SU1184813A1 - Method of producing hexachloride triammonium bismuth (iii) - Google Patents
Method of producing hexachloride triammonium bismuth (iii) Download PDFInfo
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- SU1184813A1 SU1184813A1 SU843733984A SU3733984A SU1184813A1 SU 1184813 A1 SU1184813 A1 SU 1184813A1 SU 843733984 A SU843733984 A SU 843733984A SU 3733984 A SU3733984 A SU 3733984A SU 1184813 A1 SU1184813 A1 SU 1184813A1
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- USSR - Soviet Union
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- bismuth
- triammonium
- hexachloride
- producing
- iii
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- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
СПОСОБ ПОЛУЧЕНИЯ ТРИАММОНИЙ ВИСМУТ METHOD OF OBTAINING TRIAMMONIUM Bismuth
Description
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Изобретение относитс к способам получени триаммоний висмут (1П)гексахлорида и может быть использовано дл получени бескислородных хлорсодержащих соединений висмута, а также в производстве чистых соединений рубрщи и цези .The invention relates to methods for producing triammonium bismuth (1P) hexachloride and can be used to obtain oxygen-free chlorine-containing bismuth compounds, as well as in the manufacture of pure compounds of rubies and cesium.
Цель изобретени - повышение выхода и чистоты лродукта и упрощение процесса за счет исключени операции упаривани раствора.The purpose of the invention is to increase the yield and purity of the product and simplify the process by eliminating the operation of evaporation of the solution.
Пример 1.К смеси из 100 г трихлорида висмута и 55 г хлористого аммони добавл ют 37,1 мл воды (исходное мольное соотношение компонентов равно 1:3,2:6,5). Смесь перемешивают при комнатной температуре 4 ч и отфильтровьшают. Получают 53,8 г соли, содержащей 65,7% RiCl, NH4C1 и 74 мл фильтрата, содержащего г/л: BiClj 715,6, М1ЦС1 426,8. Выход соли состабил 34,7%. Состав соли,%: (ЫН4)зВ;С1 99,1;NH4C1 0,9.Example 1. To a mixture of 100 g of bismuth trichloride and 55 g of ammonium chloride, 37.1 ml of water are added (the initial molar ratio of the components is 1: 3.2: 6.5). The mixture is stirred at room temperature for 4 hours and filtered. 53.8 g of salt containing 65.7% of RiCl, NH4C1 and 74 ml of filtrate containing g / l: BiClj 715.6, M1CCl1 426.8 are obtained. The output of salt was sotabil 34.7%. Composition of salt,%: (LH4) ЗВ; С1 99.1; NH4C1 0.9.
П р и м е р 2. К смеси из 100 г BiClj и 55 г добавл ют 50,0 мл (исходное мольное соотно шение компонентов 1:3,2:8,7). Смесь перемешивают при комнатной темпера туре 6 ч. Получают 53,0 г осадка.EXAMPLE 2 To a mixture of 100 g of BiClj and 55 g, 50.0 ml are added (the initial molar ratio of the components is 1: 3.2: 8.7). The mixture is stirred at room temperature for 6 hours. 53.0 g of precipitate are obtained.
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содержащего 65,9% В,-СЦ и 34% и 84 мл фильтрата, содержащего,г/л: BiClj 716,4, NH4C1 413,7. Выход соли составил 34,2%. Состав соли,%: 5 (NH4)3Bi-Cl 99,14, 0,6.containing 65.9% B, -SC and 34% and 84 ml of filtrate, containing, g / l: BiClj 716.4, NH4C1 413.7. The salt yield was 34.2%. The composition of the salt,%: 5 (NH4) 3Bi-Cl 99.14, 0.6.
ПримерЗ. К смеси из 100 г BtCli и 63,8 г WHyC добавл ют 50 мл . Смесь перемешивают 4 ч при комнатной температуре. Получают 52,3 г осадка, содержащего 66,0% BiCl и 34% и 88 мл раствора , содержащего, г/л: BiCIj 712,2, 433. Выход соли составил 31,2%. Состав соли, %: ( 99,5; jHi,Cl 0,5. Исходное мольNH ClExample 50 ml is added to a mixture of 100 g of BtCli and 63.8 g of WHyC. The mixture is stirred for 4 hours at room temperature. Obtain 52.3 g of sediment containing 66.0% BiCl and 34% and 88 ml of a solution containing, g / l: BiCIj 712.2, 433. The salt yield was 31.2%. Composition of salt,%: (99.5; jHi, Cl 0.5. Initial molNH Cl
Н,0 H, 0
нов соотношение Bid,new Bid ratio,
1 :3,7:8,7. 1: 3.7: 8.7.
Пример4. К смеси из 100 г BiCl,, и.63,8 г добавл ют 38,5 МП HjO. Смесь перемешивают 6 ч при комнатной температуре и отфильтровывают. Получают 74 мл фильрата , содержащего 642,6 г/л BiClj и 427,5 г/л и 81,9 г соли, содержащейу%: В/СЦ 62,8; 37,2. Выход соли составил 50,1%. Состав соли,%:(МН4)5В1С1 4 94,8; NH4C1 5,2. Мольное соотношение исходных компонентов равно 1:3,7:6,5.Example4. To a mixture of 100 g of BiCl, and 63.8 g, 38.5 MP HjO are added. The mixture is stirred for 6 hours at room temperature and filtered. 74 ml of the filtrate are obtained, containing 642.6 g / l of BiClj and 427.5 g / l and 81.9 g of salt containing%: B / SC 62.8; 37.2. Salt yield was 50.1%. Composition of salt,%: (МН4) 5В1С1 4 94.8; NH4C1 5.2. The molar ratio of the starting components is 1: 3.7: 6.5.
Claims (1)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU843733984A SU1184813A1 (en) | 1984-04-21 | 1984-04-21 | Method of producing hexachloride triammonium bismuth (iii) |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| SU843733984A SU1184813A1 (en) | 1984-04-21 | 1984-04-21 | Method of producing hexachloride triammonium bismuth (iii) |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| SU1184813A1 true SU1184813A1 (en) | 1985-10-15 |
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ID=21116397
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| SU843733984A SU1184813A1 (en) | 1984-04-21 | 1984-04-21 | Method of producing hexachloride triammonium bismuth (iii) |
Country Status (1)
| Country | Link |
|---|---|
| SU (1) | SU1184813A1 (en) |
-
1984
- 1984-04-21 SU SU843733984A patent/SU1184813A1/en active
Non-Patent Citations (1)
| Title |
|---|
| Mel lor J.W, Comprehensive Treatise on Inorganic and Theoretical Chemistry. 1%0, т.9, с.664-665. Там же, с. 666, () * |
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