SU1303013A3 - Method of fighting unwanted plants - Google Patents

Method of fighting unwanted plants Download PDF

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Publication number
SU1303013A3
SU1303013A3 SU843778329A SU3778329A SU1303013A3 SU 1303013 A3 SU1303013 A3 SU 1303013A3 SU 843778329 A SU843778329 A SU 843778329A SU 3778329 A SU3778329 A SU 3778329A SU 1303013 A3 SU1303013 A3 SU 1303013A3
Authority
SU
USSR - Soviet Union
Prior art keywords
phosphonomethylglycinamide
derivative
unwanted plants
formula
plants
Prior art date
Application number
SU843778329A
Other languages
Russian (ru)
Inventor
Борро Ги
Лакруа Ги
Original Assignee
Рон-Пуленк Агрошими (Фирма)
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application granted granted Critical
Publication of SU1303013A3 publication Critical patent/SU1303013A3/en

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    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/3804Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)] not used, see subgroups
    • C07F9/3808Acyclic saturated acids which can have further substituents on alkyl
    • C07F9/3813N-Phosphonomethylglycine; Salts or complexes thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/20Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N57/00Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
    • A01N57/18Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
    • A01N57/22Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing aromatic radicals
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02Phosphorus compounds
    • C07F9/28Phosphorus compounds with one or more P—C bonds
    • C07F9/38Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40Esters thereof
    • C07F9/4003Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4006Esters of acyclic acids which can have further substituents on alkyl

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Dentistry (AREA)
  • Engineering & Computer Science (AREA)
  • Plant Pathology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Biochemistry (AREA)
  • Molecular Biology (AREA)
  • Agronomy & Crop Science (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pretreatment Of Seeds And Plants (AREA)

Abstract

Herbicides of formula: <IMAGE> R and R1 being an alkyl radical.l

Description

1one

Изобретение относитс  к химичес- КИМ способам защиты растений, а именно к способу борьбы с нежелательной растительностью путем обработки растений производным N-фосфонометил- глицинамида.The invention relates to chemical methods of protecting plants, namely, a method of controlling undesirable vegetation by treating plants with an N-phosphonomethylglycinamide derivative.

Цель изобретени  - усиление эффективности способа.The purpose of the invention is to increase the efficiency of the method.

Пример 1. Используемое в способе производное N-фосфонометил- глицинамида формулыExample 1. Used in the method derived N-phosphonomethyl-glycinamide formula

ОН IOH I

NHCH CONSO СН NHCH CONSO CH

онhe

СН,CH,

33

получают дебензилированием соединени obtained by debenzylation of the compound

(011),.,СН,И (СН,С НрCHJDON (СК ) (011)., CH, AND (CH, WITH HpCHJDON (CK)

в присутствии палладиевого катали- затора, нанесенного на уголь (10% Pd). Процесс ведут в среде метанола при температуре окружающей среды В конце реакции катализатор удал ют посредством фильтрации и высаливанием окисью пропилена. Упарива  фильтрат, получают желаемое соединение с т. пл. 21 3 С.in the presence of a palladium catalyst supported on coal (10% Pd). The process is conducted in methanol at ambient temperature. At the end of the reaction, the catalyst is removed by filtration and salination with propylene oxide. Evaporation of the filtrate, get the desired compound with so pl. 21 3 C.

Пример 2, Гербицидное применение после прорастани  растительных видов.Example 2 Herbicidal use after germination of plant species.

В горщки 9x9x9 см, заполненные лекой сельскохоз йственнЪй землёй, высевают определенное количество сем н в зависимости от растительного вида и от величины семени.In the 9x9x9 cm pods, filled with a piece of agricultural land, a certain number of seeds are sown, depending on the plant species and on the size of the seed.

