TW200522B - - Google Patents

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TW200522B
TW200522B TW081102336A TW81102336A TW200522B TW 200522 B TW200522 B TW 200522B TW 081102336 A TW081102336 A TW 081102336A TW 81102336 A TW81102336 A TW 81102336A TW 200522 B TW200522 B TW 200522B
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TW
Taiwan
Prior art keywords
water
item
barrier material
aquatic
bio
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TW081102336A
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Chinese (zh)
Original Assignee
Suzuki Sogyo Kk
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Priority claimed from JP13378391A external-priority patent/JPH04298574A/en
Priority claimed from JP3182116A external-priority patent/JPH04325048A/en
Priority claimed from JP3305751A external-priority patent/JPH0571074A/en
Priority claimed from JP30574991A external-priority patent/JPH0565431A/en
Priority claimed from JP30575091A external-priority patent/JPH0565435A/en
Application filed by Suzuki Sogyo Kk filed Critical Suzuki Sogyo Kk
Application granted granted Critical
Publication of TW200522B publication Critical patent/TW200522B/zh

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Description

A6 ___B6_ 五、發明説嗍(今) (請先閲讀背面之注意事項再塡寫本頁) 窃明昔晷 本發明傜關於一種水生物阻絕材料,特別係關於一種 防止水生物附著或黏附於船底、港口設施、或漁釣設施或 如魚網、多鈎長線、囤魚塘類之工具之物質。 與海水接觸的設施如船、港口設施、漁釣設備或包含 如魚網、囤魚塘類之工具易為水生物如鼻鉗、貽具之類所 附著,導致設施之性能、功能和耐用性等降低;傳統的方 法係Μ水生物阻絕塗料如底漆之類塗附於設施或工具之上 ,以阻絕水生物附著或是防止水生物黏附其上。 但是上述方法並不能提供令人滿意的水生物阻絕功能 或作用,同時傳統用於此目的的阻絕塗料一般含有錫化合 物,該化合物舍在海水中溶解並擴散,導致對海洋和海中 生物之污染。 發明粧沭 · 本發明係考盧先前技術的缺點,本發明者投下無數心 力謹慎研究於水生物對電剌激的影響,以防止生物附著於 水中或漁用設施或工具,同時在實質上可防止對水和生物 的污染。 經濟部中央標準局R工消费合作社印製 因此,本發明的一項目的即提供一種能有效地防止水 生物附著於水中或漁釣設腌、工具的水生物阻絕材料。 本發明另一目的係提供一種利用電剌激Μ阻絕水生物 附著於水中或漁釣設施或工具之水生物阻絕材料。 本發明另一目的係提供一種同時能防止對水和生物造 成污染之水生物阻絕材料。 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 〇 81.9.20,000 經濟部中央標準局員工消費合作社印製 ^0052.^ A6 ___B6 五、發明説明(4) 依本發明所提供的水生物阻絕材料至少包含二種物質 ,在電解質存在下會形成一電極糸統及至少一種水吸收性 樹脂。當負載於水吸收性樹脂上,該物質可添加於塗料中 〇 依本發明所提供的水生物阻絕材料,其包括至少二種 具不同電雜傾向的金屬及至少一種水吸收性樹脂。添加此 金羼及樹脂作為顔料的一部分。 同時依本發明所提供的水生物阻絕材料,其包含飼、 炭黑和至少一種水吸收性樹脂;添加該物質作為顔料的一 部分。 丽式簡置說明 配合參酌附圖,對本發明之該等目的及請多優點將由 下列詳述有更佳之瞭解;其中: 第1圖係本發明原理之視圖; 第2(a)至2(f)圖係本發明水生物阻絕材料組構於水生 物阻絕漆料中之具體實例的基本型式視圖; 第3圖係本發明水生物阻絕材料之平板試驗的透視圖 第4圖係本發明水生物阻絕材料燒杯試驗的透視圖; 第5圖係本發明水生物阻絕材料之藻類附著試驗的透 視圖; 琎昍的註钿銳明 以下參考附圖來詳述本發明。 首先,本發明之原理將依第1圖來敘述。 本纸張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 4 81.9.20,000 {請先閲讀背面之注意事項再塡寫本頁) 訂. 線. 3 ,r0ο οowA6 ___B6_ Fifth, the invention said (now) (please read the precautions on the back before writing this page) Stealing the Mingxi Dialect This invention is about an aquatic barrier material, especially about preventing aquatic organisms from adhering or sticking to the bottom of the ship , Port facilities, or fishing and fishing facilities or tools such as fish nets, multi-hook long lines, and hoarding ponds. Facilities that come into contact with seawater, such as boats, port facilities, fishing equipment, or tools such as fish nets and fish ponds, are easily attached to aquatic organisms such as nasal pliers and mussels, resulting in the performance, function, and durability of the facility. Reduce; the traditional method is to apply aquatic barrier coatings such as primers to facilities or tools to block or prevent aquatic organisms from adhering to them. However, the above method does not provide a satisfactory aquatic barrier function or effect. At the same time, traditional barrier coatings used for this purpose generally contain tin compounds, which dissolve and diffuse in seawater, causing pollution to the sea and marine organisms. Invention makeup Shu · The present invention is a shortcoming of Kaulu ’s prior art. The inventor has invested countless efforts to carefully study the impact of aquatic organisms on electrical stimulation to prevent organisms from attaching to water or fishing facilities or tools. Prevent pollution of water and living things. Printed by R Industry and Consumer Cooperatives, Central Bureau of Standards, Ministry of Economic Affairs. Therefore, an object of the present invention is to provide an aquatic organism blocking material that can effectively prevent aquatic organisms from adhering to the water or for fishing, fishing, and pickling and tools. Another object of the present invention is to provide an aquatic organism-blocking material that uses electrical stimulation to block aquatic organisms from adhering to water or fishing facilities or tools. Another object of the present invention is to provide an aquatic bio-blocking material that can prevent pollution to water and organisms at the same time. This paper scale is applicable to China National Standard (CNS) A4 specifications (210 X 297 mm). 〇81.9.20,000 Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs ^ 0052. ^ A6 ___B6 5. Description of the invention (4) According to the invention The provided aquatic bio-barrier material contains at least two substances, in the presence of electrolyte will form an electrode system and at least one water-absorbing resin. When supported on a water-absorbent resin, the substance can be added to the coating. The aquatic bio-barrier material provided by the present invention includes at least two metals with different electric propensity and at least one water-absorbent resin. Add this Jin Yi and resin as part of the pigment. Meanwhile, the aquatic bio-barrier material provided by the present invention includes feed, carbon black, and at least one water-absorbing resin; this substance is added as part of the pigment. With a brief description of Lai style, with reference to the accompanying drawings, the objectives and advantages of the present invention will be better understood from the following detailed description; among them: Figure 1 is a view of the principle of the present invention; Sections 2 (a) to 2 (f ) The figure is the basic type view of the specific example of the aquatic barrier material of the present invention structured in the aquatic barrier paint; FIG. 3 is the perspective view of the flat panel test of the aquatic barrier material of the present invention. FIG. 4 is the aquatic organism of the present invention. Perspective view of the beaker test of the barrier material; Figure 5 is a perspective view of the algae adhesion test of the aquatic barrier material of the present invention; Yin Zhuming, who is in charge of the present invention, will be described in detail below with reference to the drawings. First, the principle of the present invention will be described according to FIG. The size of this paper is in accordance with Chinese National Standard (CNS) Grade 4 (210 X 297 mm) 4 81.9.20,000 (Please read the precautions on the back before writing this page). Thread. 3, r0ο ow

A 明 説 明 發、 五 種水 二 吸 少種 至一 括少 包至 料及 材M 該質 , 物 料的 材統 絕系 阻極 物電 生成 水形 種能 1 下 係在 明存 發質 本解 電 在 在 Μ 棒 屬 〇 金 上 , 脂中 樹 W 性質 水解 吸電 於入 附插 載係 係 Μ 質棒 物屬 種金 該示 中係 其圖 > 1Χ 脂第 樹 性 電會可 個統统 — 系系 該該 , 故 統即 系 , 個位 一 電 /成之 Μ2構有 子態特 離狀具 屬該而 金若 , 成.,出 解生釋 溶產棒 漸内靥 逐棒金 中 屬 自 W 金e· 質於子 解e·電 電子使 使Μ 數 整 如 例 池 電 成 形 會 統 系 極 電 該 之 〇 成 統構 系所 極連 電接 一 極 為 電 義 定 電 特Μ, 池 質 解 電 為 作 酸 硫 稀 用 使 為 作 飼 和 鋅Μ 並 伏棒 , 屬 金 勢 肋 電 生 產 而 異 差 的 位 電 極 電 準 標 有 間 鋅 和 鐧 因 使 粉礎 屬基 金為 •ft ΪΕ 種理 二 原 在該 得Κ 亦即 用明 作發 池本 電 , 種立 該建 Ϊ 中 側統 鋅系 向之 流質 側解 飼電 自 有 得置 流間 電末 的可 中 流 料電 漆之 。 於通上 浸流具 含間工 包極和 個電施 i 在設 在使釣 係W漁 徵 、及 恃成中 一 構水 之的於 明統著 發系附 本極物 且電生 , 之水 者極絕 成電阻 完同M 所不用 均 質 物 種 兩 的 統 系 極 電 。成 下形 Hut 首 明下 說在 例存 舉質 將解 統電 系在 極 , 電先 該首 (請先閲讀背面之注意事項再塡寫本頁) 裝. 訂. .線. 經濟部中央標準局員工消費合作社印製 說 的 確 Μ 明 > 更化 。氧 屬< 金 用原 可遒 <- Μ 靥 金 成 形 Μ 態 狀 衡 平 之 極 電 + 子 Z 雜 Μ屬 係 -中屬 液金 溶-在 e 的 统 系 極 電 子 離 羼 金- 靥 金 同 不 和 〇 應考 反參 極供 電Μ 為位 下電 Μ極 ·» 電 統準 系標 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 5 經濟部中央標準局员工消費合作社印製 * A6 _ B6 五、發明説明(電極系統 L’i./Li K + /K Ca^+/Ca Na+/Na Mg2+/Mg ai3+/ai 2 + Zn /Zn 2 + Fe /Fe Cd2+/Cd Ni2+/Ni Sn2+/Sn Pb2+/Pb Cu2+/Cu Ag /Ag Hg2+/Hg 上述檷準霣極電位順序係相當於其電離序列或傾向為 供參考,電離序列通常表示如下: Li>Cs>K>Ba>Sr>Ca>Na>Mg>Be>Al>Mn>Zn>Cr>Fe>Cd>Co>Hi> Sn>Pb>(H)>Sb>Cu>Hg>Ag>Pl5>Au 本發明中至少兩種建立該電極糸統的金屬係選自上述 之電離序列;但是,其它金蹰亦可適用,該金圈可視Μ每 種金靥-金羼離子電極系統的搮準電極電位、極化傾向、 與水的反應性;傷害性等為基準的電動勢來選擇。 Μ下將說明二種金屬粉末載附其上之吸水性樹脂。 為使至少二棰金靥粉末於漆料中作用如電極,需要一 種能使金靥電離的電解質,同時,該電解質亦須作為一種 能使電子在金羼和金饜雛子間移轉的媒介;然而,漆料內 原先存在的電解質會引起電極系統的電池作用在漆料儲存 期間變質。為避免上述問題的發生,本發明實例即設計成 電極反應A clearly shows that the five kinds of water absorb two kinds of less to one package to the material and the material M. The quality of the material, the system of the material, the barrier material is electrically generated, and the water form energy can be generated. On Μ stick genus 〇gold, the fat tree in the nature of W hydrolyzes and absorbs electricity in the plug-in system of the M genus stick genus gold. The picture shows its diagram > 1X fat tree tree can be all- The system should be, so the system is the system, the M2 of the one-bit electricity / succession has a sub-state special detachment belonging to the state and Jin Ruo, Cheng. From W gold e · proton to sub-solution e · electron electrons make the M number be adjusted as in the case of the electroforming club system electrode system. The pole of the system is connected to the electrode and the electrode is set to the electrode M, pool quality The electrolysis is used for acid and sulfur dilute use for feeding and zinc M parallel bars. It is a gold potential rib electricity production and the difference of the electrode standard is marked with zinc and metal. The powder foundation belongs to the type of • ft ΪΕ Li Eryuan used the Ming as a source of electricity for this kind of plant The construction of the mid-side zinc system is directed towards the liquid side, and the feeder has its own mid-stream electric paint that can be placed between the flow ends. Yu Tongshang immersion equipment includes a work pole and a power supply. In the Yu Ming system, which is based on the fishing system W Yu Zheng and the formation of a water in the formation, the polar body is attached to the polar object and is electrically generated. The water pole has an absolute resistance that is the same as the system pole of the homogeneous species that M does not use. Under the shape of Hut, the first Ming Ming said that in the example, the quality of the system will be resolved. The first one is electricity (please read the precautions on the back before writing this page). Binding. Thread. Ministry of Economic Affairs Central Standards The bureau employee consumer cooperative printed a statement that said it was more clear. Oxygen < Gold used for original <-鈥 銥 金 formed 鈥 鈥 鈥 鈥 鈥 檚 鈥 測 鈥 檚 + child Z hetero-M genus-middle genus liquid gold dissolution-in the e-system polar electron ionization gold- 靥 金Do not agree with each other. It is necessary to test the power supply of the anti-parameter electrode. The electrode is under the electric pole. »The paper standard of the electric system quasi-specimen applies to the Chinese National Standard (CNS) Grade 4 (210 X 297 mm) 81.9.20,000 5 Central Standard of the Ministry of Economy Printed by the Bureau Staff Consumer Cooperative * A6 _ B6 V. Description of the invention (electrode system L'i. / Li K + / K Ca ^ + / Ca Na + / Na Mg2 + / Mg ai3 + / ai 2 + Zn / Zn 2 + Fe / Fe Cd2 + / Cd Ni2 + / Ni Sn2 + / Sn Pb2 + / Pb Cu2 + / Cu Ag / Ag Hg2 + / Hg The above quasi-electron potential sequence is equivalent to its ionization sequence or tendency for reference. The ionization sequence is usually expressed as follows: Li > Cs > K > Ba > Sr > Ca > Na > Mg > Be > Al > Mn > Zn > Cr > Fe > Cd > Co > Hi > Sn > Pb > (H) > Sb > Cu > H > Ag > Au In the present invention, at least two metal systems for establishing the electrode system are selected from the ionization sequence described above; however, other gold oxides are also applicable, and the gold circle can be made of each gold -Select the electromotive force based on the quasi-electrode potential, polarization tendency, reactivity with water, and harmfulness of the Jingong ion electrode system. The water-absorbent resin on which the two kinds of metal powders are attached will be described below. To make at least two powders of gold thorium act as an electrode in a paint, an electrolyte that can ionize gold thorium is needed, and at the same time, the electrolyte must also be used as a medium that can transfer electrons between the gold 羼 and gold nuggets; however The electrolyte that originally exists in the paint will cause the battery function of the electrode system to deteriorate during the storage of the paint. To avoid the above problems, the example of the present invention is designed as an electrode reaction

