200411012 玖、發明說明 (翻說明廳娜·發日細屬之技·賊、鋪ΐ技術、0容、麵力式及圖式 簡單說明） 【發明所屬之技術領域】 本發明係關於一種環保塑膠袋的組成物及其製法，特 別疋關於一種低燃燒值，燃燒時低煙，焚化後不結塊，經 灰化後可完全變成粉末的環保熱處理之可分解塑膠合成 袋。 ’° 【先前技術】 使用過後的塑膠袋一般係經焚化或掩埋或堆砌等等方 式處理，光分解袋係利用光、氧、熱等因素讓轉袋自 動進行氧化及熱分解反應來裂解塑膠袋，或如生物分^袋 係利用掩埋處理。前述卿袋處理法有著許多無法解決= 問題’如光分解袋被掩埋如何裂解，或生物分解袋需= 大的掩埋場，因此，如何有效處理塑膠袋，一直是業: 的問題。爾近，公告第256846號專利案二適二 =毁的聚乙烯吹顯成物，其具有低燃燒值，义 結塊及易燃報f。前案只縣焚化方式為較佳， …、用在掩埋等方式來進行分解，因此前案無法符人产 保’且塑膠合成製品無法具有像紙袋般透氣的ϋ'『 無法回收以減少聚乙烯聚合物的產量。 〜 、 【內容】 200411012 本發明欲解決之問題是由於成塑膠組成物的成份關 係’本發明的主要目的是提供一種適用掩埋、焚化分解， 符合環保’且塑膠合成製品具有像紙袋般透氣的感覺，並 且可回收以減少聚乙烯聚合物產量的環保熱處理之可分解 塑膠合成袋的組成物及其製法。 本發明之次一目的是提供一種可以回收使用過後的塑 膠袋再製成新塑膠袋繼續使用，且低燃燒值，燃燒時低煙， 焚化後不結塊，經灰化後可完全變成粉末。 為達到上述目的的環保熱處理之可分解塑膠合成袋的 組成物，係包括有2〇〜80%的回收聚乙烯塑膠粒、〜 的第一組原料、1〇〜4〇%的第二組原料與微量潤滑劑，其中 該第一組原料包括有17〜32%的回收聚乙烯塑膠粒、65〜8〇 %且粒徑為3〜5//的粗填充物與卜5%的潤滑劑、分散劑及 混合聚乙烯塑膠粒製粒，及該第二組原料包括有17〜32%的 回收聚乙烯塑膠粒、65〜80%且粒徑為的細填充物與 1 -5%潤滑劑、分散劑及混合聚乙烯塑膠粒製粒。 較佳地’该潤滑劑為油酿胺、芬酿胺、硬脂酸辞或硬 脂酸鈣。 較佳地，本發明的塑膠袋組成物於一捏合機内混炊 切斷而製成適當尺寸之塑膠粒。 較佳地，該回收的聚乙烯粒子包括6〇〜75%的高密度聚 乙烯及25〜40%的線型低密度聚乙烯。 較佳地，該粗填充物包括50〜70%的礦物質粉末、1〇〜 200411012 %的玉米粉、15〜25%的澱粉、10〜20%的米糠粉及10〜20% 的樹葉粉末混合而成的。而該細填充物包括50〜70%的礦物 質粉末、10〜20%的玉米粉、15〜25%的澱粉、1〇〜20%的米 糠粉及10〜20%的樹葉粉末混合而成的。其中該礦物質粉末 可為2〜3//粒度的碳酸鈣（滑石）、大理石、雲母、石膏或氫 氧化鋁。 本發明係以上述組成物製成環保熱處理之可分解塑膠 合成袋的製法，係包括下列步驟： a·混製第一紕原料為塑膠粒，使第一組原料經回潮過程， 該回潮過程係產生水氣； b·混製第二组原料為塑膠粒；以及 c·混製回收聚乙烯塑膠粒、第一組原料、第二組原料與微 量潤滑劑混製，並以吹膜擠壓製成可掩埋、焚化分解，具 有像紙袋般透氣的感覺的塑膠合成袋。 較佳地，該回潮過程係將第一組原料經過水氣。 該回潮過程係放置數天至—则，使產生錢 二 原料產生濕潤，適合進行混製。 〆 本發明係完全·_袋或制處理製 塑勝粒，不須加入新的塑雜，而是加 t乙卸 齡改變舰瓣袋__覺，使本翻㈣成 袋產生像合成紙般透氣的感覺，而開發出:、> 合成袋，林侧㈣點之—。 種新穎的塑膠 吹壓成型、 紙片、 本發明的適用於射出成型、吹袋、淋膜、 擠塵式吹魏型賴m製作⑽於找材γ 200411012 膠合成材料。本發明亦不須如公告第256846號 添加物如氧化劑、抗氧化劑、極性離子化聚 口 #轉要’回收塑膠粒是可以解決的。 、、〜ιό二月…精練研磨而成，分散性佳，與各種塑膠之相 公、且燃燒時火燄溫度低，低煙，不產生戴奥辛等 有毒氣體，成品_袋膜經灰化後，可完全變成粉末。 【實施方式】 ^财絲將瓣製品回驗過清洗與乾燥使塑膠 裝品表面雜物可以清理乾淨。該轉製品包括塑勝袋、塑 膠膜等等將塑膠洲_送人破碎機i^行破碎，紐粗破碎， 再做細破碎’使成—小片__片。紐，再將其述塑 膠薄片麟並加溫使之融溶疏態狀，、旋輸送機 將融溶狀的液體送至壓出機，該壓出機將融溶液態的樹脂 (聚乙婦）冷卻降溫壓出成線狀。最後經切粒機將線狀樹脂 f成粒狀並送入冷卻水中冷卻，接著進行乾燥處理將粒狀 ，脂乾燥回收。其中該时的聚乙烯粒子包括6G〜75%的高 密度聚乙烯及25〜40%的線型低密度聚乙烯。 取17〜32%的回收聚乙烯粒子與65〜8〇%粗填充物，送 入混煉機混煉（攪拌)使其均勻，再依序放入將丨—5%的潤滑 劑、分散劑及聚乙烯臘作助劑，送入捏合機中進行捏合。月 於混鍊機與捏合機内混煉捏合時，於12〇—18〇〇c下各混鍊與 捏合20-30分鐘捏合後則將其壓出製粒，並過濾，再^二〃 段冷卻步驟將製粒冷卻收集，以製作出第一組原料。本發 8 200411012 明較佳地可以直接將處理乾淨的塑膠袋或薄膜放入混鍊 機’並加入助劑等混煉、捏合，爾後步驟與前相同。其中 该粗填充物包括50〜70%的礦物質粉末、1〇〜2⑽的玉米粉、 15〜25%的澱粉、1〇〜2〇%的米糠粉及1〇〜2〇%的樹葉粉末混 合而成的，混合時可進行混煉至粒徑3〜5//。 同樣地’取17〜32%的回收聚乙烯粒子與65〜80%細填 充物，送入混煉機混煉(攪拌)使其均勻，再依序放入將 %的潤滑劑、分散劑及聚乙職作助劑，送入捏合機中進 行匕合。於混鍊機與捏合機内混煉捏合時，於12〇-18〇。〇下 各混鍊與捏合20-30分鐘捏合後則將其壓出製粒，並過濾， 再以二段冷卻步驟將製粒冷卻收集，以製作出第二組原料。 其中該細填充物包括50〜70%的礦物質粉末、丨〇〜2⑽的玉 米籾、15〜25%的澱粉、1〇〜2〇%的米糠粉末及1〇〜2⑽的樹 葉粉末混合而成的，混合時可進行混煉至粒徑1〜2//。上述 的礦物質粉末可為2〜3//粒度的碳酸鈣（滑石）、大理石、雲 =石月或氫氧化銘。而該潤滑劑可為脂肪酸酿胺或硬脂 酸鹽。較佳地，該潤滑劑可為油醯胺、芬醯胺、硬脂酸鋅 或硬脂酸_。 本發明即是將20〜80%的回收聚乙烯塑膠粒、丨〇〜 的第一組原料、10〜4〇%的第二組原料與微量潤滑劑，經混 煉、捏合、融熔、壓擠、冷卻、切割而製成塑膠粒子，以 供製作塑膠製品用。 制本發明因係回收塑膠袋或薄膜等等塑膠材料，因此在 製成聚乙烯粒子時，較習知技術公告第256846號專利案少 200411012 許多的添加物，且以該組成物製成的塑膠製品具有像合成 紙般的透氣感覺，可取代傳統塑膠袋。