CN107571519A - A kind of preparation method of brilliant modeling fluorescent plate and brilliant modeling fluorescent plate - Google Patents
A kind of preparation method of brilliant modeling fluorescent plate and brilliant modeling fluorescent plate Download PDFInfo
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- CN107571519A CN107571519A CN201710780916.7A CN201710780916A CN107571519A CN 107571519 A CN107571519 A CN 107571519A CN 201710780916 A CN201710780916 A CN 201710780916A CN 107571519 A CN107571519 A CN 107571519A
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Abstract
The invention provides the preparation method of a kind of brilliant modeling fluorescent plate and brilliant modeling fluorescent plate; this method is stirred proportionally to add flyash, waste or used plastics and additive in high-speed mixer; after add mixture into comminutor; it is granulated; and squeezed into by extruder in mould; brilliant mould plate is made; being positioned on the word or pattern prepared in brilliant mould plate; after fluorescer, binding agent and lytic agent are mixed; pave in the brilliant mould plate prepared; back and forth rolled using hot-pressing roller, word or the brilliant modeling fluorescent plate of clear patterns is made.The preparation method of brilliant modeling fluorescent plate of the present invention, the brilliant modeling fluorescent plate stability prepared is high, beautiful in colour, landscape is strong, pollution-free, environmental protection and energy saving, it is practical the advantages that.
Description
Technical field
The invention belongs to family's ornament preparing technical field, and fluorescent plate is moulded more particularly, to a kind of brilliant modeling fluorescent plate and crystalline substance
Preparation method.
Background technology
Luminescent material has become the backing material in the fields such as presentation of information, lighting source, is society by development for many years
The development and progress of meeting plays the present of the effect to become more and more important, particularly energy scarcity, and exploitation converts efficient fluorescence
Material, it is to solve the problems, such as one of main method of energy scarcity.
Brilliant plastic composite product possesses the two-fold advantage of marble and plastics, and brilliant plastic composite section bar can be reclaimed absolutely
Regeneration, is " green " industrial product truly, and a kind of preferable alternative materials of timber.Landscape industry out of doors, when
High-quality woodwork or marble are increasingly favored by people, and the speed and the transition development rate in mine that forest disappears are also more next
It is faster.Therefore from the point of view of environmental angle, timber resources comprehensive utilization angle, there are powerful advantages using brilliant plastic composite section bar
New application direction.
On the basis of brilliant mould plate, exploitation one kind both has aesthetic property, and the ornament that and can is luminous, is using people
While brilliant mould plate is as daytime and night landscape ornaments, it is further without consuming other energy consumptions such as electric energy.
The content of the invention
In view of this, the present invention is directed to propose a kind of brilliant modeling fluorescent plate and crystalline substance mould the preparation method of fluorescent plate, with solution never
While needing to consume other energy consumptions such as electric energy, day and night landscape ornaments are also used as.
To reach above-mentioned purpose, the technical proposal of the invention is realized in this way：
A kind of preparation method of brilliant modeling fluorescent plate, it comprises the following steps：
Flyash, waste or used plastics and additive are mixed, after heating stirring, compound cooled down；
The compound of cooling is carried out by plasticizing granulation using plasticizing prilling, and uses cutting technique by the granulation of plasticizing
Particle is cut into, the extruded technique of particle is extruded, is cooled and shaped, brilliant mould plate is made；
Prefabricated graph block is positioned in brilliant mould plate, after fluorescer, binding agent and lytic agent are mixed evenly, applied
It is distributed in brilliant mould plate, forms fluorescence coating, fluorescence coating is pressed in brilliant mould plate using heat pressing process, obtains brilliant modeling fluorescent plate.
Preferably, the fluorescer is that silicate fluorescent powder, nitride and nitric oxide fluorescent powder or carbuncle type aoxidize
At least one of matter fluorescent powder, the trowel adhesive are the cruel adhesive of acrylic acid fourth, polyethylene glycol oxide, carboxymethyl cellulose
At least one of ammonium or ammonium polymethacrylate, the lytic agent are benzoic acid.
Preferably, the waste or used plastics are at least one of PP, PE and polyvinyl chloride resin.
Preferably, the fluorescent layer thickness is 0.5-3mm.
Preferably, the flyash particle diameter is 50 μm -100 μm.
Preferably, the figure on the graph block is prepared using computer, and the figure includes word or pattern, through hot pressing work
After skill, in the half embedded brilliant mould plate of the graph block.