Li K+ Ca2 Na+ Mg2' Al3 Zn2Li K + Ca2 Na + Mg2 'Al3 Zn2

Fe ‘ Cd V· Ni 2. 2 Sn2 Pb2 Cu2 Ag + Hg2' + e~ ㈠ Li θ ^> κ + 2e Ca + e ㈠ Na + 2e Mg + 3e 4~~^ Al + 2e/ Zn + 2e'㈠ Fe + 2 θ ^~~^ Cd + 2e Ni + 2e ㈠ Sn + 2e Pb + 2 θ ^~) C u + e~ ㈠ Ag + 2e ?HgFe 'Cd V · Ni 2. 2 Sn2 Pb2 Cu2 Ag + Hg2' + e ~ ㈠ Li θ ^ > κ + 2e Ca + e ㈠ Na + 2e Mg + 3e 4 ~~ ^ Al + 2e / Zn + 2e ' ㈠ Fe + 2 θ ^ ~~ ^ Cd + 2e Ni + 2e ㈠ Sn + 2e Pb + 2 θ ^ ~) C u + e ~ ㈠ Ag + 2e? Hg

Ee/V -3.045 -2.825 «2.906 -2.714 -2.363 -1.662 -0.763 -0.4402 -0.403 -0-250 -0.136 -1.126 0.337 0.799 0.854 (請先閱讀背面之注悫事項再場寫本頁) 本紙張尺度通用中國國家標準(CNS)甲4規格(210 X 297公釐) 6 81.9.20,000Ee / V -3.045 -2.825 «2.906 -2.714 -2.363 -1.662 -0.763 -0.4402 -0.403 -0-250 -0.136 -1.126 0.337 0.799 0.854 (Please read the notes on the back and write this page again) This paper size Common Chinese National Standard (CNS) Grade 4 specifications (210 X 297 mm) 6 81.9.20,000

IjOOoSS A6 B6 説 明靥產 發金時 五將存 載 末 粉 流 電 儲狀 在膠 其成 止而 防水 致海 大吸 或會 少時 減用 以使 上在 bB _ 樹樹 性性 水水 吸吸 於該 附 樹 的 狀 膠 成 該 故 醇 烯烯 乙乙 聚化 。如氧 行 ,聚 進脂 、 水樹素 海性維 由溶纖 經水基 轉含甲 移包羧 子脂素 電樹維 使性纖 得水基 脂吸甲 之 、 的納 目酸 該烯 於丙 用聚 肽 膠 聚樹 、 伯 素拉 胳阿 r' 膠質 、 白 膠蛋 凝豆、 r 胺質 釀白 酸蛋 烯 、 丙精 、 糊 酮 、 咯素 吡維 烯纖 乙 、 聚粉 、 澱 ο 者 U11舉 (f列 物所 植上 類於 膠限 、 不 m)並 60 脂 樹 性 水 吸 ra該 t /V , 膠而 耆然 黃 ., h t π 3 c a 等可 納又 酸其 藻如 、 例 (諳先閲-*?背面之注*事項再塥寫本页) 脂酵 樹烯 之乙 性 , 收物 吸產 高化 含皂 包之 Ϊ P 酯- 甲酸 酸烯 烯丙 丙 、 i 物 酯 烯 乙 酸 乙 如 聚 共 酯 酸 烯 丙 物 聚 共 酷 酸 烯 物 聚 共 枝 接 腈 烯 丙 I 粉 0 ' 物 E 產 化 皂 腈 烯 丙 聚 等 物 聚 共 酸 烯 物 I 聚粉 共澱 ί 性 同 質 水 物 吸 的&之 統 as 同A f相 δ 極丨於 成}載 形合可 能組亦 下之、質 在等物 存/黒該 質炭 , 解和外 電鋦另 在 、., ,合上 中組脂 明之樹 發銀性 本和水 鋦吸 如之 粉 屬 金 的 同 不 向 傾 離 電 種 兩 有 加 中 料 材 之 例 實 於 〇 用 上適 脂 樹 --裝. .^T'. 泉. 經濟部中央標準局員工消費合作社印製 底底成 之 、脂 用分樹 習成該 如脂; 含樹者 包合成 可混形 , 例 而 時比等 上當物 脂適加 樹 Μ 添 性係 、 水料劑 吸漆化 於該塑 附 , 、 載 ^5劑 在而色 ,確著 料明 、 漆更料 之.,顔 末漆質 氛酯 、 香 酯松 烯 、 乙香 酸松 丙 、 - 烯 、 烯 鈣 ΚΙΓ-® 化-Τ碳 氢烯含 、乙包 烯苯料 乙 、顏 化脂質 氯樹底 、 酸該 膠烯 ., 橡丙等 化 、皂 氛烴肥 含烯番 包聚松 分化 、 石 滑 石 矽 硫 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 7 81.9.20,000 ^00522五、發明説明(8 ) A6 B6 酸鋇、黏土等; 化劑包含駄酸二 .加劑包含抗凝劑 以上是得自 ,可在漆料中形 組合;例如,該 缠原電極系統或 之電極反應和標 該著色劑包含钛白、紅色氧化物等;該塑 辛_、磷酸三甲苯_、氯化石蟠等;該添 、抗垂劑、均染劑等。 塗料中所建立之金靨-金羼離子電極系統 成之電極系統並非限於金屬-金靥離子之 電極系統又可包含氣體電極系統、氧化-其姐合等;下列為參考用之不同霄極系統 準電極電位: (諳先閱讀背面之注意事項再塡寫本頁)IjOOoSS A6 B6 shows that when the gold is produced, it will be stored in the end of the powder flow storage form in the end of the glue and it will be waterproof. The sea will be absorbed by the sea or it will be reduced to the bB _ tree tree water. The gums attached to the tree form the vinyl alcohol. Such as oxygen, polyglycerin, aquatic acid, sea-based vitamins from cellosolve through water-based transfer of carboxyl-containing carboxyl-containing liposomes to make the fiber obtain water-based fat-absorbing nails, naphthoic acid and propylene Use Polypeptide Gum Tree, Besulah R 'Gum, White Gum Egg Bean Curd Beans, R Amine-Produced Methionine, Propionine, Paste Ketone, Pyrethridine Fiber, Polypowder, Dian ο The U11 cite (listed in the f column is classified as a glue limit, not m) and 60 resin tree water absorbs the t / V, and the glue is yellow. Ht π 3 ca can be contained and acidic. , Example (read first-*? Note on the back * matters and then write this page) The ethyl ester of lipase, the yield is increased by the production of soap-containing Ϊ P ester-allyl formate, i Ethylene ethene acetate such as co-co-ester acid allyl polyco-acid enolate poly-co-grafted nitrile allyl I powder 0 'product E production of saponinonitrile allyl etc. poly co-acid ene I powder The homogeneity of the same material absorbed by the water as the same as the A f phase δ, which is the same as the possible combination, and the quality is equal to / black The quality charcoal, the solution and the external electricity are different ..,, Close the middle group of fat trees and the silvery nature of the tree and the water is absorbed by the powder. Use a suitable fat tree in 〇-installed. ^ T '. Quan. The Ministry of Economic Affairs Central Standards Bureau employee consumer cooperative printed the bottom of the bottom, and the fat branch tree should be used as a fat; the tree-containing package should be mixed and mixed The shape, for example, is more suitable than the equivalent resin, suitable for the addition of resins, the water-based agent absorbs the paint, and contains ^ 5 agents in the color, it is clear that the material is clear, and the paint is better. Unfinished paints, aromatic esters of pinene, acetoacrylic acid propionate, -ene, enecalcium ΚΙΓ-®-hydrocarbon-containing, ethylenic benzene material B, pigmented lipid chloride bottom, acid gel Ene., Ethylene-propylene equalization, soap-hydrocarbon fertilizer containing fenfan, polycondensed pine, talc, silicon, sulphur and sulphur. The paper standard is China National Standard (CNS) Grade 4 (210 X 297 mm) 7 81.9.20,000 ^ 00522 V. Description of the invention (8) A6 B6 Barium acid, clay, etc .; The chemical agent contains anionic acid. The additive contains anticoagulant. Obtained from, can be combined in the paint; for example, the original electrode system or the electrode reaction and the colorant contains titanium white, red oxide, etc .; the plastic octyl, trimethyl phosphate, chlorinated stone, etc. ; The Tim, anti-sag agent, leveling agent, etc. The electrode system formed by the gold-gold ion electrode system established in the paint is not limited to the metal-gold-ion electrode system, but can also include gas electrode system, oxidation-chief, etc .; the following are the different Xiaoji systems used for reference Quasi-electrode potential: (Be sure to read the precautions on the back before writing this page)

電極系統 Pt/I', I 2Electrode system Pt / I ', I 2

Pt/Br , Br2 Pt/Cl~, Cl2 Pt/〇2/H2〇 Ag/AgCl/Cl~ Hg/Hg C1-/C1',2i .,3 電極反應 工2 + 2e_ e2I_ Br2 + 2e~ <r->2Br' C12 1/20 AgCl 2e 2Pt / Br, Br2 Pt / Cl ~, Cl2 Pt / 〇2 / H2〇Ag / AgCl / Cl ~ Hg / Hg C1- / C1 ', 2i., 3 Electrode reaction 2 + 2e_ e2I_ Br2 + 2e ~ < r- > 2Br 'C12 1/20 AgCl 2e 2

2H >2C1 + 2e Ag 42H > 2C1 + 2e Ag 4

Cl"Cl "

Pt/V' Pt/Fe Pt/Ce V、Pt / V 'Pt / Fe Pt / Ce V,

Hg^Cl2 + 2e"*e-^2Hg + 2C1Hg ^ Cl2 + 2e " * e- ^ 2Hg + 2C1

Fe Ce 3-Fe Ce 3-

Pt/S〇4 , S2〇8: V Fe3' Ce4^ S2°f 2-Pt / S〇4, S2〇8: V Fe3 'Ce4 ^ S2 ° f 2-

Fe 2 3-Fe 2 3-

^•Ce 2e *e^2SO 4^ • Ce 2e * e ^ 2SO 4

Ee/V 0.536 1.065 1.360 1.23 0.222 0.2676 -0.256 0.77 1.612,01 經濟部中央標準局員工消费合作社印製 若電解質係驗性、金雇之電離會形成氧化物或氫氧化 物而產生不同之電極反應;在實例中,使用塗料時吸水性 樹脂會吸收海水而成膠吠,故使電子得經由所吸收之海水 移轉;因而,電解質之pH值應為8.2至8.4間之弱驗性’且 ,吸水性樹脂含有醮性金屬、鐮土族金屬等時,吸水性樹 脂所吸收的海水之pH值會再提高。下列為當電解質是驗性 時,用於實例之電極反應及標準電極電位: 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 8 81.9.20,000 * A6 B6 經濟部中央標準局貝工消费合作社印製 五、發明説明() 電極系統 Pt/H2/H2〇 Cd(OH)2/Gd Ni(〇H)./Ni 2 - ί S/S Cu/Cu(CN)2' HgO/Hg Ag2〇/Ag Pt/〇2/〇H_ AgO/Ag2〇 Cu/Cu(NH3) 電極反應 包 子而另 述電極 皆可適 由 極系統 之電極 組合將 組 + 2 2H2〇 + 2e~ 4—fH2 + 20H~ Cd(OH)2 + 2e~<-9Cd + 20H~ Ni(OH)2 + 2e~w· Ni + 20H~ S . + 2 θ ^—> S ^ Cu(CN)2~ + e~^Cu + 2CN~ HgO + H2〇 + 2e ? Hg + 20H~ Ag2〇 + H2〇 + 2e~<-^2Ag + 2〇H_ 〇2 2H2〇 + 4e_f-M0H-2AgO + HgO + 2e —^Ag2〇 + 20H· + e-㈠ C.u + 2NH.Ee / V 0.536 1.065 1.360 1.23 0.222 0.2676 -0.256 0.77 1.612,01 Printed by the Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. If the electrolyte is authentic, the ionization of gold employment will form oxides or hydroxides and produce different electrode reactions; In the example, when the paint is used, the water-absorbent resin will absorb seawater to form a rubber bark, so that the electrons must be transferred through the absorbed seawater; therefore, the pH value of the electrolyte should be weak between 8.2 and 8.4. When the reactive resin contains a metal, a Simu metal, etc., the pH of the seawater absorbed by the water-absorbing resin will increase again. The following are the electrode reactions and standard electrode potentials used in the example when the electrolyte is authentic: The paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 8 81.9.20,000 * A6 B6 Central Ministry of Economic Affairs Printed by Beigong Consumer Cooperative of the Bureau of Standards 5. Description of invention () Electrode system Pt / H2 / H2〇Cd (OH) 2 / Gd Ni (〇H) ./ Ni 2-ί S / S Cu / Cu (CN) 2 'HgO / Hg Ag2〇 / Ag Pt / 〇2 / 〇H_ AgO / Ag2〇Cu / Cu (NH3) electrode reaction buns and the other electrodes can be adapted by the electrode combination of the electrode system + 2 2H2〇 + 2e ~ 4—fH2 + 20H ~ Cd (OH) 2 + 2e ~ < -9Cd + 20H ~ Ni (OH) 2 + 2e ~ w · Ni + 20H ~ S. + 2 θ ^ — > S ^ Cu (CN) 2 ~ + e ~ ^ Cu + 2CN ~ HgO + H2〇 + 2e? Hg + 20H ~ Ag2〇 + H2〇 + 2e ~ <-^ 2Ag + 2〇H_ 〇2 2H2〇 + 4e_f-M0H-2AgO + HgO + 2e — ^ Ag2〇 + 20H · + e-㈠ Cu + 2NH.

