SI9300479A - Hair treatment agent - Google Patents

Abstract

The application relates to the use of a combination of active agents consisting of (A) alkoxylated lanolin alcohols and (B) a pyrrolidone carboxylic acid and/or a pyrrolidone carboxylic acid derivative of general formula (I) in which at least one of the constituents R1 to R3 stands for a -COOR4 group in which R4 is hydrogen, an alkaline metal ion, an alkaline earth metal ion or an ammonium ion +NHR5R6R7, in which R5 to R7 are mutually independently hydrogen, alkyl groups with 1 to 22 carbon atoms, hydroxyalkyl groups with 1 to 4 carbon atoms, alkenyl groups with 2 to 22 carbon atoms, acyl groups with 2 to 22 acyl atoms or possibly substituted aromatic groups with 6 to 10 carbon atoms, and the remaining constituents R1 to R3 are hydrogen or alkyl groups with 1 to 4 carbon atoms, in aqueous preparations for washing and the care of hair. It is thus possible to obtain a strong equalising effect with an amazingly high degree of hair care in the case of dyed hair.

Description

Applicant

HENKEL KGaA

Postfach 101100

D-Dusseldorf 1. Germany

Inventors *

1. Kurt Seidel, Nosthoffenstrasse 59, 4000 Dusseldorf 13, BRD

2. Dr. Reinhard Muller, Gottfried ~ Hausmann ~ Weg 13, 5140

Erkelenz 7, BRD

3. Dr. Detlef Hollenberg, Fliederweg 31, 4006 Erkrath, BRD

4. Manuela Ehlert, Humboldtstrasse 33, 5090 Leverkusen 3, BRD

Hair treatment consisting of alcohols of woolen wax and pyrrolidonecarboxylic acid

FIELD OF THE INVENTION

The field of the invention is a hair treatment preparation with a special combination of active substances.

Technical problem and state of the art

Hair cleaning and care is an important component of human body care. Both shampoo and hair styling

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Hairstyles, such as dyeing or permanent curls, are interventions that affect the natural composition and properties of hair. For example, wet and dry combing of hair, posture and fullness of hair may be unsatisfactory after such treatment, or the hair may show increased cleavage. In addition, it is often very problematic to evenly distribute dyes applied with hair dye products, especially on severely damaged hair.

It is therefore common for a long time to undergo special hair treatments. The hair is usually treated in the form of a rinse with special active substances, for example, with quaternary ammonium salts or special polymers. This treatment improves depending on the formulation of combing ability, posture and fullness of the hair and reduces the degree of cleavage. However, the results for chlorinated, damaged hair are not satisfactory.

It has now come as a surprise that agents with the combination of the agents of two specific, in each case for their usefulness in, hair treatments of known classes of active substances unexpectedly have a good effect on the properties of heavily damaged, colored hair. In the treatment of severely damaged hair color; by these means the strongest effect of eoalisation on. surprisingly high color protection. This allows it to be far more frequently brushed and subsequently treated before re-dyeing. In addition, it permits good biodegradability and the viability of the combination of substance-active substances - the fronnulation of products with good degradability as required by ecological considerations.

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Solution to a technical problem with description of implementation examples

The subject of the invention is therefore the use of a water-soluble preparation containing a combination of active substances consisting of (A) alkoxylated wool alcohols and (B) pyrrolidonicarboxylic acid and / or pyrrolidonicarboxylic acid derivative of general equation (I)

H ² _with B ⁵

H 'in which at least one of COOR ^ in which hydrogen, an alkali metal ion or ammonia (I) substituents R ¹ to R ³ represents an alkali metal group, the earth ion + NHR ⁵ R ⁶ r ⁷ in which

R “to R? independently of one another hydrogen, alkyl groups of 1 to 22 C atoms, hydroxyalkyl groups of 1 to 4 C atoms, alkenyl groups of 2 to 22 C atoms, acyl groups of 2 to 22 C atoms, or optionally substituted aromatic groups of 6 to The 10 C atoms, and the remaining substituents R ¹ to R ^3, are hydrogen or alkyl groups of 1 to 4 C atoms, as well as of conventional ingredients for hair treatment, in particular for cleansing and care.

ATTORNEY

The use of ethoxylated wool wax alcohols (for example, HPFiedler, Lexikon der Hilfsstoffe tur Pharmazie, Kosmetik und angrenzende Gebiete, 2nd edition, Editio Cantor Aulen ™ dorf, 1981, p. 724) is well known as well as compounds according to equation (T). (eg German patent application P 4131 898.6) for the treatment of 'hair'.

From German patent file DF.-C2-33 330628 (in particular example 2), skin protection and care lotions, ethoxylated wool fatty alcohols and the sodium salt of pi rolidonecarboxylic acid are known. However, no mention can be made of the effect of this combination on hair from this printed text.

Wool wax alcohols, also referred to as lanolin alcohols, are complex mixtures of sterols and aliphatic alcohols produced from wool. The main constituents of the wax wax alcohols are cholesterol, lanoesterin and the sterines derived therefrom, C ₁₈ ~ C3Q-n-alcohols, C ₁₆ -C ₂₆ -iso-alcohols, alkanediols and iso-alkanediols.

