TW546366B - Expansion gap protection structure for a gasifier - Google Patents

Expansion gap protection structure for a gasifier Download PDF

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Publication number
TW546366B
TW546366B TW91134357A TW91134357A TW546366B TW 546366 B TW546366 B TW 546366B TW 91134357 A TW91134357 A TW 91134357A TW 91134357 A TW91134357 A TW 91134357A TW 546366 B TW546366 B TW 546366B
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Taiwan
Prior art keywords
annular
fire
gasifier
shoulder
fireproof
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TW91134357A
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Chinese (zh)
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TW200300793A (en
Inventor
John Corwyn Groen
Donald Duane Brooker
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Texaco Development Corp
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/72Other features
    • C10J3/74Construction of shells or jackets
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2200/00Details of gasification apparatus
    • C10J2200/09Mechanical details of gasifiers not otherwise provided for, e.g. sealing means

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Furnace Housings, Linings, Walls, And Ceilings (AREA)
  • Building Environments (AREA)
  • Gasket Seals (AREA)

Abstract

The expansion gap protection structure for a gasifier includes a solid, inflexible, non-compressible annular refractory shoulder extending downwardly into an expansion gap from a metallic flange that is provided at a top neck portion of the gasifier. The annular refractory shoulder extends into an annular space between a hotface layer of the refractory lining and the inside surface of the gasifier shell. The annular refractory shoulder engages an annular refractory fibrous gasket means on a top edge of a backup layer of the refractory lining of the gasifier. An annular coil of refractory rope is provided in an annular clearance space between the annular refractory shoulder and the hotface layer of the refractory lining to plug the clearance space.

Description

546366 玖、發明說明 (發明說明應敘明:發明所屬之技術領域、先前技術、内容、實施方式及圖式簡單說明)546366 发明, description of the invention (the description of the invention should state: the technical field to which the invention belongs, the prior art, the content, the embodiments and the drawings)

