TW200300793A - Expansion gap protection structure for a gasifier - Google Patents

Expansion gap protection structure for a gasifier Download PDF

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Publication number
TW200300793A
TW200300793A TW91134357A TW91134357A TW200300793A TW 200300793 A TW200300793 A TW 200300793A TW 91134357 A TW91134357 A TW 91134357A TW 91134357 A TW91134357 A TW 91134357A TW 200300793 A TW200300793 A TW 200300793A
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Taiwan
Prior art keywords
annular
gasifier
fire
fireproof
shoulder
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TW91134357A
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Chinese (zh)
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TW546366B (en
Inventor
John Corwyn Groen
Donald Duane Brooker
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Texaco Development Corp
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/74Construction of shells or jackets
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/09Mechanical details of gasifiers not otherwise provided for, e.g. sealing means

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Building Environments (AREA)
  • Gasket Seals (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)

Abstract

The expansion gap protection structure for a gasifier includes a solid, inflexible, non-compressible annular refractory shoulder extending downwardly into an expansion gap from a metallic flange that is provided at a top neck portion of the gasifier. The annular refractory shoulder extends into an annular space between a hotface layer of the refractory lining and the inside surface of the gasifier shell. The annular refractory shoulder engages an annular refractory fibrous gasket means on a top edge of a backup layer of the refractory lining of the gasifier. An annular coil of refractory rope is provided in an annular clearance space between the annular refractory shoulder and the hotface layer of the refractory lining to plug the clearance space.

