TW200523306A - Thermal stabilizer composition for halogen-containing vinyl polymers - Google Patents
Thermal stabilizer composition for halogen-containing vinyl polymers Download PDFInfo
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- TW200523306A TW200523306A TW093133957A TW93133957A TW200523306A TW 200523306 A TW200523306 A TW 200523306A TW 093133957 A TW093133957 A TW 093133957A TW 93133957 A TW93133957 A TW 93133957A TW 200523306 A TW200523306 A TW 200523306A
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- polymer
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- 239000000203 mixture Substances 0.000 title claims abstract description 71
- 229920002554 vinyl polymer Polymers 0.000 title claims abstract description 32
- 229910052736 halogen Inorganic materials 0.000 title claims abstract description 24
- 150000002367 halogens Chemical class 0.000 title claims abstract description 24
- 239000003017 thermal stabilizer Substances 0.000 title 1
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 25
- 239000011701 zinc Substances 0.000 claims abstract description 20
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 19
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 150000003751 zinc Chemical class 0.000 claims abstract description 17
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 claims abstract 2
- -1 zinc carboxylate Chemical class 0.000 claims description 44
- 229920000642 polymer Polymers 0.000 claims description 33
- 150000003573 thiols Chemical class 0.000 claims description 26
- 239000002253 acid Substances 0.000 claims description 21
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 14
- 239000005977 Ethylene Substances 0.000 claims description 14
- 229910052751 metal Inorganic materials 0.000 claims description 13
- 239000002184 metal Substances 0.000 claims description 13
- 125000000217 alkyl group Chemical group 0.000 claims description 12
- 150000002148 esters Chemical class 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 12
- 230000006641 stabilisation Effects 0.000 claims description 12
- 238000011105 stabilization Methods 0.000 claims description 12
- 239000000945 filler Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- 230000000087 stabilizing effect Effects 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- FPRWILGFWFTOHA-UHFFFAOYSA-N 2-sulfanylethyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCS FPRWILGFWFTOHA-UHFFFAOYSA-N 0.000 claims description 2
- 229920006280 packaging film Polymers 0.000 claims description 2
- 239000012785 packaging film Substances 0.000 claims description 2
- 229920006395 saturated elastomer Polymers 0.000 claims description 2
- 229940071127 thioglycolate Drugs 0.000 claims description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-M thioglycolate(1-) Chemical compound [O-]C(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-M 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- OWHSTLLOZWTNTQ-UHFFFAOYSA-N 2-ethylhexyl 2-sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS OWHSTLLOZWTNTQ-UHFFFAOYSA-N 0.000 claims 1
- 229920005601 base polymer Polymers 0.000 claims 1
- XRYLGRGAWQSVQW-UHFFFAOYSA-N clorotepine Chemical compound C1CN(C)CCN1C1C2=CC(Cl)=CC=C2SC2=CC=CC=C2C1 XRYLGRGAWQSVQW-UHFFFAOYSA-N 0.000 claims 1
- 150000002085 enols Chemical class 0.000 claims 1
- 150000004702 methyl esters Chemical class 0.000 claims 1
- YMTQMTSQMKJKPX-UHFFFAOYSA-L zinc;diphenoxide Chemical compound [Zn+2].[O-]C1=CC=CC=C1.[O-]C1=CC=CC=C1 YMTQMTSQMKJKPX-UHFFFAOYSA-L 0.000 claims 1
- PZRXQXJGIQEYOG-UHFFFAOYSA-N zinc;oxido(oxo)borane Chemical group [Zn+2].[O-]B=O.[O-]B=O PZRXQXJGIQEYOG-UHFFFAOYSA-N 0.000 claims 1
- 239000003381 stabilizer Substances 0.000 abstract description 27
- 238000006731 degradation reaction Methods 0.000 abstract description 4
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 238000002845 discoloration Methods 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 description 23
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 12
- 239000000052 vinegar Substances 0.000 description 10