Зат.ем семена покрьгоают слоем земли толщиной примерно 3 мм. и оставл ют семена прорастать до по влени  проростка на соответствующей стадии. Стади  обработки дл  злаковых  вл етс  стадией образовани  второго листа . Стади  обработки дл  двусем доль-45 растительностью путем обработки расных  вл етс  стадией сем дольных с развивающимс  насто щим первьм листом .Then the seeds are covered with a layer of earth about 3 mm thick. and the seeds are left to germinate until the germination at the appropriate stage. The processing stage for cereals is the stage of formation of the second sheet. The processing step for two half-45 vegetation by treating the spreading is the seed stage with the developing present first leaf.

Затем горщки обрабатываютс  посредством распылени  пульпы в количестве , соответствующем объемной дозе применени  пор дка 500 л/га, содержащей активное вещество в заданной концентрации.Then the pots are treated by spraying the pulp in an amount corresponding to a volumetric dose of about 500 L / ha containing the active substance in a given concentration.

Пульпа, использованна  дл  обработки ,  вл етс  суспензией или водным раствором активного вещества, со10The pulp used for the treatment is a suspension or aqueous solution of the active substance;

1515

гg

030132030132

держащего 0,1 мас.%. Семульсол  (Сё- mulsol NP 10) - поверхностно-активного агента в виде полиэтоксилирован- ного алкилфенола, в частности полиэтоксилированного нонилфе- нола (и 0,04 мас.% твина 20 - поверхностно-активного агента в виде олеата полиэтоксилированного производного сорбитола).holding 0.1 wt.%. Semulsol (Сё- mulsol NP 10) - surface-active agent in the form of polyethoxylated alkylphenol, in particular polyethoxylated nonylphenol (and 0.04 wt.% Tween 20 - surface-active agent in the form of polyethoxylated sorbitol oleate).

Обработанные горшки затем помещаютс  в резервуары, предназначенные дл  приема воды орошени , и вьщержи- ваютс  в течение 28 дней при температуре окружающей среды при относительной влажности 70%.The treated pots are then placed in tanks intended for receiving irrigation water, and held for 28 days at ambient temperature at a relative humidity of 70%.

По истечении 28 дней считают количество живых растений в горшках, обработанных пульпой, содержащей испытуемое активное вещество, и количество живых растений в контрольном горшке, обработанном в тех же услови х, но посредством пульпы, не содержащей активного вещества. Таким образом определ ют процент ингибиро25 вани  обработанных растений по сравнению с необработанным -контрольньм образцом. Процент ингибировани , равный 100% указьшает, что произошло пол- полное уничтожение рассматриваемогоAfter 28 days, the number of live plants in pots treated with pulp containing the test active substance and the number of live plants in the control pot treated under the same conditions, but not using the pulp containing no active substance, are considered. In this way, the percent inhibition of the treated plants is determined compared to the untreated control sample. The percentage of inhibition equal to 100% indicates that the complete elimination of the considered

30 растительного вида, а процент, равный О, указывает, что количество живых растений в обработанном горшке равно количеству, содержащемус  в контрольном горщке.30 plant species, and a percentage equal to O indicates that the number of living plants in the treated pot is equal to the number contained in the control pot.

Полученные результаты представлены в таблице. The results obtained are presented in the table.

Таким образом, предлагаемый способ  вл етс  более эффективным, чем способ на основе диметиламида N-фос- фонометилглициновой кислоты.Thus, the proposed method is more efficient than the N-phosphonomethylglycic acid dimethylamide-based method.

2020

3535

4040

Claims (1)