Preferably, the particle diameter of the fluorescer particle is≤50 μm.
Preferably, in the heat pressing process, using pressure roller to the fluorescence coating hot pressing, roller temperature is 100-240 DEG C, pressure
It is 15-25MPA that roller, which applies pressure,.
Preferably, the particle extrusion temperature in the expressing technique is 150-200 DEG C.
Preferably, it is made by the brilliant preparation method for moulding fluorescent plate as described in any in claim 1-9, the brilliant modeling fluorescence
Plate is upper and lower double-layer structure, and its upper strata is fluorescence coating, and its lower floor is brilliant mould plate layer, and the fluorescence coating fusion is adhered to the brilliant modeling
On the whole face of flaggy.
Relative to prior art, the preparation method of brilliant modeling fluorescent plate of the present invention has the advantage that：
(1) the brilliant modeling fluorescent plate prepared by the present invention, carries out hot pressing, fluorescence coating is with putting using heat pressing process to fluorescence coating
The brilliant mould plate for being equipped with graph block mutually combines together so that brilliant mould plate surface has each a variety of luminous patterns, is made a plate without carving
Etc. other techniques.
(2) this product utilizes industrial waste, the brilliant mould plate basic unit being made, for contained plastic heating in brilliant mould plate material
The characteristics of softening, the material prescription of fluorescer and cosolvent is added, be allowed to effectively combine between each other, this technological applicability
By force, it is readily produced, the advantages that added value of product is high.
Brief description of the drawings
The accompanying drawing for forming the part of the present invention is used for providing a further understanding of the present invention, schematic reality of the invention
Apply example and its illustrate to be used to explain the present invention, do not form inappropriate limitation of the present invention.In the accompanying drawings：
Fig. 1 is the preparation method flow chart of the brilliant modeling fluorescent plate described in the embodiment of the present invention one；
Fig. 2 is the structural representation of brilliant modeling fluorescent plate described in the embodiment of the present invention one；
Fig. 3 is the preparation method flow chart of brilliant modeling fluorescent plate described in the embodiment of the present invention two；
Fig. 4 is the preparation method flow chart of brilliant modeling fluorescent plate described in the embodiment of the present invention three；
Description of reference numerals
1- crystalline substance mould plates；2- fluorescence coatings.
Embodiment
In addition to being defined, technical term used has universal with those skilled in the art of the invention in following examples
The identical meanings of understanding.Test reagent used, is routine biochemistry reagent unless otherwise specified in following examples；It is described
Experimental method, it is conventional method unless otherwise specified.
The present invention is described in detail with reference to embodiment.
Specific embodiment 1
As shown in figure 1, a kind of preparation method of brilliant modeling fluorescent plate, it comprises the following steps：
S1:Flyash, PP resins and additive are mixed, after heating stirring, compound cooled down；
S2:The compound of cooling is carried out by plasticizing granulation using plasticizing prilling, and uses cutting technique by plasticizing
Granulation cuts into particle, and the extruded technique of particle is extruded, is cooled and shaped, brilliant mould plate is made；
S3:Prefabricated graph block is positioned in brilliant mould plate, by silicate fluorescent powder, the cruel adhesive of acrylic acid fourth and benzene first
After acid is mixed evenly, it is coated in brilliant mould plate, forms fluorescence coating, fluorescence coating is pressed on by brilliant mould plate using heat pressing process
On, obtain brilliant modeling fluorescent plate.
Figure on the graph block is prepared using computer, and the figure includes word or pattern, after heat pressing process, one
Half immerses base material, and half, which, invests surface.
As shown in Fig. 2 by brilliant modeling fluorescent plate made from the brilliant preparation method for moulding fluorescent plate, it is divided into two layers of knot up and down
Structure, its upper strata are fluorescence coating, and its lower floor is brilliant mould plate layer, and the fluorescence coating fusion is adhered on the whole face of the brilliant mould plate layer.
In plasticizing prilling, add mixture into comminutor and be granulated, after plasticizing is granulated, the coarse granule prepared is put
Enter pelleter to be cut, coarse granule is cut into tiny particle, is put into extruder, make material by heating, pressurizeing
It is squeezed on corresponding mould with flow regime, in the heat pressing process, fluorescence coating is attached in brilliant mould plate using hot press,
Fluorescence coating is back and forth rolled using the hot pressing rolling on hot press.