Cu(NH3)2 3Cu (NH3) 2 3

Eeg/V -0.827 -0.809 -0.72 -0.447 -0.429 .0.098 0.345 0.401 0.607 -0.12 括電極組合之電極系統係一種其中任一電極釋出電 一電極則 系統外, 用於本發 前述說明 。由防止 系統係包 詳述如后 合之一提 接收電子的氧化-還原反應;所除上 只要能進行氧化還原反應之任何電極系統 明。 得知,不同物質能在電解質存在下形成電., 水生物附著之作用和經濟效率來看,最佳 含銅和銀之組合或是铜和炭黑之組合;該 供一個本發明之實例,係闞於一種包括至 少兩種電離傾向不同之金屬和至少一種吸水性樹脂而為顔 料之一部份的水生物阻絕材料。 另一組合提供了本發明另一實例,係闞於包括銅、炭 黑和至少一種吸水性樹脂而成顔料之一部份的水生物阻絕 材料。 所K須注意的是兩實例各提供了具有水生物阻絕作用 本纸張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) ¥ 81.9.20,000 ----------------------〔----裝ί ^---ΤΓ------^ (請先閱讀背面之注念事項再塡寫本頁) ' * . .· -Eeg / V -0.827 -0.809 -0.72 -0.447 -0.429 .0.098 0.345 0.401 0.607 -0.12 The electrode system including the electrode combination is a kind of electrode where any electrode discharges electricity. One electrode is outside the system and is used in the foregoing description of the present invention. The prevention system package details the oxidation-reduction reaction that receives electrons as described in the latter one; except for any electrode system that can carry out the oxidation-reduction reaction. It is known that different substances can form electricity in the presence of an electrolyte. From the perspective of the role of aquatic organisms adhesion and economic efficiency, the best combination of copper and silver or copper and carbon black; this is an example of the present invention, It is a kind of aquatic bio-barrier material including at least two metals with different ionization tendency and at least one water-absorbent resin as part of the pigment. Another combination provides another example of the present invention, which is based on an aquatic bio-barrier material comprising copper, carbon black and at least one water-absorbent resin as part of a pigment. It should be noted that the two examples are provided with aquatic biological barrier effect. The paper size is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) ¥ 81.9.20,000 --------- ------------- 〔---- 装 ί ^ --- ΤΓ ------ ^ (Please read the notes on the back before writing this page) '*. . ·-

^005SS A6 B6 經濟部中央標準局员工消費合作社印製 五、發明説明(l〇) 之顔料,該顔料可成漆料的一部分。 在各實例中,上述物質可用做吸水性樹脂,以聚乙烯 酵作為吸水性樹脂最適合;而明確地說,當聚乙烯酵加入 顔料或漆料時,聚乙烯醇會吸收海水而成膠狀,使電子e一 在兩金属間或在鋦粉和炭黑間移轉,且呈現固有之足Μ防 止或阻絕水生物之附著的黏著(將詳述於后)。同時,適為 調整聚乙烯酵的皂化度和聚合度,Μ使聚乙烯酵使用期限 或其有效顯示所需之水生物阻絕作用的時間可依需要來調 整。 表 1 係Nippon Gosei Kagaku Kabushiki Kaisha公司 所製之"G0HSEH0L"聚乙烯酵的皂化度和聚合度成矩陣式 之組合且可視該些組合製備成不同的等级,其中L表示聚 合度低於1,000, Μ表示聚合度介於1000至1500以及Η表 示聚合度高於1500;而Κ表,示局部分皂化型式(78.5至 81.5moI%), Α表示局部皂化型式(86.5至89.0〇1〇1%), 0表示完全皂化型式(98.4至97.7111〇1%)以及忖表示完全 皂化型式(98.5至lOOmol% )。Μ_L 聚合度 皂化度 L Μ Η Κ 較佳 G A H 最隹 本紙張尺度通用中國國家標準(CNS)甲4规格(210 X 297公釐) 1 〇 81.9.20,000 (請先閲讀背面之注念事項再塡寫本頁) —裝_ ,11. •^^-. 0052¾ 五、發明説明(1 1) 表 於 低 或 A6 B6 看 1 來mo 性.5 造98 製於 和高 間或 期 N 用為 使度 由化 示 皂 顯和 楚者 清00 L 為 度 合 聚 烯 乙 聚 之 者 ο 度— ο 6 意 5 ^ Ε 1 δ 注 於 t 須 考 高 , *在Μ 合 — 所 聚醇 ¾烯。 而 j 次 乙 , ; 居 3聚U 用w 之 下 % 明 1 化 發10末 本.5粉 於 0〇 易 適至不 最.5其 酵78使 於 介 度 化 皂 和 Μ 足 至 加 增 會 及 高 度 化 皂 是 的 烯 乙 聚 之 高 度 合 聚 及 低 度 化 皂 及M 醇 〇 烯明 乙發 聚本 之於 低 用 度適 合較 聚醇 4月 不近 故附 , 或 水角 於下 溶右 易 1 醇表 烯於 乙位 聚各 之而 近 ,’ 附用 或作 角絕 上阻 左物 1 生 表水 於現 位顯 各久 持 材 〇 絕‘ 係阻 關物 之生 間水 法之 。 製料 化與顔 末末成 粉粉明 易屬發 不金本 而及示 水醇所 於烯圖 溶乙⑴ 難聚2( 極明至 BK 說 C0 酵將2( 烯下第 乙以如 聚 之 或 子 粒 a)鼠' 2(烯 第乙 在聚 ; 與 式係 形 4 同末 不粉 具黑 可炭 料或 3 d 粉 2 銀或 及C) /1\ 2 2 粉第 铜在 中開 圖分 (請先閲讀背面之注意事項再項寫本頁) 2 2 粉第 銅在 中覆 圖包 粉 銀 和 或 末粉 粉飼 黑 , 炭中 或圖 4 2 5 和 酵 2 烯粉 乙銅 聚或 為 3 起粉 一 銀 係和 第 如 合 配 將 造 製 〇 的 覆料 包顏 5 之 醇式 烯形 乙各 聚或 為料 起材 一 絕 係阻 4 物 末生 粉水 黑 炭 經濟部中央標準局員工消費合作社印製 而傾 然離 , 罨 明 同 說不 舉具 例種 來兩 合少 組至 的何 銀任 與至 飼用 之應 示得 所樣 圖同 e)法 /IV 2 方 及造 C)製 2(之 、 述 a)下 a 佈 /( 2 散 第別 如分 有 3 具粉 ; 銀 等和 合 2 組粉 之鋦 黑將 炭由 和係 飼料 及材 Μ 絕 , 姐 合物 組生 的水 屬之 金式 之型 向圖 粉塗 飼或 出蓋 取覆 中包 液 5 溶醇 自烯 後乙 然聚 , 為 中成 5 形 疲 , 溶之 醇燥 烯乾 乙熱 聚加 性 , 水 3 之粉 開銀 分和 於 2 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 1 1Χ 81.9.20,000 ^0052¾ ^0052¾ 經濟部中央標準局員工消費合作社印製 A6 B6 五、發明説明(12) 覆之粒子,然後散佈於塗料中而製成如第2(a)圃所示之材 料1 〇 另外,材料1可Μ將銀粉2和銀粉3在混合進行時一 起加入聚乙烯酵5中,使粉末散佈於聚乙烯酵5中而製得 ;該法使塗覆有該醇5之飼粉2粒子和Μ該酵5包覆之銀 粉3之粒子,在混Μ僅由聚乙烯酵5形成的粒子時會出現 〇 第2(c)圖所示之水生物阻絕材料係由將銅粉2和銀粉 3 —起散佈於聚乙烯醇5中或將預先混合的飼粉2和銀粉 3的混合物散佈於該酵5中而製得,以形成為聚乙烯酵5 共同包覆之銅粉2和銀粉3之粒子,然後,取出該粒子, 加熱乾燥之,之後,將粒子散佈於漆料中而形成如第2(c) 圖之材料。 在第2(a)至2(f)圖中,,飼粉2和銀粉3在聚乙烯酵5 内之分散劑在可用適合的分散器如磁土球磨機、維心研磨 機等完成。 上述之各製法係用於實驗室而非其他;該材料之大量 生產可Μ冷凍乾燥法來做,該法包括如將飼粉和銀粉分散 於吸水性樹脂中以製成液體混合物,然後將混合物噴至冷 凍室而立即形成冷凍粒子,再將顆粒真空乾燥之步驟。 另外,量產亦可用櫬械表面改良技術例如,可將鋦粉 、銀粉和吸水性樹脂在處理室中於氣相中散佈時,曝露於 主要由衝擊應力構成之櫬械能和熱能,Μ使铜粉和銀粉附 著於吸水性樹脂上,所Μ該粉末可著附或固定於該樹脂内 本纸張又度適用中國國家標準(CNS)甲4規格(210 X 297公釐) ι 〇 81.9.20,000 -------------------------裝——1---#------線---, <請先閲-*?背面之注*事項再塡寫本页) ( . f iJ〇052S A6 _B6_ 五、發明説明(1$ 而達成;為達該目的亦可用嗔砂等方法,此外,如曰本專 利公開公報第8 3 0 2 9 / 1 9 8 7號、日本專利公開公報第2 6 2 7 3 / 1987虢Μ及第298443/1987等所揭示的技術亦可適用,該 處理方法可用 Kabushiki Kaisha Kara Kikai Seisakusho 公司所製之”Nara Hybridization System”機器, Kabush ik i K a i s h a Hosokawa Micron 公司製造之" Ansmill”機器等來完成。 如上所製備之含有至少二種金靥和至少一種吸水性樹 脂的顔料或含有銅、炭黒和至少一種吸水性樹脂的顔料接 予加入漆料中,產生本發明之生物砠絕材料。 本發明上述之水生物阻絕材料之構成可做為底漆;當 底漆塗覆於船底而與海水接觸時,金羼之一會以離子型式 溶解於海水中而呈現電池作用,遂使本發明材料會由於離 子的形成、電流的產生以及,水成分的改變之彼此協合地 4 影響,而有效地阻止水生物附著著船底上;同時,在材料 中加入之聚乙烯醇會使聚乙烯醇本身呈現自清作用;且經 (諳先閲諳背面之注意事項再填.駕本頁) i裝- 1T- •線. 物 生 水 制 控 得 度 合 聚 和 度 化 皂 。 的限 醇年 烯用 乙使 聚的 之要 需需 所料 整材 調絕 由阻 經濟部中央標準局員工消費合作社印*1衣 之 屬 金 藉 之 〇 述 述 簡詳 所予 前將 於下 由M 〇 係 , 下著者 如附成 述之達 詳物所 將生子 點水離 優絕屬 之阻金 明 ,出 發先釋 本首而 解 溶 靥 的 ^ ^ » $若i 釋 該 M K 解 大 ^ 0 J 溶 力 分 I 能 部ne受 會 + 接 靥+C 子 金Me電 之 Φ 或 中Me向 質態傾 解狀離 電衡電 在平 一 , 在另 言持有 而保存 般 Μ 中 一 、 質 子解 離電 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81,9.20,000 13^ 005SS A6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 5. The pigment of the invention (l〇), which can be part of the paint. In each case, the above substances can be used as water-absorbent resins, and polyvinyl yeast is the most suitable for water-absorbent resins; and specifically, when polyvinyl yeast is added to pigments or paints, polyvinyl alcohol will absorb sea water to form a gel , So that the electron e transfers between two metals or between the powder and carbon black, and exhibits an inherent enough M to prevent or block the adhesion of aquatic organisms (will be described in detail later). At the same time, it is appropriate to adjust the saponification degree and polymerization degree of polyethylene leaven. M allows the use period of polyethylene leaven or the time required for its effective display of aquatic bio-blocking effect to be adjusted as required. Table 1 is the combination of "G0HSEH0L" made by Nippon Gosei Kagaku Kabushiki Kaisha company and the degree of polymerization of polyethylene yeast into a matrix and can be prepared into different grades based on these combinations, where L means that the degree of polymerization is less than 1,000, Μ indicates that the degree of polymerization is between 1000 and 1500 and Η indicates that the degree of polymerization is higher than 1500; and K indicates a partial saponification pattern (78.5 to 81.5mol%), and Δ indicates a partial saponification pattern (86.5 to 89.0〇10%) , 0 represents the complete saponification pattern (98.4 to 97.7111〇1%) and the mean represents the complete saponification pattern (98.5 to 100mol%). Μ_L Degree of polymerization Saponification degree L Μ Η Κ Better GAH Most standard paper size General Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 1 〇81.9.20,000 (Please read the notes on the back before reading Write this page) —install _, 11. ^^-. 0052¾ V. Description of invention (1 1) Table 1 for low or A6 B6, see 1 to mo. 5 Make 98 for and period N for use The degree is indicated by Huaxian soap and Chu Zheqing. 00 L is the degree of polyethene ethylene polymerization. Degree — ο 6 meaning 5 ^ Ε 1 δ Note that at t, you must take a high level. And j times B ,; ranks 3 poly U, use w below%, Ming 1 Huafa 10 end. 5 powder at 0〇 is easy to adapt to not the most. 5 its fermentation 78 makes the media soap and Μ enough to increase The meeting and high-level soaps are the high-polymerization and low-level soaps of ethene and low-grade soaps and M alcohols. The low-cost polymers are suitable for low-cost applications because they are not close to April, or the water angle is below Dissolve right Yi 1 Alcohol epiene in the B-position is close to each other, 'Attached or used as a corner of the upper left barrier 1 Raw surface water in the current position shows a long-standing material 〇 結' is the raw water of the barrier The law. Materialization and powder formation at the end of the powder are easy to produce without gold, and show that the water alcohol is soluble in ethylenic acid. ⑴ Difficult to polymerize 2 (Extremely bright to BK said C0 leave will be 2 Or seed a) rat '2 (eneth second in the polymerization; with the formula 4 is not powdered with black charcoal or 3 d powder 2 silver or C) / 1 \ 2 2 powder second copper in the picture (Please read the precautions on the back first and then write this page) 2 2 powder copper in the middle cover drawing powder silver and or powder powder black, charcoal or picture 4 2 5 and leaven 2 Or 3 pieces of powder-silver series and the first Ruhe will be prepared by the coating of the coating 5 of the alcohol-based ethylenic ethylene or the raw material for a series of 4 resistance of the raw powder water black carbon Ministry of Economic Affairs Printed by the Central Standards Bureau's employee consumer cooperatives, he said that he will not give any examples. He Yinren and the feed should be shown in the same way as the e) method / IV 2 Fang Hezao C) make 2 (of, a) under a cloth / (2 powders, there are 3 powders; silver and other 2 groups of powdered black powdered carbon and feed materials and materials. , The water of the sister composition group is of the gold type. Apply the powder to the drawing powder or take out the cover to take the enveloping liquid. 5 The dissolved alcohol is polymerized after the olefin, which is a form of fatigue. The dissolved alcohol is dried. Additives of B-Heat, the powder of silver 3 and the silver content of 2 are in accordance with the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 1 1Χ 81.9.20,000 ^ 0052¾ ^ 0052¾ employees of the Central Standards Bureau of the Ministry of Economic Affairs Printed by the consumer cooperative A6 B6 V. Description of the invention (12) The coated particles are then dispersed in the paint to make the material shown in the second (a) nursery 1 〇 In addition, the material 1 can be silver powder 2 and silver powder 3 When the mixing is carried out, it is added to the polyvinyl yeast 5 together, and the powder is dispersed in the polyvinyl yeast 5 to prepare; this method makes the feed powder 2 particles coated with the alcohol 5 and the silver powder 3 coated with the yeast 5 Particles will appear when mixed with particles formed only of polyvinyl yeast 5. The water bio-barrier material shown in Figure 2 (c) consists of copper powder 2 and silver powder 3 dispersed in polyvinyl alcohol 5 or A mixture of pre-mixed feed powder 2 and silver powder 3 is dispersed in the yeast 5 to form a polyvinyl yeast 5 co-package The particles of copper powder 2 and silver powder 3, then, take out the particles, heat and dry them, and then disperse the particles in the paint to form the material as shown in Figure 2 (c). In the 2 (a) to 2 ( f) In the figure, the dispersant of feed powder 2 and silver powder 3 in polyethylene yeast 5 can be completed with a suitable disperser such as a magnetic ball mill and a centripetal grinder. The above preparation methods are used in laboratories but not others; mass production of this material can be done by lyophilization, which includes, for example, dispersing feed powder and silver powder in a water-absorbent resin to make a liquid mixture, and then mixing the mixture Spray into the freezer to immediately form frozen particles, and then vacuum-dry the particles. In addition, mass production can also be used to improve the surface of the machine. For example, when the powder, silver powder and water-absorbing resin are dispersed in the gas phase in the processing chamber, they are exposed to the machine energy and heat energy mainly composed of impact stress. Copper powder and silver powder are attached to the water-absorbent resin, so the powder can be attached or fixed in the resin. The paper is also applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) ι 〇81.9. 20,000 ------------------------- install ---- 1 --- # ------ LINE ---, < please read first -*? Remarks on the back of the page will be written on this page) (. F iJ〇052S A6 _B6_ Fifth, the description of the invention (1 $ to achieve; to achieve this purpose can also use sand and other methods, in addition, such as the Japanese patent disclosure The techniques disclosed in Gazette No. 8 3 0 2 9/1 9 8 7 and Japanese Patent Publication No. 2 6 2 7 3/1987 and 298443/1987 are also applicable. The processing method can be Kabushiki Kaisha Kara Kikai The "Nara Hybridization System" machine made by Seisakusho, and the "Ansmill" machine made by Kabush ik i Kaisha Hosokawa Micron, etc. are completed. At least two pigments of gold and at least one water-absorbent resin or pigments containing copper, carbon black and at least one water-absorbent resin are added to the paint to produce the bio-barrier material of the present invention. The composition of the material can be used as a primer; when the primer is applied to the bottom of the ship and comes into contact with seawater, one of the Jin Yi will dissolve in the seawater in the form of ions to exhibit the battery function, so that the material of the present invention will be due to the formation of ions, The generation of electric current and changes in water composition affect each other in synergy with each other, and effectively prevent aquatic organisms from adhering to the bottom of the ship; at the same time, the polyvinyl alcohol added to the material will cause the polyvinyl alcohol itself to exhibit a self-cleaning effect; and After (keep reading the precautions on the back before filling in. Drive this page) i equipment-1T- • line. The bio-water system can control the degree of polymerization and degree of soap. It is expected that the adjustment of the whole material will be printed by the Ministry of Economic Affairs Central Standards Bureau Employee Consumer Cooperative * 1. The description of the clothing is provided by the gold borrower. The brief description will be given by the M series. The next author is attached. Reach In the details, Jinming, who gave birth to a child by water, is the only one who has a good resistance, so let ’s first explain the original and dissolve it. ^ ^ »$ 若 i 释 此 MK 解 大 ^ 0 J Solubility points I Energy department ne receive + connect T + C The Φ of the sub-Me-Me electricity or the Me-dissolved ionization charge to the mass state is at the same level, and it is held and stored in another language. M. I. Proton dissociation electricity This paper size applies to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 81,9.20,000 13