Формула изобретени Invention Formula Способ борьбы с нежелательнойA way to combat unwanted тений производным N-фосфонометилгли- цинамида, отличающийс  тем, что, с целью усилени  эффективности способа, в качестве производ- 50 ного N-фосфонометилглицинамида используют соединение формулыN-phosphonomethylglycinamide derivative, characterized in that, in order to enhance the efficiency of the process, a compound of the formula N-phosphonomethylglycinamide is used as a derivative ОН I NHCH CONSO СНOH I NHCH CONSO CH I 2 2 I 5 3I 2 2 I 5 3 ОН СН.| HE CH. | в количестве 0,125-8 кг/га.in the amount of 0.125-8 kg / ha. Вид растенийPlant species Предлагаемое соеди е ие.Proposed connection. Редактор Е.ПаппEditor E. Papp Составитель Н.КибаловаCompiled by N. Kibalova Техред И.ПоповичКорректор А.ЗимокосовTehred I.PopovichKorrektor A.Zimokosov Заказ 1226/57Тираж 630 .ПодписноеOrder 1226/57 Circulation 630. Subscription ВНИИПИ Государственного комитета СССРVNIIPI USSR State Committee по делам изобретений и открытий 113035, Москва, Ж-35, Раушска  наб., д. 4/5for inventions and discoveries 113035, Moscow, Zh-35, Raushsk nab., 4/5 Производственно-полиграфическое предпри тие, г.Ужгород, ул.Проектна , 4Production and printing company, Uzhgorod, Projecto st., 4 too 100 100too 100 100 00 6060 00 00 60 3060 30 6060 10ten ОABOUT 100100 60 10 6060 10 60 90 5090 50 ОABOUT 6060 ОABOUT 20 О20 o 80 О80 o 9в 109v 10 100 100100 100 100 100100 100 2020 100 100 100 30 90 100 100 100 100100 100 100 30 90 100 100 100 100 too 100 100 100too 100 100 100 9090 9898 100 100100 100 О10 60 95O10 60 95 100 100 100 100 10 20 20 30100 100 100 100 10 20 20 30
SU843778329A 1983-07-27 1984-07-26 Method of fighting unwanted plants SU1303013A3 (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR8312620A FR2549839B1 (en) 1983-07-27 1983-07-27 NOVEL SULFONAMIDE GROUP HERBICIDES DERIVED FROM N-PHOSPHONOMETHYL GLYCINE

Publications (1)

Publication Number Publication Date
SU1303013A3 true SU1303013A3 (en) 1987-04-07

Family

ID=9291278

Family Applications (1)

Application Number Title Priority Date Filing Date
SU843778329A SU1303013A3 (en) 1983-07-27 1984-07-26 Method of fighting unwanted plants

Country Status (6)

Country Link
JP (1) JPS6056991A (en)
CS (1) CS246087B2 (en)
FR (1) FR2549839B1 (en)
MA (1) MA20185A1 (en)
SU (1) SU1303013A3 (en)
ZA (1) ZA845744B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2576181B1 (en) * 1985-01-23 1987-04-03 Rhone Poulenc Agrochimie HERBICIDE MIXTURES BASED ON N- TYPE COMPOUND (PHOSPHONOMETHYLGLYCYL)
US7169933B2 (en) 2003-11-14 2007-01-30 3M Innovative Properties Company N-sulfonylaminocarbonyl containing compounds
EP1682525B1 (en) * 2003-11-14 2013-12-25 3M Innovative Properties Company N-sulfonylaminocarbonyl containing compounds

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3910969A (en) * 1974-06-28 1975-10-07 Monsanto Co N-phenylsulfonamido-n-phosphonomethyl glycine and certain derivatives thereof
US3972915A (en) * 1974-08-14 1976-08-03 Monsanto Company N-phosphonomethylglycine phenyl hydrazides
US4414158A (en) * 1980-04-29 1983-11-08 Ciba-Geigy Corporation Phosphonomethylglycylhydroxamic acid and novel herbicidally active salts thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
3778329/23-05 26.07.84 8312620 27.07.83 FR 07.04.87. Бюл. № 1-3 Рон-Пуленк Агрошими (FR) Ги Борро и Ги Лакруа (FR) 632.954(088.8) Патент FR № 2281936, кл. С 07 F 9/38, опублик. 1976. Патент FR № 2129327, кл. С 07 F 9/00, опублик. 1972. *

Also Published As

Publication number Publication date
FR2549839B1 (en) 1985-09-20
FR2549839A1 (en) 1985-02-01
MA20185A1 (en) 1985-04-01
JPS6056991A (en) 1985-04-02
ZA845744B (en) 1986-06-25
JPS647080B2 (en) 1989-02-07
CS246087B2 (en) 1986-10-16

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