SU1791433A1 - Glaze - Google Patents

Glaze Download PDF

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Publication number
SU1791433A1
SU1791433A1 SU914937027A SU4937027A SU1791433A1 SU 1791433 A1 SU1791433 A1 SU 1791433A1 SU 914937027 A SU914937027 A SU 914937027A SU 4937027 A SU4937027 A SU 4937027A SU 1791433 A1 SU1791433 A1 SU 1791433A1
Authority
SU
USSR - Soviet Union
Prior art keywords
glaze
cao
feo
mno
ai2o3
Prior art date
Application number
SU914937027A
Other languages
Russian (ru)
Inventor
Natalya I Mamchur
Tatyana N Solnyshkina
Original Assignee
Gnii Stroitelnoj Keramiki
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Gnii Stroitelnoj Keramiki filed Critical Gnii Stroitelnoj Keramiki
Priority to SU914937027A priority Critical patent/SU1791433A1/en
Application granted granted Critical
Publication of SU1791433A1 publication Critical patent/SU1791433A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
    • C03C8/04—Frit compositions, i.e. in a powdered or comminuted form containing zinc

Description

Изобретение относится к производству строительных материалов и может быть использовано при изготовлении керамических глазурованных плиток для внутренней облицовки стен, обжигаемых на поточно-конвейерных линиях.The invention relates to the production of building materials and can be used in the manufacture of ceramic glazed tiles for internal wall cladding, fired on production and conveyor lines.

Известна нефриттованная глазурь, включающая следующие компоненты. мас.%: SiO2 35 - 45; А120з 9 - 15; В2Оз 6 11; СаО 19-28; МдО 0,1-2; ΖιΟ22-5: К2О ; 0,1 - 3; ΖηΟ 0,1 - 6; Fe2O3 1.0 - 2:9. ~ 'Jade glaze is known comprising the following components. wt.%: SiO 2 35 - 45; A1 20 0 9 - 15; In 2 Oz 6 11; CaO 19-28; MdO 0.1-2; ΖιΟ 2 2-5: K 2 O; 0.1 to 3; ΖηΟ 0.1 - 6; Fe 2 O 3 1.0 - 2: 9. ~ '

Наиболее близкой по технической сущности к изобретению является глазурь, включающая следующие компоненты, мас.%: SIO242.05 - 46,16: AI2O37.85- 15,25; БегОз 1.10 - 1,15; FeO 0,48 - 0.64; СаО‘20.20·-21,81; МдО 0,99- 1,20; ΖηΟ2.76-7.96; К20 1.08 -1.28: Na2O 2,11- 5,33; В20з 8,64 - 9,57.Closest to the technical nature of the invention is the glaze, comprising the following components, wt.%: SIO 2 42.05 - 46.16: AI 2 O 3 7.85-15.25; Running 1.10 - 1.15; FeO 0.48-0.64; CaO'20.20 · -21.81; MdO 0.99-1.20; ΖηΟ2.76-7.96; K 2 0 1.08 -1.28: Na 2 O 2.11-5.33; 2 0z 8.64 - 9.57.

Недостатком такого состава глазури является повышенный температурный коэффициент линейного расширения.The disadvantage of this composition of the glaze is the increased temperature coefficient of linear expansion.

Целью изобретения является снижение температурного коэффициента линейного расширения.The aim of the invention is to reduce the temperature coefficient of linear expansion.

Поставленная цель достигается тем, что глазурь, включающая SiO2, Al2O3. Fe2O3, FeO, СаО, MgO, 2nO, Na20, K2O, ВгОЗ, дополнительно содержат ТЮ3 и МпО при следующем соотношении компонентов, мас.%:This goal is achieved by the fact that the glaze, including SiO 2 , Al 2 O 3 . Fe 2 O 3 , FeO, CaO, MgO, 2nO, Na 2 0, K 2 O, BrOZ, additionally contain TiO 3 and MnO in the following ratio of components, wt.%:

SiO2 AI2O3 Fe2O3 FeO СаО MgO МпО ΖηΟ ТЮ2 Κ2Ο Na2O Β2Ο3 SiO 2 AI 2 O 3 Fe 2 O 3 FeO CaO MgO MnO ΖηΟ TU 2 Κ 2 Ο Na 2 O Β 2 Ο 3