IjOOoSS A6 B6 經濟部中央標準局員工消费合作社印製 五、發明説明(i 4) 化學物質,則會進行連串之該物質接收由金屬釋出之霣子 e'再將電子傳送至海水中氯離子等的轚化學反應,而導 致氛氣的產生;此會破壞原有之平衡狀態Me<-Men++ne-, 而使反應向右進行,促使金鼷離子不斷地釋放至電解質中 ,遂使本發明之材料能長期由離子的釋放得持續阻絕水生 物之附著。 若該金屬是銅,則在CUeCu2 + +2e_之反應中,由於截 、炭黑等物質的存在,反應會向右進行,藉此而持續阻絕 水生物之附著。 如第2(a)和2(b)圖所示的水生物阻絕材料之構成係飼 和電離傾向小於銅或炭黑之金靥分別為聚乙烯醇所包覆; 所M,電子的移轉係視飼和電離傾向小於銅的金屬或炭黑 間之相遇機率而定;各第2(e)和2(f)圖之材料之構成為飼 和電離傾向小於銅的金靥或’炭黑共為聚乙烯醇所包覆,在 該结構中,聚乙烯酵會吸收海水使電子移轉發生,而大幅 促使銅雛子釋放至海水中。在第2(e)圖中,所示之飼粉2 和銀粉3係彼此分開,然而,該粉末亦可彼此接觸,此情 況可用銅銀合金。 由金屬溶解而產生電流之阻絕水生物附著的作用將於 下詳述。 如上所述,在提高飼離子釋出之條件下,由铜之離子 化所釋出的電子會移轉至電離傾向小於鋦之金騙(如銀), 然後再饋入海水中之氯雔子等而導致氯氧等的生成。該反 應機構係一電池作用,使電流在電離傾向不同的金羼間流 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) 81.9.20,000 .^------#·------漆 <諳先閱筇背面之注意事項再填寫本頁)( ' ' 五、發明説明(15) A6 B6 ,地 時樣 同同 著極 附正 之成 物形 生係 水氮 絕的 阻成 地生 效側 有 一 〇 得之著 即屬附 流金之 電小物 的較生 生向水 產傾絕 所離阻 電得 通在亦 絕機在 阻碰係 物相流 生屬電 水金 , 各之中 之小料 示較材 所向之 圖傾圖 ) I ) b 0 f Ο 2 電 2 生 和和和成 C0 铜 Φ 即 2 視 2 後 第係第水 生各海 產在收 的 流 電 之 中 料 材 ,吸 而始 因開 ; 醇 定烯 而乙 率聚 水 絕 阻 而 變 改 或 良 改 的 分 成 中 水 海 於 由 明 〇 說用 將作 , 之 著著 接附 物 生 用之 作成 等生 解側 電屬 於金 由之 分小 成較 之向 中傾 水離 海電 起在 引於 會由 生 , 產時 的同 流 ., 電化 述變 上生 發 而 附水 料海 材近 絕附 阻該 物 , 生而 水因 得 ; 使成 , 組 解其 溶變 中改 水或 海分 在成 會其 氣更 氯變 的會 極水 正海 成的 構近 而 用 作 清 白 有 具 酵 。烯 著乙 附聚 的因 物 會 生/料 水材 絕絕 阻阻 M物 足生 , 水 化明 變發 的本 成 組 使時 會 同 水 ·’ 海性 收黏 吸的 之料 酵材 烯至 乙著 聚附 , 會 之物 ^a生 詳水 ; 制 用限 作或 絕止 阻阻 物有 生具 水面 現表 圼其 (請先閲讀背面之注意事項再塡寫本頁) .裝. #— . .線. 經濟部中央標準局员工消費合作社印製 2 損 第耗 各漸 在逐 . 會 身水 本使 醇而 烯 , 乙制 聚控 ,M 中 加 料得 材後 一 減 每出 之釋 示的 所子 圖離 —銅 對 故 d /IV 2 至 在 制 控 度 化 皂 的 酵 。烯 久乙 持聚 用當 作 , 絕時 阻同 物 生IjOOoSS A6 B6 Printed by the Consumers ’Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs 5. Description of the invention (i 4) Chemical substances, a series of substances will be received to receive the eels e’ released from the metal and then send the electrons to chlorine in seawater The chemical reaction of ions, etc., leads to the generation of atmosphere; this will destroy the original equilibrium state Me < -Men ++ ne-, and cause the reaction to proceed to the right, prompting the continuous release of gold ions into the electrolyte. The material of the present invention can be released from ions for a long time to continuously block the attachment of aquatic organisms. If the metal is copper, in the reaction of CUeCu2 + + 2e_, the reaction will proceed to the right due to the presence of substances such as carbon black and carbon black, thereby continuously blocking the adhesion of aquatic organisms. As shown in Figures 2 (a) and 2 (b), the composition of the aquatic bio-barrier material is as follows: the gold tartium with a tendency to ionize less than copper or carbon black is coated with polyvinyl alcohol; M, electron transfer It depends on the chance of encounter between the metal and carbon black whose feeding and ionization tendency is less than copper; the material of each figure 2 (e) and 2 (f) is composed of gold or carbon black whose feeding and ionization tendency is less than copper Coated with polyvinyl alcohol, in this structure, polyvinyl yeast absorbs seawater to cause electron transfer, which greatly promotes the release of copper chicks into the seawater. In Fig. 2 (e), the feed powder 2 and the silver powder 3 shown are separated from each other, however, the powder may also be in contact with each other. In this case, a copper-silver alloy may be used. The effect of the current generated by the dissolution of the metal to block the attachment of aquatic organisms will be described in detail below. As mentioned above, under the condition of improving the release of feed ions, the electrons released by the ionization of copper will be transferred to gold scams (such as silver) whose ionization tendency is less than that of Li, and then fed into the chlorine chloride in seawater This leads to the formation of chlorine and oxygen. The reaction mechanism acts as a battery, so that the current flows between the gold and gold with different ionization tendency. The paper standard is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 81.9.20,000. ^ ------ # · ------ Lacquer < first read the precautions on the back of the book, then fill out this page) ('' V. Description of the invention (15) A6 B6, the ground pattern is the same as the very attached thing On the effective side of the water and nitrogen barrier, there is a good book on the side that is a relatively small object that belongs to the gold deposit, and it is deprived of aquatic products. Electricity water gold, the small material in each shows the map of the direction of the material) I) b 0 f Ο 2 electricity 2 Shenghehehe C0 copper Φ that is 2 after viewing 2 the first aquatic marine products are receiving The material of the galvanic current is absorbed and opened because of the absorption; the alcohol is fixed and the water is blocked by the water, and the change or good change is divided into the middle water sea. The use of the power generation and other energy generation side electricity belongs to Jinyou. Compared with the water pouring from the sea to the middle, the power is drawn to Huiyousheng, The same flow of time, the electrochemical state is changed to grow and the sea material with water material is almost never attached to the object, and the water is due to the formation; the water is changed in the solution and the sea water is changed into chlorine and chlorine The meeting water is very close to the sea and is used as innocence and leaven. The agglomeration of ene attached to B is due to the growth of the material / the water material is absolutely blocked from the growth of the M material, the hydration and the change of the group will make the same with the water. A book is attached, the meeting ^ a raw water; the use of restricted or endless barriers has a raw water surface (please read the precautions on the back before writing this page). —.. Line. Printed by the Employees ’Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 2 Loss and consumption are gradually being eliminated. The diagram shown shows the separation of copper to d / IV 2 to control the fermentation of soap. Ene Jiujie's polymerization should be used as a barrier to the same organism

和 上 K 間步 % 1 01進 5Π1得 1.性 久 持 % 1 之 ΠΙΟ用 5作 7 絕 於阻 。 介物造 度生製 化水的 皂則料 或,材 ,00該 0015於 10於益 於高助 低度且 度合 , 合聚菩 聚及改 至 本紙張又度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9,20,000Entering 5Π1 with% 1 01 from the upper K is 1. Sexual persistence ΠΙΟ of% 1 uses 5 as 7 to be absolutely ineffective. Soaps made of biochemical water can be made of materials or materials, 00, 0015 to 10, which benefit from a high degree of help and a low degree of conformity. The combination of polyjuju and the change to this paper are also applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 81.9,20,000

i;0052S A6 B6 經濟部中央標準局S工消費合作社印製 五、發明説明(1δ) 參考下列實例,將對更易於瞭解本發明,然而,下述 實例只在說明本發明,而非對本發明加κ限制。 下列貿例1和2中,作為吸水性樹脂的聚乙烯酵係 Nippon Gosei Kagaku Kabushiki Kaisha公司製造,商 品名為'' Gohsenol GM-14"皂化度:98.4至97.7莫耳%, 聚合度:1000至1500;作為電離傾向不同·之金屬係使用 Yamaishi Kinzoku Kabushiki Kaisha公司製造的組粉(VA -200,平均粒徑:5 至l〇w 及Mitsui KinzokuKogyo Kabushiki Kaisha公司製造的飼粉(MF-D3,平均粒徑:13 w);漆料成分係使用丙烯酸樹脂。 g例1 將1份鋁粉、1份飼粉與50份10%水性Gohsenol GM-14溶液混合K製備混合物、然後將其攪拌乾煉,再以咖啡 研磨櫬和球磨機辗碎;形成的混合物予篩漶處理,取出所 得之粒徑為100/i或更小之粒子;混合進行時,40份粒子 係分散於6 0份丙烯酸樹脂内,而得到本發明之水生物阻絕 材料。 管例2 製備兩10%水性0(^3^〇10^4溶液,將1份鋁粉加 入25份之上述溶液之一並予混合,再將1份飼粉加入另一 25份之上述溶液並予混合,以製得兩混合液;然後,將各 形成的混合液搅拌乾烽,再K咖啡研磨機和球磨櫬碾碎; 磨碎的混合物分別予以篩漶處理,而得到粒徑為l〇〇w或 更细之粒子;將各20份之粒子分散於60份丙烯酸樹脂中, 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) 16 81.9.20,000 (諳先閱讀背面之注念事項再塡寫本頁) -丨裝· 訂· -4.i; 0052S A6 B6 Printed by the S Industry and Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy V. Description of the invention (1δ) With reference to the following examples, it will be easier to understand the present invention. However, the following examples are only illustrative of the invention, not the invention. Add κ restriction. In the following Trade Examples 1 and 2, the polyethylene enzyme system Nippon Gosei Kagaku Kabushiki Kaisha as a water-absorbent resin is manufactured under the trade name "Gohsenol GM-14" saponification degree: 98.4 to 97.7 mol%, and the polymerization degree: 1000 to 1500; As a metal system with different ionization tendency, use the group powder (VA-200, average particle size: 5 to 10w manufactured by Yamaishi Kinzoku Kabushiki Kaisha company and the feed powder (MF-D3, average produced by Mitsui Kinzoku Kogyo Kabushiki Kaisha company Particle size: 13 w); Acrylic resin is used as the paint component. G Example 1 1 part of aluminum powder, 1 part of feed powder and 50 parts of 10% aqueous Gohsenol GM-14 solution are mixed K to prepare a mixture, which is then stirred and dried , Then crushed with a coffee grinder and a ball mill; the resulting mixture is screened, and the resulting particles with a particle size of 100 / i or smaller are taken out; when mixing is performed, 40 parts of the particles are dispersed in 60 parts of acrylic resin To obtain the aquatic biological barrier material of the present invention. Pipe Example 2 Prepare two 10% aqueous 0 (^ 3 ^ 〇10 ^ 4 solutions, add 1 part of aluminum powder to 25 parts of one of the above solutions and mix, then add 1 Part of the feed powder, add another 25 parts of the above solution And pre-mixed to prepare two mixed liquids; then, the resulting mixed liquid was stirred dry, then K coffee grinder and ball mill to grind; the ground mixture was separately screened to obtain a particle size of l 〇〇w or finer particles; disperse 20 parts of each particle in 60 parts of acrylic resin, the paper size is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) 16 81.9.20,000 (Jixian Read the notes on the back and then write this page)-丨 Installation · Order · -4.