Described batch mixer selects the happy high-speed mixer of machinery equipment Co., Ltd 500/1000 in Zhangjiagang, the granulation
Machine is had from Changzhou Yuan Sheng Machinery Co., Ltd.s production 75B comminutors, the extruder from the happy machinery equipment in Zhangjiagang
The brilliant material extruder of limit company 65/132, the hot press select 400 hot presses of skill steel seal pressure roller factory of Changzhou section production.
Preparing the thickness of fluorescence coating in the brilliant modeling fluorescent plate of gained can be set according to customer demand, preferable fluorescence
Thickness degree is 0.5-3mm, and the flyash particle diameter of the flyash is 50 μm -100 μm, and the fluorescent material is that particle diameter is≤50 μm,
In the heat pressing process, temperature that hot-pressing roller rolls is set as 150 DEG C, and application pressure is 18MPa, in the expressing technique
Particle extrusion temperature is 180 DEG C.
In the present embodiment, brilliant mould plate is produced using dead meal, has the two-fold advantage of marble and plastics, and after use,
Also recyclable recycling, when brilliant mould plate is as basic unit, surface adhesion fluorescence coating is after the heating, useless due to having in brilliant mould plate
Abandon plastics, plastic melt, can be very good to be combined with fluorescent material, the trowel adhesive of addition simply played before being ground for roller by
Fluorescent material is bonded in the effect in brilliant mould plate, and after rolling, fluorescence coating is combined the effect not by adhesive with brilliant mould plate,
But the plastics of thawing are combined with fluorescent material, are combined together, bonded compared to by adhesive bond, fluorescence coating with brilliant mould plate
Effect it is more preferable, fluorescence coating will not fall off, crystalline substance modeling fluorescent plate weatherability it is strong, it is non-aging.
Specific embodiment 2
The preparation method of brilliant modeling fluorescent plate and brilliant modeling fluorescent plate in the present embodiment is the improvement on the basis of embodiment one,
Technology contents not repeated description disclosed in embodiment one, the disclosure of embodiment one are fallen within disclosed in the present embodiment
Hold.
As shown in figure 3, brilliant modeling fluorescent plate preparation method is as follows：
S1:Flyash, PE resins and additive are mixed, after heating stirring, compound cooled down；
S2:The compound of cooling is carried out by plasticizing granulation using plasticizing prilling, and uses cutting technique by plasticizing
Granulation cuts into particle, and the extruded technique of particle is extruded, is cooled and shaped, brilliant mould plate is made；
S3:Prefabricated graph block is positioned in brilliant mould plate, by nitride and nitric oxide fluorescent powder, polyethylene glycol oxide and
After benzoic acid is mixed evenly, it is coated in brilliant mould plate, forms fluorescence coating, fluorescence coating is pressed on by brilliant modeling using heat pressing process
On plate, brilliant modeling fluorescent plate is obtained.
Figure on the graph block is prepared using computer, and the figure can prepare word or figure according to customer demand
Case, after heat pressing process, half immerses base material, and half, which, invests surface.
Preparing the thickness of fluorescence coating in the brilliant modeling fluorescent plate of gained can be set according to customer demand, preferable fluorescence
Thickness degree is 0.5-3mm, and the flyash particle diameter of selected flyash is 50 μm -100 μm, and selected fluorescent material is nanometer
Fluorescent material, the particle diameter of fluorescer particle is≤50 μm, is set as 180 DEG C in the temperature that hot-pressing roller rolls, and applies pressure and is
25MPa.The brilliant modeling fluorescent plate prepared, the word or pattern of attachment, half immerse base material, and half, which, invests surface.
Preparing the thickness of fluorescence coating in the brilliant modeling fluorescent plate of gained can be set according to customer demand, preferable fluorescence
Thickness degree is 0.5-3mm, and the flyash particle diameter of selected flyash is 50 μm -100 μm, and selected fluorescent material is nanometer
Fluorescent material, the particle diameter of fluorescer particle is≤50 μm, is set as 150 DEG C in the temperature that hot-pressing roller rolls, and applies pressure and is
18MPa.The brilliant modeling fluorescent plate prepared, the word or pattern of attachment, half immerse base material, and half, which, invests surface.