42.86 - 45,642.86 - 45.6

8,22 - 12,08.22 - 12.0

1.92- 2,481.92- 2.48

1,29 - 2,141.29 - 2.14

20.76 - 23,51 2,79-3,5420.76 - 23.51 2.79-3.54

0,07 - 0,110.07 - 0.11

0.55-4,410.55-4.41

0,18-0,280.18-0.28

0,21 -0,230.21 -0.23

3.93- 4,37 8,06-9,253.93- 4.37 8.06-9.25

Использование изобретения позволит получить экономический эффект в размере 600 тыс. руб. на производительность 1 млн. м2 плиток в год.Using the invention will allow to obtain an economic effect in the amount of 600 thousand rubles. at a productivity of 1 million m 2 tiles per year.

Claims (1)

5. Формула изобретения5. The claims Глазурь, включащая SIO2, AI2O3. РегОз. FeO, СаО. MgO, ZnO, №гО, К2О, В2О3. о т л ич а ю щ а я с я тем, что, с целью снижения температурного коэффициента линейного 10 расширения, она дополнительно содержит ТЮг и МпО при следующем соотношении компонентов, мас.%:Glaze, including SIO2, AI2O3. Reg. FeO, CaO. MgO, ZnO, No. gO, K2O, B2O3. It is due to the fact that, in order to reduce the temperature coefficient of linear expansion 10, it additionally contains Tyr and MnO in the following ratio of components, wt.%: Для получения указанной глазури используют следующие сырьевые материалы. мас.%:To obtain the specified glaze using the following raw materials. wt.%: Датолитовый концентрат44-51Datolite concentrate 44-51 Гидроокись алюминия4- 8Aluminum hydroxide 4-8 Окись цинка0,5-4Zinc Oxide 0.5-4 Каолин4-6Kaolin 4-6 Горнблендит 12 - 20Gornblendit 12 - 20 Стеклобой 2124.Cullet 2124. Глазурь получают путем совместного помола всех компонентов в шаровых мельницах до остатка на сите № 0063 не менее 0.2%. Плотность глазури при глазуровании плиток методом полива 1.67 - 1,70 г/см3. 15Glaze is obtained by joint grinding of all components in ball mills to a residue on sieve No. 0063 of at least 0.2%. The density of the glaze when glazing tiles by irrigation 1.67 - 1.70 g / cm 3 . fifteen Плитки обжигают на поточно-конвейерных линиях при максимальной температуре 980 -1000°С, продолжительность обжига 25 - 30 мин. Покрытие имеет шелковистую матовую поверхность горчичного цвета. 20The tiles are fired on production and conveyor lines at a maximum temperature of 980 -1000 ° C, the firing time is 25-30 minutes. The coating has a silky matte surface of mustard color. 20 Изобретение поясняется следующими примерами. :The invention is illustrated by the following examples. : В табл. 1 представлены составы предлагаемой глазури. \ ·In the table. 1 presents the compositions of the proposed glaze. \ В табл. 2 даны свойства приведенных 25 составов глазурей.In the table. 2 gives the properties of the given 25 compositions of glazes. SIO2 42.86-45.6: AI2O3 8,22-12,0;SIO 2 42.86-45.6: AI2O3 8.22-12.0; РегОз 1,92- 2.48;RegOz 1.92 - 2.48; FeO 1,29-2,14;FeO 1.29-2.14; СаО 20,76-23,51;CaO 20.76-23.51; MgO 2,79 - 3,54;MgO 2.79 - 3.54; ZnO 0,55-4,41;ZnO 0.55-4.41; МагО 3.93 - 4.37;MagO 3.93 - 4.37; КгО 0,21 - 0,23:KgO 0.21 - 0.23: В2О3 9.06- 9,25: ТЮг 0,18- 0,28;B2O3 9.06- 9.25: THB 0.18-0.28; МпО 0,07-0,11.MnO 0.07-0.11. Т а б л иц а1Table 1 Компоненты Components Состав | Composition | глазури glaze Предлагаемый Proposed Известный Famous 1 1 2 2 3 3 SIO2 SIO2 42,86 42.86 45,6 45.6 45,33 45.33 46,16 46.16 AI2O3 AI2O3 12.0 12.0 8,24 8.24 9,90 9.90 7,85 7.85 РегОз RegOz 2,22 2.22 2,48 2.48 1,92 1.92 1.10 1.10 FeO FeO 1,92 1.92 2,14 2.14 1,29 1.29 0.48 0.48 СаО CaO 20,76 20.76 23,51 23.51 22,54 22.54 20,2 20,2 МдО MDO 3,27 3.27 3,54 3.54 2,79 2.79 1.20 1.20 МпО MnO 0,10 0.10 0,11 0.11 0,07 0,07 ZnO Zno 4,41 4.41 0,55 0.55 2,20 2.20 7,96 7.96 ТЮг Tyug 0,26 0.26 0,28 0.28 0.18 0.18 К2ОK 2 O 0,21 0.21 0,22 0.22 0,23 0.23 1,08 1,08 ИагО Iago 3,93 3.93 4,08 4.08 4,37 4.37 5,33 5.33 ВаОз Vaoz 8,06 8.06 9,25 9.25 9.18 9.18 8.64 8.64
5 1791433 6 \ Таблиц а 25 1791433 6 \ Tables a 2 Показатели свойств Property metrics Состав Composition Известный Famous Предлагаемые Proposed 1 1 2 2 3 3 Коэффициент отражения, характеризующий матовость покрытия, % The reflection coefficient characterizing the dullness of the coating,% 25-27 25-27 20-24 20-24 22-25 22-25 20-28 20-28 Плавкость по Fusibility данным высокотемпературного микроскопа,°C Т ι- начало раз- according to a high-temperature microscope, ° C T ι- the beginning of 917 917 923 923 925 925 924 924 мягчения глазури Тг- начало плавления глазури softening the glaze Tg - the beginning of the melting of the glaze 950 950 980 980 960 960 . 970 . 970 + Тз-начало течения глазури + Tz-beginning of the flow of glaze 1000 1000 1020 1020 1030 1030 1020 1020 Продолжительность обжига, мин Duration of firing, min 25-30 25-30 25-30 25-30 25-30 25-30 25-30 25-30 Температурный коэффи цие нт л инейного расширения а х 106 град* в интервале температур 20-400°СTemperature coefficient of linear expansion a x 10 6 deg * in the temperature range 20-400 ° С 5.5 5.5 5,6 5,6 5,8 5.8 6,15 6.15 Морозостой- Frost-resistant >50 > 50 >50 > 50 >50 > 50 >50 > 50
SU914937027A 1991-04-11 1991-04-11 Glaze SU1791433A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU914937027A SU1791433A1 (en) 1991-04-11 1991-04-11 Glaze

