纖維狀木心❹^ 化，除去上述木質粉末材料的有棱角部分、突出部分 維毛狀鬍鬚部分等’形成高堆密度的木質粉末材料，上述 向堆密度的木質粉末材料負載有各種載體粒子。得到的複 合木質粉末例1和複合木質粉末例2，都具有良好的流= 性和在溶劑中的良好分散性。 另外，上述載體粒子不僅可以均勻且容易固定在被載 粉體或高堆密度的木質粉末材料的表面，而且可以熱、化 學穩定地固定在被載粉體或高堆密度的木質粉末材料的表 面0 而且，上述複合木質粉末是用載體粒子覆蓋木質粉末 材料的表面，所以利用上述載體粒子，可有效保護組成上 述複合木質粉末的被載粉體或高堆密度的木質粉末材料特 有的木質材料的各種特性和性能。 通過複合木質粉末，可對使用物件物賦予原料材料的 各種特性和性能、以及固定在表面的載體粒子的各種特性 和性能。上述複合木質粉末保留了原料材料的各種特性和 13 200524721 性能，且在木質粉末材料的表面上固定了且有夂 載體粒子，例如顏料、 ，、有各種性能的 " 導電材料、無機材料、金;I #料 塑膠材料等粉末的一種或一種以上。 i屬材抖、 通過把較細顆粒直徑的m㈣+ 堆密度的木質粉末好粗沾主 + 仕被載粉體或兩 不貝f,末材科的表δ，在防止載體 凝集的同時，可對祛田此M W 丁 <间屋生 了對使用物件物進一步有效地 的各種特性和性能。 阿卞載體拉子 另外’通過把較細顆粒直徑的載體粒子固定在被載粉 體或南堆密度的木質粉末材料的表面，得到顆粒直徑比任 何载體粒子都大的且具有與上述載體粒子相同性能和特性 的粒子，所以可更加顯著地對使用物件物賦予載體粒子的 特性和性能，並且在塗敷液等中沈澱相對較少。 【實施方式】 下面詳細說明本發明的複合木質粉末及其製造方法的 各實施例。 〆 下面詳細說明通過適用于本發明一個實施例的加工處 理得到的複合木質粉末例1和複合木質粉末例2。 通過下述實施例進一步具體且詳細地說明複合木質粉 末例1和複合木質粉末例2的製造方法。 在這裏，上述實施例的複合木質粉末例丨的組成是， 把夕個上述木質粉末材料通過破碎用球之間的摩擦破碎作 用進行破碎處理，破環木材組織，微細化，整修外面形狀 ，形成增大堆密度的作為被載粉體的高堆密度木質粉末材 料後，將比被載粉體顆粒直徑更小且硬度更高的多個載體 14 200524721 粒子固定在各個被載粉體 合太皙扒古如〇 上述貫施例的複 二1㈣成是，把破碎木材原料得到的木質粉 σ比木質粉末材料顆粒直徑更小且硬度更 粒子利用破碎麾棟 11 、載體 田士 令作用進行破碎處理，在此實施例令利 用破碎用球之間的摩擦破碎作用進行破碎處理 個載體粒子擠壓m宕* 5守把夕 末材料表面= 載粉體的高堆密度的木質粉 把多個载體粒子擠愿固定在被載粉體的 表面後，伴隨繼續利用破碎用球< f1 μ $ 破碎處理，破…" 的摩擦破碎作用進行 載粉體的高堆密度木質 ：作為上述被 被載粉體。貝如末材科自身的堆密度’把它轉化 複合木質粉末例1 首先，對得到複合木質粉東 和其他製造方法進行說明。、 的一個典型製造方法 得到複合木質粉末例】的—個典型 將木材原料利用通過衝擊 /疋，首先 機進行破碎並同時分級、或Up摩擦破碎等作用的破碎 所而顆拉直輕範圍内的木質粉末材料㈣ 步驟中得到的木質粉末材料， 二者’仗上述處理 石古石六田°下處理步驟，即利用 卞用表之間的料破碎作用進行 細化，整修表面形狀，得到增加堆密 ^材組織並 高堆密度木質粉末材料；將 又的作為被载粉體的 被載粉體的高堆密度木質粉=理步驟中得到的作為 到的載體粒子利用球磨機，“=從其他處理步驟中得 幹式球磨機等加壓設備的 15 200524721 •Μ [外力’把载體粒子通過擠壓外力固 的上述高堆密度木質粉末材料的表面，由此：被裁粉體 粉末例1。 此奸到複合木質 在本次明書中，“利用摩擦破碎作用-,, 利用破碎用球之間的摩擦破碎作用進行破碎，仃 用球磨機的摩擦破碎作用對所要 ^曰利 而說明書中“球磨機”主要是指用授拌設==碎。 著二下和園周方向授拌，利用破碎用球之間的摩擦： 仃破碎的工具，包括容器旋轉型球磨 機。摩擦破碎Μ利用摩擦進行破碎。 及肩磨 2中木η末材㈣㈣料擦破碎作 質上整修外面形狀是指，將木質粉末材料通過利用= 碎作用的破碎，破壞木材_並域，破壞比較： =質粉末材料’形成更加接近於顆粒狀的形狀，通過戴 利用摩擦破碎作用的破碎來除去外面形狀有棱角部分以及 突出部分’形成實質上稍微有點園的形狀，通過利用摩挤 破碎作用的破碎來除去纖維毛狀的鬍鬚，使交錯結合纖維 毛狀鬍鬚等的比較疏鬆的狀態部分成為比較密的狀態，由 此使作為上述被載粉體的木質粉末材料的堆密度實質上增 力口0 、上述擠壓力是指從表面的外側施加的、主要通過 从:械α備例如合適的機械設備的擠壓力，它伴隨上述摩擦 破碎’也就是伴隨擠壓、料破碎而單獨產生或與破碎作 用組合產生的擠壓力等。 16 200524721 上述固疋是指不通過化學反應或粘接等方法，通 過從表面外側施加的„力固定，使其不容易分離。龙中 作=一《定方法的以包住狀態結合是指用作為被載粉體 ^堆&度木質粉末材料的表面’例如用其凹部或纖維毛 #在王邛或邛刀包住狀態下固定，使其不容易分離。 得到複σ木貝粉末例}的另—個典型製造方法是，通 過把載體粒子塗滿或通過預混合㈣在從上述方法得到的 作為被载粉體的高堆密度木質粉末材料上面後，將表面具 有上述載體粒子的高堆密度木質粉末材料提供給上述幹： 球磨機，把表面的載體粒子固定在作為被載粉體的高堆密 度木質粉末材料上，得到複合木質粉末例丨。 但是，把上述纟質粉末材料再次機械摩帛破碎得到的 作為被載粉體的高堆密度木㈣末材料，通過上述摩擦破 τ皮卒木貝私末材料，使較細長的纖維狀木質粉末材料 斷裂，破壞木材組織並細化，形成更接近顆粒狀的形狀， 通過利用摩擦破碎作用的破碎來除去外面形狀的有棱角部 分以及突出部分，形成實質上稍微有點園的則大，通過利 用摩擦破碎作用的破碎來除去纖維毛狀的鬚鬚，使交錯姓 合纖維毛狀_的比較疏鬆的狀態部分成為比較密的： 態’實質上整修其外形形狀’增加其堆密度，並且得到形 狀比較小的、更接近顆粒形狀，同時在保持上述木材原料 自身特有的各種特性及各種功能例如吸濕性、防潮性以及 良好觸感等的狀態下’把多個載體粒子容易而且可靠地固 定在被載粉體表面。 200524721 這樣得到的複合木質粉末例丨中，把載體粒子通過擠 壓力固定在被載粉體的高堆密度木質粉末材料上，所以上 述複合木質粉末例1的載體粒子容易且均勻地固定在被載 粉體的表面。 另外，這樣得到的複合木質粉末例丨中，把載體粒子 以p父入狀態結合來固定在作為被載粉體的高堆密度木質粉 末材料的表面，所以上述複合木質粉末例丨的載體粒子容 易且均勻地固定在被載粉體的表面。 這樣得到的複合木質粉末例丨中，組成複合木質粉末 的作為被載粉體的高堆密度木質粉末材料具有足夠大的堆 密度’並把載體粒子固定在增大堆密度的高堆密度木質粉 末材料的表面，所以得到的複合木質粉末流動性良好，、^ 用上述複合木質粉末時，複合木質粉末自身不會引起凝聚 。另外，向塗料等混合物件物中混合時，分散性良好。 載體粒子只通過簡單的擠壓力固定在被載粉體上，汽 以即使把得到的複合木質粉末例！用於溶液、溶劑中、^ 在高溫區域使用時，載體粒子也不會從高堆密度 :、 末材料分離。 這樣得到的複合木質粉末例！中的載體粒子，固定> 被載粉體表面的狀態下，可以發現作為載體粒子的各種 能和特性’所以與不固定在高堆密度的木質粉末材料的: 體粒子相比，其操作性良好。 中的載體粒子覆蓋 質粉末材料的表面 此外這樣得到的複合木質粉末例1 或幾乎覆蓋作為被載粉體的高堆密度木 18 200524721 形成表面屏P早，可阻止從内側的作為被載粉體的高堆密 2木誇末材料釋放木酸或木f素等。而且可承受外側的 …、負何，防止不必要的藥口米g楚 个要的枭口口類荨的浸入’充分保護上述高 堆密度木質粉末材料，能有效地把這些特性^複合木質 粉末。 、 P這樣得到的複合木質粉末例丨中，因為多個載體粒子 後盍在被載粉體的表面，所以高堆密度木質粉末材料中原 有強度面上的硬度低和比重丨，通過被硬度高、比重大的 載體粒子覆蓋其表面，相對得到補償和保護，具有足夠的 硬度。 而且作為被載粉體的高堆密度木f粉末材料因為比較 輕，所以可實現整體輕量化，並且可以靈活而有效使用以 往不能充分利用的木材的端材等’可以起到節省資源的作 :此’複合木質粉末例丨中的作為被載粉體的高堆密 度木質粉末材料和作為固定在上述被載粉體表面的載體粒 子的氧化鈦粉末顆粒直徑的粒度分佈大體如下，其前提是 在上述固定時氧化鈦粉末也同樣被破碎。 N堆松度木質粉末材料的粒度分佈··氧化鈦粉末 度分佈 1 〜30μπι: 1 〜5μπι。 、下面舉出作為上述木質粉末材料的普通木材原料硬度 以及作為比上述原料木材硬度更高的高硬度載體粒子的氧 化鈦、石反、鎳、碳酸鈣的硬度。其中所指硬度是，通過使 19 200524721 =從規定高度落下，測定衝撞後反彈高度^謂肖氏硬 木材原料：35〜50 氣化鈦：150〜18〇 碳：60〜95 1 υυ 碳酸鈣：12〇〜ι4〇 如上忒，因為被載粉體和高堆密度木 體粒子非常細’很難直接測定這些硬：：材料或菊 的“硬度”是前原材料狀態的硬度單位，例 &畏所指 複合木質粉末例2 氏硬度。 複合木質粉末例2的一個典型製造方法，、， 木材原料利用衝擊、剪切、摩擦破碎等：先通過把 破碎的科分級、或破碎後分級的處理步驟，=機進行 粒直徑範圍内的木質粉末材料。接著把 :斤需顆 ^木質粉末材料和從其他處理步驟中得到的 U用破碎㈣之間的摩擦破碎作用的破 利用破碎用球之間的摩擦破碎作用的破碎處理=驟太 =材二破壞木材組織並細化，增加木質粉末二二 擦破碎作用的摩擦破碎處理步驟固定在通==摩 之間的摩擦破碎作用的破碎處理步驟增加堆密度球 :被：粉體的高堆密度的木質粉末材料的表面Γ上述二 球之間的摩擦破碎作用的破碎處理步驟進行至使上 20 200524721 間的摩擦破碎作用成為堆 末材料。通過上述方法得 述被載粉體通過利用破碎用球之 密度充分增加的高堆密度木質粉 到複合木質粉末例2。 複合木質粉末例2的其他製造方法，通過把載體粒子 塗滿或通過預混合附著在從上述方法得到的作為被載粉體 的高堆密度木質粉末材料上面後，對附著有上述載體粒子 的被載粉體利用破碎用球之間的摩擦破碎作用進行破碎〆 理。在上述處理步驟中利用破碎用球之間的摩擦破碎作: =質粉末材料進行破碎處理，木f粉末材料斷裂，破壞 木貝組織並細化，得到堆宋声 "在度足夠大的面堆密度木質粉末 =用2上述載體粒子通過利用破碎用球之間的摩擦破 碎處理固定在通過利用破碎用球之間的摩擦破 卞乍用的破碎處理形成的作為被載粉體的高堆密度木質粉 末材枓：面。通過上述方法得到複合木質粉末例卜 木質粉末材料通過破碎用球之間的摩擦破碎作 碎，破壞木材組織並細化，通過破碎用球< & 衣之間的摩擦作用 二#組，織被破壞並被細化，使其外面以及表面形 載^體匕’實質上整修其表面形狀。這是因為同時把被 二子供給it過破碎用球之間的摩擦破碎作用 :破碎的破碎機中’或把載體粒子在木質粉末材料上塗 破二作Γ供給上述破碎機中，通過破碎用球之間的摩擦 的^果，進订破碎，以什麼方式整修被載粉體的表面形狀 前的摩疚而使堆密度增加。也就是利用在固定載體粒子之 引、擦破碎，或利用在固定載體粒子時的擠壓力，進一 21 200524721 ' 冑體粒子後’利用施力口在上述載體粒子方面的摩擦 破碎等，實質上整修表㈣狀。 ” 體地°兒，上述木質粉末材料通過利用上述破碎用 求門摩4破碎作用的破碎，使長纖維狀的高堆密度木質 知末材料斷裂，形成更加接近顆粒狀的形狀。另外，通過 摩::破碎除去木質粉末材料的有棱角部分、突出部分，形 f整體上更加接近顆粒狀的形狀。此外木質粉末材料的纖 維毛狀#1鬚部> ’被木質粉末材料周圍的載體粒子覆蓋或 =斷從載體粒子向外延伸的部分。上述木質粉末材料通過 破用上述破碎用球之間摩擦破碎作用的破碎，木材組織被 。展並被細化’表面受到擠壓和轉動，其表面形狀被修整 廷樣得到的複合木質粉末例2是通過上述破碎用球之 被細：破碎作用來破碎木質粉末材料，木材組織被破壞並 於二:形成堆密度增加的作為被载粉體的高堆密度木質 堆密声料而且把載體粒子固定在作為上述被載粉體的高 固^質粉末材料的表面，由此可靠均句地把载體粒子 丄’堆松度木質粉末材料上。另彳，得到的複合木質 :木2充分的流動性，在使用複合木質粉末時’上述複 貝粉末不會引起相互凝聚，在混合物件物中的分散性 為被^體^複合木質粉末例2中的載體粒子固定在作 離“體的向堆密度的木質粉末材料的表面，不容易分 而且上述固定通過擠壓力實現，所以上述複合木質粉 22 200524721 末p使用於/谷液或溶劑中或尚溫區域内，載體粒子也不會 從高堆密度木質粉末材料分離，載體粒子穩定地保留在高 堆密度木質粉末材料中。 上述複合木質粉末例2中的載體粒子固定於被載粉體 的表面狀態下’顯出載體粒子具有的各種功能和特性，所 以載體粒子在使用中不會產生相互凝聚。上述複合木質粉 末例2通過把原料木材利用機械方法破壞和破碎，保持上 述原料木材自身的各種功能和性能，例如吸濕性、防潮性 以及良好觸感，而且用載體粒子覆蓋或幾乎覆蓋高堆密度 木質粉末㈣的表®，形成屏障，由此使複合木質粉末有 效地具有木材原料的各種特性和功能。 複合木質粉末例1、複合木質粉末例2的製造方法 下面詳細說明複合木質粉末例丨、複合木質粉末例2 的製造方法。 其中上述複合木質粉末_ !、複合木質粉末仓,】2的各 裝方法中’製造複合木質粉末2時所用的木質粉末材 料’實質上對應于製造複合木f粉末W i時所用的木質粉 末材料；把多個載體粒子固定在複合木質粉末作"的表： 上的方法以及形式，與把多個载體粒子固定在複合木質粉 末例1的表面上的方法以及形式幾乎相同；所以在下面= 說明中以上述複合木質粉末例1 Μ心進行敘述，並且根 據需要也對複合木質粉末例2進行說明。 木質粉末材料 在此實施例中’作為破碎物件的原料…天然木材的種 23 200524721 類包括通常使用的日本鐵杉 任何—箱仏M 到文不4針葉樹、寬葉樹的 建举廢材等之夕除了使用這些木材或木屑、或鑛屬等 也把破碎處理的甘蔵（包括"渣）、 木和寻各種木質類材料作為原料使用。 ^對木材、木料木㈣料首先㈣當的已知機械$備 例如礙磨撼望 , 气佩口又1有 破碎 ，胃失木質材料各種功能的狀態下切斷和 乍為原材料大量準備顆粒直徑 最好顆粒直徑小於等於50一的木質粉末材^更細的、 料進二卜白=準備好的木材原料，根據需要可對原材 例=或除去不需要物質等的處理’上述原材料含有Fine metal oxide powder such as ZnO or fine carbon powder. These conductive fillers are required to be uniformly dispersed and used in coating liquids such as various resin coatings. In addition, as a filling material for plastic products, by using fine powder of inorganic materials such as carbonic acid powder, the plastic products have the required dimensional stability and surface hardness. [Patent Document 1]: Japanese Patent Publication No. 3-59804 [Japanese Patent Publication] [Japanese Patent Publication No. 4-59804] However, in each of the above-mentioned existing patents, the following problems exist in contact with plastic products and coatings The sticky surface shows that this surface grinding powder has a surface grinding powder which is unique to a soft laminate of wood, and has the disadvantage that it cannot provide sufficient and uniform moisture absorption performance. In addition, the hardened portion of the thermosetting resin on the surface of plastic products and coatings is not tactile. Secondly, use the impeller to impede the mill to crush and cut the wood material that is broken by impact, shear, friction, and other effects. The wood powder has corners and protrusions and fibrous hairy whiskers. And: 200524721 There are many fibrous and slender wood flours. ^ ^ ^ Page b to increase the n-bulk density, there are solvents in coating liquids, coating liquids, etc., and the dispersibility in the mixture is extremely poor. Disadvantages: shopping in plastic products has a disadvantage of forming materials or coatings. In addition, with regard to pigments used in coatings, the diameter of the obtained wood flour particles cannot be reduced, so the pigments are dispersed in most cases. For uneven sentences, the color development of plastic garments corresponding to the amount of pigment added cannot be obtained. In addition, between the powders of the pigment as the carrier particles: | $ It is easy to produce / spin together, and the agglomerated pigment damages the surface characteristics of the J rubber product, resulting in uneven color. In addition, the pigments used are not uniformly dispersed, and after a long period of time in the solvent and solution, Shen Dian Shen, so the coating can not get a color corresponding to the amount of pigment added. In addition, agglomeration is easily generated between each powder of the pigment serving as the carrier particles, and the agglomerated pigment damages the surface characteristics and color unevenness of the coating of the plastic product. < These powders In addition, when powder coating is performed, the pigments have poor fluidity and are not uniformly mixed with each other, so that the two form a bulk state with each other. Non-dispersion In conductive coating materials in coatings, it is easy to produce uniform agglomeration. * As a result, the surface of the formed coating exhibits the conductive filler material, agglomerates, etc., which damages the surface characteristics, and produces ripples, streaks on the surface of the coating, cracks and cuts in the agglomerates, and forms a coating. Adhesive strength, abrasion resistance, water resistance, weather resistance, and the like are reduced, respectively. In addition, the electrical conductivity of the coating layer containing the fine conductive powder as a carrier filler material, because these shortcomings greatly affect the electrical bonding state between the conductive fine powders 200524721, so the conductive contained in the coating liquid The finer the particle size of the fine powder, the more it is necessary to increase the mixing ratio. Therefore, there is a conductivity of the coating to give 4 Μ θ | fen 7f ..._ 疋 Good or bad, the adhesion strength and elasticity will be relatively reduced. Unsuitable circumstances. The carbon powder used as a filler for plastic products, etc., makes part of the obtained plastic products have soft parts with different properties and shapes, and there is a problem that the products cannot have the required uniform dimensional stability and uniform surface hardness. Xin is inadequate in the above existing examples. The object of the present invention is to provide a composite wood powder and a method for manufacturing the same. The wood powder uses a high bulk density wood powder with a bulk density of 2 wood powder materials in a typical example. High pile: The wood powder is used as a carrier 'good dispersibility in the molding resin material of plastic products and coatings', and it fixes the work on the surface of the wood powder material .... ㈣Wood powder㈣ Table _ A carrier consisting of fine powders such as pigments, conductive materials, inorganic materials, metal materials, plastic materials, etc. with various properties, to obtain the wood raw material itself and the carrier particles fixed on the surface of the end material The various characteristics and peculiarities of the wood powder make the surface of the wood powder material with uniform and dense carrier particles with various properties. In the same pile, another object of the present invention is to describe the method, μ Wei presents the composite wood powder and its manufacturing °, so that carrier particles with various properties are stably and stably fixed to the wood powder with high bulk density. [Content of the invention] 200524721 The method achieves the above-mentioned object 'the composite wood powder of the present invention and its manufacture, to the above-mentioned object, the characteristic of the composite wood powder of the present invention is A: a graded wood powder having a predetermined particle diameter range The material is crushed by the friction between the crushing balls and dried: 1G% by weight 'destroys the wood structure and refines it so that the outer shape == the corner portion and the protruding portion are substantially slightly solid in shape = Higher bulk density of high-density wood ΐ :: For high-density wood powder with two T-loaded powders, the size of the powder particles is smaller and harder "by pigments, conductive materials or inorganic Materials, metal materials, plastics, or any material composed of one or more multiple carriers, the crushing force between the crushing balls of the ball mill, the external force of the squeeze, at least fixed in the It said high bulk density powder is contained on a portion of the surface. Method 2: For the above purpose, the friend of the