TR200605865A2 - Doğal gaz ve lpg'nin direkt ayrışması ile hidrojen üretimi yöntemi - Google Patents

Doğal gaz ve lpg'nin direkt ayrışması ile hidrojen üretimi yöntemi

Info

Publication number
TR200605865A2
TR200605865A2 TR2006/05865A TR200605865A TR200605865A2 TR 200605865 A2 TR200605865 A2 TR 200605865A2 TR 2006/05865 A TR2006/05865 A TR 2006/05865A TR 200605865 A TR200605865 A TR 200605865A TR 200605865 A2 TR200605865 A2 TR 200605865A2
Authority
TR
Turkey
Prior art keywords
lpg
natural gas
hydrogen production
nickel
direct decomposition
Prior art date
Application number
TR2006/05865A
Other languages
English (en)
Inventor
Rafi̇g Ali̇bey Prof.Dr.
Guli̇yev Sadig
Beycan İbrahi̇moğlu Prof.Dr.
Original Assignee
Vestel Elektroni̇k Sanayi̇ Ve Ti̇caret A.Ş.
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Vestel Elektroni̇k Sanayi̇ Ve Ti̇caret A.Ş. filed Critical Vestel Elektroni̇k Sanayi̇ Ve Ti̇caret A.Ş.
Priority to TR2006/05865A priority Critical patent/TR200605865A2/tr
Priority to RU2009118631/04A priority patent/RU2446010C2/ru
Priority to EP07826782A priority patent/EP2076332A1/en
Priority to PCT/IB2007/054240 priority patent/WO2008047321A1/en
Publication of TR200605865A2 publication Critical patent/TR200605865A2/tr

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • C01B3/22—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds
    • C01B3/24—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons
    • C01B3/26—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by decomposition of gaseous or liquid organic compounds of hydrocarbons using catalysts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/755—Nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0205—Impregnation in several steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/02—Processes for making hydrogen or synthesis gas
    • C01B2203/0266—Processes for making hydrogen or synthesis gas containing a decomposition step
    • C01B2203/0277—Processes for making hydrogen or synthesis gas containing a decomposition step containing a catalytic decomposition step
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/10—Catalysts for performing the hydrogen forming reactions
    • C01B2203/1041—Composition of the catalyst
    • C01B2203/1047—Group VIII metal catalysts
    • C01B2203/1052—Nickel or cobalt catalysts
    • C01B2203/1058—Nickel catalysts
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B2203/00—Integrated processes for the production of hydrogen or synthesis gas
    • C01B2203/12—Feeding the process for making hydrogen or synthesis gas
    • C01B2203/1205—Composition of the feed
    • C01B2203/1211—Organic compounds or organic mixtures used in the process for making hydrogen or synthesis gas
    • C01B2203/1235—Hydrocarbons
    • C01B2203/1241—Natural gas or methane

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Inorganic Chemistry (AREA)
  • Catalysts (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Doğal gaz ve LPG' nin direkt ayrışması ile hidrojen üretimi yönteminde çok kademeli adsorplanma yolu ile hazırlanmış, gamma-alüminyum oksit üzerinde nikel-demir katalizörü kullanılmaktadır. Yöntemde kullanılan katalizörün hazırlanmasında nikel ve 10 demirin nitrat tuzlarının sulu çözeltileri gamma-alüminyum yüzeyine birlikte adsorplanmakta, katalizör yüzeyindeki nikel ve demirin ağırlık oranlan l: l ve toplam miktarları ağırlıkça %20-40 aralığında olmaktadır. Bu yöntemin sıcaklığı 550-650 °C aralığında olmaktadır.
TR2006/05865A 2006-10-19 2006-10-19 Doğal gaz ve lpg'nin direkt ayrışması ile hidrojen üretimi yöntemi TR200605865A2 (tr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
TR2006/05865A TR200605865A2 (tr) 2006-10-19 2006-10-19 Doğal gaz ve lpg'nin direkt ayrışması ile hidrojen üretimi yöntemi
RU2009118631/04A RU2446010C2 (ru) 2006-10-19 2007-10-18 Способ получения водорода прямым разложением природного газа и снг
EP07826782A EP2076332A1 (en) 2006-10-19 2007-10-18 Hydrogen production method by direct decomposition of natural gas and lpg
PCT/IB2007/054240 WO2008047321A1 (en) 2006-10-19 2007-10-18 Hydrogen production method by direct decomposition of natural gas and lpg

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TR2006/05865A TR200605865A2 (tr) 2006-10-19 2006-10-19 Doğal gaz ve lpg'nin direkt ayrışması ile hidrojen üretimi yöntemi

Publications (1)

Publication Number Publication Date
TR200605865A2 true TR200605865A2 (tr) 2008-05-21

Family

ID=39099850

Family Applications (1)

Application Number Title Priority Date Filing Date
TR2006/05865A TR200605865A2 (tr) 2006-10-19 2006-10-19 Doğal gaz ve lpg'nin direkt ayrışması ile hidrojen üretimi yöntemi

Country Status (4)

Country Link
EP (1) EP2076332A1 (tr)
RU (1) RU2446010C2 (tr)
TR (1) TR200605865A2 (tr)
WO (1) WO2008047321A1 (tr)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102010049957B4 (de) * 2010-10-04 2013-11-14 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Abgasreinigungsvorrichtung, Verfahren zur Abgasreinigung sowie Pyrolysereaktor
RU2526040C1 (ru) * 2013-06-20 2014-08-20 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Способ получения моторного топлива
RU2559878C1 (ru) * 2014-06-10 2015-08-20 Федеральное государственное бюджетное учреждение науки Институт химии твердого тела Уральского отделения Российской академии наук Никель-алюминиевая шпинель в качестве катализатора парциального окисления метана и способ ее получения
RU2651195C1 (ru) * 2017-03-10 2018-04-18 Федеральное государственное бюджетное образовательное учреждение высшего образования "Тюменский индустриальный университет" (ТИУ) Способ получения синтез-газа
US20210114003A1 (en) 2017-04-14 2021-04-22 King Abdullah University Of Science And Technology Treated iron ore catalysts for production of hydrogen and graphene
CN110721691B (zh) * 2019-11-12 2020-07-24 中南大学 一种cfan催化剂及其制备和在甲烷制氢中的应用
US11890596B2 (en) * 2021-09-07 2024-02-06 United Arab Emirates University Coking resistant NiFeAl catalyst for partial oxidation of methane to synthesis gas

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2704774B1 (fr) * 1993-05-06 1995-07-21 Inst Francais Du Petrole Procédé de préparation de catalyseurs applicables à la déshydrogénation.
RU2204434C2 (ru) * 2001-05-08 2003-05-20 Институт катализа им. Г.К. Борескова СО РАН Катализатор и способ получения смеси водорода и оксида углерода
US6875417B1 (en) * 2001-10-24 2005-04-05 University Of Kentucky Research Foundation Catalytic conversion of hydrocarbons to hydrogen and high-value carbon
EP1623957B1 (de) * 2005-02-10 2008-02-06 Electrovac AG Verfahren und Vorrichtung zur Herstellung von Wasserstoff

Also Published As

Publication number Publication date
EP2076332A1 (en) 2009-07-08
WO2008047321B1 (en) 2008-07-24
RU2009118631A (ru) 2010-11-27
RU2446010C2 (ru) 2012-03-27
WO2008047321A1 (en) 2008-04-24

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