JP2009012451A - Method for molding hormesis composite material - Google Patents

Method for molding hormesis composite material Download PDF

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JP2009012451A
JP2009012451A JP2008000069A JP2008000069A JP2009012451A JP 2009012451 A JP2009012451 A JP 2009012451A JP 2008000069 A JP2008000069 A JP 2008000069A JP 2008000069 A JP2008000069 A JP 2008000069A JP 2009012451 A JP2009012451 A JP 2009012451A
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powder
composite
inorganic
hormesis
weight
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Katsuyuki Hasegawa
克之 長谷川
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ALMIGHTY KK
Almighty Co Ltd
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ALMIGHTY KK
Almighty Co Ltd
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/021Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles characterised by the shape of the surface
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B18/00Use of agglomerated or waste materials or refuse as fillers for mortars, concrete or artificial stone; Treatment of agglomerated or waste materials or refuse, specially adapted to enhance their filling properties in mortars, concrete or artificial stone
    • C04B18/02Agglomerated materials, e.g. artificial aggregates
    • C04B18/022Agglomerated materials, e.g. artificial aggregates agglomerated by an organic binder
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B40/00Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
    • C04B40/02Selection of the hardening environment
    • C04B40/0259Hardening promoted by a rise in pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/32Component parts, details or accessories; Auxiliary operations
    • B29C43/34Feeding the material to the mould or the compression means
    • B29C2043/3405Feeding the material to the mould or the compression means using carrying means
    • B29C2043/3427Feeding the material to the mould or the compression means using carrying means hopper, vessel, chute, tube, conveying screw, for material in discrete form, e.g. particles or powder or fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/02Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles
    • B29C43/04Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds
    • B29C43/06Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of definite length, i.e. discrete articles using movable moulds continuously movable in one direction, e.g. mounted on chains, belts
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/54Substitutes for natural stone, artistic materials or the like
    • C04B2111/542Artificial natural stone
    • C04B2111/545Artificial marble

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Ceramic Engineering (AREA)
  • Structural Engineering (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Civil Engineering (AREA)
  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Casting Or Compression Moulding Of Plastics Or The Like (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
  • Devices For Medical Bathing And Washing (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a method for manufacturing a composite resin molded article where molding can be facilitated, and further, a molded article can be manufactured at high precision. <P>SOLUTION: A hormesis ore powder composite stock obtained by packing a powdery reinforcing hormesis ore powder raw material of ≥60 wt.% into a matrix resin is used. The hormesis ore powder composite stock is crushed, the crushed pieces of the hormesis ore powder composite stock is arranged on a flat face or on a face with a prescribed cubic shape, are heated and pressurized, and are made close together and integrated, so as to manufacture a composite resin molded article. Various hormesis ore powders can be used as their raw materials. Further, as the matrix resin, various thermoplastic resins can be used. <P>COPYRIGHT: (C)2009,JPO&INPIT

Description

本発明は二段階で成形するホルミシス複合材料の製造方法に関するものである。   The present invention relates to a method for producing a hormesis composite material formed in two stages.

ホルミシス原石は低放射線を放射するものとして岩盤浴の材料として利用される。しかしながら、かかる原石で岩盤浴に利用できるように板状に成形するには多量の原石を必要とする(特許文献1)。また、療法対象に応じて自然放射の10倍〜10,000倍の強度範囲で線量を調整する必要がある。したがって、あらかじめ原石粉砕物と樹脂を混合したシート状のものを金型で圧縮成型するSMCプレス法などを利用して成形する方法が提案されるが、熱硬化性樹脂をマトリックス樹脂とすると、リサイクルがほとんど不可能となる欠点がある。   The hormesis rough is used as a material for bedrock baths as it emits low radiation. However, a large amount of raw stone is required to form such a raw stone into a plate shape so that it can be used for a rock bath (Patent Document 1). In addition, it is necessary to adjust the dose within an intensity range of 10 to 10,000 times the natural radiation depending on the treatment target. Therefore, a method is proposed that uses the SMC press method, which compresses and molds a sheet of raw crushed material and resin in advance using a mold, but recycling is possible when the thermosetting resin is a matrix resin. There is a drawback that is almost impossible.

そこで、熱硬化性樹脂(GFRP)の代替として、リサイクル可能な、メチルメタアクリレートなどの熱可塑性樹脂を用いる方法も考えられるが、押出成形を採用すると、成形上充填材の配合率は高々30〜40%であり、しかも均一分散が難しい。また、強度の確保上、繊維の配合が望ましく、さらに同時に遠赤外線効果、マイナスイオン効果、磁力線効果を併用するのが好ましいが、充填量40%以上の配合は困難である。各種充填材を必要に応じて配合するためには、高充填を達成する必要があるが、SMCプレス法 (Sheet Molding Compounds)を使用するにしても. 熱可塑性樹脂を使用して所定のSMCシート(基材・樹脂・充填材を混練しシート状にしたもの)を用意するのが困難であり、又量産性に欠ける。   Therefore, as an alternative to thermosetting resin (GFRP), a method using a recyclable thermoplastic resin such as methyl methacrylate is also conceivable. However, when extrusion molding is employed, the blending ratio of the filler on molding is 30 to 30 at most. 40% and uniform dispersion is difficult. Further, in order to ensure strength, it is desirable to mix the fibers, and it is preferable to use the far-infrared effect, the negative ion effect, and the magnetic line effect at the same time, but it is difficult to mix the filling amount of 40% or more. In order to blend various fillers as needed, it is necessary to achieve high filling, but even if the SMC pressing method (Sheet Molding Compounds) is used. Predetermined SMC sheet using thermoplastic resin It is difficult to prepare (a material obtained by kneading a base material, a resin, and a filler) and lacks mass productivity.

特開2006−187443号公報JP 2006-187443 A

本発明者は鋭意研究の結果、熱可塑性樹脂をマトリックスとしても、充填配合量を60重量%以上とすることはSMC工法以外には不可能であるが、熱可塑性樹脂を使用する場合、一旦混練固化させた充填材料との複合材料を作成し、これを粉砕または破砕し、これを成形材料として二段成形すると、60重量%以上、好ましくは70重量%以上85重量%までの充填材料分を樹脂分に対して配合しても成形することができ、成形すると、低線量放射線原石粉末が無機質粉末及び/又は繊維分とともに熱可塑性樹脂からなるマトリックス中に均一分散して、低線量放射線のホルミシス原石に相当する作用効果を達成できることを見出した。   As a result of diligent research, the present inventor has made it possible to use a thermoplastic resin as a matrix, but it is impossible to make the filling compounding amount 60% by weight or more except by the SMC method. When a composite material with a solidified filling material is prepared, pulverized or crushed, and formed into a two-stage molding as a molding material, a filling material content of 60 wt% or more, preferably 70 wt% or more and 85 wt% is obtained. It can be molded even if it is blended with the resin component, and when molded, the low-dose radiation rough powder is uniformly dispersed in the matrix made of the thermoplastic resin together with the inorganic powder and / or the fiber component. It has been found that the effect equivalent to the rough can be achieved.

