CN106046825A - Luggage waste and reed composite sectional material and manufacturing method thereof - Google Patents

Luggage waste and reed composite sectional material and manufacturing method thereof Download PDF

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Publication number
CN106046825A
CN106046825A CN201610381069.2A CN201610381069A CN106046825A CN 106046825 A CN106046825 A CN 106046825A CN 201610381069 A CN201610381069 A CN 201610381069A CN 106046825 A CN106046825 A CN 106046825A
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case
bag waste
phragmites communis
pvc
pelletize
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李天�
李天一
魏谦
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Hebei Hong Mu Environmental Protection Polytron Technologies Inc
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Hebei Hong Mu Environmental Protection Polytron Technologies Inc
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Priority to CN201610381069.2A priority Critical patent/CN106046825A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L75/00Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
    • C08L75/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/062HDPE
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/20Recycled plastic

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)

Abstract

The invention discloses a luggage waste and reed composite sectional material and a manufacturing method thereof and relates to the technical field of composite sectional materials. The luggage waste and reed composite sectional material is prepared from, by weight, 30-70% of recyclable PU and PVC luggage waste particles, 10-40% of reed fiber powder, 10-30% of plastic resin, 1.0-1.5% of a modifying agent, 1.0-1.5% of a lubricating agent, 1.0-1.5% of stearic acid, 0.5-1.0% of EVA, 0-10% of inorganic filler and 0-1.0% of toner through the steps of mixing, pelleting and extrusion molding. The composite sectional material prevents water and moisture and effectively eradicates insects and is high in plasticity and environment friendliness, free of pollution, nuisanceless, recyclable and good in machinability, and the service life is prolonged. The composite sectional material can be widely applied to the fields of building materials, decoration and the like. The manufacturing technology is simple, scientific and reasonable, the consumption problem of the luggage waste and reeds is solved, the environment is protected, and the waste is reused.

Description

Case and bag waste material and phragmites communis composite material and manufacture method thereof
Technical field
The present invention relates to composite material technical field.
Background technology
Along with the raising of China's Living consumption, the demand of all kinds of case and bag and leatherware is increased by people, thus case Bag processing enterprise and leatherware enterprise create substantial amounts of leather leftover bits, additionally the little paper mill with phragmites communis as raw material Closing down, cause a large amount of phragmites communis not to be effectively addressed, both the above refuse is only by burning or the other side, and burns and can produce Raw dioxin contamination environment, stacks not only land occupation resource for a long time, but also can produce dieseling, discharge substantial amounts of dense smoke And toxic gas, serious pollution surrounding enviroment, resident living is caused ill effect.
Prior art has use case and bag and leatherware waste material to produce composite material, but its cost and performance there is also Not enough.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of case and bag waste material and phragmites communis composite material and manufacture method thereof, should Complex section bar is waterproof and dampproof, insect protected, termite-proof, effectively stops insects harassing and wrecking, increases the service life, and plasticity is strong, high-environmental Property, pollution-free, nuisanceless, reusable edible, machinability is good, can follow closely, can dig, can bore, surface can japanning, install simple, execute Work is convenient.Extensively can apply in the fields such as building materials, garden landscape, urban operating mechanism, commercial location, decoration.Manufacturing process is simple, Low cost, performance can meet requirement, solves the problem of outlet of phragmites communis, it is achieved protection environment and refuse reclamation.
For solving above-mentioned technical problem, the technical solution used in the present invention is: a kind of case and bag waste material and phragmites communis are compound Material, including the raw material of following percentage by weight: PU and PVC case and bag waste granules 30-70%, the reed fiber powder 10-40% of recovery, Plastic resin 10-30%, modifying agent 1.0-1.5%, lubricant 1.0-1.5%, stearic acid 1.0-1.5%, EVA 0.5-1.0%, inorganic Filler 0-10%, toner 0-1.0%, blended, pelletize, extrusion molding prepare.