本發明並可回收塑 膠材料以減少聚乙細聚合物產量，且回收使用過後的塑膠 袋再製成新塑膠袋繼續使用，具備低燃燒值，燃燒時低煙， 焚化後不結塊，經灰化後可完全變成粉末的特性。 本發明係以上述塑膠粒組成物製成環保熱處理之可分 解塑膠合成袋的製法，係包括下列步驟： a·混製第一組原料為塑膠粒，使第一組原料經回潮過程， 該回潮過程係產生水氣； b·混製第二組原料為塑膠粒； c·此製回收聚乙烯塑膠粒、第一組原料、第二組原料與微 量潤滑劑混製，並以吹膜擠壓製成可掩埋、焚化分解，具 有像紙袋般透氣的感覺的塑膠合成袋。 較佳地，該回潮過程係將第一組原料經過水氣。或者 該回潮過程係放置數天至一個月，使產生水氣，使第一組 原料產生濕潤，適合進行混製。 施例： 。首先，取用製作粗填充物的試料共i〇〇g，其中含有50 ^且粒度為2〜3#的碳酸妈粉末、12%的玉米粉、14%的救 粉、m的米糠粉末及12%的樹葉粉末混合而成的，混合 時可進行混煉至粒徑3〜5卩的粗填充物試料。 。其次，取用製作細填充物的試料共l〇〇g，其中含有50 %且粒度為2〜3//的碳酸鹤粉末、12% &玉米粉、14%的殺 200411012 粉、12%的米糠粉末及12%的樹葉粉末混合而成的，混合 時可進行混煉至粒徑1〜2//的細填充物試料。 取用試料共l〇〇g，其中含17%的回收塑膠試料、80% 的粗填充物、3%的潤滑劑及分散劑等助劑協助潤滑混煉捏 合及分散以製成粒徑3〜5//的第一組原料試料。同樣地，取 用試料共100g，其中含17%的回收塑膠試料、80%的細填 充物、3%的潤滑劑及分散劑等助劑協助潤滑混煉捏合及分 散以製成粒徑1〜2//的第二組原料試料。 製粒時，取用試料共l〇〇g，其中含的回收塑膠試 料' 20%的粗填充物、20%的細填充物及微量潤滑劑協助 潤滑混煉捏合，並進行融熔、壓擠、冷卻、切割等步驟得 到塑膠粒子。其中混煉前將第—組原料試料進行咖過程， 可用過水方式，或放置數天至一個月。 將塑膠粒子送入吹膜播壓機器進行吹膜作業，依需求 ^塑膠粒子送人吹膜擠壓機，在 壓機吹出各種塑膠製品，如塑腺代、 、 人膜褙 洗餐具）等等，其成品具有如紙 1的感覺，、^^材(免 二:撕裂的聲音亦近似紙品，為使—^ 接著進行塑膠_的測試，取吹轉壓機 ㈣度之薄膜，該_其加卫溫度在m 5 測定粗粒的 取5〇Cmx5Gon面積’叫光燈或透 。將薄膜200411012 发明, description of the invention (introduction to the brief description of the technology of the hall, hair and fine genus, thief, paving technology, 0 volume, face force and drawings) [Technical field to which the invention belongs] The present invention relates to an environmentally friendly plastic The composition of the bag and the manufacturing method thereof are particularly concerned with a decomposable plastic synthetic bag of environmentally friendly heat treatment, which has a low combustion value, low smoke during combustion, does not agglomerate after incineration, and can be completely turned into powder after ashing. '° [Previous technology] Plastic bags after use are generally treated by incineration, burial or stacking, etc. Photodegradation bags use light, oxygen, heat and other factors to allow the rotating bag to automatically undergo oxidation and thermal decomposition reactions to crack the plastic bags. Or, if biological separation bags are used for landfilling. There are many unsolvable solutions in the aforementioned bag treatment method = problems', such as how the photodegradation bag is buried when it is buried, or the biodegradation bag needs a large landfill site. Therefore, how to effectively deal with plastic bags has always been a problem in the industry. In recent years, Announcement No. 256846 Patent No. 2 = Destroyed polyethylene blown product, which has a low combustion value, meaning agglomeration and flammability report f. The previous case was better only by incineration in the county.