By converting these mixtures with alkylene oxides, in particular ethylene oxide and propylene oxide, alkoxy compounds are obtained which are known, inter alia, as emulsifiers, solubilizers, moisture retaining agents and conditioners.

These products do not usually represent any single alkoxylated compounds but exhibit, depending on the selected alkoxylation process, the apparently homogeneous partitioning. Given

ATTORNEY

the degree of alkoxylation refers in each case to the molar starting amounts of alcohol of wool and alkylene oxide.

The wax wax ethoxylated alcohols of the invention are preferred. Particularly preferred are ethoxylication rates of from 1 to 50, especially from 2 to 30.

Compounds (B) are 2-pyrrolidone derivatives. Preferred derivatives are 2-pyrrolidone-3-, -A-, and -5-carboxylic acids and their salts. Pred .....

The salts of these compounds are sodium, potassium, calcium, magnesium and such ammonium salts, in which the ammonium ion carries, in addition to hydrogen, one of the three C 1-4 alkyl groups.

Particularly preferred compounds (A) are 2-pyrrolidone-5-carboxylic acid and its salts. Sodium salt is particularly preferred.

According to the invention, the preparations used contain alkoxylated alcohols of wool. (A) in amounts of from 0.1 to 5% by weight, based on the total preparation. Compounds (B) are also preferably contained in amounts of 0.1 to 5% by weight.

Particularly well-suited for hair treatment are preparations containing, in addition to obligatorial components (A) and (B), a polymer compound. Preferred polymers are from the group of cationic, anionic and amphoteric polymers.

For nerve cationic polymers usually contain a quaternary atom

ATTORNEY

i177 · “b

Advantageous sludges, for example in the form of an ammonium group, thionic polymers are for example:

- Quaternary cellulose derivatives such as commercially available under the name Celquat ^R and polymer JR ^R. Compounds of Celguat H 100, Celguat L 200 and polymer JR ^R 400 are preferred quaternary cellulose derivatives.

- polysiloxanes with quaternary groups.

- polymer dimethylIdialylammonium salts and their copolymers. with esters and amides of acrylic acid and methacrylic acid. Under the designations Merquat ^R 100 (poly (dimethyldialylammonium chloride)) and Merquat ^R 550 (dimethyldialylammonium chloride-acrylamide-copolymer), commercially available products are an example of such cationic polymers.

- copolymers of vi is 1pirolidona quaternary derivatives dialkilaminoakrilata and methacrylate, for example as a way of example with diethyl quaternized vi not 1pirolidon- dime these 1 ami nome such ri 1 a t-copula name ri .. Such compounds are available under the designation Gafquat ^R 37-4 and Gafquat ^R 755 in store.

- vinylpyrrolidone-methoimidazolinecloride copolymers as offered under the code Luviquat ^R.

- Quaternary polyvinyl alcohol as well as under labels

- Polyquaternium 2,

- Polyquaternium 17,

- Polyquaternium 18 in

- Polyquaternium 27 known polymers with quaternary nitrogen atoms in the polymer main chain.

ATTORNEY

MILOS 'V L: IU ^ SN & VIC

61000 Ljubljana, Klagenfurt 177

The polymers for suitable anionic polymers of the invention are:

- polyacrylic and polymethacrylic acids, their salts, their copolymers with acrylic and methacrylic acid esters and their amides, and their dervates obtained by cross-linking with polyfunctional agents. Compounds of this type are available, for example under the names of Carbopol ^R 934, ^R Carbopol 934 P, Carbopol ^R 940, ^R Carbopol 950, Carbopol ^R 980 and ^R Hostacerin PN73.

I

- polyoxycarboxylic acids, such as polyketo and polyaldehydicarboxylic acids and their salts, such as POC ^R HS 5060 and POC ^R AS 5060.

- Crotonic acid polymers and copolymers with acrylic and methacrylic acid esters and amides, such as vinyl acetate-crotonic acid and vinyl acetate-vinylpropionate-crotonic copolymers. Compounds of this type are available as Luviset ^R CA - 66 and L..uviset ^R CAP.

Under the umbrella term ampopolymers are included amphoteric polymers, ie. polymers containing both free amino groups and free -C00H- or S0 ₃ H-groups in the molecule and capable of carrying out internal salts, two-polar polymers containing quaternary ammonium groups in the molecule and -C00 "- or - S0 ₃ " groups and such polymers containing -COOH- or -SO ₃ H groups and quaternary ammonium groups.

An example of a useful amphopolymer of the invention is an acrylic resin, obtainable under the name Amphomer ^, which represents a copolymer of tertiary butylaminoethylmethacrylate, N- (1,1,3,3-tetramethylbutyl) acrylamide, as well as two or more acrylic or methacrylic acid momers. and their simple esters.

Further useful ampho-polymers of the invention are named compounds in English Opening File 2 104 091, European Opening File 47714, European Opening File 217 274, European Opening File 283 817 and German Opening File 28 17369.

