SU1606454A1 - Method of purifying flotation fluorite concentrate from silica and calcite - Google Patents

Method of purifying flotation fluorite concentrate from silica and calcite Download PDF

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Publication number
SU1606454A1
SU1606454A1 SU884603148A SU4603148A SU1606454A1 SU 1606454 A1 SU1606454 A1 SU 1606454A1 SU 884603148 A SU884603148 A SU 884603148A SU 4603148 A SU4603148 A SU 4603148A SU 1606454 A1 SU1606454 A1 SU 1606454A1
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SU
USSR - Soviet Union
Prior art keywords
silica
purifying
calcite
concentrate
fluorite concentrate
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Application number
SU884603148A
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Russian (ru)
Inventor
Григорий Федорович Иванов
Лидия Александровна Мальчевская
Игорь Петрович Смирнов
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Предприятие П/Я А-1997
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Priority to SU884603148A priority Critical patent/SU1606454A1/en
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Publication of SU1606454A1 publication Critical patent/SU1606454A1/en

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Abstract

Изобретение относитс  к способам очистки флюоритового флотационного концентрата от примесей кремнезема и кальци  и позвол ет повысить степень очистки, а также упростить процесс. Очистку концентрата ведут автоклавным выщелачиванием при 125-150°С водным раствором бифторида аммони  при его расходе 85-95% от стехиометрии. Содержание кремнезема и кальцита в очищенном концентрате составл ет 0,1-0,2%. 1 табл.The invention relates to methods for purifying a fluorite flotation concentrate from silica and calcium impurities and allows increasing the degree of purification as well as simplifying the process. The concentrate is purified by autoclave leaching at 125-150 ° C with an aqueous solution of ammonium bifluoride at its consumption of 85-95% of stoichiometry. The content of silica and calcite in the purified concentrate is 0.1-0.2%. 1 tab.

Description

Изобретение относитс  к гидрометаллургическим способам очистки концентратов и может найти применение при получении высококачественных флюоритовых концентратов .The invention relates to hydrometallurgical methods for cleaning concentrates and may find application in the preparation of high-quality fluorite concentrates.

Целью изобретени   вл етс  повышение степени очистки и упрощение процесса.The aim of the invention is to increase the purity and simplify the process.

Способ заключаетс  в том, что очистку флюоритового концентрата ведут автоклавным выщелачиванием при 125-150°С водным раствором бифторида аммони  при его расходе 85-95% от стехиометрии.The method consists in purifying the fluorite concentrate by autoclave leaching at 125-150 ° C with an aqueous solution of ammonium bifluoride at a rate of 85-95% of stoichiometry.

Пример. Флюоритовый флотоконцен трат состава, %: СаРа 94,8; СаСОз 1.0: ЗЮз 2,2, обработали в автоклаве при 140°С водным раствором бифторида аммони  концентрацией 56 г/дм , что составл ет 90% от стехиометрически необходимого количества дл  растворени  содержащихс  в концентрате кремнезема и кальцита. После выдержки в автоклаве при перемешиванииExample. Fluorite flotation concentrate waste composition,%: SaPa 94,8; CASO3 1.0: CSP 2.2, treated in an autoclave at 140 ° C with an aqueous solution of ammonium bifluoride with a concentration of 56 g / dm, which is 90% of the stoichiometrically necessary amount for dissolving the silica and calcite contained in the concentrate. After aging in the autoclave with stirring

в течение 1 ч получили продукт,содержа- щий, %: CaF297,9: СаСОзО,1: 51020,1.for 1 h, a product was obtained containing,%: CaF297.9: CAS02, 1: 51020.1.

Результаты других примеров представлены в таблице.The results of other examples are presented in the table.

При указанных параметрах способ позвол ет в одну стадию обеспечить более высокую степень очистки по сравнению с прототипом, осуществл емым в 2 стадии, т.е. способ дает возможность повысить степень очистки и исключить одну стадию обработки и тем самым упростить процесс.With these parameters, the method allows in one stage to provide a higher degree of purification compared to the prototype, carried out in 2 stages, i.e. the method makes it possible to increase the degree of purification and eliminate one stage of processing and thereby simplify the process.

Claims (1)

Формула изобретени  Способ очистки флотационного флюоритового концентрата от кремнезема и кальцита, включающий обработку его раствором бифторида аммони  при нагревании , отличающийс  тем, что, с целью повышени  степени очистки и упрощени  процесса, бифторид аммони  берут в количестве 85-95% от стехиометрии и обработку ведут при 125-150°С.Claims A method for purifying a flotation fluorite concentrate from silica and calcite, including treating it with ammonium bifluoride solution when heated, characterized in that, in order to increase the purification rate and simplify the process, ammonium bifluoride is taken in an amount of 85-95% of stoichiometry and is treated at 125-150 ° C. ОABOUT о оoh oh 4four СПSP JbwJbw
SU884603148A 1988-11-09 1988-11-09 Method of purifying flotation fluorite concentrate from silica and calcite SU1606454A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU884603148A SU1606454A1 (en) 1988-11-09 1988-11-09 Method of purifying flotation fluorite concentrate from silica and calcite

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU884603148A SU1606454A1 (en) 1988-11-09 1988-11-09 Method of purifying flotation fluorite concentrate from silica and calcite

Publications (1)

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SU1606454A1 true SU1606454A1 (en) 1990-11-15

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Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Авторское свидетельство СССР №514772. кл. С 01 F-11/22, 1974. *

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