…, Used in landfilling to decompose, so the previous case could not meet the guarantee of the people's property and plastic synthetic products could not have the air permeability like paper bags. Polymer yield. ~ [Content] 200411012 The problem to be solved by the present invention is due to the composition of the plastic composition. The main purpose of the present invention is to provide a suitable landfill, incineration, and environmental protection, and the plastic synthetic product has a breathable feel like a paper bag. The composition of the environmentally-friendly heat-decomposable decomposable plastic synthetic bag which can be recycled to reduce the production of polyethylene polymers and a method for producing the same. A secondary object of the present invention is to provide a plastic bag that can be recycled after use and made into a new plastic bag for continued use. It has a low combustion value, low smoke during combustion, does not agglomerate after incineration, and can be completely turned into powder after ashing. The composition of the environmentally-friendly heat-decomposable decomposable plastic synthetic bag for achieving the above-mentioned purpose includes 20 to 80% recycled polyethylene plastic pellets, a first group of raw materials, and a second group of raw materials of 10 to 40%. And trace lubricants, where the first group of raw materials includes 17 ~ 32% recycled polyethylene plastic pellets, 65 ~ 80% and coarse fillers with a particle size of 3 ~ 5 // and 5% lubricants, Dispersant and mixed polyethylene plastic granules, and the second group of raw materials includes 17 ~ 32% recycled polyethylene plastic granules, 65 ~ 80% fine filler with particle size and 1 -5% lubricant, Dispersant and mixed polyethylene plastic granules. Preferably, the lubricant is oleylamine, fenfenamine, stearate or calcium stearate. Preferably, the plastic bag composition of the present invention is mixed and cut in a kneader to make plastic granules of an appropriate size. Preferably, the recovered polyethylene particles include 60 to 75% of high-density polyethylene and 25 to 40% of linear low-density polyethylene. Preferably, the coarse filling comprises 50 ~ 70% mineral powder, 10 ~ 200411012% corn flour, 15 ~ 25% starch, 10 ~ 20% rice bran powder and 10 ~ 20% leaf powder mix. Made of. The fine filling includes 50 to 70% of mineral powder, 10 to 20% of corn flour, 15 to 25% of starch, 10 to 20% of rice bran powder, and 10 to 20% of leaf powder. . The mineral powder can be 2 ~ 3 // size calcium carbonate (talc), marble, mica, gypsum or aluminum hydroxide. The present invention is a method for manufacturing an environmentally-friendly heat-decomposable decomposable plastic synthetic bag made of the above-mentioned composition. The method includes the following steps: a. The first raw material is mixed into plastic granules, and the first group of raw materials is subjected to a dampening process. Generate water vapor; b. Mixing the second