Preferably, including the raw material of following percentage by weight: PU and the PVC case and bag waste granules 30-50% of recovery, phragmites communis Fiber powder 30-40%, plastic resin 11-30%, modifying agent 1.0-1.5%, lubricant 1.0-1.5%, stearic acid 1.0-1.5%, EVA 0.5-1.0%, inorganic filler 5-10%, toner 0.5-1.0%.
Preferably, PU and the PVC case and bag waste granules of recovery is to give up in the corner produced in case and bag manufacturing enterprise production process Material, after broken, pelletize, granularity is less than 2mm.
Preferably, reed fiber powder be the phragmites communis using harvesting as raw material, granularity after cutting or broken, pelletize Less than 1mm.
Preferably, plastic resin is PVC or PE;PVC is one or both in PVC-U or flexible PVC, PE For one or more in Low Density Polyethylene, medium density polyethylene or high density polyethylene (HDPE).
Preferably, modifying agent is acrylic acid esters co-polymer ACR-401.
Preferably, lubricant is Tissuemat E or paraffin.
Preferably, inorganic filler is calcium carbonate.
Case and bag waste material and the manufacture method of phragmites communis composite material, comprise the following steps:
(1) case and bag waste material and phragmites communis crush pelletize
The broken pelletize of PU and the PVC case and bag waste material reclaimed, is first broken into 20-100mm by PU and the PVC case and bag waste material of recovery Particle diameter, then passes through granulator granulation and makes the granularity powdered granule less than 2mm, PU and the PVC case and bag waste granules i.e. reclaimed;
The broken pelletize of phragmites communis, first carries out cutting or crushing by phragmites communis, then is put into by phragmites communis in comminutor, and pelletize obtains granularity Reed fiber powder less than 1mm;
(2) mix
PU and the PVC case and bag waste granules of the recovery that step (1) is obtained and reed fiber powder, and plastic resin, modifying agent, Lubricant, stearic acid, EVA, inorganic filler and toner are placed in mixer and are mixed;
(3) pelletize, extrusion molding:
By the pelletize in comminutor of step (2) gained material, then put into extruder for shaping, obtain case and bag waste material and phragmites communis Composite material.
Preferably, step (1) case and bag waste material and phragmites communis crush in pelletize: the pelletize temperature of PU and the PVC case and bag waste material of recovery Degree is for 140-220 DEG C;The prilling temperature of phragmites communis is 100-160 DEG C;
In step (2) mix: the rotating speed of mixer is 740-1480 r/min, mixing temperature is 80-120 DEG C;
In step (3) pelletize, extrusion molding: during pelletize, first by granulator heating to 130-220 DEG C, then by step (2) gained Material puts into pelletize in comminutor, send cooling to crush by wind and makes particulate material;During extrusion molding, first extruder is heated to 130-180 DEG C, then the particulate material that comminutor is made is put into extrusion molding in extruder, after cooling and shaping, cutting Obtain case and bag waste material and phragmites communis composite material.
Preferably, in outer surface embossing, sanding or the wire drawing of case and bag waste material and phragmites communis composite material.
EVA is the English abbreviation of ethylene-vinyl acetate copolymer.
Above raw material is combined by the present invention together, change reed fiber powder, PU and the PVC case and bag waste granules of recovery and The characteristic of plastic resin, strengthens the phase between composite material major ingredient reed fiber powder and PU and the PVC case and bag waste granules of recovery Capacitive so that it is become the higher goods of physical property and take into account the double grading of timber and plastics.
Modifying agent to reclaim PU and PVC case and bag waste granules and plastic resin between be combined modifying function.
PU and the PVC case and bag waste material reclaimed pelletize again after broken, 140-220 DEG C of pelletize, makes the recovery after crushing PU and PVC case and bag waste material hot melt, plasticizing, PU and the PVC case and bag waste granules compactness making recovery is more preferable, is conducive to into quality Amount, and thinner, easily mix, improve the production efficiency of composite material.
