SU516341A3 - Способ получени замещенных бензофенонов - Google Patents
Способ получени замещенных бензофеноновInfo
- Publication number
- SU516341A3 SU516341A3 SU1824103A SU1824103A SU516341A3 SU 516341 A3 SU516341 A3 SU 516341A3 SU 1824103 A SU1824103 A SU 1824103A SU 1824103 A SU1824103 A SU 1824103A SU 516341 A3 SU516341 A3 SU 516341A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- general formula
- compound
- methoxybenzophenone
- dimethyl
- reaction
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 6
- 239000012965 benzophenone Substances 0.000 title claims 2
- 150000008366 benzophenones Chemical class 0.000 title claims 2
- 150000001875 compounds Chemical class 0.000 claims description 15
- 239000003054 catalyst Substances 0.000 claims description 7
- 125000000217 alkyl group Chemical group 0.000 claims 3
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 claims 1
- 238000005727 Friedel-Crafts reaction Methods 0.000 claims 1
- 125000005843 halogen group Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 230000003993 interaction Effects 0.000 claims 1
- 238000002955 isolation Methods 0.000 claims 1
- 239000003960 organic solvent Substances 0.000 claims 1
- -1 2,2-dimethyl-4-methoxybenzophenone Chemical compound 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 8
- 229910052753 mercury Inorganic materials 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- QGJOPFRUJISHPQ-UHFFFAOYSA-N Carbon disulfide Chemical compound S=C=S QGJOPFRUJISHPQ-UHFFFAOYSA-N 0.000 description 6
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 6
- 239000011541 reaction mixture Substances 0.000 description 5
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 4
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 4
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZXHDKGCWOIPNKR-UHFFFAOYSA-N (4-methoxy-2,3-dimethylphenyl)-phenylmethanone Chemical compound CC1=C(C)C(OC)=CC=C1C(=O)C1=CC=CC=C1 ZXHDKGCWOIPNKR-UHFFFAOYSA-N 0.000 description 2
- KFJJYOKMAAQFHC-UHFFFAOYSA-N (4-methoxy-5,5-dimethylcyclohexa-1,3-dien-1-yl)-phenylmethanone Chemical compound C1C(C)(C)C(OC)=CC=C1C(=O)C1=CC=CC=C1 KFJJYOKMAAQFHC-UHFFFAOYSA-N 0.000 description 2
- 239000012043 crude product Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- PLPFIHGWTPPJEI-UHFFFAOYSA-N (3-butoxyphenyl)-phenylmethanone Chemical compound C(CCC)OC=1C=C(C(=O)C2=CC=CC=C2)C=CC=1 PLPFIHGWTPPJEI-UHFFFAOYSA-N 0.000 description 1
- KACYORGGZIGHRR-UHFFFAOYSA-N (4-methoxy-3,4-dimethylcyclohexa-1,5-dien-1-yl)-phenylmethanone Chemical compound CC1C=C(C(=O)C2=CC=CC=C2)C=CC1(OC)C KACYORGGZIGHRR-UHFFFAOYSA-N 0.000 description 1
- HTSGKJQDMSTCGS-UHFFFAOYSA-N 1,4-bis(4-chlorophenyl)-2-(4-methylphenyl)sulfonylbutane-1,4-dione Chemical compound C1=CC(C)=CC=C1S(=O)(=O)C(C(=O)C=1C=CC(Cl)=CC=1)CC(=O)C1=CC=C(Cl)C=C1 HTSGKJQDMSTCGS-UHFFFAOYSA-N 0.000 description 1
- IBSQPLPBRSHTTG-UHFFFAOYSA-N 1-chloro-2-methylbenzene Chemical compound CC1=CC=CC=C1Cl IBSQPLPBRSHTTG-UHFFFAOYSA-N 0.000 description 1
- DTFKRVXLBCAIOZ-UHFFFAOYSA-N 2-methylanisole Chemical compound COC1=CC=CC=C1C DTFKRVXLBCAIOZ-UHFFFAOYSA-N 0.000 description 1
- YHOYYHYBFSYOSQ-UHFFFAOYSA-N 3-methylbenzoyl chloride Chemical compound CC1=CC=CC(C(Cl)=O)=C1 YHOYYHYBFSYOSQ-UHFFFAOYSA-N 0.000 description 1
- AIPHHRAFQFBEFR-UHFFFAOYSA-N C(C)(C)C1(CC(C(=O)C2=CC=CC=C2)=CC=C1OC)C Chemical compound C(C)(C)C1(CC(C(=O)C2=CC=CC=C2)=CC=C1OC)C AIPHHRAFQFBEFR-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QYFZCTDKWGVUIO-UHFFFAOYSA-N [Cl].[Sn] Chemical compound [Cl].[Sn] QYFZCTDKWGVUIO-UHFFFAOYSA-N 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 150000008280 chlorinated hydrocarbons Chemical class 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- NLFBCYMMUAKCPC-KQQUZDAGSA-N ethyl (e)-3-[3-amino-2-cyano-1-[(e)-3-ethoxy-3-oxoprop-1-enyl]sulfanyl-3-oxoprop-1-enyl]sulfanylprop-2-enoate Chemical compound CCOC(=O)\C=C\SC(=C(C#N)C(N)=O)S\C=C\C(=O)OCC NLFBCYMMUAKCPC-KQQUZDAGSA-N 0.000 description 1
- 239000012442 inert solvent Substances 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000005648 plant growth regulator Substances 0.000 description 1
- 239000012429 reaction media Substances 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C49/00—Ketones; Ketenes; Dimeric ketenes; Ketonic chelates
- C07C49/76—Ketones containing a keto group bound to a six-membered aromatic ring