Description

200300793 玖、發明說明 (發明說明應欽明:發明所屬之技術領域、先前技術、内容、實施方式及圖式簡單說明) 【發明所屬技彿^領域】 發明之背景 本發明係有關用於如氣化器之耐火管線容器的膨脹間 5隙保護結構,尤其是一種運用堅固防火材料之新穎膨脹間 隙保護結構。 t先前技術】 氣化器一般係用來處理含碳燃料,包括煤、石油焦炭 、氣體以及/或油,以生成氫及一氧化碳之氣態混合物,譬 10如炭氣、合成氣體、還原氣體及燃料氣體。 揭露於美國專利第2,809,104 & 5,484,554號案中的部 份氧化氣化器包括-高溫反應室,其由一層或數層隔熱及 防火材料圍繞,如亦稱為防火碑或防火裡襯的防火土磚, 並被一外鋼殼體或室所包封。 15 #露於美國專利第4,443,23G A 4,491,456號案中的一 注入式射出器可與前述之氣化器一起使用,以向下與包含 乱體以作部份氧化之氧氣注入含炭燃料之可抽取灰泥至氣 化器之反應室中。 該注入射出器可支持在-環形板上或在氣化器之頂頸 部上之亦稱為中間突緣的一突緣上。如此該中間突緣形成 注入射出器的-架設表面。由於注入射出器定位在氣化器 的頸部上,頸部亦被稱為注入射出器頸部。 如美國專利第5,484,559號案中所揭露的,注人射出器 備有位在中間突緣之架設表面上的一架設板或突緣。在此 200300793 玖、發明說明 組合中’當注入射出器架設在操作位置下的氣化器中時, 氣化器的頂頸部大體上會關閉,以協助維持氣化器反應室 中的一加壓:環境。 當注入射出器在氣化器上的操作位置時,注入射出器 5殼體自在氣化器的頸部上的一中間位置之氣化器頂頸開口 向下延伸。於是,一環形空間界定在注入射出器的本體部 及氣化器的頸部之圍繞防火裡襯之間。 在氣化器之基本的反應室之操作時,溫度可在22〇〇〇f 至3000V的範圍内。操作塵力可在1〇至2〇〇大氣的範圍 10 内。 防火材料,如在包括氣化器之頸部之反應室中加上裡 襯的防火碑與將氣化器自大氣溫度提升至操作溫度的加熱 過程中氣化器殼體不同的速率膨脹。通常防火裡概所備置 的膨脹間隙,尤其是氣化器之上頸部上的膨服間隙係為補 15償防火裡襯之熱膨脹而設。若未備置膨㈣隙,防火碑膨 脹會造成氣化器殼體破裂、彎曲或偏斜,因而造成防火裡 概的破知、毀壞或崩裂’尤其是靠近氣化器頸部之氣化器 的上圓頂部。 因此,a亥膨脹間隙為界定在支持中間突緣及注入射出 20 ϋ的氣化器之頂邊緣及防火裡襯之頂邊緣部之間的一間隙 空間。該間隙備置足夠的空間阻止防火裡概朝向中間突緣 膨脹,並過度加壓氣化器殼體及防火碑。然而,膨服間隙 暴露出氣化器殼體的内表面’若未保護好,可造成氣化器 殼體之%服間隙上過度加熱。 200300793 玖、發明說明 為保護氣化器殼體之膨脹間隙處之暴露的内表面,習 知的方法疋在膨脹間隙上備置一保護性的防火膨脹間隙總 成。 一種氣化器膨脹間隙的習知保護防火總成採用兩層至 5三層防火纖維毯環。該防火纖維毯在可膨脹防火裡襯之頂 邊緣及支持在氣化器頸部上的中間突緣之間延伸。防火纖 維毯的南度可填充膨脹間隙,且足以壓縮以補償防火裡槪 之向上的熱膨脹。在氣化器操作的整個熱的狀況下,中間 犬緣均維持在氣化器頸部上,而注入射出器備置在其上。 10由於固定至氣化器頸部中間突緣無法補償防火裡概的向上 膨脹。 填充膨脹間隙的防火纖維毯材料減少了自反應室過度 膨脹間隙的熱氣流,且亦阻塞了通過膨服間隙的輕射熱之 輸送。如此,可保護膨脹間隙所定位之在氣化器頸部上的 15 殼體不會過熱。 一防火纖維毯膨脹間隙總成具有數項缺點。譬如,在 '射出1"木β又之七在氣化器上的一預熱燃燒爐的操作, 以及注入射出器的操作造成在氣化器頸部上的一文氏管真 空。該真空可造成膨脹間隙總成的防火纖維材料被吸力拉 2〇至氣化器的反應室中。自膨脹間隙中損失的防火纖維材料 使得反應室的熱氣經過膨脹室,並接觸氣化室殼體,因而 造成氣化器殼體之膨脹間隙中的過熱。此外,纖維防火材 料不特別具機械上的彈性,且會由於材料自注入噴出頸中 移入移出而造成損壞。在膨脹間隙上纖維防火材料之進一 200300793 玖、發明說明 步損壞可能會來自於在氣化器操作時產生的熱的含顆粒之 系示合氣體的腐♦虫性。 -種想要解決上述問題之較新的雜氣體總成揭露於 如⑶等人的美國專利第M39,137B1號案中。該專利之揭 5露加入本文中作為參考資料,其在膨脹間隙中使用纖維防 火材料。然而,該纖維防火材料以一條或數條相當不可壓 縮之防火繩定位在膨脹間隙中,而該防火繩在中間突緣架 設在氣化器頸部架設之前在氣化器頸部開口之上延伸。因 此,當它架設在氣化器之上時,一壓縮力量藉由中間突緣 10施加於週邊突出部上。中間突緣的固定造成週邊繩突出而 靠著纖維防火材料。因此,該纖維防火材料鎖在膨脹間隙 中。該固鎖組合有助於阻止纖維防火材料自膨脹間隙中真 空地拉出。整個膨脹間隙總成可包封在一高溫合金鋼中, 以減少對膨脹間隙總成造成腐蝕性的破壞。 15 然而,即使備有Groen等人的固鎖組合,亦很難阻止 熱傳送至氣化器殼體上的膨脹間隙。一個問題在於通過的 合成氣體之驅動力量強到使得在膨脹間隙中的纖維防火材 料之孔會使熱的合成氣體通過,然後接觸並加熱氣化器殼 體。結果,氣化器的上圓頂區仍然會遭遇過高殼體溫度的 20問題,若嚴重的話,足以造成氣化操作之停頓。 因此,最好可備置一膨脹氣體保護結構,其可阻止熱 合成氣體通過膨脹間隙而朝氣化器殼體,並減少氣化器殼 體以及纖維防火材料直接暴露在膨脹間隙中的合成氣體下 200300793 玖、發明說明 【發明内容】 發明之目的及摘要 本發明的數個目的為備置一氣化器的一新穎膨脹間隙 保護結構;備置可阻擋熱的合成氣體通過膨脹間隙朝向氣 5化為殼體的一新穎氣化器膨脹間隙結構;用於包括阻止合 成氣體通過膨服間隙朝向氣化器殼體的堅固防火材料之一 氣化為的新顆膨服間隙保護結構;包括懸垂至膨脹間隙中 以阻止合成氣體通過膨脹間隙朝向氣化器殼體的一堅固環 开> 防火肩部之-新顆間隙保護結構;包括延伸至膨脹間隙 中以罪著可壓&纖維防火材料並大體上阻止可壓縮纖維 防火材料暴露於來自氣化器之合成氣體中的一堅固環形防 火肩部的一新穎膨脹間隙保護結構;包括備有一相當不可 壓縮之防火繩圈以靠著可壓縮纖維防火材料並大體上阻擔 可壓縮纖維防火材料暴露至來自氣化器之合成氣體中的肩 15部之一新穎膨脹間隙保護結構;以及阻擋合成氣體通過膨 服間隙朝向氣化器殼體的一種新穎方法。 本發明的其他目的及特徵將在下文中說明。 一膨脹間隙氣體保護結構200300793 发明 Description of the invention (The description of the invention should be made clear: the technical field to which the invention belongs, the prior art, the content, the embodiments, and the drawings are briefly explained) [Technical Field to which the invention belongs] Field of the invention The present invention relates to the use of such as gasification 5-gap protection structure for the expansion space of the refractory pipeline container of the device, especially a novel expansion-gap protection structure using a strong fireproof material. [Previous technology] Gasifiers are generally used to process carbon-containing fuels, including coal, petroleum coke, gas, and / or oil, to generate a gaseous mixture of hydrogen and carbon monoxide, such as 10 carbon, synthesis gas, reducing gas and fuel gas. Part of the oxidation gasifier disclosed in U.S. Patent Nos. 2,809,104 & 5,484,554 includes a high temperature reaction chamber surrounded by one or more layers of thermal insulation and fire-resistant materials, such as also known as fire monuments or fire linings Fireproof earthen bricks and enclosed by an outer steel shell or chamber. 15 # An injection type injector disclosed in U.S. Patent No. 4,443,23G A 4,491,456 can be used with the aforementioned gasifier to inject carbon containing oxygen downwardly with oxygen containing chaotic bodies for partial oxidation. Fuel can be pumped into the reaction chamber of the gasifier. The injector may be supported on a ring plate or on a flange, also called a middle flange, on the top neck of the gasifier. The intermediate flange thus forms the erection surface of the injector. Since the injector is positioned on the neck of the vaporizer, the neck is also called the injector's neck. As disclosed in U.S. Patent No. 5,484,559, the injection injector is provided with a mounting plate or flange on the mounting surface of the intermediate flange. In this 200,300,793, description of the invention, 'When the injection injector is set up in the gasifier in the operating position, the top and neck of the gasifier will generally be closed to help maintain the one plus in the gasifier reaction chamber. Pressure: environment. When the injection injector is in the operating position on the gasifier, the casing of the injector 5 extends downward from the top neck opening of the gasifier at an intermediate position on the neck of the gasifier. Thus, an annular space is defined between the body of the injection injector and the surrounding fireproof lining of the neck of the vaporizer. During operation of the basic reaction chamber of the gasifier, the temperature can be in the range of 2200f to 3000V. Operating dust power can be in the range of 10 to 2000 atmospheres 10. Fire-resistant materials, such as a lined fire-proof monument in the reaction chamber including the neck of the gasifier, and the gasifier shell expand at different rates during the heating process that raises the gasifier from atmospheric to operating temperature. The expansion gap usually provided in fire protection, especially the expansion gap on the neck above the gasifier is designed to compensate for the thermal expansion of the fire lining. If the expansion gap is not provided, the expansion of the fire monument will cause the shell of the gasifier to crack, bend or deflect, which will cause the fire to be broken, destroyed or cracked, especially near the gasifier's neck. On the round top. Therefore, the expansion gap is defined as a clearance space between the top edge of the gasifier supporting the middle flange and the injection 20 ϋ and the top edge of the fire lining. This gap is provided with enough space to prevent the fire prevention swell from expanding towards the middle flange, and the pressure of the gasifier shell and the fire prevention monument are excessively pressurized. However, the expansion gap exposes the inner surface of the gasifier shell 'if not properly protected, which can cause excessive heating on the% gap of the gasifier shell. 200300793 (ii) Description of the invention In order to protect the exposed inner surface of the expansion gap of the gasifier shell, a conventional method is to place a protective fireproof expansion gap assembly on the expansion gap. A conventional fire protection assembly for the expansion gap of a gasifier uses two to five layers of fireproof fiber blanket rings. The fire-resistant fiber blanket extends between the top edge of the expandable fire-resistant lining and the intermediate flange supporting the neck of the gasifier. The south side of the fire-resistant fiber blanket can fill the expansion gap and is sufficiently compressed to compensate for upward thermal expansion of the fire-resistant interior. Throughout the hot conditions of the gasifier operation, the middle dog edge is maintained on the gasifier neck and the injector is placed on it. 10 Because it is fixed to the middle flange of the gasifier neck, it cannot compensate for the upward expansion of the fire prevention. The fire-resistant fiber blanket material filling the expansion gap reduces the hot air flow from the reaction chamber's excessive expansion gap, and also blocks the transmission of light radiation heat through the expansion gap. This protects the 15 housing located on the neck of the gasifier, where the expansion gap is located, from overheating. A fireproof fiber blanket expansion gap assembly has several disadvantages. For example, the operation of a preheating burner on the 'injection 1 " wood β and seven on the gasifier, and the operation of the injection injector resulted in a venturi tube on the neck of the gasifier being empty. This vacuum can cause the fire-resistant fiber material of the expansion gap assembly to be pulled 20 to the reaction chamber of the gasifier by suction. The fire-resistant fiber material lost from the expansion gap causes the hot gas of the reaction chamber to pass through the expansion chamber and contact the gasification chamber shell, thereby causing overheating in the expansion gap of the gasifier shell. In addition, fibrous fire-resistant materials are not particularly mechanically resilient, and can be damaged by the material moving in and out of the injection nozzle. Advances in fiber fire-resistant materials in the expansion gap 200300793 玖, description of the invention Step damage may come from the hot, particle-containing system that shows the rot of the gas in the gasifier during operation. A newer heterogeneous gas assembly intended to solve the above-mentioned problems is disclosed in, for example, U.S. Patent No. M39,137B1 to CU et al. The disclosure of this patent is incorporated herein by reference, which uses a fibrous fireproof material in the expansion gap. However, the fiber fireproof material is positioned in the expansion gap with one or more rather incompressible fireproof cords, and the fireproof cord extends above the gasifier neck opening before the middle flange is erected over the gasifier neck . Therefore, when it is mounted on the gasifier, a compressive force is exerted on the peripheral protrusions by the intermediate flange 10. The fixing of the middle flange causes the peripheral rope to protrude against the fiber fire-resistant material. Therefore, the fiber fireproof material is locked in the expansion gap. This combination of locks helps to prevent the fiber fireproof material from being pulled out of the expansion gap. The entire expansion gap assembly can be enclosed in a high temperature alloy steel to reduce the corrosive damage to the expansion gap assembly. 15 However, even with the combination of locks by Groen et al., It is difficult to prevent heat transfer to the expansion gap on the gasifier housing. One problem is that the driving force of the passing synthetic gas is so strong that the holes of the fibrous fire-resistant material in the expansion gap can pass the hot synthetic gas and then contact and heat the gasifier shell. As a result, the upper dome region of the gasifier still suffers from excessively high shell temperatures, which, if severe, can cause a pause in gasification operations. Therefore, it is better to prepare an expansion gas protection structure, which can prevent the hot synthesis gas from passing through the expansion gap to the gasifier shell, and reduce the gasifier shell and the fiber fireproof material directly exposed to the synthesis gas in the expansion gap. 200300793说明 Description of the invention [Summary of the invention] The purpose and summary of the invention Several objects of the present invention are to provide a novel expansion gap protection structure for a gasifier; to provide a synthetic gas that can block heat through the expansion gap toward the shell. A novel gasifier expansion gap structure; a new expansion gap protection structure for including synthesis gas that prevents gasification of one of the sturdy fireproof materials through the expansion gap toward the gasifier shell; including overhangs into the expansion gap to prevent A strong loop of synthetic gas towards the gasifier shell through the expansion gap> New shoulder protection structure of fire-resistant shoulders; including extending into the expansion gap to compress the & fiber fire-resistant material and substantially prevent A novel swelling of compressed fiber fire-resistant material exposed to a strong annular fire-resistant shoulder in synthetic gas from a gasifier Expansion gap protection structure; includes one of the 15 shoulders provided with a relatively incompressible fireproof rope loop against the compressible fiber fireproof material and substantially preventing the compressible fiber fireproof material from being exposed to the synthetic gas from the gasifier Expansion gap protection structure; and a novel method of blocking synthesis gas from passing through the expansion gap toward the gasifier shell. Other objects and features of the present invention will be described below. An expansion gap gas protection structure