manufacturer of the composite wood powder of the present invention is characterized in that the Fang Mu-nian red dagger is used. The wood raw material is crushed by a crusher: grade to obtain a specified particle diameter range with a moisture content of less than : The processing steps of quality powder materials; will pass the above:: powder materials, friction between the balls using a ball mill for crushing =: 仃 crushing 'destroys the fibrous wood structure and refines it so that the outer layer becomes no The corners and protrusions are slightly slightly ^ 4 degrees higher than the woody wood obtained from the above processing steps: a larger high-density wood powder material composed of a powder-loaded psychological cow is carried by the above-mentioned high-bulk density Powder, which will be smaller than the above-mentioned powder particles; 200524721, one or more of a plurality of smaller diameters, higher hardness, and any material selected from pigments, conductive materials or inorganic materials, plastics, etc .: The outer part of the ball mill between the crushing balls of the ball mill is fixed at least on the surface of the high-bulk-density powder-containing two-step process. In addition, in the manufacturing method of the composite wood powder described above, the body particles are squeezed and fixed to the above-mentioned high-solid loading characteristic in that a plurality of carrier sites ^ are placed on the surface of the powder, and the particles of the war are The state of sighing is combined on the above table or the state of all or-part of the homogeneous particles bound on the surface in the state of biting. The second is: the state of being inserted in the door of the child particles being pulled by the carrier ... A plurality of carriers loaded on the surface in a state of being inserted, one or more carrier pulls in which β-shaped κ is combined on the surface of the surface, and «particles # 人 状 ㈣ carrier, which is bound to the surface in a wrapped state. Particle binding. State-4, from which to choose—more than one kind of encapsulation: the method for producing the composite wood powder according to the invention is characterized in that it also includes the encapsulation and is classified after being crushed simultaneously with the above crushing, μ㈣ or crushed and cut in the above-mentioned treatment— 纟The processing steps of shell powder materials; multiple carriers with smaller diameters and higher hardness from the upper diameter ;; 2 the above-mentioned powder particles to be crushed and crushed by friction; The structure of the ancient wood is refined and refined, while the above carrier particles are squeezed and solidified == the bulk density of the material '-while the multi-powder-laden wood powder material is smashed, or the bulk material of the knife has been increased in bulk density. High-density surface treatment steps for plutonium. At 200524721, the above-mentioned friction-breaking treatment body and a high: dense 2 ::: Γ ball mill were used to stir the powder-loaded material without Yang Yang material as well as the up and down direction of the person while crushing: Drop the second particles, and bite multiple of the above carrier particles into two ::? Under the condition of Rockwell impact, T is bound to the surface of the powder being loaded with increasing bulk density. Θ Large pile cost In addition, it is preferable to crush and dry at a temperature of 90 ~ 12 (rc damper of the upper ball to m; in a crushing condition, the temperature in the ball mill of the upper machine is equal to or less than 2. The moisture content of the wood powder material is the wood powder material graded in the small H manual 'classified after crushing the wood raw material or crushing the raw material material, and crushed by friction between 2 = balls, destroying the wood structure and Refine the slightly rounded shape on the shellfish to get a bulk density wood powder material with a higher bulk density than the above-mentioned wood powder ^, and call it a powder-loaded wood powder. ⑽Breaking and breaking, through the destruction of the above-mentioned wood powder 7 into the hair-like whiskers, etc., to form a slightly round shape as a whole, and: it 隹: as a high bulk density wood powder material. Then because of the multiple carrier particles The powder that is fixed on the surface is a wood powder material consisting of a wood powder material such as a high pile of wood powder. Therefore, it inherently retains the properties and functions of the wood and fixes it at the same time. Covering multiple carrier particles on the surface of the loaded powder 12 200524721 1 complex: its surface 'forms and barriers against these high bulk density wood powder materials, etc., and protects the high bulk density wood powder materials, etc., which is indeed effective To protect the above-mentioned high bulk density wood powder material, etc .: The obtained composite wood powder is easy to have good properties as a filling material: mobility and mixing dispersibility. At the same time, the obtained composite wood powder does have various carrier particles. Features and functions: Only used in the shop of Benden Electric Co., Ltd., the wood powder material was crushed by friction and crushing to destroy the fibrous wood core of the wood powder material, removing the angular portions of the wood powder material, The protruding portion has a hairy beard portion, etc., forming a high bulk density wood powder material, and various carrier particles are supported on the bulk density wood powder material. The obtained composite wood powder example 1 and composite wood powder example 2 have good properties. Flow = properties and good dispersibility in solvents. In addition, the above carrier particles can not only be uniformly and easily fixed to The surface of the powder carrier or the high bulk density wood powder material can be thermally and chemically fixed to the surface of the powder carrier or the high bulk density wood powder material. Moreover, the composite wood powder is coated with carrier particles on the wood. The surface of the powder material, so the use of the carrier particles can effectively protect the various characteristics and properties of the wood material peculiar to the loaded powder or the high bulk density wood powder material constituting the composite wood powder. The composite wood powder can be used for The object gives various characteristics and properties of the raw material material, and various characteristics and properties of the carrier particles fixed on the surface. The above-mentioned composite wood powder retains various characteristics of the raw material material and 13 200524721 properties, and is fixed on the surface of the wooden powder material And there are rhenium carrier particles, such as pigments, and various types of " conductive materials, inorganic materials, gold; I # material plastic materials and other powder one or more. The material belongs to the material shake. By mixing the fine particle diameter m㈣ + the bulk density of the wood powder into the main + powder or powder, the table δ of the endaceous material can prevent the carrier from agglomeration, and can The various characteristics and performances of the MW Ding < Majestic House, which are more effective for the use of objects. Aya carrier puller also 'fixes the carrier particles with a finer particle diameter on the surface of the supported powder or the wood powder material of the south density to obtain a particle diameter larger than any of the carrier particles and has the same carrier particles as above. Particles with the same properties and characteristics can more significantly impart the characteristics and properties of the carrier particles to the use object, and relatively less precipitate in the coating liquid and the like. [Embodiment] Hereinafter, each embodiment of the composite wood powder of the present invention and a manufacturing method thereof will be described in detail. 〆 A detailed description of the composite wood powder example 1 and the composite wood powder example 2 obtained by processing suitable for one embodiment of the present invention will be described below. The production method of the composite wood powder example 1 and the composite wood powder example 2 will be described more specifically and in detail with reference to the following examples. Here, the composition of the composite wood powder example of the above-mentioned embodiment is that the above-mentioned wood powder material is subjected to a crushing treatment by the frictional crushing action between the crushing balls to break the wood structure, miniaturize, and repair the outer shape to form After increasing the bulk density of the high-density wood powder material as a supported powder, a plurality of carriers having a smaller diameter and higher hardness than the supported powder particles 14 200524721 The particles are fixed to each of the supported powders. According to the above-mentioned example 2 of the above-mentioned embodiment, the wood powder σ obtained by crushing the wood raw material has a smaller particle diameter and a harder particle than the wood powder material. The crushing process is performed by using the crushing tower 11 and the carrier Tian Shiling. In this embodiment, the frictional crushing effect between the crushing balls is used to perform the crushing treatment. The carrier particles are squeezed out. * 5. The surface of the material = wood powder with a high bulk density of the powder carrier squeezes multiple carrier particles. Would like to fix it on the surface of the powder carrier, and continue to use the crushing ball < f1 μ $ High bulk density wood: as the above-mentioned supported powder. It is converted into a bulk wood powder by the bulk density of the beruaceae family. Example 1 First, a method for obtaining a composite wood powder and other manufacturing methods will be described. An example of a typical manufacturing method to obtain composite wood powder]-a typical use of wood raw materials through the impact / 疋, the first machine to crush and simultaneously classify, or Up friction crushing and other functions to straighten the light within the range The wood powder material obtained in the step ㈣ of the wood powder material is based on the above-mentioned treatment step of the ancient stone Liutian °, that is, using the material crushing effect between the surface of the concrete to refine and repair the surface shape to obtain an increased bulk material structure. And high bulk density wood powder material; the high bulk density wood powder which is another powder to be loaded is used as the carrier particles obtained in the processing step using a ball mill, "= obtained from other processing steps 15 200524721 • M [External force 'presses the carrier particles to solidify the surface of the above-mentioned high bulk density wood powder material by extruding external force, thereby: Example 1 of the powder to be cut. This is to composite wood In this book, "Using frictional crushing--, crushing using frictional crushing between crushing balls, Crushing action to be rubbed on the specification ^ Lee said "ball" primarily refers to grant stirred provided == broken. Stir in two directions and around the garden, using the friction between the crushing balls: 仃 Crushing tools, including container-rotating ball mills. Friction crushing is performed by friction. The rubbing and crushing of the wood η final material in the shoulder-grinding 2 to make the quality of the outer shape is to use the wood powder material to break through the crushing action to destroy the wood _ and the comparison. The shape is close to a granular shape, and the outer corners and protrusions are removed by wearing a crushing action using friction crushing to form a slightly round shape. The fibrous hairy beard is removed by crushing using a crushing crushing action. In order to make the relatively loose parts such as the staggered-bonded fiber hairy beards into a denser state, the bulk density of the wood powder material as the powder-loaded body is substantially increased by 0, and the pressing force means The pressing force applied from the outside of the surface, mainly through: mechanical equipment, such as suitable mechanical equipment, is accompanied by the above-mentioned frictional crushing, that is, the compression generated by the crushing alone or in combination with the crushing effect. Force etc. 16 200524721 