本発明は、低線量放射線原石粉末を含み、無機質粉末及び/又は無機質繊維と合わせて合計60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した素材を粉砕又は破砕して複合中間原料を用意する工程と、該複合中間原料を所定の成形型中に充填する工程と、成形型内に密集した複合中間原料を加熱加圧して一体化する工程を備えることを特徴とするホルミシス複合材料の成形方法にある。本発明において使用する複合中間原料はそのまま金型内に付し、これを熱プレスまたは熱ローラプレス、ベルト式プレスで加熱加圧することにより、容易にシート状に成形できるが、特に、成形型中に充填する工程では、一対の成形型に空気流とともに複合中間原料を投入する投入口を設ける一方、成形型の他方向に空気流の排出口を設け、複合中間原料を空気流とともに成形型に投入する一方下方から排気し、成形型中で空気流下流から上流に複合中間原料を順次堆積させて充填させるが、これに代えて成形型中に充填する工程では、一対の成形型で形成される型内部を減圧し、材料投入口を開放して複合中間原料を型内部に吸引充填させることも可能である。   The present invention includes a low-dose radiation raw powder and pulverizes or crushes a solidified material obtained by kneading 40 to 15% by weight of a thermoplastic resin with respect to a total of 60 to 85% by weight together with inorganic powder and / or inorganic fiber. Preparing a composite intermediate raw material, filling the composite intermediate raw material into a predetermined mold, and heating and pressurizing the composite intermediate raw material densely packed in the mold, A forming method of a hormesis composite material. The composite intermediate raw material used in the present invention can be easily formed into a sheet by applying it directly into a mold and heating and pressing it with a heat press, a heat roller press, or a belt type press. In the process of filling the mold, a pair of molds is provided with an inlet for introducing the composite intermediate raw material together with the air flow, while an outlet for air flow is provided in the other direction of the mold so that the composite intermediate raw material is formed into the mold together with the air flow While being charged, it is evacuated from below, and the composite intermediate raw material is sequentially deposited and filled in the mold from the downstream side to the upstream side, but instead of this, in the step of filling into the mold, it is formed by a pair of molds. It is also possible to decompress the inside of the mold, open the material inlet, and suck and fill the composite intermediate material into the mold.

本発明によれば、低線量放射線原石粉末とともに、ホルミシス原石粉末または無機材が高充填された一次成形材料を一旦粉砕または破砕して形成した複合中間材を成形型内に充填し、これを加熱加圧するようにしたので、ホルミシス原石粉末または無機材が高充填された樹脂マトリックス中に低線量放射線原石粉末が均一分散し、原石に相当する複合製品を成形でき、生産コストを低減することができる。   According to the present invention, a composite intermediate material formed by once crushing or crushing a primary molding material highly filled with a hormesis raw stone powder or an inorganic material together with a low-dose radiation raw stone powder is filled in a mold and heated. Since the pressurization is performed, the low-dose radiation rough powder is uniformly dispersed in the resin matrix highly filled with the hormesis rough powder or the inorganic material, and a composite product corresponding to the rough can be molded, and the production cost can be reduced. .

また、本発明によれば、低線量放射線原石粉末を含み、無機質粉末及び/又は無機質繊維と合わせて合計60〜85重量%と熱可塑性樹脂40〜15重量%とからなり、低放射線原石粉末が無機質粉末及び/又は無機質繊維とともに熱可塑性樹脂からなるマトリックス中に均一分散してなるホルミシス複合材料を提供することができる。本発明において、低線量放射線原石として各種放射線原石、例えば、ウラン鉱石、トリウム鉱石、ラジウム、ラドン鉱石などの一般放射線鉱石だけでなく、バドガッシュタイン鉱石などの各種低線量放射線原石を含むことができるが、被爆量を自然放射線の10倍から10000倍に制限するのが好ましく、配合量だけでなく、1000倍の線量を達成するためには中国ウラン原石、10000倍の線量を達成するためにはセシウム137鉱石を使用するのが好ましい。また、無機質粉末としては、耐熱性を与える水酸化アルミニウム、プラスチック製品増量剤であるタンカル、シリカなど、さらに、遠赤外線放射粉末である炭素、麦飯石、黙示石、珪藻土の1種以上を、さらにまた、各種ミネラル源である無機および有機ゲルマニウムなど、あるいは各種希土類磁石粉末等の磁性粉末を含ませることができる。無機質繊維としては、ガラス繊維、カーボン繊維および繊維ボロン等の各種繊維、有機繊維としては各種天然繊維、各種合成繊維が含まれる。導電性繊維であっては、発熱可能であるカーボンまたはグラファイト繊維が好ましい。   In addition, according to the present invention, the low-dose radiation raw powder includes a low-dose radiation rough powder, and is composed of 60 to 85% by weight in total with the inorganic powder and / or the inorganic fiber and 40 to 15% by weight of the thermoplastic resin. A hormesis composite material that is uniformly dispersed in a matrix made of a thermoplastic resin together with inorganic powder and / or inorganic fibers can be provided. In the present invention, various low-dose radiation ore, for example, general radiation ore such as uranium ore, thorium ore, radium, radon ore, as well as various low-dose radiation ore such as Badgastein ore However, it is preferable to limit the amount of exposure to 10 to 10,000 times that of natural radiation. In order to achieve not only the compounding amount but also 1000 times of the dose, It is preferred to use cesium 137 ore. In addition, as the inorganic powder, aluminum hydroxide giving heat resistance, tancal which is a plastic product extender, silica, etc., and further, one or more of carbon, barleystone, apocalypse and diatomaceous earth which are far infrared radiation powder, Moreover, magnetic powders, such as inorganic and organic germanium which are various mineral sources, or various rare earth magnet powders, can be included. Examples of inorganic fibers include glass fibers, carbon fibers, and fiber boron, and examples of organic fibers include various natural fibers and various synthetic fibers. The conductive fiber is preferably carbon or graphite fiber that can generate heat.