Preferably usable amphopolymers are such polymerizates which essentially consist of

a) Quaternary ammonium monomers according to general equation (II),

R ⁸ ~ CH = CR ⁹ -C0-Z- (C _n H _2n ) -N ^ ⁺ ) R ¹⁰ R ¹¹ R ¹² A ^ '^ (II) in which R ⁸ and R ^{9 are} each independently hydrogen or methyl group and R ^I0, R ¹¹ and R ¹² independently of each other an alkyl group having 1 to 4 carbon atoms, with a NH group or an oxygen atom, n is an integer from 2 to 5 and A ^ ~ ^ is an anion of an organic or inorganic acid and

b) monomeric carboxylic acids according to general equation (III)

R ¹³ -CH = CR ¹⁴ -COOH (III) in which R ^{1 2} and R ¹ independently of ^one another are hydrogen or methyl group.

These compounds can be used according to the invention both directly and in the form of a salt obtained by the neutralization of polymerizates, for example alkali hydroxide. Particularly preferred are those polymerisates using monomers of type (a) in which R ⁱ⁰ , R ^ ¹ and methyl groups, 1 group NH and ion are particularly preferred with regard to the details of the production of these polymerizates. halides, rnetoxysul f ata or ethoxysul f ata; acrylamidopropyl trimethylammonium chloride is a particularly preferred monomer (a), and acrylic acid is preferably used as the monomer (b) for the named polymerizates.

Preferably, the compositions of the invention contain cationic, anionic or amphoteric polymers in amounts of from 0.1 to 5% by weight, based on the total preparation.

The use of compositions containing a polymer from a group of amphoteric polymers is particularly preferred within the art of the invention.

In the art of the invention, such compositions containing additionally at least one surfactant selected from the group of cationic, anionic or nonionic surfactants are preferred.

Especially if the compositions of the invention are used as hair rinsing.

- 'TO is the preferred choice of surfactants from the group of cationic surfactants.

Examples of cationic surfactants used for hair treatment agents of the invention are, in particular, quaternary ammonium compounds. Preferred are ammonium halides, in particular chlorides and bromides, such as alkyltrimethylammonium chloride, dialkyldimethylammonium chloride, and trial which Imethylammonium chloride, insane. 1trimethylammonium chloride, steariltri methylammonium chloride, disteariIdimethylammonium chloride, lauriIdimethylammonium chloride, lauri1dimethylbenzylammonium chloride and tricetylmethylammonium chloride. Further applicable cationic surfactants are quaternary wound protein hydrolysates.

Cationic silicone oils are also suitable according to the invention, such as commercially available products Q2-7224 (manufacturer: Dow Corning; stabilized trimethylsilylamodimeticone), Dow Corning 929 emulsion (containing hydroxyl-amino-modified silicone, also referred to as amodimeticone), SM-2059 (manufacturer: General Electric), SLM-55 067 (manufacturer: Wacker). As well as Abil ^R - Quat 3270 and 3272 (manufacturer: Th. Goldschmidt; diquaternary polymethylsiloxane, Ouaternium - 80).

Alkylamidoamines, especially fatty acid amidoamines, available under the Tego Amid ^R S18 stear and lamidopropi '1 dimethyl lami n label, are distinguished in addition to their well-conditioning effect, especially by its good biodegradability.

Quaternary ester compounds are also very degradable.,

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/ «V, ₁₇₇ so-called Esterguats, such as under the trade mark Stepantex ^R distributed dialkylarnones ummetosul fat and meth 1-hydroxy laymen 1di al koi. you're a bow. alkyl -ammonium met os ul f at.

The quaternary sugar derivative used as a cationic surfactant is the commercial product Glucguat ^R 100, according to the CTFA -nomenclature Lauryl-Mmethy1-Gluceth-10 ~ Hydroxypropi1 Dimoni um Chloride.

In particular, preferred cationic surfactants are alkylamidoamines, quaternary ester compounds and quaternary sugar derivatives.

According to the invention, the shampoos used preferably contain surfactants from the group of anionic surfactants.

as anionic surfactants, suitable for use in the human body are suitable anionic surfactants. They are characterized by a water-soluble anion-releasing group such as e.g. a carboxylate, sulfate, sulfonate or phosphate group and a lipophilic alkyl group of about 10 to 22 C atoms. They may additionally be contained in a molecule of the glycol group or. half needle and col ester, amine ester groups as well as hydroxyl groups. Examples of suitable anionic surfactants are, in each case, in the form of sodium, potassium and ammonium as well as mono-, di- and t-alkanolammonium salts having 2 or 3 C atoms in the alkanol group,

..... linear fatty acids with 10 to 22 C atoms (soaps)

ATTORNEY

SAV J & ULADiFi-j

- ethercarboxylic acid of equation R-0- (CH ₂ ~ CH ₂ 0) _x CH _? -COOH in which R represents a linear alkyl group of 1.0 to 22 Catoms and x = 0 or 1 to Ιό,

- acyl sarcosides with 10 to 18 C atoms in the acyl group,

- acyltaurids with 10 to 18 C atoms in acyl groups.

- acylisethionates having 10 to 18 C atoms in the acyl group.

- a sulfo-succinic acid sulpho-succinic acid mono and dialkyl ester of 8 to 18 Catoms in the alkyl group and a sulpho-succinic mono-alkyl polyoxyethyl ester of 8 to 18 C atoms in the alkyl group and J. to 6 oxyethyl groups,

- linear alkanesulfonates having 12 to 18 C atoms,

- linear alpha-olefinsulfonates having 12 of the 18 C atoms,

- alpha-sulfo-fatty acid methyl ester of fatty acids with 12 to 18 C atoms,

- alkyl sulfates and alkylpolyglycoletersulfates according to the formula R-0CCH ₂ ~ CH ₂ O) - - OSO ^ H, in which R is preferably a linear alkyl group having 10 to 18 C atoms and x-0 or 1 to 12.