器殼體之間的_ 依據本發明,用於氣化器的一膨 包括一堅固,不具可撓 直接與氣化器的一金屬 例中,該環㈣火“自金屬突緣懸垂 部上之間隙甲。最好,防火肩部延伸至 之熱面層以及氣化器的金屬殼之間的一 備置在熱面層及氣化器殼體 10 ZUUJUU/yj 玖、發明說明包括在熱面層之頂端表面下呈 熱面層及氣化⑼體之、—科表面,以在 化器殼體之熱面層及内表面…’。该凹下空間在氣 槽之形狀。&内表面之間的支持層上具有一弧形凹 :壓:環形防火纖維塾圈裝置配置在環形凹槽中, a擇的南度可使環形防 ^ ^ 圈衣置在裱形防火肩部 延伸至㈣凹射時被環形防火肩部接合。一環形間隙空間備置在熱面層及環形防火肩部之間。邊”被二火„形圈佔據並大體上被它塞住,而該圈 連接至亚靠著熱面層的—外週邊表面堡縮。因此,當備置環形防火肩部的金屬突緣定位在氣化器 的頸部上時,環形防火肩部接合在環形凹槽中的環形防火 纖、准塾圈衣置,而防火繩環形圈佔據環形防火肩部及熱面 層之間的空間。 、在此、、且口中’來自氣化器之反應室的熱氣大體被阻止 通過氣化器的膨脹間隙而接觸氣化器的殼體。 衣开勺防火肩口 [5之堅固,不具可挽性的不可壓縮特徵 大體上阻擔熱氣通過肩結構。此外,在環形防火肩部及熱 面層之間的窄空間中的防火繩環圈大體上阻止熱氣通過繩 20 結構。 5According to the present invention, a bulge for a gasifier includes a solid, non-flexible direct metal gasifier example. Gap A. Preferably, a hot surface layer between the fireproof shoulder and the metal shell of the vaporizer is placed on the hot surface layer and the gasifier shell. 10 ZUUJUU / yj Under the top surface, there is a hot surface layer and a gasification carcass surface, which is the hot surface layer and the inner surface of the carburizer shell ... '. The recessed space is in the shape of an air groove. &Amp; An arc-shaped recess is provided on the support layer between the two layers: pressure: the ring-shaped fireproof fiber loop device is arranged in the ring groove, and the selected south degree can make the ring-shaped fireproof ^ ^ loop clothes placed on the mounted fireproof shoulder to extend to the recess When fired, it is joined by a ring-shaped fire-resistant shoulder. An annular gap space is provided between the hot surface layer and the ring-shaped fire-resistant shoulder. The edge "is occupied by and is generally plugged by the two fire" ring, which is connected to Yaqi On the hot surface layer-the outer peripheral surface is shrunk. Therefore, when the metal flange of the annular fire shoulder is positioned, When the gasifier's neck is on, the annular fire-resistant shoulders are joined to the annular fire-resistant fibers and quasi-loop clothes in the annular groove, and the fire-rope ring occupies the space between the annular fire-resistant shoulders and the hot surface layer. Here, and in the mouth, the hot gas from the reaction chamber of the gasifier is generally prevented from contacting the shell of the gasifier through the expansion gap of the gasifier. The fireproof shoulder of the clothes [5's sturdy, not irreversible The incompressible feature substantially prevents heat from passing through the shoulder structure. In addition, the fire rope loop in the narrow space between the annular fire-resistant shoulder and the hot surface layer substantially prevents heat from passing through the rope 20 structure. 5

10 1510 15

配置在%形防火肩部之下的可壓縮環形防火纖維熱圈 裝置以及防火繩環形圈亦形成阻止氣體自反應室通過朝向 氣化器殼體之膨脹間隙。 在氣化器之操作中,熱面層會加熱並膨脹。熱膨脹會 11 200300793 玖、發明說明 造成熱面朝向金屬突緣舉起,以大體上除去在熱面層之頂 邊緣及金屬突緣之間的_室溫膨服間隙距離。與防火繩環 形圈合作的環形防火肩部可有效地阻止熱氣接觸氣化器殼 體,因此而不須在熱面層頂端及金屬突緣之間備置任何塾 5 圈裝置。 因此,熱面層可在氣化器操作時膨服,以相當接近疊 置的金屬突緣。在金屬突緣及熱面層的頂邊緣之間的膨脹 間隙在氣化器操作中的此窄化另減少了熱合成氣體接觸氣 化器殼體之膨脹間隙的可能性。 10 15 20 防火肩部之堅固、 堅固、高密度、不 膨脹間隙,以有效The compressible annular fireproof fiber heat coil device and the fireproof rope ring arranged below the% -shaped fireproof shoulder also form an expansion gap that prevents gas from passing from the reaction chamber toward the gasifier shell. During operation of the gasifier, the hot surface layer will heat up and expand. Thermal Expansion Club 11 200300793 发明, description of the invention Cause the hot surface to be lifted towards the metal flange to substantially remove the _ room temperature swelling gap distance between the top edge of the hot surface layer and the metal flange. The ring-shaped fire-resistant shoulders in cooperation with the fire-rope loops effectively prevent hot gas from coming into contact with the carburettor housing, so there is no need to install any 圈 5-turn device between the top of the hot surface layer and the metal flange. As a result, the hot surface layer can be inflated during operation of the gasifier to fairly close to the stacked metal flanges. This narrowing of the expansion gap between the metal flange and the top edge of the hot surface layer during gasifier operation also reduces the possibility of the hot synthesis gas contacting the expansion gap of the gasifier housing. 10 15 20 The sturdy, sturdy, high-density, non-swelling gap of the fire-resistant shoulders is effective

因此,相互通過彼此而移動的環形 高密度、不可壓縮之特徵以及熱面層的 可壓縮之特徵大體上關閉在熱面層上的 地阻止熱氣通過膨脹間隙至氣化器殼體。Therefore, the ring-shaped high-density, incompressible feature that moves through each other, and the compressible feature of the hot surface layer substantially close the ground on the hot surface layer to prevent hot gas from passing through the expansion gap to the gasifier shell.