group of raw materials into plastic pellets; and c. Mixing and recycling polyethylene plastic pellets, the first group of raw materials and the second group of raw materials are mixed with a small amount of lubricant and extruded by blown film extrusion It is a plastic synthetic bag that can be buried, incinerated and decomposed, and has a breathable feel like a paper bag. Preferably, the rewetting process is to pass the first group of raw materials through water vapor. The re-wetting process is left for several days to -then, the money is generated. The raw materials are moist and suitable for mixing. 〆The present invention is a complete bag made of plastic or processed. It is not necessary to add new plastics, but to add t B to remove the age to change the flap bag bag, so that this bag is turned into a bag and produced like synthetic paper. Breathable feeling, and developed :, > Synthetic bag, forest side ㈣point of —. A novel type of plastic blow molding, paper sheet, and the present invention are suitable for injection molding, bag blowing, film coating, and squeeze-type blow molding. It is suitable for finding materials. 200411012 Glue synthetic material. The present invention does not need to add additives such as an oxidant, an antioxidant, and a polar ionized polymer as disclosed in Announcement No. 256846, which can be solved by recycling plastic particles. 、、 ～ ιόFebruary ... Exquisitely milled, good dispersibility, compatible with various plastics, low flame temperature during combustion, low smoke, no toxic gases such as dioxin, etc. The finished product_bag film can be completely ashed Into powder. [Embodiment] ^ Cai silk has checked the petal products for cleaning and drying, so that the debris on the surface of the plastic products can be cleaned up. The transfer products include plastic bags, plastic films, etc. The plastic continent is sent to the crusher, crushed, coarsely crushed, and then finely crushed 'to make into small pieces. Then, the plastic sheet is heated to make it melted and sparse, and the rotary conveyor sends the molten liquid to the extruder, which extrudes the molten resin (polyethyl ether). ) Cool down and press out into a line. Finally, the linear resin f is granulated by a pelletizer and sent to cooling water for cooling, followed by a drying treatment to granulate and dry the fat to recover. The polyethylene particles at this time include 6G to 75% high density polyethylene and 25 to 40% linear low density polyethylene. Take 17 ~ 32% of the recovered polyethylene particles and 65 ~ 80% of the crude filler, send it to the kneader to knead (stir) to make it uniform, and then put in order 丨 -5% lubricant and dispersant Polyethylene wax is used as an auxiliary, and it is sent to a kneader for kneading. When