- mixtures of surfactant hydroxysulfonates according to DE-A-37 25 030,

- sulfated ethers of hydroxyalkyl polyethylene and / or hydroxyalkylenepropylene glycol according to DE-A-37 23 354,

- sulfonates of unsaturated fatty acids having 12 to 24 C atoms and 1 to 6 double bonds according to DE-A-3926344,

- tartaric acid and citric acid ester with alcohols representing the accumulated products of about 2-15 ethylene oxide and / or propylene oxide molecules on fatty alcohols of 8 to 22 C atoms.

Preferred anionic surfactants are alkylsulfates, alkyl polymers lycolet on

177 ersulfates and ether carbon ·! acid with 10 to 18 C atoms in the alkyl group and up to 12 glycol ether groups in the molecule, as well as 8 to 18 C atoms in the alkyl group and mono-alkylpolyoxyethyl ester sulfoacetic acid with 8 to 18 C atoms in the alkyl group and 1 to 6 oxyethyl groups.

Non-ionic surfactants contain as a hydrophilic group crazy. a polyol group, a polyalkylene glycol ether group or a combination of polyol and polyglycol ether groups. Such compounds are, for example:

- Additives of 2 to 30 moles of ethylene oxide and / or 0 to 5 moles of propylene oxide on linear fatty alcohols of 8 to 22 C atoms, of fatty acids of 12 to 22 C atoms, and of alkylphenols of 8 to 15 C atoms in an alkyl group,

- " ^c 22 ~ ^{rnor, o} " i ⁿ diester of the fatty acid of additive products of 1 to 30 moles of ethylene oxide per glycerin, ~ Cg - C ₂ 2 -alkylmono- and oligoglycosides and their ethoxylated analogs as well as

- Additive products of 5 to 60 moles of ethylene oxide on castor oil and hardened castor oil.

Compounds used as surfactants with alkyl groups may each be single substances. As a rule, however, it is preferable to proceed from the manufacture of these substances from native plant or animal raw materials, so that mixtures of the substance with different alkyl chain lengths independent of the raw material are obtained.

For surfactants, which represent the additive products of ethyl

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- 'T4 and / or propylene oxide on fatty alcohols or derivatives of these additive products, both products with a normal homologous distribution and those with a narrowed homologous distribution may be used. Normal homogeneous distribution is understood to mean mixtures of homologens obtained from the conversion of fatty alcohol and alkylene oxide when using alkali metals, alkali metal hydroxides or alkali metal alcohols as catalysts. Narrowed homologeneous distributions, however, are obtained when, for example, hydrotalcites, alkaline earth metal salts of ether carboxylic acids, oxides, hydroxides or alcoholates of alkaline earth metals are used as catalysts. The use of products with a narrow homologous distribution may be preferred.

Preferably, the compositions of the surfactant used according to the invention contain in amounts of from 0.5 to 30% by weight, in particular from 1 to 20% by weight, according to the respective preparation.

According to the invention, the compositions used exhibit a preferred pH between 2.5 and 7, especially between 4.0 and 6.0.

Any acid that can be used for cosmetic purposes may be used to adjust this pH. It may be advantageous to use an acid from the group of edible acids. Edible acids are those acids that are taken as part of a normal diet and have a positive effect on humans. ''

For example, edible acids are acetic, lactic, tartaric,

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which authorities with one ..

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O D v E T M i K / <'«malic, ascorbic and gluconic acid. Particularly preferred in the context of the invention is the use of citric and lactic acid.

The hair treatments used according to the invention are preferably rinses, shampoos, hair treatments, shampoos or dyes and color shades. The combination of active ingredients of the invention can be'used in hair dye products as well as in permanent curling treatments. Suitable uses are preferred means formulated as guided or guided .....

alcoholic solutions, jellies, creams or lotions.

Suitable uses and formulations may contain the compositions according to the invention for any particular purpose of using conventional cosmetic accessories.

Such common ingredients are:

- amphoteric surfactants such as N-alkylglycines, N-alkylpropionic acid, N-alkylamino-butyric acid, Naikyliminodipropionic acid, N-hydroxyethyl-Nalkylamidopropylglycine, N-alkyltaurine, N-alkylsilicosine, 2-alkylaminosinopropyl 18 C atoms in the alkyl group,

- 2-pole-ion surfactants, such as the so-called betaine and 2- · alk 1-3 'carboxylate, have 1 -3-hydroxyethyl-imidazoline,

- non-ionic polymers such as, for example, vinylpyrrolidone / vinyl acrylate, copolymers, polyvinylpyrrolidone and vinylpyrrolidone / vinyl acetate.

