SU46918A1 - Method for producing phenylacetaldehyde - Google Patents
Method for producing phenylacetaldehydeInfo
- Publication number
- SU46918A1 SU46918A1 SU181453A SU181453A SU46918A1 SU 46918 A1 SU46918 A1 SU 46918A1 SU 181453 A SU181453 A SU 181453A SU 181453 A SU181453 A SU 181453A SU 46918 A1 SU46918 A1 SU 46918A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- phenylacetaldehyde
- producing
- phenylglyoxal
- poured
- producing phenylacetaldehyde
- Prior art date
Links
- DTUQWGWMVIHBKE-UHFFFAOYSA-N Phenylacetaldehyde Chemical compound O=CCC1=CC=CC=C1 DTUQWGWMVIHBKE-UHFFFAOYSA-N 0.000 title description 6
- 238000004519 manufacturing process Methods 0.000 title description 2
- 229940100595 phenylacetaldehyde Drugs 0.000 title description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- OJUGVDODNPJEEC-UHFFFAOYSA-N α-oxobenzeneacetaldehyde Chemical compound O=CC(=O)C1=CC=CC=C1 OJUGVDODNPJEEC-UHFFFAOYSA-N 0.000 description 3
- VKYKSIONXSXAKP-UHFFFAOYSA-N Hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 description 2
- WRMNZCZEMHIOCP-UHFFFAOYSA-N Phenethyl alcohol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 2
- 235000010299 hexamethylene tetramine Nutrition 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- UUWJBXKHMMQDED-UHFFFAOYSA-N 1-(3-chlorophenyl)ethanone Chemical compound CC(=O)C1=CC=CC(Cl)=C1 UUWJBXKHMMQDED-UHFFFAOYSA-N 0.000 description 1
- 210000003127 Knee Anatomy 0.000 description 1
- 229960004011 Methenamine Drugs 0.000 description 1
- 229940067107 Phenylethyl Alcohol Drugs 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L cacl2 Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 239000012259 ether extract Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000004312 hexamethylene tetramine Substances 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
Description
Пример. В круглодонной нолбе раствор ют 15,4 Z м-хлорацетофенона в 60 c« 70Vo-ro винного спирта, добавл ют 15 г уротропина и нагревают смесь с обратным холодильником на вод ной бане 5-6 часов. Продукт реакции выливают в воду, и выделившийс масл нистый СЛОЙ экстрагируют эфиромExample. 15.4 Z of m-chloroacetophenone is dissolved in 60-c "70 Vo-ro wine alcohol in a round-bottomed nolba, 15 g of hexamine is added and the mixture is heated under reflux in a water bath for 5-6 hours. The reaction product is poured into water, and the oily LOOKY separated out is extracted with ether.
ИЛИ бензолом. Эфирный экстракт, по отгонке эфира, разгон ют в вакууме. Выход фенилглиоксал с точкой кипени 108-110°-10 г, что составл ет 76Vo от теории.OR benzene. The ether extract, after distilling off the ether, is distilled in vacuo. The yield of phenylglyoxal with a boiling point of 108-110 ° -10 g, which is 76Vo from theory.
Полученные 10 г фенилглиоксала заливают в С1-образный сосуд, одно колено которого заполнено никелевым каталиводорода , назатором , пропускают ток The resulting 10 g of phenylglyoxal is poured into a C1-shaped vessel, one knee of which is filled with a nickel cataligorod, nasator, a current is passed
бане до 140 грСЕза сосуд в масл ной в течение 4 час., после to a bath up to 140 ° C, a vessel in oil for 4 hours, after
чего продуктwhat's the product
из сосуда и восстановлени выливаютfrom the vessel and the recovery is poured
отгон ют с водным паром; выход продукта перегонки с вод ным паром 7 г, что составл ет УТ/п от теории.distilled with water vapor; the yield of the distillation product with a steam of 7 g, which is UT / n from theory.
Or образовавшегос в небольшом количестве фенилэтилового спирта освобождаютс , обрабатыва фенилацетальдегид безводным хлористым кальцием.Or, a small amount of phenylethyl alcohol is released by treating the phenylacetaldehyde with anhydrous calcium chloride.
Предмет изобретенилThe subject invented
Способ получени фенилацетзльдегида из СО-хлорацетофенона, отличаюиииТс тем, что tfj-хлорацетофенок нагреванием с уротропином превращают в фенилглмоксаль с последующим восстановлением фенилглиоксал действи-гм водорода в присутствии никелевого хатализатора .The method for producing phenylacetic aldehyde from CO-chloroacetophenone differs in that tfj-chloroacetophenic is converted into phenylglymoxal by heating with urotropin followed by reduction of phenylglyoxal action-gm hydrogen in the presence of a nickel catalyst.
Related Child Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU752102136A Addition SU678212A2 (en) | 1975-02-04 | 1975-02-04 | Dog coupling |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU46918A1 true SU46918A1 (en) | 1936-05-31 |
Family
ID=
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