したがって、本発明では、1種の複合中間素材に、または1枚の最終プレートにホルミシス効果以外の各種効果、遠赤外線効果、マイナスイオン効果、磁性効果を並存させることができるが、各種効果を各中間素材に持たせ、これらを混合させる、または各層に持たせ、これらを積層するようにすることができる。すなわち、本発明は、低線量放射線原石粉末を含み、無機質粉末及び/又は無機質繊維と合わせて合計60〜85重量%と熱可塑性樹脂40〜15重量%とからなり、低放射線原石粉末が無機質粉末及び/又は無機質繊維とともに熱可塑性樹脂からなるマトリックス中に均一分散してなるホルミシス複合材料層と、無機質粉末及び/又は無機質繊維60〜85重量%と熱可塑性樹脂40〜15重量%とからなり、無機質粉末及び/又は無機質繊維が熱可塑性樹脂からなるマトリックス中に均一分散してなる無機質層とを含んでなり、ホルミシス効果とその他の効果、例えば遠赤外線効果を発揮することができる岩盤浴プレートを提供するものでもある。その場合は、無機質粉末または無機質繊維が導電性カーボンからなり、電気抵抗加熱能を備える層を含むのが好ましい。   Therefore, in the present invention, various effects other than the hormesis effect, far-infrared effect, negative ion effect, and magnetic effect can coexist in one composite intermediate material or in one final plate. It can be provided in an intermediate material and mixed, or it can be provided in each layer and laminated. That is, the present invention includes a low-dose radiation rough powder, and is composed of a total of 60 to 85% by weight and a thermoplastic resin 40 to 15% by weight together with the inorganic powder and / or the inorganic fiber, and the low radiation rough powder is an inorganic powder. And / or a hormesis composite material layer uniformly dispersed in a matrix made of a thermoplastic resin together with inorganic fibers, an inorganic powder and / or inorganic fibers 60 to 85% by weight, and a thermoplastic resin 40 to 15% by weight, A bedrock bath plate comprising an inorganic layer in which inorganic powder and / or inorganic fibers are uniformly dispersed in a matrix made of a thermoplastic resin, and capable of exerting a hormesis effect and other effects, for example, a far-infrared effect. It is also something to offer. In that case, it is preferable that the inorganic powder or the inorganic fiber is made of conductive carbon and includes a layer having an electric resistance heating ability.

本発明では、上記熱可塑性樹脂は用途に応じて各種熱可塑性樹脂が選択されてよく、充填材料種類、寸法、充填量などとの関係で調整される。ホルミスト効果を発揮する岩盤浴プレートとしては耐熱性、耐水性、剛性などを考慮し、構造材料に適するPP(ポリプロピレン),PC(ポリカーボネイト)ポリアミド樹脂などを使用するのが好ましい。また、充填材料との混練性を改善する目的で、相溶する二以上の熱可塑性樹脂を配合して調整することができる。   In the present invention, as the thermoplastic resin, various thermoplastic resins may be selected according to the use, and the thermoplastic resin is adjusted in relation to the filling material type, dimensions, filling amount and the like. It is preferable to use PP (polypropylene), PC (polycarbonate) polyamide resin, etc. suitable for the structural material in consideration of heat resistance, water resistance, rigidity, etc. as the rock bath plate exhibiting the hormist effect. Moreover, in order to improve kneadability with a filling material, two or more thermoplastic resins that are compatible can be blended and adjusted.

本発明に基づいて成形される成形品は着色するのが好ましく、一種又は二種以上の着色した60〜85重量%のホルミシス原石粉末原料に対し40〜15重量%の透明又は透光性熱可塑性樹脂を混練して固化したホルミシス原石粉末強化素材の破砕片を用意し、ホルミシス原石粉末原料を着色するのが好ましい。着色したホルミシス原石粉末原料に対し同系統に着色した熱可塑性樹脂を混練して固化したホルミシス原石含有素材の破砕片を用意することも可能であり、上記破砕片が2種以上の異種の着色材料である場合もある。   The molded article molded in accordance with the present invention is preferably colored, 40 to 15 wt% transparent or translucent thermoplastic with respect to one or more colored 60 to 85 wt% hormesis rough powder raw material. It is preferable to prepare a crushed piece of a hormesis raw stone powder reinforcing material obtained by kneading and solidifying a resin, and coloring the hormesis raw stone powder raw material. It is also possible to prepare a crushed piece of a hormesis gemstone-containing material obtained by kneading and solidifying a thermoplastic resin colored in the same system with a colored hormesis gemstone powder raw material, and the crushed piece is two or more kinds of different colored materials Can be.

本発明の他の特徴は混練固化した複合素材を粉砕又は破砕し、これを成形型内にエア充填して加熱し加圧して薄いシート、やや厚いプレート状又は立体形状の複合樹脂成形品を製造するようにした点にある。充填材が水分を含有する場合は溶融したマトリックス樹脂との混練前に、他の熱源で加熱し含有水分を蒸発させるようにしてもよく、又溶融したマトリックス樹脂と複数のホルミシス原石粉末とを混練する際にホルミシス原石粉末をマトリックス樹脂の熱によって加熱してホルミシス原石粉末の含有水分を蒸発させるようにしてもよい。このようにすると、強化ホルミシス原石粉末の乾燥工程を別途必要とせず、製造工程を簡素化できる。   Another feature of the present invention is that a kneaded and solidified composite material is pulverized or crushed, filled with air in a mold, heated and pressurized to produce a thin sheet, a slightly thick plate-shaped or three-dimensional composite resin molded product. It is in the point which was made to do. If the filler contains moisture, it may be heated with another heat source to evaporate the contained moisture before kneading with the molten matrix resin, or the molten matrix resin and a plurality of hormesis rough powders are kneaded. In this case, the hormesis rough stone powder may be heated by the heat of the matrix resin to evaporate the water content of the hormesis rough stone powder. If it does in this way, the drying process of reinforced hormesis rough stone powder is not required separately, and a manufacturing process can be simplified.

使用済みのホルミシス原石粉末素材をリサイクルする場合、回収したホルミシス原石粉末素材を適当な大きさ、例えばホルミシス原石粉末の立体的形状が残存する程度の大きさ、例えば一辺が5mm〜20mmの大きさに破砕し、適当な熱源によって加熱してマトリックス樹脂を軟化又は溶融させ、必要に応じてマトリックス樹脂を添加し、ホルミシス原石粉末素材の原料の全部又は一部として用いることもできる。   When recycling a used hormesis gemstone powder material, the collected hormesis gemstone powder material has an appropriate size, for example, a size that allows the three-dimensional shape of the hormesis gemstone powder to remain, for example, a size of 5 mm to 20 mm on a side. The matrix resin can be crushed and heated by an appropriate heat source to soften or melt the matrix resin, and if necessary, the matrix resin can be added and used as all or part of the raw material of the hormesis raw stone powder material.

成形品に表面樹脂層を形成する場合、複合樹脂成形品の表面に軟化又は溶融した合成樹脂材料を重ねることにより形成してもよく、合成樹脂製のフィルム、シート又はプレートを積層することにより形成することもできる。複合樹脂成形品の表面樹脂層は複合樹脂成形品の外表面の全部に形成してもよく、外表面の一部、例えばプレート状複合樹脂成形品の上面又は下面だけに形成してもよい。   When forming a surface resin layer on a molded product, it may be formed by stacking a softened or melted synthetic resin material on the surface of a composite resin molded product, or by stacking synthetic resin films, sheets or plates. You can also The surface resin layer of the composite resin molded product may be formed on the entire outer surface of the composite resin molded product, or may be formed only on a part of the outer surface, for example, the upper surface or the lower surface of the plate-shaped composite resin molded product.