The above-mentioned solid fixation means that it is not easily separated by applying a force applied from the outside of the surface without using chemical reaction or bonding methods. Longzhong Zuo = a method of binding in a fixed state means using For example, the surface of the powdered wooden powder material, such as its recessed portion or fiber hair, is fixed in the state of being wrapped by a king or a trowel so that it cannot be easily separated. Example of obtaining a compound σ wooden shell powder} Another typical manufacturing method is to coat the carrier particles with pre-mixed or pre-mixed high-density wood powder material obtained from the above method as the supported powder, and then place the high-heap with the carrier particles on the surface. The dense wood powder material is provided to the above-mentioned dry: a ball mill, which fixes the carrier particles on the surface to a high bulk density wood powder material as a supported powder, to obtain a composite wood powder example. However, the above-mentioned saponin powder material is mechanically rubbed again The high-density wood chip material obtained as a powder-bearing material by crushing the concrete is crushed by the friction material of the τ skin dead wood shell material by the above-mentioned friction, so as to make a relatively thin fibrous wood powder. The material breaks, destroys the wood structure and refines it to form a more granular shape. By using the crushing action to remove the angular and protruding parts of the outer shape, a slightly rounded one is formed. By using friction, The fragmentation of the crushing action removes the fibrous hairy whiskers, making the relatively loose state of the staggered and fibrous hairy part denser: the state 'substantially repairs its shape and shape' increases its bulk density, and obtains a shape comparison Smaller, closer to the shape of the particles, while maintaining the various characteristics and functions unique to the wood material itself such as moisture absorption, moisture resistance, and good touch The surface of the powder carrier. 200524721 In the composite wood powder example thus obtained, the carrier particles are fixed to the powdered high bulk density wood powder material by pressing force, so the carrier particles of the composite wood powder example 1 are easy and It is evenly fixed on the surface of the powdered body. In addition, the composite wood powder obtained in this way In the example 丨, the carrier particles are combined in the parent state to be fixed on the surface of the high bulk density wood powder material as the powder to be carried, so the carrier particles of the above composite wood powder example 丨 are easily and uniformly fixed to the powder to be carried In the example of the composite wood powder obtained in this way, the high bulk density wood powder material constituting the composite wood powder as a supported powder has a bulk density sufficiently large and the carrier particles are fixed at a high bulk density. The surface of the bulk density wood powder material, so the obtained composite wood powder has good fluidity. When the above composite wood powder is used, the composite wood powder itself does not cause agglomeration. In addition, when mixed into a mixture such as paint, the dispersibility Good. The carrier particles are only fixed to the powder to be supported by a simple extrusion force. Even if the composite wood powder is obtained, it is used in solutions, solvents, and when used in high temperature areas, the carrier particles will not High bulk density: Separation of the final material. Example of composite wood powder thus obtained! In the state of the carrier particles in the fixed> surface of the supported powder, various energies and characteristics of the carrier particles can be found 'so compared with the bulk particles of the wood powder material that is not fixed at high bulk density: its operability good. The carrier particles in the coating cover the surface of the powdery material. In addition, the composite wood powder example 1 obtained in this way or almost covers the high-density wood 18 as a supported powder. 18 200524721 The surface screen P is formed early, which can prevent the powder from being loaded from the inside. The high-density 2 quark material releases xylic acid or lignin, etc. Moreover, it can withstand the external ..., unnecessary, prevent the invasion of unnecessary medicines and mouthfuls, and fully protect the above-mentioned high-density wood powder materials, which can effectively combine these characteristics ^ composite wood powder . In the example of composite wood powder obtained in the manner of P and P, because multiple carrier particles lie on the surface of the supported powder, the hardness and specific gravity of the original strength surface of the high bulk density wood powder material are low. 2. The carrier particles with large specific gravity cover the surface, which is relatively compensated and protected, and has sufficient hardness. In addition, as a high-density wood f powder material as a loaded powder, it is relatively light, so it can achieve overall weight reduction, and it can flexibly and effectively use wood end materials that have not been fully utilized in the past. The particle size distribution of the diameter of the titanium dioxide powder particles as the high-density wood powder material as the supported powder and the carrier particles fixed on the surface of the supported powder in this example of the composite wood powder is as follows. The titanium oxide powder was also broken during the above-mentioned fixing. Particle size distribution of N-powder wood powder material · Titanium oxide powder Degree distribution 1 to 30 μm: 1 to 5 μm. The hardness of ordinary wood raw materials as the above-mentioned wood powder materials and the hardness of titanium oxide, stone, nickel, and calcium carbonate as high-hardness carrier particles higher than the hardness of the raw wood materials are listed below. The hardness referred to is that by measuring 19 200524721 = falling from a predetermined height and measuring the rebound height after impact ^ is called Shore hardwood raw material: 35 ~ 50 titanium gasification: 150 ~ 18〇 carbon: 60 ~ 95 1 υυ calcium carbonate: 12〇 ～ ι4〇 As above, because the loaded powder and high bulk density wood particles are very fine, it is difficult to directly measure these hardness :: The "hardness" of a material or chrysanthemum is the hardness unit of the former raw material state, for example & fear Referred composite wood powder example 2 hardness. A typical manufacturing method of composite wood powder example 2, wood materials using impact, shearing, friction crushing, etc .: First, through the processing steps of classifying the crushed branch or classifying after crushing, the machine performs wood in the particle diameter range. Powder material. Next, break the friction between the crushed wooden powder material and the U crushing mash obtained from other processing steps. Use the friction crushing between the crushing balls. Wood organization and refinement, increase the friction and crushing treatment steps of rubbing and crushing of wood powder. The crushing and crushing steps of friction and crushing are fixed at pass == friction, and increase the bulk density. Ball: quilt: powder with high bulk density of wood The surface of the powder material is crushed by the friction crushing step between the two balls described above until the friction crushing effect between 20 200524721 becomes the pile material. According to the method described above, the bulk powder to be used was obtained by using a high bulk density wood powder whose density of the crushing balls was sufficiently increased to a composite wood powder example 2. In another manufacturing method of the composite wood powder example 2, the carrier particles are coated with the carrier particles or pre-mixed and adhered to the high bulk density wood powder material obtained from the above method, and then the substrates to which the carrier particles are attached are coated. The powder carrier uses the frictional crushing action between the crushing balls to perform the crushing process. In the above processing steps, the frictional crushing between the crushing balls is used: = The powdery material is crushed, the wood powder material is broken, the structure of the mussel is broken and refined, and the pile of songs is obtained. Bulk Density Wood Powder = High bulk density as a supported powder formed by using the above carrier particles by using a frictional crushing process between crushing balls to fix the crushing process by using frictional crushing between the crushing balls. Wood powder material: surface. The composite wood powder is obtained by the above method. For example, the wood powder material is crushed by the friction between the crushing balls, destroying the wood structure and refining. The friction effect between the crushing balls & clothing ##, weaving It is destroyed and refined so that its outer surface and surface-shaped carrier body substantially repairs its surface shape. This is because at the same time, the two particles are supplied to it through the frictional crushing action between the crushing balls: in the crushing crusher, or the carrier particles are coated on the wooden powder material, and the two are supplied to the crusher. As a result of the friction, the order is broken, and the guilt before repairing the surface shape of the powder-loaded body increases the bulk density. That is to say, by using the attraction, rubbing and crushing of the fixed carrier particles, or by using the squeezing force when the carrier particles are fixed, further into 2005 200524721 'after the carcass particles', the frictional crushing of the carrier particles by the force application port, etc. Refurbish the table. In general, the above-mentioned wooden powder material is broken by using the crushing effect of the above-mentioned crushing Qiu Mo 4 to break the long-fibrous high-density wood powdered material into a more granular shape. In addition, through friction :: Crushing removes the angular and protruding parts of the wood powder material, and the shape is more close to the granular shape as a whole. In addition, the fiber hairiness of the wood powder material # 11 部> is covered by the carrier particles around the wood powder material Or = break the part extending outward from the carrier particles. The above-mentioned wood powder material is broken by breaking the frictional crushing action between the above-mentioned crushing balls, and the wood tissue is stretched and refined. The surface is squeezed and rotated, and its surface Example 2 is a composite wood powder obtained by trimming the shape of the sample. The above-mentioned crushing ball is used to pulverize the wood powder material: the crushing action breaks the wood powder material, and the wood structure is destroyed. Bulk density wood compacts the acoustic material and fixes the carrier particles on the surface of the high solid powder material as the above-mentioned powder to be supported, thereby being reliable Carrier particles are piled on the loose wood powder material. In addition, the obtained composite wood: Wood 2 has sufficient fluidity. When the composite wood powder is used, the above-mentioned complex shell powder does not cause mutual cohesion. The dispersibility in the mixture is that the carrier particles of the composite wood powder in Example 2 are fixed on the surface of the bulk wood powder material that is separated from the bulk, which is not easy to separate and the above fixation is achieved by squeezing force. Therefore, the above-mentioned composite wood powder 22 200524721 is used in / valley fluid or solvent or in a high temperature region, and the carrier particles will not be separated from the high bulk density wood powder material, and the carrier particles remain stably in the high bulk density wood powder material. . In the state where the carrier particles of the composite wood powder example 2 are fixed to the surface of the supported powder ', various functions and characteristics of the carrier particles are exhibited, so that the carrier particles do not agglomerate during use. The above-mentioned composite wood powder example 2 uses raw material wood to be mechanically destroyed and broken to maintain various functions and properties of the raw material wood itself, such as