SU367132A1 - METHOD OF OBTAINING LUBRICATING COOLING - Google Patents
METHOD OF OBTAINING LUBRICATING COOLINGInfo
- Publication number
- SU367132A1 SU367132A1 SU1600382A SU1600382A SU367132A1 SU 367132 A1 SU367132 A1 SU 367132A1 SU 1600382 A SU1600382 A SU 1600382A SU 1600382 A SU1600382 A SU 1600382A SU 367132 A1 SU367132 A1 SU 367132A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- split
- triethanolamine
- coolant
- tar
- stock
- Prior art date
Links
Classifications
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
- C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Landscapes
- Lubricants (AREA)
Description
1one
Изобретение относитс к способу получени смазочно-охлаждающих жидкостей на основе воды, расщепленного соанстока и триэтаноламина .This invention relates to a process for the preparation of lubricating fluids based on water, split co-anesthetics and triethanolamine.
Эти жидкости готов т, смешива компоненты при нагреваиии с добавками триэтаноламина (ТЭА).These fluids are prepared by mixing the components during heating with triethanolamine (TEA) additives.
БОЛЬШИМ недостатком iвoдныx эмульсий расш ,епленных соапстоков с ТЭА вл етс чрезвычайно высока вснениваемость в процессе приготовлени и особенно в процессе работы с использованием их в услови х замкнутых смазочно-охлаждающих систем прокатных цехов . Это - основное преп тствие использовани таких эмульсий при гор чей и холодной прокатке металлов и сплавов. Рекомендуемые пеногасители, такие как полиорганосилоксаиовые жидкости (например, ПМС-200А) и другие - неэффективны или малоэффективны по отношению к водным эмульси м расщенленных соапстоков с ТЭА. Добавка ПМС-200а, наоборот, стабилизирует нему в этой эмульсии.A GREAT disadvantage of advanced emulsions of advanced, heated soapstocks with TEA is an extremely high degree of awareness in the preparation process and especially in the process of operation using them in the conditions of closed lubricant cooling systems of rolling mills. This is a major obstacle to the use of such emulsions in the hot and cold rolling of metals and alloys. Recommended defoamers, such as polyorganosiloxaic liquids (for example, PMS-200A) and others, are ineffective or ineffective with respect to aqueous emulsions of diluted soap fluids with TEA. Additive PMS-200a, on the contrary, stabilizes it in this emulsion.
Цель изобретени - разработка способа получени СОЖ на основе расщепленного соанстока с добавкой триэтаноламина - эффективного дешевого пеногасител смазочноохлаждающей жидкости дл прокатки металлов и сплавов со слабой пенообразующей способностью .The purpose of the invention is to develop a method for the production of coolant based on split solenstock with the addition of triethanolamine, an effective cheap defoaming agent for a cooling fluid for rolling metals and alloys with a weak foaming ability.
Дл этого предложено добавл ть к навеске расщепленного соапсгока при перемешиванииFor this, it is proposed to add to the sample of the split soap with stirring
глицериновый гудрон, желательно, в количестве 8-12% от веса соанстока, а затем - триэтаноламин из расчета 60%-ной нейтрализации свободных жирных кислот соапстока, кислотное число которого определ ют предварительно . Смесь периодически перемешивают в течение 7-10 мин, потом добавл ют к ней пебольшими порци ми при интенсивном перемешиваиии нагретую до 45-55°С воду.glycerin tar, preferably in the amount of 8-12% by weight of soapstock, and then triethanolamine at the rate of 60% neutralization of free stock fatty acids, the acid number of which is determined beforehand. The mixture is periodically stirred for 7-10 minutes, then added to it in small portions with vigorous stirring and water heated to 45-55 ° C.
Способность к пенообразованию полученной таким способом смазочно-охлаждающей жидкости (СОЖ) в 20-25 раз ииже (в расчете на наибольший достижимый объем пены), чем у СОЖ на основе расщепленных соапстоков и триэтаноламипа без добавки глицеринового гудрона.The ability to foaming of the thus obtained coolant (coolant) is 20–25 times less (calculated on the largest attainable volume of foam) than coolant based on split soap stock and triethanolamine without the addition of glycerol tar.
Введение глицеринового гудрона в состав эмульсии не снижает ее смазочно-охлаждающих свойств, способствует стабилизации.The introduction of glycerol tar in the emulsion does not reduce its lubricating and cooling properties, contributes to stabilization.
Низка вспениваемость получепной по предлагаемому способу СОЖ позвол ет примен ть ее при прокатке металлов и сплавов.The low foaming capacity of the preformed coolant according to the proposed method allows it to be used in rolling metals and alloys.
Глицериновый гудрон как пепогаситель наиболее эффективен в том случае, если его добавл ть к соапстоку по предлагаемому способу , т. е. перед введением триэтаноламина. Введение глицеринового гудрона в уже готовую водную эмульсию менее эффективно.Glycerin tar as a pepogasitel is most effective if it is added to soap stock by the proposed method, i.e. before the introduction of triethanolamine. The introduction of glycerol tar into an already prepared aqueous emulsion is less effective.
Глицериновый гудрон - отход глицерииового производства масложировой промышленности , сбрасываемый в сточные воды или на шламовые пол .Glycerol tar is a waste of the glyceric production of the oil and fat industry, discharged into wastewater or on sludge floors.
Расщепленный соапсток-1продукт, получаемый после обработки сильной кислотой остатка от рафинировани масел.Splintered soap stock 1 product obtained after treatment with a strong acid residue from refining oils.
В таблице представлены результаты испытаний предлагаемого способа. Как видно, инедение глицерино-вого гудро-на от 0,1 до 1% рез«о снижает кратность образоваии тшы по сравнению с лрисадкой ПЛ1С-2(ЮА.The table presents the test results of the proposed method. As can be seen, the injection of glycerol gowd-on from 0.1 to 1% of the res “reduces the multiplicity of the formation of Tshy compared with the risk of PL1C-2 (SA.
Предмет изобретени Subject invention
Claims (2)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU1600382A SU367132A1 (en) | 1970-12-15 | 1970-12-15 | METHOD OF OBTAINING LUBRICATING COOLING |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
SU1600382A SU367132A1 (en) | 1970-12-15 | 1970-12-15 | METHOD OF OBTAINING LUBRICATING COOLING |
Publications (1)
Publication Number | Publication Date |
---|---|
SU367132A1 true SU367132A1 (en) | 1973-01-23 |
Family
ID=20461526
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU1600382A SU367132A1 (en) | 1970-12-15 | 1970-12-15 | METHOD OF OBTAINING LUBRICATING COOLING |
Country Status (1)
Country | Link |
---|---|
SU (1) | SU367132A1 (en) |
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1970
- 1970-12-15 SU SU1600382A patent/SU367132A1/en active
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