成形品は表面樹脂層を形成して所定の製品形状に加圧成形することができるが、複合樹脂成形品の表面に合成樹脂製のフィルム、シート又はプレートを積層し、あるいは軟化又は溶融した合成樹脂材料を重ねる際に、所定の製品形状に成形することもできる。この複合樹脂成形品の成形には金型やローラなどを用い、絞り成形、曲げ成形、真空成形、圧空成形、マッチモールド成形などを採用することができる。   Molded products can be molded by pressing into a predetermined product shape by forming a surface resin layer, but a synthetic resin film, sheet, or plate is laminated on the surface of a composite resin molded product, or a softened or melted synthetic material When the resin materials are stacked, they can be formed into a predetermined product shape. For molding this composite resin molded product, a die, a roller, or the like is used, and drawing molding, bending molding, vacuum molding, pressure molding, match molding, or the like can be employed.

合成樹脂製のフィルム、シート又はプレートと複合樹脂成形品とは接着剤によって接着するようにしてもよく、複合樹脂成形品のマトリックス樹脂と表面樹脂層の合成樹脂材料との親和性によって相互に結合するようにしてもよい。   The synthetic resin film, sheet or plate and the composite resin molded product may be bonded to each other by an adhesive, and bonded to each other depending on the affinity between the matrix resin of the composite resin molded product and the synthetic resin material of the surface resin layer. You may make it do.

本発明の好ましい実施形態を列挙すれば、以下通りである。   The preferred embodiments of the present invention are listed as follows.

低線量放射線原石粉末と遠赤外線放射無機質粉末及び/又は磁性粉末を含み、これらを合わせて60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した1種又は2種以上の複合素材を粉砕又は破砕して1種又は2種以上の複合中間原料を用意する工程と、該1種又は2種以上の複合中間原料を所定の成形型中に充填する工程と、成形型内に密集した1種又は2種以上の複合中間原料を加熱加圧して一体化する工程を備えるホルミシス複合材料の成形方法。これによりホルミシス効果に遠赤外線効果又は磁力線効果を併用させることができる。   1 type or 2 or more types which knead | mixed and solidified 40-15 weight% of thermoplastic resin with respect to 60-85 weight% in combination including the low-dose radiation raw powder, the far-infrared radiation inorganic powder, and / or the magnetic powder. A step of preparing one or two or more composite intermediate raw materials by crushing or crushing the composite material, a step of filling the one or two or more composite intermediate raw materials into a predetermined mold, and a mold A method for forming a hormesis composite material comprising a step of heating and pressurizing one or more composite intermediate materials densely packed therein to integrate them. Thereby, the far-infrared effect or the magnetic field effect can be used in combination with the hormesis effect.

2種以上の複合中間原料を用い、各複合中間原料が低線量放射線原石粉末を充填剤の主成分とし、充填剤60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した複合素材を粉砕又は破砕して形成したホルミシス効果複合材料と、遠赤外線放射用無機質粉末を充填剤の主成分とし、充填剤60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した複合素材を粉砕又は破砕して形成した遠赤外線放射用複合材料と、磁性材料粉末を充填剤の主成分とし、充填剤60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した複合素材を粉砕又は破砕して形成した磁性材料複合材料から選ばれ、この2種以上の組み合わせである。これにより、各種効果の最適値の組み合わせを容易にすることができる。   Two or more kinds of composite intermediate materials are used, and each composite intermediate material is mainly composed of low-dose radiation rough powder, and 40 to 15% by weight of thermoplastic resin is kneaded with 60 to 85% by weight of filler to solidify. The hormesis effect composite material formed by pulverizing or crushing the composite material and the inorganic powder for far-infrared radiation are the main components of the filler, and 40 to 15% by weight of the thermoplastic resin is kneaded with 60 to 85% by weight of the filler. The composite material for far-infrared radiation formed by pulverizing or crushing the solidified composite material and the magnetic material powder as a main component of the filler, thermoplastic resin 40 to 15% by weight with respect to 60 to 85% by weight of the filler This is a combination of two or more selected from a magnetic material composite material formed by pulverizing or crushing a composite material solidified by kneading. Thereby, the combination of the optimal value of various effects can be made easy.

複合中間材料が低線量放射線原石粉末と他の無機質粉末及び/又は有機無機繊維分とを含み、これらを合わせて60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した1種又は2種以上の複合素材を粉砕又は破砕してなる1種又は2種以上の複合中間原料であって、異なる着色を有する成形方法。これにより、人工大理石風の装飾効果を有する壁、床材にホルミシス効果を持たせることができる。   The composite intermediate material contains low-dose radiation raw powder and other inorganic powders and / or organic / inorganic fibers, and these are combined and kneaded with 40 to 15% by weight of thermoplastic resin to 60 to 85% by weight. A molding method comprising one or two or more composite intermediate materials obtained by pulverizing or crushing one or more composite materials, and having different colors. Thereby, the hormesis effect can be given to the wall and flooring which have the decoration effect of the artificial marble style.

成形型中に充填する工程では、一対の成形型に空気流とともに1種又は2種以上の複合中間原料を投入する投入口を設ける一方、成形型の他方向に空気流の排出口を設け、複合中間原料を空気流とともに成形型に投入する一方下方から排気し、成形型中で空気流下流から上流に複合中間原料を順次堆積させて充填させる成形方法。これにより各種成形の自動化が行える。   In the step of filling in the mold, a pair of molds are provided with an inlet for introducing one or more composite intermediate materials together with an air stream, while an air stream outlet is provided in the other direction of the mold, A molding method in which a composite intermediate material is introduced into a molding die together with an air flow, exhausted from below, and the composite intermediate material is sequentially deposited and filled in the molding die from downstream to upstream. Thereby, various moldings can be automated.

成形型中に充填する工程では、一対の成形型で形成される型内部を減圧し、この状態で材料投入口を開放して1種又は2種以上の複合中間原料を型内部に吸引充填させる成形方法。これにより各種成形の自動化が行える。   In the step of filling into the mold, the inside of the mold formed by the pair of molds is decompressed, and in this state, the material inlet is opened and one or more composite intermediate materials are sucked and filled into the mold. Molding method. Thereby, various moldings can be automated.