mixing and kneading in a chain mixer and a kneader, each mixed chain and kneading is performed at 120-1800c for 20-30 minutes. After kneading, it is pressed out to be granulated, filtered, and then cooled in the second stage. In the step, the granulation is cooled and collected to make a first group of raw materials. The present invention 8 200411012 It is preferred that the cleaned plastic bag or film can be directly put into a chain mixer 'and added with an auxiliary agent to knead and knead. The subsequent steps are the same as before. The coarse filling includes 50 ~ 70% mineral powder, 10 ~ 2% corn flour, 15 ~ 25% starch, 10 ~ 20% rice bran powder, and 10 ~ 20% leaf powder mixture. The product can be kneaded to a particle size of 3 to 5 // during mixing. Similarly, take 17 ~ 32% of the recovered polyethylene particles and 65 ~ 80% of the fine filler, send it to the kneader to knead (stir) to make it uniform, and then add the% lubricant, dispersant, and Polyethylene is used as an auxiliary agent and sent to the kneader for kneading. When kneading and kneading in the chain mixer and the kneader, the temperature ranges from 120 to 180. 〇 Below each mixed chain and kneading for 20-30 minutes, it is pressed out and granulated, and filtered, and the granulation is cooled and collected in a two-stage cooling step to produce a second group of raw materials. Wherein, the fine filling includes 50 ~ 70% of mineral powder, 〇〇 ~ 2⑽ of corn mash, 15 ~ 25% of starch, 10 ~ 20% of rice bran powder, and 10 ~ 2⑽ of leaf powder. When mixing, it can be kneaded to a particle size of 1 ~ 2 //. The above-mentioned mineral powder can be 2 ~ 3 // size calcium carbonate (talc), marble, cloud = stone moon or hydroxide. The lubricant may be fatty acid amine or stearate. Preferably, the lubricant may be oleylamine, fenpropamine, zinc stearate or stearic acid. In the present invention, 20 to 80% of recycled polyethylene plastic pellets, the first group of raw materials, 10 to 40% of the second group of raw materials, and a trace amount of lubricant are mixed, kneaded, melted, and pressed. Squeeze, cool, and cut into plastic particles for making plastic products. The production of the present invention is because plastic materials such as plastic bags or films are recycled. Therefore, when polyethylene particles are made, there are fewer additives than the conventional technical bulletin No. 256846 patent 200411012, and plastics made of the composition The product has a breathable feel like synthetic paper and can replace traditional plastic bags. The invention can recycle plastic materials to reduce the production of polyethylene polymer, and recycle the used plastic bags into new plastic bags and continue to use them. It has a low combustion value, low smoke during