SG11201810425QA - Isoparaffin-olefin alkylation - Google Patents

Isoparaffin-olefin alkylation

Info

Publication number
SG11201810425QA
SG11201810425QA SG11201810425QA SG11201810425QA SG11201810425QA SG 11201810425Q A SG11201810425Q A SG 11201810425QA SG 11201810425Q A SG11201810425Q A SG 11201810425QA SG 11201810425Q A SG11201810425Q A SG 11201810425QA SG 11201810425Q A SG11201810425Q A SG 11201810425QA
Authority
SG
Singapore
Prior art keywords
june
international
pct
isoparaffin
containing feed
Prior art date
Application number
SG11201810425QA
Inventor
Vinit CHOUDHARY
Jihad Dakka
Matthew Mettler
Ivy Johnson
Joshua Allen
Ajit Dandekar
Cynthia Omilian
Original Assignee
Exxonmobil Res & Eng Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Exxonmobil Res & Eng Co filed Critical Exxonmobil Res & Eng Co
Publication of SG11201810425QA publication Critical patent/SG11201810425QA/en

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7038—MWW-type, e.g. MCM-22, ERB-1, ITQ-1, PSH-3 or SSZ-25
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0018—Addition of a binding agent or of material, later completely removed among others as result of heat treatment, leaching or washing,(e.g. forming of pores; protective layer, desintegrating by heat)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/06—Washing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/54—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition of unsaturated hydrocarbons to saturated hydrocarbons or to hydrocarbons containing a six-membered aromatic ring with no unsaturation outside the aromatic ring
    • C07C2/56—Addition to acyclic hydrocarbons
    • C07C2/58—Catalytic processes
    • C07C2/62—Catalytic processes with acids
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00—Liquid carbonaceous fuels
    • C10L1/10—Liquid carbonaceous fuels containing additives
    • C10L1/14—Organic compounds
    • C10L1/16—Hydrocarbons
    • C10L1/1608—Well defined compounds, e.g. hexane, benzene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L10/00—Use of additives to fuels or fires for particular purposes
    • C10L10/10—Use of additives to fuels or fires for particular purposes for improving the octane number
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2270/00—Specifically adapted fuels
    • C10L2270/02—Specifically adapted fuels for internal combustion engines
    • C10L2270/023—Specifically adapted fuels for internal combustion engines for gasoline engines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Polarising Elements (AREA)

Abstract

INTERNATIONAL APPLICATION PUBLISHED UNDER THE PATENT COOPERATION TREATY (PCT) (19) World Intellectual Property 1 MEM 0 11101 HOE 010 1111 1 0 01 OH OH 010 HO HO 110 11110 1111 MI Organization International Bureau (10) International Publication Number (43) International Publication Date .......'\"\" WO 2017/222770 Al 28 December 2017 (28.12.2017) WIP0 I PCT (51) International Patent Classification: (74) Agent: WARD, Andrew, T. et al.; ExxonMobil Research C07C 2/62 (2006.01) CO7C 9/21 (2006.01) and Engineering Company, 1545 Route 22 East, P.O. Box CO7C 9 / 1 6 (2006.01) 900, Annandale, NJ 08801-0900 (US). (21) International Application Number: (81) Designated States (unless otherwise indicated, for every PCT/US2017/035363 kind of national protection available): AE, AG, AL, AM, (22) International Filing Date: AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, 01 June 2017 (01.06.2017) CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, (25) Filing Language: English HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, (26) Publication Language: English KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, (30) Priority Data: PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, 62/353,666 23 June 2016 (23.06.2016) US SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, 62/353,671 23 June 2016 (23.06.2016) US TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW. 62/353,687 23 June 2016 (23.06.2016) US (84) Designated States (unless otherwise indicated, for every 62/353,675 23 June 2016 (23.06.2016) US kind of regional protection available): ARIPO (BW, GH, 62/353,684 23 June 2016 (23.06.2016) US GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, (71) Applicant: EXXONMOBIL RESEARCH AND EN- UG, ZM, ZW), Eurasian (AM, AZ, BY, KG, KZ, RU, TJ, GINEERING COMPANY [US/US]; 1545 Route 22 East, TM), European (AL, AT, BE, BG, CH, CY, CZ, DE, DK, _ P.O. Box 900, Annandale, NJ 08801-0900 (US). EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, — MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, = (72) Inventors: CHOUDHARY, Vinit; 57 La Costa Dr., An-TR), OAPI (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, nandale, NJ 08801 (US). DAKKA, Jihad, M.; 3 Gleim KM, ML, MR, NE, SN, TD, TG). Rd., Whitehouse Station, NJ 08889 (US). METTLER, _ Matthew, S.; 295 N. Bridge St., Somerville, NJ 08876 = Published: (US). JOHNSON, Ivy, D.; 4 Winthrop Rd., Lawrenceville, _ with international search report (Art. 21(3)) = NJ 08648 (US). ALLEN, Joshua, W.; 3 Pine Ave., Branch- _ = burg, NJ 08876 (US). DANDEKAR, Ajit, B.; 15 Hickory Ct., Clinton, NJ 08809 (US). OMILIAN, Cynthia, F.; 2 Coddington Rd., Whitehouse Station, NJ 08889 (US). = = (54) Title: ISOPARAFFIN-OLEFIN ALKYLATION = = = . * = . = — ! 0.07 OLHSV 0.03 OLHSV 9 60 = % _ > _ c = 0 v 40% - - 65% n-05=-35% 241-2- Butene - e.0 Li-ISV C 1+7. is4 — 5 20% AVBend MCM-49 (80/20) - 1-1 0% - 14-25 mesh 150C ,N GS= Conveirsion I 1 p ti, t k ,, 0 0 10 20 30 IN IN Days on Oil N el Figure 1 el IN 1-1 (57) : In a process for the catalytic alkylation of an olefm with an isoparaffin, an olefin-containing feed is contacted with an 0 el isoparaffm-containing feed under alkylation conditions in the presence of a solid acid catalyst comprising a crystalline microporous material of the MWW framework types, wherein the olefm-containing feed consists essentially of pentenes.
SG11201810425QA 2016-06-23 2017-06-01 Isoparaffin-olefin alkylation SG11201810425QA (en)