<jG052S A6 B6 五、發明説明(17) 而得本發明之水生物阻絕材料。 下述霣例3至7中,係製備第2(a), 2(c), 2(e)和2( f)圖之各水生物阻絕材料。在製備第2(a)圔之材料時中, 作為吸水性樹脂的粉狀琴乙烯酵係Nippon Gosei Kasaku Kabushiki公司之產品;商品名為· Gohsenol GM-14"; 而在製備第2(b)和2(c)圖之材料中,係用粉狀聚乙烯醇之 水溶液作為吸水性樹脂;該些實例中,係同時使用由 Mitsui Kinzoku Kogyo Kabushiki Kaisha公司製造的飼 粉(MF-D3,平均粒徑為 13α£), Fukuda kinzoku Hakuhun Kogyo Kabushiki Kaisha公司製造的銀粉(Silcoat Agc-B )fD Dai-Nippon Ink Kasaku Kogyo Kabushiki Kaisha公 司製造商品名Donacarbo 〃之炭黑;此外,丙烯酸樹脂 係作為漆料之成分。 啻例3 , 將10份粉狀Gohsenol GM-14、 1份鋦粉和1份銀粉分 散混合於30份丙烯酸樹脂內,製備成第2(a)圖所示之水生 物阻絕材料。 g俐4 經濟部中央標準局員工消费合作社印製 {請先閲讀背面之注意事項再塡寫本頁) —裝· 製備兩10%之水性Gohsenol GM-14溶液,將1份铜粉 加入9份之上述溶液之一並混合之,再將1份銀粉加入9 份之另一溶液並混合之,而得兩混合液。然後將兩所形成 的混合液攪拌乾烽,再Μ咖啡研磨機和球磨櫬碾碎;接著 ,將各磨碎的混合物分予篩濾處理,而得到粒徑為100w^ 更细之粒子;將各10份之粒子分散混合於60份丙烯酸樹脂 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 17 81.9.20,000 A6 B6 五、發明説明(13 中 » 而 形 成 第 2 ( C ) 圓 之 水 生 物 阻 絕 材 料 0 莆 例 製 備 1 0 % 之 水 性 Go h s e η 〇 1 GM- 14溶 液 將 1 份 鋦 粉 和 1 份 炭 黑 加 入 18份 之 上 述 溶 液 中 * 混 合 成 混 合 液 1 然 後 9 將 形 成 的 混 合 液 攪 拌 乾 燥 9 再 Η 咖 啡 研 磨 機 和 球 磨 im m 碾 碎 > 磨 碎 的 混 合 物 予 Μ 篩 m 處 理 9 而 得 到 粒 徑 為 100 w或更细 之 粒 子 接 著 將 1 0 份 之 粒 子 分 散 混 合 於 3 0 份 丙 烯 酸 樹 脂 中 而 形 成 第 2(f) 圖 之 水 生 物 阻 絕 材 料 0 m 例 () 製 備 10 % 之 水 性 Go h s e η 〇 1 GM- 14溶 液 將 1 份 綢 粉 和 1 份 銀 粉 加 入 ΐδ份 之 上 述 溶 硖 中 > 混 合 成 混 合 液 > 然 後 $ 將 形 成 的 混 合 液 攢 拌 乾 燥 t 再 Μ 咖 啡 研 磨 m 和 球 磨 44¾ m 碾 碎 9 將 磨 碎 的 混 合 物 予 Μ 篩 m 處 理 t 而 得 到 粒 徑 為 100 u或更 细 之 粒 子 接 著 將 20份 之 粒 1 •子 分 散 混 合 於 30 份 丙 1»« 酸 樹 脂 中 9 而 形 成 第 2 ( e ) ΓΒΠ 圃 之 水 生 物 阻 絕 材 料 0 富 1 7 製 備 10 % 之 聚 乙 烯 醇 (商標為G oh s e no 1 KH -1 7, N ip P 〇 (請先閱讀背面之注念爭^再塡寫本頁) —裝_ .π·. .丨%, 經濟部中央標準局员工消費合作社印製< jG052S A6 B6 V. Description of the invention (17) The aquatic biological barrier material of the present invention is obtained. In the following Examples 3 to 7, the aquatic bio-barrier materials of Figures 2 (a), 2 (c), 2 (e) and 2 (f) were prepared. In the preparation of the second (a) 圔 material, as a water-absorbent resin powdered piano vinyl enzyme Nippon Gosei Kasaku Kabushiki company products; trade name · Gohsenol GM-14 "; and in the preparation of the second (b) In the material shown in Figure 2 (c), an aqueous solution of powdered polyvinyl alcohol is used as the water-absorbent resin; in these examples, the feed powder (MF-D3, average particle size manufactured by Mitsui Kinzoku Kogyo Kabushiki Kaisha Co., Ltd. is used at the same time Diameter 13α £), silver powder (Silcoat Agc-B) manufactured by Fukuda kinzoku Hakuhun Kogyo Kabushiki Kaisha company fD Dai-Nippon Ink Kasaku Kogyo Kabushiki Kaisha company trade name Donacarbo 〃 carbon black; in addition, acrylic resin is used as paint ingredient. In Example 3, 10 parts of powdered Gohsenol GM-14, 1 part of powder and 1 part of silver powder were dispersed and mixed in 30 parts of acrylic resin to prepare an aquatic barrier material as shown in Figure 2 (a). g Li 4 Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs (please read the precautions on the back before writing this page) — Pack · Prepare two 10% aqueous Gohsenol GM-14 solutions, add 1 part of copper powder to 9 parts One of the above solutions is mixed, and then 1 part of silver powder is added to 9 parts of the other solution and mixed to obtain two mixed solutions. Then, the two mixed liquids are stirred and dried, and then crushed by a coffee grinder and a ball mill; then, each grinded mixture is sieved to obtain finer particles with a particle size of 100w ^; Each 10 parts of particles are dispersed and mixed in 60 parts of acrylic resin. The paper size is in accordance with Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 17 81.9.20,000 A6 B6 V. Description of the invention (13 in »and form the second (C) Yuanshui Biological Barrier Material 0 Putuo 10% aqueous Go hse η 〇1 GM-14 solution 1 part of noodle powder and 1 part of carbon black were added to 18 parts of the above solution * mixed into mixed solution 1 Then 9, the resulting mixture is stirred and dried. Then, the coffee grinder and ball mill are crushed. The ground mixture is treated with M sieve m to obtain particles with a particle size of 100 w or finer, and then 10 parts The particles are dispersed and mixed in 30 parts of acrylic resin to form the water bio-barrier material shown in Figure 2 (f). m Example () Prepare 10% aqueous Go hse η 〇1 GM-14 solution. Add 1 part of silk powder and 1 part of silver powder to 1δ part of the above-mentioned dissolved knot > mix into a mixed solution > then $ will form the mixed solution Mix and dry t, then coffee grind m and ball mill 44¾ m, grind 9 and grind the grinded mixture to sieve m to obtain particles with a particle size of 100 u or finer, then disperse 20 parts of particles 1 In 30 parts of propylene 1 »« acid resin 9 to form the 2nd (e) ΓΒΠ garden water bio-barrier material 0 rich 1 7 Preparation of 10% polyvinyl alcohol (trademark G oh se no 1 KH -1 7, N ip P 〇 (please read the controversy on the back ^ first and then write this page) — installed _ .π · .. 丨%, printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs

Gosei Kagaku Kabushiki Kaisha公司製造;其聚合度大 於Gosenol GM-14)溶液,將1份鋦粉和1份銀粉加人18份 之上述水溶液中,予Μ混合成混合液,然後攪拌乾燥之, 再以咖啡研磨機和球磨櫬碾碎;將磨碎的混合物予以篩滤 處理,而形成粒徑為100w或更细之粒子;接著將20份之 粒子分散混合於30份丙烯酸樹脂中,而得到第2(e)圖之水 生物阻絕材料。 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 1 8 81.9.20.000 A6 B6 五、發明説明(1边 在下述實例8至19中,係使用Mitsui Kinzoku Kogyo Kabushiki Kaisha公司製造的鋦粉(MF-D3,平均粒 .徑 13m )和 Fukuda Kinzoku Hakuhun Kogyo Kabushiki Kaisha公司製造的銀粉(Silcoat Agc-B),該二粉末具有 不同之電離傾向;此外,亦可使用DaiNippon Ink Kagaku Kogyo Kabushiki Kaisha公司製造的炭黑( Donacarbo);吸水性樹胞係使用 Nippon Gosei Kagaku Kabushiki Kaisha公司製造的兩種聚乙烯醇,商品名分 為、'0〇113611〇1〖[1-17"(甚化度:78.5至31.5莫耳%,聚 合度:1500以上)和"0〇1^6{1〇11<[-05"(皂化度:98.5莫 耳%以上,聚合度:1 00 0K下)。 (接下頁) <請先閲讀背面之注*事項再塡寫本頁) —裝. 訂· .線. 經濟部中央標準局员工消費合作社印製 81.9.20,000 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) A6 B6 逋、發明説明(2Ρ) 窨例8 將 1 份 飼 粉 1 份 銀 粉 和 10 份Go h s e η 〇 1 ΚΗ - 17粒 子 混 合 1 將 形 成 的 混 合 液 分 散 混 合 於 30份 的丙 烯 酸 樹 脂 中 f 而 得 本 發 明 的 水 生 物 咀 絕 材 料 〇 宥 例 9 將 1 份 銅 粉 1 份 銀 粉 和 10 份Go h s e η ο 1 NL - 05粒 子 混 合 1 將 形 成 的 混 合 液 分 散 混 合 於 30份 的丙 烯 酸 樹 脂 中 9 而 得 本 發 明 的 水 生 物 阻 絕 材 料 0 管 例 1 〇 製 傅 兩 10 % 之 水 性 Go h s e η ο 1 KH- 17溶 液 0 分 別 將 1 份 飼 粉 和 1 份 銀 粉 加入 分開 的 9 份 上 述 之 溶 液 中 > 混 合 之 然 後 > 將 彤 成 的 混合 液予 以 攪 拌 乾 煉 > 再 >λ 咖 啡 研 磨 機 和 球 磨 櫬 予 >x 碼 碎 ;將 各徑 磨 碎 的 混 合 物 予 以 篩 濾 處 理 » 而 得 到 粒 徑 為, 100 ί £或更细之粒子; ;將各1 0 份 之 粒 子 一 起 分 散 混 合 於 30份 丙 烯酸 樹脂 9 而 得 本 發 明 的 水 生 物 阻 絕 材 料 0 實 例 11 <請先閲讀背面之注念事項再填寫本頁) 丨裝. ,ΤΓ·. .—泉- 經濟部中央標準局8工消費合作社印製 製備兩10¾之水性Gohsenol NL-05溶液。 分別將1份飼粉和1份銀粉加入9份上述之溶液中, 混合之;然後,將形成的混合液予Μ搅拌乾燥,再Μ咖啡 研磨櫬和球磨機予以碾碎;將各經磨碎的混合物予以篩滅 處理,而得到粒徑為l〇〇w或更细之粒子;接著將各1〇份 之粒子一同分散混合於30份丙烯酸樹脂中,而得本發明的 水生物阻絕材料。 本纸張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) 20 81.9.20,000 -003¾¾ A6 _ B6 經濟部中央標準局β工消費合作社印製 五、發明説明(2 1 ) 奮俐1 2 製 備 10 % 之 水 性 Go h s e η ο 1 ΚΗ- 17溶 液 0 將 1 份 飼 粉 和 1 份 銀 粉 加 入 18 份 之 上 述 溶 液 中 , 混 合 之 然 後 9 將 形 成 的 混 合 液 攪 拌 乾 燥 > 再 Μ 咖 啡 研 磨 櫬 和 球 磨 機 碾 碎 9 將 磨 碎 的 混 合 物 予 >λ 篩 m 處 理 ) 而 得 到 粒 徑 為 1 00 w或更细之 粒 子 接 著 將 20 份 粒 子 分 散 混 合 於 30 份 丙 烯 酸 樹 脂 中 > 而 得 本 發 明 之 生 物 阻 m 材 料 0 莆 例 13 製 備 10 % 之 水 性 Go h s e η 0 1 NL- 05 溶 液 〇 將 1 份 鋦 粉 和 1 份 銀 粉 加 入 1 8 份 之 上 述 溶 液 中 » 混 合 之 m 後 > 將 形 成 的 混 合 液 搜 拌 乾 燥 1 再 Μ 咖 啡 研 磨 機 m 和 球 磨 概 傲 碾 碎 » 將 磨 碎 的 混 合 物 予 Μ 篩 m 處 理 而 得 到 粒 徑 為 100 W或更细之 粒 子 接 著 將 20 份 粒 子 分 散 混 合 於 30 份 丙 烯 酸 樹 脂 中 而 得 本 發 明 之 水 生 物 阻 絕 材 料 〇 苜 例 14 將 1 份 m 粉 1 份 銀 粉 和 10份 Go h s e η 0 ] KH - 17粒 子 混 合;將形成的混合液分散混合於30份的丙烯酸樹脂中,而 料 材 絕 阻 物 生 水 該 得 例 啻 子 , 粒中 05脂 L-樹 N酸 01烯 丙 的 Go份 份30 10於 和合 黑混 炭散 份分 。 1 液料 、 合材 粉混絕 飼的阻 份成物 1 形生 將將水 ; 該 合得 η e s (請先閲讀背面之注念事項'再塡寫本頁) 例 兩 備 製 S h ο G 性 水 之 液 溶 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 11 2 81.9.20,000Manufactured by Gosei Kagaku Kabushiki Kaisha; its degree of polymerization is greater than Gosenol GM-14) solution, 1 part of noodle powder and 1 part of silver powder are added to 18 parts of the above aqueous solution, mixed with M to form a mixed liquid, then stirred and dried, and then The coffee grinder and the ball mill are crushed; the ground mixture is sieved to form particles with a particle size of 100w or finer; then 20 parts of the particles are dispersed and mixed in 30 parts of acrylic resin to obtain the second (e) Picture of aquatic bio-barrier material. This paper scale is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 1 8 81.9.20.000 A6 B6 5. Description of the invention (1 side in the following examples 8 to 19, using Mitsui Kinzoku Kogyo Kabushiki Kaisha company The manufactured powder (MF-D3, average grain size. 13m in diameter) and the silver powder (Silcoat Agc-B) manufactured by Fukuda Kinzoku Hakuhun Kogyo Kabushiki Kaisha Company have different ionization tendency; in addition, DaiNippon Ink Kagaku can also be used Carbon black (Donacarbo) manufactured by Kogyo Kabushiki Kaisha; the water-absorbing tree cell line uses two types of polyvinyl alcohol manufactured by Nippon Gosei Kagaku Kabushiki Kaisha, and the trade name is divided into '0〇113611〇1 〖[1-17 " ( Degree of change: 78.5 to 31.5 mol%, degree of polymerization: 1500 or more) and " 0〇1 ^ 6 {1〇11 < [-05 " (saponification degree: 98.5 mol% or more, degree of polymerization: 1 00 0K Bottom) (Continued on the next page) < Please read the note on the back of the item * and then write this page)-Packing. Ordering. Line. Printed by the Staff Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs 81.9.20,000 This paper size is suitable for China National Standard (CNS) A 4 specifications (210 X 297 mm) A6 B6 逋 、 Description of the invention (2P) Example 8 Mix 1 part of feed powder 1 part of silver powder and 10 parts of Go hse η 〇1 ΚΗ-17 particles 1 Mix the resulting mixture in 30 parts Acrylic resin f is obtained from the aquatic biomaterial of the present invention. Example 9 1 part of copper powder 1 part of silver powder and 10 parts of Go hse η ο 1 NL-05 particles were mixed 1 The resulting mixture was dispersed and mixed in 30 parts 9 of acrylic resin to obtain the aquatic bio-barrier material of the present invention 0 tube example 1 〇Fu two 10% aqueous Go hse η ο 1 KH-17 solution 0 1 part of feed powder and 1 part of silver powder were added to separate 9 In the above solution > after mixing > the mixture of Tongcheng is stirred and dried > again > λ coffee grinder and ball milling pre-preparation > x yard crushing; the mixture of each diameter grind is sieved Filtration treatment » For, 100 ί £ or finer particles ;; disperse and mix 10 parts of each particle in 30 parts of acrylic resin 9 to obtain the aquatic biological barrier material of the present invention 0 Example 11 < Please read the notes on the back first (Fill in this page again) 丨 Installed., ΤΓ ·...-Quan-Printed and prepared two 10¾ aqueous Gohsenol NL-05 solution by the Ministry of Economic Affairs, Central Standards Bureau, 8 Industrial and Consumer Cooperatives. Add 1 part of feed powder and 1 part of silver powder to 9 parts of the above solution, mix them; then, stir and dry the resulting mixed liquid, and then grind it with a coffee grinder and a ball mill; grind each The mixture is subjected to sieving treatment to obtain particles with a particle size of 100w or finer; then 10 parts of each particle is dispersed and mixed together in 30 parts of acrylic resin to obtain the aquatic biological barrier material of the present invention. This paper scale is applicable to the Chinese National Standard (CNS) Grade A (210 X 297 mm) 20 81.9.20,000 -003¾¾ A6 _ B6 Printed by the Central Standards Bureau of the Ministry of Economic Affairs β Industrial and Consumer Cooperatives 5. Description of invention (2 1) Li 1 2 Prepare 10% aqueous Go hse η ο 1 ΚΗ-17 solution 0 Add 1 part of feed powder and 1 part of silver powder to 18 parts of the above solution, mix and then 9 Stir and dry the resulting mixture > then M The coffee grinder and the ball mill 9 grind the ground mixture to > λ sieve m) to obtain particles with a particle size of 100 w or finer, and then disperse and mix 20 parts of the particles in 30 parts of acrylic resin > Obtained the bioresistance material of the present invention. 0 Example 13 Preparation of 10% aqueous Go hse η 0 1 NL-05 solution. 1 part of noodle powder and 1 part of silver powder were added to 18 parts of the above solution »after mixing m> ; Mix and dry the formed mixture 1 and then coffee grinder m and Grinding by ball milling »The ground mixture is treated with Μ sieve m to obtain particles with a particle size of 100 W or finer, and then 20 parts of particles are dispersed and mixed in 30 parts of acrylic resin to obtain the water biological barrier material of the present invention 〇Califerous Example 14 Mix 1 part of m powder, 1 part of silver powder and 10 parts of Go hse η 0] KH-17 particles; disperse and mix the resulting mixture in 30 parts of acrylic resin, and the material barrier is raw water. For example, in the granules, the Go portion of the 10 fats of the 05 fat L-tree N acid 01 allyl in the granules is 30 to 10 parts of the blended black blended carbon of Hehe. 1 The mixed ingredients of liquid material and compound powder are the best ingredients. 1 The form will be water; the combined η es (please read the notes on the back of the first 'and then write this page) Example two preparations S h ο G The water-soluble paper size of this paper is in accordance with Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 11 2 81.9.20,000

