SU1303013A3 - Method of fighting unwanted plants - Google Patents
Method of fighting unwanted plants Download PDFInfo
- Publication number
- SU1303013A3 SU1303013A3 SU843778329A SU3778329A SU1303013A3 SU 1303013 A3 SU1303013 A3 SU 1303013A3 SU 843778329 A SU843778329 A SU 843778329A SU 3778329 A SU3778329 A SU 3778329A SU 1303013 A3 SU1303013 A3 SU 1303013A3
- Authority
- SU
- USSR - Soviet Union
- Prior art keywords
- phosphonomethylglycinamide
- derivative
- unwanted plants
- formula
- plants
- Prior art date
Links
- 238000000034 method Methods 0.000 title claims description 9
- 241000196324 Embryophyta Species 0.000 claims description 10
- JZCSMMPWEAKXBU-UHFFFAOYSA-N [(2-aminoacetyl)amino]methylphosphonic acid Chemical class NCC(=O)NCP(O)(O)=O JZCSMMPWEAKXBU-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 239000004009 herbicide Substances 0.000 abstract 1
- 239000013543 active substance Substances 0.000 description 4
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 2
- 230000035784 germination Effects 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 229910052763 palladium Inorganic materials 0.000 description 2
- 239000004094 surface-active agent Substances 0.000 description 2
- IGFHQQFPSIBGKE-UHFFFAOYSA-N 4-nonylphenol Polymers CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-NQAPHZHOSA-N Sorbitol Polymers OCC(O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-NQAPHZHOSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 239000013068 control sample Substances 0.000 description 1
- 238000006264 debenzylation reaction Methods 0.000 description 1
- QKIUAMUSENSFQQ-UHFFFAOYSA-N dimethylazanide Chemical compound C[N-]C QKIUAMUSENSFQQ-UHFFFAOYSA-N 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000002363 herbicidal effect Effects 0.000 description 1
- 239000003621 irrigation water Substances 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Polymers CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/3804—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
- C07F9/3808—Acyclic saturated acids which can have further substituents on alkyl
- C07F9/3813—N-Phosphonomethylglycine; Salts or complexes thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/22—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Engineering & Computer Science (AREA)
- Plant Pathology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pretreatment Of Seeds And Plants (AREA)
Abstract
Description
1one
Изобретение относитс к химичес- КИМ способам защиты растений, а именно к способу борьбы с нежелательной растительностью путем обработки растений производным N-фосфонометил- глицинамида.The invention relates to chemical methods of protecting plants, namely, a method of controlling undesirable vegetation by treating plants with an N-phosphonomethylglycinamide derivative.
Цель изобретени - усиление эффективности способа.The purpose of the invention is to increase the efficiency of the method.
Пример 1. Используемое в способе производное N-фосфонометил- глицинамида формулыExample 1. Used in the method derived N-phosphonomethyl-glycinamide formula
ОН IOH I
NHCH CONSO СН NHCH CONSO CH
онhe
СН,CH,
33
получают дебензилированием соединени obtained by debenzylation of the compound
(011),.,СН,И (СН,С НрCHJDON (СК ) (011)., CH, AND (CH, WITH HpCHJDON (CK)
в присутствии палладиевого катали- затора, нанесенного на уголь (10% Pd). Процесс ведут в среде метанола при температуре окружающей среды В конце реакции катализатор удал ют посредством фильтрации и высаливанием окисью пропилена. Упарива фильтрат, получают желаемое соединение с т. пл. 21 3 С.in the presence of a palladium catalyst supported on coal (10% Pd). The process is conducted in methanol at ambient temperature. At the end of the reaction, the catalyst is removed by filtration and salination with propylene oxide. Evaporation of the filtrate, get the desired compound with so pl. 21 3 C.
Пример 2, Гербицидное применение после прорастани растительных видов.Example 2 Herbicidal use after germination of plant species.
В горщки 9x9x9 см, заполненные лекой сельскохоз йственнЪй землёй, высевают определенное количество сем н в зависимости от растительного вида и от величины семени.In the 9x9x9 cm pods, filled with a piece of agricultural land, a certain number of seeds are sown, depending on the plant species and on the size of the seed.
Зат.ем семена покрьгоают слоем земли толщиной примерно 3 мм. и оставл ют семена прорастать до по влени проростка на соответствующей стадии. Стади обработки дл злаковых вл етс стадией образовани второго листа . Стади обработки дл двусем доль-45 растительностью путем обработки расных вл етс стадией сем дольных с развивающимс насто щим первьм листом .Then the seeds are covered with a layer of earth about 3 mm thick. and the seeds are left to germinate until the germination at the appropriate stage. The processing stage for cereals is the stage of formation of the second sheet. The processing step for two half-45 vegetation by treating the spreading is the seed stage with the developing present first leaf.
Затем горщки обрабатываютс посредством распылени пульпы в количестве , соответствующем объемной дозе применени пор дка 500 л/га, содержащей активное вещество в заданной концентрации.Then the pots are treated by spraying the pulp in an amount corresponding to a volumetric dose of about 500 L / ha containing the active substance in a given concentration.