- 235000021419 vinegar Nutrition 0.000 description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 6
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 6
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 6
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 6
- 239000004014 plasticizer Substances 0.000 description 6
- 239000004800 polyvinyl chloride Substances 0.000 description 6
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 6
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- 239000000654 additive Substances 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 235000014113 dietary fatty acids Nutrition 0.000 description 5
- 239000000194 fatty acid Substances 0.000 description 5
- 229930195729 fatty acid Natural products 0.000 description 5
- 239000007789 gas Substances 0.000 description 5
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 5
- 229920000915 polyvinyl chloride Polymers 0.000 description 5
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 235000011054 acetic acid Nutrition 0.000 description 4
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 4
- 239000003963 antioxidant agent Substances 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000000314 lubricant Substances 0.000 description 4
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 description 4
- 239000000049 pigment Substances 0.000 description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 3
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 150000007513 acids Chemical class 0.000 description 3
- 125000005907 alkyl ester group Chemical group 0.000 description 3
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 3
- 239000011575 calcium Substances 0.000 description 3
- 229910052791 calcium Inorganic materials 0.000 description 3
- 150000007942 carboxylates Chemical class 0.000 description 3
- 150000001735 carboxylic acids Chemical class 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000001257 hydrogen Substances 0.000 description 3
- 239000000178 monomer Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920005862 polyol Polymers 0.000 description 3
- 150000003077 polyols Chemical class 0.000 description 3
- 239000000600 sorbitol Substances 0.000 description 3
- 239000000454 talc Substances 0.000 description 3
- 229910052623 talc Inorganic materials 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- RTBFRGCFXZNCOE-UHFFFAOYSA-N 1-methylsulfonylpiperidin-4-one Chemical compound CS(=O)(=O)N1CCC(=O)CC1 RTBFRGCFXZNCOE-UHFFFAOYSA-N 0.000 description 2
- BKCIQPUIDHPJSI-UHFFFAOYSA-N 2,3,4,5-tetramethylpyridine Chemical compound CC1=CN=C(C)C(C)=C1C BKCIQPUIDHPJSI-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- PLIKAWJENQZMHA-UHFFFAOYSA-N 4-aminophenol Chemical compound NC1=CC=C(O)C=C1 PLIKAWJENQZMHA-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 description 2
- FERIUCNNQQJTOY-UHFFFAOYSA-N Butyric acid Chemical compound CCCC(O)=O FERIUCNNQQJTOY-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N Magnesium oxide Chemical compound [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- NQRYJNQNLNOLGT-UHFFFAOYSA-N Piperidine Chemical compound C1CCNCC1 NQRYJNQNLNOLGT-UHFFFAOYSA-N 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical compound CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 239000001361 adipic acid Substances 0.000 description 2
- 235000011037 adipic acid Nutrition 0.000 description 2
- 150000001412 amines Chemical class 0.000 description 2
- JFCQEDHGNNZCLN-UHFFFAOYSA-N anhydrous glutaric acid Natural products OC(=O)CCCC(O)=O JFCQEDHGNNZCLN-UHFFFAOYSA-N 0.000 description 2
- GCAIEATUVJFSMC-UHFFFAOYSA-N benzene-1,2,3,4-tetracarboxylic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1C(O)=O GCAIEATUVJFSMC-UHFFFAOYSA-N 0.000 description 2
- AKGGYBADQZYZPD-UHFFFAOYSA-N benzylacetone Chemical compound CC(=O)CCC1=CC=CC=C1 AKGGYBADQZYZPD-UHFFFAOYSA-N 0.000 description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 2
- 239000000920 calcium hydroxide Substances 0.000 description 2
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 2
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 description 2