hygroscopicity, moisture resistance, and good touch, and it is covered or almost covered with carrier particles. The density of the powdered wood powder® forms a barrier, so that the composite wood powder effectively has the characteristics and functions of wood raw materials. Production method of composite wood powder example 1 and composite wood powder example 2 The production method of composite wood powder example 丨 and composite wood powder example 2 will be described in detail below. Wherein the above-mentioned composite wood powder _, composite wood powder bin, [2] each of the packaging methods 'the wood powder material used in manufacturing the composite wood powder 2' substantially corresponds to the wood powder material used in manufacturing the composite wood f powder W i The method and form of fixing a plurality of carrier particles to the composite wood powder are as follows: The method and form of fixing the plurality of carrier particles to the surface of the composite wood powder Example 1 are almost the same; In the description, the above-mentioned composite wood powder example 1 is described, and the composite wood powder example 2 is also described as necessary. In this embodiment, the wood powder material is used as the raw material of the broken object ... The species of natural wood 23 200524721 includes any commonly used Japanese hemlock—box 仏 M to Wenbu 4 coniferous, broadleaf construction waste, etc. In addition to using these woods or sawdusts, or minerals, crushed gannet (including "slag"), wood, and various wood-based materials are used as raw materials. ^ Known machinery for wood, wood and wood materials. For example, it is difficult to look forward to, and the aerobic mouth is broken, and the stomach loses various functions of the wood material. The size of the raw materials is the largest. Good wood powder material with a particle diameter of 50 or less. ^ Finer, feed into two = white wood material prepared, according to need, the original material can be treated = or unnecessary materials are removed. The above raw materials contain
二、、丹争酸或不需要的色素、樹脂成分等，上 處理可分別採用已知方法。 I 對已破碎的原料實施前處理。首先利用作為 "的例如通過衝擊、剪切、摩擦破碎等作用進r 破碎的礙磨機等已知破碎機’破碎上述各木材原料，^ 在不損失木質材料各種特性和功能的狀態下，得到作為原 材料的優選顆粒直徑小於等於20—的木質粉末材料:、 j種情況下，把原料木材通過利用衝擊、剪切、摩擦 破碎等作用破碎得到的作為原材料的木質粉末材料，保S 木材本身固有的各種特性和功能，含有長纖維且周圍表面 產生纖維狀的細長纖維毛狀鬍鬚。 這樣得到的作為原材料的木質粉末材料具有許多有棱 角部分、突出部分等，顯示出整體上體積增加而且相互 聚的傾向。 24 200524721 这像破碎得到的破碎木 破碎後進行分級’根據使用目：：二：:碎的同時或 。 粒度的木質粉末材料 如上該準備的作為原材料的木質 處理步驟中，也就是在利用破碎用球：二’在此後的 進订破碎處理即摩擦破碎處理的步驟中或在:作用 處理之前進行乾痒，+月卷 一 摩U、石皮碎 侵選小於耸於S舌曰〇/ 、等；】〇重量％， 4於8重1%，更優選小於等於3重量％。 々後面5亥’其中作為上述原材料的木 燥，不僅對上述木質粉太好粗、s、 、物禾材科的乾 面改質作用，而且盥使 有有效的表 合和分散時，不會對上述物件物產生壞影響。 “ 然後對通過上述處理步料 耠丈鉍祖別m ^ W雨原材枓的木質 心末材枓’利用破碎用球之間的摩擦破碎作用進行破碎， 貫施機械方法的摩擦破碎處理。在複合木質粉末例！令， 在載體粒子以前進行對木f粉末材料的摩擦破碎處理。 在復合木質粉末例2中，與載體粒子一起或在固定載體粒 子時或之後進行摩擦破碎處理。 幹式球磨機 用於上述機械摩擦破碎處理的典型設備有已知的幹式 球磨機。下面對利用上述幹式球磨機的摩擦破碎處理以及 用於製造複合木質粉末们的高堆密度木質粉末材料的形 成進行說明。 利用上述幹式球磨機對木質粉末材料或被載粉體進行 25 200524721 摩擦破碎處理中，伴隨上述摩擦破碎處理步驟，球磨機内 的溫度急劇上升，可能會造成爆炸，而且因在高溫區域内 ^察破碎’木質粉末材料或增加堆密度的高堆密度木質粉 末材料就會損失本身特有的各種特性和功能，所以通過把 冷部套管安裝在球磨機、幸# , 仕天恩機主體内壁’從供水管到排水管一直 :共:冷：：’使上述球磨機内的溫度至少保持在小於等於 80 C ’優遥小於等於。 上述=:在球磨機内部設置授拌杆和多個破碎用球3， 球3通過上㈣摔㈣摔*=的㈣手段’上述破碎用 開放的上方投入木質於太好 生摩擦破碎作用，從 閥經過取出口 7取+ 運行，處理結束後從取出 出7取出到外部，是所謂間歇結構。 =情況下，為得到上述摩擦破碎 用球-直rn5mm的氧化 1皮碎 易引起爆炸的不錢鋼球。 是球，它避免了使用容 入到具有上述結構的幹式球磨機的處理步驟中，π 入到球磨機内的木質粉末/驟中技 之間的摩擦破碎處理，县… 拌並轉動的破碎用球 摩碎而破碎，木…4 木質粉末㈣因斷裂、 除去木質粉末材料的有棱角部分、：接：顆粒狀， 鬚部分等，或使其變形，整體上更：^、纖維毛狀謂 質上稍微有點園的形狀等二更加接近顆粒狀’形成實 ，得到增加堆密 /、卜面形狀得到實質上的整修 .L 又的阿堆密度木質粉末材料。 夕對上述木質粉末材料進行上述摩擦破碎處理時， 26 200524721 ίΪ::碎之間或各破碎用球和木質粉末材料之間產 〜〜劇加熱至戶斤需溫度，除去上述木質粉末材料 的水为，而且繼續進行上述摩擦破彳，使其乾燥至水八 不足3重量％〜5重量％。 刀 也就是在上述球磨機内的球溫度為9〇〜12〇它、球 内^度為小於#於8G°⑽破碎條件下，可以乾燥破碎至含 水虿小於等於2·0重量％、顆粒直徑小於等於16/zm，得到 作為被載粉體的乾燥微細的木質粉末材料。Second, the salicylic acid or unwanted pigments, resin components, etc. can be treated by known methods. I Pre-treatment of broken raw materials. First of all, known crushers such as impact mills, such as impact, shear, friction crushing, etc., are used to crush the above-mentioned wood raw materials, ^ without losing the various characteristics and functions of the wood material, A wood powder material having a preferred particle diameter of 20- or less as a raw material is obtained: In case j, the wood powder material as a raw material is obtained by crushing the raw wood by using impact, shear, friction and crushing to protect the wood itself. Various inherent characteristics and functions, including long fibers, and a fibrous slender fibrous beard on the surrounding surface. The wood powder material obtained as a raw material in this way has many angular portions, protruding portions, and the like, and shows a tendency to increase in volume as a whole and to aggregate with each other. 24 200524721 This is like the crushed wood obtained from the crushing. The classification after crushing ’is based on the purpose of use: 2: two :: simultaneous or broken. The particle size of the wood powder material is the same as the wood processing step prepared as a raw material, that is, in the step of using the crushing ball: two 'in the subsequent step of the crushing treatment, that is, the friction crushing treatment or before: the effect of dry itching ， + 月 卷一 摩 U, stone skin crushing infiltration is less than 小于 / 舌, etc;] 0% by weight, 4 to 8 weight 1%, more preferably 3% by weight or less. 々The following 5 Hai 'wood drying as the above-mentioned raw materials, not only the above-mentioned wood flour is too coarse, s,, and the dry surface of the material family of the material to improve the role, but also when the toilet has effective formulation and dispersion, it will not Have a bad effect on the above objects. "Then the wood heart end material 枓 bismuth ancestor m ^ W rain raw material 通过 through the above processing steps is crushed using the friction crushing action between the crushing balls, and a mechanical crushing treatment is applied. Example of composite wood powder! Let the friction crushing treatment of wood f powder material be performed before the carrier particles. In composite wood powder example 2, the friction crushing treatment is performed together with the carrier particles or when or after the carrier particles are fixed. Dry ball mill Typical equipment used for the mechanical friction crushing process is a known dry ball mill. The friction crushing process using the dry ball mill and the formation of a high bulk density wood powder material for manufacturing composite wood powders are described below. Using the above-mentioned dry ball mill to perform a wood crushing process on a wooden powder material or a loaded powder 25 200524721 In the friction crushing process, the temperature in the ball mill rises sharply with the above-mentioned friction crushing process, which may cause an explosion, and it may be broken in high temperature areas. 'Wood powder materials or high bulk density wood powder materials that increase bulk density will Due to the unique characteristics and functions of the ball mill, the inner wall of the main body of the Shi Tianen machine was installed from the water supply pipe to the drain pipe by installing the cold part casing on the ball mill, Xing #, to make the temperature inside the ball mill above. Keep it at least 80 C or less. 'Youya is less than or equal to the above.' = = A mixing rod and a plurality of crushing balls 3 are set inside the ball mill. The wood is put into the upper part to cause friction and crushing. It takes + from the valve through the outlet 7 and runs. After the treatment is finished, it is taken out from the take-out 7 to the outside. It is a so-called intermittent structure. The oxidized 1 skin is easy to cause explosion, and it is a cheap steel ball. It is a ball, which avoids the use of the dry ball mill with the above structure in the processing steps, and the π into the wood powder in the ball mill / intermediate technology. The friction crushing treatment, county ... The crushed and crushed ball is crushed and broken, wood ... 4 The wood powder is broken, and the angled part of the wood powder material is removed, then: granular, whisker Etc., or make it deformed, more overall: ^, the shape of the fibrous hairy texture is slightly more round, etc. Second, it is closer to the granular shape, forming a solid, to increase the packing density, and to substantially repair the shape of the surface. L Another pile of dense wood powder material. When the above-mentioned frictional crushing treatment is performed on the above-mentioned wood powder material, 26 200524721 ίΪ :: produced between pieces or between each crushing ball and wood powder material ~~ The temperature is to remove the water of the wood powder material, and the friction breaking is continued to dry to less than 3% to 5% by weight of water. The temperature of the ball in the ball mill is 90 ~ 12. It can be dried and crushed to a water content of 2.0% by weight or less and a particle diameter of 16 / zm or less under a crushing condition of less than # at 8G ° in the sphere, to obtain a dry and fine wood as a powder. Powder material.
破碎球溫度為9〇〜12(Γ(：，所以接觸作為上述球的破碎 物件的木f粉末材料被加熱，料伴隨木質粉末材料的攪 拌’在與球分離的狀態下冷卻’重復進行上述加熱和冷卻 ，對破碎物件的木質粉末材料進行乾燥處理。 破碎物件的木質粉末材料在重復進行上述加熱和冷卻 的條件下進行破碎，同時在球之間急劇加熱的條件下，通 過球之間撞擊容易破碎，粉末内部水分的擴散也好。The temperature of the broken ball is 90 ~ 12 (Γ (:, so the wood powder material that is in contact with the broken object of the ball is heated, and the material is cooled with the stirring of the wood powder material, and the heating is repeated.) The wooden powder material of the crushed object is dried and cooled. The wooden powder material of the crushed object is crushed under repeated heating and cooling conditions, and at the same time under the condition of rapid heating between the balls, it is easy to impact between the balls. It is broken, and the diffusion of water inside the powder is also good.
為此對球磨機主體周圍的冷卻套管中一直供給冷卻水 ，使球磨機主體1内的溫度調整為小於等於8〇艺，優選小 灰等於70 C，更優選65°C左右。上述球磨機主體丨的内部 恤度通過相互調整伴隨球旋轉產生的摩擦熱的總熱量、木 質粉末材料的投入溫度和投入量、以及含水量、冷卻套管 的冷卻量等，使内部溫度調整為小於等於8(TC。 k過對木貝私末材料重復進行上述加熱和冷卻，原料 木材如的纖維受到膨脹和收縮作用，同時迅速乾燥，進一 步通過破碎球有效斷裂和破碎。 27 200524721 用木質粉末材料具有隨著此乾燥有縮小的傾 ，"樣的縮小傾向有助於在表面固定載體粒子，即有助 於咬入作用。 丁 即有助 構的制已知的密閉型幹式球磨機代替具有上述处 構的開放型幹式球磨機。 义… 在利用上述密閉形兹 擦破碎處理中，優選咬^磨‘ '心木f粉末材料的摩 Λ 璉疋球磨機内的氧濃度在15%以肉、 球磨機内溫度小於等於s 、 …… C。使用上述球磨機時，利用衆 閉用盖进閉球磨機内破碎室， ... 灸用十月性氣體例如氮氣取补 上述破碎室内的大氣，或連乳孔取代 下運作。 ，、k入虱軋，在惰性氣體氣氛 如上該，利用破碎用球之間的摩 處理主要作用盔麻4办丄 T丨尸⑺退仃破碎 .為摩^破碎’破壞木材組織並細化，整終外 “ r材心密 此分級裝置為利用直卜 把提供的高堆密戶木刀、、、風力式比重分級機， 度木貝粕末材料利用在因 旋轉器的旋轉而產生的離…“ U電機驅動的分級 下進行分級，而…排氣的吸引力的平衡 級操作中，也為了1條件的粗粉。在上述分 也為了避免在裝置内 爆炸危險性，向裝置一木貝叙末材料的 濃度在⑽以内，在Λ Λ ’在此裝置内保持氧 _ 在沒樣的惰性氣氛下運作。 這樣得到的高堆密度木 間的摩擦破碎作用進一…材科，利用破碎用球之 進订破碎處理，得到平均顆粒直徑比摩 28 200524721 粉切 粉體的高堆密度木質粉末材料=略小的作為被載 摩擦破碎前的原材料的木質粉末材：：：粉體的堆密度比 擦破碎處理前 、如末材科的堆密度更大；在摩 月J荷長纖維狀，具有有棱八 及纖維毛狀鬍#1邻八6/] + π σΡ刀、犬出部分以 分的木質粉末材料，在 /、有比較疏鬆部 平滑細密表面狀能μΓ 後成為比較園形而且 料。 作為被載粉體的高堆密度木質粉末材 1 、乍的各實施例和對比例進行說明。 只ώ列1 -1 (被載粉體的性質和狀態） 由師4侍到的主要平均顆粒直徑的 粒420 # m ~篩下 又刀佈為師上顆 粒組成的雲杉：::Λ:下稱[粒度分佈⑴的顆 會社精進企業料，利用葉輪礙磨機（株式 擊葉片和襯裏之：;Γ广250 )，把破碎旋轉器的衝 、摩擦破碎等作；為3mm’通過衝擊、剪切 徑的粒度分佈:= ，得到主要由平均顆粒直 布為32〜128/zm (以下稱[粒度分 組成的木質粉末材料。 ])的顆粒 、f ;彳f j的木質粉末材料利用風力式比 龐特科⑷製造的PS分級機）進行分級，置（ 顆粒直徑的粒度分布為u]心（以下稱[粒w要由平= 的顆粒組成的木質粉末材料，然後進一步對已度二布3]) 粉末材料利用鉍—+ * 対已分級的木質 式球磨機（三井三池化工機株式會社製造 29 200524721 的研磨j A-2GG) ’摩擦破碎兩個小時，破壞木材組織並 匕仔到〜加i隹密度的主I由平均顆粒直徑的粒度分布 :2.0〜16.〇"(以了 [粒度分布4])的顆粒組成的高堆 被度木質粉末材料’其中上述幹式球磨機具有5 4升容量 的擾拌桿，上錢拌桿巾裝填有直徑3μ的氧化錯類 製破碎用球2. 4升。 /粒度分佈4]的高堆密度木質粉末材料，其平均顆粒 直徑相當接近於[粒度分佈3]的被載粉體，其顆粒直徑略 縮小而且堆密度增加。 其中粒度分佈情況如下：木質粉末材料或利用球磨機 摩擦破碎處理得到的作為被載粉體的高堆密度木質粉末材 料（[粒度分佈2〜7])的顆粒直徑是指，例如把這些分別 在規定溶液中懸浮分散狀態下，分別沿著透明的通路流過 ，同時用在上述鐳射照射透過此通路，測定其流過方向的 長度，把得到的數值換算成直徑的顆粒直徑。另外原料木 材[粒度分冑丨]的顆粒直徑是表示’把木材原料利用試驗 用振動篩選機篩選5分鐘時，通過大網目的篩子而且留在 J、’’罔目的篩子上的木材原料用此篩子的網目直徑。 ‘‘平均顆粒直徑”是指上述被載粉體和高堆密度木質 粉末材料中累積重量百分比分佈 50重量％ (一半重量）' 顆粒的直徑。 也就是[粒度分佈3]中所示的被載粉體的鬆軟堆密度 為〇.126g/cc，且堅實堆密度為〇.286g/cc :而[粒度分佈 4]中所示的高堆密度木質粉末材料的鬆軟堆密度為 200524721 0· 186g/cc，堅實堆密声 > ,a 又馬0.463g/cc，通過摩擦破碎處理 ，咼堆岔度木質粉末鉍4 不材枓的堆密度明顯提高。 其中所說的鬆教t ώ β 隹抢度疋指在lOOcc容器中把上述被 載如體或咼堆密度木皙 貝叔末材料一邊利用24目的篩子篩選 ，一邊篩到容器中堆藉诒 積後到平，把上述容器内的被載粉體 或回堆禮、度木質粉末材 何討的總重®用1 00除的數值。另外 ，上述堅實堆密度是指在 r振動（fe敲）的lOOcc容琴 中把上述被載粉體或高所 ° 的筛子篩選，一邊r—。 末材料一邊利用24目 币1谷益中，受到振動的容器内的被载 粉體或南堆密唐太暂 木貝叔末材料結束體積變化後刮平，把上 述容器内的被載粉體或高堆 用_除的數值。"度的木質粉末材料的總重量 =外’[粒度分佈3]所示的摩擦破碎前的木質粉末材 :有直徑的顆粒比短顆粒直徑的顆粒明顯，具有报 二 #分、突出部分以及纖維毛狀鬍鬚部分。[粒度 :二所不的高堆密度木質粉末材料，整體上接近顆粒 :有園形’表面比較平滑而且細密。這些結果 顯u鏡照片的觀察確認。 這樣得到的高堆密度木質粉末材料幾乎不會產生相互 凝聚’而且在溶液等中的分散性良好，、商八…丨生相互 粉體。 R好，適合於顏料等被載 實施例1 -2 (被載粉體的性質和形狀） 與上述例相同，由上述[粒度分 又刀佈1 ]組成的雲杉鋸屑 作為原料木材，利用實施例丨—丨中 r所用的葉輪銑刀，把高 31 200524721 速旋轉的破碎旋轉器的衝整 為3_，進行破碎處理，得到、間排屑距離設定 之後’對上述已破碎的木質粉末二木質粉末材料 擦破碎兩個小時，得到ώ 用上述球磨機，摩 ⑴2” (本說明;; 堆密度的木質粉末材料，同時利用^的顆粒組成的高 置進行分級’得到由主要平均顆粒直風：式比重分級裝 2 ·。〜1 6…本說明書中稱[粒度分广的:度分佈為 堆密度的木質粉末材料。 