ATTORNEY

i. v

- direct drawing dyes,

- so-called coupling and development components as pre-products of oxidising dyes,

- reducing agents such as e.g. thioglycolic acid and its derivatives, thio-lactic acid, cysteamine, thio-iabolic ^: acid and

-mercaptoetansultonic acid,

- oxidizing agents such as hydrogen peroxide, potassium bromate and sodium bromate, thickening agents such as agar-agar, guar-gum, alginate and xanthan gum,

- Structures such as glucose and maleic acid,

- Hair-conditioning compounds such as phospholipids, for example soya-gelatin, egg lecithin and kefalin, as well as silicone oils, ~ protein hydrolysates, in particular hydrolysates of elastin, collagen, keratin, milk, egg whitening, soyaprotein, almond protein, pea protein, potato, potato maize protein and cereal protein, their fatty acid condensation products as well as quaternary protein hydrolysates.

- perfume oils, dimethylsorbitol and cyclodextrin,

- Solvent mediators such as ethanol, isopropanol, ethylene glycol, propylene glycol, glycerin and lengl diet. i col, ·· - dyes

dandruff active substances such as pyroctone, olamine and zinc omadine, ~ further pH adjusting agents,. \ r ~ \ 'gtlfiSAV

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- active substances such as panthenol, allantois, plant extracts and vitamins,

- light protection agents, ~ consistency providers such as sugar ester, polyolester or polyolalkyl ether,

- fats and waxes such as whale fat, beeswax, montane wax, paraffin And fatty alcohols.

- fatty acid alcoholamides,

- complex agents such as EDTA, NTA and phosphoric acid,

- swelling and penetration agents such as glycerin, propylene glycol monoethyl ether, carbonate, hydrogen carbonate, guanidine, urea as well as primary, secondary and tertiary phosphates,

- latex tempering agents,

- pearl gloss agents as monodistearate and ethylene glycol distearate,

- Propellants as propane-butane mixtures, N? O, dimethyl. ether,

COn and air as well as z_

- antioxidants

The combination of active ingredients of the invention is preferably used in such hair treatment agents that can be rinsed again after a certain period of action, which is typically between a few seconds and about 20 minutes.

The subject of the invention is therefore also a process for the treatment of hair. in which the hair is rinsed after treatment with the composition according to any one of claims 1 to 11, subsequently with water or a substance containing substantially

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ra. Cflov-ka 177 water.

The following examples should explain the subject of the invention in more detail.

Examples

A

I. Color - metric research for color retention in colored hair

Research Method

An eagle strand (naturally white, 2 g, about 15 cm long; Ea. Kerling) was tied at half height. To simulate severely damaged hair, the lower part of the strand was alternately cold-curled and ultra-blond twice. Cold curling was performed each time by treatment with an aqueous solution of cold-currying agent based on ammonium thioglycolate (30 minutes) followed by subsequent fixation with potassium bromate solution (10 minutes). Ultrablanding was performed with aqueous hydrogen peroxide solution and ammonium peroxide .....

of sidisulfate. The upper part was only ultra-blonded once to simulate a little damaged hair. Then, the entire strand was stained with the Poly Diadem Pflege Intensiv Tonung (mahogany-coral shade) product (HENKEL). In doing so, 4 <g color mixtures were used for i g hair strands. After a 30 minute running time, the strand was well rinsed with warm water (30 ° C) and dried with a hair dryer. The colored strand of hair was then stored at room temperature for 4 days.

After the color-metric determination of zero values, the hair strand was treated 6 times for 1 minute with the test mixture, and the hair strand was rinsed thoroughly after each treatment with water (30 ^e C) and dried with a hair dryer. Then a color-metric measurement was performed.

The measurement was performed with a Texflash (Fa. Datacolor) device with

Into the type of light D65 (daylight). In this case, the measuring experiment was fixed in a clamping device on a spectral photometer and the remission values were measured over a visible light region of 390-700 nm over a distance of 10 nm and treated with a computer. The computer program has determined the standard CIE (Commission Internationale de 1 'Eclairage) color values according to DIN 5033 and has calculated them in color distance numbers according to DIN 6174. The measurement values given below are each averaged from 4 measurement points per part of the strand.

The following sizes were determined:

Total color distance DE (relative to zero) of the heavily damaged part of the strand

Equalizing E (difference of total DE color distances after treatment of severely and slightly damaged hair)

Percentage of color strength With severely damaged part of the strand (zero value = 100%), the composition of the tested mixtures and the measurement values are given in Table 1.

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¹ natriumlauriletersulfate (about 28% of active substance; CTFA code: Sodium Laureth Sulfate) (HENKEL) ² fatty alcohol letersulfate-pearl egg-mixture (18.5% of active substance; CTFA-code: Sodium Laureth (in) Glycol Distearate) ( HENKEL) ³ 0 ^ 2-14 ~ fatty alcohol + 10 ethylene oxide acid acid sodium salt (22% of active substance; CTFA code: Sodium Laureth 11 Carboxylate) (CHEM-Y) ⁴ polyglycolester of fatty acid (HENKEL) ⁵ arnid derivative of fatty acid acids with betaine structure; CTFA code: Cocoamidopropyl Betaine (HENKEL) ^{6 c} 12 ” ^C 16” alkylglucoside with an oligomerization rate of 1.4 (about 50% of active substance; CTFA code: Lauryl Polyglycosid) (HENKEL) ⁷ lanolinal alcohol + 5 ethylene oxide (CTFA code: ( .aneth-5) (CORDA) ⁸ lanolinal alcohol + 20 ethylene oxide (CTFA code: Laneth - 20) (CORDA) ⁹ DL-2-pyrrolidone-5-carboxylic acid-sodium salt (about 50% of active substance; CTFA code: Sodium PCA ) (AJINOMOTO) * A copolymer of acrylamindopropyltrimethylammonium chloride of acrylic acid, neutralized with sodium hydroxide.