- 239000008116 calcium stearate Substances 0.000 description 2
- 235000013539 calcium stearate Nutrition 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 235000005687 corn oil Nutrition 0.000 description 2
- 239000002285 corn oil Substances 0.000 description 2
- 235000012343 cottonseed oil Nutrition 0.000 description 2
- 239000002385 cottonseed oil Substances 0.000 description 2
- 125000000392 cycloalkenyl group Chemical group 0.000 description 2
- 125000000753 cycloalkyl group Chemical group 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 2
- NIHNNTQXNPWCJQ-UHFFFAOYSA-N fluorene Chemical compound C1=CC=C2CC3=CC=CC=C3C2=C1 NIHNNTQXNPWCJQ-UHFFFAOYSA-N 0.000 description 2
- 229920001002 functional polymer Polymers 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 239000012760 heat stabilizer Substances 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 125000002524 organometallic group Chemical group 0.000 description 2
- 235000006408 oxalic acid Nutrition 0.000 description 2
- 150000002927 oxygen compounds Chemical class 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 150000007944 thiolates Chemical class 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 229910052718 tin Inorganic materials 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- ZDPHROOEEOARMN-UHFFFAOYSA-N undecanoic acid Chemical compound CCCCCCCCCCC(O)=O ZDPHROOEEOARMN-UHFFFAOYSA-N 0.000 description 2
- 239000010455 vermiculite Substances 0.000 description 2
- 229910052902 vermiculite Inorganic materials 0.000 description 2
- 235000019354 vermiculite Nutrition 0.000 description 2
- 235000012431 wafers Nutrition 0.000 description 2
- 229940098697 zinc laurate Drugs 0.000 description 2
- GPYYEEJOMCKTPR-UHFFFAOYSA-L zinc;dodecanoate Chemical compound [Zn+2].CCCCCCCCCCCC([O-])=O.CCCCCCCCCCCC([O-])=O GPYYEEJOMCKTPR-UHFFFAOYSA-L 0.000 description 2
- IMYZYCNQZDBZBQ-UHFFFAOYSA-N (+-)-8-(cis-3-octyl-oxiranyl)-octanoic acid Natural products CCCCCCCCC1OC1CCCCCCCC(O)=O IMYZYCNQZDBZBQ-UHFFFAOYSA-N 0.000 description 1
- ZWAJLVLEBYIOTI-OLQVQODUSA-N (1s,6r)-7-oxabicyclo[4.1.0]heptane Chemical compound C1CCC[C@@H]2O[C@@H]21 ZWAJLVLEBYIOTI-OLQVQODUSA-N 0.000 description 1
- OBETXYAYXDNJHR-SSDOTTSWSA-M (2r)-2-ethylhexanoate Chemical compound CCCC[C@@H](CC)C([O-])=O OBETXYAYXDNJHR-SSDOTTSWSA-M 0.000 description 1
- NAWXUBYGYWOOIX-SFHVURJKSA-N (2s)-2-[[4-[2-(2,4-diaminoquinazolin-6-yl)ethyl]benzoyl]amino]-4-methylidenepentanedioic acid Chemical compound C1=CC2=NC(N)=NC(N)=C2C=C1CCC1=CC=C(C(=O)N[C@@H](CC(=C)C(O)=O)C(O)=O)C=C1 NAWXUBYGYWOOIX-SFHVURJKSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- SQHKJSPPFSVNDF-UHFFFAOYSA-N 1,2,2,3-tetrakis(hydroxymethyl)cyclohexan-1-ol Chemical compound OCC1CCCC(O)(CO)C1(CO)CO SQHKJSPPFSVNDF-UHFFFAOYSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical group ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- ZXHDVRATSGZISC-UHFFFAOYSA-N 1,2-bis(ethenoxy)ethane Chemical compound C=COCCOC=C ZXHDVRATSGZISC-UHFFFAOYSA-N 0.000 description 1
- YJTKZCDBKVTVBY-UHFFFAOYSA-N 1,3-Diphenylbenzene Chemical group C1=CC=CC=C1C1=CC=CC(C=2C=CC=CC=2)=C1 YJTKZCDBKVTVBY-UHFFFAOYSA-N 0.000 description 1
- BSONBFVPZBKVHF-UHFFFAOYSA-N 1-(2,3-diethylphenoxy)-2,3-diethylbenzene Chemical compound CCC1=CC=CC(OC=2C(=C(CC)C=CC=2)CC)=C1CC BSONBFVPZBKVHF-UHFFFAOYSA-N 0.000 description 1
- ANMAWDWFQHQPFX-UHFFFAOYSA-N 1-(2-hydroxyethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound OCCN1C(=O)NC(=O)NC1=O ANMAWDWFQHQPFX-UHFFFAOYSA-N 0.000 description 1
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- 150000004679 hydroxides Chemical class 0.000 description 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- CDAISMWEOUEBRE-GPIVLXJGSA-N inositol Chemical compound O[C@H]1[C@H](O)[C@@H](O)[C@H](O)[C@H](O)[C@@H]1O CDAISMWEOUEBRE-GPIVLXJGSA-N 0.000 description 1
- 229960000367 inositol Drugs 0.000 description 1
- 150000004694 iodide salts Chemical class 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 125000005481 linolenic acid group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 239000000395 magnesium oxide Substances 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 239000000594 mannitol Substances 0.000 description 1