combustion, no agglomeration after incineration, and ash It can be completely turned into powder after chemical conversion. The invention is a method for preparing an environmentally-friendly heat-decomposable decomposable plastic synthetic bag made of the plastic granule composition, including the following steps: a. Mixing the first group of raw materials into plastic granules, so that the first group of raw materials undergo a re-wetting process. The process is to produce water vapor; b. The second group of raw materials are mixed into plastic pellets; c. The recycled polyethylene plastic pellets, the first group of raw materials, and the second group of raw materials are mixed with a small amount of lubricant and extruded with a blown film It is made into a plastic synthetic bag that can be buried, incinerated and decomposed, and has a breathable feel like a paper bag. Preferably, the rewetting process is to pass the first group of raw materials through water vapor. Or the rewetting process is left for several days to one month to generate water vapor and make the first group of raw materials moist, which is suitable for mixing. Example:. First, a total of 100 g of a sample for making a coarse filling was taken, which contained 50 μm of carbonate powder with a particle size of 2 to 3 #, 12% corn flour, 14% salvage powder, m bran powder, and 12 μm. % Leaf powder is mixed. When mixing, it can be kneaded to a coarse filler sample with a particle size of 3 ~ 5 卩. . Secondly, a total of 100 g of a sample for making a fine filling material was taken, which contained 50% of a carbonated crane powder with a particle size of 2 to 3 //, 12% & corn flour, 14% of a killer 200411012 powder, and 12% of Rice bran powder and 12% leaf powder are mixed. When mixing, it can be kneaded to a fine filler sample with a particle size of 1 ~ 2 //. A total of 100 g of samples were taken, which contained 17% recycled plastic samples, 80% of coarse fillers, 3% of lubricants and dispersants, and other additives to assist in lubrication, kneading, kneading, and dispersing to obtain a particle size of 3 ~ 5 // The first set of raw material samples. Similarly, a total of 100 g of samples were taken, which contained 17% recycled plastic samples, 80% fine fillers, 3% lubricants and dispersants, and other additives to help lubricate, knead and disperse to make particles 1 ~ 2 // The second set of raw material samples. During granulation, a total of 100 g of the sample was taken. The recycled plastic sample contained therein contained 20% of the coarse filler, 20% of the fine filler, and a small amount of lubricant to assist in the lubrication, kneading, and kneading, and melted and squeezed. , Cooling, cutting and other steps to obtain plastic particles. Among them, the first