本発明によれば、自然放射の100〜10,000倍の低線量放射線原石粉末を含み、無機質粉末及び/又は有機無機繊維分と合わせて合計60〜85重量%と熱可塑性樹脂40〜15重量%とからなり、低放射線原石粉末が無機質粉末及び/又は有機無機繊維分とともに熱可塑性樹脂からなるマトリックス中に均一分散してなるホルミシス複合材料を提供することができる。   According to the present invention, the low-dose radiation raw powder is 100 to 10,000 times the natural radiation, and the total amount of the inorganic powder and / or the organic / inorganic fiber is 60 to 85% by weight and the thermoplastic resin is 40 to 15%. And a hormesis composite material in which a low radiation rough powder is uniformly dispersed in a matrix made of a thermoplastic resin together with an inorganic powder and / or an organic inorganic fiber component.

無機質粉末として水酸化アルミニウムを含み、異なる着色複合中間原料を構成し、これを用いることにより、最終製品が人工大理石板を構成することができる。   By using aluminum hydroxide as the inorganic powder and constituting different colored composite intermediate raw materials, and using this, the final product can constitute an artificial marble board.

無機質粉末が遠赤外線放射粉末または磁性粉末を含み、異なる複合中間原料をなし、最終複合材料中に点在させることにより人工大理石板にホルミシス以外に遠赤外線効果又は磁力線効果を発揮させることができる。   The inorganic powder contains far-infrared radiation powder or magnetic powder, is made of different composite intermediate materials, and is interspersed in the final composite material, so that the artificial marble plate can exhibit far-infrared effect or magnetic field effect other than hormesis.

化学繊維又は天然繊維を用い、複合材料マトリックス中に繊維方向をランダムに配交して分散させることによりシート状ホルミシス複合材料に所定のフレキシブル性能に優れた引張り強度を持たせることができる。   By using chemical fibers or natural fibers and randomly dispersing and dispersing the fiber directions in the composite material matrix, the sheet-form hormesis composite material can have a predetermined tensile strength excellent in flexible performance.

繊維分として紙パルプ成分を用いることにより、最終製品を合成紙シートとして構成することができ、壁紙等にホルミシス効果を持たせることができる。   By using a paper pulp component as a fiber component, the final product can be configured as a synthetic paper sheet, and wallpaper or the like can have a hormesis effect.

低線量放射線原石粉末と無機質粉末及び/又は無機質繊維とを合わせて60〜85重量%と熱可塑性樹脂40〜15重量%とからなり、低放射線原石粉末、無機質粉末及び無機質繊維が熱可塑性樹脂からなるマトリックス中に均一分散してなるホルミシス複合材料層と、無機質粉末及び/又は無機質繊維60〜85重量%と熱可塑性樹脂40〜15重量%とからなり、無機質粉末及び/又は無機質繊維が熱可塑性樹脂からなるマトリックス中に均一分散してなる無機質層とを含んでなる岩盤浴プレート。ホルミシス複合材料プレートと遠赤外線複合材料プレートを重ねることにより両者の相乗効果を発揮させることができる。   The low-dose radiation raw powder and the inorganic powder and / or the inorganic fiber are combined to form 60 to 85% by weight and the thermoplastic resin 40 to 15% by weight, and the low-radiation raw stone powder, the inorganic powder and the inorganic fiber are made of the thermoplastic resin. Comprising a hormesis composite material layer uniformly dispersed in a matrix, inorganic powder and / or inorganic fiber 60 to 85% by weight and thermoplastic resin 40 to 15% by weight, wherein the inorganic powder and / or inorganic fiber is thermoplastic. A bedrock bath plate comprising an inorganic layer uniformly dispersed in a resin matrix. By synthesizing the hormesis composite material plate and the far-infrared composite material plate, the synergistic effect of both can be exhibited.

無機質粉末または無機質繊維として導電性カーボンまたはグラファイトからなる粉末または線維を配合し、電気抵抗加熱性能を与えると、遠赤外線放射効果を発揮させ易くすることができる。   When a powder or fiber made of conductive carbon or graphite is blended as the inorganic powder or the inorganic fiber to give electric resistance heating performance, the far-infrared radiation effect can be easily exhibited.

以下、本発明の製造例を説明する。
(製造例1)
図1は本発明に係る再生可能なホルミシス原石粉末強化樹脂製品の製造方法の好ましい実施形態を示す。ホルミシス原石粉末強化樹脂製品を製造する場合、ホルミシス原石粉末材料を準備する。このホルミシス原石粉末はナノ粒子粉末とすることもできるが、通常、平均外径10μm〜35μmの粉状のものを用いる。また、熱可塑性樹脂、例えば適当な大きさのチップ状のポリプロピレンやポリエチレンなどの熱可塑性樹脂を準備する。これらの樹脂は1種でもよく、2種が混ざったものでもよい。
Hereafter, the manufacture example of this invention is demonstrated.
(Production Example 1)
FIG. 1 shows a preferred embodiment of a method for producing a renewable hormesis rough powder reinforced resin product according to the present invention. When producing a hormesis rough powder reinforced resin product, a hormesis rough powder material is prepared. Although this hormesis rough stone powder can also be made into a nanoparticle powder, a powdery powder having an average outer diameter of 10 μm to 35 μm is usually used. Also, a thermoplastic resin, for example, a thermoplastic resin such as chip-shaped polypropylene or polyethylene having an appropriate size is prepared. These resins may be one kind or a mixture of two kinds.

他方、混練機10の加熱ヒータを作動させ、混練機10内部を熱可塑性樹脂の溶融温度、例えば100°C〜300°Cの範囲内の温度まで上昇させておき、図1の(a)に示されるように、破砕した熱可塑性樹脂のチップを混練機10内に投入し、攪拌しながら溶融させる。バインダー樹脂のチップの投入は一度に行ってもよく、複数回に分けて行ってもよい。バインダー樹脂の溶融中に攪拌羽根の回転による溶融樹脂の攪拌によって熱が発生する場合には加熱ヒータによる加熱温度はバインダー樹脂の溶融温度よりも多少低温であってもよい。   On the other hand, the heater of the kneading machine 10 is operated, and the inside of the kneading machine 10 is raised to a melting temperature of the thermoplastic resin, for example, a temperature in the range of 100 ° C. to 300 ° C., and FIG. As shown, the crushed thermoplastic resin chips are put into the kneader 10 and melted with stirring. Binder resin chips may be charged at once, or may be divided into a plurality of times. When heat is generated by stirring the molten resin by rotation of the stirring blade during melting of the binder resin, the heating temperature by the heater may be slightly lower than the melting temperature of the binder resin.