【發明所屬^^技術領域;J 發明之背景 本發明係有關用於如氣化器之耐火管線容器的膨脹間 5隙保護結構’尤其是一種運用堅固防火材料之新穎膨脹間 隙保護結構。 C先前技術】 氣化為一般係用來處理含碳燃料,包括煤、石油焦炭 、氣體以及/或油,以生成氫及一氧化碳之氣態混合物,譬 10如厌氣、合成氣體、還原氣體及燃料氣體。 揭露於美國專利第2,809,104及5,484,554號案中的部 份氧化氣化器包括一高溫反應室,其由一層或數層隔熱及 - 防火材料圍繞,如亦稱為防火磚或防火裡襯的防火土碑, , 並被一外鋼殼體或室所包封。 15 ㈣於美國專利第4,443,230及4,491,456號案中的一 注入式射出器可與前述之氣化器一起使用,以向下與包含 鲁 氣體以作部份氧化之氧氣注入含炭燃料之可抽取灰泥至氣 化器之反應室中。 該注入射出器可支持在一環形板上或在氣化器之頂頸 20部上之亦稱為中間突緣的一突緣上。如此該中間突緣形成 注入射出器的-架設表面。由於注入射出器定位在氣化器 的頸部上,頸部亦被稱為注入射出器頸部。 如美國專利第5,484,559號案中所揭露的,注入射出器 備有位在中間突緣之架設表面上的—架設板或突緣。在此 6 546366 玫、發明說明 組合中,當注入射出器架設在操作位置下的氣化器中時, 氣化器的頂頸部大體上會關閉,以協助維持氣化器反應室 中的一加壓環境。 當注入射出器在氣化器上的操作位置時,注入射出器 5殼體自在氣化器的頸部上的_中間位置之氣化器頂頸開口 向下延伸。於是,一環形空間界定在注入射出器的本體部 及氣化器的頸部之圍繞防火裡襯之間。 在氣化器之基本的反應室之操作時,溫度可在22〇〇叩 φ 至3〇〇〇〇F的範圍内。操作壓力可在10至200大氣的範圍 10 内0 防火材料,如在包括氣化器之頸部之反應室中加上裡 襯的防火碑與將氣化器自大氣溫度提升至操作溫度的加熱 _ 過程中氣化器殼體不同的速率膨脹。通常防火裡襯所備置 , 的私脹間隙,尤其是氣化器之上頸部上的膨服間隙係為補 15償防火裡襯之熱膨脹而設。若未備置膨脹間隙,防火磚膨 脹會造成氣化器殼體破裂、彎曲或偏斜,因而造成防火裡 鲁 襯的破損、毀壞或崩裂,尤其是靠近氣化器頸部之氣化器 的上圓頂部。 因此,該膨脹間隙為界定在支持中間突緣及注入射出 2〇器的氣化器之頂邊緣及防火裡襯之頂邊緣部之間的一間隙 工間。该間隙備置足夠的空間阻止防火裡襯朝向中間突緣 膨脹,並過度加壓氣化器殼體及防火磚。然而,膨脹間隙 暴露出氣化器殼體的内表面,若未保護好,可造成氣化器 殼體之膨脹間隙上過度加熱。 7 546366 玖、發明說明 為保護氣化器殼體之膨脹間隙處之暴露的内表面,習 勺方法疋在㈣脹間隙上備置_保護性的防火膨脹間隙總 成。 一種氣化器膨脹間隙的習知保護防火總成採用兩層至 5三層防火纖維毯環。該防火纖維毯在可膨脹防火裡概之頂 邊緣及支持在氣化器頸部上的中間突緣之間延伸。防火纖 維毯的高度可填充膨脹間隙,且足以壓縮以補償防火裡概 之向上的熱膨脹。在氣化器操作的整個熱的狀況下,中間 φ 大緣均維持在氣化器頸部上,而注人射出器備置在其上。 10由於固定至氣化器頸部中間突緣無法補償防火裡概的向上 膨脹。 填充膨脹間隙的防火纖維毯材料減少了自反應室過度 - 膨脹間隙的熱氣流,且亦阻塞了通過膨服間隙的輕射熱之 - 輸送。如此,可保護膨脹間隙所定位之在氣化器頸部上的 15 殼體不會過熱。 一防火纖維毯膨脹間隙總成具有數項缺點。譬如,在 · 注入射出器架設之前在氣化器上的一預熱燃燒爐的操作, 以及注入射出器的操作造成在氣化器頸部上的一文氏管真 空。该真空可造成膨脹間隙總成的防火纖維材料被吸力拉 20至氣化器的反應室中。自膨脹間隙中損失的防火纖維材料 使得反應室的熱氣經過膨脹室,並接觸氣化室殼體,因而 造成氣化器设體之膨脹間隙中的過熱。此外,纖維防火材 料不特別具機械上的彈性,且會由於材料自注入噴出頸中 移入移出而造成損壞。在膨脹間隙上纖維防火材料之進一 8 546366 玖、發明說明 步損壞可能會來自於在氣化器操作時產生的熱的含顆粒之 綜合氣體的腐蝕性。 一種想要解決上述問題之較新的膨脹氣體總成揭露於 Groen等人的美國專利第6,439,137B1號案中。該專利之揭 5露加入本文中作為參考資料,其在膨脹間隙中使用纖維防 火材料。然而,該纖維防火材料以一條或數條相當不可壓 縮之防火繩定位在膨脹間隙中,而該防火繩在中間突緣架 設在氣化器頸部架設之前在氣化器頸部開口之上延伸。因 · 此,當它架設在氣化器之上時,一壓縮力量藉由中間突緣 10施加於週邊突出部上。中間突緣的固定造成週邊繩突出而 靠著纖維防火材料。因此,該纖維防火材料鎖在膨脹間隙 中。a亥固鎖組合有助於阻止纖維防火材料自膨脹間隙中真 空地拉出。整個膨脹間隙總成可包封在一高溫合金鋼中, - 以減少對膨脹間隙總成造成腐蝕性的破壞。 15 然而,即使備有Gr〇en等人的固鎖組合,亦很難阻止 熱傳送至氣化器殼體上的膨脹間隙。一個問題在於通過的 · 合成氣體之驅動力量強到使得在膨脹間隙中的纖維防火材 料之孔會使熱的合成氣體通過,然後接觸並加熱氣化器殼 體。結果’氣化器的上圓頂區仍然會遭遇過高殼體溫度的 20問題,若嚴重的話,足以造成氣化操作之停頓。 因此,最好可備置一膨脹氣體保護結構,其可阻止熱 合成氣體通過膨脹間隙而朝氣化器殼體,並減少氣化器殼 體以及纖維防火材料直接暴露在膨脹間隙中的合成氣體下 9 546366 5 10 15 玖、發明說明 【發明内容;j 發明之目的及摘要 本务明的數個目的為備置一氣化器的一新颖膨服間隙 保護結構;備置可阻播熱的合成氣體通過膨脹間隙朝向氣 化器殼體的—新穎氣化器膨脹間隙結構;用於包括阻止合 成氣體通過膨服間隙朝合_ ^ ^ + & Π丨皁朝向乳化器殼體的堅固防火材料之一 氣化器的新穎膨脹間隙保護結構;包括懸垂至膨脹間隙中 以阻止合成氣體通過膨脹間隙朝向氣化器殼體的_堅固環 形防火肩部之-新穎間隙保護結構;包括延伸至膨服間隙中以靠著-可壓縮纖維防火材料並大體上阻止可壓縮纖維 防火材料暴露於來自氣化器之合成氣體中的—堅固環形防 火肩部的-新穎膨脹間隙保護結構;包括備有—相當不可壓縮之防火繩圈以靠著可壓縮纖維防火材料並大體上阻擋 可壓縮纖維防火材料暴露至來自氣化器之合成氣體中的肩 部之-新穎膨脹間隙保護結構;以及阻擔合成氣體通過膨 脹間隙朝向氣化器殼體的一種新穎方法。[Technical field to which the invention belongs; J Background of the invention The present invention relates to an expansion gap protection structure for a refractory pipeline container such as a gasifier ', especially a novel expansion gap protection structure using a strong fireproof material. CPrevious technology] Gasification is generally used to process carbon-containing fuels, including coal, petroleum coke, gas and / or oil, to generate a gaseous mixture of hydrogen and carbon monoxide, such as anaerobic, synthetic gas, reducing gas and fuel gas. Partial oxidation gasifiers disclosed in U.S. Patent Nos. 2,809,104 and 5,484,554 include a high temperature reaction chamber surrounded by one or more layers of heat insulation and-fireproof materials, such as also known as fire bricks or fire linings Fireproof tombstone, and enclosed by an outer steel shell or chamber. 15 An injection-type ejector as described in U.S. Patent Nos. 4,443,230 and 4,491,456 can be used with the aforementioned gasifier to inject carbon-containing fuel downward with oxygen containing Lu gas for partial oxidation. Pump the stucco into the reaction chamber of the gasifier. The injector can be supported on a ring plate or on a flange, also known as a middle flange, on the top neck 20 of the gasifier. The intermediate flange thus forms the erection surface of the injector. Since the injector is positioned on the neck of the vaporizer, the neck is also called the injector's neck. As disclosed in U.S. Patent No. 5,484,559, the injection ejector is provided with a mounting plate or flange on the mounting surface of the intermediate flange. In this 6 546366 combination of invention and description, when the injection ejector is set up in the gasifier in the operating position, the top and neck of the gasifier will generally be closed to help maintain one of the gasifier reaction chambers. Pressurized environment. When the injection ejector is in the operating position on the gasifier, the injection ejector 5 housing extends from the top neck opening of the gasifier at an intermediate position on the neck of the gasifier. Thus, an annular space is defined between the body of the injection injector and the surrounding fireproof lining of the neck of the vaporizer. During operation of the basic reaction chamber of the gasifier, the temperature can be in the range of 2200 ° φ to 3,000 ° F. Operating pressure can be in the range of 10 to 200 atmospheres. 10 Fireproof materials, such as a lined fireproof monument in the reaction chamber including the neck of the gasifier and heating to raise the gasifier from atmospheric to operating temperature _ The gasifier shell expands at different rates during the process. Generally, the swell clearance provided by the fire lining, especially the swell gap on the neck above the gasifier, is provided to compensate for the thermal expansion of the fire lining. If no expansion gap is provided, the expansion of the fire brick will cause the shell of the gasifier to crack, bend or deflect, which will cause the fire lining to be damaged, destroyed or cracked, especially near the gasifier's neck. Round top. Therefore, the expansion gap is a gap defined between the top edge of the gasifier supporting the middle flange and the injection and injection device and the top edge of the fire lining. This gap provides enough space to prevent the fire lining from expanding towards the middle flange, and excessively pressurizes the gasifier shell and fire brick. However, the expansion gap exposes the inner surface of the gasifier shell. If not properly protected, it can cause excessive heating of the gasifier shell's expansion gap. 7 546366 发明 Description of the invention In order to protect the exposed inner surface of the expansion gap of the gasifier shell, the method 疋 sets a protective fireproof expansion gap assembly on the expansion gap. A conventional fire protection assembly for the expansion gap of a gasifier uses two to five layers of fireproof fiber blanket rings. The fire-resistant fiber blanket extends between the top edge of the expandable fire-resistant interior and the intermediate flange supporting the neck of the gasifier. The height of the fire-resistant fiber blanket fills the expansion gap and is sufficient to compress to compensate for the upward thermal expansion in the fire. During the entire hot condition of the gasifier operation, the large middle φ edge is maintained on the gasifier neck, and the injection injector is placed on it. 10 Because it is fixed to the middle flange of the gasifier neck, it cannot compensate for the upward expansion of the fire prevention. The fire-resistant fiber blanket material that fills the expansion gap reduces the excess air flow from the reaction chamber-the expansion gap, and also blocks the light-radiating heat-transport through the expansion gap. This protects the 15 housing located on the neck of the gasifier, where the expansion gap is located, from overheating. A fireproof fiber blanket expansion gap assembly has several disadvantages. For example, the operation of a preheated burner on the gasifier before the injection injector was erected, and the operation of the injection injector caused a venturi tube on the neck of the gasifier to become empty. This vacuum can cause the fire-resistant fiber material of the expansion gap assembly to be pulled 20 into the reaction chamber of the gasifier by suction. The fire-resistant fiber material lost from the expansion gap causes the hot gas from the reaction chamber to pass through the expansion chamber and contact the shell of the gasification chamber, thereby causing overheating in the expansion gap of the gasifier body. In addition, fibrous fire-resistant materials are not particularly mechanically resilient, and can be damaged by the material moving in and out of the injection nozzle. Further advances in fiber fire-resistant materials in the expansion gap 8 546366 玖 Description of the invention Step damage may result from the corrosive nature of the hot, particulate-containing integrated gas generated during gasifier operation. A newer inflated gas assembly intended to solve the above problems is disclosed in U.S. Patent No. 6,439,137B1 to Groen et al. The disclosure of this patent is incorporated herein by reference, which uses a fibrous fireproof material in the expansion gap. However, the fiber fireproof material is positioned in the expansion gap with one or more rather incompressible fireproof cords, and the fireproof cord extends above the gasifier neck opening before the middle flange is erected over the gasifier neck . Therefore, when it is mounted on the gasifier, a compressive force is applied to the peripheral protrusions through the intermediate flange 10. The fixing of the middle flange causes the peripheral rope to protrude against the fiber fire-resistant material. Therefore, the fiber fireproof material is locked in the expansion gap. The ai lock combination helps prevent the fiber fireproof material from being pulled out of the expansion gap. The entire expansion gap assembly can be enclosed in a high temperature alloy steel-to reduce the corrosive damage to the expansion gap assembly. 15 However, even with the combination of Groen and others, it is difficult to prevent heat from being transmitted to the expansion gap on the gasifier housing. One problem is that the driving force of the passing synthetic gas is so strong that the holes of the fiber fireproof material in the expansion gap can pass the hot synthetic gas and then contact and heat the gasifier shell. As a result, the upper dome region of the gasifier still suffers from problems with excessively high shell temperatures, which, if severe, can cause a pause in the gasification operation. Therefore, it is better to prepare an expansion gas protection structure, which can prevent the hot synthesis gas from passing through the expansion gap to the gasifier shell, and reduce the gasifier shell and the fiber fireproof material directly exposed to the synthesis gas in the expansion gap. 9 546366 5 10 15 发明 Description of the invention [inventive content; j purpose of the invention and summary of the several purposes of the present invention is to provide a novel expansion gap protection structure of a gasifier; provision of synthetic gas that can prevent heat propagation through the expansion gap Facing the gasifier shell—a novel gasifier expansion gap structure; used to include one of the sturdy fireproof materials that prevent the synthesis gas from passing through the expansion gap towards the _ ^ + + Π 丨 soap towards the emulsifier shell Novel expansion gap protection structure; including _ sturdy annular fire-resistant shoulders that hang into the expansion gap to prevent the synthesis gas from passing through the expansion gap toward the gasifier shell; includes a novel gap protection structure; including extension into the expansion gap to rest against -Compressible fibrous fire-resistant material and substantially prevent compressible fibrous fire-resistant material from being exposed to the synthetic gas from the gasifier-strong annular Fire shoulder-novel expansion gap protection structure; including-equipped with-quite incompressible fireproof rope loops against compressible fiber fireproof material and substantially blocking exposure of the compressible fiber fireproof material to synthetic gas from the gasifier The shoulder-a novel expansion gap protection structure; and a novel method of hindering the synthesis gas through the expansion gap toward the gasifier shell.