纟顆粒組成的高 另外，這樣得到的高堆密度 處理之前木質粉末材料具有的有棱末除去在 纖維毛狀鬍鬚部分，整體上 ” Χ出部分以及 密。這此姓果可、gf ^園形，表面比較平滑且細 二、、，。果了通過顯微鏡照片的觀察確認。 而且，這些高堆密度的木質粉 的顆粒直徑，同時流動性和分散性":：較窄範圍 等被載粉體。 刀政性良好，且適合用作顏料For this reason, cooling water is always supplied to the cooling jacket around the main body of the ball mill, so that the temperature in the main body of the ball mill 1 is adjusted to 80 ° C or less, preferably 70 ° C, and more preferably about 65 ° C. The internal shirt of the main body of the ball mill described above adjusts the internal temperature to less than the total amount of frictional heat generated by the ball rotation, the input temperature and input amount of the wood powder material, the water content, and the cooling amount of the cooling jacket. It is equal to 8 (TC. K) By repeating the above heating and cooling of the wooden shell material, the fibers of the raw wood such as the fiber are subject to expansion and contraction, and at the same time are dried quickly, and further effectively broken and broken by the crushing ball. 27 200524721 Use wood powder material It has a tendency to shrink as it dries, and the "like" shrinking tendency helps to fix the carrier particles on the surface, that is, it helps to bite into the body. It is known that the closed-type dry-type ball mill which is known to be used instead of the The open dry ball mill of the above structure. Meaning ... In the above-mentioned closed-type rubbing and crushing treatment, it is preferable to bite and grind the 'heartwood f powder material' in the mill 琏 疋 琏 疋 ball mill with an oxygen concentration of 15% in meat, The temperature inside the ball mill is less than or equal to s, ...... C. When using the above ball mill, use the closed lid to enter the crushing chamber inside the ball mill, ... A gas such as nitrogen is used to supplement the atmosphere in the above crushing chamber, or it can be replaced by lactation holes. In the inert gas atmosphere, as above, the friction treatment between the crushing balls is mainly used to protect the helmet. T 丨 The corpse is regressed and broken. To break the wood structure and refine it, it is necessary to classify the high-density household wood knives, wind power, and other wind-powered specific gravity units that are provided by straight materials. Machine, degree of crustacean powder material is classified under the classification of "U motor-driven classification" generated by the rotation of the spinner, and ... In order to avoid the risk of explosion in the device, the concentration of the material in the device is not more than ⑽, and the oxygen is kept in the device in Λ Λ ', which operates under a kind of inert atmosphere. The high-density friction crushing between woods is further advanced into the wood science department. The crushing ball is used to customize the crushing process to obtain a high-density wood powder material with an average particle diameter of more than 28 200524721 powder-cut powder. The wood powder material that is the raw material before being subjected to friction crushing ::: The bulk density of the powder is larger than that of the crushed material before the crushing treatment, such as the endaceous material family; Fibrous hairy hu # 16 八 6 /] + π σ P knife, wooden powder material divided into dog parts, has a smooth and fine surface energy μΓ in relatively loose parts, and becomes a more round shape and material. Powder high-density wood powder material 1, each example and comparative examples will be described. Only 1 -1 (the nature and state of the powder), the main average particle diameter served by the teacher 4 420 # m ~ The spruce under the sieve and the knife cloth is composed of the particles on the upper part of the division :: Λ: hereinafter referred to as [the particle size distribution of the company will refine the company's materials, using the impeller to obstruct the mill (the blade and lining of the plant: Γ) Guang 250), the punching and friction crushing of the crushing rotator are used as 3mm 'particle size distribution through impact and shear diameter: =, and the average particle size is directly distributed to 32 ~ 128 / zm (hereinafter referred to as [particle size fraction Composition of wood powder material. ]) Particles, f; 彳 fj wood powder materials are classified using a wind-powered PS grader manufactured by Pontech, and set (the particle size and particle size distribution is u). = Particle consisting of wood powder material, and then further to the second degree cloth 3]) powder material using bismuth-+ * 分级 graded wooden ball mill (Mitsui Miike Chemical Machinery Co., Ltd. 29 200524721 grinding j A-2GG) 'Friction breaks for two hours, destroys the wood tissue and daggers to ~ plus the main density of I 隹 is composed of the particle size distribution of the average particle diameter: 2.0 ~ 16.〇 " (with [particle size distribution 4]) particles High-heavy-duty wood powder material 'wherein the above-mentioned dry ball mill has a scramble bar with a capacity of 54 liters, and the bar towel bar is filled with a crushing ball made of oxidized aluminum with a diameter of 3 μ, 2.4 liters. / Particle size distribution 4] The high-density wood powder material has an average particle diameter that is quite close to that of the supported powder of [particle size distribution 3], and its particle diameter is slightly reduced and the bulk density is increased. The particle size distribution is as follows: wood powder material or friction crushing using a ball mill The particle diameter of the high bulk density wood powder material ([granularity distribution 2 ~ 7]) obtained as a supported powder means that, for example, these particles are respectively suspended and dispersed in a predetermined solution and flow along a transparent path. At the same time, the above laser irradiation is used to pass through this path, and the length in the direction of flow is measured, and the obtained value is converted into the diameter of the particle diameter. In addition, the particle diameter of the raw material wood [grain size]] is used to indicate the use of wood raw materials When the screen was screened by a vibrating screen for 5 minutes in the test, the wood material passing through the large-mesh sieve and remaining on the J and sieve sieve was used as the mesh diameter of the sieve. "Average particle diameter" refers to the above-mentioned powder and Cumulative weight percentage distribution of 50% by weight (half weight) 'diameter of particles in high bulk density wood powder materials. That is, the bulk density of the supported powder shown in [particle size distribution 3] is 0.126g / cc, and The solid bulk density is 0.286 g / cc: and the bulk density of the high bulk density wood powder material shown in [Particle Size Distribution 4] is 200524721 0. 186 g / cc. The solid bulk density is> Horse 0.463g / cc, through rubbing and crushing, the bulk density of the wood powder bismuth 4 was significantly increased. The so-called Songjiao t β β 隹 疋 refers to the above-mentioned load in a 100cc container For example, the bulk or uncle Muxue powder materials are screened with a 24 mesh sieve, and then sifted into a container to be piled up and flattened. What is the total weight ® divided by 100. In addition, the above solid bulk density refers to the above-mentioned powder-loaded or high-degree sieve screened in a 100 cc container with r vibration (fe knock). . The final material uses 24 mesh coins and 1 Tanaka. The powder contained in the container subjected to vibration or the unrefined material of Nan Tai Mi Tang Taiqian Mubei is scraped flat after the volume change, and the powder contained in the container or high Heap divided by _. " Total weight of wood powder material = outside '[granularity distribution 3] wood powder material before friction crushing: particles with a diameter are more obvious than particles with short particle diameter, with two # points, protruding parts and Fibrous hairy beard parts. [Granularity: Erbuy's high bulk density wood powder material, which is close to granules as a whole: it has a circular shape 'and its surface is smooth and fine. These results were confirmed by observation of microscopic photographs. The thus obtained high bulk density wood powder material hardly causes mutual coacervation ', and has good dispersibility in a solution or the like. R is good, suitable for pigments and other carried examples 1-2 (property and shape of the supported powder) The same as the above example, the spruce sawdust composed of the above [grain size and knife cloth 1] is used as the raw material wood. Example 丨 — The impeller milling cutter used in r, the punching of the crushing rotator with a high speed of 31 200524721 is set to 3_, and the crushing process is performed to obtain the setting of the chip discharge distance. The powder material was rubbed and shredded for two hours to obtain the free use of the above-mentioned ball mill, Capricorn 2 "(this description ;; bulk density of the wood powder material, while using the high position of ^ particles composed of classification) to get direct wind from the main average particles: Specific Gravity Packing 2 .... ~ 1 6 ... In this specification, [wide particle size: wood powder material with a density distribution of bulk density. 纟 particle composition is high In addition, the thus obtained high bulk density wood powder material has The edges are removed in the fibrous hairy beard part, and the overall "X out" part is dense. This family name is fruit, gf ^ garden-shaped, the surface is relatively smooth and thin, and the fruit has passed through the microscope Observation of mirror photos confirmed that the particle diameter, fluidity and dispersibility of these high bulk densities of wood powder " :: a narrow range, etc., are contained in the powder. The knife is good and suitable for use as a pigment
對比例1 ~ J ，摩度:則組成的雲杉鑛屑利用上述球磨機 的同加上破碎用球之間的摩擦作用，摩擦 守進仃磨碎，也就是利用摩擦進行破碎。 I發現這樣得到的木質粉末材料中混合有極 貝粉末材料部分和長纖維狀部/ 近原來形狀的顆粒直徑殘留下來，不一重量%接 也钛S+疋此變成顆粒狀。 疋】用葉輪碾磨機事先把雲杉鋸屑進行破碎，形成木 32 200524721 :二末=，與利用摩擦手段增加堆密度的各實施例相 直接摩擦破料料破碎效果極差，也就 破碎，也殘留下大量的長纖維狀部分，而且另__方面 產生極細粉末狀的過分破碎的木質粉末材料。 複合木質粉末例〗中載體粒子的固定 :面、詳：說明複合木質粉末们的製造方法，上述複 °貝％末疋在上述高堆密度的木質粉末材料的表面，把 質粉末材料顆粒直徑更小且硬度更大㈣ 固定得到的。 料，^展’作為上述被载粉體的高堆密度的木質粉末材 y、各自的顆粒直徑盡可能在微細顆粒直徑範圍内。 混合物件物為塗層用塗料時被載粉體的主要部分優 &具有2〜12#m顆粒直徑範圍的粒度分佈。 μ /果犯β物件物為樹脂塗敷液或塑膠薄片、塑膠薄膜 寺成形樹脂材料的情況 、 兄下，被載粕體的顆粒直徑優選小於 :於犯“ ’更優選小於等於_。此外有效的粒度分佈 不例為顆粒直徑小於等於12"的占總量的75重量％ 以上，優選占80重量％以上。 果此σ物件物為通過喷射成形或擠壓成形得到塑膠 取品的愔汉j ^ 少 ’各南堆密度木質粉末材料顆粒直徑優選在 t) U〜9 0 // m的顆粒宙贫 位置仏乾圍内，更優選小於等於2〇 # m。 门 ’ °果混合物件物為通過壓光輥等成形手段混合 得到的塑膠薄片等製品的情況下，所用高堆密度木質 ；：材料顆粒直徑比混合在其他塑膠製品的成形樹脂材料 33 200524721 中的顆粒直徑更大。 其中載體粒子主要以咬入狀態結合 二以：咬入狀態結合時’多個載體粒子相互凝聚，互相 二並=行摩擦破碎處理時伴隨發熱。所 入狀態結合在上述表面-起，同時用上述表面包住 二：：::：，或以咬入狀態結合的載體粒子之間，或以咬 =一5的㈣粒子和以包住狀態結合的載體粒子之間 /二：：狀悲結合等。這些處理操作結束後進行冷卻 二叮心分產生收縮、與縮小作用結合在-起非常有效 =地固定也就是說不需要化學反應或枯接等可進行固 ㈣體上的载體粒子的固定是通過同時把被裁粉 體和載體粒子供給幹式球磨機來實現。另外也可以在、 質粉末材料表面事先附著載體粒子，通過這二 =:可以得到把載體粒子附著在表面的高堆密度木： 而且在上述局堆密度木質粉末材料上施加擠麼 力:=給幹式球磨機等，可以把表面的載體… 入狀恶、、ό 5在局堆密度木質粉末材料上。 2述被載粉體上和（或）高堆密度木質粉末材料的 :木〜Γ體粒子的固定’是也可以通過覆蓋上述高堆密 度木貝粕末材料的整個或部分表面一、 體粒子相互重i，屏狀t蓋 17以通過裁 表面來實現。曰狀復盡上“堆密度木質粉末材料的 複合木質粉末例2中載體粒子的固定 34 200524721 下面詳細說明在上述複合木質粉末 固定在被载粉體或高堆密度木質 ”巴載體粒子 在度木“末材科的情況。 ;L複&木質粉末例2中，裁體弟 堆密度木質粉末材料上的固 破載粉體或高 例1的古i金—*丄 亏到上述複合木質粉 的巧堆雄、度木質粉末材料的同 貝十刀末 置、高堆密度木皙扒古A 見口疋。所用的裝 方… 料的成形方法、載體粒子的固- 方法寻與上述複合木質粉末例"目同。 子的固疋 上述複合木質粉末例2是同時進行如 Γ箄弟_ ’把通過碾磨機把木材原料、木屬的破：：付到· 進行粗破碎，的破碎機例如葉_機:物皮：， 破碎手段的Γ材料和裁體粒子通過作為摩擦 度的處理.第式球磨機等’增加木質粉末材料的堆密 J处理，弟二，把載體粒子固 ^ 堆密度的高堆密度木質粉末材料表面的二載粉體或增加 面或體粒子在固定以至暫時固定於被載粉體的表 木質粉末：::堆密度的木質粉末材料表面的狀態下，增加 貝权末材料的堆密度的同時，处 度的高堆密度木質粉末材料的二的：…在增加堆密 木質粉末鉍社+ 表面的情況下，伴隨對上述 丫刀禾材枓貫施的摩擦破碎 擦破碎處理的㈣力@定在已充八^體粒子通過上述摩 粉體的高滩六虚 充刀祜大堆密度的作為被載 。隹在、度木質粉末材料上。 無論如何載體粒子固定在 _ 粉末材料的主 θ σ隹岔度的咼堆密度木質 的表面，形成複合木質粉末例2。 上述複合木質粉末例2中載體粒子的固定與上述複合 35 200524721 木質粉末例1令載體粒子的固定相 粒子以咬入狀態結合在高堆密度木質粉末把載體 載體粒子用上述表面包住狀態下結合：=的表：、把 :載體：子和以包住狀態結合的载體粒子利用相互插入狀 悲結合#主要方法實現。 於上述複合木質粉末例2的上述固定處理，在有必 =付到整齊的、作為最終處理品的上述複合木質粉末例2 ◊顆粒直控時，把被載粉體進一步分級，得到規定範圍的 所需顆粒直徑，並且把上述被載粉體與多個載體粒子一起 提供給處理裝置。扣^+ — 载體粒子固疋在上述被载粉體或高堆 質粉末材料的表面時，也可採用覆蓋上述被载粉體 或向堆密度木質粉末材料的整體或一部分表面的方法。此 外也可以通過把載體粒子相互重疊層狀覆蓋在上述被載粉 體或高堆密度纟質粉末材料的纟面來@冑。 載體粒子 下面β羊細说明把載體粒子固定在高堆密度木質粉末材 料表面的情況。 此載體粒子可採用各種顏料、各種無機材料、各種金 屬材料、各種塑膠材料、各種導電材料等中的任何一種。 也就疋況此載體粒子只要具有可咬入作為上述被載粉體的 阿堆么度木質粉末材料表面的硬度和大小，就可以使用。 上述載體粒子可以根據複合木質粉末的用途，分別使 用具有與其用途相應性質的物質。一般來言兒，把複合木質 ‘末與塑膠製品的成形樹脂材料、塗料等混合使用時，希 36 200524721 f上述複合木質粉末的载體粒子化學和熱穩定，而且 犄不會引起其特性的損、 產生不良㈣。、&對形成的塑膠製品以及塗層 載體粒子（無機材料） -在：ΠΓ兒明把無機材料的顆粒狀物作為載體粒子固 疋在作為被载粉體的高堆密度木f粉末材料的情況。 載體=具有比被载體和/或高堆密度木f粉末材料或 :粕體更冋的硬度，而且顆粒直徑比上述高堆密質 粉末材料或被載粉體的顆粒直徑小。這些條件Μ用的。 你由其中用於上述载體粒子的無機材料，在考慮混合物件 物中使用條件等的基礎上，從各種無機材料中選擇使用。 