本电明另包括一種阻止熱氣自—氣化器之反應室流 -防火裡襯之-膨關隙,並接觸氣化器之膨脹間隙的 法,該方法包括備置-階梯式環形膨服間隙於在一氣化 頸部下的防火裡襯中,其中該防火裡— 裡概的-支持層的頂端部上延伸,使得—環形'二 熱面層及氣化器殼體之間的支持層上。該方法另包括以 壓縮環形防火纖維墊圈裝置填充環形凹槽之一選擇高度 並在氣化ϋ頸部之-金屬突緣上形成_堅固、*具可: 、不可壓縮的環形防火肩部。防火肩部塑形成使其一:: :表面安裝至環形凹槽中一選擇的深度,以接合該可屋彳 環形防火纖維墊圈裝置的選擇高度。 12 200300793 玖、發明說明 該方法亦包括定位該金屬突緣,以環形防火肩部備置 在氣化器,員一上,以使環形防火肩部延伸至環形凹槽中, 亚接合可屢縮環形防火纖維墊圈裝置。此外,該方法包括 防火肩部及熱面層之間備置一選擇的環形間隙空間。該方 5法另包括備置一防火繩圈於環形間隙空間中,以塞住環形 間隙空間。 因此,本發明包括上述之結構及方法,而本發明的範 圍為申請專利範圍所界定。 0 圖式簡單說明 10 第1圖為備置加入本發明的一實施例的一膨脹間隙保 濩結構的一氣化器的一上部份的簡化片段截面圖; * 第2圖為其一放大的片段截面圖; 第3圖為備置一堅固、不具可撓性、不可壓縮之環形 防火肩部的氣化器之一金屬突緣的上下倒置下的簡化立體 15圖; 第4圖為如第1圖中所示氣化器之上部份的一片段部 馨 份剖開之立體圖;而 第5圖為備置架設在金屬突緣上的一注入射出器的氣 化器之簡化截面圖。 〇 圖式中的對應元件代表對應之元件。 C實施方式】 發明之詳細說明 現在參看圖式,尤其是第丨及5圖,一氣化器大體上 以標號1 〇代表。 13 200300793 5 10 15 20 玖、發明說明Μ的二二10包括具有一頂頸部14,亦稱為氣化器頸部 14的一外鋼容器或殼㈣。該頂頸部14有_開口 η(第! 主入射出器38(第5圖)通過它而延伸。氣化器殼體 …内表面15,其備置圍繞一反應室(第5圖)的一防 持::(!!。該防火裡襯16包括防火磚的-支持裡襯或支 H (弟2圖),而防火碎備置—頂表面或頂邊緣2〇。該 ^寺層18亦可以任何適合的習知可灌倒、可禱造防火材料 火裡襯16另包括—熱面磚22裡襯或層,亦稱為 ^ 該熱面層22有—頂表面或頂邊緣24(第2圖) 以及面對反應室Π的一熱面26。 支持層18的頂邊緣20在熱面層22的頂邊緣之下呈階 以界定-環形凹槽峨4圖)。因此,支持層㈣ 圖㈣%之底部。該頂邊緣20(第 ;圖)可’譬如,在頂邊緣24下大約117_,而環形凹槽 自熱面層22至内表面15的寬度大約為71mm。 此處所備置的尺寸僅為例示之用,且為氣化器的整個 尺寸的函數。實際上,不同尺寸的氣化器可備置不同的尺 寸。 如第2圖所清楚顯示,支持層18及熱面層22的頂邊 緣2〇及24在氣化器頸部的-頂邊緣32下凹下,以在氣化 器1〇操作時防火裡襯16加熱時允許防火裡襯16膨脹。因 此,靠近頂頸部14之頂邊緣32的氣化器殼體以一内表 面部15a(第2圖)不被防火裡襯所覆蓋。 # 14 200300793 玖、發明說明 亦稱為中間突緣的-環形金屬突緣36(第2圖)配置在 頂,員4 14的頂邊緣32上,以為一注入射出器%(第$圖) 備置-架設表面34(第1圖)。在突緣%及支持層18和熱 面層22的頂邊緣2G及24之間的空間被稱為一膨脹間隙 5 40(第 2 圖)。 膨脹間隙40的高度自支持層18的頂邊緣2〇至突緣 36的-下表面部37(第2圖)大約為157酿,而自熱面層 22的頂邊緣24至下表面部37大約為33mm。 氣化器10之在膨脹間隙40處的暴露内殼體部…藉 1〇由包括與突緣36接觸的一環形防火肩部5〇(第2圖)之一新 膨脹間隙保護結構被保護不直接暴露於熱氣及其他在氣化 器之反應室Π中的熱狀況及化學反應中。環形防火肩部 50以堅固、不具可撓性、不可壓縮的防火材料製成,譬如 ’南密度可以佛羅里達州Delray的加丨丨对公司以 15 Thermbond Formula 18商標販售之鋁鑄造材料製成。該環 形防火肩部50以可以不銹鋼製成的金屬防火錨54(第2、3 圖)連接至突緣36的下表面部37。 如第2及3圖中所清楚顯示,金屬防火錨54為奥克拉 荷馬州Broken Arrow標準的加腳、雙鉤可镱、生 气k細。4苗54 2〇包括自一腳60分叉出的長及短腳部56、58。一彎曲或釣 部64備置在長腳56的一自由端,而一相對的彎曲或釣部 66備置在短腳部58的自由端上。須知短腳部朝向氣化 氣的一中心線70定向(第1圖)。 錨54的一些例示尺寸包括自金屬突緣36的鉤部至 15 200300793 玖、發明說明 下面部37之高度大約為63mm。自鉤部66至金屬突緣36 的下表面37之端腳部58的高度大約為5〇mm。腳56、58 的厚度各大約為5mm,而自鉤部64至鉤部66的錨54之 寬度大約為50mm。錨54的腳60大約在第2圖的平面上 5延伸15inm。並大體上在垂直於第2圖之平面的一平面上 延伸大約25mm。因此,在垂直於第2圖之平面的一平面 上之錨54的腳60長度大約為25mm。 錨54在腳60處熔接至金屬突緣36的下表面部37, 亚沿著一圓形路徑以大約l〇0mm的間隔配置,而該圓形路 10徑的直徑大約與等於頂頸部14之内徑加上熱面層22之外 徑除以2,再加上大約4mm。因此該金屬錨54沿著,譬如 ,自中心線70(第1圖)算起大約275mm之半徑的一圓形中 心線定位。 在此組合下,大約十二個錨54熔接至金屬突緣36的 15下表面部37,但僅六個錨54顯示於第3圖中。金屬錨54 最好以InconeKD條焊至表面37,且在熔接前金屬突緣% 最好預熱至大約40(TF。熔接繞著腳60的週邊為連續的。 最好,錨54定位成使得連續錨54的腳短腳%之平面相對 於自氣化裔10的中心線70起的一徑向線成+ 45◦至〜45。 20 角。 一旦金屬錨54熔接至金屬突緣36,使用定位在一翻 轉金屬突緣36之表面上的任何習知構造的一模具(未顯示) 形成環形防火肩部50(第3圖)。模具操作必須備置肩部5〇 的一輪廓,而肩部50自下表面部37突出大約75mm,而 200300793 玖、發明說明 7表面部37備置大體上垂直且與頸部14的内表面15a距 離5編的一外週邊表面74。環形防火肩部50亦包括一内 週邊表面76,該表面沿著朝向環形防火肩部%的一自由 端之一方向稍許朝外週邊表面74彎曲。 5 譬如,自由端表面78最好比與金屬突緣36之下表面 妾觸之肩邛5 0的相對表面窄大約6mm。内週邊表面與 熱面層22(第2圖)之外週邊表面距離大約1〇_。 在下表面部37上的肩部50的内週邊表面76之内徑, · 譬如,等於大約熱面層22的外徑加上大約7mm。在端表 面78上的肩部5〇之内週邊表面%的内徑,譬如,等於頂 邊緣24的外徑加上大約13mm。 - 一旦環形防火肩部5〇固化,金屬突緣36及防火肩部 _ 5〇可乾燥至大約400。(:,而該溫度維持,譬如,至少四個 J、日^。可選擇地,備置新固化之防火肩部的金屬突緣 3 ό 了在預熱氣化為時,架設在氣化器上,而乾燥步驟可跟 k著金屬突緣3 6架設在氣化器之後。然而,在氣化器1 〇 ^ 的預熱步驟中,環形防火肩部50的乾燥程序可要求氣化器 10以較慢的速率加熱。 在架設備置防火肩部5 0的金屬突緣3 6於頂頸部14上 20 時’一防火纖維熱膨脹墊圈90架設在熱面層22的外週邊 表面100後。該防火纖維墊圈90定位成在支持層頂表面 20上的未壓縮狀態。防火纖維墊圈9〇的芯體可包括三個 單獨的耐至少1250°C的大約25mm厚度之防火毯製成的片 狀環92、94及96(第2圖)。環92、94及96的内徑,譬如 17 200300793 玖、發明說明 ,大於支持層18之内徑厚度lmm,而其外徑大約,譬如 小於在内表面15a上之頸部14的内徑lmm。三個防火纖 維毯製成的環92、94及96最好相互疊置,並包封在耐至 少1250°C熱的約lmm厚度之陶瓷布的鞘98中。 5 ❸里想的是,P方火纖維塾目90必、須預先組合及架設成 一單獨的置於環形槽30中的單元。 須知防火纖維墊圈90可在熱面層22的外週邊表面 1〇〇(第2圖)上承受具破壞性的摩擦能力。因此,最好鞘 · 98十分具有彈性’且可加入如Inc〇nel⑧的高溫合金線纖 10 維。 此外,在備置環形防火肩部5〇的金屬突緣%架設在 · 頁工員口P 14上之%,譬如直徑大約為13咖的一防火繩單一 圈82(第2圖)連接至緊接在防火纖維墊圈9〇之上的熱面 曰22之外週邊表面1〇〇並靠著它而壓縮。、繩圈μ最好圍 15繞著熱面層22的外週邊表面1〇〇之整個週邊延伸的一單一 片並以如黏著f (未顯示)的一可燃燒材料支持定位,而 · 該黏著帶會僅可能地壓縮繩圈82,且最好拉平它成為小於 i〇mm°在氣化器加熱中,可燃燒帶會燒掉,以允許繩圈膨 脹至其正常的未壓縮厚度。 · 2〇 在金屬突緣36架設至頂頸部14上後,當防火肩部5〇 · 下降至環形槽30中時,繩圈82的此種壓縮可使防火肩部 、自由缟78 q過繩82(第2圖)。因此,環形繩圈佔據 在1田54之内週邊表面76及熱面層22之外週邊表面1〇〇之 間的一環形凹槽空間1〇2(第2圖),以大體上塞住空間1〇2 18 200300793 玖、發明說明 如上所述,環形1 & /丨方火肩部50的内週邊表面76稍許朝 向自由端78彎曲。因此,空間1〇2必須在自防火纖維塾圈 9〇的向上方向㉙得較窄。於是,彎曲的内週邊表面%可 阻止繩圈82自空間1〇2中吸出,因為當繩82在空間⑽ 中由於熱面層22之熱膨脹而向上捲曲時會壓縮。 J後備置%形防火肩部5〇的金屬突緣%在繩圈Μ 連接至熱面層22的外週邊表面1。〇時精確地定位在頂頸部 · 14之頂上’如第1、2及5圖中所示。金屬突緣36的精確 1〇定位確保環形防火肩部與環形槽30對齊,並定位在其中, 而不干擾熱面層22的頂頸部14。 · 在此組口巾,大體上為不透氣材料製成的環形防火冑 4 50及陶究繩阻止合成氣體自反應室17通過防火纖維塾 圈90朝向氣化器殼體表面…及15的頸部14。不透氣防 火肩口P 5G亦阻止熱的合成氣體直接通過防火肩部%朝向 氣化器殼體表面15a的氣化器頸部14。 · 在氣化器10操作時,熱面層22以朝向金屬突緣36的 向上方向膨脹,因此,當氣化器加熱至操作溫度時滑過防 火肩部50。 -〇 *理想的狀況是防火肩部%的内週邊表面76必須冑 可能地接近熱面層22的外週邊表面1〇〇。然而,由於製造 及架設公差必須確保在防火肩部5〇及熱面層22之間無干 擾,防火纖維繩82被壓縮至肩部50及熱面層22之間的空 間102中(第2圖),因而顯著地限制可能會通過的氣體量 19 200300793 玖、發明說明 一旦氣化器在操作溫度下,在熱面層22的頂表面24 及金屬突緣36之間的膨脹氣體可小至3醜,以減少到達 P方火肩。卩5G的耽體里’因而顯著地在操作時減少氣化器殼 5 體12溫度之上升。 須知在金屬突緣36的下表面37以及支持層及熱面層 的頂表面2G及24之間的室溫下的距離可相對於氣化器頸 部之頂邊緣之測量並以在金屬突緣36架設前大約測量出, 此近似值以在金屬突緣36及氣化器頸部之頂邊緣%之間 10 的一壓縮墊圈厚度加以調整而算出。 本發明的某些優點已可由上述說明中瞭解,其包括用 於大體上以不透氣防火材料形成的一膨脹間隙的一保護結 構,以阻止熱的合成氣體通過膨脹間隙朝向氣化器殼體。 该膨脹間隙保護結構包括不可壓縮且不具可撓性的一堅固 15裱形防火肩部。該肩部與相當不可壓縮的防火繩圈合作以 靠著相當可壓縮的纖維防火材料,並大體上阻擋相當可壓 縮之纖維防火材料暴露至來自氣化器的反應室之合成氣體 中。 本發明的另一優點為架設在氣化器中的熱面磚可架設 20 至在熱面層及金屬突緣之間備置一大體上較習知技藝小的 間隙之南度’因為不須在熱面層之頂表面及金屬突緣之間 備置任何纖維材料。因此,可大體上關閉在熱面層的頂端 及金屬突緣之間的膨脹間隙之部份。因此,在熱面層及金 屬突緣之間的膨脹間隙部份可減至最小。 20 200300793 玖、發明說明 由於以上所述,可看出本發明的數個目的及優點可達 成。在不脫離本發明的範圍下上述結構及方法可作不同之 改變,因此配合圖式之上述說明僅為例示之用,不得視為 一種限制。 5 10 【圖式簡單說明】 弟1圖為備置加入本發明的一實施例的一膨脹間隙保 護結構的-氣化器的一上部份的簡化片段截面圖;The present invention also includes a method for preventing hot gas from flowing from the reaction chamber of the gasifier, the fire-proof lining, the expansion gap, and contacting the expansion gap of the gasifier. The method includes preparing a stepped annular expansion gap between In a fireproof lining under a gasification neck, wherein the fireproof lining-the top portion of the support layer extends on the support layer between the ring-shaped two hot surface layer and the gasifier shell. The method further comprises filling one of the annular grooves with a compressed annular fire-resistant fiber washer device to select a height and forming a sturdy, non-compressible annular fire-resistant shoulder on the metal flange of the gasification sacral neck. The fire-resistant shoulder is formed into one of the following: ::: Surface mount to a selected depth in the annular groove to engage the selected height of the housing-based annular fire-resistant fiber washer device. 12 200300793 发明, description of the invention The method also includes positioning the metal flange, and placing a ring-shaped fire-proof shoulder on the gasifier, so that the ring-shaped fire-proof shoulder extends into the ring-shaped groove, and the sub-joint can be repeatedly shrunk. Fireproof fiber washer device. In addition, the method includes placing a selected annular gap space between the fire-resistant shoulder and the hot surface layer. This method 5 also includes providing a fireproof rope loop in the annular gap space to plug the annular gap space. Therefore, the present invention includes the structure and method described above, and the scope of the present invention is defined by the scope of patent application. 0 Brief description of drawings 10 FIG. 1 is a simplified fragmentary cross-sectional view of an upper part of a gasifier equipped with an expansion gap retaining structure incorporating an embodiment of the present invention; * FIG. 2 is an enlarged fragment thereof Sectional view; Figure 3 is a simplified 15-dimensional view of the metal flange of one of the vaporizers equipped with a sturdy, non-flexible, incompressible annular fire-proof shoulder. Figure 4 is as shown in Figure 1. A fragmentary perspective view of a portion of the upper part of the gasifier shown in the figure; and Figure 5 is a simplified cross-sectional view of a gasifier equipped with an injection injector mounted on a metal flange. 〇 Corresponding components in the drawings represent corresponding components. Embodiment C] Detailed description of the invention Referring now to the drawings, particularly to Figs. 5 and 5, a gasifier is generally represented by reference numeral 10. 