本發明的其他目的及特徵將在下文中說明。 依據本發明,用於氣化器的一膨脹間隙氣體保護結構 包括一堅固,不具可撓性,不可壓縮的環形防火肩部,其 20直接與氣化器的一金屬突緣接觸。在本發明的一較佳實施 例中’該環形防火肩部自金屬突緣懸垂至在氣化器的頂肩 部上之間隙中。最好,防火肩部延伸至氣化器的防火裡襯 之熱面層以及氣化器的金屬殼之間的一空間中。 備置在熱面層及氣化器殼體之間的一支持防火裡襯層 10 546366 玖、發明說明 包括在熱面層之頂端表面下呈階梯狀的一頂端表面,以在 熱面層及氣化器殼體之間的一凹下空間。該凹下空間在氣 化器殼體之熱面層及内表面之間的支持層上具有一弧形凹 槽之形狀。 5 一可壓縮環形防火纖維墊圈裝置配置在環形凹槽中, 其選擇的高度可使環形防火纖維墊圈裝置在環形防火肩部 延伸至環形凹槽中時被環形防火肩部接合。 一環形間隙空間備置在熱面層及環形防火肩部之間。 · 該空間被一防火繩環形圈佔據並大體上被它塞住,而該圈 10連接至並靠著熱面層的一外週邊表面壓縮。 因此,當備置環形防火肩部的金屬突緣定位在氣化器 的頸部上時,環形防火肩部接合在環形凹槽中的環形防火 · 纖維墊圈裝置,而防火繩環形圈佔據環形防火肩部及熱面 - 層之間的空間。 15 在此組合中,來自氣化器之反應室的熱氣大體被阻止 通過氣化器的膨脹間隙而接觸氣化器的殼體。 · 環形的防火肩部之堅固,不具可撓性的不可壓縮特徵 大體上阻擋熱氣通過肩結構。此外,在環形防火肩部及熱 面層之間的窄空間中的防火繩環圈大體上阻止熱氣通過繩 20 結構。 配置在環形防火肩部之下的可壓縮環形防火纖維熱圈 裝置以及防火繩環形圈亦形成阻止氣體自反應室通過朝向 氣化器殼體之膨脹間隙。 在氣化器之操作中,熱面層會加熱並膨脹。熱膨脹會 11 玖、發明說明 造成熱面朝向金屬突緣舉起, 大體上除去在熱面層之頂 邊緣及金屬突緣之間的—室溫膨脹間隙距離。與防火繩環 形圈合作的環形防^部可有效地阻止熱氣接職化器殼 體,因此而不須在熱面層頂 只挪及金屬突緣之間備置任何墊 圈裝置。 因此熱面層可在氣化H操作時膨脹,以相當接近疊 置的金屬突緣。在金屬穿絲 、、、及…面層的頂邊緣之間的膨脹 間隙在氣化器操作中的f # 乍㈣此乍化另減少了熱合成氣體接觸氣 化器殼體之膨脹間隙的可能性。 因此,相互通過彼此而移動的環形防火肩部之堅固、 高密度、不可壓縮之特徵以及熱面層的堅固、高密度、不 可C縮之特徵大體上關閉在熱面層上的膨脹間隙,以有效 地阻止熱氣通過膨脹間隙至氣化器殻體。 本發明另包括-種阻止熱氣自一氣化器之反應室流至 -防火裡襯之—膨脹„:,並接觸氣化器之膨脹間隙的方 法’该方法包括備置一階梯式環形膨脹間隙於在一氣化器 頸部下的防火裡襯中’其中該防火裡襯的一熱面層在防: 裡襯的-支持層的頂端部上延伸,使得一環形凹槽界定在 熱面層及氣化器殼體之間的支持層上。該方法另包括以可 壓縮環形防火纖維墊圈裝置填充環形凹槽之—選擇高度, 並在氣化器頸部之-金屬突緣上形成—堅固、不具=性 不可壓縮的環形防火肩部。防火肩部塑形成使其一錐形 内表面安裝至環形凹槽中一選擇的深度,以接合該可壓縮 環形防火纖維墊圈裝置的選擇高度。 546366 玖、發明說明 »亥方法亦包括定位該金屬突緣,以環形防火肩部備置 在氣化h σ卩上’以使環形防火肩部延伸至環形凹槽中, 並接合可I縮環形防火纖維墊圈裳置。此外,該方法包括 防火肩邛及熱面層之間備置_選擇的環形間隙空間。該方 法另包括備置-防火繩圈於環形間隙空間中,以塞住環形 間隙空間。Other objects and features of the present invention will be described below. According to the present invention, an expansion gap gas protection structure for a gasifier includes a solid, non-flexible, incompressible annular fire-resistant shoulder, 20 of which is in direct contact with a metal flange of the gasifier. In a preferred embodiment of the present invention 'the annular fire-resistant shoulder is suspended from a metal flange into a gap on the top shoulder of the gasifier. Preferably, the fireproof shoulder extends into a space between the hot surface layer of the fireproof lining of the gasifier and the metal shell of the gasifier. A support fireproof lining layer 10 546366 provided between the hot surface layer and the gasifier shell, the description of the invention includes a top surface stepped under the top surface of the hot surface layer to A recessed space between the carburetor housing. The recessed space has the shape of an arc-shaped recess on the support layer between the hot surface layer and the inner surface of the gasifier shell. 5 A compressible annular fire-resistant fiber washer device is arranged in the annular groove, and the height is selected so that the annular fire-resistant fiber washer device is engaged by the annular fire-resistant shoulder when the annular fire-resistant shoulder extends into the annular groove. An annular gap space is provided between the hot surface layer and the annular fire-resistant shoulder. The space is occupied by and substantially plugged by a ring of fire rope, and the ring 10 is connected to and compressed against an outer peripheral surface of the hot surface layer. Therefore, when the metal flange provided with the annular fire-proof shoulder is positioned on the neck of the vaporizer, the annular fire-proof shoulder engages the annular fire-proof fiber washer device in the annular groove, and the fire-proof rope ring occupies the annular fire-proof shoulder. Department and hot surface-the space between the layers. 15 In this combination, the hot gas from the reaction chamber of the gasifier is generally prevented from contacting the shell of the gasifier through the expansion gap of the gasifier. · The rugged, non-flexible incompressible features of the annular fire-resistant shoulders generally block heat from passing through the shoulder structure. In addition, the fire rope loop in the narrow space between the annular fire-resistant shoulder and the hot surface layer substantially prevents hot air from passing through the rope 20 structure. The compressible annular fire-resistant fiber heating coil device and the fire rope annular ring arranged below the annular fire-resistant shoulder also form an expansion gap that prevents gas from passing from the reaction chamber toward the gasifier shell. During operation of the gasifier, the hot surface layer will heat up and expand. Thermal Expansion 11 玖 Description of the Invention The hot surface is lifted towards the metal flange, and the distance between the room temperature expansion gap between the top edge of the hot surface layer and the metal flange is roughly removed. The ring-shaped guard in cooperation with the fire rope loop can effectively prevent the hot gas from relaying the shell of the carburetor. Therefore, it is not necessary to provide any gasket device between the top of the hot surface layer and the metal flange. The hot surface layer can therefore expand during the gasification H operation to be fairly close to the stacked metal flanges. The expansion gap between the top edges of the metal thread ,,, and ... of the surface layer in the gasifier operation f # This change also reduces the possibility of the thermal synthesis gas contacting the expansion gap of the gasifier shell Sex. Therefore, the strong, high-density, and incompressible features of the annular fire-resistant shoulders that move through each other and the strong, high-density, and non-C-shrinkable features of the hot surface layer substantially close the expansion gap on the hot surface layer to Effectively prevents hot gas from passing through the expansion gap to the gasifier housing. The invention further includes a method for preventing hot gas from flowing from the reaction chamber of a gasifier to the fire lining and expanding it: and contacting the expansion gap of the gasifier. The method includes preparing a stepped annular expansion gap in the A fireproof lining under the neck of a gasifier 'wherein a hot surface layer of the fireproof lining extends over the top of the anti-lining-support layer, so that an annular groove is defined in the hot surface layer and gasification On the support layer between the shells of the heater. The method further comprises filling the annular groove with a compressible annular fire-resistant fiber washer device—selecting the height and forming on the metal flange of the gasifier neck—solid, not = Incompressible annular fire-resistant shoulder. The fire-resistant shoulder is formed so that a tapered inner surface is installed to a selected depth in the annular groove to engage the selected height of the compressible annular fire-resistant fiber washer device. 546366 发明, invention Explanation »The method also includes positioning the metal flange, placing a circular fire-resistant shoulder on the gasification h σ 卩 to extend the annular fire-resistant shoulder into the annular groove, and engaging a shrinkable annular fire-resistant fiber washer skirt. In addition, the method includes preparing a selected annular gap space between the fire-resistant shoulder pads and the hot surface layer. The method further includes preparing a fire-resistant rope loop in the annular gap space to plug the annular gap space.

口此本發明包括上述之結構及方法,而本發明的範 圍為申請專利範圍所界定。 圖式簡單說明 10 帛1圖為備置加入本發明的-實施例的-膨脹間隙保 護結構的-氣化㈣-上部份的簡化片段截面圖; 第2圖為其一放大的片段截面圖; 第3圖為備置-堅固、不具可挽性、不可壓縮之環形 防火肩部的氣化器之-金屬突緣的上下倒置下的簡化立體 15 圖;The present invention includes the structures and methods described above, and the scope of the present invention is defined by the scope of patent application. Brief description of the drawings 10 帛 1 is a simplified fragmentary cross-sectional view of the upper part of the present invention-an embodiment-an expansion gap protection structure-a gasification ㈣-Figure 2 is an enlarged fragmentary cross-sectional view; Figure 3 is a simplified three-dimensional view of the metal flange of the carburetor with a rugged, non-removable, incompressible ring-shaped fire-proof shoulder.