以上述奴酸爹弓的粉太望炎曲Λ丨_ 末4為典型示例的無機材料作為載 體粒子，具有上述載體粒子的高堆密度木諸末材2 時作為被載粉體）的顆粒直徑優選在規定顆粒直徑範圍， 上述規定顆粒直徑範圍適用于複合木質粉末的用途，例如 «薄片、塑膠板、各種擠壓成形品、噴射成形品等的用 返’以及例如塗敷、啥士、/ _ _ 噴射成形、擠壓成形、滾壓成形等使 用方法。 例如，混合物件物為塑膠薄膜、塑膠薄片f情況下， 顆粒直徑大小與被載粉體、複合木質粉末例2中的木質粉 末材料或被載私體、上述混合物件物為樹脂塗敷液等的情 况相同’優選小於等於32㈣，更優選小於等於20 # m，而 有放粒度刀佈的另一例為顆粒直徑小於等於上2 #爪的占 總量的75重量％以上，優選占8〇重量％以上。 37 200524721 混合物件物為通過喷射成形或擠壓成形得到的塑膠製 品的情況下，高堆密度木質粉末材料、複合木質粉末例2 中的木質粉末材料或被載粉體與複合木質粉末例1相同， 優選顆粒直徑在50〜9〇 Am範圍，更優選小於等於2〇#瓜。 混合物件物為通過壓光輥等成形手段混合成形得到的 塑膠薄片等製品的情況下，也可以使用更大的顆粒直徑。 作為載體粒子的碳酸鈣粉等無機材料粒子負載在上述 尚堆抢度木質粉末材料和被載粉體的表面的方法，與得到 上述複合木質粉末例i和複合木質粉末例2的情況完全相 同，優選把上述無機材料粒子以咬入結合方式固定在被载 粉體的高堆密度木質粉末材料表面，儘量覆蓋其表面。 一這樣得到的複合木質粉末使塑膠板等具有良好的尺寸 t疋I1生而且伴蚊溫度變化的膨脹和收縮明顯變小。 下面詳細說明各實施例的處理操作，通過上述處理 作=作為多個載體粒子的碳酸每粉末固定在上述高堆 度木^粉末材料和被載粉體表面’得到複合木質粉末。 實施例2-1 (載體粒子：碳酸鈣） 2述示例相同，由上述[粒度分佈】]的粒度分佈構 為木材原料，利用葉輪礙磨機（株式會社 衝擊苹片:25°) ’把高速旋轉的破碎旋轉器的 j葉片和襯裏之間排屬距離設定為3咖，通過 切摩擦破碎等作用進行破碎處理，得到上述[粒度剪 的被載粉體。 布2] 對這樣得到的被載粉體，進行分級，得到上述[粒度分 38 200524721 佈3]的粒度分佈的被載粉體後，進一步對上述已分級的被 載粉體，利用上述幹式球磨機，摩擦破碎兩個小時，得到 增加堆密度的上述[粒度分佈4]的粒度分佈的高堆密度木 賀粉末材料。 在這樣得到的1.5kg的高堆密度木質粉末材料中，添 加並塗滿1.5kg的碳酸鈣粉末後，把塗滿上述碳酸鈣粉末 的高堆密度木質粉末材料，同樣利用上述幹式球磨機混合 ’把所需碳酸#5粉末固定在表Φ，得到複合木質粉末。 這樣得到的複合木質粉末作為填充材料使用，得到氣 化乙烯樹脂薄片。上述氣化乙烯樹脂薄片中均勻含有上述 複口木質粉末，所以上述薄片表面沒有發粘感覺，伴隨溫 度變化的膨脹和收縮明顯變小。 實施例2-2 (載體粒子：碳酸鈣） 把鋸屑利用葉輪碾磨機（株式會社精進企業製造的 250 )，得到主要平均顆粒直徑的粒度分佈為 32.〇〜128#m範圍（本說明書中稱[粒度分佈7])的木 粉末材料。 、 把作為載體粒子的0.7kg碳酸鈣粉末塗滿在準備好的 1kg上述木質粉末材料上面後’利用上述幹式球磨機，對 已塗滿上述碳酸㈣末的纟質粉末㈣實施兩小時的摩揍 破碎處理。 丁 通過上述球磨機的摩擦破碎處理，在整修木質粉末材 广表面元狀的同4 ’使碳酸弼粉末以咬入狀態負載在上述 已整修表面形狀的高堆密度木質粉末材料1〇4的表面，由 39 200524721 此付到後合木質粉末。然後把其中得到的複合木質粉末作 為填充材料’用擠壓成形的方法得到氣化乙烯樹脂棒材。 在這樣得到的棒材中均勻含有上述複合木質粉末，所 以棒材表面沒有發㈣I，伴隨溫度變化的膨脹和收縮明 載體粒子（顏料） 下面說明作為上述載體粒 顏料粒子固定在高堆密度木質 質粉末。 子的顏料粒子、以及把上述 粉末材料表面得到的複合木 其中作為上述載體粒子的顏料粒子，除了有 在混t物件物中的使用條件，特別是耐熱性等之外，可使 用然機顏料或有機顏料等所有顏料。 粉末2 = t上述載體粒子的顏料粒子的高堆密度木質 '''知蚪為被載粉體）希望顆粒直徑盡可能在微_ 的顆粒直徑範圍。 现了此在极細 也y尤疋合物件物為塗声用冷姐η主 太材料…人 勹土層用塗枓時，尚堆密度木質粉 末材枓、锼合木質粉末例2 私 的主要部八 Τ的木貝私末材料或被載粉體 F刀"ί炎選顆粒直經為？〜1 9 ^ 巧入 ”、、2 U m乾圍内的粒度分佈。 此a物件物是塗料或 ΛΑ ^ ^ ^ 哥联塑膠溥片等塑膠材料 的^況下，馬堆密度木質粉末 的木質粉末材料或被載 複：木貝粉末例" ，更優選小於等於2。拉直徑優選小於等於心m 於專於20而且顆 的材料優選占總量的75重量%以上。…於12“ 混合物件物是塑膠 成形口口或擠壓成形品的情況 200524721 下’作為被載粉體的各高堆密 粉末例2中的作為原料材料的;末材料、複合木質 粒直徑範圍，與複合木質粉末例或被載粉體顆 50-90// m , ® ^ 1相同，優選顆粒直徑 5〇 9〇“更優選小於等於20“。 混合物件物是通過壓弁 塑膠薄片等製品的情況下二：合成形得到的 粉末材料。 T 乂使用顆粒直徑更大的木質 把作為載體粒子的顏料粒子 子負载在上述高堆密度木質 和末材枓和被載粉體的表 〜^ π ^的方去，與上述實施例的情況 元王相同，優選把上述顏料粒 于父入結合方式固定在作 為被載粕體的高堆密度木質耠古 不貝私末材料表面，覆蓋其表面。 作為載體粒子的顏料粒子，★ + Α丄 于根據者色目的的濃淡程度 ，適當設定混合量，所以备# 、 負載有上述顏料粒子的複合木質 粉末呈現與混合顏料粒子色調幾乎相同的色調並且具有良 好的流動性。 把負載有這樣得到的顏料粒子的複合木質粉末混合並 分散在塑膠成形材料時的噴射成形和擠壓成形中，這些成 形壓力都較低’且在成形品中均勻分散顏料，沒有產生顏 色不均。 下面詳細說明實施例的各處理操作，上述實施例用於 把作為各載體粒子的顏料粒子固定在上述高堆密度木質粉 末材料以及被載粉體的表面，得到複合木質粉末。 實施例3-1 (載體粒子：氧化鈦） 與上述示例相同，由上述[粒度分佈丨]的粒度分佈構 41 200524721 j的雲杉鑛屬作為木材原料’利用葉輪 精進企業製造的1MP-250 ) ’把高速旋轉的切 擊葉片和襯裏之間排心㈣定為3m， 轉= :碎等作用進行破碎處理，得到上述[粒度分佈：：: 佈的被載粉體。 」才、度刀 對這樣得到的各被載㈣進行分級， 佈3]粒度分佈的被載粉體後，再對上述已分級的::度： 利用上述幹式球磨機進行摩擦破碎兩個小時 ；； [粒度分佈4]粒度分佈的高堆密度木質粉末材 準備這樣得到的高堆密度木質粉末材料ikg，在此t ;質粉末材料上添加並塗滿〇 7kg的作為裁體顏： j子的氧化鈦後，同樣制上述球磨機，把氧化欽固定在 _度木質粉末材料的表面，得到複合木質粉末。 實施例3-2 (載體粒子··氧化鈦） 準備利用葉輪碌磨機（株式會社精進企業製造的iMp— 250 )破碎鑛肩得到的上述[粒度分佈7]粒度分佈的木質粉 末材料1.5kg，和作為載體粒子的氧化鈦粉末i 5kg，在上 述木質粉末材料塗滿氧化欽粉末後，利用上述幹式球磨機 ’對已塗滿上述氧化鈦粉末的木質粉末材料進行兩個小時 的摩擦破碎處理。 伴隨上述球磨機的摩擦破碎處理，除去上述木質粉末 材料的有棱角部分、突出部分、以及纖維毛狀鬚鬚部分， 同時得到整體上接近於顆粒狀的作為被載粉體的高堆密度 42 200524721 木質粉末材料。 把這樣得到的複合木質扒 ^ ^ ^ 、杨末作為顏料製作塑膠板時， 可侍到沒有顏色不均的白色 ^ ^ ^ 上述板觸感良好，沒有發 感見，而且隨温度變化的膨脹和收縮明顯變小。 其中把作為載體粒子 ^^ Lv ^ )顏枓粒子以咬入狀態固定在作 為被載粉體的高堆密度木皙 ^麼換+ ^ 木貝如末材料和被載粉體的表面， 在摩擦破碎處理時，苴畤χ处〜/ ,.e 5| . ^ 狀怎受到更加強大的機械衝擊 仔到更好的效果。例如，盥 等 ，、上述各貫施例不同，利用上 下方向具有攪拌葉片的球磨 . v ^ 機把上述被載粉體和高堆密 度木貝籾末材料以及作為載 而且落下衝擊條件下咬入的顏料粒子在摩擦破碎 合木質粉末。 、、” ’可得到色澤更加鮮餘的複 載體粒子（導電性粉末） 堆密戶太^把作為上述载體粒子的導電性粉末固定在高 X g粉末材料表面的複合木質粉末。 A、、曰2作為上述載體粒子的導電性粉末，除了有必要考 任意導電性的粉i例如耐熱性等之外，可使用具有 金屬述ς導電性粉末’包括例如Ag，CU，Ni等導電性 π類墓：、n〇2’ Zn〇等導電性金屬氧化物的粉末、以及 -類導電性粉末等，可以從中選擇一種或—種以上使用。 述古2為各载體粒子的導電性粉末以咬入狀態結合在上 被度木質粉末材料和被載粉體的表面的複合木質粉 ，可作為塗料中的導電性填充材料例如電磁波遮罩材料 43 200524721 電波吸收材料、以及防靜電材料笔， $ 1混合分傲女& 樹脂塗料等地塗敷液中使用。 、負載有作為各載體粒子的導電性粉末的高堆密度木所 粉末材料以及被載粉體的顆粒直徑 貝 粒直徑範圍。 “盡可此在微細顆 :如’高堆密度木質粉末材料、複合木質粉末 的二貝粉末材料或被載粉體的主要部分優選顆粒直_ ㈣範圍的粒度分佈。另外，如上該，上述優選：戶 分佈的另一例為，古土仓金痒士 、’度 力例為，冋堆被度木質粉末材料、複合 例2中的被載粉體優選顆粒直徑小 、，7i 小於等於2〇㈣，顆粒直徑小於等更優選 蛐量的％舌曰。 寻於12β«η的粒度分佈占 、.心里〇 75重置％以上，優選占8〇重量％以上。 木質TIL載體粒子的導電性粉末負載在上述高堆密度的 相同：=和被載粉體的表面的方法，與上述各實施例 冰恭巴上述導電性粉末以咬入結合方式固定在作為 高堆密度的木質粉末材料的表面，覆蓋其表面 把作為裁體粒子的導 木質粉末材料時士 Γ 負載在上述高堆密度的 — 如果疋能滿足所需各種導電率的導電性 末相互且1又來5兒，上述負載量可增加至已負載的導電性粉 互/、有電連接關係且滿足上述導電率。 作為H具體說明實施例及其對比例，上述實施例包括把 h的導電性粉末固定在上述高堆密度木質粉末 44 200524721 材料和被載粉體的表面 得到複合木質粉末 的各處理操作 實施例4-1 (載體粒子：導電性粉末） 由上述[粒度分佈u粒度分佈構成的雲㈣屑作 才原料’利用葉輪礙磨機（株式會社精進企業製造的邮 250)，把高速旋轉的破碎旋轉器衝擊葉片和襯裏 距離設定冑3丽’通過衝擊、剪切摩擦破碎等仙二 碎處理，得到上述[粒度分佈2]的木f粉末材料。仃石 對這樣得㈣被載粉體進行分級，得到上述[粒度 末佈的被載粉體後，進-步對上述已分級的木質粉 末材料，同樣制上述幹式球磨機摩擦破碎兩個小時 :増加堆密度的上述[粒度分佈4]粒度分佈的高堆密度： 貝粉末材料。 而且，在這樣得到的高堆密度木質粉末材料中，添加 ，塗滿在數量上能夠完全覆蓋其表面的作為載體導電性粉 的奴粉末，在本實施例中，相對1〇〇份重量的高堆密度 木質粉末材料需要添加並塗滿5〇份重量的碳粉末同樣： =述幹式球磨機，把碳粉末固定在表面，得到複合木質 旦然後把二甲醢胺和甲基乙基酮以1: i比例配成6〇份 重里的溶劑，在溶劑中加入2〇份重量的尿烷樹脂，準備塗 敷液’同時把上述塗敷液的尿院樹脂固體部分和把上述碳 粉末負載在表面的複合木質粉末，以i : i的重量比例混合 後利用球磨機混合10分鐘左右，得到導電性塗料。 45 200524721 利用沒樣得到的上述導電性 的塗層’測定其表面的電阻值 21…右 107~1Χ1〇8Ω , ^ /、測疋數值顯示為lx 可確涊具有良好的導電性。 另外’把上述塗敷液的尿 粉末負载在表面m 科月曰固體部分和把上述石戾 戰在表面的複合木質粉 後，混合10八户+ 士 ^ 1 . 2的重篁比例混合 刀1里左右，得到導電性塗料。 利用這樣得到的上述導電 的塗層m 科做成膜厚2一左右 性冷料㈣ 電阻值，可確認比利用上一個導電 性塗：做成的塗層具有更好的導電性。 等電 實施例4-2 (載體粒子··碳粉末） 用與上述實施例4 一 j j .,ίφ. ^ ν 相冋方法破碎木材原料，得到上 到上心：2]粒度分佈的木質粉末材料後進行分級，得 質^^=分佈3]的粒度分佈。準備叫這樣得到的木 料二Μ ㈤作為載體粒子的碳粉末，在木質粉末材 料上塗滿把上诚声伞、士 Η ，，上述幹式球磨機，對已塗滿 上述奴粉末的木質粉東叔料 得到木質粉末材料。進仃兩小時的摩擦破碎處理， 堆^樣仔到的複合木質粉末，其表面得到整修，增加了 X，而且碳粉末以咬入狀態固定在其表面。 =這樣得到的複合木質粉末作為填充材料使用的塗 料做成塗層，測定上述塗声 例W相近的導電性值’確認了具有與實施 對比例4-1 相對100份重量的30%濃度的尿院樹脂溶液，添加30 46 200524721 份重量的碳粉末後，利用球磨機混合丨〇分鐘左右，得到導 電性塗料。 然後利用這樣得到的導電性塗料做成膜厚21 “ m左右 的塗層’心其表面的電阻值’此時任何塗層表面的測定 數值都是1Χ1〇9Ω，且塗層内產生碳凝聚。 為了使形成上述塗層時表面電阻值達到lxl〇SQ以下 ’繼續混合這些尿烧樹脂溶液和碳粉末，同時測定各設定 此合％間塗層表面電阻值，其結果是利用球磨機連續混合 ㈣個小時後’做成的塗層表面電阻值開始變為ΐχΐ〇8 I示了上述例子以外的載體粒子 在上述實施例中，可看中 J有出無機:材料、顏料、導電材料 、孟屬材料等適合用作載體 材料、… 乍戰體粒子固定在高堆密度木質粉末 材枓、被載粉體。 從上述實施利的說明十可以看屮, 還包括由無機材料、 ’ μ明的載體粒子 料構成的粒子。 i屬材枓以外的材 也就是如果上述葡辦 木質粉末材料和被載”的顆增加堆密度的高堆密度 粒子的話，例如各種塑膠製品的粒；J …的 ’可作為載體粒子固定在上：❹上述實施例相同 合木質粉末粒2中的^ 袷度木質粉末材料或複 任何一個上。 篮和问堆密度木質粉末材料的 此外在得到的複合木質 、 上可賦予複合的功能，例 47 200524721 :同,½賦予導電性和著色性。這種情況下通過把顏料 “才枓固定在一個高堆密度木質粉末材料表面，可同時 複合木質粉末賦予導電功能和著色功能。 了门時對 在要得到同時具有這樣複合的功能的情況下， 上述禝合木質粉末具有的各種功能有效地賦予利用上述 二質粉末的塑膠製品上’分別準備具有上述功能的多種 載體粒子’而且以複合木質粉末能有效地具有要求功能的 -定的配合比例’固定在高堆密度木質粉末材料和被載粉Comparative Example 1 ~ J, Moment: The spruce swarf composed of the above-mentioned ball mill and the friction effect between the crushing balls and the frictional mash are ground, that is, crushed by friction. I found that the wood powder material obtained in this way was mixed with the polar powder material part and the long fibrous part / particle diameters of nearly the original shape remained, and not all the weight% and titanium S + became granulated.疋] Use an impeller mill to crush the spruce sawdust in advance to form wood. 32 200524721: Second end =, compared with the embodiments using friction means to increase the bulk density, the direct crushing of the crushed material has a very poor crushing effect. A large number of long fibrous parts also remained, and on the other hand, an extremely fine powder-like excessively broken wood powder material was produced. Fixation of carrier particles in the example of composite wood powder: surface, detail: Explains the manufacturing method of composite wood powder. The above complex °% is finally deposited on the surface of the above-mentioned high bulk density wood powder material, and the particle diameter of the quality powder material is changed. Smaller and harder ㈣ fixed. As a high-density wood powder material of the above-mentioned supported powder, the respective particle diameters are within the range of fine particle diameters as much as possible. The main part of the powder to be carried when the mixed article is a coating material for coating has a particle size distribution in a particle diameter range of 2 to 12 # m. In the case where the μ / fruit criminal β object is a resin coating liquid or a plastic sheet, a plastic film, or a molded resin material, the particle diameter of the loaded meal body is preferably smaller than: "It is more preferable to be smaller than or equal to _. It is also effective The particle size distribution is, for example, 75% by weight or more, preferably 80% by weight or more of a particle diameter of 12 or less. Therefore, the object σ is a plastic product obtained by injection molding or extrusion molding. ^ The particle diameter of each of the southern bulk density wood powder materials is preferably within the range of t) U ~ 9 0 // m particle size, and more preferably less than or equal to 20 # m. In the case of products such as plastic flakes obtained by mixing with calender rolls and other molding methods, the high bulk density wood is used: the particle diameter of the material is larger than the particle diameter of the molding resin material 33 200524721 mixed with other plastic products. It is mainly combined in the bite state and two: when the bite state is combined, 'a plurality of carrier particles are agglomerated with each other, and the two are combined with each other = accompanied by heating during the friction crushing process. The above surface starts from the above, and at the same time encloses two :::::, or between the carrier particles bound in the bite state, or between the plutonium particles with the bite = -5 and the carrier particles bound in the encapsulation state. / II: Combining state and grief, etc. After these processing operations, cooling will be performed. Dixin will shrink and combine with the shrinking effect-it is very effective = fixed, that is, no chemical reaction or dry connection is required The carrier particles on the body are fixed by simultaneously supplying the cut powder and the carrier particles to the dry-type ball mill. In addition, the carrier particles can also be attached to the surface of the powder material in advance. Through these two = :, the carrier particles can be obtained. High-density wood adhered to the surface: And the squeeze force is applied on the above-mentioned local-density wood powder material: = to a dry ball mill, etc., the carrier on the surface ... Material: 2 mentioned on the loaded powder and / or high bulk density wood powder material: wood ~ Γ solid particles can be fixed by covering the whole or part of the above-mentioned high bulk density wood shell meal material First, the surface particles, the body particles are heavy with each other, and the screen-shaped cover 17 is realized by cutting the surface. The carrier particles are fixed in the composite wood powder example 2 of the “bulk density wood powder material”, which is described in detail below in 200524721. The above-mentioned composite wood powder is fixed in the case of a powder-carrying body or a high-bulk-density wood "bark carrier particle" in Dumu "finaceae". ; L compound & Wooden powder example 2, solid-loaded powder on the cutting density wood powder material or the ancient gold of the high example 1 * The powder materials of Tongbei 10 knives are placed at the end, and the high-density Muxi Bagu A sees the mouth. The molding method used ... the method of forming the material and the method of solidifying the carrier particles are the same as those of the above-mentioned example of composite wood powder.子 固 疋 The above-mentioned composite wood powder example 2 is carried out at the same time as Γ 箄 _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _: _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ __ Skin: The Γ material and cutting particles of the crushing means are treated as friction. The ball mill of the first type, etc., increases the compaction of the wood powder material, and the second one, the carrier particles are fixed to the bulk density of the high-density wood powder material. The surface of the secondary powder or increased surface or body particles is fixed or temporarily fixed to the surface of the powder to be loaded on the surface of the wood powder: ::: bulk density of the wood powder material surface state, while increasing the bulk density of the powdered material The high density of the wood powder material of the second density: ... In the case of increasing the density of the surface of the wood powder bismuth +, the force of the friction crushing and rubbing treatment that is applied to the above knife and wood material @ 定The filled bulk particles pass through the high-density six-character shovel-filled shovel with a large density of particles as described above.