200〇^S A6 B6 五、發明説明(2 2 ) (請先閱讀背面之注意事項再塡寫本頁) 分別將1份鋦粉和1份炭黑粉末加入9份上述之溶液 中,混合之;然後,將形成的混合液予以攪拌乾煉,再Μ 咖啡研磨櫬和球磨櫬予Μ碾碎;將各經磨碎的混合物予Μ 篩濾處理,而得到粒徑為ΙΟΟμ或更细之粒子;接著將各 10份之粒子分散混合於30份丙烯酸樹脂中,而得該水生物 阻絕材料。 審例1 7 製備兩10%之水性Gohsenol NL-05溶液。 分別將1份銅粉和1份炭黑粉末加入9份上述之溶液 中,混合之;然後,將形成的混合液予K搜拌乾燥,再以 咖啡研磨機和球磨櫬予以碾碎;將各經磨碎的混合物予Μ 篩濾處理,而得到粒徑為100m或更细之粒子;接著將各 10份之粒子分散混合於30份丙烯酸樹脂中,而得該水生物 阻絕材料。 啻例1 8 經濟部中央標準局员工消費合作社印製 製備10¾之水性Gohsenol KH-17溶液。將1份銅粉和 1份炭黑加入18份之上述溶液中,混合之;然後,將形成 的混合液攪拌乾燥,再以咖啡研磨櫬和球磨機碾碎,將磨 碎的混合物予以篩瀘處理,而得到粒徑為l〇〇w或更细之 粒子;接著將20份之粒子分散混合於30份丙烯酸樹脂中, 而得該水生物阻絕材料。200〇 ^ S A6 B6 5. Description of the invention (2 2) (Please read the precautions on the back before writing this page) Add 1 part of the powder and 1 part of the carbon black powder to 9 parts of the above solution, mix them ; Then, the resulting mixture is stirred and dried, and then coffee milling and ball milling are crushed by M; the ground mixture is filtered by M to obtain particles with a particle size of 100 μ or finer ; Then disperse and mix 10 parts of each particle in 30 parts of acrylic resin to obtain the aquatic biological barrier material. Example 1 7 Two 10% aqueous Gohsenol NL-05 solutions were prepared. Add 1 part of copper powder and 1 part of carbon black powder to 9 parts of the above solution and mix them; then, mix and dry the resulting mixed liquid with K, then crush it with a coffee grinder and ball mill; The ground mixture is subjected to sieve filtration treatment to obtain particles with a particle size of 100 m or less; then 10 parts of each particle is dispersed and mixed in 30 parts of acrylic resin to obtain the aquatic bio-barrier material. Example 1 8 Printed by an employee consumer cooperative of the Central Bureau of Standards of the Ministry of Economic Affairs. Prepare 10¾ aqueous Gohsenol KH-17 solution. Add 1 part of copper powder and 1 part of carbon black to 18 parts of the above solution and mix them; then, stir and dry the resulting mixture, then grind it with a coffee grinder and a ball mill, and sieve the ground mixture To obtain particles with a particle size of 100w or finer; then 20 parts of the particles are dispersed and mixed in 30 parts of acrylic resin to obtain the aquatic bio-barrier material.

奮俐1 Q 製備10¾之水性Gohsenol NL-05溶液。將1份飼粉和 1份炭黒加入18份上述之溶液中,混合之;然後,將形成 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 〇 ? 81.9.20,000 fj 0052¾ A6 B6 經濟部中央標準局員工消費合作社印製 五、發明説明(2 3) 的混合液攪拌乾燥,再K咖啡研磨櫬和球磨櫬碾碎,將磨 碎的混合物予Μ篩濾處理,而得到粒徑為100w或更细之 粒子;接著將20份之粒子分散混合於30份丙烯酸樹脂中, 而得該水生物阻絕材料。 在下述實例20至25中,係使用Mitsui Kinzoku Kogyo Kabushiki Kaisha公司製造的銅粉(MF-D3,平均粒 徑:13 ϋ )和 Fukuda Kinzoku H a k u h u n Kogyo Kabushiki Kaisha公司製造的銀粉(Silcoat Agc-B),該二粉末具有 不同的電離傾向;此外,亦使用DaiNippon Ink Kagaku Kogyo Kahushiki Kaisha公司製造的炭黑(Donacarbo); 在實例20至23中所用之吸水性樹脂係使用Nippon Gosei Kagaku Kabushiki Kaisha公司製造的三種聚乙焼醇,其 一商品名為'' Gohsenol GM-14"(皂化度:G ,聚合度: M)實例24所用者之商品名為,、' Gohsenol 〇-17"(皂化度 :K :聚合度:H);而實例25所用者之商品名則$ Gohsenol NL-05"(皂化度:N ,聚合度:L)。 g例?0 製備兩10%之水性Gohsenol GM-14溶液。將1份飼粉 加入9份之上述溶液之一中並予混合,再將1份銀粉加入 9份上述之另一溶液中並予混合;而得到兩混合液;然後 ,將各所形成的混合物攪拌乾燥,再Μ咖啡研磨機和球磨 機碾碎;磨碎的混合物分予篩濾處理,而得到粒徑為100 Μ或更细之粒子;而得該水生物阻絕材料。 (諳先閱讀背面之注-事項再塡寫本頁) .裝· " 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 23 81.9.20,000 A6 B6 經濟部中央標準局員工消费合作社印制狄 五、發明説明(24) 製 備 兩 10 % 之 水 性 Go h s e η 〇 1 CM- 14溶 液 0 將 1 份 飼 粉 加 入 g 份 之 上 述 溶 液 之 一 中 並 予 混 合 9 再 將 1 份 銀 粉 加 入 9 份 上 述 之 另 —— 溶 液 中 並 予 混 合 9 而 得 到 二 個 混 合 液 然 後 t 將 各 所 形 成 的 混 合 物 攪 拌 乾 煉 9 再 Μ 咖 啡 研 磨 櫬 和 球 磨 機 碼 碎 » 磨 碎 的 混 合 物 分 予 篩 濾 m 理 » 而 得 到 粒 徑 為 10 0 μ或更姻之粒子 而得該水生物阻絕材料。 窨 例 22 製 備 10 % 之 水 性 Go h s e η ο 1 G M- 14溶 液 0 將 1 份 飼 粉 和 1 份 銀 粉 加 入 18份 之 上 述 溶 液 中 » 並 混 合 之 然 後 * 將 形 成 的 混 合 液 攪 拌 乾 燦 9 再 咖 啡 研 磨 櫬 和 球 磨 櫬 碾 碎 > 將 磨 碎 的 混 合 物 予 >λ 篩 m 處 理 » 而 得 到 粒 徑 為 1 00 w或更迪之 粒 子 = 即 得 該 水 生 物 阻 絕 材 料 〇 實 例 2 3 製 備 10 % 之 水 性 Go h s e n/y 1 G M- 14溶 液 〇 將 1 份 m 粉 和 1 份 炭 黑 加 入 18份 之 上 述 溶 液 中 * 並 混 合 之 飫 後 t 將 形 成 的 混 合 液 攪 拌 乾 燥 9 再 咖 啡 研 磨 櫬 和 球 磨 櫬 碾 碎 9 將 磨 碎 的 混 合 物 予 以 篩 m 處 理 參 而 得 到 粒 徑 為 100 //或更细之 粒 子 即 得 該 水 生 物 阻 絕 材 料 0 S. 例 2 4 製 備 10 % 之 水 性 Go h s e η ο 1 ΚΗ- 17溶 液 0 將 1 份 銅 粉 和 1 份 銀 粉 加 入 18份 之 上 述 溶 液 中 » 並 混 合 之 然 後 9 將 形 成 的 混 合 液 攢 拌 乾 燥 » 再 咖 啡 研 磨 機 和 球 磨 櫬 碾 碎 > 將 磨 碎 的 混 合 物 予 >λ 篩 m 處 理 9 而 得 到 粒 徑 為 100/ 』或更细之 粒 子 即 得 該 水 生 物 阻 絕 材 料 0 (請先閱讀背面之注意事16再塡寫本頁) 2 4 本纸張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000Fenli 1 Q prepared 10¾ aqueous Gohsenol NL-05 solution. Add 1 part of feed powder and 1 part of carbon black to 18 parts of the above solution and mix them; then, the paper size will be applied to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm). 81.9.20,000 fj 0052¾ A6 B6 Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economy 5. The mixed liquid of the invention description (2 3) is stirred and dried, and then crushed by K coffee grinding and ball milling, and the ground mixture is subjected to Μ screening treatment. Then, particles with a particle size of 100w or finer are obtained; then 20 parts of the particles are dispersed and mixed in 30 parts of acrylic resin to obtain the aquatic bio-barrier material. In the following Examples 20 to 25, copper powder (MF-D3, average particle size: 13 ϋ) manufactured by Mitsui Kinzoku Kogyo Kabushiki Kaisha and silver powder (Silcoat Agc-B) manufactured by Fukuda Kinzoku H akuhun Kogyo Kabushiki Kaisha were used. , The two powders have different ionization tendency; In addition, the carbon black (Donacarbo) manufactured by DaiNippon Ink Kagaku Kogyo Kahushiki Kaisha is also used; The water-absorbent resin used in Examples 20 to 23 is manufactured by Nippon Gosei Kagaku Kabushiki Kaisha Three kinds of polyethylene alcohol, one of which is named "Gohsenol GM-14" (Saponification degree: G, degree of polymerization: M) The commercial name of the person used in Example 24, "Gohsenol 〇-17" (Saponification degree: K : Degree of polymerization: H); and the trade name used in Example 25 is $ Gohsenol NL-05 " (degree of saponification: N, degree of polymerization: L). g case? 0 Prepare two 10% aqueous Gohsenol GM-14 solutions. Add 1 part of feed powder to one of 9 parts of the above solution and mix, then add 1 part of silver powder to 9 parts of the other solution and mix; and get two mixed liquids; then, stir each formed mixture After drying, it is crushed by a coffee grinder and a ball mill; the ground mixture is subjected to sieving treatment to obtain particles with a particle size of 100 M or finer; and the aquatic bio-barrier material is obtained. (Be sure to read the note on the back-matters before writing this page). Installed & " This paper scale is applicable to China National Standard (CNS) A 4 specifications (210 X 297 mm) 23 81.9.20,000 A6 B6 Central Standard of the Ministry of Economic Affairs The bureau employee consumer cooperative printed Di Wu. Description of the invention (24) Preparation of two 10% aqueous Gohse η 〇1 CM-14 solutions 0 Add 1 part of feed powder to one of g of the above solutions and mix 9 before adding 1 part of the silver powder is added to 9 parts of the other above-the solution is mixed and mixed 9 to obtain two mixed liquids and then t each of the resulting mixtures is stirred and dried 9 and then the coffee is ground and the ball mill is crushed »The ground mixture is divided Sieve filter »to obtain particles with a particle size of 100 μ or more to obtain the aquatic biological barrier material. Example 22 Preparation of 10% aqueous Go hse η ο 1 G M-14 solution 0 Add 1 part of feed powder and 1 part of silver powder to 18 parts of the above solution »and mix it then * Stir the resulting mixture to dry 9 Re-coffee grinding and ball milling &grinding; The ground mixture was subjected to > λ sieve m treatment »to obtain particles with a particle size of 100 w or more = to obtain the aquatic bio-barrier material. Example 2 3 Preparation 10% water-based Go hsen / y 1 G M-14 solution. 1 part of m powder and 1 part of carbon black are added to 18 parts of the above solution * and the mixture is mixed t the resulting mixture is stirred and dried 9 coffee ground榇 和 球磨 榇 磨碎 9 The ground mixture was sieved to obtain a particle size of 100 // or finer particles to obtain the aquatic bio-barrier material 0 S. Example 2 4 Preparation of 10% aqueous Gohse η 1 ΚΗ-17 solution 0 Add 1 part of copper powder and 1 part of silver powder to 18 parts of the above solution »and mix it then 9 Save the resulting mixture and dry it» Re-coffee grinder and ball mill grinding> will grind The crushed mixture is processed with > λ sieve m to obtain particles with a particle size of 100 / ”or finer to obtain the aquatic biological barrier material 0 (please read the notes on the back 16 before writing this page) 2 4 copies The paper size is in accordance with Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 81.9.20,000