第4圖為如第1圖中所千盏/ 汁不氣化為之上部份的一片段部 份剖開之立體圖;而 第5圖為備置架設在金屬突緣上的一注入射出器的氣 化器之簡化截面圖。 圖式中的對應元件代表對應之元件。 Γ實施方式】 發明之詳細說明 現在參看圖式,尤其是第彳β 尸 八疋罘1及5圖,一氣化器大體上 以標號10代表。 13 546366 玖、發明說明 氣化器1 〇包括具有一頂頸邮〗 貝頭# 14,亦稱為氣化器頸部 μ的-外鋼容器或殼體12。該頂頸部14有—開口13(第i 圖),-注入射出器38(第5圖)通過它而延伸。氣化器殼體 12、包括一内表面15,其備置圍繞一反應室(第5圖)的一防 火裡襯16。該防火裡襯16包括防小 匕栝防火磚的一支持裡襯或支 持層18(第2圖),而防火磚備置一 1 7貞表面或頂邊緣20。該 支持層18亦可以任何適合的習知可灌倒、可鑄造防火材料Fig. 4 is a perspective view of a fragmentary part of the upper part as shown in Fig. 1; the fifth part is an injection ejector set on a metal flange. Simplified sectional view of the gasifier. Corresponding elements in the drawings represent corresponding elements. Γ embodiment] Detailed description of the invention Now referring to the drawings, especially the 彳 β corpse 疋 罘 疋 罘 及 1 and 5, a gasifier is generally represented by the reference numeral 10. 13 546366 (1). Description of the invention The gasifier 10 includes an outer steel container or casing 12 having a neck postal shell # 14, also known as the gasifier neck μ. The top neck 14 has an opening 13 (FIG. I), and an injection ejector 38 (FIG. 5) extending through it. The gasifier housing 12, includes an inner surface 15 which is provided with a fireproof liner 16 surrounding a reaction chamber (Figure 5). The fire lining 16 includes a support lining or support layer 18 (Fig. 2) of a small dagger-resistant fire brick, and the fire brick is provided with a 17 surface or top edge 20. The support layer 18 may also be any suitable conventional pourable, castable fire-resistant material

製成。 該防火裡襯16另包括_熱面碑22裡襯或層,亦稱為 1〇熱面層22。該熱面層22有一頂表面或頂邊緣24(第2圖) 以及面對反應室17的一熱面26。 支持層18的頂邊緣20在熱面層22的頂邊緣之下呈階 級狀,以界定-環形凹槽30(第4圖)。因此,支持層㈣ 頂邊緣2〇(第2圖)為環形凹槽3〇之底部。該頂邊緣2〇(第 15 1圖)可,譬如,在頂邊緣24下大約U7mm,而環形凹槽production. The fireproof lining 16 also includes a lining or layer of the hot surface monument 22, which is also referred to as 10 hot surface layer 22. The hot surface layer 22 has a top surface or a top edge 24 (FIG. 2) and a hot surface 26 facing the reaction chamber 17. The top edge 20 of the support layer 18 is stepped below the top edge of the hot surface layer 22 to define an annular groove 30 (Fig. 4). Therefore, the top edge 20 (Figure 2) of the support layer 为 is the bottom of the annular groove 30. The top edge 20 (Fig. 151) can be, for example, approximately U7mm below the top edge 24, and the annular groove

3〇自熱面層22至内表面15的寬度大約為71醜。 此處所備置的尺寸僅為例示之用,且為氣化器的整個 尺寸的函數。實際上’不同尺寸的氣化器可備置不同的尺 寸0 2〇 如第2圖所清楚顯示,支持層18及熱面層22的頂邊 緣20及24在氣化器頸部的一頂邊緣32下凹下,以在氣化 器10操作時防火裡襯16加熱時允許防火裡襯16膨脹。因 此,靠近頂頸部μ之頂邊緣32的氣化器殼體12之一内表 面部15a(第2圖)不被防火裡襯所覆蓋。 14 546366 玖、發明說明 亦稱為中間突、緣& _ 一 的 &形金屬突緣36(第2圖)配置在 頂頸部14的頂邊緣32 μ 上’以為一注入射出器38(第5圖) 備置一架設表面34(第j 、乐1圖)。在突緣36及支持層18和熱 面層22的頂邊緣2〇乃 5 次24之間的空間被稱為一膨脹間隙 40(第2圖)。 膨脹間隙40的离疮ώ 士』士 阿度自支持層18的頂邊緣20至突緣 36的一下表面部37(第2圖)大約為157麵,而自熱面層 22的頂邊緣24至下表面部37大約為33mm。 10 15 範化益1〇之在膨脹間隙40處的暴露内殼體部15a藉 由包括與突緣36接觸的一環形防火肩部5〇(第2圖)之-新 ㈣間隙保護結構被保護不直接暴露於熱氣及其他在氣化 器之反應室17中的熱狀況及化學反應中。環形防火肩部 50以堅固、不具可撓性、不可壓縮的防火材料製成,譬如 ,高密度可以佛羅里達州Delray的%丨1訂公司以 Thembond Formula 18商標販售之鋁鑄造材料製成。該環 形防火肩部50以可以不銹鋼製成的金屬防火錨54(第2、3 圖)連接至突緣36的下表面部37。 如第2及3圖中所清楚顯示,金屬防火錨54為奥克拉 荷馬州Broken Arrow標準的加腳、雙鉤可鑄造金+。 ’’田 隹田54 包括自一腳60分叉出的長及短腳部56、58。一綠ία ’弓曲或鉤 部64備置在長腳56的一自由端,而一相對的弯曲戈约立 66備置在短腳部58的自由端上。須知短腳部58朝向氣化 氣的一中心線70定向(第1圖)。 錨54的一些例示尺寸包括自金屬突緣36的釣部64至 15 20 546366 玖、發明說明 下面部37之兩度大約為63mm。自鉤部66至金屬突緣% 的下表面37之端腳部58的高度大約為5〇mm。腳56、% 的厚度各大約為5mm,而自鉤部64至鉤部66的錨54之 寬度大約為50mm。錨54的腳60大約在第2圖的平面上 5延伸15mm。並大體上在垂直於第2圖之平面的一平面上 延伸大約25mm。因此,在垂直於第2圖之平面的一平面 上之錨54的腳60長度大約為25mm。30. The width from the hot surface layer 22 to the inner surface 15 is approximately 71 ugly. The dimensions provided here are for illustration only and are a function of the overall dimensions of the gasifier. In fact, different sizes of gasifiers can be prepared with different sizes. As shown in Figure 2, the top edges 20 and 24 of the support layer 18 and hot surface layer 22 are at the top edge 32 of the gasifier neck. It is recessed to allow the fire lining 16 to expand when the fire lining 16 is heated while the gasifier 10 is in operation. Therefore, the inner surface portion 15a (Fig. 2) of one of the carburetor housings 12 near the top edge 32 of the top neck portion µ is not covered by the fireproof lining. 14 546366 发明, description of the invention Also known as the middle protrusion, edge & _ one of the & shaped metal flange 36 (Fig. 2) is arranged on the top edge 32 μ of the top neck 14 'as an injection ejector 38 ( (Fig. 5) Prepare an erecting surface 34 (fig. J, Le 1). The space between the flange 36 and the top edge 20 or 5 times 24 of the support layer 18 and the hot surface layer 22 is called an expansion gap 40 (Fig. 2). From the top edge 20 of the support layer 18 to the lower surface portion 37 (FIG. 2) of the flange 36, the degree of heat is approximately 157, and from the top edge 24 of the heating surface layer 22 to The lower surface portion 37 is approximately 33 mm. 10 15 Fan Huayi 10's exposed inner shell portion 15a at the expansion gap 40 is protected by including a ring-shaped fire-resistant shoulder portion 50 (Figure 2) in contact with the flange 36-Xinhua gap protection structure It is not directly exposed to hot gas and other thermal conditions and chemical reactions in the reaction chamber 17 of the gasifier. The annular fire-resistant shoulder 50 is made of a strong, non-flexible, incompressible fire-resistant material. For example, high-density aluminum casting materials sold under the trademark Thembond Formula 18 by Delray, Florida. The annular fire-resistant shoulder 50 is connected to the lower surface portion 37 of the flange 36 by a metal fire-resistant anchor 54 (FIGS. 2, 3) which can be made of stainless steel. As clearly shown in Figures 2 and 3, the metal fire anchor 54 is a standard footed, double hook castable gold + of the Broken Arrow, Oklahoma. "田田 田 54 includes long and short legs 56 and 58 which branch off from one leg 60. A green bow or hook 64 is provided on a free end of the long foot 56 and an opposite curved Goyol 66 is provided on the free end of the short foot 58. Note that the short feet 58 are oriented toward a centerline 70 of the gasification gas (Figure 1). Some exemplary dimensions of the anchor 54 include the fishing portion 64 to 15 20 546366 金属 from the metal flange 36. Description of the invention The lower portion 37 is approximately 63 mm in two degrees. The height from the hook portion 66 to the end leg portion 58 of the lower surface 37 of the metal flange% is approximately 50 mm. The thickness of the feet 56% is approximately 5 mm each, and the width of the anchor 54 from the hook portion 64 to the hook portion 66 is approximately 50 mm. The foot 60 of the anchor 54 extends approximately 15 mm on the plane 5 in FIG. 2. It extends approximately 25 mm on a plane perpendicular to the plane of Figure 2. Therefore, the length of the foot 60 of the anchor 54 on a plane perpendicular to the plane of FIG. 2 is approximately 25 mm.