- 235000010355 mannitol Nutrition 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical compound NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 description 1
- 229910000000 metal hydroxide Inorganic materials 0.000 description 1
- 150000004692 metal hydroxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- VYQNWZOUAUKGHI-UHFFFAOYSA-N monobenzone Chemical compound C1=CC(O)=CC=C1OCC1=CC=CC=C1 VYQNWZOUAUKGHI-UHFFFAOYSA-N 0.000 description 1
- 229960000990 monobenzone Drugs 0.000 description 1
- 150000002762 monocarboxylic acid derivatives Chemical class 0.000 description 1
- 150000002763 monocarboxylic acids Chemical class 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 1
- NXPPAOGUKPJVDI-UHFFFAOYSA-N naphthalene-1,2-diol Chemical compound C1=CC=CC2=C(O)C(O)=CC=C21 NXPPAOGUKPJVDI-UHFFFAOYSA-N 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- ZGAZPDWSRYNUSZ-UHFFFAOYSA-N nonane-1-sulfonic acid Chemical compound CCCCCCCCCS(O)(=O)=O ZGAZPDWSRYNUSZ-UHFFFAOYSA-N 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 150000002843 nonmetals Chemical class 0.000 description 1
- JFOJYGMDZRCSPA-UHFFFAOYSA-J octadecanoate;tin(4+) Chemical compound [Sn+4].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O JFOJYGMDZRCSPA-UHFFFAOYSA-J 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- 235000021313 oleic acid Nutrition 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 150000002898 organic sulfur compounds Chemical class 0.000 description 1
- 150000002902 organometallic compounds Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- LPNBBFKOUUSUDB-UHFFFAOYSA-N p-toluic acid Chemical class CC1=CC=C(C(O)=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-N 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 239000000312 peanut oil Substances 0.000 description 1
- XNLICIUVMPYHGG-UHFFFAOYSA-N pentan-2-one Chemical compound CCCC(C)=O XNLICIUVMPYHGG-UHFFFAOYSA-N 0.000 description 1
- 125000001151 peptidyl group Chemical group 0.000 description 1
- 150000004965 peroxy acids Chemical class 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- AQSJGOWTSHOLKH-UHFFFAOYSA-N phosphite(3-) Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 150000003022 phthalic acids Chemical class 0.000 description 1
- 125000003386 piperidinyl group Chemical group 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 239000002952 polymeric resin Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 150000003304 ruthenium compounds Chemical class 0.000 description 1
- STECJAGHUSJQJN-FWXGHANASA-N scopolamine Chemical compound C1([C@@H](CO)C(=O)O[C@H]2C[C@@H]3N([C@H](C2)[C@@H]2[C@H]3O2)C)=CC=CC=C1 STECJAGHUSJQJN-FWXGHANASA-N 0.000 description 1
- 229960002646 scopolamine Drugs 0.000 description 1
- CDAISMWEOUEBRE-UHFFFAOYSA-N scyllo-inosotol Natural products OC1C(O)C(O)C(O)C(O)C1O CDAISMWEOUEBRE-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000013112 stability test Methods 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- PJANXHGTPQOBST-UHFFFAOYSA-N stilbene Chemical compound C=1C=CC=CC=1C=CC1=CC=CC=C1 PJANXHGTPQOBST-UHFFFAOYSA-N 0.000 description 1
- 235000021286 stilbenes Nutrition 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-L succinate(2-) Chemical compound [O-]C(=O)CCC([O-])=O KDYFGRWQOYBRFD-UHFFFAOYSA-L 0.000 description 1
- 239000001384 succinic acid Substances 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 description 1
- DUYAAUVXQSMXQP-UHFFFAOYSA-M thioacetate Chemical compound CC([S-])=O DUYAAUVXQSMXQP-UHFFFAOYSA-M 0.000 description 1
- 150000003568 thioethers Chemical class 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- 229940098465 tincture Drugs 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 239000004408 titanium dioxide Substances 0.000 description 1
- FICPQAZLPKLOLH-UHFFFAOYSA-N tricyclohexyl phosphite Chemical compound C1CCCCC1OP(OC1CCCCC1)OC1CCCCC1 FICPQAZLPKLOLH-UHFFFAOYSA-N 0.000 description 1
- IVIIAEVMQHEPAY-UHFFFAOYSA-N tridodecyl phosphite Chemical compound CCCCCCCCCCCCOP(OCCCCCCCCCCCC)OCCCCCCCCCCCC IVIIAEVMQHEPAY-UHFFFAOYSA-N 0.000 description 1