13 200300793 5 10 15 20 (2) The invention's 2210 includes an outer steel container or shell with a top neck 14, also known as the gasifier neck 14. The top neck portion 14 has an opening η (No.!) Through which the main entrancer 38 (Fig. 5) extends. The gasifier housing ... inner surface 15 is provided with a portion surrounding a reaction chamber (Fig. 5). Anti-holding :: (!!. The fire-resistant lining 16 includes fire-resistant brick-supporting lining or support H (Figure 2), and the fire-proof fragment is provided-the top surface or the top edge 20. The temple layer 18 can also Any suitable conventional pourable and prayable fire-resistant material. The fire lining 16 also includes a lining or layer of hot surface brick 22, also known as ^ The hot surface layer 22 has a top surface or top edge 24 (Figure 2 ) And a hot surface 26 facing the reaction chamber Π. The top edge 20 of the support layer 18 is stepped below the top edge of the hot surface layer 22 to define a ring groove (Figure 4). Therefore, the support layer ㈣ Figure ㈣ % Of the bottom. The top edge 20 (FIG .; FIG.) May be 'for example, about 117 mm below the top edge 24, and the width of the annular groove from the heating surface layer 22 to the inner surface 15 is about 71 mm. The size provided here is only As an example, it is a function of the overall size of the gasifier. In fact, different sizes of gasifiers can be prepared with different sizes. As clearly shown in Figure 2, support layer 1 The top edges 20 and 24 of 8 and hot surface layer 22 are recessed at the top edge 32 of the gasifier neck to allow the fireproof liner 16 to expand when the gasifier 10 is heated during operation. Therefore, the carburetor housing near the top edge 32 of the top neck portion 14 is not covered by a fireproof lining with an inner surface portion 15a (Figure 2). # 14 200300793 玖, description of the invention is also referred to as the middle flange -A ring-shaped metal flange 36 (picture 2) is arranged on the top edge 32 of the top member 4 14 as an injection ejector% (picture $) preparation-erection surface 34 (picture 1). At the flange% The space between the top edges 2G and 24 of the support layer 18 and the hot surface layer 22 is called an expansion gap 5 40 (Figure 2). The height of the expansion gap 40 is from the top edge 20 of the support layer 18 to the flange 36-the lower surface portion 37 (picture 2) is approximately 157, and the distance from the top edge 24 of the heating surface layer 22 to the lower surface portion 37 is approximately 33 mm. The exposed inner shell of the gasifier 10 at the expansion gap 40 The body ... by 10, a new expansion gap protection structure including one of the annular fire-resistant shoulders 50 (Figure 2) in contact with the flange 36 is protected from direct exposure to heat and other Thermal conditions and chemical reactions in the reaction chamber of the gasifier. The annular fire-resistant shoulder 50 is made of a strong, non-flexible, incompressible fire-resistant material, such as' South density can be increased by Delray, Florida. The company is made of cast aluminum material sold under the trademark 15 Thermbond Formula 18. The annular fire-resistant shoulder 50 is connected to the lower surface 37 of the flange 36 with a metal fire anchor 54 (Figures 2 and 3) that can be made of stainless steel. As clearly shown in Figures 2 and 3, the metal fire anchor 54 is Oklahoma's Broken Arrow standard footed, double hooked, and angry. 4 seedlings 54 2 0 include long and short leg portions 56 and 58 which branch off from one leg 60. A curved or fishing portion 64 is provided on a free end of the long foot 56 and an opposite curved or fishing portion 66 is provided on the free end of the short foot 58. Note that the short feet are oriented towards a centerline 70 of the gasification gas (Figure 1). Some exemplary dimensions of the anchor 54 include the hook portion of the metal flange 36 to 15 200300793. Description of the invention The height of the lower portion 37 is approximately 63 mm. The height from the hook portion 66 to the end leg portion 58 of the lower surface 37 of the metal flange 36 is approximately 50 mm. The thickness of the feet 56, 58 is about 5 mm each, and the width of the anchor 54 from the hook portion 64 to the hook portion 66 is about 50 mm. The foot 60 of the anchor 54 extends approximately 15 inm on the plane 5 in FIG. 2. It extends approximately 25 mm on a plane perpendicular to the plane of Figure 2. Therefore, the length of the foot 60 of the anchor 54 on a plane perpendicular to the plane of FIG. 2 is approximately 25 mm. The anchor 54 is welded to the lower surface portion 37 of the metal flange 36 at the foot 60, and the sub-arrangement is arranged at a distance of about 100 mm along a circular path, and the diameter of the circular path 10 is approximately equal to the top neck 14 The inside diameter plus the outside diameter of the hot surface layer 22 is divided by two, plus approximately 4 mm. Therefore, the metal anchor 54 is positioned along, for example, a circular center line having a radius of about 275 mm from the center line 70 (FIG. 1). In this combination, about twelve anchors 54 are welded to the lower surface portion 37 of the metal flange 36, but only six anchors 54 are shown in FIG. The metal anchor 54 is preferably welded to the surface 37 with an Incone KD strip, and the metal flange% is preferably preheated to about 40 (TF before welding. The welding is continuous around the periphery of the foot 60. Preferably, the anchor 54 is positioned such that The plane of the short feet of the continuous anchor 54 is + 45 ° to ~ 45 ° relative to a radial line from the center line 70 of the vaporized descent 10. Once the metal anchor 54 is welded to the metal flange 36, use A mold (not shown) of any conventional configuration positioned on the surface of a flip metal flange 36 forms an annular fire-resistant shoulder 50 (Figure 3). The mold operation must have a contour of the shoulder 50 and the shoulder 50 protrudes approximately 75 mm from the lower surface portion 37, and the 200300793 玖, invention description 7 The surface portion 37 is provided with an outer peripheral surface 74 which is substantially perpendicular and is separated from the inner surface 15a of the neck 14 by a distance of 5. The annular fireproof shoulder 50 also includes An inner peripheral surface 76 that is slightly curved toward the outer peripheral surface 74 in the direction of one of the free ends toward the annular fire-resistant shoulder%. 5 For example, the free end surface 78 is preferably more than the surface below the metal flange 36 The opposite surface of the scapular shoulder 50 is about 6mm narrow. The inner peripheral surface The distance from the outer peripheral surface of the hot surface layer 22 (Figure 2) is about 10 mm. The inner diameter of the inner peripheral surface 76 of the shoulder portion 50 on the lower surface portion 37 is, for example, equal to about the outer diameter of the hot surface layer 22 Add about 7mm. The inside diameter of the peripheral surface% within the shoulder 50 on the end surface 78, for example, is equal to the outer diameter of the top edge 24 plus about 13mm.