SU1330073A1 - Method of producing superfine phosphorus-containing silica - Google Patents
Method of producing superfine phosphorus-containing silica Download PDFInfo
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- SU1330073A1 SU1330073A1 SU853986659A SU3986659A SU1330073A1 SU 1330073 A1 SU1330073 A1 SU 1330073A1 SU 853986659 A SU853986659 A SU 853986659A SU 3986659 A SU3986659 A SU 3986659A SU 1330073 A1 SU1330073 A1 SU 1330073A1
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- phosphorus
- containing silica
- silica
- water vapor
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Abstract
Изобретение относитс к получению адсорбентов, катализаторов и наполнителей полимерных материалов, обеспечива полноту содержани фосфора при сокращении длительности обработки и упрощении технологического процесса. Способ предусматривает обработку кремнезема парами воды в количестве 3,5-10°/о, а затем обработку парами трех.хлористого фосфора . 1 табл. со со соThe invention relates to the production of adsorbents, catalysts and fillers of polymeric materials, ensuring the completeness of the phosphorus content while reducing the processing time and simplifying the process. The method involves treating the silica with water vapor in an amount of 3.5-10 ° C / o and then treating with phosphorus trichloride vapor. 1 tab. with so with so
Description
Изобретение относитс к неорганической химии, а именно к сиособам получени кремнезема .This invention relates to inorganic chemistry, namely to methods for producing silica.
Цель изобретени - упрощение способа ,The purpose of the invention is to simplify the method
Пример 1. Аэросил марки А-300 массой 2,0 г обрабатывали нарами воды до влажности 3,5°/о, загружали в лабораторный реактор и обрабатывали в парах треххлорис- того фосфора в течение 0,5 ч при 140°С. Продукты реакции удал ли вакуумированием при 140°С в течение 2 ч. Содержание фосфора в образце составило 2,7%.Example 1. A-300 aerosil with a weight of 2.0 g was treated with a batch of water to a moisture content of 3.5 ° / o, loaded into a laboratory reactor, and treated in trichlorine phosphorus vapors for 0.5 h at 140 ° C. The reaction products were removed by evacuation at 140 ° C for 2 h. The phosphorus content in the sample was 2.7%.
Пример 2. Аэросил марки А-3000 массой 2,0 обрабатывали парами воды до влажности 9,3%, загружали в лабораторный реактор и обрабатывали парами треххлорис- того фосфора нри 95°С в течение 2 ч. Затем продукты реакции удал ли вакуумированием при температуре реакции в течение 2 ч. Содержание фосфора составило 3,5°/о.Example 2. A-3000 grade Aerosil weighing 2.0 was treated with water vapor to a moisture content of 9.3%, loaded into a laboratory reactor and treated with trichlorine phosphorus vapors at 95 ° C for 2 hours. Then, the reaction products were removed by evacuation at a temperature reaction for 2 hours. The phosphorus content was 3.5 ° / o.
Пример 3. Белую сажу марки БС-100 увлажн ли парами воды до влажности 8,7%, затем загружали в лабораторный реактор и обработали парами треххлористо- го фосфора в течение 5 ч при 80°С. Содержание фосфора в образце составило 2,1%.Example 3. BS-100 brand white soot was moistened with water vapor to a moisture content of 8.7%, then loaded into a laboratory reactor and treated with phosphorus trichloride vapors for 5 hours at 80 ° C. The phosphorus content in the sample was 2.1%.
Пример 4. Аэросил марки А-3000 в количестве 20 кг загружали в промышленныйExample 4. Aerosil brand A-3000 in the amount of 20 kg was loaded into industrial
Аэросил А-300Aerosil A-300
То же Also
Бела сажа БС-100Bela Soot BS-100
3,5 9,3 8,73.5 9.3 8.7
10ten
Известный АэросилFamous Aerosil
Составитель Т. ЧиликинаCompiled by T. Chilikina
Редактор М. НедолуженкоТехред И. ВересКорректор Л. ПатайEditor M. NedoluzhenkoTehred I. VeresKorrektor L. Patay
Заказ 3532/23Тираж 455ПодписноеOrder 3532/23 Circulation 455 Subscription
ВНИИПИ Государственного комитета СССР по делам изобретений и открытийVNIIPI USSR State Committee for Inventions and Discoveries
1 13035, Москва, Ж-35, Раушска наб., д. 4/5 Производственно-полиграфическое предпри тие, г. Ужгород, ул. Проектна , 41 13035, Moscow, Zh-35, Raushsk nab. 4/5 Production and printing company, Uzhgorod, ul. Project, 4
эмалированный реактор, продували азотом дл удалени кислорода воздуха из реактора , нагревали до 130°С и ввели 2 л воды. Обработку вели в течение 0,5 ч. Затем вthe enameled reactor was purged with nitrogen to remove the atmospheric oxygen from the reactor, heated to 130 ° C, and 2 liters of water were injected. The treatment was carried out for 0.5 hours. Then in
реактор подавали 3,6 кг треххлористого фосфора и реакцию проводили в течение 2 ч при 130°С. Продукты реакции удал ли отдувкой азотом в течени.е 2 ч при 130°С. Содержание фосфора в образце составило 4%.the reactor was fed 3.6 kg of phosphorus trichloride and the reaction was carried out for 2 hours at 130 ° C. The reaction products were removed by stripping with nitrogen for 2 hours at 130 ° C. The phosphorus content in the sample was 4%.
Результаты примеров осуществлени способа по примерам 1-4 и известному сведены в таблицу.The results of the examples of the implementation of the method according to examples 1-4 and known are tabulated.
Преимуществом предлагаемого способа вл етс исключение операции сушки кремнезема и снижение температуры реакции при сохранении полноты содержани фосфора в продукте.The advantage of the proposed method is the elimination of the operation of drying the silica and lowering the reaction temperature while maintaining the full phosphorus content in the product.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU853986659A SU1330073A1 (en) | 1985-12-09 | 1985-12-09 | Method of producing superfine phosphorus-containing silica |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU853986659A SU1330073A1 (en) | 1985-12-09 | 1985-12-09 | Method of producing superfine phosphorus-containing silica |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1330073A1 true SU1330073A1 (en) | 1987-08-15 |
Family
ID=21208833
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU853986659A SU1330073A1 (en) | 1985-12-09 | 1985-12-09 | Method of producing superfine phosphorus-containing silica |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU1330073A1 (en) |
-
1985
- 1985-12-09 SU SU853986659A patent/SU1330073A1/en active
Non-Patent Citations (1)
| Title |
|---|
| Авторское свидетельство СССР № 887462, кл. С 01 В 33/16, 1981. Авторское свидетельство СССР № 700441, кл. С 01 В 33/10, 1979. * |
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