* II. Examples of use

The quantitative data in the following cases are by mass%.

I

1. Rinse your hair

Stanol ^R 1618 ¹⁰ 1.8 Tegoamide ^R S 18 ¹¹ 1.6 1,2-Propylene glycol 1.0 Citric acid 0.6 Polychol ^R 5 0.5 Ajidew ^R N 50 0.6 Perfume oil, water ad 100

^{10 c} 16 ^7c 18 ” ^ma alcohol (HENKEL)

I ¹¹ N, N-dimethyl N'-stearoyl-1,3-diamino-propane (FOUR code: Stearamidopropyl Dimethylamine) (GOLDSCHMIDT)

2. Rinse your hair

Stenol ^R 1618 1,8 Stepant.ex ^R VS 90 ¹² 1,8 1,2-Propylene glycol 0.7 Citric acid 0.9 Polychol ^R 5 0.5 Ajidew ^R N 50 0.8 Perfume oil, colorant, water ad 100 ¹² N ~ methyl ~ N (2 ~ hydroxyethyl) -N, N-di (tallowyloxyethyl) ammonium methosulfate (90% of the active substance in isopropanol) (STEPAN)

3. Rinse your hair

Stanol ^R 1618 2.5

Eumulgin ^R B l ¹³ 1.0

Eumulgin ^R B 2 ¹⁴ 1.0

Cutina ^R CP ¹⁵ 1.0

Eutanol ^R G ¹⁶ 0.5

Polawax ^R GP 200 ¹⁷ 0.75

Abil ^R Quat 3270 ¹⁸ 0.5

Dow Corning ^R 929-Emulsion ¹⁹ 2.6

Polychol ^R 5 1.0

Ajidew ^R N 50 1.5

Citric acid 0.02

Water ad 100 l ^ cetylstyrylalcohol with about 12 moles of EO (CTEA code: Ceteareth 12) (HENKEL) ¹⁴ cetylstyryl alcohol with about 20 moles of EO (CTFA code: Ceteareth - 20) (HENKEL) ¹⁵ esters of saturated long-chain fatty alcohols and fatty acids in particular palmitic acid cetyl ester (CTEA _t code: Cetyl Palmitate) (HENKEL)

J · ⁶ condensation product from saturated fatty alcohol liquids .....

hunting, predominantly decyl alcohol, prepared by the Guerbet reaction (CTEA code: Octyldodecanol) (HENKEL) ¹ 'mixture of sterile alcohol - polyethylene glycol stearate (CTEA code: Stearyl Alcohol (and) PEG - Stearate) (CORDA) diquarter oolimethylsiloxane (CTFA code); (GOLDSCHMIDT) ¹⁹ amino-functional polydimethylsiloxane (35% active substance) (DOW CORNING)

4. Hairwashing

Rewoquat ^R W 7500 ²⁰ 1.1 Lanette 0 ²ⁱ 3.0 Eumulgin ^R B 1 0.8 Eumulgin ^R B 2 1.6 Cutina ^R GMS ²² 0.5 Eutanol ^R G 1.0 Polychol ^R 5 2.0 Ajidew ^R N 50 1.5 Water ad 10

^υ 1-methyl-2-nortalgalkyl-3-acid sebaceous fat-amidoethyl-imidazoline methosulfate (about 75% of active substance) (R £ WO)

O 1.

a mixture of higher, saturated fatty alcohols, predominantly 1 and no p in t T N1

6'C C ··?

sterile alcohol (CTFA code: Cetearyl Alcohol) (HENKEL) ²² glycerin monostearate (CTFA code: Glyceryl Stearate) (HENKEL)

5. shampoo

Texapon ^R N 25 43,0 Dehy t.on ^R K 10,0 Plantar ^R ~ 1200 4.0 Euperlan ^R PK 3000 ²³ 1.6 Arquad ^R 316 ²⁴ 0.8 Polychol ^R 20 3.0 Ajidew ^R N 50 4.0 Glucamate ^R DOE 120 ²⁵ 0.5 Sodium chloride 0.2 Water ad 100

²³ liquid dispersion of substances giving pearly luster and amphotenside (about 62% of active substance; CTFA code: Glycol Distearate (and) Laureth-4 (and) Cocoamidopropyl Betaine) (HENKEL) ²⁴ tri-C ₁₆ -alkylmethylammonium chloride ( AKZO) ² ^ ethoxylated methylglucoside diolate (CTFA code: PEG 120 k '

Methyl Glucose Dioleate (AMERCHOL)

6. Shampoo

Texapon ^R N 70 ² ^ 21.0 Plantar ^R -1200 8.0 Genamin ^R DSAC ²⁷ 1,2 Cutina ^R EGMS ²⁸ 0.6 Polychol ^R 20 2.0 Ajidew A 100 ²⁹ 2.8 Antille ^R 141 ³⁰ 1.3 Sodium chloride 0.2 Magnesium hydroxide ap pH 4,5 Water ad 100