-Once the annular fire-resistant shoulder 50 is cured, the metal protrusions The edge 36 and the fire-resistant shoulder _ 50 can be dried to about 400. (:, and the temperature is maintained, for example, at least four J, day ^. Optionally, a newly cured metal shoulder 3 of the fire-resistant shoulder is provided. In the preheating and gasification stage, it is erected on the gasifier, and the drying step can be erected after the gasifier along with the metal flange 36. However, in the preheating step of the gasifier 1 〇 ^, The drying process of the annular fire-resistant shoulder 50 may require the gasifier 10 to heat at a slower rate. The metal flange 3 of the fire-resistant shoulder 50 is placed on the top of the equipment when it is 20 on the top neck 14 'a fireproof fiber thermal expansion washer 90 is erected behind the outer peripheral surface 100 of the hot surface layer 22. The fireproof fiber gasket 90 is positioned on the top surface of the support layer Uncompressed state on 20. The core of the fire-resistant fiber gasket 90 may include three separate sheet-like rings 92, 94, and 96 made of fire blankets with a thickness of about 25 mm that are resistant to at least 1250 ° C (Figure 2). The inner diameters of the rings 92, 94, and 96, such as 17 200300793 玖, invention description, are larger than the inner diameter thickness of the support layer 18 by 1 mm, and the outer diameter thereof is approximately, such as 1 mm smaller than the inner diameter of the neck portion 14 on the inner surface 15a. The rings 92, 94, and 96 made of three fire-resistant fiber blankets are preferably stacked on top of each other and enclosed in a sheath 98 of a ceramic cloth having a thickness of about 1 mm that is resistant to heat of at least 1250 ° C. 5 It is thought that the P square fire fiber head 90 must be assembled and erected in advance as a single unit placed in the annular groove 30. It should be noted that the fireproof fiber washer 90 can withstand destructive friction on the outer peripheral surface 100 (Figure 2) of the hot surface layer 22. Therefore, it is desirable that the sheath 98 is very elastic and can be added to a 10-dimensional high-temperature alloy wire fiber such as Inconel⑧. In addition, a metal flange% provided with a ring-shaped fire-resistant shoulder 50 is erected on the pager port P14, such as a single ring 82 (picture 2) of a fireproof rope with a diameter of about 13 coffee is connected to the The fire-resistant fiber washer 90 is above the hot surface 22 and the peripheral surface 100 is compressed against it. The rope loop μ is preferably a single piece extending 15 around the entire periphery of the outer peripheral surface 100 of the hot surface layer 22 and supported by a flammable material such as an adhesive f (not shown), and the adhesive The band will only likely compress the loop 82, and it is best to flatten it to less than 100 mm. During heating of the gasifier, the combustible band will burn out to allow the loop to expand to its normal uncompressed thickness. · 20 After the metal flange 36 is erected on the top neck portion 14, when the fireproof shoulder 50 · lowers into the annular groove 30, this compression of the rope loop 82 can make the fireproof shoulder and free Rope 82 (Figure 2). Therefore, the annular rope loop occupies an annular groove space 102 (Fig. 2) between the inner peripheral surface 76 of the field 54 and the outer peripheral surface 100 of the hot surface layer 22 to substantially block the space. 102. 200300793 (1) Description of the Invention As described above, the inner peripheral surface 76 of the annular 1 & square fire shoulder 50 is slightly bent toward the free end 78. Therefore, the space 102 must be narrowed in the upward direction from the fireproof fiber loop 90. Thus, the curved inner peripheral surface% can prevent the loop 82 from sucking out of the space 102 because it will compress when the rope 82 is curled up in the space 由于 due to the thermal expansion of the hot surface layer 22. The metal flange% of the rear-mounted% -shaped fire-resistant shoulder 50 is connected to the outer peripheral surface 1 of the hot surface layer 22 at the rope loop M. At 0 o'clock, it is precisely positioned on the top of the top neck 14 'as shown in Figures 1, 2 and 5. The precise 10 positioning of the metal flange 36 ensures that the annular fire-resistant shoulder is aligned with and positioned in the annular groove 30 without interfering with the top neck 14 of the hot surface layer 22. · In this set of towels, a ring-shaped fireproof 胄 4 50 made of air-impermeable material and a ceramic rope prevent synthetic gas from the reaction chamber 17 through the fireproof fiber 塾 loop 90 toward the surface of the gasifier shell ... and the neck of 15 Department 14. The airtight fireproof shoulder P5G also prevents hot synthetic gas from passing directly through the fireproof shoulders towards the carburettor neck 14 of the carburettor housing surface 15a. • When the gasifier 10 is operating, the hot surface layer 22 expands in an upward direction toward the metal flange 36, and therefore, it slides over the fireproof shoulder 50 when the gasifier is heated to the operating temperature. -〇 * Ideally, the inner peripheral surface 76 of the fireproof shoulder% must be as close as possible to the outer peripheral surface 100 of the hot surface layer 22. However, due to manufacturing and erection tolerances, there must be no interference between the fire-resistant shoulder 50 and the hot surface layer 22, and the fire-resistant fiber rope 82 is compressed into the space 102 between the shoulder 50 and the hot surface layer 22 (Figure 2) ), Thus significantly limiting the amount of gas that may pass 19 200300793 发明, invention description Once the gasifier is at operating temperature, the expansion gas between the top surface 24 of the hot surface layer 22 and the metal flange 36 can be as small as 3 Ugly to reduce the fire shoulders that reach the P side.卩 5G ’s body ’thus significantly reduces the temperature rise of the gasifier shell 5 body 12 during operation. It should be noted that the distance at room temperature between the lower surface 37 of the metal flange 36 and the top surfaces 2G and 24 of the support layer and the hot surface layer can be measured relative to the top edge of the gasifier neck and the metal flange Measured approximately before erection 36, this approximation is calculated by adjusting the thickness of a compression washer 10 between the metal flange 36 and the top edge% of the gasifier neck. Certain advantages of the present invention, which can be understood from the foregoing description, include a protective structure for an expansion gap formed generally of a gas-impermeable fireproof material to prevent hot synthesis gas from passing through the expansion gap toward the gasifier shell. The expanded gap protection structure includes a rugged 15-frame fire-resistant shoulder that is incompressible and non-flexible. The shoulder cooperates with a relatively incompressible fireproof loop to lean against a relatively compressible fibrous fireproof material and substantially blocks exposure of the relatively compressible fibrous fireproof material to synthetic gas from the reaction chamber of the gasifier. Another advantage of the present invention is that the hot surface brick erected in the gasifier can be erected from 20 to the south of the gap between the hot surface layer and the metal flange, which is generally smaller than the conventional technique. Place any fibrous material between the top surface of the facing layer and the metal flange. Therefore, the portion of the expansion gap between the top of the hot surface layer and the metal flange can be substantially closed. Therefore, the portion of the expansion gap between the hot surface layer and the metal flange can be minimized. 20 200300793 (ii) Description of the invention As described above, it can be seen that several objects and advantages of the present invention can be achieved. The above structures and methods can be changed differently without departing from the scope of the present invention. Therefore, the above description in conjunction with the drawings is for illustration only and should not be considered as a limitation. 5 10 [Brief description of the drawings] Figure 1 is a simplified fragmentary cross-sectional view of an upper part of a gasifier equipped with an expansion gap protection structure added to an embodiment of the present invention;