group of raw material samples are subjected to the coffee process before mixing, which can be carried out by water, or left for several days to one month. The plastic particles are sent to a blown film and pressure machine for blown film operation. As required, the plastic particles are sent to a blown film extruder, and various plastic products are blown out in the press, such as plastic gland generation, human film washing tableware, etc. The finished product has the same feel as paper 1, and ^^ (free 2: the sound of tearing is also similar to paper products. In order to make-^ test for plastic _, take the film of the blowing machine, the _ Its guarding temperature is m 5 for measuring coarse particles. The area of 50 cm × 5 Gon is called light lamp or transparent. The film
數量。 H 放入烘箱中 以電子天枰精稱試料1〇g放置錫箱紙上 200411012 加溫100 C士 5 Cx 1小時後’於乾焊由、人 乙株裔中，冷卻20分鐘， 再精稱之’求出加熱後減篁的％數，即兔人> | 馬 3 水率 k，〇-W/Wo。 取試料10g放入白金鉗鍋中，以宾、、w、哈Quantity. H Put 10g of sample in electronic oven into electronic oven, place it on tin paper 200411012 warm 100 C ± 5 Cx for 1 hour, and then cool it in dry soldering and human B for 20 minutes, and then weigh it carefully 'Find the% reduction after heating, that is, the rabbit-man > | horse 3 water rate k, 0-W / Wo. Take 10g of the sample and put it in the platinum tongs.
Mr5J/皿爐45〇tx 2小時 加熱灰化後取出，冷卻30分鐘，再籍避夕… 行贯柄之，侍到碳酸鈣粉 末的淨重。 分析項目 --'—_ 〇. 27/0. 28 廢塑 三成份 ~ 含水率，％ 料再 灰份，％ ~——----- 21. 45/20.13 製塑 可燃份，％ 78.28/79 59 膠袋 元素分析 碳，％ _ 58.58 或薄 氫，〇/〇 12. 33 膜 氧，％ 8. 55 氮，％ 0.00 硫，％ 0.04 氣，〇/〇 0.09 熱值 高位發熱量（乾基）， 7,122 kcal/kg 低位發熱量（乾基）， 6, 637 kcal/kg 其中低位發熱量（乾基）的公式H(〇=H(h)-6(w+9H)(kcal/kg)， H(l)： 低位發熱量（乾基）(kcal/kg) ; H(h):高位發熱量（乾基）(kcal/kg); w :水份(％ ) ; H ··氫含量(％ )。 12 200411012 检驗項目 燃燒前mg/L 燃燒後mg/L 標準佶 汞及其化合物 (總采） 0. 0025 0.0008 _ 1 ----- 0.2 雜及其化合物 (總錯） 0.119 ND(<0. 012) 5.0 錦及其化合物 __(總錫） ND(<0.010) ND(< 0.009) 1.0 鉻及其化合物 _ (總鉻） 0.173 ND(<0.0095) 5.0 六價鉻化合物 ------- ND(<0. 0098) ND(<0. 0096) 2.5 畔及其化合物 (總珅） ND(< 0.030) ND(<0. 029) 5.0 鋼及其化合物 (總銅） 0.374 5. 45 15.0 鋅及其化合物 (總鋅） 0.701 12.3 25.0 毒 性 溶 出 程 序 回收再製翅膜袋測試結果： 樣品編號 樣品尺寸(mm) 燃燒毒氣體(DDm) HC1 HF S〇2 N〇x HCN CO 樣品1 75x 75x 0. 28 1 0 0 3. 85 0 100 樣品2 75x 75x 0. 26 1 0 0 2.01 0 100 樣品3 75x 75x 0. 28 1 0 0 1.98 0 100 平均 1 0 0 2. 78 0 100 ABD-0031規範要求： HCl <150ppm HF < lOOppm S〇2< lOOppm N0X< lOOppm HCN<150ppm C0<3500ppm 13 200411012 由上結果得知’本發明適用掩埋、焚化分解，符合環. 保’且塑膠合成製品具有像紙袋般透氣的感覺 ’並且可回 收以減少聚乙烯聚合物產量，而且本發明可以回收使用過 後的塑U 70全彻地再製成具紙般透減的新塑膠袋 繼續使用，且健燒值，燃燒時低煙，焚化後不結塊:經 灰化後可完全變成粉末。 綜上所述，本發明的組成物與公告第25_號的组成 物成份及比例不_，且製法亦有異，可完全摒除新塑膠 粒的使用，確實符合發明專利要件，爰依法提出申請。' 【圖式簡單說明】 Μ j \\\ 續次頁（發明說明頁不敷使用時，請註記並使用續頁） 14Mr5J / Dish oven 45〇tx 2 hours After heating and ashing, take out, cool for 30 minutes, and avoid the eve ... Perform the handle and wait for the net weight of calcium carbonate powder. Analysis item --'—_ 〇. 27/0. 