- FDGZUBKNYGBWHI-UHFFFAOYSA-N trioctadecyl phosphate Chemical compound CCCCCCCCCCCCCCCCCCOP(=O)(OCCCCCCCCCCCCCCCCCC)OCCCCCCCCCCCCCCCCCC FDGZUBKNYGBWHI-UHFFFAOYSA-N 0.000 description 1
- 239000002383 tung oil Substances 0.000 description 1
- KOZCZZVUFDCZGG-UHFFFAOYSA-N vinyl benzoate Chemical compound C=COC(=O)C1=CC=CC=C1 KOZCZZVUFDCZGG-UHFFFAOYSA-N 0.000 description 1
- 229920006163 vinyl copolymer Polymers 0.000 description 1
- FUSUHKVFWTUUBE-UHFFFAOYSA-N vinyl methyl ketone Natural products CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 1
- 239000011667 zinc carbonate Substances 0.000 description 1
- 229910000010 zinc carbonate Inorganic materials 0.000 description 1
- 235000004416 zinc carbonate Nutrition 0.000 description 1
- 150000003752 zinc compounds Chemical class 0.000 description 1
- UGZADUVQMDAIAO-UHFFFAOYSA-L zinc hydroxide Chemical compound [OH-].[OH-].[Zn+2] UGZADUVQMDAIAO-UHFFFAOYSA-L 0.000 description 1
- 229910021511 zinc hydroxide Inorganic materials 0.000 description 1
- 229940007718 zinc hydroxide Drugs 0.000 description 1
- 229910052984 zinc sulfide Inorganic materials 0.000 description 1
- PCHQDTOLHOFHHK-UHFFFAOYSA-L zinc;hydrogen carbonate Chemical compound [Zn+2].OC([O-])=O.OC([O-])=O PCHQDTOLHOFHHK-UHFFFAOYSA-L 0.000 description 1
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 description 1
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/138—Phenolates
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/01—Use of inorganic substances as compounding ingredients characterized by their specific function
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/0091—Complexes with metal-heteroatom-bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/37—Thiols
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
- C08K5/38—Thiocarbonic acids; Derivatives thereof, e.g. xanthates ; i.e. compounds containing -X-C(=X)- groups, X being oxygen or sulfur, at least one X being sulfur
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Description
200523306 九、發明說明： 【發明所屬之技術領域】 本發明係關於用於含齒素乙烯基聚合物之安定劑紐合 物，該安定化含i素乙烯基聚合物組合物及自其形成之物 件，及安定化含鹵素乙烯基聚合物之方法。 【先前技術】 音遍使用含鹵素乙烯基聚合物（例如，聚（氯乙烯）、氯乙 烯及醋酸乙烯醋之共聚物、及聚（二氯乙烯））以製造各種物 件，例如，管、窗框、壁板、瓶子、牆面覆蓋物及包裝膜。 已儘量嘗試添加安定劑至含鹵素乙烯基聚合物内以改善可 發生在聚合物樹脂内之色彩變化，特別為此等於加工前一 至十分鐘期間發生之色彩變化。鋅鹽為有用安定劑，其可 明顯減少在加工之早期階段中在含齒素乙烯基聚合物所發 現之色彩變化。作為熱安定劑之料之—項缺點在於於加 工期間，可發生急速並破壞性的降解反應，其會導致被稱 為’’鋅灼燒"之現象。 有機硫化合物及 已經與鋅鹽一起添加其它化合物（例如 良於加工後期階段 含硫醇有機化合物）作為輔安定劑以改 脂醋）之安定劑。以每_重量份該Pvc為基準計，鋅化合物 安疋。例如，頒不Zaremsky等人之美國專利第3,〇67，166 號揭示含有低含量鋅化合物及録0旨（，例如，疏基乙酸硬 之存在 者頃發 意。 量能有效得到0.002至〇·05重量份鋅，但是，其發明 現藉由這些組合物得到之安定化程度不能令人滿 95588.doc 200523306 藉由本發明處理之問題為提供用於含南素乙縣聚合物 之安定劑組合物’特別為於加工或長期使用期間能更有效 保護含鹵素乙烯基聚合物免於降解 災巴 < 女定劑组合 物。 【發明内容】 本發明第-方面係提供衫化聚合物組合物，其包含_ 素乙稀基聚合物、填料、含硫醇有機化合物及鋅鹽，立中 以= 100重量份該含幽素乙稀基聚合物為基準計，該辞鹽之 含量能有效得到0.075至15重量份辞金屬。 本發明第二方㈣提供包含含硫醇有機化合物及辞越之 安定劑組合物，其中以每1⑼重量份含i素乙稀基聚合ί為 基準汁’該辞鹽之含量能有效得到〇.075至1.5重量份鋅金 發明第三方面係提供安定化包含填料之含-素乙烯基 聚口物之方法’該方法包括添加含硫醇有機化合物及鋅鹽 ^該含函素乙稀基聚合物内，其中以每1〇〇重量份含函素: 歸基聚合物為基準計，該鋅鹽之含量能有效得到〇们5至i $ 重量份鋅金屬。 · 本發明第时面係提供含上述安定化聚合物Μ合物之物 件0 揭示女疋劑組合物令人驚對地顯示以相當高含量鋅鹽 (亦即，以每1〇〇重量份該含鹵素乙烯基聚合物為基準計， 〇.〇75至1 $舌曰 • 里份鋅金屬之含量）可以改良填充含_素乙烯 基聚合物組合物之安定化作用。此結果出乎意料，例如， 95588.doc 200523306 頒予ZaremSky等人之美國專利第3,〇67，166號教示在0.002 至0.50份鋅之"最佳濃度以上或以下”，”在某方面，該組合 物之安定性會減少”（第3段，第27_29行）。 用於上述安定劑組合物中之適合辞鹽包括，例如，無機 鹽’例如’氣化辞、氧化辞、氫氧化鋅、碳酸鋅、鹼式碳 酸鋅、硫化鋅或硼酸辞；及有機鹽，例如，羧酸鋅、烯醇 酸鋅或酚酸辞、及含任一或多種前述辞鹽之混合物。 適合之羧酸鋅為具有2至30個碳原子之經取代或未經取 代羧酸之辞鹽。該羧酸辞較佳為式丨所代表之辞鹽： Zn[{OC(=G)}xR2]2_x ⑴ 其中X為零或一，且各R2相同或不同，並為具有丨至川個碳 原子（較佳1至17個碳原子）之飽和或不飽和、直鏈或分支鏈 烷基。用於形成鋅鹽之適合羧酸包括，例如，單羧酸，例 如，乙酸、丁酸、辛酸、新癸酸、2_乙基己酸、十一酸、 棕櫚酸、月桂酸、硬脂酸、9，1〇_二羥基硬脂酸、油酸、3,6,9_ 一咢务@欠、笨甲酸、對_第三_ 丁基苯甲酸、二曱基羥基苯 曱酸、或羥基乙酸；與二價羧酸及其單酯，例如，草酸、 丙一酸、琥珀酸、戊二酸、己二酸、反丁烯二酸、辛烷-丨，^ 一羧酸、3,6,9-三号癸烷-ΐ，ι〇_二羧酸、乳酸、順丁烯二酸、 /酉石g夂t乙一醇二緩酸（n= 10-12)、醜酸、對酜酸、及輕 基酞酸；及三-或四價羧酸（例如，半米酸、1，2,4-苯三甲酸、 笨四甲酸、擰檬酸）、及包含任一或多種上述酸之混合物。 該烯醇酸鋅較佳包括乙醯基丙酮、苯甲醯基丙酮、二苯 甲酿基甲烷之烯醇酸酯、乙醯乙酸酯、苯甲醯基乙酸醋、 95588.doc 200523306 或去氫乙酸之烯醇酸醋及包含任一或多種上述烯醇酸酿之 混合物。 精由鋅鹽得到之鋅量大於約〇〇75 phr。辞之特定量可根 μ 不同，且根據该含鹵素乙烯基聚合物調配物、加 工方目的用途、及類似考慮事項报容易由熟悉本技藝 者決定該特定量。通常，藉由鋅鹽得到之適合鋅量為0.075 Phr至1.5 phr。如文中使用，phr係指每1〇〇重量份該含鹵素 乙烯基聚合物之重量份特定組份。在此範圍内，可以使用 大於或等於0.075 phr之用量，較佳大於或等於〇1 phr，且 更佳大於或等於0^ 5 phr。亦在本範圍内，可以使用小於或 等於1.5 phr ,較佳小於或等於1〇 phr，且更佳小於或等於 0.75 phr。大於2·〇 phr可以產生緩和作用及/或被稱為鋅灼 燒之快速降解現象，而小於0 075 phr並不會得到所要安定 化程度。 適合之含硫醇有機化合物包括，例如，具有1至1 〇〇個碳 原子及1至4個姨基之烧基硫醇、疏基醋、疏基醇、疏基酸 及諸如此類。適合之含硫醇有機化合物具有由下式表示之 結構： 95588.doc 200523306