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US201662353675P 2016-06-23 2016-06-23
US201662353666P 2016-06-23 2016-06-23
US201662353687P 2016-06-23 2016-06-23
US201662353684P 2016-06-23 2016-06-23
US201662353671P 2016-06-23 2016-06-23
PCT/US2017/035363 WO2017222770A1 (en) 2016-06-23 2017-06-01 Isoparaffin-olefin alkylation

Publications (1)

Publication Number Publication Date
SG11201810425QA true SG11201810425QA (en) 2019-01-30

Family

ID=59054284

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201810425QA SG11201810425QA (en) 2016-06-23 2017-06-01 Isoparaffin-olefin alkylation

Country Status (5)

Country Link
US (2) US20170369392A1 (en)
EP (1) EP3475250B1 (en)
CN (1) CN109311781A (en)
SG (1) SG11201810425QA (en)
WO (1) WO2017222770A1 (en)

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3865894A (en) * 1966-08-25 1975-02-11 Sun Oil Co Pennsylvania Process for paraffin-olefin alkylation
US5254792A (en) * 1991-10-10 1993-10-19 Mobil Oil Corporation Isoparaffin:olefin alkylation in the presence of synthetic porous MCM-49
US5420093A (en) * 1991-10-25 1995-05-30 Institut Francais Du Petrole Catalyst based on silica and sulfuric acid and its use for the alkylation of paraffins
DE69207548T2 (en) * 1991-10-25 1996-05-15 Inst Francais Du Petrol Use of a catalyst for the alkylation of paraffins
US5304698A (en) * 1992-08-10 1994-04-19 Mobil Oil Corporation Solid catalyzed supercritical isoparaffin-olefin alkylation process
US5258569A (en) * 1992-08-13 1993-11-02 Mobil Oil Corp. Isoparaffin-olefin alkylation process with zeolite MCM-36
US5406018A (en) * 1992-12-21 1995-04-11 Kerr-Mcgee Corporation Homogenous catalyst and process for liquid phase isomerization and alkylation
US5625113A (en) * 1993-10-28 1997-04-29 Mobil Oil Corporation Isoparaffin/olefin alkylation
US5780703A (en) * 1994-05-02 1998-07-14 Mobil Oil Corporation Process for producing low aromatic diesel fuel with high cetane index
CN100528817C (en) * 2001-06-08 2009-08-19 阿尔伯麦尔荷兰有限公司 Process for catalytic alkylation of hydrocarbons
US6756030B1 (en) * 2003-03-21 2004-06-29 Uop Llc Crystalline aluminosilicate zeolitic composition: UZM-8
CA2562905C (en) * 2004-04-20 2011-10-11 Uop Llc Uzm-8 and uzm-8hs crystalline aluminosilicate zeolitic compositions and processes using the compositions
US20100263262A1 (en) * 2009-04-10 2010-10-21 Exxonmobil Research And Engineering Company Unleaded aviation gasoline
US7982084B1 (en) * 2010-03-31 2011-07-19 Uop Llc Processes using UZM-37 aluminosilicate zeolite
JP6211714B2 (en) * 2014-01-27 2017-10-11 エクソンモービル ケミカル パテンツ インコーポレイテッド Synthesis of molecular sieve with MWW skeleton structure

Also Published As

Publication number Publication date
US20180282241A1 (en) 2018-10-04
US20170369392A1 (en) 2017-12-28
CN109311781A (en) 2019-02-05
WO2017222770A1 (en) 2017-12-28
EP3475250B1 (en) 2020-12-16
EP3475250A1 (en) 2019-05-01

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