第2圖為其一放大的片段截面圖; 第3圖為備置一堅固、不具可撓性、不可壓縮之環形 防火肩部的氣化器之_金屬突緣的上下倒置下的簡化立體 圖; _ 第4圖為如第1圖中所示氣化器之上部份的一片段部 份剖開之立體圖;而 ° 弟5圖為備置架设在金屬突緣上的一注入射出器的氡 15化器之簡化截面圖。 死 20Figure 2 is an enlarged fragmentary cross-sectional view; Figure 3 is a simplified perspective view of the _ metal flange of a gasifier equipped with a rugged, non-flexible, incompressible annular fire-proof shoulder; Fig. 4 is a partially cutaway perspective view of the upper part of the gasifier as shown in Fig. 1; and Fig. 5 is a puppet of an injection injector mounted on a metal flange. Simplified sectional view of the device. Dead 20

21 200300793 玖、發明說明 【圖式之主要元件代表符號表】 10 氣化器 50 環形防火肩部 12 殼體 54 錨 13 開口 56 長腳部 14 頂頸部 58 短腳部 15 内表面 60 腳 15a 内表面部 64 鉤部 16 防火裡襯 66 鉤部 17 反應室 70 中心線 18 支持層 74 外週邊表面 20 頂邊緣 76 内週邊表面 22 熱面層 78 自由端表面 24 頂邊緣 82 繩圈 26 熱面 90 防火纖維墊圈 30 環形凹槽 92 環 32 頂邊緣 94 環 34 架設表面 96 環 36 突緣 98 鞘 37 下表面部 100 外週邊表面 38 注A射出器 102 環形凹槽空間 40 膨脹間隙21 200300793 发明 Description of the invention [List of main symbols of the main components of the drawing] 10 Vaporizer 50 Ring fire-resistant shoulder 12 Shell 54 Anchor 13 Opening 56 Long foot 14 Top neck 58 Short foot 15 Inner surface 60 foot 15a Inner surface portion 64 Hook portion 16 Fire lining 66 Hook portion 17 Reaction chamber 70 Centerline 18 Support layer 74 Outer peripheral surface 20 Top edge 76 Inner peripheral surface 22 Hot surface layer 78 Free end surface 24 Top edge 82 Rope 26 Hot surface 90 Fire-resistant fiber washer 30 Ring groove 92 Ring 32 Top edge 94 Ring 34 Erection surface 96 Ring 36 Flange 98 Sheath 37 Lower surface part 100 Outer peripheral surface 38 Note A ejector 102 Ring groove space 40 Expansion gap