HS
(MC-2)
(MG4)
HS
(MC-6) 其中 卜GtW七㈣_3，其限制條件為m+n=4; \為-H、C“18烷基、或Ci36芳基； R及R各獨立為-Η、-qh、u n _ ρ16η/ υΗ ' _SH、Cb18烷基、芳基 R C〇〇)〇-、4R16〇C(==〇); RU為環烷基、環烯基、或苯基； 二2為.Η、-OH、SH、Ci i8烷基、。i8芳基、(哪. R2〇C(=〇)_、其限制條件為在式⑽2中，當Rl1為苯基時 R為-OH ’且1-0，該_SH基團係在非鄰接之碳原子上丨 95588.doc 200523306 R13為-Η或可含有鹵素、經基、疏基或烧基取代基之二價 基團，且當R11為苯基時，該二價基團可以與苯基化合以形 成萘環；
Rl4為二價基團，且其係為-〇c(=o)r17c(=o)o-、 -0C(=0)CH=CHC(=0)0_、或评0)0Ri70C(=0)_ ; R15為Cuu烷基，較佳為_ch3、-ch2ch3; (^_12羥基烷基， 較佳為羥曱基；或
C7·36烧芳基、Cl_10環烷基、或〇1_36環烯基；且 R 為 〇6_36伸芳基、Ci-8伸烯基、-(CH2CH2〇)bCH2CH2-， 其中b= 1 -6，或
其中f=l或2。 該含硫醇有機化合物較佳為根據式MC12化合物，其中 R 為·Η，R 為 ;化1。為 _〇H、Ri6c(=〇)〇·、或 r16〇c(=〇)_ ; 且卜1，根據式MC2之化合物，其中Ru為苯基；R8為·H ; R為-H , R13為_H ; j = 1，且i=1 ;根據式mc32化合物，其 中R為·Η ’ rw為-〇c(=〇)CH=CHC㈣）〇 ;且卜工；根據式 MC4之化合物，其中R9為-H ;且卜丨·，及根據式之化合 95588.doc -10· 200523306 物，其中R15為-C2H5或 O R9 Λ^ο
SH 且R8為-Η ;而i = l ;及根據式MC6之化合物，其中R8為-Η ; 且 i = l 〇 在式M C1範圍内之適合含硫醇有機化合物包括，例如’ 表1所示之化合物： 表1 MCla HSC12H25 MCli HSCH2CH2CH2OH MClp HSCH2CH2OH MClb 〇 II hsch2coh MClj 0 II HSCH2COC18H37 MClq 〇 II HSCH2CH2COC8H17 MClc 0 II HSCHCOC8H17 ch3 MClk 0 II HSCH2CHOCC8H17 ch3 MClr 0 II HSCH2CHOCCH3 c9h19 MCld 0 II hschcoc12h25 ό MC11 0 II HSCHCOCH3 C10H 幻 MCls 0 II HSCHCOH I C10H21 MCle o II HSCH2COC8H17 MClm o II HSCH2CH20CC17H35 MClt 0 II HSCH2CH2OCC17H33 MClf 0 II hsch2coc2h5 MCln 0 II HSCHaCHaOCCuHga MClu 0 II HSCH2CH2CH2〇CCeH17 MClg hsch2choh ch3 MClo HSCH2CHOH C9H19 MClv 〇 HSCH2CH2COCHH23 MClh 0 II hsch2ch2coh 在式MC2範圍内之適合含硫醇有機化合物包括，例如， 以下化合物： -11 - 95588.doc 200523306
SH
(MC2a)
(MC2b) 在式MC3範圍内之適合含硫醇有機化合物包括，例如 表2所示之化合物：
裱2 MC3a O 0 II II HSCH2COCH2CH2OCCH2SH MC3f o o II II HSCH2CH2OC(CH2)4COCH2CH2SH MC3b O 0 II II HSCH2CH2OCCH2CH2COCH2CH2SH MC3g 0 0 MC3c 〇 0 II II HSCH2CH2OCCH=CHCOCH2GH2SH MC3d 0 0 II II HSCH2COCH2CH2OCH2CH2OCCH2SH MC3e o o II II HSCH2CO(CH2CH2〇)3CH2CH2OCCH2SH 在式MC4範圍内之適合含硫醇有機化合物包括，例如 以下化合物： (MC4a) 〇 II hsch2ch2occh2 ccoch2ch2sh 在式MC5範圍内之適合含硫醇有機化合物包括，例如 以下化合物： 12- 95588.doc 200523306 ο II CH3CH2C(CH2OCCH2SH)3 (MC5a) οII C(CH2〇CCH2SH)4 (MC5b) οII hoch2c(ch2occh2sh)3 (MC5c) οII (HOCH2)2C(CH2OCCH2SH)2 (MC5d) 在式MC6範圍内之適合含硫醇有機化合物包括，例如， 以下化合物： HSCH2CH2COCH(CH2OCCH2GH2SH)2 0 〇II II HSCH2COCH(CH2OCCH2SH)2 (MC6a) (MC6b) 該含硫醇有機化合物較佳為如式MC-1或MC-2之酼基酯 或逆酯，其中R9、r1g、或R12各獨立為r16C(=0)0-或 R160C(=0)-;或 MC-3、MC-4、或 MC-5、或 MC-6。適合之 酯類包括，例如，酼基乙酸硬脂酯、酼基乙酸2-乙基己醋、 二乙二醇雙（巯基乙酸酯）、及含一或多個上述酯之混合物。 適合之逆酯類包括，例如，硬脂酸2-巯基乙酯、己酸2-巯基 乙酯、妥爾酸2-酼基乙酯、及含一或多種上述逆酯之混合 物。可以使用Μ基酯及逆Μ基酯之混合物，其用量為，例 如，各以該含硫醇有機組份之總重量為基準計，包含1重量 %(wt%)至約99 wt%魏醋及99 wt%至1 wt%逆魏基酉旨。 95588.doc -13- 200523306 _ s ^ %有機化合物之用量可根據應用而不同，且根據該 3鹵素乙烯基聚合物調配物、加工方法、且的用途、及類 似考慮事項，很容易由熟悉本技藝的—般人決定其用量。 通常，含硫醇有機化合物之適合量為〇.〇51?1^至5〇1)1^。在 此，圍内，可以使用大於或等於〇1咖之用量，較佳大小 或等於0.25 phr，更佳大於或等於〇 5 phr。亦在此範圍内， 可以使用小於或等於4.〇 phr，較佳小於或等於3()咖，且 更佳小於或等於2.0 phr。大於4 〇咖會導致較差結果而 小於〇.〇5 phr並不會得到所要安定化程度。 安定劑可視需要包括其它輔安定劑，例如，環氧化合物、 ^屬安㈣、亞錢@旨、含氮安定劑、其它非金屬安定劑、 多元醇、塊滑石、碳酸㈣石、及含__或多種上述辅安定 劑之混合物。 適合之環氧化合物包括，例如，環氧化油，例如，大豆 油、豬油、撖欖油、亞麻仁油、花生油、箆麻油、玉米油、 桐油、棉子油、及含-或多種上述環氧化合物之混合物。 其它適合之環氧化合物包括’例如’環氧氯丙炫/雙紛續 脂、丁氧基環氧丙炫、環氧基硬脂酸縮水甘油醋、環氧化 以烯少工娘氧化大丑油酸縮水甘油酯、環氧化甲苯甲酸丁 酉曰、去水甘油、乙稀基環_己稀_氧化物；苯二齡 1，5·二羥基萘、甘油、異戊四醇（pentaerythrit〇i)、及山梨糖 醇之縮水甘油醋；#丙基縮水甘㈣、丁基縮水甘油喊、 環己烧氧化物、4-(2,3·環氧基丙氧基）乙醯苯、米基化氧淨 氧化合物、2-乙基_3_丙基縮水甘油胺、及含一或多種上:: 95588.doc 14 200523306 環氧化合物之混合物。該環氧化合物之存在量可以多至3〇 phr ° 適合之亞鱗酸s旨包括’例如’亞麟酸三烧酉旨，例如，亞 % S文一辛g曰s W酉变十二烷酯、亞磷酸三月桂酯、亞磷酸 三（十四㈣）、亞磷酸三環己自旨、亞賴三硬脂醋、二亞鱗 酸二硬脂基-異戊四醇酯、或亞磷酸三油酯；亞磷酸三J 醋，例如，亞碟酸三苯醋、亞磷酸三甲苯醋、或亞碟酸參_ 對-壬基苯酯；亞磷酸烷基二芳酯，例如，亞磷酸苯基二癸 酯或亞磷酸（2,4-二-第三-丁基苯基）二月桂酯；亞磷酸二烷 基芳酯；硫亞磷酸酯，例如，亞磷酸三硫苄酯；及含任: 或多種上述亞磷酸酯之混合物。該亞磷酸鹽之使用量可以 是，例如，0.01 phr至1〇 phr，較佳〇 〇5 phr至5 phr，且尤 佳 0· 1 phr至 3 phr 〇 金屬女疋劑之疋義為金屬鹽之非辞鹽之有機金屬鹽。適 合之金屬鹽包括，例如，金屬之氧化物、氫氧化物、硫化 物、硫酸鹽、氯化物、溴化物、氟化物、碘化物、磷酸鹽、 酚鹽、過氣酸鹽、羧酸鹽、及碳酸鹽。該金屬鹽之實例為 鹽酸、硫酸、酚、芳香族羧酸、脂肪酸、環氧化脂肪酸、 草酸、乙酸、及碳酸之鋇、鳃、鈣、錫、鎂、鈷、鎳、鈦、 銻、及鋁鹽。較佳金屬安定劑包括氫氧化鈣、氫氧化鎮、 硬脂酸鈣、2-乙基己酸鈣、辛酸鈣、油酸鈣、篦麻油酸鈣、 肉豆蔻酸鈣、棕櫚酸鈣、月桂酸鈣、月桂酸鋇、二（壬基酉分 酸）鋇、硬脂酸鋇、硬脂酸錫、硬脂酸銘、氫塊滑石、及含 一或多種上述金屬鹽之混合物。以該_化聚合物總重為美 95588.doc -15- 200523306 準汁五屬女疋劑之存在量可以多至2 wt%，較佳〇. 1 wt% 至 1 wt%。