Phragmites communis pelletize again after broken, 100-160 DEG C of pelletize, make broken after phragmites communis in the micro-carbonization of this temperature, and not Destroy fibre structure.Reed fiber powder plays drawknot effect in composite material.
All raw materials are placed in mixer and are mixed, and mixing temperature is 80-120 DEG C, make the mixing of various raw material more uniformly also Play preplasticizing effect.
Use and have the beneficial effects that produced by technique scheme:
(1) the technical problem to be solved in the present invention is to provide a kind of case and bag waste material and phragmites communis composite material and manufacture method thereof, should Complex section bar is waterproof and dampproof, insect protected, termite-proof, effectively stops insects harassing and wrecking, increases the service life, and plasticity is strong, high-environmental Property, pollution-free, nuisanceless, reusable edible, machinability is good, can follow closely, can dig, can bore, surface can japanning, install simple, execute Work is convenient.Extensively can apply in the fields such as building materials, garden landscape, urban operating mechanism, commercial location, decoration.
(2) manufacturing process is simple, low cost, and performance can meet requirement, solves the problem of outlet of phragmites communis, and realizes protection Environment and refuse reclamation.
(3) compared with the present invention moulds with Traditional Wood, per ton cost reduces about 200 yuan, impact resistance, rupture strength, resistance to The physical properties such as mill performance improve about 10%.
Detailed description of the invention
Below in conjunction with detailed description of the invention, the present invention is further detailed explanation.
In the present invention, modifying agent is acrylic acid esters co-polymer, modifying agent model: ACR-401, manufacturer: Zibo Hua Xing Plastic additive factory.
Embodiment 1
A kind of case and bag waste material and phragmites communis composite material, including the raw material of following percentage by weight: PU and the PVC case and bag waste material of recovery Granule 30%, reed fiber powder 40%, plastic resin 20%, modifying agent 1.0%, lubricant 1.5%, stearic acid 1.2%, EVA 0.8%, Inorganic filler 5%, toner 0.5%.Wherein, PU and the PVC case and bag waste granules of recovery is to produce in case and bag manufacturing enterprise production process Raw leftover bits;Plastic resin is PVC-U and flexible PVC;Modifying agent is acrylic acid esters co-polymer ACR- 401;Lubricant is Tissuemat E;Inorganic filler is calcium carbonate.
Case and bag waste material and the manufacture method of phragmites communis composite material, comprise the following steps:
(1) case and bag waste material and phragmites communis crush pelletize
The broken pelletize of PU and the PVC case and bag waste material reclaimed, first puts in shredder by PU and the PVC case and bag waste material reclaimed, Torn up by twin shaft, be broken into 20-100mm particle diameter, remove the metals such as iron nail through magnetic separation, then pass through single screw pelletizer, adopt The granularity powdered granule less than 2mm, PU and the PVC case and bag waste granules i.e. reclaimed is made with 140-220 DEG C of pelletize of preset temperature;
The broken pelletize of phragmites communis, first carries out cutting or crushing by phragmites communis, then is put in single screw pelletizer by phragmites communis, presets temperature Carry out pelletize at spending 100-160 DEG C and obtain the granularity reed fiber powder less than 1mm;
(2) mix
PU and the PVC case and bag waste granules of the recovery that step (1) is obtained and reed fiber powder, and plastic resin, modifying agent, Lubricant, stearic acid, EVA, inorganic filler and toner are placed in high-speed mixer and are mixed, and rotating speed is 740-1480 r/min, mixed Closing temperature is 100 DEG C;
(3) pelletize, extrusion molding:
By the pelletize in comminutor of step (2) gained material, then put into extruder for shaping;
During pelletize, first by granulator heating to 130-220 DEG C, then step (2) gained material is put into pelletize in comminutor, logical Cross wind and send that cooling is broken makes particulate material;
During extrusion molding, first extruder is heated to 130-180 DEG C, then the particulate material that comminutor is made is put into extruder Middle extrusion molding, obtains case and bag waste material and phragmites communis composite material after cooling and shaping, cutting.