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU914937027A SU1791433A1 (en) 1991-04-11 1991-04-11 Glaze

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Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2010126581A1 (en) * 2009-05-01 2010-11-04 Guardian Industries Corp. Vacuum insulating glass unit including infrared meltable glass frit, and/or method of making the same
US8500933B2 (en) 2007-12-14 2013-08-06 Guardian Industries Corp. Localized heating of edge seals for a vacuum insulating glass unit, and/or unitized oven for accomplishing the same
US8506738B2 (en) 2007-12-17 2013-08-13 Guardian Industries Corp. Localized heating via an infrared heat source array of edge seals for a vacuum insulating glass unit, and/or unitized oven with infrared heat source array for accomplishing the same
US8733128B2 (en) 2011-02-22 2014-05-27 Guardian Industries Corp. Materials and/or method of making vacuum insulating glass units including the same
US8802203B2 (en) 2011-02-22 2014-08-12 Guardian Industries Corp. Vanadium-based frit materials, and/or methods of making the same
US9290408B2 (en) 2011-02-22 2016-03-22 Guardian Industries Corp. Vanadium-based frit materials, and/or methods of making the same
US9309146B2 (en) 2011-02-22 2016-04-12 Guardian Industries Corp. Vanadium-based frit materials, binders, and/or solvents and methods of making the same
US9359247B2 (en) 2011-02-22 2016-06-07 Guardian Industries Corp. Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US9458052B2 (en) 2011-02-22 2016-10-04 Guardian Industries Corp. Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US9822580B2 (en) 2011-02-22 2017-11-21 Guardian Glass, LLC Localized heating techniques incorporating tunable infrared element(s) for vacuum insulating glass units, and/or apparatuses for same
US10421684B2 (en) 2014-02-04 2019-09-24 Guardian Glass, LLC Frits for use in vacuum insulating glass (VIG) units, and/or associated methods
US10465433B2 (en) 2014-02-04 2019-11-05 Guardian Glass, Llc. Vacuum insulating glass (VIG) unit with lead-free dual-frit seals and/or methods of making the same