車乂仏之有祙金屬安定劑包括有機錫羧酸鹽及硫醇鹽。適 合之有機金屬安㈣包括，例如，丁基錫參月桂基硫醇鹽、 二月桂酸二丁基錫、二丁基錫二月桂基硫醇鹽、二參二丁 基錫酸二酸軒二#、幾基縮硫酸之二煙錫冑、及含一或多 種上述有機金屬安定劑之混合物，酸Μ錢g旨及/或魏基 乙酸烧醋之有機錫硫醇鹽之單硫化物及/或多硫化物、及含 一或多種上述各物之混合物亦適於作為有機金屬安定劑。
適合之含氮安定劑包括，例如，二氰胺、受遮蔽胺、蜜 胺、尿素、二f基乙内醯脲、胍、硫脲、2_苯基β引嗓、胺 基巴丑酸8旨、跡烧基及Ν•苯基取代之順Τ烯：醯亞胺、 1，3-二烷基-6-胺基-尿嘧啶衍生#、吡咯二井二_、及含一 或多種上述主要含氮之安定劑之混合物。以含幽素乙稀基 聚合物總重為基準計，該主要含氮之安定劑之存在量可多 至1〇Wt%。非金屬安定劑尚包括硫代二丙酸二月桂S旨、3,3,_ 硫代丙酸二硬脂醋、3,3，_硫代二丙酸二节醋、3,3,_硫代二 丙酉文衣己@曰、3,3 -硫代二丙酸二油醋、3,3,_硫代二丙酸 二癸醋、3’3’-硫代二丙酸二乙§旨、3，_疏基丙基月桂醋、弘 月桂基疏基丙酸月桂酉旨、3_辛基魏基丙酸苯醋、及含一或 多種上述非金屬安定劑之混合物。以齒化聚合物總重為基 準計’該非金屬技劑之存在量可多至〇75㈣，以〇〇1 Wt%至 〇·75 Wt%為佳。 ’例如，單體性、寡聚性 有用的立體上受遮蔽之胺包括 95588.doc -16 - 200523306 或聚合性2,2,6,6，-四曱基哌啶化合物。該哌啶分子團之气可 經由，例如，氫、cvcu烧基、C3_C8烯基、或j烷 基取代。該派唆分子團之C-4碳可經由M列如，氣或氧2 = 氮基團取代。適合之2,2,6,6-四甲基㈣化合物包括，例如， 4-經基·2,2,6,6·四甲基Μ基_4_經基·2,2，m，_四甲基 派啶、4-硬脂醯氧基-2,2,6,6-四甲基哌啶、丙酸i 2 2 6卜
五甲基略咬m(3,5-二-第三_丁基_4·經基苯基）醋’、琥 珀酸二（2,2,6,6-四曱基哌啶-4-基）g旨、乙酸丨_乙醯基·2,2,6,6-四甲基派咬·4-基酯、苯三曱酸三（2,2,6,6,甲基㈣冰基） 酯、及含一或多種上述化合物之混合物。哌啶之使用量為， 例如，O.Olphr至Iphr，最好至少約〇·1ρ1π^小於〇5phr。
適合之多元醇包括，例如，異戊四醇、二異戊四醇、三 異戊四醇、雙三羥甲基丙烷、三羥甲基丙烷、肌醇、聚乙 烯醇、山梨糖醇、甘露醇、乳糖、參（羥乙基）異氰尿酸酯、 四羥甲基環己醇、四羥曱基環吡喃醇、甘油、二甘油、聚 甘油、1，3,5-參（2-羥乙基）氰尿酸、及含至少一種上述組份 之混合物。較佳多元醇包括，例如，山梨糖醇及三羥甲基 丙烧5亥多元醇之使用量為，例如，0.01 phr至20 phr，最 好至少約〇·1 phr至小於1〇 phr。 如文中使用，該名詞含鹵素乙烯基聚合物意指其中鹵素 (群）直接與碳原子連接之含鹵素聚合物。含鹵素聚合物包 括，例如，具有約14重量。/❻至約75重量％(例如，約27重量 °/〇)氯之氣化聚乙烯；氣化天然及合成橡膠；橡膠鹽酸鹽； 乳化聚苯乙烯；氣化聚（151_二氣乙烯）；氯化聚（氯乙烯）； 95588.doc •17- 200523306 聚（溴乙烯）；聚（氟乙烯）；其它氯乙烯聚合物、及含一或多 種上述聚合物之混合物。被稱為聚氯乙烯（PVC)之該氯乙烯 t合物可單獨自氯乙稀單體或包含較佳至少約70重量％氯 乙烯（以總單體重量為基準計）之單體混合物製成。適合之共 單體包括，例如，醋酸乙烯酯、丁酸乙烯酯、苯曱酸乙烯 酯、1，1-二氯乙烯、三氣乙烯、；μ氟-2_氣乙烯、反丁烯二 酸二乙酯、順丁烯二酸二乙酯、丙烯酸甲酯、丙烯酸2_乙 基己酯、α _氣丙烯酸甲酯、丙烯酸丁酯、甲基丙烯酸甲酯、 甲基丙烯酸乙酯、曱基丙烯酸丁酯、苯乙烯、乙烯酮（例如， 乙稀基甲基酮及乙烯基苯基酮）、丙烯腈、氯丙烯腈、二醋 酉义亞烯丙S曰、一醋酸：SL亞稀丙S旨、及乙稀喊（例如，乙稀基 乙基鱗、乙浠基苯基醚）（該乙浠鱗係藉由一莫耳丙烯駿與一 莫耳乙二醇二乙烯醚之反應製成）、及含一或多種前述共單 體之混合物。適合之含鹵素乙烯基共聚物包括，例如，氯 乙烯-醋酸乙烯酯（87:13)、氣乙稀_醋酸乙烯酯_順丁稀二酸 酐（86:13:1)、氣乙烯-ΐ，ΐ-二氣乙烯（95:5);氣乙烯_反丁烯 一酸一乙酯（95:5)、氯乙稀_丙烯酸2 -乙基己酯（8〇:2〇)、及 含一或多種上述共聚物之複合物。 硬質含鹵素乙稀基聚合物組合物為不含增塑劑之聚合物 組合物。半硬質含_素乙烯基聚合物組合物每丨〇〇重量份該 含鹵素乙烯基聚合物含有1至25份增塑劑。軟質含_素乙稀 基聚合物組合物每1 〇〇重量份該含_素乙婦基聚合物含有 25至100份增塑劑。適合之增塑劑包括，例如，含有自1至3 個具有8至12個碳原子之烷基之聚合酸烷酯。該烧酯之適合 95588.doc -18- 200523306 燒基包括，例如，正-辛基、2-乙基己基、癸基、十二烷基、 及含一或多種上述烷基之混合物。該烷酯之適合聚合酸包 括’例如’敝酸、苯三甲酸、苯甲酸、己二酸、癸二酸、 戊二酸、碟酸酯、及含一或多種上述酸之混合物。聚合物 增塑劑亦適合。 適合之填料包括，例如，煅土、碳酸鈣、滑石、白雲石、 石夕灰石、氧化鎂、氫氧化鎂、矽酸鹽、玻璃纖維、高嶺土、 白堊、雲母、金屬氧化物、金屬氫氧化物、碳黑、石墨、 及含有一或多種上述填料之混合物。 添里之添加量為1 〇卩心至3〇 phr。在此範圍内，可使用大 於或等於2.0 phr之數量，較佳大於或等於3〇 phr，且更佳 大於或等於4.0 Phr。亦在此範圍内，可使用小於或等於3〇 Phr，較佳小於或等K15phr，且更佳小於或等於i〇phr。 該含素聚合物組合物可視需要包含其它習知添加劑， 例如，抗氧化劑、潤滑劑、顏料、抗衝擊改質劑、加工佐 劑、發泡劑、染料、紫外線吸收劑、#周化劑、殺生物劑、 及含一或多種上述添加劑之混合物。上述添加劑之適合用 量很容易纟熟悉以藝的一般人根據該組合⑼之所要最終 性質及目的用途來決^。通常，以該含_數乙烯基聚合物 總重為基準計，各添加劑之存在量為〇 〇1至1〇，較佳 〇· 1 至 5 wt%。 適合之抗氧化劑包括，例如，盼系抗氧化劑，例如，2,卜 第三-丁基-對-甲酚、丁基化羥基茴香醚、4,4,_硫代雙 第三-丁基-間-曱酚）、4,4,_環亞己基二酚、2,5-二-第三戊基 95588.doc -19- 200523306 氫酿、4,4’-亞丁基雙（6-第三-丁基-間-甲酚）、氫醌單苄基 醚、2,2*_亞甲基·雙（4-曱基-6-第三-丁基酚）、2-第三-丁基_4_ 十二烷基氧兩、對-胺基酚、N-月桂基氧-對-胺基酚、4,4，_ 硫代雙（3-甲基第三-丁基酚）、雙[鄰四甲基丁基） 驗]琉化物、4 -十二烧基氧-2-輕基二苯曱酮、3-經基-4-(苯 基羰基）苯氧基乙酸之正-十二烷基酯、第三-丁基酚、及含 一或多種上述抗氧化劑之混合物。 適合之潤滑劑包括，例如，石壌、脂肪酸鹽、低分子量 聚乙烯（亦即，聚乙烯蠟）、脂肪酸醯胺（亦即、月桂醯亞胺 及硬脂醯胺）、雙醯胺（亦即、十亞甲基雙醯胺）、脂肪酸酯（例 如，硬脂酸丁酯、硬脂酸甘甘酯、亞麻仁油、棕櫚油、油 酸癸S曰、玉米油、棉子油、及諸如此類）、及含一或多種上 述潤滑劑之混合物。適合之顏料包括，例如，二氧化鈦、 碳黑、氧化鐵、及含一或多種上述顏料之混合物。 通常，調製以一份式混合物提供之上述熱安定劑組合物 以得到一或多種鋅鹽及至少一或多種含硫醇有機化合物。 其它適需要選用之添加劑亦可存在於該一份式混合物内， 以该一份式混合物總重為基準計，各組份之特定含量可以 自0.1至99.9重量％不等，較佳為L0至99〇重量％。很容易經 由熟悉本技藝的一般人決定能有效產生熱安定性協合性改 良之特疋Ϊ。於至鬲35 0°C溫度下改良早期的色彩，費時至 少3分鐘，較佳於35〇t下至少5分鐘。 可以於低或高f切速率下藉㈣合製備該含鹵素乙稀基 聚合物組合物。同樣，可以將熱安定性組合物併入含鹵素 95588.doc -20 · 200523306 乙烯基聚合物組合物内，其係藉由在適合磨機或混合器内 混合其各組份及該聚合物’或藉由另一種方法使該安定劑 均勾分散遍及該聚合物内。根據相容性及物理狀態（亦即， 液態或固態），該摻合物之各組份需要加熱以形成具有所要 性能特徵之均勻安定化聚合物組合物。 可使用安定化含i素乙稀基聚合物組合物，利用各種用 以使物件成型之方法（例如，模製法、擠製法、及射出成型 法）以形成各種硬質物件，例如，房屋壁板、窗框、及管。 【實施方式】 實例 藉由以下貫例進一步說明本發明，其中製備用於熱安定 性測試之PVC組合物之方法為於高剪切下混合1〇〇重量份 該PVC樹脂、填料aophr碳酸鈣）、顏料（〇5phr)、脫模劑 (0.5-2 phr)、輔安定劑（1_10 phr環氧化大豆油、及/或硬脂 酸鈣）、增塑劑（酞酸二異癸酯）及潤滑劑（〇·2_2 〇 phr)、與表 1所示之各安定劑組合物。然後於39(Tf(199°C)下在雙輥磨 機内加熱該混合組合物，並於指定之時間間隔下移除試 樣，然後形成晶片。使用Hunter Labs(L, a，b)比色計測定各 晶片之色彩變化（由dE反映）及黃度（YI)。 實例1-8表示包含含硫醇有機化合物及不同含量之鋅金 屬（由月桂酸鋅提供）之安定劑組合物對聚氣乙烯樹脂之影 響。 