錨54在腳60處熔接至金屬突緣36的下表面部, 並沿者一圓形路徑以大約100mm的間隔配置,而該圓形路 1〇徑的直徑大約與等於頂頸部14之内徑加上熱面層22之外 仫除以2,再加上大約4mm。因此該金屬錨54沿著,譬如 ,自中心線70(第i圖)算起大約275mm之半徑的一圓形中 心線定位。 15 在此組合下,大約十二個錯54炫接至金屬突緣36的 下表面部37,但僅六個錨54顯示於第3圖中。金屬錨54 最好以In__條焊至表面37,且纽接前金屬突緣% 最好預熱至大約400T。熔接繞著腳6〇的週邊為連續的。The anchor 54 is welded to the lower surface portion of the metal flange 36 at the foot 60 and is arranged at a distance of about 100 mm along a circular path, and the diameter of the circular path 10 is approximately equal to within the top neck 14 The diameter plus the hot surface layer 22 is divided by 2, plus approximately 4 mm. Therefore, the metal anchor 54 is positioned along, for example, a circular center line having a radius of about 275 mm from the center line 70 (Fig. I). 15 In this combination, about twelve mistakes 54 are attached to the lower surface portion 37 of the metal flange 36, but only six anchors 54 are shown in the third figure. The metal anchor 54 is preferably welded to the surface 37 with an In__ strip, and the metal flange% before the joint is preferably preheated to about 400T. The welding is continuous around the periphery of the foot 60.