Using conical screw extruder extrusion molding, composite material can produce difformity according to mould difference and cut Face, cooling and shaping uses circulating cooling tank cooling and shaping, cutting to use stop Length-fixing cutting.
Taking 23 pieces of this composite material sample, specification 150mm*25mm, sample state is intact, and detection is according to GB/T24508- 2009 " Wood-plastic floors ", detection project and test result see table:
Embodiment 2
A kind of case and bag waste material and phragmites communis composite material, including the raw material of following percentage by weight: PU and the PVC case and bag waste material of recovery Granule 40%, reed fiber powder 20%, plastic resin 30%, modifying agent 1.5%, lubricant 1.4%, stearic acid 1.3%, EVA 0.7%, Inorganic filler 4.1%, toner 1.0%.Wherein, PU and the PVC case and bag waste granules of recovery is in case and bag manufacturing enterprise production process The leftover bits produced;Plastic resin is flexible PVC;Modifying agent is acrylic acid esters co-polymer ACR-401;Lubricant is Paraffin;Inorganic filler is calcium carbonate.
The manufacture method of case and bag waste material and phragmites communis composite material is with embodiment 1.
Embodiment 3
A kind of case and bag waste material and phragmites communis composite material, including the raw material of following percentage by weight: PU and the PVC case and bag waste material of recovery Granule 50%, reed fiber powder 30%, plastic resin 11%, modifying agent 1.0%, lubricant 1%, stearic acid 1.0%, EVA 0.5%, nothing Machine filler 5%, toner 0.5%.Wherein, PU and the PVC case and bag waste granules of recovery is to produce in case and bag manufacturing enterprise production process Leftover bits;Plastic resin is Low Density Polyethylene, medium density polyethylene and high density polyethylene (HDPE);Modifying agent is acrylate Analog copolymer ACR-401;Lubricant is Tissuemat E;Inorganic filler is calcium carbonate.
The manufacture method of case and bag waste material and phragmites communis composite material is with embodiment 1.
Embodiment 4
A kind of case and bag waste material and phragmites communis composite material, including the raw material of following percentage by weight: PU and the PVC case and bag waste material of recovery Granule 40%, reed fiber powder 35%, plastic resin 11.7%, modifying agent 1.5%, lubricant 1.3%, stearic acid 1.5%, EVA 1%, Inorganic filler 7%, toner 1.0%.Wherein, PU and the PVC case and bag waste granules of recovery is to produce in case and bag manufacturing enterprise production process Raw leftover bits;Plastic resin is Low Density Polyethylene and medium density polyethylene;Modifying agent is acrylic acid esters co-polymer ACR-401;Lubricant is Tissuemat E;Inorganic filler is calcium carbonate.
The manufacture method of case and bag waste material and phragmites communis composite material is with embodiment 1.
Embodiment 5
A kind of case and bag waste material and phragmites communis composite material, including the raw material of following percentage by weight: PU and the PVC case and bag waste material of recovery Granule 30%, reed fiber powder 30%, plastic resin 30%, modifying agent 1.3%, lubricant 1.2%, stearic acid 1.3%, EVA 0.5%, Inorganic filler 5%, toner 0.7%.Wherein, PU and the PVC case and bag waste granules of recovery is to produce in case and bag manufacturing enterprise production process Raw leftover bits;Plastic resin is PVC-U;Modifying agent is acrylic acid esters co-polymer ACR-401;Lubricant is poly- Ethylene waxes;Inorganic filler is calcium carbonate.
The manufacture method of case and bag waste material and phragmites communis composite material is with embodiment 1.