²⁶ sodium laurylethersulfate (about 72% active substance) (HENKEL) ²⁷ dirnetildistearylammonium chloride (HOECHST) ²⁸ ethylene glycol monostearate (about 25-35% monoester, 60-70% diester; CTFA code: Glycol Stearate) (HENKEL) ²⁹ DL-2-pyrrole 5-Carboxylic acid (CTFA code: PCA) (AJINOMOTO) f® polyoxyethylene-propylene glycoldioleate (40% active substance; CTFA code: Propylene Glycol (and) PEG - 55 Propylene Glycol Oleate) (GOLDSCHMIDT)

7. shampoo

T'exapon ^R K 14 S ³ ^ · 50.0 Dehyton ^R K 10,0 Akypo ^R RLM 100 NV 4.5 Polymer Pl corresponding to DE 39 29 9730,6 Cutina ^R AGS ³² 2.0 D-Pantenol 0.5 Glucose 1.0 Salicylic acid 0.4 Sodium chloride 0.5 Polychol ^R 20 2.5 Ajidew ^R N 50 2.0 Water ad 100

³¹ natriumlauryl myristyl ether sulfate (about 28¾ active substance; CTFA code: Sodium Myreth Sulfate) (HENKEL) ³² ethylene glycol stearate (about 5-15% monoester, 85-95¾ diester; CTFA code: Glycol Distearate) (HENKEL)

8. Shampoo

Texapon ^R K 14 S 25,0 Texapon ^R SB 3 ³³ 7.5 Eucarol ^R TA ³⁴ 12,0 Akypo ^R RLM 100 NV 9.0

Dehyton ^R AB 30 ³³ 8.3 Polymer Pl, corresponding to DE 39 29 973 0.6 Elfacos ^R GT 282S ³⁶ 0.5 Polychol ^R 2'0 4.0 Ajidew A 100 2.8 Sodium chloride 0.5

KOH ad pH 5.0

Water ad 100 ³³ sulfo-succinic acid polyester based on alkylpolyglycol ether, di-Na-salt (about 40% of the active substance; CTFA code: Disodium Laurethsulfosuccinate) (HENKEL) ³⁴ lauryl alcohol + 7 ethylene oxide-tartrate-sodium salt (about 35% of the active substance ; CTFA code: Sodium Laureth - 7 Tartrate) (AUSICHEM) ³⁵ fatty amine derivative with betaine composition (about 30% of active substance; CTFA code: Coco-Betaine) (HENKEL.) Talc + 60 ethylene oxide - myristyl ether (CTFA code: Talloweth ~ 60 Myristyl Glycol) (AKZO) * 9. Treatment Clip (Flush)

Stanol ^R 1618 3.0

Eumulgin ^R B 1 0.5

Eumolgin ^R B 2 0.5 Cutina ^R CP 1, 0 Eutanol ^R G 1.5 Hostacerin ^R PN 73 ³⁷ 0.004 Dow Corning ^R 929-emulsion 2.9 Polychol ^R 5 1.5 Ajidew ^R N 50 2.0 Water ad 100

Λ7 Polyacrylic Acid - Sodium Salt Copolymer (HOECHST)

10, Treatment Clip (Remains on Hair)

Celquat ^R L 200 ^ 8 o, 6

Luviskol ^R K30 ^ ⁹ 0.2

D-Panthenol 0.5

Polymer Pl corresponding to DE 39 29 973 0.6

Dehyquart ^R SP ^4C '1.0

Nutrilan ^R I ⁴¹ 1.0

Natrosol ^R 250 HR ⁴² 1.1

Polychol ^R 5 1.5

Ajidew ^R N 50 2.0

Water ad 100 quaternum cellulose derivative (95¾ active substances; CTFA code Polyquaternium -4) (DEL. FT NATIONAL)

OP ^{VCrM K}

³⁹ irrigated 1piralidone (95% active substance, CTFA code: PVP) (BASF) ⁴⁰ aqueous oxyethylalkylammonium phosphate solution (about 50% active substance; CTFA code: Quaternium - 52) (HENKEL) ⁴ ^ · collagenhydrolyzate (about 39% active substance CTFA code: Hydrolyzed Collagen (HENKEL) ⁴² hydroxyethylcellulose (AOUALON)

11. Coloring cream

Cl2-18fat alcohol 1,2 Lanette □ 4.0 Eumulgin ^R B 2 0.8 Cutina ^R KD 16 ⁴³ 2.0 Sodium sulphite 0.5 1 L (+) - Ascorbic acid 0.5 1,2-Propylene glycol 1,2 Polymer JR ^R 400 ⁴⁴ 0.3 p-Aminophenol 0.35 p-Toluylenediamine 0.85 2-Methylresorcin 0.14 6-Methyl-m-aminophenol 0.42 Polychol ^R 5 0.5 Ajidew ^R N 50 1,2

Ammonia

1.5

Water ad J. 00 Mono / diglyceride emulsifier fatty acid mixture (CTFA code: Tallow Glycerides (and) Glyceryl Stearate (and) Potassium Stearate) (HENKEL) ⁴⁴ Quaternary hydroxyethyl cellulose (UNION CARBIDE)

12. Developmental Dispersion for Dye Cream 11.

Texapon ^R N 25 2,1

Hydrogen peroxide (50%) 12.0

Turpinal ^R SL ⁴⁵ 1.7

Latecoll ^R D ⁴⁶ 12.0

Polychol ^R 20 0.9

Ajidew ^R N 50 0.3

Water ad 100

With l-hydroxyethane-l, l-diphosphonic acid (60% of active substance; CTEA code: Etidronic Acid) (HENKEL) ⁴ ^ Acrylester-methacrylic acid copolymer (25% of active substance) (BASF)

The coloring cream had a pH of 10.0. It caused intense red hair color.

