SU172328A1 - METHOD OF OBTAINING TRIARYLIPHOSPHITES - Google Patents
METHOD OF OBTAINING TRIARYLIPHOSPHITESInfo
- Publication number
- SU172328A1 SU172328A1 SU906262A SU906262A SU172328A1 SU 172328 A1 SU172328 A1 SU 172328A1 SU 906262 A SU906262 A SU 906262A SU 906262 A SU906262 A SU 906262A SU 172328 A1 SU172328 A1 SU 172328A1
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- triaryliphosphites
- obtaining
- catalyst
- mol
- heating
- Prior art date
Links
- 239000003054 catalyst Substances 0.000 description 8
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L MgCl2 Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Natural products OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- AQSJGOWTSHOLKH-UHFFFAOYSA-N Phosphite Chemical class [O-]P([O-])[O-] AQSJGOWTSHOLKH-UHFFFAOYSA-N 0.000 description 4
- FAIAAWCVCHQXDN-UHFFFAOYSA-N Phosphorus trichloride Chemical compound ClP(Cl)Cl FAIAAWCVCHQXDN-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 2
- 125000000623 heterocyclic group Chemical group 0.000 description 2
- 229910001629 magnesium chloride Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 150000002989 phenols Chemical class 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N HCl Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- IXCSERBJSXMMFS-UHFFFAOYSA-N hydrogen chloride Substances Cl.Cl IXCSERBJSXMMFS-UHFFFAOYSA-N 0.000 description 1
- 229910000041 hydrogen chloride Inorganic materials 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000002194 synthesizing Effects 0.000 description 1
- JSDQLOKBIKEVKN-UHFFFAOYSA-N tris(2,4-dichlorophenyl) phosphite Chemical compound ClC1=CC(Cl)=CC=C1OP(OC=1C(=CC(Cl)=CC=1)Cl)OC1=CC=C(Cl)C=C1Cl JSDQLOKBIKEVKN-UHFFFAOYSA-N 0.000 description 1
Description
Известен способ получени триарилфосфитов взаимодействием треххлористого фосфора с фенолами при нагревании в присутствии .хлористого магни в качестве катализатора.A known method for producing triaryl phosphites by reacting phosphorus trichloride with phenols by heating in the presence of magnesium chloride as a catalyst.
С целью упроидени способа предлагаетс получать триарилфосфиты взаимодействием треххлористого фосфора с фенолами при нагревании в присутствии гетероциклических оснований в качестве катализатора.In order to simplify the process, it is proposed to obtain triaryl phosphites by reacting phosphorus trichloride with phenols by heating in the presence of heterocyclic bases as a catalyst.
Пример 1. Три-(2,4-дихлорфенил) фосфит .Example 1. Three- (2,4-dichlorophenyl) phosphite.
Смесь из 0,1 г моль треххлористого фосфора , 0,3 г моль 2,4-лихлорфенола и 0,3 г ииридина нагревают в течение 2-3 час до 140- и выдерживают при этой температуре до прекращени выделени хлористого водорода (2-3 час). Получают практически чистый продукт (выход 100%), который почти целиком перегон етс при 245-250 С /1 мм/, т. ил. 37-39°С.A mixture of 0.1 g mol of phosphorus trichloride, 0.3 g mol of 2,4-lichlorophenol and 0.3 g of iiridine is heated to 140 for 2-3 hours and kept at this temperature until the evolution of hydrogen chloride stops (2-3 hour). A practically pure product is obtained (yield 100%), which is almost completely distilled at 245-250 C / 1 mm /, t. Il. 37-39 ° C.
С.аНаОзСЬР.S.aNaOZSR.
Найдено, %: С 39,8; Р 5,43.Found,%: C 39.8; R 5.43.
Вычислено, %: С1 41,19; Р 5,6.Calculated,%: C1 41.19; P 5.6.
Подобный результат получен при использовании в качестве катализатора хннолина (2 моль).A similar result was obtained when using hnnoline (2 mol) as a catalyst.
Когда катализатором был хлористый магний (2 моль. %), дл завершени реакции потребовалось нагревание при 160-170С в течение 4 час. Без катализатора реакци не доходит ко конца даже при нагревании до 190- .When the catalyst was magnesium chloride (2 mol.%), Heating at 160-170 ° C was required to complete the reaction for 4 hours. Without a catalyst, the reaction does not reach the end, even when heated to 190-.
Пример 2. Три-(2,4-дп-вгор-бутилфенил)фосфит .Example 2. Three- (2,4-dp-bu-butylphenyl) phosphite.
Пол}чен в услови х синтеза три-(2,4-дихлорфенил ) фосфита при использовании в качестве катализатора пиридина (2 моль. %).It is used under the conditions of synthesis of tri- (2,4-dichlorophenyl) phosphite using pyridine (2 mol.%) As a catalyst.
Выход - 1 Output - 1
. кип. d2° 0.9792; nf, 1.5255.. kip d2 ° 0.9792; nf, 1.5255.
С42ПозО,,Р.С42ПозО ,, Р.
Найдено. %: Р 4,73. Вычислено, %: Р 4,81.Found %: P 4.73. Calculated,%: P 4.81.
Предмет пзобретени Subject matter
Способ получени триарилфосфитов взаимодействием треххлорпстого фосфора с фенола l при нагревании в ирисутствии катализатора , отличающийс тем, что, с целью упрощени способа, в качестве катализатора прпмен ют гетероциклические основани .The method of producing triaryl phosphites by the interaction of trichlorophosphorus with phenol l by heating in the presence of a catalyst, characterized in that, in order to simplify the process, heterocyclic bases are used as the catalyst.
Publications (1)
Publication Number | Publication Date |
---|---|
SU172328A1 true SU172328A1 (en) |
Family
ID=
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2383190A1 (en) * | 1977-03-10 | 1978-10-06 | Ciba Geigy Ag |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2383190A1 (en) * | 1977-03-10 | 1978-10-06 | Ciba Geigy Ag |
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