熱可塑性樹脂が十分に軟化又は溶融すると、準備したホルミシス原石粉末原料、例えばラジウム原石粉末を一度に又は複数回に分けて混練機10内に投入するとともに、他の充填材としてカーボン粉末及び/又は繊維を一度に又は複数回に分けて混練機10内に投入し、軟化・溶融した熱可塑性樹脂とラジウム原石粉末及びカーボン粉末(30重量%:35重量%:35重量%)を実質的に均一になるように混練する。充填材は一度に大量に投入すると、軟化・溶融した樹脂の温度が低下してしまうことがあるので、混練機10への投入前にホルミシス原石粉末素材の原料を予め加熱ヒータ等で適当な温度に加熱してもよい。   When the thermoplastic resin is sufficiently softened or melted, the prepared hormesis ore powder raw material, for example, radium ore powder, is charged into the kneader 10 at one time or divided into a plurality of times, and carbon powder and / or as other fillers The fibers are put into the kneader 10 at one time or divided into several times, and the softened and melted thermoplastic resin, the raw radium powder and the carbon powder (30% by weight: 35% by weight: 35% by weight) are substantially uniform. Knead so that If a large amount of filler is added at a time, the temperature of the softened and melted resin may decrease, so the raw material of the hormesis ore powder material is preliminarily heated to a suitable temperature with a heater or the like before being added to the kneader 10. You may heat to.

また、熱可塑性樹脂を溶融状態のままで長時間加熱すると、樹脂本来の物性が損なわれることもあるので、十分に溶融した後、短時間で混練を完了させるのが好ましい。本件発明者の実験によれば、溶融してから混練が完了するまでの時間は5分〜30分程度が好ましいことが判明したが、加熱温度や熱可塑性樹脂の物性によって異なるので、最適な時間は実験などによって求めるのがよい。   Further, if the thermoplastic resin is heated for a long time in a molten state, the original physical properties of the resin may be impaired. Therefore, it is preferable to complete the kneading in a short time after sufficiently melting. According to the experiments of the present inventors, it has been found that the time from melting to completion of kneading is preferably about 5 to 30 minutes. However, the optimum time varies depending on the heating temperature and the physical properties of the thermoplastic resin. Should be obtained by experimentation.

十分な混練が済むと、図1の(b)(c)に示されるように、混練物20を取り出し、破砕機11で適切な寸法、例えば一辺が3mm〜40mmの大きさの鱗片状に破砕する。この破砕片21の寸法は後の工程における加圧によって流動させるので特に限定されないが、空気流に乗せて成形型内に充填するので空気流に浮遊しやすい形状が好ましく、堆積しても堆積物全体を空気が透過するような形態とするのが肝要である。   When sufficient kneading is completed, as shown in FIGS. 1B and 1C, the kneaded product 20 is taken out and crushed into an appropriate size by a crusher 11, for example, a scale having a side of 3 mm to 40 mm. To do. The size of the crushed piece 21 is not particularly limited because it is made to flow by pressurization in a later process, but it is preferable to have a shape that easily floats in the air flow because it is placed in the air flow and filled in the mold. It is important to make the whole air permeable.

同様にして図1の(d)に示されるように、異なる着色、例えば白色、青色、赤色、黄色の破砕片21を製造する。上記製造例では1種類の複合中間原料を用いたが、同時に第2混練機10‘を用いて異なる配合の第2複合素材20’を形成し、これを破砕した複合中間原料を混合するようにしてもよい。   Similarly, as shown in FIG. 1 (d), different colored pieces, for example, white, blue, red and yellow fragments 21 are produced. In the above production example, one type of composite intermediate material was used, but at the same time, a second composite material 20 ′ having a different composition was formed using the second kneader 10 ′, and the composite intermediate material crushed from this was mixed. May be.

こうして複数の色彩の破砕片21が得られると、これらを成形面、例えば図1の(e)に示されるように、加熱した一対の金型30、31で囲まれる金型内を排気口32から排気して減圧し、複合中間原料を上部充填口33から吸引充填し、その位置で加熱加圧する。すると、色彩の異なる熱可塑性樹脂が流動しながら相互に一体化して圧縮(圧縮比L/4〜5)されるので、温度低下後、取り出し、表面を研磨すると、図1の(f)に示されるように、表面に樹脂層41が形成された磨いた表面の模様と思えるような人工大理石模様のホルミシス製品40が得られる。   When the crushed pieces 21 having a plurality of colors are thus obtained, the exhaust ports 32 are formed in the mold surrounded by a pair of heated molds 30 and 31 as shown in FIG. 1 (e). The composite intermediate material is sucked and filled from the upper filling port 33 and heated and pressurized at that position. Then, the thermoplastic resins having different colors are integrated and compressed (compression ratio L / 4 to 5) while flowing, and when the temperature is lowered and taken out and the surface is polished, the result is shown in FIG. As a result, an artificial marble patterned hormesis product 40 that can be thought of as a polished surface pattern with the resin layer 41 formed on the surface is obtained.

本発明では空気流に乗せて破砕片を成形型内に充填することができるように成形型中に充填する工程では、成形型の上方を空気流の投入口とする一方、成形型の下方を空気流の排出口とし、空気流に対し透過性を有する複合中間原料を空気流とともに成形型に投入するとともに下方から排気し、成形型中で下方から上方に中間原料を順次堆積させて充填させる。詳しくは、例えば充填機として回転した空気流に破砕片を浮遊させ、送り出し順次堆積させるサイクロン方式を用いる場合がある。   In the present invention, in the step of filling the molding die so that the crushed pieces can be filled in the molding die by being placed on the air stream, the upper side of the molding die is used as the air flow inlet, while the lower side of the molding die is A composite intermediate material that is permeable to the air flow is introduced into the mold together with the air flow and exhausted from below, and the intermediate material is sequentially deposited from below to above in the mold to be filled. . Specifically, for example, a cyclone method may be used in which crushed pieces are suspended in a rotating air stream as a filling machine, and are sequentially sent out and accumulated.

他方、成形型内を真空にして一回成形分量の破砕片の一部又は全部を減圧吸引充填する充填する方式も有効である。   On the other hand, it is also effective to use a method in which the inside of the mold is evacuated and a part of or the whole of the crushed piece of a single molding is filled under reduced pressure.

(製造例2)
製造例1では熱可塑性樹脂に対しホルミスト原石粉末及びカーボン粉末を等量配合したが、熱可塑性樹脂30重量%に対しホルミスト原石粉末70重量%を配合した第1複合材料プレートを製造し、他方、熱可塑性樹脂30重量%に対しカーボン粉末70重量%を配合した第2複合材料プレート上に重畳し、これを接合して1枚のプレートとする以外は製造例1と同様にして岩盤浴プレートを製造する。
(Production Example 2)
In Production Example 1, an equal amount of hormist stone powder and carbon powder was blended with thermoplastic resin, but a first composite material plate was blended with 70 wt% hormist stone powder with respect to 30 wt% thermoplastic resin, A bedrock bath plate was prepared in the same manner as in Production Example 1 except that it was superposed on a second composite material plate containing 70% by weight of carbon powder with respect to 30% by weight of thermoplastic resin and joined to form a single plate. To manufacture.

