SU407506A1 - Method of purifying indium from admixtures - Google Patents

Method of purifying indium from admixtures

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Publication number
SU407506A1
SU407506A1 SU7101648443A SU1648443A SU407506A1 SU 407506 A1 SU407506 A1 SU 407506A1 SU 7101648443 A SU7101648443 A SU 7101648443A SU 1648443 A SU1648443 A SU 1648443A SU 407506 A1 SU407506 A1 SU 407506A1
Authority
SU
USSR - Soviet Union
Prior art keywords
indium
electrolyte
impurities
admixtures
coal
Prior art date
Application number
SU7101648443A
Other languages
Russian (ru)
Inventor
Л.И. Юрченко
В.Е. Дьяков
И.М. Селиванов
А.Е. Семенов
М.А. Яковлев
Original Assignee
Новосибирский оловянный комбинат
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Новосибирский оловянный комбинат filed Critical Новосибирский оловянный комбинат
Priority to SU7101648443A priority Critical patent/SU407506A1/en
Application granted granted Critical
Publication of SU407506A1 publication Critical patent/SU407506A1/en

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Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

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  • Electrolytic Production Of Metals (AREA)

Description

Изобретение относитс  к металлургии рассе нных металлов.The invention relates to the metallurgy of dispersed metals.

Известен способ очистки инди  от примесей, включаклций анодное растворение инди  марки ИН-1 в электролите , последующую очистку электролита путем пропускани  его через слой активированного угл , а затем через колонну с анионообменной смолой с последующим выделением инди  электролизом .There is a known method of cleaning indium from impurities, including inclusions of anodic dissolution of indie mark IN-1 in the electrolyte, subsequent purification of the electrolyte by passing it through a layer of activated carbon, and then through a column with an anion-exchange resin, followed by separation by indie electrolysis.

Недостаток известного способа заключаетс  в , что анйонообменна  смола быстро насьвдаетс  примес ми, что требует .частой регенерации. A disadvantage of the known method is that the anion exchange resin quickly builds on impurities, which requires frequent regeneration.

С целью увеличени  продолжительности работы сорбента по предлагаемс н способу электролит до и после очистьс  на угле пропускают через слой индиевой губки,In order to increase the duration of the sorbent operation, according to the proposed method, the electrolyte is passed through a layer of indium sponge before and after cleaning with coal,

При этом, примеси более электроположительные , чем индий, содержащиес  в электролите, вьщел ютс  на иидиевой губке, а электроотрицательные на активирование угле.At the same time, the impurities are more electropositive than indium contained in the electrolyte, are allocated to the ion sponge, and the electronegative for activated carbon.

Пример. Индий марки ИЯ-1 с содержанием примесей, вес.%1 Меди 2iq- l Ртути 3,6vlQExample. Indium of the brand IL-1 with the content of impurities, wt.% 1 Copper 2iq- l Mercury 3,6vlQ

Никел  210. Железа 5-101 Nickel 210. Iron 5-101

Олова 3 10 I Tin 3 10 I

Гллли  2-10 Цинка 2-10 Свинца 3-10 1-10раствор ют анодио в электролите, содержащем 70 г/л ионов хлора при рН в 1,5 .Gllie 2-10 Zinc 2-10 Lead 3-10 1-10 dissolve anodio in an electrolyte containing 70 g / l of chlorine ions at a pH of 1.5.

Полученный электролит пропускают через индиевую губку, активированный уголь и снова индиевую губку. При этом Вначале на индиевой губке выдел ютс  примеси меди, никел , олова, свинца; на угле - примеси цинка, кадми , галли , кото{нле не могут быть очищены с помощью индиевой губки. Повторное пропускание электролита через индиевую губку позвол ет отделить примеси меди и никел , которые перешли в раствор из угл .The electrolyte obtained is passed through an indium sponge, activated carbon and again an indium sponge. First, impurities of copper, nickel, tin, lead are released on the indium sponge; on the coal, there are impurities of zinc, cadmium, and gallium, which cannot be cleaned with an indium sponge. Repeated passage of the electrolyte through the indium sponge allows the separation of copper and nickel impurities that have passed into the solution from the coal.

В даннс способе уголь сорбирует только те примеси, которые не осаждаютс  на индиевой губке.In this method, coal absorbs only those impurities that are not deposited on the indium sponge.

Въщеленный из этого электролита металл соответствует индию марки ИН-6 и имеет следуххцее содержание примесей вес.% IThe metal injected from this electrolyte corresponds to indium grade IN-6 and has the following impurity content in wt.% I

1. ЮГ1. SOUTH

Галли Gully

Нед  , Ned

Германи  Никел  Germani Nickel

Цинка :Олова Свиица 2 Zinc: Tin Lead 2

РтутиMercury

Железа Кадми  1Iron Cadmium 1

.а4075064.а4075064

Claims (1)

Формула изобретени пусканием его через слой активцрованСпособ очистки инди  от примесейтельнрсти работы сорбента, электролитThe claims of the invention by passing it through a layer of active. Method of cleaning indium from impurities of the sorbent, electrolyte АНСАНЫМ растворением в электролите сдо и псхгле очистки на угле пропускаютANSANY dissolving in the electrolyte sdo and psggle cleaning on coal is passed лослбдупцай очисткой электролита про через слой индиевой губки.Cleaning the electrolyte through a layer of indium sponge. ного угл , отличающийс  тем, что, с целью увеличени  продолжиcoal, characterized in that, in order to increase
SU7101648443A 1971-04-12 1971-04-12 Method of purifying indium from admixtures SU407506A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU7101648443A SU407506A1 (en) 1971-04-12 1971-04-12 Method of purifying indium from admixtures

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU7101648443A SU407506A1 (en) 1971-04-12 1971-04-12 Method of purifying indium from admixtures

Publications (1)

Publication Number Publication Date
SU407506A1 true SU407506A1 (en) 1978-07-05

Family

ID=20472900

Family Applications (1)

Application Number Title Priority Date Filing Date
SU7101648443A SU407506A1 (en) 1971-04-12 1971-04-12 Method of purifying indium from admixtures

Country Status (1)

Country Link
SU (1) SU407506A1 (en)

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