20 最好,錯54定位成使得連相54的腳短腳58 t平面相對 於自氣化器H)的中心線70起的一徑向線成+45。至—吵 —旦金相54熔接至金屬突緣36,使収位在1 轉金屬突緣36之表面上的任何習知構造的—模具(未顯示) 形成環形防火肩部50(第3圖)。模具操作必須備置肩部% 的-輪扉,而肩部50自下表面部37突出大約— 16 546366 玖、發明說明 下表面部37備置大體上垂直且與頸部14的内表面ΐ5&距 離5mm的一外週邊表面74。環形防火肩部5〇亦包括一内 週邊表面76,該表面沿著朝向環形防火肩部%的一自由 ^之一方向稍許朝外週邊表面74、彎曲。 5 譬如,自由端表面78最好比與金屬突緣30之下表面 37接觸之肩部5〇的相對表面窄大約—。内週邊表面與 熱面層22(第2圖)之外週邊表面距離大約1〇mm。 在下表面部37上的肩部50的内週邊表面%之内徑, 譬如,等於大約熱面層22的外徑加上大約7mm。在端表 1〇面78上的肩部50之内週邊表面76的内徑,譬如,等於頂 邊緣24的外徑加上大約13mm。 一旦環形防火肩部50固化,金屬突緣36及防火肩部 ’ 5〇可乾燥至大約4〇(TC,而該溫度維持,譬如,至少四個 · 小時。可選擇地,備置新固化之防火肩部5〇的金屬突緣 15 36可在預熱氣化器時,架設在氣化器上,而乾燥步驟可跟 隨著金屬突緣36架設在氣化器之後。然而,在氣化器1〇 · 的預熱步驟中,環形防火肩部50的乾燥程序可要求氣化器 10以較慢的速率加熱。 在木5又備置防火肩部5 0的金屬突緣3 6於頂頸部14上 20時,一防火纖維熱膨脹墊圈90架設在熱面層22的外週邊 表面100後。該防火纖維墊圈90定位成在支持層頂表面 20上的未壓縮狀態。防火纖維墊圈9()的芯體可包括三個 單獨的耐至少1250。(:的大約25mm厚度之防火毯製成的片 狀環92、94及96(第2圖)。環92、94及96的内徑,譬如 17 546366 玖、發明說明 ’大於支持層18之内徑厚度1 min,而其外徑大約,嬖如 小於在内表面15a上之頸部14的内徑imm。三個防火纖 維毯製成的環92、94及96最好相互疊置,並包封在耐至 少1250°C熱的約lmm厚度之陶瓷布的鞘98中。 5 最理想的是,防火纖維墊圈90必須預先組合及架設成 一單獨的置於環形槽30中的單元。 須知防火纖維墊圈90可在熱面層22的外週邊表面 100(第2圖)上承受具破壞性的摩擦能力。因此,最好鞘 · 98十分具有彈性,且可加入如Inc〇nei⑧的高溫合金線纖 10 維。 此外,在備置環形防火肩部50的金屬突緣36架設在 頂頭邛14上之刖,譬如直徑大約為igmm的一防火繩單一 圈82(第2圖)連接至緊接在防火纖維墊圈9〇之上的熱面 , 層22之外週邊表面1〇〇並靠著它而壓縮。繩圈82最好圍 15繞著熱面層22的外週邊表面100之整個週邊延伸的一單一 片,並以如黏著帶(未顯示)的一可燃燒材料支持定位,而 · 該黏著帶會僅可能地壓縮繩圈82,且最好拉平它成為小於 l〇mm。在氣化器加熱中,可燃燒帶會燒掉,以允許繩圈膨 脹至其正常的未壓縮厚度。 2〇 在金屬突緣36架設至頂頸部14上後,當防火肩部5〇 下降至環形槽30中時,繩圈82的此種壓縮可使防火肩部 5〇的自由端78滑過繩82(第2圖)。因此,環形繩圈佔據 在I田54之内週邊表面γβ及熱面層22之外週邊表面之 間的一環形凹槽空間1〇2(第2圖),以大體上塞住空間1〇2 18 玖、發明說明 〇 如上所述,環形防火肩部50的内週邊表面76稍許朝 向自由端78彎曲。因此,空間1〇2必須在自防火纖維墊圈 9〇的向上方向變得較窄。於是,彎曲的内週邊表面76可 阻止繩圈82自空間1〇2中吸出,因為當繩82在空間1〇2 中由於熱面層22之熱膨脹而向上捲曲時會壓縮。 然後,備置環形防火肩部50的金屬突緣36在繩圈82 連接至熱面層22的外週邊表面1〇〇時精確地定位在頂頸部 Μ之頂上,如第丨、2及5圖中所示。金屬突緣36的精確 定位確保環形防火肩部與環形槽3〇對齊,並定位在其中, 而不干擾熱面層22的頂頸部14。 在此組合中,大體上為不透氣材料製成的環形防火肩 部50及陶瓷繩阻止合成氣體自反應室17通過防火纖維墊 圈90朝向氣化器殼體表面15a及15的頸部14。不透氣防 火肩部50亦阻止熱的合成氣體直接通過防火肩部5〇朝向 氣化器殼體表面15a的氣化器頸部14。 在氣化器10操作時,熱面層22以朝向金屬突緣36的 向上方向膨脹,因此,當氣化器加熱至操作溫度時滑過防 火肩部50。 最理想的狀況是防火肩部5()的内週邊表面76必須儘 可能地接近熱面層22的外週邊表面1〇〇。然而,由於製造 及架設公差必須確保在防火肩部5〇及熱面層22之間無干 擾,防火纖維繩82被壓縮至肩部5〇及熱面層22之間的空 間102中(第2圖),因而顯著地限制可能會通過的氣體量 546366 玖、發明說明 一旦氣化器在操作溫度下,在熱面層22的頂表面24 及金屬突緣36之間的膨脹氣體可小至3mm,以減少到達 防火肩部50的氣體量,因而顯著地在操作時減少氣化器殼 5 體12溫度之上升。 須知在金屬突緣36的下表面37以及支持層及熱面層 的頂表面20及24之間的室溫下的距離可相對於氣化器頸 部之頂邊緣之測量並以在金屬突緣36架設前大約測量出, · 此近似值以在金屬突緣36及氣化器頸部之頂邊緣32之間 10 的一壓縮墊圈厚度加以調整而算出。 本發明的某些優點已可由上述說明中瞭解,其包括用 於大體上以不透氣防火材料形成的一膨脹間隙的一保護結 構,以阻止熱的合成氣體通過膨脹間隙朝向氣化器殼體。 该膨脹間隙保護結構包括不可壓縮且不具可撓性的一堅固 15環形防火肩部。該肩部與相當不可壓縮的防火繩圈合作以 罪著相當可壓縮的纖維防火材料,並大體上阻擋相當可壓 · 縮之纖維防火材料暴露至來自氣化器的反應室之合成氣體 中。 本發明的另一優點為架設在氣化器中的熱面磚可架設 2 〇至在熱面層及金屬突緣之間備置一大體上較習知技藝小的 間隙之高度’因為不須在熱面層之頂表面及金屬突緣之間 備置任何纖維材料。因此,可大體上關閉在熱面層的頂端 及金屬突緣之間的膨脹間隙之部份。因此,在熱面層及金 屬突緣之間的膨脹間隙部份可減至最小。 20 546366 玖、發明說明 由於以上所述,可看出本發明的數個目的及優點可達 成。在不脫離本發明的範圍下上述結構及方法可作不同之 改變,因此配合圖式之上述說明僅為例示之用,不得視為 一種限制。 . 5 【囷式簡單說明】 第1圖為備置加入本發明的一實施例的一膨脹間隙保 護結構的一氣化器的一上部份的簡化片段截面圖; 第2圖為其一放大的片段截面圖; $ 第3圖為備置一堅固、不具可撓性、不可壓縮之環形 10防火肩部的氣化器之一金屬突緣的上下倒置下的簡化立體 圖; 第4圖為如第i圖中所示氣化器之上部份的一片段部 * 份剖開之立體圖;而 . 第圖為備置架ό又在金屬突緣上的一注入射出器的氣 15化器之簡化截面圖。 21 546366 玖、發明說明 【囷式之主要元件代表符號表】 10 氣化器 50 環形防火肩部 12 殼體 54 錯 13 開口 56 長腳部 14 頂頸部 58 短腳部 15 内表面 60 腳 15a 内表面部 64 鉤部 16 防火裡襯 66 鉤部 17 反應室 70 中心線 18 支持層 74 外週邊表面 20 頂邊緣 76 内週邊表面 22 熱面層 78 自由端表面 24 頂邊緣 82 繩圈 26 熱面 90 防火纖維墊圈 30 環形凹槽 92 環 32 頂邊緣 94 環 34 架設表面 96 環 36 突緣 98 鞘 37 下表面部 100 外週邊表面 38 注入射出器 102 環形凹槽空間 40 膨脹間隙20 Preferably, the misalignment 54 is positioned so that the plane of the feet 58t of the consecutive phase 54 is +45 with respect to a radial line from the center line 70 of the gasifier PD). To—noisy—dan metallurgical 54 is welded to the metal flange 36 so that any conventional structure—mold (not shown) that rests on the surface of the metal flange 36—forms a ring-shaped fireproof shoulder 50 (Figure 3) ). The mold operation must be prepared with shoulders-wheel 扉, and the shoulder 50 protrudes from the lower surface portion 37 approximately-16 546366 玖, description of the invention The lower surface portion 37 is provided substantially perpendicular to the inner surface of the neck 14 ΐ 5 & distance 5mm Of an outer peripheral surface 74. The annular fire-resistant shoulder 50 also includes an inner peripheral surface 76 which is slightly curved toward the outer peripheral surface 74 in a direction of one free direction toward the annular fire-resistant shoulder%. 5 For example, the free end surface 78 is preferably narrower than the opposite surface of the shoulder 50 which is in contact with the lower surface 37 of the metal flange 30. The distance between the inner peripheral surface and the outer peripheral surface of the hot surface layer 22 (Fig. 2) is about 10 mm. The inner diameter of the inner peripheral surface% of the shoulder portion 50 on the lower surface portion 37 is, for example, equal to about the outer diameter of the hot surface layer 22 plus about 7 mm. The inner diameter of the inner peripheral surface 76 within the shoulder 50 on the end surface 10 surface 78 is, for example, equal to the outer diameter of the top edge 24 plus approximately 13 mm. Once the ring-shaped fire-resistant shoulder 50 is cured, the metal flange 36 and the fire-resistant shoulder '50 can be dried to about 40 ° C., and the temperature is maintained, for example, at least four hours. Alternatively, a newly cured fire protection can be provided The metal flange 15 36 of the shoulder 50 may be mounted on the gasifier when the gasifier is preheated, and the drying step may be mounted after the gasifier following the metal flange 36. However, in the gasifier 1 In the preheating step, the drying process of the annular fire-resistant shoulder 50 may require the gasifier 10 to heat at a slower rate. The metal flange 3 of the fire-resistant shoulder 50 is provided on the wood 5 and the top neck 14 At 20 o'clock, a fireproof fiber thermal expansion washer 90 is mounted behind the outer peripheral surface 100 of the hot surface layer 22. The fireproof fiber washer 90 is positioned in an uncompressed state on the top surface 20 of the support layer. The core of the fireproof fiber washer 9 () The body may include three separate sheet rings 92, 94, and 96 made of a fire-resistant blanket with a thickness of about 25 mm (Figure 2). The inner diameters of the rings 92, 94, and 96, such as 17 546366发明 Description of the invention 'is greater than the inner diameter thickness of the support layer 18 for 1 min, and its outer diameter is about, such as Smaller than the inner diameter imm of the neck 14 on the inner surface 15a. The rings 92, 94 and 96 made of three fire-resistant fiber blankets are preferably stacked on top of each other and encapsulated in a thickness of about 1 mm which is resistant to heat of at least 1250 ° C. Ceramic sheath 98. 5 Ideally, the fireproof fiber gasket 90 must be assembled and erected in advance as a single unit placed in the annular groove 30. Note that the fireproof fiber gasket 90 can be placed on the outer peripheral surface 100 of the hot surface layer 22 (Picture 2) It is capable of withstanding destructive friction. Therefore, it is best that the sheath 98 is very elastic and can be added with a 10-dimensional high-temperature alloy wire such as Inconei⑧. In addition, A metal flange 36 is erected on the head 邛 14. For example, a single loop 82 (picture 2) of a fireproof rope with a diameter of about igmm is connected to the hot surface immediately above the fireproof fiber washer 90, outside the layer 22. The peripheral surface 100 is compressed against it. The loop 82 is preferably a single piece extending 15 around the entire periphery of the outer peripheral surface 100 of the hot surface layer 22, and is formed by a tape such as an adhesive tape (not shown). Combustible material supports positioning, while the adhesive tape will only compress as much as possible Loop 82, and preferably flatten it to less than 10 mm. During heating of the gasifier, the combustible belt will burn out to allow the loop to expand to its normal uncompressed thickness. 