95588.doc -21 - 200523306 表1 f 組份 實例數 1* 2* 3 4 5 6 7 8 月桂酸鋅U 0.002 0.05 0.075 0.1 0.125 0.15 0.175 0.2 硫代羥基乙酸硬脂酯 2.0 2.0 2.0 2.0 2.0 0.5 0.5 0.5 以分鐘表示之dE 1* 2* 3 4 5 6 7 8 2 27.1 13.6 13.4 13.5 13.4 13.5 13·2 13.4 4 42.0 13.9 13.9 13.9 14.1 13.8 13.6 13.9 6 52.3 14.2 14.2 14.3 14.2 14.2 14.0 14.5 8 58.8 14.8 14.8 14.9 15.0 14.8 14.7 15.2 10 62.8 15.7 15.7 15.7 16.0 16.0 15.8 16.3 12 _____ 16.9 16.7 17.0 17.5 17·6 17.5 17.7 14 --- 23.9 21.1 19.0 19.4 19.1 18.8 19.8 16 --- 30.7 25.0 21.7 21.9 21.5 21.1 21.8 18 — 37.4 29.7 25.4 24.9 24.8 23.2 25.7 20 — — 35.9 30.8 29.5 28.4 27.7 30.2 以分鐘表示之YI 2* 3 4 5 6 7 8 2 42.8 4.7 4.8 4.9 4.9 5.1 5.0 5.6 4 78.8 6.3 6.4 6.4 6.8 6.9 6.7 7.4 6 104.3 8.2 8.4 8.7 8.5 9.0 8.7 9.9 8 119.3 10.2 10.3 10.5 11.0 11.1 11.1 12.6 10 127.4 12.8 12.9 12.7 13.4 14.1 14.3 15.3 12 — 15.9 15.4 15.9 16.6 16.8 16.9 17.2 14 •- 32.8 25.1 '19.4 19.8 18.9 18.6 19.9 16 — 48.4 34.5 24.6 24.3 23.0 21.7 22.R 18 —一- 卜 62.7 44.7 32.3 29.8 28.2 25.0 29.4 20 -- — 56.3 43.1 38.0 33.9 32.4 36.2 *比較實例 + +根據鋅金屬所報告之phr 表1之數據清楚表示特別就長期色彩保持而言，小於0 05 重量份鋅並不能產生含人滿意之安定化作用。於〇 〇75重量 伤辞、及至〇·1重量份鋅（其係為2；arenisky所教示之兩倍量） 下可知到更佳安定化作用，其中於1991下可發現令人接受 之色彩，費時多至約2〇分鐘。 95588.doc 22-
Claims (1)
- 200523306 十、申請專利範圍： 1 · 一種安定化聚合物組合物，其包含 含鹵素乙烯基聚合物； 填料； 含硫醇有機化合物；及 鋅鹽，其含量以每100重量份該含_素乙烯基聚合物為 基準計’可有效得到0.075至1.5重量份辞金屬。 2·如請求項1之安定化聚合物組合物，其中該含硫醇有機化 合物為巯基酯、逆巯基酯或含至少一種上述酯之混合物。 3_如請求項1或2之安定化聚合物組合物，其中該鋅鹽為羧 酸鋅、烯醇酸辞、酚酸鋅或含至少一種上述鋅鹽之混合 物。 4·如請求項1之安定化聚合物組合物，其以ι〇〇重量份該含 _素乙烯基聚合物為基準計，包含1.0至3〇重量份填料及 0.05至4重量份含硫醇有機化合物。 5·如請求項1或4之安定化聚合物組合物，其中該鋅鹽為叛 酸鋅；且該含硫醇有機化合物為巯基酯、逆酼基酯或含 至少一種上述酯之混合物。 6 ·如凊求項1或4之安定化聚合物組合物，其中該鋅鹽為具 有1至17個碳原子之飽和或不飽和、直鏈或分支鏈烧基之 1 ’且5亥含硫醉有機化合物為硫代經基乙酸硬脂g旨、硫 代私基乙酸2-乙基己酯、二乙二醇雙（硫代羥基乙酸酯）、 硬脂酸2-巯基乙酯、己酸2-酼基乙酯、妥爾酸2-巯基乙酯 或含至少一種上述之混合物。 95588.doc 200523306 7· 一種安定含有填料之含幽素乙烯基聚合物之方法，該方 法包括添加含硫醇有機化合物及辞鹽至該含齒素乙稀基 聚合物中，其中該鋅鹽之含量以每100重量份該含鹵素乙 稀基聚合物為基準計，可有效得到0.075至1·5重量份辞金 屬。 8 · —種物件， 9 ·如請求項s 其包含如請求項1之組合物。 月长項8之物件，其中該物件為管、窗框、壁板、瓶子、 牆面覆蓋物或包裝膜。其包含含硫醇有機化合物及辞鹽， 之s里以每1〇〇重量份含鹵素之烯基聚合物 可有效得敎〇75壯5重量份鋅金屬。 95588.doc 200523306 七、指定代表圖： (一) 本案指定代表圖為：（無） (二) 本代表圖之元件符號簡單說明: 八、本案若有化學式時，請揭示最能顯示發明特徵的化學式： (無） 95588.doc
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| CN102690476B (zh) * | 2012-06-12 | 2014-06-04 | 华为技术有限公司 | 一种耐高温材料及其制备方法、基站天线外罩 |
| CN105255048B (zh) * | 2015-10-30 | 2018-07-13 | 永高股份有限公司 | 一种高性能环保型u-pvc管材的制备方法 |
| CN106189017A (zh) * | 2016-07-28 | 2016-12-07 | 无锡市凯达来塑胶有限公司 | 一种聚氯乙烯环保地板 |
Family Cites Families (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3067166A (en) * | 1959-09-17 | 1962-12-04 | Ferro Corp | Stabilized halogen containing vinyl resins |
| US20020103277A1 (en) * | 1995-05-10 | 2002-08-01 | Tod C. Duvall | Synergistic blend of a metal-based stabilizer or lewis acid and a free mercaptan for enhanced pvc stabilization |
| US6528566B2 (en) * | 1995-05-10 | 2003-03-04 | Rohm And Haas Company | Latent mercaptan as a heat stabilizer |
| AU682287B2 (en) * | 1995-05-10 | 1997-09-25 | Morton International, Inc. | Latent mercaptans as multi-functional additives for halogen-containing polymer compositions |
| US5969015A (en) * | 1996-09-25 | 1999-10-19 | Witco Vinyl Additives Gmbh | Monomeric and oligomeric bisphosphites as stabilisers for polyvinyl chloride |
| CA2266147A1 (en) * | 1998-03-26 | 1999-09-26 | Paul B. Adams | A latent mercaptan as a heat stabilizer |
| TW200303887A (en) * | 2002-03-07 | 2003-09-16 | Rohm & Haas | Organic based thermal stabilizers and heat stabilized polymer compositions |
-
2004
- 2004-03-30 JP JP2004099431A patent/JP2005146245A/ja active Pending
- 2004-10-18 US US10/967,863 patent/US20050107504A1/en not_active Abandoned
- 2004-11-08 TW TW093133957A patent/TW200523306A/zh unknown
- 2004-11-08 EP EP04256901A patent/EP1541626A1/en not_active Withdrawn
- 2004-11-09 BR BR0405011-8A patent/BRPI0405011A/pt not_active IP Right Cessation
- 2004-11-11 MX MXPA04011200A patent/MXPA04011200A/es unknown
- 2004-11-12 CN CNA2004100929743A patent/CN1629218A/zh active Pending
Also Published As
| Publication number | Publication date |
|---|---|
| JP2005146245A (ja) | 2005-06-09 |
| EP1541626A1 (en) | 2005-06-15 |
| MXPA04011200A (es) | 2005-10-26 |
| US20050107504A1 (en) | 2005-05-19 |
| CN1629218A (zh) | 2005-06-22 |
| BRPI0405011A (pt) | 2005-07-05 |
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