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8500933B2 (en) 2007-12-14 2013-08-06 Guardian Industries Corp. Localized heating of edge seals for a vacuum insulating glass unit, and/or unitized oven for accomplishing the same
US8506738B2 (en) 2007-12-17 2013-08-13 Guardian Industries Corp. Localized heating via an infrared heat source array of edge seals for a vacuum insulating glass unit, and/or unitized oven with infrared heat source array for accomplishing the same
US10717668B2 (en) 2007-12-17 2020-07-21 Guardian Glass, Llc. Localized heating via an infrared heat source array of edge seals for a vacuum insulating glass unit, and/or unitized oven with infrared heat source array for accomplishing the same
WO2010126581A1 (en) * 2009-05-01 2010-11-04 Guardian Industries Corp. Vacuum insulating glass unit including infrared meltable glass frit, and/or method of making the same
US8227055B2 (en) 2009-05-01 2012-07-24 Guardian Industries Corp. Vacuum insulating glass unit including infrared meltable glass frit, and/or method of making the same
US8590343B2 (en) 2009-05-01 2013-11-26 Guardian Industries Corp. Vacuum insulating glass unit including infrared meltable glass frit, and/or method of making the same
US8763427B2 (en) 2009-05-01 2014-07-01 Guardian Industries Corp. Vacuum insulating glass unit including infrared meltable glass frit, and/or method of making the same
US9776910B2 (en) 2011-02-22 2017-10-03 Guardian Glass, LLC Vanadium-based frit materials, and/or methods of making the same
US10125045B2 (en) 2011-02-22 2018-11-13 Guardian Glass, LLC Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US9309146B2 (en) 2011-02-22 2016-04-12 Guardian Industries Corp. Vanadium-based frit materials, binders, and/or solvents and methods of making the same
US9359247B2 (en) 2011-02-22 2016-06-07 Guardian Industries Corp. Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US9458052B2 (en) 2011-02-22 2016-10-04 Guardian Industries Corp. Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US8802203B2 (en) 2011-02-22 2014-08-12 Guardian Industries Corp. Vanadium-based frit materials, and/or methods of making the same
US9822580B2 (en) 2011-02-22 2017-11-21 Guardian Glass, LLC Localized heating techniques incorporating tunable infrared element(s) for vacuum insulating glass units, and/or apparatuses for same
US10087676B2 (en) 2011-02-22 2018-10-02 Guardian Glass, LLC Vanadium-based frit materials, and/or methods of making the same
US10107028B2 (en) 2011-02-22 2018-10-23 Guardian Glass, LLC Method of making vacuum insulated glass (VIG) window unit
US9290408B2 (en) 2011-02-22 2016-03-22 Guardian Industries Corp. Vanadium-based frit materials, and/or methods of making the same
US10196299B2 (en) 2011-02-22 2019-02-05 Guardian Glass, LLC Vanadium-based frit materials, and/or methods of making the same
US10329187B2 (en) 2011-02-22 2019-06-25 Guardian Glass, LLC Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US11028009B2 (en) 2011-02-22 2021-06-08 Guardian Glass, LLC Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US11014847B2 (en) 2011-02-22 2021-05-25 Guardian Glass, LLC Vanadium-based frit materials, and/or methods of making the same
US8733128B2 (en) 2011-02-22 2014-05-27 Guardian Industries Corp. Materials and/or method of making vacuum insulating glass units including the same
US10752535B2 (en) 2011-02-22 2020-08-25 Guardian Glass, LLC Coefficient of thermal expansion filler for vanadium-based frit materials and/or methods of making and/or using the same
US10858880B2 (en) 2011-02-22 2020-12-08 Guardian Glass, LLC Vanadium-based frit materials, binders, and/or solvents and/or methods of making the same
US10465433B2 (en) 2014-02-04 2019-11-05 Guardian Glass, Llc. Vacuum insulating glass (VIG) unit with lead-free dual-frit seals and/or methods of making the same
US10421684B2 (en) 2014-02-04 2019-09-24 Guardian Glass, LLC Frits for use in vacuum insulating glass (VIG) units, and/or associated methods

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