20 erected to the metal flange 36 After the top neck 14 is brought up, when the fireproof shoulder 50 is lowered into the annular groove 30, this compression of the rope loop 82 can cause the free end 78 of the fireproof shoulder 50 to slide over the rope 82 (Fig. 2). The annular rope loop occupies an annular groove space 102 (Figure 2) between the inner peripheral surface γβ of Ita 54 and the outer peripheral surface of the hot surface layer 22 to substantially block the space 1022.说明 DESCRIPTION OF THE INVENTION As described above, the inner peripheral surface 76 of the annular fire-resistant shoulder 50 is slightly bent toward the free end 78. Therefore, the space 102 must be narrowed in the upward direction from the fireproof fiber washer 90. Thus, the curved inner peripheral surface 76 prevents the loop 82 from sucking out of the space 102 because it will compress when the rope 82 curls upward in the space 102 due to the thermal expansion of the hot surface layer 22. Then, the metal flange 36 provided with the annular fire-proof shoulder 50 is accurately positioned on the top of the top neck M when the loop 82 is connected to the outer peripheral surface 100 of the hot surface layer 22, as shown in FIGS. 1,2, and 5. As shown. The precise positioning of the metal flange 36 ensures that the annular fire-resistant shoulder is aligned with and positioned in the annular groove 30 without interfering with the top neck portion 14 of the hot surface layer 22. In this combination, an annular fire-resistant shoulder 50 and ceramic rope made of substantially air-impermeable material prevent the synthesis gas from passing from the reaction chamber 17 through the fire-resistant fiber gasket 90 toward the neck 14 of the gasifier shell surfaces 15a and 15. The airtight fireproof shoulder 50 also prevents hot synthetic gas from passing directly through the fireproof shoulder 50 toward the carburettor neck 14 of the carburettor housing surface 15a. When the gasifier 10 is operating, the hot surface layer 22 expands in an upward direction toward the metal flange 36, and therefore, it slides over the fireproof shoulder 50 when the gasifier is heated to the operating temperature. The most ideal situation is that the inner peripheral surface 76 of the fireproof shoulder 5 () must be as close as possible to the outer peripheral surface 100 of the hot surface layer 22. However, because manufacturing and erection tolerances must ensure that there is no interference between the fire-resistant shoulder 50 and the hot surface layer 22, the fire-resistant fiber rope 82 is compressed into the space 102 between the shoulder 50 and the hot-surface layer 22 (second Figure), thus significantly limiting the amount of gas that can pass through 546,366 发明, invention description Once the gasifier is at operating temperature, the expansion gas between the top surface 24 of the hot surface layer 22 and the metal flange 36 can be as small as 3 mm In order to reduce the amount of gas reaching the fireproof shoulder 50, the temperature rise of the gasifier shell 5 and the body 12 is significantly reduced during operation. It should be noted that the distance between the lower surface 37 of the metal flange 36 and the top surfaces 20 and 24 of the support layer and the hot surface layer at room temperature can be measured relative to the top edge of the gasifier neck and the metal flange Approximately measured before erection 36. · This approximate value is calculated by adjusting the thickness of a compression washer 10 between the metal flange 36 and the top edge 32 of the gasifier neck. Certain advantages of the present invention, which can be understood from the foregoing description, include a protective structure for an expansion gap formed generally of a gas-impermeable fireproof material to prevent hot synthesis gas from passing through the expansion gap toward the gasifier shell. The expansion gap protection structure includes a rugged 15-ring fire-resistant shoulder that is incompressible and non-flexible. The shoulder cooperates with a fairly incompressible fire-resistant loop to guilty of a relatively compressible fibrous fire-resistant material and generally blocks exposure of the relatively compressible fiber-fired fire-resistant material to synthetic gas from the reaction chamber of the gasifier. Another advantage of the present invention is that the hot surface brick erected in the gasifier can be erected from 20 to a height of a gap that is generally smaller than the conventional technique between the hot surface layer and the metal flange. Place any fibrous material between the top surface of the facing layer and the metal flange. Therefore, the portion of the expansion gap between the top of the hot surface layer and the metal flange can be substantially closed. Therefore, the portion of the expansion gap between the hot surface layer and the metal flange can be minimized. 20 546366 (ii) Description of the invention As described above, it can be seen that several objects and advantages of the present invention can be achieved. The above structures and methods can be changed differently without departing from the scope of the present invention. Therefore, the above description in conjunction with the drawings is for illustration only and should not be considered as a limitation. 5 [Brief description of the formula] FIG. 1 is a simplified fragmentary cross-sectional view of an upper part of a gasifier equipped with an expansion gap protection structure according to an embodiment of the present invention; FIG. 2 is an enlarged fragment thereof. Sectional view; $ Figure 3 is a simplified perspective view of the metal flange of one of the vaporizers with a strong, non-flexible, incompressible, ring-shaped 10 fire-resistant shoulder. Figure 4 is as shown in Figure i. A fragmentary perspective view of a fragmentary part of the upper part of the gasifier shown in the figure; and. The figure below is a simplified cross-sectional view of a gasifier with an injector and an injector on a metal flange. 21 546366 发明 Description of the invention [List of representative symbols of main components of the style] 10 Vaporizer 50 Ring fire shoulder 12 Case 54 Mistake 13 Opening 56 Long foot 14 Top neck 58 Short foot 15 Inner surface 60 Foot 15a Inner surface portion 64 Hook portion 16 Fire lining 66 Hook portion 17 Reaction chamber 70 Centerline 18 Support layer 74 Outer peripheral surface 20 Top edge 76 Inner peripheral surface 22 Hot surface layer 78 Free end surface 24 Top edge 82 Rope 26 Hot surface 90 Fire-resistant fiber washer 30 Ring groove 92 Ring 32 Top edge 94 Ring 34 Erection surface 96 Ring 36 Flange 98 Sheath 37 Lower surface part 100 Outer peripheral surface 38 Note injector 102 Ring groove space 40 Expansion gap