Пульпа, использованна дл обработки , вл етс суспензией или водным раствором активного вещества, со10The pulp used for the treatment is a suspension or aqueous solution of the active substance;
1515
гg
030132030132
держащего 0,1 мас.%. Семульсол (Сё- mulsol NP 10) - поверхностно-активного агента в виде полиэтоксилирован- ного алкилфенола, в частности полиэтоксилированного нонилфе- нола (и 0,04 мас.% твина 20 - поверхностно-активного агента в виде олеата полиэтоксилированного производного сорбитола).holding 0.1 wt.%. Semulsol (Сё- mulsol NP 10) - surface-active agent in the form of polyethoxylated alkylphenol, in particular polyethoxylated nonylphenol (and 0.04 wt.% Tween 20 - surface-active agent in the form of polyethoxylated sorbitol oleate).
Обработанные горшки затем помещаютс в резервуары, предназначенные дл приема воды орошени , и вьщержи- ваютс в течение 28 дней при температуре окружающей среды при относительной влажности 70%.The treated pots are then placed in tanks intended for receiving irrigation water, and held for 28 days at ambient temperature at a relative humidity of 70%.
По истечении 28 дней считают количество живых растений в горшках, обработанных пульпой, содержащей испытуемое активное вещество, и количество живых растений в контрольном горшке, обработанном в тех же услови х, но посредством пульпы, не содержащей активного вещества. Таким образом определ ют процент ингибиро25 вани обработанных растений по сравнению с необработанным -контрольньм образцом. Процент ингибировани , равный 100% указьшает, что произошло пол- полное уничтожение рассматриваемогоAfter 28 days, the number of live plants in pots treated with pulp containing the test active substance and the number of live plants in the control pot treated under the same conditions, but not using the pulp containing no active substance, are considered. In this way, the percent inhibition of the treated plants is determined compared to the untreated control sample. The percentage of inhibition equal to 100% indicates that the complete elimination of the considered
30 растительного вида, а процент, равный О, указывает, что количество живых растений в обработанном горшке равно количеству, содержащемус в контрольном горщке.30 plant species, and a percentage equal to O indicates that the number of living plants in the treated pot is equal to the number contained in the control pot.
Полученные результаты представлены в таблице. The results obtained are presented in the table.
Таким образом, предлагаемый способ вл етс более эффективным, чем способ на основе диметиламида N-фос- фонометилглициновой кислоты.Thus, the proposed method is more efficient than the N-phosphonomethylglycic acid dimethylamide-based method.
2020
3535
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Claims (1)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR8312620A FR2549839B1 (en) | 1983-07-27 | 1983-07-27 | NOVEL SULFONAMIDE GROUP HERBICIDES DERIVED FROM N-PHOSPHONOMETHYL GLYCINE |
Publications (1)
Publication Number | Publication Date |
---|---|
SU1303013A3 true SU1303013A3 (en) | 1987-04-07 |
Family
ID=9291278
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
SU843778329A SU1303013A3 (en) | 1983-07-27 | 1984-07-26 | Method of fighting unwanted plants |
Country Status (6)
Country | Link |
---|---|
JP (1) | JPS6056991A (en) |
CS (1) | CS246087B2 (en) |
FR (1) | FR2549839B1 (en) |
MA (1) | MA20185A1 (en) |
SU (1) | SU1303013A3 (en) |
ZA (1) | ZA845744B (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
FR2576181B1 (en) * | 1985-01-23 | 1987-04-03 | Rhone Poulenc Agrochimie | HERBICIDE MIXTURES BASED ON N- TYPE COMPOUND (PHOSPHONOMETHYLGLYCYL) |
US7169933B2 (en) | 2003-11-14 | 2007-01-30 | 3M Innovative Properties Company | N-sulfonylaminocarbonyl containing compounds |
EP1682525B1 (en) * | 2003-11-14 | 2013-12-25 | 3M Innovative Properties Company | N-sulfonylaminocarbonyl containing compounds |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3910969A (en) * | 1974-06-28 | 1975-10-07 | Monsanto Co | N-phenylsulfonamido-n-phosphonomethyl glycine and certain derivatives thereof |
US3972915A (en) * | 1974-08-14 | 1976-08-03 | Monsanto Company | N-phosphonomethylglycine phenyl hydrazides |
US4414158A (en) * | 1980-04-29 | 1983-11-08 | Ciba-Geigy Corporation | Phosphonomethylglycylhydroxamic acid and novel herbicidally active salts thereof |
-
1983
- 1983-07-27 FR FR8312620A patent/FR2549839B1/en not_active Expired
-
1984
- 1984-07-20 MA MA20409A patent/MA20185A1/en unknown
- 1984-07-25 ZA ZA845744A patent/ZA845744B/en unknown
- 1984-07-26 SU SU843778329A patent/SU1303013A3/en active
- 1984-07-26 JP JP59156484A patent/JPS6056991A/en active Granted
- 1984-07-27 CS CS845809A patent/CS246087B2/en unknown
Non-Patent Citations (1)
Title |
---|
3778329/23-05 26.07.84 8312620 27.07.83 FR 07.04.87. Бюл. № 1-3 Рон-Пуленк Агрошими (FR) Ги Борро и Ги Лакруа (FR) 632.954(088.8) Патент FR № 2281936, кл. С 07 F 9/38, опублик. 1976. Патент FR № 2129327, кл. С 07 F 9/00, опублик. 1972. * |
Also Published As
Publication number | Publication date |
---|---|
FR2549839B1 (en) | 1985-09-20 |
FR2549839A1 (en) | 1985-02-01 |
MA20185A1 (en) | 1985-04-01 |
JPS6056991A (en) | 1985-04-02 |
ZA845744B (en) | 1986-06-25 |
JPS647080B2 (en) | 1989-02-07 |
CS246087B2 (en) | 1986-10-16 |
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