Embodiment 6
A kind of case and bag waste material and phragmites communis composite material, including the raw material of following percentage by weight: PU and the PVC case and bag waste material of recovery Granule 35%, reed fiber powder 32%, plastic resin 17.1%, modifying agent 1.5%, lubricant 1.4%, stearic acid 1.3%, EVA 0.7%, inorganic filler 10%, toner 1.0%.Wherein, PU and the PVC case and bag waste granules of recovery is that case and bag manufacturing enterprise produced The leftover bits produced in journey;Plastic resin is high density polyethylene (HDPE);Modifying agent is acrylic acid esters co-polymer ACR-401;Profit Lubrication prescription is Tissuemat E;Inorganic filler is calcium carbonate.
The manufacture method of case and bag waste material and phragmites communis composite material is with embodiment 1.
Embodiment 7
A kind of case and bag waste material and phragmites communis composite material, including the raw material of following percentage by weight: PU and the PVC case and bag waste material of recovery Granule 50%, reed fiber powder 30%, plastic resin 10%, modifying agent 1.1%, lubricant 1.3%, stearic acid 1.1%, EVA 0.5%, Inorganic filler 6%.Wherein, PU and the PVC case and bag waste granules of recovery is to give up in the corner produced in case and bag manufacturing enterprise production process Material;Plastic resin is Low Density Polyethylene;Modifying agent is acrylic acid esters co-polymer ACR-401;Lubricant is Tissuemat E;Nothing Machine filler is calcium carbonate.
The manufacture method of case and bag waste material and phragmites communis composite material is with embodiment 1.
Embodiment 8
A kind of case and bag waste material and phragmites communis composite material, including the raw material of following percentage by weight: PU and the PVC case and bag waste material of recovery Granule 60%, reed fiber powder 15%, plastic resin 10%, modifying agent 1.2%, lubricant 1.2%, stearic acid 1.0%, EVA 1.0%, Inorganic filler 10%, toner 0.6%.Wherein, PU and the PVC case and bag waste granules of recovery is to produce in case and bag manufacturing enterprise production process Raw leftover bits;Plastic resin is medium density polyethylene;Modifying agent is acrylic acid esters co-polymer ACR-401;Lubricant is Paraffin;Inorganic filler is calcium carbonate.
The manufacture method of case and bag waste material and phragmites communis composite material is with embodiment 1.
Embodiment 9
A kind of case and bag waste material and phragmites communis composite material, including the raw material of following percentage by weight: PU and the PVC case and bag waste material of recovery Granule 70%, reed fiber powder 10%, plastic resin 15.4%, modifying agent 1.3%, lubricant 1.0%, stearic acid 1.5%, EVA 0.6%, toner 0.2%.Wherein, PU and the PVC case and bag waste granules of recovery is the limit produced in case and bag manufacturing enterprise production process Horn scraps;Plastic resin is Low Density Polyethylene and high density polyethylene (HDPE);Modifying agent is acrylic acid esters co-polymer ACR-401; Lubricant is Tissuemat E.
The manufacture method of case and bag waste material and phragmites communis composite material is with embodiment 1.
Composite material prepared by the present invention can be in the fields such as building materials, garden landscape, urban operating mechanism, commercial location, decoration Extensively application.Can be used for building template, packaging pallet, handrail, guardrail, fence, cut off, serve as a contrast shelves, seat stool, chair bar, backrest bar, table Face, door, refuse receptacle, flower case etc. use.
Outer surface at composite material of the present invention can be with embossing, sanding or wire drawing.

Claims (10)

1. a case and bag waste material and phragmites communis composite material, it is characterised in that: include the raw material of following percentage by weight: the PU of recovery With PVC case and bag waste granules 30-70%, reed fiber powder 10-40%, plastic resin 10-30%, modifying agent 1.0-1.5%, lubricant 1.0-1.5%, stearic acid 1.0-1.5%, EVA 0.5-1.0%, inorganic filler 0-10%, toner 0-1.0%, blended, pelletize, squeeze Go out what molding prepared.