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25 五、發明説明() 奩例2S 之 和形將细 確分實 個RP水足 物上 水 於a試, 粉將,更 Μ料僅 三iFA之 生施1¾海 覆in杯下 飼,碎1 -材·’ 將 S物 水設 J於。塗11燒件 份後碾JU3驗的驗 係ho動 般之 置形係te.,條 1然櫬ο 試到試 ,ιρ生用一中> 係情Tle形實 將.,磨10予得水 言 d 水使為海片板之料so情真 。之球為 分7海 而Mna毅驗樣於U基板材將的於 液合和徑 料至和 確fcfli有試一附 該基絕後杯係 5?§混機粒 材1驗 明Jel察該壺易 ;於阻然燒義 -0並磨到 絕例試 .,fi,let觀;藤其πιβ分著物,於意 ML-,研得 胆實著。驗 W01K 況與且2η部附生上著其 1Μ中啡而。物將附驗試生is,狀其 ,1.央絲水面附, no液咖 ,枓生;類試水 m 分v.之是物由中足 -底絲驗 sen溶 K 理材水用藻水海3C部上由生經形察示內足試 Ohs述再處絕的作、海為}為央板理水係圓觀所和其助 Go上,滅阻得之驗作即cm長中基的種OS的以圖周察補 性之燥篩物51¾著試料法:5殼板於OS一phT期9内觀的 水 g 乾M生25附杯材方 有形著ph的di枓星第的以驗 之18拌予水至物燒的示 具圓附di用 a材一 如V底試 0%入攪物該 1 生、到所ί 將個 a a 習in各内驗杯杯板 10加液合得例水驗得圖形再每s)in所11於箱試燒於平 備粉合混即實絕試258圓,於SU11驗te定族杯水置為 製銀混的;將阻板至第明上定yste試le固水燒海0S作 份的碎子 其平8 發板固(ble著so劑或 滿ph係 1.成磨粒 定作例 本基平絲so附。著槽 裝di驗 經濟部中央標準局員工消費合作社印製 (請先閲汸背面之注念事項再塡寫本頁) -装- 訂. 本纸張尺度適用中國國家標準(CNS)甲4規格(210 X 297父釐) 2 5 81.9.20,000 經濟部中央標準局8工消费合作社印製 Α6 ___Β6 五、發明説明(26) 使Soletellina diphos自由移動以觀察其附著狀況。 第10圖為藻類附著試驗,係將水生物阻絕材料T塗至 .15minX IOOibibX 1.5niaWFRP«P 上,然後將板 P 與藻類 S-起放至裝滿海水之燒杯內一涸月或更久,以親察藻類附著 於平板P之情形;附著於船底之有殻水生動物等同時會滋 養芽胞附著於船底;若滿類已附著於船底時,芽胞亦易附 著其上;然而若藻類不易附著於船底,則芽胞亦不能附著 其上,使有水生動物等不易獲得滋養;藻類附著實驗的意 義即在此。 海水試驗係將塗覆有之水生物阻絕材料之試驗板沉浸 於海水中一定的時間,Μ観察水生物附著於板上的情形。 平板試驗之用於試驗的樣本數為6個;燒杯試驗為4 個;藻類試驗為2個。 在各實例20至25的海水/試驗中,係將20份各實例的水 生物阻絕材料和30份丙烯酸樹脂塗料捏合然後塗至試驗板 上。 測試结果示於表2至表4。 表_2l- .實例平板試驗 燒杯試驗 藻類附著試驗 1 3個死亡 1傾死亡 燒瓶内藻類死亡 2個未能伸 3涸未能 無藻類附著 出足絲 伸出足絲 1個足絲位於 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 (諳先閱讀背面之注意事項再塡寫本頁) .裝. .ΤΓ.. 26 9..> cto 5οο25 5. Description of the invention () The sum of the 2S cases will be accurately divided into two RP waters. The water will be added to a test, the powder will be changed, and the material will be only three. 1-Cai · 'Set the S material water to J. After coating 11 burned parts, the test system of JU3 was rolled, and the dynamic system was te., The article 1 was 榇. The test was tried, ιρ 生 用 一 中> The relationship of Tle was real., Mill 10 to get water Word d The water makes the material of the sea sheet so true. The ball is divided into 7 seas and Mna Yi inspects the sample on the U-based plate. The Yuhehe and the pellets are made to the fcfli. A test is attached to the base cup 5? § Mixer granules 1 It is verified that Jel inspects the pot Yi; Yu Zhenran burns Yi-0 and grinds to the outlier test., Fi, let view; Teng Qi πιβ divided object, Yi Yi ML-, researched courageously. Test W01K condition and the 2η part is attached with its 1M Chinese coffee. The material will be attached to the test sample is, like it, 1. The surface of the central silk is attached, no liquid coffee, lansheng; the class test water m points v. The substance is from the middle foot-bottom silk test sensation K material water algae In the Department of Water and Sea 3C, the work of physical meridian and physical examination, the internal foot test, Ohs, and then the execution, and the sea are} for the central board of the water system circle and its help Go, and the test of the resistance is cm long. The type of OS is based on the weekly inspection of the supplementary dry sieve 51 ¾ sample method: 5 shell plates in the OS-phT period 9 internal view of the water g dry M Sheng 25 with cup material square shaped ph Take the test 18 and mix it with water until it burns. The display is round with a material like the V bottom test. 0% into the stirrer. 1 life, go to the place. Aa Xi in each internal test cup cup plate 10 add liquid If the water is tested, the graphics will be tested again every s) in. The test is burned in a box and mixed with the prepared powder in the box. The test is 258 yuan, and the water in the SU11 test is set to a silver-made mix; The first Ming dynasty yste trial le shui shui sea 0S as a broken piece of its flat 8 hair plate solid (bleed with so agent or full ph system 1. into an abrasive grain is set as an example of the basic flat wire so attached. With grooved di Printed by the Employee Consumer Cooperative of the Central Bureau of Standards of the Ministry of Economics and Economics (please read the notes on the back of 汸 before writing this page) -install- order . This paper scale is applicable to China National Standard (CNS) A4 specifications (210 X 297%) 2 5 81.9.20,000 Printed by the Central Bureau of Standards of the Ministry of Economic Affairs 8 Industrial and Consumer Cooperatives Α6 ___ Β6 V. Description of invention (26) Soletellina diphos Move freely to observe its attachment status. Figure 10 is the algae adhesion test, which is to apply aquatic barrier material T to .15minX IOOibibX 1.5niaWFRP «P, and then put the plate P and algae S-to the beaker filled with seawater Within a month or longer, to observe the situation where algae are attached to the flat plate P; shelly aquatic animals attached to the bottom of the ship will also nourish the spores attached to the bottom of the ship; if the full class has attached to the bottom of the ship, the spores will also easily attach However, if algae are not easily attached to the bottom of the ship, the spores cannot be attached to it, making it difficult for aquatic animals to get nourished; the significance of the algae adhesion experiment is here. The plate was immersed in sea water for a certain period of time, and the aquatic organisms were attached to the plate. The number of samples used in the plate test was 6; the beaker test was 4; the algae test was 2. In the seawater / test of each of Examples 20 to 25, 20 parts of the aquatic barrier material of each Example and 30 parts of acrylic resin paint were kneaded and then applied to the test board. The test results are shown in Tables 2 to 4. Table_2l-. Example flat plate test beaker test algae adhesion test 1 3 deaths 1 tilt death Algae death in flask 2 failed to stretch 3 failed to attach algae without algae sticking out extending filaments 1 filament is located in this paper size for China National Standard (CNS) A 4 specifications (210 X 297 mm) 81.9.20,000 (know the precautions on the back before writing this page). Installed. ΤΓ .. 26 9 .. > cto 5οο

AA

6 B (2上 明般 説 明 發 % 五 2 亡 死 個 5 能絲 未足 個出 1 伸 蓍 附 類 0 無 部 全 個亡 4 死 (請先閲讀背面之注意事項再填寫本頁) 3 3 2 亡能絲 死未足 個個出 3 亡能絲 死未足 個個出 後物 月狀 個黏著 1 有附 絲上 足殻 個於 1 位 —裝. 4 亡 死 個 部 全 個 4 後 月 個 訂. 能絲 未足 涸出 死 物 狀 黏著 有附 • . 經濟部中央標準局員工消費合作社印製 5 6 亡能絲 死未足 個個出 4 伸 2 亡 死 個 能 未 個 5 部 全 個 4 亡 死 部 全 個 4 亡 死 後物 月狀 個黏著 一 有附 後物 月狀 個黏 一 有 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐〉 27 81.9.20,000 B6 五、發明説明(28) 7 絲部 足全 出 個亡 伸 6 死 部 全 個亡 4 死 黏蓍 分附 著 部物 附有狀 (請先閲¾背面之注念事項再塡寫本頁) 經濟部中央標準局R工消费合作社印製 本纸張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐) 28 81.9.20,0006 B (2 clearly stated that the hair is sent out. 5 2 deaths and 5 deaths without enough filaments 1 extensions of Achillea spp. 0 no deaths all 4 deaths (please read the precautions on the back before filling out this page) 3 3 2 Dead energy silk is not enough to die out. 3 Dead energy silk is not fully out of the body. The shape of the moon is sticky. 1 There is a silk upper foot shell in one position-equipment. 4 All deaths are all after 4 months. A set. Nothing can die out. There is a sticky attachment.. Printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. 5 6 Nothing can be done. 4 Stretched. 2 No. can die. 4 dead parts, all 4 dead parts, one sticky, one attached, one sticky, one sticky, this paper size is in accordance with Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 27 81.9.20,000 B6 V. Description of the invention (28) 7 All the silk parts and feet are outstretched 6 All the dead parts are all dead 4 Dead sticky yarrows are attached to the attached parts (please read the notes on the back and then write this page) The size of the paper printed by the R-Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs is applicable to the Chinese National Standard (CNS) A4 specifications (210 X 297 mm) 28 81.9.20,000

A6 B6 五、發明韩嗍(巧) 經濟部中央標準局負工消費合作社印製 表 3 實例 1 0 天 20天 30天 50天 70天 90天 空白試 驗 無 附 著 附 著 附 著 附 著 附 著 附著 8 無 附 著 無 附 著 無 附 著 .附 著 附 著 附著 9 無 附 著 無 附 著 附 著 附 著 附 著 附著 10 // ” 無 附 著 無 附 著 無 附 著 J/ 11 )) // // )} 12 無附 著 13 )) >) " )) ft // 14 )) )) 附 著 附 著 附 著 附著 15 無 附 著 無 附 著 無 附 著 附 著 附 著 附著 16 ” )) 無 附 著 無 附 著 附著 17 )) )) ” 7/ 18 )) // 無附 著 19 )) η ” J/ // 表 4 ( :存 料中梅会) 實例 10 天 20天 30 天 50 天 70天 90 天 空白 無 附著 附 著 附 著 附 著 附 著 附 著 20 ” 無 附著 無 附著 無 附著 ). / 2 1 )) / ; h r 22 η ” )) JHrr m 附著 無 附著 23 η // ” 附 著 附 著 24 η )) )) )) 無 附著 無 附著 25 // // // // 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000 (請先閲讀背面之注-事項再塡寫本頁) -裝- ,^'. 29A6 B6 Fifth, the invention of Han Shi (Qiao) The Ministry of Economic Affairs, Central Standards Bureau, Negative Consumers Cooperative Printed Table 3 Example 1 0 days 20 days 30 days 50 days 70 days 90 days blank test no adhesion adhesion adhesion adhesion adhesion adhesion 8 no adhesion none Attached No Attached. Attached Attached Attached 9 No Attached No Attached Attached Attached Attached Attached 10 // ”No Attached No Attached No Attached No Attached J / 11)) // //)} 12 No Attached 13)) >) ")) ft // 14)))) Attachment Attachment Attachment 15 No Attachment No Attachment No Attachment Attachment Attachment Attachment 16 ”)) No Attachment No Attachment No Attachment Attachment 17))))” 7/18)) // No Attachment 19)) η ”J / // Table 4 (: Meihui in stock) Example 10 days 20 days 30 days 50 days 70 days 90 sky white no attachment attachment attachment attachment attachment attachment 20” No attachment no attachment attachment no attachment). / 2 1)) / ; hr 22 η ”)) JHrr m attached no attached 23 η //” attached attached 24 η)))))) no attached no attached 25 // // // // This paper size applies to China National Standard (CNS) A 4 specifications (210 X 297 mm) 81.9.20,000 (please read the note on the back-matters before writing this page)-installed-, ^ '. 29

* A6 _^_B6_ 2 〇 五、發明説明() . 由上述實例之試驗结果看出,實例1和2的水生物阻 絕材料在每個平板試驗和燒杯試驗中皆能有效地阻止* A6 _ ^ _ B6_ 2 〇 V. Description of the invention (). As can be seen from the test results of the above examples, the aquatic bio-barrier materials of Examples 1 and 2 can be effectively prevented in each flat plate test and beaker test