22twenty two

Claims (1)

200300793 拾、申請專利範圍 1·一種氣化器,其包括: a) 備置一側表面及一頸開口的一金屬氣化器殼體, b) 配置在頸開口上的一金屬突緣, c) 在氣化器内的一反應室, d) 在氣化器设體之反應室之内面上的一防火裡概, 該防火裡襯在頸開口下有一頂部,使得在防火裡襯的頂 部上之氣化器殼體的内表面不被防火裡襯覆’蓋,且該防 火裡襯的一膨脹間隙界定在防火裡襯的頂部上,以及 e) —膨脹間隙保護結構,其包括以堅固、不具可撓 性、不可壓縮的與金屬突緣接觸且自金屬突緣延伸至膨 脹間隙中的防火材料形成的一環形防火肩部。 ’其中該防火裡襯包括 2·如申請專利範圍第i項的氣化器,200300793 Patent application scope 1. A gasifier comprising: a) a metal gasifier housing provided with one side surface and a neck opening, b) a metal flange disposed on the neck opening, c) A reaction chamber in the gasifier, d) a fireproof lining on the inside of the reaction chamber of the gasifier body, the fireproof lining has a top under the neck opening, so that The inner surface of the gasifier shell is not covered by a fireproof lining, and an expansion gap of the fireproof lining is defined on the top of the fireproof lining, and e) an expansion gap protection structure including a A flexible, incompressible annular fireproof shoulder formed by fireproof material that contacts the metal flange and extends from the metal flange into the expansion gap. ’Wherein the fireproof lining includes 2. · If the vaporizer of item i of the patent application scope, 面對反應至的一熱面層,該熱面層在防火裡襯的頂部上 有一第一頂邊緣部,該頂邊緣部在頸開口下並與其有一 段距離’該防火裡襯包括在氣化器殼體之内表面及熱面 延伸至環形凹槽中,且包括與 週邊表面以及與氣化器殼體之 週邊表面。 等層的第二頂邊緣之上。 器,其中該環形防火肩部 熱面層有一段距離的一内 内表面有一段距離的一外 其中該環形槽具有自 4.如申請專利範圍第2項的氣化器, 23 200300793 拾、申請專利範圍 熱面層至環形防火肩部的内週邊表面的第一環形寬度, 而一環形防火繩圈連接至熱面層的外週邊表面,其=防 火繩的橫截面直徑佔據環形凹槽的第一環形寬度。 5·如申請專利範圍第4項的氣化器’其中該環㈣火肩部 5 具有一底自由端表面,而該環形防火肩部的内週邊表面 朝向週邊表面以朝底自由端表面的一方向彎曲,且防火 繩環形圈連接至靠近環形防火肩部的底自由端表面之熱 面層的外週邊表面。 _ 6·如申請專利範圍第3項的氣化器,其中該膨脹間隙保護 1〇 、结構另包括配置在環形凹槽中的可壓縮環形防火纖維墊 圈裝置,該環形防火纖維墊圈裝置與該環形防火肩部具 _ 有選擇高度,可使該環形防火纖維塾圈裝置在該環形《 - 部延伸至該環形凹槽中時被該環形防火肩部接合。 7·如申請專利範圍第i項的氣化器’其包括用以連接環形 15 防火肩部至金屬突緣的裝置。 8.如申請專利範圍第7項的氣化器,其中該連接裝置延 « 伸至環形防火肩部中,且包括炫接至金屬突緣的數個 間隔的金屬錨元件。 9·如申請專利範圍第!項的氣化器,其中該膨脹間隙保 0 護結構另包括配置在膨脹間隙中的可麼縮環形防火纖 維墊圈裝置,而該環形防火纖維墊圈裝置在膨脹間隙 中的選擇高度允許接合環形防火肩部。 10·如申請專利範圍第9項的氣化器,其中該環形纖維塾 圈裝置可I缩’且具有一頂表面’而該環形防火肩部 24 〜_〇793 fe、申請專利箪货圍 面區的 具有接觸及覆蓋環形防火纖維墊圈裝置之頂表 主要部份之底表面。 •如申請專利範圍第1G項的氣化器,其中該防火㈣包 括具有面對反應室之-内熱面表面的—熱面層,以及 面對氣化器殼體之-外表面,且其中該環形防火肩部 具有與熱面層之外表面相間隔的一内週邊表面,且盆 中一環形防火繩圈連接至熱面層之外週邊表面,則占Facing a heated surface layer, the thermal surface layer has a first top edge portion on the top of the fireproof lining, and the top edge portion is under the neck opening and a distance therefrom. The fireproof lining is included in the gasification. The inner surface and the hot surface of the evaporator shell extend into the annular groove, and include a peripheral surface and a peripheral surface of the vaporizer shell. Equal layer above the second top edge. Device, wherein the annular fire-resistant shoulder hot surface layer has a distance from an inner surface to a distance from an outside wherein the annular groove has a vaporizer since 4. The scope of patent application No. 2, 23 200300793 Patent scope The first annular width of the hot surface layer to the inner peripheral surface of the annular fire-resistant shoulder, and an annular fire rope loop is connected to the outer peripheral surface of the hot surface layer, which = the cross-sectional diameter of the fire rope occupies the annular groove. First ring width. 5. The gasifier according to item 4 of the patent application, wherein the ring-shaped fire shoulder 5 has a bottom free end surface, and the inner peripheral surface of the annular fire-proof shoulder faces the peripheral surface to a bottom free end surface. The direction is curved, and the loop of the fireproof rope is connected to the outer peripheral surface of the hot surface layer near the bottom free end surface of the annular fireproof shoulder. _ 6. The gasifier according to item 3 of the scope of patent application, wherein the expansion gap protection 10, the structure further includes a compressible annular fireproof fiber gasket device arranged in an annular groove, the annular fireproof fiber gasket device and the annular The fire-resistant shoulder has a selective height so that the ring-shaped fire-resistant fiber loop device can be engaged by the ring-shaped fire-resistant shoulder when the ring-shaped portion extends into the ring-shaped groove. 7. The gasifier according to item i of the patent application scope, which includes a device for connecting the annular 15 fireproof shoulder to the metal flange. 8. The carburetor according to item 7 of the patent application scope, wherein the connecting device extends into the annular fire-proof shoulder and includes a plurality of spaced metal anchoring elements that are connected to the metal flange. 9 · If the scope of patent application is the first! Item gasifier, wherein the expansion gap protection structure further comprises a shrinkable annular fireproof fiber washer device arranged in the expansion gap, and the selected height of the annular fireproof fiber washer device in the expansion gap allows the annular fire shoulder to be engaged unit. 10. The gasifier according to item 9 of the scope of the patent application, wherein the annular fiber loop device can be retracted and has a top surface, and the annular fire-resistant shoulder 24 ~ _〇793 fe, the patent-applied cargo surround The area has a bottom surface that contacts and covers a major portion of the top surface of the annular fire-resistant fiber gasket device. • If the gasifier of the scope of application for patent No. 1G, wherein the fire protection raft includes a hot surface layer facing the inner heating surface surface of the reaction chamber, and the outer surface facing the shell of the gasifier, and wherein The annular fire-resistant shoulder portion has an inner peripheral surface spaced from the outer surface of the hot surface layer, and an annular fire-proof rope loop in the basin is connected to the outer peripheral surface of the hot surface layer. 據在環形防火肩部之内週邊表面及熱面層之外表面之 間的空間。 ίο 12·—種氣化器,其包括: a) 一金屬氣化器殼體,其備置一内表面、一頂 部以及在頂部上的一開口, b )配置在頂部開口上的一金屬突緣,According to the space between the inner peripheral surface of the annular fire-resistant shoulder and the outer surface of the hot surface layer. ίο 12 · —A gasifier comprising: a) a metal gasifier housing which is provided with an inner surface, a top, and an opening on the top, b) a metal flange disposed on the top opening , c) 一内反應室,其在金屬殼體的内表面上備置 一防火裡襯,該防火裡襯包括以其一第一環形頂邊緣 配置在頂部開口下一段距離處的一熱面層以及以一第 二環形頂邊緣配置在熱面層的第一環形頂邊緣一段距 離處的一支持層,使得在熱面層之第一環形頂邊緣以 及支持層的第二環形頂邊緣上的氣化器殼體之内表面 不被防火裡襯所覆蓋,而一膨脹間隙界定在熱面層及 支持層的第一及第二環形頂邊緣上,以及 d) —膨脹間隙保護結構,其包括一堅固、不可 壓縮的環形防火肩部,其自金屬突緣向下延伸至在氣 化裔殼體的熱面層以及内表面之間的一環形空間中, 25 拾、申請專利範圍 其延伸的深度低於熱面層之第一環形頂邊緣,但高 支持層的第二環形頂邊緣。 13.如申請專利範圍第12項的氣化器,其中該膨服間隙保 護結構包括在支持層的第二環形頂邊緣上的可壓縮防 火纖維墊圈裝置,該環形纖維塾 10 以及自第二環形頂邊緣起算的—選出之高度,使^ 形防火纖維塾圈裝置的上表面被環形防火肩部接合。 H·如申請專利範圍第13項的氣化器,其中該熱面層具有 面向氣化器殼體的一外表面,而該環形防火肩部包括 與熱面層之外表面間隔的一内週邊表面,且其中一環 形防火繩圈連接至熱面層的外表面,以佔據環形防火 肩部的内週邊表面及熱面層的外表面之間的空間。 15·如申請專利範圍第14項的氣化器,其中該環形防火肩 部的内週邊表面自熱面的外表面以朝向纖維墊圈裝置 15 於c) an internal reaction chamber, which is provided with a fireproof lining on the inner surface of the metal shell, the fireproof lining comprising a hot surface layer arranged with a first annular top edge at a distance below the top opening, and A second annular top edge is a support layer disposed at a distance from the first annular top edge of the hot surface layer, so that the first annular top edge of the hot surface layer and the second annular top edge of the support layer The inner surface of the gasifier shell is not covered by a fireproof lining, and an expansion gap is defined on the first and second annular top edges of the hot surface layer and the support layer, and d) an expansion gap protection structure, which includes A sturdy, incompressible ring-shaped fire-resistant shoulder, which extends from the metal flange to an annular space between the hot surface layer and the inner surface of the vaporized shell. The depth is lower than the first annular top edge of the hot surface layer, but the second annular top edge of the high support layer. 13. The carburetor according to item 12 of the patent application scope, wherein the expansion gap protection structure comprises a compressible fireproof fiber gasket device on the second annular top edge of the support layer, the annular fiber loop 10 and the second annular ring Counting from the top edge—selected height so that the upper surface of the ^ -shaped fireproof fiber loop device is joined by the annular fireproof shoulder. H. The gasifier according to item 13 of the patent application, wherein the hot surface layer has an outer surface facing the shell of the gasifier, and the annular fire-resistant shoulder includes an inner periphery spaced from the outer surface of the hot surface layer. Surface, and one of the annular fire-resistant rope loops is connected to the outer surface of the hot surface layer to occupy the space between the inner peripheral surface of the annular fire-resistant shoulder and the outer surface of the hot surface layer. 15. The gasifier according to item 14 of the scope of patent application, wherein the inner peripheral surface of the annular fire-resistant shoulder is the outer surface of the self-heating surface facing the fiber washer device 15 at 的一方向彎曲,而防火繩環形圈連接至環形防火纖維 墊圈裝置之上表面上的熱面層的外表面。 16·如申請專利範圍第12項的氣化器,其包括用以連接環 形防火肩部至金屬突緣的裝置。 17·如申請專利範圍第16項的氣化器,其中該連接裝置包 括數個熔接至金屬突緣的間隔金屬錨元件。 18. —種阻止熱氣自一氣化器之反應室流經一防火裡襯之 一膨脹間隙並在該膨脹間隙處進入該氣化器殼體的方 法,該方法包括: a)備置一階梯式環形膨服間隙於在一氣化器頸 26 200300793 拾、申請專利範圍 下的防火裡概中’其中該防火裡槪的一熱面層在該 防火裡襯的一支持層的頂端部上延伸,使得一環形凹 槽界定在該熱面層及該氣化器殼體之間的支持層上, b)以可壓縮環形防火纖維墊圈裝置填充該環形 5 凹槽之一選擇高度, C)在該氣化器頸部之一金屬突緣上形成一堅固 不具可撓性、不可壓縮的環形防火肩部,塑形該防 火肩部以使其安裝至在環形凹槽中的一選擇深度,以 接合該可壓縮環形防火纖維墊圈裝置的選擇高度,以 10 及 d)定位該具有環形防火肩部之金屬突緣,於該 孔化為頸部上,以使該環形防火肩部延伸至該環形凹 槽中,iU妾合該可壓縮環形防火纖維塾圈裝置。 15The fire rope loop is connected to the outer surface of the hot surface layer on the upper surface of the annular fire-resistant fiber washer device. 16. The gasifier of claim 12 including means for connecting the annular fire-resistant shoulder to the metal flange. 17. The gasifier of claim 16, wherein the connection device includes a plurality of spaced metal anchor elements welded to the metal flange. 18. A method of preventing hot gas from flowing from a reaction chamber of a gasifier through an expansion gap of a fireproof liner and entering the gasifier shell at the expansion gap, the method comprising: a) preparing a stepped ring The expansion gap is in a fireproof liner in the scope of a gasifier neck 26 200300793, where a hot surface layer of the fireproof lining extends on the top of a support layer of the fireproof lining, so that a ring A shaped groove is defined on the support layer between the hot surface layer and the gasifier shell, b) a compressible annular fireproof fiber gasket device is used to fill one of the annular 5 grooves at a selected height, and C) in the gasification A rigid, non-flexible, non-compressible annular fire-resistant shoulder is formed on a metal flange of the neck of the device, and the fire-resistant shoulder is shaped to be installed to a selected depth in the annular groove to engage the Compress the selected height of the ring-shaped fireproof fiber washer device, and position the metal flange with the ring-shaped fireproof shoulder at 10 and d), and hole the neck into the hole so that the ring-shaped fireproof shoulder extends into the ring-shaped groove. IU 妾 合 妾Sook annular compression ring means fireproof fiber. 15 19.如申請專利範圍第18項的方法,其包括在環形防火肩 部及熱面層之間備置一選擇的環形空間,並在環形防19. A method as claimed in claim 18, which includes placing a selected annular space between the annular fire-resistant shoulder and the hot surface layer, and 火肩部及熱面層之間的空間中備置—環形防火繩圈, 以塞住該環形空間。 20 20·如申請專利範圍第19項的 部的内週邊表面上形成一 向環形防火纖維墊圈裝置 方法’其包括在環形防火肩 曲度’使得内週邊表面以朝 的一方向朝外週邊表面彎曲 27An annular fire rope loop is provided in the space between the fire shoulder and the hot surface layer to plug the annular space. 20 20 · A unidirectional annular fireproof fiber washer device is formed on the inner peripheral surface of the part of the scope of application for patent No. 19. The method includes the curvature of the annular fireproof shoulder so that the inner peripheral surface is bent toward the outer peripheral surface in a direction 27
TW91134357A 2001-12-07 2002-11-26 Expansion gap protection structure for a gasifier TW546366B (en)

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Publication number Priority date Publication date Assignee Title
US2809104A (en) * 1955-07-22 1957-10-08 Texas Co Gasification of liquid fuels
US4491456A (en) * 1982-06-29 1985-01-01 Texaco Inc. Partial oxidation process
US4443230A (en) * 1983-05-31 1984-04-17 Texaco Inc. Partial oxidation process for slurries of solid fuel
US5484554A (en) * 1993-01-15 1996-01-16 Texaco Inc. Oxidant injection for improved controlled oxidation

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