28 Three components of waste plastic ~ moisture content,% re-ash,% ~ ——----- 21. 45 / 20.13 Plastic flammable component,% 78.28 / 79 59 Plastic bag elemental analysis Carbon,% _ 58.58 or thin hydrogen, 〇 / 〇12. 33 Membrane oxygen,% 8. 55 Nitrogen,% 0.00 Sulfur,% 0.04 gas, 〇 / 〇0.09 calorific value high calorific value (dry basis ), 7,122 kcal / kg low calorific value (dry basis), 6, 637 kcal / kg where the low calorific value (dry basis) is H (〇 = H (h) -6 (w + 9H) (kcal / kg) , H (l): low calorific value (dry basis) (kcal / kg); H (h): high calorific value (dry basis) (kcal / kg); w: moisture (%); H ·· hydrogen content (%). 12 200411012 Inspection item mg / L before combustion mg / L standard combustion mercury and its compounds (total) 0. 0025 0.0008 _ 1 ----- 0.2 Miscellaneous and its compounds (total error) 0.119 ND (< 0. 012) 5.0 Brocade and its compound __ (total tin) ND (< 0.010) ND (< 0.009) 1.0 Chromium and its compound _ (total chromium) 0.173 ND (< 0.0095) 5.0 6 Valence chromium compounds ------- ND (< 0. 0098) ND (< 0. 0096) 2.5 and its Compound (Total 珅) ND (< 0.030) ND (< 0. 029) 5.0 Steel and its compound (total copper) 0.374 5. 45 15.0 Zinc and its compound (total zinc) 0.701 12.3 25.0 Recycling by toxic dissolution process Film bag test results: Sample number Sample size (mm) Burning poisonous gas (DDm) HC1 HF S〇2 N〇x HCN CO Sample 1 75x 75x 0. 28 1 0 0 3. 85 0 100 Sample 2 75x 75x 0. 26 1 0 0 2.01 0 100 Sample 3 75x 75x 0. 28 1 0 0 1.98 0 100 Average 1 0 0 2. 78 0 100 ABD-0031 Specification requirements: HCl < 150ppm HF < lOOppm S〇2 < lOOppm N0X < lOOppm HCN < 150ppm C0 < 3500ppm 13 200411012 From the above results, we know that the present invention is suitable for landfilling, incineration and decomposition, which is in line with environmental protection. And the plastic synthetic products have a breathable feel like paper bags, and can be recycled to reduce the production of polyethylene polymers. In addition, the present invention can completely recycle the plastic U 70 after use into a new plastic bag with paper-like permeability, and continue to use it, with a healthy burning value, low smoke during burning, and no agglomeration after incineration: it can be used after ashing Completely powder. In summary, the composition and proportion of the composition of the present invention is different from the composition of Announcement No. 25_, and the manufacturing method is also different. The use of new plastic granules can be completely eliminated, which indeed meets the requirements of the invention patent, and an application is filed according to law . '[Brief description of the diagram] Μ j \\\ Continued pages (when the description page of the invention is insufficient, please note and use the continued pages) 14