SoleteUina diphos的足絲附著其上;同時,該藻類附著 試驗指出每個實例的材料皆能有效地阻止藻類的附著;特 別是,實例1的材料會導致藻類死亡;此外,由海水試驗 中得知,各實例1和2的水生物阻絕材料完全地阻止絕了 任何水生物之附著。 與各實例3至7之含有銅、銀、或是庚黑和吸水性樹 脂的水生物阻絕材料有關連的是,由平板試驗和燒杯試驗 證明了其可有效地防止Soletellina diphos足絲之附著藻 類附著試驗顯示雖各實例3至7之材料會有黏質物附著, 但發現該情形大致上並不足以使有殻之水生動物等之芽胞 附著至船底;經由觀察發現到實例7的水生物阻絕材料能 完全地阻絕藻類的附著。 此外,實驗顯示各實例8至19之水生物阻絕材料和塗 覆有習用之丙烯酸樹脂的空白試驗比較,明顯地延滯了藻 類的附著;此外經由調整聚乙烯酵的皂化度和聚合度會使 材料的使用期限如需要的調整。 同時,實例20至25的各水生物阻絕材料,在與塗料中 不含任何水生物阻絕顔料之空白試驗相較,顯示其明顯足 Μ延遅藻類之附著。 已知附著於水中工具或設施的般魚之類會同時滋養其 芽胞附著其上;當藻類已附著於工具或設施上,芽胞則極 易附著其上,若藻類不易附著於船底,芽胞則不能附著其 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公坌) ^ 81.9.20,000 (諳先閱讀背面之注-事項再塡寫本頁) —裝, 訂. 經濟部中央標準局員工消費合作社印製 〇〇i> 饴 A6 B6 五、發明説明(3 1) 示於 顯著 地附 楚物 淸生 果水 结止 驗阻 試地 述意 上滿 由人 ; 令 易能 不料 着材 滋 0 類阻 之物 魚生 般水 使的 則明 , 發 上本 和 良 改 M 加 明 發 本 對 能 可 有 尚 地 。顯 具明 Η , 及究 施研 設述 釣上 漁由 和經 中 水 内 圍 範 利 專 請 申 之 述 下 在 要 只 外 明 〇 說疇 述範 前之 除明 此發 因本 ; 為 整可 調皆 (請先閱筇背面之注意事項再塡寫本頁) —装_ •π. 經濟部中央標準局员工消費合作社印製 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 81.9.20,000SoleteUina diphos's filaments are attached to it; at the same time, the algae adhesion test indicates that the material of each example can effectively prevent the attachment of algae; in particular, the material of Example 1 will cause the algae to die; in addition, it is known from the seawater test The aquatic barrier materials of Examples 1 and 2 completely prevented the attachment of any aquatic organisms. In connection with the aquatic bio-barrier materials containing copper, silver, or hepatic black and water-absorbent resin in each of Examples 3 to 7, the plate test and beaker test proved that they can effectively prevent the adhesion of algae to Soletellina diphos The adhesion test showed that although the materials of each of Examples 3 to 7 would have a sticky substance attached, it was found that the situation was generally not sufficient to attach the spores of shelled aquatic animals to the bottom of the ship; the aquatic barrier material of Example 7 was found through observation Can completely prevent the attachment of algae. In addition, the experiment showed that the comparison between the aquatic bio-barrier material of each of Examples 8 to 19 and the blank test coated with conventional acrylic resin obviously delayed the attachment of algae; in addition, by adjusting the degree of saponification and polymerization of polyethylene yeast The service life of the material can be adjusted if necessary. At the same time, the aquatic bio-barrier materials of Examples 20 to 25, compared with the blank test without any aquatic bio-barrier pigments in the coating, showed that they were significantly adherent to the algae. It is known that common fish and the like attached to tools or facilities in the water will nourish their spores and attach to them; when algae have attached to tools or facilities, the spores are very easy to attach to it. If the algae are not easy to attach to the bottom of the ship, the spores cannot The standard of the attached paper is in accordance with the Chinese National Standard (CNS) Grade 4 (210 X 297). ^ 81.9.20,000 (Be sure to read the notes on the back-Matters and then write this page)-installed, ordered. Central Standard of the Ministry of Economic Affairs Printed by the Bureau ’s Consumer Cooperative Society 鈴 A6 B6 V. Description of the invention (3 1) Shown in a prominently attached Chu Chuansheng fruit water to stop the test and the test description is full of people; making Yi Neng unexpected The material of class 0 resistance is as raw as water, so it is clear. Obviously ming, and the research institute said that the reason for catching the fish and the application of Fan Li in Zhongshui Neiwei under the application should be clear only before the statement. Adjustable (please read the precautions on the back of the page before writing this page) — installed _ • π. This paper is printed by the Employee Consumer Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs. The paper size is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm) 81.9.20,000

Claims (1)

A7 B7 C7 D7 經濟部中央標準局g工消费合作社印製 六、申請專利範園 :1. 一種水生物阻絕材料,係包括至少兩種轚離傾向不同 的金臛和至少一種成為顔料之一部分的吸水性樹脂。 2. 如申諝専利範臞第1項之水生物阻絕材料,其中該顔 料係構成漆料之一部分。 3. 如申請專利範圍第1項或第2項之水生物阻絕材料, 其中該至少兩種電離傾向不同之金屬和該吸水性樹脂 係彼此獨立存在。 4. 如申請專利範圍第1項或第2項之水生物阻絕材料, 其中該至少兩種電離傾向不同之金羼係分別載附於不 同之吸水性樹脂上。 5. 如申請專利範圍第1項或第2項之水生物阻絕材料, 其中該至少兩種電雔傾向不同之金羼係一同載附於相 同之吸水性樹脂上。 6. 如申請專利範圃第1項或第.2項之水生物阻絕材料, 其中該至少兩種電離傾向不同之金雇包括鋦和銀。 7. 如申請專利範圍第1項或第2項之水生物阻絕材料, 其至該吸水性樹脂包括聚乙烯醇。 8. 如申請専利範圍第7項之水生物阻絕材料,其中該聚 乙烯醇具有98.5mol%或更高之皂化度和1000或更少之 聚合度。 9. 如申請專利範圃第7項之水生物阻絕材料,其中該聚 乙烯酵之皂化度係介於78.5mol%和81.5bo1%間,而 聚合度為1500或更高。 10. —種水生物阻絕材料,係包括飼、炭黑和至少一種成 (請先閱讀背面之注意事項再塡寫本頁) 裝. 訂 .II 本紙張尺度適用中國國家標準(CNS〉甲4规格(210 X 297公釐) 32 Μ -· η ή CJ Α7 Β7 C7 D7 六、申請專利範圍為顔料之一部分的吸水性樹脂。11.如申請專利範圃第10項之水生物阻絕材料,其中該顔 料係構成漆塗料之一部分 1 2 .如申請專利 其中該錮、1 3 .如申請專利 其中該鋦和 1 4 .如申請專利 其中該飼和 15 .如申請專利 其中該吸水 1 6 .如申請專利 乙烯酵具有 聚合度。1 7 .如申請專利 乙烯醇的皂 範圍第10項或第11項之水生物阻絕材料, 炭黑和吸水性樹脂係彼此獮立存在。 範圃第10項或第11項之水生物阻絕材料, 炭黑係分別載附於不同之吸水性樹脂上。 範圍第10項或第11項之水生物阻絕材料, 炭黑係一同載附於相同之吸水性樹脂上。 範圍第10項或第U項之水生物阻絕材料,性樹脂包括聚乙烯酵。範圍第15項之水生物阻絕材料,其中該聚 98.5mol %或更大之皂化度和1〇〇〇或更少之範圍第15項之水生物阻絕材料,其中該聚 化度係介於78.5mol%和81.5mol間而聚合 枓 材 絕 阻 物 生 水 之 項 3 〇 第 高圍 更範 或利 00專 15請 為申 度如 至 該 中 其 (請先閲讀背面之注意事項再塡寫本頁) 裝. .ΤΓ. 經濟部中央標準局負工消費合作社印製 銀料 和材 铜絕 括阻 包物 係生 靥水 金之 之項 同 4 不第 向画 傾範 離利 1 ffT 種請 兩申 少如 銀料 和 材 飼絕 括阻 包物 係生 羼水 金之 之項 同 5 不第 向圍 傾範 離利 電專 種請 兩申 少如 銀料 和材 鋦絕 括阻 包物 係生 廳水 金之 之項| 同 C 不第 向画 傾範 離利 笛專 種請 兩申 少如 本紙張尺度適用中國國家標準(CNS)甲4規格(210 X 297公釐) 至 該 中 其 至 該 中 其 吸 該 中 其 A7 ^ B7 C7 ___ D7 _ 六、申請專利範圍 水性樹脂係包括聚乙烯酵。 22. 如申請專利範園第4項之水生物阻絕材料,其中該吸 氷性樹脂係包括聚乙烯酵。 23. 如申請專利範画第5項之水生物阻絕材料,其中該吸 水性樹脂係包括聚乙烯酵。 24. 如申請專利範圃第12項之水生物阻絕材料,其中該吸 水性樹脂係包括聚乙烯酵。 25. 如申請專利範麵第13項之水生物阻絕材料,其中該吸 水性樹脂係包括聚乙烯醇。 26. 如申請專利範圃第14項之水生物阻絕材料,其中該吸 水性樹脂係包括聚乙烯醇d <请先閲讀背面之注意事項再塡寫本頁) -裝. 訂. Λ·. 經濟部中央標準局w工消費合作社印製 本紙張尺度適用中國國家標準(CNS)甲4规格(210 X 297公釐)A7 B7 C7 D7 Printed by the Central Standards Bureau of the Ministry of Economic Affairs and Industry Co-operative Cooperatives 6. Application for a patent garden: 1. An aquatic biorepellent material, which includes at least two types of gold dimes with different tendency to alienation and at least one part that becomes part of the pigment Water-absorbing resin. 2. For example, the water bio-barrier material in item 1 of Shen Fen Li Fan Shao, where the pigment forms part of the paint. 3. As for the aquatic bio-barrier material according to the first or second patent application scope, wherein the at least two metals with different ionization tendency and the water-absorbent resin exist independently of each other. 4. As for the aquatic bio-barrier material according to the first or second patent application scope, wherein the at least two kinds of gold ions with different ionization tendency are respectively attached to different water-absorbent resins. 5. For example, the aquatic bio-barrier material of the first or second patent application scope, wherein the at least two types of gold broilers with different electric carbohydrate tendencies are attached to the same water-absorbent resin. 6. For example, if applying for the patent aquatic material of item 1 or item 2., the at least two types of gold employment with different ionization tendencies include manganese and silver. 7. If the aquatic bio-barrier material of the first or second patent scope is applied, the water-absorbent resin includes polyvinyl alcohol. 8. For the application of the aquatic bio-barrier material of item 7 of the scope of application, wherein the polyvinyl alcohol has a saponification degree of 98.5 mol% or higher and a polymerization degree of 1,000 or less. 9. For example, the aquatic bio-barrier material of patent application No. 7 in which the degree of saponification of the polyvinyl yeast is between 78.5mol% and 81.5bo1%, and the degree of polymerization is 1500 or higher. 10. —Aquatic bio-barrier materials, including feed, carbon black and at least one type (please read the precautions on the back before writing this page). Binding. II This paper size is applicable to the Chinese National Standard (CNS> A4 Specifications (210 X 297 mm) 32 Μ-· η ή CJ Α7 Β7 C7 D7 6. Water-absorbent resin whose patent application is a part of the pigment. 11. For example, the water bio-barrier material in the patent application No. 10 The pigment system constitutes a part of the lacquer coating 1 2. If applying for a patent among them 锢, 1 3. If applying for a patent among them 鋦 and 14 4. If applying for a patent among them feed and 15. If applying for a patent among them the water absorption 16. Such The patented vinyl yeast has a degree of polymerization. 1 7. As the water bio-barrier material of the patented soap range of vinyl alcohol item 10 or 11, carbon black and water-absorbent resins exist on each other. Fanpu item 10 or Item 11 of the aquatic bio-barrier material, carbon black is separately attached to different water-absorbent resins. Scope item 10 or item 11 of the aquatic bio-barrier material, carbon black is attached to the same water-absorbent resin Scope item 10 Item U of the aquatic bio-barrier material, the sex resin includes polyethylene yeast. Scope item 15 of the aquatic bio-barrier material, in which the polysaponification degree of 98.5mol% or greater and the range of 100,000 or less are fifteenth Item of aquatic bio-barrier material, wherein the degree of polymerization is between 78.5mol% and 81.5mol and the polymer barb material is a barrier to raw water. Item 3 is the higher range or higher range. To this (please read the precautions on the back before writing this page) installed ... ΤΓ. Printed silver and copper by the Consumer Labor Cooperative of the Central Standards Bureau of the Ministry of Economic Affairs The item is the same as the item 4: No Fan Xiangli, Fan Lili 1 ffT, please apply for less than the silver material and the material feeding, and the package item is the same as the item 5, not the fan, Fan Lili special kind. Two applications are as small as silver materials and wood materials. All items are included in the Department of Health Department's item of gold. (210 X 297 mm) Among them, A7 ^ B7 C7 ___ D7 _ VI. Patent application water-based resin system includes polyethylene leaven. 22. If applying for the patent biotechnology item 4 of the water bio-barrier material, the ice-absorbing resin includes polyethylene leaven 23. For example, the water bio-barrier material in item 5 of the patent application, where the water-absorbent resin system includes polyethylene yeast. 24. For example, in the patent application section 12, aquatic bio-barrier material, wherein the water-absorbent resin system includes polyethylene yeast. 25. For the aquatic bio-barrier material according to item 13 of the patent application, wherein the water-absorbent resin includes polyvinyl alcohol. 26. For example, in the patent application for water bio-barrier material in item 14, the water-absorbent resin includes polyvinyl alcohol d < please read the precautions on the back before writing this page) -installation. Order. Λ ·. The size of the paper printed by the Central Standards Bureau of the Ministry of Economic Affairs and Industry and Consumer Cooperatives is applicable to the Chinese National Standard (CNS) A 4 specifications (210 X 297 mm)
TW081102336A 1991-03-27 1992-03-26 TW200522B (en)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
JP13378391A JPH04298574A (en) 1991-03-27 1991-03-27 Inhibitor for deposition of aquatic organism
JP3182116A JPH04325048A (en) 1991-04-22 1991-04-22 Latching-preventive structure for aquatic organism
JP3305751A JPH0571074A (en) 1991-09-06 1991-09-06 Adhesion inhibiting fiber against aquatic organism and its use
JP30574991A JPH0565431A (en) 1991-09-06 1991-09-06 Paint for preventing adhesion of aquatic life
JP30575091A JPH0565435A (en) 1991-09-06 1991-09-06 Pigment for preventing adhesion of aquatic life

Publications (1)

Publication Number Publication Date
TW200522B true TW200522B (en) 1993-02-21

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ID=51356530

Family Applications (1)

Application Number Title Priority Date Filing Date
TW081102336A TW200522B (en) 1991-03-27 1992-03-26

Country Status (1)

Country Link
TW (1) TW200522B (en)

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