(製造例3)
熱可塑性樹脂30重量%に対しホルミスト原石粉末30重量%、カーボン粉末20重量%、カーボン繊維20重量%を配合する以外は、製造例1と同様にして岩盤浴プレートを製造する。このプレートは導電性を示し、通電することにより電気抵抗加熱が可能であった。
したがって、ホルミスト効果とともに遠赤外線効果を同時に発揮させる場合には効果的である。
(Production Example 3)
A bedrock bath plate is produced in the same manner as in Production Example 1 except that 30% by weight of raw hormist stone powder, 20% by weight carbon powder, and 20% by weight carbon fiber are blended with 30% by weight thermoplastic resin. This plate was electrically conductive and could be heated by electric resistance when energized.
Therefore, it is effective when the far infrared effect is exhibited simultaneously with the hormist effect.

(製造例4)
熱可塑性樹脂30重量%に対しホルミスト原石粉末70重量%を配合した第1複合材料プレートを製造し、他方、熱可塑性樹脂30重量%に対しカーボン粉末70重量%を配合した第2複合材料プレート、熱可塑性樹脂30重量%に対しグラファイト粉末及び繊維70重量%を配合した第3複合材料プレートを製造し、これらを重畳し、これを接合して1枚のプレートとする以外は製造例1と同様にして岩盤浴プレートを製造する。第3プレートは導電性を示し、通電することにより電気抵抗加熱が可能であった。したがって、ホルミスト効果とともに遠赤外線効果を同時に発揮させる場合には効果的である。
(Production Example 4)
A first composite material plate is prepared by blending 70% by weight of hormist ore powder with respect to 30% by weight of thermoplastic resin, while a second composite material plate with 70% by weight of carbon powder blended with 30% by weight of thermoplastic resin, Similar to Production Example 1, except that a third composite material plate was prepared by blending graphite powder and 70% by weight of fiber with 30% by weight of thermoplastic resin, superposing these and joining them into one plate. To make a rock bath plate. The third plate showed electrical conductivity and could be heated by electric resistance when energized. Therefore, it is effective when the far-infrared effect is exhibited simultaneously with the hormist effect.

(製造例5)
熱可塑性樹脂30重量%に対しホルミスト原石粉末35重量%と磁性粉末35重量%を配合したホルミスト磁性複合材料プレートを製造する。磁性粉末が樹脂に対し均一に混練しやすいようにし、磁性粉末は着磁させず、ホルミスト原石粉末と先に混練し、樹脂に混練する。他方、熱可塑性樹脂30重量%に対しカーボン粉末70重量%を配合した遠赤外線効果複合材料プレート、熱可塑性樹脂30重量%に対しグラファイト粉末及び繊維70重量%を配合した導電性複合材料プレートを製造し、これらを重畳し、これを接合して1枚のプレートとする以外は製造例1と同様にして岩盤浴プレートを製造する。第3プレートは導電性を示し、通電することにより電気抵抗加熱が可能であった。したがって、ホルミスト効果とともに遠赤外線効果を同時に発揮させる場合には効果的である。
(Production Example 5)
A hormist magnetic composite material plate is prepared by blending 35% by weight of hormist ore powder and 35% by weight of magnetic powder with respect to 30% by weight of thermoplastic resin. The magnetic powder is uniformly kneaded with the resin, and the magnetic powder is not magnetized, but is first kneaded with the hormist ore powder and kneaded with the resin. On the other hand, a far-infrared effect composite material plate in which 70% by weight of carbon powder is blended with 30% by weight of thermoplastic resin, and a conductive composite material plate in which graphite powder and 70% by weight of fiber are blended with 30% by weight of thermoplastic resin are manufactured. Then, a bedrock bath plate is produced in the same manner as in Production Example 1 except that these are superposed and joined to form one plate. The third plate showed electrical conductivity and could be heated by electric resistance when energized. Therefore, it is effective when the far infrared effect is exhibited simultaneously with the hormist effect.

本発明に係るホルミシス原石粉末強化樹脂成形品の製造方法の第1実施形態を模式的に示す図である。BRIEF DESCRIPTION OF THE DRAWINGS It is a figure which shows typically 1st Embodiment of the manufacturing method of the hormesis raw stone powder reinforced resin molding which concerns on this invention.

符号の説明Explanation of symbols

10、10‘ 混練機
11 破砕機
20、20‘ 複合素材
21 破砕片
30、31 金型
40 複合材製品
10, 10 'kneading machine 11 crusher 20, 20' composite material 21 shredded piece 30, 31 mold 40 composite material product

Claims (13)