Described batch mixer selects the happy high-speed mixer of machinery equipment Co., Ltd 500/1000 in Zhangjiagang, the granulation
Machine is had from Changzhou Yuan Sheng Machinery Co., Ltd.s production 75B comminutors, the extruder from the happy machinery equipment in Zhangjiagang
The brilliant material extruder of limit company 65/132, the hot press select 400 hot presses of skill steel seal pressure roller factory of Changzhou section production.
In the present embodiment, the crystalline substance being prepared moulds fluorescent plate, with the fluorescer of brilliant moulding material adsorption, by daytime
Day irradiation or the light-illuminating in evening are allowed to absorb, and then discharge, and form reflection, and reach landscape, the purpose of energy-conservation, it
Have the advantages that production stability is high, beautiful in colour, landscape is strong, pollution-free, environmental protection and energy saving, practical.
Specific embodiment 3
The preparation method of brilliant modeling fluorescent plate and brilliant modeling fluorescent plate in the present embodiment is the improvement on the basis of embodiment one,
Technology contents not repeated description disclosed in embodiment one, the disclosure of embodiment one are fallen within disclosed in the present embodiment
Hold.
As shown in figure 4, brilliant modeling fluorescent plate preparation method is as follows：
S1:Flyash, polyvinyl chloride resin and additive are mixed, after heating stirring, compound cooled down；
S2:The compound of cooling is carried out by plasticizing granulation using plasticizing prilling, and uses cutting technique by plasticizing
Granulation cuts into particle, and the extruded technique of particle is extruded, is cooled and shaped, brilliant mould plate is made；
S3:Prefabricated graph block is positioned in brilliant mould plate, by silicate fluorescent powder, the cruel adhesive of acrylic acid fourth and benzene first
After acid is mixed evenly, it is coated in brilliant mould plate, forms fluorescence coating, fluorescence coating is pressed on by brilliant mould plate using heat pressing process
On, obtain brilliant modeling fluorescent plate.
Figure on the graph block is prepared using computer, and the figure includes word or pattern, after heat pressing process, one
Half immerses base material, and half, which, invests surface.
In plasticizing prilling, add mixture into comminutor and be granulated, after plasticizing is granulated, the coarse granule prepared is put
Enter pelleter to be cut, coarse granule is cut into tiny particle, is put into extruder, make material by heating, pressurizeing
It is squeezed on corresponding mould with flow regime, in the heat pressing process, fluorescence coating is attached in brilliant mould plate using hot press,
Fluorescence coating is back and forth rolled using the hot pressing rolling on hot press.
Described batch mixer selects the happy high-speed mixer of machinery equipment Co., Ltd 500/1000 in Zhangjiagang, the granulation
Machine is had from Changzhou Yuan Sheng Machinery Co., Ltd.s production 75B comminutors, the extruder from the happy machinery equipment in Zhangjiagang
The brilliant material extruder of limit company 65/132, the hot press select 400 hot presses of skill steel seal pressure roller factory of Changzhou section production.
Preparing the thickness of fluorescence coating in the brilliant modeling fluorescent plate of gained can be set according to customer demand, preferable fluorescence
Thickness degree is 0.5-3mm, and the flyash particle diameter of selected flyash is 50 μm -100 μm, and selected fluorescent material is nanometer
Fluorescent material, the particle diameter of fluorescer particle is≤50 μm, is set as 150 DEG C in the temperature that hot-pressing roller rolls, and applies pressure and is
18MPa.The brilliant modeling fluorescent plate prepared, the word or pattern of attachment, half immerse base material, and half, which, invests surface.
In the present embodiment, the crystalline substance being prepared moulds fluorescent plate, and fluorescer on brilliant plastic clad plate, produces phase by heating
The various surface light emitting patterns mutually to combine together, without carving other techniques such as plate-making, stability is high, beautiful in colour, landscape
By force, pollution-free, environmental protection and energy saving, it is practical the advantages that.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all essences in the present invention
God any modification, equivalent substitution and improvements made etc., should be included in the scope of the protection with principle.
Claims (10)
- A kind of 1. preparation method of brilliant modeling fluorescent plate, it is characterised in that：It comprises the following steps：Flyash, waste or used plastics and additive are mixed, after heating stirring, compound cooled down；The compound of cooling is carried out by plasticizing granulation using plasticizing prilling, and cut the granulation of plasticizing using cutting technique Into particle, the extruded technique of particle is extruded, is cooled and shaped, brilliant mould plate is made；Prefabricated graph block is positioned in brilliant mould plate, after fluorescer, binding agent and lytic agent are mixed evenly, is coated on In brilliant mould plate, fluorescence coating is formed, fluorescence coating is pressed in brilliant mould plate using heat pressing process, obtain brilliant modeling fluorescent plate.