Case and bag waste material the most according to claim 1 and phragmites communis composite material, it is characterised in that: include following percentage by weight Raw material: PU and the PVC case and bag waste granules 30-50% of recovery, reed fiber powder 30-40%, plastic resin 11-30%, modifying agent 1.0-1.5%, lubricant 1.0-1.5%, stearic acid 1.0-1.5%, EVA 0.5-1.0%, inorganic filler 5-10%, toner 0.5- 1.0%。
Case and bag waste material the most according to claim 1 and phragmites communis composite material, it is characterised in that PU and the PVC case of described recovery Bag waste granules is the leftover bits produced in case and bag manufacturing enterprise production process, and after broken, pelletize, granularity is less than 2mm.
Case and bag waste material the most according to claim 1 and phragmites communis composite material, it is characterised in that described reed fiber powder is for adopting With the phragmites communis of harvesting as raw material, after cutting or broken, pelletize, granularity is less than 1mm.
Case and bag waste material the most according to claim 1 and phragmites communis composite material, it is characterised in that described plastic resin be PVC or PE;PVC is one or both in PVC-U or flexible PVC, PE be Low Density Polyethylene, medium density polyethylene or One or more in high density polyethylene (HDPE).
Case and bag waste material the most according to claim 1 and phragmites communis composite material, it is characterised in that described modifying agent is acrylic acid Lipin polymer ACR-401.
Case and bag waste material the most according to claim 1 and phragmites communis composite material, it is characterised in that described lubricant is polyethylene Wax or paraffin.
Case and bag waste material the most according to claim 1 and phragmites communis composite material, it is characterised in that described inorganic filler is carbonic acid Calcium.
9. case and bag waste material as claimed in claim 1 and the manufacture method of phragmites communis composite material, it is characterised in that include following step Rapid:
(1) case and bag waste material and phragmites communis crush pelletize
The broken pelletize of PU and the PVC case and bag waste material reclaimed, is first broken into 20-100mm by PU and the PVC case and bag waste material of recovery Particle diameter, then passes through granulator granulation and makes the granularity powdered granule less than 2mm, PU and the PVC case and bag waste granules i.e. reclaimed;
The broken pelletize of phragmites communis, first carries out cutting or crushing by phragmites communis, then is put into by phragmites communis in comminutor, and pelletize obtains granularity Reed fiber powder less than 1mm;
(2) mix
PU and the PVC case and bag waste granules of the recovery that step (1) is obtained and reed fiber powder, and plastic resin, modifying agent, Lubricant, stearic acid, EVA, inorganic filler and toner are placed in mixer and are mixed;
(3) pelletize, extrusion molding:
By the pelletize in comminutor of step (2) gained material, then put into extruder for shaping, obtain case and bag waste material and phragmites communis Composite material.
Case and bag waste material the most according to claim 9 and the manufacture method of phragmites communis composite material, it is characterised in that step (1) Case and bag waste material and phragmites communis crush in pelletize: the prilling temperature of PU and the PVC case and bag waste material of recovery is 140-220 DEG C;Making of phragmites communis Grain temperature is 100-160 DEG C;
In step (2) mix: the rotating speed of mixer is 740-1480 r/min, mixing temperature is 80-120 DEG C;
In step (3) pelletize, extrusion molding: during pelletize, first by granulator heating to 130-220 DEG C, then by step (2) gained Material puts into pelletize in comminutor, send cooling to crush by wind and makes particulate material;During extrusion molding, first extruder is heated to 130-180 DEG C, then the particulate material that comminutor is made is put into extrusion molding in extruder, after cooling and shaping, cutting Obtain case and bag waste material and phragmites communis composite material.
CN201610381069.2A 2016-06-01 2016-06-01 Luggage waste and reed composite sectional material and manufacturing method thereof Pending CN106046825A (en)

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Application publication date: 20161026