隹 on, wood powder material. In any case, the carrier particles are fixed on the surface of the 咼 bulk density wood of the main θ σ 隹 fork degree of the powder material to form a composite wood powder example 2. Fixation of the carrier particles in the above-mentioned composite wood powder example 2 and the above-mentioned composite 35 200524721 Wood powder example 1 The stationary phase particles of the carrier particles were bonded in a bite state to the high bulk density wood powder and the carrier carrier particles were bonded with the above surface The table of: = :, the: carrier: the carrier and the carrier particles combined in the state of encapsulation using the mutual insertion of sad sad combination # main method to achieve. In the above-mentioned fixing treatment of the above-mentioned composite wood powder example 2, when the above-mentioned composite wood powder example 2 which is a neatly processed final product is necessary, the particles to be carried are further classified to obtain a predetermined range. The required particle diameter is supplied to the processing device together with a plurality of carrier particles. ^ + — When the carrier particles are fixed on the surface of the above-mentioned powder or high-density powder material, a method of covering the entire surface or a part of the surface of the above-mentioned powder or the bulk density wood powder material may also be adopted. In addition, it is also possible to overlay the carrier particles on top of each other in a layered manner on the surface of the above-mentioned powder or high-density concrete powder material. Carrier Particles The following description of β-Shells describes the case where carrier particles are fixed to the surface of a high bulk density wood powder material. The carrier particles may be any of various pigments, various inorganic materials, various metal materials, various plastic materials, and various conductive materials. In other words, the carrier particles can be used as long as they have a hardness and a size that can bite into the surface of the Ado Mod wood powder material as the above-mentioned supported powder. According to the use of the composite wood powder, each of the carrier particles may be a substance having properties corresponding to its use. Generally speaking, when the composite wood powder is mixed with the molding resin material and paint of plastic products, the carrier particles of the above composite wood powder are chemically and thermally stable, and the properties of the composite wood powder will not be damaged. , Produce bad maggots. 、 &Amp; for the formed plastic products and coated carrier particles (inorganic materials)-in: ΠΓ 儿 明 The particles of inorganic materials are used as carrier particles and are fixed on the high bulk density wood f powder material as the supported powder Happening. Carrier = has a harder hardness than the carrier and / or high bulk density wood f powder material or: meal, and the particle diameter is smaller than the particle diameter of the above high bulk powder material or powder. These conditions M are used. You can select and use various inorganic materials from the inorganic materials used for the above-mentioned carrier particles, taking into consideration the conditions of use in the mixture. Take the above-mentioned powdered powder of Taifuyanwangqu Λ 丨 _ 4 as a typical example of the inorganic material as the carrier particles, and the high bulk density wood with the above-mentioned carrier particles 2 as the supported powder). It is preferably in a specified particle diameter range, and the above specified particle diameter range is suitable for the use of composite wood powder, such as «reuse of flakes, plastic plates, various extruded products, injection molded products, and the like, and coating, _ _ Use methods such as injection molding, extrusion molding, and roll forming. For example, in the case where the mixed object is a plastic film or a plastic sheet f, the particle diameter is the same as the powder to be loaded, the wood powder material in Example 2 of the composite wood powder, or the loaded private body, and the mixed object is a resin coating solution. The situation is the same 'preferably less than or equal to 32 ㈣, more preferably less than or equal to 20 # m, and another example of a knife cloth with a particle size is a particle diameter of less than or equal to 75% by weight of the upper 2 # claw, preferably 80% by weight %the above. 37 200524721 When the mixture is a plastic product obtained by injection molding or extrusion molding, the high bulk density wood powder material and composite wood powder in Example 2 are the same as those in Example 1 Preferably, the particle diameter is in the range of 50 to 90 Am, and more preferably 20 mm or less. In the case where the mixed article is a product such as a plastic sheet obtained by mixing and molding by a molding method such as a calender roll, a larger particle diameter may be used. The method for supporting inorganic material particles such as calcium carbonate powder as carrier particles on the surface of the above-mentioned pile-preparing wood powder material and the supported powder body is exactly the same as the case of obtaining the composite wood powder example i and the composite wood powder example 2, It is preferable that the above-mentioned inorganic material particles are fixed on the surface of the high-density wood powder material of the powder-loaded body in a bite-bonding manner to cover the surface as much as possible. A composite wood powder thus obtained makes plastic plates and the like having a good size t 疋 I1 and significantly reduces expansion and contraction due to temperature changes of mosquitoes. The processing operation of each embodiment will be described in detail below. Through the above processing, each powder of carbonic acid as a plurality of carrier particles is fixed on the above-mentioned high-density wood powder material and the surface of the supported powder body to obtain a composite wood powder. Example 2-1 (Carrier particles: calcium carbonate) The two examples described above are the same. The particle size distribution of the above [particle size distribution] is used as the raw material of the wood, and the impeller obstruction mill (impact apple tablet: 25 °) is used. The row distance between the j blade and the lining of the rotating crushing rotator is set to 3 coffee, and the crushing treatment is performed by the action of cutting friction crushing, etc., to obtain the above-mentioned [grain-size sheared powder. Cloth 2] The thus-obtained powder was classified to obtain the above-mentioned particle size distribution [particle size distribution 38 200524721 cloth 3], and then the classified powder was further subjected to the dry method. A ball mill was friction-crushed for two hours to obtain a high bulk density Muga powder material having the above-mentioned [grain size distribution 4] particle size distribution with an increased bulk density. After adding and coating 1.5 kg of calcium carbonate powder to the 1.5 kg of high bulk density wood powder material obtained in this way, the high bulk density wood powder material coated with the calcium carbonate powder was also mixed using the dry ball mill described above. The desired carbonic acid # 5 powder was fixed on the table Φ to obtain a composite wood powder. The composite wood powder thus obtained was used as a filler to obtain a vaporized vinyl resin sheet. The vaporized vinyl resin sheet uniformly contains the double-mouthed wood powder, so the surface of the sheet does not have a sticky feeling, and the expansion and contraction accompanying temperature changes are significantly reduced. Example 2-2 (Carrier particles: calcium carbonate) Using an impeller mill (250 manufactured by Sejin Co., Ltd.), a particle size distribution with a main average particle diameter of 32.〇 ~ 128 # m was obtained (in this specification) Called [particle size distribution 7]) wood powder material. 1. After coating 0.7 kg of calcium carbonate powder as a carrier particle on the prepared 1 kg of the above-mentioned wooden powder material, the above-mentioned dry ball mill was used to perform rubbing for two hours on the powdery powder which had been coated with the above-mentioned carbon dioxide powder. Crushing treatment. Through the friction crushing treatment of the ball mill described above, Ding carried the wide surface of the wooden powder material in the same manner as described above, so that the rhenium carbonate powder was loaded on the surface of the high-density wooden powder material 104 having the shape of the surface after the bite, From 39 200524721 this paid to post-combined wood powder. Then, the composite wood powder obtained therefrom was used as a filling material 'to obtain a vaporized vinyl resin rod by extrusion molding. The composite wood powder is uniformly contained in the thus obtained rod material, so there is no bun I on the surface of the rod material. Expansion and contraction due to temperature change are clear carrier particles (pigments). The pigment particles as the carrier particles described above are fixed to the high-density lignin. powder. In addition to the use of pigment particles and composite particles obtained from the surface of the powder material as the carrier particles, in addition to the conditions of use in mixed objects, especially heat resistance, natural pigments or All pigments, including organic pigments. Powder 2 = t The high bulk density wood of the pigment particles of the above-mentioned carrier particles is known as the supported powder) It is desirable that the particle diameter be as small as possible within the particle diameter range. It has been shown that the ultra-fine material is the main material for the coating of cold sound ... When the coating is used for the soil layer of humans, the bulk density of the wood powder material is mixed, and the wood powder is mixed. Example 2 The private materials of the wooden shell of the Ministry of Eight T or the powder-laden F-knife? ~ 1 9 ^ Qiao Ru ", 2 U m particle size distribution within the dry enclosure. This a object is paint or ΛΑ ^ ^ ^ In the case of plastic materials such as Gelian plastic cymbals, horsewood density wood powder wood Powdered material or compound: Mussel powder ", more preferably less than or equal to 2. The pull diameter is preferably less than or equal to 20 m and the material of the particles preferably accounts for more than 75% by weight of the total. ... mixed in 12 " When the object is a plastic molding mouth or an extruded product, 200524721 is used as a raw material in each of the high-density powders as the loaded powder; the final material, the diameter of the composite wood plasmid, and the composite wood powder For example, the particles of the loaded powder are 50-90 // m, and the ^^ 1 is the same, and the particle diameter is preferably 590 ", more preferably 20" or less. In the case of a mixture of plastic materials such as plastic flakes, it is a powder material obtained by synthesis. T 乂 uses wood with a larger particle diameter to support the pigment particles as carrier particles on the above-mentioned table of high bulk density wood and final material 枓 and the powder to be loaded, which is the same as that in the above embodiment. The same as Wang, it is preferable that the pigment particles are fixed on the surface of the high-density wood eucalyptus private material as the loaded material body by covering the surface with the parent-inlet combination method. As the carrier particle pigment, ★ + Α 丄 sets the mixing amount appropriately according to the light and shade of the person's color and purpose, so the composite wood powder with ## and the pigment particles on it has almost the same hue as that of the mixed pigment particles and has Good liquidity. The composite wood powder loaded with the pigment particles thus obtained is mixed and dispersed in the injection molding and extrusion molding when the plastic molding material is used. These molding pressures are relatively low, and the pigment is uniformly dispersed in the molded product without color unevenness. . Hereinafter, each processing operation of the embodiment will be described in detail. The above embodiment is used to fix the pigment particles as the carrier particles on the surface of the above-mentioned high bulk density wood powder material and the supported powder body to obtain a composite wood powder. Example 3-1 (Carrier particles: Titanium oxide) The same as the above example, the particle size distribution structure 41 200524721 j of the above [particle size distribution 丨] was used as a raw material of wood '1MP-250 manufactured by impeller refinement enterprise) 'The centering between the high-speed rotating cutting blade and the lining is set to 3m, and the rotation =: crushing and other effects to perform the crushing treatment to obtain the above-mentioned [grain size distribution: :: cloth-loaded powder. The graded and graded knives each graded the cloth thus obtained, cloth 3] After loading the powder with a particle size distribution, the above graded :: degree: friction crushing using the above dry ball mill for two hours; [Particle size distribution 4] Particle size distribution of high bulk density wood powder material The high bulk density wood powder material ikg thus obtained is prepared, and at this time, a fine powder material is added and coated with 07 kg as a tailor face: j After the titanium oxide, the above-mentioned ball mill was also manufactured, and the oxide was fixed on the surface of the wood powder material to obtain a composite wood powder. Example 3-2 (carrier particles ·· titanium oxide) 1.5 kg of the above-mentioned [particle size distribution 7] particle size wood powder material obtained by crushing a ore shoulder using an impeller mill (iMp-250 manufactured by Sejin Corporation) was prepared, And 5 kg of titanium oxide powder i as a carrier particle. After the wood powder material was coated with oxan powder, the wood powder material coated with the titanium oxide powder was subjected to a friction crushing treatment using the dry ball mill 'for two hours. With the friction crushing treatment of the above-mentioned ball mill, the angular portion, the protruding portion, and the fibrous whisker portion of the wood powder material are removed, and at the same time, a high bulk density close to granules as a loaded powder is obtained. 