SU121231A1 - A method of manufacturing alkali free glass - Google Patents

A method of manufacturing alkali free glass

Info

Publication number
SU121231A1
SU121231A1 SU607510A SU607510A SU121231A1 SU 121231 A1 SU121231 A1 SU 121231A1 SU 607510 A SU607510 A SU 607510A SU 607510 A SU607510 A SU 607510A SU 121231 A1 SU121231 A1 SU 121231A1
Authority
SU
USSR - Soviet Union
Prior art keywords
glass
free glass
alkali free
manufacturing alkali
silica
Prior art date
Application number
SU607510A
Other languages
Russian (ru)
Inventor
В.А. Блинов
И.И. Китайгородский
Original Assignee
В.А. Блинов
И.И. Китайгородский
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication of SU121231A1 publication Critical patent/SU121231A1/en
Application filed by В.А. Блинов, И.И. Китайгородский filed Critical В.А. Блинов
Priority to SU607510A priority Critical patent/SU121231A1/en

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00Glass compositions
    • C03C3/04Glass compositions containing silica
    • C03C3/062Glass compositions containing silica with less than 40% silica by weight
    • C03C3/07Glass compositions containing silica with less than 40% silica by weight containing lead
    • C03C3/072Glass compositions containing silica with less than 40% silica by weight containing lead containing boron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Glass Compositions (AREA)

Description

По существующим способам бесщелочное термостойкое стекло получают варкой смеси, содержащей различные стеклообразующие окислы , например, SiO2, В20з, АЬОз, РЬО.According to the existing methods, alkali-free heat-resistant glass is obtained by cooking a mixture containing various glass-forming oxides, for example, SiO2, B203, ABO3, PHO.

Предлагаемый способ получени  термически устойчивого стекла отличаетс  тем, что вначале вар т и измельчают бесщелочное свинцовое стекло, а затем составл ют смесь, содержащую 30-60% свинцового стекла н 40-70% вибромолотого кварцевого песка (или гели кремневой кислоты), причем дл  улучщени  осветлени  в смесь ввод т небольшое количество (1-3%) поваренной соли или другого осветлител .The proposed method of obtaining thermally stable glass is characterized in that first alkali free lead glass is ground and crushed, and then a mixture containing 30-60% of lead glass and 40-70% vibro-ground quartz sand (or silica gels) is made, and The clarification introduces a small amount (1-3%) of common salt or another clarifier into the mixture.

В качестве исходного стекла беретс  бесщелочное свинцовое стекло следующего состава.Alkali-free lead glass of the following composition is taken as the initial glass.

SiOa - 31-51%; ВгОз - 10-12%; АЬОз - 2%; РЬО - 42-52%; ZrO2 - 5VO.SiOa - 31-51%; VGOs - 10-12%; ABOZ - 2%; PbG - 42-52%; ZrO2 - 5VO.

Отличительной особенностью способа  вл етс  то, что при нагревании смеси измельченного свинцового стекла с кремнеземом до 1650- 1690° происходит растворение кремнезема в жидкой фазе (стекле).A distinctive feature of the method is that when the mixture of crushed lead glass with silica is heated to 1650–1690 °, the silica dissolves in the liquid phase (glass).

Таким образом, за счет растворени  кремнезема в стекле получаетс  проваренное и хорощо осветленное термостойкое стекло с коэффициентом термического расширени  примерно 15-22 .Thus, due to the dissolution of silica in glass, a boiled and well-clarified, heat-resistant glass is obtained with a thermal expansion coefficient of about 15-22.

Предмет изобретени Subject invention

1. Способ изготовлени  бесщелочного стекла на основе кремнезема, глинозема, окиси бора, окиси свинца, отличающийс  тем, что, с целью получени  стекла повышенной термической устойчивости, его изготовл ют плавлением шихты, содерл ;ащей от 30 до 60% измельченного в порошок свинцового стекла и от 70 до 40% гел  кремневой кислоты или песка, причем стекло, вводимое в щихту, должно содержать:1. A method of manufacturing an alkali-free glass based on silica, alumina, boron oxide, lead oxide, characterized in that, in order to obtain a glass with enhanced thermal stability, it is made by melting the mixture containing ground to 30 to 60% ground lead powder and from 70 to 40% gel of silicic acid or sand, and the glass introduced into the powder should contain:

121231- 2 -121231-2 -

КремнеземаSiO2 - 31-41%Silica SiO2 - 31-41%

ГлиноземаАЬОз - 2%AluminaAyOZ - 2%

Окиси бораВаОз - 10-12%BoraVaOz oxides - 10-12%

свинцаРЬО - 42-52 /о leadZiO - 42-52 / o

циркони ZrOz - 5Vo ZrOz Zirconia - 5Vo

SU607510A 1958-09-11 1958-09-11 A method of manufacturing alkali free glass SU121231A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
SU607510A SU121231A1 (en) 1958-09-11 1958-09-11 A method of manufacturing alkali free glass

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
SU607510A SU121231A1 (en) 1958-09-11 1958-09-11 A method of manufacturing alkali free glass

Publications (1)

Publication Number Publication Date
SU121231A1 true SU121231A1 (en)

Family

ID=39873868

Family Applications (1)

Application Number Title Priority Date Filing Date
SU607510A SU121231A1 (en) 1958-09-11 1958-09-11 A method of manufacturing alkali free glass

Country Status (1)

Country Link
SU (1) SU121231A1 (en)

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