22twenty two

Claims (1)

_、申請專利範圍 1 · 一種氣化器,其包括: a) 備置一側表面及一頸開口的一金屬氣化器殼體, b) 配置在頸開口上的一金屬突緣, c) 在氣化器内的一反應室, d) 在氣化器殼體之反應室之内面上的一防火裡襯, 该防火裡襯在頸開口下有一頂部,使得在防火裡襯的頂 部上之氣化器殼體的内表面不被防火裡襯覆蓋,且該防 火裡襯的一膨脹間隙界定在防火裡襯的頂部上,以及 e) —恥脹間隙保護結構,其包括以堅固、不具可撓 性、不可壓縮的與金屬突緣接觸且自金屬突緣延伸至膨 脹間隙中的防火材料形成的一環形防火肩部。 2.如申請專利範圍帛!項的氣化器,其中該防火裡襯包括 面對反應室的一熱面層,該熱面層在防火裡襯的頂部上 有一第一頂邊緣部,該頂邊緣部在頸開口下並與其有一 段距離,該防火裡襯包括在氣化器殼體之内表面及熱面 層之間的-支持層,該支持層具有在防火裡襯之頂部上 的一第二頂邊緣部,該第二頂邊緣部在第-頂邊緣部之 下並與其有—段距離,使得—環形凹槽界定在熱面層及 氣化器殼體之内表面之間的支持層的第H緣之上。 3·如申請專利範圍帛2項的氣化器,其中該環形防火肩部 延伸至環形凹槽中,且包括與熱面層有—段距離的一内 週邊表面以及與氣化器殼體之内表面有一段距離的一外 週邊表面。 4·如申請專利範圍帛2項的氣化器,其中該環形槽具有自 546366 拾、申請專利範圍 熱面層至環形防火肩部的内週邊表面的第一環形寬度, 而一環形防火繩圈連接至熱面層的外週邊表面,其中防 火繩的横截面直徑佔據環形凹槽的第_環形寬度。 5·如申請專利範圍第4項的氣化器,其中該環形防火肩部 具有一底自由端表面,而該環形防火肩部的内週邊表面 朝向週邊表面以朝底自由端表面的—方向彎曲,且防火 繩環形圈連接至靠近環形防火肩部的底自由端表面之熱_ 、 Scope of patent application 1 · A gasifier includes: a) a metal gasifier housing with one side surface and a neck opening, b) a metal flange disposed on the neck opening, c) a A reaction chamber in the gasifier, d) a fireproof lining on the inside of the reaction chamber of the gasifier shell, the fireproof lining has a top under the neck opening so that the gas on the top of the fireproof lining The inner surface of the carburetor housing is not covered by a fireproof lining, and an expansion gap of the fireproof lining is defined on the top of the fireproof lining, and e) a swollen gap protection structure including a solid, non-flexible An annular fire-resistant shoulder formed by a non-compressible, incompressible fire-resistant material that contacts the metal flange and extends from the metal flange into the expansion gap. 2. If the scope of patent application is 帛! The gasifier of claim, wherein the fireproof lining comprises a hot surface layer facing the reaction chamber, the hot surface layer has a first top edge portion on the top of the fireproof lining, and the top edge portion is under the neck opening and connected to the same. At a distance, the fireproof lining includes a support layer between the inner surface of the gasifier shell and the hot surface layer. The support layer has a second top edge portion on the top of the fireproof lining. The two top edge portions are below and at a distance from the first top edge portion, so that the annular groove is defined above the Hth edge of the support layer between the hot surface layer and the inner surface of the gasifier shell. 3. The gasifier as claimed in the scope of patent application No. 2 wherein the annular fire-resistant shoulder extends into the annular groove and includes an inner peripheral surface at a distance from the hot surface layer and the gasifier shell. The inner surface has a distance from the outer peripheral surface. 4. The gasifier according to item 2 of the scope of patent application, wherein the annular groove has a first annular width from the hot surface layer of the scope of patent application 546366 to the inner peripheral surface of the annular fire shoulder, and an annular fire rope The loop is connected to the outer peripheral surface of the hot surface layer, wherein the cross-sectional diameter of the fire prevention rope occupies the _th annular width of the annular groove. 5. The gasifier according to item 4 of the patent application, wherein the annular fire-resistant shoulder has a bottom free end surface, and the inner peripheral surface of the annular fire-resistant shoulder is bent toward the peripheral surface in a direction toward the bottom free end surface. And the ring of the fire rope is connected to the heat near the bottom free end surface of the ring fire shoulder 面層的外週邊表面。 6·如申請專利_ 3項的氣化器,其 結構另包括配置在環形凹财的可壓縮環形防火纖= 圈j置’該環形防火纖維墊圈裝置與該環形防火肩部具 擇回度’可使該環形防火纖維塾圈裝置在該環形肩 仪伸至㈣形凹槽中時被該環形防火肩部接合。 7·如申凊專利範圍帛1項的氣化器,其包括用以連接環形 防火肩部至金屬突緣的裝置。The outer peripheral surface of the facing. 6 · If you apply for a patent _ 3 gasifiers, the structure also includes a compressible annular fireproof fiber arranged in a circular recessed property = circle j is set 'the annular fireproof fiber washer device and the annular fireproof shoulder have selective reversion' The annular fireproof fiber loop device can be engaged by the annular fireproof shoulder when the annular shoulder instrument is extended into the 仪 -shaped groove. 7. The carburetor according to item 1 of the patent application scope, which includes a device for connecting the annular fire-resistant shoulder to the metal flange. 8·如申請專利範圍第7項的氣化器,其中該連接裝置延 伸至%形防火肩部中,且包括溶接至金屬突緣的數個 間隔的金屬錨元件。 申明專利範圍第!項的氣化器,其中該膨脹間隙保 ι、、σ構另包括配置在膨服間隙中的可壓縮環形防火纖 維塾圈裝置’而該環形防火纖維塾圈裝置在膨脹間隙 中的選擇高度允許接合環形防火肩部。 .如申明專利範圍第9項的氣化器,其中該環形纖維塾 圈裝置可壓縮’且具有一頂表面,而該環形防火肩部 24 546366 拾、申請專利範圍 具有接觸及覆蓋環形防火纖維墊圈裝置之頂表面區的 一主要部份之底表面。 11·如申請專利範圍第ίο項的氣化器,其中該防火裡襯包 括具有面對反應室之一内熱面表面的一熱面層,以及 5 面對氣化器殼體之一外表面,且其中該環形防火肩部 具有與熱面層之外表面相間隔的一内週邊表面,且其 中一環形防火繩圈連接至熱面層之外週邊表面,以佔 據在環形防火肩部之内週邊表面及熱面層之外表面之 · 間的空間。 10 12·一種氣化器,其包括: a) 一金屬氣化器殼體,其備置一内表面、一頂 部以及在頂部上的一開口, ’ b) 配置在頂部開口上的一金屬突緣, - c) 一内反應室’其在金屬殼體的内表面上備置 15 一防火裡襯,該防火裡襯包括以其一第一環形頂邊緣 配置在頂部開口下一段距離處的一熱面層以及以一第 鲁 一環形頂邊緣配置在熱面層的第一環形頂邊緣一段距 離處的一支持層,使得在熱面層之第一環形頂邊緣以 及支持層的第二環形頂邊緣上的氣化器殼體之内表面 20 不被防火裡襯所覆蓋,而一膨脹間隙界定在熱面層及 支持層的第一及第二環形頂邊緣上,以及 d) —膨脹間隙保護結構,其包括一堅固、不可 壓縮的環形防火肩部,其自金屬突緣向下延伸至在氣 化器殼體的熱面層以及内表面之間的一環形空間中, 25 546366 拾、申請專利範圍 其延伸的深度低於熱面層之第一環形頂邊緣,但高於 支持層的第二環形頂邊緣。 ίο 13.如申請專利範圍第12項的氣化器,其中該膨脹間隙保 護結構包括在支持層的第二環形頂邊緣上的可麼縮防 火纖維墊圈裝置,該環形纖維墊圈裝置具有_上表面 以及自第二環形頂邊緣起算的一選出之高度,使得環 形防火纖維墊圈裝置的上表面被環形防火肩部接合。 14.如申請專利範圍第13項的氣化器,其中該熱面層具有 面向氣化器殼體的一外表面,而該環形防火肩部=括 與熱面層之外表面間隔的一内週邊表面,且其中一環 形防火繩圈連接至熱面層的外表面,以佔據環形防I 肩部的内週邊表面及熱面層的外表面之間的空間。 15•如申請專利範圍第14項的氣化器,其中該環形防火肩 部的内週邊表面自熱面的外表面以朝向纖維塾圈裝置 158. The carburetor according to item 7 of the patent application scope, wherein the connecting device extends into the% -shaped fire-resistant shoulder and includes a plurality of spaced-apart metal anchoring elements welded to the metal flange. A gasifier claiming the scope of the patent !, wherein the expansion gap protection, σ, and σ structure further include a compressible annular fireproof fiber loop device disposed in the expansion gap, and the annular fireproof fiber loop device is in the expansion gap The selected height allows for the engagement of a circular fire-resistant shoulder. As stated in the gasifier of item 9 of the patent scope, wherein the annular fiber loop device is compressible and has a top surface, and the annular fire-resistant shoulder 24 546366, the scope of the patent application has contact and covers the annular fire-resistant fiber washer The bottom surface of a major part of the top surface area of the device. 11. The gasifier as claimed in item ίο, wherein the fireproof lining includes a hot surface layer having an inner hot surface surface facing one of the reaction chambers, and 5 an outer surface facing one of the gasifier shells. And wherein the annular fire-resistant shoulder portion has an inner peripheral surface spaced from the outer surface of the hot surface layer, and one of the annular fire rope loops is connected to the outer peripheral surface of the hot surface layer to occupy the inner periphery of the annular fire-proof shoulder portion The space between the surface and the outer surface of the hot surface layer. 10 12. A gasifier comprising: a) a metal gasifier housing provided with an inner surface, a top and an opening on the top, and 'b) a metal flange disposed on the top opening -C) An internal reaction chamber 'which is provided on the inner surface of the metal casing with a fireproof lining comprising a first annular top edge disposed at a distance below the top opening with a heat The surface layer and a support layer arranged at a distance from the first annular top edge of the hot surface layer with a first annular top edge, so that the first annular top edge of the hot surface layer and the second annular shape of the support layer The inner surface 20 of the gasifier shell on the top edge is not covered by the fireproof lining, and an expansion gap is defined on the first and second annular top edges of the hot surface layer and the support layer, and d) the expansion gap A protective structure comprising a solid, incompressible annular fire-resistant shoulder extending downwardly from a metal flange into an annular space between the hot surface layer and the inner surface of the gasifier shell, 25 546366, Patent application scope extended Below the top edge of the first annular surface layer of the heat, but the second annular supporting layer is higher than the top edge. ίο 13. The carburetor according to item 12 of the patent application scope, wherein the expansion gap protection structure comprises a shrinkable fireproof fiber gasket device on a second annular top edge of the support layer, and the annular fiber gasket device has an upper surface And a selected height from the second annular top edge, so that the upper surface of the annular fireproof fiber washer device is joined by the annular fireproof shoulder. 14. The gasifier according to item 13 of the application, wherein the hot surface layer has an outer surface facing the shell of the gasifier, and the annular fire-resistant shoulder portion includes an inner space spaced from the outer surface of the hot surface layer. The peripheral surface, and one of the annular fire-proof rope loops is connected to the outer surface of the hot surface layer to occupy the space between the inner peripheral surface of the annular anti-I shoulder and the outer surface of the hot surface layer. 15 • The carburetor according to item 14 of the patent application scope, wherein the inner peripheral surface of the annular fire-resistant shoulder is the outer surface of the self-heating surface to face the fiber loop device 15 的一方向青曲’而防火織環形圈連接至環形防火纖維 墊圈裝置之上表面上的熱面層的外表面。 16•如申請專利範圍第12項的氣化器,其包括用以連接環 形防火肩部至金屬突緣的裝置。 17.如申請專利範圍第16項的氣化器,其中該連接裝置包 括數個溶接至金屬突緣的間隔金屬錨元件。 18· 一種阻止熱氣自一氣化器之反應室流經-防火裡襯之 -膨脹間隙並在該膨脹間隙處進人該氣化器殼體的方 法,該方法包括: a)備置-階梯式環形膨脹間隙於在一氣化器頸 26 20 546366 公舌泰: I_________j 拾、申請專利範圍 π下的防火裡襯中’其中該防火裡襯的一熱面層在該 防火裡襯的-支持層的頂端部上延伸,使得一環形凹 槽界定在該熱面層及該氣化器殼體之間的支持層上, b)以可壓縮環形防火纖維墊圈裝置填充該環形 凹槽之一選擇高度,The one-sided direction is curved and the fire-resistant weave ring is connected to the outer surface of the hot surface layer on the upper surface of the annular fire-resistant fiber washer device. 16 • The vaporizer of claim 12 including means for connecting the annular fire-resistant shoulder to the metal flange. 17. The gasifier of claim 16, wherein the connecting device comprises a plurality of spaced metal anchoring elements which are welded to the metal flange. 18. · A method of preventing hot gas from flowing through a reaction chamber of a gasifier through a fire-resistant lining-expansion gap and entering the gasifier shell at the expansion gap, the method comprising: a) preparing-stepped ring The expansion gap is in a gasifier neck 26 20 546366 male tongue: I_________j, fire lining under the scope of patent application π, wherein a hot surface layer of the fire lining is on the top of the fire lining-supporting layer Extended on the part so that an annular groove is defined on the support layer between the hot surface layer and the gasifier shell, b) filling a selected height of the annular groove with a compressible annular fireproof fiber gasket device, 〇在該氣化器頸部之一金屬突緣上形成—堅固 、不具可撓性、不可壓縮的環形防火肩部,塑形該防 火肩部以使其安裝至在環形凹槽中的一選擇深度,以 接合該可壓縮環形防火纖維塾圈裝置的選擇高度,以 M ^ ^ ^ ^ 7ft 氣化器頸部上,以使該環形防火肩部延伸至該環形 槽中’並接合該可壓縮環形防火纖維墊圈裝置。 19·如申請專利範圍第18項的方 15 立 /、a括在%形防火 部及熱面層之間備置一選擇 长仏二間,並在環形丨〇Formed on a metal flange of the neck of the gasifier—a strong, non-flexible, incompressible annular fire-resistant shoulder, which is an option to shape the fire-resistant shoulder to fit in an annular groove Depth to engage the selected height of the compressible annular fire-resistant fiber loop device with M ^ ^ ^ ^ 7ft on the neck of the carburetor so that the annular fire-resistant shoulder extends into the annular groove 'and engage the compressible Ring-shaped fire-resistant fiber washer device. 19. If you apply for the item 18 of the scope of the patent application, 15 cubic meters, a, including a choice between the% -shaped fireproof section and the hot surface layer 火肩部及熱面層之間的空間中備 丨两直 %形防火繩圈 以塞住該環形空間。 20·如申請專利範圍第19項的方法 &、 匕括在%形防火, 20 σ 、内週邊表面上形成一曲度,使 ,使侍内週邊表面以」 向辰形防火纖維塾圈裝置的-方向朝外週邊表面彎 27A space between the fire shoulder and the hot surface layer is provided. Two straight% -shaped fire rope loops are used to plug the annular space. 20 · If method 19 of the scope of patent application &, daggers are fired in the shape of%, 20 σ, a curvature is formed on the inner peripheral surface, so that the inner peripheral surface is made of a "Chen-shaped" fireproof fiber loop device -Direction bent toward the outer peripheral surface 27
TW91134357A 2001-12-07 2002-11-26 Expansion gap protection structure for a gasifier TW546366B (en)

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Publication number Priority date Publication date Assignee Title
US2809104A (en) * 1955-07-22 1957-10-08 Texas Co Gasification of liquid fuels
US4491456A (en) * 1982-06-29 1985-01-01 Texaco Inc. Partial oxidation process
US4443230A (en) * 1983-05-31 1984-04-17 Texaco Inc. Partial oxidation process for slurries of solid fuel
US5484554A (en) * 1993-01-15 1996-01-16 Texaco Inc. Oxidant injection for improved controlled oxidation

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