- C07C49/84—Ketones containing a keto group bound to a six-membered aromatic ring containing ether groups, groups, groups, or groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
- C07C45/45—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by condensation
- C07C45/46—Friedel-Crafts reactions
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP46064658A JPS515446B2 (enExample) | 1971-08-24 | 1971-08-24 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU516341A3 true SU516341A3 (ru) | 1976-05-30 |
Family
ID=13264524
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU1824103A SU516341A3 (ru) | 1971-08-24 | 1972-08-23 | Способ получени замещенных бензофенонов |
Country Status (14)
| Country | Link |
|---|---|
| US (1) | US3873304A (enExample) |
| JP (1) | JPS515446B2 (enExample) |
| BE (1) | BE787938A (enExample) |
| BR (1) | BR7205728D0 (enExample) |
| CA (1) | CA1025688A (enExample) |
| CH (1) | CH574706A5 (enExample) |
| DE (3) | DE2265535C3 (enExample) |
| FR (1) | FR2150492B1 (enExample) |
| GB (1) | GB1355926A (enExample) |
| IL (1) | IL40159A (enExample) |
| IT (1) | IT964243B (enExample) |
| NL (1) | NL7211551A (enExample) |
| PH (1) | PH10246A (enExample) |
| SU (1) | SU516341A3 (enExample) |
Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4102672A (en) * | 1973-10-19 | 1978-07-25 | Ajinomoto Co. Inc. | Herbicidal composition of amino acid higher alkyl ester type and method for controlling weeds |
| US3954875A (en) * | 1973-12-26 | 1976-05-04 | Rohm And Haas Company | Benzophenone herbicides |
| FR2292467A1 (fr) * | 1974-11-28 | 1976-06-25 | Roussel Uclaf | Nouveaux derives de la benzophenone, leur procede de preparation et leur application comme medicament |
| ES8306085A1 (es) * | 1981-07-08 | 1983-05-01 | Raychem Corp | "un procedimiento para la preparacion de cetonas aromaticas". |
| JPS60235369A (ja) * | 1984-05-08 | 1985-11-22 | Yuasa Battery Co Ltd | ナトリウム−硫黄電池 |
| GB9620202D0 (en) * | 1996-09-27 | 1996-11-13 | Rhone Poulenc Agriculture | New herbicides |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2671016A (en) * | 1951-10-23 | 1954-03-02 | Monsanto Chemicals | Herbicidal compositions |
| US3013079A (en) * | 1957-01-18 | 1961-12-12 | Donald E Pearson | Ring halogenation of aromatic carbonyl compounds |
| US3086988A (en) * | 1961-07-12 | 1963-04-23 | Dow Chemical Co | 2-hydroxy-4-(2-hydroxyalkoxy) benzophenones and their lower alkanoic acid esters |
| US3495970A (en) * | 1969-01-08 | 1970-02-17 | Hazzard John | Herbicidal composition and method |
-
0
- BE BE787938D patent/BE787938A/xx unknown
-
1971
- 1971-08-24 JP JP46064658A patent/JPS515446B2/ja not_active Expired
-
1972
- 1972-08-18 IL IL40159A patent/IL40159A/xx unknown
- 1972-08-21 US US282270A patent/US3873304A/en not_active Expired - Lifetime
- 1972-08-22 CH CH1243772A patent/CH574706A5/xx not_active IP Right Cessation
- 1972-08-22 GB GB3911072A patent/GB1355926A/en not_active Expired
- 1972-08-22 BR BR5728/72A patent/BR7205728D0/pt unknown
- 1972-08-23 SU SU1824103A patent/SU516341A3/ru active
- 1972-08-24 CA CA150,094A patent/CA1025688A/en not_active Expired
- 1972-08-24 DE DE2265535A patent/DE2265535C3/de not_active Expired
- 1972-08-24 IT IT28483/72A patent/IT964243B/it active
- 1972-08-24 NL NL7211551A patent/NL7211551A/xx not_active Application Discontinuation
- 1972-08-24 PH PH13832A patent/PH10246A/en unknown
- 1972-08-24 DE DE2241560A patent/DE2241560C3/de not_active Expired
- 1972-08-24 DE DE2265418A patent/DE2265418C2/de not_active Expired
- 1972-08-24 FR FR7230173A patent/FR2150492B1/fr not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| JPS4828627A (enExample) | 1973-04-16 |
| PH10246A (en) | 1976-10-14 |
| BR7205728D0 (pt) | 1974-10-22 |
| IL40159A (en) | 1975-11-25 |
| DE2241560C3 (de) | 1981-04-30 |
| US3873304A (en) | 1975-03-25 |
| DE2265418B1 (de) | 1979-03-08 |
| DE2241560A1 (de) | 1973-03-08 |
| BE787938A (fr) | 1973-02-26 |
| DE2265535C3 (de) | 1982-04-29 |
| CA1025688A (en) | 1978-02-07 |
| IL40159A0 (en) | 1972-10-29 |
| DE2241560B2 (de) | 1980-09-11 |
| FR2150492A1 (enExample) | 1973-04-06 |
| JPS515446B2 (enExample) | 1976-02-20 |
| NL7211551A (enExample) | 1973-02-27 |
| DE2265418C2 (de) | 1979-10-25 |
| GB1355926A (en) | 1974-06-12 |
| DE2265535B2 (de) | 1981-07-16 |
| CH574706A5 (enExample) | 1976-04-30 |
| FR2150492B1 (enExample) | 1975-01-03 |
| IT964243B (it) | 1974-01-21 |
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