低線量放射線原石粉末と他の無機質粉末及び/又は有機無機繊維分とを含み、これらを合わせて60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した1種又は2種以上の複合素材を粉砕又は破砕して1種又は2種以上の複合中間原料を用意する工程と、該1種又は2種以上の複合中間原料を所定の成形型中に充填する工程と、成形型内に密集した1種又は2種以上の複合中間原料を加熱加圧して一体化する工程を備えることを特徴とするホルミシス複合材料の成形方法。   1 type or 2 which knead | mixed and solidified 40-15 weight% of thermoplastic resins with respect to 60-85 weight% combining these low-dose radiation raw stone powder and other inorganic powder and / or organic inorganic fiber part A step of pulverizing or crushing one or more composite materials to prepare one or more composite intermediate materials, a step of filling the one or more composite intermediate materials in a predetermined mold, and A method for forming a hormesis composite material, comprising a step of heating and pressurizing and integrating one or more composite intermediate materials densely packed in a mold. 複合中間原料の1種が低線量放射線原石粉末と遠赤外線放射無機質粉末及び/又は磁性粉末を含む請求項1記載の成形方法。   The shaping | molding method of Claim 1 in which 1 type of a composite intermediate raw material contains a low-dose radiation raw stone powder, a far-infrared radiation inorganic powder, and / or a magnetic powder. 複合中間原料の2種以上が少なくとも低線量放射線原石粉末を充填剤の主成分とし、充填剤60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した複合素材を粉砕又は破砕して形成したホルミシス効果複合材料と、遠赤外線放射用無機質粉末を充填剤の主成分とし、充填剤60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した複合素材を粉砕又は破砕して形成した遠赤外線放射用複合材料と、磁性材料粉末を充填剤の主成分とし、充填剤60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した複合素材を粉砕又は破砕して形成した磁性材料複合材料の2種以上の組み合わせからある請求項1記載の成形方法。   Two or more of the composite intermediate raw materials have at least a low-dose radiation raw powder as a main component of the filler, and a composite material obtained by kneading and solidifying 40 to 15% by weight of a thermoplastic resin with respect to 60 to 85% by weight of the filler is ground or A composite material obtained by crushing and forming a hormesis effect composite material and a far infrared radiation inorganic powder as a main component of a filler, and kneading 40 to 15% by weight of a thermoplastic resin with respect to 60 to 85% by weight of the filler. The composite material for far-infrared radiation formed by pulverizing or crushing the powder and the magnetic material powder as the main component of the filler, kneading and solidifying 40 to 15 wt% of the thermoplastic resin to 60 to 85 wt% of the filler 2. The molding method according to claim 1, wherein the molding method is a combination of two or more magnetic material composite materials formed by pulverizing or crushing the composite material. 複合中間材料が低線量放射線原石粉末と他の無機質粉末及び/又は有機無機繊維分とを含み、これらを合わせて60〜85重量%に対し熱可塑性樹脂40〜15重量%を混練して固化した1種又は2種以上の複合素材を粉砕又は破砕してなる1種又は2種以上の複合中間原料であって、異なる着色を有する請求項1記載の成形方法。   The composite intermediate material contains low-dose radiation raw powder and other inorganic powders and / or organic / inorganic fibers, and these are combined and kneaded with 40 to 15% by weight of thermoplastic resin to 60 to 85% by weight. The shaping | molding method of Claim 1 which is 1 type, or 2 or more types of composite intermediate materials formed by grind | pulverizing or crushing 1 type, or 2 or more types of composite materials, and has different coloring. 成形型中に充填する工程では、一対の成形型に空気流とともに1種又は2種以上の複合中間原料を投入する投入口を設ける一方、成形型の他方向に空気流の排出口を設け、複合中間原料を空気流とともに成形型に投入する一方下方から排気し、成形型中で空気流下流から上流に複合中間原料を順次堆積させて充填させる請求項1記載のホルミシス複合材料の成形方法。   In the step of filling in the mold, a pair of molds are provided with an inlet for introducing one or more composite intermediate materials together with an air stream, while an air stream outlet is provided in the other direction of the mold, 2. The method of forming a hormesis composite material according to claim 1, wherein the composite intermediate material is charged together with the air flow into the forming die and exhausted from below, and the composite intermediate material is sequentially deposited and filled in the forming die from downstream to upstream of the air flow. 成形型中に充填する工程では、一対の成形型で形成される型内部を減圧し、この状態で材料投入口を開放して1種又は2種以上の複合中間原料を型内部に吸引充填させる請求項1記載のホルミシス複合材料の成形方法。   In the step of filling into the mold, the inside of the mold formed by the pair of molds is decompressed, and in this state, the material inlet is opened and one or more composite intermediate materials are sucked and filled into the mold. A method for forming a hormesis composite material according to claim 1. 自然放射の100〜10,000倍の低線量放射線原石粉末を含み、無機質粉末及び/又は有機無機繊維分と合わせて合計60〜85重量%と熱可塑性樹脂40〜15重量%とからなり、低放射線原石粉末が無機質粉末及び/又は有機無機繊維分とともに熱可塑性樹脂からなるマトリックス中に均一分散してなるホルミシス複合材料。   It contains low-dose radiation raw powder 100 to 10,000 times that of natural radiation, and is composed of a total of 60 to 85% by weight together with inorganic powder and / or organic / inorganic fibers, and 40 to 15% by weight of thermoplastic resin. A hormesis composite material in which a raw radiation powder is uniformly dispersed in a matrix made of a thermoplastic resin together with an inorganic powder and / or organic inorganic fibers. 無機質粉末が水酸化アルミニウムを含み、異なる着色複合中間原料をなし、最終製品が人工大理石板を構成する請求項7記載の複合材料。   8. The composite material according to claim 7, wherein the inorganic powder contains aluminum hydroxide, forms different colored composite intermediate materials, and the final product constitutes an artificial marble board. 無機質粉末が遠赤外線放射粉末または磁性粉末を含み、異なる複合中間原料をなし、最終複合材料中に点在する請求項7記載のホルミシス複合材料。   The hormesis composite material according to claim 7, wherein the inorganic powder includes far-infrared radiation powder or magnetic powder, forms a different composite intermediate material, and is scattered in the final composite material. 有機無機繊維分が化学繊維又は天然繊維であって、複合材料マトリックス中に繊維方向をランダムに配交して分散してなる請求項7記載のホルミシス複合材料。   The hormesis composite material according to claim 7, wherein the organic / inorganic fiber component is a chemical fiber or a natural fiber, and is dispersed in the composite material matrix by randomly crossing the fiber directions. 繊維分が紙パルプ成分から成り、最終製品が合成紙シートを構成する請求項7記載のホルミシス複合材料。   The hormesis composite material according to claim 7, wherein the fiber component comprises a paper pulp component and the final product constitutes a synthetic paper sheet. 低線量放射線原石粉末と無機質粉末及び/又は無機質繊維とを合わせて60〜85重量%と熱可塑性樹脂40〜15重量%とからなり、低放射線原石粉末、無機質粉末及び無機質繊維が熱可塑性樹脂からなるマトリックス中に均一分散してなるホルミシス複合材料層と、無機質粉末及び/又は無機質繊維60〜85重量%と熱可塑性樹脂40〜15重量%とからなり、無機質粉末及び/又は無機質繊維が熱可塑性樹脂からなるマトリックス中に均一分散してなる無機質層とを含んでなる岩盤浴プレート。   The low-dose radiation raw powder and the inorganic powder and / or the inorganic fiber are combined to form 60 to 85% by weight and the thermoplastic resin 40 to 15% by weight, and the low-radiation raw stone powder, the inorganic powder and the inorganic fiber are made of the thermoplastic resin. Comprising a hormesis composite material layer uniformly dispersed in a matrix, inorganic powder and / or inorganic fiber 60 to 85% by weight and thermoplastic resin 40 to 15% by weight, wherein the inorganic powder and / or inorganic fiber is thermoplastic. A bedrock bath plate comprising an inorganic layer uniformly dispersed in a resin matrix. 無機質粉末または無機質繊維が導電性カーボンまたはグラファイトからなり、電気抵抗加熱性能を備え、遠赤外線放射効果を有する請求項7記載の岩盤浴プレート。   The bedrock bath plate according to claim 7, wherein the inorganic powder or the inorganic fiber is made of conductive carbon or graphite, has an electric resistance heating performance, and has a far infrared radiation effect.
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JPS6321200A (en) * 1986-07-14 1988-01-28 筒中プラスチツク工業株式会社 Manufacture of patterned synthetic resin material
JPH01286944A (en) * 1988-05-11 1989-11-17 Tsutsunaka Plast Ind Co Ltd Granite-tone thermoplastic resin molded article
JP2004331475A (en) * 2003-05-12 2004-11-25 Yamaha Livingtec Corp Artificial marble

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* Cited by examiner, † Cited by third party
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JP2013189406A (en) * 2012-03-14 2013-09-26 Hot House:Kk Thorium-containing molding having hormesis effect, production method therefor and pellet for attachment
JP2015193133A (en) * 2014-03-31 2015-11-05 久慈琥珀株式会社 Reproduction method of amber, and reproduced amber

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JP2009012441A (en) 2009-01-22
CN101318382A (en) 2008-12-10

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