13. shade shampoo

Texapon ^R N 70 14.0 Dehyton ^R K 10.0 Akypo ^R RLM 45 NV ⁴⁷ 14.7 Plantar ^R -1200 4.0 Polymer Pl, corresponding to DE 39 29 9730.3

Cremopho ir ^R RH 40 48 0.8 Dye C.I. 12 719 0.02 Dye C.I. 12 251 0.02 Dye C.I. 12 250 0.04 Dye C.I. 56 059 0.03 PHB-Este r 0.25 Perfume o oil is q.s. Polychol ^R 20 1.6 Ajidew ^R N 50 • 1,2 Water ad 100

⁴⁷ lauryl alcohol + 4,5 ethylene oxide - acetic acid - sodium salt (20,4% of active substance) (CHEI * 1-Y) ^{48 48} castor oil, hydrated + 45 ethylene oxide (CTFA code: PEG 40 Hydrogenated Castor Oil) (BASF) i

Washing your hair with this shampoo gives your hair a luminous, light blonde color.

17. Cream for permanent curls

Curl cream

Plantar ^R -800 ⁴⁹ 5.0 Eioglycolic acid 8.0 T urpinal ^R FIG 0.5 Ammonia (25%) 7.3 Ammonium carbonate 3.0 Chets 1 / Stearyl-Alcohol 5.0 Guer bet - Alcohol 4.0 Polychol ^R 5 3.0 Ajidew ^R N 50 2.0 Perfume oil q.s. Water ad 100

⁴⁹ C _a - - alkylglucoside with an oligomerization rate of 1.6 (ca.

60% of the active substance) (HENKEL)

Fixing solution

Plantar ^R -800 5.0 Hardened castor oil 2.0 Potassium bromate 3.5 Nitrilotriacetic acid 0.3 Citric acid • 0.2 Merquat ^R 550 ⁵⁰ 0.5

Polycho.l ^R 20 1.5 Ajidew ^R A 100 0.5 Perfume oil q.s. Water ad 100

⁵⁰ dimethyldialylammonium chloride - acrylamide - copolymer of a substance; CTFA code: Polyquarternium - 7) (MOBIL OIL.)% Active

Claims (12)

PATTERN APPLICATIONS Use of a water-soluble preparation containing a combination of active substances consisting of (A) alkoxylated wool wax alcohols and (B) pyrrolidone carboxylic acid and / or a pyrrolidone carboxylic acid derivative of general equation (I) (I) in which at least one of the substituents R ¹ to R ^{2 is a} group C00r4 in which R ^{4 is} hydrogen, an alkali metal ion, an alkaline earth metal ion or an ammonia ion + NHR ⁵ R ⁶ R ⁷ .in which R ⁵ to R ⁷ are independently hydrogen, alkyl groups of 1 to 22 C atoms, hydroxyalkyl groups of 1 to 4 C atoms, alkenyl groups of 2 to 22 C atoms, acyl groups of 2 to 22 C atoms or optionally substituted aromatic groups of 6 to 10 C atoms, and other substituents R ¹ to R ⁵ represent hydrogen or alkyl groups ..... pins with 1 to 4 C atoms, as well as the usual ingredients for hair treatment, especially for cleansing and care. MILOSA V 61000 Use according to claim 1, characterized in that it contains alkoxylated woolen alcohol (A) 1 to 50 molecules of ethylene oxide per molecule of alcohol. Use according to one of claims 1 or 2, characterized in that compound (B) according to general equation (I) is 2-pyrrolidone-5-carboxylic acid or a salt of this acid. Use according to claim 3, characterized in that compound (B) according to general equation (I) is the 2-pyrrolidone-5-carboxylic acid sodium salt. Use according to any one of claims 1 to 4, characterized in that it contains a preparation of 0.1 - 5% by weight of alkoxylated wool alcohols (A) and 0.1 - 5% by weight of compound (B). Use according to any one of claims 1 to 5, characterized in that the preparation further comprises an anionic, cationic or amphoteric polymer. Use according to claim 6, characterized in that the preparation contains an amphoteric polymer. Use according to any one of claims 1 to 7, characterized in that the preparation further comprises a surfactant selected from anionic or nonionic surfactants. Use according to claim 8., characterized in that the cationic surfactant selected from the group amidoami street «, Leiovška 17? group cationic h to contain the preparation of novel, quaternary ester compounds and quaternary sugar derivatives. Use according to claim 8, characterized in that the preparation comprises an anionic surfactant selected from the group of alkyl sulfates, alkyl ether sulfates, ether carboxylic acid and mono / and-dialkyl esters of sulfoartaric acid. Use according to any one of claims 1 to 10, characterized in that the preparation exhibits a pH value between 2.5 and 7. 12. A method for treating hair, characterized in that the hair is subsequently rinsed after treatment with the preparation according to any one of claims 1 to 11 with water or an agent containing substantially water.