- 2. the preparation method of brilliant modeling fluorescent plate according to claim 1, it is characterised in that：The fluorescer is that silicate is glimmering At least one of light powder, nitride and nitric oxide fluorescent powder or carbuncle type oxide fluorescent powder, the trowel adhesive It is described molten at least one of the cruel adhesive of acrylic acid fourth, polyethylene glycol oxide, carboxymethyl cellulose ammonium or ammonium polymethacrylate Solution agent is benzoic acid.
- 3. the preparation method of brilliant modeling fluorescent plate according to claim 2, it is characterised in that：The waste or used plastics are PP, PE At least one of with polyvinyl chloride resin.
- 4. the preparation method of brilliant modeling fluorescent plate according to claim 3, it is characterised in that：The fluorescent layer thickness is 0.5- 3mm。
- 5. the preparation method of brilliant modeling fluorescent plate according to claim 4, it is characterised in that：The flyash particle diameter is 50 μ m-100μm。
- 6. the preparation method of brilliant modeling fluorescent plate according to claim 5, it is characterised in that：Figure on the graph block is adopted Prepared with computer, the figure includes word or pattern, after heat pressing process, in the half embedded brilliant mould plate of the graph block.
- 7. the preparation method of brilliant modeling fluorescent plate according to claim 6, it is characterised in that：The particle diameter of the fluorescer particle For≤50 μm.
- 8. the preparation method of brilliant modeling fluorescent plate according to claim 7, it is characterised in that：In the heat pressing process, use Pressure roller is to the fluorescence coating hot pressing, and roller temperature is 100-240 DEG C, and it is 15-25MPA that pressure roller, which applies pressure,.
- 9. the preparation method of brilliant modeling fluorescent plate according to claim 8, it is characterised in that：Particle in the expressing technique Extrusion temperature is 150-200 DEG C.
- A kind of 10. brilliant modeling fluorescent plate, it is characterised in that：By the preparation side of the brilliant modeling fluorescent plate as described in any in claim 1-9 Method is made, and the brilliant modeling fluorescent plate is upper and lower double-layer structure, and its upper strata is fluorescence coating, and its lower floor is brilliant mould plate layer, the fluorescence Layer fusion is adhered on the whole face of the brilliant mould plate layer.
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| CN201710780916.7A CN107571519A (en) | 2017-09-01 | 2017-09-01 | A kind of preparation method of brilliant modeling fluorescent plate and brilliant modeling fluorescent plate |
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| CN201710780916.7A CN107571519A (en) | 2017-09-01 | 2017-09-01 | A kind of preparation method of brilliant modeling fluorescent plate and brilliant modeling fluorescent plate |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111807760A (en) * | 2020-06-30 | 2020-10-23 | 安徽创能环保材料有限公司 | Preparation process of desulfurized gypsum-based crystal plastic composite material |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2486316Y (en) * | 2001-07-06 | 2002-04-17 | 戴均和 | Plate material capable of emitting long after-glow noctilucent |
| CN101817987A (en) * | 2010-03-26 | 2010-09-01 | 王振宇 | Silicon-plastic composite cylindrical particles prepared from power plant waste and method for preparing plastic plate thereof |
-
2017
- 2017-09-01 CN CN201710780916.7A patent/CN107571519A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2486316Y (en) * | 2001-07-06 | 2002-04-17 | 戴均和 | Plate material capable of emitting long after-glow noctilucent |
| CN101817987A (en) * | 2010-03-26 | 2010-09-01 | 王振宇 | Silicon-plastic composite cylindrical particles prepared from power plant waste and method for preparing plastic plate thereof |
Non-Patent Citations (1)
| Title |
|---|
| 潘裕柏 等: "《稀土陶瓷材料》", 31 May 2016, 冶金工业出版社 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111807760A (en) * | 2020-06-30 | 2020-10-23 | 安徽创能环保材料有限公司 | Preparation process of desulfurized gypsum-based crystal plastic composite material |
| CN111807760B (en) * | 2020-06-30 | 2022-03-25 | 安徽创能环保材料有限公司 | Preparation process of desulfurized gypsum-based crystal plastic composite material |
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Application publication date: 20180112 |
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