42 200524721 Wood Powder material. When using the composite wood grille ^ ^ ^ and Yang Mo as pigments to make plastic plates, they can serve white with no color unevenness ^ ^ ^ The above plates have good touch, no sensation, and expansion and temperature changes The shrinkage becomes significantly smaller. Among them, the carrier particles ^^ Lv ^) the Yan particles are fixed in a bite state on the high bulk density wood that is the powder to be loaded ^ Modification + ^ The surface of the wood shell powder and the powder to be rubbed During the crushing treatment, how can the 苴 畤 χ ～~, .e 5 |. ^ Shape be subjected to a more powerful mechanical impact to achieve better results. For example, the toilets, etc., are different from the above-mentioned embodiments, using a ball mill with stirring blades in the up-and-down direction. The v ^ machine bites the loaded powder and the high-density wood shell material as well as the load and drops under impact conditions. The pigment particles are crushed together in a wood powder. "," "Can be obtained more complex color of the complex carrier particles (conductive powder) dense households too ^ as the carrier particles of the conductive powder fixed on the surface of high X g powder material composite wood powder. A ,, As the conductive powder of the carrier particles, in addition to the need to test any conductive powder i such as heat resistance, etc., conductive powders with metallic properties can be used, including conductive π types such as Ag, CU, and Ni. Tomb: One or more kinds of conductive metal oxide powders such as n〇2 'Zn〇 and conductive powders, etc., can be used. Saigu 2 is a conductive powder for each carrier particle. The composite wood powder combined with the wood powder material on the surface and the surface of the loaded powder can be used as a conductive filling material in coatings, such as electromagnetic wave shielding materials. 43 200524721 Radio wave absorption material, and antistatic material pen, $ 1 It is used in coating liquids such as mixed resins and resin paints. High-density wood powder materials and conductive particles are supported as conductive particles of each carrier particle. The diameter of the shell grain diameter range "as possible in this fine particles: The 'high bulk density powder of wood materials, or the main part of the carrier particles is preferably a composite wood powder powder powder material shell two straight _ (iv) particle size distribution range. In addition, as described above, another example of the above-mentioned preference: household distribution is the ancient soil warehouse Jinchenshi, and the “degree of force” is the wood powder material of the dumplings, and the powder in the composite example 2 preferably has a small particle diameter, , 7i is less than or equal to 20%, and the particle diameter is less than 100%. The particle size distribution found for 12β «η accounts for 75% or more of reset, preferably 80% or more by weight. The conductive powder of the wooden TIL carrier particles is supported on the same high bulk density as described above: = and the method of loading the surface of the powder body, and the conductive powder is fixed to the high pile by bite bonding with the above embodiments. The surface of the wood powder material with a high density, covering the surface, and carrying the wood powder material as the tailoring particle at the above high bulk density—if the conductivity of 疋 can meet the required conductivity is not mutually and 1 again 5, the above-mentioned load can be increased to the already-conducted conductive powder, which has an electrical connection relationship and satisfies the above-mentioned conductivity. As H, the embodiment and its comparative examples are described in detail. The above-mentioned embodiment includes each of the processing operation examples 4 in which the conductive powder of h is fixed to the above-mentioned high bulk density wood powder 44 200524721 material and the surface of the powdered body to obtain a composite wood powder. -1 (Carrier particle: conductive powder) The above [particle size distribution u particle size distribution of cloud shavings as the raw material 'using the impeller obstruction mill (Post 250 manufactured by Seijin Co., Ltd.) The distance between the impact blade and the lining is set to 胄 3 Li ', and the above-mentioned [granularity distribution 2] wood f powder material is obtained through impact crushing and shear friction crushing. Vermiculite is used to classify the obtained powdered powder to obtain the powdered powder with the above-mentioned particle size. Then, the above-mentioned classified wooden powder material is further subjected to friction crushing by the dry ball mill for two hours:増 High bulk density of the above-mentioned [particle size distribution 4] particle size distribution with added bulk density: Shell powder material. Furthermore, in the thus obtained high bulk density wood powder material, the slave powder as a carrier conductive powder which can completely cover its surface in quantity can be added and coated. In this embodiment, it is relatively high compared to 100 parts by weight. Bulk density wood powder materials need to be added and coated with 50 parts by weight of carbon powder. The same: = dry ball mill, the carbon powder is fixed on the surface to obtain composite wood denier and then dimethylamine and methyl ethyl ketone Prepare a solvent of 60 parts by weight at a ratio of 1: i, and add 20 parts by weight of urethane resin to the solvent to prepare a coating liquid. At the same time, the solid part of the urinary resin of the coating liquid and the above carbon powder are prepared. The composite wood powder supported on the surface was mixed at a weight ratio of i: i and mixed by a ball mill for about 10 minutes to obtain a conductive coating. 45 200524721 The above-mentioned conductive coating obtained from the sample is used to measure the surface resistance value 21 ... right 107 ~ 1 × 108Ω, and the measured value is displayed as lx to confirm that it has good conductivity. In addition, after loading the urine powder of the coating liquid on the surface m, the solid part and the composite wood powder with the above stone shovel on the surface were mixed, and the weight ratio mixing knife of 10 Hachinohe + 1.2 was added. To obtain conductive paint. By using the conductive coating m obtained in this way, the film thickness of about 2 to a cold material 性 resistance value can be confirmed than the previous conductive coating: the coating has better conductivity. Isoelectric Example 4-2 (Carrier Particles ·· Carbon Powder) The wood raw material was crushed by the same method as in Example 4 above, to obtain the top-to-center: 2] particle size distribution of wood powder After the material is classified, a qualitative particle size distribution is obtained. Prepare the carbon powder with the wood powder 2 MW as the carrier particles, and coat the wood powder material with a sincere umbrella and Shiba. The above-mentioned dry-type ball mill is used for the wood powder that has been coated with the slave powder. The wood powder material is obtained. After two hours of rubbing and crushing treatment, the surface of the composite wood powder piled with swatches was renovated, X was added, and the carbon powder was fixed on the surface in a bite state. = The composite wood powder obtained in this way was used as a coating material to make a coating, and the conductivity value similar to that of the above coating example W was measured. It was confirmed that the urine having a concentration of 30% of 100 parts by weight relative to the implementation of Comparative Example 4-1 was confirmed. After adding 30 46 200524721 parts by weight of carbon powder to the resin solution, they were mixed with a ball mill for about 0 minutes to obtain a conductive coating. Then, the conductive coating obtained in this way was used to make a coating with a film thickness of about 21 "m. The resistance value of the surface of the coating was measured at 1 × 109 Ω, and carbon agglomeration occurred in the coating. In order to make the surface resistance value below 1 × 10 SQ when forming the above coating layer, continue to mix these urinary resin solution and carbon powder, and measure the surface resistance value of the coating layer at the same time. The result is continuous mixing with a ball mill. After 1 hour, the surface resistance value of the finished coating began to change to ΐχΐ〇8 I shows the carrier particles other than the above examples. In the above examples, you can see that J has inorganic: materials, pigments, conductive materials, Bangladesh Materials, etc. are suitable for use as carrier materials, ... The particles of the warhead are fixed on the high-density wood powder material, and the powder is contained. From the above description of the implementation, ten can be seen, including inorganic materials, ' Particles made of particle materials. Materials other than i belong to the wood material, that is, if the above-mentioned Portuguese wood powder material and the "bulk density" particles are added to increase the bulk density, such as various plastics Grain products; ... J 'of carrier particles may be used as immobilized on: ❹ as described for Example 2 bonded wood powder particles of the wood powder material ^ lined on either or complex. Basket and bulk density wood powder materials can also provide composite functions on the obtained composite wood, Example 47 200524721: the same, ½ gives conductivity and colorability. In this case, by fixing the pigments on the surface of a high-density wood powder material, the composite wood powder can be provided with a conductive function and a coloring function at the same time. When the door is obtained, in the case of obtaining such a composite function at the same time, The various functions of the above-mentioned blended wood powder are effectively given to the plastic products using the above-mentioned two-quality powder to 'preparing multiple carrier particles having the above-mentioned functions, respectively', and the composite wood powder can effectively have the required function-definite mixing ratio ' Fixed in high bulk density wood powder material and loaded powder
以上方法得到的複合木質粉末可作為各種塑膠製品的 填充材料’而且可添加在塗料使用，料用複合木質粉束 可通過耗、擠壓等各種成形方法成形各種製品，而且可 通過簡單擠壓形成木板等，可用於各種用途。The composite wood powder obtained by the above method can be used as a filling material for various plastic products, and can be added to coatings. The composite wood powder bundle for materials can be formed into various products by various forming methods such as consumption and extrusion, and can be formed by simple extrusion. Wooden boards, etc. can be used for various purposes.
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